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APPENDIX K - SOIL ORGANIC CARBON/WATER … · Coefficients Std. Error t Stat P-value Lower 95%...

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APPENDIX K Soil Organic Carbon (K oc ) / Water (K ow ) Partition Coefficients
Transcript

APPENDIX K

Soil Organic Carbon (Koc) / Water (Kow) PartitionCoefficients

Table K-1. Values Used for Koc / Kow Correlation

Calculated Measured

Chemical log Kow log Koc Koc log Koc Koc (geomean)

Benzene 2.13 1.77 59 1.79 61.7Bromoform 2.35 1.94 87 2.10 126Carbon tetrachloride 2.73 2.24 174 2.18 152Chlorobenzene 2.86 2.34 219 2.35 224Chloroform 1.92 1.60 40 1.72 52.5Dichlorobenzene, 1,2- (o) 3.43 2.79 617 2.58 379Dichlorobenzene, 1,4- (p) 3.42 2.79 617 2.79 616Dichloroethane, 1,1- 1.79 1.50 32 1.73 53.4Dichloroethane, 1,2- 1.47 1.24 17 1.58 38.0Dichloroethylene, 1,1- 2.13 1.77 59 1.81 65Dichloroethylene, trans -1,2- 2.07 1.72 52 1.58 38Dichloropropane, 1,2- 1.97 1.64 44 1.67 47.0Dieldrin 5.37 4.33 21,380 4.41 25,546Endosulfan 4.10 3.33 2,138 3.31 2,040Endrin 5.06 4.09 12,303 4.03 10,811Ethylbenzene 3.14 2.56 363 2.31 204Hexachlorobenzene 5.89 4.74 54,954 4.90 80,000Methyl bromide 1.19 1.02 10 0.95 9.0Methyl chloride 0.91 0.80 6 0.78 6.0Methylene chloride 1.25 1.07 12 1.00 10

Pentachlorobenzene 5.26 4.24 17,378 4.51 32,148Tetrachloroethane, 1,1,2,2- 2.39 1.97 93 1.90 79.0Tetrachloroethylene 2.67 2.19 155 2.42 265

Toluene 2.75 2.26 182 2.15 140Trichlorobenzene, 1,2,4- 4.01 3.25 1,778 3.22 1,659Trichloroethane, 1,1,1- 2.48 2.04 110 2.13 135Trichloroethane, 1,1,2- 2.05 1.70 50 1.88 75.0Trichloroethylene 2.71 2.22 166 1.97 94.3Xylene, o- 3.13 2.56 363 2.38 241Xylene, m- 3.20 2.61 407 2.29 196Xylene, p- 3.17 2.59 389 2.49 311

Regression Statistics

Multiple R 0.9870R Square 0.9742Adjusted R Square 0.9733Standard Error 0.1640

Observations 31

ANOVA

df SS MS F Significance FRegression 1 29.4358 29.4358 1,094 1.4032E-24Residual 29 0.7804 0.0269

Total 30 30.2161

Coefficients Std. Error t Stat P-value Lower 95% Upper 95%Intercept 0.0784 0.0748 1.0481 0.3033 -0.0746 0.2314

X Variable 1 0.7919 0.0239 33.0742 0.0000 0.7430 0.8409

K-1

K-2

Fig

ure

K-1

. Co

rrel

atio

n P

lot:

log

Ko

w a

nd

log

Ko

c

0.00

1.00

2.00

3.00

4.00

5.00

0.00

1.00

2.00

3.00

4.00

5.00

6.00

log

Ko

w

log Koc

log

Koc

= 0

.791

9 lo

g K

ow +

0.0

784

mea

sure

d K

oc (

geom

ean)

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

Ace

nap

hth

ene

83-3

2-9

3,89

03.

59S

zabo

(19

90a)

RP

-HP

LC o

n P

IHA

C (

hum

ic a

cids

)

6,16

63.

79S

zabo

(19

90a)

RP

-HP

LC o

n C

IHA

C (

hum

ic a

cids

)

Ave

rag

e5,

028

3.70

Geo

met

ric

Mea

n4,

898

3.69

Ace

ton

e67

-64-

1

Ald

rin

309-

00-2

48,3

944.

68Lo

rd e

t al.

(198

0)"G

eesc

roft/

Rot

ham

sted

Far

m"

soil;

2.6

% O

M; p

H=

5.1;

sus

pect

48,9

784.

69B

riggs

(19

81)

Bat

com

be s

ilt lo

am (

Gr.

Br.

); 2

.05%

OC

; pH

=6.

1

Ave

rag

e48

,686

4.69

Geo

met

ric

Mea

n48

,685

4.69

An

thra

cen

e12

0-12

-7

14,5

004.

16M

cCar

thy

& J

imen

ez (

1985

)hu

mic

aci

ds

15,8

494.

20K

aric

hkof

f (19

81)

soil/

sedi

men

ts a

vera

ge; s

hake

-fla

sk U

V

19,5

624.

29La

ndru

m e

t al.

(198

4)su

rfac

e w

ater

(ge

omea

n 5

valu

es)

23,9

884.

38H

odso

n &

Will

iam

s (1

988)

cyan

opro

pyl c

olum

n; H

PLC

26,0

004.

41K

aric

khof

f et a

l. (1

979)

avg.

coa

rse

silt

frac

tion,

Doe

Run

& H

icko

ry H

ill s

edim

ents

26,3

034.

42S

zabo

et a

l. (1

990a

)R

P-H

PLC

on

PIH

AC

(hu

mic

aci

ds)

27,8

404.

44A

bdul

& G

ibso

n (1

986)

Flin

t aqu

ifer

sam

ple;

87%

san

d; fo

c =

0.0

187

31,3

294.

50La

ndru

m e

t al.

(198

4)hu

mic

aci

d (g

eom

ean

8 va

lues

)

33,8

844.

53S

zabo

et a

l. (1

990a

)R

P-H

PLC

on

CIH

AC

(hu

mic

aci

ds)

Ave

rag

e24

,362

4.39

Geo

met

ric

Mea

n23

,493

4.37

Ben

z(α)

anth

race

ne

56-5

5-3

150,

000

5.18

McC

arth

y &

Jim

enez

(19

85)

hum

ic a

cid

199,

526

5.30

Land

rum

et a

l. (1

984)

hum

ic a

cid

650,

000

5.81

Kar

ickh

off e

t al.

(197

9)av

g. c

oars

e si

lt fr

actio

n, D

oe R

un &

Hic

kory

Hill

sed

s.

840,

000

5.92

Sm

ith e

t al.

(197

8) a

s ci

ted

in D

i Tor

o et

al.

(198

5)40

% O

C

Ave

rag

e45

9,88

25.

66

Geo

met

ric

Mea

n35

7,53

75.

55

Ben

zen

e71

-43-

2

311.

50C

hiou

et a

l. (1

983)

Woo

dbur

n si

lt lo

am; f

om =

0.0

19; 2

1% c

lay

38.2

1.58

Sei

p et

al.

(198

6)fo

rest

soi

l with

0.2

% O

C; c

olum

n st

udy

43.5

1.64

Sei

p et

al.

(198

6)ag

ricul

tura

l soi

l with

2.2

% O

C; c

olum

n st

udy

491.

69A

bdul

et a

l. (1

987)

batc

h eq

uilib

rium

exp

erim

ents

; aqu

ifer

mat

eria

l; fo

c =

0.0

105

53.5

1.73

Sei

p et

al.

(198

6)fo

rest

soi

l with

3.7

% O

C; c

olum

n st

udy

601.

78K

aric

khof

f (19

81)

soils

/sed

imen

ts a

vera

ge; s

hake

flas

k U

V

K-3

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

Ben

zen

e71

-43-

2

(con

tinue

d)63

1.80

Piw

oni &

Ban

erje

e (1

989)

0.

19 p

erce

nt o

rgan

ic c

arbo

n

661.

82S

zabo

et a

l. (1

990a

)R

P-H

PLC

on

PIH

AC

(hu

mic

aci

ds)

741.

87S

zabo

et a

l. (1

990a

)R

P-H

PLC

on

CIH

AC

(hu

mic

aci

ds)

831.

92K

aric

khof

f et a

l. (1

979)

avg.

coa

rse

silt

frac

tion,

Doe

Run

& H

icko

ry H

ill s

eds.

921.

97R

oger

s et

al.

(198

0)H

astin

gs s

ilty

clay

loam

with

2.6

% O

C

981.

99P

avlo

u (1

987)

as

cite

d in

Mac

kay

et a

l. (1

992)

100

2.00

Rog

ers

et a

l. (1

980)

Ove

rton

silt

y cl

ay lo

am w

ith 1

.8%

OC

Ave

rag

e66

1.82

Geo

met

ric

Mea

n62

1.79

Ben

zo(a

)pyr

ene

50-3

2-8

478,

947

5.68

Sm

ith e

t al.

(197

8) a

s ci

ted

in D

i Tor

o (1

985)

3.

8% O

C

891,

251

5.95

Land

rum

et a

l. (1

984)

hum

ic a

cids

2,13

0,00

06.

