40
Analytical Reference Materials Atlantic RBCA VPH Cat.# 31871 Lot# A033498 & A034293
Analytical Reference Materials
Atlantic RBCA VPHCat.# 31871
Lot# A033498 & A034293
CERTIFICATE OF ANALYSIS
110 Benner Circle Bellefonte, PA 16823-8812
Tel: (800) 356-1688 Fax: (814) 353-1309
FOR LABORATORY USE ONLY - READ MSDS PRIOR TO USE
Catalog No.: 31871 Lot No.: A033498
Description: Atlantic RBCA VPH
Expiration Date¹: October 2011 Storage: Freezer
1 n-Hexane (C6) 110-54-3 99% 1000 ug/mL +/- 0.12 n-Heptane (C7) 142-82-5 99% 1000 ug/mL +/- 0.13 Benzene 71-43-2 99% 1000 ug/mL +/- 0.14 n-Octane (C8) 111-65-9 99% 1000 ug/mL +/- 0.15 Toluene 108-88-3 99% 1000 ug/mL +/- 0.16 Ethylbenzene 100-41-4 99% 1000 ug/mL +/- 0.17 p-Xylene 106-42-3 99% 1000 ug/mL +/- 0.18 o-Xylene 95-47-6 99% 1000 ug/mL +/- 0.19 n-Decane (C10) 124-18-5 99% 1000 ug/mL +/- 0.1
10 1-methyl-3-ethylbenzene (3-ethyltoluene) 620-14-4 99% 1000 ug/mL +/- 0.111 1,3,5-Trimethylbenzene 108-67-8 99% 1000 ug/mL +/- 0.112 1,2,4-Trimethylbenzene 95-63-6 99% 1000 ug/mL +/- 0.1
Solvent: P&T Methanol 67-56-1 99%
Column:30m x .25mm x .5umRtx-5 (cat.#10238)
Carrier Gas:hydrogen @ 40cm/sec.
Temp. Program:40°C (hold 2 min.) to 240°C@ 8°C/min. (hold 10 min.)
Inj. Temp:200°C
Det. Temp:250°C
Det. Type:FID
Manufactured By: n/a
1 Expiration date of the unopened ampul stored at recommended temperature.2 Purity was determined by one or more of the following techniques: GC/FID, HPLC, GC/ECD, GC/MS. Value rounded to the nearest LOWER whole percentage. In addtion to detectors listed above, chemical identity and purity are confirmed using 1 or more of the following: MS, DSC, solid probe MS, GC/FPD, GC/NPD, GC/TC, FTIR, melting point, reftactive index, and Karl Fisher. See data pack or contact Restek for further details.3 Based upon gravimetric preperation with balance calibration verified using NISTtraceable weights (7 mass levels).4 Percent Uncertainty based upon balance AND ASTM Class A volumetric glassware accuracy.
Manufactured Under Restek's ISO9001 Registered Quality System
Certificate #FM80397
12/14/2004Page 1 of 1
CERTIFICATE OF ANALYSIS
110 Benner Circle Bellefonte, PA 16823-8812
Tel: (800) 356-1688 Fax: (814) 353-1309
FOR LABORATORY USE ONLY - READ MSDS PRIOR TO USE
Catalog No.: 31871 Lot No.: A034293
Description: Atlantic RBCA VPH
Expiration Date¹: December 2011 Storage: Freezer
1 n-Hexane (C6) 110-54-3 99% 1000 ug/mL +/- 0.12 n-Heptane (C7) 142-82-5 99% 1001 ug/mL +/- 0.13 Benzene 71-43-2 99% 1000 ug/mL +/- 0.14 n-Octane (C8) 111-65-9 99% 1000 ug/mL +/- 0.15 Toluene 108-88-3 99% 1000 ug/mL +/- 0.16 Ethylbenzene 100-41-4 99% 1000 ug/mL +/- 0.17 p-Xylene 106-42-3 99% 1001 ug/mL +/- 0.18 o-Xylene 95-47-6 99% 1001 ug/mL +/- 0.19 n-Decane (C10) 124-18-5 99% 1001 ug/mL +/- 0.1
10 1-methyl-3-ethylbenzene (3-ethyltoluene) 620-14-4 99% 1000 ug/mL +/- 0.111 1,3,5-Trimethylbenzene 108-67-8 99% 1000 ug/mL +/- 0.112 1,2,4-Trimethylbenzene 95-63-6 99% 1000 ug/mL +/- 0.1
Solvent: P&T Methanol 67-56-1 99%
Column:30m x .25mm x .5umRtx-5 (cat.#10238)
Carrier Gas:hydrogen @ 40cm/sec.
