1 2 3 4 5 ANALYTICAL REPORT 6 · 2017. 1. 12. · 2-Methylnaphthalene 1.5 0.037 0.0068 mg/Kg 1...

ANALYTICAL REPORTTestAmerica Laboratories, Inc.TestAmerica Chicago2417 Bond StreetUniversity Park, IL 60484Tel: (708)534-5200

TestAmerica Job ID: 500-69043-1Client Project/Site: 3450 E 2056th Wedron IL

For:CDM Smith, Inc.125 South Wacker DriveSuite 600Chicago, Illinois 60606

Attn: Chris Albrecht

Authorized for release by:1/8/2014 5:02:42 PMEric Lang, Manager of Project Management(708)[email protected]

Designee for

Bonnie Stadelmann, Senior Project Manager(708)[email protected]

The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced except in full,and with written approval from the laboratory. For questions please contact the Project Managerat the e-mail address or telephone number listed on this page.

This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

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Table of Contents

Client: CDM Smith, Inc.Project/Site: 3450 E 2056th Wedron IL

TestAmerica Job ID: 500-69043-1

Page 2 of 152TestAmerica Chicago

1/8/2014

Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 152

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Case NarrativeClient: CDM Smith, Inc. TestAmerica Job ID: 500-69043-1

Project/Site: 3450 E 2056th Wedron IL

Job ID: 500-69043-1

Laboratory: TestAmerica Chicago

Narrative

Job Narrative

500-69043-1

Comments

No additional comments.

Receipt

The samples were received on 12/20/2013 5:15 PM; the samples arrived in good condition, properly preserved and, where required, on

ice. The temperatures of the 2 coolers at receipt time were 2.6º C and 2.9º C.

GC/MS VOA

Method(s) 8260B: The following samples were diluted to bring the concentration of target analytes within the calibration range:

GP-01B-131219 (500-69043-2), GP-02B-131219 (500-69043-4), GP-03B-131219 (500-69043-6), GP-05B-131219 (500-69043-8),

GP-11B-131220 (500-69043-20), GP-11B-131220D (500-69043-21). Elevated reporting limits (RLs) are provided.

Method(s) 8260B: The following samples were diluted due to the abundance of non-target analytes: GP-04B-131220 (500-69043-27),

GP-06B-131219 (500-69043-12), GP-06B-131219D (500-69043-13), GP-07A-131220 (500-69043-23), GP-07B-131220 (500-69043-24),

GP-07B-131220D (500-69043-25), GP-08B-131219 (500-69043-10). Elevated reporting limits (RLs) are provided.

Method(s) 8260B: The following samples submitted for volatiles analysis was received with insufficient preservation (pH >2): Trip Blank

121913 (500-69043-14), Trip Blank 122013 (500-69043-22).

Method(s) 8260B: Surrogate recovery for the following samples were outside control limits: GP-06B-131219 (500-69043-12),

GP-08B-131219 (500-69043-10). Evidence of matrix interference is present; therefore, re-analysis was not performed.

Method(s) 8260B: Surrogate recovery for the following sample was outside control limits: GP-01B-131219 (500-69043-2), GP-02B-131219

(500-69043-4), GP-03B-131219 (500-69043-6), GP-05B-131219 (500-69043-8), GP-11B-131220 (500-69043-20). Evidence of matrix

interference is present. Re-analysis was performed at a dilution for target compounds, with all surrogates meeting QC limits.

Method(s) 8260B: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for batches 218334 and 218482 were outside control

limits. Sample matrix interference is suspected because the associated laboratory control samples (LCS) recovery were within

acceptance limits.

Method(s) 8260B: The %RPD of the matrix spike (MS) and matrix spike duplicate (MSD) samples for preparation batches 218455 and

218482 recovered outside control limits.

No other analytical or quality issues were noted.

GC/MS Semi VOA

Method(s) 8270D: The following samples were diluted due to the abundance of target and non-target analytes: GP-02B-131219

(500-69043-4), GP-05B-131219 (500-69043-8). Elevated reporting limits (RLs) are provided.

Method(s) 8270D: 500-69043-4 had 2-Fluorobiphenyl at 122% (25%-119%). All other surrogate recoveries were within limits. No further

action was required.GP-02B-131219 (500-69043-4)

Method(s) 8270D: Two matrix spike and one matrix spike duplicate (MS/MSD) recoveries for batch 218462 were outside control limits.

