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An experimental investigation of hydrogen- enriched gasoline in a Wankel rotary engine F. Amrouche a, *, P. Erickson b , J. Park b , S. Varnhagen b a Renewable Energy Development Center, Hydrogen e Renewable Energy, B.P. 62, Observatory Street, Bouzare ´ah, Algiers 16340, Algeria b Mechanical and Aerospace Engineering Department, UC Davis, CA 95616, USA article info Article history: Received 29 January 2014 Received in revised form 13 March 2014 Accepted 22 March 2014 Available online 19 April 2014 Keywords: Hydrogen Gasoline Wankel rotary engine Combustion Emissions abstract The Wankel rotary engine is a potential alternative to the reciprocating engine in hybrid applications because of its favorable energy to weight ratio. In this study, a Wankel rotary engine was modified to run on a hydrogenegasoline blend. Hydrogen enrichment improved the performance of a lean-burn spark-ignition rotary engine operating at high speed and wide open throttle conditions with the original ignition timing, using 0%, %2, 4%, 5%, 7%, and 10% hydrogen energy fractions at the intake. The experimental results showed that adding hydrogen to gasoline in the engine improved the thermal efficiency and the power output. Hydrocarbon and carbon monoxide emissions were reduced while nitrogen oxide emissions increased with the increase of hydrogen fraction. Copyright ª 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. Introduction Pollution and the fossil fuel depletion are among the most important concerns in the last decade. The transportation sector that largely depends on fossil fuels and is responsible for a large portion of pollution emissions has received particular attention from scientific and political communities. Hydrogen is considered an alternative for conventional fuels because it can be produced from renewable energy sources and also, when burned in air produces only NOx as harmful emissions [1]. However, when hydrogen is used in the spark ignition engine, it can lead to combustion problems such as back firing, auto-ignition and pre-ignition. Also, the low volumetric energy density of gaseous hydrogen makes storage onboard the vehicle a great technical challenge for the transportation sector. Therefore, blends of hydrogen with a hydrocarbon fuel can be an alternative that offers the possi- bility of enhancing the mixture by taking advantage of prop- erties from both fuels. Indeed, the use of hydrogen as enrichment technique is shown to improve the engine emis- sions and performance for many fuels such as landfill gas [2], natural gas [3] and methane [4], gasoline [5e8], ethanol [9], and methanol [10]. Hydrogen blending can also partially resolve the difficulties of onboard storage of hydrogen by requiring a much smaller amount of hydrogen fuel to be stored and transported. Furthermore, hydrogen blending could poten- tially serve as the first step toward widespread use of hydrogen fuel as applied to the transportation sector. * Corresponding author. Tel.: þ213 771125072. E-mail address: [email protected] (F. Amrouche). Available online at www.sciencedirect.com ScienceDirect journal homepage: www.elsevier.com/locate/he international journal of hydrogen energy 39 (2014) 8525 e8534 http://dx.doi.org/10.1016/j.ijhydene.2014.03.172 0360-3199/Copyright ª 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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  • ww.sciencedirect.com

    i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n en e r g y 3 9 ( 2 0 1 4 ) 8 5 2 5e8 5 3 4

    Available online at w

    ScienceDirect

    journal homepage: www.elsevier .com/locate/he

    An experimental investigation of hydrogen-enriched gasoline in a Wankel rotary engine

    F. Amrouche a,*, P. Erickson b, J. Park b, S. Varnhagen b

    aRenewable Energy Development Center, Hydrogen e Renewable Energy, B.P. 62, Observatory Street, Bouzareah,

    Algiers 16340, AlgeriabMechanical and Aerospace Engineering Department, UC Davis, CA 95616, USA

    a r t i c l e i n f o

    Article history:

    Received 29 January 2014

    Received in revised form

    13 March 2014

    Accepted 22 March 2014

    Available online 19 April 2014

    Keywords:

    Hydrogen

    Gasoline

    Wankel rotary engine

    Combustion

    Emissions

    * Corresponding author. Tel.: 213 771125072E-mail address: [email protected]

    http://dx.doi.org/10.1016/j.ijhydene.2014.03.10360-3199/Copyright 2014, Hydrogen Ener

    a b s t r a c t

    The Wankel rotary engine is a potential alternative to the reciprocating engine in hybrid

    applications because of its favorable energy to weight ratio. In this study, a Wankel rotary

    engine was modified to run on a hydrogenegasoline blend. Hydrogen enrichment

    improved the performance of a lean-burn spark-ignition rotary engine operating at high

    speed and wide open throttle conditions with the original ignition timing, using 0%, %2, 4%,

    5%, 7%, and 10% hydrogen energy fractions at the intake. The experimental results showed

    that adding hydrogen to gasoline in the engine improved the thermal efficiency and the

    power output. Hydrocarbon and carbon monoxide emissions were reduced while nitrogen

    oxide emissions increased with the increase of hydrogen fraction.

    Copyright 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rightsreserved.

    Introduction

    Pollution and the fossil fuel depletion are among the most

    important concerns in the last decade. The transportation

    sector that largely depends on fossil fuels and is responsible

    for a large portion of pollution emissions has received

    particular attention from scientific and political communities.

