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    A REFINERY APPROACH TO ADDRESS CORROSION UNDER INSULATION

    & EXTERNAL CORROSION

    Rob Scanlan, Ricardo Valbuena and Ian Harrison

    ConocoPhillips,

    Humber Refinery

    South Killingholme, North Lincolnshire

    United Kingdom DN40 3DW

    Rafael Rengifo

    ConocoPhillips

    Trainer Refinery

    4101 Post Road

    Trainer, PA, 19061, USA

    ABSTRACT

    Corrosion under Insulation (CUI) and External Corrosion continue to be a major issue for all

    Petrochemical facilities throughout the world. Over many years, refineries and petrochemical plants

    have experienced extensive damage due to these mechanisms. As a result, several of the company

    refineries have been investing in a CUI and External Corrosion inspection program. This paper details

    the methodology used by two refineries for addressing this damage and lessons learned throughout the

    implementation.

    The methodologies used by the two refineries differed at first in that one approach involved an

    initial cursory inspection of all areas in the refinery and history review of all fixed equipment items

    followed by a thorough inspection and maintenance refurbishment of equipment selected by this initial

    inspection. The second approach involved a software based desk top study with no initial inspection.

    The programs are being managed as a total refurbishment project, which include the identification of

    lines and vessels operating below 350 degrees F; inspection of vessels and lines, including insulated and

    painted lines; 100% removal of insulation in areas ranked High and Medium High based on theassessment above; repair where necessary; repaint and finally re-insulate if necessary.

    1

    Paper No.

    08558

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    The paperalso describes the findings from the work carried out so far. At Refinery A which

    followed the initial cursory inspection approach, 18 vessels have had 100% insulation removal, 200

    miles of piping have been visually inspected and 16 miles of piping refurbished. For vessels, 89 areas

    had lost part or all of the corrosion allowance, 26 areas had undergone weld repairs, 2 tower top heads

    have been replaced and a further nozzle replaced. On piping, 137 areas were found to have gone through

    part or all of the corrosion allowance and 61 further pipe sections required replacement. At Refinery B,

    the areas for inspection were selected using a desk top study. The selection did not include an initial

    inspection of the entire refinery. The desk top study directed the efforts to discrete areas of the refinerywhere external conditions of insulation and long range NDEs were then used to decide whether further

    insulation removal was necessary. The approach at Refinery B has resulted in fewer inspection finds and

    it is now adjusting the CUI/External Corrosion program based on these finds and the lessons from

    Refinery A.

    Keywords: Refining, Corrosion under Insulation, External Corrosion.

    INTRODUCTION

    External corrosion and CUI continues to be a major issue for all refineries and petrochemical

    plants throughout the world. CUI was brought to the awareness of the industry as a damage mechanism

    in the early 1980s(1,2)

    . Over many years, refineries and petrochemical plants have experienced extensive

    damage due to these mechanisms and as the refineries and petrochemical sites age, this external damage

    become more prevalent. To mitigate this damage, most refineries and petrochemical sites are instigating

    a CUI/External Corrosion Program. This paper details the methodology used by two of these refineries

    to address this damage.

    Most CUI/External Corrosion programs follow the same basic steps as noted below:

    Development of Corrosion Loops or areas with emphasis on CUI and External Corrosion.

    Completion of an initial inspection of all areas in the refineries to establish scope.A thorough review of the equipment history.

    Criticality and risk ranking of pieces of equipment based on initial inspection and

    equipment history review.

    Amount of insulation removal and inspection coverage in line with the initial inspection

    and risk ranking.

    Project approach to assure sustainability for the CUI and External Corrosion Program.

    This paper also covers several case studies resulting from the work undertaken in the last three

    years. Novel techniques to prevent CUI and external corrosion such as the use of non-metallic insulation

    for sealing and cages for personal protection in lieu of insulation are also discussed.

    Site description

    Refinery Ais located on the south bank of the estuary of the River Humber on the east coast of

    England, approximately 1.5 km northwest of the town of Immingham and 0.5 km east of the village of

    Killingholme, See Figure 1. The refinery was constructed between 1966 and 1969 and commissioned in

    1970. The current capacity of the refinery is about 225,000 bpd (11.4 million metric tons per year). The

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    exports are the full range of refinery products, including LPG, dimethyl ether, gasoline (petrol), aviation

    kerosene, fuel oil, heating oil and petroleum coke.

    An aerial picture of the refinery is provided in Figure 2, with an arrow showing north, the

    prevailing winds are from the south west. The photo indicates the critical processing units of concern

    due to the cooling tower drift area as shown by the shaded area in the schematic. The refinery location is

    deemed as a mix of marine and rural due to its location.

    Refinery B is located in Trainer, Pennsylvania, approximately 10 miles south of the Philadelphiaairport on the Delaware River, and 3 miles north of the Delaware State line. The refinery currently has a

    crude oil processing capacity of 185 MBPD (9.4 million metric tons per year) and started operations in

    1910. The Refinery has been operated by several owners in the last 97 years and has undergone several

    major revamps.

    Refinery B makes a large range of products which include reformulated gasoline and low-sulfur

    diesel for the local markets. Refined products are distributed to customers in Pennsylvania, New York

    and New Jersey via pipelines. An aerial picture of the refinery is provided in Figure 3.

