ACCELERATOR DIVISIONWASTE GENERATOR’S TRAINING

Responsibilities

Waste Characterization

Container Labeling

SAA RequirementsREVISED 06/03/2010

1

TRAINING IS FOR YOU• Generate a regulated

waste

• Assist in the generation of a regulated waste;

• Add a regulated waste to container;

• Inspect SAA

• Engage in activities that involve exposure to, or management of a regulated waste

3

Chemical Waste Contacts• Sylvia Wilson, AD/Waste Coordinator

(WC) Ext. 4489 or Pager #s: 0614/ 630-218-3268

• Barry Fritz, alternate WC Ext. 2230 or Pager # 0125

4

Rad Waste Contact

• Tony Busch, AD/Rad WC Ext. 6527 or Pager #s: 0250/ 630-722-3856

5

Waste Generator’s Responsibility• Characterize, package,

label and store waste properly;

• Complete appropriate waste forms;

• Make every effort to reduce the amount of waste generated (substitute with a less hazardous material, reuse materials, recycle chemicals)

• And whenever in doubt, seek the advice of a WC

6

Waste Coordinator’s Responsibility

• Provide guidance and training;

• Review and approve Chemical Waste Pickup Request Forms;

• Conduct and document waste inspections.

In the AD, inspections are conducted quarterly

AD/RESOURCES MSDS Binders

(located in AD areas where chemicals are used)

7

8

AD/RESOURCES

• ADSP-08-0202 Regulated Waste Management

• Chemical Inventory Database *

*Must have network access to

Beamssrv1\esh.bd\public and

Filemaker Pro version 7.0

910-2009

Chemical Inventory Database e.g. Ethanol

• Chemicals and information

• Manufacturer’s Info. Name, Telephone

10

Chemical Database continuation

• Waste Codes (EPA) H/D001 (ignitable)

• Chemical locationFlammable cabinet, corrosive cabinet, chemical cabinet

• other

11

Waste Characterization

• IS IT A WASTE?

Some items are reusable. Reusable labels shall be used for identifying these items (e.g. ethanol).

DON’T USE WASTE LABELS.

REUSABLE

12

13

1. RADIOACTIVE?

• Did it come from a radiation area?

If so, the material may be a radioactive or mixed waste.

• Items must be surveyedNote: only certain chemicals are approved to be used in rad areas (i.e., KPC 820N).

• For assistance, contact a Radiological Technician.

14

2. TRASHABLE no chemicals/ liquids

• Regular garbage and shop trash

• Empty containers rendered unusable *(carboys, poly and fiberboard drums) –

remove the cap or cut the container in half so it

can’t be reused for draining fluids from vehicles

or motor equipment

15

TRASHABLE

BROKEN WOODEN PALLETS

• may only go into a 20 yd3 dumpster. Contact Sue Populorum @ X-3876.

• Contact Larry Rodriguez (BS) @ X-4225 to have pallets picked up from your location.

16

3. RECYCLABLE?free liquid

• Electronic components (printed circuit boards, ballasts ), wire, empty cans, toxic metals, i.e., lead and silver solders, etc.

17

3. RECYCLABLE?

Electronic ballasts

Remove the NiCd battery* prior to recycling

*RECYCLE AS UW

18

Lead and Silver Solder

• Hand soldering is common - assembly and repair of electronic parts.

• Best way to manage solder is to use it up completely; however, this doesn’t always happen.

