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    MECHANICS OF

    MULTIFUNCTIONALMATERIALS & MICROSYSTEMS

    B. L. (Les) LeeProgram Manager

    AFOSR/NAAir Force Research Laboratory

    AFOSR

    18 March 2011

    Distribution A: Approved for Public Release. Distribution is unlimited. 88ABW-2011-0793

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    NAME: B. L. LeeBRIEF DESCRIPTION OF PORTFOLIO:Basic research forintegrationofadvanced materialsandmicro-systemsinto future Air Force systems requiringmulti-functionality

    LIST OF SUB-AREAS:Life Prediction (Materials & Devices);Sensing & Diagnosis;Micro-, Nano- & Multi-scale Mechanics;Multifunctional Design (Shape Change);Multifunctional Design (Property Tuning);Self-Healing & Remediation;Self-Cooling & Thermal Management;Self-Sustaining Systems & Energy Management;Precognition & Neutralization of Threats;Engineered Nanomaterials

    2011 AFOSR SPRING REVIEW2302B PORTFOLIO OVERVIEW

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    Multifunctional Design

    The objective of multifunctionality is improvement in system performance Use system metric(s) to identify functions to combine and quantify gains.

    General Rules:

    Add functionality to material with most complex function-physics.

    Target unifunctional materials/components operating in the mid-to-lowerfunctional performance regimes for multifunctional replacement.

    Implement multifunctionality in the conceptual stage of system design.

    Performance of multifunctional material/component may not be as good as itsunifunctional counterpart; irrelevant as long as system performance improves.

    Strong/weak coupling between the multiple function-physics may or may notexist and/or be important.

    Multifunctional potential depends on sub-system interfacing capabilities andfunction compatibility.

    RESEARCH ISSUESGuest Lecture by Dr. J. Thomas - 2008 AFOSR M^4 Program Review

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    RF-on-Flex

    Conformal Load Bearing Arrays

    SENSOR PLATFORMSSource: AFRL/RB

    Integrate antennafunction into the

    structureAntenna structure isload bearing

    LO enabling

    Reduced maintenance

    vulnerability

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    VISION: EXPANDED

    site specific

    autonomic

    AUTONOMICAEROSPACE

    STRUCTURES Sensing & Precognition

    Self-Diagnosis & Actuation

    Self-Healing

    Threat Neutralization

    Self-Cooling

    Self-Powered

    Biomimetics

    Design for CoupledMulti-functionality

    Nano-materials

    Multi-scaleModel

    Micro- & Nano-

    Devices

    Manufacturing Sci

    Neural Network &Information Sci

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    7

    VISION: EXPANDED

    site specific

    autonomic

    AUTONOMICAEROSPACE

    STRUCTURES

    Sensing & Precognition

    Self-Diagnosis & Actuation

    Self-Healing

    Threat Neutralization

    Self-Cooling

    Self-Powered

    Biomimetics

    Design for CoupledMulti-functionality

    Nano-materials

    Multi-scale

    Model

    Micro- & Nano-Devices

    Manufacturing Sci

    Neural Network &Information Sci

    11

    FUNCTIONS OF INTEREST

    Active Regulation

    Reactive Materials

    Mesoporous Networks

    Adaptive Fluids/Solids

    Self-Regulating

    FunctionSelf-Generating

    Function

    BIO-INSPIRED SYSTEMS:BEYOND CURRENT VISION

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    VISION: EXPANDED

    site specific

    autonomic

    AUTONOMICAEROSPACE

    STRUCTURES Sensing & Precognition

    Self-Diagnosis & Actuation

    Self-Healing

    Threat Neutralization Self-Cooling

    Self-Powered

    Biomimetics

    Design for CoupledMulti-functionality

    Nano-materials

    Multi-scaleModel

    Micro- & Nano-

    Devices

    Manufacturing Sci

    Neural Network &Information Sci

    ReconfigurableSystems

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    VISION: EXPANDED

    site specific

    autonomic

    AUTONOMICAEROSPACE

    STRUCTURES Sensing & Precognition

    Self-Diagnosis & Actuation

    Self-Healing

    Threat Neutralization Self-Cooling

    Self-Powered

    Biomimetics

    Design for CoupledMulti-functionality

    Nano-materials

    Multi-scaleModel

    Micro- & Nano-

    Devices

    Manufacturing Sci

    Neural Network &Information Sci

    Energy fromAerospace

    Environ

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    PROGRAM INTERACTION

    AFOSRStructural MechanicsStructural MaterialsOrganic Chemistry

    Biosciences

    MicroelectronicsOTHERS

    AFRL/RVSpace System

    AFRL/RYUAV Antennas

    AFRL/RWMicrosystems

    AFRL/RXComposites (2)Multiscale Anal

    AFOSR MURI 05

    Self-Healing

    AFOSR MURI 06

    Energy Harvesting

    EXTRAMURALUNIVERSITIES

    INDUSTRY

    MECHANICS OFMULTIFUNCTIONAL

    MATERIALS &MICROSYSTEMS

    AFRL/RBEnergy Mgt

    Fund Flow

    ArmyNavy

    DARPA

    GameChanger 07Antenna Integration

    Discovery CT 09Reconfigurable

    AFOSR MURI 09

    Sensing Network

    Directors Call 09Energy from Environ

    NSFESF

    NASA

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    NAME: B. L. LeeBRIEF DESCRIPTION OF PORTFOLIO:Basic research forintegrationofadvanced materialsandmicro-systemsinto future Air Force systems requiringmulti-functionality

    LIST OF SUB-AREAS:Life Prediction (Materials & Devices);Sensing & Diagnosis;Micro-, Nano- & Multi-scale Mechanics;Multifunctional Design (Shape Change);Multifunctional Design (Property Tuning);

    Self-Healing & Remediation;Self-Cooling & Thermal Management;Self-Sustaining Systems & Energy Management;Precognition & Neutralization of Threats;Engineered Nanomaterials

    2011 AFOSR SPRING REVIEW2302B PORTFOLIO OVERVIEW

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    NAME: B. L. LeeBRIEF DESCRIPTION OF PORTFOLIO:Basic research for integration of advanced materials and micro-systems into future Air Force systems requiring multi-functionality

    LIST OF SUB-AREAS:Life Prediction (Materials & Devices);Sensing & Diagnosis;Micro-, Nano- & Multi-scale Mechanics;Multifunctional Design (Shape Change);Multifunctional Design (Property Tuning);

    Self-Healing & Remediation;Self-Cooling & Thermal Management;Self-Sustaining Systems & Energy Management;Precognition & Neutralization of Threats;Engineered Nanomaterials

    PROGRAM TRENDS

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    SCIENTIFIC CHALLENGES &PROGRAM ACHIEVEMENT

    Self-healable or in-situ remendable structural materials(1st-everprogram; world lead)

    Microvascular composites for continuous self-healingand self-cooling systems (1st-everprogram; world lead)

    Structural integration of energy harvest/storagecapabilities (1st-everprogram on structurally integrated multipleenergy harvest capabilities; DoD lead)

    Neurological system-inspired sensing/diagnosis/

    actuation network (potlworld lead) Mechanized material systems and micro-devices for

    reconfigurable structures (DoD lead)

    Experimental nano-mechanics (DoD lead)

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    Transformational Opportunities

    Self-healable or in-situ remendable structural materials Quantum improvement in survivability of aerospace structures*

    Microvascular composites for continuous self-healingand self-cooling systems * & Ultimate thermal management

    Structural integration of energy harvest/storagecapabilities Self-sustaining UAV and hybrid-powered aircraft

    Neurological system-inspired sensing/diagnosis/actuation network Autonomic state awareness in aerospace

    Mechanized material systems and micro-devices forreconfigurable structures Morphing wing aircraft

    Experimental nano-mechanics Experimental verification ofmulti-scale analysis

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    Other Organizations That FundRelated Work

    Self-healable or in-situ remendable structural materials ARO (co-funding on thermal remediation; coord with MURI onself-healing chemistry); NSF; industry

