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1. The universe is made up of: The system – the thing that you are studying The surroundings-...

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Page 1: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

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Page 2: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

The universe is made up of:The system – the thing that you are studyingThe surroundings- everything else

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Page 3: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

Quantity of energy needed to raise 1 gram of a substance 1° C; unit is J/g°C; symbol

is “c” Every pure substance has a unique

chemical composition, and therefore a unique specific heat.

Substances with a low specific heat make good thermal conductors.

Substances with a high specific heat make good thermal insulators.

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Page 4: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

INSULATORS

High specific heat

CONDUCTORS

Low specific heat

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Page 5: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

A physical property because it can be observed without changing the chemical composition of the substance

An intensive property because it is independent of sample size. Because it is an intensive property, it can be used to identify an

unknown substance.

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Page 6: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

TO INCREASE THE TEMPERATURE OF 1 GRAM OF WATER BY 1 °C, THE WATER MUST ABSORB 4.18 J OF ENERGY

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Page 7: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

TO INCREASE THE TEMPERATURE OF 1 GRAM OF ICE BY 1 °C, THE ICE MUST ABSORB 2.03 J OF ENERGY

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Page 8: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

TO INCREASE THE TEMPERATURE OF 1 GRAM OF STEAM BY 1 °C, THE STEAM MUST ABSORB 2.01 J OF ENERGY

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Page 9: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

FORMULA: q= m x c x ΔT q= heat (J) c = specific heat (J/g°C) m = mass (g) ΔT = change in temp., Tf - Ti (°C)

Use this equation when ONLY the temp changes (on the diagonal lines), not the phase

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Page 10: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

Take the absolute value of q. Describe whether or not that energy is

being absorbed by the system (endothermic) or released to the surroundings (exothermic).

When you get to AP Chem, you will learn that negative and positive values can be assigned to q to indicate endothermic(+) or exothermic (-).

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Page 11: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

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Page 12: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

Calculate the amount of heat, in Joules, needed to warm 250 g of water from 25°C to 95°C.

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Page 13: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

How much heat is lost when 50.0 grams of solid Al is cooled from 130°C to 62°C? The specific heat of Al is 0.897 J/g°C

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Page 14: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

1 calorie (cal) = 4.18 Joules

1 kilocalorie = 1 Calorie = 1000 calories

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Page 15: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

Use dimensional analysis to convert 550 Joules into calories.

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Page 16: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

550 Joules 1 calorie____ = 132 Joules

4.18 Joules

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Page 17: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

A granola bar has 126 Calories. Use dimensional analysis to convert this into a) calories and b) Joules

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Page 18: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

Change in internal energy of a substance Amount of heat absorbed or released

during a phase change is ΔH

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Page 19: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

heat (or enthalpy) of fusion (ΔHf)also called “latent energy of fusion”amount of energy needed to melt 1

gram of a substance at its melting point (solid liquid)

Δ Hf copper = 205 J/g Δ Hf water = 334 J/g

Formula: q = m ΔHf q= heat (J) ΔHf = heat of fusion (J/g) m = mass (g)

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Page 20: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

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Page 21: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

Calculate the amount of heat, in Joules, needed to melt 70.0g of copper at its melting point.

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Page 22: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

heat (or enthalpy) of vaporization (ΔHv)

also called “latent heat of vaporization” the amount of energy needed to

vaporize 1 gram of a substance at its boiling point; liquid gas

ΔHv water = 2260 J/g

Formula: q = m ΔHv q= heat (J) ΔHv = heat of vaporization (J/g) m = mass (g)

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Page 23: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

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Page 24: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

Calculate the heat required, in Joules, to change 250g of water at 100°C to steam at 100°C.

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Page 25: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

Calculate the amount of heat needed to change 20g of ice at -10.0°C to water at 80.0°C.

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Page 26: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

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Page 27: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

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Page 28: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

http://www.dnatube.com/video/11327/Principles-Of-Thermal-Equilibrium

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Page 29: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

An instrument used to measure the amount of heat transferred during physical or chemical changes.

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Page 30: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

Can be used to determine the identity of a sample based on temperature changes and mass of sample.

Unknown metal block

http://durangotexas.blogspot.com/2010/06/crowley-texas-school-bunsen-burner-gas.html

Mass of block: 226gInitial Temp: 100°C

Mass of water: 60g Initial Temp: 30°C

Final Temp: 50°C

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Page 31: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

Calculate the specific heat of the unknown metal.

Unknown metal block

http://durangotexas.blogspot.com/2010/06/crowley-texas-school-bunsen-burner-gas.html

Mass of block: 226gInitial Temp: 100°C

Mass of water: 60g Initial Temp: 30°C

Final Temp: 50°C

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Page 32: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

The heat (Q) lost by the block is gained by water-Qblock = Qwater

Cwater = 4.18 J/g°C

(226g)(C)(50°C-100°C)= (60g)(4.18 J/g°C)(50°C-30°C)

C = 0.444 J/g°C32

Page 33: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

For our unknown metal C = 0.444 J/g°CWhat is its identity?

http://www.webassign.net/sample/ncsugenchem202labv1/lab_4/manual.html 33

Page 34: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

A 50 gram piece of metal at 175 oC is dropped into 100 g of water at 25 oC. The final temperature of the system is 52 oC. What is the specific heat of the unknown metal? (Draw a diagram FIRST.)

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Page 35: 1. The universe is made up of: The system – the thing that you are studying The surroundings- everything else 2.

https://www.teachchemistry.org/content/aact/en/periodical/simulations.html

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