Air Liquide Global E&C Solutionsarchivo.ipa.org.ar/images/11.05.2016perlwitz.pdfLow Pressure (LP)...

Air Liquide Global E&C Solutions Air Liquide’s Engineering & Construction Activity

Mai 2016 | Air Liquide Global E&C Solutions

Air Liquide, world leader in gases, technologies and services for Industry and Health

Customers across the entire energy value chain

2 Air Liquide E&C - CONFIDENTIAL

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Product Lines

4

Driving Air Liquide Global E&C Solutions’ technology portfolio

through Product Lines strategies across all Regions

Hydrogen

Downstream &

Petrochemicals

Cryogenics

Oleochemicals

Hydrocarbons

Standard Plants

Air Liquide E&C - CONFIDENTIAL


Downstream & Petrochemicals Product Line

5

Providing best in class and

fully referenced technologies

for gas and coal monetization

comprising syngas generation

and conditioning, production of

methanol and its derivatives

up to selected petrochemicals.

Downstream & Petrochemicals


Air Liquide, world leader in gases, technologies and services for Industry and Health 6

Petrochemicals

A wealth of experience and know-how in

petrochemical processes spanning more than

60 years.

Low Pressure (LP) Methanol

Lurgi Megamethanol™

Lurgi MTP™ - Methanol-to-

Propylene

Butadiene Extraction

Acrylic Acid

Acrylates

Distapex™

G2G™ - Gas-to-Gasoline



Air Liquide MegaMethanol® Market Position

Source: PML



Methanol – Market



Methanol Production Technologies

0 10,000

Capacity (mtpd)

2,500 7,500 5,000

SMR Combined Reforming ATR

LP Synthesis GigaMethanol MegaMethanol

1-Stage Synthesis 2-Stage Synthesis



Combined Reforming for 5000 MTPD Methanol (MegaMethanol™)

Autothermal Reformer (ATR)

Lurgi Reformer™ (SMR) Combined Reforming



Methanol Synthesis in reality

Gas Cooled

Reactor

Water Cooled

Reactor



Air Liquid Methanol - Our Track Record

■ Methanol Licenses Track Record

55+ Plants licensed since 1969 (40 mtpy)

■ Multiple new MegaMethanol™ units in the last 18 months

■ 17 Oxygen reforming plants (20 mtpy)

■ 14 MegaMethanol plants (24 mtpy)

■ 21 Plants licensed since 2001 (29 mtpy)

63%

31%

6%

Natural Gas (33 plants)

Coal (11 plants)

Others (11 plants)

12

Based on installed capacity



Overall licensor market share

■ Number of operating plants

■ Total Methanol capacity

Source: Nexant, 2012

Air Liquide‘s Lurgi Technology is

the leader in methanol



Natural Gas Methanol

Sea Water Sea Water

Electricity

Backup only

Natural Gas Requirements

HHV 32 MMBTU/t MeOH =

160 MMSCFD

Plot Requirements

300 m x 400 m

40 acres

Production

5 000 MTPD Methanol Grade AA

Air Liquide MegaMethanol® – Proven in Operation

Flue Gases

Core Process Units Plant Air Separation Unit

Waste Water



Selected Reference - MegaMethanol® Plant, Malaysia

Client: Petronas Methanol (Labuan) SDN BHD

Process: MegaMethanol®

Licensor: Air Liquide

Plant Capacity: 5,000 t/d

Feedstock: Natural Gas

Scope of Work: EPC

Start-Up Year: Dec. 2008

Project Highlights: Second Methanol Plant for PML and Largest in Asia.



Air Liquide

MegaMethanol®

Process

Further Methanol Processing: MTX

Syngas

Natural Gas

Coal

Residue

ASU

MeOH to Propylene ®

DME

MeOH to Olefins

MeOH to Aromatics

MeOH to Gasoline

MeOH to Glycol

Acrylic Acid

Fuels

Ethylene,

Propylene

(Poly-Olefines)

Benzene,

Xylenes

Fuels

Ethylene Glycol



Coal

Gasification

Rectisol

Mega

Methanol

Sulfur

Recovery

MTP®

Poly-

Propylene

ASU

DME

Methanol-to-Propylene / Gas-to-Propylene



MTP® Overview - Flowsheet

MTP-Gasoline 540 t/d

Fuel Gas Internal use

Process Water 2,800 t/d Internal Use (+)

Product

Conditioning MTP-LPG 109 t/d

Water Recycle

Olefin Recycle

MegaMethanol®

5,000 t/d

Product

Fractionation

MTP Reactors (2 Operating + 1 Regenerating)

1) Propylene Purity 99.6 wt. %

60 t/d

(Optional)

DME

Pre-

Reactor

Propylene

1,410 t/d 1)

Ethylene



Utilities

Lurgi MegaMethanol® Plant MTP® Plant

Integrated Plant Configuration (GTP)