19

Lead and Silver Solder

RECYCLABLE

Disposal as regular trash is PROHIBITED

20

Lead and Silver Solder

RECYCLABLE

The Silver and lead concentration from waste (drippings) generated from soldering operations is too high & therefore will fail EPA’s toxic limit (5mg/L)

21

3. RECYCLABLE?

When solder waste is recycled,

hazardous waste classification

may be avoided

22

RECYCLING PROCEDURES

for LEAD or SILVER Recyclable

• Container must have a lid (e.g., coffee can or poly bottle)

• Container must be marked Recyclable Lead or Silver Solder

23

LEAD [Ag] SOLDER PROCEDURESRecyclable

• Lead and silver solder must be segregated

• Container shall remain closed unless adding or removing solder

• When full, secure lid to container (tape)

24

LEAD [Ag] SOLDER PROCEDURESRecyclable

2 OPTIONS (pickup)

• Contact Mike Frett (Mechanical

Dept.) or AD/WC to utilize scrap metal bins (X/Gallery)

• Or complete a Material Move Request Form to have it picked up from your location

25

Paint CansRecyclable

Empty aerosol/paint cans

Only water based paint, with a minimum volume of liquid left in the metal can, may be left open to air dry before recycling the can.

Note: Oil dry or kitty litter can also be used to absorb any liquid

26

Oil Based Paints

However, containers with leftover oil based paint must be processed as

“hazardous waste” and can’t be left- open to

air dry.

27

AD X/Gallery High Bay

(AD common collection site)(RECYCLABLE MAT’LS)

289/1/2010

Use Appropriate Container for Recyclable Materials

1. Unusable and Empty spray paints only

2. Empty metal cans 2 gallon .

29Rev. 10/09

RECYCLABLE

EMPTY PESTICIDE AEROSOL CANS ONLY

3. RECYCLABLE Alkaline Batteries

9 Volt (tape positive terminals to prevent fire or sparking)

Carbon Zinc or ManganeseNickel Oxy Hydroxide

30

3. RECYCLABLEuse battery recycling containers in your areas.

Location: X/Gallery Hi-Bay (common site) Managed by the AD/WC

31

32

RECYCLABLE MATERIALSFERMI’s Recyclable Program is

intended only for materials generated @ the lab.

HOUSEHOLD WASTE (HHW) shall remain @ home. Individuals should continue to use:

• County Waste Program

(curbside recycling and HHW days)

33*staff reduction

RECYCLING (HOUSEHOLD)

HHW drop off facility

Location: Naperville Fire Station #4 (rear of station)

Corner of Rt. 59 & Brookdale (1/2 mile south of I-88)

Hours*: 9 a.m. To 2 p.m

Saturdays and Sundays

Website: www.naperville.il.us

Department of Public Works

Tel. #: 630-420-4190,

34

Naperville

ACCEPTABLE:

Auto fluids (oil, gas, anti-freeze)BatteriesHousehold cleaners, drain openersFertilizerFlammablesHerbicides, insecticidesFluorescent bulbs, CFLMercuryMineral spirits, strippers, solventsPaints and stains (oil and alkyd)Prescription medicationsPropane tanks ( 20 lbs)ThermostatsUnknown hazardous substances

NON-ACCEPTABLE:

Explosives, AmmunitionRadioactive materialsCompressed gas (other than

propaneElectronicsEmpty paint cans and containersLatex PaintsSharpsSmoke DetectorsTiresTrash and non-hazardous materialsUnopened, useable consumer

35

4. Is it HAZARDOUS?Does it exhibit one or more of these

characteristic?

40 CFR 261

36

IGNITABLEWaste Code: D001

CFR 261.21

Flash point < 140°F

Not a liquid, but capable of causing a fire by friction, absorption of moisture or spontaneous chemical changes

37

IGNITABLED001

Ignitable compressed gas

Oxidizer (49CFR173.151)

38

Ignitable Examples

• Petroleum based paints

• Usually Alcohols and solvents

Ethyl alcohol (flash p = 55°F)

39

CORROSIVE Waste Code: D002

CFR 261.22

Aqueous and pH 2 or 12.5

Liquid and corrodes steel @ rate > ¼”/year @ test temperature of 130°F

RYDLYME (< or =1)COPPERBRITE

40

CORROSIVE (AD Incident)

Lessons Learned Incident: Feb. 16, 2006

Involved: Mislabeled/Mischaracterized 55 gallon drum of liquid

Waste Stream: descaling operation. What Happened? • Generator used pH paper to

check the pH. Results = 3• Drum of liquid was labeled

SPECIAL WASTE and submitted to the Waste Coordinator for approval.

