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7/23/2019 8. GHS Hazard Comm Labeling & SDS - 1
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Globally Harmonized System of ClassicationGlobally Harmonized System of ClassicationSystem of Classication and Labelling of ChemicalsSystem of Classication and Labelling of Chemicals
(GHS)(GHS)
Hazard Communication :Hazard Communication :
Labelling and SDS (1)Labelling and SDS (1)
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 22
One of the objectives of the workOne of the objectives of the work
on the Globally Harmonizedon the Globally HarmonizedSystem (GHS) is the developmentSystem (GHS) is the developmentof aof a harmonized communicationharmonized communication
systemsystem ,, includingincluding abelling! Safetyabelling! Safetydata sheets (S"S)data sheets (S"S) and easilyand easilyunderstandable symbols! based onunderstandable symbols! based on
classification criteria developed forclassification criteria developed forthe GHS#the GHS#
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 33
GHSGHSHazard CommunicationHazard Communication : :
LabellingLabelling
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 44
Hazard CommunicationHazard CommunicationIn the GHS DocumentIn the GHS Document
Chapter 1.4 -Chapter 1.4 - Hazard Communication :Hazard Communication : LabellingLabelling
• Target audiencesTarget audiences• ComprehensibilityComprehensibility
• Comprehensibility testing methodologyComprehensibility testing methodology• TranslationTranslation• StandardizationStandardization• Use of non-standardized or supplementalUse of non-standardized or supplemental
informationinformation• Updating informationUpdating information• Con dential business information !C"#$Con dential business information !C"#$• TrainingTraining• %abelling procedures%abelling procedures
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 55
abellingabellingThe harmo !"e# $%$ em 'or ha"ar# (omm) !(a !o ! (*)#e$The harmo !"e# $%$ em 'or ha"ar# (omm) !(a !o ! (*)#e$
he a++ro+r!a e *a e**! oo*$ o (o .e% ! 'orma !o a o)he a++ro+r!a e *a e**! oo*$ o (o .e% ! 'orma !o a o)ea(h o' he ha"ar# (*a$$e$ a # (a e or!e$ ! he GHS/ea(h o' he ha"ar# (*a$$e$ a # (a e or!e$ ! he GHS/
The )$e o' $%m o*$, $! a* 0or#$ or ha"ar# $ a eme $ o herThe )$e o' $%m o*$, $! a* 0or#$ or ha"ar# $ a eme $ o herha ho$e, 0h!(h ha.e ee a$$! e# o ea(h o' he GHSha ho$e, 0h!(h ha.e ee a$$! e# o ea(h o' he GHS
ha"ar# (*a$$e$ a # (a e or!e$, 0o)*# e (o rar% oha"ar# (*a$$e$ a # (a e or!e$, 0o)*# e (o rar% oharmo !"a !o /harmo !"a !o /
abels communicate the hazard(s) according GHSabels communicate the hazard(s) according GHS
classification to target audiencesclassification to target audiences
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 11
abelling $abelling $ %arget audiences%arget audiences
Labels co mmunicate the hazard(s)Labels co mmunicate the hazard(s)according GHS classication to targetaccording GHS classication to targetaudiencesaudiences
&& or +*a(e- Co $)mer$- Emer e (% re$+o #er$- Tra $+or
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 66
abelling $abelling $ Tar e a)#!e (e$ 728Tar e a)#!e (e$ 728
-- Consumers Consumers The *a e* ! mo$ (a$e$ !$ *! e*% o eThe *a e* ! mo$ (a$e$ !$ *! e*% o e
he $o*e $o)r(e o' ! 'orma !o rea#!*%he $o*e $o)r(e o' ! 'orma !o rea#!*% a.a!*a *e o he (o $)mer/a.a!*a *e o he (o $)mer/
The *a e*, here'ore, 0!** ee# o eThe *a e*, here'ore, 0!** ee# o e$)''!(!e *% #e a!*e# a # re*e.a o$)''!(!e *% #e a!*e# a # re*e.a o
he )$e o' he +ro#)( /he )$e o' he +ro#)( /
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 99
abelling $ %arget audiences ( )abelling $ %arget audiences ( )
