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APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY ANALYSES
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Page 1: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

APPENDIX G

2007 FUTURE BASE CASE AND SENSITIVITY ANALYSES

Page 2: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-2

Appendix G Table of Contents Page Introduction ………………………………………………………………………………. G-6 2007 Base Case …………………………………………………………………………. G-14 2007 Base Case Performance Evaluation …………………………………………….. G-14 Tile Plots …………………………………………………………………………. G-14 Comparisons Between Model Refinements ………………………………….. G-21 Sensitivity Tests …………………………………………………………………. G-23 Zero-out Runs: Urban Areas ………………………………………….. G-23 Zero-out Runs: Point Sources ………………………………………… G-25 Incremental Removal of VOC and NOx Precursor Emissions …….. G-35 Summary of Modifications to the 1999 Base and 2007 Future Cases and Resulting Design Values ……………………………………………………….. G-38 References ……………………………………………………………………………….. G-47

Page 3: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-3

Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER for a Typical Weekday (Wednesday) ….. G-6 Table G-2 Comparison of 1999 and 2007 Anthropogenic NOx Emissions in the Four-county SAER for a Typical Weekday (Wednesday)…… G-7 Table G-3 Comparison of 1999 and 2007 Predicted Maximum 8-hour Average Ozone Concentrations by Monitor, September 15th - 20th ………………………………………………………………………. G-14 Table G-4 Comparison of Predicted Peak 8-hour Concentrations for Final UT and AACOG Base and Future Case Runs ………………………. G-22 Table G-5 Modifications to the1999 Base Case and 2007 Future Case as

Part of the QA/QC Process and Resulting Peak 8-hour Predictions at CAMS 23 Associated with Each Run ……………………………… G-39

Table G-6 Modifications to the1999 Base Case and 2007 Future Case as Part of the QA/QC Process and Resulting Peak 8-hour Predictions at CAMS 58 Associated with Each Run ……………………………… G-41

Table G-7 Modifications to the1999 Base Case and 2007 Future Case as Part of the QA/QC Process and Resulting Peak 8-hour Predictions at CAMS 59 Associated with Each Run ……………………………… G-43

Table G-8 Modifications to the1999 Base Case and 2007 Future Case as Part of the QA/QC Process and Resulting Peak 8-hour Predictions at CAMS 678 Associated with Each Run……………………………… G-45

Page 4: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-4

Appendix G List of Figures Page Figure G-1 Comparison of 1999 and 2007 Anthropogenic NOx Precursor Emissions from On-road Sources within the 4-km Subdomain on Wednesday, September 15th ……………………………………… G-8 Figure G-2 Comparison of 1999 and 2007 Anthropogenic NOx Precursor Emissions from Area/non-road Sources within the 4-km Subdomain on Wednesday, September 15th……………………………………….. G-9 Figure G-3 Comparison of 1999 and 2007 Anthropogenic NOx Precursor Emissions from Low-level Point Sources within the 4-km Subdomain on Wednesday, September 15th ………………………… G-10 Figure G-4 Comparison of 1999 and 2007 Anthropogenic VOC Precursor Emissions from On-road Sources within the 4-km Subdomain on Wednesday, September 15th ………………………………………. G-11 Figure G-5 Comparison of 1999 and 2007 Anthropogenic VOC Precursor Emissions from Area/non-road Sources within the 4-km Subdomain on Wednesday, September 15th ………………………… G-12 Figure G-6 Comparison of 1999 and 2007 Anthropogenic VOC Precursor Emissions from Low-level Point Sources within the 4-km Subdomain on Wednesday, September 15th ………………………… G-13 Figure G-7 Comparison of 1999 and 2007 Predicted Daily Maximum 8-hour

Ozone Concentrations in the 4-km Subdomain on Wednesday, September 15th ………………………………………………………….. G-15

Figure G-8 Comparison of 1999 and 2007 Predicted Daily Maximum 8-hour Ozone Concentrations in the 4-km Subdomain on Thursday, September 16th ………………………………………………………….. G-16 Figure G-9 Comparison of 1999 and 2007 Predicted Daily Maximum 8-hour Ozone Concentrations in the 4-km Subdomain on Friday, September 17th ………………………………………………………….. G-17 Figure G-10 Comparison of 1999 and 2007 Predicted Daily Maximum 8-hour Ozone Concentrations in the 4-km Subdomain on Saturday, September 18th…………………………………………………………… G-18 Figure G-11 Comparison of 1999 and 2007 Predicted Daily Maximum 8-hour Ozone Concentrations in the 4-km Subdomain on Sunday, September 19th …………………………………………………………. G-19 Figure G-12 Comparison of 1999 and 2007 Predicted Daily Maximum 8-hour Ozone Concentrations in the 4-km Subdomain on Monday, September 20th…………………………………………………………… G-20 Figure G-13 Predicted Reductions in Ozone Concentrations at CAMS 23 after

Zeroing Out Anthropogenic Precursor Emissions for the 11-county Houston Area, 2-county Corpus Christi Area, and 5-county Austin Area from the 1999 Base Case and 2007 Future Case ……………. G-24

Figure G-14 Predicted Reductions in Ozone Concentrations at CAMS 58 after Zeroing Out Anthropogenic Precursor Emissions for the 11-county Houston Area, 2-county Corpus Christi Area, and 5-county Austin Area from the 1999 Base Case and 2007 Future Case ……………. G-25

Figure G-15 Predicted Reductions in Ozone Concentrations at CAMS 23 after Removing Various Point Source Emissions within the SAER– Comparison between 1999 and 2007…………………………………… G-26

Page 5: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-5

Appendix G List of Figures (continued) Page Figure G-16 Predicted Reductions in Ozone Concentrations at CAMS 58 after Removing Various Point Source Emissions within the SAER– Comparison between 1999 and 2007 ………………………. G-27 Figure G-17 Comparison of Zero Out Runs Conducted for CPS Power Plants, Cement Kilns, and Toyota Manufacturing Plant on the 2007 Future Case, Wednesday, September 15th ………………………….. G-29 Figure G-18 Comparison of Zero Out Runs Conducted for CPS Power Plants, Cement Kilns, and Toyota Manufacturing Plant on the 2007 Future Case, Thursday, September 16th……………………………… G-30 Figure G-19 Comparison of Zero Out Runs Conducted for CPS Power Plants, Cement Kilns, and Toyota Manufacturing Plant on the 2007 Future Case, Friday, September 17th…………………………………. G-31 Figure G-20 Comparison of Zero Out Runs Conducted for CPS Power Plants, Cement Kilns, and Toyota Manufacturing Plant on the 2007 Future Case, Saturday, September 18th………………………………………. G-32 Figure G-21 Comparison of Zero Out Runs Conducted for CPS Power Plants, Cement Kilns, and Toyota Manufacturing Plant on the 2007 Future Case, Sunday, September 19th ……………………………………….. G-33 Figure G-22 Comparison of Zero Out Runs Conducted for CPS Power Plants, Cement Kilns, and Toyota Manufacturing Plant on the 2007 Future Case, Monday, September 20th………………………………………… G-34 Figure G-23 Predicted Ozone Concentrations at CAMS 23 after Removing Local NOx and VOC Emissions from CAMx Run 18, Averages for September 15 -20, 1999 and 2007……………………………………. G-36 Figure G-24 Predicted Ozone Concentrations at CAMS 58 after Removing Local NOx and VOC Emissions from CAMx Run 18, Average for September 15 -20, 1999 and 2007……………………………………. G-37