41

CORROSIVE (AD Incident)

Form was approved and submitted to ESH/HCTT for pickup.

• At Site 55 (HWSF), the HCTT technician conducted a routine pH check of the waste, using 0-14 pH strips and the results = 0 to 1

42

CORROSIVE (AD Incident)

He conducts another pH test using 0-6 range pH strips, increments of 0.5 for better accuracy. Results this time = 0

• HCTT technician reclassified & relabeled the waste, HAZARDOUS WASTE

Notified the AD Waste Coordinator of the error.

43

CORROSIVE Methods to Prevent this

outdated pH paper 5 yr shelf life

ALTERNATIVES• pH strips have no shelf life

• calibrated pH meter

44

REACTIVE Waste Code: D003

CFR 261.23

Normally unstable and readily undergoes violent change w/o detonating;

Reacts violently w/water; generate toxic gases, fumes, and vapors

Explosives

Cyanides

AP0 - LITHIUM METAL

45

TOXICWaste Code: D004 – D043

CFR 261.24.

If the concentration of the contaminant exceeds EPA’s regulatory limits, the waste is hazardous.

• Metals – lead (5 mg/L) Common to test old paint on bldgs and other bldg structures for toxic metals

• Organics – methyl ethyl ketone (200 mg/L)

• Pesticides – lindane (0.4 mg/L)

46

4. HAZARDOUS?

Is it a listed EPA hazardous waste

•Non-specific

•Specific

47

LISTED HAZARDOUS WASTE?(261.32)

K- listed - hazardous waste from specific manufacture of inks, organic or inorganic chemicals and pigments, petroleum refining, iron and steel industries, wood preserving, manufacture of pesticides

Not generated @ FNAL

48

LISTED HAZARDOUS WASTE?

CFR 261.31

•The F- Listed waste is from nonspecific sources and includes spent solvents used in degreasing or other solvent operations,

and various spent solvents no longer useful

•EPA Waste Codes: F001 – F039

49

F- LISTED HAZARDOUS WASTE

• Common @ Fermi spent halogenated and non-halogenated

Waste Codes

F001

F002

F003

F005

50

F – Listed WasteF001 – spent halogenated solvents (degreasing)

1,1,1- trichloroethane

methylene chloride

tetrachloroethylene

trichloroethylene

carbon tetrachloride

chlorinated fluorocarbons

Includes all spent solvent mixtures/blends used in degreasing, containing, before use, a total of 10% or more (by volume) of one or more of these halogenated solvents or those listed in F002, F004, F005…

51

F – Listed Waste

F002 – spent halogenated solvents (non- degreasing)

1,1,1- trichloroethane

methylene chloride

tetrachloroethylene

trichloroethylene

carbon tetrachloride

chlorinated fluorocarbons

Includes all spent solvent mixtures/blends, containing, before use, a total of 10% or more (by volume) of one or more of these halogenated solvents or those listed in F001, F004, F005.

52

F – Listed Wasterevised 6/2/2010

Solvent Contaminated Rags/Wipes

with F001 and F002

must be managed as Hazardous Waste It is prohibited to purposely allow rags to air dry. Rags must be contained inside of an approved container.

53

F003 – Listed Waste

Acetone,

methanol

xylene

Ethyl acetate,

ethyl benzene

ethyl ether,

ethyl isobutyl ketone

n-butyl alcohol

Cyclohexanone

All spent solvent mixtures/blends containing, before use, only the above spent

nonhalogenated solvents; and all spent solvent mixtures/blends containing, before use,

one or more of the above solvents, and a total of 10% or more (by volume) of one or

more of these halogenated solvents or those listed in F001, F002, F004 and F005

54

F – Listed WasteF005 – spent non-halogenated solvents

Toluene

methyl ethyl ketone

carbon disulfide

isobutanol

Pyridine

benzene

2-ethoxyethanol

2-nitropropane

All spent solvent mixtures/blends containing, before use, a total of ten percent or more (by volume) of one or more of the above nonhalogenated solvents or those solvents listed in F001, F002, F004

55

Are managed as Hazardous Waste and can be commingled with other flammable solvent rags (i.e., ethanol , isopropanol, mineral spirits).

