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Handbook of Optical Constants of Solids III
Edited by
EDWARD D. PAUK
Institute for Physical Science and Technology University of Maryland
College Park, Maryland
Academic Press San Diego London Boston
New York Sydney Tokyo Toronto
Contents
List of Contributors Preface
X l l l
xvii
Part I DETERMINATION OF OPTICAL CONSTANTS
Chap te r 1 Introductory Remarks EDWARD D. PALIK
I. Introduction П. The Chapters
Ш. The Critiques IV. The Tables V. The Figures of the Tables
VI. Corrections, Additions, and Comments References
3 4 5 5 5 6
12
Chap te r 2 Determination of the Far-Infrared Optical Constants of Solids by Dispersive Fourier Transform Spectroscopy T. J. PARKER, K. A. MASLIN, a n d G. MIRJALIU
I. Introduction II. The Materials
Acknowledgment References
13
13 20 55 55
Chapte r 3 Photothermal/Photoacoustic Spectroscopic Measurements of Optical Absorption Coefficients in Semiconductors 59 ANDREAS MANDEUS
I. Introduction 59 II. Photoacoustic Spectroscopy (PAS) 60
III. Photopyroelectric Spectroscopy (PPES) 67 IV Measurements of a(A) in Semiconductors using
Photoacoustic/Photothermal Techniques 69 Acknowledgments 94 References 94
v
VI Contents
Chapter 4 Photothermal Deflection Measurements of the Extinction Coefficient к MATTHEW E. BRIGGS
I. Introduction II. Photothermal Deflection
Ш. Conclusions Acknowledgments References
99
99 103 116 117 117
Chapter 5 Determination of Optical Constants by Briiiouin Scattering HACENE BOUKARI and NICHOLAS LAGAKOS
I. Definition of Notation II. Introduction
Ш. Background on Briiiouin Scattering Technique IV. Equations for Measurement of the Index of Refraction V. Fabry-Perot Interferometers
VI. Discussion VII. Briiiouin Scattering in Thin Slabs and Optical Fibers
Vni. Special Case of Transparent Thin Slabs IX. Briiiouin Scattering in Optical Fibers
References
121
121 122 123 125 128 128 134 135 146 153
Chapter 6 Doped n-Type Silicon (n-Si) MARK AUSLENDER and SHLOMO HAVA
I. Introduction П. Contributions to Dielectric Function: Optical Properties versus
Optical Constants III. Semiclassical Theory of Free-Carrier Contribution to the Dielectric
Function: The Drude Approximation IV. Free-Carrier Contribution to the Dielectric Function in Quantum
Absorption Regime: Generalized Drude Approach V Experimental Data Overview
VI. Generalized Drude Approximation for n-Si VII. Tabulation of Optical Constants of Doped n-Si
References
155
155
156
158
159 162 166 171 185
Chapter 7 Optical Parameters for the Materials in HOC I, HOC II, and HOC III EDWARD D. PAUK
I. Introduction П. The Parameters
References
187
187 187 225
VII
Part II CRITIQUES
Subpart 1 Metals
Introduction to the Data for Several Metals 233 DAVID W. LYNCH a n d W. R. HUNTER
I. Introduction 233 References 235
П. Magnesium (Mg) 235 References 235
Ш. Titanium (Ti) 240 References 241
IV. Manganese (Mn) 249 References 250
V. Ruthenium (Ru) 253 References 254
VI. Indium (In) 261 References 262
VII. Tin (Sn) 268 References 269
Vni. Antimony (Sb) 274 References 275
IX. Rhenium (Re) 278 References 279
Optical Constants of Eight Rare-Earth Elements 287 L. WARD
287 292 293 294 297 298 300 301 302 303
341
References 344
Zirconium Nitride (ZrN), Hafnium Nitride (HfN) 351 CARL G. RIBBING a n d ARNE ROOS
References 358
I. II.
Ш. rv. V.
