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Page 1: . %3 1 4 $ +: 0jointproject-cscri.rcms.nagoya-u.ac.jp/2010_2016/records/...©Z a k967 ]?c9 » ï à ? ÿ "Ê © ù ± ³ ê ö " úÁà ÿ x Û O e-mail: wakioka@scl.kyoto-u.ac.jp

25 6 28 ( ) 29 ( )

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e-mail: [email protected] http://www.scc.kyushu-u.ac.jp/Seibutsuyuki/index.htm

e-mail: [email protected] HP: http://www.scc.kyushu-u.ac.jp/Sakutaibussei/

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e-mail:[email protected] http://www.scc.kyushu-u.ac.jp/Yuki/a_molcat/Top.html

cat. [Pd]

oxidant(– 2 H2)

N

NR1

R2

R3

R4

R5

R

O

R'H

H

H

H

H

H

R

O

R'H

H

R1

O

R3

R2

H R5

R4+cat. [Ni]

oxidant(– 2H2)

NH3

e-mail:[email protected]

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2

e-mail:[email protected] http://www.scc.kyushu-u.ac.jp/Hiheikou/index.html

C-H/C-H

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e-mail:[email protected] http://www.cm.kyushu-u.ac.jp/dv04/dv04j.html

1,4 - Conjugate Addition

[email protected]

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e-mail:[email protected] http://trout.scc.kyushu-u.ac.jp/yoshizawaJ/

( )

E-mail: [email protected] HP: http://trout.scc.kyushu-u.ac.jp/yoshizawaJ/index.html

-12

( )

“DRY” “WET”

Binding mode?Driving force?

Dominant interaction?

i = 1,2, 3...( )

∂V∂ ir

= 0

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e-mail: [email protected] http://om.kuicr.kyoto-u.ac.jp/index.html

直直接的アリール化重合:π 共役系高分子の新合成法

+

– HX

Pd cat. n

XX πHH π π π

XH π πn

Direct ArylationPolymerization

short synthetic procedure / reduced waste generation

・反応速度論に基づく反応機構解析:ヘテロアレーン類の反応性支配因子の解明 ・高活性直接的アリール化触媒の開発:高分子量ポリマーの合成

Ya-Fan Lin International Research Center for Elements Science, Institute for Chemical Research, Kyoto University, Postdoctoral Fellow E-mail:[email protected] Research Interesting Exploring the reactivity for the Fe(I) complex bearing a bis(phosphaethenyl)pyridine ligand (BPEP)

2

NPhPh

P PFeI

MesMes* Mes*

NPhPh

P PFe0

LMes Mes*

L

L

1

NPhPh

P PFeI

BrMes* Mes*

NPhPh

P PFeI

BrMes* Mes*

L

NPhPh

P PFe0

LMes* Mes*

L

at 80oC

Reactions of the Fe(I) Complex Bearing a BPEP Ligand

1 eq of L

L= π−acids,such as CO and tBuNC

L= π−acids,such as CO and tBuNC

L= π−acids,such as CO and tBuNC

L= π−acids,such as CO and tBuNC

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e-mail: [email protected] http://www.kuicr.kyoto-u.ac.jp/labos/is2/scope.html

e-mail: [email protected] http://rdb.kuicr.kyoto-u.ac.jp/researchers/view/mizuhata+yoshiyuki

AFM image (left) and photoconductivity action spectra (right) of an

annealed 50 nm cobalt phthalocyanine thin film.

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sugamata[at]boc.kuicr.kyoto-u.ac.jp

e-mail:[email protected] http://es.kuicr.kyoto-u.ac.jp

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e-mail: [email protected] http://www.scl.kyoto-u.ac.jp/~bfdc/index.html

