Materials for Femtospin Project Colin Forbes cforbes628@qub.ac.uk.

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Materials for Femtospin Project

Colin Forbes

cforbes628@qub.ac.uk

Introduction

• Brief Overview of Key materials

• Material sequencing

• Overview of experimental results

• Future

Materials of interest

• GdFeCo ternary alloys with 20-25% Gd & Co = 10%

• Gd/(FeCo) multilayers– 20-25% volume fraction of Gd

• FePt(5nm)/Co(5,10-20nm) bilayers

• FeRh

• FeTb – TbFe2 and TbFe3 ordered phases

• Elemental RE– GdFe2 ordered phases

Material Sequencing

1. GdFeCo ternary alloy

2. Gd/(FeCo) multilayers

3. FePt(5nm)/Co(5,10-20nm) bilayers

4.= FeTb, FeTb2, FeTb3

4.= FeRh4.= Gd & GdFe2

Experimental Analysis

• Ternary Alloy Depositions– GdFeCo

• Gd – 15 - 30%• Fe – 60 – 75% 50nm• Co – 10%

• SiO2 wafers used as substrates

• Depositions done at ambient temperatures

• Samples sent to Seagate

Ternary Alloy Samples

SiO2

Ta

GdxFe90-xCo10

Ta 5nm

50nm

5nm

Where x = 15 - 30

XRD Analysis Gd20Fe70Co10 (50nm)

• No crystalline structure• Amorphous surface

Heated VSM GdFeCo alloys

Heated VSM

• 20% Gd has perpendicular anisotropy at room temperature while 25% Gd has in plane anisotropy

• Magnetic properties change with temperature• 25% Gd switches from in plane to perpendicular anisotropy at

≈300°C

• Multilayers of Gd and Fe90Co10 - (40nm)

• Volume factor of Gd was either 20 or 25%• Single bilayer• Double bilayer• Quadruple bilayer

• Depositions at room temperature

• Samples sent to Seagate

Gd/(FeCo) Multilayer Samples

SiO2

Ta

Gd

Fe90Co10

Ta

SiO2

Ta

Gd

Fe90Co10

Ta

Gd

Fe90Co10

SiO2

Ta

Gd

Fe90Co10

Ta

Gd

Fe90Co10

Gd

Fe90Co10

5nm

40nm

5nm

Gd

Fe90Co10

BH Looper AnalysisTa(5nm)/[Gd(20%)/Fe90Co10](40nm)/Ta(5nm) in

Plane

Ta(5nm)/[Gd(25%)/Fe90Co10](40nm)/Ta(5nm) in Plane

VSM Analysis of Gd/FeCo multilayers

Ta(5nm)/[Gd(4nm)FeCo(16nm)]2(40nm)/Ta(5nm) in Plane

Temp / °C Temp / °C

Temp / °C

Temp / °C

Heated VSM Measurements

Ta(5nm)/[Gd(5nm)FeCo(15nm)]2(40nm)/Ta(5nm) in Plane

• Decrease in both saturation & coercivity general trend• Not what was expected – in plane to perpendicular

anisotropy switching expected at compositional temp

Future

• Improve multilayer structures of Gd/(FeCo)– Vary Volume fraction– Magnetic Properties– Crystal structure– Temperature analysis

• Investigate FePt/Co – FePt(5nm)Co(5,10-20nm) bilayers

• FeRh

• FeTb, FeTb2, FeTb3

• Gd & GdFe2