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Creation Date 01-Nov-2011 Revision Date 01-Nov-2011 Revision Number 1
Kit Safety Data Sheet
Product Name: Trichrome Stain Kit
Product Code: R40217 Component Safety Data Sheets for Kit
Code Component Name SDS Required
E
R40132 95% Ethanol Yes R40135 70% Ethanol Yes R40133 Xylene-S Yes R40025 Trichrome (Wheatley) Stain No R40134 Acid Ethanol 90% Yes R40029 Lugol’s Iodine Yes
Emergency contact information: Company Identification: Oxoid Ltd. Wade Road, Basingstoke, Hants, RG24 8PW United Kingdom Company Phone Number: +44 (0) 1256 841144 Emergency Telephone Number Carechem 24: +44 (0) 1865 407333 Email: mbd-sds@thermofisher.com
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1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product Name 95% EthanolCat No. R40132, R40217, R40219Synonyms No information available.Recommended Use Laboratory chemicals
Emergency Telephone Number Carechem 24: +44 (0) 1865 407333
2. HAZARDS IDENTIFICATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC.
R-phrase(s)R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
3. COMPOSITION/INFORMATION ON INGREDIENTS Haz/Non-haz
Component Weight % EC-No. Classification Ethyl alcohol
64-17-595 EEC No. 200-578-6 F; R11
Methyl alcohol 67-56-1
5 EEC No. 200-659-6 F; R11 T; R23/24/25-39/23/24/25
_____________________________________________________________________________________________ Thermo Fisher Scientific
E-mail address mbd-sds@thermofisher.com
Revision Date 01-Nov-2011 Revision Number 1
SAFETY DATA SHEET
Company
Page 1 / 9
Remel12076 Santa Fe DriveLenexa, KS 66215 United StatesTelephone: 1-800-255-6730Fax:1-800-621-8251
According to EC Directive 1907/2006/EC
Creation Date 01-Nov-2011
Entity / Business Name Oxoid Ltd.Wade RoadBasingstoke, Hants, UKRG24 8PWTelephone: +44 (0) 1256 841144
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_____________________________________________________________________________________________ For the full text of the R phrases mentioned in this Section, see Section 16
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes Ingestion Get medical attention. Clean mouth with water and drink afterwards plenty of water. Do not
induce vomiting. Inhalation Move to fresh air. Get medical attention if symptoms occur.. Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing MediaCO2, dry chemical, dry sand, alcohol-resistant foam. Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire Specific Hazards Arising from the ChemicalFlammable. Keep product and empty container away from heat and sources of ignition. Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Flash Point 17°C / 62.6°F Method Closed cup Autoignition Temperature 363°C / 685.4°F Explosion Limits Lower 3.3 vol % Upper 19.0 vol %
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011
Page 2 / 9 According to EC Directive 1907/2006/EC
SAFETY DATA SHEET
95% Ethanol
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_____________________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Remove all sources of ignition. Use personal protective equipment. Ensure adequate
ventilation. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment and Clean Up
Soak up with inert absorbent material. Clean contaminated surface thoroughly
7. HANDLING AND STORAGE
Handling Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Keep away from open
flames, hot surfaces and sources of ignition. Storage Keep away from heat and sources of ignition. Keep containers tightly closed in a cool, well-
ventilated place. Specific use(s) No information available.
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011
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SAFETY DATA SHEET
According to EC Directive 1907/2006/EC
95% Ethanol
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limits
Component European Union The United Kingdom
Belgium France Spain Germany
Ethyl alcohol TWA: 1000 ppm TWA; 1920 mg/m3
TWA WEL - STEL: 3000 ppm STEL; 5760
mg/m3 STEL
TWA: 1000 ppm 8 uren
TWA: 1907 mg/m3 8 uren
VME: 1000 ppm 8 heures.
VME: 1900 mg/m3 8 heures.
VLCT: 5000 ppm VLCT: 9500 mg/m3
VLA-ED: 1000 ppm 8 horas
VLA-ED: 1910 mg/m3 8 horas
500 ppm TWA; 960 mg/m3 TWA
Methyl alcohol TWA: 200 ppm 8 hr TWA: 260 mg/m3 8
hr Skin
WEL - TWA: 200 ppm TWA; 266
mg/m3 TWA WEL - STEL: 250 ppm STEL; 333
mg/m3 STEL
TWA: 200 ppm 8 uren
TWA: 266 mg/m3 8 uren
STEL: 250 ppm 15 minuten
STEL: 333 mg/m3 15 minuten
Skin
VME: 200 ppm 8 heures. restrictive
limit VME: 260 mg/m3 8 heures. restrictive
limit VLCT: 1000 ppm
VLCT: 1300 mg/m3 Skin
Skin VLA-ED: 200 ppm 8
horas VLA-ED: 266 mg/m3
8 horas
200 ppm TWA; 270 mg/m3 TWA
Skin absorber
Component Italy Portugal The Netherlands Finland AustriaEthyl alcohol TWA: 1000 ppm 8
horasSkin
STEL: 1900 mg/m3 15 minuten
TWA: 260 mg/m3 8 uren
TWA: 1000 ppm 8 tunteina
TWA: 1900 mg/m3 8 tunteina
STEL: 1300 ppm 15 minuutteina
STEL: 2500 mg/m3 15 minuutteina
STEL: 2000 ppm 15 Minuten
STEL: 3800 mg/m3 15 Minuten
MAK: 1000 ppm 8 Stunden
MAK: 1900 mg/m3 8 Stunden
Methyl alcohol TWA: 200 ppm 8 ore. TWA: 260 mg/m3 8 ore.
Skin
STEL: 250 ppm 15 minutos
TWA: 200 ppm 8 horas Skin
Skin STEL: 520 mg/m3 15
minuten TWA: 260 mg/m3 8 uren
TWA: 200 ppm 8 tunteina
TWA: 270 mg/m3 8 tunteina
STEL: 250 ppm 15 minuutteina
STEL: 330 mg/m3 15 minuutteina
Skin
Skin STEL: 800 ppm 15
Minuten STEL: 1040 mg/m3 15
Minuten MAK: 200 ppm 8
Stunden MAK: 260 mg/m3 8
Stunden
Component Switzerland Poland Norway Ireland Denmark Australia Ethyl alcohol STEL: 1000 ppm 15
Minuten STEL: 1920 mg/m3
15 Minuten MAK: 500 ppm 8
Stunden MAK: 960 mg/m3 8
Stunden
NDS: 1900 mg/m3 8 godzinach
TWA: 500 ppm 8 timer
TWA: 950 mg/m3 8 timer
STEL: 625 ppm 15 minutter.
STEL: 1187.5 mg/m3 15 minutter.
TWA: 1000 ppm 8 hr.
TWA: 1900 mg/m3 8 hr.
TWA: 1000 ppm 8 timer
TWA: 1900 mg/m3 8 timer
TWA: 1000 ppm TWA: 1880 mg/m3
_____________________________________________________________________________________________ Thermo Fisher Scientific
SAFETY DATA SHEET
95% Ethanol
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Revision Date 01-Nov-2011
According to EC Directive 1907/2006/EC
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Component Switzerland Poland Norway Ireland Denmark Australia Methyl alcohol Skin
STEL: 800 ppm 15 Minuten
STEL: 1040 mg/m3 15 Minuten
MAK: 200 ppm 8 Stunden
MAK: 260 mg/m3 8 Stunden
NDSCh: 300 mg/m3 15 minutach
NDS: 100 mg/m3 8 godzinach
TWA: 100 ppm 8 timer
TWA: 130 mg/m3 8 timer
STEL: 150 ppm 15 minutter.
STEL: 162.5 mg/m3 15 minutter.
