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1.0 TRANSPORTATION
Relevant statutory transport documentation must be accompanied with all wastes that been
delivered to the site. This is to enable tracking of waste from the generators to the treatment
facility. The used of curtain-sider trucks, tipper trucks, skip bin and IMO tanks for 1, 3, 8, 12 and
20 tonnes will be comprised. Besides the mandatory colour requirement by DOE, the trucks are
painted in the companys corporate colours. To meet European standards, the trucks are
specially designed and are approved by the Malaysian Department of Environment. To ensure
that scheduled wastes are safely transported from waste generators premises to the WMC, all
trucks are then equipped with the necessary safety and communication equipment. All waste
will not be accepted onto the site unless all criteria have been complies with and no adverse
environmental, safety or health impacts will result from its treatment. To trace the movement of
treated solidified waste from the treatment plant to the licensed disposal facility, similar
documentation will be used.
The packaging of the waste, labelling of containers, vehicle requirements and licensing
including driver training, licensing and responsibilities, loading of the vehicle and securing of the
load, placarding of the vehicle and transport documentation, are included in these transport
requirements. For liquid or sludge hazardous substances are normally use tank containers and
have to be specially designed to cope with such loads. Normally, packaged waste material is
transported in open trucks or in large quantities on flatbed truck. It is of utmost importance that
the compatibility of waste materials in a mixed should be observed since even a slight leak
between non-compatible waste components may result in a fire on the vehicle or in worst case
even an explosion in such instances. With regard to identification and placards for transport
purposes, Hazardous Waste should be controlled in the same way as the hazardous
substances. In addition, governments regulatory bodies have set three transport requirements
which is waste card system, orange box and emergency response plan.
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2.0 COLLECTION PROCEDURE
HOW DO I FILL IN A STANDARD (SINGLE MOVEMENT) CONSIGNMENT NOTE?
The description of the note in this guide is a description of the Environment Agency
consignment note. Before the hazardous waste is collected from your site, you need to start
filling in the top sheet (the Producers/Consignors/Holders Copy) of the consignment note. As
you write on the top sheet, the information will be copied to the sheets below. Each of the
consignment note copies is divided into five sections, parts A to E. We explain below how to fill
in each part of a consignment note.
Part A Notification details
The producer or holder of the waste should fill in this section.
1 Consignment note code
We set the format of the consignment note code. You must follow this format; otherwise your
consignment note will not be valid. The consignment note code must be unique. If you use acode for one load, you must not use that number again for another. The consignment note code
depends on whether your site is exempt from registration or needs to be registered. You should
look at HWR02ADo I need to notify my premises? if you are not sure.
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If your site is exempt from registration, the consignment note code must be EXEAAA/YYYZZ (or
FLYAAA/YYYZZ), where:
- EXE shows that the collection is exempt (FLY shows that the waste was fly-tipped and
breaking section 33 of the Environmental Protection Act 1990 as a result);
- AAA can be any letters or numbers (for example, the first three letters of the name of the
waste-collection business, or the postcode of the place the
fly-tipping took place);
- YYY is any letters or numbers showing the trading name for the premises; and
- ZZ is any letters or numbers used to give the waste a unique code.
For example, if Bobs Waste were collecting the waste from a company called E B
Aardvark, the consignment note code could be EXEBOB/EBA01 or EXEBOB/EBAG1.
If you need to register your site, the consignment note code must be REGNUM/YYYYY, where:
- REGNUM is the registration number we gave you when you registered your premises with us
it will have the format XXXNNN (X is a letter, N is a number), for example, ABC049; and
- YYYYY is any letters or numbers (for example, HW02L).
For example, the consignment note code could be ABC049/HW02L.
2 The waste described below is to be removed from (name, address, postcode,
telephone, email, facsimile):
8 Environment Agency HWR03A Consignment notes - standard procedure
These are the details of the place the hazardous waste is being removed from.
If your premises are registered, the name, address and postcode on the form must match the
details given to us when the site was registered..
If the site is exempt from registration, the details must fully describe the place the waste is being
removed from.
You will need to provide a postcode for the consignment to be properly completed. If your site
does not have a postcode, you must give the nearest known full postcode to the site.
If you have a phone number, e-mail address or fax number, enter these details too.
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3 Premises code (where applicable):
If the premises are registered with us, you should enter the premises code here. This is the
registration number we gave the premises when they were registered. If the premises are
exempt from registration, write N/A or Exempt here.
