SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
ARDROX® AV 30
Version: 7.0 Revision Date 12.04.2016
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SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name : ARDROX® AV 30
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub-stance/Mixture
: Corrosion inhibitor
Recommended restrictions on use
: None known.
1.3 Details of the supplier of the safety data sheet
Company : Chemetall GmbH Trakehner Strasse 3 60487 Frankfurt a.M.
Lead Organisation : Surface Treatment Telephone : +49(0)69 7165-0 Telefax : +49(0)69 7165-3567 Contact person product safety Telephone : +49(0)6971653581 E-mail address : [email protected]
1.4 Emergency telephone number
Emergency telephone number
: +49(0)5326 51-0
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)
Flammable liquids, Category 3 H226: Flammable liquid and vapour. Skin irritation, Category 2 H315: Causes skin irritation. Eye irritation, Category 2 H319: Causes serious eye irritation. Specific target organ toxicity - repeated exposure, Category 2
H373: May cause damage to organs through pro-longed or repeated exposure if inhaled.
Chronic aquatic toxicity, Category 3 H412: Harmful to aquatic life with long lasting ef-fects.
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)
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Hazard pictograms :
Signal word : Warning
Hazard statements : H226 Flammable liquid and vapour.
H315 Causes skin irritation. H319 Causes serious eye irritation. H373 May cause damage to organs through pro-
longed or repeated exposure if inhaled. H412 Harmful to aquatic life with long lasting ef-
fects.
Precautionary statements : Prevention: P210 Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources. No smoking.
P260 Do not breathe vapours, aerosols. P262 Do not get in eyes, on skin, or on clothing. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/
eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immedi-
ately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with wa-ter for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical ad-vice/ attention.
Disposal: P501 Dispose of contents/ container to an ap-
proved waste disposal plant.
Hazardous components which must be listed on the label:
Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)
2.3 Other hazards
The information required is contained in this Material Safety Data Sheet.
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SECTION 3: Composition/information on ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Chemical nature : Mixture of organic solvents.
Hazardous components
Chemical Name CAS-No. EC-No.
Registration number
Classification (REGULATION (EC)
No 1272/2008)
Concentration [%]
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics
919-857-5 01-2119463258-33
Flam. Liq. 3; H226 Asp. Tox. 1; H304 STOT SE 3; H336 Note N
>= 15 - < 20
Hydrocarbons, C10 - C13, n-alkanes, isoalkanes, cyclics, < 2 % aromatics
918-481-9 01-2119457273-39
Asp. Tox. 1; H304 Note N
>= 10 - < 25
calcium bis(di C8-C10, branched, C9 rich, alkylnaph-thalenesulphonate)
01-2119980985-16
Eye Irrit. 2; H319 Skin Irrit. 2; H315
>= 10 - < 20
Distillates (Petroleum), hy-drotreated light Kerosine-unspecified
64742-47-8 265-149-8
Asp. Tox. 1; H304 Note H (Table 3.1)
>= 2.5 - < 10
Hydrocarbons, C16-C20, n-alkanes, isoalkanes, cyclics, < 2% aromatics
919-029-3 01-2119457735-29
Asp. Tox. 1; H304 Note N
>= 2.5 - < 10
Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)
919-446-0 01-2119458049-33
Flam. Liq. 3; H226 STOT SE 3; H336 STOT RE 1; H372 Asp. Tox. 1; H304
>= 2.5 - < 10
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Aquatic Chronic 2; H411 Note P
3-Butoxypropan-2-ol,propylene glycol monobutyl ether
5131-66-8 225-878-4 01-2119475527-28
Flam. Liq. 3; H226 Eye Irrit. 2; H319 Skin Irrit. 2; H315
>= 1 - < 2.5
2,2'-(octadec-9-enylimino)bisethanol
25307-17-9 246-807-3 01-2119510876-35
Acute Tox. 4; H302 Skin Corr. 1B; H314 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 M-Factor:10
>= 0.25 - < 1
For the full text of the H-Statements mentioned in this Section, see Section 16. For the full text of the Notas mentioned in this Section, see Section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures
General advice : First-aid crew: Ensure self-protection. Move out of dangerous area. Take off contaminated clothing and shoes immediately.
