017795 - United States Environmental Protection Agency · U.S. ENVIRONMENTAL PROTECTION AGENCY-CLP...

017795

U.S. ENVIRONMENTAL PROTECTION AGENCY-CLP ianplt Management Officer 0. Box 8IB, Alaxindrli, »A 223U - 703/997-2490

ORGAN ICS ANALYSIS DATA SHEET - Page I

Laboratory Nam _M«d CeapiiChem___________ Cue NumberLit Staple ID No. a5Ofc, R _ _ _ _ _ _ DC R.port No. ________________

$uUihC spikeMultiply ill Value* anil Detection Unite by 1 Qor loQorQ ____;

(Chech Box for Approprlete Fictor)

ACID COfOUNOS BASE/NEUTRAL COMPOUNDS

PP« CA5i» ug/Hg PP/ CA5I ug/Hg

(2IA1 BB-06-2 2.4.6-trlcr.lorophenol_____400U (42B) 39636-32-9 Mi-12-chloroliopropyl letner 800:122A) 39-50-7 p-chloro-m-cretol_______IttoltfOD I43B) 11—91-1 bl»-12-cnloroetho«yln»tnane 800:124A) 95-57-6 2-chlerophenol_________•498b-)ggD I52B1 B7-66-3 hexachlorebutadlene______400:-131A) 122-B3-2 2.4-dlchlorephenol_______400U. 153B) 77-47-4 hexachlorocyclopentadlene 400:(34A) 105-67-9 2.4-dlneTnvlpnenol_______400" I54B) 76-59-1 Itophorone___________400:157A) B6-7S-5 2-nltrophenol__________BOOU I55B) 91-20-3 nepnthBlene_________4001I56M 100-02-7 4-nltrophenol_________4M8U/POCO (56B) 96-95-3 nitrobenzene__________400.I59») 31-66-5 2.4-dlnltrophenol_______ZOOOu I62B1 66-30-6 N-nltroiodlpnenylamlne____400:160A) 534-52-1 4.6-dlnltro-2-»ethylphenel BOOU (636) 621-64-7 N-nltrotodl-n-prepyleiBlne tttr-SfJ64A) 87-36-5 penttcnierophenol_______M80 HOP I66B) 117-81-7 blt(2-ethylhexyl)phthalBte 400:(65A) 106-95-2 phtnol IttnlbCO 1676) 85-66-7 butyl benzyl phtnalatt____400:

I6BBI 84-74-2 dl-n-butyl ptitnaltte_____(Non-Priority Pollutsnt Hazardous Substances) I69B1 117-64-0 dl-n-oetyl phtnalate

(706) 84-66-2 ill ethyl phthalate_______400':____65-65-0 b«ntolc aclc__________4000U (7IB) 131-11-3 dlmtnyl phthtlate_______400:| 95-46-7 2-iMthy I pheno I___ 400. I72B) 56-55-3 benzplalanthraeene 400:i____106-39-4 4-inttny I Phenol_________400U I73B1 50-33-B benzoltlpyrene_________BOO1;____95-95-4 2.4.i-trlehlBrophenol_____4000: I74B) 205-98-2 benzolbHluorantnene______800.

I75B1 207-08-9 benzolKHluorantnene 600:BASE-NEUTRAL COHPOUND5 I76EI 316-01-9 ehrviene (l3~) 4CXJ

(77B) 206-96-6 ecenaphtnylene______ 400:I 16) 63-32-9 aeinapntnane_________JOJuS^HjD (7BB) 120-12-7 anthracene____________400:( 5B) 92-67-5 benzldlne____________I600J (79B) 181-24-2 b»nzolahl)peryline_______600:I BBI 120-62-1 1,2.4-trlehlorobenzene____4ttKlJ%00 (BOB) 66-73-7 fluarene_____________400.( 9B) 116-74-1 h«»acniorobenzene_______400U (BIB) 85-01-6 ohenantnrene__________400.I12B) 67-J2-1 nmaehloroethane________40GU IB2B) 93-70-3 dlbenzo(a.h)anthrecen«____800.I16B1 111-44-4 blil2-chloro«tnyl)ether____400U IB3B1 IB3-39-8 lndeno(1.2.3-ed)pyrene____lOOi;(20EI 91-56-7 2-chlorenaphtlnlene______400U IB4B1 129-00-0 pyreneJ25B1 95-50-1 l.2-dlchlorol>enzene______400J126B) 541-73-1 l.i-dlehlorobenzene______4QOu (Non-Priority Pollutant Hazgrdout Subltancel)I27B) IOt-46-7 1.4-dlehlorebenzene1283) 91-94-1 S.i'-dlchlorabenzldlne____*M«30PO 62-53-3 enlllne_____________JOOjiI35B1 121-14-2 2.4-dlnltrotoluene_______IttalttO 100-51-6 Mnzyl alcohol______ 60i!-I36BI 606-20-2' 2.6-dlnltretoluene_______BOOU ____106-47-6 4-chloro«nl I Ina_______ 2000.

1,2-dlphenylhydrazlne 132-64-9 dlbenzofuran__________£2Si1376) 122-66-7 (»> azobenzene)_________BOOU ' 91-87-6 2tiethv I naphthalene____. 80°-I39BI 206-44-0 f luoranthene__________40Du BB-74-4 2-nltroanll Ine________ 4QO!I-(4061 7005-72-3 4-cnl oropheny I phenylether 400U 99-09-2 3-nltroanl I Ine_____ 400D-1418) 101-55-3 4-bromopnenyl ptiinyl ether 400U ____100-01-6 4-nlTroanl I Ine________ <00u-

OROAN1CS ANALYSIS DATA SHEET - Pige 3

Lib tomi; Held CompuChtmLib Supl*) i.D. Mo.

"S«ipU SpUe

A. SURROSATE SPIKE RESULTS

COMPOUND

2-Fluorophenol

Ptntifluorophenol

..- - •

D5-N1troben«ne

4 Decifloroblphenyl

Z-Fluorob1phtny1

Z-FlMoroin111nc

M

•

•

•

FRACTION

SENIVOA

SEHIVOA

SEMIVOA

SENIVOA

SENIVOA

SENIVOA

CONC (ug/kg)

Si O

f^DD

t}°\00

Sôo

4fcoo

l&jOO

J[Surroj»tes only)Spine

Added (ug/kg)5000

5000

5000

5000

. 5000

5000

%Recovery

Vk

at,

WtfK^

017797

v\gi §I i

B

RS• I

V

in

•> iS i

8 *'Q17793

BASE-NEUTRAL I ACID MATRIX SPIKE

Low Solid SamplesLab Name-Mead CompuChem

||qc Sample No. Original No. EPA No. QC Report No.Associated Saiwles 330\ , 333 Ij. " Use No§

PPit CAS No. Compounds Orlg. Sample QC Spike Added X" " Results Un/kQ Recovery

(22A) 59-50-7(24A) 95-57-8(58A) 100-02-7(64A) B7-36-5

(65A) 10B-95-2( IB) 83-32-9

( BB) 120-82-1(27B) 106-46-7(35B) 121-14-2

(63B) 621-64-7(68B) 84-74-2(69B) 117-84-0

(76B) 318-01-9(B4B) 129--00-0

p-chloro-m-cresol2-chlorophenol _4-nltrophenolpentachlorophenolphenol•cenaphthene1,2,4-trlchlorobenzene1,4-dlchlorobenzene2,4-d1n1trotolueneN-n1 trosodl -n-propyl ami ned1-n-butyl phthalatedl-n-octyl phthalitechpysene __ _. . _ ,

KM

/Poo/APflO

1100/fcoofutoMOO

SWVIMO

2000 102000 <fc>

12000 &

2000 (•$"

2000 PJI

?ODO /5f

200D /JO2000 IJ2.C

. 2000 yO

jipÔ 8000 || D

3100

M 00Aoo

pyrene / AZOV

?onn //fr?noo 'AO2000 ID2000 )/_)

017793

ft

w

09

OO

spa-,——i——' t v __i__ T i ?

01 on

S>M-

ijjS

op ro _•M

Ml

00 "*

oi

me

sro £

B§ sn i *u i

J———i———i ,.,7 IS s

-8ss

«

XLd

SL5o

a§

I

fflg

. _ i- M eo N fll 7 BTl 9« ,( ?r fcj ®w g vK..oU*8'lSr 45o1 * wo B ••'<.'! ' .'•,m 2 & u A a, M S ••• >. y y

XI$'

N

Ss

^

2>S5*

w * •- Ss £ a ?_i i , <?

Wl-i'Kill

I

a:II-

(*) CDs

8" £

W).

lUl CEiCD

-I-£

CO CO

co SiCD

if

i.

1HOL£iN

ISJs±3

:=»

ys

-2:N)

.5 -

"S"

r

MM

8 C' •• •'017804'

PROCEDURE; RK DIAGNOSTIC REPORT 6/21/B3 14:35:34DATA PILE: GR003206A14REFERENCE: FSCC6

METHOD: FSCC6 INITIALIZATION OPTION: 2 PROCESSING OPTION: 3

PROC USED POSS RMS4 4 2 4S2 2 4 BO

79 COMPOUNDS PROCESSED,

NO LIB ENTRY123456789101112131415,^718192021222324252627282930313233343536373839404142*' 444"'454647*Q

F2F3FlFlFlFlFlFlFlFlFlFlFlFl.FlFlFlFlFiFlFlFlF2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2PS

111SO234567891011121314151617181923456

" 78910U121314.151617IB1920SI22S324SS26P7

REF-1005-1640-738-1237-1B3-739-732-732-721-740-754-789-812-841-850-847.-882-502-768-876-954-672-871-879-935-942-980-994-994-1001-1008-1067-1055-1156-1147-1196-1220-1241-1320-1342-1008-1349-1422-1369-1289-1393-1497-tPPfl

PRED100416397381236IBS739732732721740754789812841850B4788250376B87695367287187993494197999399310001007106610541155114611951219124013181340100713471420136712S71391149511357

PROC USED POSS65 41 4IS 12 2

E2 FOUND

SEL DELTA PEAKS100416397381236

,738

,

72JL(

754

816(

\

,

SOS

B77954673873

931,

980

,

1001t

1064(

11551146

t

1319

,

133B

13461419

12831390149418S6

,

t

t-a,

,

(

4t

,

2,

1112,

-3,J.,,i,-2(

,

(

,

,

,

-2,

-1-1

-4-i-1-1

1112t1.t

1,1t

1(

,

,

1(

1112(

1

1,

1(

1,

11(

1,

,

1

11,

1121

RMS STANDARD/UNKNOWN181 FSCC6S1/FSCC6U1123 FSCC65S/FBCC6U2

FIT PEAKS M/E996989968994

,997

(

,

999

999

968(

,

,

998(

996996998983

936,

992

,

997,

411,

995903

,

975.

.

993

995996

,983949987997

136IBS97

-1 17274949393128146146146108121.108117108112184823341111301238213912293162180127105225107115237196162152163128165165138138168138

Sn. 196

-— "— wiTOP100416397381236

,738

(

(

721(

754789814

,

,

,

505,

877954673873

,

931942981

,

,

1001,

,

,

11551146

,

122012401319133B1007

1419,

12B5 i139014941226

TOP DELTA PEAKS11i1

! iiii2

. ii I

1111

111

11

11111

4,

1131

50 F3 3 -1391 1389 1387 -2 1 9BB51 F3 4 -1429 1427 1427 . 1 9875 2 F 3 5 -1460 145B . . . .153 F3 6 -1475 1473 1474 1 1 97654 . F3 7 -1487 14B5 1483 -2 1 997«F3 8 -1501 1499 1495 -4 1 963

F 3 9 -1504 1502 . . . .57 F3 10 -156S 1566 1567 1 1 991SB F3 11 -1583 1581 ... , .59 F3 12 -1645 1642 1642 . 1 99860 F3 13 -1653 1650 1651 1 1 99461 F3 14 -1879 1876 1877 1 1 99662 F3 15 -1930 1916 1919 3 1 99063 F3 16 -1505 1503 1502 -1 1 98864 F3 17 -1812 1809 1812 3 1 99765 F3 IS -1627 1624 1626 2 1 100066 F4 1 -2167 2167 2167 . 4 9956 7 F 4 2 -2164 2163 . . . .6B F4 3 -2172 2171 2172 1 1 995f c ? F 4 4 -2190 2189 . . . .70 F4 5 -2103 2102 2102 , 1 99571 F4 6 -2236 2235 2236 1 1 99772 F4 7 -2354 2352 2353 1 1 9947 3 F 4 8 -1917 1916 . . . .74 F4 9 -2417 2415 2414 -1 1 98875 F4 10 -2592 2590 2590 . 1 96776 F4 11 -2600 2598 2598 . i 97077 F4 12 -2627 2625 2624 .-1 1 98078 F4 13 -2365 2363 2362 -1 2 99579 F4 14 -2370 2368 2366 -2 1 991

1M 13SB . 11EM 1386 -1 2139 1427 , 1166 1458 . 12 0 4 . . .149 1483 , 1198 1495 . ' i1 6 9 . . .248 1567 . 1284 15S0 . 1178 1642 . 1178 1651 . 1,202 1877 . 1202 1919 . 177 1502 , 1149 1812 , 1266 1626 . 1240 2166 -1 1SSS 2162 . 1228 2172 , 12 5 2 . . .149 2102 . 1149 2236 . 1149 2353 . 11 8 4 . . .252 2414 . 1276 2590 , 1278 3598 . 1276 2624 . 1252 2362 , 1252 2366 . 1

m *~

OUANTITATION REPORT FILE: GR083206A14

DATA: CR0e32C6A14. TI06/21/83 13:51:00iMPLE: 1UL #3S06R +19052 IB) ON #14IBMITTED BY: 014 ANALYST: 659

AMOUNT-AREA * REF. AMNT/(REF. AREAlt RESP. FACT)RESP. FAC, FROM LIBRARY ENTRY

NO NAME1 *D3-PHENOL (INTERNAL STANDARD) (624)2 N-NITROSODIMETHYLAMINE (441)3 PHENOL (610)4 ANILINE (473)5 BIS(2-CHLOROETHYL)ETHER (411)6 3-CHLOROPHENOL (601)7 1,3-DICHLOROBENZENE (421)8 1,4-DICHLOROBENZENE (422)9 1,2-DICHLOROBENZENE (430)10 BENZYL ALCOHOL (474)11 BIS(2-CHLQROISOPROPYL)ETHER (412)12 2-METHYLPHENOL (620)13 HEXACHLOROETHANE (436)14 4-METHYLPHENOL (622)IS 3-FLUOROPHENOL (SURROGATE) (619)16 PENTAFLUOROPHENOL (SURROGATE) (623)17 DS-NITROBENZENE (SURROGATE) (447)IB DECAFLUOROBIPHENYL (SURROGATE) (470)19 ' 2-FLUOROANILINE (SURROGATE) (472)20 3-FLUOROBIPHENYL (SURROGATE) (448)

(M|i *DB-NAPHTMALENE (INTERNAL STANDARD) (460)& N-NITROSO-DI-N-PROPYLAMINE (442)23 NITROBENZENE (440)24 ISOPHORONE (438)25 2-NITROPHENOL (606)26 2,4-DIMETHYLPHENOL (603)27 BIB(2-CHLOROETHOXY)METHANE (410)28 2,4-DICHLOROPHENOL (602)29 1, 2. 4-TRICHLOROBENZENE (446)30 4-CHLOROANILINE (475)31 BENZOIC ACID (625)32 HEXACflLOROBUTADIENE (434)33 P-CHLORO-M-CRESOL (608)34 2*METHYLNAPHTHALENE (472)35 HEXACHLOROCYCLOPENTADIENE (435)36 2, 4, 6-TRICHUOROPHENOL (611)37 2-CHLORONAPHTHALENE (416)38 ACENAPHTHVLENE (402)39 •DIMETHYLPHTHALATE (42S)40 NAPHTHALENE (439)41 3- 6-DINTTROTOLUENE (438)42 2,4-DINITROTOLUENE (427)43 3-NITROANILXNEI479)44 2-NITROANILZNE(47B)45 DIBENZOFURAN (476)46 4-NITROANILINEI4BO)

0185

NO NAME47 2, 4, 5-TRICHLOROPHENOL (626)48 ttDlO-PHENANTHRENE (INTERNAL STANDARD) (467)9 ACENAPHTHENE (401)

01)0 2,4-DINITROPHENOL (60SS)SI 4-NITROPHENOL (607)52 FLUORENE (432)53 4-CHLOROPHENYU PHENYL ETHER (417)54 DIETHYLPHTHALATE (424)55 4- 6-DIN1TRO-0-CRESOL (604)56 DIPHENYLAMINE (N-NITROBO) (443)57 4-BROMOPHENYL PHENYL ETHER (414)SB HEXACHLOROBENZENE (433)59 PHENANTHRENE (444)60 ANTHRACENE (403)61 FLUORANTHENE (431)62 PYRENE (445)63 1,2-DIPHENYLHYDRAZINE (AZOBENZENE) (430)64 DI-N-BUTYLPHTHALATE (426)65 PENTACHLOROPHENOL (609)66 *D12-CHRYSENE (INTERNAL STANDARD) (459)67 BENZO(A)ANTHRACENE (405)68 CHRYSENC (418)69 3>3'-DICHLOROBENZIDINE (423)70 BUTYLBENZYLPHTHALATE (415)71 BIS(2-ETHYLHEXYL)PHTHALATE (413)72 DI-N-OCTYLPHTHALATE (429)73 BENZIDINE (404)74 BENZO(A(PYRENE (406)75 INDENOd, 2, 3-C, D)PYRENE (#437)P(| DIBENZO (A, HJ ANTHRACENE (419)17 BENZO (C, H, I) PERYLENE (408)7B BENZO(B(FLUORANTHENE (407)79 BENZO(K)FLUORANTHENE (409)

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT XTOT1 97 73B 9:13 1 1, 000 A BV 37672, 20, 000 NG 1, 212 NOT FOUND ./3 94 738.. 9:13 21 0,735 A BV 111270. SB, 742 NOiî 2,344 NOT FOUND °5 NOT FOUND J6 12B "721- 9:01 21 0,718 A BV 105102, 43, 1B2 NG»^r 2,737 NOT FOUND V8 146 754-• 9:25 21 0.751 A BV 167204. SB. 975 NCMF 3.569 146 789 9:52 31 0, 786 A BB 462, 0, IBS NC ' 0. 0110 108 814 10:10 31 0, 811 A*BB 731, 0.544 NC 0, 0311 NOT FOUND12 NOT FOUND13 NOT FOUND14 NOT FOUND /15 112 305 6:19 31 0. 503 A BV 193667, * 96.076 NC 5. 8016 NOT FOUNDW MM i ta.W-P17 82 877 iO: SB 21 0, 874 A BB 337B34. * 123,362 NG 7. 47IB 334 9S4 11:55 21 0. 950 A BB 1B6195/ , 60, 223 NG 3, 6419 ill «-3WB:25 21 0.670 A BVV?(P?/SS6ei, '/'fl*i-B*9 NG 0,6620 172 1236 15:27 31 1.231 ABB 568989, / 113.793 NG 6, BB?' ' 136 1004 12:33 21 1. 000 A BV 129644. 20, 000 NG 1, 21'-~4