VI. VII. VIII. K .
Introduction Cerium (Ce) Samarium (Sm) Gadolinium (Gd) Terbium (Tm) Dysprosium (Dy) Erbium (Er) Thulium (Tm) Ytterbium (Yb) References
Cesium (Cs) T. INAGAKI a n d E. T. ARAKAWA
viii Contents
Subpart 2 Semiconductors
Aluminum Nitride (AIN) 373 S. LOUGHIN a n d R. H. FRENCH References 377
Bismuth Silicon Oxide (Bi12Si020) and Bismuth Germanium Oxide (Bi12Ge020) 403 E. D. PAUK References 408
Boron Nitride (BN) 425 GARY L. DOLL References 429
Cadmium Germanium Arsenide (CdGeAs2) 445 J. С RIFE References 448
Copper Gallium Sulfide (CuGaS2) 459 J. С RIFE References 462
Gallium Selenide (GaSe) 473 DAVID F. EDWARDS References 477
Gallium Telluride (GaTe) 489 DAVID F. EDWARDS References 491
Iron Pyrite (FeS2) 507 E. D. PAUK References 511
Silicon (Si) Revisited (1.1-1.3 eV) 519 J O N GEIST References 524
Contents ix
Silicon (Si) Revisited (1.4-6.0 eV) 531 DAVID F. EDWARDS
References 533
Silicon-Germanium Alloys ( S i ^ _x ) Revisited 537 J. HUMÜCEK
References 538
Silver Chloride (AgCI), Silver Bromide (AgBr), Silver Iodide (Agl) 553 MASATO TAZAWA a n d ARMAND HADNI
References 556
Silver Gallium Selenide (AgGaSe2) and Silver Gallium Sulfide (AgGaS2) 573 LUIS ARTUS
References 577
Zinc Arsenide (Zn3As2) 595 J. MISIEWICZ a n d К. JEZIERSKI References 596
Zinc Phosphide (Zn3P2) 609 J. MISIEWICZ a n d K. JEZIERSKI References 612
Zinc Germanium Phosphide (ZnGeP2) 637 J. С RIFE References 640
Subpart 3 Insulators
Aluminum Oxide (Al203) Revisited 653 MICHAEL E. THOMAS a n d WILLIAM J. TROPF References 657
Barium Fluoride (BaF2) 683 MICHAEL E. THOMAS a n d WILLIAM J. TROPF References 686
Calcium Carbonate, Calcite (CaCo3) 701 WILLIAM J. TROPF
References 703
Cesium Bromide (CsBr) 717 W. J. MOORE
References 719
Cesium Chloride (CsCI) 731 JOHN E. ELDRIDGE
References 733
Cesium Fluoride (CsF) 743 JOHN E. ELDRIDGE
References 745
Beta-Gallium Oxide (ß-Ga203) 753 DAVID F. EDWARDS
References 755
Lead Fluoride (PbF2) 761 MÄRCIA A. F. DESTRO a n d ALVARO J. DAMIÄO
References 766
Lithium Tantalate (LiTa03) 777 FRANQOIS GERVAIS a n d VICENTE FONSECA
References 780
Potassium Iodide (Kl) 807 MICHAEL E. THOMAS
References 810
Potassium Niobate (KNb03) 821 IVAN BIAGGIO
References 825
Rubidium Bromide (RbBr) 845 IVAN OHÜDAL a n d MILOSLAV OHUDAL
References 848
Contents XI
Rubidium Iodide (Rbl) 857 IVAN OHUDAL and DANIEL FRANTA
References 861
Sodium Nitrate (NaN03) 871 EDWARD D. PAUK and R. KHANNA
References 873
Strontium Fluoride (SrF2) 883 MICHAEL E. THOMAS
References 886
Orthorhombic Sulfur (a-S) 899 KIRK A. FULLER, HARRY D. DOWNING, and MARVIN R. QUERRY
References 905
Cubic Thallium(l) Halides 923 WILLIAM J. TROPF
References 931
Yttrium Aluminum Garnet (¥3А15012) 963 WILLIAM J. TROPF References 966
Zircon (ZrSi04) 987 EDWARD D. PAUK and R. KHANNA References 989