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    Sing le-Screw Ext ruders and Bar r ie r Screw s1

    Peter Fischer, Johannes Wortberg

    1 Extended version of a paper presented at the VDI conference on "The Single Screw Extruder Basics and

    System Optimization", published by VDI-Verlag Dsseldorf, 1997 Kunststofftechnik

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    2

    The development of

    s ing le -sc rew p las t i f i ca t ing

    extruders

    In the USA, extruder

    development was - and still is -

    largely characterized by

    machines with smooth barrels.

    Further development has tended

    to concentrate more on the

    screws than anything else, with

    so-called 'barrier screws'

    screws in which the solid

    material is kept separate from

    the melt in the melting section

    at the center of attention.

    Although the first barrier screw

    was actually invented in Europe

    in 1959 by Maillefer, most of the

    further development work and

    the practical application of this

    principle took place in the USA.

    The first USA patent was not

    applied for until 1961 by Geyer

    from Uniroyal [1].

    Even today, smooth-bore

    extruders with barrier screws are

    superior to grooved barrel

    extruders for many applications,

    provided the conveying stability

    is adequate. This applies in

    particular to applications in

    which fluctuating proportions of

    recycled or regrind material

    have a disruptive influence on

    the normal conveying

    characteristics of the solid

    material. In such cases,

    extrusion is likely to be more

    stable with a smooth-bore

    extruder.

    In Europe, the development of

    extruders with heat-separated

    grooved bushes in the feed

    section began at the end of the

    fifties and beginning of the

    sixties. Grooves in the barrels to

    increase barrel friction and

    assist conveying of the solid

    material had been tried out long

    before then. They were,

    however, not enough to process

    the newer high-molecular weight

    HDPEs in powder and grit form.

    This specifically European

    phenomenon on the raw

    materials side has come from

    the systematic analysis and

    development of the grooved

    bush principle.

    Extruders with grooved bushes

    were initially operated with the

    conventionally flighted three-

    section screws commonly used

    in Europe. To have better

    control of the melt temperatures,

    vented screws were later

    developed, and, to improve the

    melt homogeneity, were

    subsequently equipped with

    shearing/mixing sections [2].

    One problem nevertheless

    remained: very high pressures

    at the end of the feed section

    and, as a result, considerable

    wear and tear on the screw and

    barrel.

    Fig. 1: Development of extruder screws in the USA and Europe

    a = 3-zone comp ression screwb = Uniroyal screwc = Maillefer screwd = compression screw with

    UCC(Maddock) mixere = compression screw with

    pin mixerf = barrier screwg = barrier screw with UCC

    (Maddock) m ixerh = 5-zone decompression screw

    with shearing/mixing devicei = compression screw

    with pin mixerk = no-compression screw with/

    shearing/mixing devicel = barrier screw with

    shearing/mixing device

    m = high-output barrier screwwith shearing/mixing section

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    3

    The development of extruder

    technology is basically reflected

    in the development of the

    screws . For thirty years,

    development teams went their

    different ways in the USA and

    Europe until, at the beginning of

    the nineties also due to

    increasing globalization the

    directions of development

    began to converge again.

    Combining the grooved bush

    principle with barrier screws is

    the logical step to optimize

    extrusion technology [3].

    Screw des igns and

    se lec t ion c r i te r ia

    As already mentioned, the

    choice of a suitable extrusion

    system (conventional or

    grooved bush concept)

    depends on the particular

    application. After all, the

    design of the screwdetermines the quantitative

    and the qualitative properties

    of the extrudate. In practice,

    different screw lengths have

    become established for

    different applications. For

    applications in extrusion blow

    molding, for example,

    relatively short extruders (L:D

    = 20:25) are used, whereas

    in other applications, such as

    film and pipe extrusion,

    extruders with longer screws

    (L:D 30) are generally

    employed. As a result, the

    way the total screw length is

    divided up into the "feed and

    compression" and "melting

    and homogenizing" sections

    can vary considerably.

    First of all, for a specific

    application, a decision has to be

    taken as to what proportion of

    the total screw length should be

    reserved for homogenizing the

    plastificated melt. This question

    can nowadays only be

    answered on the basis of

    experience or following an

    appraisal of the demands made

    on the melt quality. Even

    specifying the necessary melt

    quality can sometimes cause

    problems. Complying with an

    imprecisely defined melt quality

    can necessitate not only

    homogenizing elements on the

    screw (dynamic mixing

    sections), but also static mixing

    elements.