    METHODOLOGY

    As part of corporate efforts to improve mechanical integrity, a set of required standards has been

    under implementation since 2002 throughout the downstream organization. One of the key standards

    developed was a CUI and External Corrosion Required Standard. Each refinery was required to

    developed and execute its own CUI and External Corrosion program for piping and vessels following

    this standard.

    Piping Assessment Methodology

    At Refinery A, the external condition of the piping was not known in sufficient detail to allow

    the effective use of RBI software tools. Piping and painting/insulation condition and history over the 30-

    year life of the plant were questionable. As a result, the refinery prioritized the areas of the refinery

    using the consequence model from the API580 document (A-E). The likelihood of failure was based on

    the following sources of data:

    An initial cursory inspection of all the areas in the refinery looking for evidence of external

    corrosion or CUI or areas potentially affected by CUI following the API RP 574 (Inspection

    Practices for Piping System Components) section 6.3.3 (e.g. areas exposed to mist over-

    spray from cooling water towers; areas exposed to steam vents; areas with damaged or

    missing insulation; damaged paint; caulking which has hardened, separated or is missing;

    etc.).

    An External Visual Inspection (EVI) from grade of all the Oil Movement and Storage(OM&S) piping grouped and prioritised by consequence. This survey included bunds (tank

    restraining walls), bridges and ground level piperack. Specialist techniques like

    Electromagnetic Acoustic Transducer (EMAT) and Guided Wave Ultrasonic were used as

    screening tools for pipe supports, bund penetrations and bridges.

    An extensive initial inspection of pipe racks was performed using a Rope Access (Rope

    Climbing) technique, further details of the rope access process can be found in Appendix 1.

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    EMAT was again used as a screening tool for pipe supports where excessive corrosion was

    found by the rope access survey.

    Areas of concern selected by the Inspectors, senior operators and maintenance leaders as

    identified from years of walk rounds in their units.

    History and assessments from the painting and insulation specialist and the corrosion

    engineer.

    Armed with this input, the corrosion engineer and inspectors at Refinery A selected and ranked

    the piping most susceptible to CUI and External Corrosion, see Table 1. The piping selected included

    whole or sections of process units and pipe-rack sections within a unit or between units as well as

    bridges requiring lifting and bunds requiring excavation.

    Vessel Assessment Methodology

    Again the external condition of the vessels was not known in sufficient detail to allow the

    effective use of RBI software tools. The likelihood of failure was based on the following sources of

    data:

    All insulated vessels or sections of vessels or towers operating below 350 degrees

    Fahrenheit were selected for an initial review.

    A review of inspection data for these vessels was performed to determine potential

    susceptibility.

    Further information provided by the unit Inspectors, senior operators and maintenance

    leaders about their vessels of concern as identified from years of walk rounds in their units.

    Using this information the corrosion engineer and inspectors again ranked the vessels on its

    susceptibility to CUI, see Table 2.

    Refinery B based its CUI and External Corrosion implementation program on a desktop study

    process flow with no initial inspection to verify the general assumptions. The process involved selectingsome insulated vessels and piping with an operating temperature under 350F. The selection did not

    include an initial inspection of the entire refinery. The desk top study directed the efforts to discrete areas

    of the refinery where external conditions of insulation and long range NDEs were then used to decide

    whether further insulation removal was necessary. This initial desk study proved not to be successful in

    finding CUI/External corrosion damage and midway through the program, a field based approach similar

    to Refinery A was adopted. Refinery B is now in the initial stages of this new approach.

    Refurbishment Methodology

    A total refurbishment is being applied to the piping and vessels ranked as High and Medium

    High based on the above assessment methodology. On insulated piping this involves 100% insulationremoval. Painted lines are also inspected in piperacks, especially at pipe supports. Lines are lifted to

    inspect contact points at supports, following operational contingency plans in case of any loss of

    containment. Any repairs where necessary are performed and the lines repainted and finally re-insulated

    if necessary. For painted lines at pipe supports, bonded pads (See figure 5) are installed to extend the

    life of the piping.

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    circumferential bands up to 60% around the tower circumference, the band was 6-8" in height. It is

    recommended to remove all transportation attachments at commissioning. These two bands were not

    evident on the original construction drawings and were only found by a full insulation strip.

    Refinery A Case Study 6 - H.D.A Purge Tower

    The top of the tower operates at approximately 320F (160C). CUI on the top surface of the manway was

    not noticeable with the insulation in place using external inspection. Nozzle UT inspection gave a

    thickness of 9.7mm. Internal UT scan from internal surface of manway to external flange found CUI andgave a minimum thickness of 5.8mm. Nozzle inspection using UT scanning from the ID is more

    effective at finding CUI.

    Refinery A Case Study 7 - 3 Benzene Export Line

    A digital radiography inspection point noted some thinning, this was followed up by partial removal of

    asbestos insulation, the pipe was found to be suffering from CUI at the 12 oclock position with a

    remaining wall thickness of 1mm. The area was prone to flooding and therefore insulated lines should

    not sit in water.