33M

cCar

thy

& J

imen

ez (

1985

)hu

mic

aci

ds (

aver

age

8 va

lues

)

Ave

rag

e1,

166,

733

6.07

Geo

met

ric

Mea

n96

8,77

45.

99

Ben

zo(b

)flu

ora

nth

ene

205-

99-2

Ben

zo(k

)flu

ora

nth

ene

207-

08-9

Bis

(2-c

hlo

reth

yl)e

ther

111-

44-4

75.9

1.88

Wils

on e

t al.

(198

1)Li

ncol

n sa

nd; 0

.087

% O

C

Ave

rag

e76

1.88

Geo

met

ric

Mea

n76

1.88

Bis

(2-e

thyl

hex

yl)p

hth

alat

e11

7-81

-7

(Bis

(2-e

thyl

hexy

l)est

er)

87,4

204.

94R

usse

ll &

McD

uffie

(19

86)

Bro

ome

Co.

, NY

, com

posi

te s

oil;

1.59

% O

C; c

olum

n st

udy

141,

254

5.15

Car

ter

& S

uffe

t (19

83)

mea

sure

d ch

ange

in s

orpt

ion

in p

rese

nce

of h

umic

aci

ds

Ave

rag

e11

4,33

75.

06

Geo

met

ric

Mea

n11

1,12

35.

05

Bro

mo

dic

hlo

rom

eth

ane

75-2

7-4

Bro

mo

form

75-2

5-2

(Trib

rom

omet

hane

)12

62.

10H

utzl

er e

t al.

(198

6)co

lum

n, K

ewee

naw

7 s

oil;

0.85

% O

C

Ave

rag

e12

62.

10

Geo

met

ric

Mea

n12

62.

10

K-4

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

Bu

tyl b

enzy

l ph

thal

ate

85-6

8-7

16,9

814.

23R

usse

ll &

McD

uffie

(19

86)

Bro

ome

Cou

nty,

NY

, com

posi

te s

oil w

ith 1

.59%

OC

; col

umn

11,1

284.

05G

ledh

ill (

1980

)3

soils

; 1.2

-3.4

% O

C -

geo

mea

n va

lue

calc

ulat

ed fr

om r

ange

Ave

rag

e14

,055

4.15

Geo

met

ric

Mea

n13

,746

4.14

Car

baz

ole

86-7

4-8

Car

bo

n d

isu

lfid

e75

-15-

0

Car

bo

n t

etra

chlo

rid

e56

-23-

5

123

2.09

Koc

h (1

983)

sorp

tion

coef

ficie

nt (

assu

me

Kom

) fr

om u

npub

lishe

d so

urce

127

2.10

Rut

herf

ord

et a

l. (1

992)

extr

acte

d pe

at; 6

4% O

C

224

2.35

Abd

ul e

t al.

(198

7)

from

MS

thes

is

Ave

rag

e15

82.

20

Geo

met

ric

Mea

n15

22.

18

Ch

lord

ane

57-7

4-9

44,7

114.

65Jo

hnso

n-Lo

gan

et a

l. (1

992)

geol

ogic

mat

eria

l, N

. Hol

lyw

ood

dum

p (a

vg. 1

4 va

lues

)

58,8

844.

77C

hin

& W

eber

(19

89)

hum

ic a

cid

poly

mer

s

Ave

rag

e51

,798

4.71

Geo

met

ric

Mea

n51

,310

4.71

Ch

loro

ben

zen

e10

8-90

-7

831.

92C

hiou

et a

l. (1

983)

Woo

dbur

n si

lt lo

am; f

om =

0.0

19; 2

1% c

lay

117

2.07

Wils

on e

t al.

(198

1)Li

ncol

n sa

nd; 0

.087

% O

C

164

2.22

Sch

war

zenb

ach

& W

esta

ll (1

981)

K

S1

colle

cted

from

fiel

d si

te lo

catio

n; fo

c =

0.0

073

200

2.30

Sch

war

zenb

ach

& G

iger

(19

82)

as c

ited

in G

erst

l (19

90)

syst

em s

peci

fic in

form

atio

n no

t giv

en

219

2.34

Sch

war

zenb

ach

& G

iger

(19

82)

as c

ited

in G

erst

l (19

90)

syst

em s

peci

fic in

form

atio

n no

t giv

en

260

2.41

Sch

war

zenb

ach

& W

esta

ll (1

981)

av

erag

e of

six

mea

sure

men

ts;fo

c =

0.0

015

389

2.59

Rob

erts

et a

l. (1

980)

calc

ulat

ed fr

om fi

eld

data

ass

umin

g fo

c =

0.0

099

407

2.61

Sch

war

zenb

ach

& G

iger

(19

82)

as c

ited

in G

erst

l (19

90)

syst

em s

peci

fic in

form

atio

n no

t giv

en

500

2.70

Sch

war

zenb

ach

& W

esta

ll (1

981)

fie

ld s

ampl

e; 0

.08%

OC

Ave

rag

e26

02.

41

Geo

met

ric

Mea

n22

42.

35

Ch

loro

dib

rom

om

eth

ane

124-

48-1

Ch

loro

form

67-6

6-3

281.

44G

rath

woh

l (19

90)

20 C

; soi

l, sa

nd &

loes

s

401.

60H

utzl

er e

t al.

(198

3)av

erag

e of

two

soils

761.

88W

ilson

et a

l. (1

981)

Linc

oln

sand

; 0.0

87%

OC

591.

77Lo

ch e

t al.

(198

6)to

p 20

cm

, Eer

d so

il; 4

.06%

OC

(fr

om u

npub

lishe

d w

ork)

K-5

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

Ch

loro

form

67-6

6-3

(con

tinue

d)81

1.91

Loch

et a

l. (1

986)

top

20 c

m, p

eat s

oil ;

11.

6% O

C (

from

unp

ublis

hed

wor

k)

Ave

rag

e57

1.75

Geo

met

ric

Mea

n53

1.72

Ch

ryse

ne

218-

01-9

DD

D72

-54-

8

45,8

004.

66G

usta

fson

(19

89)

aver

age

valu

e fr

om c

olle

cted

mea

sure

d va

lues

Ave

rag

e45

,800

4.66

Geo

met

ric

Mea

n45

,800

4.66

DD

E72

-55-

9

86,4

054.

94K

och

(198

3)so

rptio

n co

effic

ient

(as

sum

e K

om)

from

unp

ublis

hed

sour

ce

Ave

rag

e86

,405

4.94

Geo

met

ric

Mea

n86

,405

4.94

DD

T50

-29-

3

285,

467

5.46

Ger

stl &

Min

gelg

rin (

1984

)M

alki

ya s

oil;

5.82

% O

M

496,

476

5.70

Ger

stl &

Min

gelg

rin (

1984

)N

eve

Yaa

r so

il; 2

.82%

OM

589,

537

5.77

Ger

stl &

Min

gelg

rin (

1984

)K

inne

ret G

sed

imen

t; 4.

39%

OM

747,

887

5.87

Ger

stl &

Min

gelg

rin (

1984

)K

inne

ret A

sed

imen

t; 7.

85%

OM

892,

067

5.95

Ger

stl &

Min

gelg

rin (

1984

)G

ilat s

oil;

1.25

% O

M

1,74

1,51

66.

24G

erst

l & M

inge

lgrin

(19

84)

Miv

tahi

m s

oil;

0.45

% O

M

Ave

rag

e79

2,15

85.

90

Geo

met

ric

Mea

n67

7,93

45.

83

Dib

enz(

a,h

)an

thra

cen

e53

-70-

3

565,

014

5.75

Mea

ns e

t al.

(198

0); H

asse

t et a

l. (1

980)

IL

soi

l; 1.

30%

OC

(E

PA

-20)

805,

292

5.91

Mea

ns e

t al.

(198

0); H

asse

t et a

l. (1

980)

N

D s

edim

ent;

2.28

% O

C (

EP

A-5

)

808,

991

5.91

Mea

ns e

t al.

(198

0); H

asse

t et a

l. (1

980)

IL

sed

imen

t; 2.

38%

OC

(E

PA

-23)

1,17

2,84

76.

07M

eans

et a

l. (1

980)

; Has

set e

t al.

(198

0)

IA s

edim

ent;

0.15

% O

C (

EP

A-8

)

1,69

0,97

16.

23M

eans

et a

l. (1

980)

; Has

set e

t al.

(198

0)

GA

sed

imen

t; 1.

21%

OC

(E

PA

-B2)

1,68

7,40

46.

23M

eans

et a

l. (1

980)

; Has

set e

t al.

(198

0)

MO

sed

imen

t; 2.

07%

OC

(E

PA

-4)

2,27

7,87

56.

36M

eans

et a

l. (1

980)

; Has

set e

t al.

(198

0)

IA lo

ess;

0.1

1% O

C (

EP

A-9

)

2,38

3,76

56.

38M

eans

et a

l. (1

980)

; Has

set e

t al.

(198

0)

IL s

edim

ent;

1.67

% O

C (

EP

A-2

2)

2,62

2,45

36.