Skin
TWA: 200 ppm 8 hr. TWA: 260 mg/m3 8
hr. Skin
TWA: 200 ppm 8 timer
TWA: 260 mg/m3 8 timer Skin
STEL: 250 ppm STEL: 328 mg/m3
TWA: 200 ppm TWA: 262 mg/m3
Occupational exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas Personal Protective Equipment Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced
Eye Protection Tightly fitting safety goggles Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure Hand Protection Protective gloves
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice Environmental exposure controls No information available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State LiquidAppearance ColourlesspH No information available. Boiling Point/Range 78°C / 172.4°FMelting Point/Range No information available.Flash Point 17°C / 62.6°FMethod Closed cupExplosion Limits Lower 3.3 vol % Upper 19.0 vol %
10. STABILITY AND REACTIVITY
Stability Stable under recommended storage conditions. Conditions to Avoid Heat, flames and sparks. Incompatible Materials Strong oxidizing agents
_____________________________________________________________________________________________ Thermo Fisher Scientific
SAFETY DATA SHEET
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95% Ethanol
According to EC Directive 1907/2006/EC
Revision Date 01-Nov-2011
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_____________________________________________________________________________________________ Hazardous Decomposition Products Carbon oxides Hazardous Polymerization No information available Hazardous Reactions . None under normal processing.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity Product Information Harmful by inhalation, in contact with skin and if swallowed
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationEthyl alcohol 7060 mg/kg ( Rat ) 20000 ppm/10H ( Rat )
Methyl alcohol 5628 mg/kg ( Rat ) 15800 mg/kg ( Rabbit ) 64000 ppm ( Rat ) 4 h 83.2 mg/L ( Rat ) 4 h
Chronic Toxicity Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component IARC UK Ethyl alcohol Group 1
IARC: (International Agency for Research on Cancer)IARC: (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansGroup 2A - Probably Carcinogenic to HumansGroup 2B - Possibly Carcinogenic to Humans
Sensitization No information available. Neurological Effects No information available. Mutagenic Effects No information available. Reproductive Effects No information available. Developmental Effects No information available. Target Organs Blood, Liver, Respiratory system, Central nervous system (CNS), Eyes, Reproductive System,
Gastrointestinal tract (GI), Skin, Optic nerve.
_____________________________________________________________________________________________ Thermo Fisher Scientific
95% Ethanol Revision Date 01-Nov-2011
Page 6 / 9 According to EC Directive 1907/2006/EC
SAFETY DATA SHEET 7 of 54
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12. ECOLOGICAL INFORMATION
Ecotoxicity.
Component Freshwater Algae Freshwater Fish Microtox Water FleaEthyl alcohol Leucidus idus: LC50 = 8.14
mg/L/48hPhotobacterium
phosphoreum:EC50 = 34634 mg/L/30 min
Photobacterium phosphoreum:EC50 = 35470
mg/L/5 min
EC50 = 9268 mg/L/48h EC50 = 10800 mg/L/24h
Methyl alcohol Pimephales promelas: LC50 > 10000 mg/L 96h
EC50 = 39000 mg/L 25 min EC50 = 40000 mg/L 15 min EC50 = 43000 mg/L 5 min
EC50 > 10000 mg/L 24h
Persistence and Degradability No information available Bioaccumulative Potential No information available. Mobility No information available.
Component log PowEthyl alcohol -0.32
Methyl alcohol -0.74
13. DISPOSAL CONSIDERATIONS
Waste from Residues / Unused Products
Dispose of as hazardous waste in compliance with local and national regulations
Contaminated Packaging Dispose of in accordance with local regulations.
14. TRANSPORT INFORMATION
IMDG/IMO UN-No UN1170 Hazard Class 3 Packing Group II Proper Shipping Name ETHANOL SOLUTION
ADR UN-No UN1170 Hazard Class 3 Packing Group II
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011
SAFETY DATA SHEET
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95% Ethanol
According to EC Directive 1907/2006/EC
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14. TRANSPORT INFORMATION Proper Shipping Name ETHANOL SOLUTION
IATA UN-No UN1170 Hazard Class 3 Packing Group II Proper Shipping Name ETHANOL SOLUTION
15. REGULATORY INFORMATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC Labelling
R-phrase(s)R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
S-phrase(s)S 7 - Keep container tightly closedS16 - Keep away from sources of ignition. No smokingS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS28A - After contact with skin, wash immediately with plenty of waterS45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
International Inventories
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011
SAFETY DATA SHEET
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Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS CHINA AICS KECL Ethyl alcohol 200-578-6 - X X - X X X X XMethyl alcohol 200-659-6 - X X - X X X X X
16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowedR23/24/25 - Toxic by inhalation, in contact with skin and if swallowedR39/23/24/25 - Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
Prepared By Regulatory Affairs Creation Date 01-Nov-2011 Revision Date 01-Nov-2011 Revision Summary "***", and red text indicates revision Restrictions on use No information available. Training advice No information available. Literary reference No information available. Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
End of Safety Data Sheet
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011
Page 9 / 9 According to EC Directive 1907/2006/EC
SAFETY DATA SHEET
95% Ethanol
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1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product Name 70% EthanolCat No. R40135, R40217, R2740110Synonyms No information available.Recommended Use Laboratory chemicals
Emergency Telephone Number Carechem 24: +44 (0) 1865 407333
2. HAZARDS IDENTIFICATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC.
R-phrase(s)R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
3. COMPOSITION/INFORMATION ON INGREDIENTS Haz/Non-haz
Component Weight % EC-No. Classification Ethyl alcohol
64-17-566.5 EEC No. 200-578-6 F; R11
Methyl alcohol 67-56-1
3.5 EEC No. 200-659-6 F; R11 T; R23/24/25-39/23/24/25
_____________________________________________________________________________________________ Thermo Fisher Scientific
E-mail address mbd-sds@thermofisher.com
Revision Date 01-Nov-2011 Revision Number 1
SAFETY DATA SHEET
Company
Page 1 / 9
Remel12076 Santa Fe DriveLenexa, KS 66215 United StatesTelephone: 1-800-255-6730Fax:1-800-621-8251
According to EC Directive 1907/2006/EC
Creation Date 01-Nov-2011
Entity / Business Name Oxoid Ltd.Wade RoadBasingstoke, Hants, UKRG24 8PWTelephone: +44 (0) 1256 841144
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_____________________________________________________________________________________________ For the full text of the R phrases mentioned in this Section, see Section 16
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes Ingestion Get medical attention. Clean mouth with water and drink afterwards plenty of water. Do not
induce vomiting. Inhalation Move to fresh air. Get medical attention if symptoms occur.. Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing MediaCO2, dry chemical, dry sand, alcohol-resistant foam. Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire Specific Hazards Arising from the ChemicalFlammable. Keep product and empty container away from heat and sources of ignition. Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Flash Point 21°C / 69.8°F Method Closed cup Autoignition Temperature 363°C / 685.4°F Explosion Limits Lower 3.3 vol % Upper 19.0 vol %
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011
Page 2 / 9 According to EC Directive 1907/2006/EC
SAFETY DATA SHEET
70% Ethanol
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_____________________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Remove all sources of ignition. Use personal protective equipment. Ensure adequate
ventilation. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment and Clean Up
Soak up with inert absorbent material Clean contaminated surface thoroughly
7. HANDLING AND STORAGE
Handling Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Keep away from open
flames, hot surfaces and sources of ignition. Storage Keep away from heat and sources of ignition. Keep containers tightly closed in a cool, well-
ventilated place. Specific use(s) No information available.
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011
Page 3 / 9
SAFETY DATA SHEET
According to EC Directive 1907/2006/EC
70% Ethanol
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_____________________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limits
Component European Union The United Kingdom
Belgium France Spain Germany
Ethyl alcohol TWA: 1000 ppm TWA; 1920 mg/m3
TWA WEL - STEL: 3000 ppm STEL; 5760
mg/m3 STEL
TWA: 1000 ppm 8 uren
TWA: 1907 mg/m3 8 uren
VME: 1000 ppm 8 heures.
VME: 1900 mg/m3 8 heures.
VLCT: 5000 ppm VLCT: 9500 mg/m3
VLA-ED: 1000 ppm 8 horas
VLA-ED: 1910 mg/m3 8 horas
500 ppm TWA; 960 mg/m3 TWA
Methyl alcohol TWA: 200 ppm 8 hr TWA: 260 mg/m3 8
hr Skin
WEL - TWA: 200 ppm TWA; 266
mg/m3 TWA WEL - STEL: 250 ppm STEL; 333
mg/m3 STEL
TWA: 200 ppm 8 uren
TWA: 266 mg/m3 8 uren
STEL: 250 ppm 15 minuten
STEL: 333 mg/m3 15 minuten
Skin
VME: 200 ppm 8 heures. restrictive
limit VME: 260 mg/m3 8 heures. restrictive
limit VLCT: 1000 ppm
VLCT: 1300 mg/m3 Skin
Skin VLA-ED: 200 ppm 8
horas VLA-ED: 266 mg/m3
8 horas
200 ppm TWA; 270 mg/m3 TWA
Skin absorber
Component Italy Portugal The Netherlands Finland AustriaEthyl alcohol TWA: 1000 ppm 8
horasSkin
STEL: 1900 mg/m3 15 minuten
TWA: 260 mg/m3 8 uren
TWA: 1000 ppm 8 tunteina
TWA: 1900 mg/m3 8 tunteina
STEL: 1300 ppm 15 minuutteina
STEL: 2500 mg/m3 15 minuutteina
STEL: 2000 ppm 15 Minuten
STEL: 3800 mg/m3 15 Minuten
MAK: 1000 ppm 8 Stunden
MAK: 1900 mg/m3 8 Stunden
Methyl alcohol TWA: 200 ppm 8 ore. TWA: 260 mg/m3 8 ore.
