2nd Edition [NOHSC:2011(2003)] - Parliament of Western ...file/tp+741.pdf · 2nd Edition...

National Code of Practicefor the Preparation of

Material Safety Data Sheets2nd Edition

[NOHSC:2011(2003)]

COMMONWEALTH OF AUSTRALIA

toNational Occupational Health & Safety Commission

April 2003

© Commonwealth of Australia 2003

This work is copyright. You may download, display, print and reproduce this material inunaltered form only (retaining this notice) for your personal, non-commercial use or use withinyour organisation. Apart from any use as permitted under the Copyright Act 1968, all otherrights are reserved. Requests for further authorisation should be directed to the

Commonwealth Copyright Administration, Intellectual Property Branch, Department ofCommunications, Information Technology and the Arts, GPO Box 2154, Canberra ACT 2601 orby email to: commonw o vrightOdcita.qov.au

ISBN NO. 1 92003 1034-;:ci

National codes of practice declared by NOHSC under s.38(1) of the National OccupationalHealth and Safety Commission Act 1985 (Cwlth) are documents prepared for the purpose ofadvising employers and workers of acceptable preventive action for averting occupationaldeaths, injuries and diseases In relation to workplace hazards.

The expectation of the Commonwealth Government and NOHSC is that national codes ofpractice will be suitable for adoption by Commonwealth, State and Territory governments.Such action will increase uniformity in the regulation of occupational health and safetythroughout Australia and contribute to the enhanced efficiency of the Australian economy.

It should be noted that NOHSC documents are instruments of an advisory character, exceptwhere a law, other than the National Occupational Health and Safety Commission Act 1985, oran instrument made under such a law, makes them mandatory. The application of any NOHSCdocument in any particular State or Territory is the prerogative of that State or Territory.

National Code of Practice for the Preparation of Material Safety Data Sheets

FOREWORDIn seeking to achieve Australian workplaces free from injury and disease, NOHSC works to leadand coordinate national efforts to prevent workplace death, injury and disease. We seek toachieve our mission through the quality and relevance of information we provide and toinfluence the activities of all parties with roles In Improving Australia's occupational health andsafety (OHS) performance.

In seeking to Improve Australia's OHS performance, NOHSC works to:

support and add value to efforts in the jurisdictions to tailor approaches to preventionimprovement;

facilitate, through strategic alliances, the development and Implementation of betterapproaches to achieving improved prevention outcomes; and

integrate the needs of small business into Its work.

On 24 May 2002, the Workplace Relations Ministers' Council endorsed the release of theNOHSC National OHS Strategy 2002-2012. The strategy was developed by the members ofNOHSC and reflects their agreement to share responsibility for continuously ImprovingAustralia's performance in work related health and safety.

There are five initial national priority areas for action to achieve short term and longer termimprovements. The priorities are:

reduce high incidence/severity risks;

improve the capacity of business operators and workers to manage OHS effectively;

prevent occupational disease more effectively;

eliminate hazards at the design stage; and

strengthen the capacity of government to influence OHS outcomes.

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National Code of Practice for he Preparation of Material Safety D

CONTENTS

FOREWORD iii

CONTENTS

PREFACE vii

1 TITLE 1

2 PURPOSE 1

3 SCOPE AND APPLICATION 1

4 DEFINITIONS 2

5 GUIDELINES FOR PREPARING MSDS 11

6 PREPARATION OF THE 16 HEADER MSDS 14

7 REFERENCES 36

APPENDIX 1 16 HEADER CHECKLIST 39

APPENDIX 2 - INFORMATION SOURCES 45

APPENDIX 3 - GUIDE FOR SELECTING GENERIC NAMES 51

APPENDIX 4 - CRITERIA AND FORM FOR NOTIFICATION OF A GENERIC NAME 53

APPENDIX 5 - SAMPLE CONFIDENTIALITY AGREEMENT FOR DISCLOSURE OF COMMERCIALLYCONFIDENTIAL INFORMATION 57


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National Code of Practice for the Preparation bf Material Safety Data She

PREFACE

The Material Safety Data Sheet (MSDS) is a document that describes the chemical and physicalproperties of a material and provides advice on safe handling and use of the material. Theterm Safety Data Sheet (SDS) Is also commonly used overseas to describe such a document.

Within the workplace, the MSDS Is a recognised information source, which underpins theoverall risk management program to control exposure to hazardous and dangerous materials.The advice contained on the MSDS Includes Information on health effects, exposure control,safe handling and storage, emergency procedures, and disposal. For most workplace riskassessments required by Commonwealth, State and Territory legislation, the MSDS and thelabel are the main information sources. The MSDS may also be used as an integral componentof any workplace training system.

This code of practice provides guidance on the preparation of an MSDS under the workplacehazardous substances and Dangerous Goods regulatory framework. Under this framework asupplier must produce MSDS for all hazardous substances and/or Dangerous Goods.Compliance with this code will ensure the MSDS is prepared In accordance with therecommended formats in Australia.

Under Commonwealth, State and Territory legislation, employers must obtain an MSDS for allhazardous substances and/or Dangerous Goods supplied to or used in the workplace, andensure they are available to all employees. It is also the duty of the employer to assess therisks to health and safety created by work Involving potential exposure to any hazardoussubstance and/or Dangerous Goods. This assessment Involves identifying and gatheringInformation on hazardous substances and/or Dangerous Goods used at work, where theprimary source of this information Is the MSDS and the label.

The declaration of the National Standard for the Storage and Handling of Workplace DangerousGoods [ NOHSC: 1015(2001)] in 2001, led to the development of the National Code of Practicefor the Preparation of Material Safety Data Sheets 2^° Edition [NOHSC:2011(2003)) (MSDScode) in order to incorporate the information provisions of the Dangerous Goods standard.This has also provided an opportunity to further align Australian requirements with recentinternational developments such as the Globally Harmonised System for the Classification andLabelling of Chemicals (GHS). The GHS incorporates the use of a 16 header MSDS format.The adoption of the GHS will lead to the gradual Introduction of acceptable overseas MSDS andallow Australian exporters to provide acceptable information to overseas markets. Safety DataSheet is a term used in the GHS. Along with other GHS terminology, Australia is movingtowards the adoption of terms such as Safety Data Sheet as part of its alignment withinternational developments.

Since 1994, the NOHSC MSDS code has acknowledged the use of two formats for the MSDS inAustralia, the original NOHSC 8 header format, and the 16 header format adopted by theEuropean Union and the International Labour Organization. The Second Edition of the codeprovides guidance on the preparation of a 16 header MSDS, which is consistent with theInformation requirements of the globally harmonised format,

The National Occupational Health and Safety Commission agreed to declare the National Codeof Practice for the Preparation of Material Safety Data Sheets 2nd Edition[NOHSC:2011(2003)] on 24 April 2003, with a 3-year transitional period. The newrequirements relating to the preparation of Material Safety Data Sheets, as detailed in Chapter6 of this code, therefore should come into effect in Commonwealth, State and Territoryregulations on and from 24 April 2006.

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National Code of Practice for he Preparation of Material Safety Data Sheets

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National Code of Practice for the P paration o atonal Safety Data Sheets

1 TITLEThis national code of practice may be cited as the National Code of Practice for thePreparation of Material Safety Data Sheets 2n0 Edition [NOHSC:2011(2003)].

2 PURPOSE

The purpose of this code of practice is to provide advice on the preparation ofMaterial Safety Data Sheets (MSDS) where required by legislation. The aim is toprovide consistent health and safety advice to persons who could be exposed tohazardous substances and Dangerous Goods.

3 SCOPE AND APPLICATION(a) This code of practice applies to materials

classified as:

(i) hazardous substances; and

(H) Dangerous Goods.

(b) This Code of Practice does not apply toDangerous Goods that are:

(i) Class 1-Explosives;

(H) Class 6,2-Infectious Substances;

(iil) Class 7-Radioactive Material; and

(iv) Cl combustible liquids that do not fall within the definition of a hazardoussubstance.

Provision of Hazard InformationWhile an MSDS is not required forsubstances not classified ashazardous, there's often a legislativerequirement to provide hazardInformation. It is good practice toprovide a MSDS for any material,which may give rise to a health,safety or environmental effect, Themost convenient and established wayof providing this Information isthrough an MSDS.

National Code of Practice or the Pre on of Material Safet Data Sheets

4 DEFINITIONSThe following definitions are terms referred to In the text of this code of practice.

ADG Code

Australian Code for the Transport of Dangerous Goods by Road and Rail.

Allergic reactionmeans an over-reaction by the Immune system to an antigen. It can take theform of a rash, asthma, breathing difficulties, weeping eyes or sneezing.

Antidotemeans a treatment for chemical over-exposure, which is specific (more or less) tothe chemical or class of chemicals, in contrast to supportive treatment, whichmaintains body functions.

Appearancemeans a description of the physical state of the material.

Australian Code for the Transport of Dangerous Goods by Road and Rail(ADG Code)

means the code prepared by the National Road Transport Commission inconjunction with the Advisory Committee on the Transport of Dangerous Goods(ACTDG) and the Federal Office of Road Safety which was endorsed by theAustralian Transport Council. Many of the technical requirements of the ADGCode are based on provisions of the United Nations Recommendations on theTransport of Dangerous Goods. The ADG Code covers the classification,packaging, marking, labelling and transport of Dangerous Goods (Classes 2-9). Itcomprises of the Australian Code for the Transport of Dangerous Goods by Roadand Rail, the Rail (Dangerous Goods) Rules and the Road Transport Reform(Dangerous Goods) Regulations.

Australian Standard (AS)means a standard published by Standards Australia or jointly published withStandards New Zealand.

BAT

means an equivalent to a biological limit value set by the German Commission forthe Investigation of Health Hazards of Chemical Compounds in the Work Area.

Biological limit valuemeans limit values for the level of substances in biological samples such as bloodor urine.

Bolling pointmeans the temperature at which the vapour pressure of a substance equals theatmospheric or other designated pressure.

Cancermeans a malignant tumour which can spread to other organs of the body. Asdistinct from a benign tumour which cannot (although leukemia and some othermalignant diseases are not solid tumours, they meet other criteria for cancer andcan be, and often are, included under this definition).

Carcinogenmeans an agent which is responsible for the formation of a cancer.

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National Code of Practice forthePreparation of Material Safety Data Sheets

Carcinogenic

means capable of causing cancer.

CAS Number or CAS No. (Chemical Abstracts Service Registry Number)

means a unique number assigned by the Chemical Abstracts Service, Columbus,Ohio, USA.

Chemical

means any element or compound present as an entity or contained in a mixture,

Classification

means the process whereby the toxicological, physicochemical andecotoxicological properties of a material are identified and categorised.

Combustion

means the process of burning.

Combustible liquidmeans those liquids within the meaning of Australian Standard AS 1940 Thestorage and handling of flammable and combustible liquids; see also 'flammable'.

Commercially confidential Informationmeans information, such as chemical identity or exact composition, which, ifmade public, would significantly damage commercial interests.

Composite materialmeans a material that contains a mixture of two or more types of fundamentallydifferent components.

Concentration cut-off levelmeans the concentration level in the National Occupational Health and SafetyCommission's List of Designated Hazardous Substances [NOHSC:10005], orassigned in accordance with the National Occupational Health and SafetyCommission's Approved Criteria for Classifying Hazardous Substances[NOHSC:1008].

Corrosive

means having a pH of 2.0 or less or a pH greater than 11.5 causing thedestruction of, or damage to, materials or living tissue on contact; and/or meetsthe criteria of corrosive under the ADG Code.

Corrosive substancemeans a material which has been classified as a corrosive according to theNational Occupational Health and Safety Commission's Approved Criteria forClassifying Hazardous Substances (NOHSC:1008) and/or as defined under theADG Code.

Dangerous Goods

means those goods that:

(a) are named in a specific entry in Column 2 in Appendix 2 of the ADO Code, butnot in a generic entry or in an entry where the letters 'N.O.S' are shown aspart of the Proper Shipping Name for the goods; or

(b) satisfy the criteria In Column 2 or 9 in Appendix 2 of the ADG Code; or

(c) satisfy the criteria in a Special Provision of the ADG Code that Is applied byColumn 7 in Appendix 2 of the ADG Code; or


(d) are determined to be Dangerous Goods by the authority appointed by thejurisdiction to give effect to the ADG Code; or

(e) satisfy the United Nations Dangerous Goods tests and criteria for determiningwhether goods are Dangerous Goods; or

(f) include goods defined as goods too dangerous to transported; or

(g) include Cl combustible liquids.