    Hydrogen is considered an alternative for conventional fuels

    because it can be produced from renewable energy sources

    and also, when burned in air produces only NOx as harmful

    emissions [1]. However, when hydrogen is used in the spark

    ignition engine, it can lead to combustion problems such as

    back firing, auto-ignition and pre-ignition. Also, the low

    volumetric energy density of gaseous hydrogenmakes storage

    .om (F. Amrouche).72gy Publications, LLC. Publ

    onboard the vehicle a great technical challenge for the

    transportation sector. Therefore, blends of hydrogen with a

    hydrocarbon fuel can be an alternative that offers the possi-

    bility of enhancing the mixture by taking advantage of prop-

    erties from both fuels. Indeed, the use of hydrogen as

    enrichment technique is shown to improve the engine emis-

    sions and performance for many fuels such as landfill gas [2],

    natural gas [3] andmethane [4], gasoline [5e8], ethanol [9], and

    methanol [10]. Hydrogen blending can also partially resolve

    the difficulties of onboard storage of hydrogen by requiring a

    much smaller amount of hydrogen fuel to be stored and

    transported. Furthermore, hydrogen blending could poten-

    tially serve as the first step toward widespread use of

    hydrogen fuel as applied to the transportation sector.

    ished by Elsevier Ltd. All rights reserved.

    mailto:[email protected]://crossmark.crossref.org/dialog/?doi=10.1016/j.ijhydene.2014.03.172&domain=pdfwww.sciencedirect.com/science/journal/03603199www.elsevier.com/locate/hehttp://dx.doi.org/10.1016/j.ijhydene.2014.03.172http://dx.doi.org/10.1016/j.ijhydene.2014.03.172http://dx.doi.org/10.1016/j.ijhydene.2014.03.172
  • Fig. 1 e Schematic of Wankel rotary engine.

    i n t e rn a t i o n a l j o u r n a l o f h y d r o g e n en e r g y 3 9 ( 2 0 1 4 ) 8 5 2 5e8 5 3 48526

    Hydrogen enrichment has been shown to extend the lean

    operating limit of many fuel-air flames [11]. Lean burn has

    been proven to increase thermal efficiency, and decrease

    brake specific fuel consumption but can potentially decrease

    engine flame stability [11]. The lean operating limit in an en-

    gine depends on combustion parameters such the flame speed

    and the fuel flammability limit. A slow flame speed typically

    will result in combustion instability, decreased heat release,

    and increased HC emissions [12]. The lean flammability limit

    of a fuel/air mixture also depends on the thermal diffusivity,

    reaction rate, and specific heat of the reactants. Both the

    thermal diffusivity and reaction rate are increased with the

    addition of hydrogen. Moreover, hydrogen has a diffusion

    coefficient of 0.61 cm3/s which is larger than most fuels. This

    improved diffusion improves homogeneity of themixture [13].

    In the literature, reciprocating spark ignition engines

    fueled by gasoline and hydrogen have been reported [5e8].

    However, there are no reports of hydrogen enrichment with

    the Wankel rotary engine which is an alternative to the

    reciprocating engine [14,15], especially for hybrid vehicle ap-

    plications [16].

    The Wankel engine, by using an eccentric rotary design

    instead of reciprocating pistons to produce motion is less

    complicated and has an advantage of high power to weight

    ratio as compared to similar reciprocating engines. The

    Wankel is generally more compact, has less vibration, and

    lower noise and power losses than a similar reciprocating

    engine. The Wankel also generally has flat torque character-

    istics. In the Wankel engine three combustion events occur

    with each full rotation of the rotor yielding high power espe-

    cially at the higher end of the operating speed domain. This

    results in higher performance at high speeds with a smooth

    operation of the engine [14,15].

    However, the Wankel engine also has some distinct dis-

    advantages such as: Sealing problems [14] and low power

    output at low speeds. Furthermore, Wankel engines typically

    have lower thermodynamic efficiency because of the long

    combustion-chamber shape. High emissions of NOx, CO and

    especially HC are another problem in the rotary engine. These

    drawbacks are mainly caused by the rotarys long geometry

    and relatively larger quenching area. Additionally, unburned

    gas leakage past seals to the exhaust chamber, creates further

    emissions [15].

    The experience gained through the years in operating the

    reciprocating engine with hydrogen has led to the promise of

    theWankel engine being particularly well suited for hydrogen

    enrichment. Theoretical reasons for this are as follows. The

    presence of hydrogen can make a significant difference in

    terms of emissions and performance by extending the lean

    operating conditions because of the wide flammability limits

    of hydrogen. Moreover, the absence of an exhaust valve which

    is a common hot spot in reciprocating engines causing pre-

    ignition and the physical separation of combustion and

    exhaust chambers can prevent pre-ignition and/or backfire.

    Also, the higher turbulence within the rotary combustion

    chamber could allow a leaner operating limit to be reached.

    Furthermore, the high hydrogen flame speed and relatively

    small quenching distance potentially eliminate difficulties

    with the rotary engine flame quenching. Brown et al. [1]

    experimentally investigated the performance of a single

    rotorWankel engine fueled on pure hydrogen. The enginewas

    operated at a part and open throttle at relative equivalence

    ratios varying from 1 to 4. They found out that the maximum

    power was decreased but the brake thermal efficiency in-

    creases at part load as compared to gasoline while the NOx

    emissions change was found to be negligible. Salanki [17]

    carried out an experimental study of the hydrogen fueled ro-

    tary engine for hybrid vehicle applications. They used a 2.2 kW

    Wankel rotary engine at WOT and lean conditions. The pre-

    liminary results showed an absence of combustion difficulties

    and NOx emissions are on the order of 5 ppm for power out-

    puts up to 70% of the maximum attainable on hydrogen fuel.

    Mazda has been developing hydrogen vehicles with

    hydrogen Rotary Engines (RE) from the early 1990s. Recently,

    the company has delivered the RX-8 Hydrogen RE powered. To

    achieve high power density, injectors are installed on the top

    of the housing for direct injection, and other injectors are

    placed on air intake ports. The combination of the direct and

    port injection has brought simultaneous achievement of high

    power, NOx reduction and better thermal efficiency. For

    further improvement in fuel efficiency, lean burn operation is

    used [18].