Skin
STEL: 250 ppm 15 minutos
TWA: 200 ppm 8 horas Skin
Skin STEL: 520 mg/m3 15
minuten TWA: 260 mg/m3 8 uren
TWA: 200 ppm 8 tunteina
TWA: 270 mg/m3 8 tunteina
STEL: 250 ppm 15 minuutteina
STEL: 330 mg/m3 15 minuutteina
Skin
Skin STEL: 800 ppm 15
Minuten STEL: 1040 mg/m3 15
Minuten MAK: 200 ppm 8
Stunden MAK: 260 mg/m3 8
Stunden
Component Switzerland Poland Norway Ireland Denmark Australia Ethyl alcohol STEL: 1000 ppm 15
Minuten STEL: 1920 mg/m3
15 Minuten MAK: 500 ppm 8
Stunden MAK: 960 mg/m3 8
Stunden
NDS: 1900 mg/m3 8 godzinach
TWA: 500 ppm 8 timer
TWA: 950 mg/m3 8 timer
STEL: 625 ppm 15 minutter.
STEL: 1187.5 mg/m3 15 minutter.
TWA: 1000 ppm 8 hr.
TWA: 1900 mg/m3 8 hr.
TWA: 1000 ppm 8 timer
TWA: 1900 mg/m3 8 timer
TWA: 1000 ppm TWA: 1880 mg/m3
_____________________________________________________________________________________________ Thermo Fisher Scientific
SAFETY DATA SHEET
70% Ethanol
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Revision Date 01-Nov-2011
According to EC Directive 1907/2006/EC
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Component Switzerland Poland Norway Ireland Denmark Australia Methyl alcohol Skin
STEL: 800 ppm 15 Minuten
STEL: 1040 mg/m3 15 Minuten
MAK: 200 ppm 8 Stunden
MAK: 260 mg/m3 8 Stunden
NDSCh: 300 mg/m3 15 minutach
NDS: 100 mg/m3 8 godzinach
TWA: 100 ppm 8 timer
TWA: 130 mg/m3 8 timer
STEL: 150 ppm 15 minutter.
STEL: 162.5 mg/m3 15 minutter.
Skin
TWA: 200 ppm 8 hr. TWA: 260 mg/m3 8
hr. Skin
TWA: 200 ppm 8 timer
TWA: 260 mg/m3 8 timer Skin
STEL: 250 ppm STEL: 328 mg/m3
TWA: 200 ppm TWA: 262 mg/m3
Occupational exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas Personal Protective Equipment Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced
Eye Protection Tightly fitting safety goggles Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure Hand Protection Protective gloves
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice Environmental exposure controls No information available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State LiquidAppearance Colourless Boiling Point/Range 78.0Melting Point/Range No information available.Flash Point 21°C / 69.8°FMethod Closed cupExplosion Limits Lower 3.3 vol % Upper 19.0 vol %
10. STABILITY AND REACTIVITY
Stability Stable under recommended storage conditions. Conditions to Avoid Heat, flames and sparks. Incompatible Materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides
_____________________________________________________________________________________________ Thermo Fisher Scientific
SAFETY DATA SHEET
70% Ethanol
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Revision Date 01-Nov-2011
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_____________________________________________________________________________________________ Hazardous Polymerization No information available Hazardous Reactions . None under normal processing.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity Product Information Harmful by inhalation, in contact with skin and if swallowed
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationEthyl alcohol 7060 mg/kg ( Rat ) 20000 ppm/10H ( Rat )
Methyl alcohol 5628 mg/kg ( Rat ) 15800 mg/kg ( Rabbit ) 64000 ppm ( Rat ) 4 h 83.2 mg/L ( Rat ) 4 h
Chronic Toxicity Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component IARC UK Ethyl alcohol Group 1
IARC: (International Agency for Research on Cancer)IARC: (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansGroup 2A - Probably Carcinogenic to HumansGroup 2B - Possibly Carcinogenic to Humans
Sensitization No information available. Neurological Effects No information available. Mutagenic Effects No information available. Reproductive Effects No information available. Developmental Effects No information available. Target Organs Blood, Liver, Respiratory system, Central nervous system (CNS), Eyes, Reproductive System,
Gastrointestinal tract (GI), Skin, Optic nerve.
_____________________________________________________________________________________________ Thermo Fisher Scientific
SAFETY DATA SHEET
70% Ethanol
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Revision Date 01-Nov-2011
According to EC Directive 1907/2006/EC
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12. ECOLOGICAL INFORMATION
Ecotoxicity.
Component Freshwater Algae Freshwater Fish Microtox Water FleaEthyl alcohol Leucidus idus: LC50 = 8.14
mg/L/48hPhotobacterium
phosphoreum:EC50 = 34634 mg/L/30 min
Photobacterium phosphoreum:EC50 = 35470
mg/L/5 min
EC50 = 9268 mg/L/48h EC50 = 10800 mg/L/24h
Methyl alcohol Pimephales promelas: LC50 > 10000 mg/L 96h
EC50 = 39000 mg/L 25 min EC50 = 40000 mg/L 15 min EC50 = 43000 mg/L 5 min
EC50 > 10000 mg/L 24h
Persistence and Degradability No information available Bioaccumulative Potential No information available. Mobility No information available.
Component log PowEthyl alcohol -0.32
Methyl alcohol -0.74
13. DISPOSAL CONSIDERATIONS
Waste from Residues / Unused Products
Dispose of as hazardous waste in compliance with local and national regulations
Contaminated Packaging Dispose of in accordance with local regulations.
14. TRANSPORT INFORMATION
IMDG/IMO UN-No UN1170 Hazard Class 3 Packing Group II Proper Shipping Name ETHANOL SOLUTION
ADR UN-No UN1170 Hazard Class 3 Packing Group II
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011
SAFETY DATA SHEET
Page 7 / 9
70% Ethanol
According to EC Directive 1907/2006/EC
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14. TRANSPORT INFORMATION Proper Shipping Name ETHANOL SOLUTION
IATA UN-No UN1170 Hazard Class 3 Packing Group II Proper Shipping Name ETHANOL SOLUTION
15. REGULATORY INFORMATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC Labelling
R-phrase(s)R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
S-phrase(s)S 7 - Keep container tightly closedS16 - Keep away from sources of ignition. No smokingS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS28A - After contact with skin, wash immediately with plenty of waterS45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
International Inventories
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011
SAFETY DATA SHEET
Page 8 / 9 According to EC Directive 1907/2006/EC
70% Ethanol
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_____________________________________________________________________________________________
Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS CHINA AICS KECL Ethyl alcohol 200-578-6 - X X - X X X X XMethyl alcohol 200-659-6 - X X - X X X X X
16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowedR23/24/25 - Toxic by inhalation, in contact with skin and if swallowedR39/23/24/25 - Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
Prepared By Regulatory Affairs Creation Date 01-Nov-2011 Revision Date 01-Nov-2011 Revision Summary "***", and red text indicates revision Restrictions on use No information available. Training advice No information available. Literary reference No information available. Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
End of Safety Data Sheet
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011
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SAFETY DATA SHEET
70% Ethanol
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1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product Name Xylene - SCat No. R40133, R40217, R40219Synonyms No information available.Recommended Use Laboratory chemicals
