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Aai presentation h2 s in crude 2011 copy

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The future of industrial process analysis.
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Page 1: Aai presentation   h2 s in crude 2011 copy

The future of industrial process analysis.

Page 2: Aai presentation   h2 s in crude 2011 copy

Introducing AAIOver 15 years experience in:

MANUFACTURING

DESIGNING

MARKETING

Page 3: Aai presentation   h2 s in crude 2011 copy

Advanced PROCESS ANALYZERS and SAMPLING SYSTEMS

For the PETROCHEMICAL, CHEMICAL, ENVIRONMENTAL, POWER GENERATION, PHARMACEUTICAL, and

SEMICONDUCTOR industries.

Introducing AAI

Page 4: Aai presentation   h2 s in crude 2011 copy

Our goal at AAI is to provide INNOVATIVE and ELEGANT process analyzers, sampling systems, and dedicated service.

Our emphases are ACCURACY, AUTOMATION, and SIMPLE RELIABILITY.

Mission Statement

Page 5: Aai presentation   h2 s in crude 2011 copy

Headquarters

BOSTONBOSTON

CONCORD, MA, USA

•SALES•MANUFACTURING•DESIGN•TRAINING•SUPPORT

Page 6: Aai presentation   h2 s in crude 2011 copy

SAN TOME, VENEZUELASystems: OMA-300 UV-VIS with two integrated MCP-200’sApplications: H2S, SO2, NOx, ammonia, methane, CO, CO2

OSAKA, JAPANSystems: OMA-300 H2S, TLG-837Applications: H2S, air demand (Tail Gas), sulfur pit

CADEREYTA, MEXICOSystems: TLG-837Applications: sulfur recovery tail gas (H2S, SO2, COS, CS2)

JUBAIL, SAUDI ARABIASystems: OMA-300 H2S Applications: H2S in water

FORT MCMURRAY, ALBERTA, CANADASystems: OMA-300 H2SApplications: H2S in natural gas (oil sands)

KARAMAY, CHINASystems: OMA-300 H2S, TLG-837Applications: Sulfur Recovery (H2S, SO2, COS, CS2)

WHITING, INDIANA, USASystems: OMA-300, TLG-837Applications: Sulfur Recovery (H2S, SO2, COS, CS2)

KANSAS CITY, KANSAS, USASystems: OMA-300 Chlorine with Teflon Sampling SystemApplications: Cl2, NCl3

GUJARAT, INDIASystems: OMA-300 H2S with integrated MCP-200Applications: H2S, R-SH, CO2

HOLSTEIN PLATFORM (OFFSHORE)Systems: OMA-300 H2S OFFSHORE EDITION Applications: H2S

RIO DE JANEIRO, BRAZILSystems: OMA-300 UV-VIS, Double Headspace Sampling SystemApplications: H2S, ammonia in water

RAS LAFFAN, QATARSystems: OMA-300, TLG-837Applications: H2S, mercaptans, air demand (tail gas)

Key References

Page 7: Aai presentation   h2 s in crude 2011 copy

ABSORBANCEANALYTE

CONCENTRATION

MOLAR ABSORPTION COEFFICIENT

PATH LENGTH

(Derived from Beer-Lambert Law)

=

(constants)

Basis

Page 8: Aai presentation   h2 s in crude 2011 copy

Optical Design

Page 9: Aai presentation   h2 s in crude 2011 copy

The OMA Series

SOLID STATE DIODE ARRAY TECHNOLOGYUnrivaled accuracy in online analysis.

classic (stainless steel)explosion-prooffiberglassrack-mountedportable

MULTI-SPECIES MONITORINGdriven by proprietary software & background correction method

CONTINUOUS RELIABILITYOMA delivers true automation for modern process control—no moving parts, no consumables, and no labor

applications?

MEHQaromatics

benzenetitanium oxide

chlorine

EDC purity

metal ions

CEMammonia slip

sulfur recovery

semiconductor chemistrydiesel in jet fuel

clean-in-place

oil in water

TBC

glycols in water

color

CONTINUOUS EMISSIONS

MONITORINGOIL IN WATER

SULFUR RECOVERY

Page 10: Aai presentation   h2 s in crude 2011 copy

nova-II SpectrometerDIODE ARRAY1,024 photodiodes for high-res spectra

BROAD SPECTRAL RESPONSE190-1100nm wavelength range

MAXIMAL LIGHT THROUGHPUTstate-of-the-art optics, powerful Xe source

EXCEPTIONAL IN LOW UVminimal stray light

CMOS ANALOG CIRCUITRYlow noise, low power consumption

ETHERNET INTERFACEfor remote access

Page 11: Aai presentation   h2 s in crude 2011 copy

FOCUS: Measuring H2S in Crude Oil

Page 12: Aai presentation   h2 s in crude 2011 copy

OMA-300 H2S

WIDE DYNAMIC RANGE 0-10 ppm and 0-100 % in one analyzer with uncompromised accuracy; no dilutions or sample distortion (as required in lead acetate tape methods)

CORRECTS FOR AROMATICS no mis-attributed absorbance

FIBER OPTIC CONNECTIVITY electronics safe from corrosive H2S

SOLID STATE DIODE ARRAY no filters, no malfunctioning moving parts

H2S aromatics (BTX) mercaptans

SO2 COS

MONITORED SPECIES: H2S, SO2, COS, aromatics (BTX), mercaptans

Page 13: Aai presentation   h2 s in crude 2011 copy

The Crude Problem

Online H2S analysis is required to determine how much processing a specific crude stream requires and to differentiate crudes by commercial value.

BUT

Oil naturally contains aromatic compounds that absorb heavily in the UV range (blocking signal). To complicate matters, heavier crudes are too dark and dense to transmit a light signal.

Page 14: Aai presentation   h2 s in crude 2011 copy

What is ‘Headspace?’

Headspace sampling is designed to strip H2S out of an opaque liquid process such as crude oil.

A column of the liquid sample is heated such that H2S (low boiling pt) evaporates out of solution while the interfering components (high boiling pt) in the crude remain in solution.

A carrier gas is sent through the column to collect H2S vapor and bring it into the flow cell.

Page 15: Aai presentation   h2 s in crude 2011 copy

Headspace Sampling

Page 16: Aai presentation   h2 s in crude 2011 copy

Headspace System

APPLICATIONH2S in light crude

• Single headspace column• 600mm stainless steel flow cell

Page 17: Aai presentation   h2 s in crude 2011 copy

Technical Drawing

Page 18: Aai presentation   h2 s in crude 2011 copy

www.a-a-inc.com


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