Density

means the ratio of mass of a material to its volume. It is measured at 25°C(unless otherwise stated) and expressed in grams per cubic centimetre (g/cm3) orkilograms per cubic metre (kg/m3).

Dermatitismeans an inflammation of the skin. Irritant contact dermatitis is direct damageto the skin, which is due to contact with the irritant substance, for example,acids, alkalis or organic solvents in sufficient concentration and for sufficient time.It occurs soon after exposure and persists long after exposure has ceased.Allergic contact dermatitis is an inflammatory reaction caused by substances,which penetrate the skin and cause a specific allergic response (sensitisation)after a variable lag period ranging from a matter of days to several months.Once sensitisation has occurred, exposure to only a relatively small quantity ofthe substance will trigger a reaction within 48-96 hours due to developedhypersensitivity of the body.

Dose

means the amount of test substance administered. Dose is expressed as mass(grams or milligrams) or as mass of test substance per unit mass of test animal(e.g. milligrams per kilogram body mass), or as constant dietary concentrations(milligrams per kilogram of food).

Employee

means an individual who works under a contract of employment, apprenticeshipor traineeship.

Emergency services authoritymeans an organisation with functional jurisdiction over emergency response asdefined by a State, Territory or Commonwealth jurisdiction.

Employee representativeincludes an employee member of a health and safety committee whereestablished in the workplace, or a person elected to represent a group ofemployees on health and safety matters.

Employermeans a corporation or an Individual who employs persons under a contract ofemployment, apprenticeship or traineeship.

Note: The definition of employer includes the self-employed which means aperson who works for gain, other than under a contract of employment,apprenticeship or traineeship, whether or not that person employs others.

Epidemiologicalmeans relating to the study of the relationships determining the frequency anddistribution of disease in a human community.


Evaporationmeans the change of state from a liquid to a gas.

Explosive limitshas the same meaning as flammable limits (q.v).

Exposure standard

means an airborne concentration of a particular substance in a person's breathingzone, as established by the National Occupational Health and SafetyCommission's Exposure Standards for Atmospheric Contaminants in theOccupational Environment [NOHSC:1003].

Flammabilitymeans the conditions under which a material ill burn.

Flammable

means being capable of being ignited and burning in air; see also 'flammableliquid' and 'combustible liquid'.

Flammable limitsmeans the range of concentrations of a flammable vapour in air at which a flamecan be propagated or an explosion will occur, if a sufficient source of ignition ispresent. Normally expressed as upper and lower limits of this range, as apercentage of the volume of vapour in air. The term 'explosive limits' has thesame meaning as 'flammable limits'. Has the same meaning as explosive limits(q.v).

Flammable liquidmeans a liquid which is capable of being ignited and burning in air and whichmeets the criteria of the ADG Code (liquids with a flashpoint of not more than60.5°C closed-cup test, or not more than 65.6°C open-cup test).

Generic name

means a name applied to describe a category or group of chemicals. Examples ofgeneric names are azo dyes and halogenated aromatic amines.

Hazard

means an intrinsic capacity associated with a material or process capable ofcausing harm.

Hazardous substance

means a substance which:

(a) Is listed on the National Occupational Health and Safety Commission's List ofDesignated Hazardous Substances [NOHSC:10005]; or

(b) has been classified as a hazardous substance In accordance with the NationalOccupational Health and Safety Commission's Approved Criteria for ClassifyingHazardous Substances [NOHSC: 1008].

Hazchem Code

means an emergency action code of numbers and letters which gives informationto emergency services. Its use is required by the ADG Code for Dangerous Goodsin bulk.

Health effects criteriameans the basis on which a substance is evaluated with respect to itstoxicological data.

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Identificationmeans providing information on the name of a product, some of its other names,its use, properties and chemical composition found In sections 1 and 2 of theMSDS.

Ignitionmeans setting fire to or being set fire to.

Ignition temperaturemeans the minimum temperature required to start or cause self-sustainedcombustion in any substance in the absence of a high temperature ignitionsource, such as a spark or a flame.

Incompatibilitymeans a situation where any substance or residue, which by combiningchemically with the incompatible substances or promoting self-reaction ordecomposition of the incompatible substances, may create a hazard; or inaccordance with regulation 2.6 of the Rail (Dangerous Goods) Rules andregulation 2.6 of the Road Transport Reform (Dangerous Goods) Regulations.

Information, Additionalmeans information that may be useful for the users of the MSDS. Suchinformation should be provided if relevant and available.

Information, Coremeans information essential to understanding the hazards of the material. It alsoallows MSDS prepared in accordance with this code of practice to be consistentwith the information requirements of overseas systems. This information shouldalways be included in the MSDS.

Ingredientmeans any component of a substance.

Inhalationmeans breathing in.

Interactionmeans modification of toxic effects of one substance by another. The effects canbe amplified (synergism) or reduced (antagonism).

Irritantmeans a substance that will produce local irritation or inflammation on contactwith tissues and membranes, such as skin or eyes, or that will, after inhalation,produce local irritation or inflammation of nasal or lung tissue,

Label

means a set of information on a container which identifies the substance in thecontainer, Identifies whether the substance Is hazardous and provides basicinformation about the safe use and handling of the substance. For DangerousGoods, label means one or more of the following:

a class label;

a subsidiary risk label; or

a mixed class label.

National Code of Practice or the Preparation of Material Safety Data h ts

MAK

means an equivalent to an exposure standard set by the German Commission forthe Investigation of Health Hazards of Chemical Compounds in the Work Area.

Material Safety Data Sheet (MSDS)

means a document that describes the properties and uses of a material, that is,identity, chemical and physical properties, health hazard information, precautionsfor use and safe handling information.

May

means that a recommendation is optional.

Melting point

means the temperature at which a substance changes from solid to liquid,normally measured in °C.

Metabolism

means the process(es) by which the administered substances are structurallychanged In the body either by enzymatic or non-enzymatic reactions.

Mixture

means a physical combination of ingredients resulting from the deliberate mixingof those ingredients; or a chemical reaction of ingredients that may form morethan one new compound or have unreacted ingredients still present.

mm Hg

means millimetres of mercury (Hg), This is a unit of pressure (760 mm Hg =101,325 kPa).

Mutagenic

means able to produce a mutation.

National Exposure Standard

means an airborne concentration of a particular material In the worker's breathingzone, exposure to which, according to current knowledge, should not causeadverse health effects nor cause undue discomfort to nearly all workers. Theexposure standard can be of three forms: time-weighted average (TWA); peaklimitation; or short term exposure limit (STEL).

Oral

means ingested or administered via the mouth.

Packing Group, as defined by the ADG Code

means the division of Dangerous Goods of Classes 3, 4, 5, 6.1, 8 and some Class9 into three groups according to the degree of hazard they present: (greatdanger), (medium danger) and (minor danger).

pH

means a value representing how acidic or alkalinic a solution is. Acids have a pHof less than 7. The lower the pH, the stronger the acid (normal minimum 0).Alkalis have a pH greater than 7. The higher the pH the stronger the alkali[(normal maximum 14) (0.01 M hydrochloric acid has a pH of 2. 0.01 M sodiumhydroxide has a pH of 12. 0.1 M acetic acid, a weak acid, has a pH of 3 and 0.1M ammonium hydroxide, a weak alkali, has a pH of 11)].

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As the pH scale (shown below) is logarithmic, the intervals are exponential, andthus represent far greater differences in concentration than the values seem toIndicate.

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14

strong acid neutral strong alkali

Pure water has a pH of 7. The pH of seawater is 7.8-8.2, pH of gastric juices Is1,7, pH of urine Is 5-7, pH of blood is 7.3-7.5 and the pH of milk Is 6.5-7.

Physical state/formmeans whether a material is In the solid, liquid or gaseous state at a specifiedtemperature and pressure.

Poisons Schedulemeans a listing of substances requiring specific labelling and precautions in use.The Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) ispublished by the Australian Health Ministers' Advisory Council (AHMAC) and is thebasis for Commonwealth, State and Territory poisons legislation.

ppm

means parts per million. ppm (w/v) in water = mg/L; ppm (w/w) in solids =mg/kg.

Practicablemeans 'practicable' in Victoria, Queensland, Western Australia and the NorthernTerritory, 'reasonably practicable' in New South Wales, South Australia, theAustralian Capital Territory, Tasmania and Commonwealth jurisdictions.

Productmeans a material in a form that is sold or supplied.

Product namemeans the brand name, trade name, code name or code number specified by asupplier.

Proper Shipping Namemeans the formalised UN name used for identifying materials, which are classifiedas Dangerous Goods.

Riskmeans the likelihood that a material will cause harm in the circumstances of Itsuse.

Risk Phrase

means a phrase describing the hazard of a substance as provided in the NationalOccupational Health and Safety Commission's Approved Criteria for ClassifyingHazardous Substances [NOHSC:1008].

Safety Phrasemeans a phrase describing the safe handling, storage or use of personalprotective equipment for a material.

Shall

means mandatory.

Should

means a recommendation.

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Solubilitymeans a measure of how soluble a substance is, Solubility in water is usuallyexpressed as g/L. Other units include 9/100 cm3, percent w/v or ppm of water.

Skin irritationmeans the production of inflammatory changes in the skin following theapplication of a test substance.

Specific gravitymeans the ratio of the density of a material to the density of some standardmaterial, such as water, at a specified temperature.

Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP)means the standard prepared by the Australian Health Ministers' Advisory Council(AHMAC).

Subsidiary riskmeans a risk in addition to the class to which Dangerous Goods are assigned andwhich is determined by a requirement to have a subsidiary risk label Inaccordance with the ADG Code.

Substance

means any natural or artificial entity, composite material, mixture or formulation,other than an article.

Supplier

means a manufacturer or importer of hazardous substances or Dangerous GoodsFor the purposes of this code of practice.

Teratogenlc

means able to produce abnormalities n a developing foetus, that is, causing birthdefects.

TLV

means Threshold Limit Value. These values are a type of exposure standardpromulgated by the American Conference of Governmental Industrial Hygienists(ACGIH).

Toxic effectmeans the property of a substance producing damage to an organism. Thisusually refers to functional (systemic) damage but may be developmental Inrespect of tissue and skeleton in the case of the embryo. The damage may bepermanent or transient.

Toxicity

means the capacity of a substance to produce damage to an organism, Thisusually refers to functional (systemic) damage but may be developmental Inrespect of tissue and skeleton in the case of the embryo. The damage may bepermanent or transient.

Trade name

means a company product name which may or may not be registered.

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Type I Ingredientsmeans an Ingredient which: (a) in accordance with the National OccupationalHealth and Safety Commission's Approved Criteria for Classifying HazardousSubstances [NOHSC:1008] is carcinogenic, mutagenic, teratogenic, a skin orrespiratory sensitiser, very corrosive, corrosive, toxic or very toxic, a harmfulsubstance which can cause irreversible effects after acute exposure, or a harmfulsubstance which can cause serious damage to health after repeated or prolongedexposure; OR (b) has an exposure standard listed in the National OccupationalHealth and Safety Commission's Exposure Standards for AtmosphericContaminants in the Occupational Environment [NOHSC:1003]; AND (c) ispresent In a quantity which exceeds the lowest relevant concentration cut-offlevel specified for the hazard classification in the National Occupational Healthand Safety Commission's Approved Criteria for Classifying Hazardous Substances[NOHSC:1008].

Type II Ingredientsmeans an Ingredient which: (a) is a harmful substance (not covered by section1(a) above) in accordance with the National Occupational Health and SafetyCommission's Approved Criteria for Classifying Hazardous Substances[NOHSC:1008]; AND (b) is present In a quantity which exceeds the lowestrelevant concentration cut-off level specified for the hazard classification In theNational Occupational Health and Safety Commission's Approved Criteria forClassifying Hazardous Substances [NOHSC:1008],

Type III Ingredientsmeans any ingredient which does not meet the criteria for either Type I or Type IIingredients described above.

United Nations (UN) Numbermeans a system of four digit numbers assigned by the United Nations Committeeof Experts on the Transport of Dangerous Goods. UN Numbers are assigned toone material or to a group of materials with similar characteristics. They are notnecessarily unique to one material, and may cover a group of materials withsimilar hazardous properties. For example, ORGANOPHOSPHORUS PESTICIDE,LIQUID, TOXIC UN No. 3018.