4 The waste willbe taken to (name, address & postcode):
This provides details about the site the hazardous waste is going to be delivered to (that is, the
consignee). You must provide full details of the consignee, and any consignee you choose to
send waste to must either hold a permit to receive your waste or be exempt from holding a
waste permit. You are responsible for making sure this is the case. If the consignee holds a
waste permit, the name, address and postcode you give on the form should match the name,
address and postcode on the consignees permit.
5 The waste producer was (if different from 2) (name, address, postcode,
telephone, e-mail, facsimile):
If the waste producers details are the same as those in part A2, you can write As A2 here. If
the producer is different, you must give the producers details. For example, if the waste is
asbestos and a contractor produced it at your facility, you need to identify the asbestos
contractor as the waste producer and enter their business address here.
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Part B Description of the waste
The producer or holder of the waste should fill in this section.
You need to fill in part B for each type of hazardous waste that is being collected. You should
use continuation sheets if necessary.
1 Theprocess giving rise to the waste(s) was:
You should provide a full written description of the process that created the waste. It is not
enough to just enter Manufacturing. If you are moving more than one type of hazardous waste
which has been produced by more than one process, you should describe the main production
process involved in creating the waste.
2 SIC for the process giving rise to the waste:
The SIC (or Standard Industrial Classification) is a coding scheme that classifies businesses
and other economic activities. You must provide the most detailed SIC code from the 2003
version of the scheme for the main activity that produced (or holds) the waste. If the premises
are registered with us, you need to give the SIC code for the main waste-producing activity on
the premises. The SIC you give on the consignment note is not necessarily the code you were
given at the time you registered the premises, but is the code used for the actual process that
created the hazardous waste described on the note. If you are moving more than one type of
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waste which has been produced by more than one process, you should give the SIC for the
main production process involved in creating the waste.
For more details on the SIC 2003 code, see
www.environment-agency.gov.uk/business/topics/waste/32198.
10 Environment Agency HWR03A Consignment notes - standard procedure
3 WASTE DETAILS
You must fill in all of the following for each type of hazardous waste you are having collected.
Description of waste
If you are using a consignment note your contractor has provided, this section might be called
The waste is:.
You need to provide a written description of every type of hazardous waste you are having
collected.
The description must not simply reproduce the description from the List of Waste Regulations
(LoWR), which is the catalogue of all types of waste. You must provide a full description. For
example, it is not enough to describe a waste acid from a pickling process as pickling acids
(the description in the LoWR for code 11 01 05). You should instead write something like
sulphuric acid used for pickling.
You must not write Laboratory chemicals as a type of waste. Instead, you must separately
identify each chemical in the hazardous waste. If you do not have enough space to record all of
the details on one row of the table, use both rows. You can use continuation sheets for other
types of hazardous waste you are having collected.
List of Wastes (EWC) code (6 digits):
You should choose an appropriate EWC code for each type of hazardous waste. The code
should match the description of the waste and the business or process that produced it. You
can get help on choosing an EWC code from our guide WM2 -
Interpretation of the definition and classification of hazardous waste, which you can find at
www.environment-agency.gov.uk/static/documents/GEHO0603BIRB-e-e.pdf
Quantity (kg):
You must give the quantity (total weight), in kilograms, of each type of hazardous waste that has
an EWC code. This should be the total weight of the waste the carrier is actually collecting. If
the hazardous waste is a liquid, you can show the weight in kilograms by using a suitable
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method to convert the volume of the liquid to its equivalent weight. If you do not have a suitable
method for doing this, convert one litre into one kilogram.
The chemical/biological components of the waste and their concentrations are:
You should give details of all the relevant chemical or biological parts (components) of the
waste and their concentrations so that carriers, consignees or other people can see what is in
each type of hazardous waste. This will also include parts of the waste that do not make it
hazardous (for example, metals such as iron in pickling acids).
Properly describing all the components of the waste is important in choosing how to dispose of
the waste.
Physical form (gas, liquid, solid, powder, sludge or mixed)
You should write either Gas, Liquid, Solid, Powder, Sludge or Mixed for each type of
waste that has an EWC code.
Hazard code(s)
You must give this information for all of the hazards appropriate to each hazardous waste. The
hazardous properties are set out in appendix B. You must provide the correct hazards for each
type of the wasteit is not enough to put H1 toH14.
Container type, number and size
You must give the number and size of each container of hazardous waste (for example, 4 x 45
gallon drums, 1 x 14 cubic yard skip).