    Microvascular composites for continuous self-healing

    and self-cooling systems NSF (manufacturing process) Structural integration of energy harvest/storage

    capabilities AFOSR/ARO/AFRL/ARL/NRL (DoD Task Force)

    Neurological system-inspired sensing/diagnosis/

    actuation network NSF/ESF (joint workshop, initiative coord) Mechanized material systems and micro-devices for

    reconfigurable structures AFRL/RX,RB,RW (joint lab task)

    Experimental nano-mechanics ARO (high-rate); Sandia

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    PROGRAM COLLABORATION

    THE 1ST

    MULTIFUNCTIONALMATERIALS FOR DEFENSE

    WORKSHOP

    Theme 10: Power and Energy

    In conjunction with:The 2010 Annual Grantees/Contractors Meeting for

    AFOSR Program on

    Mechanics of Multifunctional Materials & Microsystems(M^4)

    13-14 May 2010Hyatt Regency Reston, Reston, VA

    Workshop Co-Chairs:James Thomas (NRL)

    Eric Wetzel (ARL/WMRD)William Baron (AFRL/RBSA)

    Organizing Committee:B.-L. (Les) Lee (AFOSR), Co-Chair

    Bruce LaMattina (ARO), Co-ChairWilliam Baron (AFRL/RBSA)Gregory Reich (AFRL/RBSA)

    William Nothwang (ARL/SEDD)Daniel OBrien (ARL/WMRD)

    Eric Wetzel (ARL/WMRD)James Thomas (NRL)

    Agent for 8 Projects; Concluded

    BAA 06-028:

    FY07 ARO MURI Topic #24Self-healing Polymer Composites through

    Mechanochemical TransductionGrant PI: Jeff Moore (UIUC)

    PM: David Stepp (ARO)

    Co-PM: Douglas Kiserow (ARO)

    WORKSHOP:2006/01/05, Chapel Hill, NC

    KICK-OFF:2007/10/03, Aberdeen, MD

    BioSensing and BioActuationProposed Research Opportunities/Challenges

    1. Hierarchical Organization of Biological SystemsUncover the unifying aspects underlying hierarchical bio-structures and bio-systems and usethem for sensing and actuation; apply to new multi-scale and multi-functional sensor/actuatorconcepts.

    2. Sensor Informatics Guided by LifeCreate new knowledge that will be exploited in novel bio-inspired data mining and dynamiccontrol, including capabilities to monitor, assess, and control living and engineered systems in

    sensor-rich environments.3. Multifunctional Materials and Devices for Distributed

    Actuation and SensingUnderstand biological systems and mechanisms that lead to their ability to exhibit fault-tolerant

    actuation with a wide dynamic range, the production of practical means for producing artificialstructures that exhibit similar behaviors, and their incorporation into useful engineered systems.

    4. Forward Engineering & Design of Biological/BiomedicalComponents & SystemsSynthesize hybrid synthetic-living systems through systems-level integration of biological andengineered components that sense, actuate, compute, regenerate and efficiently allocateresources in order to achieve desired responses and functions.

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    VISION: EXPANDED

    site specific

    autonomic

    AUTONOMICAEROSPACE

    STRUCTURES Sensing & Precognition

    Self-Diagnosis & Actuation

    Self-Healing

    Threat Neutralization Self-Cooling

    Self-Powered

    Biomimetics

    Design for CoupledMulti-functionality

    Nano-materials

    Multi-scaleModel

    Micro- & Nano-

    Devices

    Manufacturing Sci

    Neural Network &Information Sci

    ReconfigurableSystems

    Energy fromAerospace

    Environ

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    VISION: EXPANDED

    site specific

    autonomic

    AUTONOMICAEROSPACE

    STRUCTURES Sensing & Precognition

    Self-Diagnosis & Actuation

    Self-Healing

    Threat Neutralization Self-Cooling

    Self-Powered

    Biomimetics

    Design for CoupledMulti-functionality

    Nano-materials

    Multi-scaleModel

    Micro- & Nano-

    Devices

    Manufacturing Sci

    Neural Network &Information Sci

    PIs & Co-PIs:

    Scott White(UIUC)Jeffrey Moore(UIUC)Nancy Sottos(UIUC)Sia Nemat-Nasser(UC San Diego)Markus Buehler(MIT)Scott White(UIUC)*Jeffrey Moore(UIUC)*

    Nancy Sottos(UIUC)*Jennifer Lewis(UIUC)*Philippe Geubelle(UIUC)*Kenneth Christensen(UIUC)*Jonathan Freund(UIUC)*Chris Mangun(CU Aero)Tom Darlington(Nanocomposix)

    Tony Starr(SensorMetrix)Tom Hahn(UCLA)

    ^ YIP; * MURI

    THREE APPROACHES

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    THREE APPROACHESFOR SELF-HEALING

    MICRO & NANOCAPSULES

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    SEM of 20wt% functionalized capsules in Epoxy (EPON 828/DETA)

    10 um

    Shell wall

    1 m

    100 nm

    Microtome Epoxy

    (3-glycidoxypropyl)trimethoxysilane(GLYMO) to limit aggregation andimprove dispersion

    SiO2

    PUF

    Core09: MICRO & NANOCAPSULESFOR SELF-HEALING (UIUC: Sottos)

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    All fibers coated by dip-coat method All concentrations determined by TGA

    15 m

    Successfully deposited capsules onto bothglass and graphite fibers using a solution dipcoating procedure

    Capsule Deposit On Fibers

    MICROVASCULAR COMPOSITES

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    Objective:

    DoD Benefit:

    Technical Approach:

    Budget:

    $K

    Major Reviews/Meetings:

    FY05 FY06 FY07 FY08 FY09 FY10

    504,311 1,242,709 1,047,076 1,115,244 1,057,424 500,920

    To achieve synthetic reproduction of autonomicfunctions, such as self-healing and self-cooling,for aerospace platforms through creation andintegration of complex materials systemscontaining microvasculararchitectures.

    (a) Natural models of microvascular systemsare studied to guide the engineering design ofoptimal networks for self-healing and self-cooling structural composites. (b) Thesenetworks are fabricated using direct-writeassembly techniques while integrating materialcomponents that realize the desired multi-

    functionality. (c) A full compliment ofexperimental and analytical techniques areemployed to demonstrate system efficiency.

    The advances in self-healing and self-coolingcomposite structures will lead to the increaseof reliability and responsiveness of aerospacevehicles allowing longer flight time and

    reduced chance for unexpected failure.

    30 August 2006: Seattle, WA 20 August 2007: Urbana, IL21 August 2008: Arlington, VA31 August 2009: Urbana, IL

    Nature01

    MICROVASCULAR COMPOSITES(UIUC/Duke/UCLA: White et al)

    MURI 05

    PM:B. L. Lee (NA); Co-PM:Hugh Delong (NL)

    Mi l H li

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    Microvascular HealingPerformance Comparison

    Optimal pressure profiles for dynamic pumping enable 100%

    healing efficiency for repeated healing cycles

    MURI 05

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    Pressure Driven Flow Oscillation

    Qualitative match between experimental and simulation results

    Simulation of pump driven oscillation in a T-junction Experiment with pump driven oscillation in a 25 m simulated crack

    Simulation

    Experiments

    Interface folding Packet of well mixed

    fluid

    MURI 05

    Engineering Design Of

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    Multiple Network:2 part epoxy(Toohey et al. Adv. Func. Mat. 2009)

    Interpenetrating Network:2 part epoxy(Hansen et al., Adv. Mat. 2009)

    Single Network:DCPD/Grubbs(Toohey et al, Nature Materials, 2007)

    Engineering Design OfMicrovascular Network

    MURI 05

    3D Microvacular Composites Via

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    3D Woven Preform Integration of Sacrificial Fibers Resin Infusion

    3D Woven Composite Fiber Removal 3D Vascular Composites

    3D Microvacular Composites ViaSacrificial Fibers

    MURI 05

    5 mm

    Development of Sacrificial

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    Treatment of PLA fibers by solvent-assisted catalyst diffusion

    Drying

    Development of SacrificialPolylactide (PLA) Fibers

    When exposed to high temperature, a catalyst treated PLA fiber depolymerizes

    into gaseous monomer thereby making the evacuation process very easy.