Vapour densitymeans the ratio of the density of the vapour compared to the density of air. Thedensity of air is nominally set to 1.D. Vapours with a vapour density greater than1.0 will tend to stay close to the floor, whereas vapours with a vapour densityless than 1.0 will tend to rise.

Volatilemeans able to pass readily into the vapour state.

w/vmeans weight per volume. This Is a measure of the content of a solid in asolution.

w/wmeans weight per weight. This is a measure of the content of a solid in a solid.

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Na bona! Code of Praai fo the Preparation of rial Safety Data Sheets

5 GUIDELINES FOR PREPARING MSDSThe supplier of hazardous substances and/or Dangerous Goods has a legalrequirement to prepare an MSDS under Commonwealth, State and Territorylegislation.

The writer of the MSDS needs to keep in mind that a Material Safety Data Sheet(MSDS) must inform its audience of the possible hazards of a material, andprovide information on the safe storage, handling and disposal of the material. AnM505 contains information on the potential health effects of exposure and how towork safely with the material. It also contains hazard information on the use,storage, handling and emergency procedures related to that material.

When writing the 11505, information should be presented in English in a

consistent and complete form, with the workplace audience firmly in mind.However, it should be considered that all or part of the MSDS can be used toinform workers, employers, health and safety professionals, emergency personnel,relevant government agencies, as well as members of the community.

Language used in the MSDS should be simple, clear and precise, avoiding jargon,acronyms and abbreviations. Vague and misleading expressions should not beused. Phrases such as 'may be dangerous', 'no health effects', 'safe under mostconditions of use', or 'harmless' are also unacceptable.

5.1 THE 16 HEADER MSDS SECTIONS

The 16 header MSDS contains the following sections. Chapter 6 of this codedetails the information required For each of these 16 sections listed below:

Section 1 Identification of the material and supplier

Section 2 Hazards identification

Section 3 Composition /Information on Ingredients

Section 4 First aid measures

Section 5 Fire fighting measures

Section 6 Accidental release measures

Section 7 Handling and storage

Section 8 Exposure controls/personal protection

Section 9 Physical and chemical properties

Section 10 Stability and reactivity

Section 11 Toxicological information

Section 12 Ecological information

Section 13 Disposal considerations

Section 14 Transport information

Section 15 Regulatory information

Section 16 Other information

All sections of an MSDS should be completed. Where information relevant to aparticular section is not available, the MSDS should state 'Not available'. If theinformation item Is not relevant, this should be noted as 'Not relevant'. Blanksections tend to confuse or mislead and are therefore unacceptable.

Abbreviations such as 'N/A' or 'N/R' should not be used, as their usage could leadto confusion. For example, 'N/A' may mean either 'not available' or 'not


applicable'. In general, where abbreviations are used, a legend explaining theabbreviations should be included.

5.2 INFORMATION REQUIREMENTS

There are Information requirements for the preparation of an MSDS. For thepurposes of this code, Information has been separated Into core and additionalinformation.

Core Information is essential to understanding the hazards of the material. It alsoallows MSDS prepared in accordance with this code of practice to be consistentwith the information requirements of overseas systems. This information shouldalways be included In the MSDS. The checklist at Appendix 1 illustrates the coreinformation required in the MSDS.

The MSDS may also contain additional information. Where a material hasadditional relevant and available information about its nature and/or use, thatinformation should be included. The checklist at Appendix 1 also Illustrates theadditional information.

5.3 DOCUMENT FORMAT

An MSDS is not a fixed length document. Thelength of the MSDS should be commensuratewith the hazard of the material and theinformation available.

All pages of a printed MSDS should benumbered and the total number of pages alsogiven on each page. For example, 'page 1 of3', 'page 2 of 3', 'page 3 of 3'. An acceptablealternative is to number each page and toIndicate on each page whether there is a pagefollowing.

There should be some indication of the end of the MSDS, such as the words 'Endof MSDS'.

5.4 UNITS

Numbers and quantities should be expressed In units appropriate to Australia. Forexample, degrees Celsius (°C), not degrees Fahrenheit (°F), and litres, notgallons. In general, the International System of Units (SI) should be used.However, provision should be made for non-SI units where such units are Inwidespread usage In Australia. For example, mm Hg for vapour pressure, anddegrees Celsius (°C) not degrees Kelvin (K) for temperature.

5.5 HOW TO CLASSIFY

A material is classified as hazardous and/or dangerous if it is:

(a) classified as hazardous according to the latest edition of the NOHSC ApprovedCriteria for Classifying Hazardous Substances [NOHSC:1008) and is above thecut-off concentration criteria for being classified as a hazardous substance;

(b) specified In the NOHSC list of Designated Hazardous Substances[NOHSC:10005];

(c) classified for physicochemical hazards according to the ADG Code (includingclass(es), subsidiary risk(s), Packing Group, Proper Shipping Name and UNNumber); and/or

(d) specified as dangerous in the ADG Code or determined by the CompetentAuthorities.

An MSDS for Two Pack SystemsFor two pack systems (e.g. two packisocyanate paints or epoxyadhesives), an MSDS for eachcomponent material should beprovided, with a clear description ofthe hazards, adverse health effects,safe handling and any other relevantinformation related to eachcomponent and the combinedmaterial.

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National Code of Practice or the Preparation of Material Safety Data Shee

5.6 ACCEPTABILITY OF AN OVERSEAS MSDS

Currently, MSDS prepared overseas areaccepted by Commonwealth, State andTerritory legislation if they meet the followingrequirements:

(a) the MSDS is prepared in accordance withthis code Including the provision of thefollowing information:

(i) Australian contact details name ofsupplier, address and telephonenumber, Including emergency contactdetails (see section 6.1);

(II) classification In accordance with theAustralian hazardous substance andDangerous Goods regulatoryframework (see section 6.2);

Classification Alignment withAustraliaCountries that use the same systemof classification as Australia offer thebasis for an acceptable MSDS. Ingeneral MSDS that use ECclassification criteria will provide anMSDS that can more easily beadapted to Australian requirements.

Referencing Over seas DocumentsEnsure that refcroncrs to overseasdocuments (o q OVOI`ed, exposurestandards) are adequate to identifytheir source of origin.

(Hi) ingredient disclosure as required by Commonwealth, State and Territorylegislation (see section 6.3);

(Iv) national exposure standard value if available (see section 6.8); and

(v) relevant additional Australian regulatory Information (see section 6.15).

5.7 EXPLANATORY TEXT

The Information included in the boxed text throughout the code is supplementaryguidance material and does not form part of this code of practice.

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6 PREPARATION OF THE 16 HEADER MSDS

6.1 SECTION 1 - IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Provide the name and supplier of the product (material), recommended uses andthe contact detail information of the supplier including an emergency contact inthis section.

6.1.1 CORE INFORMATION

Product (material) name.

Other names.

Recommended use.

Supplier name, address, telephone number, and Australian emergency contactnumber.

6.1.2 Product (Material) NameThe identity of the material should be exactly as found on the label for thematerial.

If one generic MSDS is used to cover several grades or minor variants of amaterial, all grades or material names should be listed on the MSDS or the MSDSshould clearly delineate the range of materials included.

6.1.3 Other NamesThe material may also be identified by alternative names, numbers, companyproduct codes, or other unique identifiers. Provide other names or synonyms bywhich the product is labelled or commonly known in Australia, if applicable. ForDangerous Goods the Proper Shipping Name, as identified in the ADG Code,should be provided in this subsection if it has not appeared as the product name.Additionally, the name as specified in the Australian Health Ministers' AdvisoryCouncil's (AHMAC) Standard for the Uniform Scheduling of Drugs and Poisons(SUSDP), should be provided in this subsection if it has not appeared as theproduct (material) name.

6.1.4 Recommended Use

Provide the recommended or intended use of the material and indicate anyrestrictions on use.

6.1.5 Supplier Name, Address, Telephone Number and Australian EmergencyContact NumberProvide the name, address and phone number of the Australian supplier, includingemergency phone number.

Companies should include references to emergency information services on theirMSDS.

Emergency Phone NumberIndicate if the telephone numbers have any restrictions, such as hours of operation (e.g. Monday -Friday, 8:00 a.m. - 6:00 p.m., or 24 hours) or are limited to a specific type of information (e.g.general information, medical emergencies, transportation emergencies). Where a PoisonsInformation Centre (PIC) phone number Is used, this arrangement should be confirmed with the PICbeforehand, and the PIC provided with copies of M505 for all relevant materials.

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6.2 SECTION 2 - HAZARDS IDENTIFICATION

Describe the hazards of the materials and the appropriate warning information(risk and safety phrases) associated with those hazards in this section.


Hazard classification, including a statement of overall hazardous or dangerousnature.

Risk phrase(s).

Safety phrase(s).

6.2.2 Hazard Classification

This Section indicates the hazardous and/ordangerous classification of the material.

(a) If the material is classified in accordancewith section 5.5, provide a statement ofoverall hazardous or dangerous nature. Thewording to be used is:

(i) HAZARDOUS SUBSTANCE, DANGEROUSGOODS; or

(ii) HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS; or

(iii) DANGEROUS GOODS.HAZARDOUS SUBSTANCE.

NON°

6.2.3 Risk Phrase(s)

Based on the classification provide theappropriate risk phrase(s) (see Approved Criteriafor Classifying Hazardous Substances[ NOHSC: 1008] ).

6.2.4 Safety Phrase(s)

Based on the classification provide theappropriate safety phrase(s) (see ApprovedCriteria for Classifying Hazardous Substances[NOHSC: 1008]).

Description of Classification

It is useful to describe how thematerial was classified, e.g.,'classified as hazardous according tothe criteria of NOHSC.

Non-Hazardous and Non-Dangerous MaterialsRegarding NON-HAZARDOUS andNON-DANGEROUS materials, there isno legal requirement to provide anMSDS for such mate rims. However, itis good practice to do so as an MSDSis a well-accepted and effectivemethod for the provision of workplaceinformation.

GHS Hazard and PrecautionaryStatementsRisk and safety phrases are referredto as hazard and precautionarystatements in the GHS.

Poisons ScheduleThe Standard for the UniformScheduling of Drugs and Poisons(SUSDP) lists some substances usinga risk based classification system.This information should also beProvided In section 15 of the MSDS.

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6.3 SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

Identify the ingredient(s) of the material in this section.


Pure substancesChemical identity of the pure substance,

Common name(s), synonym(s).

CAS Number(s).

Mixtures or Composite MaterialsChemical Identity of Ingredients.

Proportion of ingredients.

CAS Number for ingredients.

6.3.2 Chemical Identity of the Pure SubstanceThe identity of a material is provided by its common chemical name.

For a pure substance, or each Ingredient of a mixture, the chemical name shouldbe assigned as follows:

(a) the name as listed in the NOKSC List of Designated Hazardous Substances[NONSC:10005]; and/or

(b) the Proper Shipping Name assigned in the ADG Code where the substance isspecifically listed In the ADG Code and meets the classification criteria ofsection 2 of that code; and/or

the name as it appears in the SUSDP where the substance is scheduled;and/or

(d) the recognised chemical name as used in readily available scientific andtechnical handbooks, journals and texts, where none of the above areapplicable.

The chemical name can be identical to the product name.

6.3.3 Common Name(s), Synonym(s)Common names and synonyms should be provided where appropriate. Synonymscan include recognised abbreviations, for example, TD1' for toluene diisocyanate.

6.3.4 CAS Number(s)The Chemical Abstract Service (CAS) Registry Number should be provided whereavailable. Chemical Abstract Service Registry Numbers provide a uniqueidentification, See Appendix 2 for more Information.

6.3.5 Chemical Identity of IngredientsFor materials classified as hazardous substances or Dangerous Goods, theIngredients that contribute to that classification should be disclosed in accordancewith subsections 6.3.5 to 6.3.7 of this code.

All ingredients may be listed, even if they are not hazardous substances orDangerous Goods, as they may contribute to the effects of the material.

(c)

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National Code of Practice for the Prepa

6.3.6 Proportion of Ingredients(a) The material should have the proportion o

ingredients described as:

(I) exact percentages in descending orderby mass or volume; or

(II) ranges of percentages In descendingorder by mass or volume.