Page 6: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-6

INTRODUCTION To create a 2007 future case on which to model attainment, certain adjustments were made to the 1999 base case. Meteorological fields, boundary/initial conditions, dry deposition algorithms, chemical mechanisms and other model configurations remained identical between the September 1999 and 2007 simulations. However, VOC, NOx, and CO emission estimations from anthropogenic sources were adjusted to account for such factors as anticipated growth/decline in population and employment and the impact of federal, state and regional emission reduction measures. The biogenic emissions inventory (EI) for the 2007 base was the same as that used for the 1999 base case, in accordance with EPA guidelines. Tables G-1 and G-2 provide comparisons between the 1999 anthropogenic modeling EI developed for the four-county San Antonio Early Action Compact Region (SAER) and the 2007 anthropogenic modeling EI. Despite projections in population growth in all four SAER counties between 1999 and 2007, most emissions categories are expected to decrease between the base year and attainment year. Overall, anthropogenic VOC emissions for the SAER were projected to decrease by 20.88% between 1999 and 2007; likewise, anthropogenic NOx emissions were projected to decrease by 30.11% during the same timeframe. Table G-1. Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER for a Typical Weekday (Wednesday). County

On-Road (tpd)

Area / Non-road (tpd)

Point (tpd)

Total (tpd)

1999 Bexar 75.52 111.98 6.30 193.80 Comal 6.15 6.70 0.34 13.20 Guadalupe 5.57 7.77 0.45 13.78 Wilson 1.57 3.73 0.07 5.37 Total (tpd) 88.81 130.18 7.17 226.15

2007 Bexar 42.42 98.55 11.82 152.79 Comal 3.85 5.53 0.52 9.90 Guadalupe 3.42 6.98 1.10 11.50 Wilson 0.98 3.68 0.07 4.74 Total (tpd) 50.67 114.75 13.50 178.93

% Difference between 1999 and 2007 Bexar -43.83% -11.99% 87.47% -21.16% Comal -37.42% -17.45% 50.94% -24.98% Guadalupe -38.63% -10.08% 145.00% -16.58% Wilson -37.42% -1.31% 0.00% -11.82% Total -42.95% -11.85% 88.44% -20.88%

Page 7: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-7

Table G-2. Comparison of 1999 and 2007 Anthropogenic NOx Emissions in the Four-county SAER for a Typical Weekday (Wednesday). County

On-Road (tpd)

Area / Non-road (tpd)

Point (tpd)

Total (tpd)

1999 Bexar 119.57 39.39 88.59 247.55 Comal 11.64 3.57 12.16 27.38 Guadalupe 10.47 4.24 0.51 15.21 Wilson 1.89 0.93 0.00 2.82 Total (tpd) 143.58 48.12 101.26 292.96

2007 Bexar 67.45 39.18 53.24 159.86 Comal 7.07 3.70 13.77 24.53 Guadalupe 6.47 3.40 8.07 17.95 Wilson 1.34 1.04 0.00 2.39 Total (tpd) 82.34 47.32 75.08 204.74

% Difference between 1999 and 2007 Bexar -43.59% -0.53% -39.90% -35.42% Comal -39.30% 3.46% 13.22% -10.39% Guadalupe -38.15% -19.65% 1492.19% 17.99% Wilson -29.00% 12.17% 0.00% -15.44% Total -42.65% -1.67% -25.85% -30.11% Figures G-1 through G-3 provide graphical comparisons of the anthropogenic NOx EIs for 1999 and 2007 by source category, both in terms of magnitude of concentrations and spatial allocation of plumes. Similarly, figures G-4 through G-6 provide graphical comparisons between estimated 1999 and 2007 anthropogenic VOC emissions inventories. As indicated by these pictures, on-road precursor emissions are concentrated in urban areas. By comparison, area/non-road and point source emissions are more dispersed. It is also evident that, overall, most anthropogenic emission categories are expected to decrease between 1999 and 2007.

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Page 14: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-14

2007 BASE CASE Once the 1999 base case was modified by replacing the photochemical model’s emissions inputs (i.e., replacing the 1999 local, state, and regional anthropogenic EI with a 2007 local, state, and regional EI), the model was rerun. The resulting episode projection represents the 2007 future case for the SAER. The impact of modifying the anthropogenic local and regional emissions inventories between the 1999 base and 2007 future cases is demonstrated in table G-3. As shown, the 2007 projection predicts a decrease in ozone concentration at each San Antonio monitoring station (7x7 array of cells near monitor) compared to the 1999 base case predictions. Table G-3. Comparison of 1999 and 2007 Predicted Maximum 8-hour Average Ozone Concentrations by Monitor, September 15th - 20th.

CAMS Station 1999 Predicted 8-hr Max. Ozone

2007 Predicted 8-hr Max. Ozone

1999-2007 Percent Change

CAMS 23 89.0 ppb 84.5 ppb -5.0% CAMS 58 87.8 ppb 82.8 ppb -5.6% CAMS 59 78.1 ppb 73.6 ppb -5.7% CAMS 678 80.1 ppb 77.4 ppb -3.3% 2007 BASE CASE PERFORMANCE EVALUATION Appendix E describes a variety of tests that were conducted on the 1999 base case in order to evaluate model performance. For a future case, such as the 2007 projection, methods of analyzing model performance are more limited. Ozone metrics and several other types of analyses that compare the model’s predictions with actual measurements cannot be performed prior to compilation of those actual future measurements. As a consequence, performance analyses conducted on the 2007 future case were restricted to tile plots, comparisons between model refinements, and sensitivity runs. Tile Plots Tile plots provide an indication of where the model is or isn’t performing correctly given known changes to modeling input in the future case. These plots are visual representations of the model’s predictions and provide such information as when and where the model predicts urban plumes. The following tile plots (figures G-7 through G-12) represent comparisons between the 1999 and 2007 8-hour daily maximum ozone concentrations within the modeling domain for each day of the primary episode.