Temp. Program:40°C (hold 2 min.) to 240°C@ 8°C/min. (hold 10 min.)
Inj. Temp:200°C
Det. Temp:250°C
Det. Type:FID
Manufactured By: JAM
1 Expiration date of the unopened ampul stored at recommended temperature.2 Purity was determined by one or more of the following techniques: GC/FID, HPLC, GC/ECD, GC/MS. Value rounded to the nearest LOWER whole percentage. In addtion to detectors listed above, chemical identity and purity are confirmed using 1 or more of the following: MS, DSC, solid probe MS, GC/FPD, GC/NPD, GC/TC, FTIR, melting point, reftactive index, and Karl Fisher. See data pack or contact Restek for further details.3 Based upon gravimetric preperation with balance calibration verified using NISTtraceable weights (7 mass levels).4 Percent Uncertainty based upon balance AND ASTM Class A volumetric glassware accuracy.
Manufactured Under Restek's ISO9001 Registered Quality System
Certificate #FM80397
12/14/2004Page 1 of 1
QA Report: Atlantic RBCA VPH (Cat.#31871)Lot # A033498 Lot # A034293
COMPONENT Run #1 Run #2 Run #3 Run #1 Run #2 Run #3n-Hexane (C6) 529157 553023 550234 569842 572525 557892n-Heptane (C7) 570693 595515 590481 611976 612406 600588benzene 615925 641723 633141 660820 661916 649032fluorobenzene (IS) 455539 474941 467442 486872 487830 477727n-Octane (C8) 591217 616895 607299 627341 627068 612208toluene 621519 646353 634104 663262 662239 645757ethylbenzene 616163 643616 627906 658105 656211 642937p-xylene 618657 645209 627497 661352 657957 645431o-xylene 614080 639105 622542 655613 649734 636467n-Decane (C10) 587417 612608 595477 631164 626610 6159001-methyl-3-ethylbenzene 601488 627774 611064 641803 636751 6248171,3,5-trimethylbenzene 604315 631419 613002 643082 639712 6296771,2,4-trimethylbenzene 597109 622175 604967 642409 635698 627878
RELATIVE RESPONSE FACTORSLot # A033498 Lot # A034293
COMPONENT Run #1 Run #2 Run #3 AVG STD DEV % RSD Run #1 Run #2 Run #3 AVG STD DEV % RSD %D MEANn-Hexane (C6) 1.162 1.164 1.177 1.168 0.008 0.71 1.170 1.174 1.168 1.171 0.003 0.25 -0.25n-Heptane (C7) 1.253 1.254 1.263 1.257 0.006 0.46 1.257 1.255 1.257 1.257 0.001 0.08 0.01benzene 1.352 1.351 1.354 1.353 0.002 0.13 1.357 1.357 1.359 1.358 0.001 0.07 -0.37fluorobenzene (IS)n-Octane (C8) 1.298 1.299 1.299 1.299 0.001 0.05 1.289 1.285 1.282 1.285 0.004 0.27 1.04toluene 1.364 1.361 1.357 1.361 0.004 0.29 1.362 1.358 1.352 1.357 0.005 0.39 0.25ethylbenzene 1.353 1.355 1.343 1.350 0.006 0.46 1.352 1.345 1.346 1.348 0.004 0.27 0.21p-xylene 1.358 1.359 1.342 1.353 0.009 0.68 1.358 1.349 1.351 1.353 0.005 0.37 0.02o-xylene 1.348 1.346 1.332 1.342 0.009 0.65 1.347 1.332 1.332 1.337 0.008 0.63 0.37n-Decane (C10) 1.289 1.290 1.274 1.284 0.009 0.71 1.296 1.284 1.289 1.290 0.006 0.46 -0.441-methyl-3-ethylbenzene 1.320 1.322 1.307 1.316 0.008 0.61 1.318 1.305 1.308 1.310 0.007 0.52 0.461,3,5-trimethylbenzene 1.327 1.329 1.311 1.322 0.010 0.73 1.321 1.311 1.318 1.317 0.005 0.37 0.431,2,4-trimethylbenzene 1.311 1.310 1.294 1.305 0.009 0.72 1.319 1.303 1.314 1.312 0.008 0.64 -0.56