Emergency Telephone Number Carechem 24: +44 (0) 1865 407333
2. HAZARDS IDENTIFICATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC.
R-phrase(s)R10 - FlammableR38 - Irritating to skinR43 - May cause sensitization by skin contactR50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
3. COMPOSITION/INFORMATION ON INGREDIENTS Haz/Non-haz
Component Weight % EC-No. Classification D-Limonene 5989-27-5
>98.0 EEC No. 227-813-5 R10 Xi; R38
R43 N; R50-53
_____________________________________________________________________________________________ Thermo Fisher Scientific
Remel12076 Santa Fe DriveLenexa, KS 66215 United StatesTelephone: 1-800-255-6730Fax:1-800-621-8251
Creation Date 01-Nov-2011
Entity / Business Name Oxoid Ltd.Wade RoadBasingstoke, Hants, UKRG24 8PWTelephone: +44 (0) 1256 841144
E-mail address mbd-sds@thermofisher.com
Revision Date 01-Nov-2011 Revision Number 1
Page 1 / 8 According to EC Directive 1907/2006/EC
SAFETY DATA SHEET
Company
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_____________________________________________________________________________________________ Butylated hydroxyanisole
25013-16-5<0.024 EEC No. 246-563-8 Xn; R22
Xi; R36/37/38 Carc. Cat. 3; R40
N; R51-53 For the full text of the R phrases mentioned in this Section, see Section 16
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes Ingestion Clean mouth with water and drink afterwards plenty of water. Do not induce vomiting. Obtain
medical attention. Inhalation Move to fresh air. Get medical attention if symptoms occur.. Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing MediaCO2, dry chemical, dry sand, alcohol-resistant foam. Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire Specific Hazards Arising from the ChemicalFlammable. Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Flash Point 48°C / 118.4°F Method No information available. Autoignition Temperature 255°C / 491°F Explosion Limits Lower 0.7 vol % Upper 6.1 vol %
_____________________________________________________________________________________________ Thermo Fisher Scientific
SAFETY DATA SHEET
Xylene - S
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Revision Date 01-Nov-2011
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6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Remove all sources of ignition. Avoid contact with skin, eyes and clothing. Use personal
protective equipment. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment and Clean Up
Soak up with inert absorbent material. Clean contaminated surface thoroughly
7. HANDLING AND STORAGE
Handling Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Keep away from open
flames, hot surfaces and sources of ignition. Storage Keep away from heat and sources of ignition. Keep tightly closed in a dry and cool place. Specific use(s) No information available.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limits
Component European Union The United Kingdom
Belgium France Spain Germany
D-Limonene MAK: 20 ppm 8 Stunden.
MAK: 110 mg/m3 8 Stunden.
skin notation Peak: 40 ppm
Peak: 220 mg/m3 TWA: 20 ppm 8
Stunden. exposure factor 2
TWA: 110 mg/m3 8 Stunden. exposure
factor 2
Component Italy Portugal The Netherlands Finland AustriaD-Limonene TWA: 25 ppm 8
tunteina TWA: 140 mg/m3 8
tunteina STEL: 50 ppm 15
minuutteina STEL: 280 mg/m3 15
minuutteina
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011
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SAFETY DATA SHEET
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Xylene - S
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Component Switzerland Poland Norway Ireland Denmark Australia D-Limonene STEL: 40 ppm 15
Minuten STEL: 220 mg/m3 15
Minuten MAK: 20 ppm 8
Stunden MAK: 110 mg/m3 8
Stunden
TWA: 25 ppm 8 timer
TWA: 140 mg/m3 8 timer
STEL: 37.5 ppm 15 minutter.
STEL: 175 mg/m3 15 minutter.
Occupational exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas Personal Protective Equipment Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced
Eye Protection Tightly fitting safety goggles Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure Hand Protection Protective gloves
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice Environmental exposure controls No information available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State LiquidAppearance Clear - Colourlessodor CitruspH No information available. Boiling Point/Range 175°C / 347°FMelting Point/Range No information available.Flash Point 48°C / 118.4°FExplosion Limits Lower 0.7 vol % Upper 6.1 vol %
10. STABILITY AND REACTIVITY
Stability Stable under recommended storage conditions. Conditions to Avoid Heat, flames and sparks. Exposure to air. Incompatible Materials Strong oxidizing agents
_____________________________________________________________________________________________ Thermo Fisher Scientific
SAFETY DATA SHEET
Xylene - S
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Revision Date 01-Nov-2011
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_____________________________________________________________________________________________ Hazardous Decomposition Products Carbon oxides, Thermal decomposition can lead to release of irritating gases and vapors Hazardous Polymerization No information available Hazardous Reactions . None under normal processing.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationD-Limonene 4400 mg/kg ( Rat ) 2000 mg/kg ( Rabbit )
Butylated hydroxyanisole 2 g/kg ( Rat ) Chronic Toxicity Carcinogenicity This product contains one or more substances which are classified by IARC as carcinogenic to
humans (Group I), probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B)
Component IARC UK
Butylated hydroxyanisole Group 2B IARC: (International Agency for Research on Cancer)IARC: (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansGroup 2A - Probably Carcinogenic to HumansGroup 2B - Possibly Carcinogenic to Humans
Sensitization May cause sensitization by skin contact. Neurological Effects No information available. Mutagenic Effects No information available. Reproductive Effects No information available. Developmental Effects No information available. Target Organs No information available.
_____________________________________________________________________________________________ Thermo Fisher Scientific
SAFETY DATA SHEET
Xylene - S Revision Date 01-Nov-2011
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12. ECOLOGICAL INFORMATION
Ecotoxicity. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Component Freshwater Algae Freshwater Fish Microtox Water FleaD-Limonene 0.619-0.796 mg/L LC50 96 h
35 mg/L LC50 96 h Persistence and Degradability No information available Bioaccumulative Potential No information available. Mobility No information available.
13. DISPOSAL CONSIDERATIONS
Waste from Residues / Unused Products
Dispose of as hazardous waste in compliance with local and national regulations
Contaminated Packaging Dispose of in accordance with local regulations.
14. TRANSPORT INFORMATION
IMDG/IMO UN-No UN2052 Hazard Class 3 Packing Group III Proper Shipping Name DIPENTENE
ADR UN-No UN2052 Hazard Class 3 Packing Group III Proper Shipping Name DIPENTENE
IATA UN-No UN2052 Hazard Class 3 Packing Group III Proper Shipping Name DIPENTENE
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011
Page 6 / 8
SAFETY DATA SHEET
According to EC Directive 1907/2006/EC
Xylene - S
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14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC Labelling
R-phrase(s)R10 - FlammableR38 - Irritating to skinR43 - May cause sensitization by skin contactR50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
S-phrase(s)S24 - Avoid contact with skinS37 - Wear suitable glovesS60 - This material and its container must be disposed of as hazardous wasteS61 - Avoid release to the environment. Refer to special instructions/ Safety data sheets
International Inventories
Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS CHINA AICS KECL D-Limonene 227-813-5 - X X - X X X X XButylated hydroxyanisole 246-563-8 - X X - X X X X X
16. OTHER INFORMATION
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011
SAFETY DATA SHEET
Page 7 / 8 According to EC Directive 1907/2006/EC
Xylene - S
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16. OTHER INFORMATIONFull text of R-phrases referred to under sections 2 and 3R10 - FlammableR22 - Harmful if swallowedR38 - Irritating to skinR40 - Limited evidence of a carcinogenic effectR43 - May cause sensitization by skin contactR36/37/38 - Irritating to eyes, respiratory system and skinR50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environmentR51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Prepared By Regulatory Affairs Creation Date 01-Nov-2011 Revision Date 01-Nov-2011 Revision Summary "***", and red text indicates revision Restrictions on use No information available. Training advice No information available. Literary reference No information available. Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
End of Safety Data Sheet
_____________________________________________________________________________________________ Thermo Fisher Scientific
Xylene - S Revision Date 01-Nov-2011
Page 8 / 8 According to EC Directive 1907/2006/EC
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product Identifier Product Description: Trichrome (Wheatley) StainCat No. R40025, R40217, R40219
Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicalsUses advised against No Information available Details of the supplier of the safety data sheet
E-mail address mbd-sds@thermofisher.com Emergency Telephone NumberCarechem 24: +44 (0) 1865 407333
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture REGULATION (EC) No 1272/2008 Not hazardous
Classification according to EU Directives 67/548/EEC or 1999/45/EC For the full text of the R phrases mentioned in this Section, see Section 16 R-phrase(s) none
Label Elements
Signal Word None Hazard Statements
Other Hazards No information available.
_____________________________________________________________________________________________
SAFETY DATA SHEET
Creation Date 13-Sep-2011
CompanyRemel12076 Santa Fe DriveLenexa, KS 66215 United StatesTelephone: 1-800-255-6730Fax:1-800-621-8251
SupplierOxoid Ltd.Wade RoadBasingstoke, Hants, UKRG24 8PWTelephone: +44 (0) 1256 841144 .
Revision Date 13-Sep-2011
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Revision Number 1
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Component EC-No. Weight % CAS-No Classification GHS
Classification REACH No.
Acetic acid 64-19-7
EEC No. 200-580-7
1 64-19-7 R10 C; R35
Skin Corr. 1A (H314) Flam. Liq. 3 (H226)
01-2119475328-30
Phosphotungstic acid 12067-99-1
EEC No. 235-087-6
< 1.0 12067-99-1 C; R34 Skin Corr. 1B (H314)
-
C.I. Acid Green 5 5141-20-8
EEC No. 225-906-5
< 1.0 5141-20-8 - - -
Fast green fcf 2353-45-9
EEC No. 219-091-5
< 1.0 2353-45-9 Muta. Cat. 3; R68 Muta. 2 (H341)
-
Disodium 4,5-dihydroxy-3-phenylazonaphthalene-2,7-disulphonate 4197-07-3
EEC No. 224-085-0
< 1.0 4197-07-3 - - -
For the full text of the R phrases mentioned in this Section, see Section 16
4. FIRST AID MEASURES
Description of first aid measures Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Obtain medical attention. Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes. Get medical attention if irritation develops and persists.. Ingestion Clean mouth with water and drink afterwards plenty of water. Do not induce vomiting without
medical advice. Get medical attention. Inhalation Move to fresh air. If symptoms persist, obtain medical attention.. Notes to Physician Treat symptomatically
5. FIRE-FIGHTING MEASURES
Extinguishing media Suitable Extinguishing MediaUse extinguishing measures that are appropriate to local circumstances and the surrounding environment Extinguishing media which must not be used for safety reasonsNo information available.