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G-21

As demonstrated by these plots, urban plumes are replicated predictably, both in terms of intensity and spatial allocation. Peak ozone concentrations are predicted downwind of city centers and major point sources in these tile plots. In addition, the overall reduction in NOx, VOC, and CO emissions (local and regional) between 1999 and 2007 reduced the magnitude of the ozone plumes in each of the daily 1999-2007 comparisons. Comparisons Between Model Refinements As described in appendix E, the original September 1999 model was developed by ENVIRON and refined through a collaboration between ENVIRON, UT Austin1, and AACOG (meteorological model and air quality input refinements). Subsequently, the model was provided to the Texas Near Nonattainment (NNA) partners2, or their contractors, for further modifications. These modifications included refinement of the emissions inventory inputs, development of the future case, and clean air strategy analyses. Because the model was modified by more than one agency during this process, there was a concern that the various agencies’ models would become dissimilar and provide different predictions for the base case, future case, and control strategy runs. A great amount of effort was spent ensuring that the Austin and San Antonio base and future cases contained identical input. Often this involved discussions between the two agencies, as well as TCEQ, regarding the most appropriate EI data for local and regional areas. Discrepancies in emissions inputs were corrected prior to the final AACOG and UT runs. An analysis was conducted by AACOG staff to determine any differences between the final 1999 base case refined by UT Austin and the final base case refined by AACOG, based on predicted concentrations at two Austin monitors. The 2007 future cases developed by UT and AACOG were similarly analyzed. The results of these analyses are provided in table G-4. The table provides daily peak 8-hour predictions within the 7x7 array of cells near the Murchison and Audubon monitors for the 1999 and 2007 base cases. As shown, the differences between predictions by AACOG’s final run (labeled 1999_sos.f) and UT’s final run (labeled 1999_v3) are insignificant. With regards to the Murchison monitor, the average difference (six episode days) in ozone concentrations between the two 1999 base cases was 0.00 ppb, while the average difference at the Audubon monitor was 0.05 ppb. For the 2007 future cases, the average differences in peak ozone concentrations for the six-day episode was -0.06 ppb (Murchison) and –0.04 ppb (Audubon). These results provide additional, independent verification of the performance of the 1999 base case and 2007 future case.

1 UT Austin acted on behalf of Austin modeling. 2 Development of the September 1999 photochemical model simulation was a collaboration between TCEQ and four Texas NNAs: Austin, Corpus Christi, San Antonio, and Victoria.

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Page 23: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-23

Sensitivity Tests Sensitivity tests are used throughout model development as diagnostic tools. These tests are conducted by perturbing model input. Results of sensitivity tests are analyzed in terms of whether the model responded to changes in input and, further, whether the model responded in a manner judged to be appropriate to input modifications. In addition to providing an indication of model performance, sensitivity tests are useful for providing key information. For example, when applied to a projection year base case, sensitivity runs may be used to analyze the impact of emissions sources in the future. Furthermore, these evaluations may be used to predict the impact of control strategies and assist with determining what types of precursor reductions are likely to be the most effective for reducing ozone concentrations. The 2007 future case sensitivity tests were conducted by modifying model input in one of two ways: 1) removing the precursor emissions for specific point sources/urban areas, or 2) reducing the local anthropogenic NOx and VOC emissions inventories in incremental amounts. The results of modifying model input to the 2007 future case are provided in the following sections. Zero-Out Runs: Urban Areas Appendix E describes sensitivity tests conducted on the 1999 base case in which the anthropogenic NOx and VOC EIs for Austin, Corpus Christi, and Houston were removed from, or “zeroed out” of, the model. These tests were also conducted on the 2007 future case, i.e., the 2007 NOx and VOC EIs for Austin, Corpus Christi, and Houston were removed from the future case in three separate tests. Figures G-13 and G-14 provide the predicted changes in ozone concentrations at CAMS 23 and CAMS 58, respectively, after removing the anthropogenic EIs for each of the three urban areas and compares those values to the 1999 sensitivity runs. As shown by the graphs in figures G-13 and G-14, removing the anthropogenic EI for the 11-county Houston area had the greatest predicted impact on 2007 ozone concentrations in the San Antonio area, followed by the 2-county Corpus Christi area and 5-county Austin area. Moreover, this trend is the same whether referring to the 1999 base or 2007 future case sensitivity runs. During the 1999 episode, the predominate wind direction was such that Houston emissions were more likely to impact San Antonio than Austin or Corpus Christi. Since the meteorological inputs remain identical between base and future cases, it stands to reason that Houston emissions would continue to demonstrate the greatest influence on San Antonio ozone concentrations during the September episode.

Page 24: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-24

Figure G-13. Predicted Reductions in Ozone Concentrations at CAMS 23 after Zeroing Out Anthropogenic Precursor Emissions for the 11-county Houston Area, 2-county Corpus Christi Area, and 5-county Austin Area from the 1999 Base Case (orange) and 2007 Future Case (blue).

2.25 parts per billion

0.55 parts per billion

0.24 parts per billion

2.72 parts per billion

0.64 parts per billion

0.27 parts per billion

0.0% 0.5% 1.0% 1.5% 2.0% 2.5% 3.0% 3.5%

Austin Removed

Corpus Removed

Houston Removed

Percent Reduction in Ozone (ppb)

19992007

Page 25: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-25

Figure G-14. Predicted Reductions in Ozone Concentrations at CAMS 58 after Zeroing Out Anthropogenic Precursor Emissions for the 11-county Houston Area, 2-county Corpus Christi Area, and 5-county Austin Area from the 1999 Base Case (orange) and 2007 Future Case (blue).

Zero-Out Runs: Point Sources Analyses were also conducted in which specific point source emissions were removed from the model in separate sensitivity runs. These tests were run at the request of local elected officials and the TCEQ to identify likely strategies (VOC versus NOx) for ambient ozone reductions in the SAER. Figures G-15 and G-16 provide the predicted changes in ozone concentrations at CAMS 23 and 58, as the result of conducting these zero out runs for 1999 and 2007. One run, labeled “CPS Spruce 1 Coal Plant Removed,” simulates the impact of removing a currently-existing 750-megawatt power plant from the 2007 future case in the San Antonio area. A second run, “Remove All CPS Power Plants,” simulates the impact of removing the nine power plants in the San Antonio region in 1999 from the 1999 base case and removing seven power plants (due to anticipated closures of two plants) from the 2007 future case. A third run “Remove Cement Plants” represents the removal of emissions from all cement kilns in the 4-county SAER. The last run, “Toyota Removed,” simulates the impact of removing the EI for a major manufacturing plant from the 2007

2.19 parts per billion

0.45 parts per billion

0.35 parts per billion

2.61 parts per billion

0.57 parts per billion

0.40 parts per billion

0.0% 0.5% 1.0% 1.5% 2.0% 2.5% 3.0% 3.5%

Austin Removed

Corpus Removed

Houston Removed

Percent Reduction in Ozone (ppb)

19992007

Page 26: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-26

Figure G15. Predicted Reductions in Ozone Concentrations at CAMS 23 after Removing Various Point Source Emissions within the SAER– Comparison between 1999 (orange) and 2007 (blue).