    The various constructions of

    homogenizing elements will be

    dealt with in more detail later.

    While a wide variety of screw

    concepts are still in use, current

    developments are concentrating

    very much on barrier screws.

    For this reason, this report will

    concentrate on such models

    while taking a wider look at the

    topic of single-screw extrusion.

    Fig. 2 shows schematically the

    basic concept of barrier screws

    for different lengths of extruders,

    with and without barrel venting.

    The concept is the same for new

    extruders as it is for the

    retrofitting of existing machines.

    The evaluation of a barrier

    plastificating section is generallycarried out by looking at the

    differences in the pitch and flight

    depths and the design of the

    feed section and outlet area of

    the barrier flights. Both North

    American and European barrier

    Fig. 2 Basic concept of barrier screws

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    4

    screw developments have

    moved in the direction of

    designs which conform, to a

    very large extent, to the princip le

    of the Dray and Lawrence screw.

    The characteristic features of

    these screws are that, through

    elevations in the respective

    pitches of the main flight of the

    screw and the barrier flight, a

    sufficiently wide channel is

    created in the solids channel

    this encourages plastificating

    and that, through a variable

    adjustment of the flight depth

    profiles, the melt temperature

    curve can also be adjusted, with

    the aim being to keep the melt

    temperatures as low as

    possible. Although barrier screw

    designs still exist today with a

    solids channel that is not sealed

    off, the only way of ensuring

    complete melting in the barrier

    plastificating section is to use

    solids channels with a 'dead-

    end' groove (Fig. 3).

    The front of the barrier flight at

    the beginning of the barrier

    plastificating section can be

    designed with the melt channel

    closed at the rear end or with an

    open melt channel. In this case,

    even if we assume that

    unmelted material enters the

    melt channel, complete

    plastification is nevertheless

    ensured by the end of the

    barrier section because of the

    long residence time in the melt

    channel. A detailed description

    of different barrier screw

    concepts, including their

    characteristic features, is given

    in [4].

    For extrusion applications in

    which relatively high extrusion

    temperatures are required (e.g.

    paper coating), the screw

    geometries must be modified by

    making the flight depths in the

    melt-filled sections smaller so

    that, due to the higher

    dissipation energy, the target

    melt temperatures are reached.

    This could possibly also be

    done by adapting the feed

    sections to reduce the specific

    melt throughputs. Last but not

    least, the shearing sections

    used for such applications can -

    and must - be dimensioned in

    such a way that the necessary

    temperature increase is

    reached.

    For other applications, for

    example foam extrusion, exactly

    the opposite course must be

    taken to keep the melt

    temperatures as low as possible

    after injecting the b lowing agent.

    Here, the best solution is to

    regard the extrusion system as a

    highly effective heat exchanger,

    and to enhance its effectiveness

    through reduced dissipation in

    large-dimensioned screw

    channels and through frequent

    interface renewal by the screw

    flights on the inner wall of the

    barrel.

    Fig. 3: Transition between feed section and barrier section on a doubleflighted/paired screw of 150 mm diameter

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    5

    We will now deal with the

    influences of the raw material

    and the extruder feed section

    geometry, which determine the

    conveying properties of an

    extruder.

    Universal screws / h igh-

    ou tpu t sc rews

    For the user, the ideal situation

    would be to have a screw on

    which as many different plastics

    as possible could be processed

    at high throughput speeds and

    with good melt homogeneity.

    Some of the most important

    requirements are:

    Processability of mixtures

    with different sized and

    different shaped granules

    High plastificating

    performance

    Gentle but complete

    plastification

    Good melt homogeneity

    Controlled melt temperatures

    Minimal change in the

    material through degradation

    or crosslinking

    High level of versatility: ability

    to process a broad selection

    of raw materials with a wide

    range of throughput rates

    Low performance-related

    investment and operating

    costs

    In recent years, so-calledgrooved barrel extruders with

    barrier screws have proved to

    be the most suitable systems

    among sing le-screw machines.