(b) Ranges to be used are:

> 60% 30 - 60%

on of Material Safety Data Sheets

Percentage CompositionsPercentage compositions should addup to or indicate a total of 100%,even If an estimate of non-hazardousingredients needs to be provided.

10 - < 30% < 10%.

(c) When using a proportion range, the health hazard effects should describe theupper limit of the range.

6.3.7 Confidentiality ProvisionsAs stated in section 6.3.2, ingredients should be listed by chemical name,common name and/or synonym. Commonwealth, State and Territory legislationhave disclosure provisions for ingredients. However, concern about commercialconfidentiality may cause the supplier to choose not to disclose the ingredientInformation. Non-disclosure Is not acceptable for Ingredients that are classifiedwith a particular health hazard. The hazardous substances regulations deal withthis by defining Type I, II and III Ingredients. Definitions of Type I, II and IIIingredients are based on the material's toxicity and concentration in the finalproduct.

Disclosure of Ingredients

When a material is classified as a hazardous substance and/or Dangerous Goods,the ingredients that contribute to the classification should be disclosed.

Type I Ingredients are those associated with serious health and/or safety hazardswhen present in mixtures above certain concentrations. Type I Ingredients, bydefinition, are associated with particular hazards (see Chapter 4), or have aNational Exposure Standard, and are present in a quantity that exceeds the lowestrelevant concentration cut-off level specified for the hazard classification. Theseingredients must be disclosed with their full chemical name; generic names arenot permitted, If the final material is classified as a Dangerous Goods, fulldisclosure of any Ingredients that contribute to the classification is required.

Type II Ingredients are those that present less serious health hazards than Type Iingredients, when present in mixtures above certain concentrations, but which arestill harmful, Confidentiality can be maintained for these ingredients through theuse of a designated generic name that describes the hazardous functionality of theingredient but avoids the specific chemical name. Appendix 3 provides guidanceon the selection of generic names.

Type III Ingredients are those Ingredients that are not classified as Type I or IIingredients or Dangerous Goods, either because of their low toxicity or becausethey are present in mixtures at levels below specified concentration cut-off levels,These materials do not need to be disclosed In the MSDS. However, to avoidconfusion, it is recommended that all Ingredients be Indicated on the MSDS andthe label. If commercial confidentiality is an issue, use a statement like 'otheringredients determined not to be hazardous' and a concentration range.

Where a Type III ingredient is not a hazardous substance but has knownsynergistic effects it should be identified.

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National Code of Practice for the Preparation of Material Safely Data Sheets

If the Ingredients are below the concentration cut-off for classification, but whencombined cause the mixture to be classified as hazardous, these should bedisclosed.

Where the chemical identity of an ingredient has not been disclosed on the MSDS,It Is necessary to Include the name and contact details on the MSDS for furtherinformation. The manufacturer or Importer has an obligation underCommonwealth, State and Territory legislation to disclose the chemical identity ofan Ingredient in specific emergency and non-emergency situations.

Table 1 Summary of Ingredient Disclosure

MATERIAL DEFINITION DISCLOSURE

All Dangerous goods.

Type I Ingredient

Type II Ingredient

Type III Ingredient

An Ingredient which: (a) in accordance with theNational Occupational Health and SafetyCommission's Approved Criteria for ClassifyingHazardous Substances DVOHSC:10081 iscarcinogenic, mutagenic, teratogenic, a skin orrespiratory sensitiser, very corrosive, corrosive,toxic or very toxic, a harmful substance whichcan cause irreversible effects after acuteexposure, or a harmful substance which cancause serious damage to health after repeatedor prolonged exposure; OR (b) has an exposurestandard listed in the National OccupationalHealth and Safety Commission's ExposureStandards for Atmospheric Contaminants in theOccupational Environment [NOHSC:1003]; AND(c) is present in a quantity which exceeds thelowest relevant concentration cut-off levelspecified for the hazard classification in theNational Occupational Health and SafetyCommission's Approved Criteria for ClassifyingHazardous Substances [NOHSC:10081.

An ingredient which: (a) is a harmful substance(not covered by section 1(a) above) inaccordance with the National OccupationalHealth and Safety Commission's ApprovedCriteria for Classifying Hazardous Substances[NOHSC:1008]; AND (b) is present in a quantitywhich exceeds the lowest relevant concentrationcut-off level specified for the hazardclassification in the National Occupational Healthand Safety Commission's Approved Criteria forClassifying Hazardous Substances[NOHSC:10081

Any ingredient, which does not meet the criteriafor either Dangerous Goods or Type I or Type IIingredients described above.

Full Disclosure.

Full disclosure is always required.

The chemical name shall be disclosedon the P4505.

A claim of commercial confidentialitycannot be made.

Generic names are not permitted.

Generic names are permitted.

A generic name may be used whichshould describe the functionality ofthe ingredient, which contributes tothe hazard. Appendix 3 providesguidance on the selection of a genericname.

No disclosure is required. However,full description of any ingredients witha known adverse health effect orDangerous Goods property is goodpractice.

Typo I IngredientsBased on the definition, ingredients with the following risk phrases (from the 1999 Approved Criteria for ClassifyingHazardous Substances [NOFISC:1008]) may be construed as Type 1 Ingredients:R23, R24, R25, R26, R27, R28, R34, R35, R39, R40, R42, R43, R45, R46, R47, R48, R49, R60, R61, R62, R63.

Type II IngredientsBased on this definition, Ingredients with the following risk phrases (from the 1999 Approved Criteria for ClassifyingHazardous Substances [NOHSC:1008]) may be construed as Type 2 Ingredients:R20, R21, R22, R29, R31, R32, R33, R36, R37, R38, R41, R64, R65.

18


6.4 SECTION 4 - FIRST AID MEASURES

Describe the initial care that can be given without the use of sophisticatedequipment and without a wide selection of medications available. If medicalattention is required, the instructions should state this, including its urgency.


Description of necessary first aid measures according to routes of exposure.

Indication of medical attention and any special treatment needed (notes tophysician should include a description of most important symptoms, acute anddelayed).

6.4.2 Description of Necessary First Aid MeasuresProvide first aid instructions by relevant routes ofexposure. Use subheadings to indicate theprocedure for each route (e.g. Inhalation, skin,eye, and ingestion).

Describe expected immediate and delayedsymptoms.

Provide advice, including if:

(a) immediate medical attention is required and if delayed effects can beexpected after exposure;

(b) movement of exposed individual from area to fresh air is recommended;

(c) advice on removal and handling of clothing and shoes from individual Isrecommended;

(d) any known antidotes may be administered by persons trained In their use aspart of the recommended first aid procedure; and

(e) any information on specific first aid facilities, such as showers or eyewashes,are necessary in a workplace where the particular material is used.

6.4.3 Medical Attention and Special TreatmentProvide information on any medical and special treatments, For example, clinicaltesting and medical monitoring for delayed effects, specific procedures, details onemesls or lavage, antidotes, contraindications. Specific antidotes should beindicated where they are available. Describe the most important symptomscaused by exposure, whether acute or delayed.

6.4.4 ADDITIONAL INFORMATION

Aggravated medical conditions caused by exposure.

6.4.5 Aggravated Medical Conditions Caused by Exposure

A list of possible 'aggravated medical conditions' may be Included in this section,

Scheduled Poison First Aid AdviceIf a material is a scheduled poison,the first aid advice should beconsistent with that required by theStandard for the Uniform Schedulingof Drugs and Poisons (susor).

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National Code of Practice for the Pre oration of Material Safe Data Sheets

6.5 SECTION 5 - FIRE FIGHTING MEASURES

Describe the fire and explosive properties of the material and provide advice onhow to deal with incidents in this section.


Suitable extinguishing media.

Hazards from combustion products.

Precautions for fire fighters and special protective equipment.

6.5.2 Suitable Extinguishing MediaProvide information on the appropriate type of extinguishers or fire fightingagents. In addition, Indicate whether any extinguishers are inappropriate for aparticular situation involving the material.

6.5.3 Hazards From Combustion ProductsProvide advice on whether hazardous combustion products can occur when amaterial burns. For example:

(a) 'may produce toxic fumes of carbon monoxide if burning'; or

(b) 'produces oxides of sulfur and nitrogen on combustion'.

6.5.4 Precautions For Fire Fighters and Special Protective Equipment

Provide advice on any precaution to beobserved in fighting fire. For example, 'keepcontainers cool with water spray'.

Provide information on protective clothing to beworn by fire fighters. For example, boots,overalls, gloves, equipment and breathingapparatus.


Hazchem Code

6.5.6 Hazchem Code

If a Hazchem Code is availiable it should beincluded. See the ADG Code for furtherinformation.

Emergency Services InformationConsult the emergency servicesauthority for specific advice.

Hazchem CodeThe Hazchem Code for bulkdangerous goods provides codedInformation on the fire-fightingmedium to be used. This includesInformation on clothing andequipment for personal protection,the risk of violent reaction orexplosion, spillage action and whetherevacuation should be considered inthe event of an incident with thematerial.

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National Code of Practice for the Preparation or Material Safety Data Sheets

6.6 SECTION 6 - ACCIDENTAL RELEASE MEASURES

Recommend the appropriate response to spills, leaks, or releases in order toprevent or minimise the adverse effects on persons, property and theenvironment In this section.


Emergency procedures.

Methods and materials for containment and clean up.

6.6.2 Emergency Procedures

Provide advice on emergency procedures related to accidental spills and release ofthe material.

SAA/SNZ HB 76: DANGEROUS GOODS-INITIAL EMERGENCY RESPONSE GUIDE

This handbook provid' em( rgcncy n.sponse Information for safely dealing with act dents, spills,leaks or fires in which Dangerou Goods are involved, Information on hazards, pink dive clothingand emergency procedures is also given. It can be used for the transport and rtordgc of all typesof Dangerous Good:, UN Numbers and Proper Shipping Names (ba.ed on the UNRecommendations on the Iran poet of Dangerous Goods) are referenced to the appropriateemergency response guides.

6.6.3 Methods and Materials for Containment and Clean Up ProceduresProvide appropriate advice on how to containand clean up a spill,

Appropriate containment techniques mayinclude:

(a) bunding, covering of drains; and

(b) capping procedures.

Appropriate clean up procedures may Include:

(a) neutralisation techniques;

(b) decontamination techniques;

(c) adsorbent materials;

(d) cleaning techniques;

(e) vacuuming techniques; and

(1) equipment required for containment/clean up (Include the use of non-sparkingtools and equipment).

Provide any other Issues relating to spills and releases. For example, includingadvice on Inappropriate containment or clean up techniques.

Distinguishing Spill VolumesIn 6.6.3, distinguish betweenresponses for large and small spillswhere spill volume impactssignificantly on the hazard; theprocedures for containment andrecovery may indicate differentpractires are required. If PersonalPratte-two Equipment (PPE) isrequired for containment/clean up -Infer readers to section 8 of theMSDS.

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National Code of Practice for the Pr ration of Material Safet Data Sheets

6.7 SECTION 7 - HANDLING AND STORAGE

Provide guidance on safe handling practices that minimise the potential hazards topeople, property and the environment from the material. Emphasise precautionsthat are appropriate to the unique properties of the material, rather thanreviewing general storage and handling practices.


Precautions for safe handling.

Conditions for safe storage, Including any incompatibilities.

6.7.2 Precautions for Safe Handling

Provide advice that:

(a) minimises contact between the worker andthe material;

(b) prevents handling of incompatiblematerials; and

(c) minimises the release of the material tothe environment.

Include general warnings on what practices toavoid or restrict.

6.7.3 Conditions for Safe StorageProvide advice on specific storage requirementsIncluding:

(a) How to avoid:

(i) explosive atmospheres;(H) corrosive conditions;(Hi) flammability hazards;(iv) Incompatible materials;(v) evaporative conditions; and(vi) potential ignition sources (including

electrical equipment).

(b) How to control the effects of:

(i) weather conditions;(ii) ambient pressure;(Ili) temperature;(iv) sunlight;(v) humidity; and(vi) vibration.

How to maintain the integrity of thematerial by the use of:

(i) stabilizers;(H) anti-oxidants; and(iii) phlegmatlsers.

Other advice including:

(I) ventilation requirements; and(ii) packaging compatibilities.

(c)

(d)

Safe Handling of ArticlesWhere an article, which contains ahazardous substance or DangerousGoods, introduces a hazard of itsown, then the hazards of that articleshould also be addressed whenconsidering safe handling procedures.For example, when determining safehandling procedures for batteries andfire extinguishers.