    Because all published studies found in literature are

    focused on the performance of pure hydrogen in the Wankel

    engine, we have a strong motivation to investigate the effect

    of hydrogen addition to a gasoline fueled single rotor Wankel

    engine. This study provides experimental data on the engine

    performance and emissions at or near the Lower Operating

    Limit as found with gasoline only operation. Because the best

    operating of the Wankel engine is reached at high speed, a

    speed of 3000 rpm and a wide open throttle was used during

    these tests.

    Experimental procedure

    Experimental setup

    The engine used in this test bench is a 0.530 L single rotor, air

    cooled Wankel engine, using a single spark plug. The

    http://dx.doi.org/10.1016/j.ijhydene.2014.03.172http://dx.doi.org/10.1016/j.ijhydene.2014.03.172
  • Table 1 e OMC Wankel engine technical specifications.

    Type of engine Rotary Wankel engine

    Number of rotors Single rotor

    Cooling Air cooled

    Engine manufacturer Outboard Marine Corps, USA

    Ignition source Spark plug

    Fuel supply system Fuel injection

    Displacement (cc) 530 cm3

    Compression ratio 8.75e1

    Power output 26 kW @ 5500 rpm

    Weight 27 kg

    Fuel 50 parts gasoline, 1 part oil

    Engine geometry

    Eccentricity 3 generating radius 3 width of rotor housing (mm) 13.97 mm 92.202 mm 77.7748 mm

    i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n en e r g y 3 9 ( 2 0 1 4 ) 8 5 2 5e8 5 3 4 8527

    schematic of theWankel engine used in this study is shown in

    Fig. 1. This engine is manufactured by Outboard Marine Cor-

    poration, USA. The engine Technical Specifications are listed

    in Table 1.

    This OMC Wankel engine was initially built with a carbu-

    retor to prepare the intake air/fuel mixture. To achieve real

    time control over the air/fuel mixture preparation as well as

    hydrogen addition, two fuel injection systems were added,

    one for gasoline and the other for hydrogen, the two injectors

    were mounted into an aluminum block in the fueling system,

    this block became a mixing chamber that allows the gasoline

    vapor and fumigated hydrogen tomix in the intake air stream.

    The aluminum injector block was mounted between the en-

    gine and the carburetor. The carburetor is used only as a

    throttle body for the engine. The gasoline fuel flow was

    metered by a calibrated Micromotion CMF010M Coriolis flow

    meter with an RFT9739 transmitter with an accuracy of 0.10%

    of rate for flow rates of 0e23 g/s. The hydrogen used in this

    study was bottled industrial hydrogen (99.95% purity) that is

    regulated down to 35 PSIG (2.41 bar) after two steps of pressure

    reduction, and is regulated and metered via a calibrated Aal-

    borg differential pressure mass flow controller, model GFC 47,

    with an accuracy of 3% (0e20% full scale), and 1.5%(20e100% full scale). The air mass flow was metered via a

    specifically designed orifice plate, and a large air chamber was

    added past the intake to damp cyclic variations in air flow

    caused by the engine operation. The inlet temperature of air

    was also measured. The schematic of the experimental set up

    is shown in Fig. 2.

    The spark timing, injection timing and pulse durations of

    hydrogen and gasoline were controlled via a hybrid electronic

    control unit (HECU) developed in the laboratory. That HECU

    uses the original electromotive ECU, two different softwares

    (Wintech Electromotive and National Instruments (Austin TX)

    LabView version 7 software) and computers for the control of

    the injection timing and pulse durations of gasoline and

    hydrogen according to the desired air-to-fuel ratio and the

    specified hydrogen energy fractions in the intake.

    The exhaust emissions were filtered, and water vapor was

    removed. The sample was then split between three calibrated

    emissions measurement systems. These were:

    1) a Horiba MEXA-574GE emissions analyzer, which analyzes

    the HC, CO, CO2 and O2. The O2 and HC emissions were

    determined by a hydrogen flame ionization detection

    method, and the CO and CO2 were measured by a non-

    dispersive infrared method. The Horiba has a time

    response less than 10 s, a repeatability of 0.04%, 20 ppm,

    0.1%, and 0.4%, respectively, for CO, HC, CO2 and O2.

    2) a California Analytical model 400 Heated Chem-

    iluminescence Photodiode Detector (HCLD) for measuring

    NO and NOx. The resolution of this equipment is 0.1 ppm,

    repeatability of 0.5% of full-scale, and sensitivity up to

    5 ppm.

    3) a California Analytical model 300 Non dispersive Infrared

    (NDIR) Analyzer for measuring CO, and CO2, it has a line-

    arity and repeatability of better than 1%, and a 90%

    response time of in 2 s.

    During the experiment, the measured emissions showed a

    good consistency between the different systems.

    The air to fuel ratio was determined in three ways. There

    were:

    1) Monitoring by the HoribaMEXA-574GE emissions analyzer;

    2) Direct calculation of the ratio from the measured mass

    flow rate of air, gasoline and hydrogen;

    3) A Bosch Universal Exhaust Gas Oxygen (UEGO) sensor

    installed in the exhaust stream. This sensor was controlled

    by an Innovative Motorsports LC-1 wideband controller

    which determined the real time oxygen content in the

    exhaust stream and output a predicted air-to-fuel ratio.

    This air-to-fuel ratio was used as a feedback signal ratio, in

    a closed loop control system, by the ECU to achieve more

    precise control of the air-to-fuel ratio.

