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Appendix M Aquitard K v literature review
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  • Appendix M Aquitard Kv literature review

  • International Aquitard Vertical Hydraulic Conductivity Review Report for Queensland Gas Company

    Final 1

    17 April 2012

  • The SKM logo trade mark is a registered trade mark of Sinclair Knight Merz Pty Ltd.

    International Aquitard Vertical Hydraulic Conductivity Review

    Final 1

    17 April 2012

    Sinclair Knight Merz ABN 37 001 024 095 Floor 11, 452 Flinders Street Melbourne VIC 3000 PO Box 312, Flinders Lane Melbourne VIC 8009 Australia Tel: +61 3 8668 3000 Fax: +61 3 8668 3001 Web: www.globalskm.com

    COPYRIGHT: The concepts and information contained in this document are the property of Sinclair Knight Merz Pty Ltd. Use or copying of this document in whole or in part without the written permission of Sinclair Knight Merz constitutes an infringement of copyright.

    LIMITATION: This report has been prepared on behalf of and for the exclusive use of Sinclair Knight Merz Pty Ltd’s Client, and is subject to and issued in connection with the provisions of the agreement between Sinclair Knight Merz and its Client. Sinclair Knight Merz accepts no liability or responsibility whatsoever for or in respect of any use of or reliance upon this report by any third party.

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

    SINCLAIR KNIGHT MERZ

    T:\Projects\Groundwater Management\Stage 2 CSG WMMP\FINAL APPENDICIES\Appendix M - Aquitard kv_literature review_final1.docx PAGE i

    Contents

    1. Introduction 3

    2. Terminology 4

    3. Objective 6

    4. Surat Basin Conceptualisation 7

    4.1. Regional Geological Setting 7

    4.2. Hydrogeology 10

    4.2.1. Major aquifers and aquitards 10

    4.2.2. Vertical Hydraulic properties 10

    5. Method 13

    5.1. Data Search 13

    5.2. Data Compilation 13

    5.3. Permeability and hydraulic conductivity 14

    6. Results 15

    6.1. Distribution of Kv’ 15

    6.2. Comparison of Kv’ and K 16

    6.3. Effect of lithology on Kv’ 17

    6.4. Effect of data source on Kv’ 21

    7. Discussion 23

    7.1. Effect of test methods on Kv’ 23

    7.1.1. Laboratory tests 23

    7.1.2. Field tests 24

    7.1.3. Conductivity estimated from models 25

    7.2. Effect of discontinuities, bores, and multiphases on Kv’ 26

    7.2.1. Discontinuities (joints, fractures, and faults) 26

    7.2.2. Bores 27

    7.2.3. Multiphase conductivity 29

    8. Conclusions 31

    9. References 33

    Appendix A Documents consulted 36

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

    SINCLAIR KNIGHT MERZ

    T:\Projects\Groundwater Management\Stage 2 CSG WMMP\FINAL APPENDICIES\Appendix M - Aquitard kv_literature review_final1.docx PAGE 1

    Executive Summary

    An international literature review of 180 published papers has investigated the range of vertical

    hydraulic conductivity (Kv’) for aquitards in sedimentary basins with lithology similar to those

    encountered in the Surat Basin, such as sandstone, silt, siltstone, mudstone, clay, claystone and

    shale.

    The international literature review showed that around the world, the range of measured or

    estimated vertical hydraulic conductivities of sedimentary facies typical of the Surat Basin is

    extremely wide, ranging between 1 x 10-12

    m/day (1 x 10-9

    mD) and 3 m/day (3 x 10+3

    mD).

    The results of the literature review are summarised in the following table:

    Median of lower values

    Median of upper values

    All lithologies (sandstone, coal, silt, siltstone, mudstone, clay, claystone,

    shale)

    All methods (285 citations)

    10-5

    m/day (10

    -2 mD)

    5 x 10

    -4 m/day

    (0.5 mD)

    Fine grained lithology (mudstone, clay, claystone, shale)

    All methods (193 citations)

    10-6

    m/day (10

    -3 mD)

    2 x 10-5

    m/day (2 x 10

    -2 mD)

    Laboratory tests (47 citations)

    10-8

    m/day (10

    -5 mD)

    4 x 10-7

    m/day (4 x 10

    -4 mD)

    Field Tests (45 citations)

    4 x 10-5

    m/day (4 x 10

    -2 mD)

    10-3

    m/day (1 mD)

    Field measurements are shown to yield systematically higher values of Kv’ (of approximately three

    orders of magnitude) than laboratory testing of core samples. It is fair to assume that a large

    proportion of field values collected in this review will contain results that are derived from shallow

    depths (because many more tests will have been undertaken at shallow depths). It should also be

    noted that as depth of burial increases, hydraulic conductivity typically decreases. These values

    therefore may not be as representative of aquitards that are located at large depths.

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

    SINCLAIR KNIGHT MERZ

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    Rock defects were shown to have a significant impact on regional Kv’. A simple set of vertical

    non-intersecting vertical fractures of 0.1 mm (100 μm) openings spaced every 10km in a virtually

    impervious matrix results in a regional Kv’ of 5.8 x 10-3

    mD (5 x 10-6

    m/day). Poorly constructed,

    poorly decommissioned, abandoned or failed bores or those screened across multiple units, could

    be considered to have a similar impact on regional Kv’ as those caused by rock defects.

    The median Kv’ value of 1 x 10-3

    mD (1 x 10-6

    m/day) used in the GEN 2 model would appear to

    be reasonable. However, the upper bound of the Kv’ range used in the GEN 2 groundwater model

    (5 x 10-6

    m/day) may be too low if the aquitard is fractured or contains poorly constructed bores.

    The lower value of the range (5 x 10-7

    m/day) can be regarded as appropriate.

    Notes:

    In the literature, hydraulic conductivities are reported in a large variety of forms. Some articles

    provide single hydraulic conductivity estimation while most provide ranges of values. Single

    values were considered as a range whose lower and upper values were equal. Therefore, hydraulic

    conductivities are reported by two distributions: the first is constituted by the lower values of the

    ranges and the second by the upper value of the reported ranges. The ―median of lower values‖ is

    the median of the first distribution (i.e. all the ranges lower values) and the ―median of upper

    values‖ is the median of the second distribution (i.e. all the ranges upper values).

    Laboratory tests are reported regardless of the methodology used. It is important to note that

    the methodology (particularly whether it is a permeability to gas or to water) yields outputs

    that can range over 1 order of magnitude for the same samples.

    Values were rounded to 1 significant figure and the conversion factor used in this document is

    1mD = 10-3

    m/day.