F003 and F005 Rags/Wipes

revised 6/2/2010

56

Continuation of

It is prohibited to purposely air dry solvent rags and wipes

• Solvents naturally evaporate from rags and wipes during the course of their use. This is unavoidable and it is acceptable if rags and wipes become devoid of free liquids in this way. However, it is not permissible to spread wet rags/wipes out to

deliberately allow them to dry. This is considered treatment and would require a special permit from IEPA. It also would potentially create

safety and health hazards and contribute to ground-level ozone (i.e., smog) formation. Hint: Try to minimize the amount of solvent you apply to the rag/wipe. Use repeated applications, if necessary, rather than saturating the rag/wipe with solvent.

57

5. Other Contaminated Rags and Wipes

• Hazardous Waste

• Special Waste

58Revised 6/2/2010

PROPER DISPOSAL OF CONTAMINATED WIPES/RAGS

Contaminant Category/Conditions Waste Code

Lead

Lead-contaminated items Hazardous D008

Beryllium SPECIAL None

Beryllium powder Hazardous P015

Solvents

Mineral spirits, ethanol, xylene, acetone, methanol

HAZARDOUS •Collect rags in a labeled garbage bag and place contaminated wipes inside of an approved container•Disposal in regular trash is prohibited !

D001 and F003

Mineral spirits, ethanol, isopropanol

Hazardous D001

59

P-Listed Waste (acutely toxic)40 CFR 261.33

may cause severe health effects and have been found to be fatal to humans in low doses; if scientific studies shown it has lethal effects on experimental animals or if it

causes serious irreversible or incapacitating illiness

Discarded/commercial chemical products (expired), off-specification species, container residues and spill residues

P-Waste must also be 100% of the waste or be the sole active ingredient

60

P-Listed Waste (acutely toxic)

EPA Waste Codes: P001 – P205

beryllium powder P015 Sodium azide – P105

61

U – Listed Waste (toxic)Although harmful, isn’t as toxic as P-listed waste. U- waste includes chemicals that

display other characteristics, I.e. ignitable , corrosive, reactive , toxic (40CFR261.33)

Discarded Commercial Chemical Products

EPA Waste Codes

U001 – U411

EXAMPLES acetone (U002) methanol (U154)

How to Get Rid of Unwanted/Useable Chemicals

62

EXCESS CHEMICAL DATABASE

FNAL established has a database to facilitate the exchange of chemicals

between groups at the lab.

63

6410/21/09

EXCESS CHEMICAL DATABASE

Information includes a table comprised of unwanted; however, reuseable chemicals from various division and sections

• Chemical name, • Condition of the chemical, • Contact person • Any comments regarding the chemical

65

click on : Waste Minimization AD Waste Min./Pollution Prevention Info)

quick link to: EXCESS CHEMICAL LIST

66

Administration

Computer Support

ES&H Tools

Environment

Fire Department

Industrial Hygiene

Medical

People

Radiation

Etc.

Quick LinksQuick Links

•DocDB ESHS

•Emergency Info

•Excess Chemical List

•FAQs

•Forms/Services

•Lab Safety Cmte

•Login/Create Account

•MSDS Search

•Etc.