-- Emergency respondersEmergency responders Emer e (% re$+o #er$ ee# ! 'orma !oEmer e (% re$+o #er$ ee# ! 'orma !o
o a ra e o' *e.e*$/o a ra e o' *e.e*$/
To 'a(!*! a e !mme#!a e re$+o $e$, he%To 'a(!*! a e !mme#!a e re$+o $e$, he%ee# a(()ra e, #e a!*e# a # $)''!(!e *%ee# a(()ra e, #e a!*e# a # $)''!(!e *%
(*ear ! 'orma !o / Th!$ a++*!e$ ! he(*ear ! 'orma !o / Th!$ a++*!e$ ! hee.e o' a a((!#e #)r! ra $+or a !o ,e.e o' a a((!#e #)r! ra $+or a !o ,! $ ora e 'a(!*! !e$ or a 0or +*a(e$/! $ ora e 'a(!*! !e$ or a 0or +*a(e$/
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS :;:;
abelling $ %arget audiences ( )abelling $ %arget audiences ( )
-- Transport Transport The UN Re(omme #a !o $ o heThe UN Re(omme #a !o $ o he
Tra $+or o' Da ero)$ Goo#$, Mo#e*Tra $+or o' Da ero)$ Goo#$, Mo#e*re )*a !o $, (a er 'or a 0!#e ra e o're )*a !o $, (a er 'or a 0!#e ra e o'
ar e a)#!e (e$ a* ho) h ra $+orar e a)#!e (e$ a* ho) h ra $+or0or er$ a # emer e (% re$+o #er$ are0or er$ a # emer e (% re$+o #er$ are
he +r! (!+a* o e$/ O her$ ! (*)#ehe +r! (!+a* o e$/ O her$ ! (*)#eem+*o%er$, ho$e 0ho o''er or a((e+em+*o%er$, ho$e 0ho o''er or a((e+#a ero)$ oo#$ 'or ra $+or or *oa# or#a ero)$ oo#$ 'or ra $+or or *oa# or) *oa# +a( a e$ o' #a ero)$ oo#$) *oa# +a( a e$ o' #a ero)$ oo#$! o or 'rom ra $+or .eh!(*e$, or 're! h! o or 'rom ra $+or .eh!(*e$, or 're! h(o a! er$/(o a! er$/
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS ::::
%arget audiences needs have been identified%arget audiences needs have been identified
Workplace -Workplace - Em+*o%er$ a # 0or er$ ee# o o0 he ha"ar#$ $+e(!'!( o heEm+*o%er$ a # 0or er$ ee# o o0 he ha"ar#$ $+e(!'!( o he
(hem!(a*$ )$e# a # or ha #*e# ! he 0or +*a(e, a$ 0e** a$ ! 'orma !o a o)(hem!(a*$ )$e# a # or ha #*e# ! he 0or +*a(e, a$ 0e** a$ ! 'orma !o a o)he $+e(!'!( +ro e( !.e mea$)re$ re )!re# o a.o!# he a#.er$e e''e( $ hahe $+e(!'!( +ro e( !.e mea$)re$ re )!re# o a.o!# he a#.er$e e''e( $ ham! h e (a)$e# % ho$e ha"ar#$/m! h e (a)$e# % ho$e ha"ar#$/
Consumers -Consumers - The *a e* ! mo$ (a$e$ !$ *! e*% o e he $o*e $o)r(e o'The *a e* ! mo$ (a$e$ !$ *! e*% o e he $o*e $o)r(e o'! 'orma !o rea#!*% a.a!*a *e o he (o $)mer/ The *a e*, here'ore, 0!** ee# o! 'orma !o rea#!*% a.a!*a *e o he (o $)mer/ The *a e*, here'ore, 0!** ee# o
e $)''!(!e *% #e a!*e# a # re*e.a o he )$e o' he +ro#)( /e $)''!(!e *% #e a!*e# a # re*e.a o he )$e o' he +ro#)( /
Emergency responders - labels, placards :Emergency responders - labels, placards : Emer e (% re$+o #er$ ee#Emer e (% re$+o #er$ ee#! 'orma !o o a ra e o' *e.e*$/ To 'a(!*! a e !mme#!a e re$+o $e$, he% ee#! 'orma !o o a ra e o' *e.e*$/ To 'a(!*! a e !mme#!a e re$+o $e$, he% ee#a(()ra e, #e a!*e# a # $)''!(!e *% (*ear ! 'orma !o / Th!$ a++*!e$ ! he e.ea(()ra e, #e a!*e# a # $)''!(!e *% (*ear ! 'orma !o / Th!$ a++*!e$ ! he e.eo' a a((!#e #)r! ra $+or a !o , ! $ ora e 'a(!*! !e$ or a 0or +*a(e$/o' a a((!#e #)r! ra $+or a !o , ! $ ora e 'a(!*! !e$ or a 0or +*a(e$/
Transport - labels, placards, transport documents :Transport - labels, placards, transport documents : TThe UNhe UNRe(omme #a !o $ o he Tra $+or o' Da ero)$ Goo#$, Mo#e* Re )*a !o $,Re(omme #a !o $ o he Tra $+or o' Da ero)$ Goo#$, Mo#e* Re )*a !o $,(a er 'or a 0!#e ra e o' ar e a)#!e (e$ a* ho) h ra $+or 0or er$ a #(a er 'or a 0!#e ra e o' ar e a)#!e (e$ a* ho) h ra $+or 0or er$ a #emer e (% re$+o #er$ are he +r! (!+a* o e$/ O her$ ! (*)#e em+*o%er$,emer e (% re$+o #er$ are he +r! (!+a* o e$/ O her$ ! (*)#e em+*o%er$,
ho$e 0ho o''er or a((e+ #a ero)$ oo#$ 'or ra $+or or *oa# or ) *oa#ho$e 0ho o''er or a((e+ #a ero)$ oo#$ 'or ra $+or or *oa# or ) *oa#+a( a e$ o' #a ero)$ oo#$ ! o or 'rom ra $+or .eh!(*e$, or 're! h+a( a e$ o' #a ero)$ oo#$ ! o or 'rom ra $+or .eh!(*e$, or 're! h(o a! er$/(o a! er$/