    The calculated andmeasured air to fuel ratios has shown a

    good agreement between the three methods during all the

    experiments.

    The specific equivalence ratio of the gaso-

    lineehydrogeneair mixture was calculated by Eq. (1) [5]:

    l _mair.

    _mg$AFst;g _mH2$AFst;H2

    (1)

    where _mair, _mg, _mH2are respectively the measured air, gasoline

    and hydrogen mass flow rates (kg/h). AFst,g and AFst;H2 are the

    stoichiometric air-to-fuel ratios of gasoline and hydrogen,

    such as AFst,g 14.6 and AFst;H2 34:3.A calibrated Kistler 6051B high temperature piezoelectric

    pressure transducer was used to capture the working

    http://dx.doi.org/10.1016/j.ijhydene.2014.03.172http://dx.doi.org/10.1016/j.ijhydene.2014.03.172
  • Fig. 2 e Schematic of the experimental set up.

    Table 2 e Engine operating conditions during theexperiments.

    Hydrogen energy fraction 0%, %2, 4%, 5%, 7%, 10%

    Ignition timing

    (degree Crank Angle BTDC)

    15

    Engine speed (rpm) 3000

    Equivalence ratio f LOL of gasoline

    Throttle position Wide open

    i n t e rn a t i o n a l j o u r n a l o f h y d r o g e n en e r g y 3 9 ( 2 0 1 4 ) 8 5 2 5e8 5 3 48528

    chamber pressure data. This transducer is mounted in the

    engine housing that was machined and tapped for this pur-

    pose. The signal was amplified using a Kistler 5010B charge

    amplifier. A 58-tooth (60-2) trigger wheel and a Hall effect

    magnetic sensor were mounted on the engines output shaft

    to obtain crank angle position data, the crank angle signal was

    synchronized with the pressure trace.

    The pressure and crank angle were recorded using Na-

    tional Instruments (Austin TX) LabView version 7 software.

    Chamber pressure and crank angle signals for over 100

    consecutive cycles were sampled and treated post process via

    Matlab to obtain chamber pressure against crank angle

    profiles.

    A Telma CC100 eddy current dynamometer was coupled to

    the engine to control and measure the engine speed and tor-

    que output.

    The control of the dynamometer as well as the majority of

    data acquisition in the engine test cell was accomplished

    using components from the Superflow 742 product line. The

    brain of the system was the Superflow ProSensor box, which

    communicated with the Superflow ProConsole and Superflow

    WinDyn software for real time data display.

    Tests conditions

    The tests were performed at an engine speed of 3000 rpm and

    at wide open throttle. After a warm-up period of the engine on

    gasoline, the appropriate air to fuel ratio and hydrogen energy

    fraction was set. The engine was again allowed to come to

    steady state at each operating condition and the data were

    collected. Table 2 summarizes the operating conditions used

    in the experiments.

    There are different methods of defining engine lean oper-

    ating limit (LOL). As defined by Badr [19] the lean misfire limit

    or LOL is defined as the equivalence ratio at which first misfire

    occurs. Also it is defined by Shiomoto [20] as the equivalence

    ratio at which CO and HC emissions starts to increase. Ma [12]

    defined the LOL as the excess air ratio (defined as the recip-

    rocal of equivalence ratio) at which coefficient of variations

    (COV) in IMEP reaches 10%. This is because it is generally

    accepted that a COV above 10%will be perceived by a driver as

    a poor running condition. However, in this study, LOL was

    based the equivalence ratio at which first misfire occurs when

    the engine was running on pure gasoline.

    For this work, the hydrogen input was adjusted according

    to the intake energy of the gasoline fuel. For each energy

    fraction of hydrogen added to the fuel mixture, gasoline flow

    rate was reduced through decreasing gasoline flow rate by the

    ECU to keep the global excess air ratio of the hydrogen gas-

    olineeair mixture at an approximately fixed air-to-fuel

    equivalence ratio for gasoline.

    The hydrogen energy fraction in the total fuel energy varies

    from 0% to 10%. The lean operating limit of gasoline which is

    equal to an equivalence ratio of 0.77 was used during these

    tests. Since we wanted to investigate the effect of different

    amount of hydrogen addition on engine performance and

    emissions with all engine operation parameters unchanged,

    http://dx.doi.org/10.1016/j.ijhydene.2014.03.172http://dx.doi.org/10.1016/j.ijhydene.2014.03.172
  • (a)

    (b)

    0 1 2 3 4 5 6 7 8 9 10 11 1210

    12

    14

    16

    18

    20

    22

    24

    26

    Hydrogen Energy Fraction (%)

    )raB(

    erusserPrebmah

    Cgnikro

    Wmu

    mi xaM

    22.5

    25

    27.5

    30)C

    DTA

    D(erusser

    i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n en e r g y 3 9 ( 2 0 1 4 ) 8 5 2 5e8 5 3 4 8529

    so the spark timing was kept at 15 CA BTDC of the originalengine. Such a fixed ignition timing control strategy was also

    adopted by other researchers for exploring the performance of

    hydrogen-enriched engines [5,21e25].

    The energy fraction of hydrogen in the total intake gas is

    defined as energy fraction, calculated as follow [26]:

    %H2 "

    _mH2 LHVH2

    _mg LHVg _mH2 LHVH2

    # 100 (2)

    where _mH2 , _mg are respectively themass flow rate of hydrogen

    and gasoline (g/s).

    LHVH2 , LHVg are the lower heating value, respectively, of

    hydrogen and gasoline (MJ/kg), such as LHVH2 120:1,LHVg 43.5.