There were 2 RPD's > 30%. Sample matrix interference is suspected because the associated laboratory control sample (LCS) recovery

was within acceptance limits.GP-04A-131220 (500-69043-26 MS), GP-04A-131220 (500-69043-26 MSD)

Method(s) 8270D: Two matrix spike / matrix spike duplicate (MS/MSD) recoveries for batch 218463 were outside control limits. Sample

matrix interference is suspected because the associated laboratory control sample (LCS) recovery was within acceptance

limits.GP-06A-131219 (500-69043-11 MS), GP-06A-131219 (500-69043-11 MSD)


TestAmerica ChicagoPage 3 of 152 1/8/2014

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Case NarrativeClient: CDM Smith, Inc. TestAmerica Job ID: 500-69043-1


Job ID: 500-69043-1 (Continued)

Laboratory: TestAmerica Chicago (Continued)

GC VOA

Method(s) 8260B: The laboratory control sample (LCS) for batch 218642 recovered outside control limits for the following analytes:

1,1,1-Trichloroethane. These analytes were biased high in the LCS and were not detected in the associated samples; therefore, the data

have been reported.


Metals

Method(s) 6010B: The matrix spike (MS) precision for sample 500-69043-11 was outside control limits for Pb. The associated laboratory

control sample (LCS) precision met acceptance criteria, therefore the data has been reported. The %RPD for the MS/MSD was outside

control limits for Pb.

Method(s) 6010B: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for sample 500-69043-26 were outside control limits for

Pb. The associated laboratory control sample (LCS) recovery was within acceptance limits, therefore the data has been reported


Organic Prep

No analytical or quality issues were noted.

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Detection SummaryTestAmerica Job ID: 500-69043-1Client: CDM Smith, Inc.


Client Sample ID: GP-01A-131219 Lab Sample ID: 500-69043-1

☼Acetone

RL

0.0046 mg/Kg

MDL

0.0020

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA10.0049 8260B

☼Lead 0.48 mg/Kg0.14 Total/NA16.2 B 6010B

Client Sample ID: GP-01B-131219 Lab Sample ID: 500-69043-2

☼Toluene

RL

0.14 mg/Kg

MDL

0.063


Total/NA5004.6 8260B

☼Ethylbenzene - DL 1.4 mg/Kg0.69 Total/NA5000220 8260B

☼Xylenes, Total - DL 2.8 mg/Kg0.38 Total/NA5000890 8260B

☼Acenaphthene 0.037 mg/Kg0.0067 Total/NA10.012 J 8270D

☼Benzo[a]anthracene 0.037 mg/Kg0.0050 Total/NA10.0089 J 8270D

☼Benzo[a]pyrene 0.037 mg/Kg0.0072 Total/NA10.0090 J 8270D

☼2,4-Dimethylphenol 0.37 mg/Kg0.14 Total/NA10.19 J 8270D

☼Fluoranthene 0.037 mg/Kg0.0069 Total/NA10.021 J 8270D

☼Fluorene 0.037 mg/Kg0.0052 Total/NA10.038 8270D

☼2-Methylnaphthalene 0.037 mg/Kg0.0068 Total/NA11.5 8270D

☼Naphthalene 0.037 mg/Kg0.0057 Total/NA10.93 8270D

☼Phenanthrene 0.037 mg/Kg0.0052 Total/NA10.10 8270D

☼Pyrene 0.037 mg/Kg0.0074 Total/NA10.034 J 8270D

☼Lead 0.51 mg/Kg0.15 Total/NA114 B 6010B


☼Acetone

RL

0.0045 mg/Kg

MDL

0.0019





☼Ethylbenzene

RL

1.3 mg/Kg

MDL

0.64


Total/NA5000440 8260B

☼Toluene 1.3 mg/Kg0.58 Total/NA50006.1 8260B

☼Xylenes, Total - DL 25 mg/Kg3.5 Total/NA500001700 8260B


☼Fluorene 0.17 mg/Kg0.025 Total/NA50.12 J 8270D







☼Acetone

RL

0.0048 mg/Kg

MDL

0.0021





TestAmerica Chicago

This Detection Summary does not include radiochemical test results.

