5.1 Nature of Pollution. .

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5.1 Nature of Pollution

https://www.youtube.com/watch?v=vPOrywC0k9I

Sub-subtopics

5.1.1 Define the term pollution.5.1.2 Distinguish between the terms point source pollution and non-point source pollution, and outline the challenges they present for management.5.1.3 State the major sources of pollutants.

5.1.1 Pollution

●“the addition to the biosphere of a substance or an agent (such as heat) by human activity, at a rate greater than that at which it can be rendered harmless by the environment.” – Rutherford, pg. 276

3.1.1 Examples of Pollution

●Gases●CO2?●Ozone (O3)?●Liquids●Solids●Noise●Light●Heat

5.1.2 Point Source Pollution

Pollution from an easily recognizable, single siteChernobyl (26 April, 1986)Bhopal, India (2-3 December, 1984)

Tailpipe of a car (multiple point sources can act as a non-point source)Easy to manage/regulate

Identifiable source (factory chimney, waste disposal pipe, oil tanker, etc.)

Identifiable culprit (factory, house, drilling platform, etc.)

5.1.2 Non-point Source Pollution

Pollution released from numerous, widely dispersed sitesChemical fertilizersNeighborhoods/citiesRunoff

Difficult to manage/regulate

Who is the culprit?

More widespread laws difficult to enforce

Air pollution spreads hundreds of kilometers

http://lab.visual-logic.com/wp-content/uploads/2010/02/image.png

Sources and Effects

http://www.nature.nps.gov/air/aqbasics/images/AQBasicSources.gif

5.1.3 Major Pollutants(from Rutherford, table 15.1, pg 277)

MAJOR SOURCE

POLLUTANT EFFECTS

Combustion of fossil fuels

●Carbon dioxide CO2

●Sulfur dioxide SO2

●Nitrogen oxides NOX

●Photochemical smog●Carbon monoxide CO

●Greenhouse gas; climate change●Acid deposition; respiratory problems●Respiratory infections, eye irritation, smog●Damages plants, eye irritation, respiratory problems●Suffocation (binds w/ hemoglobin in red blood cell)

Domestic waste

●Organic waste (food & sewage)●Waste paper●Plastics (containers & packaging)●Glass●Tins

●Eutrophication; water-borne diseases●Landfill; deforestation●Landfill; derived from oil●Manufacturing energy; landfill (recyclable)●Landfill (recyclable)

Industrial waste

●Heavy metals (Hg, Pb, Cd, etc.)●Fluorides●Heat●Lead●Acids

●Poisoning●Poisoning●Reduces oxygen solubility (BOD)●Disabilities in children; poisoning●Corrosive

Agricultural waste

●Nitrates●Organic waste●Pesticides

●Eutrophication●Eutrophication; spread diseases●Biomagnification; bioaccumulation

5.1.3 AIR Pollutants – EU

Korea & the U.S.

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5.1.3 Major Pollutants – AIR

INDOOR

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5.1.3 Major Pollutants - WATER

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5.1.3 Major Pollutants - LAND

Retrieved on 03-11-2011 from: http://visual.merriam-webster.com/images/earth/environment/land-pollution.jpg

5.2 Detection & Monitoring of Pollution

Sub-subtopics

5.2.1 Describe two direct methods of monitoring pollution.5.2.2 Define the term biochemical oxygen demand (BOD) and explain

how this indirect method is used to assess pollution levels in water.5.2.3 Describe and explain an indirect method of measuring pollution

levels using a biotic index.

5.2.1 Methods of MonitoringWhere to start?

AIR

WATER

LAND

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What to do?

DIRECT

INDIRECT

CHANGES

GradientsTime periods

Transects

Particulate Matter (PM)● Removed by rain

Sheets of glue-coated paper with grids for standard amount of time.

● microscope/magnifying lens● % coverage● # of specimens

NumberSizeLocation

Sources of error?