    The maximum working chamber temperature was calcu-

    lated from the pressure in this paper using the ideal gas law

    [27]:

    Tmax Pmax Vmmix RMix

    (3)

    where Rmix,mmix, Pmax,V are respectively the gas constant, the

    mass of the mixture, the maximum working chamber pres-

    sure and working chamber volume.

    The error bars shown represent the standard deviation.

    2.5

    5

    7.5

    10

    12.5

    15

    17.5

    20

    Prebmah

    Cgnikro

    Wmu

    mixaMrof

    elgnA

    kn

    Results and discussion

    Working chamber pressure trace

    Fig. 3 shows the variations of the working chamber pressure

    according to the crank angle with hydrogen enrichment levels

    of 0%, 2%, 4%, 5%, 7%, and 10% energy fraction, at a constant

    TDC BDC -90+902

    4

    6

    8

    10

    12

    14

    16

    18

    20

    22

    Crank Angle(Degree)

    Pres

    sure

    (bar

    )

    0% H22% H24% H25% H27% H210% H2

    -70

    Fig. 3 eWorking chamber pressure trace for 0%, 2%, 4%, 5%,

    7% and 10% hydrogen energy fractions.

    0 1 2 3 4 5 6 7 8 9 10 11 120

    Hydrogen Energ Fraction(%)

    arC

    Fig. 4 e a) Maximum working chamber pressure at

    different hydrogen energy fraction levels; b) the relevant

    Crank angle of maximum working chamber pressure at

    different hydrogen energy fractions.

    spark timing of 15 DBTDC and at LOL. According to the pres-

    sure trace data, the working chamber pressure increases as

    the hydrogen fraction increases. Because of high flame speed

    (six times faster than that of gasoline), a larger heating value

    and diffusivity of hydrogen, with hydrogen addition, the peak

    working chamber pressure is raised earlier and is much closer

    to TDC than the gasoline fueled engine pressure trace, but

    after reaching its peak value, pressure drops more quickly

    than the pure gasoline fueled engine, which means the com-

    bustion duration and post-ignition temperature is reduced

    with hydrogen addition. This yields a more isochoric heat

    release theoretically yielding better efficiency in the energy

    conversion process. The sudden jump in pressure around

    90 (Fig. 3) is due to the sensor coming into contact with thefollowing working chamber.

    http://dx.doi.org/10.1016/j.ijhydene.2014.03.172http://dx.doi.org/10.1016/j.ijhydene.2014.03.172
  • 0 1 2 3 4 5 6 7 8 9 10 11 125

    6

    7

    8

    9

    10

    11

    12

    13

    14

    15

    Hydrogen Energy Fraction (%)

    )w

    K(rewoP

    ekarB

    detcerroC

    EAS

    Fig. 6 e SAE corrected indicated brake power at different

    hydrogen energy fractions.

    i n t e rn a t i o n a l j o u r n a l o f h y d r o g e n en e r g y 3 9 ( 2 0 1 4 ) 8 5 2 5e8 5 3 48530

    At lean conditions, the fuel is harder to ignite than at

    stoichiometric condition which is why the spark timing has to

    be advanced at LOL [5]. However, the spark timing in this

    experiment is fixed at 15 DBTDC, which makes the combus-

    tion for pure gasoline suffer. The high diffusivity, the low

    flammability limit and the low ignition energy of the hydrogen

    improve the combustion of the gasolineehydrogen fuel

    mixture. This hydrogen addition makes the air/fuel mixture

    more homogenous and increases laminar burning velocity

    that results in increased maximum pressure. This increases

    the maximum pressure in the working chamber as shown in

    Fig. 4a. For pure gasoline, at fixed spark timing, the combus-

    tion duration is longer when running close to LOL and the

    gasoline in the working chamber is incompletely burnt

    resulting in a reduced working chamber combustion temper-

    ature and pressure. However, when hydrogen is added the

    combustion is shorter and that phenomenon continues as the

    hydrogen fraction increases [6].

    As is shown in Fig. 4b, when hydrogen is added at fixed

    spark timing, it advances the relevant crank angle for the peak

    working chamber pressure. Indeed, since the same ignition

    timing has been adopted, the increase of peak pressure value

    and the shift of its position toward TDC for the blends prove

    that combustion speed increases as the hydrogen content in

    the blend increases. Furthermore, it was demonstrated by

    Kahraman et al., [28] andMa et al., [22] the engine performance

    peaks generally when the crank angle for the maximum cyl-

    inder pressure appears around 10e15 DCA ATDC. Hydrogen

    appears to shift the maximum peak pressure around this

    location in DCA when the hydrogen energy fraction is over 4%.

    This is likely due to the low ignition energy and fast flame

    speed of hydrogen that improves the combustion by short-

    ening the flame development and propagation durations,

    which offer the same effect as increasing spark advance [5].

    Brake thermal efficiency

    The thermal efficiency of an engine is an important factor in

    determining the performance of an automobile [15] and its

    economics [5].

    0 1 2 3 4 5 6 7 8 9 10 11 1210

    12

    14

    16

    18

    20

    22

    24

    26

    28

    30

    Hydrogen Energy Fraction (%)

    Bra

    ke T

    herm

    al E

    ffici

    ency

    (%)

    Fig. 5 e Brake thermal efficiency at different hydrogen

    energy fractions.

    Fig. 5 shows the change in brake thermal efficiency with

    variation of the hydrogen energy fraction added to the gaso-

    line at 3000 rpm, at the LOL. As it can be seen in Fig. 5, for pure

    gasoline, the brake thermal efficiency of this engine is rela-

    tively low. However, when hydrogen is added the brake

    thermal efficiency increaseswith the increase of the hydrogen

    fraction to about 28.8% with 10% hydrogen energy fraction.

