1
FIRST SESSIONAL ASSIGNMENT
Design a 1-2horizental condenser for the condensation of 60,000lb/hr of pure n
propanol coming from the top of distillation column operating at 15 psig, at which it
boils at 244 oF. Water at 85
Submitted to:
Dr. ING. NAVEED RAMZAN
Prepared by:
ASIF NADEEM TABISH 2005
ZEESHAN TALIB 2005
USMAN FAROOQ 2005
QAIM ALI
MUHAMMAD TARIQ 2005
FIRST SESSIONAL ASSIGNMENT
2horizental condenser for the condensation of 60,000lb/hr of pure n
propanol coming from the top of distillation column operating at 15 psig, at which it
F. Water at 85 oF will be used as cooling medium.
Dr. ING. NAVEED RAMZAN
ASIF NADEEM TABISH 2005-Chem-03
ZEESHAN TALIB 2005-Chem-07
USMAN FAROOQ 2005-Chem-53
QAIM ALI 2005-Chem-87
MUHAMMAD TARIQ 2005-Chem-89
2horizental condenser for the condensation of 60,000lb/hr of pure n-
propanol coming from the top of distillation column operating at 15 psig, at which it
03
07
53
87
89
2
WORKING PRINCIPLE OF EQUIPMENT
Heat Transfer from a hot stream to cold stream can be accomplished by following heat
transfer mechanism
1. Conduction
2. Convection
3. Radiation
In exchangers heat transfer occurs by a combination of 2 or 3 of these heat transfer
mechanisms.
Steady State Heat Transfer
When the rate of heat transfer remains constant and is unaffected by time,
then the flow of heat is steady state.
Unsteady State Heat Transfer
An unsteady state exists when the rate of heat transfer at any point varies
with time.
Most industrial processes in which heat transfer is involved are assumed to
operate under steady state conditions even though in some cases unsteady state
conditions are observed e.g.
• During start up
• Cool down
• Surge conditions
Unsteady State Conditions are observed in:
• Batch Process
• Cooling & heating of material .e.g. polymer & glass
• Certain types of regeneration
Steady State Heat Transfer Considerations:
Most cases of heat transfer in exchangers involve the flow of heat from one
fluid through a retaining wall to another fluid. The heat that is transferred flows from
warmer fluid to colder fluid through several thermal resistances in series.
Total resistance to heat transfer
Rtot = (Th _ Tc) /q Where,
Th = Temperature of hot fluid
3
Tc = Temperature of cold fluid
Rtot is comprised of
• Resistance due to convective heat transfer 1 / hh
• Resistance due to fouling on warm side Rhf
• Resistance to heat transfer through wall x/ kw
• Resistance due to fouling on colder side Rcf
• Resistance due to convective heat transfer in cold fluid 1/ hc
so
Rtot = 1/U = 1/ hh + Rhf + x/ kw + Rcf + 1/ hc
Consequences of Heat Transfer
Heat transfer to a fluid or from a fluid may lead to
• Vaporization (The change of Phase from liquid to vapor)
• Condensation (The change from vapor to liquid)
• Super heating of vapor ( Change in sensible heat of vapor)
• Sub-cooling of condensed liquid ( Change in sensible heat o liquid)
4
CONDENSATION
The process of heat transfer accompanied by a phase change from vapor
to liquid at constant pressure is called condensation.
• Since vapor liquid heat transfer usually occurs at constant pressure, the
condensation of a single compound normally occurs isothermally.
• If a mixture of vapors instead of a single compound is condensed then
condensation may not take place isothermally, there may be sub-
cooling of condensed liquid.
But in our case we have pure n-propanol, so there is only phase change at
isothermal conditions.
CONDENSATION MECHANISMS
1) Drop-wise Condensation
When a saturated pure vapor comes in contact with a cold surface such as
tubes, it condenses and may form liquid droplets on the surface of tube, such a type is
drop wise condensation.
2) Film-wise Condensation
When a distinct film of condensed vapors appears & coats the tube and
additional vapor is required to condense onto the liquid film, then it is film wise
condensation
COMPARISON OF TWO CONDENSATION MECHANISMS
Due to the resistance of condensate film to the heat passing through it the
heat transfer coefficient for drop wise condensation are 4 to 8 times greater than film
wise condensation.