_____________________________________________________________________________________________
Trichrome (Wheatley) Stain Revision Date 13-Sep-2011
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_____________________________________________________________________________________________ Special hazards arising from the substance or mixture Thermal decomposition can lead to release of irritating gases and vapors Advice for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Avoid contact with the skin and the eyes. Environmental precautions Prevent further leakage or spillage if safe to do so Methods and material for containment and cleaning up Soak up with inert absorbent material. Clean contaminated surface thoroughly.
7. HANDLING AND STORAGE
Precautions for Safe Handling Ensure adequate ventilation. Avoid contact with skin and eyes. Wear personal protective equipment. Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place Specific End Uses
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure limitsComponent European Union The United Kingdom France Belgium SpainAcetic acid - STEL: 37 mg/m3
STEL: 15 ppm TWA: 10 ppm
TWA: 25 mg/m3
VLCT: 10 ppm VLCT: 25 mg/m3
TWA: 10 ppm 8 uren TWA: 25 mg/m3 8 uren
STEL: 15 ppm 15 minuten
STEL: 38 mg/m3 15 minuten
VLA-EC: 15 ppm 15 minutos
VLA-EC: 37 mg/m3 15 minutos
VLA-ED: 10 ppm 8 horas
VLA-ED: 25 mg/m3 8 horas
_____________________________________________________________________________________________
SAFETY DATA SHEET
Trichrome (Wheatley) Stain Revision Date 13-Sep-2011
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_____________________________________________________________________________________________ Phosphotungstic acid STEL: 10 mg/m3 15 min
TWA: 5 mg/m3 8 hr Component Italy Germany Portugal The Netherlands Finland Acetic acid - MAK: 10 ppm 8
Stunden. MAK: 25 mg/m3 8
Stunden. Peak: 20 ppm
Peak: 50 mg/m3 TWA: 10 ppm 8
Stunden. exposure factor 2
TWA: 25 mg/m3 8 Stunden. exposure
factor 2
STEL: 15 ppm 15 minutos
TWA: 10 ppm 8 horas
MAC-TGG 25 mg/m3 TWA: 5 ppm 8 tunteina TWA: 13 mg/m3 8
tunteina STEL: 10 ppm 15
minuutteina STEL: 25 mg/m3 15
minuutteina
Component Austria Denmark Switzerland Poland Norway Acetic acid STEL: 20 ppm 15
Minuten STEL: 50 mg/m3 15
Minuten MAK: 10 ppm 8
Stunden MAK: 25 mg/m3 8
Stunden
TWA: 10 ppm 8 timer TWA: 25 mg/m3 8 timer
STEL: 20 ppm 15 Minuten
STEL: 50 mg/m3 15 Minuten
MAK: 10 ppm 8 Stunden
MAK: 25 mg/m3 8 Stunden
NDSCh: 30 mg/m3 15 minutach
NDS: 15 mg/m3 8 godzinach
TWA: 10 ppm 8 timer TWA: 25 mg/m3 8 timer
STEL: 20 ppm 15 minutter.
STEL: 37.5 mg/m3 15 minutter.
Component Bulgaria Croatia Ireland Cyprus Czech Republic Acetic acid TWA: 25.0 mg/m3
STEL : 37.0 mg/m3TWA: 10 ppm 8 satima.
TWA: 25 mg/m3 8 satima.
TWA: 10 ppm 8 hr. TWA: 25 mg/m3 8 hr. STEL: 15 ppm 15 min
STEL: 37 mg/m3 15 min
TWA: 10 ppm TWA: 25 mg/m3
TWA: 25 mg/m3 8 hodinách.
Ceiling: 35 mg/m3
Component Estonia Gibraltar Greece Hungary Iceland Acetic acid TWA: 10 ppm 8
tundides. TWA: 25 mg/m3 8
tundides. STEL: 10 ppm 15
minutites. STEL: 25 mg/m3 15
minutites.
TWA: 10 ppm 8 hr TWA: 25 mg/m3 8 hr
STEL: 15 ppm STEL: 37 mg/m3
TWA: 10 ppm TWA: 25 mg/m3
STEL: 25 mg/m3 15 percekben.
TWA: 25 mg/m3 8 órában.
TWA: 10 ppm 8 klukkustundum.
TWA: 25 mg/m3 8 klukkustundum. Ceiling: 20 ppm
Ceiling: 50 mg/m3
Component Latvia Lithuania Luxembourg Malta Romania Acetic acid TWA: 10 ppm
TWA: 25 mg/m3TWA: 10 ppm
TWA: 25 mg/m3TWA: 10 ppm 8
Stunden TWA: 25 mg/m3 8
Stunden
TWA: 10 ppm TWA: 25 mg/m3
TWA: 10 ppm 8 ore TWA: 25 mg/m3 8 ore
Component Russia - TWA Slovak Republic Slovenia Sweden Turkey
_____________________________________________________________________________________________
SAFETY DATA SHEET
Trichrome (Wheatley) Stain
Revision Date 13-Sep-2011
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_____________________________________________________________________________________________ Component Russia - TWA Slovak Republic Slovenia Sweden Turkey Acetic acid Skin notation
MAC: 5 mg/m310 25
TWA: 10 ppm 8 urah TWA: 25 mg/m3 8 urah
STV: 10 ppm 15 minuter
STV: 25 mg/m3 15 minuter
LLV: 5 ppm 8 timmar. LLV: 13 mg/m3 8
timmar.
TWA: 10 ppm 8 saat TWA: 25 mg/m3 8 saat
Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits
established by the region specific regulatory bodies.Derived No Effect Level (DNEL) No information available.Predicted No Effect Concentration (PNEC)
No information available.
Exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areasPersonal protective equipment Eye Protection Safety glasses with side-shields Hand Protection Protective gloves Skin and body protection Long sleeved clothing Respiratory Protection When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators
Hygiene Measures Handle in accordance with good industrial hygiene and safety practiceEnvironmental exposure controls No information available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State LiquidAppearance Dark blue / GreenpH No information available. Boiling Point/Range Not applicableMelting Point/Range No information available.Flash Point Not applicableAutoignition Temperature No information available.
10. STABILITY AND REACTIVITY
Reactivity Chemical Stability Stable under recommended storage conditions.