67

Chemical MSDS CAS Volume/Wt. Qty. Remaining Grade Condition Comments Expires Contact

CANTEX 14799 5 @ 1 gallon each

5 @ 1 gal each unused unknown 01/15/2010 Sylvia Wilson

CHLOR RID 15325 1 x 5 gal 1 x 2.5 gal opened Condition is good

02/27/2010 Sylvia F. Wilson

PRIMER S-911 PVC NO. 10

PURPLE WELDING SOLVENT

18813 5 @ 1 gal each 5 @ 1 gal each unused unknown 01/15/2010 Sylvia F. Wilson

68

Excess Chemicals on the Database

If you see a chemical on the database or if you want to put a chemical on the list

• Contact the WC or ES&H personnel

69

Excess Chemicals on the Database

• DON’T BRING your unwanted, reusable chemicals to the DIV/ESH DEPARTMENT. It should remain in your location

• You can also subscribe to this website http://www-esh.fnal.gov/owa user/esh mailing lists.html. 

This can save the lab money!

70

Before ordering new chemicals

• Fermilab’s Excess Chemical List

• Contact the Waste Coordinator

AD Chemical Inventory/MSDS Database

HAZARDOUS WASTE LABELTHE ACCUMULATION START DATE BEGINS WHEN 55 GALLON VOLUME LIMIT, OR 1 QT. VOLUME LIMIT FOR P-LISTED

WASTE IS EXCEEDED. OTHERWISE THE START DATE BEGINS AT THE LAB’S PERMITTED SITE (SITE 55)

71

72

6. SPECIAL WASTE

Special waste is a waste that isn’t hazardous as defined by RCRA; however, there are state regulations that govern the transportation and disposal of these types of waste.

Liquids and TSCA materials. TSCA: to control substances determined to cause

unreasonable risk to public health or the environment.  Asbestos abatement and the use, storage, transport and disposal of polychlorinated biphenyls (PCBs) are included in these regulations.

73

INDUSTRIAL PROCESS WASTE

POLLUTION CONTROL WASTE

PIMW (potentially infectious medical waste)

Liquid, solid, semisolid, or gaseous waste generated when manufacturing a product or performing a service

Examples: cutting lubricants, equipment cleanings, used solvents from parts cleaners, polychlorinated biphenyls (PCBs) containing materials.

Pollution control waste is generated when contaminants are removed from the air, soil, or water.

Examples: Cleanup waste from PCB spills (includes empty containers) and asbestos-containing materials (ACM) generated during demolition and renovation operations.

Generated in connection with diagnosis, treatment, medical research, biological testing, immunization of humans or animals.

Examples: Needles, syringes, medical sharps, bandages

74

BALLAST/CAPACITOR

• Capacitor and ballast manufactured after July 1, 1978 that didn’t contain PCB’s should be marked No PCB's if it didn’t contain PCBs .

• If unmarked, the item should be treated as PCB contaminated..

75

IMPORTANTNon-PCB liquid filled ballast

Can’t be disposed of via dumpster because they may contain a toxic fluid (diethylhexyl phthalate*) or other fluids (oil). These types of ballasts shall be discarded as Special Waste.

* If unused, the waste code would be U028.

76

Mandatory Requirements for PCB Materials

included in handout

• Temporary storage areas must be labeled with Large PCB Mark - label that is 6”x 6”

77

Mandatory Requirements for PCB Materials

included in handout

• Both Special Waste and PCB labels must be affixed to the waste container. Avoid covering manufacturer’s information

• Contact the WC for labels.

78

Mandatory Requirements for PCB Materials

• The out-of-service date must be marked on the “Special Waste” label. If items are collected in a container, the earliest out-of-service date applies.

• Capacitors and ballasts may only be stored at the SAA for up to 30 days from the date of removal from service.

• Chemical Waste Pickup Request Form must be completed promptly.

79

Mandatory Requirements for PCB Materials

included in handout

• Leaky capacitors and ballasts - containerized and separated from non-leaky capacitors.

• Containers shall be in good condition and labeled

• Use only non-regulated metal to short out your capacitors

80

Mandatory Requirements – PCB Mat’ls

• Hi-Bay/X-Gallery SAA is for approved, non-radioactive PCB capacitors and ballasts only.

• Generators should notify the waste coordinator prior to placing any PCB waste at this location to ensure that the waste is being processed promptly.

