Background to Research Leading to Development of...

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Background to Research Leading to Development of Upflow

Filtration Lisa Glennon Hydro International, Inc. Portland, ME Robert Pitt Department of Civil, Construction, and Environmental Engineering University of Alabama, Tuscaloosa, AL Uday Khambhammettu Metcalf & Eddy, Inc. San Diego, CA

• Critical source area controls are important components of a comprehensive stormwater management program

• Pollution prevention, outfall controls, better site design, etc., are usually also needed

• In contaminated areas, infiltration should only be used cautiously, after pre-treatment to minimize groundwater contamination

Large parking areas, convenience stores, and vehicle maintenance facilities are usually considered critical source areas.

Storage yards, auto junk yards, and lumber yards

along with industrial storage areas, loading docks, refueling areas, and manufacturing sites.

Measured Particle Sizes, Including Bed Load Component, at Monroe St. Detention Pond, Madison, WI

Need to remove very small particles for high levels of stormwater control

High levels of pollutant reduction require the capture of very fine particulates, and likely further capture of “dissolved” pollutant fractions.

Analyte % Ionic % ColloidalMagnesium 100 0Calcium 99.1 0.9Zinc 98.7 1.3Iron 97 3Chromium 94.5 5.5Potassium 86.7 13.3Lead 78.4 21.6Copper 77.4 22.6Cadmium 10 90

Filtered Sample Ionic and Colloidal Associations

Most of the “dissolved” stormwater metals are in ionic forms and are therefore potentially amenable to sorption and ion-exchange removal processes.

Development of Stormwater Control Devices using Media

• Multiple treatment processes can be incorporated into stormwater treatment units sized for various applications. – Gross solids and floatables control (screening) – Capture of fine solids (settling or filtration) – Control of targeted dissolved pollutants

(sorption/ion exchange)

Pilot-Scale Treatment Tests using Filtration, Carbon Adsorption, UV Disinfection, and Aeration

Pilot-scale filters examining many different media.

Lab and pilot-scale filters and multi-chambered treatment train (MCTT)

MCTT Cross-Section

Pilot-Scale Test Results for SS

Pilot-Scale Test Results for Zn

Milwaukee, WI, Ruby Garage Public Works Maintenance Yard MCTT Site

Minocqua, WI, MCTT Installation

Wisconsin Full-Scale MCTT Test Results (median % reductions and median effluent quality)

Milwaukee (15 events)

Minocqua (7 events)

Suspended Solids 98 (<5 mg/L) 85 (10 mg/L)

Phosphorus 88 (0.02 mg/L) >80 (<0.1 mg/L)

Copper 90 (3 µg/L) 65 (15 µg/L)

Lead 96 (1.8 µg/L) nd (<3 µg/L)

Zinc 91 (<20 µg/L) 90 (15 µg/L)

Benzo (b) fluoranthene >95 (<0.1 µg/L) >75 <0.1 µg/L)

Phenanthrene 99 (<0.05 µg/L) >65 (<0.2 µg/L)

Pyrene 98 (<0.05 µg/L) >75 (<0.2 µg/L)

Water Environment Research Foundation (WERF) project on Metals Removal from Stormwater

Main Project Goals: • Contribute to the science of metals’ capture from urban

runoff by filter media and grass swales. • Provide guidelines to enhance the design of filters and

swales for metals capture from urban runoff.

Media Filtration Goals: • Characterize physical properties • Assess & quantify ability of media to capture metals • Rank media & select media for in-depth study • Evaluate effect of varying conditions on rate and extent of

capture • Laboratory- and pilot-scale studies of pollutant removal • Disposal issues of used media (using TCLP)

Treatment Media Examined during WERF Study

• Traditional Media – Ion Exchange Resin – Granular activated

carbon (GAC) – Sand

• Other Low Cost (disposable) media – Compost – 2 Zeolites – Iron Oxide Coated Sand – Agrofiber – Cotton Mill Waste – Peat-Sand Mix – Kudzu – Peanut Hull Pellets

• Metals Examined - Copper, Cadmium, Chromium, Zinc, Lead, and Iron

Laboratory Media Studies • Rate and Extent of Metals Capture – Capacities

(partitioning) – Kinetics (rate of

uptake)

• Effect of pH & pH changes due to media, particle size, interfering ions, etc

• Packed bed filter studies

• Physical properties and surface area determinations

Cation Exchange Capacities for Different Media

CEC (meq/100 g) Peat Moss 22

Compost 19

Activated Carbon 5.4

Zeolite 6.9

Cotton Waste 3.8

Agrofiber 9.4

Sand 3.5

Contaminant Losses during Anaerobic vs. Aerobic Conditions between Events

Pilot-Scale Downflow Filtration Setup

Media Investigated: • Activated Carbon • Zeolite • Sand • Lightweight Sand • Loamy Soil • Municipal Leaf

Compost • Peat Moss • Kenaf Fiber • Cotton Textile Waste

Pilot-Scale Filtration Setup after Pre-Treatment by Stormwater Pond

Clogging Problems Originally Addressed by Pre-Treatment. What about Upflow Filtration?