Page 1 of 1 (1) \\Qadata\ezchrom\Projects\standards\Data\Cat-Rep1.#31871 Lot#A033498 Method: \\Qadata\ezchrom\Projects\standards\Method\cevol.met Acquired: 12/3/04 10:43:03 PM Printed: 12/7/04 9:59:27 AM Cat.#31871 Lot#A033498Atlantic RBCA VPH 40°C (hold 2 min.) to 240° C @ 8° C/min. (hold 10 min.)Column: Rtx-502.2 105m x .53mm x 3.0um Cat.#10910Inj: 200 C Split @ 40 cc/min.Det: FID @ 250 CCarrier Gas: Hydrogen @ 40 cm/sec.
Minutes0 5 10 15 20 25 30 35
Volts
0.05
0.10
0.15
0.20
Volts
0.05
0.10
0.15
0.2010
.55
13.7
314
.03
14.3
5 16.9
317
.50
20.5
420
.68
21.6
422
.77
23.4
023
.53
24.4
3
FID ResultsRetention Time Area Area Percent
10.55 529157 6.941
13.73 570693 7.486
14.03 615925 8.080
14.35 455539 5.976
16.93 591217 7.755
17.50 621519 8.153
20.54 616163 8.083
20.68 618657 8.115
21.64 614080 8.055
22.77 587417 7.706
23.40 601488 7.890
23.53 604315 7.927
24.43 597109 7.833
Totals7623279 100.000
Page 1 of 1 (2) \\Qadata\ezchrom\Projects\standards\Data\Cat-Rep2.#31871 Lot#A033498 Method: \\Qadata\ezchrom\Projects\standards\Method\cevol.met Acquired: 12/3/04 11:33:19 PM Printed: 12/7/04 9:59:52 AM Cat.#31871 Lot#A033498Atlantic RBCA VPH 40°C (hold 2 min.) to 240° C @ 8° C/min. (hold 10 min.)Column: Rtx-502.2 105m x .53mm x 3.0um Cat.#10910Inj: 200 C Split @ 40 cc/min.Det: FID @ 250 CCarrier Gas: Hydrogen @ 40 cm/sec.
Minutes0 5 10 15 20 25 30 35
Volts
0.05
0.10
0.15
0.20
Volts
0.05
0.10
0.15
0.20
10.4
9 13.6
713
.97
14.2
8 16.8
717
.44
20.4
720
.62
21.5
822
.71
23.3
423
.47
24.3
7
FID ResultsRetention Time Area Area Percent
10.49 553023 6.956
13.67 595515 7.490
13.97 641723 8.072
14.28 474941 5.974
16.87 616895 7.759
17.44 646353 8.130
20.47 643616 8.095
20.62 645209 8.115
21.58 639105 8.039
22.71 612608 7.705
23.34 627774 7.896
23.47 631419 7.942
24.37 622175 7.826
Totals7950356 100.000
Page 1 of 1 (3) \\Qadata\ezchrom\Projects\standards\Data\Cat-Rep3.#31871 Lot#A033498 Method: \\Qadata\ezchrom\Projects\standards\Method\cevol.met Acquired: 12/4/04 12:23:10 AM Printed: 12/7/04 10:00:19 AM Cat.#31871 Lot#A033498Atlantic RBCA VPH 40°C (hold 2 min.) to 240° C @ 8° C/min. (hold 10 min.)Column: Rtx-502.2 105m x .53mm x 3.0um Cat.#10910Inj: 200 C Split @ 40 cc/min.Det: FID @ 250 CCarrier Gas: Hydrogen @ 40 cm/sec.
