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NON-MONOTONIC FLOW CURVES AND VORTICITY BANDING INSHEAR THICKENING SUSPENSIONS

Romain MariDepartment of Applied Mathematics and Theoretical Physics, University of Cambridge

Laboratoire Interdisciplinaire de Physique, CNRS-Université Grenoble-Alpes

Rahul ChackoDept. of Physics, Durham

Suzanne Fielding Mike CatesDAMTP, Cambridge

Ryohei SetoOkinawa (OIST)

Jeff MorrisLevich Institute, City College of NY

Morton Denn

SHEAR THICKENING[Cwalina & Wagner, JOR 2014]

260nm silica + polymer brush in PEG 200

~500nm calcium carbonate + polymer brush in PEG 200

[Egres & Wagner, JOR 2005]

SHEAR THICKENING

Transition between two (roughly) Newtonian branchesNewtonian suspending �uidHard particlesSize Brownian motion not necessaryInertia is not involved (Stokes �ow)Stabilized (=short-range repulsion)

100nm − 100μm

SUSPENSIONS OF HARD PARTICLES

Rate independent rheology

SUSPENSIONS OF HARD PARTICLES

Rate independent rheology

But it depends on friction

no contacts contacts

THICKENING SCENARIO (1)[Fernandez et al, PRL 2013]

[Seto et al, PRL 2013][Heussinger, PRE 2013]

[Wyart and Cates PRL 2013][Mari et al, JOR 2014]

STABILIZATION = SOFT REPULSION

Small stresses , no contacts

Large stresses , many contacts

σ ≪ /F ∗ a2

σ ≫ /F ∗ a2

NUMERICAL SIMULATIONS, RATE CONTROLLED[Seto, Mari, Morris & Denn, PRL 2013][Mari, Seto, Morris & Denn, JOR 2014]

THICKENING SCENARIO (2)[Wyart & Cates, PRL 2014]

Continuous Shear Thickening

THICKENING SCENARIO (2)[Wyart & Cates, PRL 2014]

Continuous Shear Thickening

THICKENING SCENARIO (2)[Wyart & Cates, PRL 2014]

Discontinuous Shear Thickening

THICKENING SCENARIO (2)[Wyart & Cates, PRL 2014]

Discontinuous Shear Thickening

THICKENING SCENARIO (2)[Wyart & Cates, PRL 2014]

Shear Jamming

STRESS-CONTROLLED SIMULATIONS[Mari, Seto, Morris & Denn, PRE 2015]

Non-monotonic �ow curves:S-shaped (discontinuous thickening)Arches (shear jamming)

WYART-CATES MODEL[Wyart & Cates, PRL 2014]

In practice,

"Minimal constitutive model" with qualitative features of ST:

σ = ηγ̇η(ϕ, f) = ( (f) − ϕη0 ϕJ )−2

(f) = f + (1 − f)ϕJ ϕμ

J ϕ0J

f = f(σ)

: "fraction of frictional contacts": only lubricated contacts: only frictional contacts

ff = 0f = 1

f(σ) ≈ exp(− /σ)σ0

FLOW INSTABILITIES

Stress-controlleduniform �ow curves

Uniform �ow unstable

[Hermes et al, 2015]

NORMAL STRESSES ACROSS SHEAR THICKENING[Mari, Seto, Morris and Denn, JOR 2014]

Normal stresses almost proportional to shear stress

STEADY GRADIENT BANDINGAt the interface:

=σ(1)xy σ

(2)xy

=p(1)yy p

(2)yy

STEADY GRADIENT BANDINGAt the interface:

=σ(1)xy σ

(2)xy

=p(1)yy p

(2)yy

Impossible!

STEADY VORTICITY BANDINGAt the interface:

=p(1)zz p

(2)zz

=γ̇(1) γ̇(2)

Impossible!

BANDING AND PARTICLE MIGRATIONSuspension balance model [Nott & Brady, JFM 1994]:

∇ ⋅ = ϕR(ϕ)( − )Σp vp vp+f

Reducing the problem to 1d

Conservation relationsMass conservation:

Momentum balance:

Stress control:

Constitutive model:Wyart-Cates + linear response:

Σ → ≡ σσzz

v → ≡ vvz

ϕ + (ϕv) = 0∂t ∂z

σ = −Rϕv∂z

⟨σ⟩ = ⟨η(ϕ, f)⟩γ̇

η(ϕ, f) = ( (f) − ϕη0 ϕJ )−2

(f) = f + (1 − f)ϕJ ϕμJ ϕ0

Jf = − [f − (σ)]∂t γ̇γ−1

0 f ∗

(σ) = exp(− /σ)f ∗ σ0

VORTICITY INSTABILITY MODEL

VORTICITY INSTABILITY MODELLinear stability analysis:

Unstable when

X = + δXX0 eikz+λt

η < − η∂σγ̇0k2γ0

ϕR∂ϕ

Hopf bifurcation and

Instability towards travelingbands

Reλ > 0 Imλ ≠ 0

TRAVELING BANDS

0:00 / 0:37

Fields snapshot

Strain-rate vs strain

TRAVELING BANDS

TRAVELING BANDS

Higher imposed stress

Very similar to Hermes et al.

"STOKESIAN DYNAMICS" SIMULATIONS

Instability for: η < − η∂σγ̇0k2 γ0

ϕR∂ϕ

Need /a ≳ 60Lz

Simulations with very large aspect ratio in favor of the vorticity

0:00 / 0:14

"STOKESIAN DYNAMICS" SIMULATIONSUniform �ow curve

σ/ = 0.5σ00:00 / 0:09

σ/ = 1σ00:00 / 0:15

σ/ = 2σ00:00 / 0:04

σ/ = 4σ00:00 / 0:01

COMPARISON WITH MODELSimulation Model

Snapshots from simulation

Flow curve when bandedFinite size effectsPhase diagram? Need to explore moreparameter spaceExperiments are not controlling volume,vorticity normal stress bounded

NEAR FUTURE

0:00 / 0:21