But drop wise condensation occurs rarely because special conditions are
required for it to occur. It occurs by the presence of dirt on the surface or by the use of
a contaminant that adheres to the surface. Steam is the only pure vapor known to
condense in a drop wise manner. Drop wise condensation also occurs when several
materials condense simultaneously as mixture and where the condensate mixture is
not miscible as in the case of hydrocarbons and steam but we have pure n-propanol so
mechanism is of film wise.
Film wise condensation may be considered as self diffusion process. The
saturation pressure of the vapor in the vapor body is greater than the saturation
pressure of the cold condensate in contact with the cold surface. This pressure
5
difference provides potential for driving vapors out the vapor body at a great rate.
Here the controlling resistance is the film of condensate on cold tube wall. It is the
slowness with which the heat of condensation passes through this film that
determines the condensing coefficient.
NUSSELT THEORY FOR CONDENSATION ON SURFACE
The following assumptions are involved for condensation on surfaces as given by
Nusselt.
• The heat delivered by the vapor is latent heat only.
• The drainage of the condensate film from the surface is by laminar flow
only and the heat is transferred through the film by conduction.
• The thickness of the film at any point is a function of the mean velocity
of flow and of the amount of condensate passing at that point.
• The velocity of the individual layers of the film is a function of the
relation between frictional shearing force and weight of the film.
• The quantity of the condensate is proportional to the quantity of heat
transferred which is in turn related to the thickness of the film and of
the temperature difference between the vapor and the surface.
• The condensate film is so thin that temperature through it is linear.
• The surface is assumed to be relatively smooth and clean.
• The temperature of the solid surface is assumed to be constant.
6
MAIN PARTS OF HORIZONTAL CONDENSER
The principal components of horizontal condenser are:
1. Shell
2. Tubes
3. Tube sheets
4. Tube Bundles
5. Baffles
6. Shell Cover
7. Inlet & Outlet Nozzles
8. Channel Or Bonnet 9. Channel Cover
10. Pass Partition
11. Flanges
12. Expansion Joint
13. Tie Rods
14. Connections
15. Support Saddles
7
EXPLANATION:
Usually, for the case of condensers processes streams are taken in the shell
side and utilities are inside the tubes to ensure the tube outside condensation. But, it
also depends upon the requirements and nature of the fluids. They are commonly
termed as shell side and tube side fluids respectively. Shell side fluids are non
corrosive in nature and their flow rate is kept low.
Using a small tube diameter makes the exchanger both economical and
compact. However, it is more likely for the heat exchanger to foul up faster and the
small size makes mechanical cleaning of the fouling difficult. To prevail over the
fouling and cleaning problems, larger tube diameters can be used. Thus to determine
the tube diameter, the available space, cost and the fouling nature of the fluids must
be considered. Typically, exchangers are usually cheaper when they have a smaller
shell diameter and a long tube length.
Tube sheets are usually fixed tube sheets but in some cases floating tube
sheets are also used. Tube bundles are set of tubes and can be made up of several
types of tubes plain, longitudinally finned etc.
Baffles are used to increase the heat transfer by creating the turbulence, and
to reduce the virbational motion of the tube bundles. Three types of baffles mostly
used are:
1. Segmented baffles
2. Disc and doughnut baffles
3. Orifice baffles
Specially, for the case of condensers longitudinal baffles are preferred.
Cover is provided to the outer surface of the shell to prevent the early damage
of the equipment due to change in atmospheric conditions. Shell cover also serves as
insulator to prevent the heat loss to the atmosphere up to some extent.
Inlet and Outlet nozzles are used for the entrance and exit of the tube side and
shell side fluids. It is commonly termed as Tube inlet, Tube outlet, Shell inlet, Shell
outlet.
Channel or bonnet is simply throws the fluid to tubes through tube sheets.
Usually, it is connected to both ends of the exchangers (rare & front end).They are
stationary. Channel cover is provided for the protection of fluids inside the channel
due to change in environmental constraints.