Provision of General HygieneAdviceIt is good practice to provide adviceon general hygiene. For example:

prohibiting eating, drinking andsmoking in contaminated areas;

wash hands before eating; and

remove contaminated clothingand protective equipment beforeentering eating areas.

Storage and Handling References

Further advice on storage andhandling is provided in the:

National Code of Practice for theStorage and Handling ofWorkplace Dangerous Goods

[NOFI5C:2017I;

SAA/SNZ HB 76:1997 DangerousGoods - Initial emergencyresponse guide, and

Relevant Australian Standards.

Consistent Advice

Ensure that the advice provided is

consistent with the physical and

chemical properties in Section 9.

22


SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Detail engineering control measures needed to minimise exposure to and risksassociated with the hazards of the material In this section.


National exposure standards.

Biological limit values.

Engineering controls.

Personal protective equipment.

6.8.2 National Exposure Standards

Exposure Standards

NOHSC has approved National Exposure Standards for Atmospheric Contaminants in theOccupational Environment [NOHSC:1003].

Exposure standards represent airborne concentrations of individual chemical substances, whichaccording to current knowledge, should neither impair the health of, nor cause undue discomfortto, nearly all workers.

Australian exposure standards are generally expressed as a Time-Weighted Average (TWA)concentration of that substance over an eight-hour working shift, and apply to an eight-hour day,for a five-day working week over an entire working lifetime. Short Term Exposure Limits (STEL)and Peak Limitations may also be specified for short periods of exposure such as 15 minutes.

These exposure standards may be reviewed from time to time and therefore the most recentedition of this publication should be consulted.

Where available, list the NOHSC exposure standards, including notations, for apure substance and for each of the ingredients of a mixture. These should bereferred to In the MSDS as ES-TWA, ES-STEL and ES-Peak. Use the chemicalname, as specified in the NOHSC Exposure Standards for AtmosphericContaminants in the Occupational Environment [NOHSC:1003].

Alternative StandardsWhere NOHSC exposure standards are not allocated, overseas exposure standardsmay be used. Examples of overseas standards include those of the Health andSafety Executive (HSE) in the United Kingdom, American Conference ofGovernmental Industrial Hygienists (ACGIH) or the German MAK.

If there is no exposure standard allocated, then the MSDS should state that thereis 'no exposure standard allocated',

6.8.3 Biological Limit Values

Where required under the National Model Regulations for the Control of WorkplaceHazardous Substances [NOHSC:1005], for the health surveillance of hazardoussubstances, the appropriate biological limit should be listed. Such limits areoutlined in the Guidelines for Health Surveillance [NOHSC:7039].

Where NOHSC biological limits are not allocated, overseas limits may be used.Examples of overseas standards include those of the Health and Safety Executive(HSE) in the United Kingdom, American Conference of Governmental IndustrialHygienists (ACGIH) or the German BAT.

If there is no biological limit allocated, then the MSDS should state that there is'no biological limit allocated'.

23


6.8.4 Engineering ControlsEngineering control measuresThe description of appropriate exposure control measures should relate to theintended modes of use of the material, Indicate whether special engineeringcontrols are necessary, and specify which type. For example:

(a) 'use only in a well ventilated area';

(b) 'maintain air concentrations below exposure standards';

(c) 'use local exhaust ventilation';

(d) 'use only in an enclosed system';

(e) 'use only in spray paint booth or enclosure';

(f) 'use mechanical handling to reduce human contact with materials'; or

(g) 'use explosive dust handling controls',

6.8.5 Personal Protective Equipment (PPE)

Identify the personal protective equipment(PPE) needed to minimise the potential forIllness or injury due to exposure from thematerial.

Eye/face protection - specify the type of eyeprotection (safety glasses, goggles) and/or faceshield required, based on the hazard of thematerial and potential for contact.

Skin protection - specify the protectiveequipment to be worn (e.g. gloves, boots,bodysuit) based on the hazards associated withthe material and the potential for contact.

Respiratory protection specify appropriatetypes of respiratory protection based on theexposure, Including air-purifying respiratorsand the proper purifying element (cartridge or canister).

Thermal hazards when specifying protective equipment to be worn for materialsthat represent a thermal hazard, special consideration should be given to theconstruction of the PPE.

Special Requirements for PPE

See also Section 5 of the MSDS forspecific fire/chemical PPE advice.

Special requirements may exist forgloves or other protective clothing toprevent skin, eye or lung exposure.Where relevant, this type of PPEshould be clearly stated. Forexample, 'PVC gloves' or 'nitrilerubber gloves'.

Special requirements may exist forrespirators. Vague information suchas 'use face mask' is not acceptablewhereas 'use half-fate filter respiratorsuitable for organic vapours' would beacceptable.

24


6.9 SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Describe the empirical data of the material in this section. Refer o the definitionsin Chapter 4 for further Information,


Clearly Identify the following properties andnote if specific characteristics do not apply, arenot available or are irrelevant.

Specify appropriate units of measure and/orreference conditions where appropriate.

(a) Appearance (colour, physical form, shape).

(b) Odour.

(c)

(d) Vapour pressure.

(e) Vapour density.

(f) Boiling point/range.

(g) Freezing/melting point (specify which).

(h) Solubility (specify solvent, e.g. water).

(I) Specific gravity or density.

(j) Information for flammable materials, including:

(i) flash point and method of detecting flash point;(U) upper and lower flammable (explosive) limits in air; and(iii) ignition temperature.


(a) Specific heat value.

(b) Particle size.

(c) Volatile organic compounds (VOC) content.

(d) Evaporation rate.

(e) Viscosity.

(f) Percent volatile.

(g) Octanol/water partition coefficient.

(h) Saturated vapour concentration (Include reference temperatures).

(i) Additional characteristics not noted above may also be provided if applicableto the material.

(j) Flame propagation or burning rate of solid materials.

(k) Properties of both flammable and non-flammable materials that may initiateor uniquely contribute to the intensity of a fire (e.g. Class 4 or Class 5).

(I) Potential for dust explosion.

(m) Reactions that release flammable gases or vapours.

(n) Fast or intensely burning characteristics.

(o) Non-flammables that could contribute unusual hazards to a fire, such asstrong oxidizing and reducing agents or peroxide formers.

(p) Release of invisible flammable vapours and gases.

(q) Decomposition temperature.

Provision of Physical/ChemicalInformationThe data Included in this subsectionshould apply to the al-Meal dS usedat work. If the material a mixtureor formulation, the phy sal datashould describe Mc mn ture orformulation. If that inform Mon is notavailable the physit al/chemicalproperties of the ingredients shouldbe provided.

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National Code of Practice for the Pr ation of Material Safet Data S

6.10 SECTION 10 - STABILITY AND REACTIVITY

Describe reactivity hazards of the material In this section.

Provide specific test data for the product as a whole, where available. However,the information may also be based on general data for the class or family ofchemical if such data adequately represents the anticipated hazard of thematerial.


Chemical stability.

Conditions to avoid.

Incompatible materials.

Hazardous decomposition products.

Hazardous reactions.

6.10.2 Chemical StabilityIndicate If the material is stable or dangerously unstable under normal ambientand anticipated storage and handling conditions of temperature and pressure.

6.10.3 Conditions to AvoidList conditions such as heat, pressure, shock, or other physical stresses that mightresult in a hazardous situation.

6.10.4 Incompatible MaterialsList classes of chemicals or specific materialswith which the material could react to producea hazardous situation (e.g. explosion, releaseof toxic or flammable materials, liberation ofexcessive heat).

6.10.5 Hazardous Decomposition Products

Availability of DataIf data for mixtures are not available,ingredient data should be provided.In determining incompatibility,consider the materials, containers,and contaminants that the materialmight be exposed to duringtransportation, storage and use.

List known and reasonably anticipated hazardous materials produced as a result ofoxidation, heating, or reaction with another material, including the production offlammable and toxic materials.

6.10.6 Hazardous Reactions

If relevant, state if the material will react or polymerize, releasing excess pressureor heat, or creating other hazardous conditions. Describe under what conditionsthe hazardous reactions may occur.

26


6.11 SECTION 11- TOXICOLOGICAL INFORMATION

Describe, In lay language, the potential adverse health effects and symptomsassociated with exposure to the material and Its Ingredients or known by-products.

While this section is used primarily by medical professionals, occupational healthand safety professionals, and toxicologists, the language used in this sectionshould be understandable to anyone in the workplace.


Health effects from likely routes of exposure and symptoms related to thephysical, chemical and toxicological characteristics as determined by theclassification, including:

(a) acute and chronic health effects;

(b) possible routes of exposure;

(c) range of effects following exposure;

(d) dose, concentration or conditions of exposure likely to cause Injury;

(e) delayed effects; and

(f) relevant negative data.

6.11.2 Health Effects from Likely Routes of Exposure

Provide Information on:

(a) acute and chronic health effects relating to human exposure to the material.Where human data are not available, animal data should be summarised andthe species clearly identified;

(b) the effects of the material via each possible route of exposure that Is, throughIngestion (swallowing), inhalation or skin/eye exposure. A statement shouldbe made if these health effects are not known;

the effects following exposure, ranging from the first symptoms at the lowestexposures to the consequences of severe exposure; for example, 'headachesand dizziness may occur, proceeding to fainting or unconsciousness; largedoses may result in coma and death';

(d) the dose, concentration or conditions of exposure likely to cause injury.Where possible, doses should be linked to symptoms and effects and includethe period of exposure likely to cause harm. For example, '10 ppmrespiratory irritation, 250-300 ppm difficulty in breathing, 500 ppmunconsciousness leading to death after 30 minutes';

(e) whether delayed effects can he expected after short or long term exposure;and

relevant negative data. For example, the statement 'carcinogenicity studiesin the rat have shown no significant increase in the incidence of cancer'.

(c)

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National Code of Practice for the Pre aration of Materal Safet Data eet

GUIDANCE ON COMPLETING SECTION 11

GENERAL VERSUS SPECIFIC STATEMENTS

General statements such as 'toxic' with no supporting data or 'safe if properlyused' are not acceptable as they may be misleading and do not provide adescription of health effects. Phrases such as 'not applicable', 'not relevant', orleaving blank spaces In the health effects section can lead to confusion andmisunderstanding and should not be used. For health effects where information isnot available, this should be clearly stated. Health effects should be describedaccurately and relevant distinctions made. For example, allergic contactdermatitis and irritant contact dermatitis should be distinguished from each other.

WHERE SPECIFIC CHEMICAL DATA ARE NOT AVAILABLE

It may not always be possible to obtain information on the hazards of a substanceas many have never been fully tested. In cases where data on the specificsubstance are not available, data on the chemical class, if appropriate, may beused. Where generic data are used or where data are not available, this shouldbe stated clearly on the MSDS.

MIXTURE VS INGREDIENT INFORMATION

Most frequently the material requiring an MSDS is a mixture. If the mixture hasnot been tested for its health effects as a whole then information on Ingredientsshould be provided. After collecting data on health effects and dose-response foreach ingredient, an estimation of the combined health effects needs to be made.When using ingredient data to estimate the health effects of a mixture thefollowing should be taken Into account:

(a) the concentrations of the ingredients, including airborne concentrations;

(b) the relevant hazard of the material; and

(c) any potential interactions in the body between the ingredients.

Ingredients may Interact with each other in the body resulting In different rates ofabsorption, metabolism and excretion. As a result, the toxic actions may bealtered and the overall toxicity of the mixture may be different from Itsingredients.

It is necessary to consider whether the concentration of each Ingredient issufficient to contribute to the overall health effects of the mixture. Theinformation on toxic effects should be presented for each ingredient, except:

(a) if the information Is duplicated, It Is not necessary to list this more than once.For example, if two ingredients both cause vomiting and diarrhoea, It is notnecessary to list this twice. Overall, the mixture Is described as causingvomiting and diarrhoea;

(b) if it is unlikely that these effects will occur at the concentrations present. Forexample, when a mild irritant Is diluted in a non-irritating solution, therecomes a point where the overall mixture would be unlikely to cause Irritation.

Predicting the interactions between ingredients is extremely difficult, and whereinformation on Interactions Is not available, assumptions should not be made andinstead the health effects of each ingredient should be listed separately.