42M

eans

et a

l. (1

980)

; Has

set e

t al.

(198

0)

SD

sed

imen

t; 0.

72%

OC

(E

PA

-6)

2,66

3,31

76.

43M

eans

et a

l. (1

980)

; Has

set e

t al.

(198

0)

IN s

edim

ent;

0.95

% O

C (

EP

A-1

5)

2,69

1,87

06.

43M

eans

et a

l. (1

980)

; Has

set e

t al.

(198

0)

IL s

edim

ent;

1.48

% O

C (

EP

A-2

6)

2,96

2,60

36.

47M

eans

et a

l. (1

980)

; Has

set e

t al.

(198

0)

IL s

edim

ent;

1.88

% O

C (

EP

A-2

1)

3,02

0,26

26.

48M

eans

et a

l. (1

980)

; Has

set e

t al.

(198

0)

WV

soi

l; 0.

48%

OC

(E

PA

-14)

K-6

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

Dib

enz(

a,h

)an

thra

cen

e53

-70-

3

(con

tinue

d)3,

059,

425

6.49

Mea

ns e

t al.

(198

0); H

asse

t et a

l. (1

980)

K

Y s

edim

ent;

0.66

% O

C (

EP

A-1

8)

Ave

rag

e2,

029,

435

6.31

Geo

met

ric

Mea

n1,

789,

101

6.25

1,2-

Dic

hlo

rob

enze

ne

(o)

95-5

0-1

267

2.43

Lee

et a

l. (1

989)

untr

eate

d M

arle

tte s

oil,

B+

hor

izon

; 0.3

% O

C

280

2.45

Lee

et a

l. (1

989)

untr

eate

d M

arle

tte s

oil,

A h

oriz

on; 2

.59%

OC

310

2.49

Chi

ou e

t al.

(197

9)W

illam

ette

silt

loam

; 0.9

28%

OC

; 3.5

deg

rees

Cel

sius

321

2.51

Chi

ou e

t al.

(198

3)W

oodb

urn

silt

loam

; 1.9

% O

M; 9

% s

and;

68%

silt

; 21%

cla

y

386

2.59

Sta

uffe

r &

Mac

Inty

re (

1986

)A

ppal

ache

e so

rben

t; 1.

4% O

C; p

H =

6.3

438

2.64

Sta

uffe

r &

Mac

Inty

re (

1986

)A

ppal

ache

e so

rben

t; 1.

4% O

C; p

H =

4.1

485

2.69

Frie

sel e

t al.

(198

4)pe

aty

soil;

29%

OM

497

2.70

Piw

oni &

Ban

erje

e (1

989)

sedi

men

t, 0.

19%

OC

; avg

. 2 v

alue

s

529

2.72

Frie

sel e

t al.

(198

4)fo

c re

port

ed a

s a

rang

e; a

vg. o

f sev

eral

exp

er.

Ave

rag

e39

02.

59

Geo

met

ric

Mea

n37

92.

58

1,4-

Dic

hlo

rob

enze

ne

(p)

106-

46-7

273

2.44

Chi

ou e

t al.

(198

3)W

oodb

urn

silt

loam

; fom

= 0

.019

; 21%

cla

y

280

2.45

Sou

thw

orth

& K

elle

r (1

986)

Dor

mon

t soi

l with

1.2

% O

C; 6

0% c

lay

300

2.48

Hut

zler

et a

l. (1

983)

co

lum

n; G

rayl

ing

soil;

1.5

2% O

C; B

21 h

oriz

on

398

2.60

Wils

on e

t al.

(198

1)Li

ncol

n sa

nd; 0

.087

% O

C

429

2.63

Frie

sel e

t al.

(198

4)re

port

ed a

s K

om; f

oc g

iven

as

a ra

nge

603

2.78

Sch

war

zenb

ach

& W

esta

ll (1

981)

K

S1

field

sam

ple;

0.7

3% O

C

665

2.82

Sou

thw

orth

& K

elle

r (1

986)

Api

son

soil

with

0.1

1% O

C; 8

6% c

lay

700

2.85

Hut

zler

et a

l. (1

983)

ba

tch;

ave

rage

of f

ive

soils

724

2.86

Sch

war

zenb

ach

& G

iger

(19

82)

as c

ited

in G

erst

l (19

90)

syst

em s

peci

fic in

form

atio

n no

t pro

vide

d

733

2.87

Sch

war

zenb

ach

& W

esta

ll (1

981)

aver

age

of s

ix m

easu

rem

ents

; aqu

ifer

mat

eria

l; fo

c =

0.0

015

832

2.92

Chi

n &

Web

er (

1989

)hu

mic

aci

d po

lym

ers

850

2.93

Sou

thw

orth

& K

elle

r (1

986)

Ful

lert

on s

oil w

ith 0

.06%

OC

911

2.96

Loch

et a

l. (1

986)

top

20 c

m o

f Eer

d so

il; 0

.06%

OC

; col

umn

1,02

43.

01W

u &

Gsc

hwen

d (1

986)

Cha

rles

Riv

er s

edim

ent;

8.5%

OC

1,25

93.

10S

chw

arze

nbac

h &

Gig

er (

1982

) as

cite

d in

Ger

stl (

1990

) sy

stem

spe

cific

info

rmat

ion

not p

rovi

ded

1,37

53.

14S

chw

arze

nbac

h &

Wes

tall

(198

1)fie

ld s

ampl

e; 0

.08%

OC

Ave

rag

e68

72.

84

Geo

met

ric

Mea

n61

62.

79

3,3-

Dic

hlo

rob

enzi

din

e91

-94-

1

K-7

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

1,1-

Dic

hlo

roet

han

e75

-34-

3

461.

66Ju

ry e

t al.

(199

0)so

il; s

elec

ted

621.

79R

oy e

t al.

(198

7)co

mpu

ted

from

an

isot

herm

; 4.0

4% O

C

Ave

rag

e54

1.73

Geo

met

ric

Mea

n53

1.73

1,2-

Dic

hlo

roet

han

e10

7-06

-2

221.

34Ju

ry e

t al.

(199

0)so

il; s

elec

ted

331.

52C

hiou

et a

l. (1

979)

Will

amet

te s

ilt lo

am; 0

.928

% O

C; 2

0 de

gree

s C

elsi

us

761.

88W

ilson

et a

l. (1

981)

Linc

oln

sand

; 0.0

87%

OC

Ave

rag

e44

1.64

Geo

met

ric

Mea

n38

1.58

1,1-

Dic

hlo

roet

hyl

ene

75-3

5-4

651.

81S

chw

ille

(198

8) (

seco

ndar

y)

Ave

rag

e65

1.81

Geo

met

ric

Mea

n65

1.81

cis

-1,2

-Dic

hlo

roet

hyl

ene

156-

59-2

tran

s-1

,2-D

ich

loro

eth

ylen

e15

6-60

-5

381.

58B

russ

eau

& R

ao (

1991

)T

ampa

san

dy a

quife

r m

ater

ial;

0.13

% O

C; <

2m

m

Ave

rag

e38

1.58

Geo

met

ric

Mea

n38

1.58

1,2-

Dic

hlo

rop

rop

ane

78-8

7-5

471.

67C

hiou

et a

l. (1

979)

Will

amet

te s

ilt lo

am; 0

.928

% O

C; 2

0 de

gree

s C

elsi

us

Ave

rag

e47

1.67

Geo

met

ric

Mea

n47

1.67

1,3-

Dic

hlo

rop

rop

ene

542-

75-6

241.

38Le

istr

a (1

970)

cis-

, av

g. 3

soi

ls; c

ompu

ted

from

vap

or p

hase

sor

ptio

n

261.

41Le

istr

a (1

970)

tran

s- ,

avg.

3 s

oils

; com

pute

d fr

om v

apor

pha

se s

orpt

ion

321.

51W

auch

ope

et a

l. (1

992)

tran

s-, p

erso

nal c

omm

. (un

publ

ishe

d so

urce

, Dow

Che

mic

al)

Ave

rag

e27

1.44

Geo

met

ric

Mea

n27

1.43

Die

ldri

n60

-57-

1

23,3

084.

37S

haro

m e

t al.

(198

0)B

ever

ly s

andy

loam

; 2.5

% O

M

26,1

064.

42S

haro

m e

t al.

(198

0)P

lain

field

san

d; 0

.7%

OM

27,3

994.

44S

haro

m e

t al.

(198

0)B

ig C

reek

sed

imen

t; 2.

8% O

M

Ave

rag

e25

,604

4.41

Geo

met

ric

Mea

n25

,546

4.41

K-8

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

Die

thyl

ph

thal

ate

84-6

6-2

691.

84R

usse

ll &

McD

uffie

(19

86)

Bro

ome

Cou

nty,

NY

, com

posi

te s

oil w

ith 1

.59%

OC

; col

umn

981.

99R

usse

ll &

McD

uffie

(19

86)

Con

klin

, NY

, san

d; 0

.26%

OC

; col

umn;

avg

. 4 v

alue

s

Ave

rag

e84

1.92

Geo

met

ric

Mea

n82

1.92

Dim

eth

yl p

hth

alat

e13

1-11

-3

7.6

0.88

Sei

p et

al.