    With many grooved barrel

    extruders, the pressure build-up

    at the end of the feed section is

    too high, encouraging wear and

    tear and impairing the stability of

    the process. This can be

    countered by enlarging the pitch

    or making the screw channel

    deeper, although this involves

    the risk of plastification and

    homogeneity problems.

    A better solution than a screw

    with a stepped pitch or channel

    depth is a barrier screw. At the

    beginning of the barrier

    plastificating section, the

    conveying flight changes to a

    greater pitch; the beginning of

    the barrier flight also has a

    higher pitch. The depth of the

    channels is adjusted to the

    desired conveying and melting

    characteristics. These two

    measures result in a fairly

    balanced, low pressure profile,

    or even in a pressure build-up

    towards the end of the screw

    (Fig. 4).

    When assessing the

    "universality" of a screw, the

    homogeneity of the melt plays a

    dominant role. This is

    particularly true when

    processing mixtures of different

    materials, and also with regrind

    material, with color

    masterbatches and with the so-

    called 'direct extrusion' process

    (combining compounding and

    extrusion in one step, "in-line").

    Barrier screws, too, must be

    provided with elements for

    homogenizing after the meltingsection. Depending on the

    requirements of the raw

    materials and the demands

    made on the product, shearing

    sections must be used for

    dispersion (for example for color

    pigments), and/or distributing

    mixing elements must be

    provided for axial and transverse

    mixing.

    0

    50

    100

    150

    200

    250

    300

    350400

    450

    500

    0 50 100 150 200 250

    screw speed [rpm]

    pressure[bar]

    meltpressure in front of the screw tip

    meltpressure after grooved feed bush

    PE - HD Host alen GM 7746

    Extruder 50 mm, 28:1 L/D

    Fig. 4: Meltpressure in front of the screw tip and after grooved feed bush

    (source: KKM)

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    6

    In practice, barrier screws with

    neutral-pressure, (multiple-

    )spiral shearing elements and

    with faceted mixing sections

    designed to give good flow

    properties have proved

    successful, also for direct

    coloring with a color masterbatch

    (Fig. 5).

    With homogenizing elements of

    this kind, the best way of

    maintaining full control of the

    general thermal conditions, and

    thus of keeping the melt

    temperature closely under

    control, is to ensure that good

    heat transfer by convection to

    the temperature control system

    of the extruder barrel is possible,

    both in the area of the spiral

    shearing elements and in the

    area of the faceted mixing

    sections, through constant

    renewal of the surfaces and/or

    interfaces between the moving

    screw elements and the fixed

    inner surface of the barrel. A

    further influence can be exerted

    on the temperature of the melt

    by taking additional measures,

    for example, by fitting a

    temperature control system on

    the inside of the screw (e.g. as a

    closed cooling system),

    As regards extruders for

    universal applications - in other

    words, extruders capable of

    processing a very wide range of

    raw materials, including regrind

    (fluctuating proportions,

    recycled material etc.) - a

    decision has to be taken in each

    individual case whether or not to

    use the g rooved barrel extrusion

    concept. The decision is not

    always an easy one to make. If

    excessively large variations in

    the raw material properties

    especially the bulk density, flow

    properties and friction

    coefficients are to be

    expected, it is probable that

    using the grooved bush concept

    will lead to excessive

    fluctuations in melt throughput

    due to the fact that the output

    characteristics are governed by

    the solids conveying in the feed

    section. In such cases a

    smooth-bore extrusion system

    can or must be used. This is

    particularly true for processing

    raw materials with a fairly high

    shredded content and

    consequently a low bulk density.

    Another possibility is to pre-

    compact the shredded material

    so that grooved barrel machines

    can function perfectly.

    Fig. 5: Spiral shearing section and faceted mixing section after a barrier section

    Homogen izing e lements Bar r ie r p las t i f i ca t ingsec t ion

    Feed sect ion

    Good d ispersive/distributive mixing effect

    Heat transfer to the barrel

    Low pressure loss

    Effective separation of solidsfrom melt

    High homogenizing effect

    Good control of melttemperature

    Clear pressure build-up

    Melt throughput gearedto homogenizing capacity

    Low pressure level

    Low torque

    Reduced wear and tear

    Fig. 6: Barrier screw concept with homogenizing elements

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    7

    Fig. 6 summarizes the three

    sections and shows the special

    characteristics of a barrier screw

    with homog enizing elements.

