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D.K. Schroder, Semiconductor Device Theory - 1
MOS Capacitors
-VG1 VG2 VG3p-Type
-VG1
Accumulation
Layer
VG2
Depletion
Region
VG3
Inversion
Layer
s
s s
D.K. Schroder, Semiconductor Device Theory - 1
Energy Band Diagram
When metal, oxide, and
semiconductor are
brought together, we get
the band diagram below
This band diagram is very
important; it will be used
over and over to discuss
MOS devices
Energy:
Voltage or Potential: E
nerg
yV
olt
ag
e
EC
EV
EF
Ei
EV
EC
Electron Affinity
Work Function M
M O Sx
For SiO2: 9 eV
For Si: 1.1 eV
p-Type
GateOxide
D.K. Schroder, Semiconductor Device Theory - 1
Energy and Potential Band Diagrams
To discuss MOS devices we need to understand band diagrams
Band diagrams are at the heart of MOS devices; difficult to
understand
Consider the energy band diagram as a potential band diagram
The substrate is grounded and a positive gate voltage VG is
applied to the gate
Part of VG is dropped across the oxide, Vox, and part across the
semiconductor, known as the surface potential, s
En
erg
y
EC
EV
EF
Ei
x
Vo
ltag
e, P
ote
nti
al
VG
F
x
Vox
s
(Surface potential)
VG=V
ox+
s
D.K. Schroder, Semiconductor Device Theory - 1
Potential Band Diagram
Potentials
Semiconductor potential (intrinsic energy level): , taken as the reference potential = 0
Surface potential (intrinsic energy level at the surface): s
Fermi potential:
Oxide potential: Vox Gate voltage: VG VG = Vox + s
V,
VG
F
0 W x
Vox
s
tox
The Fermi level is flat, because there is no current
(assume the oxide is a perfect insulator)
i
AF
n
N
q
kTln
D.K. Schroder, Semiconductor Device Theory - 1
Band Diagrams
As the gate voltage is changed, the surface condition
changes from accumulation through depletion to
inversion
-VG1 VG2 VG3p-Type
-VG1
Accumulation
Layer
VG2
Depletion
Region
VG3
Inversion
Layer
s
s s
D.K. Schroder, Semiconductor Device Theory - 1
MOS-C Equations
The electron/hole densities are
Poissons equation is
where
Poissons equation can be written as
kTq
i
kTq
iFF ennenp /)(/)( ;
i
ADUUUU
os
i
os
AD
n
NNee
K
qn
K
NNnpq
dx
dFF
)()( )(
FFFF UUUUUUDi
eeeeLdx
Ud )(22
2
2
1
kTqUkTqUkTqU ssFF /,/,/
FF U
i
A
i
U
i
D
ii
osDi e
n
N
n
pe
n
N
n
n
nq
kTKL ;;
2 2
D.K. Schroder, Semiconductor Device Theory - 1
More Equations
Using the identity
gives
After integration
The electric field is then
FFFF UUUUUUDi
eeeeLdx
Ud )(22
2
2
1
Di
Fsss
L
UUF
q
kTU
dx
dU
q
kT ),(
2
2
2
2
1
dx
dU
dU
d
dx
Ud
)()(1 )(2
2
FFFFFF UUUUUUUU
Di
eeeeUeeLdx
dU
U
UUUUUU
Di
dxdU
dUeeeeLdx
dUd FFFF
0
)(
2
/
0
21
D.K. Schroder, Semiconductor Device Theory - 1
The F Function
The F function, F(U,UF), is proportional to the electric field
F(Us,UF) is proportional to the surface electric field
)1()1(),( sUU
s
UU
Fs UeeUeeUUFsFsF
102
103
104
105
-0.2 0 0.2 0.4 0.6 0.8 1
F (
Us, U
F)
s (V)
Acc
um
ula
tio
n
Depletion
Inv
ers
ion
The F function
is the normalized
electric field
D.K. Schroder, Semiconductor Device Theory - 1
Charge
The surface can be accumulated, depleted, or inverted, depending on the surface potential
Di
Fsosssoss
L
UUF
q
kTKUKQ
),(
1010
1011
1012
1013
-0.2 0 0.2 0.4 0.6 0.8 1
|Qs|/
q (
cm
-2)
s (V)
Accumulation
Depletion
Inversion
2F
0
5 1011
1 1012
-0.5 0 0.5 1 1.5
|Qs|/
q (
cm
-2)
VG (V)
Accumulation
Depletion
Inversion
VT (S = 2F)
2/~ seQs
ssQ ~
2/~ seQs
D.K. Schroder, Semiconductor Device Theory - 1
Surface Potential/Gate Voltage
The gate voltage can be changed over a wide range;
it is ultimately limited by oxide breakdown
The surface potential can only be varied over a range
approximately equal to the band gap potential EG /q
s (Accumulation)
s (Inversion)
s (Flatband)
EG/q
-0.3
-0.1
0.1
0.3
0.5
0.7
0.9
1.1
-4 -3 -2 -1 0 1 2 3 4Su
rface P
ote
nti
al
(V)
Gate Voltage (V)
2F
Inversion
DepletionAccumulation
Flatband
VT
EG
/q
Di
Fs
ox
osssFBG
ox
s
ox
GoxoxsFBG
L
UUF
q
kT
C
KUVV
C
Q
C
QVVVV
),(;;
D.K. Schroder, Semiconductor Device Theory - 1
Capacitance
Capacitance is mea-
sured by applying a dc
voltage to bias the
device and an ac voltage
to measure the
capacitance
The time varying ac
voltage changes the
charge on the gate and
also the charge in the
semiconductor
What charge in the
inverted semiconductor
responds? Holes or
electrons?