Expected Advantages: • Reduced Clogging: Sump

collects large fraction of sediment load.

• Prolonged Life: Particles trapped on the surface of the media will fall into the sump during quiescent periods.

• High Flow Rates: Since large and heavy solids will be removed by way of settling in the sump prior to encountering the filter, the filters can be operated at higher flow rates.

No sump

With sump

Upflow Filter Design with Sump

Upflow Filters for Metals Removal

Pressure gage

•Sump

• Particulate Solids: Good removal (>90%) for all media for all runs.

• Particulate Metals: Generally 80-100% removal for Pb, Zn, Cd, and Fe and 60-95% removal for Cu and Cr.

• Peat had the best removal rates for particulate bound metals. Removal rates of compost and zeolite were about the same.

Main features of the MCTT can be used in smaller units. The Upflow FilterTM uses sedimentation (22), gross solids and floatables screening (28), moderate to fine solids capture (34 and 24), and sorption/ion exchange of targeted pollutants (24 and 26).

Upflow filter insert for catchbasins

Upflow FilterTM patented

Successful flow tests using prototype unit and mixed media as part of EPA SBIR phase 1 project (controlled lab tests). Phase 2 tests recently completed (field tests), and ETV testing now starting.

15 to 20 gpm/ft2 obtained for most media tested

0 2 4 6 8 10 12 14

Residence Time, minutes

al Series1Series2Series3

80 to 90% removal of dissolved zinc using sand/peat upflow filtration

0 5 10 15 20

Headloss (inches)

Test site drainage area, Tuscaloosa, AL (anodized aluminum roof, concrete and asphalt parking areas; total of 0.9 acres)

EPA SBIR2 UpFlowTM Filter tests using Frankenstein 2 prototype

Support material and media

EPA-funded SBIR2 Field Test Site Monitoring Equipment, Tuscaloosa, AL

Flow tests (300 gpm) for bypass capacity

Treatment Flow Rates for Mixed Media

Performance Plot for Mixed Media on Suspended Soilds for Influent Concentrations of 500 mg/L, 250mg/L, 100 mg/L and 50 mg/L

Influent Conc. Effluent Conc.

High Flow 500

Mid Flow 500

Low Flow 500

High Flow 250

Mid Flow 250

Low Flow 250

High Flow 100

Mid Flow 100

Low Flow 100

High Flow 50

Mid Flow 50

Low Flow 50

Media (each bag)

Flow (gpm)

Influent SS Conc.

(mg/L)

Average Effluent SS

Conc. (mg/L)

% SS reduc.

Zeo+ Zeo High (21) 480 75 84 Zeo+ Zeo Mid (10) 482 36 92 Zeo+ Zeo Low (6.3) 461 16 97 Mix + Mix High (27) 487 75 85 Mix + Mix Mid (15) 483 42 91 Mix + Mix Low (5.8) 482 20 96

Suspended Solids Removal Tests

Zeo: Manganese-coated zeolite Mix: 45% Mn-Z, 45% bone char, 10% peat moss

Performance Plot for Particle Size Distributions

0102030405060708090

0.1 1 10 100 1000 10000

Particle Size (um)

Influent PSD50 mg/L High Flow50 mg/L Mid Flow50 mg/L Low Flow100 mg/L High Flow100 mg/L Mid Flow100 mg/L Low Flow250 mg/L High Flow250 mg/L Mid Flow250 mg/L Low Flow500 mg/L High Flow500 mg/L Mid Flow500 mg/L Low Flow

Upflow Filter Mixed Media Tests (Mn-coated Zeolite, Bone Char, Peat Moss)

0 to 0.45 µm (TDS)

concentration in particle size range (mg/L):

350 m/day (or less)

760 m/day

1200 m/day (to

overflow) 69 (and smaller) 0 0 0

70 0 0 0 80 0 0 0

93 (and larger) 0 0 0 0.45 to 3 µm

2.1 (and smaller) 0 0 0

4.2 0 0 0 10.4 80 42 26

20.8 (and larger) 80 62 34 60 to 120 µm

4.4 (and smaller) 95 95 95 8.9 97 97 97

22.2 98 97 97 44.4 (and larger) 98 98 98

% Reductions

100806040200

60504030

Mean0.771

84.17 10.81 12 0.402 0.302

StDev N AD P78.25 13.71 12 0.224

VariableInfluent (mg/L)Effluent (mg/L)

