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E
SUB-COMMITTEE ON POLLUTION PREVENTION AND RESPONSE 7th session Agenda item 3
PPR 7/INF.17
13 December 2019 ENGLISH ONLY
Pre-session public release: ☒
SAFETY AND POLLUTION HAZARDS OF CHEMICALS AND PREPARATION OF
CONSEQUENTIAL AMENDMENTS TO THE IBC CODE
Information supporting a review of the products listed in the MEPC.2/Circular
Note by the Secretariat
SUMMARY
Executive summary: This document contains an overview of products that have had their GESAMP Hazard Profiles amended since the adoption of the 2004 amendments to the IBC Code (resolutions MEPC.119(52) and MSC.176(79)), products that currently only have a pollution (P) hazard rating in chapter 17 of the IBC Code, but have been assigned an additional safety (S) hazard rating in the 2019 amendments to the IBC Code, and products assigned to List 2 of the MEPC.2/Circular that have a component with a safety hazard in the contains name
Strategic direction, if applicable:
6
Output: 6.3
Action to be taken: Paragraph 5
Related documents: PPR 1/Circ.6, PPR 7/3 and MEPC.2/Circ.25
Introduction
1 The 2019 amendments to the IBC Code were adopted as resolutions MEPC.318(74) and MSC.460(101) and are expected to enter into force 1 January 2021. These amendments include a complete revision of the carriage requirements for all products listed in chapters 17 and 18 of the IBC Code, following their assessment in accordance with chapter 21 of the IBC Code.
PPR 7/INF.17 Page 2
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2 During the twenty-fifth session of the PPR Working Group on the Evaluation of Safety and Pollution Hazards of Chemicals (ESPH 25), the Working Group discussed how to review the products in Lists 2 and 3 of the MEPC.2/Circular (PPR 7/3, paragraphs 6.1 to 6.8) in order to ensure that the carriage requirements are assigned using the most up-to-date GESAMP Hazard Profiles and the revised Criteria for assigning carriage requirements for products subject to the IBC Code (chapter 21 of the IBC Code). 3 In this context, the Group noted it was important to shorten the Lists of products in the MEPC.2/Circular and discussed possible approaches on how to achieve that. As a way forward, in order to identify products that should have had their carriage requirements updated since they were included in the MEPC.2/Circular, the Group requested the Secretariat to submit to PPR 7 or ESPH 26 an overview of the GESAMP Hazard Profiles that have been amended since the 2004 amendments to the IBC Code and a list of the products that currently only have a pollution (P) hazard rating but have been assigned an additional safety (S) hazard rating in the 2019 amendments to the IBC Code. 4 To that end, the following information is provided in the annexes to this document:
.1 in annex 1 there is a list of products that have had their GESAMP Hazard Profiles amended since the 2004 amendments to the IBC Code (resolutions MEPC.119(52) and MSC.176(79));
.2 in annex 2 there is a list of the products that currently have a pollution (P)
only hazard rating in chapter 17 or 18 of the IBC Code or are "Other Substances" (OS) in chapter 18 of the IBC Code, but have been assigned an additional safety (S) hazard rating in the 2019 amendments to the IBC Code; and
.3 in annex 3 there is a list of products in list 2 (pollution hazards only) of the
MEPC.2/Circular that have a component with a safety hazard in the contains name.
Action requested of the Sub-Committee
5 The Sub-Committee is invited to note the information contained in this document and take action as appropriate.
***
PPR 7/INF.17 Annex 1, page 1
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ANNEX 1
GESAMP HAZARD PROFILES THAT HAVE BEEN AMENDED SINCE THE ADOPTION OF THE 2004 AMENDMENTS TO THE IBC CODE
TRN Name EHS Name
Tetrachloroethane 1,1,2,2-Tetrachloroethane
Propylene glycol 1,2-Propylene glycol
1,2,3-Trichloropropan 1,2,3-Trichloropropan
1,2-Butylene oxide 1,2-Butylene oxide
1,2-Dichloropropane 1,2-Dichloropropane
1,3-Cyclopentadiene dimer (molten) 1,3-Cyclopentadiene dimer (molten)
1,3-Pentadiene 1,3-Pentadiene
Glutaraldehyde solutions (50% or less) 1,5-Pentanedial solution, (5-50%)
1,5,9-Cyclododecatriene 1,5,9-Cyclododecatriene
1,6-Dichlorohexane 1,6-Dichlorohexane
1,6-Hexanediol, distillation overheads 1,6-Hexanediol, distillation overheads
1-Dodecene 1-Dodecene
1-Heptanol 1-Heptanol
1-Nitropropane 1-Nitropropane
2,2,4-Trimethyl-1,3-pentanediol diisobutyrate
2,2,4-Trimethyl-1,3-pentanediol diisobutyrate
2,4-Dichlorophenol 2,4-Dichlorophenol
2,4-Dichlorophenoxyacetic acid, triisopropanolamine salt solution
2,4-Dichlorophenoxyacetic acid, triisopropanolamine salt soln.