80

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT ^ y.TOT22 130 873'" 10:35 21 0,870 A BV 97623. 216. 165 NCi^ 13. 0623 NOT FOUND ' 5

82 9n 11:38 21 0, 927 A BV 2272. 0. 494 NG 0. 03139 9 (2 11:46 31 0, 93B A BB 302. 0, 230 NC 0, 01

26 122 T31 12:16 21 0,977 ABB 462, 0. 222 NC 0,01S7 NOT FOI/ND28 NOT FO>M) ,29 ISO 1001 -12:31 21 0, 997 A BB 124816. 35, 694 NCy/* 3. 3730 NOT FOUND t"31 NOT FOUND32 NOT FOUND33 107 1133. 14:26 21 X 150 A BV BB363, 34. 572 NC 'vtf 2.0934 115 1146 14:19 31 1, 141 A BB 486, 0, 203 NC • 0. 0135 NOT FOUND36 196 1220 15: IS 21 1, 315 A BB 809. 0. 332 NC 0, 0237 162 1240 15:30 21 1, 235 A BB BBS, 0, 198 NC 0, 0138 132 1319 16:29 31 1. 314 A BB 706. 0, 170 NG 0. 0139 163 1338 16:43 21 1, 333 A VB 4087, 0, 809 NC 0. 0540 12B 1007 12:35 21 1, 003 A BB 2301, 0. 311 NG 0, 0241 NOT FOUND ,42 165 1419 -17:44 31 1, 413 A VB 74132. 45, 013 NG W 2. 7243 NOT FOUND •44 136 1285 16:04 21 1, 280 A BV 1850, 1, 137 NC 0, 0745 168 1390 17:22 SI 1, 3B4 A BB 3873. 0. 490 NC 0. 0346 138 1494 18:40 21 1,408 AtBB 817. . 3, 280 NC 0, 2047 196 1326 IS: 19 21 1,221 A BB 9481, 7. 490 NC 0. 4548 188 1639 20:29 48 1,000 A VV 110766. 20, 000 NC , 1, 2149 154 1358-16:58 48 0.829 A VB 206163, 3B. 939 NG 3,56SO 184 1386 17:19 48 0,846 A*BB 1103. 3, 380 NG 'J 0,20M| 139 1437--17 :S0 48 0,871 A BV 1B9123, 237. 333 NG 15. 56ad 166 1458 18:13 48 0,890 ABB 2327, 0, 582 NC J 0.04S3 NOT FOUND54 149 1483 18)32 '48 '0.905 ABB 10344, 2, 310 NG 0,1455 19B 1495 18:41 48 0.912 A BB 1743. 3, 715 NG 0, 2256 NOT FOUND57 248 1567 19:35 48 0,956 A BB 437, 0, 341 NG 0, 02SB 284 1580 19:45 48 0,964 A BB S25. 0, 309 NC 0, 0259 178 1642 20:31 48 1,002 A VV 6244, 1, 001 NC 0. 0660 178 1651 20:3B 48 1.007 A VB 4640, 0, 927 NC 0,0661 202 1877 23:28 48 i, 14S A VB 9B71. 1, 597 NC J 0. 1062 «S02 1919 -"231: 39 48 1.171 A VV 333840. 55, 227 NG U 3, 34-W.63 77 1502 18:46 48 0, 916 A VB 2314, 0, 311 NG \ 0, 0364 149 1812"'22139 48 1.106 ABB 4S9416, 36, 876 NG 3,65 266 1626- 20:19 48 0.992 A BV 27739, 26, 962 NG 1, 63 (66 240 3166 27:04 66 1.000 A VV 194467, 40, 000 NG }, 2,4267 328 2162 27:01 66 0,996 A BV 28233. 5, 040 NG Uf"/ 0, 3068 22B 3172 - 27:09 66 1. 003 A VV 26S394, 74, 829 NC Vfr 4, 5269 NOT FOUND70 149 2102 26:16 66 0.970 A VB 3B76, 1, 3B5 NG 0,0871 149 3236 37:57.66 1.032 A VB 8452. 2, 032 NC 0,1272 149 23S3.--29:25 66 1.086 AW 393192, 59. 269 NC Uf*' 3. SB^rut SI4-73 NOT FOUND ° k74 252 2414 30:10 66 1, 114 A VB 15596, 3, 671 NC 0, 2275 376 3590' 32:22 66 1.196 A BV 17565, 3, 270 NC?W .0, 3276 278 2598 32:28 66 1,199 AW 17220. 5, 065 NG H) V 0, 317- 276 2624 •• 32:48 66 1. 811 A VV 1B316, S, 934 NC ' 0, 36

NO M/E SCAN TIME REF RRT METH AREA(HCHT) AMOUNT '/.TOT78 252 2362 29:31 66 1, 090 A BV 16430, 2, 792 NG 0, 1779 252 2366 -29:34 66 1,092 AW 15SB6, 4. 710 NG 525-0, 28

2 2:17 0.182 50, 00 0.2073 9:14 1,00 0,735 1.00 38,74 50,00 0.343 0.443 0.774 9:09 0, 738 50, 00 0, 3545 9:09 0, 738 50, 00 0. 3546 9:01 1. 00 0. 717 1. 00 45, IB SO, 00 0, 324 0, 359 0, 907 9:13 0, 736 50, 00 0. 342B 9:25 1. 00 0, 750 1. 00 SB, 9B SO, 00 0. 516 0. 437 1, IB9 9:52 1,00 0,785 1,00 0.19 50.00 0.001 0. 385 0.0010 10:09 1, 00 0. BOB 1. 00 0. 54 50, 00 0. 002 0. 207 0, 0111 10:31 0, 837 SO, 00 0. 12512 10:37 0,846 SO,.00 0,30113 10:35 0, 843 50, 00 0. 200

• 14 11:01 0,878 50,00 0,37315 6:16 1, 01 0, 500 1, 01 96. 08 36. 00 0. 59B 0. 311 1, 9216 9:36 0, 764 50. 00 0. 10017 10:57 1,00 0,672 1,00 123,56 50,00 1.042 0.422 2.4718 11:35 1, 00 0, 949 1. 00 60, 32 30,00 0, 574 0, 477 i. 2019 Bi 24 1, 00 0. 669 1, 00 10. 87 50, 00 0, 079 0, 364 0, 2220 15:2B 1, 00 1, 231 1, 00 113, 79 30, 00 1, 756 0. 771 2,2621 12:34 1,00 1,000 1,00 20,00 20,00 1,000 1,000 1,0022 10:53 1, 00 0, 867 1, 00 316, 17 50, 00 0, 301 0, 070 4. 3223 10:59 0, B75 50, 00 0. 19124 11:41 1, 00 0, 930 1, 00 0, 49 SO, 00 0, 007 0, 710 0, 01tg_L 11:46 1, 00 0, 937 1, 00 0, 23 SO. 00 ' 0, 001 0. 203 0. 00T7 12:15 1.00 0,975 1,00 0.22 50,00 0.001 0.321 0.00 I27 12:25 0,989 50,00 0.38428 12:25 0,989 50,00 0,29029 12:31 1, 00 0. 996 1, 00 55, 69 50, 00 0. 385 0, 346 1. 1130 12:36 1.003 249,99 0.03131 13:20 1,062 249,99 0,10032 13:11 1,050 30,00 0. 22B33 14:27 1,00 1, ISO 1,00 34,57 50,00 0,273 0,394 0,6934 14:20 1,00 1,141 1,00 0,20 30.00 0.001 0.369 0,0033 14:57 1,190 50,00 0.18636 15:15 1, 00 1, 214 1, 00 0, 33 SB. 00 0, 002 0, 376 0. 0137 13:31" 1, 00 1. 235 1. 00 0, 20 SO, 00 0, 003 0. 667 0, 003B 16:30 1, 00 1, 313 1, 00 0. 17 50, 00 0. 002 0, 640 0. 0039 16:46 i, 00 1, 335 1, 00 0, Bl SO, 00 0, 013 0. 779 0, 0240 12:36 1,00 1,003 1.00 0,31 50,00 0,007 1,143 0.0141 16:52 1.342 30,00 0,13443 17:46 1,00 1,415 1,00 45,01 56,00 0,229 0,254 0,9043 17:07 1,362 249,99 0,03544 16:07 1..00 1,363 1,00 t 14 249,99 0.001 0.231 0.0045 17:25 1,00 1,366 1,00 0.49 50,00 0,009 0,904 0.0146 IB: 43 i. 00 1, 490 1, 00 3. 2B 249, 99 0, 001 0, 036 0. 0147 13:21 1.00 1,222 1,00 7.49 249,99 0,006 0,195 0,0348 20:30 1, 00 i. 006 1, 00 20, 00 20, 00 1. 000 1, 000 1, 0049 17:00 1,00 0,639 1,00 58,94 50,00 0,745 .0.632 1.1830 17:23 1,00 0. B4B 1,00 3.38 249.99 0.001 0.059 0,0131 17:52 1.00 0,871 1,00 257,33 125,00 0.273 0.133 2,06! 418:15 100 0.690 1.00 0.58 50,00 0.006 0,722 0.01cq sio

535455ft~SB5960616263646566676B6970717273747576777B79

18:2618:3518: 4616:4819:3619:4720:3420:4023:2924:0018:4922:3930:3027:0527:0327:0927:2226:1727:5729:2523:5630:1332:2432:3032:5029:3429:37

1, 001, 00

1,001,001, 001,001, 001, 001, 001, 001.001, 001. 001, 00

1, 001, 001. 00

1,001, 001, 001, 001,001. 00

0, 8990. 9070.9150. 9170.9560,9651, 0031.0061.1461.1710. 9161,1050. 9921, 0000.9991.0021,0110.9701,0321, 0660, BBS1, 1151.1961.3001, 3121.0911,094

1.001, 00

1, 001,001,001,001,001, 001, 001,001,001, 001,001, 00

1, 001,001, 00

1.001.001, 001. 001, 001, 00

2,3,

0,0,1,0,1,

55,0,

56,26,40,5,74.

1,2,59,

3.5,5,5.2,4,

3171

343100936023318696000483

380327

672707937971

50,50,

249.50.50.50,50,50.50,50,30,50,SO.40,50.50.50.50,50,30,

ISO,50,50,SO,30,50,50,

900099000000000000000000000000800000000000000000000000

0, 8370, 001

0. 0020, 0020,0230, 017 '0.0361.2130, 0061,6590, 1001, 0000, 1161,092

0. 0160.0351. 618

0. 0640. 0720. 0710,0760. 0680, 064

0,3290, 6090,0650, 0740.3320. 3071,1260, 9041, 1161, 0960, 8181, 4560,1861.0001, 1520, 7300, 0440, 5760. 8561, 3650. 0040. 8740, 6860, 6990.6421, 2100, 681

0, 050, 01

0, 010,010, OS0,020. 031, 100, 011.140, 541. 000,101, 50

0, 030.041.19

0.070,110. 100. IE0. 060, 09

O)

rj1?;

w

Vlie-

-HI/. m KI *

C Is *

WTN-I" j"& FJ

Si8Ml

Sw£

1<u?

•j j

Ii

S 01781-' 80

PS-

Wl

ui

tt

r

.S

Fr-Jw!

£

MOS

C7i

e? i sJ- i r! i 01,7813

-* H» "O• • d

, .

Fw

Hv uiK Pi° J28 £ s

i

O)

_ ___ _ ___ _ _ _ a>

*r "" "" "" *

01

Ml

Kffl-

. . .

• M ,__.gjsgg®S

H"-H.SB-K®* i

V/• — '

Jit-

^l8

V- -

IOli-^ UiSl^ffl g

cp in is i—A Ki tO (»f— »•*. • B • « o?tj\ Si Co tn *s tvCD IT| W $ ^© ffl • Si (S •

gats

I"i»B §

I

&I__I I

CD CD CTI

woo.. K,SQ

""l- *,- *CJ] 4h 0) ffii|^ i j as o as is uj jj»' s £

35 OJCD $ M® *rriZ m i» ffi a jk oSOI • CDUI •

j

z

m- g"8S ^g 5 N

S

8-r

Si

s-

g

fs 8 6 aco JB <n i", i , , , . i , , , , i , , , , i

•vt *••

> IB

-———-•-- "

_

;• . .

•1M ———

X

-

H n] u^ is Q

fri •• oo !p

/>e>«uirwig

GUJcnoIH; _ , wi

S

l->1

1

1— e5m °OS "•* \f\

f»— s

*• "•C —— ! ——— ! ——— , ——— , ——— p..,.,,,., ——— | ——— , | , , , , | , , , ., , y..

£J C (T.;..-.':' «' ?

CP _

s-

017813

is ei uii , , , ,

8i- St\

a\ -• -• ui w^r»T- T. «&£>£:B8'SS

s-

§_.

i1S" • " -,a

CO

Op Cj:J jSrnSi"

CJ ••S T-

8017813

? m ©n» P P

i*g

mB

mz

ini

s *8- __ —————— t—————————————— |u

5*

8-t

8

8

6J-

.s

8 s s aos ea u> co

10 IS

ai'-j————————————— -———————————— 89B

s-i e

r-x

S

1 017821

3 ? 9 ft a

s

•H

-

—

•

,

® * Wl COr —— 1 —— i —— i —— i —— 1 — ->- 1. 1 —— i__,l . . . . 1 . . . . I

!-

L_ "— •—— "

=.

__ -

-

m

••••••HKM

"

•

•

mt

~ nrn^s

BsiNjo on Is c

" 11

V

; §

S

•6fi

3

i- S

s4k*ffi

»„

5?13 mffi

. .. .. MI IS)

K | nf7W'?o£ g Ul «0/C»i

% V ?

g _ _

1-

-i—i—i—i—|—i—i—i—i—« C\/vki'U>5

30

s

9tSH ?

m

S 8 S iS

81=.

8

wI

f

I

t

mK?

*

24'

S yi &i (x) •vjV 00 Si 10 tOm « • • •

OS CD CO UiI . . . , I I , ... I**

a-

^Mt^mOJ W«— OCDKi« HCD .S 73

SsH

4kEZ

Op

wp- |4k CTj

CGC;,7d P 01782530

5 $ P $ ?OS CS N Cfl

8

8-

Ml J

8-

so

i;jiM "

8|1Z^3 , 3

K)l!

Ul

9

* oft

i SBNUJ

ui e 4» mCD 5 Ul Si• .

4k 10I , I I I I

a-

jn i/i ig QSgciP

UICOCD to

I

4kMl

CTl90oi C

• MSOT

V

§»f

-

«•

I

-

co"

-

—

8:

i*

8 S § SGD C& 10 CO

r —

«•Ml

pi

(•>

=-

r

-

:

-

w >•

««

""

=

* c T?

' I1u\gr*

i

i1'1E i.«* vlig e

no p

»-«

—— I —— i —— i —— i —— [ —— I —— l —— I —— I —— | l 1-1 — i— i —— p— i —— i —— i —— t— \ rj»r

P to Of?823

3 U\

t*

8-t

H

MW

%S

B?'

•—.——I—.——I gg

§ c^"-i S ^^ ap 9#|823

8CD

Hi a-i

Si-

i!PIIr^r6

aSMlz

s

g3i

K

^

i - 5 t °S . £ 017830

3 i* P . * «S S to COi , , , I i , , , I , i , , . . I

ft*m

SI**-

j i»wf- W

CJ1OrOIXi

10v

SMi

g33II

90W DO

017831

c/t Si 4k LO 3 tn mCD w N fj\ *v HI CEi« es 01 fom A cc

• i . ... i . . . . i . . . . i , , , . i i , i , i

4k*J

8-

U! " M ' Sg-

rvCr-utrwi

imis j5ro + :

HI

«4k

gE»

M\z

S 5? 017832

0*•8-

i-

•

'*:-

K.!Sl

-"

'

*

cn GI 4« ccift G is) 4*

• , f . 1 , , I 1 1 , , , , 1 I I • i 1

t*.

*v

4 *•

M

-

- — •

— -

^

-

-'_

-

—

|l!lB*. t!0 Xt

WUlc vi, J-» Mi 1 1 |T1

v' + ""

Qti

17•»*•

. E

n

. i

1

EMiho£a

~ OR•• U 1

1""*fn

pj

p.. .-•»..•! as iCiu,v, (.J ts ig 017833 f

^ HBM **'**'

•f y © 4k••ii ® fit /om • . lr

CD o hJ

U)Mr-<»y" :8H

U~l\,'

S .

x»4k

ISi

3 O| CJ 4kf t P P . *co a CD

-J—.1 . ni—in I,—i . ' . . . • . ' . . . . i

8-

8-1

SrnT"

(or wig

i. ;

$V

H.17835

8 8

8-1

y—o

CS 4k,

toFwL/1i- MI a\ mM CO .