_____________________________________________________________________________________________
SAFETY DATA SHEET
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_____________________________________________________________________________________________ Possibility of Hazardous Reactions Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions . None under normal processing.. Conditions to Avoid Incompatible products. Incompatible Materials Strong oxidizing agents. Hazardous Decomposition Products None under normal use conditions
11. TOXICOLOGICAL INFORMATION
Information on Toxicological Effects
Acute Toxicity Product Information Product does not present an acute toxicity hazard based on known or supplied
information
Component Information Component LD50 Oral LD50 Dermal LC50 InhalationAcetic acid 3310 mg/kg ( Rat ) 1060 mg/kg ( Rabbit ) 11.4 mg/L ( Rat ) 4 hPhosphotungstic acid 3300 mg/kg ( Rat )C.I. Acid Green 5 2 g/kg ( Rat )Fast green fcf 2 g/kg ( Rat )
Chronic Toxicity Carcinogenicity There are no known carcinogenic chemicals in this product
Sensitization No information available.Mutagenic Effects No information availableReproductive Effects No information available.Developmental Effects No information available.Target Organs Respiratory system, Eyes, Teeth, Skin.Endocrine Disruptor Information None known
_____________________________________________________________________________________________
Revision Date 13-Sep-2011
SAFETY DATA SHEET
Trichrome (Wheatley) Stain
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12. ECOLOGICAL INFORMATION
Toxicity Ecotoxicity effects
Component Freshwater Algae Freshwater Fish Microtox Water FleaAcetic acid Pimephales promelas:
LC50 = 88 mg/L/96hLepomis macrochirus: LC50 = 75 mg/L/96h
Photobacterium phosphoreum: EC50 = 8.8 mg/L/15 min Photobacterium phosphoreum: EC50 = 8.8 mg/L/25 min Photobacterium phosphoreum: EC50 = 8.8 mg/L/5 min
EC50 = 95 mg/L/24h
Persistence and degradability No information available Bioaccumulative potential No information available. Component log Pow
Acetic acid -0.2
Mobility in soil No information available. Results of PBT and vPvB assessment Other adverse effects No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods Waste from Residues / Unused Products
Dispose of in accordance with local regulations
_____________________________________________________________________________________________
SAFETY DATA SHEET
Trichrome (Wheatley) Stain
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Revision Date 13-Sep-2011
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_____________________________________________________________________________________________ Contaminated Packaging Empty containers should be taken to local recyclers for disposal 14. TRANSPORT INFORMATION
IMDG/IMO Not regulated
ADR Not regulated
IATA Not regulated
15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture International Inventories
Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS CHINA AICS KECL Acetic acid 200-580-7 - X X - X X X X XPhosphotungstic acid 235-087-6 - X X - X X - X XC.I. Acid Green 5 225-906-5 - X X - - X X X -Fast green fcf 219-091-5 - X X - X X X X XDisodium 4,5-dihydroxy-3-phenylazonaphthalene-2,7-disulphonate
224-085-0 - - - - - - - X -
Legend TSCA - United States Toxic Substances Control Act Section 8(b) InventoryEINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical SubstancesDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List PICCS - Philippines Inventory of Chemicals and Chemical SubstancesENCS - Japan Existing and New Chemical SubstancesCHINA - China Inventory of Existing Chemical SubstancesAICS - Inventory of Chemical SubstancesKECL - Existing and Evaluated Chemical Substances
Chemical Safety Assessment
_____________________________________________________________________________________________
SAFETY DATA SHEET
Trichrome (Wheatley) Stain
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Revision Date 13-Sep-2011
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16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3R10 - FlammableR34 - Causes burnsR35 - Causes severe burnsR68 - Possible risk of irreversible effects
Revision Date 13-Sep-2011Revision Summary Not applicableThis safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
End of Safety Data Sheet
_____________________________________________________________________________________________
Revision Date 13-Sep-2011
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product Name Acid Ethanol 90%Cat No. R40134, R40217, R40219Synonyms No information available.Recommended Use Laboratory chemicals
Emergency Telephone Number Carechem 24: +44 (0) 1865 407333
2. HAZARDS IDENTIFICATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC.
R-phrase(s)R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
3. COMPOSITION/INFORMATION ON INGREDIENTS Haz/Non-haz
Component Weight % EC-No. Classification Ethyl alcohol
64-17-585 EEC No. 200-578-6 F; R11
Methyl alcohol 67-56-1
5 EEC No. 200-659-6 F; R11 T; R23/24/25-39/23/24/25
Isopropyl alcohol 67-63-0
5 EEC No. 200-661-7 F; R11 Xi; R36
R67
_____________________________________________________________________________________________ Thermo Fisher Scientific
Revision Date 01-Nov-2011 Revision Number 1
SAFETY DATA SHEET
Company Remel12076 Santa Fe DriveLenexa, KS 66215 United StatesTelephone: 1-800-255-6730Fax:1-800-621-8251
Creation Date 01-Nov-2011
Entity / Business Name Oxoid Ltd.Wade RoadBasingstoke, Hants, UKRG24 8PWTelephone: +44 (0) 1256 841144
Page 1 / 11 According to EC Directive 1907/2006/EC
E-mail address mbd-sds@thermofisher.com
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_____________________________________________________________________________________________
Acetic acid 64-19-7
0.5 EEC No. 200-580-7 R10 C; R35
For the full text of the R phrases mentioned in this Section, see Section 16
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes Ingestion Get medical attention. Clean mouth with water and drink afterwards plenty of water. Do not
induce vomiting. Inhalation Move to fresh air. Get medical attention if symptoms occur.. Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing MediaCO2, dry chemical, dry sand, alcohol-resistant foam. Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire Specific Hazards Arising from the ChemicalFlammable. Keep product and empty container away from heat and sources of ignition. Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Flash Point 18.33°C / 65°F Method Closed cup Autoignition Temperature No information available.
_____________________________________________________________________________________________ Thermo Fisher Scientific
SAFETY DATA SHEET
Acid Ethanol 90%
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Revision Date 01-Nov-2011
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_____________________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Remove all sources of ignition. Use personal protective equipment. Ensure adequate
ventilation. Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment and Clean Up
Soak up with inert absorbent material Clean contaminated surface thoroughly
7. HANDLING AND STORAGE
Handling Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Keep away from open
flames, hot surfaces and sources of ignition. Storage Keep away from heat and sources of ignition. Keep containers tightly closed in a cool, well-
ventilated place. Specific use(s) No information available.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limits
Component European Union The United Kingdom
Belgium France Spain Germany
Ethyl alcohol TWA: 1000 ppm TWA; 1920 mg/m3
TWA WEL - STEL: 3000 ppm STEL; 5760
mg/m3 STEL
TWA: 1000 ppm 8 uren
TWA: 1907 mg/m3 8 uren
VME: 1000 ppm 8 heures.
VME: 1900 mg/m3 8 heures.
VLCT: 5000 ppm VLCT: 9500 mg/m3
VLA-ED: 1000 ppm 8 horas
VLA-ED: 1910 mg/m3 8 horas
500 ppm TWA; 960 mg/m3 TWA
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Component European Union The United Kingdom
Belgium France Spain Germany
Methyl alcohol TWA: 200 ppm 8 hr TWA: 260 mg/m3 8
hr Skin
WEL - TWA: 200 ppm TWA; 266
mg/m3 TWA WEL - STEL: 250 ppm STEL; 333
mg/m3 STEL
TWA: 200 ppm 8 uren
TWA: 266 mg/m3 8 uren
STEL: 250 ppm 15 minuten
STEL: 333 mg/m3 15 minuten
Skin
VME: 200 ppm 8 heures. restrictive
limit VME: 260 mg/m3 8 heures. restrictive
limit VLCT: 1000 ppm
VLCT: 1300 mg/m3 Skin
Skin VLA-ED: 200 ppm 8
horas VLA-ED: 266 mg/m3
8 horas
200 ppm TWA; 270 mg/m3 TWA
Skin absorber
Isopropyl alcohol STEL: 500 ppm 15 min
STEL: 1250 mg/m3 15 min
TWA: 400 ppm 8 hr TWA: 999 mg/m3 8
hr
TWA: 200 ppm 8 uren
TWA: 500 mg/m3 8 uren
STEL: 400 ppm 15 minuten
STEL: 1000 mg/m3 15 minuten
VLCT: 400 ppm VLCT: 980 mg/m3
VLA-EC: 500 ppm 15 minutos
VLA-EC: 1250 mg/m3 15 minutos
VLA-ED: 400 ppm 8 horas
VLA-ED: 998 mg/m3 8 horas
MAK: 200 ppm 8 Stunden.
MAK: 500 mg/m3 8 Stunden.
Peak: 400 ppm Peak: 1000 mg/m3 TWA: 200 ppm 8
Stunden. exposure factor 2
TWA: 500 mg/m3 8 Stunden. exposure
factor 2Acetic acid - STEL: 37 mg/m3
STEL: 15 ppm TWA: 10 ppm
TWA: 25 mg/m3
TWA: 10 ppm 8 uren TWA: 25 mg/m3 8
uren STEL: 15 ppm 15
minuten STEL: 38 mg/m3 15
minuten
VLCT: 10 ppm VLCT: 25 mg/m3
VLA-EC: 15 ppm 15 minutos
VLA-EC: 37 mg/m3 15 minutos
VLA-ED: 10 ppm 8 horas
VLA-ED: 25 mg/m3 8 horas
MAK: 10 ppm 8 Stunden.
MAK: 25 mg/m3 8 Stunden.
Peak: 20 ppm Peak: 50 mg/m3 TWA: 10 ppm 8
Stunden. exposure factor 2
TWA: 25 mg/m3 8 Stunden. exposure
factor 2
Component Italy Portugal The Netherlands Finland AustriaEthyl alcohol TWA: 1000 ppm 8
horasSkin
STEL: 1900 mg/m3 15 minuten
TWA: 260 mg/m3 8 uren
TWA: 1000 ppm 8 tunteina
TWA: 1900 mg/m3 8 tunteina
STEL: 1300 ppm 15 minuutteina
STEL: 2500 mg/m3 15 minuutteina
STEL: 2000 ppm 15 Minuten
STEL: 3800 mg/m3 15 Minuten
MAK: 1000 ppm 8 Stunden
MAK: 1900 mg/m3 8 Stunden
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Component Italy Portugal The Netherlands Finland AustriaMethyl alcohol TWA: 200 ppm 8 ore.