2,4-Dichlorophenoxyacetic acid, diethanolamine salt solution
2,4-Dichlorophenoxyacetic acid, diethanolamine salt, solution
Toluenediamine 2,4-Tolylenediamine
2,6-Diaminohexanoic acid phosphonate mixed salts solution
2,6-Diaminohexanoic acid phosphonate mixed salts solution
2-Ethyl-3-propylacrolein 2-Ethyl-3-propylacrolein
2-Ethylhexanoic acid 2-Ethylhexanoic acid
tert-Amyl alcohol 2-Methyl-2-butanol
2-Methyl-5-ethyl pyridine 2-Methyl-5-ethylpyridine
2-Nitropropane 2-Nitropropane
2-Propene-1-aminium, N,N-dimethyl-N-2-propenyl-, chloride, homopolymer
2-Propene-1-aminium, N,N-dimethyl-N-2-propenyl-, chloride, homopolymer (aqueous solution)
2-Propenoic acid polymer with furandione (65% in 2-butoxyethanol)
2-Propenoic acid polymer with furandione (65% in 2-butoxyethanol)
3-(methylthio)propionaldehyde 3-(Methylthio) propionaldehyde
4-Methylpyridine 4-Methylpyridine
Acrylic acid / dimethyldiallylammonium chloride copolymer, partial sodium salt (MWt 1500-4000, aqueous solution)
Acrylic acid / dimethyldiallylammonium chloride copolymer, partial sodium salt (MWt 1500-4000, aqueous solution)
Acrylic acid/ethenesulphonic acid copolymer with phosphonate groups, sodium salt solution
Acrylic acid/ethenesulphonic acid copolymer with phosphonate groups, sodium salt (aqueous solution)
Acrylonitrile Acrylonitrile
Alkyl (C10-C15, C12 rich) phenol poly(4-12)ethoxylate
Alkyl (C10-C15, C12 rich) phenol poly(4-12)ethoxylate
Alkyl (C12+) dimethylamine Dodecyl-, Tetradecyl-, Hexadecyl-dimethylamine mixture
PPR 7/INF.17 Annex 1, page 2
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TRN Name EHS Name
Alkyl (C7-C9) nitrates Alkyl (C7-C9) nitrates
Alkyl(C8+)amine, Alkenyl (C12+) acid ester mixture
Alkyl amine, alkenyl acid ester, mixture
Alkylbenzenes mixture (containing less than 1% naphthalene)
Alkylbenzenes mixture (containing less than 1% naphthalene)
Alkylbenzenes mixtures (containing naphthalene)
Alkylbenzenes mixtures (containing naphthalene)
Allyl alcohol Allyl alcohol
Alpha-Pinene Alpha-Pinene
Aluminium chloride (30% or less)/hydrochloric acid (20% or less) solution
Aluminium chloride/hydrogen chloride solution
Ammonium hydrogen phosphate solution Diammonium hydrogen phosphate
Ammonium polyphosphate solution Ammonium polyphosphate solution
Benzene sulphonyl chloride Benzene sulphonyl chloride
Beta-Pinene Beta-Pinene
Butyl acetate (all isomers) Butyl acetate
Butyl benzyl phthalate Butyl benzyl phthalate
Butyl butyrate (all isomers) Butyl butyrate
Butyl octyl phthalate Butyl octyl phthalate
Butyl stearate Butyl stearate
3-Methoxy-1-butanol Butylene glycol monomethyl ether
Butyric acid Butyric acid
Drilling brines (containing calcium bromide Calcium bromide (solutions)
Calcium carbonate slurry Calcium carbonate slurry
Calcium hydroxide slurry Calcium hydroxide
Calcium hypochlorite solution (15% or less) Calcium hypochlorite solutions containing less than 15% but more than 1.5% Ca(OCl)2
Calcium hypochlorite solution (more than 15%)
Calcium hypochlorite solutions containing 15% Ca(Ocl)2 or more
epsilon-Caprolactam (molten or aqueous solutions)
Caprolactam
Carbon disulphide Carbon disulphide
Cashew nut shell oil (untreated) Cashew nut shell oil (untreated)
Castor oil Castor oil (containing less than 10% free fatty acids)
Chlorobenzene Chlorobenzene
Chlorosulphonic acid Chlorosulphonic acid
Coal tar pitch (molten) Coal tar pitch (molten)
Coconut oil Coconut oil
Coconut oil fatty acid Coconut oil fatty acid
Cotton seed oil Cotton seed oil
Creosote (coal tar) Creosote (coal tar)
Cresols (all isomers) Cresols (mixed isomers)
Crotonaldehyde Crotonaldehyde
Cyclohexanone Cyclohexanone
Cyclopentene Cyclopentene
Decahydronaphthalen Decahydronaphthalen
Decyl acrylate Decyl acrylate
Di-(2-ethylhexyl) phthalate Di-(2-ethylhexyl) phthalate
Di-(2-ethylbutyl) phthalate Di-(2-ethylbutyl) phthalate
Di-(2-ethylhexyl) phthalate Di-(2-ethylhexyl) phthalate
PPR 7/INF.17 Annex 1, page 3
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TRN Name EHS Name
Dialkyl phthalates C9-C13 Dialkyl (C7-C13) phthalates
Dialkyl (C9 – C10) phthalates Dialkyl (C9 – C10) phthalates
Dibromomethane Dibromomethane
Di-n-butyl phthalate Dibutyl phthalate
Dichloropropene/Dichloropropane mixture Dichloropropane and dichloropropene, mixtur
Diethyl phthalate Diethyl phthalate
Diethyl sulphate Diethyl sulphate
Diethylene glycol diethyl ether Diethylene glycol diethyl ether
