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Chapter 9Acids and Bases
Acids and Bases
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Acids and Bases – What they do in water
Acids produce H+ in aqueous solutions water
HCl H+(aq) + Cl- (aq)
Bases produce OH- in aqueous solutions
water
NaOH Na+(aq) + OH- (aq)
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Acids
Produce H+ (as H3O+) ions in water
Produce a negative ion (-) too
Taste sour
Corrode metals
React with bases to form salts and water
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Bases
Produce OH- ions in water
Taste bitter, chalky
Are electrolytes
Feel soapy, slippery
React with acids to form salts and water
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Learning Check AB1
Describe the solution in each of the following as: 1) acid 2) base or 3)neutral.
A. ___soda
B. ___soap
C. ___coffee
D. ___ wine
E. ___ water
F. ___ grapefruit
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Solution AB1
Describe each solution as:
1) acid 2) base or 3) neutral.
A. _1_ soda
B. _2_ soap
C. _1_ coffee
D. _1_ wine
E. _3_ water
F. _1_ grapefruit
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Learning Check AB2
Identify each as characteristic of an A) acid or B) base
____ 1. Sour taste
____ 2. Produces OH- in aqueous solutions
____ 3. Chalky taste
____ 4. Is an electrolyte
____ 5. Produces H+ in aqueous solutions
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Solution AB2
Identify each as a characteristic of an A) acid or B) base
_A_ 1. Sour taste
_B_ 2. Produces OH- in aqueous solutions
_B_ 3. Chalky taste
A, B 4. Is an electrolyte
_A_ 5. Produces H+ in aqueous solutions
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Some Common Acids
HCl hydrochloric acid
HNO3 nitric acid
H3PO4 phosphoric acid
H2SO4 sulfuric acid
CH3COOH acetic acid
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Learning Check AB3
Give the names of the following
A. HBr (aq) 1. bromic acid
2. bromous acid
3. hydrobromic acid
B. H2CO3 1. carbonic acid
2. hydrocarbonic acid
3. carbonous acid
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Solution AB3
A. HBr 3. hydrobromic acid
The name of a nonoxy acid begins with the prefix hydro- and ends with -ic acid. In a nonoxy acid, the negative anion end in -ide.
B. H2CO3 1. carbonic acid
The name of an oxyacid is named with the stem of the anion (carbonate) changed to
-ic acid
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Some Common Bases
NaOH sodium hydroxide
KOH potassium hydroxide
Ba(OH)2 ________________________
Mg(OH)2 ________________________
Al(OH)3 aluminum hydroxide
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Learning Check AB4
Match the formulas with the names:
A. ___ HNO2 1) hydrochloric acid
B. ___ Ca(OH)2 2) sulfuric acid
C. ___ H2SO4 3) sodium hydroxide
D. ___ HCl 4) nitrous acid
E. ___ NaOH 5) calcium hydroxide
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Solution AB4
Match the formulas with the names:
A. _4__ HNO2 1) hydrochloric acid
B. _5__ Ca(OH)2 2) sulfuric acid
C. _2__ H2SO4 3) sodium hydroxide
D. _1__ HCl 4) nitrous acid
E. _3__ NaOH 5) calcium hydroxide
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Learning Check AB5
Acid, Base Nameor Salt
CaCl2 ______ _________________
KOH ______ _________________
Ba(OH)2 ______ _________________
HBr ______ _________________
H2SO4 ______ __________________
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Solution AB5
Acid, Base Nameor Salt
CaCl2 salt calcium chloride
KOH base potassiuim hydroxide
Ba(OH)2 base barium hydroxide
HBr acid hydrobromic acid
H2SO4 acid sulfuric acid
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Acids & Bases –What they do with H+
Acids are hydrogen ion (H+) donors
Bases are hydrogen ion (H+) acceptors
HCl + H2O H3O+ + Cl-
donor acceptor + -
+ +
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Neutralization Reactions
When acid and bases with equal amounts of hydrogen ion H+ and hydroxide ions OH- are mixed, the resulting solution is neutral.
NaOH (aq) + HCl(aq) NaCl + H2O
base acid salt water
Ca(OH)2 + 2 HCl CaCl2 + 2H2Obase acid salt water
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Neutralization
H3O+ and OH- combine to produce water
H3O+ + OH- 2 H2O
from acid from base neutral
Net ionic equation:
H+ + OH- H2O
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Ionization of Water
Occasionally, in water, a H+ is transferred between H2O molecules
. . . . . . . .H:O: + :O:H H:O:H + + :O:H-
. . . . . . . . H H H
water molecules hydronium hydroxide ion (+) ion (-)
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Pure Water is Neutral
Pure water contains small, but equal amounts of ions: H3O+ and OH-
H2O + H2O H3O+ + OH-
hydronium hydroxide
ion ion
1 x 10-7 M 1 x 10-7 MH3O+ OH-
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Ion Product of Water Kw
[ ] = Molar concentration
Kw = [ H3O+ ] [ OH- ]
= [ 1 x 10-7 ][ 1 x 10-7 ]
= 1 x 10-14
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Acids
Increase H+
HCl (g) + H2O (l) H3O+ (aq) + Cl-
(aq)
More [H3O+] than water > 1 x 10-7M
As H3O+ increases, OH- decreases
[H3O+] > [OH-]H3O+
OH-
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Bases
Increase the hydroxide ions (OH-)
H2O
NaOH (s) Na+(aq) + OH- (aq)
More [OH-] than water, [OH-] > 1 x 10-7M
When OH- increases, H3O+ decreases
[OH] > [H3O+]
H3O+OH-
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pH
Indicates the acidity [H3O+] of the solution
pH = - log [H3O+]
From the French pouvoir hydrogene
(“hydrogen power” or power of
hydrogen)
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Concentration changes by powers of 10
pH =1 has 10x more than pH = 2
pH = 1 has 100x more than pH = 3
More Less
1 2 3 4 5 6 7 8 9 10 11 12 13 14
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In the expression for [H3O+]
1 x 10-exponent
the exponent = pH
[H3O+] = 1 x 10-pH M
pH
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pH Range
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Neutral
[H+]>[OH-] [H+] = [OH-] [OH-]>[H+]
Acidic Basic
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Some [H3O+] and pH
[H3O+] pH
1 x 10-5 M 5
1 x 10-9 M 9
1 x 10-11 M 11
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7 8 9 10 11 12 133 4 5 62 141 9 10 11 123 4 5 621
Neutral Weak Alkali
Strong
Alkali
Weak Acid
Strong Acid
The pH Scale
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Detecting Acids and Bases
• You can detect an acid using an indicator.
• INDICATOR - A substance that changes color in the presence of an acid or a base.
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INDICATORS• Litmus paper is an indicatorAn acid turns blue litmus paper redA base turns red litmus paper blue
• Cabbage juice can be used as an indicator
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• There are several ways to test pHThere are several ways to test pH
– Blue litmus paper (red = acid)Blue litmus paper (red = acid)
– Red litmus paper (blue = basic)Red litmus paper (blue = basic)
– pH paper (multi-colored)pH paper (multi-colored)
– pH meter (7 is neutral, <7 acid, >7 base)pH meter (7 is neutral, <7 acid, >7 base)
– Universal indicator (multi-colored)Universal indicator (multi-colored)
– Indicators like phenolphthaleinIndicators like phenolphthalein
– Natural indicators like red cabbage, Natural indicators like red cabbage, radishesradishes
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