Minutes0 5 10 15 20 25 30 35
Volts
0.05
0.10
0.15
0.20
Volts
0.05
0.10
0.15
0.20
10.4
8
13.6
513
.95
14.2
7 16.8
617
.43
20.4
520
.60
21.5
522
.68
23.3
023
.43
24.3
2
FID ResultsRetention Time Area Area Percent
10.48 550234 7.068
13.65 590481 7.585
13.95 633141 8.133
14.27 467442 6.004
16.86 607299 7.801
17.43 634104 8.145
20.45 627906 8.065
20.60 627497 8.060
21.55 622542 7.997
22.68 595477 7.649
23.30 611064 7.849
23.43 613002 7.874
24.32 604967 7.771
Totals7785156 100.000
Page 1 of 1 (4) \\Qadata\ezchrom\Projects\standards\Data\Cat-Rep1.#31871 Lot#A034293 Method: \\Qadata\ezchrom\Projects\standards\Method\cevol.met Acquired: 12/4/04 1:13:21 AM Printed: 12/7/04 10:00:29 AM Cat.#31871 Lot#A034293Atlantic RBCA VPH 40°C (hold 2 min.) to 240° C @ 8° C/min. (hold 10 min.)Column: Rtx-502.2 105m x .53mm x 3.0um Cat.#10910Inj: 200 C Split @ 40 cc/min.Det: FID @ 250 CCarrier Gas: Hydrogen @ 40 cm/sec.
Minutes0 5 10 15 20 25 30 35
Volts
0.05
0.10
0.15
0.20
Volts
0.05
0.10
0.15
0.20
10.4
7
13.6
413
.94
14.2
6 16.8
417
.41
20.4
420
.58
21.5
422
.67
23.3
023
.43
24.3
3
FID ResultsRetention Time Area Area Percent
10.47 569842 6.989
13.64 611976 7.506
13.94 660820 8.105
14.26 486872 5.971
16.84 627341 7.694
17.41 663262 8.135
20.44 658105 8.071
20.58 661352 8.111
21.54 655613 8.041
22.67 631164 7.741
23.30 641803 7.871
23.43 643082 7.887
24.33 642409 7.879
Totals8153641 100.000
Page 1 of 1 (5) \\Qadata\ezchrom\Projects\standards\Data\Cat-Rep2.#31871 Lot#A034293 Method: \\Qadata\ezchrom\Projects\standards\Method\cevol.met Acquired: 12/4/04 2:03:21 AM Printed: 12/7/04 10:00:43 AM Cat.#31871 Lot#A034293Atlantic RBCA VPH 40°C (hold 2 min.) to 240° C @ 8° C/min. (hold 10 min.)Column: Rtx-502.2 105m x .53mm x 3.0um Cat.#10910Inj: 200 C Split @ 40 cc/min.Det: FID @ 250 CCarrier Gas: Hydrogen @ 40 cm/sec.
Minutes0 5 10 15 20 25 30 35
Volts
0.05
0.10
0.15
0.20
Volts
0.05
0.10
0.15
0.20
10.4
9
13.6
613
.97
14.2
8 16.8
617
.43
20.4
620
.61
21.5
622
.69
23.3
223
.45
24.3
4
FID ResultsRetention Time Area Area Percent
10.49 572525 7.045
13.66 612406 7.536
13.97 661916 8.145
14.28 487830 6.003
16.86 627068 7.716
17.43 662239 8.149
20.46 656211 8.075
20.61 657957 8.096
21.56 649734 7.995
22.69 626610 7.711
23.32 636751 7.835
23.45 639712 7.872
24.34 635698 7.822
Totals8126657 100.000
Page 1 of 1 (6) \\Qadata\ezchrom\Projects\standards\Data\Cat-Rep3.#31871 Lot#A034293 Method: \\Qadata\ezchrom\Projects\standards\Method\cevol.met Acquired: 12/4/04 2:53:24 AM Printed: 12/7/04 10:00:56 AM Cat.#31871 Lot#A034293Atlantic RBCA VPH 40°C (hold 2 min.) to 240° C @ 8° C/min. (hold 10 min.)Column: Rtx-502.2 105m x .53mm x 3.0um Cat.#10910Inj: 200 C Split @ 40 cc/min.Det: FID @ 250 CCarrier Gas: Hydrogen @ 40 cm/sec.