    MURI 05

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    Journal Covers

    INTERACTIONS WITH

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    University of BristolMultifunctional Materials Group

    Ian BondHollow fiber delivery

    EPFL Laussane

    Laboratoire de technologie des composites et polymresJan-Anders Mnson, Vronique MichaudShape memory + self-healing

    AFRL/RXPolymers and Composites Branches

    Jeff Baur, Rich Vaia, Ajit RoySacrificial wax fibers, permeability testing, composites design

    INTERACTIONS WITHOTHER RESEARCH GROUPS

    Delft UniversityCentre for Materials

    Sybrand van der ZwaagShaped encapsulation vesicles

    MURI 05

    Technology Transfer:

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    Transitioning of capsule technology for self-healing composites, adhesive & coating

    Key challenges are size scale and integration method

    Technology Transfer:

    SELF-HEALING MATERIALS

    2006-2009: STTR (AF) on self-healingaerospace composites

    2009: STTR (Army) on self-healing, self-diagnosing multifunctional composites

    Self-healing coatings for electronics

    Application development for adhesive

    MURI S i ff STTR08 THERMALLY

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    O

    O

    O

    O

    O

    Mendomer 401

    O

    O

    O

    O

    O O

    Mendomer 602

    Goals:

    Less brittle and lower glass transitiontemperature (Tg) for better adhesionand conformal coating

    MURI Spin-off>>STTR08: THERMALLYREMENDABLE COMPOSITES

    19

    HEAT

    THERMALLY REMENDABLEPOLYMERS (UCLA: Wudl)

    C O O

    O

    O

    4

    N

    N

    O

    O

    3

    O+ N

    O

    O

    O

    N

    O

    OPolymer

    N N

    O

    OO

    O

    MURI05

    4th DAMAGE 4th HEALING

    5th HEALING5th DAMAGE

    Healing ofDelamination

    StrainEnergy (mJ)

    HealingEfficiency (Time)

    Virgin 10.04

    1st healing 8.68 86.4% (1 hr)

    2nd healing 8.88 88.4% (2 hr)

    3rd healing 9.82 97.8% (3 hr)

    4th healing 9.42 93.8% (3 hr)

    Crosslink bonds of Diels-Alder cyclo-addition

    polymers are thermally reversible and can bereestablished after separation (unlike epoxy)

    Fabricated CFRPs with thermally remendablematrix materials and resistive heating network ofcarbon fiber reinforcement

    Demonstrated multiple rounds of healing ofdelamination and microcracks

    Resistive heating is dependent on layuporientation and most uniform with surfaceelectrodes laid at 45 relative to fibers Structural properties of CFRPs are comparableto traditional epoxy based CFRPs

    Core10: BIO INSPIRED STRUCTURAL

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    Core10: BIO-INSPIRED STRUCTURALREMODELING (UIUC: White/Moore)

    Regeneration in biology: New approach: Dynamic polymers

    + inert scaffolds

    *Dynamic polymers can be reversibly changedfrom liquid to solid and vice versa due todynamic covalent bond that can be triggered to

    disassociate by an activating agent.

    *

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    VISION: EXPANDED

    site specific

    autonomic

    AUTONOMICAEROSPACE

    STRUCTURES Sensing & Precognition

    Self-Diagnosis & Actuation

    Self-Healing

    Threat Neutralization Self-Cooling

    Self-Powered

    Biomimetics

    Design for CoupledMulti-functionality

    Nano-materials

    Multi-scaleModel

    Micro- & Nano-

    Devices

    Manufacturing Sci

    Neural Network &Information Sci

    PIs & Co-PIs:

    Abraham Stroock(Cornell U)Noel Holbrook(Harvard U)Patrick Kwon(Mich St U)Vikas Prakash(Case Western)Scott White(UIUC)*Jeffrey Moore(UIUC)*Nancy Sottos(UIUC)*

    Jennifer Lewis(UIUC)*Philippe Geubelle(UIUC)*Kenneth Christensen(UIUC)*Jonathan Freund(UIUC)*Ajit Roy(AFRL/RXBT)Jeff Baur(AFRL/RXBC)

    * MURI

    Multi-physics Optimization of

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    Multi-physics Optimization ofMicrovascular Network

    Multi-objective constrained genetic algorithms Generalized finite element method for fluid/solid thermal problem

    2D and 3D implementation for network optimization

    Initial grid Optimal network

    MURI 05

    Enhancing Heat Transfer with

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    Heat-TransferEnhancement >Increased pressuredrop

    Enhancing Heat Transfer withWavy Microchannels

    Serpentine microchannel

    Flow direction

    2a

    Secondary flows due to waviness drawhot fluid from wall into main flowstreamCrest Trough

    Efficiency of serpentine (wavy) channels in enhancingconvective heat transfer studied computationally todetermine optimal waviness and flow rates.

    Various a/ studied (a=amplitude;=wavelength of waviness).

    Bulk heat transfer in wavy channels comparedto that of a straight microchannel of equivalenthydraulic diameter.

    Efficiency, :

    MURI 05

    PLANT-MIMETIC HEAT PIPES

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    Robust heat transfer in the presenceof large gravitational and inertial

    stresses.

    Plant mimetic use of liquids at large

    negative pressures within a microfluidic

    heat pipe.

    Fundamental understanding of

    thermodynamics and transport

    processes in this regime. Insights into plant strategies for the

    management of negative pressures and

    recovery from cavitation.

    Objectives:

    MEMS platform

    Achievements:

    Plant physiology

    Elucidation of structure and

    biochemistry xylem elements

    implicated in autonomic refilling. Physical, chemical, and molecular

    biological characterization of refilling.

    Figure: AFM image of bordered pit

    membrane.Fabrication.

    Development of wick membrane in

    silicon platform with unprecedented

    stability (down to -200 bars - Figure). Development of MEMS sensor for

    measuring pressures down to -500

    bars.

    Figure: Development and testing of

    inorganic wick membrane. Stability

    limit of liquid water. Complete stability

    to -3 MPa (-30 bars). Absolute limit:

    -20 MPa (-200 bars).

    Perspectives:

    Foundation of technical approachesand physical and biological

    understanding to enable robust

    engineering with liquids at negative

    pressures.

    Efficient, passive heat transfer with

    small form factor and weight for

    avionics cooling.

    0%

    20%

    40%

    60%

    80%

    100%

    0 10 20 30

    %intact

    Pressure ( -MPa)

    cavitatedintact

    silicon solgel

    PLANT-MIMETIC HEAT PIPES(Cornell U / Harvard U: Stroock)

    THERMAL MANAGEMENT OF

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    ACCOMPLISHMENTS:

    Developed molecular dynamics (MD) computationaltools to study the effect of CNT side wallfunctionalization with CH2 molecules on the interfacethermal conductance at the atomistic scale

    Simulated two axially aligned CNTs embedded inepoxy polymer, one is being heated and thermalenergy taken out through the other.