SUMMARY OF TOXICITY DATA

Summarise the data available. Where there is a substantial amount of test dataon the ingredient or the material, it may be desirable to summarise results byroute of exposure or to discuss only selected studies that are representative of thehazards that give rise to the classification reported in Section 2 of the MSDS.

28


HUMAN/ANIMAL DATA

If there are human data, including exposure information, human case histories orepidemiological studies these should be highlighted. Where there are no humandata, report effects based on animal testing. All studies should be adequatelyreferenced including the epidemiological studies.

CARCINOGENICITY STUDIES

Carcinogenicity studies should include whether the evidence is animal or human,the type of study and the type of cancer and/or organs affected.

In addition, where possible, an indication of the weight of evidence forcarcinogenicity in humans should be Included. This can be obtained fromgovernment/international agencies, which evaluate the carcinogenic potential ofselected substances. A sample statement would be 'has been classified as aprobable human carcinogen by the International Agency for Research on Cancer'.

COMPOUNDING EFFECTS

Information on compounding effects should be Included if relevant. For example:

(a) if symptoms are exacerbated by drinking alcohol, taking medication orsmoking;

(h) if the substance is secreted in breast milk; or

(c) if pre-existing medical conditions such as asthma, high blood pressure or apredisposition to allergic reactions may place an Individual at an increasedrisk.

OTHER INFORMATION

All information on adverse health effects should be included even when notrequired by the Approved Criteria.

29


6.12 SECTION 12 - ECOLOGICAL INFORMATION*

Provide Information to evaluate the environmental impact of the material if it isreleased to the environment. It can assist in handling spills, and evaluating wastetreatment practices and should clearly Indicate species, media, units, test durationand test conditions.

Where Information is not available this should be stated.


Ecotoxicity.

Persistence and degradability.

Mobility.

6.12.2 EcotoxicityEcotoxlcity information can be provided usingaquatic and/or terrestrial toxicity data, whereavailable. The relevant ecotoxicologicalclassification criteria are found in the ApprovedCriteria. Examples of hazard statements forecotoxicity are as follows:

(a) very toxic to aquatic organisms;

(b) may cause long-term adverse effects n theaquatic environment;

(c) toxic to flora;

(d) toxic to fauna;(e) toxic to soil organisms;

(f) toxic to bees;

(g) may cause long-term adverse effects inthe environment; and

(h) dangerous to the ozone layer.

6.12.3 Persistence/Degradability

*Regulatory Requirements on theProvision of EcologicalInformationProvision of ecological information Is arequirement of the GHS. At the timeof publication of this code, there is noconsistent national requirement underthe Commonwealth, State andTerritory hazardous substancesregulations to provide thisinformation. However, underDangerous Goods regulation, someStates and Territories require thisinformation.

Advice on Ecological Information

National chemical assessmentschemes include assessment ofenvironmental hazards. Refer toNICNAS, Environment Australia (EA)or National Registration Authority(NRA) reports for advice onecotoxicity, persistence,degradability and mobility.

Information on persistency/degradability can be determined using half-life data forsoils and/or water/sediment systems. Where a ready biodegradability study hasbeen conducted, the results of this can also be reported in this section. If usingpersistence statements, ensure that the criteria are referenced. Refer to theEnvironment Australia (EA) website <www.etabv.au> for the relevant criteria.

6.12.4 MobilityInformation on mobility can be determined from relevant mobility data such asadsorption studies or leaching studies. Modeled data are also acceptable. Forexample, K values can be predicted from octanoi /water partition co-efficients.Leaching and mobility can be predicted from models such as PRZM (softwarepackage). If using mobility statements, ensure that the criteria are referenced.Refer to the Environment Australia (EA) website <ww,w,ta oov,au> for the relevantcriteria.


(a) Environmental Fate (exposure).

(b) Bloaccumulative potential.

(c) Other adverse environmental effects.

30


6.13 SECTION 13 - DISPOSAL CONSIDERATIONS

Provide information on disposal and recyclingand/or its container in this section.

6.13.1 CORE INFORMATION REQUIRED

Disposal methods, including disposal ofcontainers.

Special precautions for landfill orincineration.

6.13.2 Disposal Methods

Provide information for proper disposal,recycling or reclamation of the material and/orits container to assist in the determination ofsafe and environmentally preferred wastemanagement options.

(a) Specify disposal containers and methods.

(b) Discuss physical/chemical properties thatmay affect disposal options.

(c) Discourage sewage disposal.

6.13.3 Special Precautions for Landfill or IncinerationWhere appropriate, Identify any special precautions for incineration or landfill.

or reclamation of the material

Waste Classification

The generator of waste has theresponsibility for proper wasteclassification, transportation anddisposal.

Classify waste under applicable Stateand local regulations.

Information on the ManufacturedMaterial

Advise that the Information applies tothe in it, Hal as manufactured.Processing, use, or contaminationmay make the Informationinappropriate, inaccurate, orincomplete.


6.14 SECTION 14 - TRANSPORT INFORMATION

Provide basic classification information for the preparation of a material fortransporting/shipment.

Where information is not available or relevant this should be stated.


UN Number.

UN Proper Shipping Name.

Class and subsidiary risk(s).

Packing Group.

Special precautions for user.

Hazchem Code.

6.14.2 UN Number

Provide the UN Number from the ADG Code for Dangerous Goods, The UNNumber is assigned to goods by The UN Committee of Experts on the Transport ofDangerous Goods and is published by the UN in Recommendations on theTransport of Dangerous Goods.

6.14.3 Proper Shipping NameProvide the Proper Shipping Name. The Proper Shipping Name is used to identifyDangerous Goods and is in upper case lettering In APPENDIX 2 of the TechnicalReferences of the ADG Code.

6.14.4 Class and Subsidiary Risk(s)Provide the class and subsidiary risk(s) for Dangerous Goods. The classes arespecified in the ADG Code.

6.14.5 Packing GroupProvide the Packing Group number. The Packing Group number Is a conventionused to classify the degree of hazard within a class for most Dangerous Goods ofClasses 3 to 9. Packing Group I is the highest hazard and Packing Group III thelowest. The Packing Group is specified in the ADG Code.

6.14.6 Special Precautions for UserAny other special requirements (for example, hazards such as shock sensitivity orspecific storage requirements during transit/warehousing) should be restatedhere, if relevant to transport.

6.14.7 Hazchem Code

Provide the Hazchem Code as published in the ADG Code.


Material for export - advice on overseas regulatory transport requirements.

6.14.9 Material for exportIf the product is intended for export, section 14 Transport Information, mayindicate the relevant International regulatory transport requirements. Forexample:

(a) US Department of Transport requirements such as technical names,hazardous substances/reportable quantities, modal restrictions, packaging,labelling, or exemptions;

32


(b) surface shipments in Europe - International Regulations Concerning theCarriage of Dangerous Goods by Road (ADR) and European AgreementsConcerning the International Carriage of Dangerous Goods by Rail (RID);

(c) shipment by water International Maritime Organization Rules (IMDG Code);and

(d) shipment by air International Civil Aviation Organization (ICAO) andInternational Air Transport Association (IATA) regulations.


6.15 SECTION 15 - REGULATORY INFORMATION

Describe any other regulatory information on the material that is not providedelsewhere In the MSDS.


The regulatory status of a material (including its Ingredients) under relevantAustralian health, safety and environmental legislation including:

(a) the Standard for the Uniform Scheduling ofDrugs and Poisons (SUSDP) establishedunder the Therapeutic Goods Act (1989)(as amended);

(b) any applicable prohibition ornotification/licensing requirements,including for carcinogens underCommonwealth, State or Territorylegislation;

(c) the Agricultural and Veterinary Chemicals Act 1988 and/orCommonwealth, State or Territory control of use legislation; and

(d) the Industrial Chemicals (Notification and Assessment) Act 1989; includinglisting on the Australian Inventory of Chemical Substances (A1CS).

6.15.2 ADDITIONAL INFORMATIONAdditional national and/or international regulatory information should be includedhere.

Poisons Schedule Number

If the substance has not beenscheduled, then the MSDS shouldstate that there is no PoisonsSchedule number allocated to thesubstance. For example, 'no PoisonsSchedule number allocated' and'none allocated'.

applicable

34


6.16 SECTION 16 OTHER INFORMATION

Provide information relevant to the preparation of the MSDS in this section.


Date of preparation or last revision of theMSDS.


(a) Provide a key/legend to abbreviations andacronyms used in the MSDS.

(b) Provide literature references.

(c) Provide sources for data.

Preparation and Revisions

When revisions are made to anMSDS, clearly indicate where thechanges have been made to theprevious version of the MSDS, withan explanation of the changes.

35

National Code of Practice ration of erial Safet Data Shee

7 REFERENCES

National Occupational Health and Safety Commission, 'National Model Regulationsfor the Control of Workplace Hazardous Substances' [NOHSC:1005(1994)] inControl of Workplace Hazardous Substances: National Model Regulations andNational Code of Practice, Australian Government Publishing Service, Canberra,1994, chtte://www.n m>.

National Occupational Health and Safety Commission, 'National Code of Practicefor the Control of Workplace Hazardous Substances' [NOHSC:2007(1994)] inControl of Workplace Hazardous Substances: National Model Regulations andNational Code of Practice, Australian Government Publishing Service, Canberra,1994, chttal/www.n .o Mation/NOMSCPubticationsguatext/(00-13-12,htra>,

National Occupational Health and Safety Commission, 'National Model Regulationsfor the Control of Scheduled Carcinogenic Substances [NOHSC:1011(1995)]', inControl of Workplace Hazardous Substances Part 2 Scheduled CarcinogenicSubstances: National Model Regulations and National Code of Practice, AustralianGovernment Publishing Service, Canberra, 1995,

Ion . .tIons/falltext/toc/H3-22.htm>.

National Occupational Health and Safety Commission, 'National Code of Practicefor the Control of Scheduled Carcinogenic Substances [NOHSC:2014(1995)]', inControl of Workplace Hazardous Substances Part 2 - Scheduled CarcinogenicSubstances: National Model Regulations and National Code of Practice, AustralianGovernment Publishing Service, Canberra, 1995,

oh I. au an 0 Siff°

National Occupational Health and Safety Commission, National Standard for theStorage and Handling of Workplace Dangerous Goods [NOHSC:1015(2001)],National Occupational Heath and Safety Commission, Sydney, 2001,

ht up it .1 5 I* Po

National Occupational Health and Safety Commission, National Code of Practicefor the Storage and Handling of Workplace Dangerous Goods[NOHSC:2016(2001)], National Occupational Heath and Safety Commission,Sydney, 2001, ch PA>

National Occupational Health and Safety Commission, National Code of Practicefor Labelling Hazardous Substances and Dangerous Goods in the Workplace[NOHSC:2012(1994)], National Occupational Health and Safety Commission,Canberra, 2002.

36

National Code of Practice for the Preparation y Data Sh

National Occupational Health and Safety Commission, 'Adopted National ExposureStandards for Atmospheric Contaminants In the Occupational Environment[NOHSC:1003(1995)]', in Exposure Standards for Atmospheric Contaminants Inthe Occupational Environment: Guidance Note and National Exposure Standards,Auslnfo, Canberra, 1995,<fttpithivimnalicv,gov.automsintOr:PPilon/Datal2nesaX1111591.6tandardsilodeZ111P.12>

National Occupational Health and Safety Commission, Approved Criteria forClassifying Hazardous Substances [NOHSC:1008(1999)], Auslnfo, Canberra,1999,<btud wv

National Occupational Health and Safety Commission, Guidelines for HealthSurveillance [NOHSC:7039(1995)], Auslnfo, Canberra, 1995,

,i

National Occupational Health and Safety Commission, List of DesignatedHazardous Substances [NOHSC:10005(1999)], Auslnfo, Canberra, 1999,cannLywww n 01

National Road Transport Commission and Federal Office of Road Safety, AustralianCode for the Transport of Dangerous Goods by Road and Rail, 6`h Edition,Australian Government Publishing Service, Canberra, 1998.

Australian Health Ministers' Advisory Council, Standard for the uniform schedulingof drugs and poisons No. 16, Australian Government Publishing Service, Canberra,1999.

NOTE: Reference should be made to the relevant Commonwealth, State andTerritory legislation, which has adopted these national references.