    Refinery A Case Study 8Vent on 12Naptha Line

    An insulated unused vent line with a pressure gauge was found during the EVI program. The insulation

    was removed to reveal severe CUI with a remaining thickness down to 0.56mm. Always remove

    unnecessary insulation.

    Refinery A Case Study 9 - 3 Hydrogen High Pressure Line

    This high pressure hydrogen line sat on structural support and was partially buried by fireproofing.

    Contact point corrosion was down to 1.75mm; the line was lifted and radiographed. It is prudent not to

    let process lines sit in fireproofing, which is a moisture trap and only allows limited visual inspection.

    Refinery A Case Study 1014 RefineryNitrogen Supply

    EVI survey indicated major external corrosion at a water run off point from a road bridge. Corrosion

    products were removed to give a minimum thickness remaining of 2.7mm at the contact point.

    Considerations need to be given to water run off locations from bridges and to provide protection to

    inaccessible lines.

    Refinery A Case Study 11 - Virgin Distillate Run Down Lines

    Severe corrosion was found at contact supports within a ground level piperack which is subject toflooding. The Naptha feed line failed with several other lines subject to severe external corrosion.

    Areas of flooding need to be controlled and access for underside inspection needs to be provided.

    Refinery A Case Study 12 - 1 Instrument Analyzer for 6 Sour Vent Gas

    Severe CUI of the analyzer piping was found to have a minimum thickness of 0.74mm. Prior to the find,

    new insulation had been installed over the old insulation without refurbishment, therefore hiding the area

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    of concern to visual inspection. Inspection of instrument piping should be included in any inspection

    plan and old insulation should not have new installed over the existing.

    Refinery A Case Study 13 - LPG Jetty Flushing Line

    External corrosion occurred at a pipe support contact point on the Jetty on the LPG flushing line. Heavy

    corrosion at the support contact point had resulted in completely corroding through the wear pad (3mm

    thick). The measured pipe wall thickness remaining next to the wear pad was 2.9mm. Previously welded

    supports added to the line were not re-painted leading to excessive corrosion.

    Refinery A Case Study 146 Hydrogen Export Line

    Heavy external corrosion down to 1.5mm was found at a contact point where the line was sat in

    fireproofing, which acted as a moisture trap. This example was found by Guided Wave Ultrasonics.

    Extra protection is required at all line support contact points, do not fireproof support contact points.

    Refinery A Case Study 15 - 12 Blending Storage Diesel Line in Bund

    External corrosion found within wrapped area that was buried in the soil bund. An initial partial dig

    gave a UT thickness of 5.7mm; however wrapping was in poor condition. Complete bund excavation

    and wrapping removal indicated a remaining wall thickness of 2mm. The section of line was replaced

    prior to the bund replacement. Underground wrap systems breakdown over time. At this location the

    wrap not reinstated and an underground paint was used.

    Refinery B Case Study 16 - Diesel Treater Tank PV-1407

    A small leak was detected at the bottom of the Diesel Treater Tank PV-1407. The metal jacket or

    cladding was new. The insulation was in extremely poor condition when the cladding was removed. This

    revealed a general corrosion attack with a thick corrosion products scale. The vessel was replaced and a

    Root Cause Analysis initiated. Poor coating application and cladding over damaged insulation werenoted as potential causes.

    Refinery B Case Study 17 - FCC Fractionator Top Reflux Out of Overhead Accumulator Piping

    Circuit

    A pinhole leak was detected at a support contact point, where a pack of cables created an environment

    for debris and rust to accumulate. The corrosion attack observed was local and very severe at the 6

    oclock position contact point. The piping section was replaced and a contact point bonded pad was

    installed.

    Refinery B Case Study 18 - Tank Farm Distillate Line

    A pinhole leak was detected at a soil to air interface adjacent to a road crossing. The corrosion attack

    observed was severe and local to the soil to air interface on both sides of the road crossing where the

    coating/wrapping was in poor condition. The piping was replaced and the soil to air wrapped to current

    refinery standards. Visual inspection of soil to air interface should always include some soil removal to

    assess the coating/wrapping condition.

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    DISCUSSION

    Refinery A has been undertaking its CUI/External Corrosion Program for the past 3 years; the

    findings from the program are detailed in Table 3. At the time of writing this paper, Refinery A had

    inspected and refurbished 18 vessels involving 100% insulation removal, refurbished 16 miles of piping

    in 5 piperack systems and inspected and assessed approximately 200 miles of piping. The refinery has

    classed a find as where part or all of the corrosion allowance has been lost due to CUI or external

    corrosion.

    The assessment process undertaken for vessels proved to be accurate at Refinery A. Of the 18

    vessels inspected, CUI to some degree was found on 16 vessels, i.e. an 89% hit rate. On these 16

    vessels, 89 areas have lost part or all of the corrosion allowance, 26 further areas have undergone weld

    repairs, 2 tower top heads and a nozzle have also been replaced.

    The CUI/External Corrosion Program on piping was less accurate. The total number of pipes

    inspected/refurbished as part of the CUI/External Corrosion Control program is approximately 1800.

