Post on 28-Dec-2015
transcript
Carbon CompoundsIsomers
Monkemeier
Honors Biology
Carbon Skeletons
The framework of biological molecules consists predominately of carbon atoms bonded to other carbon atoms or atoms of oxygen, hydrogen, nitrogen or sulfur.
Carbon skeletons form the backbone of biological molecules
Carbon skeletons occur in chains, branched chains or rings.
Four Major Types of Biological Molecules and Carbon Skeletons!
The four major types of biological molecules: carbohydrates, lipids, nucleic acids, and proteins.
Carbon chains often contain hydrogen. The C-C and C- H bonds are nonpolar since carbon and hydrogen have similar electronegativities.
Functional Groups
Functional Groups are specific groups of atoms (that are covalently bonded together) that have definite chemical properties that they retain no matter where they occur.
Functional Groups attached to a “carbon – chain” molecule provide that molecule with their definite chemical properties!
Functional Groups
Carbon Skeletons and Isomers!
Isomers are compounds with the same chemical formula but different structural arrangements.
Structural Isomers
When differences exist in in the actual structure of the carbon skeleton the compounds are structural isomers.
Sterioisomers
These molecules have the same carbon skeleton but differ in how the groups attached to this skeleton are arranged.
Enantiomers
A subcategory of sterioisomers that are mirror images of each other.
Chiral molecules are mirror images of each other.
Chiral molecules are characterized by their effect on polarized light and chiral molecules rotate to the left or right.
Chiral Molecules
Levorotatory rotates the molecule to the left and is designated L
Dextrorotatory rotates the molecule to the right and is designated D.
Chiral Molecules and Living Systems
Living systems tend to produce only a single enantiomer of the tow possible forms (L or D); for example, in most organisms:
D – Sugars
L – amino Acids
HOW?
How do living systems build huge polymers like starch or enzymes?
Instead of building them one atom at a time, they build them one monomer at a time.
Monomers are molecules that act as subunits that when put together form polymers (large macromolecules).
Monomers to Polymers
Monomers to Polymers
Dehydration Synthesis: Monomers to Polymers
Polymers back to Monomers: Hydrolysis
The Four Major Categories
Carbohydrates, Lipids, Proteins and nucleic acids are all built and broken down using the SAME TWO REACTIONS.
Dehydration Synthesis (aka condensation) forms bonds between monomers.
Hydrolysis (sometimes aka decomposition) breaks the bonds between monomers
In both reactions: DO NOT FORGET THE ROLE of WATER!
NEXT TIME!
The four major categories of macromolecules!
WE LOVE AP!