90
018991 V !
018991
V !
U.S. t'lVireXMMTAL PROTECTION AGENCY-CU* Stopli MnigiMnt Oftle*" ", fex r.l, AlnunOrU, VA 22913 - 70VJ57-24W
(M UV£L LIQUIDORCANICS WALTSIS DATA MU - Peg* 1
Utxritory MM HMO Ojupueimi__________ du *m»xr ( b fr"?_____ ...Ut> tapl* ID It. -- '"l'l+5(a"' QC Nwt Ha. -9 / f /& -/C '_
. Multiply Oit»ctlgi\ lUln by I ]_[ or loQorE] ____(ChtcK Dux for ApproefliU Fictgr)
• ACID (XMPOUN05 BASE/NEUTRAL COTOUND5
PW CAM US/1 PW CAM M9/I
(2IA1 It-06-2 J,4.6-trleliloropmn.l _____ MU (42B) 396MHK-9 bl»-(;-chli)rol»cprmiynttntr 40U40U (4») ll->l-l i-(2-cMofi»Tlxixy)n»rn«nt 40U
(24M _»-a7-» ;<Moro9t>«nol MU (5gl 17-tt-i lx»»cMofo6yt»dlini ______ ZOUTilAI '" ia-»3-Z 2,4-<lchlQropti«iicil MU |}JB) 77-47-4 hmclHofiicycloi ntiillint JOU(34A1 10VJ7-9 2.4-0 IxTtwIptunol _______ 20U (MB) 7»-5»-l lnmDBTCnt ___________ JOU1?7A1 M-7}-} ifillropmnol __________ W 18JB) gl-20-3 MptlTMItfK ___________ 20U_JMAI IOO-Oi-7 4-filtrixirmiol _________ ZOOU (Mfll »-it-i nltrotKurn _________ JOU
. IOOU (62B| KOQ-t M^iltrotodlphtnylailm 20U_____ttOAl »4-«-l 4,6-fllnltro.2-<»TnylplmK»l 400 (63B| 6J1-64-7 (HilTroKiill-fmrppyHnIni 40U164A1 l7-3fr-5 ptnt»ctilorMih«ncil ________ «U (MB| 117-81-7 6lilZ-tTtiylh«i(Yl)ptiTh«liT« KXl'''VI IO»-»-2 pt^nol ______________ JOU 1678) IVM-7 tuTyl lnn»yl pnttt»Ht» 20U
IMBl 14-74-2 dl-fl-tHityl pntfalitti ZW(Hoo-ft-lorlTy Mlut«nt (kardaia &ibitinc*t) (6«) I17-84-0 ai-fl-octyl pfttluliti _____ 20U
1706) l4-6t-> altThyl pHTMUtt ________ JOUtytt-o txfiroic tcia _______ joou i7ib> lii-n-i aixtnyi pti-TMUti _____ jou
~ tS-48-7 z-Mtnylprnnol JOU I72BI 86-jS? l)«ma(i|«nTHr»ctTn ______ 40U108-39-4 4^tTHylpmnol JOU 1736) J0-i3»» b»flto<«lpyrM» _________ JOUB-9V4 J,4.?-trlcmcfopl>tnol _____ JOOU (74B) JO>-»-2 l»iBHI»Hluof»iitt»tii ______ 40U
" '(7«) J07-Ot-» b»ntolKHIupr«nth»n» 40UJASE-tCUTRAl CCHTOKI5 H6B) il»-0|.g ctiryMni _____________ JOU
' (77B) JO»->ft-» «c*nipl\tflyl«ii« _________ JOU( IB) U-M-9 »c«niphtt)t(i» __________ JOU (766) IJO-IJ-7 »nthr»c»ot ____________ JOU( SB) K-17-S WKilldln* KU 178B) III-84-J M(i»>(om IP«ryl»ni 40U1 86) 120-B2-I l.2.«-TTlchlofot>«im)i _____ JOU (BOB) I6-7V7 fluortni JOU( 16) 118-74-1 m»MlHorot<«i\mii _______ JW (0IBI l>-OI-8 pMntnttirtni _________ JOU(IJB) 67-77-1 h»xx;Moro«ttitn« ________ JOU (B3B) 9>70-3 dlDOTPi(l,h|»ntHr«cOT« _____ 40U(HB) ni-44-4 blKJ-cMortxttiylXttur JOU (MB) )H-i»-} ~ lnd«w(l,J.Xillpyr»n» 40u'IJOBi tl-»-7 J^hmrompntniUM ______ JOU (e4Bl 1JHXH1 »yr«nt MU
' JOU______(J») 941-7M I.KIcmorolxrmtx ______ JOU (Nw-frlcrlty follutMt I*I*«PU« Subit«ne«)1JTBI 106-46-7 1,4-alcMOTObxlI** MU
I3JB) IJI-I4-J J,4 Hnltrotolim>« _______ 40U ____ IOO-51-t btntrl ilcoftol1MB) 606-JO-J J.minltrotDlMM _______ 40U 106-47-8 4-cMoroKilllM
l,J-dlph«iylliyitrulM(STB) «J-«fr-7 (•» Hotmanl 40U________H>B) 206-44-0 tluocinmdl ___________ JJU;<B| T008-7J-? 4-cMoroph«oyl plxnylttlm' JOU
(418) IOI-5SJ 4-<x-o»>(iH«nyl ptunyl «TD«- JW
ORGANIC! ANALYSIS DATA SHEET - Pigi 2
IJoorMory MM Mud CoupwCtHni ______ <*»• Nwbw ito^l- 5 A S - 5"49 -1Ub S«plf ID No. HH>~(o 1)0 taport Ha. ' /A?. 9
D»tKtlon Unit! by I £]«• loQorQ g(Chtck BOK lor Approprliti FtcTor)
KOLATIU5
PP» CASI ug/l
( 2V)I 3V)( 4V)( 6V)( 7V)(10V)I1IV)(13V)(14V)(19V)(16V)(19V)(J3V)(J9V)(30V)(3JV)(33V)
(MV)144V)(45V)(46V)(47V)(4BV)(49V)(90V)(91V)(B9V)<B6V)(B7V)(HV)
107-02-6I07-1J-171-43-296-23-5109-90-7107-06-271-99-679-34-579-00-579-34-579-00-3110-79-t67-66-379-39-4196-60-975-B7-910061-02-610061-01-09100-41-479-09-274-B7-374-63-979-89-279-J7-479-69-479-71-B124-46-1127-16-4IOO-B»-379-01-679-01-4
•croldnKrylooltrll*b*n»nicarbofi tirrtchlorln*chlorop«nlw(,2-Dlchloro«tMn«,1,1-trlcnlorMtnin*,l-4lcMoro*tniniiliJ-trlcMorovrMn*. l>2i2-t(trichlorM7h«ni
chlorocthintJ-eMoTMtnylvlnyl ith«rctilorotor* I .i'l.lxtlcnlorotTMniI.J-Trini-dlcniorMtMnitiJ-dlcMoroprooin*trini-1,3-oletilaroprop«niGli.1,3-dlcliloroprop*n«•tl\vlb*ni*ntMThyltnt eniorld* 3.f-ehloroMtnanibroMMtfMiiftbroaotor*broiodlcliloroMtltim( 1 uororr 1 CM oromtlun*dlchlorodltluoroMTMnicttloradlbromoMttwnitctricniwocttm*tOllNMtrlchlorMttnfn«lnyl chlorldi
100U100U9U9U9U9U9U9U9U9U9U9Ufu-9U9U9U9U10U9Ujtr9U9U9U9U9UNA9U9U.9U5090
(NM-Prlorlty Pollutiirt tfcnrdotn SubitmcM)
67-64-17B-93-379-1SO9I9-7B-6IOft-10-1100-42-9IM-09-499-47-6
•errant2-tMtinon*cirtxmdliultldt2-fnxinom4-«tliy 1 -2-«*nT>noniftyrm*vinyl Mttitio-nylm
1000IOOU100IOOUIOOU50iou50
018993GO 17;,;]
ORGANICS ANALYSIS DATA SHEET - Pago 3
nnplo Number
Z2/&LOH LEVEL LIQUID
Laboratory Name Head CompuCliim____________ Cose Number /gg? •Ub Samplo ID No. /4.<&~" 9= R«port to. $.9
Multiply Detection limits by I 0or(CnocK Box lor Appropriate Factor)
PESTICIDES
PP» CA5» ug/l
(39P) 309-00-2(SOP) 60-57-1(9IPI 57-74-9(92P) 50-29-3(93P) 72-55-9(94P) 72-54-6(95P) 115-29-7(96P) 115-29-7(97P) 1031-07-8(96P) 78-20-8(9JP) 742I-4W(IOOP) 76-44-8IIOIP) 1024-57-3(I02P) 319-84-6(103P) 319-85-7U04P) 319-86-8(I05P) 58-89-9(I06P) 53469-21-9(I07P) 11097-69-7(I08P) 1 1 104-28-2(I09PI III4I-I6-5(HOP) 12672-29-6(11 IP) 11096-82-5(II2P) 12674-11-2(II3P) 80DI-35-2
niorlndleldrlnoniordane4,41-DQT4,4<-DDE4, 4'-ODDendosullnn 1•ndosultan IIoncosultan sultate•ndrln•ndrln aldtnydehoptacniorheptacnior opoxldeBilC-AlphaBHC-BettBHC-DolTnBHC-GaimaPCB-1242PCB-1254PCB-I22IPCB-1232PCB-I24BPCS- 1260PCB-1016toxapnone
O.IU0.1UO.IU0, IUO.IUO.IUO.IUO.IU0, IUO.IUO.IUO.IUO.IUO.IU0.1UO.IUO.IUO.IUO.IU0, IU0.1UO.IUO.IUO.IU0.1U
DIOXIN5 ug/l
2,3,7,8-tiitrachlorodltionzo-11296) 1746-01-6 p-dloxln 0.002U
30
GC SCREEN DATA SHEET
Laboratory Name___Mead CojipuChem
Case Number )i {-7- /)-r- 57 9—/
SampleID Number£J./3f
MSI*
FractionVGAB/N/APesticidesDloxln
VOAB/N/APesticidesD1ox1n
VOA.B/N/APesticidesDloxln
VOAB/N/APesticidesDloxln
VOAB/N/APesticidesD1ox1n
VOAB/N/APesticidesD1ox1n
VOAB/N/APesticidesD1ox1n
GCDetectable*
Medium Level(Gof toMaUn
Dateof
Screen—,__—
Level ofGC/MS
Analysis"*-UL.L,L.
