8/20/2019 2nd PU Chemistry Jan 2015_0001.pdf

1/2

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RAMANACARA

DISTRICT

quESTroN

PAPER FOR

pREpAMTORy

EXAMTNATTON

JAN

-

2015

Subject

:

CHEMISTRY

Class: II

PUC

Subject

Code

:

34

i

Time

:

3

hrs

15

Min

Ma:r.

Marks

: 70

General

Inst{uctions:

1.

All

the

parts

are

compulsory

2.

Draw relevunt

diagram/tigure

wherever necessary

3.

Numerical problems should

be

solved

with

relevantformulae.

PART

-A

I Answer

the

following

questions:-

l0

x

L

=

l0

1.

Define

Molarity.

2. Define

Raoult's

law of

relative

lowering

of

vapour

pressure.

3.

Write

the

SI

unit of

molar

conductivity.

4.

Give

an

exErmple

for

zero

order

reactiion.

5. Wtite

the catalyst

used

in

the

decomposition

of

potassium

chlorate to

form

potassium

chloride

and

oxygen.

6.

Write

the composition

of

copper matte.

7.

Which

noble

gas

does not occur in

nature.

8.

Name

the Protein

present

in hair.

9.

Acetic

acid

is

soluble

in water?'S/hy

?

10.which

is the

nitrogenous

base

present

only in

RNA

but

not in

DNA.

PART

-

B

rr.

Answer

any

FIYE

of the

follorving

questions.

5 x z

=

la

1

1.

Calculate

the

number

of

atoms present

in

FCC

crystal

?

12.

What is corrosion

?

Name

one method

to prevent

it

?

13.Derive

an expression

for

half

life

period

of

a

first

order

reaction

?

i4.what

is the

Lanthanoid

contraction?

Mention

one

of it's

consequences?

t5.How

do

you

prepare

diethyl

ether

by

delrydration

of ethanol

?

t 6.Explain

Kolbe's

reaction.

17.What

are

food

preservatives

?

Give

an

example.

lS.What

are

antiseptics

?

Give

example.

PART

-

C

III.

Answer

any

FIYE

of the

following

questions.

5

x

3

=

15

19.How

is

aluminium

extracted

from

bauxite

ore

by Hall

*

Heroult

method.

20.For

the

manufacture

of

ammonia

by

Haber's

process

,

Write the

r

equation

and

conditions.

21.

A)

Give any

two

reasoRs

for the anomalous

behaviour

of

oxygen.

B)

Give one

example

for

Interhalogen

compound

.

22.How

is

potassium

dichromate prepared

from

chromite

ore

?

23.why

do

transition

elements

form

complex

compounds

? Name the

element

which

exhibits

highest

oxidation

state.

24.using

vBT

e4plain

for

Geometry

and

magnetic

properly

of

I

Ni(cN)+]2-

25.'Write the postulates

of wemers

theory

of co-ordination

compounds.

Question Paper for Preparatory Examination Jan - 2015

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8/20/2019 2nd PU Chemistry Jan 2015_0001.pdf

2/2

-

PART

-

D

IV.

Alswer

any

THREE

of

the

following

questions.

3

x

5

=15

26.A)

calculate

the packing

efficierrcyin

simple

cubic

lattice.

3

B)

write

the

differences

between

scottky

and

Frenkel

defects

.

2

27.A)

on dissolving2.3A

gram

of

a

solute

in

+o

gram

of

benzene,

the

boiling point

of

solution

was

higher

than

ttrat'if

Uenzene

by

0'g

lK.

the

value

of

Kb

for

benzene

is

2.53k.kg/mo1. Calculate

the

molar

mass

of

the

solute.

;

3

B)state

Henry's

law.

Write it,s

mathematicalfarm.

2

28.A)

Calculate

the

emf

of

the cell

in

which

the followi

ng

reaction

takes

place.

Ni(s

)+2

Ag.1o.

o o

t na;--*Ni2+(0.

0

8I\4)+2Ag1,;

GiventhatEo."ll

:1.05V.

v\v/

3

B)

A

galvanic

cell

after

mf i, recharged

by

passing

current

though

it.

What

tlpe

of cell

it

?

Give

* .*u*pl,

z

29.A)

The

rate

constant

of

a

reaction

double

when

the

temperature

changes

from

300k

to 310k.

calculate

the

activation

energy

of

the

reaction.

3

B)

what

is pseudo

first

order

reaction

?

Give

an

example.

z

30.A)

Give the

differences

between

physical

adsorption

and

chemical

adsorption

z

B)

What

is homogeneous

catalysis

?

Give

an

example.

z

C)

What is

emulsion.

1

V.

Answer

any

FOUR

of

the

following

i'RI

l

.I

G

l'

2'.

J

L

4x5=20

31.A)

Explain

SNI

mechanism

by taking

tertiary

butyl

bromide

as an

example.

3

B)

What is

fitting,s

reaction

?

Give

an

example.

z

32.A)

Explain

the

preparation

ofphenol

from

",r..r".

z

B)

Complete

the

reaction

CI{3CI+NaI

dry

acetone?

i

C)

Explain

Williamson's

ethercyrth.rG.

-

2

33.A)How

is

Benzoyl

chloride

converted

into

benzaldehyde

?

Name

the

reaction.

3

B)Explain

estrification

re4ction

with

an

example.

z

34.+)

Explain

Hoffmann

bromamid

reaction

*ith

* .*ample.

2

B)

Explain

carbylamines

reaction

with

an

example.

r

--'

2

C)Name

the

reagent

used

for

dehydrohalogenation.

1

35.A) Write

the

Haworth

structure

of

sucrosel

2

B)

j,

What

is

denaturation

of prorein.

1

ii.

Give

an

example

for

basic

x

amino

acid.

I

iii.

Give

an

example

for

non

reducing

sugar.

1

36'A)Name

the

monomers

used

in

the pr"p*ulion

of

polythene

and

natural

rubber.

z

B)

Give

an

example

for thermo

plastic

polymer.

1

C)

What

is

vulcanizationof

rubber.

z

i

?k ?k

rr

?k

rr,r

?k

?k

?k

?k *

r(

?k ?k ?k

?k

rr

?k

rr

?k ?k

* ?k*

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