    The temperature drop between the CNT decreaseswith increasing functionalization, but the interfaceresistance does not diminish to zero even with

    saturation of the functionalization

    MD simulation ofCNT embedded inpolymer network

    Effect of CNT polymerfunctionalization on interface

    thermal resistance

    b c d e

    THERMAL MANAGEMENT OFINTERFACE (AFRL/RX: Roy)

    BACKGROUND:

    Lack of knowledge in materials design for improvingthermal conductivity of fiber reinforced composites

    At least 20x improvement of through-the-thicknessthermal conductivity (to ~ 7-10 W/mK) is desired

    OBJECTIVE:

    To establish multiscale modeling for multifunctionaldesign integrated with processing of materials

    To enhance thermal conductivity of composites byusing nano-constituents on carbon fibers to form athermal pathway network through the matrix phase

    DoD BENEFITS:

    Establishment of fiber reinforced composites withenhanced through-the-thickness thermal properties

    for aerospace platforms Transition of the computational modeling capability

    for innovative thermal interface design of composites

    S O P

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    VISION: EXPANDED

    site specific

    autonomic

    AUTONOMICAEROSPACE

    STRUCTURES Sensing & Precognition

    Self-Diagnosis & Actuation

    Self-Healing

    Threat Neutralization Self-Cooling

    Self-Powered

    Biomimetics

    Design for CoupledMulti-functionality

    Nano-materials

    Multi-scaleModel

    Micro- & Nano-

    Devices

    Manufacturing Sci

    Neural Network &Information Sci

    PIs & Co-PIs:

    Gregory Huff(Texas A&M)Akira Todoroki(Tokyo Tech)fu-Kuo Chang(Stanford U)*Peter Peumans(Stanford U)*Boris Murmann(Stanford U)*Philip Levis(Stanford U)*Andrew Ng(Stanford U)*

    Rahmat Shoureshi(U Denver)*Robert McLeod(U CO)*Greg Carman(UCLA)*Yong Chen(UCLA)*Frank Ko(U Brit Columbia)*Somnath Ghosh(Ohio St U)*^John L. Volakis(Ohio St U)Roberto Rojas(Ohio St U)^Stephen Bechtel(Ohio St U)^Dick James(U MN)^Max Shtein(U Mich)^Nick Kotov(U Mich)^Ben Dickinson(AFRL/RWGN)Greg Reich(AFRL/RBSA)Jeff Baur(AFRL/RXBC)

    * MURI; ^ GameChanger

    BUILT-IN SENSING NETWORK

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    Stretchable Matrix

    Autonomous System

    Multi-Scale Design,Synthesis & Fabrication

    Sensors(temperature,

    pressure,strain, etc)

    Local neurons(processor, memory,

    communicationdevices)

    BUILT-IN SENSING NETWORK(Stanford/UC/DU/UCLA: Chang et al)

    MURI 09

    Synaptic Circuits

    Synapse:

    Cognition and decision-making aredetermined by a relative level ofcumulative signal strength with respectto the synapse threshold values

    Biological sensory systems

    rely on large numbers ofsensors distributed overlarge areas and arespecialized to detect andprocess a large number ofstimuli. These systems arealso capable to self-organizeand are damage tolerant.

    PM:B. L. Lee (NA); Co-PM:Hugh Delong (NL)

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    SENSORS/ACTUATORS FOR MAV

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    Flow Sensing Hairs - Principles of bio hairs

    understood, but translation to engineered

    system with similar performance is not

    Models - Models for hair feedback control

    have not been examined

    Materials - Silicon or polymer hairs with

    optical, piezoresistive, or capacitive

    transduction shown Carbon nanotube (CNT)

    gauge factor to 1000 for single-CNT devices,

    ~2 for traditional gauge factors, limited work

    on CNT array strain sensing, even less on fiber

    Artificial Hair Concept - CNT arrays on

    rigid fibers have the required hair rigidity/

    dimension, displacement sensitivity, material

    robustness, and design flexibility to enable

    integrated flow sensing to detect gust

    alleviation and enable complex maneuvering

    Model - Hair length vs. boundary layer

    thickness can be optimized for increased

    sensitivity

    Materials - CNT array mechanics are highly

    dependent on morphology, but vertically

    aligned CNT (VACNT) sensor yields nearly

    linear resistance change with strain

    MAIN ACHIEVEMENTS:

    Artificial Hair Model - Developed viscoelastic, nonlinear

    fluid reaction hair sensor model Explored design

    geometry & material for individual hair performance

    Materials - Characterized morphology effect of VACNT

    array mechanics Developed and characterized first

    VACNT-based electromechanical flow/strain sensor

    HOW IT WORKS: Model - Numerically solve hair sensor governing

    equations to explore and optimize design

    Materials - Compression reorients CNTs, reducing

    electrical resistance Force imparted to hair converted toelectrical signal within sensor pore

    ASSUMPTIONS AND LIMITATIONS: Model - Assume 1-way interaction (flow to hair) with

    parallel surface, small deflections, rt circular X-section

    Materials - Repeatable and uniform CNT deposition

    Robust adhesion of CNTs to carbon fiber with

    environmental changes

    Current Impact Optimal hair lengths are 50-100% of (d99)

    boundary layer thickness for steady flow

    Pore sensitive to depth, not width with 1.5-

    3 micron level deflections expected

    Planar VACNT sensor gauge factor of 30

    Planar flow sensor created on copper

    substrate (difficult)

    Planned Impact Test CNT sensor in wind tunnel (Eglin AFB)

    Enhance sensor gauge factor

    Extend to fuzzy fiber for artificial hair

    Extend model to oscillatory flow

    Eval. sensor impact on vehicle performance

    Research Goals Model & validate artificial hair model

    Understand parameter space for optimal

    sensor performance

    Understand and model physics of

    electromechanical response of CNT array

    Demonstrate flow sensing capability inside

    wind tunnel

    CNT-Based Artificial Hair Airflow Sensor

    STATEOFTHEART

    END-OF-PHASEGOAL

    QU

    ANTITATIVEIMPACT

    NEWINSIGHTS

    Nanoindentation of foam-like and beam-like VACNT arrays

    Schematic of proposed CNT-coated carbon fiber sensor

    Planar CNT Flow Sensor Prototype on DMA

    Localized CNTBuckling

    SENSORS/ACTUATORS FOR MAV(RW: Abate; RB: Reich; RX: Baur)

    LOAD-BEARING ANTENNAS

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    Ohio State University / College of Engineering

    CHANGING COURSE FOR UAVS

    Ohio State electrical and computer engineers have solved a radar and surveillanceproblem for unmanned aerial vehicles (UAVs) with the help of atypicalcollaborators: embroidery experts.

    The UAVs ranging in size from more than 40 feet long to ones that could beeasily confused with hi-tech Frisbees can serve many functions, fromsurveillance to data collection. However, their relatively small size cannot

    accommodate the large antennas necessary for long-distancecommunication. So the engineers are developing new technology to weavesensor and communication antenna systems into the structure of the UAVs.

    This research is part of the three-year, $3.5 million GameChanger program, now inits final year and funded by the Air Force Defense Research Sciences Program.

    The GameChanger philosophy involves a different perspective on aircraft design:Instead of mechanical and aerospace engineers designing a plane foraerodynamics, in this case electrical and computer engineers dictate the initialform of the plane based on its radar or surveillance function.

    To weave the sensor and communication systems into the structure of the aircraft so the UAV itself becomes the antenna researchers needed lightweight,load-bearing, flexible materials that could conform to the aircrafts surface.Polymers fit the required criteria, but first researchers had to determine how to printantennas on them, as polymers are not mechanically compatible with traditionalconductors.

    News in Engineering

    antenna layer:microstrip patches,dipoles, bowties and etc.

    feeding layer:feeding networks,impedance tuning stubs

    circuits layer:filters, mixers,LNAs and etc.

    LOAD BEARING ANTENNAS(OSU/U Mich/U MN/UCLA: Volakis)

    LOAD-BEARING ANTENNAS

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    Design next generation antennas (broadband and narrowband) that are

    structurally ruggedized, reconfigurable and sufficiently miniaturized forUAV applications.

    Develop a new class of materials for load-bearing/conformal/light-weightantennas (incl. ferroelectric, ferromagnetic, multi-ferroic, bondable polymercomposites, 3D textiles and nanomaterials).

    Develop analytical techniques for tractable electro-magneto-thermo-mechanical theory from fully coupled 3-D equations.

    Integrate new antenna designs into a lightweight structure and developfigures of merit (design rules) for structural integration.

    Objectives:

    Main Achievements:

    Developed new technology by embroidering metal coated electronic fibers(e-fibers) on polymers for conformal load bearing antennas.