0.10 parts per billion

0.01 parts per billion

0.16 parts per billion

1.20 parts per billion

0.0 parts per billion

- 0.17 parts per billion

0.69 parts per billion

-0.2% 0.0% 0.2% 0.4% 0.6% 0.8% 1.0% 1.2% 1.4% 1.6%

Toyota Removed

Remove CementPlants

Remove All CPSPower Plants

CPS Spruce 1Coal Plant Removed*

Percent Reduction in Ozone (ppb)

19992007

*based on 5.93 tons/day of NOx in 2007 only

Page 27: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-27

Figure G-16. Predicted Reductions in Ozone Concentrations at CAMS 58 after Removing Various Point Source Emissions within the SAER– Comparison between 1999 (orange) and 2007(blue).

future case. Since the plant is not scheduled to be in operation until 2006, removing these emissions have no impact on the 1999 base case. As shown in these graphs, removing all power plant emissions had the greatest impact on both the 1999 and 2007 simulations. Since the combined power plants were the largest source of precursors (NOx) of all sources tested, this type of result is expected. Conversely, the Toyota plant, which has the lowest emission rates (primarily VOC), impacts San Antonio ozone concentrations the least. With the exception of the results of removing the cement kiln emissions from the 1999 base case at CAMS 23, each sensitivity run demonstrates a decrease in predicted 1999 or 2007 ozone concentrations. The predicted increase in ozone concentration at CAMS 23 is most likely a reversal of the model’s ozone scavenging process. During much of the 1999 episode, the model predicts conditions in which decreases in NOx cause ozone concentrations to increase (NOx reduction disbenefit). Thus, removing the NOx emissions from kilns near the monitor causes the model to predict increased ozone concentrations at that location in the 1999 base case.

0.08 parts per billion

0.01 parts per billion

0.26 parts per billion

0.97 parts per billion

0.0 parts per billion

0.08 parts per billion

0.74 parts per billion

0.0% 0.2% 0.4% 0.6% 0.8% 1.0% 1.2% 1.4% 1.6% 1.8%

Toyota Removed

Remove CementPlants

Remove All CPSPower Plants

CPS Spruce 1Coal Plant Removed*

Percent Reduction in Ozone (ppb)

19992007

*based on 5.93 tons/day of NOx in 2007 only

Page 28: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-28

This NOx reduction disbenfit is much less evident in the 2007 future case. Consequently, removing the NOx emissions associated with the San Antonio area power plants causes larger ozone reductions in the 2007 future case than in the 1999 base case. Since there are no power plants in the vicinity of CAMS 23, removing the 1999 power plant emissions from the model did not cause an increase in predicted ozone levels in the 1999 base case, as was demonstrated by the cement kiln sensitivity run. At the request of EPA Region 6, the output from each point source “zero out” simulation was run through a graphics program, PAVE, to obtain a visual depiction of the impact of removing these sources in the SAER. The plots for zeroing out point sources were created for all primary episode weekdays, when applicable,3 as shown in figures G-17 through G-22. An advantage these plots have compared to the graphs for CAMS 23 and 58, shown previously, is that they provide an indication of the impact of modifying emissions in terms of spatial distribution. As shown by these graphs, the impact of removing point source emissions was, to a large extent, influenced by the model’s meteorological processes, particularly wind direction. The September 15th – 17th plots, for example, indicate that these emissions primarily affect counties to the west and northwest of Bexar County. In addition, the cement kiln zero out runs tended to show the widest area of influence. This is an expected outcome since the cement kiln emission sources are spread throughout the San Antonio area, whereas all seven CPS power plants are located in southeast Bexar County. Similarly, the Toyota manufacturing plant is represented by a single point in south Bexar County on the plots.

3 Weekends were not included for the Toyota set of sensitivity runs because the plant is not scheduled to be operational on Saturday and Sunday.

Page 29: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-29

Figu

re G

-17.

Com

paris

on o

f Zer

o O

ut R

uns

Con

duct

ed fo

r CPS

Pow

er P

lant

s, C

emen

t Kiln

s, a

nd T

oyot

a M

anuf

actu

ring

Plan

t on

the

2007

Fu

ture

Cas

e, W

edne

sday

, Sep

tem

ber 1

5th.

Rem

oval

of C

PS P

ower

Pl

ant E

mis

sion

s R

emov

al o

f San

Ant

onio

are

a C

emen

t Kiln

Em

issi

ons

Rem

oval

of T

oyot

a M

anuf

actu

ring

Plan

t Em

issi

ons

Page 30: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-30

Figu

re G

-18.

Com

paris

on o

f Zer

o O

ut R

uns

Con

duct

ed fo

r CPS

Pow

er P

lant

s, C

emen

t Kiln

s, a

nd T

oyot

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anuf

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ring

Plan

t on

the

2007

Fu

ture

Cas

e, T

hurs

day,

Sep

tem

ber 1

6th.

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oval

of C

PS P

ower

Pla

nt

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al o

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Ant

onio

Are

a C

emen

t Kiln

Em

issi

ons

Rem

oval

of T

oyot

a M

anuf

actu

ring

Plan

t Em

issi

ons

Page 31: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-31

Figu

re G

-19.

Com

paris

on o

f Zer

o O

ut R

uns

Con

duct

ed fo

r CPS

Pow

er P

lant

s, C

emen

t Kiln

s, a

nd T

oyot

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Plan

t on

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2007

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e, F

riday

, Sep

tem

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7th.

Pr

oble

ms

with

the

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of a

tile

plo

t for

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r 17th

cem

ent k

iln s

ensi

tivity

run

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PS P

ower

Pl

ant E

mis

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s R

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ota

Man

ufac

turin

g Pl

ant E

mis

sion

s

Page 32: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-32

Figu

re G

-20.

Com

paris

on o

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o O

ut R

uns

Con

duct

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r CPS

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lant

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atur

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8th.

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ays

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nt

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Em

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ons

Page 33: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-33

Figu

re G

-21.

Com

paris

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Page 34: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-34

Figu

re G

-22.

