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100206

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QA Summary

% RSD

2rc~cchlcrc~=thir:c' 2.21,4-Dichlorobutane1 3.6para-Bromofluorobezene? 10.3

In = 52 = 3

Dally Run Log

11/23/32 RO R01 R02_ R03 R04 R05

Method Blank XFC43 XPurgeable Stds. XInternal Std. X X • X X XSurrogate Stds. X X X X XGC/MS Std. X X X X XField Blank X

_ * 100207U

Page 3 of 3

ORIGINAL(Red)

5 UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION III

.„. .4? CENTRAL REGIONAL LABORATORY**"°' 839 BESTGATE ROAD 301-224-2740

ANNAPOLIS, MARYLAND 214C1 F7S-322-3752

DATE : December 30, 1982

SUBJECT: Osborne Dump: Soil Samples for VOCs by GC/MSSuperfund (821108-02-07, 09) 12/16/82 - 12/27/82

FROM : Rich Dreisch£pChemist '

TO : Daniel K. DonnellyChief, Lab Section

THRU: John Austin 3ATeam Leaderf Organic Analysis Unit

The above soil samples were analyzed by GC/MS for volatile organiccompounds. Standard procedures were followed for soil samples at mediumor low levels.

The samples were collected in non-secure cont^-ners un?-:<*"b

proper sample, containers are used, the nominal detection imit isgenerally 5 ppb (ng/g).

Samples 821108-05 and 06 exhibited no presence of volatile organics,wjn'le sample 821108-07 contained numerous unsaturated and saturatedaliphatic and cyclic hydrocarbons collectively estimated to be at thepercent levels of concentration.

»kcc: Patricia Krantz

. RD/jlm

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QA Sunmery

% RSD

BrcrrochloroTstharel 10.41,4-Dichlorobutane2 3.3Para-Bromofluorobenzenel 6.5

!n = 8 12/17/822n = 7 12/17/82

Dueterated Benzene and Toluene = Surrogate Spike Recovery

12/17/82 Assuming Std. Water Run = 100%

D6 63% +38 soil + stds (MB)D6 42% +26 soil only

DS 52% +40 soil + stds (MS)D8 32%+.27 soil only

1002J.fl

Page 3 of 4

ORIGINAL(Red)

Daily Run Log12/16/32 RO RIO Rll R12 R13 R14 R15 R15 R17

FC 43 csl XMethod E1?.r.'< X XField Blank XSurrogate Spike X XSurrogate Stds X X X X X X"X XInternal S t d X X X X X X X XGC/MS S t d X X X X X X X XAmtrak Runs X XAudit WP782 Con #4 XPurgeable Stds X

12/17/82 R30 R30.5 R31 R32 R33 R34 R35 R36 R37

FC 43 cal XRain water XPurgeable Stds XMethod Blank XSurrogate Spike X X X X X X XSurrogate Stds X X X X X ' X X XGC/MS Stds X X X X X X X XInternal S t d X X X X X X X X

Page 4 of 4

100211

~ UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION III

' +\ -.^ • CENTRAL REGiONAL. LABORATORY839 BESTGATE ROAD 301-224-27*0

ANNAPOLIS. MARYLAND 214Q1 FT5-922-3752

DATE : December 21, 19S2*

SUBJECT: GC/MS Analysis of Superfund Samples from Osborne Dump821108-02 - 07, 09, 11 - 13

FROM : John Austin (\.C\ Joseph L. SlaytonvfJChemist & Chemist U

TO : Daniel K. DonnellyChief, Lab Section

The samples were examined for the presence of organic compounds listed as"Base/Neutral" and "Acid" extractable priority pollutants using fusedsilica capillary column/gas chromatography/mass spectrometry.Concentrations of these compounds were determined using the relativeresponse of authentic standards to the internal standard. Detectionlimits are 10 ppm for solids and 1 ppb for liquids.

The samples were also examined for the presence of compounds in additionto those on the priority pollutant list. Tentative identification ofthsse ci 'pou'-i: v/c.3 "i^= o-i t'-.= co-pariso-: of ss^ple spectra to theEPA/NIH Mass Spectral Library. Concentrations for these compounds wereestimated based on the response of the internal standard.