TWA: 260 mg/m3 8 ore. Skin
STEL: 250 ppm 15 minutos
TWA: 200 ppm 8 horas Skin
Skin STEL: 520 mg/m3 15
minuten TWA: 260 mg/m3 8 uren
TWA: 200 ppm 8 tunteina
TWA: 270 mg/m3 8 tunteina
STEL: 250 ppm 15 minuutteina
STEL: 330 mg/m3 15 minuutteina
Skin
Skin STEL: 800 ppm 15
Minuten STEL: 1040 mg/m3 15
Minuten MAK: 200 ppm 8
Stunden MAK: 260 mg/m3 8
StundenIsopropyl alcohol STEL: 400 ppm 15
minutos TWA: 200 ppm 8 horas
TWA: 200 ppm 8 tunteina
TWA: 500 mg/m3 8 tunteina
STEL: 250 ppm 15 minuutteina
STEL: 620 mg/m3 15 minuutteina
STEL: 800 ppm 15 Minuten
STEL: 2000 mg/m3 15 Minuten
MAK: 200 ppm 8 Stunden
MAK: 500 mg/m3 8 Stunden
Acetic acid - STEL: 15 ppm 15 minutos
TWA: 10 ppm 8 horas
MAC-TGG 25 mg/m3 TWA: 5 ppm 8 tunteina TWA: 13 mg/m3 8
tunteina STEL: 10 ppm 15
minuutteina STEL: 25 mg/m3 15
minuutteina
STEL: 20 ppm 15 Minuten
STEL: 50 mg/m3 15 Minuten
MAK: 10 ppm 8 Stunden
MAK: 25 mg/m3 8 Stunden
Component Switzerland Poland Norway Ireland Denmark Australia Ethyl alcohol STEL: 1000 ppm 15
Minuten STEL: 1920 mg/m3
15 Minuten MAK: 500 ppm 8
Stunden MAK: 960 mg/m3 8
Stunden
NDS: 1900 mg/m3 8 godzinach
TWA: 500 ppm 8 timer
TWA: 950 mg/m3 8 timer
STEL: 625 ppm 15 minutter.
STEL: 1187.5 mg/m3 15 minutter.
TWA: 1000 ppm 8 hr.
TWA: 1900 mg/m3 8 hr.
TWA: 1000 ppm 8 timer
TWA: 1900 mg/m3 8 timer
TWA: 1000 ppm TWA: 1880 mg/m3
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Component Switzerland Poland Norway Ireland Denmark Australia Methyl alcohol Skin
STEL: 800 ppm 15 Minuten
STEL: 1040 mg/m3 15 Minuten
MAK: 200 ppm 8 Stunden
MAK: 260 mg/m3 8 Stunden
NDSCh: 300 mg/m3 15 minutach
NDS: 100 mg/m3 8 godzinach
TWA: 100 ppm 8 timer
TWA: 130 mg/m3 8 timer
STEL: 150 ppm 15 minutter.
STEL: 162.5 mg/m3 15 minutter.
Skin
TWA: 200 ppm 8 hr. TWA: 260 mg/m3 8
hr. Skin
TWA: 200 ppm 8 timer
TWA: 260 mg/m3 8 timer Skin
STEL: 250 ppm STEL: 328 mg/m3
TWA: 200 ppm TWA: 262 mg/m3
Isopropyl alcohol STEL: 400 ppm 15 Minuten
STEL: 1000 mg/m3 15 Minuten
MAK: 200 ppm 8 Stunden
MAK: 500 mg/m3 8 Stunden
NDSCh: 1200 mg/m3 15 minutach
NDS: 900 mg/m3 8 godzinach
TWA: 100 ppm 8 timer
TWA: 245 mg/m3 8 timer
STEL: 150 ppm 15 minutter.
STEL: 306.25 mg/m3 15 minutter.
TWA: 200 ppm 8 hr. STEL: 400 ppm 15
min Skin
TWA: 200 ppm 8 timer
TWA: 490 mg/m3 8 timer
STEL: 500 ppm STEL: 1230 mg/m3
TWA: 400 ppm TWA: 983 mg/m3
Acetic acid STEL: 20 ppm 15 Minuten
STEL: 50 mg/m3 15 Minuten
MAK: 10 ppm 8 Stunden
MAK: 25 mg/m3 8 Stunden
NDSCh: 30 mg/m3 15 minutach
NDS: 15 mg/m3 8 godzinach
TWA: 10 ppm 8 timer
TWA: 25 mg/m3 8 timer
STEL: 20 ppm 15 minutter.
STEL: 37.5 mg/m3 15 minutter.
TWA: 10 ppm 8 hr. TWA: 25 mg/m3 8 hr.
STEL: 15 ppm 15 min
STEL: 37 mg/m3 15 min
TWA: 10 ppm 8 timer
TWA: 25 mg/m3 8 timer
STEL: 15 ppm STEL: 37 mg/m3
TWA: 10 ppm TWA: 25 mg/m3
Occupational exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas Personal Protective Equipment Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced
Eye Protection Tightly fitting safety goggles Skin and body protection Long sleeved clothing. Chemical resistant apron. Antistatic boots. Impervious gloves. Hand Protection Protective gloves
Hygiene Measures When using, do not eat, drink or smoke. Provide regular cleaning of equipment, work area and
clothing. Environmental exposure controls No information available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State LiquidAppearance Clear ColourlesspH No information available. Boiling Point/Range No information available.Melting Point/Range No information available.
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9. PHYSICAL AND CHEMICAL PROPERTIESFlash Point 18.33°C / 65°FMethod Closed cup
10. STABILITY AND REACTIVITY
Stability Stable under recommended storage conditions. Conditions to Avoid Heat, flames and sparks. Incompatible Materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Hazardous Polymerization No information available Hazardous Reactions . None under normal processing.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity Product Information Harmful by inhalation, in contact with skin and if swallowed
Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationEthyl alcohol 7060 mg/kg ( Rat ) 20000 ppm/10H ( Rat )
Methyl alcohol 5628 mg/kg ( Rat ) 15800 mg/kg ( Rabbit ) 64000 ppm ( Rat ) 4 h 83.2 mg/L ( Rat ) 4 h
Isopropyl alcohol 4396 mg/kg ( Rat ) 12800 mg/kg ( Rat ) 12870 mg/kg ( Rabbit )
72.6 mg/L ( Rat ) 4 h
Acetic acid 3310 mg/kg ( Rat ) 1060 mg/kg ( Rabbit ) 11.4 mg/L ( Rat ) 4 h Chronic Toxicity Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component IARC UK Ethyl alcohol Group 1
IARC: (International Agency for Research on Cancer)IARC: (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansGroup 2A - Probably Carcinogenic to HumansGroup 2B - Possibly Carcinogenic to Humans
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Sensitization No information available. Neurological Effects No information available. Mutagenic Effects No information available. Reproductive Effects No information available. Developmental Effects No information available. Target Organs Blood, Liver, Respiratory system, Central nervous system (CNS), Eyes, Reproductive System,
Gastrointestinal tract (GI), Skin, Optic nerve.
12. ECOLOGICAL INFORMATION
Ecotoxicity.
Component Freshwater Algae Freshwater Fish Microtox Water FleaEthyl alcohol Leucidus idus: LC50 = 8.14
mg/L/48hPhotobacterium
phosphoreum:EC50 = 34634 mg/L/30 min
Photobacterium phosphoreum:EC50 = 35470
mg/L/5 min
EC50 = 9268 mg/L/48h EC50 = 10800 mg/L/24h
Methyl alcohol Pimephales promelas: LC50 > 10000 mg/L 96h
EC50 = 39000 mg/L 25 min EC50 = 40000 mg/L 15 min EC50 = 43000 mg/L 5 min
EC50 > 10000 mg/L 24h
Isopropyl alcohol 1000 mg/L EC50 > 72 h 1000 mg/L EC50 > 96 h
1400000 µg/L LC50 96 h 9640 mg/L LC50 96 h
11130 mg/L LC50 96 h
= 35390 mg/L EC50 Photobacterium
phosphoreum 5 min
13299 mg/L EC50 = 48 h
Acetic acid Pimephales promelas: LC50 = 88 mg/L/96h
Lepomis macrochirus: LC50 = 75 mg/L/96h
Photobacterium phosphoreum: EC50 = 8.8
mg/L/15 min Photobacterium
phosphoreum: EC50 = 8.8 mg/L/25 min
Photobacterium phosphoreum: EC50 = 8.8
mg/L/5 min
EC50 = 95 mg/L/24h
Persistence and Degradability No information available Bioaccumulative Potential No information available. Mobility No information available.