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

    SINCLAIR KNIGHT MERZ

    T:\Projects\Groundwater Management\Stage 2 CSG WMMP\FINAL APPENDICIES\Appendix M - Aquitard kv_literature review_final1.docx PAGE 3

    1. Introduction

    Extraction of gas and water from the Walloon Coal Measures (WCM) will result in pressure

    changes within this unit and has the potential induce vertical leakage from overlying and/or

    underlying units. The amount and rate of potential leakage is predicted in the GEN2 model

    (Golder Associates, 2011) to be small and the effects relatively localised. It is recognised,

    however, that the model is based on assumed hydraulic properties, albeit a broad range.

    Queensland Gas Corporation’s (QGC’s) Connectivity Programme (QGC, 2011) is designed to

    provide much greater confidence in the predicted hydraulic impacts of pumping from the WCM.

    The objectives of the Connectivity Programme are to:

    1. Develop a scientifically robust and defensible understanding of the nature of the vertical

    leakage induced by CSG development across the QGC tenements and adjacent areas

    2. Demonstrate, through a comprehensive monitoring programme, the nature of the vertical

    leakage

    3. Characterise the key factors, both natural and anthropogenic, affecting vertical leakage

    4. Characterise the spatial and temporal variation in vertical leakage

    5. Identify any risks associated with unacceptable vertical leakage and develop response plans

    for any risks

    6. Develop a detailed understanding of the potential for extraction from the WCM on QGC

    leases to affect vertical leakage from the Condamine alluvium.

    The studies proposed to be undertaken to determine the hydraulic connectivity between the WCM

    and the overlying and underlying aquifers, the leakage rates in and out of these aquifers and the

    resulting impacts, are summarised in the Stage 1 CSG Water Monitoring and Management Plan

    (WMMP).

    This report presents the findings of the first task in the Stage 1 WMMP, Aquitard Vertical

    Hydraulic Conductivity Review section.

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

    SINCLAIR KNIGHT MERZ

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    2. Terminology

    Aquifer Geological formation that comprises materials that have a moderate to high hydraulic

    conductivity. Water supply wells are usually sunk into aquifers because the high

    hydraulic conductivity enables moderate to high pumping rates

    Aquitard Geological formation that comprises materials that have a low hydraulic conductivity.

    Water supply wells are not usually sunk into aquitards because the low hydraulic

    conductivity enables only low pumping rates

    Intrinsic

    permeability (k)

    Intrinsic permeability is the portion of hydraulic conductivity which is representative of

    the properties of the porous medium (not the fluid) and is a function of the size of the

    openings through which the fluid moves

    k = C d2 (dimensions are L

    2 or Area)

    C = dimensionless constant

    d = mean pore diameter

    dimensions are L2 or Area

    Relationship between hydraulic conductivity and intrinsic permeability is K = k (ρg/µ)

    ρ = density of fluid (g/cm3)

    µ = dynamic viscosity of fluid

    density units = g/cm3

    viscosity units = centipoise

    1 centipoise = 0.01 g/(cm sec)

    g = acceleration constant due to gravity = 9.80665 m/s2

    Hydraulic

    conductivity

    (K)

    Hydraulic Conductivity is a term used for permeability of geologic material to water flow

    K =Q/Ai (dimensions are L/T)

    Q = discharge (L3/T)

    A = cross sectional area of groundwater flow (L2)

    i = groundwater gradient (L/L)

    Kv vertical hydraulic conductivity of an aquifer

    Kv’ vertical hydraulic conductivity of an aquitard

    Kh horizontal hydraulic conductivity of an aquifer

    Kh’ horizontal hydraulic conductivity of an aquitard

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

    SINCLAIR KNIGHT MERZ

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    Millidarcy

    (mD)

    Intrinsic permeability (1 mD = 8.64 x 10-4

    m/day).

    m/day Hydraulic conductivity (1 m/day = 1,157.4 mD)

    L/sec litres per second

    a x 10-n scientific notation equivalent to a x 10-n

    aE-N scientific notation equivalent to a x 10-n

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

    SINCLAIR KNIGHT MERZ

    T:\Projects\Groundwater Management\Stage 2 CSG WMMP\FINAL APPENDICIES\Appendix M - Aquitard kv_literature review_final1.docx PAGE 6

    3. Objective

    The purpose of this project is to search international literature for documented values of vertical

    conductivities related to leakage in confined aquifers, including existing CSG fields in North

    America, Asia and Europe, major groundwater basins and geothermal fields. The literature search

    aimed to identify the bounds (absolute minimal and maximal values) of vertical hydraulic

    conductivities (i.e. coefficient of permeability) of aquitards overlying and underlying the producing

    aquifer. It aimed to identify most likely values of vertical hydraulic conductivities for lithologies

    comparable to the Surat Basin. It also aimed to document the main criteria controlling vertical

    conductivities in order to provide some insight in the Surat Basin vertical hydraulic conductivities.

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

    SINCLAIR KNIGHT MERZ

    T:\Projects\Groundwater Management\Stage 2 CSG WMMP\FINAL APPENDICIES\Appendix M - Aquitard kv_literature review_final1.docx PAGE 7

    4. Surat Basin Conceptualisation

    The geological setting of the Surat Basin has been described in detail in various previous QGC

    reports, notably in the groundwater impact assessment report for the Queensland Curtis Liquefied

    Natural Gas QCLNG (Golder Associates, 2011), from which most of the information below has

    been sourced.

    4.1. Regional Geological Setting

    The Surat Basin is a sub-basin of the GAB, located across central southern Queensland and central

    northern New South Wales (Figure 1). The Surat Basin is a complex multilayered sedimentary

    sequence of fluvially deposited sandstone units interspersed with marginal-marine mudstone and

    siltstone units. The GAB basin sediments extend to more than 3,000m in thickness, but the coal

    measures targeted by the CSG extraction are generally at depth less than 1,200m. Figure 1

    summarises the representative stratigraphic column of the Surat Basin units at QGC tenements. The

    coal seams within the WCM unit are not present as laterally continuous seams or layers but as

    numerous thin, disconnected coal plies in a matrix of generally low permeability sediments (Figure

    2). The coal seams comprise 10% to 15% of the full thickness of the WCM and include up to 40 to

    45 laterally discontinuous individual coal seams of varying thicknesses, extent and variable

    permeability. These are the layers which are targeted for their CSG resource. The coal is

    interbedded with shales, siltstones and mudstones, which comprise 85% to 90% of the full

    thickness of the WCM.

