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Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

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מגמות במחקר סולארי בעולם ובישראל : לאיפה אפשר להגיע ומה דרוש. Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials Bar-Ilan University, Israel. The Need/Challenge: 10TW Renewable Energy. - PowerPoint PPT Presentation
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Page 1: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Arie ZabanDepartment of Chemistry

Institute for Nanotechnology and Advanced MaterialsBar-Ilan University, Israel

ובישראל בעולם סולארי במחקר : מגמותדרוש ומה להגיע אפשר לאיפה

Page 2: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

14 MW power plant at the Nellis Air Force Base (south Nevada).~30 million kilowatt-hours (30MWh) of electricity annually. Expected to reduce carbon dioxide emissions by 24,000 tons/year.

Contraction cost: $100 million. Land: 140 acres (570 dunam). The company that owns the panels is leasing the land at no cost, and Nellis is agreeing to buy the power for 20 years at about 2.2 cents/kWh, instead of the 9 cents they are paying to Nevada Power, saving the Air Force $1 million each year. None of the $100 million cost came from the Air Force.

North America’s Largest Solar-Electric Plant Switched On (28/12/2007)

The Need/Challenge: 10TW Renewable Energy

Page 3: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

14 MW power plant at the Nellis Air Force Base (south Nevada).

North America’s Largest Solar-Electric Plant Switched On (28/12/2007)

One plant, every hour,

for the next: 81 years

The Need/Challenge: 10TW Renewable Energy

Page 4: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

One plant, every hour,

for the next: 81 years

The Need/Challenge: 10TW Renewable Energy

2012 installation = 24GW• one plant every 5 hrs.• >150G$

Page 5: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Research Goals

Energy Cost ($/KWh)

system cost ($/m2)

system efficiency (%)

effective sun (KWh/m2)

Page 6: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Best Research Cell Efficiencies

Page 7: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

0

1E+27

2E+27

3E+27

4E+27

0 1 2 3 4hn (eV)

phot

ons/

(m2 eV

)Single-Bandgap PV and the Solar Spectrum (AM 1.5)

Page 8: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Prince, JAP 26 (1955) 534Loferski, JAP 27 (1956) 777

Optimal Bandgap for Single Junction PV

Page 9: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Best Research Cell Efficiencies

Page 10: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Production, Laboratory, Theoretical PV Module Efficiency

Page 11: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Global PV Module Price Learning Curve for c-si Wafer-Based and CdTe Modules, 1979 To 2015

Page 12: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

0

1E+27

2E+27

3E+27

4E+27

0 1 2 3 4hn (eV)

phot

ons/

(m2 eV

)Multi-Bandgap PV and the Solar Spectrum (AM 1.5)

Page 13: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

• cost • concentration• current matching

Multi-Bandgap Photovoltaics

Page 14: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

With optical losses

Bennett and Olsen, 1988, IEEE PVSC, p. 868

Maximum Efficiency for Ideal Multi-Bandgap PV

Page 15: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Best Research Cell Efficiencies

Page 16: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Production, Laboratory, Theoretical PV Module Efficiency

Page 17: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Third Generation Options

Page 18: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Up-Conversion for a Single Junction

0

1E+27

2E+27

3E+27

4E+27

0 1 2 3 4hn (eV)

phot

ons/

(m2 eV

)

Down-Conversion for a Single Junction

Third Generation Options

Page 19: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Third Generation Options

Multiple exciton generation (MEG)

Phonon cooling

Auger recombinationMEG

Phonon cooling

Page 20: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Third Generation Options

Luminescent solar concentrators

Plasmonic solar cells

Antenna-based solar cells

Page 21: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Best Research Cell Efficiencies

Page 22: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Best Research Cell Efficiencies: Emerging PV

Page 23: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Research Goals

Energy Cost ($/KWh)

system cost ($/m2)

system efficiency (%)

effective sun (KWh/m2)

Page 24: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

System Cost

Light collection (wave guide effect)

Anti reflection coating

Charge collection

Page 25: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Combinatorial Material (Absorber) Library

Co3O4 All-Oxide PV:combinatorial material science

conductance

Page 26: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Bright Future Needs:

Co3O4 • Basic science• Material science• Long term funding (fuel replacement program)• Centers of excellence (nano)• Partnership with industry

Page 27: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

7 למאורת ב7רקיע הש7מים, על להאירוהיו.הארץ

and let them be lights in the expanse of the sky to give light on (upon) the earth.

Thank You

Page 28: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

The Photovoltaic (PV) Mechanism

cosT breakdown of currenT convenTional pv sysTems in The

uniTed sTaTes , 2010

Page 29: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

The Photovoltaic (PV) Mechanism

average worldwide pv module price level and Their cosT sTrucTure by

Technology (2010).

Page 30: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Production, Laboratory, Theoretical PV Module Efficiency

Page 31: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

QDSSCs: Co-Sensitization (in series)

Page 32: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

Low Cost Multi-Bandgap Solar CellsTwo Bands Spectral Splittingwith David Cahen and Igor Lubomirsky, WIS

Page 33: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

hu

refractive index matching

low band-gap PV

medium band-gap PV

high band-gap PV

Waveguide Based PV System

Page 34: Arie Zaban Department of Chemistry Institute for Nanotechnology and Advanced Materials

CdSe-QR Sensitized Solar Cell: Dipole Effect

Sample (nm)Voc (mV)

Jsc (mA/cm2)

FF (%)

η (%)

5.0 QDs 531 7.81 52 2.1440x5.0 QRs 564 9.68 49 2.69

Nano Lett. (2012), 12, 2095


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