    When pure gasoline is used in the engine, the highest thermal

    efficiency is found close stoichiometric conditions near 22%,

    and with the increase of excess air found at the LOL, the

    combustion becomes incomplete, resulting in a lower power

    output and brake thermal efficiency [5].

    Therefore, because of hydrogens high diffusion, heating

    value (hydrogen is 120.97 MJ/kg, while gasoline is 44.4 MJ/kg),

    flame speed (six times higher than that of gasoline), and the

    wider flammability range of hydrogen, higher charge homo-

    geneity and shortened burn duration and a more complete

    and faster combustion of hydrogen enriched gasolineeair

    mixtures at LOL is observed. This contributes to decreased

    cooling and exhausts losses, leading to a higher brake thermal

    efficiency than the baseline. Indeed, adding hydrogen to the

    air/fuel mixture has a significant effect on reducing the flame

    quenching distance, and also reduces the combustion dura-

    tion during expansion, reducing losses during the combustion

    by more closely approximating an ideal constant volume heat

    release, which leads to an increase in thermal efficiency.

    As it was noted by Salanki et al. [17], who ran a rotary en-

    gine at 3300 rpmwith pure hydrogen, use of hydrogen leads to

    an increase in thermal efficiency as compared to gasoline

    especially in a lean condition where the equivalence ratio is

    ranging between 0.3 and 1.

    Compared to the reciprocating engine, the Wankel rotary

    engine is known to have higher cooling losses because of a

    larger surface to volume ratio of the working chamber and a

    longer time required for one-cycle (1. 5 times longer than that

    of the equivalent reciprocating engine). Hence, for higher

    thermal efficiency it is effective to raise the burning speed

    which allows a more isochoric combustion. The hydrogen

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  • (a)

    (b)

    0 1 2 3 4 5 6 7 8 9 10 11 1230

    40

    50

    60

    70

    80

    90

    100

    Hydrogen Energy Fraction (%)

    Volu

    met

    ric E

    ffici

    ency

    (%)

    70 75 80 85 90 95 100 10550

    55

    60

    65

    70

    75

    80

    85

    90

    95

    100

    Rotor Temparature(Degree Celcius)

    )%(

    ycneiciffEcirte

    muloV

    Fig. 7 e a) Volumetric efficiency at different hydrogen

    energy fractions; b) volumetric efficiency dependence on

    rotor temperature.

    (a)

    (b)

    0 1 2 3 4 5 6 7 8 9 10 11 12200

    225

    250

    275

    300

    325

    350

    375

    400

    425

    450

    475

    500

    525

    550

    575

    600

    Hydrogen Energy Fraction (%)

    )h-wk/g(noitp

    musnoCleuF

    cificepSekar

    B

    300 325 350 375 400 425 450 475 500 525 55015

    16

    17

    18

    19

    20

    21

    22

    23

    24

    25

    26

    27

    28

    29

    30

    Brake Specific Fuel Consumption(g/kw-h)

    Bra

    ke T

    herm

    al E

    ffici

    ency

    (%)

    Fig. 8 e a) Brake specific fuel consumption at different

    hydrogen energy fractions; b) thermal efficiency

    dependence on brake specific fuel consumption.

    820

    840

    )suicl

    1700

    1800

    (Deg

    ree

    Cel

    cius

    )Exhaust Temperature

    Maximum Working Chamber Temperature

    i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n en e r g y 3 9 ( 2 0 1 4 ) 8 5 2 5e8 5 3 4 8531

    addition contributes to raising the burn velocity, which is a

    solution to obtaining stronger squish flow and better output

    performance which becomes especially true at high speed.

    This confirms the fact that even a small amount of hydrogen

    addition effectively improves the engine lean burn capability

    in the Wankel engine as shown by the data collected.

    0 2 4 6 8 10 12760

    780

    800

    Hydrogen Energy Fraction (%)

    eC

    eergeD(

    erutarepmeTtsuahxE

    -2 0 2 4 6 8 10 121400

    1500

    1600

    Max

    imum

    Wor

    king

    Cha

    mbe

    r Tem

    pera

    ture

    Fig. 9 e Exhaust gas temperature and the maximum

    working chamber temperature for different hydrogen

    energy fractions.

    SAE corrected indicated brake power

    To insure that repeatable data could be collected on a daywith

    different ambient conditions, the power output was corrected

    using SAE standard J1349. Fig. 6 shows the SAE corrected brake

    power. As expected, running the engine on gasoline at the

    LOL, reduces the power produced by the engine because less

    fuel is burned completely. Therefore, when hydrogen is added

    there is a slight improvement at these operating conditions.

    The brake power of a Wankel rotary engine fueled on

    hydrogen enriched gasoline showed an improvement in per-

    formance as compared to pure gasoline. Compared to recip-

    rocating engines, at high speed the Wankel rotary engine

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  • i n t e rn a t i o n a l j o u r n a l o f h y d r o g e n en e r g y 3 9 ( 2 0 1 4 ) 8 5 2 5e8 5 3 48532

    produces more overall power due to less parasitic power los-

    ses moving air in and out of the engine and smaller frictional

    losses because of the absence of a reciprocating mass. Further

    theWankel has a high charging efficiency due to longer intake

    and exhaust strokes, and the absence of intake and exhaust

    valves causing gas flow resistance. Also, since hydrogen has

    fast burning characteristics, it is expected that better torque

    results at high speed operation because in this condition the

    engine needs a fuel which burns more quickly. Furthermore,

    the engine brake torque increases with the increase of the

    hydrogen energy fraction. Contributing to this torque increase

    is the complete burn up of fuel as enabled by the smaller

    quenching distance of the hydrogen fuel. The Wankel engine

    has historically suffered from a large relative area and related

    quenching by its rotor housing interface resulting in higher

    squish flow. Decreasing the quenching distance by adding

    hydrogen enables previously unburnt fuel to attain combus-

    tion adding to the torque and the related efficiency.