UN identification number(s), Proper shipping name(s), UN Class(es),
Packing group(s) and Special handling requirements
You need to fill in these sections if the hazardous waste is also dangerous for carriage. See
appendix C for more details.
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1 Carrier name:, On behalf of (name,address, postcode, telephone, e-mail,
facsimile):
The carrier must give their name, the name of their business and all appropriate address and
contact details.
2 Carrier registration no./reason for exemption:
A carrier must either be registered or exempt from registration. The carrier must give their
registration number if they have one. If the carrier is exempt, they should give the reason for the
exemption (for example, a waste producer can transport their own 12 Environment Agency
HWR03A Consignment notes - standard procedure waste without being a registered waste
carrier). However, producers of construction and demolition waste must always be registered as
a carrier. It is good practice to regularly check that the details the carrier has given are correct.
A carrier registration is valid for three years, and we may revoke (cancel) it in certain
circumstances. You can check if the carrier has a valid registration by looking at the online
electronic public register on our website or by contacting us on 08708 506506.
The carriers registration details must be those of the actual carrier. So, if a subcontractor has
been used, the subcontractors registration details must be given, not the main contractors
details.
3 Vehicle registration no. (or mode of transport, if not road):
The carrier must enter the registration number of the vehicle they are using to collect the
hazardous waste. If the waste is not being carried by road, the carrier must identify which
method of transport they are using (for example, railway, canal barge and so on).
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Part D Consignors certificate
After they have filled in part C, the carrier should give you the consignment notes back. You, as
the consignor, should then sign part D of the note.
There is a declaration in part D. You need to check that you have filled in parts A and B
correctly and that the carrier has filled in part C. In part C the carrier writes his carrier
registration numberby signing part D, you are declaring that you have checked the carrier is
registered.
You are also declaring that the waste is packaged and labelled correctly. If you are aware of any
particular issues relating to how the waste should be handled, you should tell the carrier about
them.
Note: You should not fill in part D before the carrier has arrived to collect the waste and has
given you copies of the consignment note, with part C filled in, for you to check.
1 Consignor name:, On behalf of (name, address, postcode, telephone, e-mail,
facsimile):
Environment Agency HWR03A Consignment notes - standard procedure 13
You must give your name, the name of your business and all appropriate address and contact
details. If these are the same as in part A2, you can write As A2. When you have checked and
filled in the details above, you should sign part D. You can then enter the date and time (using
the 24-hour clock) that you signed the form.
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HAZARDOUS WASTE LABELLING AND MARKING
A critical step in the safe handling of a hazardous waste is labelling and marking all containers
accordingly. To ensure uniformity in the labelling and marking of containers while the waste is
being accumulated to its ultimate disposal, both the US Department of Transportation (DOT)
and US Environmental Protection Agency (EPA) offer specific regulatory guidance for
hazardous waste generators to follow. It is important to note that these requirements are
different from the OSHA hazardous communication standard (29 CFR 1910.1200), which offers
labelling guidance for hazardous waste materials that have not been designated as waste.
DOT Bulk vs. Non-bulk Packages
Because the DOT hazardous waste labelling and marking requirements are different based on
the size of the container, it is important to distinguish between bulk and non-bulk packages.
Non-Bulk Packages
Under 49 CFR 171.8 non-bulk packaging is defined as packaging which has:
A maximum capacity of 450-liters (119-gallons) or less as a receptacle for a liquid
A maximum net mass of 400-kilograms (882-pounds) or less and a maximum capacity of 450-
liters (119-gallons) or less as a receptacle for a solid
A water capacity of 454-kilograms (1,000-pounds) or less as a receptacle for a gas as defined
in 49 CFR 173.115
Bulk Packages
Under 49 CFR 171.8, a bulk package is defined as a packaging, other than a vessel or a barge,
including a transport vehicle or freight container, in which hazardous waste materials are loaded
with no intermediate form of containment and which has:
A maximum capacity greater than 450-liters (119-gallons) as a receptacle for a liquid
A maximum net mass greater than 400-kilograms (882-pounds) and a maximum capacity
greater than 450-liters (119-gallons) as a receptacle for a solid
A water capacity greater than 454-kilograms (1,000-pounds) as a receptacle for a gas as
defined in 49 CFR 173.115
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While the DOT guidelines for properly labelling and marking non-bulk and bulk containers are
similar, they are not the same. This document outlines the rules for non-bulk packaging.