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Client Sample ID: GP-03B-131219 (Continued) Lab Sample ID: 500-69043-6

☼Toluene

RL

0.028 mg/Kg

MDL

0.013



☼Ethylbenzene - DL 0.28 mg/Kg0.14 Total/NA100079 8260B


☼2,4-Dimethylphenol 0.37 mg/Kg0.14 Total/NA10.40 8270D





☼Phenanthrene 0.037 mg/Kg0.0052 Total/NA10.024 J 8270D



☼Acetone

RL

0.0048 mg/Kg

MDL

0.0021



☼Methyl Ethyl Ketone 0.0048 mg/Kg0.0017 Total/NA10.0054 8260B



☼Ethylbenzene

RL

0.012 mg/Kg

MDL

0.0059


Total/NA505.8 8260B



☼Di-n-octyl phthalate 0.91 mg/Kg0.30 Total/NA50.63 J 8270D








☼Acetone

RL

0.0047 mg/Kg

MDL

0.0020


Total/NA10.0069 8260B



☼Ethylbenzene

RL

0.012 mg/Kg

MDL

0.0059


Total/NA502.4 8260B


☼Xylenes, Total 0.024 mg/Kg0.0032 Total/NA504.1 8260B





TestAmerica Chicago


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Client Sample ID: GP-06A-131219 (Continued) Lab Sample ID: 500-69043-11

☼Acetone

RL

0.0053 mg/Kg

MDL

0.0023



☼Methyl Ethyl Ketone 0.0053 mg/Kg0.0019 Total/NA10.0072 8260B

☼Toluene 0.0053 mg/Kg0.00075 Total/NA10.0030 J 8260B



☼Ethylbenzene

RL

0.13 mg/Kg

MDL

0.067


Total/NA5000.90 8260B






☼Benzo[b]fluoranthene 0.036 mg/Kg0.0078 Total/NA10.021 J 8270D

☼Benzo[g,h,i]perylene 0.036 mg/Kg0.012 Total/NA10.013 J 8270D

☼Chrysene 0.036 mg/Kg0.0099 Total/NA10.018 J 8270D

☼Fluoranthene 0.036 mg/Kg0.0067 Total/NA10.12 8270D





☼Pyrene 0.036 mg/Kg0.0072 Total/NA10.088 8270D


Client Sample ID: GP-06B-131219D Lab Sample ID: 500-69043-13

☼Ethylbenzene

RL

0.13 mg/Kg

MDL

0.064


Total/NA5000.24 8260B





☼Bis(2-ethylhexyl) phthalate 0.18 mg/Kg0.065 Total/NA10.26 8270D



☼Naphthalene 0.035 mg/Kg0.0055 Total/NA10.0085 J 8270D




Client Sample ID: Trip Blank 121913 Lab Sample ID: 500-69043-14

No Detections.


☼Di-n-octyl phthalate

RL

0.18 mg/Kg

MDL

0.059


Total/NA1J0.12 8270D


TestAmerica Chicago


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☼Di-n-octyl phthalate

RL

0.18 mg/Kg

MDL

0.059





☼Acetone

RL

0.0051 mg/Kg

MDL

0.0022


Total/NA10.0076 8260B






☼2-Methylnaphthalene 0.039 mg/Kg0.0072 Total/NA10.035 J 8270D





☼Acetone

RL

0.0057 mg/Kg

MDL

0.0025



☼Methyl Ethyl Ketone 0.0057 mg/Kg0.0021 Total/NA10.0056 J 8260B


☼Bis(2-ethylhexyl) phthalate 0.17 mg/Kg0.062 Total/NA10.063 J 8270D



☼Acetone

RL

0.0052 mg/Kg

MDL

0.0022






☼Ethylbenzene - DL

RL

1.4 mg/Kg

MDL

0.72


Total/NA5000160 8260B

☼Toluene - DL 1.4 mg/Kg0.66 Total/NA500039 8260B





☼2-Methylnaphthalene - DL 0.18 mg/Kg0.034 Total/NA54.1 8270D



☼Ethylbenzene

RL

0.14 mg/Kg

MDL

0.072


Total/NA50065 8260B


TestAmerica Chicago


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Client Sample ID: GP-11B-131220D (Continued) Lab Sample ID: 500-69043-21

☼Xylenes, Total - DL

RL

2.9 mg/Kg

MDL

0.39


Total/NA5000310 8260B






☼2-Methylnaphthalene - DL 0.71 mg/Kg0.13 Total/NA2020 8270D

☼Naphthalene - DL 0.71 mg/Kg0.11 Total/NA2016 8270D


Client Sample ID: Trip Blank 122013 Lab Sample ID: 500-69043-22

No Detections.