JA/JLS:jr

cc: P. J. KrantzQAO, CRL

100212

Sample Description:

Lab # Description

821103-01 Osborne Durcp, Blank, Sta 01, Tag ?312022-./, /*_•__ ... •» _- ...11 r-,-- ''--j. C-- ^' -"-- £?*o"i; c - - *-î co-wMic 1,-fc.i. .f/, «u : i «ic;y ncok, ^w^. \._, iia Tjii.^^^ ^-- i i

-03 Osborne Dump, Wall Seep East, Sta 03, Tag 1312027 soil-04 Osborne Dump, Dry Pond Cores, Sta 04, Tag #312029 soil-05 Osborne Dump, Dry Pond Surface, Sta 05, Tag #312030 soil-06 Osborne Dump, Seep by Carcass, Sta 06, Tag #312031 soil-07 Osborne Dump, Cardborad Drum Soil, Sta 07, Tag #312032 soil-09 Osborne Dump, Pond One East, Sta 09, Tag #312033 soil-11 Osborne Dump, Blank, Tag #312023, 24, 25-12 Osborne Dump, Pond Three, Tag #312036, 37, 35-13 Osborne Dump, Swamp, Tag #312039, 40, 41

ORIGINAL(Red)

, ORIGINAL(Red)

BASE/NEUTRAL EXTRACTA3LE PRIORITY POLLUTANT COMPOU.ND DETECTION LIMITS

-Water Soil /SedimentParameter Gas I ppb rcg/kg (wet wt)

Acenaphthsne 83-32-9 1 10Acenaphthylene 208-96-8 1 10Anthracene 120-12-7 1 * 10Benzidine 92-87-5 1 10Benzo(a)Anthracene 56-55-3 1 10Benzo{b)fluoranthene 205-99-2 1 10Benzo(k)fluoranthene 207-08-9 1 10Benzo( a) pyrene 50-32-8 1 10Benzo (gh1) Perylene 191-24-2 1 10Bis(2-Chloroethoxy) Methane 111-91-1 1 10Bis(2-Chloroethyl) Ether 111-44-4 1 10Bis(2-Chloroisopropyl)Ether 39638-32-9 1 10Bis(2-Ethylhexyl) Phthalate 117-81-7 1 104-Bromophenyl Phenyl Ether 101-55-3 1 10n-Butylbenzylphthalate 85-6S-7 1 102-Chloronaphthalene 91-58-7 ' 1 1 04-Chlorophenyl Phenyl Ether 7005-72-3 1 10Chrysene 218-01-9 1 10Dibenzo(a,h)Anthracene 53-70-3 1 101,2-Dichlorobenzene 95-50-1 1 101,3-Dichlorobenzene 541-73-1 1 10l,4-D1chlorc-!:srz«?e 105-45-7 1 10

Diethylphthalate 84-66-2 1 10Dimethylphthalate • 131-11-3 1 10Di-n-Butylphthalate 84-74-2 1 102,4-Dinitrotoluene 121-14-2 1 102,6-Dinitrotoluen2 606-20-2 1 10Di-n-Octylphthalate 117-84-0 1 101,2-Diphenylhydrazine 122-66-7 1 10Fluoranthene 206-44-0 1 10Fluorene 86-73-7 . 1 10Hexachlorobenzene 118-74-1 1 10Hexachlorobutadiene 87-68-3 1 10Hexachlorocyclopentadiene 77-47-4 1 10Hexachloroethane 67-72-1 1 .10Isophorone 78-59 1 1 10Indeno(l,2,3-cd)Pyrene 193-39-5 1 10Naphthalene 91-20-3 • 1 10Nitrobenzene 98-95-3 1 10N-NHrosodimethylamine 62-75-9 1 10N-Nitrosodi-n-propylamine 621-64-7 1 10N-Nitrosodiphenylamine 86-30-6 1 10Phenanthrene 85-01-8 1 10Pyrene 129-00-0 1 101,2,4-Trichlorobenzene ' •- 120-82-1 1 10c