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS :2:2
La e**! <ro(e#)re$La e**! <ro(e#)re$*llocation of abel elements*llocation of abel elements+eproduction of the symbol+eproduction of the symbol+eproduction of the Hazard ,ictograms+eproduction of the Hazard ,ictogramsSignal -ordsSignal -ords
Hazard StatementsHazard Statements,recautionary statements and pictograms,recautionary statements and pictograms,roduct and supplier identification,roduct and supplier identification.ultiple hazards and precedence of information.ultiple hazards and precedence of information
*rrangements for presenting the GHS label*rrangements for presenting the GHS labelelementselementsSpecial labelling arrangementsSpecial labelling arrangements
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS :3:3
La e* E*eme $La e* E*eme $ <!( o ram$<!( o ram$
,ictogram for flammable li/uidin the 01 .odel +egulations(Symbol$ 2lame$ 3lack or -hite43ackground#
,ictograms prescribed by the GHSshould have a black symbol on awhite background with a red framesufficiently wide to be clearlyvisible#
GHS <!( o ram UN RTDG <!( o ramGHS <!( o ram UN RTDG <!( o ram
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS :4:4
La e**!La e**! <!( o ram$<!( o ram$ :: Convey health, physical &Convey health, physical &
environmental hazard information.environmental hazard information.
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HAZARD COMMUNICATION -LABELLING & SDS :5
Oxidizers Organic Peroxides
Flammables Self Reactives Pyrophorics Self-Heating Emits Flammable
Gas
Explosives Self Reactives Organic Peroxides
Acute Toxicity (severe) Corrosives Gases underpressure
Carcinogen Respiratory Sensitizer Reproductive Target Organ Toxicity Mutagenicity
Environmental Toxicity
Iriitant Dermal Sensitizer Acute To xicity
(harmful )
GHS Pictograms
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HAZARD COMMUNICATION -LABELLING & SDS :1
UN Dangerous Goods Transport Labelling
Class 1Explosives
Class 1Div. 4
Class 1Div. 5
Class 1Div. 6
Class 2, Div. 2.1Flammable gases
Class 2Div. 2.2, Non
ammablenon toxic g as
Class 2Div. 2.3Toxic g ases
Class 3 Flammable liquids
Class 4 ,Div.4.1Flammable
solids
Class4,Div.4.2Spontaneouscombustion
Class 4, Div. 4.3Emit ammable gasesin contact with water
Class 5 ,Div.5.1Oxidizingsubstances
Class 5 ,Div.5.2Organicperoxides
Class 6 ,Div.6.1Toxicsubstances
Class 8Corrosivesubstances
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS ::
La e**!La e**!
Signal Words:Signal Words: ““ Danger”Danger” oror “Warning”“Warning”
are used to emphasis h azard andare used to emphasis h azard andindicate the relative of severity of theindicate the relative of severity of thehazard.hazard.
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS :6:6
La e**!La e**!
Hazard Statements:Hazard Statements: Standard phrased assigned to a hazard class a ndStandard phrased assigned to a hazard class a ndcategory to specied the nature of the hazard.category to specied the nature of the hazard.
Example : Acute Toxicity OralExample : Acute Toxicity Oral
= (a e or% :(a e or% :“ “ Fatal if swallowed “ Fatal if swallowed “
= Ca e or% 2Ca e or% 2“ “ Fatal if swallowed ” Fatal if swallowed ”
= Ca e or% 3Ca e or% 3“ “ Toxic if swallowed” Toxic if swallowed”
= Ca e or% 4Ca e or% 4 “ “ Harmful if swallowed” Harmful if swallowed”
= Ca e or% 5Ca e or% 5
“ “ Maybe harmful if swallowed” Maybe harmful if swallowed”
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HAZARD COMMUNICATION -LABELLING & SDS :9
Label elements Example Acute toxicity,oral)
(GHS Recommendation Annex )
Ca e or%:
Ca e or%2
Ca e or%3
Ca e or%4
Ca e or%5
Da er
>a a* !'$0a**o0e#
Da er
>a a* !'$0a**o0e#
Da er
To?!( !'$0a**o0e#
ar !