☼Fluoranthene

RL

0.039 mg/Kg

MDL

0.0073









☼Ethylbenzene

RL

1.5 mg/Kg

MDL

0.76


Total/NA50008.4 8260B









☼Ethylbenzene

RL

0.012 mg/Kg

MDL

0.0062


Total/NA503.7 8260B










TestAmerica Chicago


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Client Sample ID: GP-04A-131220 (Continued) Lab Sample ID: 500-69043-26

☼Ethylbenzene

RL

0.0051 mg/Kg

MDL

0.0010








☼Ethylbenzene

RL

1.4 mg/Kg

MDL

0.72


Total/NA500051 8260B

☼Xylenes, Total 2.8 mg/Kg0.39 Total/NA5000130 8260B

☼Acenaphthene 0.035 mg/Kg0.0064 Total/NA10.061 8270D

☼Anthracene 0.035 mg/Kg0.0059 Total/NA10.050 8270D




☼Benzo[g,h,i]perylene 0.035 mg/Kg0.011 Total/NA10.012 J 8270D






☼Pyrene 0.035 mg/Kg0.0070 Total/NA10.068 8270D

☼2-Methylnaphthalene - DL 0.18 mg/Kg0.033 Total/NA55.2 8270D


TestAmerica Chicago


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Method SummaryTestAmerica Job ID: 500-69043-1Client: CDM Smith, Inc.


Method Method Description LaboratoryProtocol

SW8468260B Volatile Organic Compounds (GC/MS) TAL CHI

SW8468270D Semivolatile Organic Compounds (GC/MS) TAL CHI

SW8466010B Metals (ICP) TAL CHI

EPAMoisture Percent Moisture TAL CHI

Protocol References:

EPA = US Environmental Protection Agency

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

TAL CHI = TestAmerica Chicago, 2417 Bond Street, University Park, IL 60484, TEL (708)534-5200

TestAmerica Chicago

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Sample SummaryTestAmerica Job ID: 500-69043-1Client: CDM Smith, Inc.