    Volumetric efficiency

    Volumetric efficiency is a parameter related to the load and

    temperature on the Wankel. An increase in the temperature

    was indicative of a decrease in the density of themixture inlet

    into the combustion chamber, reducing volumetric efficiency.

    Since this engine is air-cooled, the operating temperature in-

    side the housing is dependent on load rather than being

    thermostatically controlled to a set value as in liquid-cooled

    engines. As the operating temperature increases in the

    housing there is less liquid fuel vaporized in the working

    chamber, and the charge cooling decreases, thus reducing the

    volumetric efficiency. As can be seen in Fig. 7a, as the

    hydrogen energy fraction increases, there is less liquid fuel

    vaporized inside the working chamber, which leads to less

    charge cooling, resulting in lower volumetric efficiency.

    Additionally, adding hydrogen increases the combustion

    temperature, resulting in higher temperature of the rotor and

    working chamber causing a lower volumetric efficiency

    compared to the same equivalence ratio as shown in Fig. 7b.

    Previous studies made on pure hydrogen fueled rotary engine

    air cooled, have shown the same behavior of the engine

    regarding the effect of the volumetric efficiency and the rotor

    temperature [17]. It should also be noted that as a low-density

    gaseous fuel, hydrogen displaces a significant amount of air

    further lowering the volumetric efficiency.

    Brake specific fuel consumption (BSFC)

    Fig. 8a shows the brake specific fuel consumption for the

    Wankel engine running on pure gasoline and hydrogen

    enriched 0%, 2%, 4%, 5%, 7%, and 10% energy fraction of gas-

    oline at LOL and 3000 rpm. According to Fig. 8a, the BFSC de-

    creases from 506 g/kWh for pure gasoline to 312 g/kWh with

    an addition of 10% by energy fraction of hydrogen which

    represents a drop of about 38%, and this is attributedmainly to

    an increased thermal efficiency (see Fig. 8b) and the higher

    specific energy value of hydrogen. The higher the mean

    effective pressure is, the better the specific fuel consumption

    will be. The main reason for this is that a higher mean effec-

    tive pressure relatively reduces the effect of more constant

    frictional losses. Also, the increase of combustion duration

    which occurs at low equivalence ratios increases the BSFC.

    Exhaust temperature and the working chamber maximumtemperature

    As can be seen in Fig. 9, at the LOL, when hydrogen enrich-

    ment increases, the exhaust temperature dropped and is

    proportional with the increase of hydrogen energy fraction. At

    the LOL, because of the increased efficiency due to shorter

    burn duration, the additions of hydrogen lead to a fast and

    complete combustion of the fuel/air mixtures, less fuel is

    burnt during the expansion stroke which decreases the post-

    ignition combustion duration and decreases the exhaust los-

    ses as manifested by exhaust temperature. This phenomenon

    was also noted by other researchers [5]. This proves that

    hydrogen is effective for reducing the exhaust losses, espe-

    cially at lean conditions [29].

    The calculated maximum working chamber temperature

    increases as the hydrogen energy fraction increases as shown

    in Fig. 9 and the maximum working chamber temperature

    affects the NOx emissions. These results were also seen by Ji

    et al. [29], where the in-cylinder temperature increased with

    hydrogen addition at the same manifold pressure as

    compared to pure gasoline engine operation.

    Emissions

    Fig. 10a illustrates the brake specific emissions of NOx at the

    LOL, 3000 rpm and WOT. As is shown, the brake specific NOx

    emissions increase with hydrogen blending levels. Moreover,

    the brake specific NOx emissions rise from 0.29 g/kWh for

    pure gasoline to 0.69 g/kWh for a hydrogen energy fraction of

    10%, which represents an increase of over 100% of brake

    specific emissions of NOx. As it was seen previously, this is

    due to the increase of the working chamber pressure and

    temperature that is activated by the fast burning velocity and

    high flame temperature of hydrogen which tends to stimulate

    the formation of thermal NOx.

    However, as it can be seen in Fig. 10b, the HC emissions

    decrease from 0.0309 g/kWh for pure gasoline to 0.0046 g/kWh

    for hydrogen enriched at 10% hydrogen energy. This is a drop

    of 85% in HC brake specific emissions. Indeed, when the pure

    gasoline is burnt, as the fuel/air mixture approaches the LOL

    there is less fuel burnt and more air which leads to an

    incomplete combustion and some partial misfiring which in-

    creases the production of a hydrocarbon emissions for pure

    gasoline. On the other hand, because hydrogen has a high

    flame speed, low ignition energy, wide flammability and

    diffusivity and small quenching distance, HC emissions

    caused by incomplete combustion decrease. As explained

    previously flame quenching occurs when a flame propagates

    close to the chamberwall or a crevice in the engine. The cooler

    wall acts as a heat sink, preventing complete combustion in

    the region close to the wall or within the crevice, increasing

    the emissions of HC and CO. This phenomenon is more pro-

    nounced in the case of the Wankel engine because of its ge-

    ometry. Adding hydrogen has a significant effect on reducing

    the flame quenching distance of the fuel mixture and the

    flame can propagate much closer to the chamber wall than

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  • i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n en e r g y 3 9 ( 2 0 1 4 ) 8 5 2 5e8 5 3 4 8533

    that of gasoline, which reduces HC emissions caused by the

    crevice effect [7].