V -t*

B-±

>-10

DATA: GR003206A14. TI0HJS1./B3 13:51:00bnrtPLE: JLUL 1I3206R +(9852 IS) ON «14SUBMITTED BY: «14 ANALYST: 639

AMOUNT-AREA * REF, AMNT/<REF. AREA) # RESPRESP, FAC. FROM LIBRARY ENTRY

NO1234567B910111213141516,17IBAP

212223242526272B2930313233343536373839404142434445* -.4

M/ERICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRIC

f RIC

SCAN88130281237241246250'S592642772853083203323463534194455066446686736866946997217387547707757B4

" 789873931954

10011022103110991145115512031236127612S3133B

TIME1:061:37S:312:5B3:013:043:073:143:183:283:343:514:004:094:194:255:145:346:198:038:21B:258:348:408:449:019:139:259:379:419:489:52

10:5511:3811:5512:3112:4612:5313:4414:1914:2615:0215:8715:5716:0216:43

REF RRT1111111111111111111111111111111111111111111111

1, 0001,4772,2842, 6932,7392,7952,8412,9433.0003,1483,2393,5003,6363,7733,9324,0114,7615.0573,7507.3187,3917,6487.7957,8867,9438,1938, 386B, 56B8,7508,8078,9098,9669,92010, 58010, 84111, 37511, 61411, 71612, 48913, 01113,12513, 67014. 04514, 50014, 5B015, 285

METHA BBA BBA BVA VVA VVA VVA VBA BBA BBA BVA VBA BBA BBA BBA BVA VBA BBA BBA BBA BBA BVA VVA VVA VVA VBA BBA BVA VBA BBA BVA VVA VBA BBA BBA BBA BVA VBA BBA BBA BBA BBA BBA BBA BBA BBA BV

. FACT)

AREA(HGHT) AMOUNT534B06000.17377700.11004100.66615290,9760760,12374000,7516150,1932B,10400,101416,64136.12377.18267.25B26.21859.7953.50098,29276,

• 682717,8028,31127,106111.126665,30337,94314,339164,419794,676792,9464,66B72,63277,111774,2547790,36191,B69560.959541,53194,7134.17421,15381,432932,

B198,2023680,

B1B1,7087,7963,

100,3.2,12,1,2,1,0,0,0.0,0,0,0,0,0,0,0,0,0,0,0,0,0,0.0,0,0,

00024905845682531440S004002019012002003005004001009005128002006020024006018063078127

0, 0020,0,0,0,0,0.0,0,0,0.0,0,e,e,o,e,o,

0130120214760071631790100010030030B100S378002001001C, i . f

HOT78,2,1,9,1,1,1,0,0,0,0,0,e,e,0,e,

• o.e,0,e,0,0,0,0,0,0.0,0,e,0,0,0,0,0,0,0,0.0,o,0,0,0,0,0.o,0,

j ^. i > f_

9957638444831100000101000000000001001000 i00OSOS0001OS0610000101OS380113140100000006 |00 !30 :ee00 '00 i017837 |,

NO474B0ml,,j51525354555657SB5960616263646566676B697071727374«3f l777B7980Bl82B3848586B788899091

M/ERICRZCRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRICRIC

SCAN135813831390141914271458146614831495150215311556157916261639.165116701753181218391B771905191919571971198420952095210221132137216721722230223622952306235323622366'24142470259025982624

TIME16: 5B17: 1717:2217:4417:50IB: 13IB: 1918: 3218:4118:4619:0819:2719:4420: 1920:2920:3820:5221:5522:3922:5923:2B23:4923:5924:2624:3824: 4826:1126:1126:1626:2526: 4327:0527:0927: 5227: 5728: 4128:4929:2529:3129:3430:1030:5232: 2232:2832:48

REF RRT111111111111111•111111111111111111111i11111111

15, 43S15. 71613. 79516, 12516, 21616, 56816, 65916. 85216, 98917, 06817, 39817. 68217. 94318. 47716, 625IB, 761IB, 97719. 92020. 59120, 898SI, 330SI, 64BSI, B0722, 239SS, 39822.54=S3, B07S3, S07 •S3, BS684, OilS4. 2B424. 625S4. 68285,34125. 40986. 08086. SOS86. 73936, 84186. 88627. 432SB, 06B29, 43289, 52329, BIB

METHAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA

VBBVVBBVVBBBBBBVBVVBBBBBBVBVVBBBBBVBBBBBBBBVVBBVVVVBBBBVVB88BBBVVBVVVBBVVBBVVVVBVVVBBVVVBV

AREA(HCHT) AMOUNT936459,

9148.11000.474538,B7S4B0,5344,5976,3B62S,12947,7422,5356,10602,12734,S35354.330608.

BS13,7092,28262,864915,

S5B1,24832.12348,B96516,14139,26661,6126,9.534,10913.12488,1B204.24703.634822.573704.11305,32524,8293.5279.

B40369.42710.33759.3B079.7913.47586.46810,50485,

00000,0,0,0i0,0,0,0,0.0,0,0.0,0,0,0.0,0,0.0.0,0,0.0,0.0.0.0,0,0.0,0,0.0,0,0,0.0,0.0.0.

, 175, 002, 002i 089163

, 001001,00700200100100200204406200200100516S001005002168003005001002002002003005156107002006002001157006006007001009009009

7.TOT0,140, 000. 000,070. 130, 000, 000, 010, 000, 000, 000, 000,000.030, 050.000. 000.000.130, 000. 000. 000, 130,000, 000. 000.000, 00e. eo0.00e, ooe, 120. 060.000,000. 00e, eo0. IS0,010, 000, 010. 000, 010, 010, 01

m " d53:5 S*" -^- L~l~ " ' "—•" C»l""" i"»»K r™ P«

r-- - • i-^ ™- —:rj •.'•"•"•» "AW *W* IT! W. .U WUl <feCt>*<A> NOl 4».4« W SCl iT.O-a r*fr l CuLOLtlfflulQQ • LnffltOr^KOOO* •oiri .ii'. n Tft K ret* •«»««iWW^WI«»B"^ UBI IWIW—!<«** ~>|W' 11»V**«W W*p .—. , , i . .——, B _,—— —— _, zP

zfiSS

TJhO

*iN - =J"Si

?i- RV

« W

« j. *CD <t*

!>D C

a?

'»F

U.S. ENVIRONMENTAL PROTECTION AKNCT-CLP SMple Mmagtmnt OfficeP.O. Ben BIB, Alixindrli, VA 22313 - 703/997-2490

•» ORSANICS ANALYSIS DATA SHEET

Laboratory Hum Mead ConpuCheinLab Sw.li ID No. 35O7^

Duplicate T5uflN< spikeMultiply ill Values and Detection llnlti by 1

(Check Box

ACID CQiPDUUSS

PfjJ, CAM ug/hg

I21A) BB-06-2 2,4,6-trlcnlorophenol 400UI22A) 99-90-7 p-chloro-n-creiol ttttt-IWU(24A) 95-57-fl 2-chloroDhenol M8ir/W(3IA) 122-63-2 2,4-dlchlorophenol 400U(34AI 105-67-9 2,4-dlnethylphenol 400U(57A) BB-79-9 2-nlTrophanol BOOU(9BA) 100-02-7 4-nltrophenol MMteTfcCP(99A) 9I-6B-5 2.4-dlnltrophenol 2000U(60M 934-32-1 4,6-dlnltro-2-mthylphenol BOOu(64AI B7-36-5 pentachlorophenol 6Mv£C&(65A) 108-95-2 ptienol W*B/£PD

(Non-Priority Pollutant Hizardoui Substances)

,1 69-65-0 benzole acid 4000:95-46-7 2-netnyl phenol 400:10B-39-4 4-Mthyl phenol 400U93-95-4 2,4,9-trlchlorophenol 4000U

BASE-NEUTRAL CDf OUIfflS

( IB) B3-32-9 icenaphthene AMilSÔ( 9B) 92-B7-5 benzldlne 1600uI BB) 120-B2-1 1,2,4-trlchlorooanzene 4*e»SIPP( 9fi) 116-74-1 hexachlorobenzene 400U(12B) 67-72-1 heitachloroetnane 400U(1BB) 111-44-4 bl»(2-chloroathyl)etner 40DU(203) 91-9B-7 2-chloronapnthtlane 400U(25B) 95-90-1 1,2-dlcnlorobenzene 400U(26B) 941-73-1 1.3-dlchlorobenzene 400u(27B) 106-46-7 1.4-dlchlorobenzane ttteKW(23E) 91-94-1 3.3'-dlehlorobenzldlno BOOU(35B) 121-14-2 2.4-dlnltrotoluene MelM?1363) 606-20-2 2.6-dlnltrotoluane' BOOu

• l,2-dlpnanylhydr»lne(376) 122-66-7 (as azobenzene) BOOU1396) 206-44-0 fluoranthent 400u(403) 7005-72-3 4-chlorophenyl phenylather 400U(4IB) 101-95-3 4-brcnopheny 1 phenyl ether 400U

Senple Number

LOW LEVEL SOLID- Page 1

Gate Number ' ' TOC Rtport No. [ Jp"— 2.7

POT loQorJU ____for Approprlita Factor)

BASE/NEUTRAL COtfOUNDS

ffl CA5« ug/ng

(42B) 3963B-32-9 bli-(2-chloroliopropyl)ether BOOU(43BI 11—91-1 bli-(2-chloroethoiiy)n<TnDne BOOU(92B) B7-6B-3 hexgchlorobutadlene(33B) 77-47-4 hexechlorocyclopentedlene(94B) 76-59-1 llootiorone(99BI 91-20-3 nephthalene(36B) 96-95-3 nitrobenzene(62B) 66-30-6 N-nltroiodlphenylemlne(63B) 621-64-7 N-nltroiodl-n-propylinlneI66B) 117-61-7 bl>(2-ethylhe>yl)pnthBlate(67B) 63-66-7 butyl beniyl phthalete(66BI B4-74-2 .dl-n-butyl phthaleti(69B) 117-64-0 dl-n-octyl pnthalate(7031 64-66-2 dlethyl pnthalBte(71B) 131-11-3 dlMthyl pnthelate(723) 96-35-3 benzole lanthracene(733) 90-33-6 benzolalpyrene(74B) 205-99-2 benzolbH luoranthene(79B) 207-06-9 benzoUM luoranthene(763) 316-01-9 chrviene(7731 20B-96-6 acenephthylene(7BB) 120-12-7 anthracene(7931 161-24-2 b*nzo(gnl)perylar.e(BOB) 66-73-7 fluorene(813) B5-01-B -pnenahthrine(B2B) 53-70-3 dlbenzola.hlanthracene(633) 163-39-3 lndenoll,2,3-cd)pyrene(B4B) 129-00-0 pyrene

400U400:'400.40011400.'400.MM; fitt't'400U400:HXrSPOO4M»J?Per400:'400.400:600:'600.BOOU•««. ytoc400:400uBOO:400:400.'BOO:BOOU«*toJ26()P

(Non-Priority Pollutant Hazardous SuPltancii)

62-93-3 aniline 400'.100-31-6 benzyl alcohol106-47-0 4-chloroanlllne132-64-9 dlbenzofurah91-97-6 2-Mthy (naphthalene66-74-4 2-nltroanlllni99-09-2 3-nltroenll ln§100-01-6 4»nltro«nl line

BO:.2000.403.BOOJ4000:4009.4000.

017840

MSANICS AHALTS1S DATA SHEET • F«ge 3

Lib Km; n>te6d CompuChmiLib S«p1e 1.0, No.

Sample Spike

A. SURROOATE SPIKE RESULTS

COMPOUND

2-Fluorophenol

Ptntifluorophenol

,.- - •

1 ' PS-Nitrobenzene

Deufloroblphenyl

t>FlMorob1phci\yl

2-FluoroinU1ne

-

•

FRACTION

5EHIVOA

SEMIVOA

SEHIVOA

SEMIVOA

SEHIVOA

SEMIVOA

•

CONC (us/kg)

34-00

«9i?oo

tco

/POO

4&OG

35QV

,|Surroj«tes only)SpUe

Added (ug/kg)5000

5000

5000

5000

5000

5000

IRecovery&8-

%

1B-

3&

<?2-

7o

017841

I? sinu

i '.

rv

9 9p)17842

so

BASE-NEUTRAL I ACID DUPLICATE ANALYSIS

L«b Name-Mead CompuChemQ' ~*smp1e No. Or1g. No. EPA No. QC ReportAssociated Samples 3 API , 32.34 Case No.

PPf Compounds . • QC Sample Results Original Sample Results Relative XDifference

2-flMOrophenol ____ gfrOQ. £800 II

decafluoroblphenyl ____/ fOO StfOO(22A) p-chloro-m-cresol /JPO(24A) 2-chlorophenol ___( 4) 4-n1trophenol ?H9 IOP0Q(64A) pentachlorophenol t_____(65A) phenol __( IB) iceniphthene __( BB) 1,2,4-trlchlorobenzene _(27B) 1,4-dlchlorobenzene __

pentafluorophenol a POP 1200 73. ds-n1trobenzene if1) 002-fluorob1phenyl IfbOQ .^feogi 02-flMoroan1l1ne

(35B) 2,4-djnltrotoluene 17 0 1900 __._(63B) N-n1trosod1-n-propylam1ne(6BB) d1-n-butyl phthalnte(69B) d1-n-octyl phthalate(76B) chpy*«ne •(B4B) pyrene

rs

CB

8

I 1

Olio•• (Jo

m -SJ

-tj >5i73

<*>.•*•

-

-r'iz

017844'9

S 5M"

ae,\ )s

LOSi

•• r

8'

"S3

8'iR

I'

1

-•i»i) a

/

U)

017845

FK£ja4S 8ft® rF>5

•vl-aWl

•2 S*•

u-,i

01784

W'

PROCEDURE: RK DIAONOSTIC REPORT 6/S1/B3 16: 89: S<?DATA FILE: GR003207A14RE^RENCE: FSCC6

1 £THOD: FSCC6 INITIALIZATION OPTION: 2 PROCESSING OPTION: 3REPORT: FSCC6SI

< —— STANDARDS ——— >< —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN

4 4 2 33 65 24 B 153 FSCC6S1/FSCC6U122 4 160 15 B 2 114 FSCC6S2/FBCC6U2

79 COMPOUNDS PROCESSED, 31 FOUND

< COMPOUND' x —————— SEARCH —————— x SAT x ——— CHRO ——— >NO LIB ENTRY REF PRED SEL DELTA PEAKS FIT PEAKS M/E TOP DELTA PEAKSi F2 1 -1003 1804 1804 . 1 9<?6 , 136 1004 . 12 F3 1 -1648 ib38 1638 . 1 996 IBS 1638 , 13 Fl 1 -738 737 737 . i 955 , 97 737 . , 14 Fl S0 -1237 1236 1236 . 2 993 -l~Wi7S 1236 . 15 Fl 2 -183 184 , . , , . 74 .•6 Fl 3 -739 739 737 -2 i 996 . 94 737 , 17. Fl 4 -732 732 . . , , 93 735 1B Fi 5 -732 732 , , . 93 735 19 Fl 6 -721 7S1 720 -1 1 999 . 128 719 -1 1

10 Fl 7 -740 740 , . , 14611 Fl 8 -754 754 753 -1 1 1800 . 146 753 . 112 Fl 9 -789 7B9 , , , , 14613 Fi 10 -812 B12 . . , , , 108 813 . 2J" Fl 11 -B41 640 . , , , , 1 2 1 , . ,; 1 Fl 12 -B50 849 . , , , 10816 Fl 13 -847 846 . . , , . 117 . • ,17 Fl 14 -882 BB1 , , , 10818 Fi 15 -502 502 502 . 1 995 , 112 502 , 119 Fl 16 -768 768 769 1 i 993 . 184 769 , 120 Fl 17 -876 B75 877 S 1 990 ,82 877 , 121 Fl 18 -954 953 954 1 1 990 , 334 954 , 122 Fl 19 -672 672 671 -1 1 1000 , 111 671 . 123 F2 2 -871 870 874 4 2 9B9 1 130 873 -1 284 F2 3 -879 B7B . , , , 12325 F2 4 -935 934 . , , , 82 931 126 F2 5 -942 941 . . . . 13927 F2 6 -980 979 , , , 12228 F2 "7 -994 993 . , . , , 9329 F2 B -994 993 , , . , 16230 F2 9 -1001 1808 1000 . 1 999 .180 1000 , 131 F2 10 -100B 1007 1E732 F2 11 -1067 1066 10533 F2 12 -1055 1054 22534 F2 13 71156 1155 1155 , 1 1800 , 107 11S55 , 133 F2 14.-1147 1146 11536 F2 15 -1196 1195 23737 F2 16 -1220 1219 19638 F2 17 -1S41 1240 16239 F2 IB -1320 131B 15240 F2 19 -1342 1340 163 1338 , 1/ F2 20 -108B 1007 1HB 1006 •, 1vr' F2 21 -1349 1347 16543 F2 22 -1422 1420 1419 -1 1 991 ,44 F2 23 -1369 1367 . . . , ,45 F2 24 -12S9 1288 , , , , , 138 • ,46 F2 25 -1393 1391 . , , , , 168 .,47 F2 26 -1497 1495 , , . , , 1 3 8 , ' ™«n PQ en _1 )«1 1 3OT 1OOO 1 I O7A 1OA

V F3 2 -1560 1SS8 1356 , 1 997 154 135B , 130 F3 3 -1391 1389 18451 F3 4 -1429 1427 1427 . 1 985 , 1 3 9 1427 . 152 F3 5 -1460 145B , . , , , 16653 F3 6 -1475 1473 204?4 F3 7 -1487 14B3 1482 -3 1 997 , 149 14B2 , 1•'"""* F3 8 -1501 1499 1496 -3 1 964 . 198 1494 -2 156 F3 9 -1504 1502 , . . , , ' 169 ,5 7 F 3 1 8 -1568 1566 , . . . . 2 4 8 , . ,S B F 3 1 1 -1583 1581 . . . . . 2 8 4 . . .5 9 F 3 1 2 -1643 1643 . . . . . 1 7 8 1642 . 160 F3 13 -1653 1651 . . . . , 1 7 8 1650 . 161 F3 1't -1879 1B76 202 1876 . 162 F3 18 -1920 1917 1919 2 1 995 -1 202 1919 . 16 3 F 3 1 6 -1505 1503 . . . . . 7 7 . . .64 F3 17 -1812 1809 1811 2 1 995 , 149 1811 . 165 F3 18 -1627 1625 1625 . 1 1800 . 266 1625 . 166 F4 1 -2167 2166 2167 1 4 996 . 240 2166 -1 16 7 F 4 2 -2164 2163 . . . . . 2 2 8 . . .68 F4 3 -2172 2171 2172 1 1 999 , 2 2 8 2172 . 16 9 F 4 4 -2190 2189 . . . . . 2 5 2 , , .78 F4 5 -2103 2102 149 2102 . 171 F4 6 -2236 2235 149 2235 . 172 F4 7 -2354 2352 2353 1 1 996 , 149 2353 . 17 3 F 4 B -1917 1916 , , . . . 1 8 4 . . .74 F4 9 -2417 2415 2415 , 1 968 . 2 5 2 2414 -1 175 F4 10 -2592 2590 276 2590 . 176 F4 U -2600 2598 2598 , 1 968 , 2 7 8 2598 . 177 F4 12 -2627 2625 . . . . 276 S624 , 17B F4 13 -2363 2363 2362 -1 2 972 , 252 2362 . 179 F4 14 -2370 236B 236B , 1 975 , 252 2367 -1 1

01,73 4 3

QUANTITATION REPORT FILE: GR003207A14

DATA: GR003207A14. TI86£51/83 14:46:00Si*' LE: 1UL *3207R l-(9052 IS) ON It 14SUBMITTED BY: »14 ANALYST: 659

AMOUNT»AREA * REF. AMNT/(REF..AREA)* RESP. FACT)RESP. FAC. FROM LIBRARY ENTRY

NO NAME1 *D3-PHENOL (INTERNAL STANDARD) (624)2 N-NITROSODIMETHYLAI1INE (441)3 PHENOL (618)4 ANILINE (473)5 BIS(2-CHLOROETHYL)ETHER (411)6 2-CHLOROPHENOL (601)7 1< 3-DICHLOROBENZENE (421)B 1.4-DXCHLOROBENZENE (422)9 1,2-DICHLOROBENZENE (428)10 BENZYL ALCOHOL (474)11 BIS(2-CHLOROISOPROPYL)ETHER (412)12 2-METHYLPHENOL (620)13 HEXACHLOROETHANE (436)14 4-METHYLPHENOL (622)15 2-FLUOROPHENOL (SURROGATE) (619)16 PENTAFLUOROPHENOL (SURROGATE) (6S3)17 OS-NITROBENZENE (SURROGATE) (447)IB DECAFLUOROBIPHENYL (SURROGATE) (470)JQ 2-FLUOROANILINE (SURROGATE) (472)i ) 2-FLUOROBIPHENYL (SURROGATE) (448)21 *08-NAPHTHALENE (INTERNAL STANDARD) (460)22 N-NITROSO-DI-N-PROPYLAMINE (442)23 NITROBENZENE (448)24 ISOPHORONE (43B)25 2-NITROPHENOL (686)26 2,4-DIMETHYLPHENOL (603)27 BIS(2-CHLOROETHOXY)METHANE (410)2B 2,4-DICHLOROPHENOL (602)29 1, 2, 4-TRICHLOROBENZENE (446)SO 4-CHLOROANILINE (475)31 BENZOIC ACID (625)32 HEXACfHLOROBUTADIENE (434)33 PrCHLORO-M-CRESOL (688)34 2-METHYLNAPHTHALENE (472)35 HEXACHLOROCYCLOPENTADIENE (435)36 2, 4, 6-TRICHLOROPHENOL (611)37 2-CHLORONAPHTHALENE (416)38 ACENAPHTHYLENE (482)39 DIMETHYLP.HTHALATE (425)40 NAPHTHALENE (439)41 2.6-DINITROTOLUENE (428)42 2i 4-DINITROTOLUENE (427)43 3-NITROANILINE1479)44 2-NITROANILINE1478)45 DIBENZOFURAN (476)«' 4-NITROANILINE(4BO)