Lab Sample ID Client Sample ID ReceivedCollectedMatrix

500-69043-1 GP-01A-131219 Solid 12/19/13 09:30 12/20/13 17:15

500-69043-2 GP-01B-131219 Solid 12/19/13 09:45 12/20/13 17:15

500-69043-3 GP-02A-131219 Solid 12/19/13 10:30 12/20/13 17:15

500-69043-4 GP-02B-131219 Solid 12/19/13 10:45 12/20/13 17:15

500-69043-5 GP-03A-131219 Solid 12/19/13 11:30 12/20/13 17:15

500-69043-6 GP-03B-131219 Solid 12/19/13 11:45 12/20/13 17:15

500-69043-7 GP-05A-131219 Solid 12/19/13 13:30 12/20/13 17:15

500-69043-8 GP-05B-131219 Solid 12/19/13 13:45 12/20/13 17:15

500-69043-9 GP-08A-131219 Solid 12/19/13 15:45 12/20/13 17:15

500-69043-10 GP-08B-131219 Solid 12/19/13 16:00 12/20/13 17:15

500-69043-11 GP-06A-131219 Solid 12/19/13 14:45 12/20/13 17:15

500-69043-12 GP-06B-131219 Solid 12/19/13 14:50 12/20/13 17:15

500-69043-13 GP-06B-131219D Solid 12/19/13 14:55 12/20/13 17:15

500-69043-14 Trip Blank 121913 Water 12/19/13 00:00 12/20/13 17:15

500-69043-15 GP-09A-131220 Solid 12/20/13 08:45 12/20/13 17:15

500-69043-16 GP-09B-131220 Solid 12/20/13 08:55 12/20/13 17:15

500-69043-17 GP-10A-131220 Solid 12/20/13 09:45 12/20/13 17:15

500-69043-18 GP-10B-131220 Solid 12/20/13 10:00 12/20/13 17:15

500-69043-19 GP-11A-131220 Solid 12/20/13 11:20 12/20/13 17:15

500-69043-20 GP-11B-131220 Solid 12/20/13 11:30 12/20/13 17:15

500-69043-21 GP-11B-131220D Solid 12/20/13 11:45 12/20/13 17:15

500-69043-22 Trip Blank 122013 Water 12/20/13 00:00 12/20/13 17:15

500-69043-23 GP-07A-131220 Solid 12/20/13 13:30 12/20/13 17:15

500-69043-24 GP-07B-131220 Solid 12/20/13 13:45 12/20/13 17:15

500-69043-25 GP-07B-131220D Solid 12/20/13 13:55 12/20/13 17:15

500-69043-26 GP-04A-131220 Solid 12/20/13 14:25 12/20/13 17:15

500-69043-27 GP-04B-131220 Solid 12/20/13 14:35 12/20/13 17:15

TestAmerica Chicago

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Client Sample ResultsTestAmerica Job ID: 500-69043-1Client: CDM Smith, Inc.


Lab Sample ID: 500-69043-1Client Sample ID: GP-01A-131219Matrix: SolidDate Collected: 12/19/13 09:30

Percent Solids: 91.3Date Received: 12/20/13 17:15

Method: 8260B - Volatile Organic Compounds (GC/MS)RL MDL

Acetone 0.0049 0.0046 0.0020 mg/Kg ☼ 12/21/13 06:55 12/31/13 17:53 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

0.0046 0.00063 mg/Kg 12/21/13 06:55 12/31/13 17:53 1☼Benzene





Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued)RL MDL

Benzo[b]fluoranthene






N-Nitrosodi-n-propylamine



Lab Sample ID: 500-69043-2Client Sample ID: GP-01B-131219Matrix: SolidDate Collected: 12/19/13 09:45



Acetone





Method: 8260B - Volatile Organic Compounds (GC/MS) - DL (Continued)

Toluene-d8 (Surr) 102 75 - 120 12/19/13 09:45 01/01/14 19:54 5000

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Method: 8270D - Semivolatile Organic Compounds (GC/MS)RL MDL

Acenaphthene 0.012 J 0.037 0.0067 mg/Kg ☼ 01/02/14 07:08 01/03/14 14:02 1


0.037 0.0049 mg/Kg 01/02/14 07:08 01/03/14 14:02 1☼Acenaphthylene






2-Methylphenol






Acetone 0.021 0.0045 0.0019 mg/Kg ☼ 12/21/13 06:55 12/31/13 18:16 1


0.0045 0.00061 mg/Kg 12/21/13 06:55 12/31/13 18:16 1☼Benzene






Acetone






Toluene-d8 (Surr) 104 75 - 120 12/19/13 10:45 01/01/14 20:49 50000



Acenaphthene






2-Methylphenol






Acetone 0.011 0.0048 0.0021 mg/Kg ☼ 12/21/13 06:55 12/31/13 18:38 1


0.0048 0.00066 mg/Kg 12/21/13 06:55 12/31/13 18:38 1☼Benzene






Acetone






Toluene-d8 (Surr) 104 75 - 120 12/19/13 11:45 01/01/14 21:43 1000



Acenaphthene






2-Methylphenol






Acetone 0.022 0.0048 0.0021 mg/Kg ☼ 12/21/13 06:55 12/31/13 19:01 1


0.0048 0.00066 mg/Kg 12/21/13 06:55 12/31/13 19:01 1☼Benzene






Acetone






Toluene-d8 (Surr) 104 75 - 120 12/19/13 13:45 01/02/14 12:51 500



Acenaphthene






2-Methylphenol






Acetone 0.0069 0.0047 0.0020 mg/Kg ☼ 12/21/13 06:55 12/31/13 19:24 1


0.0047 0.00065 mg/Kg 12/21/13 06:55 12/31/13 19:24 1☼Benzene






Acetone






Acetone 0.028 0.0053 0.0023 mg/Kg ☼ 12/21/13 06:55 12/31/13 19:46 1


0.0053 0.00073 mg/Kg 12/21/13 06:55 12/31/13 19:46 1☼Benzene






Acetone






Benzo[b]fluoranthene 0.021 J 0.036 0.0078 mg/Kg ☼ 01/02/14 07:08 01/03/14 19:44 1