    Designed and tested volumetric and planar woven antennas based on e-fibers and polymer composites

    Demonstrated the feasibility of first everCNT antenna whose gain isequivalent to the perfectly conducting (but rigid) patch antennas.

    Developed coupled multi-physics & multi-scale models for electro-magnetic composite materials undergoing mechanical excitation.

    Developed models to tune antenna via ferroelectrics materials undermechanical and thermal loads

    Developed fully overlapping Domain Decomposition Technique for FiniteElement Modeling of small features in large media

    antenna layer:microstrip patches,dipoles, bowties and etc.

    feeding layer:feeding networks,impedance tuning stubs

    circuits layer:filters, mixers,LNAs and etc.

    LOAD BEARING ANTENNAS(OSU/U Mich/U MN/UCLA: Volakis)

    GameChanger07PM:B. L. Lee (NA); Co-PM:Arje Nachman (NE)

    VISION EXPANDED

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    VISION: EXPANDED

    site specific

    autonomic

    AUTONOMICAEROSPACE

    STRUCTURES Sensing & Precognition

    Self-Diagnosis & Actuation

    Self-Healing

    Threat Neutralization Self-Cooling

    Self-Powered

    Biomimetics

    Design for CoupledMulti-functionality

    Nano-materials

    Multi-scaleModel

    Micro- & Nano-

    Devices

    Manufacturing Sci

    Neural Network &Information Sci

    ReconfigurableSystems

    PIs & Co-PIs:

    Ray Baughman(U Texas Dallas)Nicolas Triantafyllidis(U Mich)John Shaw(U Mich)Shiv Joshi(NextGen)Sharon Swartz(Brown U)Nakhiah Goulbourne(VA Tech)Benjamin Shapiro(U MD)

    Elisabeth Smela(U MD)Patrick Mather(Syracuse U)H. Jerry Qi(U CO)Martin Dunn(U CO)Minoru Taya(U WA)Frank Ko(U Brit Columbia)Hiroyuki Kato(Hokkaido U)Xin Zhang(Boston U)C. T. Sun(Purdue U)Thomas Siegmund(Purdue U)Aaron Dollar(Yale U)A. John Hart(U Mich)Greg Reich(AFRL/RBSA)Richard Vaia(AFRL/RXBN)

    ^ YIP

    VISION EXPANDED

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    VISION: EXPANDED

    site specific

    autonomic

    AUTONOMICAEROSPACE

    STRUCTURES Sensing & Precognition

    Self-Diagnosis & Actuation

    Self-Healing

    Threat Neutralization Self-Cooling

    Self-Powered

    Biomimetics

    Design for CoupledMulti-functionality

    Nano-materials

    Multi-scaleModel

    Micro- & Nano-

    Devices

    Manufacturing Sci

    Neural Network &Information Sci

    Energy fromAerospace

    Environ

    PIs & Co-PIs:

    Max Shtein(U Mich)+Henry Sodano(U FL)Dan Inman(VA Tech)Sven Biln(Penn St U)Michael Strano(MIT)Greg Carman(UCLA)Gleb Yushin(GA Tech)

    Minoru Taya(U WA)*Paolo Feraboli(U WA)*Martin Dunn(U CO)*Ronggui Yang(U CO)*Kurt Maute(U CO)*Se-Hee Lee(U CO)*Y. Sungtaek Ju(UCLA)*Tom Hahn(UCLA)*

    Dan Inman(VA Tech)*Ioannis Chasiotis(UIUC)*Carl Schulenburg(PowerMEMS)Tim Fisher(Purdue U)Benji Maruyama(AFRL/RXBN)Thuy Dang(AFRL/RXBN)Michael Durstock(AFRL/RXBN)

    + PECASE; ^ YIP; * MURI

    INTEGRD ENERGY HARVESTING

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    Objective:

    To develop self-powered load-bearingstructures with integrated energy harvest/storage capabilities, and to establish new multi-functional design rules for structuralintegration of energy conversion means.

    DoD Benefit:Self-powered load-bearing structures withintegrated energy harvest/storage capabilitieswill provide meaningful mass savings andreduced external power requirements over awide range of defense platforms includingspace vehicles, manned aircraft, unmanned

    aerial vehicles, and ISR systems.

    Technical Approach:

    (a) A combination of experimental andanalytical techniques are employed to advancethe efficiency of the energy conversion means(as an integral part of load-bearing structures)and to optimize their multifunctionalperformance and ability to cover larger areas.

    (b) Multifunctional composites are created with

    individual layers acting as photovoltaic/thermo-electric/piezoelectric power harvesting andelectrochemical power storage elements.

    Budget:

    $K

    FY06 FY07 FY08 FY09 FY10 FY11

    693,335 1,169,560 1,180,608 1,219,324 1,179,991 568,571

    Major Reviews/Meetings: 29 August 2007: Seattle, WA 5 August 2008: Boulder, CO

    11 August 2009: Blacksburg, VA18 August 2010: Los Angeles, CA

    polymersolar cells

    thermo-electrics (TE)antenna system underthe wing with TE

    polymerbattery cells

    INTEGR D ENERGY HARVESTING(U WA/U CO/UCLA/VPI: Taya et al)

    MURI 06

    PM:B. L. Lee (NA);

    Co-PMs: Joan Fuller (NA), David Stargel (NA)

    INTEGRD ENERGY HARVESTING

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    Year 4 Highlights

    Developed new anti-reflection surface coating inspired bymoth eyes for solar cells with higher transmittance

    Process scale-up of dye-sensitized solar cells (DSSC) Integrated the DSSC onto a quasi-wing structure and

    confirmed the endurance under 44,000+ bending cycles Shrink-fit integration and FGM electrodes for linear TE

    modules with increased durability Microwave synthesis of nano-particles of Bi2Te3 Design of scalable and stretchable thin-film Li ion

    batteries for UAV structures Modeling of electrochemical and mechanical response of

    solid-state electrolyte and their morphology effects

    Simulations predicting onset of mechanical failure leadingto capacity fade in agreement with experiments

    Experimental characterization of cracking and twining in Sianode with Li ion insertion (first-everobservation).

    Assessed battery survivability in co-curing environment UAV test bed at U Colorado

    INTEGR D ENERGY HARVESTING(U WA/U CO/UCLA/VPI: Taya et al)

    MURI 06

    4-Point Bending Test

    DSSC

    e

    e

    e

    e

    e

    e

    e

    e

    Li+

    Li+Li+

    Li+

    Li+

    A

    e

    e

    e

    e

    e

    e

    e

    e

    Li+

    Li+Li+

    Li+

    Li+

    A

    Fe-SMA

    Cu-SMA

    SCIENTIFIC CHALLENGES &

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    SCIENTIFIC CHALLENGES &PROGRAM ACHIEVEMENT

    Self-healable or in-situ remendable structural materials(1st-everprogram; world lead)

    Microvascular composites for continuous self-healingand self-cooling systems (1st-everprogram; world lead)

    Structural integration of energy harvest/storagecapabilities (1st-everprogram on structurally integrated multipleenergy harvest capabilities; DoD lead)

    Neurological system-inspired sensing/diagnosis/actuation network (potlworld lead)

    Mechanized material systems and micro-devices forreconfigurable structures (DoD lead)

    Experimental nano-mechanics (DoD lead)

    PROGRAM TRENDS

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    NAME: B. L. Lee

    BRIEF DESCRIPTION OF PORTFOLIO:Basic research for integration of advanced materials and micro-systems into future Air Force systems requiring multi-functionality

    LIST OF SUB-AREAS:

    Life Prediction (Materials & Devices);Sensing & Diagnosis;Micro-, Nano- & Multi-scale Mechanics;Multifunctional Design (Shape Change);Multifunctional Design (Property Tuning);

    Self-Healing & Remediation;Self-Cooling & Thermal Management;Self-Sustaining Systems & Energy Management;Precognition & Neutralization of Threats;Engineered Nanomaterials

    PROGRAM TRENDS

    EXPERIMENTAL NANOMECHANICS

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    Cracks were imaged in nanometer

    scale by AFM to obtain their geometryand the grain structure at the crack tip.