    Structurally, the lithological units are continuous across large areas within the basin although some

    faulting, capable of locally displacing or disconnecting aquifers, is present. It has been suggested

    that such faults can act as preferential permeable zones or alternatively as impermeable barriers to

    groundwater movement (Habermehl, 2002 cited in WorleyParsons 2010). The sediments often dip

    in a south-westerly direction. The WCM, outcropping on the eastern side of the basin, are found at

    depths ranging from 100m to 800m along QGC tenements (Figure 3).

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

    SINCLAIR KNIGHT MERZ

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    Figure 1. Surat Basin location (from QGC 2011)

    Table 1. Lithology characteristics and hydrogeological role of the main units

    Formation Dominant

    behaviour

    Lithology

    Mooga

    Sandstone

    Aquifer Fluvial quartzose sandstone with thinly interbedded mudstone and

    siltstone

    Orallo

    Formation

    Confining Medium to coarse grained sandstone interbedded with

    carbonaceous siltstone, silty mudstone, tuffs and coals

    Gubberamunda Aquifer Medium to coarse grained quartz rich sandstone interbedded with

    fine grained sandstone, siltstone and shale

    Westbourne

    Formation

    Confining Interbedded shales, silstones and fine grained sandstone

    Springbok

    Sandstone

    Poor Aquifer Sandstone, interbedded with carbonaceous siltstones, mudstone,

    tuff and occasional coal beds

    Walloon Coal

    Measures

    Coal measures Coal seams interbedded with shale, siltstone and mudstone

    Confining layers Sandstone, siltstone and mudstone with high clay content.

    Durabilla

    Formation

    Confining Fine to coarse grained sandstone interbedded with siltstone and

    mudstone

    Hutton

    Sandstone

    Aquifer Fluvial sandstone beds with minor thin conglomerate beds,

    interbedded silts, and beds of mudstone rich in clay

    Evergreen

    Formation

    Confining Thinly bedded mudstone, siltstone and sandstone intervals

    Precipice

    Sandstone

    Aquifer Fine to coarse quartzose sandstone. Minor siltstone and clay matrix.

    Bowen Basin

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

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    Figure 2. Coal Seam distribution within WCM

    Figure 3. Schematic north-east to south-west cross section of the Surat Basin (from University of Southern Queensland, 2011)

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

    SINCLAIR KNIGHT MERZ

    T:\Projects\Groundwater Management\Stage 2 CSG WMMP\FINAL APPENDICIES\Appendix M - Aquitard kv_literature review_final1.docx PAGE 10

    4.2. Hydrogeology

    4.2.1. Major aquifers and aquitards

    As illustrated on Table 1, most formations within the Surat Basin comprise interbedded sandstone,

    siltstone and mudstone. The formations that are dominated by Sandstones form the main aquifers,

    with the aquitards dominated by shales, mudstones and siltstones. Due to the interbedded nature

    within the formations, significant variability of hydraulic conductivity would be expected to occur

    within each aquifer and aquitard. This variability may be greater within an aquifer or aquitard than

    between aquifers and aquitards. For conceptualisation purposes and subsequent numerical

    modelling, every unit was classified (Golder Associates, 2011) into aquifer and aquitard units

    according to its most representative facies. The hydrogeological role played by each unit are

    summarised in Table 1. The Surat Basin deposits can then be conceptualised by 5 main aquifers

    (Mooga Sandstone, Gubberamunda, Springbok, Hutton, Precipice) separated by as many aquitard

    (Orrallo, Westbourne, Durabilla, Evergeen formations). The WCM is also considered as an

    aquitard despite the aquifer properties of the coal seams.

    4.2.2. Vertical Hydraulic properties

    According to Habermehl (2002, quoted in Worley Parsons, 2010) the representative horizontal

    hydraulic conductivity for the GAB aquifers ranges from 0.1 to 10m/day (1 x 102 to 1.2 x 10

    4 mD),

    while the average vertical hydraulic conductivities for the leaky, low permeability, confining beds

    range from 1 x 10-4

    m/day to 1 x 10-1

    m/day (0.12 to 120 mD).

    Routine core analyses carried out on Walloon Coal Measure sediments from a range of wells across

    the QGC tenements in the Surat Basin provide a range of hydraulic conductivities as summarised in

    Table 2. All measurements were carried out at overburden pressure. Both vertical and horizontal

    hydraulic conductivities show variation in hydraulic conductivities ranging over several order of

    magnitudes. Downhole field estimates provide higher conductivities than laboratory core analyses.

    This database formed a source of information upon which the hydraulic conductivities of the GEN2

    numerical model were determined. The range of values used in the GEN2 model are summarised in

    Table 3.

    The University of Southern Queensland, in an attempt to assess the cumulative impacts in the Surat

    Basin associated with the coal seam gas industry ( University of Southern Queensland, 2011), has

    done a comparative study of hydraulic conductivities used in groundwater numerical models

    among the four main CSG companies. Even though hydraulic conductivity values used in the four

    models are mostly consistent, they vary by several orders of magnitude between models and up to 5

    orders of magnitude for the Evergreen Formation. This emphasizes the difficulty in accurately

    assessing hydraulic conductivities. The reason may be partly due to the lack of test results for some

    of the units, but even results for well documented units such as the WCM are also spread over

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

    SINCLAIR KNIGHT MERZ

    T:\Projects\Groundwater Management\Stage 2 CSG WMMP\FINAL APPENDICIES\Appendix M - Aquitard kv_literature review_final1.docx PAGE 11

    several orders of magnitude. Well documented units are usually based on laboratory core sampling,

    which do not account for rock fractures that are important to regional flow. Aquifer hydraulic tests

    are often conducted over a too short a period to induce vertical flow through aquitards and obtain

    estimates of vertical conductivity.

    Table 2. QGC WCM hydraulic conductivity test results

    Test method Lithology

    Horizontal intrinsic

    permeability and hydraulic

    conductivity

    Vertical intrinsic

    permeability and hydraulic

    conductivity

    [mD] [m/day] [mD] [m/day]

    Laboratory

    core testing

    Sandstone and

    siltstones 0.01 to 128

    8.6 x 10-6

    to

    1.1 x 10-1

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

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    Impacts, as identified by the numerical groundwater model (GEN2 in Golder Associates 2011), are

    sensitive to hydraulic conductivity parameters and particularly for the vertical hydraulic

    conductivity of confining layers separating pumped coal seams and GAB aquifers. The large

    uncertainty associated with these parameters reduces the confidence of the potential impacts. The

    current study aims at determining the extent to which this uncertainty can be reduced.

