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A functional model for the cysteinate ligated non-heme iron

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______________________________________________________________________________________________________________ Terutaka Kitagawa; Abhishek Dey; Priscilla Lugo-Mas; Jason B. Benedict; Werner Kaminsky; Edward Solomon; Julie A. Kovacs; J. Am. Chem. Soc. 2006, 128, 14448-14449. 1
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______________________________________________________________________________________________________________

Terutaka Kitagawa; Abhishek Dey; Priscilla Lugo-Mas; Jason

B. Benedict; Werner Kaminsky; Edward Solomon; Julie A.

Kovacs;

J. Am. Chem. Soc. 2006, 128, 14448-14449.

1

Kovacs et al., Eur. J. Inorg. Chem. 2007, 29–382

Coulter et al, J Biol Inorg Chem (2002) 7: 653–6583

Rees et al, (2000) Biochemistry 39:2499–25084

[FeII(cyclam-PrS)]+

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6

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[FeIII(cyclam-PrS)(OOH)]+

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ν

ν

Favours superoxide reduction and Fe−O,

as opposed to O−O bond cleavage.

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Journal of Biological Inorganic Chemistry

Issue: Volume 7, Number 6 Date: June 2002 Pages: 647 - 652

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