37


38

National Code of Practice for the Prtpatatton of Material Safety Data Sheets

APPENDIX 1 - 16 HEADER CHECKLISTThis Checklist outlines the necessary information to prepare the 11, header MSDS formatrequired under workplace hazardous substances and Dangerous Goods legislation A copy ofthis checklist ran he downloaded from cwww nottsc _goy au-P

Core information is listed In regular fount, edditional information IS in italics

SECTION 1 IDENTIFICATION OF THE MATERIALAND SUPPLIER

o Product (material) name

o Other names

o Recommended use

Supplier name/address/telephone no./Emergency phone number

SECTION 2 HAZARDS IDENTIFICATIONo Hazard classification, Including a statement of overall hazardous or dangerous nature

Risk phrase(s)

o Safety phrase(s)

SECTION 3 COMPOSITION/INFORMATION ONINGREDIENTS

SUBSTANCE

o Chemical identity of the pure substance

Common name(s), synonym(s)

o CAS Number(s)

MIXTURE

Chemical identity of ingredients

o Proportion of ingredients

ti CAS Number(s) for Ingredients

39


SECTION 4 FIRST AID MEASURES

a Description of necessary measures according to routes of exposure

Indication of medical attention and special treatment needed including description of mostimportant symptoms, acute and delayed

Additional information

0 Aggravated medical conditions caused by exposure

SECTION 5 FIRE FIGHTING MEASURES

o Suitable extinguishing media

a Hazards from combustion products

Special protective precautions and equipment for fire fighters


Hazchem Code

SECTION 6 ACCIDENTAL RELEASE MEASURES

Emergency procedures

o Methods and materials for containment and dean up

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

o Conditions for safe storage, including any Incompatibilities

SECTION 8 EXPOSURE CONTROLS/PERSONALPROTECTION

a National exposure standards

a Biological limit values

o Engineering controls

o Personal protective equipment

40

National Code of Practice for the Preparation of Material Safety Data Sh

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

o Appearance (colour, physical form, shape).

o Odour.

o pH.

Vapour pressure.

o Vapour density.

o Bolling point/range.

o Freezing/melting point (specify which).

Solubility (specify solvent, e.g. water).

o Specific gravity or density.

Information for Flammable materials, Including:

o Flash point and method of detecting flash point;

upper and lower flammable (explosive) limits in air; and

o ignition temperature.


o Specific heat value.

a Particle size.

Volatile organic compounds (VOC) content.

o Evaporation rate.

Viscosity.

o Percent volatile.

o Octanol/water partition coefficient.

Saturated vapour concentration (include reference temperatures).

Additional characteristics not noted above may also be provided if applicable to thematerial.

o Flame propagation or burning rate of solid materials.

Properties of both flammable and non-flammable materials that may initiate or uniquelycontribute to the intensity of a fire (e.g. Class 4 or Class 5).

o Potential for dust explosion.

n Reactions that release flammable gases or vapours.

O Fast or intensely burning characteristics.

Non-flammables that could contribute unusual hazards to a fire, such as strong oxidizingand reducing agents or peroxide formers.

CI Release of invisible flammable vapours and gases.

o Decomposition temperature.

41

National Code of Practi 0 the P e a ation of Material Safe Data Shee

SECTION 10 STABILITY AND REACTIVITY

o Chemical stability

Conditions to avoid

o Incompatible materials

Hazardous decomposition products

Hazardous reactions

SECTION 11 TOXICOLOGICAL INFORMATION

o Health effects from the likely routes of exposure

SECTION 12 ECOLOGICAL INFORMATION

Ecotoxicity

o Persistence and degradability

a Mobility


o Environmental fate (exposure)

Bioaccumulative potential

SECTION 13 DISPOSAL CONSIDERATIONS

Disposal methods and containers

o Special precautions for landfill or incineration

SECTION 14 TRANSPORT INFORMATION

UN Number

a UN Proper Shipping Name

Class and subsidiary risk

o Packing Group

Special precautions for user

Hazchem Code

42


SECTION 15 REGULATORY INFORMATIONo The regulatory status of a material (including its ingredients) under relevant Australianhealth, safety and environmental legislation.


O Additional national and/or international regulatory information.

SECTION 16 OTHER INFORMATIONDate of preparation or last revision of the MSDS


o Key/legend to abbreviations and acronyms used in the 11/41505.

o Literature references.

u Sources for data.

43

National Code of Pract ce fo he Pr ion of Material Safe Data Sheets

44


APPENDIX 2 - INFORMATION SOURCESINFORMATION SOURCES RELEVANT TO THE PREPARATION OF

MATERIAL SAFETY DATA SHEETS

1. HAZARD CLASSIFICATION (SEE ALSO CARCINOGENS)

List of Designated Hazardous SubstancesNOHSC (National Occupational Health & Safety Commission).

A database of the more common hazardous substances, which provides guidance on theappropriate Risk and Safety information for the MSDS.

Free at: <htto://www,Potsrmovmp/ONStpfprmatipid atabasesPlazardpusSukstardtsz,

Classification, hazardous substances, Risk phrases and Safety phrases.

Approved Criteria for Classifying Hazardous SubstancesNOHSC (National Occupational Health & Safety Commission).

This document outlines the approved Australian classification criteria used in determiningwhether a substance Is hazardous.

Free at: <hrio;//www,nolisc,nov,au/0115Informalion/NCaSCPublIcations/fulltext/sundards/noli5c1QUAS

2. NOHSC CODES OF PRACTICEThe following codes of practice provide useful information on hazardous substances andDangerous Goods.

Hazardous SubstancesNational Code of Practice for the Control of Workplace Hazardous Substances[NOHSC:2007(1994)].

Free at:

National Code of Practice for the Control of Scheduled Carcinogenic Substances[NOHSC:2014(1995)].

Free at: cm):

Dangerous GoodsNational Standard for the Storage and Handling of Workplace Dangerous Goods[NOHSC: 1015(2001)].

Free at: ctqp://www,nohsc.nov.au/ OP otOlpdf>

ns/ful x / 3-20,htm>

45


3. AUSTRALIAN STANDARDSThe Australian Standards for the following classes of Dangerous Goods form an Important partof the Dangerous Goods framework and contain useful guidance for the control of the hazardsassociated with these classes of Dangerous Goods.

Class 2 - GasesAS/NZS 1596

AS 1894

AS 2022

AS 2927

AS 3961

AS 4332

The storage and handling of LP gas.

Code of practice for the safe handling of cryogenic fluids.

SAA anhydrous ammonia code.

The storage and handling of liquefied chlorine gas.

Liquefied natural gas storage and handling.

Storage and handling of gases In cylinders.

Class 3 - Flammable and Combustible LiquidsAS 1940 The storage and handling of flammable and combustible liquids.

Class 5 - Oxidizing Agents and Organic PeroxidesAS 2714 The storage and handling of hazardous chemical materials - Class 5.2

substances (organic peroxides).

AS 4326 The storage and handling of oxidising agents.

Class 6 - Toxic SubstancesAS/NZS 4452 The storage and handling of toxic substances.

AS 4081 The storage, handling and transport of liquid and liquefied polyfunctionalisocyanates.

Class 8 - Corrosive SubstancesAS 3780 The storage and handling of corrosive substances.

Class 9 - MiscellaneousAS/NZS 4681 The storage and handling of Class 9 (miscellaneous) Dangerous Goods and

articles.

Mixed ClassesAS/NZS 3833 The storage and handling of mixed classes of Dangerous Goods in packages

and intermediate bulk containers.

Subscription details at: <taw: co

4. EXPOSURE STANDARDS

Exposure Standards for Atmospheric Contaminants in the OccupationalEnvironment.Exposure Standards Database.NOHSC (National Occupational Health & Safety Commission).

The Exposure Standards database is a searchable database providing the airborneconcentrations of individual chemical substances, which according to current knowledge shouldneither, impair the health of, nor cause undue discomfort to, nearly all workers. The exposurestandards serve as guides only.

46


Free at: <kw),

Exposure standards and hazardous substances.

5. PLAIN ENGLISH FACT SHEETS ON CHEMICALS

CHEMINFOCanadian Centre for Occupational Health and Safety.

Comprehensive summarized occupational health and safety information on chemicals written innon-technical language. Each profile provides a detailed evaluation of health, fire andreactivity hazards, as well as recommendations on topics such as handling and storage,personal protective equipment, accidental release, first aid, and hazard classifications,including WHMIS, OSHA and the European Union (EU). Records are designed for use by healthand safety professionals, employees working with chemicals, users and writers of MaterialSafety Data Sheets, fire fighters, and other emergency response personnel.

Subscription details at: rorfuct5/database,5Sierninfo.htmi>

Classification, first aid, hazardous substances, personal protective equipment, and storage.

New Jersey Right to Know Hazardous Substance Fact Sheets

These fact sheets provide brief and clear information on the identification, routes of exposure,health hazards, US exposure limits and workplace controls and practices for over 900hazardous chemicals under the New Jersey Right to Know legislation.

Free at: <httpJAvww.statemi.us/jvalth/eoli/rtkwetilrrkb$fslitm>

Exposure routes, first aid, and hazardous substances.

ToxFAQs

Agency for Toxic Substances and Disease Registry.

Searchable and browse able database of hazardous substances which provides answers to themost frequently asked questions about exposure to hazardous substances found aroundhazardous waste sites and the effects of exposure on human health.

Free at: <hulk./

NIOSH Pocket Guide

National Institute for Occupational Safety and Health (US).Provides general industrial hygiene information on several hundred chemicals/classes forworkers, employers, and occupational health professionals. The NPG does not contain ananalysis of all pertinent data, rather it presents key information and data In abbreviated ortabular form for chemicals or substance groupings (e.g. cyanides, fluorides, manganesecompounds) that are found In the work environment. The information In the NPG Includeschemical structures and formula, Identification codes, synonyms, exposure limits, chemical andphysical properties, incompatibilities and reactivities, measurement methods, respiratorselections, signs and symptoms of exposure, and procedures for emergency treatment.

Free at: <jittr)://www.cdc,novint0511/^

Exposure standards, personal protective equipment, and hazardous substances.

47


6. CARCINOGENS

CANCERLITNational Cancer Institute, US.CANCERLIT is a bibliographic database, which Indexes all areas of the international literatureon cancer from the 1960s to the present, providing references and summaries. It is updatedwith more than 8,000 records every month.

Free at: <

Carcinogens, mutagens, and toxicology.

IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicalsto Humans.International Agency for Research on CancerThese monographs are critical reviews of the literature on chemicals, industrial processes andIndustries associated with human cancer by the various IARC working groups.

IARC provides a searchable database of chemical agents and their evaluations as well as acomplete list of agents, mixtures and exposures and their classification available free at:

Summaries free at:

Full monographs available in print, CD-ROM and via Internet subscription.

Go to: <Carcinogens, classification, and hazardous substances.

CCRIS (Chemical Carcinogenesis Research Information System)CCRIS contains scientifically evaluated data derived from carcinogenicity, mutagenicity,tumour promotion, and tumour inhibition studies on over 2500 chemicals.

Free at: <hthph/ m Ch.. gyjsel-bin/sis/htmlqen7WEhn.>

Carcinogens, hazardous substances, and mutagens.

7. CHEMICAL IDENTIFICATION AND VERIFICATION

ChemlDplusNational Library of Medicine, US.

Chemlpp /us Is a free, web-based search system that provides access to structure andnomenclature authority flies used for the identification of chemical substances cited In NationalLibrary of Medicine (NLM) databases. ChemlDplus also provides structure searching and directlinks to many biomedical resources at NLM and on the Internet for chemicals of interest. Thedatabase contains over 349,000 chemical records, of which over 56,000 Include chemicalstructures, and Is searchable by Name, Synonym, CAS Registry Number, Molecular Formula,Classification Code, Locator Code, and Structure.

Free at: < psaditmi>

48

National Code of Practice for the Preparation of Material Safety Data S

Registry FileThe Registry File contains over 15 million unique chemical substance records Identified by theChemical Abstracts Service (CAS). Records contain Identifying information such as CASRegistry numbers, CA index names, commonly used synonyms and some trade names,polymer class terms, molecular formula and structure diagrams. The Registry file Is unique toSIN and the locator field indicates which other files (indexed by CAS numbers) on the STNsystem contain information on the chemical - thus it will indicate whether there is a record forthe chemical in RTECS, HSDB, Chem list, Med line, Toxline, Toxlit etc.

Subscription details at: chttp://www,cas.orq>

EL PERSONAL PROTECTIVE EQUIPMENT

HAZARDTEXTMicromedex.