(198

6)fo

rest

soi

l with

0.2

% O

C; c

olum

n st

udy

42.8

1.63

Sei

p et

al.

(198

6)ag

ricul

tura

l soi

l with

2.2

% O

C; c

olum

n st

udy

72.7

1.86

Sei

p et

al.

(198

6)fo

rest

soi

l with

3.7

% O

C; c

olum

n st

udy

Ave

rag

e41

1.61

Geo

met

ric

Mea

n29

1.46

Di-

n-b

uty

l ph

thal

ate

84-7

4-2

1,38

43.

14R

usse

ll &

McD

uffie

(19

86)

Bro

ome

Cou

nty,

NY

, com

posi

te s

oil w

ith 1

.59%

OC

; col

umn

1,77

53.

25R

usse

ll &

McD

uffie

(19

86)

Con

klin

, NY

, san

d; 0

.26%

OC

; ads

orp.

; avg

. 4 v

alue

s; c

olum

n

Ave

rag

e1,

580

3.20

Geo

met

ric

Mea

n1,

567

3.20

2,4-

Din

itro

tolu

ene

121-

14-2

2,6-

Din

itro

tolu

ene

606-

20-2

Di-

n-o

ctyl

ph

thal

ate

117-

84-0

En

do

sulf

an11

5-29

-7

2,04

03.

31G

usta

fson

(19

89)

aver

age

valu

e fr

om c

olle

cted

mea

sure

d va

lues

Ave

rag

e2,

040

3.31

Geo

met

ric

Mea

n2,

040

3.31

En

dri

n72

-20-

8

7,72

43.

89S

haro

m e

t al.

(198

0)B

ever

ly s

andy

loam

; 2.5

% O

M

7,79

33.

89S

haro

m e

t al.

(198

0)or

gani

c so

il; 7

5.3%

OM

14,2

854.

15S

haro

m e

t al.

(198

0)P

lain

field

san

d; 0

.7%

OM

15,8

854.

20S

haro

m e

t al.

(198

0)B

ig C

reek

sed

imen

t; 2.

8% O

M

Ave

rag

e11

,422

4.06

Geo

met

ric

Mea

n10

,811

4.03

Eth

ylb

enze

ne

100-

41-4

165

2.22

Chi

ou e

t al.

(198

3)W

oodb

urn

silt

loam

; fom

= 0

.019

; 21%

cla

y

184

2.27

Lee

et a

l. (1

989)

untr

eate

d S

t. C

lair

soil;

0.4

4% O

C; 4

4% c

lay;

B+

hor

izon

191

2.28

Lee

et a

l. (1

989)

untr

eate

d O

shte

mo

soil;

0.1

1% O

C; 6

.3%

cla

y; B

+ h

oriz

on

240

2.38

Hod

son

& W

illia

ms

(198

8)H

PLC

; cya

nopr

opyl

col

umn

K-9

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

Eth

ylb

enze

ne

100-

41-4

(con

tinue

d)25

52.

41V

owle

s &

Man

tour

a (1

987)

Tam

ar e

stua

ry s

edim

ent;

4.02

% O

C; 0

.2%

syn

th. s

ea s

alt

Ave

rag

e20

72.

32

Geo

met

ric

Mea

n20

42.

31

Flu

ora

nth

ene

206-

44-0

41,6

874.

62S

zabo

et a

l. (1

990a

)R

P &

HP

LC o

n P

IHA

C (

hum

ic a

cids

)

51,6

584.

71A

bdul

& G

ibso

n (1

986)

Flin

t aqu

ifer

sam

ple;

87%

san

d; fo

c =

0.0

187

54,9

544.

74S

zabo

et a

l. (1

990a

)R

P &

HP

LC o

n C

IHA

C (

hum

ic a

cids

)

Ave

rag

e49

,433

4.69

Geo

met

ric

Mea

n49

,096

4.69

Flu

ore

ne

86-7

3-7

3,98

93.

60A

bdul

et a

l. (1

986)

Bor

den

aqui

fer

mat

eria

l (av

g. 2

val

ues,

foc

= 0

.009

1,0.

0121

)

4,61

53.

66A

bdul

et a

l. (1

986)

Flin

t aqu

ifer

mat

eria

l (av

g. 8

val

ues)

5,57

63.

75A

bdul

et a

l. (1

986)

War

ren

aqui

fer

mat

eria

l (av

g. 8

val

ues)

8,91

33.

95C

arte

r &

Suf

fet (

1983

)hu

mic

mat

eria

ls (

DO

C)

14,1

254.

15S

zabo

et a

l. (1

990a

)R

P-H

PLC

on

CIH

AC

(hu

mic

aci

ds)

16,2

184.

21S

zabo

et a

l. (1

990a

)R

P-H

PLC

on

PIH

AC

(hu

mic

aci

ds)

Ave

rag

e8,

906

3.95

Geo

met

ric

Mea

n7,

707

3.89

Hep

tach

lor

76-4

4-8

6,81

03.

83Ju

ry e

t al.

(199

0)se

lect

ed

13,3

304.

12G

usta

fson

(19

89)

aver

age

valu

e fr

om c

olle

cted

mea

sure

d va

lues

Ave

rag

e10

,070

4.00

Geo

met

ric

Mea

n9,

528

3.98

Hep

tach

lor

epo

xid

e10

24-5

7-3

Hex

ach

loro

ben

zen

e11

8-74

-1

80,0

004.

90K

aric

khof

f & M

orris

(19

85a)

GA

sed

imen

ts; 0

.5-1

.5%

OC

Ave

rag

e80

,000

4.90

Geo

met

ric

Mea

n80

,000

4.90

Hex

ach

loro

-1,3

-bu

tad

ien

e87

-68-

3

α-H

exac

hlo

rocy

clo

hex

ane

319-

84-6

(alp

ha-B

HC

)1,

022

3.01

Wah

id &

Set

huna

than

(19

79)

sing

le m

easu

rem

ent;

late

ritic

soi

l; 1.

62%

OM

1,25

33.

10W

ahid

& S

ethu

nath

an (

1979

) si

ngle

mea

sure

men

t; la

terit

ic s

oil;

1.27

% O

M

1,33

03.

12W

ahid

& S

ethu

nath

an (

1979

) si

ngle

mea

sure

men

t; K

ari s

oil;

24.6

% O

M

1,38

63.

14W

ahid

& S

ethu

nath

an (

1979

) si

ngle

mea

sure

men

t; sa

ndy

soil;

12.

6% O

M

1,53

23.

19W

ahid

& S

ethu

nath

an (

1979

) si

ngle

mea

sure

men

t; al

luvi

al s

oil;

0.75

% O

M

K-1

0

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

α-H

exac

hlo

rocy

clo

hex

ane

319-

84-6

(con

tinue

d)2,

004

3.30

Wah

id &

Set

huna

than

(19

79)

sing

le m

easu

rem

ent;

late

ritic

soi

l; 2.

88%

OM

2,02

43.

31W

ahid

& S

ethu

nath

an (

1979

) si

ngle

mea

sure

men

t; la

terit

ic s

oil;

1.00

% O

M

2,09

03.

32W

ahid

& S

ethu

nath

an (

1979

) si

ngle

mea

sure

men

t; P

okka

li so

il; 5

.52%

OM

2,12

33.

33W

ahid

& S

ethu

nath

an (

1979

) si

ngle

mea

sure

men

t; K

ari s

oil;

8.21

% O

M

2,16

83.

34W

ahid

& S

ethu

nath

an (

1979

) si

ngle

mea

sure

men

t; la

terit

ic s

oil;

0.60

% O

M

2,20

03.

34W

ahid

& S

ethu

nath

an (

1979

) si

ngle

mea

sure

men

t; la

terit

ic s

oil;

0.92

% O

M

2,89

13.

46W

ahid

& S

ethu

nath

an (

1979

) si

ngle

mea

sure

men

t; al

luvi

al s

oil;

0.70

% O

M

Ave

rag

e1,

835

3.26

Geo

met

ric

Mea

n1,

762

3.25

β-H

exac

hlo

rocy

clo

hex

ane

319-

85-7

(bet

a-B

HC

)1,

156

3.06

Wah

id &

Set

huna

than

(19

79)

sing

le m

easu

rem

ent;

late

ritic

soi

l; 1.

27%

OM

1,47

03.

17W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; la

terit

ic s

oil;

1.62

% O

M

1,68

13.

23W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; K

ari s

oil;

24.6

% O

M

1,79

43.

25M

ills

& B

igga

r (1

969b

)V

enad

o cl

ay; 3

.5%

OC

; 50%

mon

tmor

illon

ite; 2

C; 1

/n=

0.86

1

1,82

13.

26W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; sa

ndy

soil;

12.

6% O

M

1,86

83.

27W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; la

terit

ic s

oil;

1.00

% O

M

1,95

83.

29W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; al

luvi

al s

oil;

0.75

% O

M

2,09

83.