If inhaled : Move to fresh air. If symptoms persist, call a physician.
In case of skin contact : Wash off with soap and plenty of water. If symptoms persist, call a physician.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids. Consult a physician.
If swallowed : Rinse mouth with water. Do NOT induce vomiting. Consult a physician.
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4.2 Most important symptoms and effects, both acute and delayed
Symptoms : No information available.
Risks : Causes skin irritation. Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically. For specialist advice physicians should contact the Poisons Information Service.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide (CO2) Dry powder Alcohol-resistant foam Water spray
Unsuitable extinguishing media
: High volume water jet
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire-fighting
: May form toxic gases on heating or in case of fire. Carbon monoxide Carbon dioxide (CO2) Sulphur oxides Aldehydes
5.3 Advice for firefighters
Special protective equipment for firefighters
: In the event of fire, wear self-contained breathing apparatus.
Further information : Use water spray to cool unopened containers.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions : Ensure adequate ventilation. Remove all sources of ignition.
6.2 Environmental precautions
Environmental precautions : Do not flush into surface water or sanitary sewer system.
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Avoid subsoil penetration.
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up : Ensure adequate ventilation. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13).
6.4 Reference to other sections
For further information see Section 8 of the safety data sheet. For disposal considerations see sec-tion 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms. Have eye wash bottle or eye rinse ready at the work place. To avoid risks to man and the environment, comply with the instructions for use.
Advice on protection against fire and explosion
: Keep away from sources of ignition - No smoking. Normal measures for preventive fire protection. Take precautionary measures against static discharges. Vapours may form explosive mixtures with air.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
: Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a place accessible by authorized persons only. Protect from frost, heat and sunlight.
Storage period : 36 month
Storage temperature : 4 - 38 °C
7.3 Specific end use(s)
Specific use(s) : Corrosion inhibitor
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
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Contains no substances with occupational exposure limit values. DNEL/DMEL
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics,
< 2% aromatics
: End Use: Workers DNEL Exposure routes: Inhalation Potential health effects: Long-term systemic effects Value: 871 mg/m3
End Use: Workers DNEL Exposure routes: Skin contact Potential health effects: Long-term systemic effects Value: 208 mg/kg bw/day
calcium bis(di C8-C10, branched, C9 rich, alkylnaph-
thalenesulphonate)
: End Use: Workers DNEL Exposure routes: Skin contact Potential health effects: Long-term systemic effects Value: 0.00032 mg/kg bw/day
End Use: Workers DNEL Exposure routes: Inhalation Potential health effects: Long-term systemic effects Value: 2.23 mg/m3
3-Butoxypropan-2-ol,propylene glycol mono-
butyl ether
: End Use: Workers DNEL Exposure routes: Inhalation Potential health effects: Long-term systemic effects Value: 270.5 mg/m3
End Use: Workers DNEL Exposure routes: Skin contact Potential health effects: Long-term systemic effects Value: 44 mg/kg bw/day
2,2'-(octadec-9-enylimino)bisethanol
: End Use: Workers DNEL Exposure routes: Inhalation Potential health effects: Long-term systemic effects Value: 1.76 mg/m3
End Use: Workers DNEL Exposure routes: Skin contact Potential health effects: Long-term systemic effects Value: 0.25 mg/kg bw/day
PNEC calcium bis(di C8-C10, branched, C9 rich, alkylnaph-
: Fresh water Value: 0.00027 mg/l
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thalenesulphonate) Marine water
Value: 0.000027 mg/l
Sewage treatment plant Value: 10 mg/l
Intermittent use/release Value: 0.0027 mg/l
Fresh water sediment Value: 4.69 mg/kg
Marine sediment Value: 0.469 mg/kg
Soil Value: 0.936 mg/kg
3-Butoxypropan-2-ol,propylene glycol mono-butyl ether
: Fresh water Value: 0.525 mg/l
Marine water Value: 0.0525 mg/l
Fresh water sediment Value: 2.36 mg/kg dry weight (d.w.)
Marine sediment Value: 0.236 mg/kg dry weight (d.w.)
Soil Value: 0.16 mg/kg
2,2'-(octadec-9-enylimino)bisethanol
: Fresh water Value: 0.000214 mg/l
Marine water Value: 0.000021 mg/l
Sewage treatment plant Value: 1.5 mg/l
Fresh water sediment Value: 1.692 mg/kg dry weight (d.w.)