  • Aquitard Vertical Hydraulic Conductivity Review and Analysis

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    T:\Projects\Groundwater Management\Stage 2 CSG WMMP\FINAL APPENDICIES\Appendix M - Aquitard kv_literature review_final1.docx PAGE 13

    5. Method

    5.1. Data Search

    A review of existing literature and information on vertical hydraulic conductivity and leakage rates

    for aquitards within major fractured rock and sedimentary basins throughout the world was

    undertaken using the Science Direct On-line Reference Database and Willey Online Library.

    Google and Google Scholar search engines were also used to search relevant literature. The search

    was implemented by using either separately, or in combination, the following key words: Vertical

    hydraulic conductivity, permeability, aquitard, coal seam gas, coal seam gas impacts, shale, clay,

    mudstone, coal, siltstone, sandstones, Surat Basin, Bowen Basin, Shale gas, shale gas impact,

    Barnett shale, Marcellus shale, Utica, geological nuclear waste management, etc.

    After, collecting relevant articles some extended literature was researched using the references

    quoted in articles, or by using search engines to search literature from authors identified as being

    specialists on the hydrogeology of aquitards, such as C.E. Neuzil.

    To manage the volume of material to be reviewed, emphasis was placed on major journals (e.g.

    Groundwater). Relevant information quoted on free access abstracts was also considered.

    Although the amount of reference material that could be obtained and reviewed is limited by the

    timeframe for the study, a substantial resource comprising 180 references was compiled. The

    documents consulted are referenced in Appendix A.

    5.2. Data Compilation

    In the literature, hydraulic conductivities are reported in a large variety of forms and units. The

    reported hydraulic conductivities were obtained by a large variety of means, including several

    laboratory techniques, field experiments, derived from modelling, or simply stated without

    reference. They refer to various scales, ranging from decimetre large core samples to regional

    aquitards comprising several stratigraphic units. Lithological descriptions of a single unit for which

    a value of hydraulic conductivity is provided can also be very detailed (e.g. Fluvial sandstone beds

    with minor thin conglomerate beds, interbedded silts, and beds of mudstone rich in clay) and such a

    detailed description cannot be practically kept for a statistical analysis of hydraulic conductivity

    references as it would generate as many categories as there are references. Consequently, for the

    scope of this study it was necessary to group the references into explicit categories. Lithology was

    grouped into the following six categories: clay, coal, mudstone, sandstone, shale and silt &

    siltstone. For a complex lithological description the main lithology was adopted when it was clearly

    stated; otherwise the lithology corresponding to the finest grain size was considered (e.g. the Kv’

    for the unit given above as an example would then be put in the ―sandstone‖ category).

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    Results were categorised as ―laboratory‖, ―model‖ or ―field‖ obtained values irrespective of the

    laboratory, modelling, or field testing methods used. Articles or book extracts referring to ranges of

    conductivities without providing details on how the values were obtained were labelled ―text

    book‖.

    Some documents provide a range of values as they refer to several laboratory tested samples, or to

    the uncertainty of the Kv’ estimation determined from field methods, whereas other articles provide

    only a single value (which could be the average or the median value of a sample). So as not to

    exclude any information, the distinction between Kv’ min and Kv’ max was retained and articles

    providing single Kv’ values were given a Kv’ min and Kv’ max equal to that value.

    Many references mentioned hydraulic conductivity (K) without discriminating between vertical

    (Kv’) and horizontal conductivity (Kh’). References that did not make this distinction were

    included if the material was considered relevant to this study. Thus in the collected literature, 132

    references to vertical hydraulic conductivity were considered, along with 159 references to

    hydraulic conductivity alone (i.e. where hydraulic conductivity was not categorised as horizontal or

    vertical).

    It is widely recognised that, due to the nature of sediment deposition and diagenesis, horizontal

    conductivity can be up to several order of magnitude larger than vertical conductivity. Including

    values of K in this study, which focuses on estimation of Kv’, would not underestimate Kv’ but

    could potentially lead to an overestimation of the upper end of Kv’.

    5.3. Permeability and hydraulic conductivity

    It is important also to emphasize that permeability is an intrinsic property of a rock regardless of

    the fluid (gas or liquid) flowing through it, and hydraulic conductivity characterises both the rock

    and the viscosity of the fluid. Hydrogeologists tend to consider hydraulic conductivity to water

    (expressed in m/day) while petrophysicists consider the intrinsic permeability expressed in

    millidarcy (mD) which are usually measured on core sample with gas. The Darcy (and

    consequently MilliDarcy) is not an SI (International System of Units). A medium with a

    permeability of 1 Darcy permits a flow of 1 cm/sec of a fluid with a viscosity of 1 centipoise under

    a pressure gradient of 1 atmosphere/cm. To convert to equivalent values of hydraulic conductivity

    for water at 20ºC and at normal atmospheric conditions 1mD = 8.64 x 10-4

    m/day and inversely,

    1m/day = 1,157.4 mD. However, in this report, using that conversion factor, all units are presented

    both in terms of hydraulic conductivity using units of m/day, and in terms of permeability using the

    Millidarcy. Values were rounded to two significant figures.

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    6. Results

    6.1. Distribution of Kv’

    The distribution of all the data obtained from the literature review are presented in Figure 4. This

    shows there is significant overlap between the minimum and maximum Kv’ values. The upper and

    lower bound values of the min and max datasets are offset by approximately 2 orders of magnitude.

    The median of the minimum and maximum value are 1 x 10-5

    m/day (1 x 10-2

    mD) and 5 x 10-4

    m/day (5 x 10-1

    mD).

    Figure 4 Distribution of minimum and maximum Kv’

    0

    5

    10

    15

    20

    25

    30

    35

    40

    45

    50

    -12 -11 -10 -9 -8 -7 -6 -5 -4 -3 -2 -1 0 1 2

    Co

    un

    t o

    f va

    lue

    s

    Log Kv' (m/day)

    log Min (Kv')

    Log Max (Kv')

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    6.2. Comparison of Kv’ and K

    It is evident that the distributions of Kv’ and K (ie those that are not identified as Kv’ or Kh’)

    values are similar as illustrated by Figure 5 and Figure 6. The inclusion of K references in the

    report is therefore not considered to introduce any significant bias towards larger values of

    hydraulic conductivity, but offers the advantage of increasing the pool of references. Also

    noticeable, the lower value of hydraulic conductivity found in the literature refers to K and not to

    Kv’.