32W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; al

luvi

al s

oil;

0.70

% O

M

2,41

53.

38W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; K

ari s

oil;

8.21

% O

M

2,54

83.

41W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; la

terit

ic s

oil;

0.60

% O

M

2,69

73.

43W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; la

terit

ic s

oil;

0.92

% O

M

3,14

33.

50W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; la

terit

ic s

oil;

2.88

% O

M

3,15

83.

50W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; P

okka

li so

il; 5

.52%

OM

3,56

33.

55M

ills

& B

igga

r (1

969b

)S

tate

n pe

aty

muc

k, 1

2.8%

OC

; 20

° C

; 1/n

= 0

.950

Ave

rag

e2,

241

3.35

Geo

met

ric

Mea

n2,

139

3.33

γ-H

exac

hlo

rocy

clo

hex

ane

58-8

9-9

(Lin

dane

)73

12.

86A

dam

s &

Li (

1971

)S

vea

sil,

A h

oriz

on ;

foc

= 0

.031

735

2.87

McC

all e

t al.

(198

0)av

erag

e fo

r th

ree

soils

, 0.6

8-2.

01%

OC

757

2.88

Hug

genb

erge

r et

al.

(197

2)G

ila s

ilt lo

am; f

oc =

0.0

038;

cou

lmn

stud

y

760

2.88

Kis

hi e

t al.

(199

0)cl

ay lo

am (

allo

phan

e); s

oil p

H =

4.8

9; fo

c =

0.1

04

760

2.88

Wah

id &

Set

huna

than

(19

80)

late

rtic

soi

l; 2.

88%

OM

; 1:1

764

2.88

Ada

ms

& L

i (19

71)

Heg

ne s

ic, A

hor

izon

; fo

c =

0.0

43

764

2.88

Ada

ms

& L

i (19

71)

Heg

ne s

ic, B

hor

izon

; fo

c =

0.0

06

769

2.89

Ada

ms

& L

i (19

71)

Far

go s

ic, A

hor

izon

; fo

c =

0.0

52

812

2.91

Ada

ms

& L

i (19

71)

Hub

bard

ls, A

hor

izon

; fo

c =

0.0

12

814

2.91

Ada

ms

& L

i (19

71)

Ont

onag

on c

, A h

oriz

on ;

foc

= 0

.035

826

2.92

Ada

ms

& L

i (19

71)

Mila

ca s

l, A

hor

izon

; fo

c =

0.0

17

852

2.93

Mill

s &

Big

gar

(196

9a)

1.1%

OC

; Ca

Col

umbi

a si

lt lo

am

K-1

1

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

γ-H

exac

hlo

rocy

clo

hex

ane

58-8

9-9

(con

tinue

d)85

52.

93A

dam

s &

Li (

1971

)K

ranz

burg

sic

l, B

hor

izon

; fo

c =

0.0

1

878

2.94

Ada

ms

& L

i (19

71)

Sve

a si

l, B

hor

izon

; fo

c =

0.0

08

960

2.98

Kis

hi e

t al.

(199

0)sa

ndy

loam

(al

loph

ane)

; soi

l pH

= 5

.41;

foc

= 0

.079

1

968

2.99

Kay

& E

lrick

(19

67)

Muc

k (3

8% O

C)

985

2.99

Ada

ms

& L

i (19

71)

Fay

ette

sil,

A h

oriz

on ;

foc

= 0

.023

986

2.99

Kay

& E

lrick

(19

67)

Hon

eyw

ood

loam

(2.

1% O

C)

1,00

53.

00A

dam

s &

Li (

1971

)C

anis

teo

cl, B

hor

izon

; fo

c =

0.0

06

1,01

03.

00R

ippe

n et

al.

(198

2)A

lfiso

l; U

dalf,

Par

a br

own

eart

h; 0

.76%

OC

; soi

l pH

= 7

.45

1,03

03.

01K

ay &

Elri

ck (

1967

)F

ox lo

amy

sand

(1.

7% O

C)

1,07

93.

03A

dam

s &

Li (

1971

)Le

ster

fsl,

A h

oriz

on ;

foc

= 0

.023

1,10

33.

04H

ugge

nber

ger

et a

l. (1

972)

Pac

happ

a sa

ndy

loam

; foc

= 0

.005

1,10

33.

04S

haro

m e

t al.

(198

0)B

ever

ly s

and

loam

; 2.5

% O

M

1,10

93.

04W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; sa

ndy

soil;

12.

6% O

C

1,12

53.

05A

dam

s &

Li (

1971

)Z

imm

erm

an s

, A h

oriz

on ;

foc

= 0

.007

1,13

03.

05H

ugge

nber

ger

et a

l. (1

972)

Ken

twoo

d sa

ndy

loam

; foc

= 0

.009

3

1,20

03.

08K

ishi

et a

l. (1

990)

light

cla

y (m

ontm

orill

onite

- il

lite)

; pH

= 5

.26;

foc

= 0

.032

3

1,20

43.

08W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; la

terit

ic s

oil;

1.27

% O

M

1,22

73.

09K

ay &

Elri

ck (

1967

)B

rook

ston

e sa

ndy

loam

(1.

9% O

C)

1,26

33.

10A

dam

s &

Li (

1971

)B

rain

erd

fsl,

A h

oriz

on ;

foc

= 0

.026

1,27

43.

11A

dam

s &

Li (

1971

)B

eard

en s

il, B

hor

izon

; fo

c =

0.0

02

1,30

03.

11K

ishi

et a

l. (1

990)

light

cla

y (m

ontm

orill

onite

); s

oil p

H =

5.1

8; fo

c =

0.0

151

1,30

03.

11M

cCal

l et a

l. (1

983)

Not

sta

ted

if th

ese

are

orig

inal

dat

a

1,31

83.

12M

iller

& W

eber

(19

86)

Ann

Arb

or s

oil;

1.14

% O

C

1,32

23.

12M

orea

le &

van

Bla

del (

1978

)Lu

bbee

k II

soil;

0.5

3% O

C; 1

0% c

lay

1,33

53.

13M

orea

le &

van

Bla

del (

1978

)Lu

bbee

k I s

oil;

0.07

% O

C; 2

% c

lay

1,45

23.

16M

ills

& B

igga

r (1

969a

) 3.

1% O

C; C

a V

enad

o cl

ay

1,45

53.

16A

dam

s &

Li (

1971

)B

rain

erd

sl, B

hor

izon

; fo

c =

0.0

01

1,45

83.

16M

iller

& W

eber

(19

86)

Del

ta s

oil;

0.12

% T

OC

1,47

83.

17S

haro

m e

t al.

(198

0)B

ig C

reek

sed

imen

t; 2.

8% O

M

1,52

53.

18W

ahid

& S

ethu

nath

an (

1978

)P

okka

li so

il; 5

.52%

OM

; 1:1

0; 5

min

eq.

1,58

03.

20W

ahid

& S

ethu

nath

an (

1980

)P

okka

li so

il; 5

.52%

OM

; 1:1

1,68

13.

23W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; K

ari s

oil;

24.6

% O

M

1,72

43.

24W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; la

terit

ic s

oil;

1.00

% O

M

1,83

03.

26A

dam

s &

Li (

1971

)B

lue

Ear

th s

il, A

hor

izon

; fo

c =

0.1

1

1,85

93.

27C

aron

et a

l. (1

985)

Pow

ervi

lle s

edim

ent (

NJ)

; 2-4

% O

C

1,89

63.

28W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; la

terit

ic s

oil;

2.88

% O

M

1,93

53.

29W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; al

luvi

al s

oil;

0.70

% O

M

1,97

03.

29S

haro

m e

t al.

(198

0)P

lain

field

san

d; 0

.7%

OM

1,97

63.

30W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; la

terit

ic s

oil;

1.62

% O

M

2,05

83.

31S

haro

m e

t al.

(198

0)or

gani

c so

il; 7

5.3%

OM

2,09

03.

32W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; P

okka

li so

il; 5

.52%

OM

2,12

23.

33W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; al

luvi

al s

oil;

0.75

% O

M

K-1

2

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

γ-H

exac

hlo

rocy

clo

hex

ane

58-8

9-9

(con

tinue

d)2,

123

3.33

Wah

id &

Set

huna

than

(19

79)

sing

le m

easu

rem

ent;

Kar

i soi

l; 8.

21%

OM

2,26

03.

35S

penc

er &

Clia

th (

1970

)G

ila s

ilt lo

am; 0

.35%

OC

; fro

m v

apor

pha

se d

esor

p.; 3

0° C

2,26

83.

36A

dam

s &

Li (

1971

)B

lue

Ear

th s

il, B

hor

izon

; fo

c =

0.0

83

2,29

03.

36W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; la

terit

ic s

oil;

0.92

% O

M

2,44

83.

39W

ahid

& S

ethu

nath

an (

1979

)si

ngle

mea

sure

men

t; la

terit

ic s

oil;

0.60

% O

M

2,58

43.

41M

ills

& B

igga

r (1

969a

)11

.9%

OC

; Sta

ten

peat

y m

uck

2,64

63.