    As presented in Fig. 10c, the CO brake specific emissions

    decrease with the increase of hydrogen energy fraction. It can

    be seen in that Fig. 10c that the CO brake specific emissions

    drop from 2.409 g/kWh for pure gasoline to 0.86 g/kWh for 10%

    hydrogen which represents a drop of about 64% in CO brake

    specific emissions. That is explained by the fact that because

    the maximum working chamber temperature increased with

    hydrogen addition the oxidation reaction of CO into CO2 is

    stimulated. Moreover, because the gasoline is partly replaced

    by hydrogen that does not contain a carbon atom, the

    hydrogen enriched gasoline exhausts less carbonaceous

    emissions than the original gasoline engine [7,5].

    Fig. 10d shows the variation of the CO2 brake specific

    emissions against the hydrogen energy fraction of 0%, 2%, 4%,

    5%, 7%, and 10% at WOT, 3000 rpm and LOL. It can be found

    from Fig. 10d that the CO2 brake specific emissions is reduced

    from 116 g/kWh for pure gasoline to 74 g/kWh with the 10%

    energy fraction of hydrogen added fuel mixture, which rep-

    resents a drop of about 36%. This is due to both the fact that

    hydrogen is carbon free and the fact that efficiency increases.

    (a)

    (b)

    -2 0 2 4 6 8 10 120

    0.1

    0.2

    0.3

    0.4

    0.5

    0.6

    0.7

    0.8

    0.9

    1

    Hydrogen Energy Fraction (%)

    )h-wk/g(x

    ON

    snoissimE

    cificep Sekar

    B

    0 1 2 3 4 5 6 7 8 9 10 11 120

    0.005

    0.01

    0.015

    0.02

    0.025

    0.03

    0.035

    0.04

    Hydrogen Energy Fraction (%)

    )h-wk/g()viuqE

    naxeh-n(C

    Hsnoissi

    mEcificepS

    ekarB

    (c

    (

    Fig. 10 e Brake specific emissions at different hydrog

    Conclusion

    The Wankel rotary engine is a promising alternative to the

    reciprocating engine, especially for hybrid applications.

    Because of the geometry of the Wankel engine, the concept of

    hydrogen enrichment is well suited for the improvement of its

    performance. It has been conclusively proven that a small

    amount of hydrogen by energy fraction improves the perfor-

    mance and emissions with exception of NOx for a Gasoline

    Wankel Rotary Engine at LOL, 3000 rpm, fixed spark timing

    andWOT. Themain conclusions resulting from this paper are

    summarized as follows:

    1) At fixed spark timing and LOL, the pressure trace indicated

    an increase in the peak working chamber pressure with

    advancing the relevant crank angle for peak pressure of a

    gasoline Wankel engine with the increase of hydrogen

    energy fraction added to the fuel mixture, which increases

    the maximum working chamber temperature.

    2) The brake thermal efficiency of the original gasoline

    Wankel rotary engine was enhanced by about 28% over the

    )

    d)

    0 1 2 3 4 5 6 7 8 9 10 11 120

    0.25

    0.5

    0.75

    1

    1.25

    1.5

    1.75

    2

    2.25

    2.5

    2.75

    3

    Hydrogen Energy Fraction (%)

    )hWk/g(

    OC

    s noissimE

    cificepSekar

    B

    0 1 2 3 4 5 6 7 8 9 10 11 1250

    60

    70

    80

    90

    100

    110

    120

    130

    Hydrogen Energy Fraction (%)

    )hWk/g(

    2O

    Csnoissi

    mEcificepS

    ekarB

    en energy fractions: a) NOx; b) HC; c) CO; d) CO2.

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  • i n t e rn a t i o n a l j o u r n a l o f h y d r o g e n en e r g y 3 9 ( 2 0 1 4 ) 8 5 2 5e8 5 3 48534

    baseline by adding 10% energy fraction of hydrogen in the

    gasoline fuel mixture, decreasing the brake specific fuel

    consumption and the exhaust temperature of the engine.

    3) Because of the air cooling system of the engine, the volu-

    metric efficiency is proved to be highly sensitive to the

    operating temperature of the engine (the rotor) and volu-

    metric efficiency decreased with hydrogen enrichment.

    This is also due to the low volumetric energy density of

    hydrogen displacing intake air.

    4) The performance of the original gasolineWankel engine as

    indicated by the Bmep, Torque and Power are improved as

    the energy fraction of hydrogen increases in the fuel

    mixture at the conditions tested.

    5) Because the increase of the peakworking chamber pressure

    and temperature, the NOx brake specific emissions are

    raised by 137% as the energy fraction of hydrogen increased

    from 0% to 10%. However, reductions in the brake specific

    emissions of HC by 85%, COby 64% and CO2 by 36% occurred

    with increasing hydrogen fraction due to better combustion

    of the air/fuel mixture at the conditions tested.

    Acknowledgments

    The authors thank Moller International for their donation of

    the Wankel research engines. The University of California,

    Green Transportation Laboratory and the Hydrogen Produc-

    tion and Utilization Laboratory and all their associated

    members made this work possible.

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experimental investigation of hydrogen-enriched gasoline in a Wankel rotary engineIntroductionExperimental procedureExperimental setupTests conditionsResults and discussionWorking chamber pressure traceBrake thermal efficiencySAE corrected indicated brake powerVolumetric efficiencyBrake specific fuel consumption (BSFC)Exhaust temperature and the working chamber maximum temperatureEmissionsConclusionAcknowledgmentsReferences

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