Normal Probability Plot of Concentration for Particle Range 0-0.45 um

2520151050

60504030

Mean0.011

5.215 3.384 12 0.500 0.167

StDev N AD P9.36 7.604 12 0.942

VariableInfluent (mg/L)_1Effluent (mg/L)_1

Normal Probability Plot of Concentration for Particle Range 0.45-3 um

100806040200-20

99.9999

Mean0.011

0.6858 0.9493 12 1.699 <0.005

StDev N AD P19.98 16.23 12 0.942

Normal Probability Plot of Concentration for Particle Range 60-120 um

3002001000-100

60504030

Mean0.011

* * 12 *

StDev N AD P113.2 91.94 12 0.942

Normal Probability Plot of Concentration for Particle Range >240 um

August 29, 2005 Hurricane Katrina Rainfall and Runoff and Sampling Periods

Treatment Flow Rate Changes during 10 Month Monitoring Period

Treatment Flow Rates needed for Seattle, WA

Treatment Flow Rates needed for Atlanta, GA

1 10 100 1000

Influent Suspended Solids (mg/L)

70 to 90% SS reductions for influent concentrations >80 mg/L

1 10 100 1000

Influent Suspended Solids (mg/L)

Effluent SS <100 mg/L whenever influent is <500 mg/L

Particulate Solids Removal by Particle Size, during Monitoring Period (UpFlow Filter, with Sump)

COD and phosphorus concentrations as a function of particle size

Copper and zinc concentrations as a function of particle size

UpFlow Filter™

Components: 1. Access Port 2. Filter Module Cap 3. Filter Module 4. Module Support 5. Coarse Screen 6. Outlet Module 7. Floatables

Baffle/Bypass

Hydro International, Ltd.

Upflow Filter Components

1. Module Cap/Media

Restraint and Upper Flow Collection Chamber

2. Conveyance Slot 3. Flow-distributing

Media 4. Filter Media 5. Coarse Screen 6. Filter Module

Hydraulic Characterization

Assembling Upflow Filter modules for lab tests Initial CFD

Model Results

High flow tests

Operation during normal and bypass conditions

Draindown between events

ETV test setup at Penn State - Harrisburg

Upflow Filter can be evaluated in WinSLAMM

Conclusions • The bench-scale treatability tests conducted during

the development of the MCTT showed that a treatment train was needed to provide redundancy because of frequent variability in sample treatability storm to storm, even for a single sampling site.

• Possible to develop other stormwater controls that

provide treatment train approach. • Upflow filtration with a sump and interevent drainage

provided the best combination of pre-treatment options and high flow capacity, along with sustained high contaminant removal rates.

Conclusions (continued) Constituent and units

Reported irreducible concentrations (conventional high-level stormwater treatment)

Effluent concentrations with treatment train using sedimentation along with sorption/ion exchange

Particulate solids (mg/L)

10 to 45 <5 to 10

Phosphorus (mg/L)

0.2 to 0.3 0.02 to 0.1

TKN (mg/L) 0.9 to 1.3 0.8 Cadmium (µg/L) 3 0.1 Copper (µg/L) 15 3 to 15 Lead (µg/L) 12 3 to 15 Zinc (µg/L) 37 <20

Selected References • Barrett, M. Performance Summary Report for the Multi-

Chambered Treatment Trains. Prepared for the California Department of Transportation. May 2001.

• Clark, S., R. Pitt, and R. Raghavan. SBIR Phase 1 report for Upflow Filtration Treatment of Stormwater. U.S. EPA. Publication pending 2003.

• Corsi, S.R., S.R. Greb, R.T. Bannerman, and R.E. Pitt. Evaluation of the Multi-Chambered Treatment Train, a Retrofit Water Quality Management Practice. U.S. Geological Survey. Open-File Report 99-270. Middleton, Wisconsin. 24 pgs. 1999.

• Johnson, P., R. Pitt, S. Clark, M. Urritta, and R. Durrans. Innovative Metal Removal for Stormwater Treatment. Water Environment Research Foundation. Publication pending 2003.

• Pitt, R., B. Robertson, P. Barron, A. Ayyoubi, and S. Clark. Stormwater Treatment at Critical Areas: The Multi-Chambered Treatment Train (MCTT). U.S. Environmental Protection Agency, Wet Weather Flow Management Program, National Risk Management Research Laboratory. EPA/600/R-99/017. Cincinnati, Ohio. 505 pgs. March 1999.

Acknowledgements WERF Project 97-IRM-2

Project Manager: Jeff Moeller

U.S. EPA Small Business Innovative Research Program (SBIR1 and SBIR2 plus ETV testing)

Project Officer: Richard Field

Many graduate students at the University of Alabama and Penn State-Harrisburg

Industrial Partners (US Infrastructure and

Hydro International)

Background to Research Leading to Development of...

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