5.2.1 Monitoring AIR Quality

Soil (edaphic) factors● physical properties● chemical properties● biological properties● processes● characteristics

No one measure is an indicator:● texture● density● infiltration● water retention● organic matter● mineral content (N, P, K)● microbial biomass● soil respiration

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5.2.1 Monitoring SOIL Quality

Secondary Data Sources:● World - HWSD and ISRIC● Czech Republic - ČPS● EU - JRC’s LUCAS● U.S. - NRCS● China - MLR ● India - IISS (for soil types)● Russia - VINITI● Australia - GRDC and

soilquality.org● South Africa - ARC-ISCW

What they measure:● same as last slide● degradation/aggradation

Retrieved on 01-11-2103 from: http://soilquality.org/images/dynamic_graph.gif

Direct Sampling Methods(chemical indicators)● salinity (probe)● pH (probe; universal indicator paper)● temperature (probe)● Dissolved Oxygen (DO probe)● wave action● flow velocity (orange)● turbidity (secchi disk)

○ Total Suspended Solids (TSS)○ Total Dissolved Solids (TDS)

● Biochemical Oxygen Demand (BOD)● Chemical Oxygen Demand (COD)● nitrates (No3

- probe; test kit)● ammonia (NH3 probe; test kit)● phosphate (probe; test kit)● conductivity (probe)

5.2.1 Monitoring WATER Quality

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5.2.1 Monitoring WATER Quality

Secondary Data Sources:● Czech Republic - ČHMI● EU - WISE● U.S. - NWQMC● China - IPE ● India - CPCB’s NWMP● Russia - VINITI● Brazil - ANA● Australia - NWQMS● South Africa - WMS● Egypt - EMWIS-EG

What they measure:● same as last slide● hardness● potability

Retrieved on 01-11-2013 from: http://ks.water.usgs.gov/pubs/reports/wrir.00-4126.cov.ill.jpeg

5.2.2 B.O.D.Biological Oxygen Demand (BOD5)● First done in England 1912● measures organic pollution in H2O (aerobic bacteria & fungus)● units: mg (O2 consumed)/L● usually 5 days incubation at 20 ºC

○ 68% of BOD exerted after this time● tests vary 10-20%● Indirect method

Chemical Oxygen Demand

Retrieed on 04-11-2013 from: http://www.bre.umd.edu/agtopics/pict/bodpict.gif

5.2.2 B.O.D.

Steps for measuring Biological Oxygen Demand (BOD5)

1. Sample H2O of measured volume

2. Measure the O2 level (probe)3. Place sample in a dark, 20 ºC

place for 5 daysa. Why in the dark?

4. After 5 days, remeasure O2

5. BOD5 = (Step 2 - Step 4) / L

Retrieved on 04-11-2013 from: http://www.globalw.com/images/products/OxiTop.jpg

The greater the organic matter (nutrient load), the greater the BOD5 number

● sewage● fertilizer● runoff● detergents● others?

Municipal sewage (3-stage process): BOD ~20 mg/L

Untreated sewage● Europe: BOD ~600 mg/L● U.S.: BOD ~200 mg/L

(greater per capita water use)

What is ppm?

5.2.2 B.O.D.

Retrieved on 04-11-2013 from: http://www.enright.ie/wp-content/uploads/2008/10/bod-levels.jpg

Eastern European Sewers

Retrieved on 04-11-2013 from: http://wwws4.eea.europa.eu/data-and-maps/figures/changes-in-wastewater-treatment-in-countries-of-europe-between-1980s-and-2005-east-3/csi24_fig5_291008.xls/image_large

5.2.2 Nutrients in European Freshwater

The greater the organic matter (nutrient load), the greater the BOD5 number

● sewage● fertilizer● runoff● detergents● others?

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5.2.3 Biotic IndicatorsAnother indirect method: Indicator Species● tolerant of organic pollution and/or low O2 levels● intolerant of organic pollution and/or low O2 levels

● More dangerous in summer○ solubility of O2 as temperature○ warm organic pollutants do the same

● Tubifex vs. mayfly nymph?● Others: fish, underwater plant life, algae (diatoms), bacteria (fecal

coli)

Retrieved on 04-11-2013 from: http://www.ib.bioninja.com.au/_Media/indicator_species.jpeg

5.2.3 Trent Biotic Index

Based on disappearances

Measures diversity● Generally, pollution , diversity

○ abundance may be high, but low richness

● Maximum value = 10

Retrieved on 04-11-2013 from: http://nationalinsectweek.co.uk/sites/default/files/images/pollutdetect.gif

5.2.3 Trent Biotic Index

Retrieved on 04-11-2013 from: http://click4biology.info/c4b/D/G4.htm