Minutes0 5 10 15 20 25 30 35
Volts
0.05
0.10
0.15
0.20
Volts
0.05
0.10
0.15
0.20
10.4
6
13.6
313
.93
14.2
5 16.8
317
.40
20.4
320
.57
21.5
322
.66
23.2
823
.42
24.3
1
FID ResultsRetention Time Area Area Percent
10.46 557892 7.003
13.63 600588 7.539
13.93 649032 8.147
14.25 477727 5.997
16.83 612208 7.685
17.40 645757 8.106
20.43 642937 8.071
20.57 645431 8.102
21.53 636467 7.989
22.66 615900 7.731
23.28 624817 7.843
23.42 629677 7.904
24.31 627878 7.882
Totals7966311 100.000
Area % Report Data File: \\Qadata\ezchrom\Projects\standards\Data\Hexane -Lot#08110PB-Rep2 Method: \\Qadata\ezchrom\Projects\standards\Method\HP2VOL.met Acquired: 4/30/04 5:21:43 PM Printed: 5/3/04 3:33:10 PM Hexane Lot#08110PB 40°C (hold 2 min.) to 240° C @ 8° C/min. (hold 10 min.) Column: Rtx-502.2 105m x .53mm x 3.0um Cat.#10910 Inj: 200 C Split @ 40 cc/min. Det: FID @ 250 C Carrier Gas: Hydrogen @ 40 cm/sec.
Minutes0 5 10 15 20 25 30 35
Vol
ts
0.0
0.5
1.0
1.5
Vol
ts
0.0
0.5
1.0
1.5
6.38
6.78
8.00
18.5
4
20.7
0
27.0
8
FID Results Retention Time Area Area Percent
6.38 4344 0.060 6.78 7162770 99.079 8.00 26012 0.360
18.54 1821 0.025 20.70 2980 0.041 27.08 31447 0.435
Totals
7229374 100.000
File : G:\MSDATA\08110PB.D Operator : SEE Acquired : 28 Apr 2004 7:26 am using AcqMethod VOL Sample Name: Hexane Lot#08110PB Misc Info : Vial Number: 41 CurrentMeth: C:\HPCHEM\1\METHODS\DEFAULT.M
5.00 10.00 15.00 20.00 25.00 30.00 35.000
20000
40000
60000
80000
100000
120000
140000
160000
180000
200000
220000
240000
260000
280000
Time-->
Abundance
TIC: 08110PB.D 9.11
20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 950
2000
4000
6000
8000
m/z-->
Abundance
Scan 1052 (9.073 min): 08110PB.D41
57
8644 53 7138 50
20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 950
2000
4000
6000
8000
m/z-->
Abundance
#112278: Hexane57
43
2986
3971
26 5350 6734 63
Area % Report \\Qadata\ezchrom\Projects\standards\Data\Heptane Lot#40178 Method: \\Qadata\ezchrom\Projects\standards\Method\CEVOL.met Acquired: 6/10/02 3:32:18 PM Printed: 6/24/02 8:46:47 AM Heptane Lot#40178 40° C hold 2 min. to 240° C @ 8° C/min. hold 10 min. Column: Rtx-502.2 105m x .53mm x 3.0um Cat.#10910 Inj: 200 C Split @ 40 cc/min. Det: FID @ 250 C Carrier Gas: Hydrogen @ 40 cm/sec.