*Answer Yes or No.»»lndkate"M" for medium level GC/MS analysis.
Indicate1^" for low level GC/MS analysis.
ORGANICS ANALYSIS DATA SHEET - Page 4
Lab Name Mead CompuChetn ' EPA
CompuCheml / V S"(eSample Number^ /3F
A. SURROGATE SPIKE RESULTS
COMPOUND
dg-Toluene
d4-l,2-D1chloroethane
Fraction
VOA
VOA
ConcentrationTotal (ug//)
V.3*
,5 • •?(.
(Surrogates only)Spike
Added (ug )
„/
4
Recovery
IL7
V
COMPOUND
2-Fluorophenol
Pentafluorophenol
d5-N1trobenzene
2-Fluorob1phenyl
2-Fluoroan1l1ne
DecafluoroDiphenyl
Fraction
FSCC
FSCC
FSCC
FSCC
FSCC
FSCC
ConcentrationTotal (ug.'X)
u-£
wfffO
r~tt/'
£0
(Surrogates only)SpUe,,
Added ug/(?)
, CtV.
/£'."
,co
/ SO
fl 0
i C -'
" XRecovery
6 (••
^
iV
/«(,7
,'=.'10
COMPOUND
1,2,3,4-TCDD
Fraction
TCDD
ConcentrationTotal (ug /(}
7.3
(Surrogates only)SplKe
Added V')
-55
%Recovery
£&018996
p 1 •( I" - I f(.Mi I i h.C-
at
LIST OF COMMONLY USED FOOTNOTES FOR EPA
II Indistinguishable Isomers.I Presence Indicated by extracted 1on current profile; definitive spectra not
obtainable due to Interference.q Quant'1 tated from secondary 1on.
Cl Concentration estimated; Interferences present with primary quantitatlonIons,
D Sample analysis using a ____ dilution.
SE Sample extract could not be concentrated to 1.0 ml, thus the detectionlimits are higher than normal.
DL Detection limits are adjusted to show change in sample quantity processed.Tne surrogate recoveries are not available.
SR Surrogate recoveries are not available because 1t was necessary to dilutetne extract, based on GC screening results.
SC Suspected laboratory contaminant.LT Less than the specified detection Unit but greater than one half of tne
detection limit (present but BDL).
EV Estimated value. This footnote is used when estimating a concentrationfor a tentatively Identified compound.
H Volatile vial received with headspace.SV Amount corrected for sample volume.DC Compound calculated from a ____ dilution.CR Compound calculated using total RIC area. All secondary Ions saturated.
PC Pesticide or PCB confirmed by GC/MS.
PN Pesticide or PCB cannot be confirmed by GC/MS.U Compound analyzed for but not detected. Tne number Is the minimum detection
limit.
BDL Below Detection Limit
018997
51-
DATA REPORTING QUALIFIERS
The attached list of footnotes 1s used by Mead CompuChem to qualify dataresults. This list Incorporates and/or supersedes footnotes suggested inEPA contracts. Explicit definitions of the footnotes are also provided.As specified contractually-and alao enforced •*>? Cnt.rrc p.i'iunntl, notationsor changes to data values are Initialled by the CompuChem employee makingand/or approving the change.To eliminate any confusion between footnotes and Initials, the followingprocedure Is employed:
1. Footnotes are indicated to the left of the data value.
2. Initials are Indicated to tne right of the data value.
3. Initials are circled.
For example:ug/1 s
(87V) 79-01-6 Trkloroethylene .......... "W. <vr cFootnote value Initial
Tne reported value of 1000 ug/1 trlchloroethylene has been calculated from asecondary 1on (as indicated by Footnote Q). This notation has been Initialledby a CompuChem employee with Initials KH.
018998OGH'M
30
/
QUALITY ASSURANCE NOTICE
This sample has low recovery for pentafluorophenol. The re'cove'yof the surrogate pentafluorophenol periodically dips below laboratorycontrol limits. This phenomenon 1s under investigation. Since theother acid surrogate exhibits nonr.al recovery, the sample results havebeen reported without any additional analyses.
Quality Assurance Analyi*
018993
30
ORGANICS ANALYSIS DATA SHEET - Po_o 4
Lab *m«: HEAD COMPICHEHCC REPORT NO!
'
1
2
3A
5
6
7
8
9
10
11
12
1314
15
16
17
18
19
20
21
22
23
24
25
26
27
,28
29
30
8. TENTATIVELY IDENTIFIED COMPOUNDS
CAS. COMPOUND iVME
lAfffi lP
SAMPLE NUWER_ Z3/J8
FRACTIONf HAXIMIM SCORE AHAINEDMASS HATCHING ROUTINES
(SPECIFY)
•
019000C** v ... •• , ,U >. i ,•;. u
nutLOW UYU LIQUID
_______ LAI Mp\HEl NEAD_BM»UBjII*_s«TSbT 'ORIBllML NO. PA NO. BC nPOnf*)! I Jfl "C~~
MBE I »f 1
ASSOCIATE) WW «i_J44Q- ...K.M CA»EIBiI tig") •
me «c nut ADDCDCAM_____COMPOUNB5 _•__________IHfll HC5UIT5 UfflE RESULTS us/I I HECOVtKY
KTMH-t icroliln_______C 3V) 107-H-1 •erylonltrll*< 4Y) 7MS?( »V) 86-23-9 eirbofi tttrieMerldi1 TV) 1M-9IM
JllOy)r 107 )6-? _____________
(I1VI TI.99-6 l.1.1.tTletilero»t1ant_(13V) 75-34-3 1,MlcMcfo«tMn»
niVI_ 79-34-5 l.l.».»»1»1rieMorDitliin«(16VI 79-00-3 chief ottlnfii
ivl gtmrcMoi-efern
WV) 7V.5-4HCV) H6-60-9 l.?-trini-dleMore*fhtn«(37VI Ti-17.9 1.2-dlehlorMroflint!(33V) lBOtt-02-t
_ 10061-01-05(MVI 100-<M rthyltxrmrn(44V1 79-0»-3 •tnyl«n» cti|prld»(4iV) 74-<7-i ctiloromTMni(46V1
(47V) n-n-1 tro»o)on«UIVl TVI7-4IMV1 T9-6W1 «|pxirotrlcMorei»«ttni>«
«lcMofodUluore«i«tl>iiiii1J4-4I-1
iiiv) m-li-4JMVI lOt-M-i
Tt-01-tIMV) T9-OM irlntl
1002
1 I
PC WfLE KSULTS OKIS. tMPLE KSULTS MUTIVt rftCtKT
_ao_ i9 - —s.iq 40 _jl11 - -k(j> A1 _A
.;d*. TSLO nub.
019002I'./., '.'
BASE-NEUTRAL & ACID MATRIX SPIKE
Low liquid Samples1 4 '7 1 mA £51 ffi) Lab Name-Mead CompuChem
qc Sample Ho. Original No. EPA No. Qc RBportAssociate Sa es Wfl Wl, N V &|a Ho
PP« CAS No. Compounds Or1g. Sample QC Spike Added 1Results Results ug/1 Recovery
(22A) 59-50-7 p-chloro-m-cresol _(24A) 95-57-8 2-chlorophenol _(58A) 100-02-7 4-nitrophenol _
(64A) 87-36-5 pentachlorophenol _(65A) 10B-95-2 phenol _( IB) 83-32-9 acenaphthene _( 8B) 120-82-1 1,2,4-trichlorobenzene ._,(27B) 106-46-7 l,4-d1chlorobenzene _(35B) 121-14-2 2,4-d1n1trotoluene _(63B) 621-64-7 T>j'itr<iip6cJi-N-f
(68B) 84-74-2 di-n-butyl phthalate(69B) 117-84-0 di-n-octyl phthalate(76B) 318-01-9 chrysene
(BAB) 129-00-0 pyrene
019003
2-fluorophenolpentafluorophenold_.n1trobenzene92-fluorobiphenyl2-fluoroan1Hnedecafluorobiphenyl
(22A) p-chloro-m-cresol(24A) 2-chlorophenol(5BA) 4-nitrophenol(64A) pentachlorophenol
(65A) phenol( IB) acenaphthene( BB) 1,2,4-trichlorobenzene
(27B) 1,4-dichlorobenzene(35B) 2,4-din1trotoluene(63B) N-n1trosod1-n-propyl»n1ne
(6BB) d1-n-butyl phthalate(69B) d1-n-octyl phthalate
(76B) chrysene
(B4B) pyr«ne
019004GG1T30
30
/ i
|,J,T.»-1«tr»eM«rt«l»«MO ' ___lint) nu<n+- £*'•'"' ————•———
mtfSff V®*'**' " ,019005IMIOU GwlToJ.
30
Ill Mt*
019008G- ., _. >•> •• -\
\; I Jfc
ORWNICS muLYSis DATA am - cage 2
Laboratory (tare Had ConmOigii Cast Hmfcer I la 6.7'Lab Sarple ID Ho. (ffifi j'aji' R)A- jrctrurett Blarf QC Report No.
Associated Sanples .