    For universal application, use

    can generally be made of

    screws designed according to

    the above concept in lengths of

    between 20 and 30 x D. The

    feed section consists either of a

    shallow-flighted feed section

    with subsequent decompression

    (grooved bush concept) or a

    constantly deep-flighted feed

    section (smooth-bore extruder),

    followed by the barrier

    plastificating section and the

    homogenizing sections.The best

    solution is first to have

    dispersively acting mixing

    elements, and then distributively

    acting elements. Fig. 7 shows

    possible and commonly used

    constructions.

    In recent years, "static-dynamic"

    mixer systems with spherical

    indentations in a rotor and stator

    have become quite popular.

    They are marketed under such

    names as CTM, TMR,

    STAROMIX and 3-DD [5].

    Although they have a good

    mixing action, some of them

    have an inadequate self-

    cleaning system and others

    have problems with wear and

    tear. Apart from this, it is

    essential that the melt is 100 %.

    Opera t ion w i th bar r ie r

    sc rews

    With barrier screws, designed

    according to the principle ofDray and Lawrence screws, the

    solids channel has been made

    wider. This provides a larger

    contact surface area for the

    material being melted so as to

    introduce energy via the barrel

    heating. This means that, with

    barrier screws, the heating

    process must be started

    immediately after the material is

    fed in. Either a constant

    temperature program must be

    set over the length of the barrel,

    or the temperature must be set

    so that it actually drops from the

    feed section to the end of the

    barrel.

    The temperature at the end of

    the barrel is the same as in a

    conventional screw, in other

    words it is geared to the melt

    temperature. In the first heating

    zone after the grooved bush, it is

    perfectly in order to work at a

    temperature which is about 20

    30 C higher. In the lower to

    medium speed range, the

    temperature in the final barrel

    section is set at the same level

    as the melt temperature.

    The temperature at the end of

    the barrel is the same as in a

    conventional screw, in other

    words it is geared to the melt

    temperature. In the first heating

    zone after the grooved bush, it is

    perfectly in order to work at a

    temperature which is about 20

    30 C higher. In the lower to

    medium speed range, the

    temperature in the final barrel

    section is set at the same level

    as the melt temperature.

    With low-viscosity melts, or in

    cases in which high melt

    temperatures are required,

    correspondingly higher settingsare recommended. It is also

    advisable to keep a watch on

    the relative periods in which the

    heating and cooling units are

    switched on (controller output

    signals), so as to work in the

    medium range of settings (20 ...

    80 %). As a rule, this will mean

    that the deviations between

    target values and actual values

    are sufficiently small to ensure

    process stability.Fig. 7: Executions of shearing and mixing elements (source: KTP)

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    8

    In practice, it is not difficult to

    establish the optimum

    temperature settings.

    Because of the special

    characteristics of barrier screws,

    it has often proved an

    advantage to turn up the heating

    output in the first and second

    barrel sections, and to increase

    the fan or cooling capacity in the

    two sections at the end.

    Prac t ica l exper ience

    The broad range of application

    of barrier screws for polyolefins

    can be seen in Fig. 9. All these

    materials were successfully

    processed with the same 50mm/28 D screw with a twin-

    spiral shearing section and a

    faceted mixing section on a

    grooved barrel extruder. Further

    details are contained in one of

    the later articles.

    High-speed extrusion systems

    are generally characterized by

    the fact that the system is set upto suit a limited range of raw

    materials, but so as to achieve

    maximum melt throughputs in

    the specified melt quality. For

    this purpose, the combination of

    a grooved barrel extruder and a

    barrier screw with a

    homogenizing section is

    particularly recommended. With

    larger screw diameters, a

    double-flighted or twin-pair

    screw system can be used to

    improve the conveying

    properties in the feed section

    and to raise the melting

    capacity.

    One example at the upper end

    of the speed scale involves

    retrofitting an existing 150 mm

    33 D extruder for working with

    MDPE and LDPE for the

    sheathing of steel pipes. The

    objective in this case was quite

    clearly to achieve maximum

    possible melt output with high

    product homogeneity (specified

    in reference samples) and, at

    the same time, to keep the melt

    temperatures as low as

    possible. In addition, the system

    had to have outstanding self-

    cleaning and material

    changeover characteristics.