Minutes0 5 10 15 20 25 30 35
Vol
ts
0.1
0.2
0.3
0.4
Vol
ts
0.1
0.2
0.3
0.49.78
FID Results Retention Time Area Area Percent
9.78 1808877 100.000
Totals 1808877 100.000
File : G:\MSDATA\40178.D Operator : JHL Acquired : 11 Jun 2002 3:39 am using AcqMethod VOL Sample Name: Heptane Lot#40178 Misc Info : Vial Number: 5 CurrentMeth: C:\HPCHEM\1\METHODS\VOL.M
5.00 10.00 15.00 20.00 25.00 30.00 35.000
200000
400000
600000
800000
1000000
1200000
1400000
1600000
1800000
2000000
2200000
2400000
2600000
Time-->
Abundance
TIC: 40178.D 12.12
0 10 20 30 40 50 60 70 80 90 1000
1000
2000
3000
4000
5000
6000
7000
8000
9000
m/z-->
Abundance
Scan 1408 (12.116 min): 40178.D43
7157
100
8551 6537 77
0 10 20 30 40 50 60 70 80 90 1000
1000
2000
3000
4000
5000
6000
7000
8000
9000
m/z-->
Abundance
#4133: Heptane43
29 57 71
10015
85512 65
Area % Report \\Qadata\ezchrom\Projects\standards\Data\Benzene Lot#05934EO Method: \\Qadata\ezchrom\Projects\standards\Method\CEVOL.met Acquired: 7/13/02 12:18:50 AM Printed: 7/15/02 6:06:04 PM Benzene Lot#05934EO 40° C hold 2 min. to 240° C @ 8° C/min. hold 10 min. Column: Rtx-502.2 105m x .53mm x 3.0um Cat.#10910 Inj: 200 C Split @ 40 cc/min. Det: FID @ 250 C Carrier Gas: Hydrogen @ 40 cm/sec.
Minutes0 5 10 15 20 25 30 35
Vol
ts
0.1
0.2
0.3
0.4
0.5
Vol
ts
0.1
0.2
0.3
0.4
0.59.
81
FID Results Retention Time Area Area Percent
9.81 1985765 100.000
Totals 1985765 100.000
File : G:\MSDATA\05934EO.D Operator : JHL Acquired : 12 Jul 2002 11:21 pm using AcqMethod VOL Sample Name: Benzene Lot#05934EO Misc Info : Vial Number: 22 CurrentMeth: C:\HPCHEM\1\METHODS\VOL.M
5.00 10.00 15.00 20.00 25.00 30.00 35.000
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
7500000
8000000
8500000
9000000
9500000
1e+07
1.05e+07
1.1e+07
1.15e+07
1.2e+07
Time-->
Abundance
TIC: 05934EO.D 12.43
5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 850
1000
2000
3000
4000
5000
6000
7000
8000
9000
m/z-->
Abundance
Scan 1442 (12.416 min): 05934EO.D78
51
397463
36 48 6044 54
5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 850
1000
2000
3000
4000
5000
6000
7000
8000
9000
m/z-->
Abundance
#30179: Benzene78
51
3974632615 36 48
Page 1 of 1 Area % Report \\Qadata\ezchrom\Projects\standards\Data\Octane --Lot#02740EB Method: \\Qadata\ezchrom\Projects\standards\Method\CEVOL.met Acquired: 9/30/03 1:00:54 PM Printed: 10/1/03 12:06:54 PM Octane Lot#02740EB 40°C (hold 2 min.) to 240°C @8°C/min. (hold 10 min.) Column: Rtx-502.2 105m x .53mm x 3.0um Cat.#10910 Inj: 200 C Split @ 40 cc/min. Det: FID @ 250 C Carrier Gas: Hydrogen @ 40 cm/sec.