    This has yielded 137 finds and 61 pipe replacements for an inspection hit rate of 11% for the High and

    Medium High risk ranked piping systems. The finding hit rate was less than expected for piping ranked

    Medium High and High. The piping of concern was 37 years old and exposed to the mist from the

    cooling towers. More damage at the 6 oclock position was expected between supports. However, 48%

    of these finds occurred at contact points on pipe supports, 14% at field welds where the coating had

    broken down and 34% at other locations e.g. through earth bunds, bridges etc.

    The desk top methodology used by Refinery B did not find any significant CUI/External

    corrosion. The corrosion found them as it manifested in the form of leaks. Since the start of the

    program, Refinery B experienced 5 CUI/External failures. Each failure instigated a Root Cause

    Analyses (RCA) investigation, these RCA findings revealed coating damage and design flaws as a major

    contributor to the failure. The failures experienced reinforced the need for a revised CUI/Program with

    more initial inspections to validate assumptions (similar to Refinery A) and with 100% insulation

    removals on critical piping systems and vessels deemed High or Medium High following the initialinspection.

    Some of the major findings and lessons from the CUI/External Corrosion Program from Refinery

    A and Refinery B regarding the assessment procedures and site work are detailed below; a section of

    novel repair methods is also included.

    Lessons Learned - Assessment Procedures:

    Desk top RBI software assessments based on assumptions are not effective in prioritizing for

    CUI or external corrosion. The CUI prioritization and ranking requires detailed field data and

    knowledge of inspection and maintenance history.Visual inspection of the external condition of insulated equipment alone and without

    consideration of operational and maintenance history is not effective. (See Case Study 12).

    Effective CUI and External Corrosion management requires the development and implementation

    of work processes to assure sustainability.

    Large site implementations such as the ones described in this paper require the full backing of

    management to again ensure sustainability and continued funding.

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    CUI/External Corrosion finds and leaks should be documented, tracked and trended to determine

    the need and pace of new inspections and refurbishments.

    Lessons Learned - Site work

    100% insulation removal was required when inspecting vessels deemed as having a High or

    Medium High susceptibility to CUI since damage was not always at the expected locations. One

    vessel had transportation rings hidden beneath the insulation that formed a water trap causing

    CUI. On another vessel CUI was found underneath the Fireproofing. See Case Studies 3 and 5.

    Vessel inspection found that 90% of the CUI damage occurred at attachments and breaks in the

    metal cladding. Severe CUI leading to replacement was also found around the top heads on two

    vessels. See Case Studies 2 and 4.

    During the visual inspection of piperacks using rope access, the corrosion found at Refinery A

    was around pipe supports where debris and water was able to collect. EMAT was implemented

    using rope access trained personnel as a follow up to evaluate the worst support contact points.

    The accuracy of this technique was validated several times in the field by physically lifting the

    pipes and inspecting visually and with pit gages.

    The rope access inspection had other benefits in that it was able to highlight areas of immediate

    concern needing immediate refurbishment or repair.The rope access technique also provided a further safety benefit by having the opportunity to

    remove unattached debris within the pipe rack such as loose nuts and bolts, gaskets, and scaffold

    clips.

    Quality control of all the steps in the refurbishment program is critical for the future integrity of

    the vessels or piping. Some of these steps include the quality assurance of blasting, inspection,

    painting, insulation and addition of support pads.

    Novel Repair Methods

    Whilst undertaking full inspection of the vessel, the opportunity to blast and paint should be

    undertaken. Current best practice is a thermally sprayed aluminum coating (TSA) (3).One development undertaken at Refinery A is that all attachments and the top head of vessels are

    sealed using non-metallic cladding to reduce the possibility of water ingress. See Figure 4.

    When the pipes were lifted for blasting and painting as part of the pipe refurbishment project,

    support pads were fitted to increase the future life of the piping system, See Figure 5.

    At the initial stages of the CUI/External Corrosion Program, a survey was performed on piping

    with Insulation for Personnel Protection (Ip) at Refinery A. Initial results indicated that 6% of Ip

    locations had CUI. As a result, all Ip is being replaced with perforated cladding See Figure 6.

    CONCLUSIONS

    The CUI risk ranking process of vessels and piping requires detailed field data and knowledge of

    their inspection and maintenance history.

    Full vessel insulation removal using the vessel assessment process produced a CUI hit rate of

    89% for the 18 vessels inspected, with 89 areas having lost part or all of the corrosion allowance,

    26 further areas have undergone weld repairs, 2 tower top heads and a nozzle have also been

    replaced.

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    The CUI/External Corrosion Control program produced 61 pipe replacements and a hit rate of

    11% for the High and Medium High risk ranked piping systems. The finding hit rate was less

    than expected for piping ranked Medium High and High. The piping of concern was 37 years old

    and exposed to the mist from the cooling tower. More damage at the 6 oclock position was

    expected between supports. However, the majority of these finds occurred at contact points on

    pipe supports or at field welds.

    Close visual inspection of the piperacks via rope access provided many benefits, these included;

    Quick collection of field data on which the piping refurbishment priority of the piperackswas based.

    It also highlighted areas of immediate concern which could not be performed with a visualinspection from the ground. These allowed for their immediate refurbishment or repair.

    Provided an added safety benefit of having the opportunity to identify and remove potentialfalling objects from piperacks.