    Fig. 8: Temperature program for b arrier screws

    Fig. 9: Specific throughput vs. Screw speed (Quelle: KKM)

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    9

    Fig. 10 gives some examples of

    results obtained with and

    without a gear pump. Using this

    concep t, the targets were readily

    achieved, which meant that the

    installed d rive power was almost

    completely utilized for the given

    range of raw materials. Further

    increases in throughput are

    conceivable over and above

    these figures. However, this

    would make it necessary to

    adapt the drive unit by raising

    the motor power and

    proportionally increasing the

    screw speed. It also becomes

    increasingly important to take

    special measures to prevent

    excessive wear and tear

    because of the greater influence

    of the peripheral speeds of the

    screw.

    The production of fuel tanks is

    an impressive example of the

    direct recycling of production

    scrap. A problem here is that,

    with blow molding,

    comparatively short extruders

    are used.

    Depending on the shape of the

    tank and on other boundary

    conditions, between 40 and 60

    % flash occurs as scrap at the

    production machine. This ismaterial which was cut off at the

    top and bottom of the parison

    and from the pinch-off edges of

    the blow mould. This material is

    directly ground and fed back

    into the machine.

    Fig. 10: Production data with extruder 150mm/33:1 for steel pipe coating

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    10

    Fig. 11 gives the key operating

    data for a grooved barrel

    extruder with a diameter of

    150 mm/20 D equipped with a

    barrier shearing/mixing section

    screw for processing high-molecular weight HDPE grit

    containing regrind material.

    One notable application for

    'specialty screws' are vented

    extruders, which are used, for

    example, in plants producing flat

    film and sheets. Because such

    machines are being increasingly

    combined with melt pumps, thesecond stage of the screw only

    needs to convey the melt

    against the pump pre-pressure

    (and possibly against the

    resistance of melt filters), but

    does not have to overcome the

    resistance of the connection,

    possibly a static mixing element,

    and the die. Consequently,

    much higher throughputs canbe achieved, with plastification

    and homogenization being

    carried out in the first stage of

    the screw.

    Fig. 12 shows the concept of a

    vented screw with a barrier

    plastificating section in stage 1,and a three-zone profile plus

    faceted mixing section in stage

    2. Such vented screws with

    barrier plastification are being

    successfully used for e.g.

    polystyrene, polycarbonate and

    PMMA.

    Extruder 150 mm / 20 D

    PE-HD Lupolen 4261A

    with 50 % regrind

    0

    100

    200

    300

    400

    500

    600

    700

    5 10 15 20 25 30 35 40 45

    screw speed [r pm]

    Throughput[kg/h]

    190

    195

    200

    205

    210

    215

    Melttemperature[C]

    [kg/h]

    [C]

    Fig. 11: Production data with extruder 150mm/20:1 for industrial blow moulding

    Fig. 12: barrier screw configuration for vented extruder 90mm/30:1

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    11

    Extruder concepts for

    d i f ferent p last ics / new

    high-per formance

    mate r ia l s

    For most applications, grooved

    barrel extruders with a heat

    separation system between the

    feed section and the subsequent

    barrel have become established

    in Europe. As a rule, the feed

    bushes are axially grooved and

    correspond to the construction

    concept shown in Fig. 13.

    A good thermal layout - in otherwords sufficient and uniform

    heat dissipation in the area of

    the grooved bush - is of

    particular importance. For this

    purpose, the cooling channels

    and heat transfer resistances

    must be optimized. In many

    cases, temperature control units

    or installations with bypass

    control etc. are fitted to create

    constant thermal conditions.

    An optimized thermal layout is

    also essential for the rest of the

    barrel. Even though the target is

    to generate as little excess heat

    energy as possible via the

    screw, it is not possible with

    high-speed extrusion to

    dispense with good cooling of

    the barrel, at least not in some

    sections. Special companies

    offer heating/cooling

    combinations for this purpose,

    in which a great deal of heat can

    be dissipated via aluminum or

    copper elements. Some

    machine manufacturers also

    supply customized systems of

    this kind. When new materials

    come on to the market, the

    question continually arises

    about the most suitable extruder

    and whether they can be

    processed on existing

    machines. This was the case

    with LLDPE, and it is now

    happening with the metallocene

    polyolefins, for example

    mLLDPE. The goal of the

    chemical industry is where this

    has not happened already to

    make it possible to run mPE on

    existing extruders by modifying

    the molecular structure.