YOUmESug/1
107-02-fl acroleln ________ 1CTDTTS-l acrylonltrne >P7TTO benzene ffi"
carbon tetracnionde >ccti1orc6ergene »j
107 5-2 1.2-d1criloroet(»ne H3TFSS l,l.l,-trjc>noroet>iane «
I.l-d1cli1oret,iane F. plCTioroettoie IP1.1.2.2-tetrachloroettiiinechloroettwte
110-75-8 Z-chloroetnylvinyl etter~ctiliAulofni 117'I,l-<h\ch1cfoetfene IP
79-34-575-00-3
1 .1 3. ,2-tetrachloroettisnechloroettwte
I56-60-S7B-B7-510D61-OZ-6 trans-1.3kHch1oropropene " 'IPlGQSl-01-<£ cl5.1.3 cn1oropropene_ H)100-41-4 ; etHylbenzene ' IP
nettylene ctilorlae IF74 7-3 chlororettvme74-83-9 braionetnane75-Z5-275-Z7-4
braiDform 1(raipdlchlorcretJiane I
75-69-4 tlLcrotrlcWoranethme75-71-8 (tlcfflorodlfluoraiBttaneT_4-43-l cnliyxiQTbrcnpiEttiane____IB1Z7-1B-4 tetracrloroettiere IP10B-68-379-01-675-01-4
toluene 1trtchloroettenevinyl chloride
(Non-Priority Pollutant Hazardous Substances)67-64-1 acetone7B-93-375-15-0
Z-tutanonecarbondisultlde
519-78 iZ-nexanone^ ttiyi-2-pemanone____IPjtyrtne "
____vinyl ace95-47-6 o-iylaie
1004.-.108-05-4
styrenevinyl acetate
019007,.,., *!««.. >U u i i 0 0
Lab 5anp1e"17D.~No.fli/y<i</>3A/J Instrument BlanKQC Report No; '"~"" ' ~
A. SURROGATE SPIKE RESULTS
COMPOUNDD4 1.2-D1ch1oroethaneD8-Toluene
.'
FRACTIONVOAVOA
CONC.(ug/l[%•/k.l
(SurrogatesAddeS (ug/1)
M-f.o*_e7e.</0
Only]RecoveryI/O(0*>
FORM 1 (continued) Data Reporting Qualifiers
For reporting results to EPA, the following results qualifiers are used.Additional flags or footnotes explaining results are encouraged. Definition ofsuch flags must be explicit, however.(a) Value - If the result 1s a value greater than or equal to the detection
limit, report the value.(b) U - Indicates compound was analyzed for but not detected. Report the
minimum detection limit value with the U, e.g., 10U, The foot-note should read: U-compound was analyzed but not detected. Thenumber Is the minimum detection limit.
(c) X - If the mass spectral data Indicate the presence of a compoundthat meets the Identification criteria but the quantitativeresults 1s less than the specified detection limit out greaterthan zero, report the detection Unit as K, e.g., 10K. The foot-note should read: K-Actual value, within the limitations of thismethod, 1s less than the value given.
(d) 1 - Indicates as estimated value which 1s used when estimating a con-centration for tentatively Identified compounds, e.g., 1200J.The footnote should read: 0 - Estimated value.
(e) Other - Other specific flags and footnotes may be required to properlydefine the results. If used, they must be fully described 1n apage attached to the data summary report.
(f) " - This flag applies to pesticides parameters where the Iden-tification has been performed using two column confirmation (asspecified In Method 608) but the level 1s too low for verifica-tion of the compound by mass spectrometry.
ynt30
019008ca:
> t
Lab Nane: _ __ Case Ho. _.Lab Sample I.D. Mo. /ift fl aftplnstriment BlankQC Report No.: ________ ___
B. TENTATIVELY IDENTIFIED COMPOUNDS
t1234567891011121314IS161718192021222324252627282930
CAS .
•
COMPOUND NAME '
ifAX "
-
HUG-BNBNBNBNBNBNBNBNBNBNACIDACIDACIDACIDACIDACIDACIDACIDACIDACIDVOAVOAVOAVOAVOAVOAVOAVOAVOAVOA
Pur. 1st.Cone.
01900?n - ,. '.. • .u u I , w..;
' QUALITY ASSURANCE NOTICE
. The volatile analysis of blank $j;!o&3{,/3-jto>is, thepresence oT the laboratory artifact slloxane tt scan "5 7? .This compound Is routinely observed as in Instrument contaminantind nay or may not actually be present 1n this sample. Slloxanehas not been listed as one of the non-priority pollutant compoundsIdentified 1n this sample.
Quality Assurance Analyst
019010cor: 5'.;
30
P.O. ft» IU, AlnMrfrli, »A XU\)
10* LEVEL LIQUID(KANICS MALTSII DATA MEH • Itg* 1 «^
I r»tory MM _ te«d Cgi»uCI«»«_ ________ CmU WlilDto.
Assodated Samples. _______•Miltiv Dittctlon Ililti ky I jor loQbrQ
p, Ion far Apogee lit* F«ettr)
KIP COMPOUNDS ' iASE/NEinm COMPOUNDS
PM CAM •Q/l fit CAM pjg/l
(7U1 H-06-? 2,4.6-1rletilerotfi«nol IOU U2BI MtM-M-t tli-(2-cMofoltOBroovll«tl«r MU(22A) »-KM Khloro-»-cr»Kil 10U (4Sfl)
I-cMoroiili«(iol __________ IOU imi J7-«-i d«xichlofol)ut l«tit ______ IOU13IA) I2?»a>-; 2,4-<lcMorotti»fio! _______ IOU Hi6) T7-n-< li«»«cMofocreloMntialtm IQU(MM 10>-fl7-< ?,4-ai»«1tnlp(i«nol _______ IQU (MB) Tl-i»-l Itottiofoni __________ IQU1»7AI M-7J-5 2-dltrDCtwol __________ MU (3581 »l-iO-i MtHtlMlini ____________ IOU(MM HXHi;-7 4-fiUroctxnol IOOU ^MBl M-»-i ullracttmrn ___________ IOU(MA) il-M-i 2.4-<lnltrotl>*nol ________ UOU (t_B) tt-Va-t IHiltrotodlplnnylmlM _____ IOU(MM -M-J2-I 4,Hlnl1ro-8iathyliih*nol MU (»3B) i71-64-7 IH>ltroMO'l-ii-»rooyl«iiiln* 20U(64A) n->t-i nnt»chloro«l)OTol ________ MU (66B1 in-«l-7 •lii;-*thyll)«xYllpl\trnlit» IOU(t>A) 10C"»S2 »t>»nol _________ IDU I67BI li-M-7 B-xtyl bturyl Hittxlttt _____ IOU
(MB) M-74-3 «l-fl-butyl M>tl-l»t» ______ IOUCNon-Prlorlty PelliitMt Hiurtfoui SUMTIIKPM) »W1 I17-«4 1 <l-«.octYl Hittalitt _____ Wu
(7081 M-ftt-? «l»ttiyl MitlaUt* ________ IOUbtntolc »elii IOOU (7IB) IM-ll-i «l»«tftvl »htMlit« _______ IOU
IOU 17881 J6-iS5 b*fna(il»nthr»Mn« _______ IOUIOU__________
i.4,.-trleMefoth*i>ol _____ IOOU 174B1 M>-«»-2 bM»oll)Hliior»nTHOT* ______ KU17MI M7-OB-9 D^io(Mfluor»nThOT« ______ MU(TM1
( It) am-t ictni.htttyit __________ JOU IIM) HO-12-7 mthr»CTM ___________ JOUJOU (TM) lll-»4-i____________
I Ml ITO-M-I l)2,4-trlcMorot)»tiint _____ JOU IIOB) Jt-TM «luomm _____________ «OUt Ml 111-74-1 (much lorotnni«ni _______ IOU 1111) iS01-« HKninthrBM __________ JOU(IB) «7-T2-l lniucMiifMtmm* ________ IOU ia«) »MO-5 <l_mio(i.h)inthric»i _____ M_(IM) 111-44-4 bltU-cMQfMttiTlHTIxr "T5u(JOB) I1-H-? 2-cMoro(Hphn«l»nt _______ IOU (M8I 1»-OIH) »yr»it« _____________ __ J2iL(H8I »-»-l 1.2-dlcMerolxKiMin ______ IOU(Mtl M1-75-1 I.HIcMorot»n»t!>« _____ IOU .Hon-rnwlty PollMtint Mttrtfwi(2TB) IQt-W-T |.4-<lcMorol)t«m»« ______ JOH.
_____H1-I4-I ..4-<H.HTOtolutn« _______ MU IDO-iW Ixnivl ilcohol _________ MU
OtB) tOt-M-t i.HlnltTDtoliuM _______ MU IOM1-a »<Morap»nlllB« ________ JW«lb»nietunn ——————————— «_,
»u n-n-t______J3M! 106-44-0 tl.or»nttMn« __________ WU H-T4-4 l^llroMllln* ________ J«_,(4081 TOOJ-T2-3 4-cMorMtxnyl nN_nvl«th«' IOU 1HH-1 l ltr-inllln* _______ _J22i(4111 lOI-iVi pt-ariaptitnfiyl »h«iyl «ttnr IOU 100-01-*
019011C- f t-"-...U Jl • t) f
30
QUALITY ASSURANCE NOTICE
This sample has low recovery for pentafluorophenol. The recoveryof the surrogate pentafluorophenol periodically dips below laboratorycontrol limits. This phenomenon 1s under Investigation. Since theother add surrogate exhibits normal recovery, the sample results havebeen reported without any additional analyses.
•7Quality Assurance Analyst
019012
30
ORSANICS ANALYSIS DATA SHEET - Page 3
Lab Name: Mead CompuChem
Lab Sample 1.0. No.• ITan
A. SURROGATE SPIKE RESULTS
COMPOUND
2-Fluorophenol
Pentafluorophenol
D6-Pfl*w>l
DS-Nltrobenzene
• Decaflorobiphenyl
2-Fluorob1pheny1
2-FluoroanU1ne
FRACTION
SEMIVOA
SEMI VOA
SEHWOA
SEMIVOA
SEMIVOA
SEMIVOA
SEMIVOA
CONC (ug/1)'
tf
lit
16H»Vn
(Surrogates only)Spike
Added (ug/1)
100
100
100 ~
100
100 .