Page 3 of 26

100214

, ORIGINAL(Red)

ACID EXTRACTABLE PRIORITY POLLUTANT COMPOUND DETECTION LIMITS

Water Soil/SedimentPera-etsr Gas $ ppb no/kg (v;et v;t)

P-Chloro-m-cresoi 5S-50-? 1 102-Chlorophenol 95-57-8 1 102,4-Dichlorophenol 120-83-22,4-Dimethylphenol 105-67-94,6-Dinitro-o-cresol 534-52-12,4-Dinitrophenol 51-28-52-Nitrophenol • 88-75-54-Nitrophenol 100-02-7

10101010101010Phenol 108-95-2

Pentachlorophenol 87-86-5 1 102,4,6-Trichlorophenol 88-06-2 1 10

Page 4 of 26

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, ORIGINALU.S. Environmental Protection Agency, Central Regional Laboratory

Project Name: Osborne Dump (Superfund),ls, .;.,.rH . P«B Fyfr*-t ' Fsiinc.n

OTHER

Scan #

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Sample Number:

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COMPOUNDS


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Unknown Base Peak 57 m/e

Methyl ( 1 -methylethy 1 Jbenzene i somer

Methyl (1 -methyl ethyl )benzene isomer

Unknown Base Peak 57 m/e

Hydrocarbon (Best Matched

Estimated cone.ppb

821108-12

Estimated cone.ppb

1.3

1.4

2.8

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trace <1 (.9)

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2584 Unknown Base Peak 57 m/e ' 1.9

Page 7 of 26

100218

ORIGINAL) (Red)

U.S. Environmental Protection Agency, Central Regional Laboratory

Project Name: Osborne Dunp (Superfund) _______________________

iuic/": ocSc Extract 62 05- i

OTHER COMPOUNDS

Estimated cone.Scan f Tentative Identification ppb _____

710 2-Cyclohexen-l-ol 4.0

784 2-Cyclohexen-l-one 4.0«

1079 Unknown Base Peak 68 m/e 1.3

Page 8 of 26

100219

ORIGINAL» (Red)

U.S. Er.vircnnental Protection Agency, Central Regional Laboratory

Project Name: Osborne Dunp (Superfund)

SciT.plc 'i-.T-c;':

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Scan #

--•- £At,-£:t

COMPOUNDS


szr.K-r.

Estimated cone.ppb

None Detected

Sample Number:

OTHER

Scan #

934

Sample Number:

OTHER

Scan #

762

765

934

1050

1190

1570

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COMPOUNDS


£-Chlcro-cyclohexonol 57 m/e

Acid Extract

COMPOUNDS


Unknown With Base Peak 126 m/e


4-Chlorocyclohexanol

2-Bromochlorohexanol



S21108-12

Estimated cone.ppb

5.7

821108-13

Estimated cone.ppb

1.2

3.0

16

1.3

2.4

2.7

Page 9 of 26

100220

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ORIGINAL(Red)


Project Name; Osborne Dunp (Superfund)__________________________

SaiT.ple .\u~.bcf: Soil 821105-G2

OTHER COMPOUNDS

None Detected

rcg/kg wet wt.

OTHER COMPOUNDS

Estimated cone.Scan f Tentative Identification ppb ______

2541 Unknown With Base Peak 191 m/e 22


Sample Number: Soil 821108-03_______________________________________ mg/kg wet wt.

Estimated cone.ppb

Page 14 of 26

100225

ORIGINALI (Red)


Project Name; Osborne Dump (Super-fund)____________________

mg/kg wet wt.OTHER COMPOUNDS

Estimated cone.Scan $ Tentative Identification ppb______

872 Hydrocarbon (Best Matched2,4,6,-Trimethyl octane) 130

904 Hydrocarbon (Best Matched2,3,4-THmethyl pentane) 37


951 Hydrocarbon (Best Matched3-Methyl heptane) 15

1005 Hydrocarbon (Best Matched3,3-Dimethylhexane 61

3074 Unknown With Base Peak 252 m/e ' 12

Page 15 of 26

100226

ORIGINAL1 (Red)

