Synthetic glyco-O-sulfatome for profiling of human natural antibodies

Supplementary data

Galina Pazynina, Marina Sablina, Tatiana Ovchinnikova, Tatiana Tyrtysh, Svetlana Tsygankova,

Alexander Tuzikov, Kira Dobrochaeva, Nadezhda Shilova, Nailia Khasbiullina, Nicolai Bovin*

Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, ul.

Miklukho-Maklaya 16/10, Moscow, 117997, Russian Federation.

* professorbovin@yandex.ru (N.V. Bovin), phone +7 495 330 0300, fax +7 495 330 5592.

Table of Contents

1H NMR spectrum of compound 2 4

13C NMR spectrum of compound 2 5

1H NMR spectrum of compound 3 6

13C NMR spectrum of compound 3 7

1H NMR spectrum of compound 4 8

13C NMR spectrum of compound 4 9

1H NMR spectrum of compound 5 10

13C NMR spectrum of compound 5 11

1H NMR spectrum of compound 9 12

13C NMR spectrum of compound 9 13

1H NMR spectrum of compound 10 14

13C NMR spectrum of compound 10 15

1H NMR spectrum of compound 12 16

13C NMR spectrum of compound 12 17

1H NMR spectrum of compound 13 18

13C NMR spectrum of compound 13 19

1H NMR spectrum of compound 15 20

13C NMR spectrum of compound 15 21

1H NMR spectrum of compound 16 22

13C NMR spectrum of compound 16 23

1H NMR spectrum of compound 17 24

13C NMR spectrum of compound 17 25

1H NMR spectrum of compound 34 26

1H NMR spectrum of compound 35 27

1H NMR spectrum of compound 37 28

1H NMR spectrum of compound 40 29

1H NMR spectrum of compound 41 30

1H NMR spectrum of compound 43 31

13C NMR spectrum of compound 43 32

1H NMR spectrum of compound 44 33

13C NMR spectrum of compound 44 34

1H NMR spectrum of compound 45 35

13C NMR spectrum of compound 45 36

1H NMR spectrum of compound 54 37

1H NMR spectrum of compound 55 38

1H NMR spectrum of compound 58 39

13C NMR spectrum of compound 58 40

1H NMR spectrum of compound 59 41

1H NMR spectrum of compound 60 42

13C NMR spectrum of compound 60 43

1H NMR spectrum of compound 61 44

13C NMR spectrum of compound 61 45

2

1H NMR spectrum of compound 64 46

1H NMR spectrum of compound 68 47

1H NMR spectrum of compound 70 48

1H NMR spectrum of compound 72 49

13C NMR spectrum of compound 72 50

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2

4

2

5

3

6

3

7