017843

Ir

NO NAME47 2, 4, 5-TRICHLORQPHENOL (626)

r"~S #D10-PHENANTHRENE (INTERNAL STANDARD) (467)f9 ACENAPHTHENE (481)50 2. 4-DINITROPHENOL (685)51 4-NITROPHENOL (607)52 FLUORENE (432)53 4-CHLOROPHENYL PHENYL ETHER (417)54 DIETHYLPHTHALATE (424)55 4. 6-DINITRO-O-CRESOL (604)56 DIPHENYLAMINE (N-NITROSO) (443)57 4-BROMOPHENYL PHENYL ETHER (414)SB HEXACHLOROBENZENE (433)59 PHENANTHRENE (444)60 ANTHRACENE (483)61 FLUORANTHENE (431)62 PYRENE (445)63 1. 2-DIPHENYLHYDRAZINE (AZOBENZENE) (430)64 DI-N-BUTYLPHTHALATE (426)65 PENTACHLOROPHENOL (609)66 *D12-CHRYSENE (INTERNAL STANDARD) (459)67 BENZO! A) ANTHRACENE (485)68 CHRYSENE (418)69 3.3'-DICHLOROBENZIDINE (423)70 BUTYLBENZYLPHTHALATE (415)71 BIS(2-ETHYLHEXYL)PHTHALATE (413)72 DI-N-OCTYLPHTHALATE (429)73 BENZIDINE (404)

, ; BENZO (A)PYRENE (486},j INDENOd, 2, 3-Ci D) PYRENE (#437)76 DIBENZOtA, H> ANTHRACENE (419)77 BENZO (G, H, DPERYLENE (408)7B BENZO (B)FLUORANTHENE (407)79 BENZO (K)FLUORANTHENE (409)

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT1 97 737 9: 13 1 1. 800 A BV 470BB, 28, 800 NG 1. 272 NOT FOUND __, _ __3 94 737 9: 13 21 8. 734 A BV 122862. faST'MS NC4 93 735 9: 11 21 8, 732 A BV 611, 0, 239 NC 0, 025 93 735 9: 11 21 8, 732 A BV 611, 0. 539 NC e eg ——6 12B '719 8:59 21 8,716 A BV 103996, (5e. 137 NC S. 54/«Q7 NOT FOUND -T- ———————————— ~B 146 753 9: 25 21 8, 750 A BV 187033. f59, 225 NC 3, TS/g)9 NOT FOUND10 188 B13 10: 18 21 8, 810 A*BB 694, 8, 464 NG 0, 0311 NOT FOUND12 NOT FOUND U/G "'']'>13 NOT FOUND14 NOT FOUND15 112 502 6:16 21 8,500 A BV 1BB462, 83, 937 NC 5,3116 184 769 9:37 21 8.766 A BBfWP 34368. ?"' 4Br9BB NC 3.0617 82 877 1B:5B 21 8,874 A BV 371134. 121, B65 NC 7.72IB 334 954 11:55 21 8,930 ABB .155076, 45. 030 NC 2,83J" 111 671 8:23 21 8, 668 A BVWU'f WWrfc W Mh-*» NC 0,674 172 1236 15:27 21 1,231 ABB 602109,, l«8Hb07 NC

21 136 1004 12:33 21 1,880 A BV 144406. 20. 000 NC

NO M/E SCAN TIME REF RRT METH ARE A (HOHT) AMOUNT _____ '/.T_2S 130 873 10:35 21 0. B70 A*BB 1183B0, £gl9, 4-7 NO 'P.?.. NOT FOUNDi ^ 82 931 11: 36 21 8. 927 A BB 430. 0. 084 NC 0. 0125' NOT FOUND26 NOT FOUND27 NOT FOUND28 NOT FOUND __29 180 1000 12: 30 21 8. 996 A BB 132513. L53, 084 NC 3. 367538 NOT FOUND31 NOT FOUND32 NOT FOUND _33 107 1155 14: 26 21 i, 150 A BV 90964, (517952 NC 2. 0234 NOT FOUND35 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND39 163 1338 16: 43 21 1, 333 A BB 2240, 0, 398 NC 0, 0340 128 1006 12: 34 21 1. 002 A BB 725. 0. 088 NC 0. 0141 NOT FOUND _____________42 165 1419 17: 44 21 1, 413 A BB 7B9B4, (ga 057 NC 2. 73/<L>43 NOT FOUND —————————————44 NOT FOUND45 NOT FOUND46 NOT FOUND47 196 1228 15: 21 21 1. 223 A*BV 2025, 1, 436 NC 0, 0946 188 1638 20: 2B 48 1. 880 A BV 127261. 20. 0BC NC 1, S749 154 1358 16: 58 48 8, 829 A BB 235B94. i ZB. &P7 Nf. a. 7g/«S! t NOT FOUND ' • _____________51 139 1427 17: 58 4B 8. 871 A BV 199433. (236. 374 NC 14. 97 /c£)52 NOT FOUND ———— ' "^53 NOT FOUND54 149 1482 18: 31 48 8, 985 A VB 6135, 1, 192 NC 0, 0855 198 1494 IB: 48 4B 8. 912 A BB 395. 8. 732 NC 8. 0556 NOT FOUND57 NOT FOUND58 NOT FOUND59 178 1642 20: 31 48 1, 002 A BB 1301, 8, 182 NC 0, 0168 178 1650 20: 37 48 1. 007 A BB 683. 0. 119 NC 0. 0161 202 1876 23: 27 48 1. 145 A BB 1B41. 0. 559 NO 0. OS62 202 .919 23: 59 48 i. 172 A BV 35254B, £_-. 460 NC 3.63 NQT FOUND t _____________ _64 i49 IBii 22: 38 48 1, 106 A BB 466598, (50. 276 NG 3. lB_/«Tj63 266 1625 28: 19 48 8. 992 A BV 23779. Cg0. 117 NC 1, 27 /*O66 240 2166 27: 04 66 1. 080 A BV 174B54, 40, 000 NG _TS367 NOT FOUND ._68 228 2172 27: 09 66 1, 003 A BV 23294B. r79, 320 NC 5. OSf69 NOT FOUND78 149 2102 26: 16 66 8. 970 A BB 643. 0, 255 NC 0. 0271 149 2235 27: 56 66 1. 032 A VV 1760. 0. 471 NC 0, 0372 149 2353 29: 23 66 1, 086 A BB 417213. Qfi, 945 NC 4. 43 /73 NOT FOUND74 252 2414 30: 10 66 1, 114 A BV 2069. 0. 542 NC 0, 0375 276 2590 32: 22 66 1, 196 A BV 2711. 0. 905 NO 0. 06It 278 2598 32: 28 66 i, 199 A BB 2931. 0. 959 NC 0, 067 ..-'276 3624 32:48 66 1,211 ABB 3017. 1, 075 NG 0,07

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT78 252 2362 29:31 66 1, 090 A BV 2612, 0, 532 NC 0, 0379 232 2367 29:33 66 1, 093 A VB 2162. 0, 727 NG 0. 05

Nu RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R, FAC R. FAC(L) RATIO1 9:13 1, 80 1, 008 1, 00 28, 80 28, 00 1.800 1, 800 1, 002 2:17 0,162 50,00 0,2073 9:14 1, ee 0, 735 i, 80 38, 41 58, 80 8. 340 0, 443 0. 774 9:09 1, 00 0, 728 i. 01 0. 24 30, 00 0, 002 0. 354 0. 005 9:89 1, 08 0, 728 i, 81 8, 24 58. 80 0, 082 8. 354 0. 006 9:81 1, 80 0, 717 i, 80 40, 14 50, 00 0, 288 0, 359 0, 807 9:15 0, 736 SO, 00 0, 3428 9:25 1, 80 0, 750 1. 88 59, 23 58, 00 0, 518 8, 437 1, 189 9:32 0, 765 SB. 88 0, 36510 10:09 1. 08 0. 688 i. 88 8. 46 !30, 00 0. 002 0, 207 0, 0111 18:31 0, 837 56. 00 0, 12512 10:37' 0,646 50,00 0,30113 10:35 0, 643 50, 80 0, 20014 11:81 0.878 < 58.08 8,37315 6:16 1, 80 8, 508 1, 80 83, 94 58, 80 0, 522 0, 311 1, 6616 9:36 1,00 8,764 1.80 48,39 50,00 0,096 8.188 0,9717 10:57 1, 00 8, 672 1. 80 121. 86 38. 00 1, 028 0, 422 2. 44IB 11:35 1,08 0,949 1.80 45.83 58,00 8.430 0,477 0,9019 B: 24 1, 08 8, 669 1, 08 10. 65 58. 00 8, 077 8, 364 0, 2120 15:26 1,08 1,231 1,00 186.11 38,00 1,668 8.771 2,1621 12:34 1,88 1,888 1,80 20,80 28,00 1,080 1,880 1,0022 10:33 1,88 0,667 1.80 219,43 50,00 0,386 8,878 4,3923 10:59 8,675 58,80 0,19124 11:41 1.88 0,930 1,80 0,88 58,00 8,081 8/710 8.00, 11:46 8,937 SB, 80 8.283

... 12:15 0,975 50,00 0,321 |27 12:25 8, 989 50, 00 8, 384 '28 .12t 25 0, 969 58. 00 8. 29829 12:31 1. 88 8, 996 1, 88 53, 86 SB, 88 8, 367 0, 346 1, 0630 12:36 1, 083 249, 99 8, 83131 13:28 1, 862 249, 99 8. 10032 13:11 1,858 58,00 8, 22B33 14:27 1, 88 1, 150 1. 00 31. 95 58, 80 0, 252 8, 394 8, 6434 14:20 1, 141 58, 00 8, 36935 14:57 1,190 58,00 0,16636 15:15 1, 214 50, 80 8, 37637 15:31' 1,235 58. 00 0, 68736 16:30 1, 313 50, 00 8, 64839 1-: 46 1. 88 1. 333 1, 00 8, 48 58. 00 0. 006 8. 779 8, 0148 12:36 1, 80 1. 803 1, 88 0, 09 50, 00 0, 882 1. 143 0,0041 16:32 1, 342 58, 00 8, 15442 17:46 1, 88 1. 415 1, 88 43, 06 30, 08 8, 219 8, 254 0, 8643 17:07 i, 362 249, 99 0. 03544 16:07 . 1, 283 249, 99 0, 25145 17:25 1, 386 58, 00 8. 90446 18:43 1. 498 249. 99 8, 83647 15:21 i, 88 1, 222 i, 08 1, 44 249, 99 0, 001 0, 195 0. 0146 28:30 1, 88 1, 888 1, 88 28. 00 20. 00 1, 888 1, 888 1, 8049 17:80 1, 88 0, 629 1, 00 56, 78 50, 00 0. 741 . 0. 632 1, 1750 17:23 0, 646 249, 99 8, 05951 17:52 1, 80 0, 871 1. 08 236, 37 125. 00 0, 251 0, 133 1, 89....,/ 18:15 0.690 30,00 0,722 " ;..,y ;\'l

017852so ,

«"1r Tss56S7583968616263646566676B6978717273747376777879

> 4

18:2616:3516:4618:4819:3619:4728:3420:4823:2924:8816:4922:3920:2827:0527:8327:8927:2226:1727:5729:2523:5838:1332:2432:3832:5829:3429:37

1, 881,00

1. 001.881.801. 88

1.801. 881.00

1. 80

1,801.081, 88

1, 881, 801, 081, 801,801.80

0, 6990. 9070,9130.9170.9560.9651.8831.8881.1461.1718,9181.1058.9921, 0888,9991,0021,0118. 9781, 832i, 0B68,8651,1151,1961,2801,2121, 0911,094

1,88i, 88

i, 881,881, 881,08

i, 801, 081,88

1. 88

1, 881. 081. 00

1.881,881, 881, 881,88i, 00

J.0.

0.0.0.

50,

SO,20,40.

79.

0.0.69.

0.0.0.1,0,0,

1973

IB1226•46

281280

32

264795

549096085373

30,50,

249,30.38.se,se,se,50,50.so,50,se,48.se.50.so.50,se.se.

ISO.se.so,so,50,50.se,

00oe99000080808080800080808080000000000008800000000000

8. 8198.800

8, 8848, 0828.8861. 188

1.4678, 8751. 888

1.157

8, 8038. 8861.909

8. 0098.8128. 8138, 8148.8138. 810

0, 3290. 8090. 0850. 8740,2320, 3871. 1268, 9841, 1161, 8980, 6181,4580, 1861, 8881,1520. 7380, 0440.3760, 8561, 3650, 0040, 6740, 6660, 6990, 6421,2100, 681

0. 028, 00

0, 000, 000.011, 01

1.010, 401, 00

1,59

0.010.01' ' . 40

i. '010. 020. 028. 828,818, 01

017853

011

8-

8-

a-

8"

81

i-

S-

1 -i8"

r 'J

•M •-

••••m «

•i•• "

_•

m•__, ^

i*

•

*

V4

1,

•-

,

"* ,— i — i — , — , | . . . . i . • • • i i/uG !,;"''/ ' '

w ' «

^

r* »—

SSîCD (S 5gafs

ss*

8

-JsHS

a

"1 <_ O> * «

8-

S'

£'

sH

_i3'5<v + *f\LOkD

Sr

1

A*

3mPS

^s<j":^

jmoN!»•• X.

r" f " j i s *w " >.' 1.1 v/ v " JnS Oi7855*

9f

oa

m w5 1

8-i

8-

W Ul _) SI I , . . . I , 1 , 1 , , _ _ I

8 , ___________

.v „ 0

g*

SiOf

-a 2m v s_

»

? g 8 *1 igrn • • • •. > «u W C9 CD PM' I i i , , I , _.__I,__. , , _I

_>»Si_hjiSWv

S

i'5S_.

RS"W

2 a g ft „m CB 0 ki ui . . . . i _.._. . . . , i , . , , i

6-

8-

.„./

iI3E

a

!=?

s

0178GO

a g £ go> 0 In r<

^ ^ Mffri*"''

] a i

J-88§tl_

"'rriWS

S U',.,U.« . en 5

P Ofteej' i.

? s! §nl V V<B si to n

1 i . . . 1 . , , . ! . , . . !

8-EU

'~*&!

Scott Ito •• 'g§8i

rJ*Kv9

s-1 -I S

£?8rn.3

1 ^5

8 P £ ffiBJ Si CO rJI , ... I . , . . I . • V.....J.. I

sH

8

rn:

,- * jm«_!£§LO-,_Q *•UliUIfo>sI— IU1V

s•*z

imS

ICi2IIZ

32rpa

P| *5 "v"SB

8-

CDjpm

J\17864r .*! 7 I I N

„30

£Si

8

r

ui OJ I.TI nwW" =j

E

4>MiCO

ScOJ

S.?•ym

Ss

2

i-

W

a?•jJrn

CGOCa r'jjj*'________ M S <-.

S 017865

0) di 001 , , , ,

8-

CD.-I

8-

-Ja

t A (ijl

|i

-E?

| 8c p 5i7867

m w m

-

8-

„

CO Jjl

§1

§

B?i-m

E—, " o%& •*

c§ (L

so " 017863

8*"

•• cn "•a°

O1 A (_

01 Cfl p-

51 •

ffB-iue

SS"

NU1

8s„

^

Sri

l^^wCO.

pH

8Sg"

tpii4kS

m. g

g 8 g S g J3i i i ? i i i T i i i i"" "

r *' .

255 io!ncncn• f

H. i_<PJ3 _!yini 01ig W _)

•

p-lF

* *

cnioui• *

1_ r-Strsi l-. . CdUlCSi -vlSol ^

" >i^ •

SN*S)*>-|SJ

CT| 10Si J* M)• • gi

'i-Ul

ffl V

CoMih-4k

Sfis

IJ

• >->

SIC?

SCO" _>-to C3

•-.V

Hl/i

*• L3 I- <D —' CT|§ ? ft P

•n ui is TO

V •••

^>, o

s. 'C

Is

.r-... Hw I, ./, j O

30 c.

5 « 8 Is S !I l.,J_y

?S-" "'-"300

w

si mooi CO 4k

M Cl

i-S>01

Wl

S-

S Ui f-

sss?sco enffl h J ••09 is

»o s3Is I,-HrOmVK£o-J3C

|

1

X-E

a-J

_

£"c&

en "iCO

STB-J&*

gH

4 on:OUH

lasa?s

y s 8 a g tî-t . 5 • ui • 161 ° I T I I I ? I I I f .....' I I T

-1

V V1)011>i 0? t_5 ra J

-sj Q

rowFH

Si0

*w>i-U"

m vwo

iCD

s Is * «8 i Ip g1 ii » S3 * il ^ Sooi7872

r

"017873

S 8 F- -

wi

f y _s

CJ1

,fI s

^ •1--"

. - -*8l_s? WK!

Itti ray

I on-..

s s

00 IMJ ffl

a\

UJ-NJ_

SS"

S®"

II-Sen

O

»—<

s~ —

'"" 1

CO S

,

U1 i!D

01

73

aw pp a ?^ a p? a 8oSi Ml P 1* ^ ig ?CO

2'•' 'N

_l-

CO £l _•• m

oo tr\•• ooC*l CDCO

00 "*J

-1

ipjjj

.. fcr-

-tl/l

p>

pp ••

^CQr*

r^l PZ £ LO

s.

U

g«n

KILoro-J H Ecsi-\<rO ^ SCEiCBi- kcOO>M 4k

^8. §Km

s • JJ ..'.? _^JS>SHaim

eg co•• N* —•»_ c01

(SCO••4kCOO K5gg

»-U3« M'wci

0-.U)£ O H*.0 U) N't

CO — 1CutcouJlhJCO

Egfflo,

s

i E'

I"!

r,

ax-

I

af... N

HUJ g Prw r r ^ j u s i S

* $ g i c& t— gi eno U> "« " t- * ikI i i T i i i T I i i i i i i i

COCki* +

G

BEft*

NIH>IfkUl

&(

en

.JIB.

