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Dep’t of Chemical Engineering

Hoseo University, Korea

(kklim@hoseo.edu)

2011-11-16~19 H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

Prof. Gye Gyu Lim, Ph.D.

President of KDA (www. Koreadme.com)

Contents

I. General Aspects

II. DME R&D in Korea 1. Trial Supply of DME+LPG Mixture to House Holds

2. Safety for Machinery and Equipment applying to DME

3. Development of DME synthesis Process using COG from Steel Company

4. Overseas Commercial Plant Construction

5. DME Vehicle development

III. Upcomings

2011-11-16~19 H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

A. Where to use it in Korea?

2011-11-16~19 H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

I. General Aspects

B. How to make it in Korea?

2011-11-16~19

NG Coals Bio Sources COG

Syngas (CO+H2)

(Cu, Cr, Zn)

(Co, Fe)

F- T Liquids

DME

MeOH

Gasoline

Naphtha

Middle Distilates

Diesel/Jet Fuels

10TPD Plant

H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

C. Is it feasible and economical?

2011-11-16~19

DME Production Cost =1.42MeOH Price+Fixed Costs DME Selling Price = LPG Price x (Selling Factor) x Selling Factor Avg x Selling Factor Avg = 75 ~90 % (Ben Iosefa, the 6th Asian DME Conference, Seoul, Korea 2009)

H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

D. Milestones on DME in Korea

Lab/Bench Scale (2001 – 2003)

Pilot Plant 50KPD (2003 – 2006)

Demo Plant 10TPD (2004 – 2008)

1. Saudi Arabia: 1MTPA(2010 – 2013) 2. Oman (MOU, 2010) 3. Indonesia(MOU,2010)

4. Iran (MOU, 2010)

DME-FPSO (2010-2015)

Overseas DME Plants

2011-11-16~19 H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

Initial Supply Period: 2010.8. ~ 2011.7. ( 4 Locations Selected)

Storage Tanks Typical Cylinders Underground Storage Charging Dispense

1. Trial Supply of DME+LPG Mixture to House Holds

A. Charge and Storage Facilities for DME mixture with LPG

II. DME R&D in Korea

H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan 2011-11-16-19

B. Four Locations: Individual Facility Specifics

Specifics Chunil Gas /S.E. Dongbang Gas /E. Mokpo Gas/S. Youngin Energy/S.

Storage Tank Underground Type

15TON

Underground Type

9.9 TON

Underground Type

9.9 TON

Underground Type

9.9 TON

Compressor

power:5.5kw

(7.5HP)

370 ℓ/min

power:5.5kw

(7.5HP)

370 ℓ/min

power:5.5kw

(7.5HP)

370 ℓ/min

power:5.5kw

(7.5HP)

370 ℓ/min

Pumps

power :3.75kw

(5HP)

120L / min

power :5.5kw

(7.5HP) Ground

Type

200L / min

power :5.5kw

(7.5HP) Ground

Type

200L / min

power :5.5kw

(7.5HP)Ground

Type

200L / min

Loading Arms 50A / 25A 1SET 50A / 25A 1SET 50A / 25A 1SET 50A / 25A 1SET

Charging

800 kg/hr x 2 set LOAD SELL attached

Dimension: 500Wx780Lx1800H

800 kg/hr x 2 set LOAD SELL attached

Dimension: 500Wx780Lx1800H

800 kg/hr x 2 set LOAD SELL attached

Dimension: 500Wx780Lx1800H

800 kg/hr x 2 set LOAD SELL attached

Dimension: 500Wx780Lx1800H

Sprinkling Pump

5.5 Kw, 460L/min (MAX)

H : 100M (MAX)

7.5 Kw, 460L/min H : 100M (MAX)

FRP type (25,000L)

Control Valve 50A Solenoid Valve

Type

7.5 Kw, 460L/min H : 100M (MAX)

Underground Tank (25,000L)

H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

Locations

Months of 2010 Months of 2010

Total

8 9 10 11 12

Mokpo 190 kg 1,916 kg 1,815 kg 2,424 kg 2,954 kg 9,299 kg

Dongbang 244 kg 1,022 kg 1,018 kg 1,266 kg 1,500 kg 5,050 kg

Chunil - 1,442 kg 3,182 kg 4,792 kg 4,490 kg 13,906 kg

Youngin - - - 1,490 kg 3,552 kg 5,042 kg

Total 434 kg 4,380 kg 6,015 kg 9,972 kg 12,496 kg 33,297 kg

Increasement - 3,946 kg 1,635 kg 3,957 kg 2,524 kg -

Increasing ratio - 909.2% 37.3% 65.8% 25.3% -

C. Four Locations: Individual Amount of DME Supplied

H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

(unit :house No.)

Locations

Planning 8 9 10 11 12

home commercial

home comm

ercial home

comm

ercial home

comm

ercial home

comm

ercial home

comm

ercial

Mokpo 50 50 - 13 4 50 17 42 39 46 32 47

Dongbang 50 50 1 3 10 11 20 19 25 25 61 32

Chunil 50 50 13 18 15 31 15 35 30 37 30 37

Youngin 50 50 - - - - - - - 27 25 52

Total 200 200 14 34 29 92 52 96 94 135 148 168

Monthly 400 48 121 148 229 316

% - 12.0% 30.3% 37.0% 57.3% 79.0%

Increasment - - 152.1% 22.3% 54.7% 38.0%

D. Four Locations: Number of Households for Each Location

H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

2. Safety for Machinery and Equipment applying to DME

2011-11-16~19

Typical Facilities

- Gas range

- Gas boiler

- Small size of

Storage cylinder

- Connecting Hose

- Gas regulator

- Gas meter

- others

Y.G.Kim, 2010 KDA spring seminar, Seoul

Y.G.Kim, 2010 KDA spring seminar, Seoul

H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

A. Assessment of safety for the use of DME-LPG mixture

Performance test

- Gas ranges

- Boilers

- Regurators

- Others

2011-11-16~19

B. Performance for Machinery applying to LPG+DME

H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

3. Development of DME synthesis Process

using COG from Steel Company

Hyundai Steel : Coke Oven Gas(COG) to DME for Local cities using KOGAS’s DME process.

2011-11-16~19 H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

4. Overseas Commercial Plant Construction

Saudiarabia: KOGAS-AMSG Joint Study

Agreement for 300,000 ton/yr

-

Equatorial Guinea: Sona Gas,

Indonesia : DME FPSO for Stranded Gas well containing CO2 <20%

Mongolia : CBM to DME

Mozambique: Pandae gas well (2.7 tcf), Temane gas well (1.0 tcf)

Others

2011-11-16~19

Jubail Industrial Site

DME FPSO

H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

5. DME Vehicle development

2011-11-16~19

A. Emission test(EPAcvs-75mode) w/ Diesel Oxydation Catalyst (by KIER):

-Proto-type DME Truck (3,300 cc)

- Midium-duty DME Bus

DE08TiS(8,071 cc)

B. ECU Development : Control Algorism

for Air path(EGR&VGT) and Injection

(by KATECH)

C. Engine Performance Test: Santafe

Performance Test (by KATECH)

H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

III. Upcomings

2011-11-16~19 H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan

Thank you for

your attention!

2011-11-16~19 H OSEO UNIV CIT R&D CENTER 7th Asian DME Conference , Niigata, Japan