8
Heat Exchangers are categorized on the basis of passes involved in tube side
and shell side. It depends upon heat requirement and their use for special purposes
that what type of exchanger should be installed. 1-2 pass heat exchanger indicates
that there is one shell pass and two tube passes.
Flanges are used to connect the tube sheet to channel and with shells. ie. shell
flange rare, shell flange stationary, shell cover flange. All these are used for connecting
by using nuts and bolts. Using of flanges is preferable than welding because of easy
cleaning and they are also easily removable.
Due to change in atmospheric conditions like change in temperature causes
the expansion of the parts of the exchangers. In order to accommodate this expansion,
we use expansion joints.
The basic purpose of tie rods is to provide the support for tubes. They are
preferably used when we are dealing with the longer horizontal exchangers.
Different kinds of connections are applied to the exchangers to maintain the
process conditions inside the exchangers like
• Vent Connection
• Drain Connection
• Instrument connection
Vent connection is usually applied to remove the non condensible gases and to
maintain the required pressure. It is applied on the top of the exchangers. Drain
connection is applied at the bottom of the exchanger to remove the settled material in
the shell side fluid. Drain connection is applied at the rare end of the exchangers. The
purpose of instrument connection is to maintain the process conditions by installing
any type of instrument like thermocouples and pressure gauges.
Saddles are also used for the support purpose of the exchangers. They also
provide us the security of the equipment like corrosion of different parts of the
equipment.
9
DESIGN PROCEDURE:
CALCULATION OF HEAT LOAD:
Heat balance (Q) = m Cp ∆T (Btu/hr)
CALCULATION OF LMTD:
T1 T2
t2 t1 LMTD = (∆ T1 - ∆ T2) / ln (∆ T1/∆ T2)
= (T1-t2) – (T2 –t1) / ln {(T1-t2)/ (T2 –t1)}
Average temperature of cooling water ta = (t1 + t2) / 2
ASSUMTION BASED CALCULATIONS:
Assume Design overall Coefficient (UD) = 75 – 150 (Btu/ ft2.hr.0F)
Heat Transfer Area A = Q / UD ∆TLMTD ( ft2)
Tube Lay out & size i.e. length, OD, BWG, pitch and no of passes
Number of tubes Nt = A / �D0 L
Comparing the Number of tubes with standard value
Selection of Shell layout and size i.e. ID, Baffle spacing and no. of passes
Correction of UD and flow area on the basis of standard number of tubes
TUBE SIDE CALCULATIONS:
Calculation of Flow area at = Ntat/144n ( ft2)
Calculation of Mass Velocity tt amG /&= ( lb/hr ft2)
Velocity of water in tubes ρ3600
tGv = ( ft/s)
Determination of viscosity of fluid inside tube at ta = μ (lb/ft hr)
Diameter of tube = Dt (ft)
CONDENSER
10
Reynolds Number calculation µ
tte
GDR =
Determination of tube inside heat transfer coefficient = hi (Btu/hr.ft2.oF)
Calculation of hio OD
IDhh iio = (Btu/hr.ft2.oF)
Determination of fanning friction factor ƒ
Calculation of tube side Pressure Drop
t
tt sDx
LfGP
ϕ10
2
1022.5=∆
Calculation of Return Loss
′
=∆g
v
s
nPr 2
4 2
Total pressure drop along tube side ∆PT = ∆Pt + ∆Pr psi
SHELL SIDE CALCULATIONS
