APPENDIX G
2007 FUTURE BASE CASE AND SENSITIVITY ANALYSES
G-2
Appendix G Table of Contents Page Introduction ………………………………………………………………………………. G-6 2007 Base Case …………………………………………………………………………. G-14 2007 Base Case Performance Evaluation …………………………………………….. G-14 Tile Plots …………………………………………………………………………. G-14 Comparisons Between Model Refinements ………………………………….. G-21 Sensitivity Tests …………………………………………………………………. G-23 Zero-out Runs: Urban Areas ………………………………………….. G-23 Zero-out Runs: Point Sources ………………………………………… G-25 Incremental Removal of VOC and NOx Precursor Emissions …….. G-35 Summary of Modifications to the 1999 Base and 2007 Future Cases and Resulting Design Values ……………………………………………………….. G-38 References ……………………………………………………………………………….. G-47
G-3
Appendix G List of Tables Page Table G-1 Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER for a Typical Weekday (Wednesday) ….. G-6 Table G-2 Comparison of 1999 and 2007 Anthropogenic NOx Emissions in the Four-county SAER for a Typical Weekday (Wednesday)…… G-7 Table G-3 Comparison of 1999 and 2007 Predicted Maximum 8-hour Average Ozone Concentrations by Monitor, September 15th - 20th ………………………………………………………………………. G-14 Table G-4 Comparison of Predicted Peak 8-hour Concentrations for Final UT and AACOG Base and Future Case Runs ………………………. G-22 Table G-5 Modifications to the1999 Base Case and 2007 Future Case as
Part of the QA/QC Process and Resulting Peak 8-hour Predictions at CAMS 23 Associated with Each Run ……………………………… G-39
Table G-6 Modifications to the1999 Base Case and 2007 Future Case as Part of the QA/QC Process and Resulting Peak 8-hour Predictions at CAMS 58 Associated with Each Run ……………………………… G-41
Table G-7 Modifications to the1999 Base Case and 2007 Future Case as Part of the QA/QC Process and Resulting Peak 8-hour Predictions at CAMS 59 Associated with Each Run ……………………………… G-43
Table G-8 Modifications to the1999 Base Case and 2007 Future Case as Part of the QA/QC Process and Resulting Peak 8-hour Predictions at CAMS 678 Associated with Each Run……………………………… G-45
G-4
Appendix G List of Figures Page Figure G-1 Comparison of 1999 and 2007 Anthropogenic NOx Precursor Emissions from On-road Sources within the 4-km Subdomain on Wednesday, September 15th ……………………………………… G-8 Figure G-2 Comparison of 1999 and 2007 Anthropogenic NOx Precursor Emissions from Area/non-road Sources within the 4-km Subdomain on Wednesday, September 15th……………………………………….. G-9 Figure G-3 Comparison of 1999 and 2007 Anthropogenic NOx Precursor Emissions from Low-level Point Sources within the 4-km Subdomain on Wednesday, September 15th ………………………… G-10 Figure G-4 Comparison of 1999 and 2007 Anthropogenic VOC Precursor Emissions from On-road Sources within the 4-km Subdomain on Wednesday, September 15th ………………………………………. G-11 Figure G-5 Comparison of 1999 and 2007 Anthropogenic VOC Precursor Emissions from Area/non-road Sources within the 4-km Subdomain on Wednesday, September 15th ………………………… G-12 Figure G-6 Comparison of 1999 and 2007 Anthropogenic VOC Precursor Emissions from Low-level Point Sources within the 4-km Subdomain on Wednesday, September 15th ………………………… G-13 Figure G-7 Comparison of 1999 and 2007 Predicted Daily Maximum 8-hour
Ozone Concentrations in the 4-km Subdomain on Wednesday, September 15th ………………………………………………………….. G-15
Figure G-8 Comparison of 1999 and 2007 Predicted Daily Maximum 8-hour Ozone Concentrations in the 4-km Subdomain on Thursday, September 16th ………………………………………………………….. G-16 Figure G-9 Comparison of 1999 and 2007 Predicted Daily Maximum 8-hour Ozone Concentrations in the 4-km Subdomain on Friday, September 17th ………………………………………………………….. G-17 Figure G-10 Comparison of 1999 and 2007 Predicted Daily Maximum 8-hour Ozone Concentrations in the 4-km Subdomain on Saturday, September 18th…………………………………………………………… G-18 Figure G-11 Comparison of 1999 and 2007 Predicted Daily Maximum 8-hour Ozone Concentrations in the 4-km Subdomain on Sunday, September 19th …………………………………………………………. G-19 Figure G-12 Comparison of 1999 and 2007 Predicted Daily Maximum 8-hour Ozone Concentrations in the 4-km Subdomain on Monday, September 20th…………………………………………………………… G-20 Figure G-13 Predicted Reductions in Ozone Concentrations at CAMS 23 after
Zeroing Out Anthropogenic Precursor Emissions for the 11-county Houston Area, 2-county Corpus Christi Area, and 5-county Austin Area from the 1999 Base Case and 2007 Future Case ……………. G-24
Figure G-14 Predicted Reductions in Ozone Concentrations at CAMS 58 after Zeroing Out Anthropogenic Precursor Emissions for the 11-county Houston Area, 2-county Corpus Christi Area, and 5-county Austin Area from the 1999 Base Case and 2007 Future Case ……………. G-25
Figure G-15 Predicted Reductions in Ozone Concentrations at CAMS 23 after Removing Various Point Source Emissions within the SAER– Comparison between 1999 and 2007…………………………………… G-26
G-5
Appendix G List of Figures (continued) Page Figure G-16 Predicted Reductions in Ozone Concentrations at CAMS 58 after Removing Various Point Source Emissions within the SAER– Comparison between 1999 and 2007 ………………………. G-27 Figure G-17 Comparison of Zero Out Runs Conducted for CPS Power Plants, Cement Kilns, and Toyota Manufacturing Plant on the 2007 Future Case, Wednesday, September 15th ………………………….. G-29 Figure G-18 Comparison of Zero Out Runs Conducted for CPS Power Plants, Cement Kilns, and Toyota Manufacturing Plant on the 2007 Future Case, Thursday, September 16th……………………………… G-30 Figure G-19 Comparison of Zero Out Runs Conducted for CPS Power Plants, Cement Kilns, and Toyota Manufacturing Plant on the 2007 Future Case, Friday, September 17th…………………………………. G-31 Figure G-20 Comparison of Zero Out Runs Conducted for CPS Power Plants, Cement Kilns, and Toyota Manufacturing Plant on the 2007 Future Case, Saturday, September 18th………………………………………. G-32 Figure G-21 Comparison of Zero Out Runs Conducted for CPS Power Plants, Cement Kilns, and Toyota Manufacturing Plant on the 2007 Future Case, Sunday, September 19th ……………………………………….. G-33 Figure G-22 Comparison of Zero Out Runs Conducted for CPS Power Plants, Cement Kilns, and Toyota Manufacturing Plant on the 2007 Future Case, Monday, September 20th………………………………………… G-34 Figure G-23 Predicted Ozone Concentrations at CAMS 23 after Removing Local NOx and VOC Emissions from CAMx Run 18, Averages for September 15 -20, 1999 and 2007……………………………………. G-36 Figure G-24 Predicted Ozone Concentrations at CAMS 58 after Removing Local NOx and VOC Emissions from CAMx Run 18, Average for September 15 -20, 1999 and 2007……………………………………. G-37
G-6
INTRODUCTION To create a 2007 future case on which to model attainment, certain adjustments were made to the 1999 base case. Meteorological fields, boundary/initial conditions, dry deposition algorithms, chemical mechanisms and other model configurations remained identical between the September 1999 and 2007 simulations. However, VOC, NOx, and CO emission estimations from anthropogenic sources were adjusted to account for such factors as anticipated growth/decline in population and employment and the impact of federal, state and regional emission reduction measures. The biogenic emissions inventory (EI) for the 2007 base was the same as that used for the 1999 base case, in accordance with EPA guidelines. Tables G-1 and G-2 provide comparisons between the 1999 anthropogenic modeling EI developed for the four-county San Antonio Early Action Compact Region (SAER) and the 2007 anthropogenic modeling EI. Despite projections in population growth in all four SAER counties between 1999 and 2007, most emissions categories are expected to decrease between the base year and attainment year. Overall, anthropogenic VOC emissions for the SAER were projected to decrease by 20.88% between 1999 and 2007; likewise, anthropogenic NOx emissions were projected to decrease by 30.11% during the same timeframe. Table G-1. Comparison of 1999 and 2007 Anthropogenic VOC Emissions in the Four-county SAER for a Typical Weekday (Wednesday). County