    Doping caused a drop in fracturetoughness of laminated polysiliconwhile it increased the toughness of

    coarse grain polysilicon films

    10 m

    Edge crack

    Substrate

    Specimen

    150 m

    25 m long sharp cracks created in 2 mthin polycrystalline silicon specimens bynanoindentation near free edge

    Crack tip

    500 nm

    EXPERIMENTAL NANOMECHANICS(UIUC: Chasiotis)

    MULTISCALE ANALYSIS:

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    U SC S SOn-Going Research

    72

    Cracks were imaged in nanometerscale by AFM to obtain their geometryand the grain structure at the crack tip.

    Doping caused a drop in fracturetoughness of laminated polysilicon

    while it increased the toughness ofcoarse grain polysilicon films

    10 m

    Edge crack

    Substrate

    Specimen

    150 m

    25 m long sharp cracks created in 2 mthin polycrystalline silicon specimens bynanoindentation near free edge

    Crack tip

    500 nmEXPERIMENTAL NANOMECHANICS(UIUC: Chasiotis)

    36

    MAIN ACHIEVEMENTS:

    HOW IT WORKS: The non-linear mechanical response of hierarchical

    structure of proteins is caused by the structural transition

    mechanisms during deformation.

    The alterable structure enables proteins to combine

    disparate material properties (flexible, strength,

    robustness).

    The structural and mechanical property of

    intermediated filaments are altered by point mutation.

    Current engineering materialsRemain limited in their ability to

    combine disparate properties such

    as high strength, robustness,

    self-healing, mutability

    Biological materials and structures Show intriguing material properties combine

    disparate properties in a single material

    De novo materials design Requires bottom-up structural design, from nano

    to macro need to understand structure-property

    links in biological materials

    Multi-scale analysis of biological

    structures Intermediated filaments, found in cells nuclear

    envelop, provide intriguing mechanical properties

    provide great extensibility, strength, mechanical

    robustness, and ability to self-heal structural

    analysis reveals a intricate design, from atomistic to

    macroscopic.

    IMPACT Provide the first atomic

    mechanism and condition

    of the stiffening behaviorof alpha-helical materials.

    Developed model to link

    the microscopic structural

    transition with the

    macroscopic behavior.

    Enables to seek the

    mechanical property of

    protein materials with

    mutation.

    TRANSITIONS New MURI project for fiber design PI visitedAFRL in 2010 (Wright-Patterson AFB) PI

    awarded PECASE

    FUTURE RESEARCH GOALS Facilitate merger of structure, material

    property and function through the bottom-up

    multi-scale design, from atomic to macroscopicbehavior.

    Quantitatively understand the assembling

    process of protein materials and factors to

    affect the material property of those assembled

    structures.

    Quantitatively understand the cascaded

    activation of mutations and their effect on

    material performance.

    Provide basis for new engineering paradigm

    to functionalize the hierarchical structural

    materials (e.g. new composites or polymers

    combine high flexibility, ultimate strength, self

    healing and robustness): novel materials for

    advanced Air Force technologies

    Multi-scale approach to understand biological protein materials & translate design concepts into engineering applications

    STATUS

    QUO

    END-OF-PHASEGOAL

    QUANTITATIVEIMPACT

    NEWINSIGHTS

    Study of nuclear lamina

    (meshwork of filaments).

    Discovered the flaw

    tolerance of this structure is

    caused by non-linear

    mechanical response of

    intermediate filaments.The adhesion energy of

    the lamin tail is changed

    due to mutation, leading

    to altered mechanical

    response of filaments

    Mechanism of the - transition caused by mechanical force.

    Structural transition related

    Non-linear mechanical property

    Qin, Kreplak, Buehler, PRL, 2010, PLOS ONE, 2009

    Qin, Buehler, PRL, 2010

    Example of hierarchical structure of lamin at nuclear

    lamina.

    Materials science paradigm

    applied to the hierarchical

    structure of protein

    materials.

    Buehler,Nature Nanotechnology,1

    STRUCTURAL HIERARCHIES INPROTEIN MATERIALS (MIT: Buehler)

    MULTISCALE ANALYSIS:

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    U SC S SJoint ARO/AFOSR/NSF Workshop

    72

    Cracks were imaged in nanometerscale by AFM to obtain their geometryand the grain structure at the crack tip.

    Doping caused a drop in fracturetoughness of laminated polysilicon

    while it increased the toughness ofcoarse grain polysilicon films

    10 m

    Edge crack

    Substrate

    Specimen

    150 m

    25 m long sharp cracks created in 2 mthin polycrystalline silicon specimens bynanoindentation near free edge

    Crack tip

    500 nmEXPERIMENTAL NANOMECHANICS(UIUC: Chasiotis)

    36

    MAIN ACHIEVEMENTS:

    HOW IT WORKS: The non-linear mechanical response of hierarchical

    structure of proteins is caused by the structural transition

    mechanisms during deformation.

    The alterable structure enables proteins to combine

    disparate material properties (flexible, strength,

    robustness).

    The structural and mechanical property of

    intermediated filaments are altered by point mutation.

    Current engineering materialsRemain limited in their ability to

    combine disparate properties such

    as high strength, robustness,

    self-healing, mutability

    Biological materials and structures Show intriguing material properties combine

    disparate properties in a single material

    De novo materials design Requires bottom-up structural design, from nano

    to macro need to understand structure-property

    links in biological materials

    Multi-scale analysis of biological

    structures Intermediated filaments, found in cells nuclear

    envelop, provide intriguing mechanical properties

    provide great extensibility, strength, mechanical

    robustness, and ability to self-heal structural

    analysis reveals a intricate design, from atomistic to

    macroscopic.

    IMPACT Provide the first atomic

    mechanism and condition

    of the stiffening behaviorof alpha-helical materials.

    Developed model to link

    the microscopic structural

    transition with the

    macroscopic behavior.

    Enables to seek the

    mechanical property of

    protein materials with

    mutation.

    TRANSITIONS New MURI project for fiber design PI visitedAFRL in 2010 (Wright-Patterson AFB) PI

    awarded PECASE

    FUTURE RESEARCH GOALS Facilitate merger of structure, material

    property and function through the bottom-up

    multi-scale design, from atomic to macroscopicbehavior.

    Quantitatively understand the assembling

    process of protein materials and factors to

    affect the material property of those assembled

    structures.

    Quantitatively understand the cascaded

    activation of mutations and their effect on

    material performance.

    Provide basis for new engineering paradigm

    to functionalize the hierarchical structural

    materials (e.g. new composites or polymers

    combine high flexibility, ultimate strength, self

    healing and robustness): novel materials for

    advanced Air Force technologies

    Multi-scale approach to understand biological protein materials & translate design concepts into engineering applications

    STATUS

    QUO

    END-OF-PHASEGOAL

    QUANTITATIVEIMPACT

    NEWINSIGHTS

    Study of nuclear lamina

    (meshwork of filaments).

    Discovered the flaw

    tolerance of this structure is

    caused by non-linear

    mechanical response of

    intermediate filaments.The adhesion energy of

    the lamin tail is changed

    due to mutation, leading

    to altered mechanical

    response of filaments

    Mechanism of the - transition caused by mechanical force.

    Structural transition related

    Non-linear mechanical property

    Qin, Kreplak, Buehler, PRL, 2010, PLOS ONE, 2009

    Qin, Buehler, PRL, 2010

    Example of hierarchical structure of lamin at nuclear

    lamina.

    Materials science paradigm

    applied to the hierarchical

    structure of protein

    materials.