Com

paris

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Page 35: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-35

For the most part, removing point source emissions caused the model to predict decreases in ozone concentrations along the area of impact. However, the model also predicts some areas of increased ozone concentrations, the most prominent of which is the Thursday, September 16th plot depicting the impact of zeroing out cement kiln emissions. Likewise some of the Toyota sensitivity runs exhibit small increases in ozone concentrations near the plant, despite the very low NOx emissions the plant represents (0.34 tons/day). This NOx reduction disbenefit is less pronounced in the power plant sensitivity runs. However, these tile plots depict ozone concentrations in the lowest atmospheric grid layer, whereas power plants pollutants are emitted, by computer simulation, into higher grid layers. Incremental Removal of VOC and NOx Precursor Emissions Across-the-board sensitivity runs were conducted by removing 25%, 50%, 75%, and 100% of the local (4-county SAER) NOx emissions, VOC emissions, and combinations of the two, from the 2007 future case. Figures G-23 and G-24 provide the results of the across-the-board reduction runs for CAMS 23 and CAMS 58 (San Antonio downwind monitors), averaged over the six day modeling period conducted on the 1999 base and 2007 future cases. At the 25% reduction level (CAMS 23), VOC reductions were slightly more effective than NOx reductions at lowering ozone concentrations. At CAMS 58, 25% NOx and 25% VOC reductions are equally effective. These results are somewhat different than those predicted for the 1999 base case in that, at the 25% level, VOC reductions were more effective than NOx for reducing ozone concentrations in the SAER. These results tend to support the evaluation of both VOC and NOx control strategies as possible means of reducing ambient ozone concentrations in the San Antonio region.

Page 36: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-36

Figure G-23. Predicted Ozone Concentrations at CAMS 23 after Removing Local NOx and VOC Emissions from CAMx Run 18, Averages for September 15 -20, 1999 and 2007.

60

65

70

75

80

85

90

0% 25% 50% 75% 100%Anthropogenic Emission Reductions (percentage)

Ozo

ne C

once

ntra

tion

(ppb

)

NOx Reduction VOC Reduction NOx & VOC Reduction

8 hour standard - 85 ppb

1999

60

65

70

75

80

85

90

0% 25% 50% 75% 100%Anthropogenic Emission Reductions (percentage)

Ozo

ne C

once

ntra

tion

(ppb

)

NOx Reduction VOC Reduction NOx & VOC Reduction

8 hour standard - 85 ppb

2007

Page 37: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-37

Figure G-24. Predicted Ozone Concentrations at CAMS 58 after Removing Local NOx and VOC Emissions from CAMx Run 18, Average for September 15 -20, 1999 and 2007.

60

65

70

75

80

85

90

0% 25% 50% 75% 100%Anthropogenic Emission Reductions (percentage)

Ozo

ne C

once

ntra

tion

(ppb

)

NOx Reduction VOC Reduction NOx & VOC Reduction

8 hour standard - 85 ppb

1999

60

65

70

75

80

85

90

0% 25% 50% 75% 100%Anthropogenic Emission Reductions (percentage)

Ozo

ne C

once

ntra

tion

(ppb

)

NOx Reduction VOC Reduction NOx & VOC Reduction

8 hour standard - 85 ppb

2007

Page 38: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-38

SUMMARY OF MODIFICATIONS TO THE 1999 BASE AND 2007 FUTURE CASES AND RESULTING DESIGN VALUES As described previously, a great amount of time and effort were spent ensuring the 2007 future cases developed by UT Austin and AACOG were consistent. As part of that effort, UT and AACOG staff, in consultation with the TCEQ, evaluated local and regional 2007 EI files used as input to the two future cases. Whenever inconsistencies in emissions or procedures were identified, staff from UT, AACOG, and the TCEQ determined the most appropriate data to incorporate into the models. Both the UT and AACOG future cases were modified to reflect these decisions. Tables G-5 through G-8 summarize the impact of making these modifications to AACOG’s 2007 future case. The future case runs, labeled A through G, represent the first future case (A) developed by AACOG, projected from the 1999 base case labeled CAMx Run 18 (see appendix E for more information), through the final 2007 future case run (G). The far right column lists changes that were made to the model for each run. Results of making the modifications to the future case model simulation are provided for each monitor in the San Antonio region (CAMS 23, 58, 59, and 678). Based on analyses between the AACOG and UT final future cases (see section on “Comparisons Between Model Refinements”), it is evident that the extra effort required to analyze all model inputs resulted in consistent, well-performing future case simulations on which to model control strategy effectiveness and base attainment demonstrations.

Page 39: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-39

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n ac

tiviti

es

Base

Cas

e.A

2007

84.5

6

Base

Cas

e.B

2007

80

.00

76.2

180

.05

89.4

593

.92

92.6

785

.38

85.0

6

Upd

ated

regi

onal

EI H

DD

non

-road

EI

(pro

vide

d by

TC

EQ)

U

pdat

ed A

ustin

Poi

nt S

ourc

e C

ontro

l EI

(Alc

oa)

U

pdat

ed S

an A

nton

io c

onst

ruct

ion

and

quar

ry e

quip

men

t em

issi

ons

Page 40: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-40

CA

MS

23

(con

tinue

d)

Base

Cas

e.D

20

07

80

.09

76.1

980

.01

89.4

593

.93

92.6

785

.39

85

.07

In

corp

orat

ed n

ew w

aste

wat

er e

stim

ates

Rev

ised

Aus

tin P

oint

Sou

rce

Con

trol E

I (A

lcoa

)

Base

Cas

e.E

2007

79

.70

75.2

079

.57

88.7

392

.48

91.4

584

.52

84.3

5

Rev

ised

Aus

tin P

oint

Sou

rce

Con

trol E

I

Inco

rpor

ated

new

regi

onal

tem

pora

l pro

file

for p

oint

sou

rces

Adde

d C

O fo

r Aus

tin o

n-ro

ad E

I (3

Cou

nty)

Incl

uded

sta

ge1

(125

k) fo

r the

4-c

ount

y Sa

n An

toni

o M

SA

R

emov

ed ta

nk tr

uck

unlo

adin

g on

Sun

day

to

mat

ch E

PA g

uida

nce

U

pdat

ed o

ther

are

a so

urce

tem

pora

l pro

files

to

mat

ch E

PA g

uida

nce

U

pdat

ed T

exas

regi

onal

are

a an

d no

n-ro

ad

emis

sion

s

U

pdat

ed T

exas

poi

nt s

ourc

es (b

esid

es C

PS)