Diheptyl phthalate Diheptyl phthalate
Dihexyl phthalate Di-hexyl phthalate
Diisobutyl phthalate Diisobutyl phthalate
Diisobutylamine Diisobutylamine
Diisodecyl phthalate Diisodecyl phthalate
Diisoheptyl phthalate Diisoheptyl phthalate
Diisononyl phthalate Diisononyl phthalate
Diisooctyl phthalate Diisooctyl phthalate
Isopropyl ether Diisopropyl ether
Dimethyl adipate Dimethyl adipate
Dimethyl glutarate Dimethyl glutarate
Dimethyl phthalate Dimethyl phthalate
Dinonyl phthalate Dinonyl phthalate
Di-n-propyl phthalate Di-n-propyl phthalate
Dioctyl phthalate Di-n-octyl phthalat
Diphenyl Diphenyl
Diphenylmethane diisocyanate Diphenylmethane-4,4'-diisocyanate
Dipropylene glycol Dipropylene glycol
Dipropylene glycol dibenzoate Dipropylene glycol dibenzoate
Ditridecyl phthalate Ditridecyl phthalate
Diundecyl phthalate Diundecyl phthalate
Dodecene (all isomers) Dodecene (all isomers)
Dodecyl phenol Dodecyl phenol
Dodecylamine/tetradecylamine mixture Dodecylamine/tetradecylamine mixture
1,3,5-Hexahydrotriethanol-1,3,5-triazine solution
Ethanoltriazine (aqueous solution)
Ethoxylated long chain (C16+) alkyloxyalkylamine
Ethoxylated long chain (>C16)alkyloxyalkanamine (LOA)
Ethoxylated tallow amine (>95%) Ethoxylated tallow amine (>95%)
Ethyl 3-ethoxypropionate Ethyl 3-ethoxypropionate
Ethyl acrylate Ethyl acrylate
Ethyl tert-butyl ether Ethyl tert-butyl ether
Ethylbenzene Ethylbenzene
Ethylcyclohexane Ethyl cyclohexane
Ethylene glycol Ethylene glycol
Ethylene glycol (>75%)/Sodium alkyl carboxylates/borax mixture
Ethylene glycol (>75%)/Sodium alkyl carboxylates/borax mixture #)
Ethylene glycol (>85%)/Sodium alkyl carboxylates mixture
Ethylene glycol (>85%)/Sodium alkyl carboxylates mixture
Ethylene glycol butyl ether acetate Ethylene glycol butyl ether acetate
2-Ethoxyethyl acetate Ethylene glycol ethyl ether acetate
Ethylene glycol methyl ether acetate Ethylene glycol methyl ether acetate
PPR 7/INF.17 Annex 1, page 4
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TRN Name EHS Name
Ethylene glycol acetate Ethylene glycol monoacetate
2-Ethoxyethanol Ethylene glycol monoethyl ether
Ethylene glycol phenyl ether Ethylene glycol phenyl ether
Ethylene vinyl acetate copolymer (emulsion) Ethylene vinyl acetate copolymer (emulsion)
Fatty acids, (C8-C10) Fatty acids saturated, C8-C10
Fatty acids, (C12+) Fatty acids, linear C12+ saturated with C12+ unsaturated
Fatty acids, linear, C8-C18 saturated with C18 unsaturated
Fatty acids, (C8-C18)
Fish by-products (fresh) Fish by-products (fresh)
Fish oil Fish oil (containing less than 10% free fatty acids)
Fish silage (containing 3% or less formic acid with antioxidant)
Fish silage (containing 3% or less formic acid with antioxidant
Fish silage protein concentrate (containing 4% or less formic acid)
Fish silage protein concentrate (containing 4% or less formic acid)
Fluorosilicic acid solution (20-30%) Fluorosilicic acid solution (20-30%)
Fumaric adduct of Rosin, water dispersion Fumaric adduct of rosin (water dispersion)
Furfuryl alcohol Furfuryl alcohol
Glucitol/glycerol blend propoxylated (containing 10% or more amines)
Glucitol/glycerol blend propoxylated (containing 10% or more amines)
Glycerol ethoxylated Glycerol ethoxylated
Glycerol monooleate Glycerol monooleate
Groundnut oil Groundnut oil
n-Heptanoic acid Heptanoic acid
Heptyl acetate Heptyl acetate
Hexamethyleneimine Hexamethyleneimine
Waxes (Hydrocarbon waxes)1 Hydrocarbon wax
Iso-and cyclo-alkanes (C12+) Iso-and cyclo-alkanes (C12+)
Isophorone diisocyanate Isophorone diisocyanate
Isoprene Isoprene
Lactonitrile solution (80% or less) Lactonitrile solution (80% or less)
Lard Lard (containing less than 10% free fatty acids)
Latex, ammonia (1% or less)- inhibited Latex, ammonia inhibited
Dodecyl methacrylate Lauryl methacrylate
Alkyl(C12-C16) propoxyamine ethoxylate Linear alkyl (C12-16) propoxyamine ethoxylate
Linseed oil Linseed oil (containing less than 4% free fatty acids)
Maltitol solution Maltitol Syrup
m-Chlorotoluene m-Chlorotoluene
Metam sodium solution Metam-sodium (ISO)
Methacrylonitrile Methacrylonitrile
Methyl alcohol Methanol
Methyl acrylate Methyl acrylate
Methyl butyl ketone Methyl butyl ketone
Methyl propyl ketone Methyl propyl ketone
Methyl salicylate Methyl salicylate
1 This product has been renamed and the new TRN name is included in brackets. EHS name correspond to
the renamed product.