On-Road (tpd)
Area / Non-road (tpd)
Point (tpd)
Total (tpd)
1999 Bexar 75.52 111.98 6.30 193.80 Comal 6.15 6.70 0.34 13.20 Guadalupe 5.57 7.77 0.45 13.78 Wilson 1.57 3.73 0.07 5.37 Total (tpd) 88.81 130.18 7.17 226.15
2007 Bexar 42.42 98.55 11.82 152.79 Comal 3.85 5.53 0.52 9.90 Guadalupe 3.42 6.98 1.10 11.50 Wilson 0.98 3.68 0.07 4.74 Total (tpd) 50.67 114.75 13.50 178.93
% Difference between 1999 and 2007 Bexar -43.83% -11.99% 87.47% -21.16% Comal -37.42% -17.45% 50.94% -24.98% Guadalupe -38.63% -10.08% 145.00% -16.58% Wilson -37.42% -1.31% 0.00% -11.82% Total -42.95% -11.85% 88.44% -20.88%
G-7
Table G-2. Comparison of 1999 and 2007 Anthropogenic NOx Emissions in the Four-county SAER for a Typical Weekday (Wednesday). County
On-Road (tpd)
Area / Non-road (tpd)
Point (tpd)
Total (tpd)
1999 Bexar 119.57 39.39 88.59 247.55 Comal 11.64 3.57 12.16 27.38 Guadalupe 10.47 4.24 0.51 15.21 Wilson 1.89 0.93 0.00 2.82 Total (tpd) 143.58 48.12 101.26 292.96
2007 Bexar 67.45 39.18 53.24 159.86 Comal 7.07 3.70 13.77 24.53 Guadalupe 6.47 3.40 8.07 17.95 Wilson 1.34 1.04 0.00 2.39 Total (tpd) 82.34 47.32 75.08 204.74
% Difference between 1999 and 2007 Bexar -43.59% -0.53% -39.90% -35.42% Comal -39.30% 3.46% 13.22% -10.39% Guadalupe -38.15% -19.65% 1492.19% 17.99% Wilson -29.00% 12.17% 0.00% -15.44% Total -42.65% -1.67% -25.85% -30.11% Figures G-1 through G-3 provide graphical comparisons of the anthropogenic NOx EIs for 1999 and 2007 by source category, both in terms of magnitude of concentrations and spatial allocation of plumes. Similarly, figures G-4 through G-6 provide graphical comparisons between estimated 1999 and 2007 anthropogenic VOC emissions inventories. As indicated by these pictures, on-road precursor emissions are concentrated in urban areas. By comparison, area/non-road and point source emissions are more dispersed. It is also evident that, overall, most anthropogenic emission categories are expected to decrease between 1999 and 2007.
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G-14
2007 BASE CASE Once the 1999 base case was modified by replacing the photochemical model’s emissions inputs (i.e., replacing the 1999 local, state, and regional anthropogenic EI with a 2007 local, state, and regional EI), the model was rerun. The resulting episode projection represents the 2007 future case for the SAER. The impact of modifying the anthropogenic local and regional emissions inventories between the 1999 base and 2007 future cases is demonstrated in table G-3. As shown, the 2007 projection predicts a decrease in ozone concentration at each San Antonio monitoring station (7x7 array of cells near monitor) compared to the 1999 base case predictions. Table G-3. Comparison of 1999 and 2007 Predicted Maximum 8-hour Average Ozone Concentrations by Monitor, September 15th - 20th.
CAMS Station 1999 Predicted 8-hr Max. Ozone
2007 Predicted 8-hr Max. Ozone
1999-2007 Percent Change
CAMS 23 89.0 ppb 84.5 ppb -5.0% CAMS 58 87.8 ppb 82.8 ppb -5.6% CAMS 59 78.1 ppb 73.6 ppb -5.7% CAMS 678 80.1 ppb 77.4 ppb -3.3% 2007 BASE CASE PERFORMANCE EVALUATION Appendix E describes a variety of tests that were conducted on the 1999 base case in order to evaluate model performance. For a future case, such as the 2007 projection, methods of analyzing model performance are more limited. Ozone metrics and several other types of analyses that compare the model’s predictions with actual measurements cannot be performed prior to compilation of those actual future measurements. As a consequence, performance analyses conducted on the 2007 future case were restricted to tile plots, comparisons between model refinements, and sensitivity runs. Tile Plots Tile plots provide an indication of where the model is or isn’t performing correctly given known changes to modeling input in the future case. These plots are visual representations of the model’s predictions and provide such information as when and where the model predicts urban plumes. The following tile plots (figures G-7 through G-12) represent comparisons between the 1999 and 2007 8-hour daily maximum ozone concentrations within the modeling domain for each day of the primary episode.
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G-21
As demonstrated by these plots, urban plumes are replicated predictably, both in terms of intensity and spatial allocation. Peak ozone concentrations are predicted downwind of city centers and major point sources in these tile plots. In addition, the overall reduction in NOx, VOC, and CO emissions (local and regional) between 1999 and 2007 reduced the magnitude of the ozone plumes in each of the daily 1999-2007 comparisons. Comparisons Between Model Refinements As described in appendix E, the original September 1999 model was developed by ENVIRON and refined through a collaboration between ENVIRON, UT Austin1, and AACOG (meteorological model and air quality input refinements). Subsequently, the model was provided to the Texas Near Nonattainment (NNA) partners2, or their contractors, for further modifications. These modifications included refinement of the emissions inventory inputs, development of the future case, and clean air strategy analyses. Because the model was modified by more than one agency during this process, there was a concern that the various agencies’ models would become dissimilar and provide different predictions for the base case, future case, and control strategy runs. A great amount of effort was spent ensuring that the Austin and San Antonio base and future cases contained identical input. Often this involved discussions between the two agencies, as well as TCEQ, regarding the most appropriate EI data for local and regional areas. Discrepancies in emissions inputs were corrected prior to the final AACOG and UT runs. An analysis was conducted by AACOG staff to determine any differences between the final 1999 base case refined by UT Austin and the final base case refined by AACOG, based on predicted concentrations at two Austin monitors. The 2007 future cases developed by UT and AACOG were similarly analyzed. The results of these analyses are provided in table G-4. The table provides daily peak 8-hour predictions within the 7x7 array of cells near the Murchison and Audubon monitors for the 1999 and 2007 base cases. As shown, the differences between predictions by AACOG’s final run (labeled 1999_sos.f) and UT’s final run (labeled 1999_v3) are insignificant. With regards to the Murchison monitor, the average difference (six episode days) in ozone concentrations between the two 1999 base cases was 0.00 ppb, while the average difference at the Audubon monitor was 0.05 ppb. For the 2007 future cases, the average differences in peak ozone concentrations for the six-day episode was -0.06 ppb (Murchison) and –0.04 ppb (Audubon). These results provide additional, independent verification of the performance of the 1999 base case and 2007 future case.
