General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 1 Chapter 6...

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General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 1

Chapter 6 Chemical Reactions and Quantities

6.5Molar Mass

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 2

The molar mass is the mass of one mole

of a substance the atomic mass of an

element expressed in grams

Molar Mass

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 3

Give the molar mass to the nearest 0.1 g.

A. K = ________

B. Sn = ________

Learning Check

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 4

Give the molar mass to the nearest 0.1 g.

A. K = 39.1 g

B. Sn = 118.7 g

Solution

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 5

Molar Mass of CaCl2

For a compound, the molar mass is the sum of the molar masses of the elements in the formula. We calculate the molar mass of CaCl2 to the nearest 0.1 g as follows.

Element Number of Moles

Atomic Mass Total Mass

Ca 1 40.1 g/mole 40.1 g

Cl 2 35.5 g/mole 71.0 g

CaCl2 1 111.1 g

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 6

Molar Mass of K3PO4

Determine the molar mass of K3PO4 to 0.1 g.

Element Number of Moles

Atomic Mass Total Mass in K3PO4

K 3 39.1 g/mole 117.3 g

P 1 31.0 g/mole 31.0 g

O 4 16.0 g/mole 64.0 g

K3PO4 1 212.3 g

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 7

One-Mole Quantities

32.1 g 55.9 g 58.5 g 294.2 g 342.3 g

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc.

Guide to Calculating Molar Mass

8

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 9

Calculate the molar mass for Al(OH)3 to the nearest 0.1g.

1) 44.0 g/mole

2) 75.0 g/mole

3) 78.0 g/mole

Learning Check

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 10

STEP 1 Obtain the molar mass of each element. Al 27.0 g/mole O 16.0 g/mole

H 1.0 g/moleSTEP 2 Multiply each by the subscript in the formula.

1 mole Al x 27.0 g Al = 27.0 g 1 mole Al

3 moles O x 16.0 g O = 48.0 g 1 mole O

3 moles H x 1.0 g H = 3.0 g 1 mole H STEP 3 Total: 1 mole of Al(OH)3 = 78.0 g (3)

Solution

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 11

Prozac, C17H18F3NO, is an antidepressant that inhibits the uptake of serotonin by the brain. What is the molar mass of Prozac?

1) 40.0 g/mole

2) 262 g/mole

3) 309 g/mole

Learning Check

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 12

3) 309 g/mole

STEP 1 Obtain the molar mass of each element. C 12.0 g/mole H 1.0 g/mole

F 19.0 g/mole N 14.0 g/mole O 16.0 g/mole

STEP 2 Multiply each by the subscript in the formula. 17 moles C x 12.0 g C = 204 g

1 mole C 18 moles H x 1.0 g H = 18 g

1 mole H

Solution

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 13

STEP 2 (continued) 3 moles F x 19.0 g F = 57.0 g

1 mole F 1 mole N x 14.0 g N = 14.0 g

1 mole N

1 mole O x 16.0 g O = 16.0 g 1 mole O

STEP 3 Total: 1 mole of C17H18F3NO = 309 g

Solution (continued)

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 14

Methane (CH4), known as natural gas, is used in gas stoves and gas heaters.

1 mole of CH4 = 16.0 g of CH4

The molar mass of methane can be written as conversion factors.

16.0 g CH4 and 1 mole CH4

1 mole CH4 16.0 g CH4

Conversion Factors from Molar Mass

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 15

Acetic acid, C2H4O2, gives the sour taste to vinegar.

Write an equality and two molar mass conversion factors for acetic acid.

Learning Check

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 16

Acetic acid, C2H4O2, gives the sour taste to vinegar.

Write an equality and two molar mass conversion factors for acetic acid.

Equality:

1 mole of acetic acid = 60.0 g of acetic acid

Molar mass conversion factors:

1 mole acetic acid and 60.0 g acetic acid

60.0 g acetic acid 1 mole acetic acid

Solution

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 17

Guide to Calculations Using Molar Mass

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 18

Aluminum is often used for the structure of lightweight bicycle frames. How many grams of Al are in 3.00 moles of Al?

3.00 moles Al x 27.0 g Al = 81.0 g of Al1 mole Al

mole factor for Al

Calculating Grams from Moles

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 19

The artificial sweetener aspartame (NutraSweet), C14H18N2O5 , is used to sweeten diet foods, coffee, and soft drinks. How many moles of aspartame are present in 225 g of aspartame?

Learning Check

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 20

STEP 1 Given: 225 g of aspartame, C14H18N2O5

STEP 2 Plan: g of aspartame moles of aspartame

STEP 3 Determine molar mass of aspartame:

14(12.0) + 18(1.0) + 2(14.0) + 5(16.0)

= 294 g/mole

STEP 4 Set up problem to calculate the moles of aspartame:

225 g aspartame x 1 mole aspartame

294 g aspartame mole factor (inverted)

= 0.765 mole of aspartame

Solution

General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc.

Converting Between Mass, Moles, and Particles

21