Calculation of Flow area as = (Ds.PD.LB) / (144PT) (ft2)
Calculation of Mass Velocity s
s a
mG
&= (lb/hr ft2)
Equivalent Dia. of Shell side ( )
o
otte d
dppD
ππ 4/86.0*4 2−= (ft)
Calculation of viscosity of fluid inside shell = μ (lb/ft hr)
Reynolds Number calculation µ
see
GDR =
Determination of fanning friction factor for above Reynolds Number ƒ
Determination of specific gravity of n-propanol
Calculation of shell side Pressure Drop ( )
se
sssd sDx
NDfGP
ϕ10
2
1022.5
1+=∆ (psi)
11
CONDENSATIOM ZONE CALCULATIONS:
Calculation of Condensation loading 3/2tLN
WG =′′ (lb/ft2hr)
Assume ho (Btu/hr.ft2.oF)
Calculation of Temp of tube wall ( )avoio
oaw tT
hh
htt −
++= (oF)
Calculation of Ave temp of film tf = ( Tv + tw)/2 (oF)
Where,
Tv =Ave. Temp. of condensation (oF)
ta =Ave temp of cold fluid (oF)
Determination of
Thermal conductivity (k),
Viscosity ( μ) and
Specific_gravity at tf
Verifying the value of ho from graph 12.9
Calculation of Clean overall coefficient for Condensation zone
oio
oioc hh
hhU
+= Btu/hr.ft2.oF
Calculation of Dirt factor RD = (UC – UD) / UCUD hr.ft2.oF/Btu
12
DESIGN CALCULATIONS OF CONDENSER:
Vapors T1= 244oF condensate T2= 244oF
Hot Water t2= Cooling water t1 = 85 oF
Inlet Temperature of n-propanol T1= 244oF
Outlet Temperature of n-propanol T2 = 244oF
Mass flow rate of n-propanol m1 = 60,000 lb/hr
LATENT HEAT OF n-Propanol
λ = ∑ [Ci(1-Tr)i/3
]|i=(1-6) …………….…………. (1
Where latent heat of n-propanol is expressed in kj/kg and temperature is expressed in
Kelvin
Critical Temperature of propanol Tc = 536.78 oC
Reduced Temperature Tr = 0.7282
For n-propanol
C1 C2 C3 C4 C5 C6
2222.5 -8368.5 14567 -2870.3 -9655.7 4966.0
λ = [{2222.5*(1-0.7282)1/3} – {8368.4*(1-0.7282)2/3} + {14567*(1-0.7282)3/3} –
{2870.3*(1-0.7282)4/3} – {9655.7*(1-0.7282)5/3} + {4966.0*(1-0.7282)6/3}]
= 1439.65 - 3511.36 + 3959.30 – 505.35 – 1101.20 + 366.86
= 648.0 kj/kg = 278.55 Btu/lb
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HEAT LOAD:
Heat load for condensing the vapors: Q1 = m1 λ
= 60,000 * 278.55 Btu/hr
= 16,713,000 Btu/hr
HEAT BALANCE FOR WATER:
Assumption:
Cooling Water flow rate = 500,000 lb/hr
Q2 = m2Cp(Tout – Tin)
16,713,000 = 50,000 * 1 * (Tout - 85)
Tout = 118.42 oF
So
Outlet Temperature of water = 118.42oF
CALCULATION OF LMTD:
As LMTD = (T2 – t1) – (T1 – t2) / ln {(T2 – t1) / (T1 – t2)}
= (224 - 85) – (224 – 118.42) / ln{(224 - 85)/ (224 – 118.42)}
= 141.63 oF
Average temperature of cooling water = (85+118.42)/2
= 101.71 oF
ASSUMED CALCULATIONS:
Assume Design overall Coefficient (Ud) = 110 Btu/hr.ft2.oF
Heat Transfer Area: wd
t
tU
QA
∆=
.
= 16713000/(110*141.63)
= 1072.72ft2
14
Tube Lay out & size:
Length = 12 ft
OD, BWG, pitch = 1in, 12 BWG, 1-1/4Triangular pitch
Passes = 2
Out side surface area per linear ft a’ = 0.2618
No. of tubes = Nt = A/ a”L
= 1072.77 / (0.2618*12)
= 341
Nearest standard value for 1” OD tube on 1-1/4” triangular pitch and shell
dia 27’’ = 334 tubes ……………………(2
Area of tubes = (Nt * a’ * L)
= (334 * 0.2618 * 12)
= 1049.29 ft2
Corrected value of UD = 16,713,000 / (141.63*1049.29)
= 112.46 Btu/ft2.hr.oF
Close to out assumed value (UD = 110) so our assumption is right.