U

pdat

ed L

ehig

h ce

men

t Kiln

con

trols

Upd

ated

poi

nt s

ourc

e cu

t off

poin

t fro

m 2

0m

to 5

0m o

n th

e 4-

km g

rid to

mat

ch th

e 12

-km

gr

id c

ut o

ff

U

pdat

ed V

icto

ria’s

EI

Base

Cas

e F

2007

79

.70

75.2

079

.57

88.7

392

.49

91.4

684

.53

84.4

2

Upd

ated

Vic

toria

's m

obile

EI

U

pdat

ed c

hem

ical

and

tem

pora

l pro

files

for

Texa

s ar

ea a

nd n

on-ro

ad e

mis

sion

s Ba

se C

ase

G

2007

79

.57

75.0

779

.50

88.6

992

.50

91.5

784

.48

84.5

2

Upd

ated

San

Ant

onio

asp

halt

emis

sion

s

Upd

ated

tank

er tr

uck

unlo

adin

g em

issi

ons

U

pdat

ed ta

nker

truc

ks in

tran

sit e

mis

sion

s

Upd

ated

em

issi

ons

from

oth

er g

asol

ine

dist

ribut

ion

activ

ities

Upd

ated

em

issi

ons

for R

OP

cont

rols

Page 41: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-41

Tabl

e G

-6. M

odifi

catio

ns to

the1

999

Base

Cas

e an

d 20

07 F

utur

e C

ase

as P

art o

f the

QA/

QC

Pro

cess

and

Res

ultin

g Pe

ak 8

-hou

r Pr

edic

tions

at C

AMS

58 A

ssoc

iate

d w

ith E

ach

Run

. C

AM

S 58

Pe

ak P

redi

cted

8-h

our O

zone

Con

cent

ratio

ns

R

un L

abel

Ye

ar

15th

16

th

17th

18

th

19th

20

th

Aver

age

Base

Cas

e D

esig

n Va

lue

Mod

ifica

tions

to M

odel

Base

Cas

e.A

1999

75.

95 7

7.44

81

.93

98.6

8 10

2.75

91.6

6 88

.07

87.0

0

Base

Cas

e.B

1999

75.

95 7

7.44

81

.93

98.6

7 10

2.68

91.6

4 88

.05

87.0

0

Upd

ated

qua

rry a

nd c

onst

ruct

ion

equi

pmen

t em

issi

ons

Base

Cas

e.D

19

99 7

5.95

77.

44

81.9

298

.67

102.

6891

.63

88.0

587

.00

Inco

rpor

ated

new

was

tew

ater

est

imat

es fr

om

San

Anto

nio

Wat

er S

yste

m

Base

Cas

e.E

1999

76.

00 7

7.41

81

.87

98.7

2 10

1.92

91.5

0 87

.90

87.0

0

Upd

ated

199

9 ar

ea a

nd n

on-ro

ad s

ourc

e te

mpo

ral p

rofil

es fo

r reg

iona

l Tex

as to

mat

ch

2007

tem

pora

l pro

files

Upd

ated

poi

nt s

ourc

e cu

t off

poin

t fro

m 2

0m

to 5

0m fo

r the

4km

grid

Ba

se C

ase

F 19

99 7

5.74

77.

44

82.1

698

.67

101.

9091

.51

87.9

087

.00

Upd

ated

Vic

toria

's m

obile

EI w

ith la

test

dat

a fro

m U

T

Upd

ated

che

mic

al a

nd te

mpo

ral p

rofil

es fo

r Te

xas

area

and

non

-road

em

issi

ons

Upd

ated

Vic

toria

's p

oint

sou

rces

Upd

ated

Tex

as N

EGU

and

EG

U s

ourc

es

outs

ide

of H

oust

on

U

pdat

ed L

ouis

iana

poi

nt s

ourc

e em

issi

ons

U

pdat

ed A

ustin

’s a

rea

& no

n-ro

ad s

ourc

es

Base

Cas

e G

19

99 7

5.59

77.

26

82.0

198

.57

101.

8391

.30

87.7

687

.00

Upd

ated

San

Ant

onio

asp

halt

emis

sion

s

Upd

ated

tank

er tr

uck

unlo

adin

g em

issi

ons

U

pdat

ed ta

nker

truc

ks in

tran

sit e

mis

sion

s

Upd

ated

em

issi

ons

for o

ther

gas

olin

e di

strib

utio

n ac

tiviti

es

Base

Cas

e.A

2007

82

.19

Ba

se C

ase.

B 20

07 7

4.11

75.

41

79.0

789

.45

93.9

290

.17

83.6

982

.69

Upd

ated

regi

onal

EI H

DD

non

-road

EI

(pro

vide

d by

TC

EQ)

U

pdat

ed A

ustin

Poi

nt S

ourc

e C

ontro

l EI

(Alc

oa)

U

pdat

ed S

an A

nton

io c

onst

ruct

ion

and

quar

ry e

quip

men

t em

issi

ons

Page 42: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-42

CA

MS

58

(con

tinue

d)

Base

Cas

e.D

20

07

74

.28

75

.40

79.0

2

89

.45

93.9

3

90

.18

83.7

1

82

.71

In

corp

orat

ed n

ew w

aste

wat

er e

stim

ates

Rev

ised

Aus

tin P

oint

Sou

rce

Con

trol E

I (A

lcoa

) Ba

se C

ase.

E 20

07 7

3.91

74.

46

78.5

788

.73

92.4

889

.17

82.8

982

.03

Rev

ised

Aus

tin P

oint

Sou

rce

Con

trol E

I

Inco

rpor

ated

new

regi

onal

tem

pora

l pro

file

for p

oint

sou

rces

Adde

d C

O fo

r Aus

tin o

n-ro

ad E

I (3

Cou

nty)

Incl

uded

sta

ge1

(125

k) fo

r the

4-c

ount

y Sa

n An

toni

o M

SA

R

emov

ed ta

nk tr

uck

unlo

adin

g on

Sun

day

to

mat

ch E

PA g

uida

nce

U

pdat

ed o

ther

are

a so

urce

tem

pora

l pro

files

to

mat

ch E

PA g

uida

nce

U

pdat

ed T

exas

regi

onal

are

a an

d no

n-ro

ad

emis

sion

s

U

pdat

ed T

exas

poi

nt s

ourc

es (b

esid

es C

PS)

U

pdat

ed L

ehig

h ce

men

t Kiln

con

trols

Upd

ated

poi

nt s

ourc

e cu

t off

poin

t fro

m 2

0m

to 5

0m o

n th

e 4-

km g

rid to

mat

ch th

e 12

-km

gr

id c

ut o

ff

U

pdat

ed V

icto

ria E

I Ba

se C

ase

F 20

07 7

3.90

74.

46

78.5

788

.73

92.4

989

.18

82.8

982

.04

Upd

ated

Vic

toria

's m

obile

EI

U

pdat

ed c

hem

ical

and

tem

pora

l pro

files

for

Texa

s ar

ea a

nd n

on-ro

ad e

mis

sion

s Ba

se C

ase

G

2007

73.