13.S. Environmental Protection Agency, Central Regional Laboratory

Project Name: Osborne Dump (Superfund)_______________________

______________________________________mg/kg wet wt.OTHER COMPOUNDS

Estimated cone.Scan # Tentative Identification ppb____

817 Hydrocarbon (Best Matched3,4-Dimethyl octane) 20

866 Hydrocarbon (Best Matched1-Methyl-2-propylcyclohexone 24



907 Hydrocarbon (Best Matched3-Ethyl-2,3-dimethyl pentane) 81

913 Hydrocarbon (Best Matched5-Ethyl-2-methyl heptane 180

921 Hydrocarbon (Best Matched.3,3-Dimethyl hexane) 84

930 Hydrocarbon (Best Matched3,7-Dimethyl nonane) 83

938 Hydrocarbon (Best Matched2-Cyclohexyl-2-cyclohexyl-decane) 170


969 Hydrocarbon (Best Matched2,4-Dimethyl decane) 63

983 ClOH18 Isomer (Best MatchedDecahydro naphthalene) 46

990 ClOH20 Isomer (Best MatchedIsooctanol) 40

1000 Cio,H20 Isomer (Best Matched1-Methyl-3-propyl cyclohexane) 15

1003 C1QH20 Isomer (Best Matchedi^ ' l,2-Dimethyl-3-(l-methyl ethyl)

cyclopentane) 67

,- .. (Red)


Project Name; Osborne Durso (Superfund)_______________________

Sample Number: Soil 821103-05____________________________________________ing/kg wet wt.

OTHER COMPOUNDS

Estimated cone.Scan % Tentative Identification ppb_____

1017 Hydrocarbon (Best Matched4,6,8-Trimethyl-l-nonane) 70


1040 Hydrocarbon (Best Matched2,5,6-Trimethyl decane) 80

1048 Hydrocarbon (Best Matched3,3-Dimethyl hexane) • 27

1054 Hydrocarbon (Best Matched2,3,3-Trimethyl pentane) 49

1077 U-:-:••- "•-.•• E:si ?«fc S3 -/= 2*

1082 Unknown With Base Peak 43 ra/e 13

1088 Hydrocarbon (Best Matched4-0-Methyl ethyl heptane) 36

1109 Hydrocarbon (Best Matched3-Ethyl-2,7-dimethyl octane) • 24

1162 Hydrocarbon (Best Matched2,3,6-Trimethyl heptane) 45

1233 Hydrocarbon (Best Matched2,3,7-Trimethyl octane) 55



1330 Cyclohexane derrivative (Best MatchedOctylcyclohexane) 32

1353 Hydrocarbon (Best Matched2,6,11-Trifliethyl dodecane) 58

Page 17 of 26

100228

)U.S. Environ.~er.tal Protection Agency, Central Regional Laboratory '

Project Name: Osborne Durcp (Superfund)_______________________

SC.TPIs ii jr.;b£ r: 3o"i 1 C i. . i •«. »• - w C___mg/kg wet wt.

OTHER COMPOUNDS

Estimated cone.Scan # Tentative Identification ppb______


1445 0-decyl hydroxylamine 95



1553 Hydrocarbon (Best Matched4-Cyclohexyl-4-cyclohexyl tridecane) 16



1615 Unknown With Base Peak 97 m/e IS

1632 Hydrocarbon (Best Matched4,6-Dimethyl undecane) 94

1680 Hydrocarbon (Best Matched4,6-Dimethyl nonane) " 34

1686 Hydrocarbon (Best Matched2,7,10-Trimethyl decane) 140


1722 Hydrocarbon (Best Matched3-Ethyl-2,7-Dimethyl octane) 52


1843 Hydrocarbon (Best MatchedHexylcyclohexane) 10

1852 Hydrocarbon (Best Matched3',7-Dimethyl nonane) 27

CPage 18 of 26

100229

U.S. Environmental Protection Agency, Central

Project Name:

o i.T.p , £ 4i-~C 3 .' I

OTHER

Scan #

1858

1940

2094

2124

2185

2258

2358

2410

2542

Sample Number:

OTHER

Scan #

Osborne Dump (Superfund)«•--• i•v'w* 4 1

COMPOUNDS


Hydrocarbon (Best Matched3,7-Dimethyl nonane)


Unknown with Base Peak 83 m/e

Unkno'wn with Base Peak 57 m/e





0-decyl hydroxylamine

Soil

COMPOUNDS


ORIGINAL> (Red)

Regional Laboratory

r% 1 t -» ~, r* -O.1 1 ! O-^J

mg/kg wet wt.