Shell side:
ID = 27in
Baffle spacing = 36in
Baffles are segmental with 25% cut and side to side flow mechanism
Passes ss = 1
TUBE SIDE CALCULATIONS:
Flow area per tube: at’ = 0.479 in2
at = Ntat/144n
= (334*0.479)/144*2
= 0.555ft2
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Mass Velocity:
tt amG /&=
= (500,000/0.555)
= 900078.76 lb/hr ft2
Velocity of water in tubes ρ3600
tGv =
= (900078.76/58.79*3600)
= 4.25 ft/s
Tube inside coefficient hi = 1070 Btu/hr.ft2.oF ………………………. (3
Viscosity at average temperature 101.71oF
μ = 1.74 lb/ft hr
Tube inside diameter Dt = 0.0652 ft ………………………… (4
Reynolds No µ
tte
GDR =
= (0.0652 * 900078.76)/1.74
= 33727.09
Tube outside coefficient OD
IDhh iio =
= (1070 * 0.0652) / 0.0833
= 837.50 Btu/hr.ft2.oF
Friction Factor for given Reynolds No
= 0.00021 ……………………………… (5
16
Pressure Drop along Tube side
ΔPt = fG2Ln / 5.22-E10*Dsφ …….. ……………………..(6
= (0.00021*900078.762*12*2) / (5.22-E10*0.0652*1.0*1.0)
=1.20psi
Return Loss ΔPr = (4n*V2)/(2sg) …………………..……..(7
= (4*2*4.252)/(2*32.15)
= 2.247psi
Total Pressure drop in tube side ΔPT = (ΔPt + ΔPr)
= 1.20 + 2.247
= 3.447psi
SHELL SIDE CALCULATIONS:
Baffle spacing LB = 36 in
Number of Baffles = 4 (with side to side flow mechanism)
Shell Diameter Ds = 27 in
Number of shell passes = 1
Tube Dimensions
OD, BWG, pitch = 1in, 12 BWG, 1.1/4Triangular pitch.
Tube clearance PD = 1.25 - 0.25
= 0.25 in
Shell inside flow area as = (Ds.PD.LB) / (144PT)
= (27*0.25*36) / (1.25*144)
= 1.35 ft2
Mass Velocity s
s a
mG
&=
= 60,000 / 1.35 = 4.44x104 lb/hr ft2
17
Equivalent Dia. of Shell side
( )
o
otte d
dppD
ππ 4/86.0*4 2−= ……………………………….. (8
= 4(1.25*0.86*1.25 – π *12*0.25) / ( π*12)
= 0.059 ft
Viscosity of n-propanol μ = 0.0242 lb/hr.ft
Reynolds No
µ
see
GDR =
= (0.059*4.44x104)/0.0242
= 108247.93
For above Reynolds Number ƒ = 0.0014 ft2/in2
Density of n-propanol vapors ρ = PM/RT
= (29.7*60.10*703.67) / (14.7*359/492)
= 0.236 lb/ft2
Specific gravity of n-propanol s = 0.00377
Diameter of shell Ds = 27 / 12
= 2.25 ft
Pressure drop on shell side ( )
se
sssd sDx
NDfGP
ϕ10
2
1022.5
1+=∆
Assuming φs =1
= 0.0014*(4.44*104)2*2.25*5)
2*5.22*1010*0.059*0.00377
= 1.34 psi
18
CONDENSATION ZONE:
Condensation loading 3/2tLN
WG =′′
= 60,000/12*3342/3
= 103.86 lb/ft2hr
Let ho = 150 Btu/hr.ft2.oF
hio = 837.50 Btu/hr.ft2.oF
Temp of tube wall ( )avoio
oaw tT
hh
htt −
++=
…………………………. (9
= 101.75 + {175/ (837.50 + 175)}*(244 – 101.75)
= 126.33oF
Ave temp of film = tf = ( Tv + tw)/2
= (244 + 126.24)/2
= 185.12oF
Thermal conductivity of propanol condensate can be calculated by using equation for
reduced temperature between 0.25 and 0.80 and below 3.5 MPA ……………………….. (10
And critical temperature of n-propanol is 536.78K
So kL = 1.811*10-4*13.38*60.101.001*18.43/14.82
kL = 0.102 Btu/ft hr oF
19
μ = 0.62 lb/ft hr
s = 0.80 (sp. gravity)
By using these values from graph 12.9 we get
ho = 170 Btu/hr.ft2.oF
Close to assumed (ho= 175 Btu/hr.ft2.oF ) so our assumption is right.