Marine sediment Value: 0.1692 mg/kg dry weight (d.w.)
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Soil Value: 5 mg/kg dry weight (d.w.)
8.2 Exposure controls
Engineering measures
Ensure adequate ventilation, especially in confined areas. Electrical equipment should be protected to the appropriate standard. Keep only in the original container.
Personal protective equipment
Respiratory protection : In case of insufficient ventilation wear suitable respiratory equipment. Recommended Filter type: Type A
Hand protection : Nitrile rubber Protective gloves complying with EN 374. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local condi-tions under which the product is used, such as the danger of cuts, abrasion, and the contact time.
Eye protection : Eye protection (EN 166) Tightly fitting safety goggles
Skin and body protection : Chemical resistant protective clothing according to DIN EN 13034 (Type 6)
Hygiene measures : Take off contaminated clothing and shoes immediately. Keep away from food, drink and animal feedingstuffs. Wash hands before breaks and immediately after handling the product. Avoid contact with skin and eyes. Do not breathe vapour. Do not breathe spray.
Environmental exposure controls
General advice : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
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Appearance : liquid
Colour : light brown
Odour : hydrocarbon-like
Flash point : 46 °C Method: closed cup
Boiling point/boiling range : 155 - 200 °C
Density : 0.9 g/cm³ at 20 °C
Water solubility : practically insoluble
Viscosity, kinematic : 98 mm²/s at 40 °C Ubbelohde IIc
Flow time : 20 sec. at 40 °C 4 mm Method: ISO 2431
9.2 Other information
Explosivity : Vapours may form explosive mixture with air.
Directive 1999/13/EC on the limitation of emissions of vol-atile organic compounds
: Value: 405 g/l
SECTION 10: Stability and reactivity
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under normal conditions. 10.3 Possibility of hazardous reactions
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Hazardous reactions : Vapours may form explosive mixture with air.
10.4 Conditions to avoid
Conditions to avoid : Keep away from open flames, hot surfaces and sources of ignition. Protect from frost.
10.5 Incompatible materials
Materials to avoid : Strong oxidizing agents Reducing agents
10.6 Hazardous decomposition products
Risk of decomposition.
: No decomposition if stored and applied as directed.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Acute oral toxicity Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics
: LD50: > 5,000 mg/kg Species: Rat Method: OECD Test Guideline 401
Hydrocarbons, C10 - C13, n-alkanes, isoalkanes, cyclics, < 2 % aromatics
: LD50: > 5,000 mg/kg Species: Rat Method: OECD Test Guideline 401
calcium bis(di C8-C10, branched, C9 rich, alkylnaph-thalenesulphonate)
: LD50: > 2,500 mg/kg Species: Rat
Distillates (Petroleum), hy-drotreated light Kerosine-unspecified
: LD50: > 2,000 mg/kg
Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)
: LD50: > 15,000 mg/kg Species: Rat
3-Butoxypropan-2-ol,propylene glycol mono-butyl ether
: LD50: > 2,000 mg/kg Species: Rat Method: OECD Test Guideline 423
2,2'-(octadec-9-enylimino)bisethanol
: LD50: > 300 - 2,000 mg/kg Species: Rat Method: OECD Test Guideline 401
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Acute inhalation toxicity calcium bis(di C8-C10, branched, C9 rich, alkylnaph-thalenesulphonate)
: LC50: > 9,000 mg/l Exposure time: 1 h Species: Rat
Distillates (Petroleum), hy-drotreated light Kerosine-unspecified
: LC50: > 5 mg/l
Acute dermal toxicity Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics
: LD50: > 5,000 mg/kg Species: Rabbit Method: OECD Test Guideline 402
Hydrocarbons, C10 - C13, n-alkanes, isoalkanes, cyclics, < 2 % aromatics
: LD50: > 2,000 mg/kg Species: Rat Method: OECD Test Guideline 402
calcium bis(di C8-C10, branched, C9 rich, alkylnaph-thalenesulphonate)
: LD50: > 10,000 mg/kg
Distillates (Petroleum), hy-drotreated light Kerosine-unspecified
: LD50: > 2,000 mg/kg
Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)
: LD50: > 3,400 mg/kg Species: Rabbit
3-Butoxypropan-2-ol,propylene glycol mono-butyl ether
: LD50: > 2,000 mg/kg Species: Rat Method: OECD Test Guideline 402
Skin corrosion/irritation
Skin irritation : Causes skin irritation.