    Buehler,Nature Nanotechnology,1

    STRUCTURAL HIERARCHIES INPROTEIN MATERIALS (MIT: Buehler)

    2-5 May 2011, Arlington, VA

    WORKSHOP ONMULTISCALE EXPERIMENTS

    Ioannis Chasiotis (U Illinois), Chair

    WORKSHOP ONMULTISCALE ANALYSIS FOR

    MULTIFUNCTIONAL DESIGNSomnath Ghosh (Johns Hopkins U), Co-Chair

    Tom Hahn (UCLA), Co-Chair

    WORKSHOP ONCOMPUTATIONAL MULTISCALE

    MATERIALS MODELINGSomnath Ghosh (Johns Hopkins U), Chair

    Joint Organizing Committee:Bruce LaMattina (ARO), Co-Chair

    B.-L. (Les) Lee (AFOSR), Co-ChairGlaucio Paulino (NSF), Co-Chair

    3 Workshop ChairsJeff Baur(AFRL/RX)Ajit Roy (AFRL/RX)

    John Beatty (ARL/WMRD)Ernest Chin (ARL/WMRD)Eric Wetzel (ARL/WMRD)

    James Thomas (NRL)

    NANOMATERIALS FOR

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    Engineered Nanomaterials for

    Multifunctional Structures: Shape Memory AlloyNano-rodsfor Actuation

    Carbon Nanotube(CNT) Grown on Graphite Fibers

    CNT-BasedContinuous FiberReinforcement

    Layer-by-Layer(LBL) Assembled CNT Composites

    Alignmentof Nanoreinforcement

    Graphite / Bi2Te3 / Bi2Se3 / MoSe2Nano-platelets

    Gecko"AdhesionUsing Ordered Arrays of CNTs

    Self-Healing ViaNanoscale Capsules

    Reactive CNTfor Active Armors ExperimentalNanomechanics

    U Wisconsin U Michigan Brown U U Delaware Stanford U U IllinoisCarbon Solutions Case Western CU Aero3Tex UC San Diego MIT U Texas Dallas UCLA

    STRUCTURES: 06 INITIATIVE

    NANOMATERIALS FOR

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    Engineered Nanomaterials for

    Multifunctional Structures: Shape Memory AlloyNano-rodsfor Actuation

    Carbon Nanotube(CNT) Grown on Graphite Fibers

    CNT-BasedContinuous FiberReinforcement

    Layer-by-Layer(LBL) Assembled CNT Composites

    Alignmentof Nanoreinforcement

    Graphite / Bi2Te3 / Bi2Se3 / MoSe2Nano-platelets

    Gecko"AdhesionUsing Ordered Arrays of CNTs

    Self-Healing ViaNanoscale Capsules

    Reactive CNTfor Active Armors ExperimentalNanomechanics

    U Wisconsin U Michigan Brown U U Delaware Stanford U U IllinoisCarbon Solutions Case Western CU Aero3Tex UC San Diego MIT U Texas Dallas UCLA

    STRUCTURES: 06 INITIATIVE

    PIs & Co-PIs:

    Nancy Sottos (UIUC)Vikas Prakash (Case Western)Ajit Roy (AFRL/RXBT)Frank Ko (U Brit Columbia)*Ray Baughman (U Texas Dallas)A. John Hart (U Mich)Michael Strano (MIT)

    Greg Carman (UCLA)Ronggui Yang (U CO)*Se-Hee Lee (U CO)*Tim Fisher (Purdue U)Ioannis Chasiotis(UIUC)John Kieffer(U Mich)Nicholas Kotov(U Mich)Jimmy Xu(Brown U)Erik Thostenson(U Del)Mrinal Saha(OK St U)Alexander Bogdanovich(3Tex)Yuntain T. Zhu(NC St U)Kelechi Anyaogu(Nico)David L Carnahan(NanoLab)

    ^ YIP;* MURI

    SUMMARY

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    SUMMARY

    The program is fully focused on the establishment of advanced

    multi-functional aerospace structures. A major progress has been made in pursuing a new vision for

    autonomic systems and providing research support for baselinemultifunctional materials and microsystems.

    Three initiatives for autonomic aerospace structures are highlysuccessful: microvascularcomposites(MURI 05),structurally integrated energy harvest/storage capabilities

    (MURI 06) and load bearing antennas(GameChanger 07).

    Three new initiatives are implemented for reconfigurablemultifunctional structures,energy harvesting from aerospace

    environment and neurological system inspired sensorynetwork(MURI 09).

    A new initiative is planned for multiscale analysis for multi-functional designin close collaboration with AFRL TD PIs,

    AFOSR PMs and the colleagues at other funding agencies.

    Back-Up Slides

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    Back Up Slides

    Modeling and Simulation for

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    Electro-Thermo-MechanicalComputational Tools

    Domain Decomposition

    Techniques to Model Nanowires

    Inside Polymer Composites

    OBJECTIVES

    Develop integrated multi-scale multi-physics computational model for analysis and

    design of load bearing antenna.

    Robust finite element for coupled electro-magnetic and mechanical structural response Multi-scale effects through the incorporation of semi-analytical methods

    Homogenization methods for continuum constitutive models to be inserted in

    macroscopic analysis

    Methods for microstructural design to facilitate optimal property distribution

    ACCOMPLISMENTS High-performance parallel computational framework

    Electro-magnetic code for solving Maxwells equations

    Finite deformation model/code for structural mechanics under dynamic loading with

    hyper-elastic material model Coupling of EM and Dynamic Codes

    Multi-time scaling algorithm for coupling mechanical and EM solutions in real time

    CHALLENGES

    1. Large matrix system needed for highprecision;

    2. Ill -conditioned matrices haveconvergence difficulty;

    3. Repetitive re-meshing for in situdesigns

    Modeling Small UWB Antennas

    on UAV Platform

    Feed

    50 x

    y

    z

    Planar Spiral

    Mesh on Planar

    Spiral

    Detailed Mesh Background Mesh

    gConformal Load Bearing Antennas

    ACTIVE MATERIALS FOR

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    48

    To design better actuators/morphingdevices using shape memory alloyhoneycomb which combines benefits ofcellular structures and monolithic SMAs

    Objectives:

    After non-uniformity due to structurallevel instabilities at moderate strains, thedeformation pattern becomes uniformagain upon further straining .

    This morphing behavior reverses underunloading.

    CELLULAR SHAPE MEMORY

    STRUCTURES (U Mich: Triantafylli)

    47

    Forest-drawn carbon nanotube sheets

    have higher specific strength than steel.

    Charge injection of carbon nanotubesheets produces giant width-directionactuation (>3.3 X) from 80 to 1900 K.

    Sheets CONTRACT in nanotubedirection by up to 2% during actuation.

    Generated stress is 32 times the stressgeneration capability of natural muscle.

    Motor

    Nanotube Forest

    Mandrel

    Meterlongcarbonnanotubesheet

    Forest

    Sheet (right) being spun

    from nanotube forest (left)

    Side view of above sheetspinning from forest

    300 K, 0 kV

    300 K, 5 kV

    1500 K, 5 kV

    NANOTUBE ARTIFICIAL MUSCLE(U Texas Dallas: Baughman)

    ADAPTIVE STRUCTURES

    BAT-INSPIRED MORPHING WING

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    CURRENTSTAT

    E

    NEWINSIGH

    TS

    QUANTITATIVEIMPACT

    END-OF-PHASEGOAL

    MAIN ACHIEVEMENTS (Contd): Current Impact

    Inertial Measurement (IM)

    Acceleration and angular velocities recorded forstraight and obstructed flights Dorsal mount miniature wireless IM Unit (IMU)

    Mechanical Characterization of Bat Membrane Strain experiments Constitutive modeling

    -Fiber bundle dist.-Fiber bundle comp.-Base matrix corrugation

    Result satisfy materialanisotropy property

    MAIN ACHIEVEMENTS:

    Skeletal Assembly Bones assembled in CAD CAD model guides

    mechanical design

    Robotic Wing 4 DOF

    High flapping frequency

    Data Smoothing, Motion Trajectory

    Motion capture dataimproved

    Motion trajectory definedfor humerus and radius

    High-fidelity models forcomponents and integratedstructure representative of a

    bat-wing

    Quantitative evaluation offlight performance, energyconsumption and efficiency

    Estimates of weight, volumeand geometry of a roboticbat-wing

    Guidelines to develop an

    autonomous, hovering, highlymaneuverable, bat-like MAV

    Reconfigurable hovering ultra-maneuerablebat technologies (RHUMBAT) offers

    potential benefits in operational robustness. Most research has focused on recreating

    three degrees of freedom (DOFs) assoc

    with this motion: flap, lag, and feather Small vehicle size and low inertia make fine-

    scale control required for envisionedmissions difficult.