1 UT Austin acted on behalf of Austin modeling. 2 Development of the September 1999 photochemical model simulation was a collaboration between TCEQ and four Texas NNAs: Austin, Corpus Christi, San Antonio, and Victoria.
G
-22
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UT
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G-23
Sensitivity Tests Sensitivity tests are used throughout model development as diagnostic tools. These tests are conducted by perturbing model input. Results of sensitivity tests are analyzed in terms of whether the model responded to changes in input and, further, whether the model responded in a manner judged to be appropriate to input modifications. In addition to providing an indication of model performance, sensitivity tests are useful for providing key information. For example, when applied to a projection year base case, sensitivity runs may be used to analyze the impact of emissions sources in the future. Furthermore, these evaluations may be used to predict the impact of control strategies and assist with determining what types of precursor reductions are likely to be the most effective for reducing ozone concentrations. The 2007 future case sensitivity tests were conducted by modifying model input in one of two ways: 1) removing the precursor emissions for specific point sources/urban areas, or 2) reducing the local anthropogenic NOx and VOC emissions inventories in incremental amounts. The results of modifying model input to the 2007 future case are provided in the following sections. Zero-Out Runs: Urban Areas Appendix E describes sensitivity tests conducted on the 1999 base case in which the anthropogenic NOx and VOC EIs for Austin, Corpus Christi, and Houston were removed from, or “zeroed out” of, the model. These tests were also conducted on the 2007 future case, i.e., the 2007 NOx and VOC EIs for Austin, Corpus Christi, and Houston were removed from the future case in three separate tests. Figures G-13 and G-14 provide the predicted changes in ozone concentrations at CAMS 23 and CAMS 58, respectively, after removing the anthropogenic EIs for each of the three urban areas and compares those values to the 1999 sensitivity runs. As shown by the graphs in figures G-13 and G-14, removing the anthropogenic EI for the 11-county Houston area had the greatest predicted impact on 2007 ozone concentrations in the San Antonio area, followed by the 2-county Corpus Christi area and 5-county Austin area. Moreover, this trend is the same whether referring to the 1999 base or 2007 future case sensitivity runs. During the 1999 episode, the predominate wind direction was such that Houston emissions were more likely to impact San Antonio than Austin or Corpus Christi. Since the meteorological inputs remain identical between base and future cases, it stands to reason that Houston emissions would continue to demonstrate the greatest influence on San Antonio ozone concentrations during the September episode.
G-24
Figure G-13. Predicted Reductions in Ozone Concentrations at CAMS 23 after Zeroing Out Anthropogenic Precursor Emissions for the 11-county Houston Area, 2-county Corpus Christi Area, and 5-county Austin Area from the 1999 Base Case (orange) and 2007 Future Case (blue).
2.25 parts per billion
0.55 parts per billion
0.24 parts per billion
2.72 parts per billion
0.64 parts per billion
0.27 parts per billion
0.0% 0.5% 1.0% 1.5% 2.0% 2.5% 3.0% 3.5%
Austin Removed
Corpus Removed
Houston Removed
Percent Reduction in Ozone (ppb)
19992007
G-25
Figure G-14. Predicted Reductions in Ozone Concentrations at CAMS 58 after Zeroing Out Anthropogenic Precursor Emissions for the 11-county Houston Area, 2-county Corpus Christi Area, and 5-county Austin Area from the 1999 Base Case (orange) and 2007 Future Case (blue).
Zero-Out Runs: Point Sources Analyses were also conducted in which specific point source emissions were removed from the model in separate sensitivity runs. These tests were run at the request of local elected officials and the TCEQ to identify likely strategies (VOC versus NOx) for ambient ozone reductions in the SAER. Figures G-15 and G-16 provide the predicted changes in ozone concentrations at CAMS 23 and 58, as the result of conducting these zero out runs for 1999 and 2007. One run, labeled “CPS Spruce 1 Coal Plant Removed,” simulates the impact of removing a currently-existing 750-megawatt power plant from the 2007 future case in the San Antonio area. A second run, “Remove All CPS Power Plants,” simulates the impact of removing the nine power plants in the San Antonio region in 1999 from the 1999 base case and removing seven power plants (due to anticipated closures of two plants) from the 2007 future case. A third run “Remove Cement Plants” represents the removal of emissions from all cement kilns in the 4-county SAER. The last run, “Toyota Removed,” simulates the impact of removing the EI for a major manufacturing plant from the 2007
2.19 parts per billion
0.45 parts per billion
0.35 parts per billion
2.61 parts per billion
0.57 parts per billion
0.40 parts per billion
0.0% 0.5% 1.0% 1.5% 2.0% 2.5% 3.0% 3.5%
Austin Removed
Corpus Removed
Houston Removed
Percent Reduction in Ozone (ppb)
19992007
G-26
Figure G15. Predicted Reductions in Ozone Concentrations at CAMS 23 after Removing Various Point Source Emissions within the SAER– Comparison between 1999 (orange) and 2007 (blue).
0.10 parts per billion
0.01 parts per billion
0.16 parts per billion
1.20 parts per billion
0.0 parts per billion
- 0.17 parts per billion
0.69 parts per billion
-0.2% 0.0% 0.2% 0.4% 0.6% 0.8% 1.0% 1.2% 1.4% 1.6%
Toyota Removed
Remove CementPlants
Remove All CPSPower Plants
CPS Spruce 1Coal Plant Removed*
Percent Reduction in Ozone (ppb)
19992007
*based on 5.93 tons/day of NOx in 2007 only
G-27
Figure G-16. Predicted Reductions in Ozone Concentrations at CAMS 58 after Removing Various Point Source Emissions within the SAER– Comparison between 1999 (orange) and 2007(blue).
future case. Since the plant is not scheduled to be in operation until 2006, removing these emissions have no impact on the 1999 base case. As shown in these graphs, removing all power plant emissions had the greatest impact on both the 1999 and 2007 simulations. Since the combined power plants were the largest source of precursors (NOx) of all sources tested, this type of result is expected. Conversely, the Toyota plant, which has the lowest emission rates (primarily VOC), impacts San Antonio ozone concentrations the least. With the exception of the results of removing the cement kiln emissions from the 1999 base case at CAMS 23, each sensitivity run demonstrates a decrease in predicted 1999 or 2007 ozone concentrations. The predicted increase in ozone concentration at CAMS 23 is most likely a reversal of the model’s ozone scavenging process. During much of the 1999 episode, the model predicts conditions in which decreases in NOx cause ozone concentrations to increase (NOx reduction disbenefit). Thus, removing the NOx emissions from kilns near the monitor causes the model to predict increased ozone concentrations at that location in the 1999 base case.