Minutes0 5 10 15 20 25 30 35
Vol
ts
0.25
0.50
0.75
Vol
ts
0.25
0.50
0.7512.9
3
FID Results Retention Time Area Area Percent
12.93 3045989 100.000
Totals 3045989 100.000
File : G:\MSDATA\02740EB.D Operator : SEE Acquired : 30 Sep 2003 9:25 am using AcqMethod VOL Sample Name: Octane Lot#02740EB Misc Info : Vial Number: 15 CurrentMeth: C:\HPCHEM\1\METHODS\DEFAULT.M
5.00 10.00 15.00 20.00 25.00 30.00 35.000
200000
400000
600000
800000
1000000
1200000
1400000
1600000
1800000
2000000
2200000
Time-->
Abundance
TIC: 02740EB.D 14.72
15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 951001051101151200
1000
2000
3000
4000
5000
6000
7000
8000
9000
m/z-->
Abundance
Scan 1711 (14.728 min): 02740EB.D43
8557
71
11451 65 7737 98
15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 951001051101151200
1000
2000
3000
4000
5000
6000
7000
8000
9000
m/z-->
Abundance
#5673: Octane43
5785
7129
1145138 65
Page 1 of 1 Area % Report \\Qadata\ezchrom\Projects\standards\Data\Toluene -Lot#CH471 Method: \\Qadata\ezchrom\Projects\standards\Method\CEVOL.met Acquired: 11/4/03 4:19:56 PM Printed: 11/5/03 8:24:35 AM Toluene Lot#CH471 40°C (hold 2 min.) to 240° C @ 8° C/min. (hold 10 min.) Column: Rtx-502.2 105m x .53mm x 3.0um Cat.#10910 Inj: 200 C Split @ 40 cc/min. Det: FID @ 250 C Carrier Gas: Hydrogen @ 40 cm/sec.
Minutes0 5 10 15 20 25 30 35
Vol
ts
0.05
0.10
0.15
Vol
ts
0.05
0.10
0.1513.2
8
FID Results Retention Time Area Area Percent
13.28 587681 100.000
Totals 587681 100.000
File : G:\MSDATA\CH471.D Operator : SEE Acquired : 4 Nov 2003 6:41 pm using AcqMethod VOL Sample Name: Toluene Lot#CH471 Misc Info : Vial Number: 3 CurrentMeth: C:\HPCHEM\1\METHODS\DEFAULT.M
5.00 10.00 15.00 20.00 25.00 30.00 35.000
100000
200000
300000
400000
500000
600000
700000
800000
900000
1000000
1100000
1200000
1300000
1400000
1500000
Time-->
Abundance
TIC: CH471.D 15.29
20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 1000
1000
2000
3000
4000
5000
6000
7000
8000
9000
m/z-->
Abundance
Scan 1775 (15.279 min): CH471.D91
39 6551
6145 74 8678
20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 1000
1000
2000
3000
4000
5000
6000
7000
8000
9000
m/z-->
Abundance
#117292: Toluene91
653951
27 6145 77 8655 73
Page 1 of 1 Area % Report Data File: \\Qadata\ezchrom\Projects\standards\Data\Decane Lot#07910DG Method: \\Qadata\ezchrom\Projects\standards\Method\SVRAW.met Acquired: 3/30/03 11:25:47 AM Printed: 4/17/03 1:18:50 PM Decane Lot#07910DG 40° C hold 2 min. to 330° C @ 10° C/min. hold 10 min. Rtx-5 30m x .25mm x .5um Cat.#10238 Injector 250° C Split 20cc/min. Detector FID @ 330° C Carrier gas Hydrogen @ 40 cm/sec.
Minutes0 5 10 15 20 25 30 35 40
Vol
ts
0
1
2
Vol
ts
0
1
27.66
FID Results Retention Time Area Area Percent
7.66 2733469 100.000
Totals 2733469 100.000
File : G:\MSDATA\07910DG.D Operator : SEE Acquired : 29 Mar 2003 2:31 pm using AcqMethod SVRAW Sample Name: Decane Lot#07910DG Misc Info : Vial Number: 17 CurrentMeth: C:\HPCHEM\1\METHODS\DEFAULT.M
5.00 10.00 15.00 20.00 25.00 30.00 35.000
50000
100000
150000
200000
250000
300000
350000
400000
450000
500000
550000
600000
650000
700000
Time-->
Abundance
TIC: 07910DG.D 8.23
10 20 30 40 50 60 70 80 90 100 110 120 130 140 1500
2000
4000
6000
8000
m/z-->
Abundance
Scan 1169 (8.223 min): 07910DG.D57
43
71
85
98 1421136551 7937
10 20 30 40 50 60 70 80 90 100 110 120 130 140 1500
2000
4000
6000
8000
m/z-->
Abundance
#112241: Decane57
43
71
8529
99 14211351 6514 77
Area % Report
Data File: \\Qadata\ezcbrom\Projects\standards\Data\I,3,5-Trimethylbenzene 1ot# 660502Method: \\Qadata\ezcbram\Projects\standards\Method\CEVa 1.metAcquired: 9/12/006:33:54 AMPrinted: 9/12/007:22:36 AM1,3,5-Trimethylbenzene Lot# 66050/2
40 C hold 2 min. to 240 C @ 8 CIminohold 10 min.Column: Rtx-502.2 105mx .53mm x 3.0um Cat.#10910
Inj: 200 C Split @ 40 cc/min.Det: Fro @ 250 CCarrier Gas: Hydrogen @ 40 cm/sec.
r--r--a)....