    Figure 5. Distribution of minimum hydraulic conductivity according to their references as Kv’ or K in the literature

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    Figure 6 Distribution of maximum hydraulic conductivity according to their references as Kv’ or K in the literature

    6.3. Effect of lithology on Kv’

    For this study the values of hydraulic conductivities presented in the literature, independently of the

    methodology used to derive the values (laboratory testing, field tests, modelling, text books), have

    been grouped into six relevant lithological categories. Figure 7 and Figure 8 represents the

    distribution for all the lithologies in a combined graph. Figure 9 and Table 4 represent the

    distribution for each of the lithologies separately. Note: sandstones are present within the aquitard

    units of the study area and have therefore been included in the assessment.

    Each lithology distribution of Kv’ ranges across several order of magnitudes and intersects. The

    whole spectrum of Kv’ value ranges over 13 orders of magnitude. The breakdown into individual

    lithology exhibits the same wide range of conductivities of over 10 orders of magnitude.

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    All lithologies except coal range over values of that are associated with both aquifer and aquitard

    behaviour. It is therefore not possible on the basis of lithology alone to determine whether a

    hydrogeological unit is primarily an aquitard or an aquifer.

    Table 4. Distribution of Kv’ by lithology in mD (a) and in m/day (b).

    Lithology Min Kv’ [mD] Max Kv’ [mD] Range, in order of

    magnitude [mD]

    Sandstone 1 x 10-5

    1 x 10+4

    10

    Silt & Siltstone 1 x 10-8

    1 x 10+5

    14

    Mudstone 1 x 10-9

    1 x 10+4

    14

    Shale 1 x 10-9

    1 x 10+3

    13

    (a)

    Lithology Min Kv’ [m/day] Max Kv’ [m/day] Range, in order of

    magnitude [m/day]

    Sandstone 1 x 10-8

    1 x 10+1

    10

    Silt & Siltstone 1 x 10-11

    1 x 10+2

    14

    Mudstone 1 x 10-12

    1 x 10+1

    14

    Shale 1 x 10-12

    1 x 100 13

    (b)

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    Figure 7 Distribution of minimum value of Kv’ by lithology in m/day

    Figure 8. Distribution of maximum value of log Kv’ by lithology in m/day

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    Figure 9. Distribution of minimum and maximum log Kv’ in m/day for each lithology by their number of citation in literature

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    6.4. Effect of data source on Kv’

    Values of hydraulic conductivity can be derived from field tests (eg pumping tests), laboratory

    tests, or they can be derived from models and other reference material. The distribution of Kv’ per

    acquisition method is presented in Figure 10 and Figure 11. These show that Kv’ derived from

    field tests tend to be greater than those derived from laboratory tests, particularly for the minimum

    Kv’ values. If we include only the lithologies that are most likely to form an aquitard (ie mudstone,

    clay, claystone and shale this results in a significant 3 to 4 order of magnitude difference between

    laboratory derived values and field test derived values (Table 5).

    Figure 10 Distribution of minimum log Kv’ [in m/day] in literature for different methods of value derivation

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    Figure 11 Distribution of maximum log Kv’ [in m/day] in literature for different methods of value derivation

    Table 5 Median of minimum and maximum Kv’ of fine grained lithologies derived from laboratory and field test methods

    Aquisition method

    Median of lower values (m/day)

    Median of upper values (m/day)

    all methods 10-6

    2 x 10-5

    Laboratory tests

    10-8

    4 x 10-7

    Field Tests 4 x 10-5

    10-3

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    7. Discussion

    7.1. Effect of test methods on Kv’

    Hydraulic conductivity can be determined using a number of different methods including

    laboratory tests on core samples, field tests using boreholes, and from groundwater models.

    7.1.1. Laboratory tests

    In a laboratory, hydraulic conductivity is tested on a small core sample which usually has a

    diameter and length of decimetre scale. Various laboratory techniques are available, but the main

    method consists of placing the core sample in a cell and applying the overburden pressure to the

    core. An air pressure (or alternatively another gas like helium or methane or a liquid like water) is

    then applied to one face of the sample, creating a flow of air through the core. By measuring the air

    flow and the viscosity of air (or used gas), the conductivity can be derived using Darcy’s law.

    The measure of hydraulic conductivity from core testing can provide lower hydraulic conductivity

    values compared to other methods for the following reasons:

    The integrity of a core sample relies on the absence of open fractures, thus fracture zones tend

    not to be sampled for laboratory testing (Ahmed et al, 1989)

    Non-cohesive materials (i.e. solid containing a high proportion of sand or silt) tend to be easily

    damaged or disturbed during collection of the core and hence are less likely to be sampled for

    testing (Hammenneister et al)

    The fluids/muds that are used during drilling can alter the properties of the formation which

    can lead to a reduction in hydraulic conductivity (Sharma and Wunderlich, 1985)

    The measure of permeability depends on the laboratory technique used. Permeability obtained

    by standard core analysis techniques using gas are different from those using water. Measuring

    intrinsic permeability of sandstone and shale cores, Bloomfield (Bloomfield et al. 1995)

    obtained an average permeability to gas one order magnitude greater than the permeability to

    water (5.1 x 10-1

    mD or 4.4 x 10-4

    m/day and 4.3mD or 3.7 x 10-3

    m/day respectively).

    However, using three different laboratory methods to measure matrix gas permeability, Luffel

    (1993) reported that one of the techniques yielded permeability estimations 3 to 10 times

    greater than the two others. This emphasises that despite the controlled environment of a

    laboratory and despite the potential biases in the core sampling, results from permeability

    measurements remain uncertain. Any proposed values of permeability from laboratory tests

    encompass an uncertainty of at least one order of magnitude.

    The difference between Kv’ derived core tested in the laboratory and Kv’ from field tests described

    in Section 6.4 and Table 5 indicate that core samples do not account for hydraulic conductivity

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    provided by discontinuities such as fractures and bedding joints which on a regional scale have a

    significant effect on Kv’. Laboratory results, unless a large number of samples are tested, also do

    not take into account the variability of lithology that occurs within an aquitard. Laboratory

    measurements are precise, but provide little insight into large scale hydraulic conductivity besides

    providing an absolute minimum for regional Kv’. This is consistent with Hart (2006), who showed

    that while measurements of Kv’ from a core of the Moquoteka Formation ranged from 1.6 x 10-9

    to

    3.5 x 10-7

    m/day (1.8 x 10-6

    mD to 4.1 x 10-4

    mD), the regional behaviour suggested that regional

    Kv’ was more likely around 1.6 x 10-6

    m/day (1.8 x 10-3

    mD).

    In general, therefore, laboratory results should be considered to represent a lower bound value for

    regional Kv’.