100
100
%Recovery
tf
fff
72
<io
n^
ill
019013 1
M f» »"ie » 09
•n T\ -nKH R n
01 in * w
i
t
n MO
•fl
oo ij en
-i -n tiS ri
f> P) O
» W N
•n -n TIK n n
prt•sim?Q
/s*
iagses
•niili
iH
1
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r|,fi
i
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•»••.m ^J1 5
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ri«i<
IDENTIFIED C
iiii im*
o«
i
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019014V i'j
30
OIOXIHS,
30
U0« LEVEL LIQUID
019015001741
WGANICS ANALYSIS DATA SHEET
Lab HaM; Head CorouChein Case! _Lab SanpU l.D. Mo. I */ C > / QC Report* 1 SI , 1 1
Associated Samples 1M KQ -HI fi
A. SURROGATE SPIKE RESULTS
COMPOUND
1,2,3,4-TCDD
FRACTION
PEST
Unit ,'CONC. Area
^ ——
Surrogates onl^)Sp ke UnitAdded Area
-
•
tRecovery
iq,</
019016 <-icor_2
l«9
TOO {W-MKCHtD NA2AUOUS HAJTt)KlITOUlU
I. JDff Wl iK; mi *fr;» v±**vl I""!*"
t. litfo if ten tntinittjr m 120 t» 122te wltMnlOS if Sundird Amlyili ( ATsve-Ttov PHmN
3. Rttintfon tt« of pcik MUfM for H/t3aottlt If VE «2
4. IffMl tfi MtM OP 5>*wr, i»ry«,i > J.6" ;
I. hrcint (Ucovery Cilcvlatdn
A. teount 1,1,1,4 TOO (nM) feund In >wpli kind M irti if «/i J20uid irtttrnil iun«ir< cileulitfon to v
C. Jpfki 1ml 1.1,1,4.100: B.OOC pf
I ttMVffT • A II | jcoj - "•'""-*"" * '°C
*io<=_ I10B
I. UC fRUniltar if ktctpMntf if wrpli «I tfm nm r~] Mtin wirigi kielpMM if fwr nm calffrritlM fc~l " '
019017
30
i '•"
' ki*-tf• e -;....... o, f
?" ""'•'•
;-5 019018
IRCCEDURE RK DIAGNOSTIC RE' "''/•'ATA FILE CNOOi45v:i2ErEREN:E IFBS
METHOD IFE'S INITIALIZATION CT'ION :>• 'PORT IF&5S1
: —— STANDARDS —— :••: — PLUS UNKNOWNS --- ..:s< N.VH::.PROC USED FOSS RMI5 PROC USED TOSS KMS lit. \NUAKP i.r;,.,'v,,-.
2 2 1 0 22 S V 35 T'-l'I'-.il irfii.".2 2 1 o 2:1 n i 4* trr;;3^ urs'.'J
45 COMPOUNDS PROCESSED, 10 FOUND: COMPOUND : •: ——— ———— SEARCH --- — --- — HIM . - - - - - . OIKO •NO LIB ENTRY RIIF PRED SEL DELTA r-EAK'3 FIT ff.Ai-'j f\ :. ' :> ?f..'i VJ 1 1E2 163 193 I '»G3 UO V:'.'3 VM a 225 225 235 V <)'•.'3 VJ 3 31 34 %>1 VJ 3 59 62 A.'5 VJ 4 76 796 VJ S 47 50 ••'•>7 VJ 6 126 130 r,.-,S VJ 7 143 145 VI9 VK i 162 183 163 1 'fa.'. KU> Hi.:
10 VK 2 117 119 119 1 -I'iQ i].l n .•11 VK 3 1S7 158 10112 VK 4 171 172 s',-,13 VK 5 197 198 ,-,iIt VK 6 210 211IS VK 7 222 223 2231* VK B 237 23717 VK 9 2&1 2t,l •IS VK 10 2hfl 2bS19 VK 11 278 27820 VN 2 129 131 rill21 VN 3 235 235 M22 VN b 146 14B '!.-,23 VL 1 326 327 327 1 'i'H, l|.» p.: •24 VM 3 449 450 450 1 o«j-,< 100 4rsO '.25 VL 2 301 305 ,-,t.26 VL 1 309 31027 VL 4 320 321 ' V;IO2B VL. 5 329 329 M29 VL 6 333 33430 VL 7 333 33431 VL B 333 333 l.: •32 VL 9 3E2 363 LM33 VL 10 4Sa 429 430 I 1 UhW If, -I -I ;o34 VL 11 427 420 n. |35 VL 12 452 453 •/..'36 VL 13 475 477 U.'37 VL 14 516 31.0 UV-,3B VL 13 352 3S3 . ;, I39 VM i 326 327 32V 1 Wf, |U I.1,' ;40 VN 1 326 327 327 1 •«,•, il.l ,1,','41 VN 4 391 3r'2 rnl
V 5 421 422 -ul n , n,, , n. U1.1U1.142 VN43 m 1 371 27244 VN B ti02 60445 VN 9 tOO 6.12
li g
'JANTITATION REPORT FILE: CN001456C12
/03/MW: 2S ML i''56 •"• 5 UL (9633-1-3637)BMTi'
5/03/83 i:29 00A*?M' 2S ML i4Si - — - —— • —— •••UBMTl'TED BY: 12 ANALYST: 714
•MOUNTaAREA » REF. AMNT/tREF. AREA)» RESP. FACT):ESF FAC. FROM LIBRARY ENTRY
NO NAMEi «'BROMOCHLOROMETHANE (INTERNAL STANDARD)2 CHLOROMETHANE3 VINYL CHLORIDE1 CHLOROETHANE5 BROMOMETHANE
7 ACRYLONITRILES *BROMOCHLOROMETHANE (INTERNAL STANDARD)9 METHYLENE CHLORIDE10 TRICHLOROFLUOROMETHANEii !• 1-DICHLOROETHYLENE12 1- i-DICHLOROETHANE13 TRANS-i, 2-DICHUOROETHYLENEit CHLOROFORM15 i. 2-DICHLOROETHANE16 i, 1, 1-TRICHLOROETHANE17 CARBON TETRACHLORIOEIB BROMODICHLOROMETHANE•,° '06 BENZENE (INTERNAL STANDARD)
S-L 3-OICHLOROPROPENE.22 TRICHLOROETHYLENE23 BENZENE24 CIS-1. 3-DICHLOROPROPENE25 i, 1. 2-TRICHLOROETHANE26 DIBROMOCHLOROMETHANE27 BROMOFORM2S 1, 1, 2. S-TETRACHLORQETHYLENE29 i, 1. 2. 2-TETRACHLOROETHANE30 TOLUENE31 CHLOROBENZENE32 ETHYLBENZENE33 2-CHLOROETHYL VINYL ETHER34 «D6 BENZENE (INTERNAL STANDARD)35 »D4 i, S-OICHLOROETHANE (SURROGATE)36 KDB TOLUENE (SURROGATE)37 »D6 BENZENE (INTERNAL STANDARD!33 ACETONE (2-PROPANONE)35 2-BUTANONE
41 2-HEXANONE42 CARBON DISULFIDE43 VINYL ACETATE44 STYRENE45 0-XYLENE
SCAN TIME REF RRT METH AREA(HCHT) AMOUNT XTOT019020
G0tfw
NO M/E SCAN TIME REF RRT METH AREA(HCHT) AMOUNT '/.TOT- 130 1S2 9: IS 1 i. 800 A BB 10561, 4. 000 UG/L 12. 10
' FOUNDFOUND
4"" NOT FOUND5 NOT FOUND6 NOT FOUND7 NOT FOUND8 130 182 9:15 8 1. 000 A BB 10561. 4, 000 UC/L 12. 10 .9 84 119 6:03 8 0.654 ABB 10421, 3. 383 UC/L 10. 23- *310 NOT FOOR011 NOT FOUND12 NOT FOUND13 . NOT FOUND14 83 222 11:17 8 1.220 ABB 15832. 1, 343 UC/L 4, 67 v~-oIS NOT FOURS"16 NOT FOUND17 NOT FOUNDIB NOT FOUND19 84 327 16:37 19 i. 000 A BB 640S2. 4. 000 UC/L 12. 1020 NOT FOUND21 NOT FOUND23 NOT FOUND23 NOT FOUND24 NOT FOUND25 NOT FOUND26 NOT FOUND27 NOT FOUND2S 164 430 21:31 19 1. 315 A BB 2994. 0. 349 UG/L 1. 062WNOT FOUND3™NOT FOUND31 NOT FOUND32 NOT FOUND33 NOT FOUND34 84 327 16:37 34 i. 000 A BB 64052, 4, 000 UG/L 12, 1035 67 233 11:37 34 0.719 ABB 9308. 3, 563 UC/L 10.7836 100 450 22:32 34 i. 376 A BB 49649, 4. 2B3 UG/L 12. 9637 84 327 16:37 37 i. 000 A BB 64052, 4. 000 UG/L 12, 1038 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND45 NOT FOUND '
NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R. FAC R, FAC(L) RATIOi 9:09 1.01 1,000 1,00 4,00 4.00 1,000 1,000 1,002 1:35 0. 172 16. 00 1. 1033 3:00 0, 328 16, 00 1. 3434 3:52 0,422 16.00 0. 75BS 2:23 0. 261 16. 00 1. 7796 6:30 0.711 159,99 0,0387 7:13 0,789 159,99 0.056
9.09 1 01 1, 000 1. 00 4. 00 4, 00 1, 000 1, 000 i, 005:57 1.02 0.650 1,01 3,38 16.00 0,247 1,167 0,21
01
so
NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R, FAC R. FAC(L) RATIOIP 7 53 0. 861 16. 00 4. 907U B: 38 0, 944 16. 00 1, 315ISA 9: SB 1. 089 16. 00 0. 78213 .0:40 i. 167 16. 00 0. 9B314 11: 20 1, 00 1, 239 0. 9S 1. 55 16. 00 0. 375 3. 881 0. 10IS 12: 06 1. 322 16. 00 1. 38416 13: 22 1, 461 16. 00 3. 36217 13: 47 1. 506 16. 00 4. 304IB 14:20 1.567 16.00 0.24019 16: 46 0. 99 1, 000 1. 00 4. 00 4. 00 1. 000 1. 000 1. 0020 15: 36 0 930 16. 00 0. OB421 15:55 0.948 16.00 0.40622 16: 28 0. 982 16. 00 0. 46323 16:36 1. 009 16, 00 0. 63824 17:11 1. 024 16. 00 0. 17925 17:11 1.024 16.00 0.17226 17:05 i. 018 16,00 0.26127 19:43 1.176 16.00 0.135HB Si: 51 1. 00 1. 303 1. 01 0. 35 16, 00 0, 012 0. 335 0. 0239 Si: 51 1.302 16,00 0.13630 23:05 1.376 16.00 0.53931 84:15 1.445 16.00 0. 85B33 26:20 1.570 16.00 0.38233 18:09 1.082 16.00 0.07034 16: 46 0. 99 1. 000 1. 00 4. 00 4, 00 1, 000 1. 000 1. 0035 12:00 1. 00 0. 715 1, 00 3. 36 4. 00 0. 145 0. 163 0. 8936 22:56 1. 00 1. 367 1, 01 4. 29 4, 00 0. 775 0. 724 1. 0737 16:46 0.99 1.000 1,00 4,00 4.00 1,000 1.000 1.003fA 6: 30 0. 388 120, 00 0. 00339* 12:03 0. 716 120.00 0,0.0440 20:08 1. riOO 120.00 O. 02341 21:33 1. 285 120.00 0.02042 7., 22 0.439 16.00 0.87043 13:59 0.833 16,00 0,20244 30:45 1, 833 16, 00 0, 75045 32:11 1, 91S 16.00 0.489
019022
COMPUCHEM NO.______ DATE
IDENTIFIER VOA •-LOH LEVEL.LIQUID
0 COMPOUND LIST - NO. ___ (Page One of Two)COMPUCHEMCOMPOUND QUANT.REPORT CORRECTION DETECTION
COUNTER NUMBER COMPOUND NAME_______VALUE x FACTOR . • RESULT LIMIT (ug/1)2. 221 CHLOROMETHANE ............. ____ ____ ___ -5-|3. 231 VINYL CHLORIDE ............ ____ ____ ___ . "VI4. 209 CHLOROETHANE
'5. 220 BROMOMETHANE6. 201 ACROLEIN .................. ____ ____ ___ Wfr"ZO7. 202 ACRYLONITRILE ............. ____ ____ ___ WO^O8. 222 METHYLENE9. 230
. 10. 21611. 21412. 226 TRANS-1.2-DICHLOROETHYLENE ____ ____ ___ -6- I13. 211 CHLOROFORM ................ 1.5" ____ ._/.£", -5- '14. 215
£15. 22716. 20617. 21218. 21719. 25020. 22921. 203 BENZENE ................... ____ ____ ___ *- I22. 218 CIS-1,3-DICHLOROPROPENE ... ____ ____ ___ W- 223. 22824. 20825. 20526. 22427. 223 1,1,2,2-TETRACHLOROETHANE . ____ ____ ___ -* '28. 225 TOLUENE29. 207 CHLOROBENZENE30. 219 ETHYLBENZENE31. 210 2-CHLOROETHYL VINYL ETHER . ____ ____ ___ Jr\34. 252 ACETONE (2-PROPANE) ....... ____ ____ __019> :w
PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON SECOND SHEET OF THE COMPOUND LIST 11OQI74D
30
COMPUCHEM NO.______ DATE_____
A IDENTIFIER VOA - LOW LEVEL LIQUID
COMPOUND LIST - NO. ___ (Page Two of Two)COMPUCHEMCOMPOUND QUANT.REPORT CORRECTION DETECTION
COUNTER _ NUMBER COMPOUND NAME_____ VALUE x FACTOR, » RESULT LIMIT (ug/U39. 253 2-BUTANONE ................ ____ ____ ___ -266 VO40. 256 4-METHYL-2-PENTANONE ...... ____ ____ ___ WO Z&41. 255 2-HEXANONE ................ ____ ____42. 254 CARBON D1SULFIDE ..........43. 257 VINYL ACETATE ............. ____ ____ ___ W244. 251 STYRENE ................... ____ ____ ___ «• '45. 239 o-XYLENE .................. ____ ____ ___ "H
Correction Factor Calculation:(Use ONLY 1f factor affects all data, otherwise use correct calculation sheet.)
019024001750
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30
MEAD COMPUCHEh>iSS LIST . DATA; BF830502B12 tt 174 BASE IVE. 955/02/8317:56:00+ B: Si RIC; 6937faJiMPLE: 2UU BFBtt8676foATO #175 SUMMED - #35 XI. 00
37 0. 00 MINIMA MIN INTEN; 0. MAX INTEN: 14064.367 # 0 MAXIMA
1ASS V. RA'
37 6, BO38 5, 7039 3, 0940 0, 4745 1. 324"? 3. 5950 22. SB51 6, 785S 0. 4156 i. 6857 4. 5161 4 456S 4. 4163 3, 156B 13. 7869 13. 9173 7. 9171 20. 2B75 59 5076 4. 97
4. 2S3. 49
BB 4. 0792 2. 2193 3. 4594 12. 4395 100. 0096 6. 44174 78. 16175 4 2°176 77 25177 5 M267 2. 27
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'ROCEDURE: RK DIAGNOSTIC REPORT &/0&/B3 IB:04:443 AT A FILE: OHOOMSd-BU*EF--1ENCE: FSCC6
.THOD: FSCCfr INITIALIZATION OPTION: 2 PROCESSIN8 OPTION: 3REPORT: FSCCfrS
C —— STANDARDS ——— X —— PLUS' UNKNOWNS —— X - LIST NAMES - >PROC USED PQSS RMS PROC USED POSS RMS STANDARD/UNKNOWN
4 4 1 £7 79 17 1 110 FSCC6S/FSCC6U
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LIB ENTRYFlF3F2F4FlFlFlFlFlFlFlFlFlFlFlFl 'FlFlFlFlFlFlFlF2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2F2
1111234967891011121314191617181920234967891011121314151617181920SI82S3242526
REF-794-1699-1068-2176-470-795-782-BIO-819-843-851-882-874-899-892-934-916-655-782-946-967-778-1264-923-949-9BB-1004-1008-1026-1043-1060-1071-1033-1102-1167-1195-1235-1290-1283-1360-1349-1071-1429-1487-1402-1309-1423-1S03
am ?** ™'PRED SEL DELTA PEAKS FIT PEAKS M/E71' 1 7911657 16971065 1069S174 2174466791778806815B40848879671896889931913691 649' -2778 780 2943 943964 969 1774 772 -21261 1262 19209469891001100910231040109710681030109911641192123212471280135713421068142714851399130614211501
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3UAMTITATION REPORT FILE: OH0014S6B16
DAT/1.:. GH001456B16. TI39/ >83 16:57:00SAMPLE: 1UL 1456 5-3-19S3SUBMITTED BY: 016 ANALYST: 727
>il1QUNT=AREA * REF. AMNT/(REF. AREA)* RESP. FACT)FAC, FROM LINEAR FIT TO WHOLE , RL
NQ NAME1 #624 D3-PHENOL (INTERNAL STANDARD)2 441 N-NITROSODIMETHYLAMINE3 610 PHENOL4 473 ANILINE9 411 BISC2-CHLOROETHYL)ETHER6 601 2-CHLOROPHENOL7 421 1> 3-DIGHLQROBENZENEB 422 1,4-DICHLQRQBENZENE9 420 1,2-DICHLQRQBENZENE10 474 BENZYL ALCOHOL11 412 BIS<2-CHLDROISOPRQPYL)ETHER12 620 2-METHYLPHENOL13 436 HEXACHLORQETHANE14 622 4-METHYLPHENOL19 41619 2-FLUOROPHENOL (SURROGATE STANDARD)16 #623 PENTAFLUOROPHENOL (SURROGATE STANDARD)17 0447 D9-NITROBENZENE (SURROGATE STANDARD)18 , #470 DECAFLUOROBIPHENYL (SURROGATE STANDARD)1S: '#472 S-FLUOROANILINE (SURROGATE STANDARD)20 #448 S-FLUOROBIPHENYL (SURROGATE STANDARD)21 *460 OS-NAPHTHALENE (INTERNAL STANDARD)22 442 N-NITRQSQ-DI-N-PROPYLAMINE23 440 NITROBENZENE24 438 ISQPHORONE25 606 2-NITRQPHENQL26 603 2.4-DIMETHYLPHENQL27 410 BIS(2-CHLOROETHOXY)METHANESB 602 2,4-DICHLDROPHENQL29 446 li2>4-TRICHLOROBENZENE30 475 4-CHLORQANILINE31 625 BENZOIC ACID32 434 HEXACHLQRDBUTADIENE33 60S P-CHLORO-M-CRESOL34 477 2-METHYLNAPHTHALENE39 439 HEXACHLORQCYCLQPENTADIENE36 611 2,4,6-TRICHLORQPHENQL37 416 2-CHLORONAPHTHALENE38 402 ACENAPHTHYLENE39 425 DIMETHYLPHTHALATE40 439 NAPHTHALENE41 428 E, 6-DINITRQTOLUENE42 427 2,4-DINITRQTQLUENE43 479 3-N1TROANILINE44 478 2-NITRQAN1LINE4r 476 DIBENZOFURAN 01904316-'-180 4-NITRQANILINE
0317GUso