Estimated cone.ppb

27

17

14

23

24

31

37

18

55

821108-06mg/kg wet wt.

Estimated cone.ppb

None Detected

Page 19 of 26

3.0Q230

) ORIGINALU.S. Environmental Protection Agency, Central Regional Laboratory

Project Name: Osborne Dump (Superfund)____________________________

ociTip i•; iij~w£r"I o"i i o^ img/kg wet wt.

OTHER COMPOUNDS

Estimated cone.Scan # Tentative Identification ppb_____

417 Hydrocarbon (Best Matched Heptane) 82

472 2-(Dimethylamine)ethanol 120

508 4-Pentenal 32

530 Methyl benzene 39

547 Dimethyl cyclohexane isomer 77

561 • Hydrocarbon (Best Matched1,1,3-Trimethyl cyclopentane) 24

568 Hydrocarbon (Best Matched1-Ethyl-2-methyl cyclopentane) 42

576 Octane 660

591 Hydrocarbon (Best Matched1,3-Dimethyl cyclohexane) 44

612 Hydrocarbon (Best Matched2,4-Dimethyl heptane) 110

622 Hydrocarbon (Best Matched2-Methyl octane) 690

637 Ethyl cyclohexane . 980

642 Trimethylcyclohexane isomer 1300

659 Hydrocarbon (Best Matched1-Methyl-2-pentyl cyclopropane) 320

665 Trimethyl cyclohexane isomer 1600

672 Hydrocarbon (Best Matched2,5,7-Trimethyl decane) 500*

"M

678 Hydrocarbon (Best Matched2-Methyl octane) • 3000

Page 20 of 26

100231

> ORIGINAL1 (Red)

U.S. Environmental Protection Agency, Central Regions! Laboratory

Project Name: Osborne Dump (Super-fund)_______________________

Sample Number: Soil 621103-07______________________________________ing/kg wet wt.

OTHER COMPOUNDS

Estimated cone.Scan # Tentative Identification ppb____

682 Ethyl benzene 130

689 Hydrocarbon (Best Matched3-Methyl octane) 3000

694 Dimethyl benzene isomer 570

704 Trimethyl cyclohexane Isomer 540

717 Hydrocarbon (Best MatchedDimethyl cyclooctane) 2000

734 Hydrocarbon (Best Matched Nonane) 13000

753 Ethyl-methyl cyclohexane isoner 340

759 Heptyl hexylether 2000



789 Propyl cyclohexane * 7000

798 Hydrocarbon (Best Matched3-Ethyl-2-methyl heptane) 4400

817 Hydrocarbon (Best Matched3-Ethyl-2-methyl heptane) 4600

825 Hydrocarbon (Best Matched4-Methyl nonane) 19000


867 Methyl-propyl cyclohexane Isomer 5900

883 Hydrocarbon (Best Matched decane) 32000

Page 21 of 26

100232

ORIGINAL» (Red)


Project' Name; Osborne Dunp (Siiperfund) _______________________

Scii £*: 1 1 OS-07mg/kg v/et wt.