42M

iller

& W

eber

(19

86)

Mic

hayw

e so

il; 0

.13%

TO

C

2,71

03.

43M

orea

le &

van

Bla

del (

1978

)Z

olde

r so

il; 0

.19%

OC

; 1%

cla

y

2,92

63.

47W

ahid

& S

ethu

nath

an (

1978

)al

luvi

al s

oil;

0.75

% O

M; 1

:20;

5 m

in e

qulib

ratio

n

2,98

33.

47C

hiou

et a

l. (1

979)

Will

amet

te s

ilt lo

am; 1

.6%

OM

; 26%

cla

y

3,24

93.

51A

dam

s &

Li (

1971

)U

len

sl, B

hor

izon

; fo

c =

0.0

03

Ave

rag

e1,

477

3.17

Geo

met

ric

Mea

n1,

352

3.13

Hex

ach

loro

cycl

op

enta

die

ne

77-4

7-4

Hex

ach

loro

eth

ane

67-7

2-1

Ind

eno

(1,2

,3-c

d)p

yren

e19

3-39

-5

Iso

ph

oro

ne

78-5

9-1

(Iso

octa

phen

one)

Met

ho

xych

lor

72-4

3-5

80,0

004.

90K

aric

khof

f et a

l. (1

979)

avg.

Doe

Run

and

Hic

kory

Hill

coa

rse

silt

sed.

frac

tions

Ave

rag

e80

,000

4.90

Geo

met

ric

Mea

n80

,000

4.90

Met

hyl

bro

mid

e74

-83-

9

(Bro

mom

etha

ne)

90.

95B

riggs

(19

81)

pres

ente

d as

a v

alue

for

seve

ral c

hem

ical

s

Ave

rag

e9

0.95

Geo

met

ric

Mea

n9

0.95

Met

hyl

ch

lori

de

75-0

9-2

(chl

orom

etha

ne)

60.

78Ju

ry e

t al.

(199

0)so

il; s

elec

ted

Ave

rag

e6

0.78

Geo

met

ric

Mea

n6

0.78

Met

hyl

ene

chlo

rid

e75

-09-

2

(Dic

hlor

omet

hane

)10

1.00

Dan

iels

et a

l. (1

985)

sele

cted

Ave

rag

e10

1.00

Geo

met

ric

Mea

n10

1.00

K-1

3

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

Nap

hth

alen

e91

-20-

3

830

2.92

Kis

hi e

t al.

(199

0)lig

ht c

lay;

1.5

1% O

C

843

2.93

Vow

les

& M

anto

ura

(198

7)T

amar

est

uary

sed

imen

t; 4.

02%

OC

; 0.2

% s

ynth

. sea

sal

t

871

2.94

Kar

ickh

off (

1981

)so

ils/s

edim

ents

ave

rage

; sha

ke fl

ask

UV

907

2.96

Sta

uffe

r &

Mac

Inty

re (

1986

)A

ppal

ache

e so

il; 1

.4%

OC

; pH

= 3

.1

912

2.96

Hod

son

& W

illia

ms

(198

8)un

publ

ishe

d ex

perim

enta

l res

ults

by

sam

e au

thor

s

960

2.98

Sou

thw

orth

& K

elle

r (1

986)

Ful

lert

on s

oil;

0.06

% O

C

1,00

03.

00S

outh

wor

th &

Kel

ler

(198

6)A

piso

n so

il; 0

.11%

OC

1,00

03.

00K

an &

Tom

son

(199

0)D

OM

1,09

63.

04M

cCar

thy

& J

imin

ez (

1985

)hu

mic

aci

d po

lym

ers

1,16

13.

06Lo

kke

(198

4)av

g. 1

0 va

lues

1,29

03.

11R

ippe

n et

al.

(198

2)A

lfiso

l; 0.

76%

OC

1,30

03.

11K

aric

khof

f et a

l. (1

979)

aver

age

of D

oe R

un &

Hic

kory

Hill

sed

imen

ts

1,33

33.

12K

aric

khof

f (19

82)

Mis

siss

ippi

Riv

er s

edim

ent;

foc

= 0

.015

1,40

03.

15P

odol

l et a

l. (1

989)

Men

lo P

ark

soil;

1.6

% O

C

1,41

33.

15S

zabo

et a

l. (1

990a

)R

P-H

PLC

on

CIH

AC

(hu

mic

aci

ds)

1,44

03.

16R

ippe

n et

al.

(198

2)E

ntis

ol; 1

.11%

OC

1,44

53.

16S

zabo

et a

l. (1

990a

)R

P-H

PLC

on

PIH

AC

(hu

mic

aci

ds)

1,61

03.

21R

ippe

n et

al.

(198

2)S

peye

r so

il, 0

.15-

0.5

mm

; 1.1

2% O

C

1,86

13.

27B

arre

tt et

al.

(199

4)so

il; 0

.13%

OC

1,95

03.

29W

ood

et a

l. (1

990)

Eus

tis s

and;

0.7

4% O

C; b

atch

& c

olum

n da

ta

Ave

rag

e1,

231

3.09

Geo

met

ric

Mea

n1,

191

3.08

Nit

rob

enze

ne

98-9

5-3

30.6

1.49

Sei

p et

al.

(198

6)fo

rest

soi

l with

0.2

% O

C; c

olum

n st

udy

761.

88W

ilson

et a

l. (1

981)

Linc

oln

sand

; 0.0

87%

OC

861.

93B

riggs

(19

81)

aver

age

for

four

soi

ls; 0

.6-2

.5%

OC

88.8

1.95

Sei

p et

al.

(198

6)ag

ricul

tura

l soi

l with

2.2

% O

C; c

olum

n st

udy

103

2.01

Sei

p et

al.

(198

6)fo

rest

soi

l with

3.7

% O

C; c

olum

n st

udy

142

2.15

Mill

er &

Web

er (

1986

)D

elta

soi

l with

foc

= 0

.001

2

190

2.28

Lokk

e (1

984)

Grib

skov

B h

oriz

on s

oil;

2.58

%O

C; a

vg. 2

val

ues

191

2.28

Wils

on e

t al.

(198

1)Li

ncol

n sa

nd; 0

.087

% O

C

229

2.36

Hod

son

& W

illia

ms

(198

8)un

publ

ishe

d ex

perim

enta

l res

ults

by

sam

e au

thor

s

270

2.43

Lokk

e (1

984)

Grib

skov

C h

oriz

on s

oil;

1.82

%O

C; a

vg. 2

val

ues

Ave

rag

e14

12.

15

Geo

met

ric

Mea

n11

92.

08

Pen

tach

loro

ben

zen

e60

8-93

-5

11,3

814.

06W

u &

Gsc

hwen

d (1

986)

Iow

a so

il; 2

.1%

OC

35,4

554.

55W

u &

Gsc

hwen

d (1

986)

Nor

th R

iver

sed

imen

ts; a

ppro

x. 4

.4%

OC

38,5

604.

59B

arbe

r et

al.

(199

2)sa

nd/g

rave

l aqu

ifer;

avg

, 2 m

easu

rem

ents

; 0.0

54, 0

.062

% O

C

40,0

004.

60K

aric

khof

f & M

orris

(19

85a)

GA

sed

imen

ts; 0

.5-1

.5%

OC

K-1

4

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

Pen

tach

loro

ben

zen

e60

8-93

-5

(con

tinue

d)55

,176

4.74

Wu

& G

schw

end

(198

6)C

harle

s R

iver

sed

imen

ts; a

ppro

x. 8

.5%

OC

Ave

rag

e36

,114

4.56

Geo

met

ric

Mea

n32

,148

4.51

Pyr

ene

129-

00-0

43,8

074.

64M

eans

et a

l. (1

980)

IL s

edim

ent w

ith 2

.38%

OC

(E

PA

-23)

45,7

094.

66A

bdul

et a

l. (1

987)

aqui

fer

mat

eria

l, 1.

05%

OC

48,2

364.

68M

eans

et a

l. (1

980)

IL s

edim

ent w

ith 1

.67%

OC

(E

PA

-22)

50,6

504.

70M

eans

et a

l. (1

980)

ND

sed

imen

t with

2.2

8% O

C (

EP

A-5

)

51,4

694.

71M

eans

et a

l. (1

980)

ND

sed

imen

t with

2.0

7% O

C (

EP

A-4

)

54,7

674.

74W

oodb

urn

et a

l. (1

989)

Web

ster

soi

l; 2.

23%

OC

; 14

C; 3

0:70

met

hano

l:wat

er

57,7

634.

76M

eans

et a

l. (1

980)

WV

soi

l with

0.4

8% O

C (

EP

A-1

4)

58,8

844.

77S

zabo

et a

l. (1

990a

)R

P-H

PLC

on

PIH

AC

(hu

mic

aci

ds)

59,5

154.

77M

eans

et a

l. (1

980)

IL s

edim

ent w

ith 1

.88%

OC

(E

PA

-21)

59,6

464.

78M

eans

et a

l. (1

980)

IL s

oil w

ith 1

.30%

OC

(E

PA

-20)

61,9

364.