Harm')* !' S0a**o0e#
NoS%m o*
ar !
Ma% eharm')* !'
$0a**o0e#
Signal &ord
'ictograms
Hazard
statements
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HAZARD COMMUNICATION -LABELLING & SDS 2;
Label elements ExampleCarcinogenicity)
(GHS Recommendation Annex )
Ca e or% :A Ca e or% :B Ca e or% 2
Da er
Ma% (a)$e (a (er 7state route of
exposure if it isconclusively proventhat no other routesof exposure causethe hazard )
Da er
Ma% (a)$e (a (er 7state route of
exposure if it isconclusively proventhat no other routesof exposure causethe hazard )
ar !
S)$+e( e# o' (a)$!(a (er 7 state route of
exposure if it isconclusively proventhat no other routesof exposure causethe hazard )
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HAZARD COMMUNICATION -LABELLING & SDS 2:
Label elements Example 3 Aquatic toxicity,acute)
(GHS Recommendation Annex )
Ca e or% : Ca e or% 2 Ca e or% 3
ar !
@er% o?!( o a )a !(
*!'e
No $%m o*
No $! a* 0or#
To?!( o a )a !( *!'e
No $%m o*
No $! a* 0or#
Harm')* o a )a !( *!'e
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 2222
La e**!La e**!
Precautionary S tatementsPrecautionary Statements
GHS label should include appropriateprecautionary information
GHS document contains e5amples ofprecautionary statements which can be used
%he intent is to harmonize precautionarystatements in the future as *nne5 to6,urple book7
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -
LABELLING & SDSLABELLING & SDS 2323
abellingabellingPrecautionary statements:Precautionary statements:
Measures to minimize or prevent adverseMeasures to minimize or prevent adverseeffects.effects.
Example : (GHS Recommendation Annex 3)Example : (GHS Recommendation Annex 3)
* # # #* # # # *ccident caused by ingestion*ccident caused by ingestion
8f swallowed! seek medical advice immediately8f swallowed! seek medical advice immediatelyand show this container or label#and show this container or label#
8f swallowed! rinse mouth with water (only if the8f swallowed! rinse mouth with water (only if the person is conscious)#person is conscious)#
8f swallowed! and the victim is conscious and8f swallowed! and the victim is conscious andalert! induce vomiting immediately! as directedalert! induce vomiting immediately! as directed
by medical personnel#by medical personnel#
S b&9ommittee of :5perts on the Globall Harmoni ed S stem of 9lassification and abelling of 9hemicals
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HAZARD COMMUNICATION -LABELLING & SDS 24
*90%: %O;898%< & O+* 9H*,%:+ #')
Hazard 9ategory Signal -ord Hazard Statement : Da er >a a* !' $0a**o0e#
2 Da er >a a* !' $0a**o0e#
'recautionary Statements
're(ention )esponse Storage *isposal )eference
+ ,eep out ofreach of
children.
+ *o not eatdrin or smo e&hen using thisproduct.
+ /ash handsthoroughly
after handling.
0(oid allcontact .
# S/0%%2/3*:#mmediately call a'2#S2 C2 T)2%C3 T3)5 doctor/physician .
Sho&container5label5Safety *ata Sheet&hen possible.
#nduce (omiting !ifconscious$.- if knowledge of thechemical indicatesthisaction is notcontraindicated.
6i(e &ater5nothingtodrin .
6i(e a slurry ofacti(ated charcoal- if ingestion of a
+ Store locked up# "ispose of thismaterial and itscontainer to ### #/// ! a((or#a (e 0! h*o(a*re !o a* a !o a*! er a !o a*re )*a !o 8/
+ if likely to be usedby the generalpublic#
== +ead directions>label>Safety "ata Sheetbefore use#
Specific treatment isurgent (see ### on thislabel)/// re'ere (e oS)++*eme a* >!r$ A!#I $ r)( !o /!' !mme#!a e a#m! !$ ra !oo' a !#o e !$ re )!re#/
== if likely to be usedcommercially /
Symbol S ull andcrossbones
Sub&9ommittee of :5perts on the Globally Harmonized System of 9lassification and abelling of 9hemicals(?@@ >A)
":B: O,.:1% O2 G08"*19: 2O+ 8., :.:1%*%8O1 ,recautionary Statements (,S) Draft !
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -
LABELLING & SDSLABELLING & SDS 2525
abellingabelling
Product IdentierProduct Identier
1ame or number used for a hazardousproduct on a label or in the S"S#
0ni/ue means by which the substance ormi5ture can be identified within theparticular use setting
01 proper shipping name also to be usedon the package when substance or mi5turecovered by the 01 +%"G
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -
LABELLING & SDSLABELLING & SDS 2121
La e**!La e**!