HAZARDTEXT information to assist with the management of hazardous chemical incidents suchas spills or leaks toxicity, fire and explosion data, chemical reactivity, personal protectiveequipment and disposal guidelines. A good source of information on personal protectiveequipment.

Subscription details at:

Hazardous substances, chemical spills, emergency procedures, and personal protectiveequipment.

9. TOXICITY REVIEWSThe following sources provide full text reviews of the toxicity of chemical substances.

Environmental Health CriteriaInternational Programme on Chemical Safety.These criteria are reviews of environmental and toxicological literature on chemicals andphysical agents published as a joint venture of the United Nations Environment Programme,the International Labour Organization and the World Health Organization.

Free at: 41tWanwy,,instimorgL0005./ebs,htmt>

ECETOC

The European Centre for Ecotoxicology and Toxicology of Chemicals (ECETOC).

ECETOC publishes a range of reports varying in scope from those on specific chemicals (e.g,the Joint Assessment of Commodity Chemicals reports (JACC)) to those dealing with thefundamental principles underlying the various branches of science in toxicology andecotoxicology (e.g. monographs and technical reports). ECETOC publications are produced bytask forces composed of appropriate experts drawn from member companies and otherorganisations.

Subscription details at: cht

49


HSDB (Hazardous Substances Databank)National Library of Medicine, US.

HSDB focuses on the toxicology of potentially hazardous chemicals, It is enhanced withinformation on human exposure, industrial hygiene, emergency handling procedures,environmental fate, regulatory requirements, and related areas. All data are referenced andderived from a core set of books, government documents, technical reports and selectedprimary journal literature. HSDB is peer-reviewed by the Scientific Review Panel (SRP), acommittee of experts in the major subject areas within the data bank's scope. HSDB isorganised into individual chemical records, and contains over 4500 such records.

Free at: <bttp://toxnetnImmih.st

RTECSNational Institute of Occupational Safety St Health (NIOSH).Registry of Toxic Effects of Chemical Substances (RTECS) provides data for over 130,000chemicals including identifying information such as CAS number, chemical names andsynonyms. Toxicity data Include acute and chronic animal tests data, human data, skin andeye irritation data, Threshold Limit Values, IARC determinations, in vitro toxicity test data, USNational Toxicology Programme (NTP) and TSCA Inventory data. RTECS provides the originalreference for each value given.

Subscription details at: <

ToxlineNational Library of Medicine, US.Toxline indexes the literature on pharmacological, biochemical, physiological and toxicologicaleffects of chemicals and provides references and summaries of the literature, Tox line consistsof 16 different files, including TSCATS and Indexes journals, patents, government reports,criteria documents and meeting reports as well as the IARC (International Agency for Researchon Cancer) Monographs and the WHO/ILO/UN sponsored Environmental Health Criteria.

Free at: <http://toxnevIlm.flihmitv/Sql-OiniSiiis

Hazardous substances, toxicity testing, toxicology

(Ng>

10. GUIDANCE MATERIAL

Use and Selection of PPEHB 9-1994 Occupational personal protection, Standards Australia, 1994.

This Handbook provides guidance for occupational hygienists, and other occupational healthand safety practitioners, training personnel, workshop and laboratory supervisors, industrialrelations officers, union officials, members of occupational health and safety committees,students In occupational health and safety courses and other persons concerned withoccupational personal protection. This edition refers to more than 50 Australian Standards, aswell as many other international and overseas Standards.

Subscription details at: chttp://www.standard$.com.

National Code of Practice for the Control of Workplace Hazardous Substances[NOHSC:2007(1994)]. Section 12.16: The use of personal protective equipment as a controlmeasure. Note: Includes references to Australian Standards for specific types of PPE.

Free at: ch it ,[itn. to P,, .t50


APPENDIX 3 - GUIDE FOR SELECTING GENERICNAMES

1 INTRODUCTORY NOTE1.1 This guide is based on the procedure for naming hazardous substances (division of

substances into families) which Is described in EEC Council Directive 67/548/EEC.

1.2 The families are defined In the following manner:

(a) inorganic or organic substances whose properties are Identified by having acommon chemical element as their chief characteristic. The family name Isderived from the name of the chemical element. These families are Identifiedas in section by the atomic number of the chemical element (001 to 013); and

(b) organic substances whose properties are identified by having a commonfunctional group as their chief characteristic:

(i) the family name is derived from the functional group name; and

(11) these families are identified by the number convention found in section(601 to 650);

(c) sub-families bringing together substances with a common specific characterhave been added in certain cases.

2 ESTABLISHING THE GENERIC NAME2.1 General principles2.1.1 In selecting a generic name, the following approach is adopted:

(a) Identity of the functional groups and chemical elements present in themolecule; and

(b) determine the most important functional groups and chemical elements,which contribute to its properties.

2.1.2 The identified functional groups and elements taken Into account are the names offamilies and sub families,

2.2 Practical application2.2.1 After having conducted a search to see if the substance belongs to one or more

families or sub-families on the list, the generic name can be established in thefollowing way:

(a) If the name of a family or sub-family is sufficient to characterise the chemicalelements or important functional groups, this name will be chosen as thegeneric name.

Examples:

1,4-dihydroxybenzenefamily 604: phenols and derivativesgeneric name: phenol derivative.

butanols family 603alcohols and derivatives sub family: aliphatic alcoholsgeneric name: aliphatic alcohol

a 2-Isopropoxyethanolfamily 603: alcohols and derivativessub-family: glycolethersgeneric name: glycolether

5


methacrylatefamily 607: organic acids and derivativessub-family: acrylatesgeneric name: acrylate

(b) If the name of a family or sub-family is not sufficient to characterise thechemical elements of important functional groups, the generic name shouldbe a combination of the corresponding different family or sub-family names.

Examples:

lead hexafluorosilicatefamily 009: fluorine compoundssub-family: inorganic fluoridesfamily 082: lead compoundsgeneric name: inorganic lead fluoride

chlorobenzenefamily 602: halogenated hydrocarbonssub-family: halogenated aromatic hydrocarbonsfamily 017: chlorine compoundsgeneric name: chlorinated aromatic hydrocarbon

2,3,6-tricholorophenylacetic acidfamily 607: organic acidssub-family: halogenated aromatic addsfamily 017: chlorine compoundsgeneric name: chlorinated aromatic acid

1-chloro-1-nitropropanefamily 610: chloronitrated derivativesfamily 601: hydrocarbonssub-family: aliphatic hydrocarbonsgeneric name: chlorinated aliphatic hydrocarbon

tetrapropyl dithiopyrophosphatefamily 015: phosphorus compoundssub-family: phosphoric estersfamily 016: sulfur compoundsgeneric name: thiophosphoric ester

NB: In the case of certain elements, notably metals, the name of the family orsub-family may be indicated by the words 'organic' or 'inorganic'.

Examples:

dimercury chloridefamily 080: mercury compoundsgeneric name: Inorganic mercury compound

barium acetatefamily 056: barium compoundsgeneric name: organic barium compound

ethyl nitritefamily 007: nitrogen compoundssub-family: nitritesgeneric name: organic nitrite

sodium hydrosulfitefamily 016: sulfur compoundsgeneric name: Inorganic sulfur compound

52

National Code of Practu- i- for the Propel-anon of Material Sakti/ Data Sheets

APPENDIX 4 - CRITERIA AND FORM FORNOTIFICATION OF A GENERIC NAME

CRITERIA

1 Information to be provided by the manufacturer or importer of a hazardous substanceto NOHSC, where a Type II Ingredient is commercially confidential and a generic nameis used to protect the confidentiality of the ingredient.

2 The manufacturer or importer responsible for placing the hazardous substance on themarket shall provide evidence that the divulging of the chemical identity of thepreparation on the label or MSDS will place at risk the confidential nature of his/herproperty.

Specific factors which need to be considered In determining if a claim to NOHSC forcommercial confidentiality should be made Include:

(a) whether there would be significant detriment to the owner's business If theidentity of the substance was disclosed:

(I) If so, an explanation should be provided;

(b) whether the substance Is identified by other than trade or generic names inJournals or other public sources. For example, registers, public files ofgovernment agencies, patent applications etc;

(c) whether the substance has been granted confidential status in another country:

(i) if so, information on which countries should be provided;

(d) whether the substance has been Identified publicly in another country:

(I) if so, Information should be provided on why granting confidential status inAustralia will protect commercial interest;

(e) whether the substance has been patented:

(i) if so, information should be provided on why granting confidential status willprotect commercial interest;

(1) whether a public or private disclosure about the substance has been made outsidethe owner's organisation regarding the importation or manufacture of thesubstance;

whether the owner has taken precautions to prevent disclosure that the substancehas been manufactured or imported:

(i) if so, information should be provided on what measures have been taken;

(h) what the ramifications arising from loss of commercial confidentiality would be;

(I) whether it would be practicable for competitors to analyse and duplicate thesubstance;

whether failure to disclose the information would compromise the protection ofoccupational health, public health or the environment; and

(k) the benefits of having public access to this Information.

(g)

4 The generic name used on the label and MSDS must be the same.

5


5 The generic name used should contain enough information about the hazardoussubstance to ensure risk free handling.

6 In order to avoid multiple notifications, only one declaration of confidentiality is

necessary if a set of hazardous substances:

(a) contain the same hazardous ingredients in the same concentration range;

(b) have the same classification and labelling; and/or

(c) have the same intended uses.

7 The declaration of confidentiality must include all the elements provided for In thisform, not forgetting the product name of each substance. A single consistent genericname must be used to protect the chemical identity of the same Ingredient underconsideration in the case of all the substances referred to.

54


DECLARATION OF CONFIDENTIALITY

Name of person responsible for placing substance on market

Address:

Phone No: Fax No:

Email: Website:

Type II ingredients for which confidentiality is propo ed and the generic name.

Composition of hazardous substance (as per NOHSC Code of Practice for Preparation of MSDS[NOHSC:2011]

CAS NO

(or AICS* NO)

Chemical name

tGeneric

Name

Composition

e/o

NB: Where ingredients are assified provisionally, accomp nying information (bibliograp is references) should beprovided as evidence that the provisional classification takes account of all existing pertinent Information available onthe properties of the Ingredient.

't Australian Inventory of Chemical Substances,

t according to International Nomenclature & classification see the National Occupational Health and SafetyCommission's Approved Criteria for Classifying Hazardous Substances [ NOHSC: 1008(1999)),

Justification for the Confidentiality

Product name of the hazardous substance

Is the product name the same for use overseas and in all of Australia? Yes/No

If NO, specify the product name used overseas and in the different jurisdictions.

Overseas

(specify)

NSW VIC QLD SA

TAS NT ACT Commonw'lth WA

Classification of the hazardous substance(s) according to the National Occupational Health and SafetyCommission's Approved Criteria for Classifying Hazardous Substances [NOHSC:10013( 999)).

Intended uses for the hazardous substance(s)

Labelling of the substance(s) according to the National Occupational Health and Safety Commission'sNational Code of Practice for the Labelling of Workplace Substances [NOHSC:2012(2001)]. Mimi)example oflabel.

Material Safety Data Sheet(s) conforming to the National Occupational Health and Safety Commission'sNational Code of Practice for the Preparation of Material Safety Data Sheets [NOHSC:2011]. Attach SDS.

Signature: Date:__.....


56

National rode of Practice for the Preparation of Material Safety Data Sheets

APPENDIX 5 - SAMPLE CONFIDENTIALITYAGREEMENT FOR DISCLOSURE OF COMMERCIALLY

CONFIDENTIAL INFORMATIONIN CONSIDERATION of my being given access to confidential information concei ning [... insertdescription of confidential information Ln he released ], foi the put poses of [ insert thepurpose of the release of the confidential inforinghon...].

I hereby undertake as follows:

1. That, except insofar as Is necessary to achieve the above purpose, I will not divulge orcommunicate any of the confidential information to any other person.

2. That I will not use the confidential Information for any other purpose than the purposefor which the confidential information was released.

3. That I will provide a secure storage environment for the confidential information andwill institute and maintain an effective control of access to the confidential informationuntil such time as It is destroyed after the specific purpose for which the informationwas released has been completed.

GIVEN by me (signature of recipient)

(print name and position)

in the presence of (signature of witness)

(print name and position)

at (place of signature) on (date of signature)

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