Hazardous Waste Labelling vs. Marking
The DOT reference to a label is very specific. Labels refer to the diamond-shaped hazmat logos
placed on non-bulk containers, and resemble bulk container placards. Everything else on a non-
bulk package is a marking.
Hazardous Waste Labelling
The design and size of labels are based on international standards and are used to identify the
hazards within the container. Each diamond (square-on-point) label measures at least 100mm
(4" x 4") on each side as prescribed in 49 CFR 172.407(c)(1).
DOT Hazardous Waste Label Examples:
Placement of Hazardous Waste Labels
The proper placement of labels is important. Labels must appear in their entirety because the
specified size, print style, border, width, and color of labels. Labels should be located near any
markings and on the same surface. Labels should not be placed on the bottom of containers.
They should always be visible.
http://www.grainger.com/search/material-handling/ecatalog/N-bih/Ntt-DOT+Labelhttp://www.grainger.com/search/material-handling/ecatalog/N-bih/Ntt-DOT+Label8/13/2019 Assignment Envi Tinggal Anep Je
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Multiple Hazardous Waste Labels
If the waste has multiple hazards associated with it multiple labels should be displayed next to
each other. The DOT recommends a six- inch space (15 cm) between labels. The label
designating the primary hazard should be above and to the left of the label designating the
subsidiary hazard.
Hazardous Waste Labels and Overpacking
Whenever hazardous material packages are overpacked, the inner containers must be properly
labelled. The same applies to the overpack container.
Hazardous Waste Markings
Marking is a critical process in preparing hazardous materials for transportation. A marking on a
hazardous materials package contains important information about the identification and
dangers of the hazardous material. While there is no standardized hazardous waste marker
format, both the DOT and EPA have specific marking requirements.
While there is no standardized hazardous waste marking format, the following general
guidelines should be followed when placing markings on hazardous packages:
Markings must be durable
Markings must be in English
Markings must be printed on or affixed on the surface or on a label, tag or sign
Markings must be displayed on a contrasting color background
Markings must not be obscured or covered up by other labels or attachments
Markings must not be located next to any other markings (such as advertisement) that would
limit their effectiveness
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Hazardous Waste Markings and Overpacking
As mentioned above with the labelling requirements, whenever hazardous material packages
are overpacked, the inner containers must be properly marked. The same applies to the
overpacking.
DOT Hazardous Waste Marking Requirements
There are five components of a DOT marking on a non-bulk package.
Proper shipping name and identification number
Technical name (if required)
Special permit number
Consignors or consignees name and address
Special hazard warning
Proper Shipping Name and Identification Number
This information can be found in the hazardous materials table, 49 CFR 172.101. If the material
is considered to be a hazardous waste, the word waste must be included with the proper
shipping name. The format for properly displaying the shipping name for a hazardous waste is:
Waste (shipping name), (hazard class), (UN or NA number), (packing group)
Example: Waste Acetone, 3, UN1090, PGII
Technical Name
If the shipping name being used is a non-chemical specific shipping name, a technical name(s)
is required for additional clarification. A non-chemical specific shipping name, as defined in 49
CFR 172.203(k), can be easily identified by the shipping name. Any shipping name that ends in
N.O.S. (not otherwise specified) must be marked with the technical name(s) in parentheses in
association with the proper shipping name. The technical name should correspond to the
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hazardous ingredients of the waste, which can be found on the Material Safety Data Sheet
(MSDS).
Example: Waste Flammable Liquids, n.o.s. (Xylene, Toluene), 3, UN1993, PGII
Special Permit
Occasionally, hazardous materials may be placed inside a package, which was issued under a
special permit by the DOT. If a special permit package is used, the container should be marked
DOT-SP followed by the special permit number assigned by the US DOT.
Consignors or Consignees Name and Address
The consignor is the party offering a hazardous material shipment for transportation. The
consignee is the party receiving the hazardous material shipment.
Special Hazard Warning
When offering a hazardous material, which has a special hazard (e.g inhalation hazard, marine
pollutant), the shipper must indicate this hazard on the marking.
Other DOT Non-Bulk Package Markings
Along with the hazardous waste marking requirements, there may be addition markers that are
required. For example:
This End Up Marking
This marking is the package-orientation marking. It is applied to any package which holds inner
containers of liquid hazardous materials. Inner packaging may be non-specification containers
made of glass or earthenware, plastic or metal.
All packages having inner packages containing liquid hazardous materials must be packed with
their closures upward and legibly marked with package-orientation arrows on two opposite
vertical sides and with the arrows pointing in the correct upright direction. Arrows for purposes
other than indicating proper package orientation may not be displayed on a package containing
a liquid hazardous material.