Supplier Identication:Supplier Identication: The name, address an d telephone sh ould beThe name, address an d telephone sh ould beprovided on the label.provided on the label.
Supplemental Information:Supplemental Information:non-harmonized informationnon-harmonized information ..
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 22
La e* e?am+*eLa e* e?am+*e
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 2626
Precedence for the allocation of symbolsPrecedence for the allocation of symbols(1)(1)
For substances an d mixtures co veredFor substances and mixtures coveredbyby the UN Recommendations on thethe UN Recommendations on the
Transport of Dangerous Goods, ModelTransport of Dangerous Goods, ModelRegulationsRegulations ,, the p recedence ofthe p recedence ofsymbols for physical hazards shouldsymbols for physical hazards should
follow the rules offollow the rules of the UN Modelthe UN ModelRegulationsRegulations ..
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 2929
Precedence for the allocation of symbolsPrecedence for the allocation of symbols(2)(2)
For health hazards the following principles ofFor health hazards the following principles ofprecedence a pply:precedence a pply:(a) if the (a) if the Skull and crossbonesSkull and crossbones applies,applies,
thethe Exclamation markExclamation mark should not appear;should not appear;
(b) if the (b) if the Corrosive symbolCorrosive symbol applies,applies,thethe Exclamation markExclamation mark should not appearshould not appearwhere it is used for skin or eye irritation;where it is used for skin or eye irritation;
(c) if the (c) if the Health hazard symbolHealth hazard symbol appears forappears forrespiratory sensitisation, therespiratory sensitisation, the ExclamationExclamation
markmark should not appear where it is u sedshould not appear where it is u sedfor skin sensitisation or for skin or eyefor skin sensitisation or for skin or eyeirri tation.irri tation.
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 3;3;
Precedence for the allocation of symbolsPrecedence for the allocation of symbols(3)(3)
Precedence for allocation of signalPrecedence for allocation of signalwords If the signal wordwords If the signal word ‘‘DangerDanger ’’
applies, the signal wordapplies, the signal word ‘‘WarningWarning ’’ should not appear.should not appear.
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 3:3:
Precedence for the allocation of symbolsPrecedence for the allocation of symbols
Skin>:ye irritationSkin>:ye irritation
Skin sensitization!Skin sensitization! Skin>:ye irritationSkin>:ye irritation
"*1G:+"*1G:+ -*+181G-*+181G
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HAZARD COMMUNICATION -LABELLING & SDS 32
6lobal Haze7y
6lobalethylene( !Hazanol
C"S #o$ ! !
*anger
Hazard statements Combustible li%uid
Harm&ul i& s'allo'ed o ic in contact 'ith s*inCause serious s*in burns and eye
irritationCause serious eye irritation
Supplier: +nited #ations Corp$ Ltd$ 1!1, -eace ".e$ ene.a, S'itzerland 0L: 1 213 44 444 5"6: 1 213 44
444
6HS%abel
'roduct
identi er
'ictograms
Hazardstatements
Signal&ord
Supplieridenti cation
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 3333
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 3434
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 3535
GHSGHSHazard CommunicationHazard Communication : :
ContinueContinue
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Globally Harmonized System of ClassicationGlobally Harmonized System of ClassicationSystem of Classication and Labelling of ChemicalsSystem of Classication and Labelling of Chemicals
(GHS)(GHS)
Hazard Communication :Hazard Communication :Labelling and SDS ( )Labelling and SDS ( )
GHS ,+*9%89* %+*8181G &GHS ,+*9%89* %+*8181G & * %echnical *ssistance for * %echnical *ssistance for C1&+98 membersC1&+98 membersDakarta! .arch ? E ?A! ?@@FDakarta! .arch ? E ?A! ?@@F
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 33
GHSGHSHazard CommunicationHazard Communication : :
Sa&ety Data Sheet (SDS)Sa&ety Data Sheet (SDS)
d h
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 3636