    One aspect not being examined

    here, but nevertheless of

    considerable importance, is the

    question of how the material

    behaves in the dies and after

    emerging from the die. With

    blown film extrusion, for

    example, this would concern the

    melt elasticity and the bubble

    stability.

    D

    N

    DT

    L

    A

    A

    BH

    H = 3 - 3,5mm

    = 7 - 8L = 3 - 3,5 D

    n = D(mm)/5D - D = ca.4mmB = 7 - 8mm

    NT

    Fig. 13 : Lay-out data for grooved feed sections

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    12

    Basically, it can be said that

    mPE can also be run on

    extruders used for processing

    LLDPE. This applies both to

    grooved barrel machines andsmooth-bore extruders [6].

    However, because of the

    specific material properties,

    there is a difference in the

    throughput rates (Fig. 14) which,

    in turn, leads to differences in

    melt temperature (Fig. 15) and

    outputs. On the other hand, this

    phenomenon is not specific to

    metallocene.

    One of the most important

    factors concerning the

    conveying properties in the feed

    section is evidently not the free

    flowing characteristics or the low

    degree of hardness of the

    granules. In fact, the large

    influence of lubricants as can

    be seen in Fig. 16 indicatesthat friction on the surface of the

    screw plays a major role,

    something which has also been

    encountered with "normal"

    polyolefins (cf. Fig. 9). One way

    of countering the poor

    conveying characteristics of thesolid material is to add a

    lubricant or material containing a

    lubricant. Another possibility,

    this time on the machine side, is

    to reduce the coefficient of

    friction by cooling the screw,

    coating the surface etc.

    Fig. 14: Specific throughput vs. Screw speed for grooved feed extruder 80 mm/30:1(source: Reifenhuser [6] )

    Fig. 15: Melt temperature vs. Screw speed (source: KKM)

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    13

    For engineering plastics (i.e.

    polyamides, polyesters,

    polyurethanes or thermoplastic

    elastomers), use is nowadays

    predominantly made of smooth-

    bore extruders. This is due not

    only to "tradition", but also to the

    predominantly low throughputs

    involved. Plastics of this kind

    can, however, also be

    processed without problem on

    grooved barrel extruders, as is

    shown in [8]. For blow molding

    with PA6, a grooved bush/screw

    concept similar to the one used

    for PE has given good results

    [9].

    Grooved feed sections are also

    being increasingly used in

    extruders with a barrel venting

    system. The grooves with a

    semi-circular, sickle, saw-tooth

    or rectangular cross-section

    are either cut in the one-part

    barrel, or a normal grooved

    bush concept is used. This

    means that the construction of

    vented extruders is currently in a

    process of change, as was

    already explained with the

    barrier vented screws.

    Direc t com pound ing in the

    ex t ruder

    This term is used to explain the

    combination of compounding

    and extruding in one step. The

    process, which aims primarily to

    cut down costs, is still in its

    infancy, despite all the efforts

    being made by machine

    manufacturers and plasticsproducers. For processing, use

    is made primarily of co-rotating

    twin-screw extruders, which offer

    far more possibilities in terms of

    process technology. They can,

    for example, be used for

    incorporating fillers and

    reinforcing agents, for blending

    different polymers or for

    simultaneously carrying out

    reactions (reactive

    treatment/extrusion).

    There has, however, been no

    lack of attempts to also use

    single-screw extruders for

    compounding or for the so-

    called in-line extrusion. Systems

    of this kind are repeatedly

    shown and marketed. The

    possibilities and limitations are

    obvious.

    One special kind of in-line

    extrusion is the blow molding of

    tubular film from mixed film

    waste (DSD fraction). After a

    temporary phase of euphoria,

    normality has, however,

    returned. Apart from technical

    problems with individual

    components of the plant and the

    doubts about the product

    quality, it has been found that

    the cost structure is also

    negative over the long term.

