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ACIDS AND BASES
Chapter 7
Reactions that form water: Acids and Bases
Objective 4: To learn the key characteristics of the reactions between strong acids and bases
Properties of Acids
Acids are proton (hydrogen ion, H+) donors
Acids have a pH lower than 7 Acids taste sour Acids effect indicators
Blue litmus turns red Methyl orange turns red
Acids react with active metals, producing H2
Acids react with carbonates Acids neutralize bases
Acids are Proton (H+ ion) Donors
Strong acids are assumed to be 100% ionized in solution (good H+ donors).
Weak acids are usually less than 5% ionized in solution (poor H+ donors).
HCl
H2SO4 HNO3
H3PO4 HC2H3O2 Organic acids
Acids Effect
Indicators
Blue litmus paper turns red in contact with an acid.
Methyl orange turns red with addition of an acid
Acids React with Active Metals
Acids react with active metals to form salts and hydrogen gas.
Mg + 2HCl MgCl2 + H2(g)
Zn + 2HCl ZnCl2 + H2(g)
Mg + H2SO4 MgSO4 + H2(g)
Acids React with Carbonates
2HC2H3O2 + Na2CO3
2 NaC2H3O2 + H2O + CO2
Effects of Acid Rain on Marble(calcium carbonate)
George Washington:BEFORE
George Washington:AFTER
Acids Neutralize Bases
HCl + NaOH NaCl + H2O
Neutralization reactions ALWAYS produce a salt and water.
H2SO4 + 2NaOH Na2SO4 + 2H2O
2HNO3 + Mg(OH)2 Mg(NO3)2 + 2H2O
Properties of Bases Bases are proton (hydrogen ion, H+) acceptors
Bases have a pH greater than 7 Bases taste bitter Bases effect indicators
Red litmus turns blue Phenolphthalein turns purple
Solutions of bases feel slippery Bases neutralize acids
Bases are Proton (H+ ion) Acceptors
Sodium hydroxide (lye), NaOH
Potassium hydroxide, KOH Magnesium hydroxide,
Mg(OH)2
Calcium hydroxide (lime), Ca(OH)2
OH- (hydroxide) in base combines with H+ in acids to form water
H+ + OH- H2O
Bases Effect Indicators
Red litmus paper turns blue in contact with a base.
Phenolphthalein turns bright pink in a base.
Bases Neutralize Acids
Milk of Magnesia contains magnesium hydroxide, Mg(OH)2, which neutralizes stomach acid, HCl.
2 HCl + Mg(OH)2 MgCl2 + 2 H2O
Mixing Strong Acids and Strong Bases
Aqueous hydrochloric acid reacts with aqueous sodium hydroxide
HCl(aq) + NaOH(aq) H2O(l) + NaCl (aq)
Complete ionic equation:
H+(aq) + Cl-(aq) + Na+(aq) + OH-(aq) H2O(l) + Na+(aq) + Cl-(aq)
Net ionic equation:
H+(aq) + OH-(aq) H2O(l)
Mixing Strong Acids and Strong Bases
Aqueous hydrobromic acid reacts with aqueous sodium hydroxide
HBr(aq) + NaOH(aq) H2O(l) + NaBr (aq)
Complete ionic equation:
H+(aq) + Br-(aq) + Na+(aq) + OH-(aq) H2O(l) + Na+(aq) + Br-(aq)
Net ionic equation:
H+(aq) + OH-(aq) H2O(l)
Mixing Strong Acids and Strong Bases
Aqueous sulfuric acid reacts with aqueous potassium hydroxide
H2SO4(aq) + 2KOH(aq) 2H2O(l) + K2SO4(aq)
Complete ionic equation:
2H+(aq) + SO42-(aq) + 2K+(aq) + 2OH-(aq)2H2O(l) + 2K+(aq) + SO4
2-(aq)
Net ionic equation:
H+(aq) + OH-(aq) H2O(l)