Now Clean overall coefficient for Condensation zone is:
oio
oioc hh
hhU
+=
= (837.50*175) / (837.50 + 175
= 144.75 Btu/hr.ft2.oF
Dirt factor:
RD = (UC – UD) / UCUD
= (144.75-112.46)/144.75*112.46
= 0.002 hr.ft2.oF/Btu
REFERENCES:
1) Eq. 31 Korean J. chem. Engg 17(1) 93-100
2) Table-9 Process Heat Transfer by D.Q.Kern
3) Fig-25 Process Heat Transfer by D.Q.Kern
4) Table-10 Process Heat Transfer by D.Q.Kern
5) Fig-26 Process Heat Transfer by D.Q.Kern
6) Eq.7.45 Process Heat Transfer by D.Q.Kern
7) Eq.7.46 Process Heat Transfer by D.Q.Kern
8) Eq.14-34 Plant Design and Economics by Peter Timmerhaus
9) Eq.5-33 Process Heat Transfer by D.Q.Kern
10) Eq.2-135 Perry’s Chemical Engineers Handbook 7th edition
20
MECHENICAL DESIGN:
STREAMS INVOLVED:
1) Process fluid :
N-propane at 224oC
2) Service fluid :
Water at 85 co
NATURE OF FLUID:
1) N-propane
2) Water
MATERIAL OF CONSTRUCTION:
Shell side: Mild steel
Tube side: stainless steel 430
CHARACTERISTICS OF STAINLESS STEEL 430:
Composition:
Cr = 14.00-18.00%
Ni = not present
C = 0.12 %
Major characteristics:
Good corrosion resistance properties against oxidizing media.
Applications:
Chemical processing towers, condensers, furnaces etc.
*(Ref: plant design by timerhaus 5th edition)
TYPE OF CONDENSER SELECTED:
Bundle dia; Db = do (Nt/K1) 1/n1
Where:
do = tube outside dia = 1”
21
Db = Bundle dia =?
Nt = No. of tubes = 334
K1 & n1 are constants
K1 = 0.249 & n1 = 2.207
So:
Bundle dia calculated = 0.65m
&
Shell inside dia = 27” = 685.8mm
Shell inside dia – bundle dia = 35.8mm
From graph:
22
STANDERD AEP TYPE CONDENSER:
A = Chanel & removable cover
E = One shell pass
P = outside packed floating head
TEMA standards important parameters for AEP type:
Definition Generally for petroleum and related processing
application.
Corrosion allowance 1/8 inch
Tube diameters ¾, 1, 1 ¼ ,1 ½ & 2 inch OD
Tube pitch 1.25 inch
Minimum shell diameter 8 inch tabulated
Longitudinal baffle
thickness
¼ inch minimum
Minimum tie rod diameter 3/8 inch
Floating head cover 1.3 times tube flow area
Significant feature:
One tube sheet “floats “in shell or with shell, tube bundle may or may not
be removable from shell, but back cover can be removed to expose tube ends.
23
Area of application:
High temperature differentials, above about 200°F.extremes; dirty
fluids requiring cleaning of inside as well as outside of shell, horizontal or vertical .
Limitations:
Internal gaskets offer danger of leaking. Corrosiveness of fluids on shell side
floating parts. Usually confined to horizontal units.
Maintenance:
Provision for differential expansion floating head
Removable bundle yes
Replacement bundle possible yes
Individual tubes replaceable yes
Tube interiors cleanable yes, mechanically or chemically
Tube exteriors with triangular pitch
cleanable
chemically only
Tube exteriors with square pitch cleanable yes, mechanically or chemically
Number of tube passes normally no limitations
Internal gaskets eliminated yes
*(ref : Rules of Thumb for Chemical Engineers (3rd Ed) by Carl R. Branan)