81

PCB COLLECTION SITEX/GAL

82

SPECIAL WASTE LABELS

ASBESTOS WASTE

• The contractor is responsible for labeling ACM (pre-printed marked bags or containers).

• The WC is responsible

for affixing a “Special Waste” label to the waste.

SPECIAL WASTE LABELTHE ACCUMULATION START DATE BEGINS AT THE TIME OF WASTE ACCUMUATION

83

84

Absorbed Waste from Cleanupsoil/glycol

Trashable: Usually involves non-contaminated absorbent materials (wipes, rags, pads) from non-PCB oil or glycol cleanups

Rule of thumb: ≤1 ft3/dumpster and waste should be double bagged.

Large liquid spills – Used Oil or Special Waste

85

WHAT IS COLD SOLVENT CLEANING? (Cleaning electronic components and wipe cleaning aren’t included)

Process of cleaning and removing grease, wax and other impurities from metal and other parts and keeping the solvent below its boiling point (BP). If it exceeds its BP it is vapor degreasing and requires a permit.

Also referred to as degreasing or parts washing

86

Cold Solvent Cleaning

1. Degreasers must remain closed when parts aren’t handled (prevent evaporation and ground level ozone (smog)

2. Cleaned parts must be drained inside the degreaser until drip free.

3. Waste solvent shall be stored in a covered container.

87

Cold CleaningDept Heads should notify

the EO whenever:

• New potential air emission sources are introduced

• Modifications to your operations that increases the amount of air contaminants being released

88

Cold CleaningMore Information :

• ADSP-08-0501, AIR EMISSION SOURCE PROGRAM

89

7. USED OILS

• All transformer oils (Shell Diala) and petroleum based oils > 5 gallons are tested for halogens (i.e., PCBs, CFCs (freons)

90

USED OIL CONTINUATION

• If oil is contaminated, then another sample is taken and analyzed off-site

• Also there is a storage limitation of no more than 3 days for contaminated oil (i.e., freon) to be stored at a SAA.

• Greater than 55 gallons of oil must be relocated to the lab’s permitted facility (Site 55)

91

USED OIL CONTINUATION

Oils contaminated with PCB and CFC can’t be recycled.

DON’T use the same chemical funnel to transfer oils

USED OIL

89

93

8. USED OIL FILTERSnon-radioactive

• NON-REGULATED WASTE and can’t be disposed of as regular trash.

• Must be stored in a covered and sealed container for disposal.

New Non-Reg Label

94

95

9. MIXED WASTERadioactive and Hazardous

Must comply :• EPA (RCRA) Code

• FERMI’S Radiation Policies & Waste Procedures (ADSP-10-0201)

+

9611/5/09

10. UNIVERSAL WASTE (UW) (hazardous waste)

40 CFR 273

Materials are recycled and managed in accordance with UW requirements

BatteriesFluorescent Lamps & HID

Mercury Containing Devices

976/2/2010

UNIVERSAL WASTE 40 CFR 273.2

BATTERIES,

• LEAD ACIDLEAD ACID*• LITHIUM• NICKEL CADMIUM• SILVER OXIDE• MERCURY• Nickel Metal Hydride

(NMh)

* * Generators should tape the Generators should tape the positive terminalpositive terminalss

Universal (batteries)

98

99

AD/COMMON COLLECTION SITE BATTERIES

100

Fluorescent and High Intensity Lamps (Universal Waste)

40 CFR 273.14

Compact fluorescent lamps (CFLs)

(a) twin-tube integral,

(b) triple-tube integral,

(c) triple-tube integral,

(d) integral model with

casing that reduces

glare,

(e) modular circline and

ballast, and

(f)modular quad-tube and

ballast.

CFLs can be installed in regular incandescent fixtures

and consume less than one-third as much

electricity as incandescent lamps do.