°'*g-5i<r

V

£

_iin r.) c p r ^ c s i C D * - c n c o — i c oS i M " ' S . « > 3

Sz en S f f i ? 1 SWP S S S S "

B

. Si'

9

TltO_

B

^

5 £ 5 s S P3 JP - u , , , ?, | f i i i i • I ' ' - '

r*

£CO

-S fi *? 2IS ^ 88 * 017873

ido

coco

S"SS«ffp-la<

S?2'CD

Wl

'•,. .v

s ._-—— f- g-

s

H-

Isft*

' IB23 S! 1 017880

S£ K 9g P SK f -C S"

» c. g c s 5 I— » • . ( S 3 , . T i i

•"S I I I I

'S-

-

kLCi_ .aiigss£

SiSi

II P il P K p i§

F.

2

DAT*' CR003207A14, TI06,' 1/83 14:46:00SAMPLE: 1UL «3207R +(9652 IS) ON *14SUBMITTED BY: »14 ANALYST: 659

AMOUNT-AREA * REF, AMNT/CREF. AREA)*'RESP. FACT)RESP. FAC. FROM LIBRARY ENTRY

15 RIC 413 5:10 2 4. 747 A BB 52318, 0, 010 0,0116 RIC 439 S: 29 25, 046 A BB 33346, 0. 007 0. 0117 RIC S02 6:16 2 5. 770 A BB 668301, 0, 133 0, 10IB RIC 642 8:01 27. 379 A BB 8800, 0, 002 0, 001 I RIC 666 8:19 2 7, 655 A BV 87914, 0. 018 0. 0120 RIC 671 8:23 2 7, 713 A VV 133932, 0, 6E7 0, OS21 RIC 694 B: 40 27, 977 A VV 170355. 0. 034 0.0322 RIC 699 8:44 2 B, 034 A VV 115302, 0, 023 0, 0223 RIC 707 B: 50 2 8. 126 A VV 1365B4. 0. 0E7 0,0224 RIC 720 9:00 2 B, 276 A VB 407858, 0, 0B1 0, 0625 RIC 737 9:13 28, 471 A BV 469988, 0, 094 0.0726 RIC 753 9:25 2 8, 6S5 A VV 75B503, 0. 151 0, 1227 RIC 769 9:37 2 B, B39 A BV 185097, 0. 037 0, 0328 RIC 786 9:49 29, 034 A VB 292550, 0. 058 0,0429 RIC 874 10:55 2 10, 046 A BB 2B93130, 0, STB 0, 4430 RIC 930 11:37 2 10, 690 A BB 45908, 0. 009 0,0131 RIC 954 11:55 2 10, 966 A BB 797085. 0. 159 0,1232 RIC 1000 12:30 2 11, 494 A BV 1036290, 0, 207 0,1633 RIC 1019 12:44 2 11, 713 A VB 26353, 0, 005 0,0034 RIC 1144 14,' 18 2 13, 149 A BB 8062, 0, 002 0,0035 RIC 1155 14:26 2 13, 276 A 88 42B229, 0. 086 0,0736 RIC 1236 15:27 2 14. 207 A BV 2083160. 0, 416 0,3237 RIC 1276 15:57 2 14, 667 A BB 64B6, 0. 001 0,0038 RIC 1358 16:58 2 15, 609 A BB 984776, 0. 197 0, 1539 RIC 1382 17:16 2 15, 885 A 88 6274, 0, 001 0, 0040 RIC 1419 17:44 2 16, 310 A BV 495B28. 0. 099 0, 0841 RIC 1427 17:50 2 16, 402 A VB B96248. 0. 179 0, 1442 RIC 1445 IB: 04 2 16, 609 A BB 5340, 0.001 0, 0043 RIC 1451 IS: 08 2 16, 67B A BB 5277, 0, 001 0, 0044 RIC 1466 18:19 2 16, 851 A BB 5178, 0,001 0, 004f RIC 1483 IB: 32 2 17, 046 A VB 25120, 0. 005 0, 00

, 4 ... V RIC 1531 19: OB 2 17, 598 A BB 3290. 0. 081 0, 00

NO rVE SCAN TIME RSF RRT METH AREA(HCHT) AMOUNT '/.TOT"~ ..RIC 1555 19:86 2 17. 874 A VB 5979. 0. 001 0, 00

Wr i57B j .43 2 18, 136 A BV 7665, 0, 002 0, 001625 20:19 2 16, 678 A BV 23§2A§, " ~ ~~ " ~"

50 RIC 163B 20:28 2 IB. 82B A VB J £-_3614 -,-_.51 RIC 1749 21:152 2 20. 103 A 66 17335, 0, 003 0, 00

- - - - — — „ „„ oti A OD P7_S1A. 0.175 ' 0.13

41 RIC 1576 19:43 2 16, 136 A 6V 7665, e, BWB ., w«49 RIC 1625 20:19 2 16, 676 A 6V 23J2_8, 0, 048 0, 04— —— 163B 20:28 2 IB, 828 A VB 3 £-_3614bj e, 067 0. OS-

1749 21:152 2 20, 103 A 66 1733S,1811 22:36 2 20, 816 A 86 874516,

53 RIC 1904 23:46 221,885 A 6V 12250.. „,—— _. ...— DTP 1010 sa,B9 222.057 AW S7B700, 0.176 0.13

52 RIC 1811 22:36 S 20. 616 A 86 874516, 0, 175S3 RIC 1904 23:46 S 21. 885 A 6V 12250. . 0, 002 0. 0054 RIC 1919 23:59 2 22. 057 A VV 678700, 0, 176 0. 1355 RIC 1956 24:27 S 22. 463 A BB 17464. 0, 003 • 0, 0056 RIC 1970 24:37 2 22. 644 A 6V 19964. 0, 004 0, 0057 RIC 2075 25:56 2 23, 851 A BB 5855. 0, 001 0. 00SB RIC 2094 26:10 2 24, 069 A BV 6640. 0, 001 0. 0059 RIC 2113 26:25 2 24, 267 A 66 17376, 0, 003 0. 0060 RIC 2137 26:43 2 24, 563 A 66 21091, 0, 004 0. 0061 RIC 2167 27:05 2 24. 906 A 6V 761080. 0, 152 0. 1262 RIC 2172 27:09 2 24. 966 A VB 537064, 0, 107 0, 0863 RIC 2230 27:52 2 25, 632 A BV 6501. 0. 002 0. 0064 RIC 2236 27:57 2 25. 701 A VB 7144. 0, 001 0, 00.- R-P sane za, w a at. 494 ABB 6760, 0.001 0.00

15 n0178Q3

^ ^ HM*n**"'

s-

g-

N>

J

coa: n S5Swa 3 i*!** R^ - -

rto- ,csT I

2' !°

enwiw KV TI(*« *I :_ -~•"*-•• • • -»-™--

S,

1i.. IB-S

— .* AOOJCOlTlX

at *•

I/I

S

x>Em

corhN.1 ••

His

U.S. ENVIRONMENTAL PROTECTION AGENCY-CLP Sample Management OfficeP.,0. flox BIB, Alexandria, VA 22313 - 703/557-2490

LOH LEVEL SOLID'ORGAN ICS ANALYSIS DATA SHEET - Page I

Laboratory Name Mend CompuChem____ _______ Case NumberLab Sample ID No. Blank .319(4.associated sa

Multl

A

PPI CAS<

(21A) B6-06-2(22A)124A)(3IA)(34 A)(57A)(5BA)(59A)(60A)(64A)(6DA)

59-50-795-57-fl122-B3-2105-67-9BB-75-5100-02-75I-8B-5534-52-187-36-5108-95-2

.mples 2*3,0 1 . i:j_ifPC Report No iSfe-SS"

ply all Values on'd Defection limits by 1 J_J or 10 LJ or jj ____(Check Box tor Appropriate Factor)

CID COMPOUNDS BASE/NEUTRAL COMPOUNDS

ug/kg PPf CA5«

2,4,6-trkhlorophenol 400U (42BI 3963B-32-9 bls-(2-chlorolsopropyl latherp-chloro-m-cresol2-chlorophenol2.4-dlchloropnenol2,4-dlmethylphenol2-nltrophenol4-nltrophenol2.4-dlnltrophenol4 ,6-d 1 n 1 tro-2-methy 1 pheno 1pentachloropnenolphenol

(Non-Priority Pollutant Hazardous Substances)

i 65-B5-0 benzole acid

1 IB)( SB)( BB)( 9B)(12BI(16B)(20B)(25B)(26B)(27B)(26B)(35B)(36B)

(37B)(39B)(40B)(41B)

95-46-7IOB-39-495-95-4

2-metnylphenol4-methyl phenol2.4, 5-tr 1 ch 1 oropheno 1

BA5E-HEUTRAL COMPOUNDS

63-32-9 aconaptithene92-B7-5120-82-1118-74-167-72-11)1-44-491-5B-795-50-1541-73-1106-46-791-94-1121-14-2606-20-2

122-66-7206-44-07005-72-3101-55-3

benzldlne1 ,2,4-trlctilorobanzenehoxachlorobenzanehexBChloroethanebls(2-chloroethyl)ether2-ch loronaphthfll one1 ,2-dlchlorobenzene1 r3-dlchlorobenzene1,4-dlchlorobenzene3.3>-dlchlorolianzldlha2.4-dlnltrotoluene2.6-dlnltrotoluene1,2-dlphenylhydrazlne(as azobenzene)f 1 uorenthana4"Chlorophenyl phenylethar4-bromopneny 1 phenyl ether

400U400U400U400UBOOU4000U2000UBOOUBOOU400U

4000U4DOU400U4000U

400U1600U400U400U400U400U400U400U400U400UBOOUBOOUBOOU

BOOU400U400U400U

I43BII52B)(53B)(54B)(55B)(56B)(62B)(63B)(66B)I67B)(6BB)(69B)(70B)(71B)(72B)(73B)(74BI(75B)(76B)(77B)(76B)(79B)(BOB)(BIB)(B2B)(63B)(B4B)

11—91-1B7-6B-377-47-478-59- 191-20-398-95-366-30-6621-64-7117-81-785-68-784-74-2117-84-064-66-2131-11-356-55-350-33-B205-99-2207-OB-9316-01-92QB-96-6120-12-7IBI-24-2B6-73-785-01-853-70-3163-39-5129-00-0

(Non-Priority

62-53-3100-51-6106-47-6132-64-991-57-6B8-74-499-09-2100-01-6

bls-(2-chloroethoxylmetnanohexach 1 orobutad 1 onehexach 1 orocyc 1 opontad 1 oneIsoohoronenaphthalenenitrobenzeneN-n 1 trosod 1 phony 1 ami neN-nltrosodl-n-propy lamlnebl s (2-ethy 1 hexy 1 Iphthfll atebutyl benzyl pntnalatedl-n-butyl phthalBtedl-n-octyl phthalBtedl ethyl phthalatedimethyl phthalatebenzota Janthracenebenzole Ipyrenebanzo(b)f luoranthenebenzolklf luorantheneohryseneacenaohthyleneanthracenebenzotqhl Jpervlenef luorenephenanthrenedlbenzota.hlanthraceneIndenof 1 ,2,3-cd}pvrenepyrenfl

ug/kg

eoouBOOU400U400U400U400U400U400Ueoou400U400U400U400U400U400U400UBOOUBOOUeoou4QOU400U400UBOOU400U400UBOOUBOOU400U

Pollutant Hazardous Substances)

aniline 400Ubenzyl alcohol4-chloroBnlllnedlbenzofursn2-mathyl naphtha lane2-nltroenlllne3-nltroanlllne4-nltroanl 1 Ine

BOOU2000U400UBOOU4000U4000U4000U

ORGAN1CS ANALYSIS DATA SHEET - Page 3

Lab Name! tHe.d CompuChem

Lab Sample I«D. No.Blank

A, SURROGATE SPIKE RESULTS

COMPOUND

2-Fluorophenol

Pentafluorophenol

D5-N1trobenzene

Decaf loroblphenyl

2-Fluorob1phenyl

2-F1uoroan1Hne

•

FRACTION

SEHIVOA

SEHIVOA

SEHIVOA

SEHIVOA

SEHIVOA

SEHIVOA

CONC (ug/kg)

/?$£>

900

S&oe

&£>0D

34-00

Zaoo

(Surrogates only)Spike

Added (ug/kg)

5000

5000

5000

5000

5000

5000

tRecovery

3k

V

_5£100

b%t>0

f 017.883i c,:;;,.;.T

90 !

•

o

n•>

S

K

03

t

n

M

8

en

inn1

01

/>

*

8

w

z

M

TlIAnt

H

•n8

0

T)

8•n8 3

•nq

i\8S:>

•nUlnn

•ni/)nn•n8

?o5(T\

•n|y)

m<

_im

m8*

SUl•»

ii

FRACTIOH 1

•o|t«H<

noaem."SIp

ECD

m1/1

i>

- =1 i

•nmo

IK

017887

MS"

___ ,.. F8.1u

i5 '

4)

TI ir:,ui O

P=——————————————————————gus

___________ u;i «~'""—"~ n" """ »-•

"""iTj f\

I I-B i

fn

f

_i'W__*r'OOIJ7883EJS

!i. • mG' Q ,;,;,

T1&Ifl C.'

3

.$§

?,

in

!DC~\IRE; RK DIAGNOSTIC REPORT 6/07/83 4:33. 11\TA KILE; CHQ03194C16•FERENCE: FSCC6METHOD: FSCC6 INITIALIZATION OPTION: g PROCESSIN6 OPTION: 3REPORT: FSCC6S

——— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >SRQC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN

4 4 1 98 79 21 1 IBS FSCC6S/FSCC6U


COMPOUND X ————————— SEARCH ————————— X SAT X ———— CHRP ————— 2MD LIB ENTRY REF PRED SEL DELTA PEAKS FIT PEAKS M/E TOP DELTA PEAKS1 Fl 1 -721 736 727 1 1 9BB .97 727 . I.S F3 1 -1523 1526 1525 . 1 703 106 1525 . 13 F2 1 -966 9fcB 967 -1 1 995 . 136 967 . 14 F4 1 -19BB 1990 1990 . 1 997 . 240 1990 , 15 F l 2 -247 2 1 9 . . . . . 7 1 . . .6 T! 3 -724 726 . . , . 94 727 17 F l « -72S 7 3 0 , . . . . 9 3 . . .B F l 5 -72B 7 3 0 . . . . . 9 3 . . .9 F J 6 -727 7 2 9 , . . . . 1 2 U10 Fl 7 -746 ' 74B , , . . 11611 Fl B -7D6 758 . . , , . Hi1/12 Fl 9 -7B5 7B7 . . . 116i: fl 10 -791 793 , . . , 10B14 Fl 11 -816 81B , . . 12115 Fl 12 -BIB 820 . . . . . 1 0 8 .16 Fl 13 -B34 836 . . . . 11717 Fl 11 -B43 845 . . . . 10CIB Fl 15 -588 590 . , . . , 112 . .19 Fl 16 -739 741 743 2 1 980 . 184 743 . 220 Fl 17 -B53 853 BSD . 1 99ti . 82 8Sb . 121 Fl IB -B99 901 901 , 1 997 331 901 . 122 Fl If -686 6BB 68B . 1 996 -1 111 688 . 123 Fl 20 -1160 1162 1165! , 1 983 -1 172 1162 I24 F2 2 -B40 842 842 . 1 922 . 1 3 02 5 F 2 3 -856 B 5 B . . . . . 1 3 3 . . ._6 F2 '4 -897 899 . , . . 82 899 J27 F-1 5 -909 911 , , . . 13?28 F2 6 -928 930 , , . . . IH2 .2 9 F 2 7 -943 9 4 5 . . . . . 9 3 . . .3 0 F 2 B -951 9 5 3 . . . . . 1 6 2 . . .V>.. fS *i -961 963 ... . . 1803 2 F 2 1 0 -995 9 9 7 . . . . . 1 2 7 , , ,3 3 F 2 1 1 -969 9 7 1 , . . . . 1 0 5 . . .34 F2 12 -1004 1006 , . , , . 22S , . .3 5 F 2 1 3 -10B2 1084 . . . . . 1 0 7 . . .36 F2 14 -10B8 1090 1092 2 1 903 . 1 1 537 F2 15 -1129 1131 . . . . . , 237 . - -.., . . .38 F2 16 -1147 1149 . , . , 196 v»,..,. ,(Jj39 F2 17 -1171 1173 , . . . 16'2 11744 / F 2 18-1242 1244 . . . . . 1 5 2 124541"" R2 19 -1245 1247 . , . . • . 163 1247 , 14 ? F 2 2 0 -969 9 7 1 . . . . . 1 2 8 9 7 0 . . )4 3 F 2 2 1 -1255 1257 . . . . . 1 6 5 . . .4 4 R 2 2 2 -1321 1323 . . . . . 16 ,45 F2 23 -1270 12BO . . , . 13B ps,

"

47 F2 25 -iau- UU3 . . . . ,-w .-.I B F 2 2 6 -1391 1393 . . . . . 1 3 8 . . .49 F2 27 -1153 1155 19650 F3 2 -1275 1277 1277 . 1 996 154 1277 . 15 1 F 3 3 -1311 1313 , , . . . 1 8 4 . . .5S -~,3 4 -1303 1305 . , ... 139 1307 , 153 3 5 -1363 1365 1366 1 1 933 . 166 1366 . 15 4 F 3 6 -1369 1371 , . . . . 2 0 4 , , .55 F3 7 -1369 1371 1370 -1 1 900 , 149 1370 , 15 6 F 3 8 -1390 1392 . , . . . 1 9 8 . . .57 F3 9 -1393 139B 1396 1 1 99S . 169 1396 . 158 F3 10 -1453 1455 . , . . 24859 F3 11 -1471 1473 28460 F3 12 -15?7 1539 . . , . 1 7 8 1529 , 16 1 F 3 1 3 -1534 1536 . . . . . 1 7 8 1539 . 16 2 F 3 1 4 -1735 1737 . . . . . 2 0 2 1738 . 163 • F3 15 -1772 1774 , 202 1775 , 164 F3 16 -1396 139B 77 1398 . 165 F3 17 -1654 1656 165S -1 1 924 , 149 1655 , 166 F3 IB -1534 1536 . . . . 26667 F4 2 -1985 19B7 1987 , 1 996 228 1983 1 16 8 F 4 3 -1992 1994 . . . . . 2 2 B 1994 . 16 9 F 4 4 -1996 1998 , , . . . 2 5 2 . . .70 F4 5 -1912 1914 1<?14 . 1 933 149 1914 . 171 F4 6 -2023 2025 20S4 -1 1 949 . 149 2024 . 172 F4 7 -2125 2127 2127 , 1 904 149 2127 . 17 3 F 4 8 -1769 1771 . . . . . 1 8 1 . . .74 F4 9 -2215 2217 2221 4 1 9_S . 252 2221 . 17 5 F 4 1 0 -2457 2459 . . . . . 2 7 676 F4 11 -2465 2467 / . . . 27877 T4 12 -2526 252S. . . . . 2767 8 F 4 1 3 -2164 2166 . . . . . 2 5 2 2168 . 17 5 F 4 1 4 -2168 2170 . . . . . 2 5 2 2160 . 2