PPR 7/INF.17 Annex 1, page 5
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TRN Name EHS Name
2-Methyl-2-hydroxy-3-butyne Methylbutynol
Methylene bisthiocyanate Methylene dithiocyanate
Microsilica slurry Silica slurry
N,N-Dimethyldodecylamine N,N-Dimethyldodecylamine
n-Alkanes (C9-C11) n-Alkanes (C9-C11)
Nitric acid (less than 70%) Nitric acid (90% or less)
Nitric acid (70% and over) Nitric acid (90% or less)
Nonane (all isomers) Nonane
Nonylphenol Nonyl phenol
Chlorotoluenes (mixed isomers) o-Chlorotoluene
Olefins (C13+, all isomers) Olefins C13 and above, all isomers
Olive oil Olive oil
Palm kernel acid oil Palm nut oil fatty acid
Palm kernel fatty acid distillate Palm kernel fatty acid distillate
Palm kernel oil Palm nut oil
Palm oil Palm oil (containing less than 15% free fatty acids)
Palm olein Palm olein
Palm stearin Palm stearin
Paraffin wax (Paraffin wax, highly-refined)2 Paraffin wax, highly-refined
p-Chlorotoluene p-Chlorotoluene
Petrolatum (Paraffin wax, semi-refined)2 Paraffin wax, semi-refined
Phosphoric acid Phosphoric acid
Poly(tetramethylene ether) glycol (mw 600-3000)
Poly(tetramethylene ether) glycol (mw 600-3000)
Polyalkyl (C18-C22) acrylate in xylene Poly(C18-C22)alkyl acrylate in xylene
Polyether (molecular weight 1350+) Polyether (molecular weight 2000+) (LOA)
Polyethylene polyamines (more than 50% C5 -C20 paraffin oil)
Polyethylene amines / paraffin mixtures
Polyethylene polyamines Polyethylene polyamines
olefin amide alkeneamine polyol Polyolefin amide alkylene amine polyol
Poly(20)oxyethylene sorbitan monooleate Polyoxyethylene sorbitan monooleate
Propylene oxide Propylene oxide
Pyridine Pyridine
Rapeseed oil Rapeseed oil (high erucic acid; containing less than 4% free fatty acids)
Sodium aluminate solution Sodium aluminate (solution)
Sodium carbonate solution Sodium carbonate
Sodium dichromate solution (70% or less) Sodium dichromate solution
Sodium hydrogen sulphide (6% or less)/sodium carbonate (3% or less) solution
Sodium hydrogen sulphide (6% or less)/sodium carbonate (3% or less)
Sodium hydrosulphide solution (45% or less) Sodium hydrogen sulphide, solutions
Sodium hydrosulphide/Ammonium sulphide solution
Sodium hydrogen sulphide/Ammonium sulphide(mixture)
No registered TRN Name Sodium hydroxide (30% or less)/Sodium aluminate (25% or less) solution
Soyabean oil Soyabean oil (containing less than 4% free fatty acids)
Sulphuric acid Sulphuric acid
2 This product has been renamed and the new TRN name is included in brackets. EHS name correspond to
the renamed product.
PPR 7/INF.17 Annex 1, page 6
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TRN Name EHS Name
Sunflower seed oil Sunflower oil
Dichloroethyl ether sym-Dichlorodiethyl ether
Tall oil (crude and distilled) Tall oil, crude and distilled
Tall oil crude Crude Tall Oil
Tall oil fatty acid (resin acids less than 20%) Tall oil fatty acid (resin acids less than 20%)
Tall oil pitch Tall oil pitch
Tallow Tallow
tert-Amyl methyl ether tert-Amyl methyl ether
Tert-Dodecanethiol Tert-Dodecanethiol
Titanium dioxide (64 – 77% solution in water) Titanium dioxide slurry
Toluene diisocyanate Toluene diisocyanate
Triethylene glycol Triethylene glycol
Trimethylacetic acid Trimethylacetic acid
Tripropylene glycol Tripropylene glycol
Trixylyl phosphate Trixylenyl phosphate
Tung oil Tung oil
Urea/Ammonium nitrate solution Urea/Ammonium nitrate solution (containing < 1% aq. Ammonia)
Vegetable protein solution (hydrolysed) Vegetable protein solution,hydrolyzed
Vinyl ethyl ether Vinyl ethyl ether
Waxes (Hydrocarbon wax)3 Hydrocarbon wax
Xylenol Xylenols (mixtures)
***
3 This product has been renamed and the new TRN name is included in brackets. EHS name correspond to
the renamed product.
PPR 7/INF.17
Annex 2, page 1
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ANNEX 2
PRODUCTS THAT HAVE CHANGED FROM "P" TO "S/P" IN COLUMN D OF THE 2019 AMENDMENTS TO THE IBC CODE (RESOLUTIONS MEPC.318(74) AND MSC.460(101))
Product name in the IBC Code:
Acetochlor
Alcohol (C9-C11) poly (2.5-9) ethoxylate
Alcohol (C6-C17) (secondary) poly(3-6) ethoxylates
Alcohol (C6-C17) (secondary) poly(7-12) ethoxylates
Alcohol (C12-C16) poly(1-6) ethoxylates
Alcohol (C12-C16) poly(20+) ethoxylates
Alcohol (C12-C16) poly(7-19) ethoxylates
Alkanes (C6-C9)
Iso- and cyclo-alkanes (C10-C11)
Iso- and cyclo-alkanes (C12+)
Alkaryl polyethers (C9-C20)