Hazard Communication in the GHSHazard Communication in the GHSDocumentDocument
Chapter 1.5, Hazard communication :Chapter 1.5, Hazard communication : Safety dataSafety datasheets (SDS)sheets (SDS)
Role of the SDS in the GHSRole of the SDS in the GHS
Criteria for determining whether an SDSCriteria for determining whether an SDS
should be producedshould be produced
GG eneral guidance for compiling a S DSeneral guidance for compiling a S DSSDSSDS formatformat
SDSSDS contentcontent
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 3939
Role of the SDS in the GHSRole of the SDS in the GHS
SDS $ho)*# +ro.!#e (om+rehe $!.eSDS $ho)*# +ro.!#e (om+rehe $!.e! 'orma !o a o) a (hem!(a* $) $ a (e or! 'orma !o a o) a (hem!(a* $) $ a (e orm!? )re 'or )$e ! 0or +*a(e/m!? )re 'or )$e ! 0or +*a(e/
Bo hBo h employersemployers a #a # workersworkers )$e ! a$ a)$e ! a$ a$o)r(e o' $o)r(e o' ! 'orma !o a o)! 'orma !o a o) ha"ar#$ha"ar#$ ,,! (*)#! e .!ro me a* ha"ar#$, a # o! (*)#! e .!ro me a* ha"ar#$, a # oo a! a#.!(e oo a! a#.!(e o $a'e % +re(a) !o $/$a'e % +re(a) !o $/
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 4;4;
SDSSDS Target AudiencesTarget Audiences
SDS +ro.!#e$ a !m+or a $o)r(e o'SDS +ro.!#e$ a !m+or a $o)r(e o'! 'orma !o 'or ar e a)#!e (e$ ! 'orma !o 'or ar e a)#!e (e$
- or +*a(e 7em+*o%er a # 0or er8or +*a(e 7em+*o%er a # 0or er8- Co $)mer$Co $)mer$- Emer e (% re$+o #er$ 7! (*)#! <o!$o Ce re$8Emer e (% re$+o #er$ 7! (*)#! <o!$o Ce re$8- Tra $+or er$ = TREM (ar#Tra $+or er$ = TREM (ar#- Tho$e ! .o*.e# ! he +ro'e$$!o a* )$e o' <e$ !(!#e$Tho$e ! .o*.e# ! he +ro'e$$!o a* )$e o' <e$ !(!#e$
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 4:4:
T)38 Card
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 4242
Criteria for determining whether aCriteria for determining whether aSDS should be producedSDS should be produced
SDS $ho)*# e +ro#)(e# 'or a** $) $ a (e$SDS $ho)*# e +ro#)(e# 'or a** $) $ a (e$a # m!? )re$ 0h!(h mee he harmo !"e#a # m!? )re$ 0h!(h mee he harmo !"e#(r! er!a 'or +h%$!(a*, hea* h or e .!ro me a*(r! er!a 'or +h%$!(a*, hea* h or e .!ro me a*ha"ar#$ ) #er he GHS a # 'or a** m!? )re$ha"ar#$ ) #er he GHS a # 'or a** m!? )re$0h!(h (o a! $) $ a (e$ ha mee he0h!(h (o a! $) $ a (e$ ha mee he(r! er!a 'or (ar(! o e !(, o?!( o re+ro#)( !o(r! er!a 'or (ar(! o e !(, o?!( o re+ro#)( !o
or $+e(!'!( ar e or a $%$ em!( o?!(! % !or $+e(!'!( ar e or a $%$ em!( o?!(! % !(o (e ra !o $ e?(ee#! he () -o'' *!m! $ 'or(o (e ra !o $ e?(ee#! he () -o'' *!m! $ 'orSDS $+e(!'!e# % he (r! er!a 'or m!? )re$/SDS $+e(!'!e# % he (r! er!a 'or m!? )re$/
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When is a S DS required?When is a S DS required?
SDS should be produced for allSDS should be produced for allsubstancessubstances and and mixturesmixtures which meetwhich meet
the harmonized criteria under the GHSthe harmonized criteria under the GHSand for all mixtures which containand for all mixtures which containsubstances t hat meet the GHS criteriasubstances t hat meet the GHS criteriaexceeding theexceeding the c ut-off limitscut-off limits 'or ea(h'or ea(hha"ar# (*a$$/ha"ar# (*a$$/
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 4444
General guidance for compiling a S DSGeneral guidance for compiling a S DS
:/5/3/: C) -o'' .a*)e$ (o (e ra !o *!m! $:/5/3/: C) -o'' .a*)e$ (o (e ra !o *!m! $SDS $ho)*# e +ro.!#e# a$e# o he e er!(SDS $ho)*# e +ro.!#e# a$e# o he e er!(
() -o'' .a*)e$ (o (e ra !o *!m! $ ! #!(a e#() -o'' .a*)e$ (o (e ra !o *!m! $ ! #!(a e#
! Ta *e :/5/: ! Ta *e :/5/:
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 4545
9ut&off values>9oncentration limits for each health andenvironmental hazard class
Hazard 9lassHazard 9lass
9ut&off value >9ut&off value >
9oncentration imit9oncentration imit A() e To?!(! % A() e To?!(! % ≧ ≧ :/;:/;
S ! Corro$!o Irr! a !oS ! Corro$!o Irr! a !o ≧ ≧ :/;:/;
Ser!o)$ #ama e o e%e$ e%e !rr! a !oSer!o)$ #ama e o e%e$ e%e !rr! a !o ≧ ≧ :/;:/;
Re$+!ra or% S ! Se $! !"a !oRe$+!ra or% S ! Se $! !"a !o ≧ ≧ :/;:/;
.utagenicity$ 9ategory '.utagenicity$ 9ategory ' 7 7 @#'@#'