79A

bdul

& G

ibso

n (1

986)

Flin

t aqu

ifer

sam

ple;

87%

san

d; fo

c =

0.0

187

62,8

604.

80M

eans

et a

l. (1

980)

GA

sed

imen

t with

1.2

1% O

C (

EP

A-B

2)

63,4

004.

80H

asse

tt et

al.

(198

0)fr

om r

egre

ssio

n of

14

sedi

men

ts/s

oil s

ampl

es

64,7

064.

81M

eans

et a

l. (1

980)

IA lo

ess

with

0.1

1% O

C (

EP

A-9

)

66,0

694.

82S

zabo

et a

l. (1

990a

)R

P-H

PLC

on

CIH

AC

(hu

mic

aci

ds)

67,1

894.

83M

eans

et a

l. (1

980)

IL s

edim

ent w

ith 1

.48%

OC

(E

PA

-26)

67,4

674.

83M

eans

et a

l. (1

980)

IA s

edim

ent w

ith 0

.15%

OC

(E

PA

-8)

67,6

084.

83K

aric

khof

f (19

81)

soils

/sed

imen

ts a

vera

ge

76,3

164.

88M

eans

et a

l. (1

980)

KY

sed

imen

t with

0.6

6% O

C (

EP

A-1

8)

82,4

214.

92M

eans

et a

l. (1

980)

IN s

edim

ent w

ith 0

.95%

OC

(E

PA

-15)

84,0

004.

92K

aric

khof

f et a

l. (1

979)

avg.

Doe

Run

, Hic

kory

Hill

coa

rse

silt

sedi

men

t fra

ctio

ns

84,0

004.

92K

aric

khof

f (19

82)

Mis

siss

ippi

R. s

edim

ent,

1.5%

OC

85,2

564.

93M

eans

et a

l. (1

980)

SD

sed

imen

t with

0.7

2% O

C (

EP

A-6

)

87,8

334.

94K

aric

khof

f & M

orris

(19

85b)

Mis

siss

ippi

R. s

edim

ent,

1.48

% O

C (

deso

rptio

n)

95,3

954.

98K

aric

khof

f & M

orris

(19

85b)

Ohi

o R

. sed

imen

t; 3.

04%

OC

(de

sorp

tion)

131,

325

5.12

Gau

thie

r et

al.

(198

6)flu

ores

c. q

uenc

h. te

ch.;

13 s

oil h

umic

& fu

lvic

aci

ds (

avg.

)

133,

590

5.13

Vow

les

& M

anto

ura

(198

7)T

amar

est

uary

sed

imen

t; 4.

02%

OC

; 0.2

% s

ynth

. sea

sal

t

Ave

rag

e70

,808

4.85

Geo

met

ric

Mea

n67

,992

4.83

Str

yen

e10

0-42

-5

912

2.96

Bed

ient

et a

l. (1

983)

as

cite

d in

Mey

lan

et a

l. (1

992)

ex

perim

enta

l mea

sure

men

t

Ave

rag

e91

22.

96

Geo

met

ric

Mea

n91

22.

96

K-1

5

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

1,1,

2,2-

Tet

rach

loro

eth

ane

79-3

4-5

791.

90C

hiou

et a

l. (1

979)

Will

amet

te s

ilt lo

am; 0

.928

% O

C; 2

0 de

gree

s C

elsi

us

Ave

rag

e79

1.90

Geo

met

ric

Mea

n79

1.90

Tet

rach

loro

eth

ylen

e12

7-18

-4

177

2.25

Sei

p et

al.

(198

6)fo

rest

soi

l with

0.2

% O

C; c

olum

n st

ufy

205

2.31

Sei

p et

al.

(198

6)ag

ricul

tura

l soi

l wtih

2.2

% O

C; c

olum

n st

udy

224

2.35

Sch

war

zenb

ach

& G

iger

(19

82)

as c

ited

in G

erst

l (19

90)

spec

ific

syst

em in

form

atio

n no

t pro

vide

d

224

2.35

Piw

oni &

Ban

erje

e (1

989)

n-

core

sed

imen

t; fo

c =

0.0

133

225

2.35

Wils

on e

t al.

(198

1)Li

ncol

n sa

nd; 0

.087

% O

C

235

2.37

Piw

oni &

Ban

erje

e (1

989)

av

g. 8

val

ues;

J-c

ore

sed.

; foc

= 0

.001

5 -

0.00

89; a

vg. 1

/n>

0.94

237

2.38

Frie

sel e

t al.

(198

4)re

port

ed a

s K

som

; foc

rep

orte

d as

a r

ange

; 32

soils

263

2.42

Abd

ul e

t al.

(198

7)eq

uilib

rium

bat

ch e

xper

imen

ts; a

quife

r m

ater

ial;

foc

= 0

.010

5

268

2.43

Pig

nate

llo (

1990

)A

gaw

am fi

ne s

andy

loam

soi

l; 2

.57%

OC

; avg

. 2 v

alue

s

269

2.43

Bru

ssea

u &

Rao

(19

91)

Tam

pa s

andy

aqu

ifer

mat

eria

l; 0.

13%

OC

; < 2

mm

311

2.49

Loch

et a

l. (1

986)

top

20 c

m o

f Pod

zol s

oil;

0.87

% O

C

348

2.54

Sei

p et

al.

(198

6)fo

rest

soi

l with

3.7

% O

C; c

olum

n st

udy

356

2.55

Pav

iost

athi

s &

Mat

hava

n (1

992)

coar

se s

and

with

0.0

9% O

C

362

2.56

Chi

ou e

t al.

(197

9)W

illam

ette

silt

loam

; 0.9

3% O

C; 2

0 de

gree

s C

elsi

us

373

2.57

Sch

war

zenb

ach

& W

esta

ll (1

981)

avg.

of 6

mea

s. w

/ diff

eren

t Co

& s

orbe

nts;

0.1

5% O

C

Ave

rag

e27

22.

43

Geo

met

ric

Mea

n26

52.

42

To

luen

e10

8-88

-3

94.4

1.97

Sei

p et

al.

(198

6)ag

ricul

tura

l soi

l wtih

2.2

% O

C; c

olum

n st

udy

992.

00V

owle

s &

Man

tour

a (1

987)

Tam

ar e

stua

ry s

edim

ent;

4.02

% O

C; 0

.2%

syn

th. s

ea s

alt

115

2.06

Abd

ul e

t al.

(198

7)eq

uilib

rium

bat

ch e

xper

imen

ts, a

quife

r m

ater

ial;

foc

= 0

.010

5

123

2.09

Gar

barin

i & L

ion

(198

6)ze

in; 5

7% O

C

126

2.10

Sza

bo e

t al.

(199

0a)

RP

-HP

LC o

n P

IHA

C (

avg.

, hum

ic a

cids

)

134

2.13

Sei

p et

al.

(198

6)fo

rest

soi

l with

3.7

% O

C; c

olum

n st

udy

150

2.18

Wils

on e

t al.

(198

1)Li

ncol

n sa

nd; 0

.087

% O

C

151

2.18

Gar

barin

i & L

ion

(198

6)S

apsu

cker

Woo

ds s

oil w

ith 7

.51%

C

151

2.18

Gar

barin

i & L

ion

(198

6)lig

nin;

65%

OC

164

2.21

Gar

barin

i & L

ion

(198

6)S

apsu

cker

Woo

ds e

ther

ext

ract

ed s

oil w

ith 7

.05%

C

182

2.26

Sza

bo e

t al.

(199

0a)

RP

-HP

LC o

n C

IHA

C (

avg.

, hum

ic a

cids

)

247

2.39

Sch

war

zenb

ach

& W

esta

ll (1

981)

avg.

of 6

mea

s. w

/ diff

eren

t Co

& s

orbe

nts;

0.1

5% O

C

Ave

rag

e14

52.

16

Geo

met

ric

Mea

n14

02.

15

K-1

6

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

To

xap

hen

e80

01-3

5-2

95,8

164.

98G

usta

fson

(19

89)

aver

age

valu

e fr

om c

olle

cted

mea

sure

d va

lues

Ave

rag

e95

,816

4.98

Geo

met

ric

Mea

n95

,816

4.98

1,2,

4-T

rich

loro

ben

zen

e12

0-82

-1

864

2.94

Chi

ou e

t al.

(198

3)W

oodb

urn

silt

loam

; fom

= 0

.019

; 21%

cla

y

885

2.95

Sou

thw

orth

& K

elle

r (1

986)

Dor

mon

t soi

l; 1.

2% O

C

1,03

33.

01S

cheu

nert

et a

l. (1

994)

soil;

2.0

6% O

C

1,30

03.

11S

outh

wor

th &

Kel

ler

(198

6)F

ulle

rton

soi

l; 0.

06%

OC

1,30

33.

11B

aner

jee

et a

l. (1

985)

aver

age

of 2

1 va

lues

; sub

surf

ace

allu

vial

soi

l

1,38

93.

14W

ilson

et a

l. (1

981)

av

erag

e of

two

valu

es

1,43

53.