    EMAT was found to be very good for screening and evaluating pipe support contact points, but

    the technique is very operator dependant.

    Trials with the latest Guided Wave Ultrasonic Techniques are looking promising, especially for

    screening of pipelines with limited access i.e. bunds, bridges etc. The accuracy of the techniqueshould improve after more field experience.

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    Figure 1A Schematic Locating Refinery A and its Crude import via the Monobouy .

    Figure 2An aerial photo of refinery A indicating the areas of concern from the cooling tower drift due

    to the prevailing winds from the south west.

    N

    Prevailing Wind

    From South West

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    Figure 3An aerial photo of Refinery B.

    Div UnitCUI

    Priority

    Year

    Planned

    A PR Coke Drums Piperack - Trial Section 1 2006

    D UP IPC piping 1 2006

    C UP LPG Bullet Piping 1 2006

    BB PR HAD-AEU Piperack 1 2007

    BE PR ALKY Piperack - All Sections 1 2007

    C PR CTU-FCC Piperack - Cooling Towers Section 1 2007

    BB PR No.2 CRU Unit Piperack 1 2008BB PR Sulphur & SWS Piperack 1 2008

    BE UP ALKY Unit Piping 1 2008

    BB UP HAD-AEU Unit Piping 1 2008

    BE PR PRU Unit Piperack 2 2008

    A PR Coke Drums Piperack - Section 2 2 2008

    A PR Coke Drums Piperack - Section 3 & 4 2 2009

    C PR CTU-FCC Piperack - FCC to Utilities Section 2 2009

    BB UP CAT POLY & Merox Unit Piping 2 2009

    B UP Sulphur & SWS Unit Piping 2 2009

    BB PR CPU Piperack 2 2009

    C PR Piperack Utilitiies 2 2009

    BB PR Piperack Ave B Aromatics 3 2009

    BE UP Butamer Unit Piping 3 2009

    C UP Utilities Area 51 3 2009

    C UP Tank Farm Piping - LPG 3 2009A UP Rail Loading 3 2009

    B UP NO 1 CRU 3 2009

    BB UP NO 2 CRU Unit Piping 3 2009

    B UP VRU 3 2009

    BE UP PRU Unit Piping 3 2009

    BE PR Butamer Piperack 3 2009

    C/BB PR Piperack Ave C - Utilities to AEU 3 2009

    Refinery A - CUI Piping Project

    Table 1A listing of the piping systems requiring refurbishment following the risk analysis performed.

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    Vessel Vessel Name RankYear

    Planned

    W7050 New SWS 1 2005

    W3631 Alky Isostripper 1 2005

    W574 Benzene Tower 1 2005

    D3309 W305 Ovhd Drum 1 2005

    D7402 Amine knockout Drum 1 2005

    D5423 CPU Reactor 1 2007

    W534 Stripper Column 2 2006

    W533 Raffinate Splitter 2 2006

    W531 Extractor 2 2006

    W-573 2 2006

    D-3622 SGP Butane Drier 2 2006

    D-3623 SGP Butane Drier 2 2006

    W4701 Aromatics Extr 2 2006

    W308 2 2006

    W-575 2 2006

    W6301 No 2 Reformer Stab. 2 2007

    D421A Butane Drier 3 2007

    D454 Propane Drier 3 2007D455 Propane Drier 3 2007

    D583 W575 Ovhd Accum. 3 2007

    W4441 3 2007

    W535 Recovery column 3 2007

    D306 4 2008

    D308 4 2008

    D5402 4 2008

    D5408 4 2008

    Refinery A - CUI Vessel Work Scope

    Table 2A listing of the vessels requiring refurbishment following the risk analysis performed.

    Program Grit Blast & Paint Weld Repairs Replacement Total

    Piping 137 0 61 198

    Vessels 89 26 3 118

    316

    External Corrosion/Corrosion Under Insulation Find

    Note: Finds Are Defined As Where The Corrosion Allowance (3mm) Has Been Lost

    Table 3A listing of the corrosion finds from the CUI / External Corrosion project being undertaken at

    Refinery A.

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    Figure 4Non metal cladding used to seal the top head and attachments to prevent future water

    ingress

    Figure 5The figures indicate piping in a piperack that has been refurbished, with pads added.

    Figure 6. Perforated cladding which has been used to replace insulation for personnel protection.

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    Table 4 - Refinery A Case Study 1 - FCC Feed Drum

    Duty: FCC Feed Drum Material: Carbon Steel

    Wall Thickness: 12.7mm Damage mechanism: Crack

    Commissioning Date: 1985 Period of Metal Loss: 21 years

    Photograph:

    Description of Corrosion Mechanism or Detail

    The FCC feed drum operates at 193C (380F) which is above the temperature for CUI. The lifting lugs had been left on

    the vessel at installation and not totally encapsulated in cladding. Severe corrosion was experienced behind the lifting

    lug which acted as a heat sink, lowering the temperature locally to below 300F (149C). The CUI products forced the

    lifting lug away from the vessel causing a through wall crack on the top head.

    Action Taken

    Lifting lugs were removed and the vessel repaired. Full paint coating and insulation re-instated.

    Lessons Learned / Design Change

    Remove lifting lugs at installation. If you do have to keep them, then fully encapsulate the lifting lugs in cladding.