    EXCEED in BlendsEffect of slip in the LDPE blend component on specific output

    on grooved barrelextruders

    2

    2.2

    2.4

    2.6

    2.8

    3

    3.2

    3.4

    80mm

    24 L/D

    grooved

    75mm

    25 L/D

    grooved

    80mm

    30 L/D

    grooved

    Increase: 10 % 15 % 20 %

    EXCEED

    1MI /0.918D

    EXCEED

    1MI /0.918D

    EXCEED

    1MI /0.918D

    + 10 %

    LDPE

    + 20 %

    LDPE

    + 30 %

    LDPE

    with slip

    Slip additivated LDPE as blend partner gives 10 - 20 % higher specificversus no slip in the LDPE

    + 5 %

    LDPE + 5 %

    LDPE

    withslip

    withslip

    + 5 %

    LDPE

    no slip

    kg/rpm/h

    Fig 16: Influence of slip agent on specific throughput with mPE (source: EXXON [7])

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    14

    Despite all the progress being

    made to adapt extruders and

    extrusion lines to the

    requirements of waste

    processing, it must be said that

    the production of extruded

    quality products using recyclate

    is limited. Not so much because

    of the machine and processing

    technologies, but more because

    of the products and the

    specified quality. For the time

    being, in extrusion, the recycling

    of production scrap will continue

    to have priority over the

    processing of post-consumer

    recyclate.

    Possib le appl ica t ions and

    l im i ta t i ons

    At this point, it should be said

    that the possible range of

    applications for grooved barrel

    extruders with barrier screws is

    almost "boundless". This is

    shown elsewhere.

    Retro f i t t ing to op t imize

    the sys tem

    Whenever funds for capital

    expenditures become short, the

    purchase of new machines

    tends to be put back or

    eliminated completely. In such

    circumstances, optimizing the

    existing system can be a help.

    Where there is a need to modify

    existing extrusion lines to cope

    with a higher output and/orimproved melt quality, a modern

    screw concept can be adapted

    to the given circumstances.

    When making a modification of

    this kind, it first has to be borne

    in mind that the machine in

    question is of a given length

    (e.g. frequently between 20 and

    25 x D), which can not be

    changed, and that it has an

    existing drive unit. This

    sometimes leads to restrictions

    as far as the attainable specific

    melt throughput is concerned,

    due to bottlenecks with the

    torque of the screw drive unit.

    The torque results from the

    installed motor power and the

    installed gear reduction. In some

    cases, the gear reduction can

    be adapted so that a higher

    drive torque is produced on the

    screw shank. Since there is a

    directly proportional relationship

    between the specific output and

    the screw drive torque, it is

    possible in such cases to

    achieve an increase in the

    specific melt throughput equal

    to the increase in torque.

    Fig. 17 gives an example of a

    successful retrofit.

    Fig. 17: Production data with grooved feed extruder 60mm/24:1 after installing a barrier mixing screw(source: Kuhne)

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    15

    Protec t ing the sc rew and

    bar re l aga ins t wear and

    tea r

    One important aspect

    concerned with protection

    against wear and tear has been

    discussed already, namely wear-

    reducing screw geometries.

    Quite astonishing results can be

    obtained by harmonizing the

    conveying characteristics and

    the pressure build-up, and by

    optimizing the melting process

    from time to time in conjunction

    with a multiple flight design.

    With grooved barrel extruders,

    for example, through optimized

    harmonization of the system

    (adapting the feed section

    geometry to the downstream

    sections and vice versa),

    grooved bushes made of nitride

    steel can be used instead of

    hard metal or PM-HIP material

    (see below), because of the

    much lower pressures involved.

    On the other hand, new plastics

    - in some cases necessitating

    higher processing temperatures

    - fillers and reinforcing agents or

    pigments, higher peripheral

    velocities of the screw etc. etc.

    are resulting in higher and

    higher stresses. They can only

    be countered by taking special

    measures to increase the

    protection against wear and

    tear, as is state-of-the-art already

    in injection molding [10].