    7.1.2. Field tests

    Field estimation of aquitard hydraulic conductivity can be undertaken directly by testing the

    aquitard, or indirectly by inducing flow from an aquitard into an aquifer by pumping. These are

    described below:

    Rowe (1993) describes a pumping test method to evaluate the hydraulic conductivity of

    aquitards. It consists of pumping the aquifer while monitoring the aquitard. The pumping test

    should extend over a long enough period to trigger leakage in the aquitard. A pumping test

    that is too short, which is often the case due to time and cost limitations, tends to result in an

    under-estimate of Kv’ because there has been insufficient time for leakage from the aquitard to

    occur during the test (Kruseman and de Ridder, 1991). Pumping tests within an aquitard can

    provide an estimate of aquitard properties but tend to test only a small area due to the low

    hydraulic conductivity of the aquitard.

    Geochemical or isotopic method exist to evaluate groundwater age, flow path, transmissivity

    and hence conductivity, of low permeable aquitards.

    Estimation of the vertical hydraulic gradient across an aquitard, assuming steady state

    conditions, can be used to estimate aquitard vertical permeability. Usually this technique is

    applied with a numerical model for which the vertical conductivity of the aquitard is adjusted

    as part of the calibration process to match observed heads.

    Slug tests within a portion of an aquitard separated by packer have also been successfully used

    (Ayan et al., 1994).

    Methods using earth tides and barometric fluctuation can also be used to derive Kv’ (Cutillo

    and Bredehoeft, 2011).

    Compared to laboratory techniques, a major advantage of field testing is that discontinuities such as

    joints, faults, bedding planes fractures, and heterogeneity are included in the resultant Kv’. Some

    methods, such as long term pumping test can also determine Kv’ values that are representative of

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    large areas or thicknesses. Laboratory tests in comparison generally only represent a discrete

    location within the test site (i.e. aquitard).

    Field tests generally become increasingly difficult and expensive to conduct as the depth of

    investigation increases. The duration of tests for deep wells tend to be short due to the difficulties

    encountered in managing hot and/or saline/corrosive water, and limits on the power of bore pumps

    to lift water from large depths which can result in an underestimation of Kv’. It is fair to assume

    that a large proportion of field values collected in this review contain results that are derived from

    shallow depths, because many more tests will have been undertaken at shallow depths. It should

    also be noted that as depth of burial increases, hydraulic conductivity typically decreases (McKee

    et al. 1986). These values therefore, may not be as representative of aquitards that are located at

    large depths. However, it is difficult to make generalisations about the reliability of field tests

    without knowing the full details of how the test site was configured, how the test was conducted, its

    duration and how the data was collected. Usually this information is not available in reference

    material such as that used in the study.

    7.1.3. Conductivity estimated from models

    Numerical groundwater modelling can be used to infer the value of vertical conductivity at a

    regional scale. Indeed, every model needs to be calibrated to obtain a good match between

    observed and calculated heads. The calibrated parameters can be used as an estimation of the real

    parameter value. The most important limitation of this approach resides in the fact that

    groundwater models generally do not have a unique solution. Various combinations of parameters

    can calibrate a model and uncertainty in the parameter estimation occurs as a result. The quality of

    the parameter estimation relies on a proper conceptualisation of the hydrogeological system. The

    numerical model links all model parameters. The estimation of one parameter, in this case Kv’, will

    directly rely on the estimation of the other parameters, which may also have levels of uncertainty

    similar to those of Kv’, such as groundwater recharge and evaporation. The method also relies

    directly on the quality and quantity of observed heads. Transient observations recorded over a large

    number of years contribute to narrowing down the distribution of calibrating parameters and to the

    success of this method.

    If a system is well understood conceptually and well documented through proper long term

    monitoring, groundwater modelling, by incorporating all the hydrogeological information

    available, has the potential to reliably estimate accurate bounds for Kv’ across aquitards at a

    regional scale (Macfarlane, 1993).

    Hydraulic conductivity can also be obtained from grain size analysis models. This method has

    been excluded from this assessment because they are only applicable to unconsolidated sediments,

    which are not present in the formations of the GAB.

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    7.2. Effect of discontinuities, bores, and multiphases on Kv’

    7.2.1. Discontinuities (joints, fractures, and faults)

    Discontinuities play a key role in aquitard Kv’. If discontinuities form an interconnected network

    they are likely to be a significant control on regional hydraulic parameters. If the discontinuities

    can be considered as isolated features in a bulk mass of low conductivity material, the regional

    conductivity will be only partially influenced by those features, depending on their spacing

    (frequency) and width.

    According to a simple parallel plate model from Snow (1968) and reported in (Hart, 2006), a

    simple set of non-intersecting fractures of 0.1 mm (100 μm) openings spaced every 10km is enough

    to produce an aquitard of a virtually impermeable matrix with a regional Kv’ of 5 x 10-6

    m/day (5.8

    x 10-3

    mD, Figure 12). Similarly, assuming a negligible matrix Kv’, fractures with openings of 0.1

    mm (100 μm) would need to be spaced every 100km to give the aquitard a regional Kv’ of 5 x 10-7

    m/day (5.8 x 10-4

    mD). Thinner fractures with 0.01 mm (10μm) openings would need to be spaced

    every 100m for a similar Kv’. Consequently, the chosen minimal value of 5 x 10-7

    m/day (5.8 x 10-4

    mD) is likely to be associated with a virtually unfractured rock, while a value of 5 x 10-6

    m/day (5.8

    x 10-3

    mD) would indicate little fracturing. A fractured rock aquitard with more open fractures

    would have greater Kv’ values. The range of Kv’ values used in the GEN2 groundwater model for

    some confining units (between 5 x 10-7

    and 5 x 10-6

    m/day or 5.8 x 10-4

    and 5.8 x 10-3

    mD) may

    therefore be too limited to represent a fractured aquitard.

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    Figure 12 Combination of fracture aperture and spacing that creates regional hydraulic

    conductivities of 5.7 x 10-4

    , 5.7 x 10-3

    and 5.7 x 10-2

    mD (resp. 5 x 10-7

    , 5 x 10-6

    and

    5 x 10-5

    m/day)

    7.2.2. Bores

    As with natural discontinuities, poorly constructed, poorly decommissioned, abandoned failed

    bores, or bores screened across multiple units, may also act as sites of preferred flow which can

    potentially affect regional vertical hydraulic conductivity values (Figure 13).

    Bore construction requirements vary depending on the legislation under which a bore is licensed

    and as a result, bores (including recently drilled bores) may be constructed to standards that are not

    suitable for the prevention of inter-aquifer flow. For example, bores drilled for water supply are

    regulated under the Queensland Water Act (2000) which has stringent controls on bore design to

    prevent inter-aquifer flow. Bores drilled under the Petroleum and Gas Act (2004) have different

    controls on bore design for the prevention of inter-aquifer flow.