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    Table 5 - Refinery A Case Study 2 - Sour Water Stripper Tower

    Duty: Sour Water Stripper Tower Material: CS with SS cladding

    Wall Thickness: 12.7mm Damage mechanism: Thinning

    Commissioning Date: 1985 Period of Metal Loss: 21 years

    Photograph:

    Description of Corrosion Mechanism or DetailSour Water Stripper Tower - Tower operates at 255F (107C) at the bottom and 180F (82C) at the top. Picture 1 -

    Section of lower support ring which has virtually corroded through (22mm), shell was also showing losses of 3-4mm.

    Picture 2 - Section of tower just below top head experienced severe CUI. Picture indicates 2-3 inches of corrosion

    products (10mm thick). On the left hand side of the picture is the exposed internal SS cladding.

    Action Taken

    Support ring cut out and replaced, Shell of tower overlayed. Top of tower replaced.

    Lessons Learned / Design Change

    Regular inspection of Cladding integrity is required. Top head cladding was in an extremely poor condition.

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    Table 6 - Refinery A Case Study 3 - Amine Knockout Drum

    Duty: Amine Knockout Drum Material: Carbon Steel

    Wall Thickness: 10mm Damage mechanism: 10mm

    Commissioning Date: 1978 Period of Metal Loss: 28 years

    Photograph:

    Description of Corrosion Mechanism or DetailKnock out drum operates at about 80F (27C). Severe corrosion of skirt, up to 10mm loss, full wall thickness metal loss.

    Action Taken

    Vessel was repaired, overplated and re-fireproofed.

    Lessons Learned / Design Change

    Continued inspection of Fireproofing is required.

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    Table 7 - Refinery A Case Study 4 - AEU Recovery Column

    Duty: AEURecovery Column Material: Carbon Steel

    Wall Thickness: 11.1mm Damage mechanism: CUI

    Commissioning Date: 1966 Period of Metal Loss: 41 years

    Photograph:

    Description of Corrosion Mechanism or Detail

    The recovery column operates at 180F (82C) at the top of the tower. Picture 1 indicates 40mm of scale above the 3rd

    vacuum ring from the top of the tower. The rings were not water shedding. The second picture shows the metal loss

    with the scale removed. The remaining thickness was as low as 2mm at various locations.

    Action Taken

    Temporary plates were bonded around the shell above the stiffening ring. New top section for tower ordered for

    replacement in April 08.

    Lessons Learned / Design Change

    Consideration for vacuum ring supports should be made during design stage, these supports should be drilled where

    possible.

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    Table 8 - Refinery A Case Study 5 - AEU Extractor Tower

    Duty: AEU Extractor Tower Material: Carbon steel

    Wall Thickness: 19.1mm Damage mechanism: CUI

    Commissioning Date: 1968 Period of Metal Loss: 39 years

    Photograph:

    Description of Corrosion Mechanism or Detail

    The Extractor Tower operates at approximately 180F (82C). Severe CUI was found at the transportation support bands.Support bands discovered during full insulation strip. Up to 10mm loss at two circumferential bands, 60% around the

    tower circumference, bands were 6-8" in height.

    Action Taken

    Weld overlayed the tower back to 19mm at first opportunity.

    Lessons Learned / Design Change

    Remove all transportation attachments at commissioning. These two bands were hidden by insulation and were not

    evident on the original construction drawings and were only found by a full insulation strip.

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    Table 9 - Refinery A Case Study 6 - H.D.A Purge Tower

    Duty: H.D.A Material: Carbon steel

    Wall Thickness: 10mm Damage mechanism: CUI

    Commissioning Date: 1982 Period of Metal Loss: 25 years

    Photograph:

    Description of Corrosion Mechanism or Detail

    Top of tower operates at approximately 320F (160C). CUI on top surface of top manway not noticeable with insulationin place from external inspection. Nozzle UT inspection gave a thickness of 9.7mm. Internal UT inspection of manway

    (i.e. scan from internal surface to external flange) found CUI and gave a minimum thickness of 5.8mm. Pictures show

    CUI with an approximate loss of 4mm.

    Action Taken

    Insulation removed and area grit blasted. Inspected indicated loss on shell up to 1.5mm. Area painted and insulation

    replaced.

    Lessons Learned / Design Change

    Nozzle inspection using UT scanning from the ID is more effective at finding CUI.

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    Table 10 - Refinery A Case Study 7 - 3 Benzene Export Line

    Duty: 3 Benzene Export Line Material: Carbon Steel

    Wall Thickness: 5.5mm Damage mechanism: CUI

    Commissioning Date: 1969 Assumed Period of Metal Loss: 38 years

    Photograph:

    Description of Corrosion Mechanism or Detail

    Thinning found while conducting digital radiography of nearby bend, this was followed up by partial removal ofasbestos insulation, the pipe was found to be suffering from CUI at the 12 oclock position with a remaining wall

    thickness of 1mm. The area was prone to flooding.

    Action Taken

    The line was Furmanite clamped; Guided wave inspection of line back to pump was performed. Awaiting asbestos

    insulation removal for full inspection.

    Lessons Learned / Design Change

    Do not allow insulated lines to sit in water.

