Absorbtion of Sulfamethoxazole an Organic Pollutant
By: Juan Martinez
Raised in Texas Pearsall High School
College Credit Summer Prep Track Basketball
Texas A&M University Kingsville Basketball Track AAEE
Background
The summer pre freshmen engineering program (PREP) molded my brain and in my 4th year the focus of the program was water management and treatment.
PREP took the 4th year students on a tour to San Antonio Water Systems (SAWS) we saw the water management and treatment systems.
Motivation
The research objective was to remove pharmaceuticals from waste water and storm water. The removal of pharmaceuticals would
protect fish populations and prevent undetermined long term health effects on humans
Objective
Need for a low-cost sorbent Wastewater emerging
contaminants Pharmaceuticals and
personal care products Indirect water reuse
Improve drinking water source quality
Remove natural organic matter (NOM) DBP precursorsIncreasing loads of synthetic organics, such as pesticides in developing countries
So there is a need for removal but there is still yet a demand to remove these compounds Sulfamethoxazole was used in the study
It is used to treat urinary tract infections Removal of compounds by adsorption to a solid
material (adsorbent) Bio Chars can become to answer to a problem
that we know about, but refuse to look at.
adsorption
Important Materials
Chars Bio solids (BS) Forced Draft Pine
(FD) Natural Draft Pine
(ND) Powder Activated
Carbon (PAC) Eucalyptus Low
Temperature (LOW)
Waters Big Elk Meadow
(BEM) Deionized (DI) Stormwater (SW) Waste Water (WW)
brick beehive kilnRoyal Thai Forestry DepartmentWood Energy Research CentreSaraburi Province, Thailand
Procedure
Muffled Glass and Filters 500 degrees C 3 hours for Glass 2 hours for filters
Procedure
Jar tester Initial speed 250 RPM
for 1 min Constant Speed 70
RPM Test times
10min 30min 60min
Procedure
Procedure
4 ml of treated water 2 pumps of the
cocktail set to 8ml Cocktail
Solvent Surfactant Fluors or Scintillators
Results
BEM Ranking1. PAC2. FD3. BS 4. ND5. LOW
DI Ranking1. PAC2. FD3. BS4. ND5. Low
FD and PAC
0 5 10 15 20 25 30 35 40 45-20
0
20
40
60
80
100
120
PAC DI
10 min10 min30 min30 min60 min60 min14 days7 days
Dose
Perc
ent
Rem
aini
ng
0 20 40 60 80 100 120 140-20
0
20
40
60
80
100
120FD DI
10 min30 min60 min10 min30 min60 min14 days7 days
Dose
Perc
ent
Rem
aini
ng
Results Waste Water
0 50 100 150 200 250 3000
20
40
60
80
100
120
PAC WW
10 min30 min60 min
Dose
Perc
ent
Rem
aini
ng
Results Waste Water
0 50 100 150 200 250 3000
20
40
60
80
100
120
FD WW
10 min30 min60 min
Dose
Perc
ent
Rem
aini
ng
Results Waste Water
0 50 100 150 200 250 3000
20
40
60
80
100
120
WW
10 min30 min60 min10 min30 min60 min
Dose
Perc
ent
Rem
aini
ng
Results Storm Water
0 50 100 150 200 250 300 350 4000
20
40
60
80
100
120
FD SW
10 min30 min60 min
Dose
Perc
ent
Rem
aini
ng
Results Storm Water
0 50 100 150 200 2500
20
40
60
80
100
120
PAC SW
10 min30 min60 min
Dose
Perc
ent
Rem
aini
ng
Results Storm Water
0 50 100 150 200 2500
20
40
60
80
100
120
SW
10 min30 min60 min10 min30 min60 min
Dose
Perc
ent
Rem
aini
ng
PAC was the best performing char used but there is still data proving other options are available
The experiment has room for improvement and expansion
Future test many look at the other chars not searched here
Future test may have a mixture of chars The field of biochar had the potential to solve the
growing issue with pharmaceuticals in the water
Conclusion
Ryan B Mahoney Kyle Shimabuku
Dr. Lupita Montoya
Dr. Scott Summers
Acknowledgments
QUESTIONS?
PREGUNTAS?