0.036 0.012 mg/Kg 01/02/14 07:08 01/03/14 19:44 1☼Benzo[g,h,i]perylene 0.013 J

0.036 0.011 mg/Kg 01/02/14 07:08 01/03/14 19:44 1☼Benzo[k]fluoranthene



Lab Sample ID: 500-69043-13Client Sample ID: GP-06B-131219DMatrix: SolidDate Collected: 12/19/13 14:55



Acetone








0.035 0.011 mg/Kg 01/02/14 07:08 01/03/14 20:03 1☼Benzo[g,h,i]perylene



Lab Sample ID: 500-69043-14Client Sample ID: Trip Blank 121913Matrix: WaterDate Collected: 12/19/13 00:00

Date Received: 12/20/13 17:15


Acetone






Acetone






Acetone 0.0076 0.0051 0.0022 mg/Kg ☼ 12/21/13 06:55 12/31/13 21:17 1


0.0051 0.00070 mg/Kg 12/21/13 06:55 12/31/13 21:17 1☼Benzene








0.039 0.013 mg/Kg 01/02/14 07:08 01/08/14 11:55 1☼Benzo[g,h,i]perylene






Acetone 0.019 0.0057 0.0025 mg/Kg ☼ 12/21/13 06:55 12/31/13 21:40 1


0.0057 0.00078 mg/Kg 12/21/13 06:55 12/31/13 21:40 1☼Benzene






Acetone 0.012 0.0052 0.0022 mg/Kg ☼ 12/21/13 06:55 01/02/14 13:16 1


0.0052 0.00071 mg/Kg 12/21/13 06:55 01/02/14 13:16 1☼Benzene






Acetone






Toluene-d8 (Surr) 102 75 - 120 12/20/13 11:30 01/03/14 11:34 5000



Acenaphthene






3 & 4 Methylphenol






Acetone






Toluene-d8 (Surr) 105 75 - 120 12/20/13 11:45 01/03/14 12:01 5000



Acenaphthene 0.026 J 0.036 0.0064 mg/Kg ☼ 01/02/14 07:08 01/08/14 13:33 1


0.036 0.0047 mg/Kg 01/02/14 07:08 01/08/14 13:33 1☼Acenaphthylene






3 & 4 Methylphenol



Lab Sample ID: 500-69043-22Client Sample ID: Trip Blank 122013Matrix: WaterDate Collected: 12/20/13 00:00

Date Received: 12/20/13 17:15


Acetone






Acetone








0.035 0.011 mg/Kg 01/02/14 07:04 01/07/14 22:51 1☼Benzo[g,h,i]perylene 0.012 J

0.035 0.010 mg/Kg 01/02/14 07:04 01/07/14 22:51 1☼Benzo[k]fluoranthene






N-Nitrosodiphenylamine

Definitions/GlossaryTestAmerica Job ID: 500-69043-1Client: CDM Smith, Inc.


Qualifiers

GC/MS VOA

Qualifier Description

X Surrogate is outside control limits

Qualifier

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

F1 MS and/or MSD Recovery exceeds the control limits

F2 MS/MSD RPD exceeds control limits

* LCS or LCSD exceeds the control limits

GC/MS Semi VOA



Qualifier



X Surrogate is outside control limits

Metals


B Compound was found in the blank and sample.

Qualifier




Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CNF Contains no Free Liquid

DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision level concentration

MDA Minimum detectable activity

EDL Estimated Detection Limit

MDC Minimum detectable concentration

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative error ratio

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

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QC Association SummaryTestAmerica Job ID: 500-69043-1Client: CDM Smith, Inc.


GC/MS VOA

Prep Batch: 217834

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Solid 5035500-69043-1 GP-01A-131219 Total/NA






Solid 5035500-69043-11 MS GP-06A-131219 Total/NA

Solid 5035500-69043-11 MSD GP-06A-131219 Total/NA


Solid 5035500-69043-16 GP-09B-131220 Total/NA







Prep Batch: 218172


Solid 5035500-69043-2 - DL GP-01B-131219 Total/NA









Solid 5035500-69043-10 MS GP-08B-131219 Total/NA

Solid 5035500-69043-10 MSD GP-08B-131219 Total/NA


Solid 5035500-69043-13 GP-06B-131219D Total/NA




Solid 5035500-69043-21 - DL GP-11B-131220D Total/NA





Analysis Batch: 218334


Solid 8260B 217834500-69043-1 GP-01A-131219 Total/NA






Solid 8260B 217834500-69043-11 MS GP-06A-131219 Total/NA

Solid 8260B 217834500-69043-11 MSD GP-06A-131219 Total/NA

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GC/MS VOA (Continued)