    In the USA, so-called bimetal

    barrels have been used in

    extruders for years and years. In

    Europe, too, instead of the

    conventional nitride steel

    barrels, processors are making

    increasing use of barrels that

    have been given a centrifuged,

    wear-resistant and, if needed,

    corrosion-resistant armored

    layer. Apart from the fact that

    this approx. 1.5 2 mm thick

    coat can be adapted to suit the

    particular type of stress, it also

    offers, with its consistent

    properties, a certain "reserve" of

    wear and tear, even if the

    process engineering parameters

    are not quite right.

    For small and medium-sized

    wear-protected screws (up to

    approx. 50 mm), fully hardened

    tool steel is used, particularly

    cold work steel X 155 CrVmO

    12.1 (DIN 1.2379). To achieve a

    (limited) corrosion resistance,

    frequent use is made of

    rustproof, acid-resistant 17 %

    chrome steel X 35 CrMo17 (DIN

    1.4122). By ionitriding to

    increase the surface hardness,

    however, this material loses

    some of its corrosion resistance.

    For very high corrosion

    protection, it is preferable to

    choose special materials, e.g.

    Inconel 625.

    With larger screws, it is common

    to armor-plate the screw flights,

    which are particularly prone to

    wear and tear. This involves

    using the tungsten inert gas arc

    welding or the plasma-powder

    application (PPA) welding

    method. The most popular

    materials for this are nitride

    steel, 30 CrMoV9 (DIN 1.8519)

    and 14 CrMoV6.9 (DIN 1.7735),

    or chrome steel X 35 CrMo17

    (DIN 1.4122). Hard alloys such

    as Stellite 12, Colmonoy 50,

    Colmonoy 56, Colmonoy 83 etc.

    are also used for armor-plating.

    The screw root surface and

    flanks can also be protected by

    nitriding, by a hard chrome layer

    or by armor-plating.

    Hot isostatic pressed materials

    (HIP) [10, 11] produced by

    powder metallurgy are gaining

    increasing importance. Both

    "natural hard" and hardenable

    alloys are used. The materials

    can be produced either as

    homogeneous systems or as

    composite systems, in the latter

    case, either in conjunction with

    steel, e.g. as the core with an

    external hard shell for screws or

    screw elements, or as a

    composite of the hard alloy

    powder with inserted hard

    substances.

    The PM-HIP materials have the

    advantage that a fine,

    homogeneous and pore-free

    structure is formed, which is

    much preferable to the

    conventionally produced

    materials. The wear-inhibiting

    hard phases (usually carbides)

    are also distributed more finely

    and evenly in the fine-grain

    structure, which means that less

    surface area is open to attack in

    the matrix. The components can

    be equipped specifically to cope

    with the expected stresses.

    Hardness values of up to 72

    HRC can be attained. Fig. 18

    shows the overall properties and

    behavior of PM-HIP materials.

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    16

    With materials examined on a

    universal disk tribometer, it was

    found that the relative wear

    decreases significantly with an

    increasing proportion of

    vanadium carbide.

    If we look at the market as a

    whole, solutions in which PM-

    HIP materials are used in single-

    screw extruders are still the

    exception rather than the rule.

    The higher the demands made

    on the plastics and their

    additives, the more popular the

    new systems will become, also

    for these machines.

    0

    1

    2

    3

    4

    5

    6

    0 10 20 30 40

    Vol.-% VC

    Rel.Wear

    Rel. Volumetric wear

    Material Element [Gew.- %] VC [Vol.- %]C Cr V

    X 220 CrVMoW 20 4 2,2 20 4,1 6,9

    X 250 CrVMoW 22 6 2,5 21,6 6 10,3

    X 260 CrVMo 26 4 2,6 26 4 6,2

    X 270 CrVMoW 17 9 2,7 17 9 15,7

    X 310 CrVMoW 15 10 3,1 15,2 10,3 18

    X 340 VCrWMo 13 13 3,4 12,8 13,3 23,4

    X 350 VCrMoW 13 9 3,5 8,5 13 22,8

    X 380 VCrWMo 17 13 3,8 12,5 17 29,7

    X 410 VCrWMo 17 14 4,1 14 17 29,5

    X 450 VCrWMo 18 13 4,5 13 18 31,1

    X 500 VCrWMo 20 13 5 13 19,5 33,4

    Fig 18: Relative abrasive wear of PM-HIP materialsdependent from VC content (source: Reiloy)

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