0.08 parts per billion
0.01 parts per billion
0.26 parts per billion
0.97 parts per billion
0.0 parts per billion
0.08 parts per billion
0.74 parts per billion
0.0% 0.2% 0.4% 0.6% 0.8% 1.0% 1.2% 1.4% 1.6% 1.8%
Toyota Removed
Remove CementPlants
Remove All CPSPower Plants
CPS Spruce 1Coal Plant Removed*
Percent Reduction in Ozone (ppb)
19992007
*based on 5.93 tons/day of NOx in 2007 only
G-28
This NOx reduction disbenfit is much less evident in the 2007 future case. Consequently, removing the NOx emissions associated with the San Antonio area power plants causes larger ozone reductions in the 2007 future case than in the 1999 base case. Since there are no power plants in the vicinity of CAMS 23, removing the 1999 power plant emissions from the model did not cause an increase in predicted ozone levels in the 1999 base case, as was demonstrated by the cement kiln sensitivity run. At the request of EPA Region 6, the output from each point source “zero out” simulation was run through a graphics program, PAVE, to obtain a visual depiction of the impact of removing these sources in the SAER. The plots for zeroing out point sources were created for all primary episode weekdays, when applicable,3 as shown in figures G-17 through G-22. An advantage these plots have compared to the graphs for CAMS 23 and 58, shown previously, is that they provide an indication of the impact of modifying emissions in terms of spatial distribution. As shown by these graphs, the impact of removing point source emissions was, to a large extent, influenced by the model’s meteorological processes, particularly wind direction. The September 15th – 17th plots, for example, indicate that these emissions primarily affect counties to the west and northwest of Bexar County. In addition, the cement kiln zero out runs tended to show the widest area of influence. This is an expected outcome since the cement kiln emission sources are spread throughout the San Antonio area, whereas all seven CPS power plants are located in southeast Bexar County. Similarly, the Toyota manufacturing plant is represented by a single point in south Bexar County on the plots.
3 Weekends were not included for the Toyota set of sensitivity runs because the plant is not scheduled to be operational on Saturday and Sunday.
G
-29
Figu
re G
-17.
Com
paris
on o
f Zer
o O
ut R
uns
Con
duct
ed fo
r CPS
Pow
er P
lant
s, C
emen
t Kiln
s, a
nd T
oyot
a M
anuf
actu
ring
Plan
t on
the
2007
Fu
ture
Cas
e, W
edne
sday
, Sep
tem
ber 1
5th.
Rem
oval
of C
PS P
ower
Pl
ant E
mis
sion
s R
emov
al o
f San
Ant
onio
are
a C
emen
t Kiln
Em
issi
ons
Rem
oval
of T
oyot
a M
anuf
actu
ring
Plan
t Em
issi
ons
G
-30
Figu
re G
-18.
Com
paris
on o
f Zer
o O
ut R
uns
Con
duct
ed fo
r CPS
Pow
er P
lant
s, C
emen
t Kiln
s, a
nd T
oyot
a M
anuf
actu
ring
Plan
t on
the
2007
Fu
ture
Cas
e, T
hurs
day,
Sep
tem
ber 1
6th.
Rem
oval
of C
PS P
ower
Pla
nt
Emis
sion
s R
emov
al o
f San
Ant
onio
Are
a C
emen
t Kiln
Em
issi
ons
Rem
oval
of T
oyot
a M
anuf
actu
ring
Plan
t Em
issi
ons
G
-31
Figu
re G
-19.
Com
paris
on o
f Zer
o O
ut R
uns
Con
duct
ed fo
r CPS
Pow
er P
lant
s, C
emen
t Kiln
s, a
nd T
oyot
a M
anuf
actu
ring
Plan
t on
the
2007
Fu
ture
Cas
e, F
riday
, Sep
tem
ber 1
7th.
Pr
oble
ms
with
the
grap
hics
so
ftwar
e pr
even
ted
the
com
plet
ion
of a
tile
plo
t for
the
Sept
embe
r 17th
cem
ent k
iln s
ensi
tivity
run
Rem
oval
of C
PS P
ower
Pl
ant E
mis
sion
s R
emov
al o
f Toy
ota
Man
ufac
turin
g Pl
ant E
mis
sion
s
G
-32
Figu
re G
-20.
Com
paris
on o
f Zer
o O
ut R
uns
Con
duct
ed fo
r CPS
Pow
er P
lant
s, C
emen
t Kiln
s, a
nd T
oyot
a M
anuf
actu
ring
Plan
t on
the
2007
Fu
ture
Cas
e, S
atur
day,
Sep
tem
ber 1
8th.
N
ot A
pplic
able
Toyo
ta M
anuf
actu
ring
Plan
t is
not
sche
dule
d to
be
oper
atio
nal o
n Sa
turd
ays
Rem
oval
of C
PS P
ower
Pla
nt
Emis
sion
s R
emov
al o
f San
Ant
onio
Ar
ea C
emen
t Kiln
Em
issi
ons
G
-33
Figu
re G
-21.
Com
paris
on o
f Zer
o O
ut R
uns
Con
duct
ed fo
r CPS
Pow
er P
lant
s, C
emen
t Kiln
s, a
nd T
oyot
a M
anuf
actu
ring
Plan
t on
the
2007
Fu
ture
Cas
e, S
unda
y, S
epte
mbe
r 19th
.
N
ot A
pplic
able
Toyo
ta M
anuf
actu
ring
Plan
t is
not
Sche
dule
d to
be
Ope
ratio
nal o
n Su
nday
s
Rem
oval
of C
PS P
ower
Pl
ant E
mis
sion
s R
emov
al o
f San
Ant
onio
Ar
ea C
emen
t Kiln
Em
issi
ons
G
-34
Figu
re G
-22.
Com
paris
on o
f Zer
o O
ut R
uns
Con
duct
ed fo
r CPS
Pow
er P
lant
s, C
emen
t Kiln
s, a
nd T
oyot
a M
anuf
actu
ring
Plan
t on
the
2007
Fu
ture
Cas
e, M
onda
y, S
epte
mbe
r 20th
.
Rem
oval
of C
PS P
ower
Pl
ant E
mis
sion
s R
emov
al o
f San
Ant
onio
Are
a C
emen
t Kiln
Em
issi
ons
Rem
oval
of T
oyot
a M
anuf
actu
ring
Plan
t Em
issi
ons
G-35
For the most part, removing point source emissions caused the model to predict decreases in ozone concentrations along the area of impact. However, the model also predicts some areas of increased ozone concentrations, the most prominent of which is the Thursday, September 16th plot depicting the impact of zeroing out cement kiln emissions. Likewise some of the Toyota sensitivity runs exhibit small increases in ozone concentrations near the plant, despite the very low NOx emissions the plant represents (0.34 tons/day). This NOx reduction disbenefit is less pronounced in the power plant sensitivity runs. However, these tile plots depict ozone concentrations in the lowest atmospheric grid layer, whereas power plants pollutants are emitted, by computer simulation, into higher grid layers. Incremental Removal of VOC and NOx Precursor Emissions Across-the-board sensitivity runs were conducted by removing 25%, 50%, 75%, and 100% of the local (4-county SAER) NOx emissions, VOC emissions, and combinations of the two, from the 2007 future case. Figures G-23 and G-24 provide the results of the across-the-board reduction runs for CAMS 23 and CAMS 58 (San Antonio downwind monitors), averaged over the six day modeling period conducted on the 1999 base and 2007 future cases. At the 25% reduction level (CAMS 23), VOC reductions were slightly more effective than NOx reductions at lowering ozone concentrations. At CAMS 58, 25% NOx and 25% VOC reductions are equally effective. These results are somewhat different than those predicted for the 1999 base case in that, at the 25% level, VOC reductions were more effective than NOx for reducing ozone concentrations in the SAER. These results tend to support the evaluation of both VOC and NOx control strategies as possible means of reducing ambient ozone concentrations in the San Antonio region.