Serious eye damage/eye irritation
Eye irritation : Causes serious eye irritation.
Respiratory or skin sensitisation
Sensitisation : No data available
Sensitisation 3-Butoxypropan-2- : Buehler Test
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ol,propylene glycol mono-butyl ether
Species: Guinea pig No sensitising effects are known.
Toxicology Assessment
Repeated dose toxicity : May cause damage to organs through prolonged or repeated exposure if inhaled.
SECTION 12: Ecological information
12.1 Toxicity
Ecotoxicology studies for the product are not available. Toxicity to fish Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics
: Limit Test LC50: > 1,000 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout) Method: OECD Test Guideline 203
Hydrocarbons, C10 - C13, n-alkanes, isoalkanes, cyclics, < 2 % aromatics
: > 1,000 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout) Method: OECD Test Guideline 203
calcium bis(di C8-C10, branched, C9 rich, alkylnaph-thalenesulphonate)
: LC50: > 0.28 mg/l Exposure time: 96 h Species: Fish Test substance: Read-across (Analogy)
Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)
: EC50: 10 - 30 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout)
3-Butoxypropan-2-ol,propylene glycol mono-butyl ether
: LC50: > 100 mg/l Exposure time: 96 h Species: Pimephales promelas (Fathead minnow)
2,2'-(octadec-9-enylimino)bisethanol
: LC50: > 0.1 - 1 mg/l Exposure time: 96 h Species: Brachydanio rerio (Zebra danio) Method: OECD Test Guideline 203
Toxicity to daphnia and other aquatic invertebrates Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics,
: Limit Test EC50: > 1,000 mg/l Exposure time: 48 h
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< 2% aromatics Species: Daphnia magna (Water flea) Method: OECD Test Guideline 202
Hydrocarbons, C10 - C13, n-alkanes, isoalkanes, cyclics, < 2 % aromatics
: > 1,000 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) Method: OECD Test Guideline 202
calcium bis(di C8-C10, branched, C9 rich, alkylnaph-thalenesulphonate)
: EC50: > 0.27 mg/l Exposure time: 48 h Species: Daphnia (water flea)
Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)
: EC50: 10 - 20 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea)
3-Butoxypropan-2-ol,propylene glycol mono-butyl ether
: static test EC50: > 1,000 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea)
2,2'-(octadec-9-enylimino)bisethanol
: EC50: > 0.001 - 0.01 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) Method: OECD Test Guideline 202 GLP: yes
EC100: > 0.001 - 0.01 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Method: OECD Test Guideline 211
Toxicity to algae Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics
: IC50: > 1,000 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae)
NOEC: 100 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae)
Hydrocarbons, C10 - C13, n-alkanes, isoalkanes, cyclics, < 2 % aromatics
: > 1,000 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae) Method: OECD Test Guideline 201
NOEC: 1,000 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae)
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Method: OECD Test Guideline 201
calcium bis(di C8-C10, branched, C9 rich, alkylnaph-thalenesulphonate)
: NOEC: > 0.27 mg/l Exposure time: 72 h Species: Algae
Hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)
: EC50: 4.6 - 10 mg/l Exposure time: 72 h Species: Algae
2,2'-(octadec-9-enylimino)bisethanol
: EC50: > 0.001 - 0.01 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae) Method: OECD Test Guideline 201
12.2 Persistence and degradability
Biodegradability Hydrocarbons, C16-C20, n-alkanes, isoalkanes, cyclics, < 2% aromatics
: Ready biodegradability 74 % Readily biodegradable
2,2'-(octadec-9-enylimino)bisethanol
: Method: OECD Test Guideline 301D GLP: yes This surfactant complies with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Readily biodegradable
12.3 Bioaccumulative potential
Bioaccumulation : Bioaccumulation is unlikely.
12.4 Mobility in soil
Distribution among environmental compartments calcium bis(di C8-C10, branched, C9 rich, alkylnaph-thalenesulphonate)
: Adsorption/Soil Information taken from reference works and the literature.