Component log PowEthyl alcohol -0.32
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Component log PowMethyl alcohol -0.74
Isopropyl alcohol 0.05Acetic acid -0.2
13. DISPOSAL CONSIDERATIONS
Waste from Residues / Unused Products
Dispose of as hazardous waste in compliance with local and national regulations
Contaminated Packaging Dispose of in accordance with local regulations.
14. TRANSPORT INFORMATION
IMDG/IMO UN-No UN1170 Hazard Class 3 Packing Group II Proper Shipping Name ETHANOL SOLUTION
ADR UN-No UN1170 Hazard Class 3 Packing Group II Proper Shipping Name ETHANOL SOLUTION
IATA UN-No UN1170 Hazard Class 3 Packing Group II Proper Shipping Name ETHANOL SOLUTION
15. REGULATORY INFORMATION
The preparation is classified as dangerous in accordance with Directive 1999/45/EC Labelling
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R-phrase(s)R11 - Highly flammableR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
S-phrase(s)S 7 - Keep container tightly closedS16 - Keep away from sources of ignition. No smokingS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS28A - After contact with skin, wash immediately with plenty of waterS45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
International Inventories
Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS CHINA AICS KECL Ethyl alcohol 200-578-6 - X X - X X X X XMethyl alcohol 200-659-6 - X X - X X X X XIsopropyl alcohol 200-661-7 - X X - X X X X XAcetic acid 200-580-7 - X X - X X X X X
16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3R10 - FlammableR11 - Highly flammableR35 - Causes severe burnsR36 - Irritating to eyesR67 - Vapors may cause drowsiness and dizzinessR20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR68/20/21/22 - Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowedR23/24/25 - Toxic by inhalation, in contact with skin and if swallowedR39/23/24/25 - Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
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16. OTHER INFORMATIONPrepared By Regulatory Affairs Creation Date 01-Nov-2011 Revision Date 01-Nov-2011 Revision Summary "***", and red text indicates revision Restrictions on use No information available. Training advice No information available. Literary reference No information available. Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
End of Safety Data Sheet
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1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product Name Lugol's IodineCat No. R114353, R21528, R21670, R21671, R40029, R40217Synonyms No information available.Recommended Use Laboratory chemicals
Emergency Telephone Number Carechem 24: +44 (0) 1865 407333
2. HAZARDS IDENTIFICATION
The preparation is non-dangerous in accordance with Directive 1999/45/EC.
R-phrase(s)none
3. COMPOSITION/INFORMATION ON INGREDIENTS Haz/Non-haz
Component Weight % EC-No. Classification Potassium iodide
7681-11-09 EEC No. 231-659-4 -
Iodine 7553-56-2
4 EEC No. 231-442-4 Xn; R20/21 N; R50
For the full text of the R phrases mentioned in this Section, see Section 16
_____________________________________________________________________________________________ Thermo Fisher Scientific
Entity / Business Name Oxoid Ltd.Wade RoadBasingstoke, Hants, UKRG24 8PWTelephone: +44 (0) 1256 841144
E-mail address mbd-sds@thermofisher.com
Revision Date 01-Nov-2011 Revision Number 1
SAFETY DATA SHEET
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Company
According to EC Directive 1907/2006/EC
Remel12076 Santa Fe DriveLenexa, KS 66215 United StatesTelephone: 1-800-255-6730Fax:1-800-621-8251
Creation Date 01-Nov-2011
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4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes
and shoes Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if
symptoms occur.. Inhalation Move to fresh air Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing MediaUse extinguishing measures that are appropriate to local circumstances and the surrounding environment Extinguishing media which must not be used for safety reasonsNo information available. Specific Hazards Arising from the ChemicalKeep product and empty container away from heat and sources of ignition Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Flash Point Not applicableMethod No information available. Autoignition Temperature No information available.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Environmental Precautions Prevent further leakage or spillage if safe to do so. Should not be released into the
environment. Methods for Containment and Clean Up
Soak up with inert absorbent material Keep in suitable, closed containers for disposal.
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7. HANDLING AND STORAGE
Handling Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Storage Keep container tightly closed in a dry and well-ventilated place. Specific use(s) No information available.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limits
Component European Union The United Kingdom
Belgium France Spain Germany
Iodine STEL: 0.1 ppm; 1.1mg/m3
TWA 0.1ppm; TWA 1mg/m3
VLCT: 0.1 ppm VLCT: 1 mg/m3
VLA-EC: 0.1 ppm 15 minutos
VLA-EC: 1 mg/m3 15 minutos
TWA: 0.1 ppmTWA: 1.1 mg/m3
skin absorber
Component Italy Portugal The Netherlands Finland Austria
Iodine Ceiling: 0.1 ppm 0.1ppm MAC; 1mg/m3 MAC
STEL: 0.1 ppm 15 minuutteina
STEL: 1.1 mg/m3 15 minuutteina
Skin
Skin STEL: 0.1 ppm 15
Minuten STEL: 1 mg/m3 15
Minuten MAK: 0.1 ppm 8
Stunden MAK: 1 mg/m3 8
Stunden Ceiling: 0.1 ppm Ceiling: 1 mg/m3
Component Switzerland Poland Norway Ireland Denmark Australia
Iodine STEL: 0.1 ppm 15 Minuten
STEL: 1 mg/m3 15 Minuten
MAK: 0.1 ppm 8 Stunden
MAK: 1 mg/m3 8 Stunden
NDSCh: 1 mg/m3 15 minutach
NDS: 0.5 mg/m3 8 godzinach
Ceiling: 0.1 ppm Ceiling: 1 mg/m3
STEL: 0.1 ppm 15 min
STEL: 1 mg/m3 15 min
Ceiling: 0.1 ppm Ceiling: 1 mg/m3
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_____________________________________________________________________________________________ Occupational exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas Personal Protective Equipment Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced
Eye Protection Tightly fitting safety goggles Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure Hand Protection Protective gloves
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice Environmental exposure controls No information available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State LiquidAppearance Yellow to brownpH No information available. Boiling Point/Range No information available.Melting Point/Range No information available.Flash Point Not applicable
10. STABILITY AND REACTIVITY
Stability Stable under normal conditions. Conditions to Avoid Extremes of temperature and direct sunlight. Incompatible Materials Strong oxidizing agents, Ammonia, Reducing agents Hazardous Decomposition Products None under normal use conditions Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions . None under normal processing.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity Product Information Product does not present an acute toxicity hazard based on known or supplied information
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Component Information
Component LD50 Oral LD50 Dermal LC50 InhalationPotassium iodide 2779 mg/kg (Rat)
Iodine 14 g/kg ( Rat ) Chronic Toxicity Carcinogenicity There are no known carcinogenic chemicals in this product
Sensitization No information available. Neurological Effects No information available. Mutagenic Effects No information available. Reproductive Effects Experiments have shown reproductive toxicity effects on laboratory animals. Developmental Effects No information available. Target Organs Respiratory system, Central nervous system (CNS), Eyes, Central Vascular System (CVS),
Skin.
12. ECOLOGICAL INFORMATION
EcotoxicityVery toxic to aquatic organisms. However, at the concentration present, this preparation is not expected to present significant adverse environmental effects.
Component Freshwater Algae Freshwater Fish Microtox Water FleaPotassium iodide Onchorhynchus mykiss:
LC50: 3200 mg/L/120hIodine Oncorhynchus mykiss: LC50
= 1,7 mg/l/96 hEC50 = 0,2 mg/l/48 h
Persistence and Degradability No information available Bioaccumulative Potential No information available. Mobility No information available.
Component log PowPotassium iodide 0.04
Iodine 2.49
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13. DISPOSAL CONSIDERATIONS
Waste from Residues / Unused Products
Dispose of in accordance with local regulations
Contaminated Packaging Empty containers should be taken to local recyclers for disposal
14. TRANSPORT INFORMATION
IMDG/IMO Not regulated
ADR Not regulated
IATA Not regulated
15. REGULATORY INFORMATION
The preparation is non-dangerous in accordance with Directive 1999/45/EC Labelling
R-phrase(s)none
S-phrase(s)none
International Inventories
Component EINECS ELINCS NLP TSCA DSL NDSL PICCS ENCS CHINA AICS KECL Potassium iodide 231-659-4 - X X - X X X X XIodine 231-442-4 - X X - X - X X X
16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3R50 - Very toxic to aquatic organismsR20/21 - Harmful by inhalation and in contact with skin
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16. OTHER INFORMATION
Prepared By Regulatory Affairs Creation Date 01-Nov-2011 Revision Date 01-Nov-2011 Revision Summary "***", and red text indicates revision Restrictions on use No information available. Training advice No information available. Literary reference No information available. Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
End of Safety Data Sheet
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