Alkenyl (C11+) amide
Alkyl acrylate/vinylpyridine copolymer in toluene
Alkyl (C3-C4) benzenes
Alkyl (C5-C8) benzenes
Alkyl (C9+)benzenes
Alkyl (C11-C17) benzene sulphonic acid
Alkyl (C8-C10)/(C12-C14):(40% or less/60% or more) polyglucoside solution (55% or less)
Alkyl (C8-C10)/(C12-C14):(60% or more/40% or less) polyglucoside solution(55% or less)
Alkyl (C7-C11)phenol poly(4-12) ethoxylate
Alkyl (C8-C40) phenol sulphide
Alkyl (C8-C9) phenylamine in aromatic solvents
Alkyl (C9-C15) phenyl propoxylate
Alkyl (C8-C10) polyglucoside solution (65% or less)
Alkyl (C8-C10)/(C12-C14):(50%/50%) polyglucoside solution (55% or less)
Alkyl (C12-C14) polyglucoside solution (55% or less)
Aluminium sulphate solution
2-Amino-2-methyl-1-propanol
Ammonium thiosulphate solution (60% or less)
Amyl acetate (all isomers)
n-Amyl alcohol
Amyl alcohol, primary
sec-Amyl alcohol
tert-Amyl alcohol
tert-Amyl methyl ether
Aviation alkylates (C8 paraffins and iso-paraffins BPT 95 - 120°C)
Benzenetricarboxylic acid, trioctyl ester
Benzyl acetate
Benzyl alcohol
Butylbenzene (all isomers)
Butyl benzyl phthalate
Butyl butyrate (all isomers)
Butylene glycol
gamma-Butyrolactone
PPR 7/INF.17 Annex 2, page 2
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Product name in the IBC Code:
Calcium hydroxide slurry
Calcium lignosulphonate solutions
Calcium long-chain alkyl (C11-C40) phenate
Calcium long-chain alkyl salicylate (C13+)
Calcium nitrate solutions (50% or less)
Calcium nitrate/Magnesium nitrate/Potassium chloride solution
epsilon-Caprolactam (molten or aqueous solutions)
Chlorinated paraffins (C10-C13)
Chlorinated paraffins (C14-C17) (with 50% chlorine or more, and less than 1% C13 or shorter chains)
4-Chloro-2-methylphenoxyacetic acid, dimethylamine salt solution
1-(4-Chlorophenyl)-4,4- dimethyl-pentan-3-one
Citric acid (70% or less)
Cycloheptane
Cyclohexane
Cyclohexyl acetate
1,3-Cyclopentadiene dimer (molten)
Cyclopentene
p-Cymene
Decahydronaphthalene
Decanoic acid
Diacetone alcohol
Dialkyl (C7-C13) phthalates
Dibutyl hydrogen phosphonate
2,6-Di-tert-butylphenol
Dibutyl phthalate
Diethylbenzene
Diethylene glycol
Diethylene glycol diethyl ether
Diethylene glycol phthalate
Di-(2-ethylhexyl) adipate
Diethyl phthalate
Diglycidyl ether of bisphenol A
Diglycidyl ether of bisphenol F
Diheptyl phthalate
Di-n-hexyl adipate
Dihexyl phthalate
Diisobutyl ketone
Diisobutyl phthalate
Diisononyl adipate
Diisooctyl phthalate
Diisopropylbenzene (all isomers)
Diisopropylnaphthalene
Dimethyl glutarate
Dimethyl octanoic acid
Dimethyl phthalate
Dinonyl phthalate
Dioctyl phthalate
Dipentene
Diphenyl
Diphenylamine (molten)
PPR 7/INF.17
Annex 2, page 3
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Product name in the IBC Code:
Diphenylamines, alkylated
Diphenyl/Diphenyl ether mixtures
Diphenylol propane-epichlorohydrin resins
Dithiocarbamate ester (C7-C35)
Diundecyl phthalate
Dodecane (all isomers)
Dodecene (all isomers)
Dodecyl alcohol
Dodecylbenzene
Dodecyl phenol
Dodecyl Xylene
Drilling brines (containing calcium bromide)
Drilling brines (containing zinc chloride)
2-Ethoxyethyl acetate
Ethyl acetate
Ethyl acetoacetate
Ethyl amyl ketone
Ethylbenzene
Ethyl tert-butyl ether
Ethyl butyrate
Ethylcyclohexane
S-Ethyl dipropylthiocarbamate
Ethylene carbonate
Ethylene glycol
Ethylene glycol acetate
Ethylene glycol butyl ether acetate
Ethylene glycol diacetate
Ethylene glycol methyl ether acetate
Ethylene glycol phenyl ether
Ethylene glycol phenyl ether/Diethylene glycol phenyl ether mixture
Ethylene-vinyl acetate copolymer (emulsion)
2-Ethylhexanoic acid
Ethyl propionate
Fatty acid (saturated C13+)
Fatty acids, essentially linear (C6-C18) 2-ethylhexyl ester
Formamide
Furfuryl alcohol
Glycerine
Glycerol monooleate
Glyceryl triacetate
Glycidyl ester of C10 trialkylacetic acid
Glycine, sodium salt solution
Glyoxal solution (40% or less)
Glyphosate solution (not containing surfactant)
n-Heptanoic acid
Heptanol (all isomers) (d)
Heptyl acetate
1-Hexadecylnaphthalene / 1,4-bis(hexadecyl)naphthalene mixture
Hexamethylene glycol
Hexamethylenetetramine solutions
PPR 7/INF.17 Annex 2, page 4
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Product name in the IBC Code:
Hexane (all isomers)
1,6-Hexanediol, distillation overheads
Hexanoic acid
Hexanol
Hexene (all isomers)
Hexyl acetate
Hexyl acetate
Hexylene glycol
N-(Hydroxyethyl)ethylenediaminetriacetic acid, trisodium salt solution