G-36
Figure G-23. Predicted Ozone Concentrations at CAMS 23 after Removing Local NOx and VOC Emissions from CAMx Run 18, Averages for September 15 -20, 1999 and 2007.
60
65
70
75
80
85
90
0% 25% 50% 75% 100%Anthropogenic Emission Reductions (percentage)
Ozo
ne C
once
ntra
tion
(ppb
)
NOx Reduction VOC Reduction NOx & VOC Reduction
8 hour standard - 85 ppb
1999
60
65
70
75
80
85
90
0% 25% 50% 75% 100%Anthropogenic Emission Reductions (percentage)
Ozo
ne C
once
ntra
tion
(ppb
)
NOx Reduction VOC Reduction NOx & VOC Reduction
8 hour standard - 85 ppb
2007
G-37
Figure G-24. Predicted Ozone Concentrations at CAMS 58 after Removing Local NOx and VOC Emissions from CAMx Run 18, Average for September 15 -20, 1999 and 2007.
60
65
70
75
80
85
90
0% 25% 50% 75% 100%Anthropogenic Emission Reductions (percentage)
Ozo
ne C
once
ntra
tion
(ppb
)
NOx Reduction VOC Reduction NOx & VOC Reduction
8 hour standard - 85 ppb
1999
60
65
70
75
80
85
90
0% 25% 50% 75% 100%Anthropogenic Emission Reductions (percentage)
Ozo
ne C
once
ntra
tion
(ppb
)
NOx Reduction VOC Reduction NOx & VOC Reduction
8 hour standard - 85 ppb
2007
G-38
SUMMARY OF MODIFICATIONS TO THE 1999 BASE AND 2007 FUTURE CASES AND RESULTING DESIGN VALUES As described previously, a great amount of time and effort were spent ensuring the 2007 future cases developed by UT Austin and AACOG were consistent. As part of that effort, UT and AACOG staff, in consultation with the TCEQ, evaluated local and regional 2007 EI files used as input to the two future cases. Whenever inconsistencies in emissions or procedures were identified, staff from UT, AACOG, and the TCEQ determined the most appropriate data to incorporate into the models. Both the UT and AACOG future cases were modified to reflect these decisions. Tables G-5 through G-8 summarize the impact of making these modifications to AACOG’s 2007 future case. The future case runs, labeled A through G, represent the first future case (A) developed by AACOG, projected from the 1999 base case labeled CAMx Run 18 (see appendix E for more information), through the final 2007 future case run (G). The far right column lists changes that were made to the model for each run. Results of making the modifications to the future case model simulation are provided for each monitor in the San Antonio region (CAMS 23, 58, 59, and 678). Based on analyses between the AACOG and UT final future cases (see section on “Comparisons Between Model Refinements”), it is evident that the extra effort required to analyze all model inputs resulted in consistent, well-performing future case simulations on which to model control strategy effectiveness and base attainment demonstrations.
G
-39
Tabl
e G
-5. M
odifi
catio
ns to
the1
999
Base
Cas
e an
d 20
07 F
utur
e C
ase
as P
art o
f the
QA/
QC
Pro
cess
and
Res
ultin
g Pe
ak 8
-hou
r Pr
edic
tions
at C
AMS
23 A
ssoc
iate
d w
ith E
ach
Run
. C
AM
S 23
Pe
ak P
redi
cted
8-h
our O
zone
Con
cent
ratio
ns
R
un L
abel
Ye
ar
15th
16
th
17th
18
th
19th
20
thAv
erag
e D
esig
n Va
lue
Mod
ifica
tions
to M
odel
Base
Cas
e.A
1999
81
.63
78.2
581
.39
98.6
810
2.54
93.7
389
.37
89.0
0
Base
Cas
e.B
1999
81
.62
78.2
581
.36
98.6
710
2.46
93.6
889
.34
89.0
0
Upd
ated
qua
rry a
nd c
onst
ruct
ion
equi
pmen
t em
issi
ons
Base
Cas
e.D
19
99
81.6
2 78
.25
81.3
698
.67
102.
4693
.67
89.3
489
.00
Inco
rpor
ated
new
was
tew
ater
est
imat
es fr
om
San
Anto
nio
Wat
er S
yste
m
Base
Cas
e.E
1999
81
.73
78.1
681
.36
98.7
210
1.59
93.4
989
.18
89.0
0
Upd
ated
199
9 ar
ea a
nd n
on-ro
ad s
ourc
e te
mpo
ral p
rofil
es fo
r reg
iona
l Tex
as to
mat
ch
2007
tem
pora
l pro
files
Upd
ated
poi
nt s
ourc
e cu
t off
poin
t fro
m 2
0m
to 5
0m fo
r the
4km
grid
Ba
se C
ase
F 19
99
81.3
5 78
.22
81.5
298
.67
101.
4993
.42
89.1
189
.00
Upd
ated
Vic
toria
's m
obile
EI w
ith la
test
dat
a fro
m U
T
Upd
ated
che
mic
al a
nd te
mpo
ral p
rofil
es fo
r Te
xas
area
and
non
-road
em
issi
ons
Upd
ated
Vic
toria
's p
oint
sou
rces
Upd
ated
Tex
as N
EGU
and
EG
U s
ourc
es
outs
ide
of H
oust
on
U
pdat
ed L
ouis
iana
poi
nt s
ourc
e em
issi
ons
U
pdat
ed A
ustin
’s a
rea
& no
n-ro
ad s
ourc
es
Base
Cas
e G
19
99
81.1
4 78
.08
81.3
698
.57
101.