JAN'-STATION REPORT FILE; GHQ03194C16

\TA; QH003194C16, TIj/07/83 3;06:001MPLE: 1,0 UL FBCC SAMPLE 3194+5UL*8B84~026JBMITTED BY: DWA«16 ANALYST: 602

1QUNT=AREA * REF. AMNT/(REF,AREA)* RESP. FACT)•SP, FAC. FROM LINEAR FIT TO WHOLE , RL

>IO NAME1 *624 D3-PHENOL (INTERNAL STANDARD)2 441 N-NITROSODIMETHYLArllNE3 610 PHENOL4 473 ANILINE5 411 BIS(2-CHLORQETHYL)ETHER6 601 2-CHLOROPHENOL7 421 1,3-DICHLQRQBENZENEB 422 1,4-DICHLOROBENZENE9 420 1,2-DICHLDRQBENZENE10 474 BENZYL ALCOHOL11 412 BIS(2~CHLQRQISOPRQPYL)ETHEK12 620 2-METHYLPHENOL13 436 HEXACHLOROETHANE14 622 4-METHYLPHENOL15 *619 ,2-FLUORQPHENOL' (SURROGATE STANDARD)16 #623 PENTAFLUDRQPHENOL (SURROGATE STANDARD.)1? H447 D5-N1TROBENZENE (SURROGATE? STANDARD) '18 «470 DECAFLUOROBIPHENYL (SURROGATE STANDARD)19 H472 2-FLUOROANILINE (SURROGATE STANDARD)20 H44B 2-FLUOROBIPHENYL (SURROGATE STANDARD)21 #460 DB-NAPHTHALENE (INTERNAL STANDARD)22 442 N-NITRQSD-DI-N-PROPYLAMINF.23 440 NITROBENZENE24 430 ISOPHORONE25 606 2-NITRQPHENOL26 603 2i4-DIMETHYLPHENOL27 410 BIS(2.-CHLORDETHOXY)METHAIC28 602 2,4-DICHLDROPHENDL29 446 '1,2,4-TRICHLQRDBENZENE30 475 4-CHLOROANILINE31 625 BENZOIC ACID32 434 HEXACHLOROBUTADIENF:33 608 P-CHLORD-M-CRESOL34 477 2-METHYLNAPHTHALENE35 . 435 HEXACHLOROCYCLOPENTADIENE36 611 2,4,6-TRICHLOROPHENOL37 416 2-CHLORQNAPHTHALENE38 402 ACENAPHTHYLENE39 425 DIMETHYLPHTHALATE40 439 NAPHTHALENE41 42B 2,6-DINITROTOLUENE I w f ''" V42 427 2i4-DlNITROTQLUENE ' ' '4' .479 3-NITROANILINH 01789241- 478 2-NITRDANILINE U4.i«"45 476 DIBENZOFURAN wfl46 480 1-NITROANILINE '

NO NAME47 626 2,4,5-TRICHLORDPHENOL48 *467 D10-PHENANTHRENE (INTERNAL STANDARD)49 401 ACENAPHTHENE50 605 2,4-DINITROPHENOL51 607 4-NITROPHENOL52 432 FLUORENE53 417 4-CHLQRQPHENYL PHENYL ETHER54 424 DIETHYLPHTHALATE55 604 4,6-DINITRQ-Q-CRESOL56 443 DIPHENYLAMINE57 414 4-BROMOPHENYL PHENYL ETHER58 433 HEXACHLOROBENZENE59 444 PHENANTHRENE60 403 ANTHRACENE61 431 FLUORANTHENE62 445 PYRFNE63 430 1,2-DlPHENYLHYDRAZINE (AZOBENZENE)64 426 DI-N-BUTYLPHTHALATE65 609 PENTACHLQROPHENDL66 #459 D12-CHRYSENE (INTERNAL STANDARD)67 400 BENZD(A)ANTHRACENE'68 41B CHRYSENE69 423 3,3'-DICHLOROBENZIDINE70 415 BUTYLBENYLPHTHALATE7' ,413 BIS(2-ETHYLHEXYL)PHTHALATE7t '429 DI-N-OCTYLPHTHALATE;73 404 BENZIDINE74 406 BENZO(A)PYRENE75 437 INDENO(1, ?,. 3-C, D)PYRENE76 419 DIBENZD(A,H1ANTHRACENG77 408 BENZO(G, H, DPERYLENC7B 407 BENZO(B)FLUORANTHENE79 409 BENZO(K)FLUORANTHENli

NO M/E SCAN TIME REF RRT METH AREA(HQHT) AMOUNT '/.TOT

017893U,.,,,),.!

3 M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOTI 97 727 9:05 1 1.000 A BV 37372. 20. 000 NG 3,52i1 NOT FOUND3 94 727 9:05 1 1.000 ABB 1700, 1, 201 N8 0, IPil NOT FOUND5 NOT FOUNDb NOT FOUND7 NOT FOUND3 NOT FOUND9 NOT FOUND0 NOT FOUND1 NOT FOUND2 NOT FOUND3 NOT FOUND4 NOT FOUND , ,, -j^5 NOT FOUND . «'6 184 743 9:17 1 1.022 A*BV 7997. 10. 115 NG 1.277 82 B55 10:41 1 1,176 A BV 311656. 138. 731 NC 17.488 334 901 11:16 1 1.237 ABB 160663. 254. 272 NG 32.049 111 68S 8:36 1 0,946 ABB 301459. 119. 348 NG 15.0410 172 1162 14:31 1 1. 59B A BV 3B7616. 148, 650 NG 18.73II 13i 967 12:05 21 1 000 A UV 66326 20.000 NG ' 2 52IK NOT FOUND.'3 NOT FOUND!4 B2 899 11:14 21 0.930 ABB 1963. 0, 706 NG 0. O1?!b 10T FOUND26 NOT FOUND27 NOT' FOUND28 NOT FOUND29 NOT FOUND30 NOT FOUND31 NOT FOUND32 NOT FOUND33 NOT FOUND34 NOT FOUND3S NOT FOUND36 NOT FOUND37 162 1174 14:40 El 1.214 ABB 750 0. 3DQ NG 0.0338 152 1245 15:34 El 1.287 A BB 123B. 0.331 N5 0.0139 163 1247 15:35 21 1.290 A 013 16Q6 0. 640 NG 0,0840 128 970 12:07 El 1.003 ABB 1941. 0. 462 NG 0.0641 NOT FOUND42 NOT FOUND«? NOT FOUND44 NOT FOUND45 168 1307 16:20 21 1.352 A BD 12B9. 0. 467 NG 0,0646 NOT FOUND47 NOT FOUND48 1BB 1525 19:04 4B 1.000 A BV 6B912. 20, 000 NG 2. 5C O49 154 1277 15:58 48 0.837 A BB 892 0.349 NG 0.01 -'50 NOT FOUND _««S'5) 139 1307 16; 20 48 0.057 ABB 801. 2. 03"9 NG 0. (__,_[ 7 OaSt5t l66 1366 17:04 48 0.896 ABB 953. 0. 347 NG 001 r'53 NOT FOUND ~54 149 1370 17:07 48 0.898 A BE 3157 0 BB1 NG 0.11 .55 NOT FOUND 056 169 1396 17:27 48 0 915 A BB 2088. 1.289 NG »0 ,9-16

ID7 NOT FOUND•B NOT FOUND•9 178 1529 19:07 48 1.003 A BB '' 2109, 0, 957 N8 0,07,0 17B 1539 19:14 4B 1.009 ABB 19S4. 0. 532 NG 0.07.1 202 1738 21:43 48 1.140 ABB 2466, 0, 649 NG 0,00,2 202 1775 22:11 48 1.164 ABE 2462. 0. 615 NG 0.08.3 77 1398 17:28 43 0.917 ABB 2535. 0. 997 NG 0.08,4 149 1695 20:41 48 1:085 ABB 8432. 1. 483 NG 0.18,5 NOT FOUND,6 240 1990 24:52 66 1.000 ABB BOSB4. 40. 000 NG 9.04,7 228 1988 24:51 66 0.999 A BV 3010. i. 034 NG 0.13>B 228 1994 24; 55 66 1,002 A VD 2544. 0. 980 NG 0.12M NOT FOUND'0 149 1914 23:55 66 0,962 ABB 1616. 0. 975 NC 0.12'1 149 2024 25:18 66 1 017 A BB 4040 1, IBS NG 0.19'2 149 2127 26:35 66 1.069 ABB 4534, 1. 165 NG 0.15'3 NOT FDUMD'4 252 2221' 27:46 66 1,116 ABB 1383. 1. 073 NG 0.14'5 NOT FOUND?6 NOT FOUND77 NOT FOUND '?B 252 2168 27:06 66 1. 009 A BV 2326. 0. 907 NG 0,11'9 252 2168 27; 06 66 1. OB9 A*BB 3790. 1. 700 NG 0.21

\IO 7ET(L) RATIO RRTIL) RATIO AMNT AMNT(L) R. FAC R.FAC(L) RATIO1 '9:03 1,00 1.000 1.00 20 00 20.00 1,000 1.000 ' 1.002 3:05 0.311 50.00 0.2373 9:03 1.00 1,000 1..00 1,20 50 00 0.025 1,034 0,024 9-Oei 1,006 ' 50.00 0.7065 9:06 l.OOc. DO. 00 0. 7B6t 9: 05 1. 00" SO 00 0, 7197 9: 19 1. 030 50. 00 0, 632B 9:27 1, 044 00. 00 0, 8209 9:49 1,084 50.00 0,69910 9; 53 1,093 SO. 00 0,36611 10'13 1.127 50.00 0.24"12 10; 13 1. 130 50. OCi 0. 60413 10:25 • 1. 152 50. 00 0, 35614 10:32 1,164 50.00 0, 6S315 7:21 0 78'V SO. 00 0. 48216 9:14 1,01 1,021 1.00 10.12 50.00 0.117 0. 57B 0.2017 10:40 1,00 1, 17B 1.00 130.73 5000 4,951 1.641 277IB 11:14 1.00 1.242 1.00 254. H7 50.00 2,34G 0.462 5.0919 8:34' 1.00 0. 94B 1,00 119.35 50 00 4.405 1, Bit. 2 3920 14:30 1.00 1,602 1.00 148. 68 50.00 5.665 1.905 2.9721 12:04 1,00 1,000 1,00 20.00 20.00 1,000 1.000 1.0022 10:30 0. 870 50,00 0.07823 10:42 0. 886 50. 00 0,20224 11:13 1 00 0,929 1.00 0.71 50.00 0.012 0.838 0.0125 11:22 0,941 50.00 0.175 _,,.«-26 11:36 0.961 0000 0315 01'7-p"027 ;i:47 0.976 5000 0.441 "'.,',,"3B"""ll:63 0. 9B4 SO. 00 0. H9129 12.01 0.995 50 00 0.32730 12:26 1.030 230.00 0.345 ty ,31 12:07 1.003 250. 00 0 17i '

s's SI"\

ae,

oa

e<C

I *-

I?

ffii Wot_____________I—————————————L

s- ":":

u>-u.i

i» SI

-IlS.E

.. '-' "o r,

.ili r,-8,?

01789;

Cl"&J

'.si-

B ra

C HiPjn•noI.JIQ

rn

ilO

i^ri " » S1f

OC1 JRE: RK DIAGNOSTIC REPORT 6/07/B3 4; 39.53JA FILE: GH003194C16IFERENCE: FSCC6METHOD: FSCC6 INITIALIZATION OPTION: 2 PROCESSING OPTION: 3REPORT: FSCC6S

——— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >'ROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN

4 4 1 9B 79 21 1 123 F5CC65/FSCC6U


COMPOUND X ————————— SEARCH ————————— X SAT X ———— CHRO ————— :>JO LIB ENTRY REF PRED SEL DELTA PEAKS FIT PEAKS M/E TOP DELTA PEAKS1 Fl 1 -724 726 727 1 1 98E . 97 727 . 12 F3 1 -1523 15J5 15.2S , 1 983 18B 1525 . 13 F2 1 -966 968 967 -1 1 995 . 136 967 .14 F1 1 -1988 1990 1990 . 1 997 , 240 1990 . 1f i n 2 -247 2-»9 . . . . . 7 4 . .6 F l 3 -724 7 2 6 . . . . . 9 4 7 2 V . 17 F l 4 -728 7 3 0 . . . . . 9 r ? . . .B F l 5 -728 7 3 0 . . . . . T O . .< 7 F ; 6 -727 .729 . . . . . 1 B U10 Fl 7 -746 71B . . . 146I! Fl B -7R6' 758 . . . . 14612 Fl 9 -7B5 767 . . • . . 14613 !\ 10 -791 793 . . . . . 10IJ14 Fl 11 -816 BIS . . . ' . 121I T , F l • I B -818 B S O . . . . . 10L< . . .16 Fl 13 -B3'i B26 . . . . 1JV.7 Fl 14 -B13 8<!5 . . . lOfi18 Fl 15 -58y bi'O . . . . llr!19 Fl 16 -739 741 74320 Fl 17 -853 8S5 8T/l>21 Fl 16 -899 901 90)22 Fl 19 -68n 6BB 6BK23 Fl CO -1160 1162 116221 FS 2 -BIO 812 BIS

980 , 181 743 , 2995 . 82 855 . 1997 . 334 901 . 1996 -1 111 6BB . 1983 -1 172 1162 . 19SiJ 130

2S F2 3 -B!)6 8?B . . . 1332 6 F 2 ' 4 -897 B i t . . . . B ? 8 9 9 . 12 7 F 2 « 5 -909 9 1 1 . . . . 13l? .PB F2 6 -928 930 . . . . . 1f!_ .29 F2 7 -913 915 . ' 9330 F2 H -951 953 . . . . . J6_ .: • ; f-i' 9 -961 9 6 3 , . . . I S O ,3 2 F 2 1 0 -995 9 9 7 . . . . . 1 2 V_ 3 F 2 1 1 -969 9 7 1 . . . . . 1 0 5 , , .3 1 F 2 1 2 -1001 1006 . . . . . 2 2 5 , , .3 5 F 2 1 3 -1082 1084 . . . . . 1 0 7 .36 F2 14 -1088 1090 1092 2 1 903 1153 7 F 2 1 5 -1129 1131 . . . . . 2 3 7 . . .3 8 F 2 1 6 -1147 1149 . . . . . 1 9 6 . . .39 F2 17 -1171 1173 . . ' . . 16*3 1174 . i40 -.'1-2 18 -1242 1244 . . . . 1 5 ? 1245 . 14 J l ' 2 19-1245 1247 . . . 1 6 3 1247 .<•"..•1 2 F 2 2 0 -969 9 7 1 . . . . . 1 2 3 9 7 04 3 F 2 2 1 -1255 1257 . . . . . 1 6 54 4 F 2 2 2 -1321 1323 . . . . . 1 6 345 F2 23 -1278 12BO . . . . 13B Sg .• - " - • • - - • " • " • ' nrn

• 8 F 2 2 6 -1391 1393 . . . . . 1 3 8 . .' • 9 F 2 2 7 -1193 1155 . . . . . 1 9 6 . . .>0 F3 S -1275 1277 ]277 . 1 996 . 194 1277 . 1' 1 F 3 3 -1311 1313 . . . . . 1 8 4 .) 2 F 3 4 -1303 1305 . . . . . 1 3 9 1307 . 153"~>3 5-1363 1369 1366 1 1 933 166 1366 . 1* 4 , - 3 6 -1369 1371 . . . . . 2 0 4 , .>S F3 7 -1369 1371 1370 -1 1 900 . 149 1370 . 15 6 F 3 8 -1390 1392 . . . . . 1 9 8 . . .57 F3 9 -1393 1395 1396 1 1 998 . 169 1396 . 15 8 F 3 1 0 -1453 1455 . . . . . 2 4 B . . .5 9 F 3 1 1 -1471 1473 , . . . . 2 8 4 . . .s O F 3 1 2 -1937 1529 . . . . . 1 7 8 1529 , 1s i F 3 1 3 -1534 1536 . . . . . 1 7 8 1539s2 F3 14 -1735 1737 ., . . , . 2 0 2 1738i3 F3 15 -1772 1774 202 1775s 4 F 3 1 6 -1396 1398 . . . . . 7 7 139B»5 F3 17 -1654 1656 1655 -1 1 924 . 149 1655j > 6 F 3 1 8 -1534 1536 . . . . . 2 6 6 . . .67 F4 2 -1985 19B7 1987 , 1 996 22B 19BB 1 16 8 F 4 3 -1992 1994 . . . . . 2 2 8 1994 . 16 9 F 4 4 -1996 1998 . . . . . 2 5 2 . . .70 F4 5 -1912 1914 1914 , 1 933 149 1914 . 171 F4 6 -2023 202S 2024 -1 1 949 , 149 3024 . 172 F4 7 -2125 2127 2127 . 1 904 149 3127 , 173 F4 8 -1769 1771 , , . . 10474 F4 9 -2215 2217 2HS1 4 1 923 . 252 2221 . 17 5 P 4 1 0 -2457 2459 . . . . . 2 7 6 . . .7 6 F 4 1 1 -2465 2467 . . . . . 2 V U . . .7 7 F 4 1 2 -2826 2538 . . . . . 2 7 6 . . .7 8 F 4 1 3 -2164 2166 . . . . . 2 5 2 2160 , 1T ,F4 11. -2168 2170 ... . . . 2 5 2 216Q , 2