e-mail: [email protected] http://www.scl.kyoto-u.ac.jp/~kouzou/index.html

hydrophilicsignal

amplifier

fluorescence

hydrophobicanalyte

amphiphilic activator

polyiontransporter

O

O

O5

O11

O

O24

O

O20

O16

OO

O26

O15

O

O30

O17

OHO

O

O

HO

OO4

OO3

OO7

O

O6

OO8

O

O27

O

O10

OO9

O28

O

O23

O

O

O21

NH

HN

OH2N

ONH

H2N

ONH

NH2+

O

NH2

HNH2N

A6

NH

HN

OH2N

ONH

H2N

ONH3

+

OHNH2N

A5

NH

HN

OH2N

ONH

H2N

NH2

NH2+

A4

NH

NH3+

OH2N

ONH

H2N

A3

NH

HN

OH2N NH2

NH2+

A2

NH

NH3+

OH2N

A1

NH

HN

ON

ONH

N

ONH

NH2+

O

NH2

HNN

O5A6

NH

HN

ON

ONH

N

NH2

NH2+

O5A4

NH

HN

ON NH2

NH2+

NH

HN

ON

ONH

N

ONH3

+

OHNN

O5A5

NH

NH3+

ON

ONH

N

O5A2

O

O29

O

NH

NH2O

N

O5A3

O5A1

OO12

OO13

OO14

O

O22

O19

O

O18

O

O

O25

O

O2

OO1

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e-mail: [email protected]

π

π

e-mail:[email protected] http:// noncry.kuicr.kyoto-u.ac.jp /

NMR

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e-mail: [email protected] http://advmat.chem.nagoya-u.ac.jp/matsushita.html

e-mail: [email protected] http://advmat.chem.nagoya-u.ac.jp/yoshikawa.html

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e-mail: [email protected]

e-mail:[email protected] http://qc.chem.nagoya-u.ac.jp/indexj.html

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O

OH

OH

HO OH

OH

β-fructose (9)

O

HO OH

HO

H

OH OH

OHO O

HMF

O

OH

OH

HO OH

OH

1

O

OH

OH

HO OH2

OH

2

+ H3O+

3

- H2O O

HO OH

HO H

OH

4

+ H2O O

HO OH

HO H

O

5

- H3O+

O

HO OH

HO O

H

6

O

HO OH

HO O

H

H

H

7

O

HO OH

HO

H

OHH

8

O

HO OH

HO

H

OH2OH

9

O

HO OH

HO

H

OH OH

+ H3O+

Hydrogen-shift

+ H2O+ H2O

- H3O+

Rotation

- H2O

β-glucose (1)

- 3 H2O

OHO O

HMF

Proposed mechanism Calculated free energy Calculated free energy

e-mail: [email protected] http://qc.chem.nagoya-u.ac.jp/index.html

DFTB

1 e-mail:[email protected] http://qc.chem.nagoya-u.ac.jp/

glucose hydrolysis in acid environment

y

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1 e-mail:[email protected] http://qc.chem.nagoya-u.ac.jp/indexj.html

e-mail:[email protected] http://biochem.chem.nagoya-u.ac.jp/

0.0 1.0

ES

CT

0

50

100

150

200

250

sFre

e E

ner

gy

(kca

l / m

ol)

ES CT . ss=0 s=1 CT .

0

0.2

0.4

0.6

0.8

1

800 900 1000 1100

1ST EX

2ND EX

Wavelength (nm)

Oscilator Strength

.

g(r)

.

-Mdm12

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e-mail:[email protected] http://www.os.rcms.nagoya-u.ac.jp/

HNu Nu

O MHH X

O

O

*NR

O

*n n

OOH

OO

X

RO-AllR2N-AllR3C-All

(AllOH)

RS-All

S

e-mail:[email protected] http://nano.chem.nagoya-u.ac.jp

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D1

D1 e-mail:[email protected] http://nano.chem.nagoya-u.ac.jp/japanese/people/sasaki.html

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e-mail: [email protected]

in-situ

e-mail:[email protected]

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e-mail: [email protected]

e-mail:[email protected] http://noy.chem.nagoya-u.ac.jp/

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e-mail:[email protected] http://photon.chem.nagoya-u.ac.jp/

e-mail:[email protected] http://photon.chem.nagoya-u.ac.jp/

226 nm

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e-mail:[email protected] http://orgreact.chem.nagoya-u.ac.jp/Saito-CV.html

e-mail:[email protected] http://bioinorg.chem.nagoya-u.ac.jp/

P450

Angew 2012

RGB

JACS 2013

JACS 2013

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e-mail:[email protected] http://bioinorg.chem.nagoya-u.ac.jp/

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(PD)

e-mail: [email protected]

XAFS

[email protected]