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
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12.6 Other adverse effects
Chemical Oxygen Demand (COD) 2,2'-(octadec-9-enylimino)bisethanol
: 3,880 mg/g
Additional ecological infor-mation
: water endangering Harmful to aquatic life with long lasting effects. Even leakage of small amounts in the subsoil can contaminate drinking water. Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product : In accordance with local and national regulations.
Contaminated packaging : Dispose of as unused product.
Waste Code : Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
SECTION 14: Transport information
ADR UN number : 1139 UN proper shipping name : COATING SOLUTION Transport hazard class(es) : 3 Packing group : III Classification Code : F1 Hazard Identification Number : 30 Limited Quantity (LQ) Inner Packaging
: 5.00 L
Maximum quantity : 30.00 KG Labels : 3 Tunnel restriction code : (D/E) Environmentally hazardous : no Special Provision 640E
IATA UN number : 1139 Description of the goods : Coating solution Class : 3
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Packing group : III Labels : 3
IATA_C Packing instruction (cargo aircraft)
: 366
Packing instruction (LQ) : Y344 Maximum quantity : 220.00 L Environmentally hazardous : no
IATA_P Packing instruction (passen-ger aircraft)
: 355
Packing instruction (LQ) : Y344 Maximum quantity : 60.00 L Environmentally hazardous : no
IMDG UN number : 1139 Description of the goods : COATING SOLUTION Class : 3 Packing group : III Labels : 3 EmS Number 1 : F-E EmS Number 2 : S-E Limited Quantity (LQ) Inner Packaging
: 5.00 L
Marine pollutant : no "IMDG-Code segregation group not applicable".
"IMDG-Code segregation group not applicable".
RID UN number : 1139 Description of the goods : COATING SOLUTION Transport hazard class(es) : 3 Packing group : III Classification Code : F1 Hazard Identification Number : 30 Labels : 3 Limited Quantity (LQ) Inner Packaging
: 5.00 L
Maximum quantity : 30.00 KG
Environmentally hazardous : no Special Provision 640E
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SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).
: Not applicable
Water contaminating class (Germany)
: WGK 2 water endangering VWVWS A4
Other regulations : The product is classified and labelled in accordance with EC
directives or respective national laws. Regional or national implementations of GHS may not imple-ment all hazard classes and categories.
15.2 Chemical Safety Assessment
For a mixture it is not mandatory to include an exposure scenario in the material safety data sheet.
The necessary safety - related information is stated in the first 16 sections.
SECTION 16: Other information
Full text of H-Statements referred to under sections 2 and 3.
H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H372 Causes damage to organs through prolonged or repeated exposure if
inhaled. H373 May cause damage to organs through prolonged or repeated exposure
if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects.
Full text of Notas referred to under section 3
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Note H (Table 3.1) The classification and labelling shown for this substance applies to the hazardous property(ies) indicated by the hazard statement(s) in combi-nation with the hazard class(es) and category(ies) shown. The require-ments of Article 4 for manufacturers, importers or downstream users of this substance apply to all other hazard classes and categories. For hazard classes where the route of exposure or the nature of the effects leads to a differentiation of the classification of the hazard class, the manufacturer, importer or downstream user is required to consider the routes of exposure or the nature of the effects not already considered. The final label shall follow the requirements of Article 17 and of section 1.2 of Annex I.
Note N The classification as a carcinogen need not apply if the full refining his-tory is known and it can be shown that the substance from which it is produced is not a carcinogen. This note applies only to certain complex oil-derived substances in Part 3.
Note P The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0,1 % w/w benzene (EINECS No 200-753-7). When the substance is not classified as a carcinogen at least the precautionary statements (P102-)P260-P262-P301 + P310-P331 (Table 3.1) or the S-phrases (2-)23-24-62 (Table 3.2) shall apply. This note applies only to certain complex oil-derived substances in Part 3.
Further information
The information provided is based on our current knowledge and experience and apply to the product as delivered. Regarding the product properties, these are not guaranteed. The delivery of this safety datasheet does not free the recipient of the product from his own responsibility to follow the relevant rules and regulations concerning this product. . This data sheet contains changes from the previous version in section(s): 3