CJJJ.7893

W^TftTIDN REPORT FILE: GH003194C16

•TA: GH003194C16, TI1/07/83 3:06:00iMPLE: 1,0 UL FSCC SAMPLE 3194+5UL#BB84-026EMITTED BY: OWAK16 ANALYST: 602

10UNT=AREA * REF, AMNT/(REF. AREA)# RESP. FACT)iSP. FAC. FROM LINEAR FIT TO WHOLE . RL

.10 NAME1 #624 D3-PHENQL (INTERNAL STANDARD)2 441 N-NITRQSQDIMETHYLAMINE.3 610 PHENOL4 473 ANILINE5 411 BISO-CHLDROETrlYDETHER •6 601 2-CHLOROPHENOL7 421 1,3-DICHLOROBENZENEB 422 1,4-DICHLQRQBENZENE9 420 1,2-DICHLOROBENZENE10 474 BENZYL ALCOHOL11 412 BIS(2-CHUOROISOPROPYL)ETHER12 620 2-METHYLPHENQL13 436 HEXACHLDROETHANE14 632 4-METHYLPHENOL15 #619 2-FLUOROPHENOL (SURROGATE STANDARD)1 ,#623 PENTAFLUDROPHENOL (SURROGATE STANDARD)IV #447 • D5-NITROBENZENE (SURROGATE STANDARD)18 #470 DECAFLUOROBIPHENYL (SURROGATE STANDARD)19 #472 2-FLUOROANILINE (SURROGATE STANDARD)30 #448 2-FLUOROEIPHENYL (SURROGATE STANDARD)2) *46Q D8-NAPHTHAUENE (INTERNAL STANDARD)22 442 N-NITROSO-DI-N-PROPYLAMINE23 440 NITROBENZENE24 438 ISQPHORONE25 606 2-NITROPHENOL26 603 2,4-DIMETHYLPHENOL27 410 EIS(2-CHLORQETHOXY)METHANE28 602 2,4-DICHLORQPHENOL29 446 -1,2, 4-TRICHLQRDBENZENi:30 475 4-CHLQRQANILINE31 625 BENZOIC ACID32 434 HEXACHLDROBUTADIENE33 60S P-CHLORO-M-CRESQL34 477 3-METHYLNAPHTHALENE3S 425 HEXACHLQROCYCLOPENTADIENr?36 611 2,4,6-TRICHLOROPHENOL37 416 3-CHLORONAPHTHAUENE38 102 ACENAPHTHYLENE39 125 DIMETHYLPHTHALATLv40 439 NAPHTHALENE 017C)0041 42B 2,6-DINITROTOLUENE4? 427 2i4-DINITROTQLUENE ' C~ i " "' i 479 3-NITROANILINE '^vwrtj4?" 47B 2-NITRDANILINE45 476 DIBENZOFURAN46 ISO 4-NITROANILINE

10 M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT HTGT1 97 727 9:05 1 1.000 A BV 27372. 20, 000 NG 2,522 NOT FOUND3 94 727 9:05 1 1.000 ABB 1700. 1.201 NG 0.154 NOT FOUND5 NOT FOUND6 NOT FOUND7 NOT FOUNDB NOT FOUND9 -NOT FOUND .. ..0 NOT FOUND.1 NOT FOUND.2 NOT FOUND.3 NOT FOUND,4 NOT FOUND15 NOT FOUND16 18-1 743 9:17 1 1.022 A«BV 7997. 10. 115 NG 1.R717 82 B55 10:41 1 1.176 A BV 311636. 133.731 NG 17. 4BIS 234 901 11:16 1 1.239 ABB 160663. 554. 272 NG 32.0419 111 688 636 1 0.946 ABB 301459. 119. 348 NG 190120 172 1162: 14.31 1 1.598 A BV 3B7616. 148. 658 NG 18.73!U 1'ja 967 12:05 SI 1.000 A BV 66326. 20.000 NG 2 922? NOT FOUND2_ NOT FOUND24 82 899 11-14 21 0.930 ABB 1962. 0, 706 NG 0.0725 MOT FOUND26 NOT FOUND27 NOT FOUND28 NOT FOUND2V NOT FOUND30 NOT FOUND31 NOT FOUND33 NOT FOUND33 NOT FOUNP34 NOT FOUND3Si NOT FOUND36 NOT FOUND37 162 1171 14.40 21 1.214 A EB 7513. 0.398 NG 0 0538 19H 1245 15 31 21 1. 2B7 A BB 1238. 0.331 NG 0 0439 163 1247 15'35 21 I. 2r/0 A ED 16D6 0,640 NG 0 OF40 128 970 12.07 21 1 003 A EB 1941. 0,462 NG 0 Ofr41 NOT FOUND43 NOT FOUND' . : :C 1 r QUND44 NOT FOUND45 16B 1307 16:20 31 1. 39S A BB 12B9. 0, 467 NG 0.0646 NOT FOUND'47 NOT FOUND fi4Q 1BB 1525 19; 04 48 1.000 A BV 68913 30. 000 NG 2.33 f,. <49 154 1277 15:58 48 0.837 A BB 892 0, 349 NG 0.04 C"50 NOT FOUND • ' '5:' 139 1307 16 20 4B 0 857 A DB 801 2. 03"9 NG 0 !2(fl17QQig:5 166 1366 17-04 48 0. B96 A BB 953 0.347 NG - 0 01 *-S3 NOT FOUND54 149 1370 17 07 48 0, B9B A BE 3157 0 981 NG 0 115(1 NOT FOUND " .56 169 1396 17 27 48 0.919 A BB 20BE 1.389 NG»0 0 16

57 NOT FOUND58 NOT FOUND59 178 1529 19:07 48 1.003 A, BB 2109. 0, 557 NG 0.0760 178 1539 19:14 48 1.009 A BB 1954. 0,832 NG 0.0761 202 173B 21:43 4B 1.140 ABB 2466. 0. 649 NG 0. OB62 202 1779 22:11 4B 1 164 A BB 2462. 0.615 NG O.OB63 77 1398 17: 2B 48 0.917 ABB 2535. 0. 597 NG 0.0364 149 1655 30:41 48 1.086 A EB 8432. 1.493 NG 0 1C68 NOT FOUND66 340 1990 34:93 66 1.000 A BB 80581. 40.000 NG S 0467 228 19BB 24'51 66 0 999 A BV 3010. 1.034 NG 0 1368 228 199-1 24:85 66 1.002 A VB 2541. 0,950 NG 0 126V NOT FOUND70 149 1914 23:55 66 0.962 A BB 1616. 0.975 NC 0.1271 149 2024 25:18 66 1.017 ABB . 4040. 1.4BBN6 0.1972 141? aiZj? 26.35 66 1 069 A BB 4504. 1.165 NG 0 1573 NOT FOUND74 252 2221 27:46 66 1 116 A BD 13S3. 1.073NG 0.147b NOT FOUND76 NOT FOUND7V NOT FOUND

'i 3. 05 0 341 50. O'O 0. 2373 903 1.00 1.000 1 00 1.20 50.00 0.02? 1.031 0 0£4 906 l.OOfc 50.00 0. 7_i-5 9:06 1. 006 50. 00 0 78ot 9:05 1 004 50.00 0, 7197 9.19 1 030 50 00 0 6320 9 2'.' 1. 044 30 00 0. 8309 9:49 1. 081 50 00 0. 69910 9.53 1. 093 50 00 0. 36i11 10: 12 1 137 50.00 0. 31"112 10. 13 1 130 50. 00 0 60413 10.25 • 1. 15?. 50. 00 0 35s,11 10. 33 I. 164 50. 00 0. 68215 6:59 0772 50.00 0,59116 9:14 1.01 1.021 1.00 10,12 50.00 0.117 0. 570 0.2017 10:40 1,00 1,178 1.00 138.73 5000 4,554 1,641 2.7718 11:14 1,00 1 243 1,00 254,37 50.00 3. 34Q 0.463 5.0"19 8'34 1.00 0. 94B 1,00 119. 3!5 50.00 1.109 1.846 2.3920 14:30 1,00 1.602 1.00 148.65 50.00 5,665 1.905 S.f721 12:04 1.00 1.000 1.00 20.00 20.00 1.000 1.000 1.0022 10:30 0,870 50.00 0.07823 10:42 0. 886 50 00 0.30234 11:13 1,00 0,939 1 00 0.71 5000 0.013 0,838 0.0125 11:22 0.941 5000 0.17526 11-36 0.961 5000 '0315 _'•""'27 11:47 0976 50.00 . 0461 A1 On^'^12 /ll 53 0 984 50 00 0 ?91 U1OUO29"' 12-01 0. 995 50. 00 0.32V30 12:26 1.030 250.00 0. 34S _>,31 12; 07 1.003 250.00 0.175 *

_r

""" $2 r 5 j» Bg us || 0 ] i i i t i i i i i i ...L r . i- — i — i — i.8"

*•

•a-IC.I

T

•'i»~.' •

•

'' !' r| "

?g-n w .

''•N,.' I. 'I

3° .*

?g-

i.:;':!'•" .

(— *"

•

.

1

,

•

*

•'

•-

!

— -_=»-is?i'"" * C7 'h'' •"

•*""' » *

.. .-?'

.,!

.

•

•CT| !•• "

___ ___ Ul CTj 01 t

•'"""'" ' S' 'irl *~ .

•

* -• gTI "..J (Xl

*"

-.

.

?'"'t"

„

Jâ

•

•

*m "J| Q r-

•

•

•

..a, !•^jcjib

p=-B*iu

-• -4 I;..'. •.!

? in '/'

•

S?8y oi en hi v fj*j;] *•' i»' M S

K, w JU

Sllo Ol

Im

4-,5,F

IP ! iIT! r.

1

1

1

:"'jyig"Ti

w u-i I1''!

• ' yir"l

: ^ 6$ fi 017&05

HI i' r,*' <~ ®M crj CM- pj P!-1 e;Is fe ti kis p ^ n jgg fS

M -W<LI RATIO RRTiU RATIO Ufa ABNJILI ». FAC », FACILI RATIO

s s» i:i sts sis5 -»' s ss sII! il i il I! i 1 s§S It5 i:- -sjg SSSffiS -"[:§'" "" «"•££»•s !.! _g ta j.s .. as x Ê SB LS i:| « r. I t= iig «E g;S ,.« SK ..» «.- ,-» "" J-Si °'°=s :;;s .." "«! ..» •-- 1 »» sts ora •57 .18.10 0.95 , »«•«« 0_197

S S!;j; ,00 S'So ...o «.» ;_:»; j-°« j-.™ ;:»S K:S !:SS !.S S'S iS |S fS- -..» «.«SB:E',.» iS jS rs gS s«J J5 S.SS El! i:S5 !:SS !:S >-'i , ;» »" iS l"73 22:07 0.890 »«• » 0 6E6 0. oc71 37:41 1.00 1.114 I. 00 1-07 J«. w75 30- 43 1.836 ^- g 0. E6fl76 30:49 1-240 »»• 0 25B

=

T

,-i'l?,-

a - §

-IP-IPII

<s. *•' cn Ciiw to Sn• i 4^ • • ^-. Vr.n i- 1-;. r.n isj 9

REPORT FILE: EXTRA

'AT A: GH0031S«IC16. TIJ-/07/B!) 3:06:00SAMPLE: 1.0 UL FSCC SAMPLE 3194-t-5UL«BB84-036SUBMITTED BY: _WAttl6 ANALYST; 602

* REF. AMNT/ (REF. AREA)* RESP, FACT)'.ESP. FAC, FROM LIBRARY ENTRY

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT1 . RIC 284 3:33 15 0.344 A BV 54553. 3.037 0. B33 RIC 293 3: 40 '15 0.353 A VB 54748. 3.048 0.833 RIC 561 7:01 15 0,483 A BV 346874. 19.435 5,374 RIC 667 8:20 15 0.574 ABB 10235. 0,570 0.105 RIC 688 8:36 15 0,592 ABB 12549BO. 69.875 18.966 RIC 727 9:05 15 0.626 A BV 128214. 7,140 1.947 RIC 741 9:16 15 0. 63B A VB 638-6. 3.554 0.96B RIC 764 9:33 15 0. 6f)7 ABB 18961. 1.056 0.399 RIC 855 10:41 15 0.736 ABB 1227800. 68.362 18.5510 RIC 901 -11:16 15 0.775 ABB 758931, 42.356 11.4711 RIC 967 12:05 15 0.833 A ED 197379. 10.990 2.9812 RIC 1042 13:01 15 0,897 ABB 10306. 0.574 0.1613 RIC 1098 13:43 15 0,945 A VB 6883. 0.383 0 1014 RIC 1098 13:43 16 0.945 A VB 7754. 0.433 0.1215 RIC 1162 14:31 15 1,000 A BV 1796040. 100,000 27.1416 RIC 1213 15:10 15 1,044 ABB 11017. 0.613 0.171' iRIC 1366 17:04 15 1,176 A BV 5617. 0.313 ' 0. 08IB RIC 1371 17:OB 15 1.180 A VE 8506. 0.474 0 1319 RIC 1397 17:38' 15 1.50?. A BV 11012. 0, 65D 0. IE20 RIC 1449 18' 07 15 1 247 A BV 5417. 0.302 00821 RIC 1455 18:11 IS 1.253 AW 6359. 0.352 0.1032 RIC 1462 18.16 15 1.350 AW 8516. 0307 0.0823 RIC 1469 18:22 15 1.264 AW 12901. 0.718 0.1924 RIC 1491 18:38 15 1.283 AW 6451. 0.359 0.1025 RIC 1499 18:44 15 1 290 A W 6360. 0.349 0 0936 RIC 1535 19:04 15 1.312 A BV 197170. 10.978 2. <7C27 RIC 1539 19:14 15 1,334 A VB ' 5742 0.330 0.0938 RIC 1592 19:54 15 1.370 A BV 10031. 0.559 0 1539 RIC 1,603 30:01 15 1.379 AW 59B6. 6.333 0.0930 RIC 1655 30:41 15 1,434 A BR 19966. 1,113 0.3031 RIC 1736 21:42 15 1.494 AW 10182 0.567 0.1533 RIC 1773 23:09 15 1,525 AW 10547. 0,587 0 1633 RIC 1BOB 32:36 15 1,556 AW 7511. 0,418 0,1134 RIC 1843 23:02 15 1,586 A BV 5390. 0.300 0,0835 RIC 1914 33:55 15 1.647 AVIS 75B1 0.422 0.1136 RIC 1935 21:11 15 1.665 ABE 8765, 0.488 0,1337 RIC 1990' 34:53 15 1.713 ABB 271996, 15,144 1,1138 RIC 2034 35:18 15 1.742 A BV 16601, 0,929 0.3539 RIC 2126 26:34 15 1.830 ABB 10016. 0,558 0.1540 RIC 2173 37:10 15 1. B70 ABB 10603. 0,590 0,16

c.-.-..-, „ 017907v U W i, J <» i ,

OR5ANICS ANALYSIS DATA MET - Pigi 3LM LEVEL MUD

t-m Co-oiX3>«i____________ Caw HwMr '" ' '

SMBla S>lk*

•-Itlply DtttcrlM llrtt* 1? 1

__PC «t«ert MoT' IK7-3O

tor A»pro«rl»ta tatter)

•t5TICIDC5

IMP) 30VOO-J(MPI 60-97-1KIP) 17-74-9I92P) n-zv-:(tJP) 72-5S-9t»4P| 72-94-6(t9P) 1U-29-7IMP) 1tS2>-7I»7P) 1031-07-t(«••) Tt-20-J(9ff>) 7421-43-4(IMP) 76-44-6nOIP) IQJ4-97-3(107PI 31»44-fi(I03P) 3l«-89-7(104P) 519-B6-8(109P) 9B-B9-9(106P) 93469-21-9(107P) 1)097-69-7(10BP) 11104-26-2(1D9P) It 141- It-5(MOP) 12672-29-6(HIP) 11096-52-9(I12P) 12674-11-2(115PI BOOI-3S2

lloYInfltiarltiefilordant4,4>-OOT4.41-ODE4.41-ODD•nmulfifl ltndnulfm II•naoiulfan aulfataHttfrlfimdrln aldthyfliiMDTaeMorhnfichlor tfon Id*HOAIghaSHC-tetitHC*D»ITlBHC-GmnaPCB-1242PCS-1294PC8-122IPCS-1232PCS- 1246PCS- 1260PCB-1016tonaorwtii

4hW.•*7f3B4.0U4.0U4.0U4.DU4.0(14.0U4.0U

_*.*«.DU4r«U4.0U4.WJ4.DU4.DU4.0U4.0U4.0U4.0U4.DU4.0U4.0U4.0U4.0U

533&1.7

<*<*&

DIOXINS iig/kg

B.OMU

tUTICIKS MffRIX PIKE

LOW SOLIDS

__ _____ IM mutt Scitf cofueux»U «, IK »,

^ 3201, -

KV»-3 4.4' CT

4.11-ait

. ****** M'-COD_. 1»-»-7

£1 1»-I»-Tiff) «3i«a7-iM»l n-70 »«rln

SSL WI-4V4 «|>4YI>

m__ itMi-7 »c-i«tiIMP »tMt-l BOOilti

1C*

•Bg IMei-tM KMM2Off 11017 1-7 PJ-1B4

SE »tM.»-2 IQ-IPt

C-t-Ji I7-O4

*IC «C »l« MOID*!____aaêues________«wu muin u»»n n»ui.Tt ua/ko « «JH»-V»-»— I'*1'"___________ ^ 53'3 83.2 rJV_

ic-n-i <i»t«rii> /k/j> fc4.7 80.A ffQ17.74-t iMiftex__________

«0» 7* 4-1 lotttHlpr A/J •_ 4 ' " 81.6 5"ff"

ion »B?4-fM tKttactilor noilNIgff >l*-4--6

"<•*>017910

i$ , s>->'"(•, **f-i>-» rtS<Vi l''$?o. 7 mH ?ty fl"fo•Vo 'an, """"es l3« *»rw

•" i';"T,.,

I'Mor

""Pel

m., iMil '

WlfiS ,flff?f. S J '•'-llnflili /SiftV'11 _* ' 4 V?'-'•1 //"()/ *h«ri.'4S 4ti '&31I »''flfti 4".'!'(/;,'' Kt,- "<!;'/%' J>'-^ ^ J""";'•iiifif-lllifU'U "XHpWV. _"« •?'«.''

' /-/ jsSBftf-^ ^/fA'fe $##/$ ;.•'/»•

-,W•

? (i'/ /-A'^ A-A

// /If ^-^ ^*,// 111! iW:'$ *fr **>•'<> ilttitS ,V_fto"^ /•*%•«' *«W Avi -' /-F/ /.-//A*/ j rA'- /•#>

0179U""rV

017912

fiP.PLITUDE x.25 uV-se.conds (Enla'sed x 47.54)f, U 0) M>_i pa w a

g'gjO O <B a

2-'s®cTs

TJ

7fS -^=—16.66_____________,, aa'O ' ————___,— , :; „ , Jll .BS1

mWO»' Hc m _M W -^

rovi

nl NSi TT- .- • • ,-n——————————————10, ,,-ri Cl i -it—. -»- -I r f i"2- • _J. ===:ias.eiMIL.U'C(.-.' =ro

333,93 017973I. Ju

0 Channel i 9

'Injected at 15i43i44 ON JLIN 8, 1983*P09 Seqi SE«93 Subsrj/SaMp . 1/32 Btl i 3S

//Min DeJav Min-Ar Punch,300 10, Ob 32767 Auto

DvT ID-I.V) Ref-RTW XRTW ZPi]-f Iso0,00 0 ,30 5.0 . lOfl. 00 NO.