16F

riese

l et a

l. (1

984)

peat

y so

il; 0

.29%

OM

1,44

13.

16F

riese

l et a

l. (1

984)

repo

rted

as

Kso

m; f

oc r

epor

ted

as a

ran

ge

1,55

43.

19Le

e et

al.

(198

9)un

trea

ted

Mar

lette

soi

l, A

hor

izon

; 2.5

9% O

C

1,86

73.

27Le

e et

al.

(198

9)un

trea

ted

Mar

lette

soi

l, B

t hor

izon

; 0.3

% O

C

1,98

63.

30S

chw

arze

nbac

h &

Wes

tall

(198

1)K

S1

field

mat

eria

l; fo

c =

0.0

073

1,99

53.

30S

chw

arze

nbac

h &

Gig

er (

1982

) as

cite

d in

Ger

stl (

1990

)sy

stem

spe

cific

info

rmat

ion

not p

rovi

ded

2,10

03.

32S

outh

wor

th &

Kel

ler

(198

6)A

piso

n so

il w

ith 0

.11%

OC

2,34

73.

37S

chw

arze

nbac

h &

Wes

tall

(198

1)av

g. o

f 6 m

eas.

w/ d

iffer

ent C

o &

sor

bent

s; 0

.15%

OC

2,57

03.

41S

chw

arze

nbac

h &

Gig

er (

1982

) as

cite

d in

Ger

stl (

1990

) sy

stem

spe

cific

info

rmat

ion

not p

rovi

ded

3,11

83.

49W

u &

Gsc

hwen

d (1

986)

Cha

rles

Riv

er s

edim

ent w

ith a

ppro

xim

atel

y 8.

8% O

C

3,12

53.

49S

chw

arze

nbac

h &

Wes

tall

(198

1)fie

ld s

ampl

e; 0

.8%

OC

Ave

rag

e1,

783

3.25

Geo

met

ric

Mea

n1,

659

3.22

1,1,

1-T

rich

loro

eth

ane

71-5

5-6

105.

92.

02Lo

ch e

t al.

(198

6)to

p 20

cm

of E

erd

soil;

4%

OC

107

2.03

Frie

sel e

t al.

(198

4)re

port

ed a

s K

som

; foc

rep

orte

d as

a r

ange

129

2.11

Hod

son

& W

illia

ms

(198

8)cy

anop

ropy

l col

umn,

HP

LC

172

2.24

Loch

et a

l. (1

986)

top

20 c

m o

f Pod

zol s

oil;

0.87

% O

C

179

2.25

Chi

ou e

t al.

(197

9)W

illam

ette

silt

loam

; 0.9

3% O

C; 3

.5 d

egre

es C

elsi

us

Ave

rag

e13

92.

14

Geo

met

ric

Mea

n13

52.

13

1,1,

2-T

rich

loro

eth

ane

79-0

0-5

60.0

1.78

Sei

p et

al.

(198

6)fo

rest

soi

l with

0.2

% O

C; c

olum

n st

udy

63.7

1.80

Sei

p et

al.

(198

6)ag

ricul

tura

l soi

l wtih

2.2

% O

C; c

olum

n st

udy

761.

88W

ilson

et a

l. (1

981)

Linc

oln

sand

; 0.0

87%

OC

108

2.03

Sei

p et

al.

(198

6)fo

rest

soi

l with

3.7

% O

C; c

olum

n st

udy

Ave

rag

e77

1.89

Geo

met

ric

Mea

n75

1.87

K-1

7

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

Tri

chlo

roet

hyl

ene

79-0

1-6

571.

76R

uthe

rfor

d &

Chi

ou (

1992

)pe

at; 5

7% O

C

631.

80S

mith

et a

l. (1

990)

so

il; 4

.02%

OC

(fr

om v

apor

pha

se e

xper

imen

ts)

651.

81A

bdul

et a

l. (1

987)

equi

libriu

m b

atch

exp

erim

ents

; aqu

ifer

mat

eria

l; fo

c =

0.0

105

691.

84B

russ

eau

& R

ao (

1991

)T

ampa

san

dy a

quife

r m

ater

ial;

0.13

% O

C; <

2m

m

72.5

1.86

Sei

p et

al.

(198

6)fo

rest

soi

l with

0.2

% O

C; c

olum

n st

udy

841.

92S

tauf

fer

& M

acIn

tyre

(19

86)

App

alac

hee

soil;

1.4

% O

C; p

H =

3.2

841.

93P

iwon

i & B

aner

jee

(198

9)

aqui

fer

solid

; 0.1

9% O

C

871.

94R

oger

s &

McF

arla

ne (

1981

)O

vert

on s

ilty

clay

loam

; foc

=0.

018;

1/n

=0.

93

921.

96W

ilson

et a

l. (1

981)

Linc

oln

sand

; 0.0

87%

OC

95.8

1.98

Sei

p et

al.

(198

6)ag

ricul

tura

l soi

l wtih

2.2

% O

C; c

olum

n st

udy

992.

00P

igna

tello

(19

90a)

Aga

wam

soi

l; 2.

57%

OC

(2

valu

es)

100

2.00

Dou

st &

Hua

ng (

1992

) as

cite

d in

Mac

kay

et a

l. (1

993)

orga

nic

carb

on s

oil

101

2.00

Frie

sel e

t al.

(198

4)re

port

ed a

s K

om; f

oc r

epor

ted

as a

ran

ge; 3

2 so

ils

103

2.01

Loch

et a

l. (1

986)

top

20 c

m o

f Eer

d so

il; 4

% O

C

106

2.03

Gar

barin

i & L

ion

(198

6)S

apsu

cker

Woo

ds s

oil w

ith 7

.51%

C

111

2.05

Gar

barin

i & L

ion

(198

6)ze

in; 5

7% O

C

120

2.08

Gar

barin

i & L

ion

(198

6)lig

nin;

65%

OC

122

2.09

Gar

barin

i & L

ion

(198

6)sa

psuc

ker

woo

ds e

ther

ext

ract

ed s

oil;

7.05

% O

C

123

2.09

Hut

zler

et a

l. (1

986)

colu

mn;

Kew

eena

w 7

soi

l; 0.

85%

OC

(av

g. 3

val

ues)

142

2.15

Sei

p et

al.

(198

6)fo

rest

soi

l with

3.7

% O

C; c

olum

n st

udy

150

2.17

Rog

ers

& M

cFar

lane

(19

81)

Has

tings

silt

y cl

ay lo

am; f

oc =

0.0

26; F

reun

dlic

h; 1

/n =

0.8

2

Ave

rag

e97

1.99

Geo

met

ric

Mea

n94

1.97

Vin

yl c

hlo

rid

e75

-01-

4

o-X

ylen

e95

-47-

6

222

2.35

Vow

les

& M

anto

ura

(198

7)T

amar

est

uary

sed

imen

t; 4.

02%

OC

; 0.2

% s

ynth

. sea

sal

t

234

2.37

Sza

bo e

t al.

(199

0a)

RP

-HP

LC, C

IHA

C (

hum

ic a

cids

)

251

2.40

Sza

bo e

t al.

(199

0a)

RP

-HP

LC, P

IHA

C (

hum

ic a

cids

)

258

2.41

Roy

et a

l. (1

987)

Cat

lin s

orbe

nt a

t 23

degr

ees

Cel

sius

; 4.0

4% O

C

Ave

rag

e24

12.

38

Geo

met

ric

Mea

n24

12.

38

m-X

ylen

e10

8-38

-3

158

2.20

Sei

p et

al.

(198

6)ag

ricul

tura

l soi

l with

2.2

% O

C; c

olum

n st

udy

166

2.22

Abd

ul e

t al.

(198

7)eq

uilib

rium

bat

ch e

xper

imen

ts; a

quife

r m

ater

ial;

foc

= 0

.010

5

289

2.46

Sei

p et

al.

(198

6)fo

rest

soi

l; 3.

7% O

C; c

olum

n st

udy

Ave

rag

e20

42.

31

Geo

met

ric

Mea

n19

62.

29

K-1

8

Tab

le K

-2. C

olle

cted

Ko

c Val

ues

(H

ydro

ph

ob

ic O

rgan

ics)

Ch

emic

alC

AS

No

.K

oc

(L/k

g)

Lo

g K

oc

So

urc

eC

om

men

ts

p-X

ylen

e10

6-42

-3

260

2.41

Vow

les

& M

anto

ura

(198

7)T

amar

est

uary

sed

.; 4.

02%

OC

; 0.2

% s

ynth

etic

sea

sal

t

333

2.52

Sch

war

zenb

ach

& W

esta

ll (1

984)

soil;

0.1

5% O

C; a

vg. 6

val

ues

347

2.54

Sch

war

zenb

ach

& G

iger

(19

82)

as c

ited

in G

erst

l (19

90)

syst

em s

peci

fic in

form

atio

n no

t pro

vide

d

Ave

rag

e31

32.

50

Geo

met

ric

Mea

n31

12.

49

K-1

9

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K-21

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K-22

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K-23

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K-24

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