Analysis Batch: 218334 (Continued)


Solid 8260B 217834500-69043-16 GP-09B-131220 Total/NA



Solid 8260BLCS 500-218334/6 Lab Control Sample Total/NA

Solid 8260BMB 500-218334/5 Method Blank Total/NA



Water 8260B500-69043-14 Trip Blank 121913 Total/NA

Water 8260BLCS 500-218369/4 Lab Control Sample Total/NA

Water 8260BMB 500-218369/6 Method Blank Total/NA




Solid 8260B 218172500-69043-2 - DL GP-01B-131219 Total/NA







Solid 8260B 218172500-69043-10 MS GP-08B-131219 Total/NA

Solid 8260B 218172500-69043-10 MSD GP-08B-131219 Total/NA


Solid 8260B 218172500-69043-13 GP-06B-131219D Total/NA











Solid 8260BLCSD 500-218482/7 Lab Control Sample Dup Total/NA











Water 8260B500-69043-22 Trip Blank 122013 Total/NA

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GC/MS VOA (Continued)



Water 8260BLCS 500-218488/4 Lab Control Sample Total/NA

Water 8260BMB 500-218488/6 Method Blank Total/NA












Solid 8260B 218172500-69043-21 - DL GP-11B-131220D Total/NA



GC/MS Semi VOA

Prep Batch: 218462










Solid 3541LCS 500-218462/2-A Lab Control Sample Total/NA

Solid 3541MB 500-218462/1-A Method Blank Total/NA

Prep Batch: 218463
















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GC/MS Semi VOA (Continued)

Prep Batch: 218463 (Continued)











Solid 3541500-69043-21 - DL GP-11B-131220D Total/NA

Solid 3541LCS 500-218463/2-A Lab Control Sample Total/NA

Solid 3541MB 500-218463/1-A Method Blank Total/NA



Solid 8270D 218462LCS 500-218462/2-A Lab Control Sample Total/NA

Solid 8270D 218463LCS 500-218463/2-A Lab Control Sample Total/NA

Solid 8270D 218462MB 500-218462/1-A Method Blank Total/NA

Solid 8270D 218463MB 500-218463/1-A Method Blank Total/NA



Solid 8270D 218463500-69043-1 GP-01A-131219 Total/NA

Solid 8270D 218463500-69043-2 GP-01B-131219 Total/NA








Solid 8270D 218463500-69043-11 MS GP-06A-131219 Total/NA

Solid 8270D 218463500-69043-11 MSD GP-06A-131219 Total/NA


Solid 8270D 218463500-69043-13 GP-06B-131219D Total/NA








Solid 8270D 218462500-69043-26 MS GP-04A-131220 Total/NA

Solid 8270D 218462500-69043-26 MSD GP-04A-131220 Total/NA






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GC/MS Semi VOA (Continued)








Solid 8270D 218463500-69043-20 - DL GP-11B-131220 Total/NA


Solid 8270D 218463500-69043-21 - DL GP-11B-131220D Total/NA

Solid 8270D 218462500-69043-27 - DL GP-04B-131220 Total/NA

Metals

Prep Batch: 218329


Solid 3050B500-69043-1 GP-01A-131219 Total/NA

Solid 3050B500-69043-2 GP-01B-131219 Total/NA










Solid 3050B500-69043-11 DU GP-06A-131219 Total/NA

Solid 3050B500-69043-11 MS GP-06A-131219 Total/NA

Solid 3050B500-69043-11 MSD GP-06A-131219 Total/NA


Solid 3050B500-69043-13 GP-06B-131219D Total/NA








Solid 3050BLCS 500-218329/2-A Lab Control Sample Total/NA

Solid 3050BMB 500-218329/1-A Method Blank Total/NA

Prep Batch: 218336






Solid 3050B500-69043-26 DU GP-04A-131220 Total/NA

Solid 3050B500-69043-26 MS GP-04A-131220 Total/NA

Solid 3050B500-69043-26 MSD GP-04A-131220 Total/NA


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Metals (Continued)