35. 017 Minutes> 1 voltat on base] Ineof peaks >

ITM Factor Ar-pa Area '/. NSPIP

0,0 1,00000 869SO. M ,0870.0 3,0000(1 1852(,5. Ftp . 1 Bh

i 0.0 1,00000 193541U. "S 19,4751 (l.O J . O O Q t I O 3P3543. BB 3P6.'8 0 0 1,0000(1 3170S7. m ,31950 00 1,0011(10 6944604, "S 6,98881 O . l i l.OOOflO 133513. BB ,134.99 0.0 1 .000011 111603. BB ,1.12.34 0.11 1,00000 Si 7886. Brj , !J19<.«6 (I. (I 1 .0000(1 56?3_B. BB ,5fi64,10 0,0 1.0000(1 3911.54. BB .394i £9 0.0 1,001100 (.33983. Bfl .638'• 5* 0,0 1. llOOOII 663555. BB .A6B

'' 'fl.ll ). 00000 ?94J597. B?, P.960J O . l l 1,00001) 1026531?. Bfi 1. . 1)33•«i - 0 . 0 3..001KIU 806H&3. BH ,P10

.S.87 0 II 1.00000 840484. .BB ,8466,23 (1.0 1 ,00000 131BPB. BB .1326.49 0,0 1.00000 56663. BB ,0576.65 0.0 1 .00000 742R94, BFi ,7476.78 0,0 l.OOOIIU S1.692S. BB .5206 95 0.0 1 .000011 39P007. BR .3947.09 0.0 1.00000 1B74U, Bh , 1.01?7.28 0.0 i.. 00000 J.111B1B. BB 1 .1197.54 0.0 1.00000 SS697. BB ,056•' 90 0.0 1.00000 14P9P876, "S 14,38?f JS 0.0 I. 00000 368S95, BB .371^.^8 0.0 .1.00000 P.715SP7. BB P. 7333 B7 (j.ll \ . O O U O I i I4298ri94 "S 14.3BS?.B4 0.0 l . O O O U O 81321(3 BB .81.8,1.05 O.p 1.00)11)1) 3692!?* , BB .392J.S5 0.0 1 .0000(1 229339, BB ,P311.94 0.0 1.00000 65856, BB , Ofct.42 II. 0 1,00000 10P9fl09, BB 1,036

;.70 0.0 1.000011 132991. BB ,134.96 0.0 1.00000 51015. BB ,051!.30 0.0 1.00000 14A43324. "S 14.73581 '0.0 1. O O O O l l 2H56967. BB 8. .71S? 0,0 1.0000(1 169552, BB ,171

-.06' 0,0 1. 00000 1738HV, BB ,175.,43 fl.O 1,00000 1528797. BB 1.538,52 0,0 1,00000 167693?,. BB 1,687.'12 0.0 1.00000 BB306. BB .089.95 0,0 1.00000 67095. BB .060.91 0,0 1.00000 93989, BB .095 ..97 11,0 1,00000 72B6P7. BFi ,733 A17Q14.53 0.0 1,00000 201624. BB ,203 Vliat-^25 0,0 1,00000 3179838. BB 3.200.28 0,0 1.00000 56365, BB ,057 p " ,•'••••'_9: 0,0 1,00000 1988104. BB P. 001 I, «...,,/ J ,J

Jl Area = 99378384. Total Area '/. = 100.00:essed data filei P9332 Raw data fllei R933P

ORGANIC; ANALYSIS DATA SHEET - Piya j.—^ ' LM LEVEL SOLID

JkHt ConouCtiam___________ C*M NuatwCoacuCoq

SAMPLE SPIKEIbltlaly 0»tact1of lluin *y 1 POT m

tdwek Box for Approprlita Factor)

DIOXIN5 ug/kg

1746-OM »^ Ion In _______ O.MIXJ

,417,915<-' - •,* U (J

rtniCIDO DUPLICATE MM-TIIS

LOW SOLIDS

EW I**.ISINAl NO, PA NO. _ OC KWRT to I 1^7-JQ

ewe «BI i">»a.

dleldrlnOP heptachlor

SWPLI ICSUI.TS onie. wru KSM.TS MUTIVE KKOHTuq/ko . ' uo/ko________DIFfCTENCE

liull waplH m r«*«r»* ->'% • "IIt** aortlin,II tati It r»»ort«d in i fir nlgm taili. '

77

RMP.:TUDE: x.2S uV-secon. .SnUrged >. 64.21)

D s a® <Si osCD GEi O(9 O 03

017917'" ••»«)«.'

4,00 Channel. 909 Injected at J6i24i56 ON JUN 8, 1983CAP09 Seqi SEQ93 Subsq/Sanp . 1/33 BU . 33

MV/Min Delay Min-Ar Bunch.300 10 DO 3-767

DvT ID-l.vl Ref-RTW m« BHiJ-f Iso0.00 0 .30 50 IfiU.OO NO

35.00t'i ninuie?.. > 1 voltnor on baseline

TTM Factor fine? Ares '/. Nan-

0.0 i.O O I l O O 18S46R, BB .344- 0 ,11 1 .00000 68SL'4h. BB J .275;,i) fj 0 1,00000 9107536. *<3 17.124li II .11 .1 0000(1 208)4) , BB .386>d O.p 1 OQuiHi 77681. BB .14131 (I II 1 ,0(10(111 )03«l?.l . BB 1 .901;'i j) J 1,000011 339460. H* .6293 (i .1) ) .00000 163746. BB ,303J. OJ ). .000(10 4433949. BS 8.303"B II II 1.0000(1 Jr.?)V) . BB .300

..9fr 0.11 l . U O i l l i U 17S873. Bf.i ,3_fc'• -22 II 0 1.00000 IHi&lP. BB .?)6,ft -6? p . l l I . O O I I U O 551VJ. BB .102-'.03 (I. II ) .000(10 jfii'BSS. BB .301?1.7 ? 0.0 1 O O O O O 11395U. BB .21117 / II 0 1 001100 405.57P7. BS 7 47518.4V 1.0 l.OH O O l i ISSI^fiO. BB 2.8421-0-90 1.0 1.000(1(1 )Bt>7?7 BB 31619.12 II.II l.OOIIOl! 51004, BB .1.00.9 79 (I.(l 1.00000 J790P7. BB .33?HI. 04 i . l l 1.000.10 82:JC,1.0. BB l.S2'3?1,11 00 l.OQIl(I(I UfiVSV?-, BB P 7P5''33 II. 0 1 O O O U O 10ftOV2. BB .WOO'.'.80 II.(i 1.00000 366)073. BB 6.781'.?.£?, 0. : 1.000(10 174394. BB ,322'4.B6 II U 1 .00000 . 11803(1. BB ,219!?.33 0.0 l.OOOIiU 1.83fl'-!B96. "S 34.II4B'7.8B (i.O 1. O O O U O )S73fi6. BB .292•& *? Il j 1.01)000 102V368. BB 1,907V.SS II. (I l . O O U O O 4174P.35. BB 7.731i.£7 on i DIIOOO aafiini. BW ,1.54i?.02 II.0 1.00000 146049 BB ,P713,95 i.O l . O O O I I U 21.S474, BB .3994,77 (I.O J. 00(100 74069. BF !i37t»\ Area * S3991.152. Total. Area '/. = 100. Ill)

dat* file. P9333 Raw dais file: R9333

RMPLITUDE x.25

- r. 01791.3

r

• ,

-06

i

017920

flMPLITUDE x.2S uV-seconds (Enlarged x•" f 10en o </i oo o e G,o o o o

O & O C'o o o B

017921

ILE. P73S6 ON CRN 199.06.53

-1 CHANNEL. 7 * PEAKS, -22FACTOR AREA AREA z

i

0164387.75.71

/. 581,40.3.01iB.0921,04

0/000.000,000,000,000.000,000.000.000.000.000.000.000,000,000,000,000.000.000.000.000,00

1.000001,000001.000001 .000001.00000i. 000001.000001.000001.000001,000001.000001,000001.000001.000001.000001. 000001.000001,000001.000001.000001.000001.00000

B070499 BS4810119 BS139870 BB46637 BB

11049B BFi14264 BB

1995669 BS24001 BB24749 BB.1.99454 BB63405R BB24062 BB419063 BB26637 BB

1301 7B1 BB79872 BBPS 88

9iS§*8_ 889934S1 BB170177 BF

27.69416.610

.480,160,379.049

6. 840.082.0(35.684

2.179.063

f .441,091

4.4f>7,274,073.327

33 if?3:_K

AREA ~ 29141532 TOTAL ARFA 7. = 100.000... CP 3209 INJECTED AT 16.07.10 ON JUN 10, 1983METHOD. TEMPO? SFQ. SFQ73 SUB8Q/SAMP. 1 / 56 PTI.•• 56

JDT". MV/M.IN DELAY. fUN-AN BUNCH REPORTS > .300 O.-OO 100011 AUTO NO .•UNK DVT ID-I.VI. REF-RTW fcRTW 2B1L-F ISOi 0.00 0 ,30 5.0 100.00 N(lIAL RUN TIME. 25.017 MINUTES

NK. 1,00000 STD-AMT. 1.0000 SAMP-AMTi l.OdOOli NOT ON BASELINE

DATA FILE. R7356 PARAM FILF.S= MFTHOD,

Ulan

ORGANIC! ANALYSIS DATA SHEET - Page JLOK LEVEL SOLID

.CompuCh-n____________ C»»» Nu»l>»r ___«>. oan juy-fo gc feporr NO.lated samples

Dttwrrlon MinlTi By I Q or 10 Q or Q _____(CtiKk Beit (or Appropriate Fictor)

PESTICIDES

PPI CA5» ug/Kg

509-OD-2 aldrln 4.0U

DIOXINS ug/dg

2tJ.7,B-t<trachlorcKlll»nio-I129B1 1746-01-6 p-ciloxln________O.OBOU

017923

fltlPLITUDE x.2S uV-iteconds Enlarged x 15.97)* _ ) * • » t o

1 '-1Ht3(9

3*cft10M

U.•*(B

<A,,,~0ST)r? r•» »5""It

*MOT*0 COa,a<M

. *XI U0 6)AQlH"J M(_rn

MO* -1 -e nj,,,£,"° .233 S01i-roCOWMWlIV „

n>" <rtT A "'r0'&it.*nc~" -.•— 00* .• Oi~ °<6OPCO

ro,N(8

N*

o> s o eS 09 (8 0909 09 09 09• ' • • t

. — , —— refi ——— T ———— , ———— | ———— , ———— | —— m

"

,„,„,

' —— "" _ ^- ,., - -., :. ,...„ „ „, -.i .SB. ———— '6l , ••f ' V 'is* 2.13 *

""~ —**— ,66

) 9.S6

12. 99

*

•

,

,

'

i . i ' i

017924c»"wiij

JpL-Ji ————— i ————— . —————————————————————————————Si

,„„.„„, • ,, -.. r 0 - 'I u.,»! pun tine. 25.017 ninutesEnded not on

RT ITM Factor Area Area X

1 H II «1 "11 il m * § ;i,'h 569S7BQ, Total Ar** X • 100,00data file. P7S1B R*« «*ata file. R7SJB

017925

|__r"

RUPLITUDE x.2S uV-secono. (Enlarged xn w o f_! 09 03 (0^ co si aH. S 8 Q__« O> 09 OJ

BOJ**'«»

Li

s ?n.

(I Hc m r-

oOJr-in*..u

'£ K0 tfl ,«* O Q•oVI (.ocG*Zm

D3•B

5-

* Wrrl.JWo cnft I .>—..—— Up95

U 10.31

12.82

•IE.46

23. S4

, 17928

Report, 2670.00 Channel. S f nu rllkl ,, 400-,_ ,„ CPMB6 Injected at 14.34,35 ON JUN 13, 1983Sa^Je. Uri4oci « _ZBkCI Method, CAPOS Seq, SEQ50 Subsq/Sanp, I/ S Btl,

! £ • " ' " "ual run tine. 35.004 ninwte*Ended not on baseline

RT ITM Factor Area Area X Nane

1031 0,0 1.00000 ' 25643. BB 1.24111 95 OiO 1.00000 151699. BB 7.344'? 61 Q 0 i 00(100 19562, BB ,947?&.__ 8:0 . .Odin p£7610, bB 12.95613 69 00 1.00000 40417. BB 1.95713 94 (10 I 000(10 10B33. BB .524i?'46 C l i o t i O O O O O 345S56. BB 16.73017.42 0,0 1 .00000 2094P. BB 1 ,0)418.23 0 0 1.00000 21RU20. BB 10.26S19.02 fl 0 1.00000 380)8. BB 1.841Ti-.i,;. 0 ti 1 . O O O U l i 11061, BB ,536S;? 0V II (i 1,000(10 JS367B. BB 7.440/:• /.;; II (I l . O U H b l i 11SB5. BB .561S". S« O (1 l.OIKUKI 404958. BB' 19.606

. , (i i- i.OOOIHi 1,7 274, BB 8.389;•: .i", n ii • O l u d O 4APO«. BB 2.1f>9r BV u U i Utn.i.i'. MI?.l._. .HW 1,467', )Q6 (I II '' !i'. til".: l?-i'' 5 . Hi' .81?.3U.53 0 0 ). . U l l O l i i - '.Vila* i-' .92;',32.45 (I.O 1 .OlldOO 6'?0?.i-'- I-- .'. !?47

Total ftrea = 80 478. Total. fNr. .. f ••• Km u»Processes dats fSlei P500? Rflw data file, RSIltlS

017927

QUALITY CONTROL. NOTICE

CASESQC report^ 127,30

Due to a poor sample matrix, the pesticide sample spike performed 1n thiscase was diluted 100:1. Accurate quantHatlon was still difficult however.Under normal quality control standards,another sample spike would have beenperformed. However, the other sample In this case batch showed similar matrixproblems. Therefore, we are reporting the original pesticide sample spikeand duplicate data.

Paul Mills

Quality Assurance-Director / /

(XA"

I ;> 017923r -' s

^

Lib lU-ts Held CowuCheii

M6MIC5 AHALYSIS DATA SHEET - •

CASE*

BUnk-TCDD Associated samples 32.01.*•; '. •. •. '

j A, SURROGATE SPIKE RESULTS

COMPOUHO

1,2,3,4-TCOD

it

,

•

I

FRACTION

PEST

Unit ArtiCone.

235-

(Surrogates only)Spike UnitAdded Area

SD

IRecovery

ft*/

017 3•w *'

SO

COMPUCHEH NO. f-) .._ DATE_r'-Y

IDENTIFIER TCDD - LOH LEVEL SOLID

COMPOUND LIST ' - NO.

COMPOUND REMRT CORRECTION RESULTS I DETECTION*ySSSf COMPOUNDS VALUE x FACTOR - Jufl/kflLl UHIT(ug/fcfl.)

469 2378-TCDD 20 x

SURROGATE (1234-TCDD) RECOVERY •

Quant Report Value M/E 320 (1234-TCDD) x 100X250 (Spike Level) p g / u l .

x 100%250

t Quant, Report value M/E 230 (1234-TCDD) •200 po/yl x Area H/E 320 (1234-TCDD)

1 Area M/e 332 (Sample) RF Shift Std.

200

CORRECTION FACTOR • Q

Final Extract Nlol time (ml) x „ i c , M" X 0,008' U.I »l ^ —— Vol. Extracted (g)

KKOCEDUREi RK. DIAGNOSTIC REPORT 6/24/83 14:31;14DATA FILE: TC003486A03INFERENCE: TC.'"" METHOD: TC INITIALIZATION OPTION: 2 PROCESSING OPTION.' 3

REPORT: TCS

,; —— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED • POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN

_ -2 5 70 7 5 1 89 TCS/TCU' •!• •'

7 COMPOUNDS PROCESSED. 5 FOUND•)

COMPOUND X ———————— SEARCH ———————— X SAT X ———— CHRO ————— >LIB ENTRY REF PRED SEL DELTA PEAKS FIT PEAKS M/E TOP DELTA PEAKS

i TC 1 493 494 494 . 1 B32 . 332 494 , 1_ TC 2 482 482 4B2 . 5 994 320 4B2 , 1IS TC 3 482 4B2 482 . 1 994 322 482 , 1A TC 4 482 482 4B2 . 1 994 . 257 483 1 15 TC 5 494 494 . , , , . 320 497 , 2Q TC 6 494 494 , . , , 322 494 , 17 TC 7 494 494 494 . 1 932 , 257

017931

t> so

MEAD COMPUCHEMOUANTITATION REPORT FILE: TC0034B6A03

iliTA: TC0034B6A03, TII 24/83 12: 40: 00SAMPLE: 2UL TCDD SAMPLE #3486-069 (6/7/83) ON #3SUBMITTED BY: 03 ANALYST: 586

AMOUNT«AREA(HCHT) * REF. AMNT/<REF. AREA(HGHTI* RESP. FACT) 'iRESP. FAC. FROM LIBRARY ENTRY

•t '"C NAME

*13C12-2, 3, 7, 8-TCDD (INTERNAL STANDARD)j 1, 2. 3. 4-TCDD3 i, 2, 3, 4-TCDD4 1, 2. 3. 4-TCDD5 2. 3. 7. B-TCDD6 2, 3. 7. 8-TCDD7 2, 3, 7, 8-TCDD8 2, 3, 7, 8-TCDD

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT1 332 494 11:04 1 1.000 A BV 1630550. 200, 000 PG/UL 24. 21 J.dfl2 320 482 10:48 1 0,976 AW 1044350. 205, 176 PC/UL 24, 84 1.1: 322 482 10:48 1 0,976 AW 1319730. 201. 630 PG/UL 24. 41 S-ai, 2S7 483 10:49 1 0. 97B AW 461278, 207. 194 PG/UL 25, 08 1.<\S 330 497 11:08 1 1, 006 A W 17295, 3. 714 PG/UL 0. 456 320 494 11:04 1 1, 000 A W 12235, 2, 628 PG/UL 0, 327 322 494 ill 04 1 i. 000 A W 34496. 5. 770 PG/UL 0. 703 NOT FOUND

NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R. FAC R, FAC(L) RATIO1 11:03 1. 00 1. 000 1, 00 200. 00 200. 00 1. 000 1. 000 1. 00234C1W

o7

10:4810:4610:4811:0411:0411:04

1,001, 001.001.011,001.00

0.9780. 9760, 97B1,0021.0021,002

1. 001, 001, 001, 001,001,00

205,SOI.207,3.2.5,

IB6319716377

200,-00.200,200.200,200,

000000000000

0,6400, 8090. 2830.0110. 0080. 021

0,6240, 8030.2730,5710,5710. 733

1.031,011. 040,020,010.03

8 11:04 1.00S 200.00 0, 26B

: . uijSjJJ)

i <_a < f^°x1

HAO G>O O10°

31,

sco -. _ <r -si <»>

&S/•%

S„ •>•>!_

B

I

i

01733s

t

wun

$ IPw **yi v O

J'' Ti _"---•' - " ':''' £' C •<* ' ®

ll p

'8

g 8 „ S, .0 U) . . . «? , , I T l i l t[ t i l .I

_fi.

"* WkiK' . W 5

o» CD c»w filass I ag 3 ai ^

CD *

CO 70

WCi-iri^H&S

o o JC1

8 1

05

I

** rso $W*

•

P gE o; ..P «E

• -i

gg

BS'• • •'

• f

N!"

? XS(> 88? 89

s

oW

Date post:	30-Jun-2019
Category:	Documents
Upload:	lyque
View:	222 times
Download:	0 times

017795 - United States Environmental Protection Agency · U.S. ENVIRONMENTAL PROTECTION AGENCY-CLP...

Documents