2-Hydroxy-4-(methylthio)butanoic acid
Isoamyl alcohol
Isobutyl alcohol
Isobutyl methacrylate
Lactic acid
Latex: Carboxylated styrene-Butadiene copolymer; Styrene-Butadiene rubber
Lauric acid
Long-chain alkaryl polyether (C11-C20)
Long-chain alkaryl sulphonic acid (C16-C60)
Long-chain alkylphenate/Phenol sulphide mixture
Magnesium hydroxide slurry
Magnesium long-chain alkaryl sulphonate (C11-C50)
Magnesium long-chain alkyl salicylate (C11+)
3-Methoxy-1-butanol
3-Methoxybutyl acetate
N-(2-Methoxy-1-methyl ethyl)-2-ethyl-6-methyl chloroacetanilide
Methyl acetoacetate
Methyl alcohol
Methylamyl alcohol
Methyl amyl ketone
Methylbutenol
Methyl butyl ketone
Methylbutynol
Methyl butyrate
Methylcyclohexane
Methylcyclopentadiene dimer
Methyl ethyl ketone
Methyl isobutyl ketone
N-Methylglucamine solution (70% or less)
3-Methyl-3-methoxybutanol
Methyl propyl ketone
N-Methyl-2-pyrrolidone
Methyl salicylate
Myrcene
Naphthalenesulphonic acid-Formaldehyde copolymer, sodium salt solution
Neodecanoic acid
Nitrilotriacetic acid, trisodium salt solution
Nonane (all isomers)
Nonanoic acid (all isomers)
Nonyl methacrylate monomer
Nonylphenol
Nonylphenol poly(4+)ethoxylate
PPR 7/INF.17
Annex 2, page 5
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Product name in the IBC Code:
Octamethylcyclotetrasiloxane
Octanoic acid (all isomers)
Octanol (all isomers)
n-Octyl acetate
Octyl aldehydes
Octyl decyl adipate
Olefin mixtures (C5-C7)
Olefin mixtures (C5-C15)
alpha-Olefins (C6-C18) mixtures
Oleic acid
Pentanoic acid
n-Pentyl propionate
1-Phenyl-1-xylyl ethane
Phosphate esters, alkyl (C12-C14) amine
alpha-Pinene
beta-Pinene
Pine oil
Polyalkyl (C18-C22) acrylate in xylene
Polyaluminium chloride solution
Poly(2+)cyclic aromatics
Polyethylene glycol dimethyl ether
Polyisobutenamine in aliphatic (C10-C14) solvent
Polyisobutenyl anhydride adduct
Polyglycerin, sodium salt solution (containing less than 3% sodium hydroxide)
Polyolefin amide alkeneamine (C17+)
Polyolefinamine (C28-C250)
Polyolefinamine in alkyl (C2-C4) benzenes
Polyolefinamine in aromatic solvent
Polyolefin aminoester salts (molecular weight 2000+)
Polyolefin anhydride
Polyolefin phenolic amine (C28-C250)
Potassium oleate
Potassium formate solutions
Potassium thiosulphate (50% or less)
n-Propyl alcohol
Propylene carbonate
Propylene glycol phenyl ether
Propylene tetramer
Propylene trimer
Rape seed oil fatty acid methyl esters
Rosin
Sodium alkyl (C14-C17) sulphonates (60-65% solution)
Sodium benzoate
Sodium carbonate solution
Sodium hydrogen sulphide (6% or less)/Sodium carbonate (3% or less) solution
Sodium poly(4+)acrylate solutions
Sodium silicate solution
Sodium sulphate solutions
Sodium sulphite solution (25% or less)
Sodium thiocyanate solution (56% or less)
PPR 7/INF.17 Annex 2, page 6
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Product name in the IBC Code:
Sulpholane
Sulphurized fat (C14-C20)
Tetrahydronaphthalene
Tetramethylbenzene (all isomers)
Toluene
Tributyl phosphate
Tridecane
Tridecanoic acid
Tridecyl acetate
Triethylbenzene
Triethyl phosphate
Triisopropanolamine
Trimethylbenzene (all isomers)
2,2,4-Trimethyl-1,3-pentanediol diisobutyrate
Trixylyl phosphate
Turpentine
Undecanoic acid
1-Undecene
Undecyl alcohol
Urea/Ammonium phosphate solution
Urea solution
White spirit, low (15-20%) aromatic
Xylenes/ethylbenzene (10% or more) mixture
Zinc alkenyl carboxamide
***
PPR 7/INF.17
Annex 3, page 1
K:\PPR\07\PPR 7-INF.17.docx
ANNEX 3
PRODUCTS IN LIST 2 OF THE MEPC.2/CIRCULAR THAT HAVE A COMPONENT WITH A SAFETY HAZARD IN THE CONTAINS NAME
Trade name Component with a safety hazard Representative country and company
Anglamol 99 Oleylamine USA (Lubrizol)
ASH 1925 ISO- AND CYCLO-ALKANES (C12+)
ZAF (PetroSA)
ASH 2636 ISO- AND CYCLO-ALKANES (C12+)
ZAF (PetroSA)
ASH-H ISO- AND CYCLO-ALKANES (C12+)
ZAF (PetroSA)
ASH-M ISO- AND CYCLO-ALKANES (C12+)
ZAF (PetroSA)
9/C10 AROMATICS Trimethylbenzene (all isomers) GBR (SABIC (UK))
CAN 17 Ammonium nitrate solution (93% or less)
NOR (Yara International S. A.)
CELANESE MAM BLEND
Dodecyl alcohol USA (Celanese)
CF 2000 Iso- and cyclo-alkanes (C10-C11) BEL (ExxonMobil)
CF 2100 ISO- AND CYCLO-ALKANES (C12+)
BEL (ExxonMobil)
CFX 2000 ISO- AND CYCLO-ALKANES (C12+)
BEL (ExxonMobil)
CFX 2100 Iso- and cyclo-alkanes (C10-C11) BEL (ExxonMobil)
CN9 Ammonium nitrate solution (93% or less)
NOR (Yara International S. A.)