Prep Batch: 218336 (Continued)


Solid 3050BLCS 500-218336/2-A Lab Control Sample Total/NA

Solid 3050BMB 500-218336/1-A Method Blank Total/NA







Solid 6010B 218336500-69043-26 DU GP-04A-131220 Total/NA




Solid 6010B 218336LCS 500-218336/2-A Lab Control Sample Total/NA

Solid 6010B 218336MB 500-218336/1-A Method Blank Total/NA














Solid 6010B 218329500-69043-11 DU GP-06A-131219 Total/NA












Solid 6010B 218329LCS 500-218329/2-A Lab Control Sample Total/NA

Solid 6010B 218329MB 500-218329/1-A Method Blank Total/NA

General Chemistry



Solid Moisture500-69043-1 GP-01A-131219 Total/NA

Solid Moisture500-69043-2 GP-01B-131219 Total/NA

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General Chemistry (Continued)












Solid Moisture500-69043-11 DU GP-06A-131219 Total/NA

Solid Moisture500-69043-11 MS GP-06A-131219 Total/NA

Solid Moisture500-69043-11 MSD GP-06A-131219 Total/NA


Solid Moisture500-69043-13 GP-06B-131219D Total/NA












Solid Moisture500-69043-26 DU GP-04A-131220 Total/NA

Solid Moisture500-69043-26 MS GP-04A-131220 Total/NA

Solid Moisture500-69043-26 MSD GP-04A-131220 Total/NA


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Surrogate SummaryTestAmerica Job ID: 500-69043-1Client: CDM Smith, Inc.


Method: 8260B - Volatile Organic Compounds (GC/MS)Prep Type: Total/NAMatrix: Solid

Lab Sample ID Client Sample ID (70-122) (75-120) (70-134) (75-122)

BFB DBFM 12DCE TOL

103 100 103 95500-69043-1

Percent Surrogate Recovery (Acceptance Limits)

GP-01A-131219

89 101 100 96500-69043-3 GP-02A-131219

98 104 104 97500-69043-5 GP-03A-131219

91 102 102 98500-69043-7 GP-05A-131219

96 100 91 98500-69043-9 GP-08A-131219

93 98 87 99500-69043-11 GP-06A-131219

95 90 86 104500-69043-11 MS GP-06A-131219

92 94 83 104500-69043-11 MSD GP-06A-131219

92 97 87 95500-69043-15 GP-09A-131220

96 97 86 98500-69043-16 GP-09B-131220

94 96 91 99500-69043-17 GP-10A-131220

92 94 90 96500-69043-18 GP-10B-131220

94 101 94 96500-69043-19 GP-11A-131220

89 92 81 103500-69043-26 GP-04A-131220

90 92 80 101500-69043-26 MS GP-04A-131220

88 93 85 103500-69043-26 MSD GP-04A-131220

101 99 102 103LCS 500-218334/6 Lab Control Sample

93 97 85 102LCS 500-218482/6 Lab Control Sample

88 93 82 103LCSD 500-218482/7 Lab Control Sample Dup

89 94 91 96MB 500-218334/5 Method Blank

92 94 80 101MB 500-218482/5 Method Blank

Surrogate Legend

BFB = 4-Bromofluorobenzene (Surr)

DBFM = Dibromofluoromethane

12DCE = 1,2-Dichloroethane-d4 (Surr)

TOL = Toluene-d8 (Surr)

Method: 8260B - Volatile Organic Compounds (GC/MS)Prep Type: Total/NAMatrix: Solid

Lab Sample ID Client Sample ID (75-120) (75-120) (75-125) (75-120)

BFB DBFM 12DCE TOL

101 91 186 X 105500-69043-2

Percent Surrogate Recovery (Acceptance Limits)

GP-01B-131219

101 95 115 102500-69043-2 - DL GP-01B-131219

100 94 131 X 104500-69043-4 GP-02B-131219

102 93 108 104500-69043-4 - DL GP-02B-131219

101 89 133 X 102500-69043-6 GP-03B-131219

98 96 109 104500-69043-6 - DL GP-03B-131219

99 93 127 X 101500-69043-8 GP-05B-131219

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