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MORE ABOUT LATTICES
I. The reciprocal lattice
II. The crystallographic restrictionIII. Lattices and groups
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vector scalar products (dot product)
a b = |a| |b| cos()
Notice: a b = 0 if and onlyifa and b are perpendicular.
b
a
I. The reciprocal lattice
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|a| |b| cos()
= |a| x length of theprojection of b onto a
= |b| x length of theprojection of a onto b
|p|/|b| = cos()
|p| = |b| cos()
p =projection ofb onto a
b
a
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a b* = a* b = 0
a a* = b b* = 1
For a lattice L, with basis vectors a and b, the vectors a*and b* defined by
1
a*
b*
b
a
define a lattice L* calledthe reciprocal latticeof L.
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L*
L
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L* is the diffraction pattern of a lattice L.
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Lattice vector t = xa + yb +zc, x,y,z whole numbers
Reciprocal lattice vector t* = ha* + kb* + lc*, ditto
t * t = (t* = ha* + kb* + lc*) (xa + yb +zc)
= h a* xa + kb* yb + lc* zc
= hx + ky + lz
When t * t = 0, hx + ky + lz = 0,
which is the equation of the lattice plane (of L)
through the origin perpendicular to t * = [hkl]
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The lattice planes of L perpendicular to the vectort* = [hkl] in L* have equations
hx + ky + lz = whole number
and the coordinates of the lattice points in thoseplanes, expressed in terms ofa, b, and c, are triples
xyz, where x,y, and z are whole numbers satisfyingthe equation.
For every t* in L, each point of L lies in one of these
planes.
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00
00
The distance d between two successive lattice planes isthe projection of a point in that plane onto the reciprocallattice vector [hkl] perpendicular to it.
And a little algebra shows that 1/|[hkl]| = d.
That is, the length of a reciprocal lattice vector t* is
1/distance between the lattice points perpendicular to it.
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The greater the interplanar spacing, theshorter the reciprocal lattice vector in the
perpendicular direction.
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Notice that the greater the distance between planes,
the denser the distribution of lattice points in the planes.
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Bravais Law of Reticular DensityThe faces that appear on a crystal will be parallelto the lattice planes with greatest density.
That is, they will be parallel to the lattice planes withlargest interplanar distances.
Which means with shortest reciprocal lattice vectors.
Thus, according to Bravais, the crystal will have the
shape of the Voronoi cell of the reciprocal lattice.
Can we predict the shape of a crystal from its lattice?
And this agrees with reality surprisingly well!
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d is the minimumdistancebetween pairs ofpoints in thelattice
d
II. The so-called crystallographic restriction
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9060
49
B'
d
d
?
BAd BA
If A and B are lattice points, and we rotate B around A tolattice point B, the distance between B and B cannot be
less than d.
Thus the angle of rotation must be at least 60 degrees.
Which means the rotation can only be 2-,3-,4-,5- or 6- fold.
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!!!!!
BUT> d
72
7272
So 5-fold rotation is impossible in a 2D or 3D lattice!So are 7-, 8-, .. fold rotations. The only possibilitiesare 2, 3, 4, and 6.
This is the so-called crystallographic restriction.
However, successive 5-fold rotations imply acontradiction.
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But, it turns out, the crystallographic restriction is a
theorem about lattices, not a law of nature.
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III. Lattice groups
The symmetry group G of a lattice includestranslations and rotations, and in some
cases reflections and other operations.
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The subgroup T of translations (allthe
translations) is a normal subgroup of G.
(A subgroup generated by fewer than nindependent translations is notnecessarilynormal.)
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The site-symmetrygroups S of latticepoints are subgroups
of G.These subgroups areconjugate.
The number of cosets of T in G is |S|, the order ofthe site-symmetry groups S.
Thus thepoint groupP = G/T is a group of order
|S|, and G is a semi-direct product of T and S.