C and Q are most commonly
in units of F/cm2 and C/cm2!
VG
vG ~
p
Cox Cs
QG
Qn Qb
Q
x
Minority
electrons
Majority
holes
C = dQ/dV
D.K. Schroder, Semiconductor Device Theory - 1
Which Carriers Respond?
Deep Depletion
Initially: no inversion
layer; to form inversion
layer, ehp need to be
thermally generated
t
VG
p -Type
+ + +
- --
NA
Initially: inversion layer;
inversion electrons are
not able to follow the
applied voltage. Majority
holes can follow.
VG
p -Type
~
vg
f 0.01-1 MHz
++++++
High Frequency
Initially: inversion layer;
inversion electrons are
able to follow the applied
voltage vg by thermal
generation
VG
p -Type
~
vg
f
D.K. Schroder, Semiconductor Device Theory - 1
MOS Capacitor
Capacitance consists of
Cox: oxide capacitance
Cp: accumulation capacitance
Cb: bulk (space-charge region) capacitance
Cn: inversion capacitance
Cit: interface trap capacitance
Cox
Cp
Cb
Cn
Cit
p
D.K. Schroder, Semiconductor Device Theory - 1
MOS Capacitor
The capacitance is
G
G
dV
dQC
itnbp
s
its
ox
dQdQdQdQ
d
dQdQ
dVC
1
itnbpox CCCCC
C
11
1
sox
its
G
its
G
G
ddV
dQdQ
dV
dQdQ
dV
dQC
The charge is
)( itnbpitsG QQQQQQQ
This gives
D.K. Schroder, Semiconductor Device Theory - 1
MOS Capacitance
Accumulation
Cp >> Cox
Depletion
Cb Cox Cit
Inversion low frequency
Cn >> Cox
Inversion high frequency
Cb Cox
Cox
Accumulation
Cox
Cp
Cb
Cn
Cit
Cox
Inversion - lf
Cox
Cp
Cb
Cn
Cit
Cox
Cp
Cb
Cn
Cit
Cb
Cox
Inversion - hf
Cox
Cp
Cb
Cn
Cit
Cox
Cb
Cit
Depletion
D.K. Schroder, Semiconductor Device Theory - 1
Low-Frequency Capacitance
The capacitance from these equations is the low-frequency capacitance, because the assumption is that the electrons in the inversion layer are able to follow the ac gate voltage
),(
)]1()1([
2
Fs
UUUU
Di
osss
UUF
eeee
L
KUC
sFsF
soxox
sox
ox
oxs
oxs
CCC
C
CC
C
CC
CCC
/1
1
/1
0
0.2
0.4
0.6
0.8
1
-4 -2 0 2 4
C/C
ox
VG (V)
s = 2Fs = F
Flatband
Accumul'nStrong
Inversion
Depletion
Weak Invers.
s
s
s
ss
dU
dQ
kT
q
d
dQC
D.K. Schroder, Semiconductor Device Theory - 1
High-Frequency Capacitance
At high-frequencies, the inversion layer electrons are unable to follow the ac gate voltage
The slowly varying dc voltage allows an inversion layer to form
),(
)1/()1(1
2
,
FS
UUUU
Di
osShfS
UUF
eeee
L
KUC
SFSF
S F
S
U
F
UUU
FSS
U
dUUUF
Ueee
UUFUe
0
3),(2
11
),(/1
0
0.2
0.4
0.6
0.8
1
-4 -2 0 2 4
C/C
ox
VG (V)
lf
hf
D.K. Schroder, Semiconductor Device Theory - 1
Deep-Depletion Capacitance
In deep-depletion, the gate voltage is applied so rapidly that the inversion layer charge, Qn, has not yet formed, i.e., Qn = 0
The device will return to equilibrium due to thermal electron-hole pair generation
For high-quality devices, this can take minutes to hours
o
oxiFBG
oxdd
V
CQVV
CC
)/(21
0
0.2
0.4
0.6
0.8
1
-4 -2 0 2 4
C/C
ox
VG (V)
lf
ddhf
Such devices are
used in charge-
coupled devices
D.K. Schroder, Semiconductor Device Theory - 1
Gate Depletion
Poly-Si gates are doped to 1019 1020 cm-3
For positive gate voltages, the gate depletes slightly
Adds additional series capacitance, CG
Leads to overall capacitance reduction in inversion
0
0.2
0.4
0.6
0.8
1
-4 -2 0 2 4
C/C
ox
VG (V)
1020
3x1019
ND = 1019 cm-3
SoxGox
ox
CCCC
CC
//1
D.K. Schroder, Semiconductor Device Theory - 1
Non Ideal MOS Work Function
Work function difference, MS
qSM
M S
)(
MSFBV
i
AGFFFB
n
N
q
kT
q
EsubstrgateV ln
2)()(
F
S
M
E
V,
VG=V
FBE
C
EV
EF
VG= 0
D.K. Schroder, Semiconductor Device Theory - 1
SiO2 and SiO2/Si Interface
Si, Si/SiO2 interface, SiO2 bulk, and oxide defect structure
Si
D
B
Hydrogen
A
C
A: Si-Si Bond
(Oxygen Vacancy)
B: Dangling Bond
C: Si-H Bond
D: Si-OH Bond
Oxygen
Dangling Bond
This looks
really messy!