EC6359A [[(2-hydroxyethyl)imino]dimethylene]bisphosphonic acid, sodium salt
USA (Nalco)
COROL 24 Dodecyl alcohol JPN (Ecogreen)
EPF S20 Alkanes (C6-C9) SGP (ExxonMobil)
Epikote TN 1001-X-75
Diphenylol propane-epichlorohydrin resins
NDL (Hexion Spec. Ch. BV)
Escaid 100 Alkyl (C5-C8) benzenes BEL (ExxonMobil)
Escaid 110 ISO- AND CYCLO-ALKANES (C12+)
BEL (ExxonMobil)
Escaid 110 Special Fluid
ISO- AND CYCLO-ALKANES (C12+)
SGP (ExxonMobil)
Escaid 120 ISO- AND CYCLO-ALKANES (C12+)
BEL (ExxonMobil)
Escaid 120ULA ISO- AND CYCLO-ALKANES (C12+)
BEL (ExxonMobil)
Escaid 120ULA (H) ISO- AND CYCLO-ALKANES (C12+)
BEL (ExxonMobil)
Exxal 7 Alcohol Heptanol (all isomers) USA (ExxonMobil)
Exxal 8 Alcohol Octanol (all isomers) USA (ExxonMobil)
Exxal 9 Alcohol Nonyl alcohol (all isomers) NDL (ExxonMobil)
Exxal 12 Alcohol Undecyl alcohol USA (ExxonMobil)
Exxal L9 Alcohol Nonyl alcohol (all isomers) USA (ExxonMobil)
PPR 7/INF.17 Annex 3, page 2
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Trade name Component with a safety hazard Representative country and company
Exx-Print M 75 A ISO- AND CYCLO-ALKANES (C12+)
BEL (ExxonMobil)
EXX-Print M74 A-S ISO- AND CYCLO-ALKANES (C12+)
BEL (ExxonMobil)
Exx-Print M79D ISO- AND CYCLO-ALKANES (C12+)
BEL (ExxonMobil)
Exx-Print T 76 A ISO- AND CYCLO-ALKANES (C12+)
BEL (ExxonMobil)
Exx-Print T 82A ISO- AND CYCLO-ALKANES (C12+)
BEL (ExxonMobil)
Exxsol D 30 Alkanes (C6-C9) BEL (ExxonMobil)
Exxsol D 40 Alkanes (C6-C9) BEL (ExxonMobil)
Exxsol D 60 Iso- and Cyclo- Alkanes (C10-C11) BEL (ExxonMobil)
Exxsol D 80 Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)
Exxsol D 120 Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)
Exxsol D 130 Fluid Iso- and Cyclo- Alkanes (C12+) SGP (ExxonMobil)
Exxsol D 140 Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)
Exxsol D 180/200 SP
Iso- and Cyclo- Alkanes (C10-C11) BEL (ExxonMobil)
Exxsol D 220/230 Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)
Exxsol D60(S) Iso- and Cyclo- Alkanes (C12+) SGP (ExxonMobil)
Exxsol D95 Iso- and Cyclo- Alkanes (C12+) SGP (ExxonMobil)
Exxsol D100 Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)
Exxsol D100 ULA (formerly Exxsol D100 S)
Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)
Exxsol D110 Alkyl (C5-C8) benzenes SGP (ExxonMobil)
Exxsol DSP 60/95 S Alkanes (C6-C9) BEL (ExxonMobil)
Exxsol DSP 60/95 SH
Alkanes (C6-C9) BEL (ExxonMobil)
Exxsol DSP 145/160
Alkanes (C6-C9) BEL (ExxonMobil)
FORSA™ SCW88003 SCALE INHIBITOR
[[(Phosphonomethyl)imino]bis [ethylenenitrilobis(methylene)]] tetrakisphosphonic acid, ammonium salt solution (60% or less)
GBR (Baker Hughes)
HAN 8070 Alkyl (C5-C8) benzenes BEL (ExxonMobil)
HAN 8572 Poly(2+)cyclic aromatics BEL (ExxonMobil)
HITEC 6561 Dodecene (all isomers) USA (Afton)
Isopar G Iso- and Cyclo- Alkanes (C10-C11) BEL (ExxonMobil)
Isopar H Iso- and Cyclo- Alkanes (C10-C11) BEL (ExxonMobil)
Isopar L Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)
Isopar L (E) Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)
ISOPAR L AP Iso- and Cyclo- Alkanes (C12+) SGP (ExxonMobil Chemical)
Isopar M Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobil)
Isopar N Iso- and Cyclo- Alkanes (C12+) GBR) ExxonMobil
KALCOL 1260 Dodecyl alcohol MYS (Fatty Chemical (MYS))
KALCOL 2465 Dodecyl alcohol USA (Fatty Chemical (MYS))
KALCOL 2470 Dodecyl alcohol USA (Fatty Chemical (MYS))
PPR 7/INF.17
Annex 3, page 3
K:\PPR\07\PPR 7-INF.17.docx
Trade name Component with a safety hazard Representative country and company
KemSweep NLP 5000
Iso- and Cyclo- Alkanes (C12+) GBR (Kemira)
LINEVOL 911 Undecyl alcohol USA (Shell)
Lubrizol 3700D Alkenyl (C11+) amide USA (Lubrizol)
Lubrizol 6950J Alkenyl (C11+) amide USA (Lubrizol)
Lubrizol 9222K Calcium long-chain alkyl phenate sulphide (C8-C40)
USA (Lubrizol)
Lubrizol 9297 Calcium long-chain alkyl phenate sulphide (C8-C40)
USA (Lubrizol)
Lubrizol 9297J Calcium long-chain alkyl phenate sulphide (C8-C40)
USA (Lubrizol)
Lubrizol 9827R Alkenyl (C11+) amide USA (Lubrizol)
Lubrizol 16012 Alkenyl (C11+) amide USA (Lubrizol)
Lubrizol 17001 Alkenyl (C11+) amide USA (Lubrizol)
Lubrizol 20015 Alkenyl (C11+) amide USA (Lubrizol)
Lubrizol 21021 Alkenyl (C11+) amide USA (Lubrizol)
Lubrizol 74090 Alkenyl (C11+) amide USA (Lubrizol)
Lubrizol 76460 Alkenyl (C11+) amide USA (Lubrizol)
Lubrizol 79023 Calcium long-chain alkyl phenate sulphide (C8-C40)
USA (Lubrizol)
Lubrizol A99 Oleylamine USA (Lubrizol)
Lubrizol PV1127 Alkenyl (C11+) amide USA (Lubrizol)
MISC16443A Methanol USA (NALCO Champion)
MOSSPAR 1925 Iso- and Cyclo- Alkanes (C12+) ZAF (PetroSA)
MOSSPAR 2636 Iso- and Cyclo- Alkanes (C12+) ZAF (PetroSA)
MOSSPAR H Iso- and Cyclo- Alkanes (C12+) ZAF (PetroSA)
MOSSPAR M Iso- and Cyclo- Alkanes (C12+) ZAF (PetroSA)
MOSSTANOL 120 n-Propyl alcohol ZAF (PetroSA)
MOSSTANOL P Cyclopentanol4 ZAF (PetroSA)
Nappar 10 Alkanes (C6-C9) BEL (ExxonMobil)
Neodol 24 Dodecyl alcohol USA (Shell)
Neodol 25 Dodecyl alcohol USA (Shell)
Neodol 91 Undecyl alcohol USA (Shell)
Neodol 135 Undecyl alcohol USA (Shell)
NESSOL 40 White spirit, low (15-20%) aromatic FIN (Neste)
NESSOL 60 White spirit, low (15-20%) aromatic FIN (Neste)
NESSOL D40 Iso- and Cyclo- Alkanes (C10-C11) FIN (Neste)
NESSOL D60 Iso- and Cyclo- Alkanes (C10-C11) FIN (Neste)
NESSOL D80 Iso- and Cyclo- Alkanes (C10-C11) FIN (Neste)
NESSOL D100 Iso- and Cyclo- Alkanes (C12+) FIN (Neste)
NESSOL D100+ Iso- and Cyclo- Alkanes (C12+) FIN (Neste)
NEXBASE 3015 Iso- and Cyclo- Alkanes (C12+) FIN (Neste)
NEXBASE®3020 Iso- and Cyclo- Alkanes (C12+) FIN (Neste)
NEXBASE®3030 Iso- and Cyclo- Alkanes (C12+) FIN (Neste)
NEXBASE®3043 Iso- and Cyclo- Alkanes (C12+) FIN (Neste)
NEXBASE®3050 Iso- and Cyclo- Alkanes (C12+) FIN (Neste)
NEXBASE®3060 Iso- and Cyclo- Alkanes (C12+) FIN (Neste)
NEXBASE®3080 Iso- and Cyclo- Alkanes (C12+) FIN (Neste)