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@#'@#'
+eproductive %o5icity+eproductive %o5icity ≧ ≧ @#'@#'
S+e(!'!( Tar e Or a S%$ em!( To?!(! %S+e(!'!( Tar e Or a S%$ em!( To?!(! %7S! *e E?+o$)re 7S! *e E?+o$)re +epeat :5posure)+epeat :5posure)
≧ ≧ :/;:/;
Ha"ar#o)$ o he A )a !( E .!ro meHa"ar#o)$ o he A )a !( E .!ro me ≧ ≧ :/;:/;
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 4141
Safety Data SheetsSafety Data Sheets,rimarily workplace use,rimarily workplace use
'A heading format agreed! similar to the 8 O and'A heading format agreed! similar to the 8 O and8SO format! but8SO format! but sections ? and reversedsections ? and reversed
.inimum additional information specified! where.inimum additional information specified! whereapplicable or available! under the relevantapplicable or available! under the relevant
headingsheadings
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 44
S"S format (')S"S format (')%he information in the S"S should be presented using the%he information in the S"S should be presented using the
following 'A headings in the order following 'A headings in the order !.e e*o0 !.e e*o0
:/:/ I#e !'!(a !oI#e !'!(a !o2/2/ Ha"ar#7$8 !#e !'!(a !oHa"ar#7$8 !#e !'!(a !o3/3/ Com+o$! !o ! 'orma !o o ! re#!e $Com+o$! !o ! 'orma !o o ! re#!e $4/4/ >!r$ -a!# mea$)re$>!r$ -a!# mea$)re$5/ >!re-'! h ! mea$)re$5/ >!re-'! h ! mea$)re$
1/ A((!#e a* re*ea$e mea$)re$1/ A((!#e a* re*ea$e mea$)re$/ Ha #*! a # $ ora e/ Ha #*! a # $ ora e
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 4646
SDS format (2)SDS format (2)
# ,hysical and chemical properties# ,hysical and chemical properties
'@# Stability and reactivity'@# Stability and reactivity ''# %o5icological information''# %o5icological information '?# :cological information'?# :cological information ' # "isposal considerations' # "isposal considerations ' # %ransport information' # %ransport information ' # +egulatory information' # +egulatory information 'A# Other information'A# Other information
* S"S is not a fi5ed length document# %he length of the S"S should* S"S is not a fi5ed length document# %he length of the S"S shouldbe commensurate with the hazard of the material and thebe commensurate with the hazard of the material and theinformation available#information available#
MinimuminformationforaSDScontent( 1)MinimuminformationforaSDScontent( 1)
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 4949
Minimum information for a SDS content ( 1)Minimum information for a SDS content ( 1)
:: Identication of the
substance o r mixture
and of the supplier
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% he GHS/
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 5;5;
Minimum information for a SDS content ( 2)Minimum information for a SDS content ( 2)
3 Composition/
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NOTE >or ! 'orma !o o
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0h!(h are hem$e*.e$ (*a$$!'!e#a # 0h!(h (o r! ) e o he
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.i5ture%he chemical identity and
concentration or concentration ranges of all ingredients which
are hazardous within themeaning of the GHS and are
present above their cut&off levels#
MinimuminformationforaSDScontent( 3)MinimuminformationforaSDScontent( 3)
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 5:5:
Minimum information for a SDS content ( 3)Minimum information for a SDS content ( 3)
4 First aid measures De$(r!+ !o o' e(e$$ar% mea$)re$, $) #!.!#e# a((or#! o he
#!''ere ro) e$ o' e?+o$)re, !/e/! ha*a !o , $ ! a # e%e (o a(a # ! e$ !o /
Mo$ !m+or a $%m+ om$ e''e( $, a() e a # #e*a%e#/
I #!(a !o o' !mme#!a e me#!(a* a e !o a # $+e(!a* rea me ee#e#, !' e(e$$ar%/
5 Fire-ghting measures S)! a *e 7a # ) $)! a *e8 e? ! )!$h! me#!a/
S+e(!'!( ha"ar#$ ar!$! 'rom he
(hem!(a* 7e/ / a )re o' a % ha"ar#o)$ (om )$ !o +ro#)( $8/
S+e(!a* +ro e( !.e e )!+me a # +re(a) !o $ 'or '!re'! h er$/
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 5252
Minimum information for a SDS content ( 4)Minimum information for a SDS content ( 4)
1 Accidental releasemeasures