80 7

4.28

78

.50

88.6

9 92

.50

89.2

5 82

.84

82.1

2

Upd

ated

San

Ant

onio

asp

halt

emis

sion

s

Upd

ated

tank

er tr

uck

unlo

adin

g em

issi

ons

U

pdat

ed ta

nker

truc

ks in

tran

sit e

mis

sion

s

Upd

ated

em

issi

ons

from

oth

er g

asol

ine

dist

ribut

ion

activ

ities

Upd

ated

em

issi

ons

for R

OP

cont

rols

Page 43: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-43

Tabl

e G

-7. M

odifi

catio

ns to

the1

999

Base

Cas

e an

d 20

07 F

utur

e C

ase

as P

art o

f the

QA/

QC

Pro

cess

and

Res

ultin

g Pe

ak 8

-hou

r Pr

edic

tions

at C

AMS

59 A

ssoc

iate

d w

ith E

ach

Run

. G

ray

strik

e-th

roug

h nu

mbe

rs a

re v

alue

s th

at fa

ll be

low

the

EPA

requ

irem

ent (

EPA

1999

, p. 4

1) o

f 70

ppb

to b

e in

clud

ed in

the

RR

F C

AM

S 59

Pe

ak P

redi

cted

8-h

our O

zone

Con

cent

ratio

ns

Run

Lab

el

Year

15

th

16th

17

th

18th

19

th

20th

Av

erag

eBa

se C

ase

Des

ign

Valu

e M

odifi

catio

ns to

Mod

el

Base

Cas

e.A

1999

66.

95 7

2.04

69

.83

72.5

3 83

.04

86.6

5 76

.82

79.0

0

Base

Cas

e.B

1999

66.

95 7

2.04

69

.83

72.5

3 82

.90

86.6

1 76

.78

79.0

0

Upd

ated

qua

rry a

nd c

onst

ruct

ion

equi

pmen

t em

issi

ons

Base

Cas

e.D

19

99 6

6.95

72.

04

69.8

372

.53

82.9

086

.60

76.7

879

.00

Inco

rpor

ated

new

was

tew

ater

est

imat

es fr

om

San

Anto

nio

Wat

er S

yste

m

Base

Cas

e.E

1999

67.

33 7

2.30

69

.86

72.5

8 82

.24

86.2

5 76

.65

79.0

0

Upd

ated

199

9 ar

ea a

nd n

on-ro

ad s

ourc

e te

mpo

ral p

rofil

es fo

r reg

iona

l Tex

as to

mat

ch

2007

tem

pora

l pro

files

Upd

ated

poi

nt s

ourc

e cu

t off

poin

t fro

m 2

0m

to 5

0m fo

r the

4km

grid

Ba

se C

ase

F 19

99 6

7.12

72.

33

70.0

972

.38

81.9

086

.46

76.6

379

.00

Upd

ated

Vic

toria

's m

obile

EI w

ith la

test

dat

a fro

m U

T

Upd

ated

che

mic

al a

nd te

mpo

ral p

rofil

es fo

r Te

xas

area

and

non

-road

em

issi

ons

Upd

ated

Vic

toria

's p

oint

sou

rces

Upd

ated

Tex

as N

EGU

and

EG

U s

ourc

es

outs

ide

of H

oust

on

U

pdat

ed L

ouis

iana

poi

nt s

ourc

e em

issi

ons

U

pdat

ed A

ustin

’s a

rea

& no

n-ro

ad s

ourc

es

Base

Cas

e G

19

99 6

6.89

72.

38

69.9

072

.12

81.7

586

.26

78.1

379

.00

Upd

ated

San

Ant

onio

asp

halt

emis

sion

s

Upd

ated

tank

er tr

uck

unlo

adin

g em

issi

ons

U

pdat

ed ta

nker

truc

ks in

tran

sit e

mis

sion

s

Upd

ated

em

issi

ons

for o

ther

gas

olin

e di

strib

utio

n ac

tiviti

es

Base

Cas

e.A

2007

74

.96

Ba

se C

ase.

B 20

07 6

4.65

67.

40

67.6

868

.97

78.7

384

.15

73.3

875

.51

Upd

ated

regi

onal

EI H

DD

non

-road

EI

(pro

vide

d by

TC

EQ)

U

pdat

ed A

ustin

Poi

nt S

ourc

e C

ontro

l EI

(Alc

oa)

Page 44: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-44

CA

MS

59

(con

tinue

d)

Base

Cas

e.D

20

07

64

.70

67

.40

67.6

6

68

.97

78.7

3

84

.15

73.3

8

75

.51

U

pdat

ed S

an A

nton

io c

onst

ruct

ion

and

quar

ry e

quip

men

t em

issi

ons

In

corp

orat

ed n

ew w

aste

wat

er e

stim

ates

Rev

ised

Aus

tin P

oint

Sou

rce

Con

trol E

I (A

lcoa

) Ba

se C

ase.

E 20

07 6

4.25

65.

90

68.0

569

.21

76.9

983

.03

72.6

474

.87

Rev

ised

Aus

tin P

oint

Sou

rce

Con

trol E

I

Inco

rpor

ated

new

regi

onal

tem

pora

l pro

file

for p

oint

sou

rces

Adde

d C

O fo

r Aus

tin o

n-ro

ad E

I (3

Cou

nty)

Incl

uded

sta

ge1

(125

k) fo

r the

4-c

ount

y Sa

n An

toni

o M

SA

R

emov

ed ta

nk tr

uck

unlo

adin

g on

Sun

day

to

mat

ch E

PA g

uida

nce

U

pdat

ed o

ther

are

a so

urce

tem

pora

l pro

files

to

mat

ch E

PA g

uida

nce

U

pdat

ed T

exas

regi

onal

are

a an

d no

n-ro

ad

emis

sion

s

U

pdat

ed T

exas

poi

nt s

ourc

es (b

esid

es C

PS)

U

pdat

ed L

ehig

h ce

men

t Kiln

con

trols

Upd

ated

poi

nt s

ourc

e cu

t off

poin

t fro

m 2

0m

to 5

0m o

n th

e 4-

km g

rid to

mat

ch th

e 12

-km

gr

id c

ut o

ff

U

pdat

ed V

icto

ria E

I Ba

se C

ase

F 20

07 6

4.25

65.

90

68.0

569

.21

77.0

183

.05

72.6

474

.89

Upd

ated

Vic

toria

's m

obile

EI

U

pdat

ed c

hem

ical

and

tem

pora

l pro

files

for

Texa

s ar

ea a

nd n

on-ro

ad e

mis

sion

s Ba

se C

ase

G

2007

63.

98 6

5.93

67

.82

68.9

2 76

.84

82.9

6 73

.66

74.4

8

Upd

ated

San

Ant

onio

asp

halt

emis

sion

s

Upd

ated

tank

er tr

uck

unlo

adin

g em

issi

ons

U

pdat

ed ta

nker

truc

ks in

tran

sit e

mis

sion

s

Upd

ated

em

issi

ons

from

oth

er g

asol

ine

dist

ribut

ion

activ

ities

Upd

ated

em

issi

ons

for R

OP

cont

rols

Page 45: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-45

Tabl

e G

-8. M

odifi

catio

ns to

the1

999

Base

Cas

e an

d 20

07 F

utur

e C

ase

as P

art o

f the

QA/

QC

Pro

cess

and

Res

ultin

g Pe

ak 8

-hou

r Pr

edic

tions

at C

AMS

678

Asso

ciat

ed w

ith E

ach

Run

. G

ray

strik

e-th

roug

h nu

mbe

rs a

re v

alue

s th

at fa

ll be

low

the

EPA

requ

irem

ent (

EPA

1999

, p.