....cociN
Page 'I of 1 (28)
0.3
fa,I
rO.1, 0.0
!!!0>
10 15 20 25-r30 35
Minutes
Fro ResultsRetention Time
19.7720.61
Area1097445
8871
Area Percent99.198
0.802
TotalS! 1106316 ! 100.000 ]
I.
~
031
!!! 0.2;g
0.1
0.0o 5
File: L:\MSDATA\660502.D
Operator: JHLAcquired: 12 Sep 2000 8:35 am using AcqMethod VOLSample Name: 1.3,5-Trimethylbenzene Lot# 66050/2Misc Info: 40 C hold 2' then 240 C @ 8 CIminohold 10'Vial Number. 33CurrentMeth: C:\HPCHEM\1\METHODS\VOLM
c::= ~ C>""'.0" C>
~""""" =""~ .,..,. ,..,...O~
Ab~ .-.c:Janc:::Je
j
~j
7OOOj
Sc::ar> 2455 (2"1.<:>99 rriri): 66C>502.D
li5
II
"120
50C>C>
3
2
"1 OC>C>
50 55 60 65 70 75 so
..-rV:z:-~Abundar1c>e
#"1 "19301: BenzenE!" "1.3. 5-trirret:hyI-105
120
.
"1~
50 55 60 65 70 75 so
1'T"\I:z:-~
..
..
..
..
..
Area % Report Data File: \\Qadata\ezchrom\Projects\standards\Data\1,2,4-Trimethylbenzene Lot# 480162 Method: \\Qadata\ezchrom\Projects\standards\Method\CEVOL.met Acquired: 9/22/2000 5:34:38 PM Printed: 9/25/2000 9:45:38 AM 1,2,4-Trimethylbenzene Lot# 48016/2 40° C hold 2 min. to 240° C @ 8° C/min. hold 10 min. Column: Rtx-502.2 105m x .53mm x 3.0um Cat.#10910 Inj: 200° C Split @ 40 cc/min. Det: FID @ 250° C Carrier Gas: Hydrogen @ 40 cm/sec.
Minutes0 5 10 15 20 25 30 35
Vol
ts
0.1
0.2
0.3
0.4
Vol
ts
0.1
0.2
0.3
0.4
20.1
820
.47
FID Results
Retention Time Area Area Percent 20.18 6199 0.518 20.47 1189635 99.482
Totals 1195834 100.000
File : L:\MSDATA\480162.D Operator : JHL Acquired : 22 Sep 2000 2:25 pm using AcqMethod VOL Sample Name: 1,2,4-Trimethylbenzene Lot# 48016/2 Misc Info : 40 C hold 2' then 240 C @ 8 C/min. hold 10' Vial Number: 12 CurrentMeth: C:\HPCHEM\1\METHODS\VOL.M
10 20 30 40 50 60 70 80 90 100 110 1200
1000
2000
3000
4000
5000
6000
7000
8000
9000
m/z-->
Abundance
Scan 2544 (21.856 min): 480162.D105
120
77 9139 51 6559 988545 113
10 20 30 40 50 60 70 80 90 100 110 1200
1000
2000
3000
4000
5000
6000
7000
8000
9000
m/z-->
Abundance
#119306: Benzene, 1,2,4-trimethyl-105
120
77 915139 6559 85 982715
5.00 10.00 15.00 20.00 25.00 30.00 35.000
200000
400000
600000
800000
1000000
1200000
1400000
1600000
1800000
2000000
Time-->
Abundance
TIC: 480162.D 21.86