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47,_.S626 2,4,9-TRICHLOROPHENOL46, V467 D10-PHENANTHRENE (INTERNAL STANDARD)49 401 ACENAPHTHENE90 609 2,4-DINITROPHENOL51 607 4-NITROPHENOL92 432 FLUORENE93 417 4-CHLORQPHENYL PHENYL ETHER94 424 D1ETHYLPHTHALATE ,95 604 4,6-DINITRQ-Q-CRESOL56 443 DIPHENYLAMINE97 414 4-BRQMOPHENYL PHENYL ETHER98 433 HEXACHLQRQBENZENE59 444 PHENANTHRENE60 403 ANTHRACENE61 431 FLUORANTHENE62 445 PYRENE63 430 1,2-DIPHENYLHYDRAZINE (AZOBENZENE)64 426 DI-N-BUTYLPHTHALATE65 609 PENTACHLORQPHENQL66 t459 D12-CHRYSENE (INTERNAL STANDARD)67 409 BENZQtA)ANTHRACENE6B 418 CHRYSENE69 4S3 3,3'-DICHLORQBENZIDINE70 419 BUTYLBENYLPHTHALATE71 413 BIS(2-ETHYLHEXYL)PHTHALATE72 429 DI-N-OCTYLPHTHALATE??. 404 BENZIDINE7>' '406 BENZO(A)PYRENE79 437 INDENOU.2,3-C.DJPYRENE76 419 DIBENZO(A,H)ANTHRACENE77 40B BENZO(G, H, DPERYLENE78 407 BENZQ(8)FLUORANTHENE79 409 BENZD(K)FLUORANTHENE
NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT
019044 J001771}
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NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT1 •--> 97 790 9:92 1 1.000 A BV 37391. 20.000 NS 9,98'2 NOT FOUND3 94 791 9:93 1 1.001 ABB 1710. 0.883 NG 0.294 NOT FOUND9 NOT FOUND6 NOT FOUND7 NOT FOUND8 NOT FOUND9 NOT FOUND10 NOT FOUND11 NOT FOUND12 NOT FOUND13 NOT FOUND14 NOT FOUND19 112 649 8:07 1 0.822 A BV 51994. 33.231 NG 9.27 "16 184 780 9:49 1 0.987 ABB 811.' 1.171 NG 0,33 '17 82 943 11:47 1 1.194 ABB 83832. 42, 919 NO 11,86-IB 334 965 12:04 1 1, 223 ABB 50971. 67.730 NG 18,89'19 111 772 9:39 1 0.977 A BV 41913. 36,708 NG 10,24'SO 172 1262 19:46 1 1.997 ABB 134948, 61, 443 NO 17.1421 136 1069 13:19 SI 1.000 ABB 66S43, 20,000 NG 9. 98 '•22 NOT FOUNDS3 NOT FOUND24 NOT FOUND29 NOT FOUND26 NOT FOUND27 -NOT FOUNDSB NOT FOUND29 NOT FOUND30 NOT FOUND31 NOT FOUND32 NOT FOUND33 NOT FOUND34 NOT FOUND39 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND i39 163 1342 16:46 21 1,260 ABB 1400. 0.691 NG 0,1940 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND45 NOT FOUND46 NOT FOUND47 196 1S99 19:41 21 1.178 ABB 1023, 1.696 NG 0,464B 188 1697 20:43 4B 1.000 ABB 470B9. 20. 000 NG 9. 98 c49 NOT FOUND90 NOT FOUND91 NOT FOUND52 NOT FOUND53 NOT FOUND niQnjr94 149 1471 18:23 48 0.888 ABB S8B9, 1.209NG 0.34 UJ.y(J 4 095""'NOT FOUND56 169 1906 18:49 48 0.909 ABB 449, 0.968 NG 0,27
G,'1. t "'" I«.) I i { 1
57.. NOT FOUND51 NNOT FOUND99 178 1661 30:46 48 1, 002 A BB 477. 0, 200 NG 0. 0660 178 1670 20:92 48 1, 008 A BB 333. 0, 161 NG 0. 0461 202 1882 23:31 48 1.136 ABB 1499. 0. 6B9 NG 0.1963 202 19S4 34:03 48 1.161 ABB 1308. 0,581 NQ 0.1663 NOT FOUND64 149 1768 28:06 4B 1. 067 A BB 9539. 1. 949 NG 0. 4369 366 1633 20:29 48 0,986 ABB 395, 1.300 NQ 0.3666 240 2174 27:10 66 1.000 A BV 77109. 40. 000 NG 11.1667 228 2168 27:06 66 0.997 A BV 818. 0, 379 NG 0. 1168 328 2181 37:16 66 1.003 ABB B98. 0. 429 NG 0,1369 NOT FOUND70 149 2049 25:34 66 0,941 ABB 540. 0. 384 NG 0.1171 149 2176 27:12 66 1.001 A VB 4321. 1. 697 NG 0.4772 149 2368 29:36 66 1.089 ABB 9141. 2.879 NG 0.8073 NOT FOUND74 NOT FOUND75 NOT FOUND76 NOT FOUND77 NOT FOUND78 392 3527 31:39 66 1,162 ABB 487. 0.272 NQ 0.0879 292 2539 31:44 66 1,168 A VB 198. 0. Ill NG 0.03
MO RET(L)1 9:95P. 9:52 0.993 50.00 0.731 ;
9:56 0,99 1,001 1.00 0,88 50,00 0,018 1,036 0.024 ' 9:46 0.989 50.00 . 0,2129 10:07 1,030 50.00 0.992 ' t6 10:14 1.031 50.00 0.886 ]f7 10:32 1,062 90,00 0.806B 10:38 1,072 50,00 0,9389 11:01 1.111 90,00 0,69710 10:59 1.101 30,00 0,39211 11:14 1.132 90.00 0,30013 11:09 1.133 30.00 0.66013 11:40 1,176 90.00 0. 43S14 11:37 1.194 90,00 0.63019 8:11 0,99 0.825 1,00 33.33 50.00 0,556 0,836 0.6616 9:46 1.00 0,909 1,00 1.17 50.00 0,009 0.370 0.0217 11:49 1.00 1,191 1,00 42.92 90.00 0,897 1.099 0.85IB 12:05 1,00 1.218 1,00 67,73 50.00 0.945 0,403 1,3919 9:43 0.99 0,980 1,00 36,71 50,00 0.444 0,605 0.7320 15:48 1.00 1.992 1,00 61.44 90.00 1.444 1,175 1.2321 13:21 1.00 1.000 1,00 20,00 20,00 1.000 1.000 1.00S3 11:32 0.864 80. 00 0,07823 11:52 0.889 50,00 0.22924 12:21 0.929 50.00 1.01125 12:33 0,940 50,00 0.23926 12; 36 0.944 50.00 0,37527 12:49 0,961 50.00 0.49428 13:02 0,977 SO. 00 0.3143' 13:15 0,993 50,00 0.330 Ol^d/lR ol3_- 13:23 1.003 250,00 0,069 U0.3U U31 12:59 0.967 290,00 0.332 n .-. v f-.->
V vl J. i ( (,.
3P-,13;46 1,032 90.00 0.2093w 14:39 1.093 90.00 0.44134 14:56 1.119 50.00 0.39435 19:26 1.156 50.00 0.15936 19:37 1.170 90.00 0.20837 16:02 1.201 90.00 0.65438 17:00 1.373 50.00 0.46639 16:49 1.00 1.359 1.00 0.69 90.00 0.008 0.612 0,0140 13:23 1,003 90.00 1.36441 17:52 1.33B 50,00 0.24042 18:39 1. 392 90. 00 0.63943 17:31 1,313 290,00 0.00644 16:22 1.286 290.00 0.22645 17:47 1. 332 90,00 0,79846 18:47 1.407 290.00 0.03347 19:43 1.00 1.177 1.00 1,66 250.00 0.001 0,187 0,0148 20:44 1,00 1.000 1,00 20.00 20.00 1.000 1.000 1,0049 17:26 0.841 90.00 0,94990 17:31 0,845 290.00 0.11991 17:38 0.891 135.00 0,15092 18:35 0,896 50.00 0.96253 18:34 0,895 50.00 0,36894 18:25 1.00 0. BBS 1,00 1.21 50,00 0.025 1.015 0.0299 IB: 48 0.907 250.00 0, IBS56 18:49 1.00 0,907 1,00 0,97 50,00 0.004 0.197 0.0257 19:40 0.949 90, 00 0.2219P 20:01 0,966 . 50.00 0, SBO5 20:47 1.00 1.002 1,00 0,20 90.00 0.004 1.014 0.0060 20:54 1,00 1,008 1,00 0,16 50.00 0.003 0,881 0,0061 23:33 1,00 '1.136 1,00 0,68 90,00 0,012 0,909 0.0162 24:09 1,00 1,163 1.00 0,98 50.00 0,011 0.956 0.0163 18:55 0.913 90.00 1.49664 22:07 1.00 1.067 1.00 1.94 50.00 0.047 1,520 0,0369 20:29 1.00 0.985 1.00 1.30 50.00 0.003 0,116 0,0366 27:12 1,00 1.000 1.00 40,00 40.00 1,000 1,000 1,0067 27:08 1,00 0,998 1.00 0.38 90.00 0.008 1.120 0,0168 27:17 1,00 1,003 1.00 0.43 90.00 0.009 1,086 0,0169 27:09 0,996 90.00 0.01470 29:34 1.00 0.940 1, 00 0, 38 90.00 0.006 0, 730 0.0171 27:14 1.00 1.001 1.00 1.70 90.00 0.049 1,321 0.0372 29:37 1,00 1,089 1.00 2,87 90.00 0.099 1,690 0.0673 23:99 0,862 190,00 0. 00574 33:28 1.230 90.00 0.65879 42:04 1.546 90.00 0.31276 42:20 1.997 50.00 0. 39477 44:39 1.639 90.00 0.3847B 31:38 1,00 1.163 1.00 0.27 50.00 0.005 0. 928 0.0179 31:46 1.00 1,168 1.00 0.11 90.00 0,003 0.934 0,00
30
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019047 *•:!