101

102

Fluorescent and High Intensity Lamps (Universal Waste)

40 CFR 273.14

PACKAGE LAMPS PROPERLY

to prevent breakage and release of toxic vapors

• ORIGINAL PACKING BOXORIGINAL PACKING BOX

• POLY SLEEVES (WC)POLY SLEEVES (WC)

103

MANAGEMENT OF BROKEN FLUORESCENT LAMPS

All spill debris must be cleaned up and placed inside of a structurally sound, sealed, and labeled container

104

105

Spent LampsFinal Collection Point

Site 38 RAD SURVEY & LABEL LAMPS

106

Spent LampsFinal Collection Point

Site 38 sign log sheet (clipboard)

107

UNIVERSAL WASTE MERCURY DEVICES

40 CFR 273.4 Thermostats, thermometers, barometers, switches

• Pack mercury devices in rigid, sealable containers with packing materials i.e., bubble wrap or other adequate materials to prevent breakage

• Store mercury devices in an inside, dry area not exposed to weather;

• Mark container with a “Universal Waste Mercury Containing Equipment” label

Universal (Hg devices)

108

109

12. UNKNOWNS

Chemicals should always be identified and labeled properly

Unfortunately, this doesn’t always happen.

110

UNKNOWN WASTE(abandoned)

• Creates serious concerns, problems and extra costs (sampling and analysis).

• Usually lacks the initial and necessary information to properly characterize the waste.

• Difficult to handle and store

111

WHAT CAN YOU DO?

1. Check w/others in the location to see if they may have any process knowledge of the waste or it’s origin

2. Look for written records, check the container for any legible markings (bar codes manufr/stock #s) on lid/bottom of container

3. Check to see if the material looks like another material already in use

112

WHAT CAN YOU DO?

• Contact the AD/Waste Coordinator.

• He/She will give you a form (Unknown Material Request Form) to complete

• Attach the completed form to a completed “Chemical Waste Pickup Request Form” and submit both forms to the WC for review and approval.

113

UNKNOWN MATERIAL REQUEST FORM• Requestor:____________________________________________ Phone

#:_____________________•   • Location of Material (Bldg/Room/Cabinet #) __________________________________________•  • Description of Container (size) ___________________________ (type) _____________________

1. General Description of the Material (aqueous, color, pH) • a) circle one: solid/ liquid/ oil/ multi-phase (describe)

• b) describe the material color:•   • c) describe the material texture:•   • d) Document pH results, only if it can be easily obtained.•  • e) Is there a distinct odor? Note: If the smell is not very obvious, then don’t sniff the

material.•   • f) Does the waste resemble another product normally used in the area that the unknown was

found?  • 2. PERSONNEL SURVEY: Describe the actions that you’ve taken to identify the waste (e.g.,

discussions with building and area managers, co-workers and contractors in the work area). AD/ESH Dept.

114

DON’T LET YOUR WASTE BECOME A STRANGER !

WAYS TO PREVENT UNKNOWNS

• Label all containers (i.e., product and waste containers).

• Don’t remove or cover the manufacturer’s label.

• Keep track of the expiration dates on materials and

• Use materials that are about to expire first.

• Only order what is necessary to do the task to prevent unnecessary chemical waste.

115

Ways to Prevent Unknowns

• Get rid of chemicals you don’t want or plan on using in the future.

• Secure loose and deteriorating labels on containers

• Complete a waste pickup form to ensure that waste does not have a chance to remain in a work area and be forgotten.

116

UNKNOWN(catastrophic event)

• If you find any unlabeled chemical that has crystallized or there is any other indication that it may be unstable, DO NOT TOUCH IT!

• Contact the WC or AD/ES&H Department

ASAP

Labels Available

117

118

12. EMPTY CONTAINERS40 CFR 261.7

A container is considered empty when all materials have been removed, using common practices e.g., pouring, pumping, aspirating

119

EMPTY CONTAINERSall metal cans > 5 gallons

•Complete a waste form and check Non-Regulated category on the form

•Label the container with an “EMPTY” label.