41)

of 7

0 pp

b to

be

incl

uded

in th

e R

RF

CA

MS

678

Peak

Pre

dict

ed 8

-hou

r Ozo

ne C

once

ntra

tions

R

un L

abel

Ye

ar

15th

16

th

17th

18

th

19th

20

th

Aver

age

Base

Cas

e D

esig

n Va

lue

Mod

ifica

tions

to M

odel

Base

Cas

e A

1999

70.

34 7

1.19

69

.83

80.0

3 92

.94

88.4

7 78

.80

77.0

0

Base

Cas

e B

1999

70.

33 7

1.19

69

.83

80.0

1 92

.81

88.3

3 78

.75

77.0

0

Upd

ated

qua

rry a

nd c

onst

ruct

ion

equi

pmen

t em

issi

ons

Base

Cas

e D

19

99 7

0.33

71.

19

69.8

380

.01

92.8

088

.32

78.7

577

.00

Inco

rpor

ated

new

was

tew

ater

est

imat

es fr

om

San

Anto

nio

Wat

er S

yste

m

Base

Cas

e E

1999

70.

57 7

1.45

69

.86

80.0

6 91

.99

87.9

2 78

.64

77.0

0

Upd

ated

199

9 ar

ea a

nd n

on-ro

ad s

ourc

e te

mpo

ral p

rofil

es fo

r reg

iona

l Tex

as to

mat

ch

2007

tem

pora

l pro

files

Upd

ated

poi

nt s

ourc

e cu

t off

poin

t fro

m 2

0m

to 5

0m fo

r the

4km

grid

Ba

se C

ase

F 19

99 7

0.39

71.

50

70.0

979

.81

91.6

087

.84

78.5

477

.00

Upd

ated

Vic

toria

's m

obile

EI w

ith la

test

dat

a fro

m U

T

Upd

ated

che

mic

al a

nd te

mpo

ral p

rofil

es fo

r Te

xas

area

and

non

-road

em

issi

ons

Upd

ated

Vic

toria

's p

oint

sou

rces

Upd

ated

Tex

as N

EGU

and

EG

U s

ourc

es

outs

ide

of H

oust

on

U

pdat

ed L

ouis

iana

poi

nt s

ourc

e em

issi

ons

U

pdat

ed A

ustin

’s a

rea

& no

n-ro

ad s

ourc

es

Base

Cas

e G

19

99 7

0.16

71.

51

69.9

079

.63

91.4

987

.65

80.0

977

.00

Upd

ated

San

Ant

onio

asp

halt

emis

sion

s

Upd

ated

tank

er tr

uck

unlo

adin

g em

issi

ons

U

pdat

ed ta

nker

truc

ks in

tran

sit e

mis

sion

s

Upd

ated

em

issi

ons

for o

ther

gas

olin

e di

strib

utio

n ac

tiviti

es

Base

Cas

e A

2007

74

.71

Ba

se C

ase

B 20

07 7

0.43

69.

14

68.9

976

.78

87.0

389

.14

76.9

275

.21

Upd

ated

regi

onal

EI H

DD

non

-road

EI

(pro

vide

d by

TC

EQ)

U

pdat

ed A

ustin

Poi

nt S

ourc

e C

ontro

l EI

(Alc

oa)

Page 46: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G

-46

CA

MS

678

(con

tinue

d)

Base

Cas

e D

20

07

70

.56

69

.14

68.9

4

76

.77

87.0

4

89

.14

76.9

3

75

.22

U

pdat

ed S

an A

nton

io c

onst

ruct

ion

and

quar

ry e

quip

men

t em

issi

ons

In

corp

orat

ed n

ew w

aste

wat

er e

stim

ates

Rev

ised

Aus

tin P

oint

Sou

rce

Con

trol E

I (A

lcoa

) Ba

se C

ase

E 20

07 7

0.08

68.

00

68.8

976

.26

85.5

387

.83

76.1

074

.51

Rev

ised

Aus

tin P

oint

Sou

rce

Con

trol E

I

Inco

rpor

ated

new

regi

onal

tem

pora

l pro

file

for p

oint

sou

rces

Adde

d C

O fo

r Aus

tin o

n-ro

ad E

I (3

Cou

nty)

Incl

uded

sta

ge1

(125

k) fo

r the

4-c

ount

y Sa

n An

toni

o M

SA

R

emov

ed ta

nk tr

uck

unlo

adin

g on

Sun

day

to

mat

ch E

PA g

uida

nce

U

pdat

ed o

ther

are

a so

urce

tem

pora

l pro

files

to

mat

ch E

PA g

uida

nce

U

pdat

ed T

exas

regi

onal

are

a an

d no

n-ro

ad

emis

sion

s

U

pdat

ed T

exas

poi

nt s

ourc

es (b

esid

es C

PS)

U

pdat

ed L

ehig

h ce

men

t Kiln

con

trols

Upd

ated

poi

nt s

ourc

e cu

t off

poin

t fro

m 2

0m

to 5

0m o

n th

e 4-

km g

rid to

mat

ch th

e 12

-km

gr

id c

ut o

ff

U

pdat

ed V

icto

ria E

I Ba

se C

ase

F 20

07 7

0.08

68.

00

68.8

976

.26

85.5

587

.84

76.1

074

.61

Upd

ated

Vic

toria

's m

obile

EI

U

pdat

ed c

hem

ical

and

tem

pora

l pro

files

for

Texa

s ar

ea a

nd n

on-ro

ad e

mis

sion

s Ba

se C

ase

G

2007

69.

89 6

7.86

68

.75

76.1

1 85

.50

87.8

7 77

.45

74.4

6

Upd

ated

San

Ant

onio

asp

halt

emis

sion

s

Upd

ated

tank

er tr

uck

unlo

adin

g em

issi

ons

U

pdat

ed ta

nker

truc

ks in

tran

sit e

mis

sion

s

Upd

ated

em

issi

ons

from

oth

er g

asol

ine

dist

ribut

ion

activ

ities

Upd

ated

em

issi

ons

for R

OP

cont

rols

Page 47: APPENDIX G 2007 FUTURE BASE CASE AND SENSITIVITY … · G-3 Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER

G-47

REFERENCES U.S. Environmental Protection Agency (May 1999). Draft Guidance on the Use of Models and Other Analyses in Attainment Demonstrations for the 8-hour Ozone NAAQS. Research Triangle Park, NC: Office of Air Quality Planning and Standards.


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