Reforming

Methanol

Synthesis

Purification

DME and

MTP

Reaction

Methanol

Distillation

Steam and Condensate System

Methanol Liquid

Grade AA

Methanol Vapour



MTP/GTP® References

4 Licenses awarded

3 MTP Plants under commercial operation (470, 000 tpy) - Datang Power Corporation (DTP: Duolon) – start-up 2011

- Shenhua Ningxia Coal Industry Group (SNCG: Ningdong) – start-up 2010

- Shenhua Ningxia Coal Industry Group (SNCG: Ningdong) – start-up 2014

1 GTP Plant in the U.S. (BASF) under engineering (470, 000 tpy)



Gas to Propylene: BASF presentations

BASF

press

release:

BASF

Investor Day

presentation:



Hydrogen Product Line

22

Offering hydrogen to the

refining and chemicals

markets with our

competitive range of

small and large Steam

Methane Reformers.

Hydrogen



Hydrogen

Steam Methane Reformer (including

small scale) - Hydrogen Production

SMR-X™ - Zero Steam Hydrogen

Production

Pressure Swing Adsorption (PSA) -

Hydrogen Purification

ATR

Offering hydrogen to the refining and

chemicals markets with a competitive range of

small and large Steam Methane Reformers.



Hydrocarbons Product Line

24

Offering a full portfolio of

natural gas treatment

technologies from well to

clean product including

Liquefied Natural Gas

(small-, mid- to large scale)

as well as re-gasification

technologies.

Hydrocarbons



Liquefied Natural Gas (LNG)

100 years of cryogenic experience available for

LNG with small- to large- scale plants, and

equipment to serve applications ranging from

peak shaving, LNG as a fuel, to base load LNG

for export markets.

Small-scale LNG (Nitrogen

Refrigeration Cycle)

Mid- to Large- scale LNG

(Mixed Refrigerant Cycle)

Boil-Off Gas Reliquefaction



Natural Gas Treatment

Nitrogen Rejection Unit

Natural Gas Liquids Recovery

Acid Gas Removal

Combined Membranes

Amine washes

Omnisulf™ - Acid Gas enrichment

and removal

Cryocap™

Offering a full portfolio of natural gas treatment

technologies from well to clean product as well

as re-gasification technologies.



Sulfur

OxyClaus™ Sulfur Recovery Unit

Sulfur Recovery Unit

Lurgi Tail Gas Treatment (LTGT™)

Sub-dewpoint tail gas technologies

(Sulfreen™)

Sulfur degassing (Aquisulf™)

Claus - Emission-free Sulfur Recovery

Unit

Sulfur Management technologies that are

helping customers to meet increasingly

stringent environmental targets.



Standard Plants Product Line

28

Fully packaged cost efficient

plants mastering cryogenic

and adsorption technologies

for oxygen and nitrogen

production from 40 to 800

tons per day.

Standard Plants



Standard Plants

Yango™ - Standard Air Separation Unit

Sigma - Standard Air Separation Unit

Vacuum Swing Adsorption On-Demand

Oxygen Generator

Nitrogen Generation System

HYOS™ R - Hydrogen Generation

System

Fully packaged cost efficient plants mastering

cryogenic and adsorption technologies for

oxygen and nitrogen production from 40 to 800

tons per day.



Cryogenics Product Line

30

Providing state-of-the-

art Air Separation Units

and Cryogenics

technologies that yield

the lowest possible Total

Cost of Ownership.

Cryogenics



Cryogenics

Large Air Separation Unit

CO Cold Box - Syngas Separation and

Purification

Liquid Nitrogen Wash

Hydrogen, Nitrogen and Argon Recovery

Cryocap™ H2 - Cryogenic CO2 Separation

Cryocap™ Oxy - Cryogenic CO2 Separation

for Oxycombustion

Helium Extraction and Liquefaction State-of-the-art Air Separation Units and

Cryogenics technologies that yield the lowest

possible Total Cost of Ownership.



Oleochemicals Product Line

32

Providing oil seed extraction

and refining, fatty acids, fatty

alcohols, glycerin, sorbitol

and methyl esters alongside

biodiesel technologies.

Oleochemicals



Biodiesel & Oleochemicals

Sliding Cell Extractor - Seed Crushing and

Extraction

Natural Oil Refining

Lurgi Biodiesel

Methyl Ester Distillation/Fractionation

Fatty Acid

Production (Oil Splitting)

Distillation/Fractionation

Hydrogenation

Glycerin Distillation and Bleaching

Fatty Alcohol

Wax Ester and Methyl Ester Route

LP3 - Low Pressure Fatty Alcohol Production

Bio Propylene Glycol

Sorbitol Production

Proven Lurgi technologies to ensure

smooth, reliable operations, superior

product quality and maximum efficiency.


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