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    Table 11 - Refinery A Case Study 8Vent on 12 Naptha Line

    Duty: Vent on 12 Naptha line Material: Carbon Steel

    Wall Thickness: 3.9mm Damage mechanism: CUI

    Commissioning Date: 1969 Period of Metal Loss: 38 years

    Photograph:

    Description of Corrosion Mechanism or Detail

    An insulated unused vent line with a pressure gauge was found during the EVI program. The insulation was removed to

    reveal severe CUI with a remaining thickness down to 0.56mm.

    Action Taken

    Vent and pressure gauge replaced.

    Lessons Learned / Design Change

    Remove unnecessary insulation.

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    Table 13 - Refinery A Case Study 1014 RefineryNitrogen Supply

    Duty: 14 RefineryNitrogen

    Supply

    Material: Carbon Steel

    Wall Thickness: 7.9mm Damage mechanism: Contact point

    Commissioning Date: 1969 Assumed Period of Metal Loss: 38 years

    Photograph:

    Description of Corrosion Mechanism or Detail

    EVI survey indicated major external corrosion at a water run off point from a road bridge. Corrosion products were

    removed to give a minimum thickness remaining of 2.7mm at the contact point.

    Action Taken

    Line has been replaced. All lines under bridge refurbished and painted with underground spec paint, and pipe contact

    support pads added.

    Lessons Learned / Design Change

    Change water run off from bridge and provide better protection to inaccessible lines.

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    Table 14 - Refinery A Case Study 11 - Virgin Distillate Run Down Lines

    Duty: Distillate rundown Material: Carbon steel

    Wall Thickness: 6mm Damage mechanism: Contact point

    Commissioning Date: 1969 Period of Metal Loss: 38 years

    Photograph:

    Description of Corrosion Mechanism or Detail

    Severe corrosion found at contact supports within a ground level piperack which is subject to flooding. The Napthafeed line failed with several other lines subject to severe external corrosion.

    Action Taken

    Failed line replaced, one other line clamped and three other lines underwent guided wave UT and were found to be

    acceptable until next opportunity, when they will be replaced.

    Lessons Learned / Design Change

    Control areas of flooding and provide access for underside inspection.

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    Table 16 - Refinery A Case Study 13 - LPG Jetty Flushing Line

    Duty: LPG Jetty Flushing Line Material: Carbon Steel

    Wall Thickness: 6mm Damage mechanism: Contact point

    Commissioning Date: 1984 Period of Metal Loss: 23 years

    Photograph:

    Description of Corrosion Mechanism or Detail

    External corrosion occurred at a pipe support contact point on the Jetty on the LPG flushing line. Heavy corrosion at

    the support contact point had resulted in completely corroding through the wear pad (3mm thick), the measured pipe

    wall thickness remaining was 2.9mm.

    Action Taken.

    Line depressured and corrosion products removed to assess support location. Severely corroded section was replaced.

    Full line was lifted, blasted and painted. Nine more wear pad areas required remedial work.

    Lessons Learned / Design Change

    Previously welded supports added to line were not re-painted leading to excessive corrosion.

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    Table 18- Refinery A Case Study 146 Hydrogen Export Line

    Duty: 6 Hydrogen Export Line Material: Carbon steel

    Wall Thickness: 7.1mm Damage mechanism: Contact point

    Commissioning Date: 1985 Period of Metal Loss: 22 years

    Photograph:

    Description of Corrosion Mechanism or Detail.

    Heavy external corrosion down to 1.5mm was found, worst location at contact point where the line was sat infireproofing, which acted as a moisture trap. Found by Guided wave Ultrasonics.

    Action Taken.

    Line taken out of service and replaced with a contact point bonded pad.

    Lessons Learned / Design Change.

    Extra protection is required at all line support contact points, do not fireproof lines.

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    Table 17- Refinery A Case Study 15 - 12 Blending Storage Diesel Line in Bund

    Duty: 12 Blending storage

    Diesel Line in Bund

    Material: Carbon Steel

    Wall Thickness: 6.3mm Damage mechanism: CUI

    Commissioning Date: 1969 Period of Metal Loss: 38 years

    Photograph:

    Description of Corrosion Mechanism or DetailExternal corrosion found within wrapped area that was buried in the soil bund. Initial partial dig gave a UT thickness of

    5.7mm; however wrapping was in poor condition. Complete bund excavation and wrapping removal indicated a

    remaining wall thickness of 2mm.

    Action Taken.

    Replaced the section of line prior to the bund replacement. .

    Lessons Learned / Design Change.

    Underground wrap systems breakdown over time. Wrap not reinstated, an underground paint specification was used.

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    Table 19 - Refinery B Case Study 16Diesel Treater Tank PV-1407

    Duty: Diesel Treater Tank PV-

    1407

    Material: Carbon steel

    Wall Thickness: X.X mm Damage mechanism: CUI

    Commissioning Date: 1952 Period of Metal Loss: 55 years

    Photograph:

    Description of Corrosion Mechanism or Detail.

    Severe corrosion detected at the bottom of the vessel, no sign of insulation deterioration was observed in the vessel and

    the insulation metal jacket looked in very good condition. Corrosion attack observed was generalized severe corrosion

    with thick corrosion product scale. The insulation under the metal jacket was in poor condition.