4093
.20
88.9
689
.00
Upd
ated
San
Ant
onio
asp
halt
emis
sion
s
Upd
ated
tank
er tr
uck
unlo
adin
g em
issi
ons
U
pdat
ed ta
nker
truc
ks in
tran
sit e
mis
sion
s
Upd
ated
em
issi
ons
for o
ther
gas
olin
e di
strib
utio
n ac
tiviti
es
Base
Cas
e.A
2007
84.5
6
Base
Cas
e.B
2007
80
.00
76.2
180
.05
89.4
593
.92
92.6
785
.38
85.0
6
Upd
ated
regi
onal
EI H
DD
non
-road
EI
(pro
vide
d by
TC
EQ)
U
pdat
ed A
ustin
Poi
nt S
ourc
e C
ontro
l EI
(Alc
oa)
U
pdat
ed S
an A
nton
io c
onst
ruct
ion
and
quar
ry e
quip
men
t em
issi
ons
G
-40
CA
MS
23
(con
tinue
d)
Base
Cas
e.D
20
07
80
.09
76.1
980
.01
89.4
593
.93
92.6
785
.39
85
.07
In
corp
orat
ed n
ew w
aste
wat
er e
stim
ates
Rev
ised
Aus
tin P
oint
Sou
rce
Con
trol E
I (A
lcoa
)
Base
Cas
e.E
2007
79
.70
75.2
079
.57
88.7
392
.48
91.4
584
.52
84.3
5
Rev
ised
Aus
tin P
oint
Sou
rce
Con
trol E
I
Inco
rpor
ated
new
regi
onal
tem
pora
l pro
file
for p
oint
sou
rces
Adde
d C
O fo
r Aus
tin o
n-ro
ad E
I (3
Cou
nty)
Incl
uded
sta
ge1
(125
k) fo
r the
4-c
ount
y Sa
n An
toni
o M
SA
R
emov
ed ta
nk tr
uck
unlo
adin
g on
Sun
day
to
mat
ch E
PA g
uida
nce
U
pdat
ed o
ther
are
a so
urce
tem
pora
l pro
files
to
mat
ch E
PA g
uida
nce
U
pdat
ed T
exas
regi
onal
are
a an
d no
n-ro
ad
emis
sion
s
U
pdat
ed T
exas
poi
nt s
ourc
es (b
esid
es C
PS)
U
pdat
ed L
ehig
h ce
men
t Kiln
con
trols
Upd
ated
poi
nt s
ourc
e cu
t off
poin
t fro
m 2
0m
to 5
0m o
n th
e 4-
km g
rid to
mat
ch th
e 12
-km
gr
id c
ut o
ff
U
pdat
ed V
icto
ria’s
EI
Base
Cas
e F
2007
79
.70
75.2
079
.57
88.7
392
.49
91.4
684
.53
84.4
2
Upd
ated
Vic
toria
's m
obile
EI
U
pdat
ed c
hem
ical
and
tem
pora
l pro
files
for
Texa
s ar
ea a
nd n
on-ro
ad e
mis
sion
s Ba
se C
ase
G
2007
79
.57
75.0
779
.50
88.6
992
.50
91.5
784
.48
84.5
2
Upd
ated
San
Ant
onio
asp
halt
emis
sion
s
Upd
ated
tank
er tr
uck
unlo
adin
g em
issi
ons
U
pdat
ed ta
nker
truc
ks in
tran
sit e
mis
sion
s
Upd
ated
em
issi
ons
from
oth
er g
asol
ine
dist
ribut
ion
activ
ities
Upd
ated
em
issi
ons
for R
OP
cont
rols
G
-41
Tabl
e G
-6. M
odifi
catio
ns to
the1
999
Base
Cas
e an
d 20
07 F
utur
e C
ase
as P
art o
f the
QA/
QC
Pro
cess
and
Res
ultin
g Pe
ak 8
-hou
r Pr
edic
tions
at C
AMS
58 A
ssoc
iate
d w
ith E
ach
Run
. C
AM
S 58
Pe
ak P
redi
cted
8-h
our O
zone
Con
cent
ratio
ns
R
un L
abel
Ye
ar
15th
16
th
17th
18
th
19th
20
th
Aver
age
Base
Cas
e D
esig
n Va
lue
Mod
ifica
tions
to M
odel
Base
Cas
e.A
1999
75.
95 7
7.44
81
.93
98.6
8 10
2.75
91.6
6 88
.07
87.0
0
Base
Cas
e.B
1999
75.
95 7
7.44
81
.93
98.6
7 10
2.68
91.6
4 88
.05
87.0
0
Upd
ated
qua
rry a
nd c
onst
ruct
ion
equi
pmen
t em
issi
ons
Base
Cas
e.D
19
99 7
5.95
77.
44
81.9
298
.67
102.
6891
.63
88.0
587
.00
Inco
rpor
ated
new
was
tew
ater
est
imat
es fr
om
San
Anto
nio
Wat
er S
yste
m
Base
Cas
e.E
1999
76.
00 7
7.41
81
.87
98.7
2 10
1.92
91.5
0 87
.90
87.0
0
Upd
ated
199
9 ar
ea a
nd n
on-ro
ad s
ourc
e te
mpo
ral p
rofil
es fo
r reg
iona
l Tex
as to
mat
ch
2007
tem
pora
l pro
files
Upd
ated
poi
nt s
ourc
e cu
t off
poin
t fro
m 2
0m
to 5
0m fo
r the
4km
grid
Ba
se C
ase
F 19
99 7
5.74
77.
44
82.1
698
.67
101.
9091
.51
87.9
087
.00
Upd
ated
Vic
toria
's m
obile
EI w
ith la
test
dat
a fro
m U
T
Upd
ated
che
mic
al a
nd te
mpo
ral p
rofil
es fo
r Te
xas
area
and
non
-road
em
issi
ons
Upd
ated
Vic
toria
's p
oint
sou
rces
Upd
ated
Tex
as N
EGU
and
EG
U s
ourc
es
outs
ide
of H
oust
on
U
pdat
ed L
ouis
iana
poi
nt s
ourc
e em
issi
ons
U
pdat
ed A
ustin
’s a
rea
& no
n-ro
ad s
ourc
es
Base
Cas
e G
19
99 7
5.59
77.
26
82.0
198
.57
101.
8391
.30
87.7
687
.00
Upd
ated
San
Ant
onio
asp
halt
emis
sion
s
Upd
ated
tank
er tr
uck
unlo
adin
g em
issi
ons
U
pdat
ed ta
nker
truc
ks in
tran
sit e
mis
sion
s
Upd
ated
em
issi
ons
for o
ther
gas
olin
e di
strib
utio
n ac
tiviti
es
Base
Cas
e.A
2007
82
.19
Ba
se C
ase.
B 20
07 7
4.11
75.
41
79.0
789
.45
93.9
290
.17
83.6
982
.69
Upd
ated
regi
onal
EI H
DD
non
-road
EI
(pro
vide
d by
TC
EQ)
U
pdat
ed A
ustin
Poi
nt S
ourc
e C
ontro
l EI
(Alc
oa)
U
pdat
ed S
an A
nton
io c
onst
ruct
ion
and
quar
ry e
quip
men
t em
issi
ons
G
-42
CA
MS
58
(con
tinue
d)
Base
Cas
e.D
20
07
74
.28
75
.40
79.0
2
89
.45
93.9
3
90
.18
83.7
1
82
.71
In
corp
orat
ed n
ew w
aste
wat
er e
stim
ates
Rev
ised
Aus
tin P
oint
Sou
rce
Con
trol E
I (A
lcoa
) Ba
se C
ase.
E 20
07 7
3.91
74.
46
78.5
788
.73
92.4
889
.17
82.8
982
.03
Rev
ised
Aus
tin P
oint
Sou
rce
Con
trol E
I
Inco
rpor
ated
new
regi
onal
tem
pora
l pro
file
for p
oint
sou
rces
Adde
d C
O fo
r Aus
tin o
n-ro
ad E
I (3
Cou
nty)
Incl
uded
sta
ge1
(125
k) fo
r the
4-c
ount
y Sa
n An
toni
o M
SA
R
emov
ed ta
nk tr
uck
unlo
adin
g on
Sun
day
to
mat
ch E
PA g
uida
nce
U
pdat
ed o
ther
are
a so
urce
tem
pora
l pro
files
to
mat
ch E
PA g
uida
nce
U
pdat
ed T
exas
regi
onal
are
a an
d no
n-ro
ad
emis
sion
s
U
pdat
ed T
exas
poi
nt s
ourc
es (b
esid
es C
PS)
U
pdat
ed L
ehig
h ce
men
t Kiln
con
trols
Upd
ated
poi
nt s
ourc
e cu
t off
poin
t fro
m 2
0m
to 5
0m o
n th
e 4-
km g
rid to
mat
ch th
e 12
-km
gr
id c
ut o
ff
U
pdat
ed V
icto
ria E
I Ba
se C
ase
F 20
07 7
3.90
74.