——————— IDENTIFIER SEHI-VOLAT1LES - LOW LEVEL LIQUID
, COMPOUND QUANT.REPORT CORRECTION DETECTIONCOUNTER ' NUMBER COMPOUNDS______ VALUE x FACTOR • RESULT LIMIT (ug/1).J 441 N-NITROSODIMETHYLAH1NE ..... ____ ____ fj" 20
V3 610 PHENOL ..................... ____ ____ ___ 204 473 ANILINE .................... ____ ____ ___ 205 411 B1S(2-CHLOROETHYL)ETHER .... ____ ____ ___ 206 601 .2-CHLOROPHENOL ............. ____ ____ ___ 207 421 1,3-DICHLOROBENZENE ........ ____ ____ ___ 208 422 1,4-DICHLOROBENZENE ........ ____ ____ ___ 209 420 1,2-DICHLOROBENZENE ........ ____ ____ ___ 2010 474 BENZYL ALCOHOL ............. ____ ____ ___ 4011 412 BIS(2-CHLOROISOPROPYL)ETHER. ____ ____ ___ 4012 620 2-METHYLPHENOL ............. ____ ____ ___ 2013 436 HEXACHLOROETHANE ........... ____ ____ ___ 2014 622 4-METHYLPHENOL ............. ____ ____ ___ 2022 442 N-NITROSO-DI-N-PROPYLAMINE . ____ ____ ___ 4023 440 NITROBENZENE ............... ____ ____ ___ 2024 438 ISOPHORONE ................. ____ ____ ___ 2025 606 2-NITROPHENOL .............. ____ ____ ___ 4026 603 2,4-DIMETHYLPHENOL ......... ____ ____ ___ 20
410 BIS(2-CHLOROETHOXY)HETHANE.. ____ ____ ;___ 4028 602 2,4-DICHLOROPHENOL ......... ____ ____ ___ 2029 446 1,2,4-TRICHLOROBENZENE ..... ____ ____ ___ 2030 475 4-CHLOROANILINE ............ ____ ____ ___ 10031 625 BENZOIC ACID ............... ____ ____ ___ 20032 434 HEXACHLOROBUTADIENE ........ ____ ____ ___ 2033 608 P-CHLORO-M-CRESOL .......... ____ ____ ___ 4034 477 2-METHYLNAPTHALENE ......... ____ ____ ___ 4035 435 HEXACHLOROCYCLOPENTADIENE .. ____ __.__ ___ 2036 611 2,4,6-TRICHLOROPHENOL....... ____ ____ ___ 2037 416 2-CHLORONAPHTHALENE ........ ____ ____ ___ 2038 402 ACENAPHTHYLENE ............. ____ ____ ___ 2039 42P DIMETHYLPHTHALATE .......... ____ ____ ___ 2040 439 NAPHTHALENE ................ ____ ____ ___ 2041 428 2,6-DINlTROTOLUENE ......... ____ ____ ___ 4042 427 2,4-DINITROTOLUENE ......... ____ ____ ___ 4043 478 2-NITROANIL1NE ............. ____ ____ ___ 200-44 480% 3-N1TROANILINE ............. ____ ____ ___O^fl'ffS
476 DIBENZOFURAN ............... ____ ____ ___J C,"!''i20/ !
PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON SECOND SHEET OF THE COMPOUND LIST!!30
COMPUCHEM HO. ______ DATE ______ t 01 tSOMPOUNO'UST NO. ____
———— IDENTIFIER SEMl-VOLATILES LOH LEVEL LIQUID
COMPOUND QUANT. REPORT CORRECTION DETECTIONjyrJTJR HUHB COMPOUNDS _______ VALUE X FACTOR • RESULT LIMIT Jug/I]~"« 479 4-HITROANILINE ................... ____ ____ /•'• 200
47 626 2,4,5-TRICHLOROPHENOL ............ ____ ____ ____ 20049 401 ACENAPHTHENE ..................... ____ ____ ____ 2050 M5 2,4-DINITROPHENOL ................ ____ ____ ____ 10051 607 4-N1TROPHENOL .................... ____ ____ ____ 20052 432 FLUORENE ......................... ____ ____ ___ 2053 417 4-CHLOROPHENYL PHENYL ETHER....... ____ ____ ____ 2054 424 D1ETHYLPHTHALATE ................ ____ ____ ____ 2055 604 4,6-DINITRO-O-CRESOL ............. ____ ____ ____ 4056 443 DIPHENYLAMINE (N-N1TROSO) ........ ____ ____ - ____ 2057 414 4-BROMOPHENYL PHENYL ETHER ....... ____ ____ ____ 2058 433 HEXACHLOROBENZENE ................ ____ ____ ____ 2059 444 PHENANTHRENE ..................... ____ ____ ____ 2060 403 ANTHRACENE ....................... ____ ____ ____ 2061 431 FLUORANTHENE ..................... ____ ____ ____ 2062 445 PYRENE ........................... ____ ____ ____ 2063 430 1,2-DIPHENYLHYDRAZlNE (AZOBENZENE) ____ ____ ____ 40-4 426 OI-N-BUTYLPHTHALATE .............. ____ ____ 1. ____ 2065 609 • PENTACHLOROPHENOL ................ ____ ____ ___ ^ 4067 405 BENZO(A)ANTHRACENE .............. ____ ____ ____ 2068 418 CHRYSENE ......................... ____ ____ ____ 2069 423 3,3'.DICHLOROBENZIOINE ........... ____ ____ ____ 4070 415 BUTYLBENZYLPHTHALATE ............. ____ ____ ____ 2071 413 B1S(2-ETHYLHEXYL)PHTHALATE........ ____ ____ ____ 2072 429 Dl-H-OCTYLPHTHALATE .............. ____ ____ ____ 2073 404 BENZJDINE ........................ ____ ____ ____ 8074 406 BENZO(A)PYRENE ................... ____ ____ ___ 4075 437 INDENO(1,2,3-C,D)PYRENE .......... ____ ____ ____ 4076 419 OIBEHZO(A,H)ANTHRACEHE ........... ____ ____ ___ 4077 4<k BENZO(e,H,I)PERYLENE ............. ____ ____ ____ 4078 407 (EHZO(B)FLUORAHTHENE ............. ____ ____ ____ 4079 409 IENZO(K)FLUORANTHENE ............. t _____ ____ __ £_ 40
Instrutent Code 239 - Correction Factor CilculitlonFinal extraction volum; (ml ) 1000 _______ Dilution Conversion\5ml for Af, l.0ml for B/N * Volume of Simple Used (ml) x Factor * z • Factor'.____ l ,'dnl) 1000 ,"B75 or 1.0 (ml) * ," (BIJ x ————— * z •
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•ROfEDURE: RK DIAGNOSTIC REPORT 3/11/83 12:03:33JATA FILE: TC001456AQ4(EFFJ2ENCE: TC
' ,HOD: TC INITIALIZATION OPTION: Z PROCESSING OPTION.' 3REPORT! TCS
; ——— STANDARDS ———— X —— PLUS UNKNOWNS —— X - LIST NAMES - '.<PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN
2 2 6 13 7 S 2 103 TCS/TCU
7 COMPOUNDS PROCESSED. 5 FOUND
C COMPOUND X ————————— SEARCH —————————— X SAT X ———— CMRO ————— :•NO LIB ENTRY REF 'PRED SEL DELTA PEAKS FIT PEAKS M/E TOP DELTA PEAKS1 TC 1 734 762 762 . 2 833 . 322 762 . 12 TC 2 737 745 745 . 3 995 . 3£fl 745 . 13 TC 3 727 745 745 . 1 995 3SS 745 . 14 TC 4 737 745 745 . 1 995 £27 745 . 15 TC 5 755 763 . . . , . 3206 TC 6 753 763 . . , . . 352 .7 TC 7 755 763 762 -1 a 962 . £27 761 -1 1
MEAD COMPUCHEM3UANTITATXON REPORT FILE: TC001456A04
3A'', ' TC0ei456A04. TI35/11/83 11:33:00SAMPLE: 2UL TCDD SAMPLE »1456 (5/5/83) ON tt4SUBMITTED BY: 04 ANALYST: 719
>iMOUNT=AREA<HGHT) * REF. AMNT/ (REF. AREA (HCHT)* RESP. FACT)FAC. FROM LIBRARY ENTRY
NO NAME1 #13C12-2, 3i 7. 8-TCDD2 L 2, 3, 4-TCDD3 1, 2, 3, 4-TCDD4 1, 2, 3, 4-TCDD5 2, 3, 7, 8-TCDD6 2, 3, 7, B-TCDD7 2, 3, 7, 8-TCDD
NO M/E SCAN TIME REF RRT METH AREA(HOHT) AMOUNT 7.TOT1 33S 762 17: 04 1 1, 800 A BV 3144890, 200. QUO PC 46, 962 320 745 16: 41 1 0, 978 A BB 775647, 72. 8E1 PC/UL 17. 093 323 745 16: 41 1 0. "778 A BB 957919. 73. 323 PC/UL 17. 194 257 745 16: 41 1 0, 978 A BB 385663. 74, 894 PC/UL 17. 565 NOT FOUND6 NOT FOUND7 257 761 17:03 1 8.999 A VB 26784. 5.371 PC/UL l! 26
Nl RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R, FAC R. FAC(L) RATIO.1 17:00 1,00 1,000 1,00 200.00 200.00 1.000 1,000 1,002 16:35 1,01 0,976 1,00 72,88 200.00 0.247 0,677 0,363 16:35 1.01 0.976 1,00 73.32 200.00 0.305 0.831 0,374 16:37 1,00 0,977 1,00 74.89 200.00 0,123 0,327 0,375 17:01 1.001 200,00 0. 3296 17:00 1,000 500,00 0.7147 17:01 1.00 1,001 1,00 5,37 200.00 0,009 0,317 0.03
019071
3,
i !
a? 8P BP 8
e05
a-
5 w -.1JiU) 03oven *
r ( . ' V I , ' *
y / ' '
''7 i •"
,.-'//
«»«:
a§lH OQ o
ljQ 13* 1/1
8
1
§S
" ''4 ,ffisn??H. rt- H1 O "' -ffV-tt JS K 8 S M S wurtyw
en hfci tri (o h3 10 (& GI **j ® "**' '• i J—« • l (T| • • ttl • • CElui ra cri ui ci ui ui ffl o-i y <S| Wcs UP b:< si UP en cci UP ra £' • t-'(OUi • (Si OT • (CO'1 • <9 "J •
30
RI1PLITUDE y..25 uV-seeonds [Enlar(i*d >. 6.681
* 8 g o gt o 3 9 SN.