    Action Taken.

    Vessel replacement, Root Cause Analysis.

    Lessons Learned / Design Change.

    The metal jacket or cladding was new. The insulation was in extremely poor condition when the cladding was removed.

    This revealed a general corrosion attack with a thick corrosion products scale. The vessel was replaced and a Root

    Cause Analysis initiated. Poor coating application and cladding over damaged insulation were noted as potential causes.

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    Table 19 - Refinery B Case Study 17FCC Fractionator Top Reflux Out of Overhead Accumulator

    Piping Circuit

    Duty: FCC Fractionator Top

    Reflux

    Material: Carbon steel

    Wall Thickness: X.X mm Damage mechanism: Contact Point

    Commissioning Date: 1949 Period of Metal Loss: 58 years

    Photograph:

    Description of Corrosion Mechanism or Detail.

    A pinhole leak was detected at a support contact point, where a pack of cables created room for debris and rust

    accumulation. Corrosion attack observed was severe with very localized pitting corrosion at the contact point (6:00)

    Action Taken.

    Piping section replaced with a contact point bonded pad.

    Lessons Learned / Design Change

    GUL is not always the best technique for contact point inspection because of the very localized nature of this attack.

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    Table 20 - Refinery B Case Study 18Tank Farm Distillate Line

    Duty: Tank Farm Distillate Line Material: Carbon steel

    Wall Thickness: X.X mm Damage mechanism: Soil to Air Interface

    Commissioning Date: 1977 Period of Metal Loss: 30 years

    Photograph:

    Description of Corrosion Mechanism or Detail.

    A pinhole leak was detected at a soil to air interface at the sides of a road crossing. The corrosion observed was severe

    with very localized pitting corrosion at the soil to air interface on both the sides of the road crossing, where the

    coating/wrapping was in poor condition.

    Action Taken.

    Piping section replaced and coating repaired as per ConocoPhillips Refining Engineering Practices

    Lessons Learned / Design Change.

    GUL is not the best technique for soil to air interfaces inspection because of the very localized nature of this attack and

    attenuation produced by the coating and buried conditions

    REFERENCES

    1. Meeting on Corrosion underInsulation November 1980.2. James Richardson A review of the European meeting on Corrosion under Lagging held in

    England, November 1980, ASTM 880 Corrosion of Metals under Thermal Insulation Ed.

    Pollock/Barnhart, pp42-59

    3. EFC WP13 and WP15Corrosion under Insulation (CUI) GuidelinesEuropean Federation ofCorrosion (EFC) 2007.

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    APPENDICES

    Visual Inspection of Pipe work located within the Unit Piperacks

    Introduction

    An external Visual Inspection was carried out on the piping systems within the Unit pipe racks by

    ConocoPhillips and Oceaneering Inspection personnel.Objectives

    The objective of the inspection was to inspect all the piping systems within the unit to determine the

    external integrity of the piping and to address any immediate problems with a view to making any

    recommendations for any further inspections, which may be required.

    Method

    Fall arrest trained inspection personnel were used to visually inspect all the pipe work within the

    confines of the pipe rack. Any areas of concern were assigned a severity rating, reported and

    photographed. The adopted system to identify the pipe work and its position is explained further in theGuidelines for Inspection of Pipe racks.

    The inspection addressed the following items:

    Insulation Pipe Supports Corrosion Mechanical Damage Paint Work

    The method used to apply a severity rating system is explained in the Guidelines for Inspection of

    Pipe racks.

    Results

    Any areas of immediate concern were followed up at the time of the inspection. Photographs were

    taken of any areas that were rated 4 or above. Any item with a severity rating of 3 or above was assigned

    a tag number which is referenced on the report and has been tagged on-site to help identification. Areas

    of concern at pipe supports and were pipes sit on concrete support beams were identified to allow further

    inspection using the Emat Inspection System, the results of which were reported separately.

    Recommendations

    Insulation - Any area with a severity rating of 3 or above indicates that the insulation has been

    compromised and may allow water ingress, which may lead to corrosion (CUI). Therefore, the

    insulation in these areas needs to be removed to allow further inspection.

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    Pipe Supports - Areas of concern which have been identified have now been scheduled for further

    inspection by Emat.

    Paintwork- Any area with a severity rating of 3 or above indicates that the paintwork has broken down

    sufficiently so that it does not provide the protection that was intended. Therefore, the pipe work needs

    cleaning and preparing to carry out remedial paintwork.

    Corrosion or Mechanical DamageAny Corrosion or Mechanical damage with a severity rating of 4

    or above will require further inspection. These areas will need access providing.

    In order to assist with the identification of the areas recommended for further work each item of concernhas been assigned a tag number which is included in the report and a yellow tag has been attached to the

    area of the pipe on site.

    For guidance examples of severity 4 and 5 ratings for each category are provided below;

    Assessment Examples

    Insulation

    Severity 4 Severity 5

    Pipe Supports

    Severity 4 Severity 5

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    Paintwork

    Severity 4 Severity 5

    Corrosion or Mechanical Damage

    Severity 4 Severity 5


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