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e-mail:[email protected]

Sum frequency generation spectroscopy measurements on electrode/electrolyte interface in Li-ion and Li-air batteries

1

e-mail:[email protected]

Structure and Stability of Surfactant Monolayer on the Solid Surface Investigated by SFG and AFM

Hi, my name is Peng Qiling and from Hokkaido university. Since April

2011, I have joined professor Osawa research group in the catalysis research center and fortunately I

have obtained the master degree this March. In order to better understand the interfacial phenomena

on the molecular level, I continued my Ph.D course in the same group this April. Now, my research

topic is Structure and Stability of Surfactant Monolayer on the Solid Surface Investigated by SFG and

AFM. Thanks, everyone.

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E-mail: maitakase[at]cat.hokudai.ac,jp

1 [email protected] http://www.hucc.hokudai.ac.jp/~k15391/

表面プラズモン共鳴  +光触媒反応  新規有機合成反応手法の開発

光照射・波長・強度・偏光方位 光触媒への寄与

・電子励起・局所加熱・引力

効率的プラズモン電場の形成

多面体酸化チタン

表面プラズモン共鳴 +光触媒反応

新規有機合成反応手新規有機合成反応手法の開発手法の開発

光照射・波長・強度

位・偏光方位・偏 光触媒への寄与・電子励起・局所加熱・引力力力・引力引力引力引

射長度位光方位 光触媒

効率的プラズモン電場の形成

多面体酸化チタン

表 光 新新

単体 球状 多面体構造 特殊構造

増強電場 増強電場 強電フレーム構造

中空構造

二量体 辺で近接 頂点で近接 辺と頂点で近接

高次規則配列

サイズ:数 nm ~ 300 nm

1 μm

1 μm

1 μm

1 μm

1 μm

1 μm

300 nm

300 nm

LLLLLLLLLLL 42 44242 42 42 242 42 42 242 mmmmmmmmmmm

222222222 gggggggggggg

------- 11111111111

25%25%25%25%25%25%25%25%25%25%25% ncncncncncncncncncncnc HHHHHHHHHHH 43 43 43 43 4343 43 43 43 43443 mmmmmmmmmmmm

2222222222 ggggggggggggggggg

-1

19%19%19%19%19%19%19%19%19%19%9% 19% nncnncncnncnccnncncncncncncncncncncnnc

5005005005005005005005005005000LLLLLLLLLL500L 15 15 15 15 15 1515 15151515 mmmmmmmmmmm

22222222222 gggggggggg

----- 11111111

15%15%15%15%15%15%15%15%15%5%5 15% ncncncncncncncncncncnc 5005005005005005000500050 HHHHHHHHHH50050050050050050050050050050050 HHHHHHHHHHH500H 1515 15 15 1515 15 15 15151515 mmmmmmmmmmmm

2222222222 gggggggggggg

----- 11111111111

19%19%19%19%19%19%19%19%19%19%19% 19% nnnnnnnnnnnnccccccccccc

FBFBFFB 19.19.19.5 m5 m5 mm5 mmm5 m19.5 m

2222222 gggggggggg

-------- 1111111 17%17%17%17%17%% 17% ncncncncnccncncccnc

500500500FBFBFBFFBB5005005005005 00FBFBFBFFBFBB500FB 88888 .1 .1 1 1 .1 mmmmm.1 m

BBBBBBBBBB222BBBB2 ggggggggg

---- 11111 13%13%13%13%13%3 13% ncncncncncncncnncnc

gggg----111111111111111111111111111111111111111111

cccc

500FBFBH + L500L + 500H

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kshimizu[at]cat.hokudai.ac.jp

e-mail:[email protected] http://www.cat.hokudai.ac.jp/takahashi/

Second Ring Adducts of Pentacene

A=A

AA

dienophiles

Method II

aromatization

5,14-dihydropentacene

A=A

AA R

R

R

R

dienophiles

Method I

desilylation

AA

2nd ring adduct of pentacene

AA

AA

Disfavoured 2nd ring adduct of pentaceneFavoured Central ring adduct of pentaceneA=A

dienophiles+

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e-mail: [email protected]

( ) 1 e-mail: [email protected] http://www.cat.hokudai.ac.jp/fukuoka/


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