46
78.5
788
.73
92.4
989
.18
82.8
982
.04
Upd
ated
Vic
toria
's m
obile
EI
U
pdat
ed c
hem
ical
and
tem
pora
l pro
files
for
Texa
s ar
ea a
nd n
on-ro
ad e
mis
sion
s Ba
se C
ase
G
2007
73.
80 7
4.28
78
.50
88.6
9 92
.50
89.2
5 82
.84
82.1
2
Upd
ated
San
Ant
onio
asp
halt
emis
sion
s
Upd
ated
tank
er tr
uck
unlo
adin
g em
issi
ons
U
pdat
ed ta
nker
truc
ks in
tran
sit e
mis
sion
s
Upd
ated
em
issi
ons
from
oth
er g
asol
ine
dist
ribut
ion
activ
ities
Upd
ated
em
issi
ons
for R
OP
cont
rols
G
-43
Tabl
e G
-7. M
odifi
catio
ns to
the1
999
Base
Cas
e an
d 20
07 F
utur
e C
ase
as P
art o
f the
QA/
QC
Pro
cess
and
Res
ultin
g Pe
ak 8
-hou
r Pr
edic
tions
at C
AMS
59 A
ssoc
iate
d w
ith E
ach
Run
. G
ray
strik
e-th
roug
h nu
mbe
rs a
re v
alue
s th
at fa
ll be
low
the
EPA
requ
irem
ent (
EPA
1999
, p. 4
1) o
f 70
ppb
to b
e in
clud
ed in
the
RR
F C
AM
S 59
Pe
ak P
redi
cted
8-h
our O
zone
Con
cent
ratio
ns
Run
Lab
el
Year
15
th
16th
17
th
18th
19
th
20th
Av
erag
eBa
se C
ase
Des
ign
Valu
e M
odifi
catio
ns to
Mod
el
Base
Cas
e.A
1999
66.
95 7
2.04
69
.83
72.5
3 83
.04
86.6
5 76
.82
79.0
0
Base
Cas
e.B
1999
66.
95 7
2.04
69
.83
72.5
3 82
.90
86.6
1 76
.78
79.0
0
Upd
ated
qua
rry a
nd c
onst
ruct
ion
equi
pmen
t em
issi
ons
Base
Cas
e.D
19
99 6
6.95
72.
04
69.8
372
.53
82.9
086
.60
76.7
879
.00
Inco
rpor
ated
new
was
tew
ater
est
imat
es fr
om
San
Anto
nio
Wat
er S
yste
m
Base
Cas
e.E
1999
67.
33 7
2.30
69
.86
72.5
8 82
.24
86.2
5 76
.65
79.0
0
Upd
ated
199
9 ar
ea a
nd n
on-ro
ad s
ourc
e te
mpo
ral p
rofil
es fo
r reg
iona
l Tex
as to
mat
ch
2007
tem
pora
l pro
files
Upd
ated
poi
nt s
ourc
e cu
t off
poin
t fro
m 2
0m
to 5
0m fo
r the
4km
grid
Ba
se C
ase
F 19
99 6
7.12
72.
33
70.0
972
.38
81.9
086
.46
76.6
379
.00
Upd
ated
Vic
toria
's m
obile
EI w
ith la
test
dat
a fro
m U
T
Upd
ated
che
mic
al a
nd te
mpo
ral p
rofil
es fo
r Te
xas
area
and
non
-road
em
issi
ons
Upd
ated
Vic
toria
's p
oint
sou
rces
Upd
ated
Tex
as N
EGU
and
EG
U s
ourc
es
outs
ide
of H
oust
on
U
pdat
ed L
ouis
iana
poi
nt s
ourc
e em
issi
ons
U
pdat
ed A
ustin
’s a
rea
& no
n-ro
ad s
ourc
es
Base
Cas
e G
19
99 6
6.89
72.
38
69.9
072
.12
81.7
586
.26
78.1
379
.00
Upd
ated
San
Ant
onio
asp
halt
emis
sion
s
Upd
ated
tank
er tr
uck
unlo
adin
g em
issi
ons
U
pdat
ed ta
nker
truc
ks in
tran
sit e
mis
sion
s
Upd
ated
em
issi
ons
for o
ther
gas
olin
e di
strib
utio
n ac
tiviti
es
Base
Cas
e.A
2007
74
.96
Ba
se C
ase.
B 20
07 6
4.65
67.
40
67.6
868
.97
78.7
384
.15
73.3
875
.51
Upd
ated
regi
onal
EI H
DD
non
-road
EI
(pro
vide
d by
TC
EQ)
U
pdat
ed A
ustin
Poi
nt S
ourc
e C
ontro
l EI
(Alc
oa)
G
-44
CA
MS
59
(con
tinue
d)
Base
Cas
e.D
20
07
64
.70
67
.40
67.6
6
68
.97
78.7
3
84
.15
73.3
8
75
.51
U
pdat
ed S
an A
nton
io c
onst
ruct
ion
and
quar
ry e
quip
men
t em
issi
ons
In
corp
orat
ed n
ew w
aste
wat
er e
stim
ates
Rev
ised
Aus
tin P
oint
Sou
rce
Con
trol E
I (A
lcoa
) Ba
se C
ase.
E 20
07 6
4.25
65.
90
68.0
569
.21
76.9
983
.03
72.6
474
.87
Rev
ised
Aus
tin P
oint
Sou
rce
Con
trol E
I
Inco
rpor
ated
new
regi
onal
tem
pora
l pro
file
for p
oint
sou
rces
Adde
d C
O fo
r Aus
tin o
n-ro
ad E
I (3
Cou
nty)
Incl
uded
sta
ge1
(125
k) fo
r the
4-c
ount
y Sa
n An
toni
o M
SA
R
emov
ed ta
nk tr
uck
unlo
adin
g on
Sun
day
to
mat
ch E
PA g
uida
nce
U
pdat
ed o
ther
are
a so
urce
tem
pora
l pro
files
to
mat
ch E
PA g
uida
nce
U
pdat
ed T
exas
regi
onal
are
a an
d no
n-ro
ad
emis
sion
s
U
pdat
ed T
exas
poi
nt s
ourc
es (b
esid
es C
PS)
U
pdat
ed L
ehig
h ce
men
t Kiln
con
trols
Upd
ated
poi
nt s
ourc
e cu
t off
poin
t fro
m 2
0m
to 5
0m o
n th
e 4-
km g
rid to
mat
ch th
e 12
-km
gr
id c
ut o
ff
U
pdat
ed V
icto
ria E
I Ba
se C
ase
F 20
07 6
4.25
65.
90
68.0
569
.21
77.0
183
.05
72.6
474
.89
Upd
ated
Vic
toria
's m
obile
EI
U
pdat
ed c
hem
ical
and
tem
pora
l pro
files
for
Texa
s ar
ea a
nd n
on-ro
ad e
mis
sion
s Ba
se C
ase
G
2007
63.