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    In a study of the Maquoketa Aquitard in Wisconsin (Hart, 2006) estimated that only 50 wells of 0.1

    m radius open to aquifers above and below a shale unit and evenly spaced 10 km apart across the

    ~60 km x 100 km extent of the Aquitard would be sufficient to provide a Kv’ of 1.6 x 10

    -6 m/day

    (1.8 x 10-3

    mD), while laboratory estimates of Kv’ from core samples from the same unit ranged

    from 1.6 x 10-9

    to 1.6 x 10-7

    m/day (1.8 x 10-6

    mD to 4.1 x 10-4

    mD ).

    A total of 1,158 flowing bores in the GAB have been capped between 1999 and 2010 resulting in

    an ongoing reduction in discharge of 298,778 ML/year or 258 ML/year/bore (GABCC, 2010). A

    further 537 bores were due to be decommissioned as part of the Phase 3 Basin renewal program.

    When this is completed a total of 1,695 bores will have been decommissioned. Divided over the

    full GAB area of 1.7 million km2 results in one bore per 1,468 km

    2 (it is likely that this is an over-

    estimate of the area per bore because the artesian area will be smaller than the total basin). Using

    an average pressure head of 160 m, an assumed drawdown to ground surface (i.e. 160 m of

    drawdown), and an average aquifer depth of 1,000 m, the vertical gradient is 0.16. Using Darcy’s

    equation the resultant Kv’ is 3.0 x 10-6

    m/day (3.5 x 10-3

    mD) from bore discharge alone. If matrix

    Kv’ is included the Kv’ would be expected to be greater than 3.0 x 10-6

    m/day (3.5 x 10-3

    mD).

    Although this is a relatively crude analysis it demonstrates that flow through bores could have a

    significant effect on Kv’.

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    Figure 13. Diagrammatic representation of possible leakage pathways through an abandoned well. a) Between casing and cement b) between cement plug and casing c) through the cement pore space as a result of cement degradation d) through casing as a result of corrosion e) through fractures in cement and f ) between cement and rock (from Gasda 2004)

    7.2.3. Multiphase conductivity

    Hydraulic conductivity of a porous medium is reduced when a gas phase appears in the bulk rock

    (Kissel, 1975). With the porosity being jointly shared by the two phases, the volume of voids

    available for water decreases as the volume of gas increases and thus the hydraulic conductivity

    decreases. Figure 14 shows an example of a gas and water relative permeability curves derived

    experimentally by Kissel (1975). It is noticeable that with a water saturation of 80%, the

    permeability of the water phase is reduced by one order of magnitude compared to its value at

    100% saturation. At 50% of water saturation the permeability to water becomes virtually zero

    compared to the fully saturated value.

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    Figure 14 Example of gas and water relative permeability curves (from Kissel 1975)

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    8. Conclusions

    The international literature review determined that around the world, measured or estimated

    vertical hydraulic conductivities of facies similar of those encountered in the Surat Basin, such as

    sandstone, siltstone, mudstone and shale, range over 14 orders of magnitude. The lowest vertical

    hydraulic conductivity from core samples was 1 x 10-12

    m/day (1 x 10-9

    mD). The lowest vertical

    hydraulic conductivities from field tests were one order of magnitude higher than laboratory tests.

    The higher hydraulic conductivity, as determined from field tests, is potentially due to the influence

    of defects (i.e. joints, faults, bedding planes) that cannot be represented in laboratory samples.

    Short duration field tests (e.g. slug tests, packer tests or short duration pumping tests) may also

    underestimate vertical hydraulic conductivity. The shallow depth that many of the field values in

    this review may have been derived may lead to an over-estimate of Kv’ for aquitards that occur at

    greater depths, such as those in the Surat Basin. In general laboratory results should be considered

    to represent a lower bound value for regional Kv’.

    Snow (1968) demonstrated the significance of defects on hydraulic conductivity by calculating that

    a simple set of vertical non-intersecting fractures of 0.1 mm (100 μm) openings spaced every 10km

    in an theoretical impervious matrix results in a regional Kv’ of 5 x 10-6

    m/day (5.8 x 10-3

    mD). With

    the defects spaced at 100 km apart the Kv’ reduces to 5 x 10-7

    m/day (5.74 x 10-4

    mD), which is still

    significantly greater than the lowest values identified in the literature search. This indicates that

    Kv’ values less than 5 x 10-6

    m/day (5.8 x 10-3

    mD) are not likely to be representative of the

    regional Kv’ because they do not take into account defects within the rock mass. Even if defects are

    widely spaced they can have a significant impact on Kv’.

    In addition to natural defects, poorly constructed, poorly decommissioned, abandoned or failed

    bores, or bores screened across multiple units, may contribute to Kv’ by allowing flow between

    aquifers. Hart (2006) estimated that only 50 wells evenly spaced 10 km apart would be sufficient to

    provide a Kv’ of 1.5 x 10-6

    m/day (1.8 x 10-3

    mD), while laboratory estimation of Kv’ from core

    samples ranged from 1.5 x 10-9

    m/day to 3.5 x 10-7

    m/day (1.8 x 10-6

    to 4.1 x 10-4

    mD).

    Discharge from the 1,158 flowing bores in the GAB that have been capped between 1999 and 2010

    is equivalent to a Kv’ of 3.0 x 10-6

    m/day (3.5 x 10-3

    mD), if the bores are assumed to be uniformly

    spaced across the GAB. Given that the bores are not uniformly spaced, the Kv’ in some areas

    would be greater than 3.0 x 10-6

    m/day (3.5 x 10-3

    mD) and in other areas less than 5.6 x 10-6

    m/day

    (6.5 x 10-3

    mD). The number of poorly constructed, poorly decommissioned, abandoned or failed

    bores and the nature of natural defects, potentially has a large influence on Kv’.

    The literature review supports the current range of conductivities used in the GEN2 numerical

    models (which were between 1 x 10-6

    m/day to 1 x 10-5

    m/day or 1.2 x 10-3

    and 1.2 x 10-2

    mD). The

    range is within the expected values for Kv’ used for similar modelling approaches by 4 major

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    companies in the CSG industry in the Surat Basin, as investigated by the University of Southern

    Queensland (2011).

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    9. References

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    and Interrelationships. SPE Anual Technical Conference, San Antonio, Oct 1989.