SoS1*crrOPVI
"
5»TJrn ,3,w-2 o3T3
IDpt> P-«
olna,j,
w .EP W0 0
-12m
[IP Us M w
4«"S °
a -i '„"9S^1 3
Si"' M« »
Ul
M
"10
ro
1C
r, PS. * '-•£ S * o
.I,
3.151
) 4.73i(
ij1'l
) 9.76|
-
*
,
*
13. S5
IS. 0S
\ 17.96
. 1 • p — — — i — — — i — — — i — — — p.
0190700170!,!
C'
Column BColumn A_
Capillary Column OB-5 30M1 5% 2250/1.95* 2401 Supelco yff ! then 210 at 20Eon*. 190. I50thermal hold 1 then 250 at 3 hold 20AP/CH4, 25 ce/Bln. ftr/CH4, 50 cm/sec
IB Alpha-BHC1A Alpha-BHC 2B Beta-BHC2A Beta-BHC 3B Garona-BHC3A Sama-BHC 4B Heptachlor Epoxlde4A Heptachlor Epoxlde 5B Alpha-Chlordane5A Alpha-Chlordane 6B p,p'-DDE6A P.P'-DDj- - - - -7A p,p'-ODD8A n.p'-DDT9A Endosulfan SulfatePrn^ n?66 Standard——— 10B Delta-BHCIDA Delta-BHC 11B HeptachlorHA Heptachlor . 1UB Aldrln2A Aldrln 13B Delta-Chlordane13A nelta-Chlordane ' 14B Endosulfan Ie -14A Endosulfan 1 • 15B Dleldrln u n |5A Dieldrln 16B Endrln and Endosulfan n ,*16A Endrln 17B Endrln Aldehyde 8.
'17A Endosulfan IIISA Endrln Aldehyde
019074
CGK.O;:
FWPLITUDE x.2S uV-feccmds (Enlarged x 2.3?)
019n.7o
V \
RHPLITUDE x.2S uV-seconds [Enlarged /. 2. 51)
3 1 1 *
13rn ,j,ro
('! 15,
JW
»n
um
n CP
30
// i" I ,'v t
RI1PLITUDE x.25 uV-seconds (Enlarged x .81)p- io
019077
v ;
DETECTION LIMIT SUMMARY FORVOft OF HAZARDIOUS SUBSTANCE LIST COMPOUNDS
Mead CompuChem*
Compound I.D,Bromocnlorometnane (IS)CnloroetnaneVinyl tnlorldeuiloroetnaneBromometnaneAcroleinAcrylonitrileMetnylene CnloriaeTncnlorotluorometnane1,1-DJcnloroetnylene1,1-IOicnloroetnane1,2-Trans-DicnloroetnyleneCnloroform1,2-Oicnloroethane1,1,1-TrlcnloroetnaneCarDon tetracnlorlde"•"omoaicnlorometnane
*-uicn)oroDutane (IS)1,2-DlcnloropropaneTran5-1.3-D1cnloropropyleneTricnloroetnyleneBenzene115-1,3-01 cMloroproijene1,1.2-Tricnloroetnane1, 2-DiDromocnlorometnaneBromoform1,1,2,2-Tetracnloroetnylenel,l,_,<!-TetracnloroetnaneTolueneChlorooenzeneEtny oenzene2-Cn' oroetnyl vinyl etner"4-1.2 Oicnloroetnane (Surr.)ulu- benzene llnt.Std.)°b " Toluene (Surr.)Acetone2-Butanoneu-Mp;tnyl-<;-Pentanone2-HexanoneCaroon dlsulfldeVinyl acetateStyrene0-Xylene
Low Level WaterDetection Limits
(ug/l)«
ba56
1001UO
bbb5b5bSbb
bbbb10b5bbbbbbb
IOU2001001001010b5
Low Level SolidDetection Limits
(ug/kg)*
2.52.52.b2.b
b'ObU2.b2.52.b2.52.b2.52.52.52.62.5
2.52.52.52.55.02.52.52.52.52.52.52.52.62.5
50100bU50b52.52.5
Medium LevelDetection Limits
(ug/g)*
555b
1001005555555555
5555105555b555b
1002001001001010b5
J x StandardDeviation
ng on-column
1112
IS362123434223
41242
1132111111
la83013
0190792 .2
•.timated MDL,-SigmaDL COIC.fM
30
DETECTION LIMIT SUMMARY FORSEMIVOLAT1LE HAZARD10US SUBSTANCE LIST COMPOUNDS
Compound l.D.
"li-PHENUL (IS)N-NITROSODIMETHYLAMINEPHENULANILINEBlS(i!-CHLOROETHYL)ETHEK2-UHLOROPHENOLl,3-DICnLORl)6EIUENE1,4-DICHLOROBENZENE1,2-PlCHLOROBENZENEBENZYL ALCOHOLB1SU-CHLOR01SOPROPYDETHER2-METHYLPHENOLHEXACHLORUETHANE4-METHYLPHENOL2-FLUOROPHENOL (Surr.)
r "ENTAFLUORUPHENOL (Surr.)L 'b-PHENUL. (Surr)^•NITROBENZENE (Surr,)DECAFLUUROB1PHENYL (Sum.)2-FLUOROAN1L1NE (Surr)2-FLUUROB1PHENYL (Surr)U6- NAPHTHALENE (IS)iVNlThOSO-lil-N-PROmAMlNENITROBENZENEISOPHORUNE2-MTRUPHENUL2.4-01METHYLPHENOLlilS(2-CHLOROETHOXY)METHANE2,4-UKHLOROPHENOL1,2,4-TRlCHLOROUENZENE4-CHLORUANILINEBEN201C ACIOHEXACHLOKOBUTADIENEP-CHLURU-M-CHESOL2-METHYLNAPTHALENEHEXACHLOROCYCLUPENTftDlENE2,4,6-TRICHLOROPHENOL2-CHLORUNAPHTHALENEACENAPHTHYLENEDIMETHYLPHTHALATENAPHTHALENE2,b-UlNlTROTOLUENE
Mead CompuChem8Low Level waterDetection Limit
(ug/1)*
2020202020202020204040202020
" 4020204U2U4020201UU20020404020202020202040
Low Level SolidDetection Limit
(ug/Kg)*
4004UO400400400400400400400800800400400400
8004004UO80040080040040020004000400800BOO400400400400400400800
Medium LevelDetection Limit
(ug/g)*
1010101010101010102020101010
2010102010201010bO10010202010101010101020
3 x StandardDeviation**
ng on-column
34106454448343
843226bb
271010437104365-4
.sti mated MuL«*3-S1gma DL
DETECTION LIMIT SUMMARY FORSEM1VOLAT1LE HAZARDIOUS SUBSTANCE LIST COMPOUNDS
Compound l.D.1 2.4-D1NITRUTOLUENEp 2-N1TRUAN1L1NE3-NlTKOANILlNEDlBElUOFuRAfl" "4-N1TROAHILINE2,4,5-TRlCHLOROPHENOL"10-PHENANTHRENE (IS)ACEHAPHTHENE2,4-DlNITROPHENOL4-N1TROPHENOLFLUORENE4-CHLOROPHENYL PHENYL ETHERUIETHYLPHTHALATEt.b-DlNITRO-O-CRESOLDlf""-NYLAI1INE (N-N1TROSO)t-1 inurtltiiiL PHENYL ETHERHEXACHLUROBENZENEPHENANTHRENEANTHRACENEFLUURANTHENEPYRENt1,2-DIPHENYLHYDRAZlNE (AZQBENZENEDl-N-BUTYLPHTHALATEPENTrtCHLUROPHENOLQ12-CHRYSENE (IS)'BEhZUIA ANTHRACENECHRYSENE3,3'-01CHLURUBENZlUlNEBUTYLBEHZYLPHTHALATEBIS(2-ETHYLHEXYL)PHTHALATEDl-N-UCTYLPHTHALATEBENZ1D1NEt)ENZU(A PYRENEINDENUt ,2,3-C,D)PYRENEDlBENZUlA.H, ANTHRACENErifcin.u(fi,h,I PWYLENEBENZO(B)FLUORANTHENEBENZU(K)FLUORANTHENE
Mead CompuChem8Low Level waterDetection Limit
(ug/1)*4020020020
2UU200
20100IOU2020204020202020202020402040
2020402020208040404040
Low Level boliaDetection Limits
(ug/kg)*8004000400040040uO4000
400201)04000400400400800400400400400400400400800400BOO
400400800400400400
1600800800800800
Medium LevelDetection Limit
(ug/g)*2000001010000
10bO1001010102010101010101010201020
1010201010104020202020
J x Standard.Deviation**
ng on-column819935b
47
1145421469559631310
10 "' 'B204166
>20a10887
>20•Estimated MDL
**3-S1gma CL
•H
DETECTION LIMIT SUMMARY FORPESTICIDES HAZARDIOUS SUBSTANCE LIST COMPOUNDS
Compound I.D.ALPHA BHCBETA BHC
DELTA BHC
HEPTACHLOR EPOXIDE
CHLORODANE
DDE
ODD
DOT
ENDOSULFAN SULFATE
GAMMA BHC
HEPTACHLUR
GAMMA CHLORDANE
ENUUSULFAN 1
ENDOSULFAN II
ALDRIN
DIELDR1N
ENDR1N
TCDD
Mead CompuChem9Low Level flaterDetection Limits
(ug/D*0.10.10.1
0.10.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.002
Low Level SolidDetection Limits
(ug/kg)*
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
0.08
Medium LevelDetection Limits
(uy/g)*0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.002
3 x StandardDeviation**
ng on-column
0.0019
0.0030
0.0008
0.0013
0.0008
0.0007
0.0062
0.0136
0.0091
0.0023
0.0027
0.0025
0.0039
0.0126
0.0032
0.0043
0.0082
"Estimated MDL**3-S1gma DL