    Our unique approach considers actuatorsthat are distributed across the structure.

    We provide detailed analysis for selection ofactuation DOF using motion capture andrevealing complex morphologies of joints.

    Wing membrane characterization showsthickness inhomogeneities to be consideredin materials selection.

    In depth understanding of

    bat skeletal structure andskeletal dynamics duringflight

    Materials analysis forstructural and aerodynamicsurfaces

    Translation of bat dynamicsto robotic system

    Biological Experiments Examined wing fiber

    under polarized light Guides constitutive

    model development

    IMU

    Right wing assembly

    Preliminary design

    Wing fibersImproved suturing and biaxial setup

    Simulated Stress-Strain CurveBiaxial loading

    Strain analysis

    (NextGen/Brown U/VPI: Joshi)

    REVERSIBLE SHAPE MEMORYS CO

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    Commonly Used Shape Memory

    Polymers (SMP) One-way shape memory (SM) effects Not

    being able to recover the temporary shape

    No design tools available

    Two-way Shape Memory Polymers Two-way SM effects using switching

    between two stable states No two-way SM

    due to intrinsic material property change

    Two-way SMPs Applications Require combinatorial methods for

    material synthesis, modeling, and design.

    Two-Way SMP by the Concept of

    Opposing Microstructural-Scale

    Spring Two opposing spring can generate motions

    if one or both of them can change properties

    as temperature changes Opposing spring

    can be realized through material/structure

    design at micro-scale.

    MAIN ACHIEVEMENTS: Demonstrate two-way shape memory effects assisted by

    external force.

    Fabricate reversible free-standing two-way shape

    memory polymer composites.

    HOW IT WORKS: Stretched induced crystallization (SIC) can relax the

    stress Opposing microstructural-scale spring creates

    reversible free-standing two-way SMP Shape memory

    effect is fully reversible.

    Current Impact First free-standing two-way SMP based onintrinsic material property change Large

    reversible actuation strain

    Planned Impact Two-way SMPs for multifunctionalstructural Design tools that enhance robust

    design Novel applications based on two-

    way SMP

    Research Goals Complete understanding of material

    behaviors Design tools for novel

    applications of these materials Explore

    other polymer-based shape memory

    materials Explore applications with AFRL

    STATUSQUO

    END-OF-PHASEGO

    AL

    Q

    UANTITATIVEIMPACT

    NEWINSIGHTS

    Proposed applications: a) Rotational actuation

    in shear to enable autonomous rotation for

    mirror motion, wing joints. b) Reversible

    blistering of two-way SMPs for variable

    boundary layer aircraft control surfaces.

    Ki Ks(T)Ki Ks(T)

    The spring on

    the left has a

    constant

    stiffness Ki and

    the stiffness of

    right spring Ksdepends on the

    temperature.

    SMPin shearStator

    Rotor

    Reversible TorsionVia SMP Shear

    to mirror(a)

    (b)

    SMPin shearStator

    Rotor

    Reversible TorsionVia SMP Shear

    to mirror

    SMPin shearStator

    Rotor

    Reversible TorsionVia SMP Shear

    to mirror(a)

    (b)

    Two-way shape

    memory effect

    assisted by an

    external force

    2W-SMP 2W-SMP is

    stretched at

    high T, then

    cooled to low T

    2W-SMP is

    laid on top

    of the

    polymer

    A polymer

    layer is photo-

    synthesized

    on top.

    0mn 1min 2min 3min 4min 5min 6min 7min

    Heating Cooling

    (Syracuse U / U CO: Mather)

    Thermoelectric Module IntegrationMURI 06

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    TE design

    Analysis results

    Phi TE Linear TELinear TE w/ FGM

    and shrink-fit (1.25mm)Linear TE w/ FGM

    and shrink-fit (2.5mm)Linear TE w/ FGM

    and shrink-fit (2.5mm)

    Generated temperature gapacross TE element (deg C)

    338 344 344 346 394

    Maximum normal stress onelectrode (Mpa)

    -1100 -1200 -535 -591 -642

    Maximum shear stress on

    electrode (MPa) 146 617 329 311 337Maximum shear stress on TE

    element (MPa)125 71 34 43 56

    Power density (W/cm2) 0.80 0.87 0.87 0.89 1.15

    Module efficiency (%) 12.8 13.3 13.3 13.4 14.8

    Fe-SMA

    Cu-SMA

    Fe-SMA

    Cu-SMA

    Grazing material(Ag)

    CNT

    SMA

    Electrode (Cu)

    n-type: Mg2

    Si0.96

    Bi0.03

    In0.01

    p-type: Si0.93Ge0.05B0.02 Heat source side: Fe-SMA

    Heat exhaust side: Cu-SMA

    CNT in grazing material gives: locking Ag reducing the creep strain

    Fe-SMA

    Cu-SMA

    450C

    50C

    Thermoelectric Module IntegrationMURI 06

    Modeling and Simulation ofL d B i Li I B i

    MURI 06

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    e

    e

    e

    e

    e

    e

    e

    e

    Li+

    Li+Li+

    Li+

    Li+

    AMacro-scale (1D)

    Micro-scale (1/2/3D)

    input

    discharge current

    porosity

    temperature

    mech. loads

    input

    material system

    particle geometry

    outputcapacity (utilization*)

    voltage (electric power)

    Li concentration*

    chemical eigenstrains*

    deformation*& stress*

    temperature*

    output

    particle Li concentration*

    particle deformation*

    particle stress* (degradation)

    * as function of space and time

    Multiscale framework allows connection between microscale behavior, e.g.,stress development, as a function of actual battery operating conditions

    gLoad Bearing Li Ion Batteries

    MURI 06

    STTR10: HYBRID ENERGY HARVEST(P MEMS)

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    Jan 09

    Paramagnetic State

    (Heating)

    Ferromagnetic State

    (Cooling)

    OscillationAmplitude

    Bi-Directional

    Magnetic Force

    SpringForce

    SpringForce

    MagenticForce

    Perm-magnet Perm-magnet Perm-magnet

    Force

    FerromagneticState

    ParamagneticState

    StateTransition

    Tcurie

    Tcurie -1C Tcurie +1C

    Temperature

    Bi-directional

    Extract work from phase transitions

    Pairing solar panels with magneto-thermoelectric

    power generator as active thermal backplane forsolar panel cooling and hybrid energy harvest

    (PowerMEMS)

    magneto-thermoelectricpower generator(STTR07)

    ENERGY HARVESTING ONSPACECRAFT (P St t Bil )

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    PROJECT SUMMARY

    ACCOMPLISHMENTSAPPROACH

    Objectives:

    Team:

    Develop system concepts for use of ElectrodynamicTethers (EDT) on an array of spacecraft in variety oforbits and for various missions

    Address EDT performance parameters

    Evaluate various system components required

    Explore energy storage devices

    Sven Biln, PI, and Jesse McTernan, Penn StateBrian Gilchrist, Co-PI, and Iverson Bell, Univ. MichiganRob Hoyt, Nestor Voronka, Co-Is, TUI, Inc.

    Explore EDT system architecturesfor energy harvesting and storage

    Employ tether simulation toolsTeMPEST and TetherSim forverifying performance

    Develop and extend simulationtools to include energy harvestingmodes and new components

    Define new architectures fori l i i d

    ChipSat system concept development andfeasibility study

    CubeSat system concept development andsolar panel comparison study

    Large spacecraft system conceptdevelopment and voltage and currentmagnitudes study

    Work underway to implement an energystorage module for TeMPEST

    EDTs can be used toharvest energy andprovide propulsion

    SPACECRAFT (Penn State: Bilen)


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