OTHER COMPOUNDS . -

Estimated cone.Scan # Tentative Identification ppb ____

900 2-Ethyl-l-decanol 3200

913 Hydrocarbon (Best Hatched4-Methyl decane) 18000

921 5-Ethyl-2-methyl octane 3300

938 CinH20 Isomer (Best Matched1 -Methyl propyl) • 13000

960 Hydrocarbon (Best Matched5-Methyl decane) 6700



1001 Ethyl -dimethyl benzene isomer Trace <10

1018 Hydrocarbon (Best Matched Undecane) 16000

1021 ClOH20 Isomer (Best Matched2, 3-Dihydro-l -methyl -IH-indene) Trace <10


1062 Tetramethyl benzene. isomer 620

1076 Pentyl cyclohexane 1600

1120 (Dimethyl penyl) ethanone isomer Trace < 10

1125 1,2,3,4-Tetrahydro naphthalene 190

1143 Hydrocarbon (Best Matched Dodecane) 920


Page 22 of 26

100233

ORIGINAL» (Red)

U.S. Environmental Protection Agency, Central Regional Laboratory*

Project Narse: Osborne Dump (Superfund)________________________________________

Sc~ole Nutter: Soil 821103-07____________________________________ mg/kg wet wt7

OTHER COMPOUNDS

Estimated cone.Scan f Tentative Identification ppb______

1274 2,3-Dihydro IH-inden-l-one 30

1294 1-Methyl naphthalene 210

1316 1-Methyl naphthalene Trace <10



1388 l.T-Biphenyl 66

1420 Dimethyl naphthalene isomer 28

1437 Dimethyl naphthalene isomer 2i

1470 2H-Isolndole-l,3(2H)-dione isomer 35

1482 Hydrocarbon (Best Matched2,4,6-Trimethyl octane) t 55

1608 CinHi? (Best Matched3A,4,7,7A-Tetrahydro-4,17-methano-IH-indene) 50

1671 l,V(,l,3-Propanediyl)bisbenzene Trace <10

1885 0-decyl hydroxlamine 38

This complex sample contained approximately 50 additional peaks whichwere poorly resolved and were not identified (10-100 ppm)

Page 23 of 26

100234

ORlGWAl(Red)


Project Name: Osborne Dump (Superfund)_____.__1- «i.._u«.« . r_j' noiir" O£111. ic »1u-'*wCt • «"* i » w& I *',,v"*

mg/kg wet wt.OTHER COMPOUNDS

Estimated cone.Scan # Tentative Identification ppb_______


1317 1,3-Isobenzofurandione 34




2045 Unknown Hydrocarbon With Base Peak 57 m/e 13

2123 Hydrocarbon (Best Matched3,8-Dimethylundecane) 13

2"iS4 Unknown With Base Peak 57 m/e 31







Page 24 of 26

10023S

ORIGINAL(Red)

Surrogate Spike Recoveries

,02-Fluoro D6 D5 Nitro 2-Fluoro-phenol phenol benzene 1,1'-biphenyl

821108-11 54.6 32.4 61.4 72.9821108-12 32.3 23.9 81.9 " 84.0821108-13 1* 1* 86.6 85.3

lab Reagent Blank 53.5 31.6 77.9 81.6

Mean Expected Recovery 67 40 85 73from samples withno matrix effect

*Sample 821108-13 formed a red emulsion during the extraction procedurewhich may have interfered with the extraction of phenolic compounds.

Page 25 of 26

100236

ORIGINAL, '. • \ (Red)

Quality Control

i j 1. Each day before acquisition of any samples the mass spectrometer is* calibrated using FC43.

2. The calib-aticn is verified by obtaining the spectra of a knowncompound (DFTPP). All mass assignments and relative abundances arefound to be in acceptable ranges or the instrument is adjusted untilsuitable spectra of the known are obtained.

3. Immediately before analysis each sample is spiked with an internalstandard DIO-anthracene. All quantitation or estimates ofconcentration are made in comparison to the internal standard.

4. Mixed standards of extractable priority pollutants are analyzedbefore each group of samples. The relative response of eachcompound versus the internal standard is determined for use inquantitation.

5. For each group of samples extracted a method blank is prepared andexamined for laboratory introduced contamination.

6. Organic free water accompanies the samplers from the laboratory tothe field and 1s returned and stored with the samples. Such fieldblanks are examined for contamination.

7. All water samples were spiked with a mixture of surrogate compoundsprior to a'nalys1matrix effects.

?; \ prior to analysis. Recovery r•:•••- --.-'•-- •,-,• = - .:?--•••••-r ^." -•; cêc< for

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100237

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