<er$o a* +re(a) !o $, +ro e( !.e e )!+me a # emer e (%
+ro(e#)re$/E .!ro me a* +re(a) !o $/Me ho#$ a # ma er!a*$ 'or
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or !o*o !(a* *!m! .a*)e$/ A++ro+r!a e e ! eer! (o ro*$/I #!.!#)a* +ro e( !o mea$)re$,$)(h a$ +er$o a* +ro e( !.ee )!+me /
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 5353
Minimum information for a SDS content ( 5)Minimum information for a SDS content ( 5)
9 Physical and chemicalproperties
A++eara (e 7+h%$!(a* $ a e, (o*o)r8/O#o)r/O#o)r hre$ho*#/
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 5454
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(hem!(a* a # o?!(o*o !(a*
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 5555
Minimum information for a SDS content ( 7)Minimum information for a SDS content ( 7):2 Ecological information E(o o?!(! % 7a )a !( a #
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De$(r!+ !o o' 0a$ e re$!#)e$a # ! 'orma !o o he!r
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 5151
Minimum information for a SDS content (8)Minimum information for a SDS content (8):4 Transport information UN )m er/
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 55
A4.2.5 Other information requirementsA4.2.5 Other information requirements
I a##! !o o he m! !m)m ! 'orma !oI a##! !o o he m! !m)m ! 'orma !o
re )!reme $ 7$ee A4/2/4/28, he SDS ma% a*$ore )!reme $ 7$ee A4/2/4/28, he SDS ma% a*$o(o a! a##! !o a* ! 'orma !o / here a ma er!a*(o a! a##! !o a* ! 'orma !o / here a ma er!a*ha$ a##! !o a* re*e.a a # a.a!*a *e ! 'orma !oha$ a##! !o a* re*e.a a # a.a!*a *e ! 'orma !oa o) ! $ a )re a # or )$e, ha ! 'orma !oa o) ! $ a )re a # or )$e, ha ! 'orma !o$ho)*# e ! (*)#e# ! he SDS 7$ee A4/3/:1 'or$ho)*# e ! (*)#e# ! he SDS 7$ee A4/3/:1 'or')r her a#.!(e o a##! !o a* ! 'orma !o')r her a#.!(e o a##! !o a* ! 'orma !ore )!reme $8/re )!reme $8/
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 5656
UnitsUnits
N)m er$ a # )a ! !e$ $ho)*# eN)m er$ a # )a ! !e$ $ho)*# ee?+re$$e# ! ) ! $ a++ro+r!a e o he re !oe?+re$$e# ! ) ! $ a++ro+r!a e o he re !o! o 0h!(h he +ro#)( !$ e! $)++*!e#/ I! o 0h!(h he +ro#)( !$ e! $)++*!e#/ I
e era*,e era*, hehe I er a !o a* S%$ em o' U ! $I er a !o a* S%$ em o' U ! $7SI8 $ho)*# e )$e#/7SI8 $ho)*# e )$e#/
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 5959
Internationally-recognisedInternationally-recognisedstandards for SDSstandards for SDS ILO Recommendation 177ILO Recommendation 177 19901990 EU SDS Directive 91/155/EECEU SDS Directive 91/155/EEC 19911991
USA Standard ANSI Z 400.1USA Standard ANSI Z 400.1 19931993ISO SDS Standard 11014-1ISO SDS Standard 11014-1 19941994
Guidance on the preparation of SDS is availableGuidance on the preparation of SDS is availableas Annex 4 toas Annex 4 to “GHS Purple book”“GHS Purple book”
GHS S"S (S*2 %< "*%* SH %)GHS S"S (S*2:%< "*%* SH::%)
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HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 1;1;
GHS S"S (S*2:%< "*%* SH::%)GHS S"S (S*2:%< "*%* SH::%)2O+.*%2O+.*%
'#'# 8dentity of manufacturers> suppliers8dentity of manufacturers> suppliers?#?# Hazard (s) identificationHazard (s) identification
## 9omposition>information on ingredients9omposition>information on ingredients## 2irst aid measures2irst aid measures## 2ire fighting measures2ire fighting measures
A#A# *ccidental release measures*ccidental release measures
I#I# Handling and storageHandling and storageF#F# :5posure control>personal protection:5posure control>personal protection
## ,hysical and chemical properties,hysical and chemical properties'@#'@# Stability and reactivityStability and reactivity''#''# %o5icological information%o5icological information
'?#'?# :cological information:cological information' #' # "isposal consideration"isposal consideration' #' # %ransport information%ransport information' #' # +egulatory information+egulatory information'A#'A# Other informationOther information
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A A CO CA OHAZARD COMMUNICATION
GHSGHSHazard CommunicationHazard Communication
Thank youThank you