4 Does not have a GESAMP Hazard Profile.
PPR 7/INF.17 Annex 3, page 4
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Trade name Component with a safety hazard Representative country and company
NExTAME Olefin mixtures (C5-C15) FIN (Neste)
Octimise G2003 Solvent naphtha2 BEL (Innospec)
Octimise G2048 Alkyl (C3-C4) benzenes BEL (Innospec)
OLOA 219M Calcium long-chain alkyl phenate sulphide (C8-C40)
USA (Chevron Oronite)
OLOA 219U Calcium long-chain alkyl phenate sulphide (C8-C40)
USA (Chevron Oronite)
OrePrep F-597 Frother
1,6-Hexanediol, distillation overheads
USA (CYTEC)
Petrinex T9 Naphthalene GBR (SABIC (UK))
PHASETREAT 7623
Ethylene glycol monoalkyl ethers NOR (Clariant Oil Services Scandinavia AS)
PROP BH n-Propyl alcohol ZAF (SASOL)
R097671A lkenyl (C11+) amide USA (Lubrizol)
R-50428 Ethylene glycol USA (North American Shipbuilding)
RM 50141 Propylene tetramer USA (Chevron Oronite)
RM 100D Polyolefin amide alkeneamine (C17+)
USA (Lubrizol)
RM 50132 Propylene tetramer USA (Chevron Oronite)
RM 50142 Propylene tetramer USA (Chevron Oronite)
RM 50440 Propylene tetramer USA (Chevron Oronite)
SABUTOL n-Propyl alcohol ZAF (SASOL)
SBP 60-95 Hexane (all isomers) ISR (Gadiv)
SCAL16475A Diethylenetriamine pentaacetic acid, pentapotassium salt (40% solution)5
GBR (ChampionX)
L16660A Diethylenetriamine pentamethylene phosphonic acid, pentasodium salt solution
GBR (ChampionX)
SCALETREAT 13850
Ethylene glycol NOR (Clariant Oil Services Scandinavia AS)
SCW85902KCL
[[(Phosphonomethyl)imino]bis[ethylenenitrilobis (methylene)]] tetrakisphosphonic acid, ammonium salt solution (60% or less)
GBR (Baker Hughes)
SELEXOL SOLVENT
Polyethylene glycol dimethyl ether USA (Dow)
SOLGAD 100 Alkyl (C3-C4) benzenes ISR (Gadiv)
SOLGAD 150 Alkyl (C5-C8) benzenes ISR (Gadiv)
SOLGAD 150ULN Alkyl (C3-C4) benzenes ISR (Gadiv)
SOLGAD 200 Methyl naphtalene (molten)3 ISR (Gadiv)
SOLGAD 200ULN Methyl naphtalene (molten) ISR (Gadiv)
SOLTROL 130 Iso- and Cyclo- Alkanes (C10-C11) USA (Chevron Phillips)
Solvesso 100 Alkyl (C3-C4) benzenes BEL (ExxonMobile)
Somentor 32 Iso- and Cyclo- Alkanes (C12+) BEL (ExxonMobile)
Somentor 32 S Iso- and Cyclo- Alkanes (C12+) SGP (ExxonMobil Asia Pacific Pte Ltd)
5 Does not have complete GESAMP Hazard Profile.
PPR 7/INF.17
Annex 3, page 5
K:\PPR\07\PPR 7-INF.17.docx
Trade name Component with a safety hazard Representative country and company
Somentor 34 Iso- and Cyclo- Alkanes (C12+) NLD (ExxonMobile)
Varsol 30 Alkanes (C6-C9) BEL (ExxonMobile)
Varsol 40 Alkyl (C3-C4) benzenes BEL (ExxonMobile)
Varsol 60 Alkyl (C5-C8) benzenes BEL (ExxonMobile)
Varsol 80 Alkyl (C5-C8) benzenes BEL (ExxonMobile)
Varsol 120 Alkyl (C5-C8) benzenes BEL (ExxonMobile)
Varsol 140 Alkyl (C9+) benzenes BEL (ExxonMobile)
WAXTREAT 3553 Alkyl (C3-C4) benzenes NOR (Clariant Oil Services Scandinavia AS)
Xylenes Concentrates
Ethylbenzene GBR (ExxonMobile)
__________