Note: Containers that once contained a “P-listed” waste shall be disposed of as a “Hazardous Waste”

121

Satellite Accumulation Areas (SAA)

• Label waste containers @ the time of accumulation

• Containers shall be compatible with the waste/chemical (preferred manufacturer’s container)

• Ensure chemical compatibility with other nearby waste (MSDS)

122

Satellite Accumulation Areas (SAA)

• Inspect containers for corrosion, leaks and deterioration

• Containers shall remain closed, unless adding or removing waste

• Hazardous waste must remain @ SAA

123

Satellite Accumulation Areas (SAA)

• Use secondary containment when storing hazardous waste near or with products.

• Hazardous waste shall never exceed 55 gallons or 1 qt of P-listed waste @ the SAA

124

Common Mistakes @ SAA(delay pickup)

• Unable to locate item

• SAA isn’t accessible

• Containers should be clean & free of liquid residue on lids and side surfaces

125

Common Mistakes @ SAA(delay pickup)

• Incomplete or improperly labeled item(s)

• Containers without tight fitting lids or closures

• Information on label is defaced

Use a Sharpie permanent black marker, other

colors will fade due to sunlight and weather

conditions

126

Common Mistakes @ SAA(delay pickup)

• Integrity of the waste container is poor (corroded, not road worthy, leaky, etc)

• Containers aren’t protected outdoors (i.e., no lid covers, conditions too cold for outdoor storage, snowbound

127

D R U M CA P ACITY(problem @ SAA)

• Drum is too full. Drums can hold more than 55 gallons. Extra space allows liquids to expand in the container due to temperature.

• Rule of thumb - maintain at least 3” of headspace in waste container.

Bulging containers present a safety hazard for others who handle them

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WCoordinator55 - gallon bung drums55 -gallon open head steel drums 55 gallon bung type poly drums 1- 10 gallon poly buckets w/lids5 gallon used carboys for non-hazardous liquids

Stockroom 5 gallon carboys HDPE bottles cans w/lid

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COLLECTION WASTE PICKUP SCHEDULE

• 1st and 3rd Wednesday of each month

• CHEMICAL WASTE PICKUP REQUEST FORM (ES&H Websites)

Acelerator Division Home

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Quick Links Report Safety ConcernESH NewslettersAD ESH PlanAD Injury Rates & GoalsESH Contacts

ESH SECTION• Forms/Services

PPE & Equipment AvailabilityEmployee Safety Suggestions

ESH Department AD LinksBldg Managemt.

ENVIRONT’L PROTECTION

•Waste Managemt Guidance

Interlocks, RAD Protection,etc.

Fermi at Work Accelerator Division Home Fermilab Phone/Email

http://www-bdnew.fnal.gov/esh/Default.htm

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Administration

Computer Support

ES&H Tools

Environment

Fire Department

Industrial Hygiene

Medical

People

Radiation

Etc.

Quick LinksQuick Links

•DocDB ESHS

•Emergency Info

•Excess Chemical List

•FAQs

•Forms/Services

•Lab Safety Cmte

•Login/Create Account

•MSDS Search

•Etc.

Link to ES&H Section

ES&H, Environmental Protection, Hazard Control Team, Forms & Instructions

Instructions for Hazard Control Technology Team File Maker Pro Forms

WASTE TYPE FileMaker Pro Version

PDF VERSION INSTRUCTIONS

Radioactive Waste Certification and Pickup

Request Form Request Form HTML PDF

Rad. Waste Certification and Pickup- Continuation Sheet

Continuation Sheet

Chemical Waste Certification and Pickup Form

Request Form Request Form HTML PDF

Haz. Radioactive Mixed Waste Certification and Pickup

Request Form Request Form HTML PDF

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REVISED

CHEMICAL WASTE PICKUP REQUEST FORM

11/11/2008

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REVISION Chemical Waste Pickup Request Form

Comments section:

All items have been evaluated by the Waste Coordinator for potential reuse/recycling prior

to being declared waste.

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Chemical Waste Pickup Form

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