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American Process Sugar Production Technology
Sugars: Exploring New Sources
December 10, 2013
David Glassner
SVP, Development & Commercialization
Sugar is the New Crude®
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American Process Company Overview
Founded in 1995
Three current business lines
• Process engineering (energy efficiency)
• Green power plus® (GP+)
• American Value Added Pulping ® (AVAP)
Worldwide operations in Atlanta, Alpena, MI,
Thomaston, GA, Romania and Greece
~90 employees
Equity stake taken by GranBio
2
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GreenPower+® - Bolt on Sugar production
• Makes sugars from hemicelluloses
• In co-production mode
• Advantages: Small CAPEX
Synergistic with biomass based renewable power, pellets, sugarcane 1G plants
AVAP® - Bulk sugar production
• Makes sugars from cellulose & hemicelluloses
• Advantages: Low cost clean sugars
Able to produce sugars at large scale
3
Green Power+
Cellulose
Hemicelluloses
Lignin
Hemicelluloses
6
Cellulose
Hemicelluloses Lignin
Cellulose
Hemicelluloses
AVAP
Lignin
American Process Sugar Producing Technology
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GreenPower+ Technology
GreenPower+™ - Bolt on Sugar production
• Makes sugars from hemicelluloses
• In co-production mode
• Advantages: Small CAPEX
Synergistic with biomass based renewable power, pellets, sugarcane 1G plants
4
Green Power+
Cellulose
Hemicelluloses
Lignin
Hemicelluloses
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Green Power Plus Applications
Corrugated box manufacturing
Masonite type board manufacturing
Inefficient biomass power operations
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Conventional Biomass Power
Lignin
Power
Plant Cellulose Hemicelluloses
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Lignin
Hemicellulose
Extraction
Hydrolysis
Power
Plant
Fermentation
Power
Plant Cellulose Hemicelluloses
Lignin Cellulose
GreenPower+ ACETATE
Conventional Biomass Power and Green Power Plus
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Alpena Green Power Plus Commercial Demonstration
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Recognized by the EPA as a cellulosic ethanol producer
Converting ~7,000 tons per year of hemicelluloses to sugars and acetic acid
Converting sugars to ~700,000 gallons per year cellulosic ethanol
Converting acetic acid to ~700,000 gallons per year of potassium acetate deicer
Started up in 2013
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Alpena Biorefinery - Fermentors
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www.americanprocess.com Alpena Biorefinery - Ethanol Distillation Columns 10
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American Value Added Pulping® (AVAP)
Sulfur dioxide, ethanol and water cook of biomass
Key process differentiators
• High sugar yields and highly digestible cellulose fiber provide low operating and capital
cost process
• High purity cellulose fiber can provide glucose stream suitable for non-volatile
chemicals, hydrophobic chemicals and catalytic chemical processes
• Works equally well on softwoods, hardwoods and agricultural residues
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6
Cellulose
Hemicelluloses Lignin
Cellulose
Hemicelluloses
AVAP
Lignin
Glucose
Xylose
Steam and Power
or
Lignin co-product
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Thomaston Plant Process Layout
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FRACTIONATION
Cook biomass, separate
liquor and cellulose
fiber
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Chip Hopper
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Digester, Inlet Hopper and Blow Tank
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Wash (Filtrate) Tanks
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Thomaston Plant Process Layout
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CHEMICAL RECOVERY
FRACTIONATION
Recover and recycle
chemicals & separate
lignin
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Scrubber, Sulfur Dioxide and Ethanol Recovery Columns
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Thomaston Plant Process Layout
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CHEMICAL RECOVERY
FRACTIONATION
ENZYMATIC HYDROLYSIS
Cellulose fiber
enzymatic hydrolysis
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Enzymatic Hydrolysis Plant
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AVAP® Fiber is Highly Digestible by Enzymes
Nearly all cellulose in AVAP® produced fiber is converted
to glucose by commercial enzymes
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0
20
40
60
80
100
120
0 20 40 60 80 100 120 140 160 180
Glu
cose
co
nve
rsio
n (
%)
Time (h)
Commericalenzyme_0.1g/g
Glucan conversion (%) = the amount of glucose in hydrolysate
liquor (g) / [the amount of glucan in starting fiber (g) / 0.9] × 100
Time, h CE1
0.1 g/g
24 95.1
48 95.2
72 99.6
96 100.0
168 101.1
1CE: commercial enzyme
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Thomaston Plant Process Layout
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CHEMICAL RECOVERY
FRACTIONATION
ENZYMATIC HYDROLYSIS
FERMENTATION
Ferment sugars to products
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Seed Revival, Propagation and Production Fermenters
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Production Fermenters
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Thomaston Plant Process Layout
24 CONFIDENTIAL MATERIAL
CHEMICAL RECOVERY
FRACTIONATION
ENZYMATIC HYDROLYSIS
FERMENTATION
Cook biomass, separate
liquor and cellulose
fiber
Recover and recycle
chemicals & separate
lignin
Ferment sugars to products
Cellulose fiber
enzymatic hydrolysis
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Road to Commercialization
Integrated Demo
Scale up partnerships
First implementers
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Alpena GreenPower+® Thomaston AVAP®
• GranBio partnership
• GreenPower+®
• First license sold - start up 2015
• AVAP®
• First license sold - start up 2016
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Key Messages
American Process is developing two new sugar
production technologies
• Green Power+
• Commercial demonstration Alpena, MI
• First commercial license sold
• In design phase
• Startup in early 2015
• AVAP
• Demonstration plant in Thomaston, GA
• First commercial license sold
• Startup planned for 2016
26 CONFIDENTIAL MATERIAL