98 6
5.93
67
.82
68.9
2 76
.84
82.9
6 73
.66
74.4
8
Upd
ated
San
Ant
onio
asp
halt
emis
sion
s
Upd
ated
tank
er tr
uck
unlo
adin
g em
issi
ons
U
pdat
ed ta
nker
truc
ks in
tran
sit e
mis
sion
s
Upd
ated
em
issi
ons
from
oth
er g
asol
ine
dist
ribut
ion
activ
ities
Upd
ated
em
issi
ons
for R
OP
cont
rols
G
-45
Tabl
e G
-8. M
odifi
catio
ns to
the1
999
Base
Cas
e an
d 20
07 F
utur
e C
ase
as P
art o
f the
QA/
QC
Pro
cess
and
Res
ultin
g Pe
ak 8
-hou
r Pr
edic
tions
at C
AMS
678
Asso
ciat
ed w
ith E
ach
Run
. G
ray
strik
e-th
roug
h nu
mbe
rs a
re v
alue
s th
at fa
ll be
low
the
EPA
requ
irem
ent (
EPA
1999
, p.
41)
of 7
0 pp
b to
be
incl
uded
in th
e R
RF
CA
MS
678
Peak
Pre
dict
ed 8
-hou
r Ozo
ne C
once
ntra
tions
R
un L
abel
Ye
ar
15th
16
th
17th
18
th
19th
20
th
Aver
age
Base
Cas
e D
esig
n Va
lue
Mod
ifica
tions
to M
odel
Base
Cas
e A
1999
70.
34 7
1.19
69
.83
80.0
3 92
.94
88.4
7 78
.80
77.0
0
Base
Cas
e B
1999
70.
33 7
1.19
69
.83
80.0
1 92
.81
88.3
3 78
.75
77.0
0
Upd
ated
qua
rry a
nd c
onst
ruct
ion
equi
pmen
t em
issi
ons
Base
Cas
e D
19
99 7
0.33
71.
19
69.8
380
.01
92.8
088
.32
78.7
577
.00
Inco
rpor
ated
new
was
tew
ater
est
imat
es fr
om
San
Anto
nio
Wat
er S
yste
m
Base
Cas
e E
1999
70.
57 7
1.45
69
.86
80.0
6 91
.99
87.9
2 78
.64
77.0
0
Upd
ated
199
9 ar
ea a
nd n
on-ro
ad s
ourc
e te
mpo
ral p
rofil
es fo
r reg
iona
l Tex
as to
mat
ch
2007
tem
pora
l pro
files
Upd
ated
poi
nt s
ourc
e cu
t off
poin
t fro
m 2
0m
to 5
0m fo
r the
4km
grid
Ba
se C
ase
F 19
99 7
0.39
71.
50
70.0
979
.81
91.6
087
.84
78.5
477
.00
Upd
ated
Vic
toria
's m
obile
EI w
ith la
test
dat
a fro
m U
T
Upd
ated
che
mic
al a
nd te
mpo
ral p
rofil
es fo
r Te
xas
area
and
non
-road
em
issi
ons
Upd
ated
Vic
toria
's p
oint
sou
rces
Upd
ated
Tex
as N
EGU
and
EG
U s
ourc
es
outs
ide
of H
oust
on
U
pdat
ed L
ouis
iana
poi
nt s
ourc
e em
issi
ons
U
pdat
ed A
ustin
’s a
rea
& no
n-ro
ad s
ourc
es
Base
Cas
e G
19
99 7
0.16
71.
51
69.9
079
.63
91.4
987
.65
80.0
977
.00
Upd
ated
San
Ant
onio
asp
halt
emis
sion
s
Upd
ated
tank
er tr
uck
unlo
adin
g em
issi
ons
U
pdat
ed ta
nker
truc
ks in
tran
sit e
mis
sion
s
Upd
ated
em
issi
ons
for o
ther
gas
olin
e di
strib
utio
n ac
tiviti
es
Base
Cas
e A
2007
74
.71
Ba
se C
ase
B 20
07 7
0.43
69.
14
68.9
976
.78
87.0
389
.14
76.9
275
.21
Upd
ated
regi
onal
EI H
DD
non
-road
EI
(pro
vide
d by
TC
EQ)
U
pdat
ed A
ustin
Poi
nt S
ourc
e C
ontro
l EI
(Alc
oa)
G
-46
CA
MS
678
(con
tinue
d)
Base
Cas
e D
20
07
70
.56
69
.14
68.9
4
76
.77
87.0
4
89
.14
76.9
3
75
.22
U
pdat
ed S
an A
nton
io c
onst
ruct
ion
and
quar
ry e
quip
men
t em
issi
ons
In
corp
orat
ed n
ew w
aste
wat
er e
stim
ates
Rev
ised
Aus
tin P
oint
Sou
rce
Con
trol E
I (A
lcoa
) Ba
se C
ase
E 20
07 7
0.08
68.
00
68.8
976
.26
85.5
387
.83
76.1
074
.51
Rev
ised
Aus
tin P
oint
Sou
rce
Con
trol E
I
Inco
rpor
ated
new
regi
onal
tem
pora
l pro
file
for p
oint
sou
rces
Adde
d C
O fo
r Aus
tin o
n-ro
ad E
I (3
Cou
nty)
Incl
uded
sta
ge1
(125
k) fo
r the
4-c
ount
y Sa
n An
toni
o M
SA
R
emov
ed ta
nk tr
uck
unlo
adin
g on
Sun
day
to
mat
ch E
PA g
uida
nce
U
pdat
ed o
ther
are
a so
urce
tem
pora
l pro
files
to
mat
ch E
PA g
uida
nce
U
pdat
ed T
exas
regi
onal
are
a an
d no
n-ro
ad
emis
sion
s
U
pdat
ed T
exas
poi
nt s
ourc
es (b
esid
es C
PS)
U
pdat
ed L
ehig
h ce
men
t Kiln
con
trols
Upd
ated
poi
nt s
ourc
e cu
t off
poin
t fro
m 2
0m
to 5
0m o
n th
e 4-
km g
rid to
mat
ch th
e 12
-km
gr
id c
ut o
ff
U
pdat
ed V
icto
ria E
I Ba
se C
ase
F 20
07 7
0.08
68.
00
68.8
976
.26
85.5
587
.84
76.1
074
.61
Upd
ated
Vic
toria
's m
obile
EI
U
pdat
ed c
hem
ical
and
tem
pora
l pro
files
for
Texa
s ar
ea a
nd n
on-ro
ad e
mis
sion
s Ba
se C
ase
G
2007
69.
89 6
7.86
68
.75
76.1
1 85
.50
87.8
7 77
.45
74.4
6
Upd
ated
San
Ant
onio
asp
halt
emis
sion
s
Upd
ated
tank
er tr
uck
unlo
adin
g em
issi
ons
U
pdat
ed ta
nker
truc
ks in
tran
sit e
mis
sion
s
Upd
ated
em
issi
ons
from
oth
er g
asol
ine
dist
ribut
ion
activ
ities
Upd
ated
em
issi
ons
for R
OP
cont
rols
G-47
REFERENCES U.S. Environmental Protection Agency (May 1999). Draft Guidance on the Use of Models and Other Analyses in Attainment Demonstrations for the 8-hour Ozone NAAQS. Research Triangle Park, NC: Office of Air Quality Planning and Standards.