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    Ayan C., Colley N., Cowan G., Ezekwe E., Wannell M., Goode P., Halford F. Joseph J., Mongini

    A., Pop J. 1994. Measuring Permeability Anisotropy: The Latest Approach, Oilfield Review,

    October 1994

    Bloomfield J.P. and Williams A.T. 1995. An empirical liquid permeability – gas permeability

    correlation for use in aquifer properties studies. Quaterly Journal of Engineering Geology, 28.

    Cutillo, P. A, and Bredehoeft, J. D. 2011: Estimating Aquifer Properties from the Water Level

    Response to Earth Tides. GROUND WATER No. 4 Vol. 49, pages 600–610, July-August 2011.

    Duffield Glenn, 1996-2007. Aqtesolv for Windows, version 4.50 professional, hydrosolve Inc.

    Ferris J.G., Knowles D.B., Brown R.H. and Stallman R.W. 1962. Theory of aquifer test, Geological

    survey water-supply papaer 1536-E.

    GABCC (2010): Great Artesian Basin Committee Annual Report 2009-2010.

    http://www.gabcc.org.au/public/content/ViewCategory.aspx?id=70

    Gasda S.E., Bachu S. and Celia M.A. 2004. Spatial characterization of the location of potentially

    leaky wells penetrating a deep saline aquifer in a mature sedimentary basin, Environmental

    Geology.

    Golder Associates 2009. QGC Groundwater Study Surat Basin, Queensland, Report for

    Queensland Gas Company Report 087633050 016 R.

    Golder Associates 2011. Groundwater Impact Assessment Report for QCLNG Project, Report

    107635002-019-R-5503.

    Habermehl M.A. 2002. Hydrogeology, Hydrochemistry and Isotope Hydrology of the Great

    Artesian Basin, Bureau of Rural Science program, Canberra, ACT.

    Hammenneister, D. P., Blout, D., and McDaniel, J. C. DRILLING AMD CORING METHODS

    THAT MINIMIZE THE DISTURBANCE OF CUTTINGS, CORE, AND ROCK FORMATION

    IN THE UNSATURATED ZONE, YUCCA MOUNTAIN, NEVADA, CONF-8511172—3 DE86

    008851. http://www.osti.gov/bridge/servlets/purl/59845-QUVhus/59845.pdf

    http://xa.yimg.com/kq/groups/9928130/137174367/name/Perm+estimation+various+sources.pdfhttp://www.gabcc.org.au/public/content/ViewCategory.aspx?id=70http://www.osti.gov/bridge/servlets/purl/59845-QUVhus/59845.pdf

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    Hantush, M.S. 1960. Modification of the theory of leaky aquifers, Jour. of Geophys. Res., vol. 65,

    no. 11.

    Hunt, B. And Scott D., 2005. An extension of the Hantush and Boulton solutions. ASCE Journal of

    Hydrologic Engineering, Vol. 10, No3.

    Hart D.J., Bradbury K.R. and Feinstein D.T. 2006. The vertical Hydraulic Conductivity of an

    Aquitard at two Spatial Scales, GroundWater Vol. 44, No.2, March April 2006.

    Kissel F. N. and Edwards J.C. 1975. Two phase flow in coalbeds, Bureau of Mines Report of

    investigations.

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    International Institute for Land Reclamation and Improvement, the Netherlands. Publication No.

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    Broadwater #10, ATP 648P - Broadwater #13, ATP 648P - Kenya East #25, ATP 648P - Kenya

    East #26, ATP 648P - Kenya East #28, ATP 648P - Woleebee creek #4, ATP 651P - Woleebee

    creek #5, ATP 651P - Woleebee creek #6, ATP 651P - Woleebee creek #7, ATP 651P).

    QGC 2011. Stage 1 CSG Water Monitoring and Management Plan, QGC document submitted to

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    Sharma, M. M., and Wunderlich, R., W. 1985: The alteration of rock properties due interactions

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    Worley Parsons 2010. Spatial Analysis of Coal Seam water Chemistry. Task1: Literature Review,

    40513, WorleyParsons.

    http://faculty.engr.utexas.edu/sharma/pdfs/conference/Conf-3.pdf

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    Appendix A Documents consulted

    Note: Most of the documents consulted were freely available and downloaded from the internet.

    The complete reference was not always available for each document and to consult those

    documents, it is recommended to use a web search engine using the information provided in this

    listing.

    Abaci S. & al. 1992. Relative permeability measurements for 2 phase flow in unconsalidated

    sands,Mine Water and the Environment, vol 11, No. 2, June 1992

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    correlation for use in aquifer properties studies. Quaterly Journal of Engineering Geology, 28.

    ACS laboratories - Not dated - Special core analysis final report of Walloon Coal and Sandstone

    samples for QGC, ACS.

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    with water-based and oil-based muds,PhD dissertation, University of Texas.

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    Australian govt. 2011. Hydraulic Conductivity measurment,www.connectedwater.gov.au.

    Barrash W. and Morin R.H. No date. Hydrostratigraphy and distribution of secondary permeability

    in the Brule formation, cheyenne county, Nebraska,Geological Society of America bulletin v.99

    No.4.

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    frenchman Flat Well Clustrer RNM-2s, Nevada Test Site, Nevada.

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    Journal 9.

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    Borchardt M. A. & al. 2007. Human Enteric viruses in groundwater from a confined bedrock

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    Contamination: A "state of the Science" Report,Awwa Research foundation

    Collective, no date. Part II: Case histories of land subsidence due to groundwater withdrawal, No

    Ref.

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    Duan Z., Mao S., 2006. A thermodynamic model for calculating methane solubility, density and

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    Habermehl M.A. ,2002. Hydrogeology, Hydrochemistry and Isotope Hydrology of the Great

    Artesian Basin,Bureau of Rural Science program, canberra, ACT.

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    of coal,Geotechnical and Geological Engineering.

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    at two Spatial Scales,Vol. 44, No.2 - Ground Water - March April 2006.

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    monitoring,CWiMI - SMI – UQ.

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    nov. 2007, CSIRO.

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    siltstone),Jounral of Canadian Petroleum Technology, volume48, No8.

    Jorgensen P.R. & al., No date. Aquifer vulnerability to pesticide migration through till aquitards.

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    survey of Canada.

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    Kleeschulte M.J., Seeger C.M.,2003. Stratigraphy and vertical Hydrulic Conductivity of the St.

    Francois Confining Unit in the Viburnum Trend and Evaluation of the Unit in the Viburnum Trend

    and Exploration Areas, Southeastern Missouri,Water-Resources Investigations Report 03-4329.

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    sources of systematic error,PhD Thesis, University of british Colombia.

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