D.K. Schroder, Semiconductor Device Theory - 1
Oxide Charges/Interface Traps
Charge Type Location Cause Effect on Devices
(1) Interface SiO2/Si Dangling Junction Leakage Current
Dit(cm-2 eV-1) Trapped Interface Bonds Noise, Threshold Voltage
Nit, Qit Charge Shift, Subthreshold Slope
(2) Fixed Close to Si+ (?)
Nf, Qf Charge SiO2/Si Threshold Voltage Shift
(cm-2, C/cm2) Interface
(3) Oxide In SiO2 Trapped
Not, Qot Trapped Electrons Threshold Voltage Shift
Charge & Holes
(4) Mobile In SiO2 Na, K, Li
Nm, Qm Charge Threshold Voltage Shift
x x x x + + + +
+ +
(1) (2)
(3)(4) SiO2
Si
D.K. Schroder, Semiconductor Device Theory - 1
Non Ideal MOS Oxide Charge
Oxide charges, Qox, Qf The flatband voltage due to oxide charge density rox
(C/cm3) is
For a charge sheet Qox (C/cm2) at distance x1 in the oxide
For charge sheet Qf at x = tox
ox
ox
ox
t
ox
oxox
FBC
Q
t
xdxxx
t
x
CV
ox
1
0
1)()(1
r
oxox t
ox
oxox
t
ox
oox
FB dxxt
x
Cdxxx
KV
00
)(1
)(1
rr
ox
fFB
C
QV
D.K. Schroder, Semiconductor Device Theory - 1
Non Ideal MOS Interface States
Interface state charge, Qit
Interface state charge depends on surface potential
Hence VFB also depends on s
Acceptors
Donors
0
0+
ox
sitFB
C
QV
)(
EC
Ei
EFEV-
0
0
D.K. Schroder, Semiconductor Device Theory - 1
Non Ideal MOS
The flatband voltage due to all effects is
Oxide charges and interface state charges are quite low today and the oxide capacitance is high
Can neglect VFB components due to these charges
VFB mainly due to work function difference
ox
sit
t
ox
oxoxox
fMSFB
C
Qdxx
t
x
CC
QV
ox )()(
1
0
r
i
AGF
GMSFB
n
N
q
kT
q
E
q
EV ln
22
D.K. Schroder, Semiconductor Device Theory - 1
Displacement / Electric Field
Consider two solids, one with
dielectric constant K1 and one
with dielectric constant K2
They meet at a plane
The plane has a sheet charge
density of Q C/cm2
The perpendicular flux
density D is continuous
across the interface
For an oxide/semiconductor
interface with Q = 0
QDD )( 21
):( 1
111
fieldelectricnormal
KD o
+
+
+
+
+
+
+
D
Q
K1 K2
QKK oo 2211
2211:0 oo KKQFor ssoxoxKK
D.K. Schroder, Semiconductor Device Theory - 1
Electric Field
The electric field in the semiconductor is
The electric field in the oxide is
At the oxide-semiconductor interface
With Kox = 3.9, Ks = 11.7, s = ox/3
)()(;;0
xWK
qNxdx
K
qNd
K
qN
dx
d
os
Ax
Wos
A
os
A
oxCxdx
d
10 )(;
ox
s
oxsssoxox
K
KKK
s
0 W x
oxs = ox/3
D.K. Schroder, Semiconductor Device Theory - 1
Review Questions
What is the surface condition, i.e., p-type, n-type, etc, for s = F ?
Why is the surface potential excursion limited to approximately the band gap potential?
When an MOS-C is biased into depletion or inversion, can one measure the voltage drop across the semiconductor, s?
What is the Fermi level behavior in the oxide?
Why can s not be much higher than 2F? Why are inversion electrons unable to follow the high-
frequency applied signal?
Why does the high-frequency capacitance saturate for positive gate voltages?
Does the deep-depletion C/Cox VG curve apply for high or low frequencies?
Gate depletion adds to the oxide capacitance. What can be done to eliminate this effect?
By how much does VFB change from an n+ to a p+ gate?