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Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper...

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1 Additives for Paper Impregnation BL Interface & Performance
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Page 1: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

1

Additives for Paper

Impregnation

BL Interface & Performance

Page 2: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

2

Paper Impregnation Process Needs Additives

Additives for Paper Impregnation

DryingUnwind RewindDip coating

Resin Bath

Wetting agent

Dispersant

Defoamer

Antidust

Page 3: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

3

TEGO® Surten W 111

▪ Alcohol alcoxylate

▪ 100% active

▪ No foaming

▪ Enhanced penetration

into the paper

▪ Nonylphenol ethoxylate-free

TEGOPREN® 5878

▪ Organomodified siloxane

▪ 100% active

▪ Low foaming

▪ Enhanced penetration

into the paper

▪ Nonylphenol ethoxylate-free

Wetting Agents for Paper Impregnation

Additives for Paper Impregnation

Page 4: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

4

Test Method / Wetting Behavior of Aminoresins on Paper

Additives for Paper Impregnation

Draw down direction

For each test two stripes are cut from one sheet of paper. For the measurement always a control without additive and one

with the wetting agent is measured to ascertain comparable results. A drop with a defined volume is put on the paper and

at once drawn down with our draw down machine. Then the length and width of the resin film is measured and noted down

as difference compared to the control in % shorter (length) and % broader (width).

Page 5: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

5

Test Setup & Performance of Wetting Agents

Additives for Paper Impregnation

Determination of film length

The shorter the film the faster does the

resin penetrate into the paper

Determination of film width

The broader the film the better the

penetration into the paper

1 2 3 4

1. Control without additive (powder

resin + hardener)

2. Competitor, Octylphenolethoxylate

3. TEGO® Surten W 111

4. TEGOPREN® 5878

Page 6: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

6

OMS are 10 Times as Effective as Standard Wetting Agents

Additives for Paper Impregnation

0

2

4

6

8

10

12

14

0 0,1 0,2 0,3 0,4 0,5

Film

len

gth

[cm

]

Concentration [%]

competitor

TEGOPREN 5878

0,05

Perf

orm

an

ce

high

low

Page 7: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

7

▪ In Melamine resins for impregnation of decor paper and overlays

▪ In Phenolic resins for impregnation of Kraft paper

Where are Antifoams used?

Additives for Paper Impregnation

Page 8: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

8

TEGO® Antifoam 2360

▪ Excellent antifoaming properties

▪ Especially designed for sensitive surfaces like Melamine or Polyurethane

▪ No surface defects

▪ Transparent films

▪ Easy to handle emulsion

Antifoam for Impregnation of Decor Papers and Overlays

Additives for Paper Impregnation

Page 9: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

9

Stirring Test for Foaming Behavior of Resin Formulations

Additives for Paper Impregnation

How to run the test:

1. 160 ml resin + defoamer is poured into a 250 ml beaker

2. Stirring for 1 minute at 2500 rpm

3. Resin is poured into a 50 ml calibration flask

4. Weight is determined

Interpretation

High weight = few entrained air = good defoamer performance

Low weight = much entrained air = poor defoamer performance

The amount of air can be calculated by using the following formula:

Volume of air % = 100 – (g*2)/D

g = weight of 50 ml stirred resin; D = density of the air free resin

The stirrer must be completely covered with resin.

Cage Stirrer:

Diameter: 2

cm

Height: 2 cm

1 23

Page 10: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

10

Antifoams / Results Stirring Test

Additives for Paper Impregnation

Melamine Resin + 0.2% Antifoam

0

5

10

15

20en

train

ed

air

(V

ol.

-%)

Control Competitor TEGO® Antifoam

2360

Perf

orm

an

ce

high

low

Page 11: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

11

TEGO® Antifoam 2290

▪ High efficient antifoam

▪ Based on paraffinic oil and is completely silicone free

▪ Very compatible

▪ Self-emulsifiable antifoam concentrate

▪ Easy to use

Antifoam for Phenolic Resins in the Impregnation of Kraft Paper

Additives for Paper Impregnation

Page 12: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

12

Antifoams / Results Stirring Test

Additives for Paper Impregnation

0

5

10

15

20

25e

ntr

ain

ed

air

[V

ol%

]

Without antifoam competitor

antifoam

TEGO® Antifoam

2290

Phenolic Resin + 0.05% Antifoam

Perf

orm

an

ce

high

low

Page 13: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

13

200 µm Films of Phenolic Resin on Glass

Additives for Paper Impregnation

Without Antifoam Competitor Antifoam TEGO® Antifoam 2290

Antifoam dosage = 0,05 w%

Page 14: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

14

TEGOMER® Dispersing Agents

In the production of single-colored surfaces

the pigments may be dispersed in the resin

bath.

Mainly this is done in the production of white

surfaces by dispersing TiO2 in the resin.

If the dispersion is not good enough,

separation of the pigment will occur. These

separations often build up hard layers in the

resin bath and are not easy to remove.

Without TEGOMER® DA

Additives for Paper Impregnation

Page 15: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

15

TEGOMER® Dispersing Agents

Additives for Paper Impregnation

By adding TEGOMER® DA

dispersing agents separations are

avoided.

No hard layers are build up and

cleaning of the impregnation bath is

getting easier.

With TEGOMER® DA

Page 16: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

16

C

C

C

C

C

C

C

C

C

C

c

TEGOMER® DA 640

▪ Polyether phosphate

▪ Anionic

▪ 30% active content in water

▪ Solvent and Nonylphenol

ethoxylate-free

TEGOMER® DA 850

▪ Organic modified polymer

▪ Nonionic

▪ 40% active content in water

▪ Solvent and nonylphenol

ethoxylate-free

TEGOMER® Dispersing Agents

Additives for Paper Impregnation

Page 17: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

17

Wetting Agents

Defoamer

Dispersing Agents

TEGOPREN® 5878

TEGO® Surten W 111

TEGO® Antifoam 2360 for Melamine resins

TEGO® Antifoam 2290 for Phenolic resins

TEGOMER® DA 640

TEGOMER® DA 850

Additives for Paper Impregnation

Additives for Paper Impregnation

Page 18: Additives for Paper...9 Stirring Test for Foaming Behavior of Resin Formulations Additives for Paper Impregnation How to run the test: 1. 160 ml resin + defoamer is poured into a 250

18


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