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EPA Hazardous Waste Marking Requirements
The EPA requires certain information to be shown on containers of 110 gallons or less used in
transportation. This information is listed below.
Hazardous Waste Warning Statement
The following statement must be included on non-bulk packages: HAZARDOUS WASTE:
FEDERAL LAW PROHIBITS IMPROPER DISPOSAL. IF FOUND, CONTACT THE NEAREST
POLICE, OR PUBLIC SAFETY AUTHORITY, OR THE U.S. ENVIRONMENTAL PROTECTION
AGENCY.
Generators Name and Address
This is the same as the consignors address.
Generators EPA Identification Number
This is a twelve-digit number assigned by the EPA to each hazardous waste generator. It is also
included on the hazardous waste manifest.
Manifest Document Number
This is a five-digit number which is assigned by the generator. It is unique for each shipment.
Accumulation Start Date
This date is determined by the generator. It is the date that the generator first placed a
hazardous waste inside the package. There are time limits related to the amount of time a
generator can accumulate hazardous waste at its site. Consequently, this date is very important.
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EPA Waste Codes
In order for a hazardous material to be classified as a waste, it must carry an EPA waste code.
Waste codes provide more information regarding the specific hazards associated with the
waste. For more information on identifying the proper waste code, refer to 40 CFR 261.
Example Hazardous Waste Marking:
1. Hazardous warning statement
2. Generator name and address
3. Generator EPA ID number
4. Accumulation start date
5. EPA waste codes
6. Manifest document number
7. Proper shipping name, technical name, special hazard warning (if applicable) and DOT special
permits (if applicable)
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3.0 ANALYSIS
The typical parameters analysed for the amount of oily waste were SW305(55.6%), SW306
(9.3%), SW307 (7.4%), SW 309 (23.1%) and SW312 (4.6%) that includes heavy metal analysis,
Toxicity Characteristic Leaching Procedure (TCLP), oil and grease, total organic carbon, pH
value, total solids, total chlorine, calorific value, flash point, viscosity and polymerisation
reaction.
3.1 SW 305Spent lubricating oil
Heavy Metal Analysis
Elemental Analysis Atomic Absorption ppm (mg/l)
Element Symbol Detection Limit (ppm)
Sulphur S 8000
Calcium Ca 1200
Zinc Zn 650
Lead Pb 40
Phosphorous P 600
Iron Fe 100
Magnesium Mg 65Sodium Na 55
Silicon Si 40
Boron B 40
Manganese Mn 10
Copper Cu 40
Molybdenum Mo 15
Aluminum Al 15
Tin, Chromium, Barium,
Nickel, VanadiumSn, Cr, Ba, Ni, V
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Physical and Chemical Properties
Appearance: Transparent amber oil.
Physical state: Liquid/Oil.
Odor: Mineral oil odor
Odor threshold (ppm): Not established
Specific gravity (H2O=1): 0.870.90
Solubility in water (20C): Negligible
Solubility in fat: Not Determined.
Coefficient of water/oil solubility: Not Determined.
Partition coefficient (n-octanol/water): Not Determined.
Melting point: Liquid.
Boiling point: > 550F.
Evaporation rate (Butyl Acetate=1): < 0.01
Vapor Density (Air=1): > 5
Vapor Pressure (mm Hg): < 0.01
Oxidizing properties: Unknown.
Flash Point: 415 - 475 F (COC), (PMCC) ASTM D 93 C >60.5
(lower if contaminated with fuel or solvent)
Viscosity: @ 40C ASTM D 445 mm2/s +/-80
Polymerisation Reaction: Polymerisation is not known to occur under normal
temperatures and pressures. Hazardous
polymerisation will not occur.
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3.2 SW 306Spent hydraulic oil
Heavy Metal Analysis
Absorption Elemental Analysis Atomic ppm (mg/l)
Element Symbol Detection Limit (ppm)
Copper Cu 0.003
Magnesium Mg 0.0003
Chromium Cr 0.006
Tin Sn 0.1
Lead Pb 0.01
Iron Fe 0.006
Zinc Zn 0.001
Manganese Mn 0.002
Cadmium Cd 0.002
Physical and Chemical Properties
Physical state, appearance, and odor: Liquid, amber, petroleum odor.
Odor threshold: Not available
Molecular weight: Not applicable
Specific gravity: 0.88 (water = 7) (approximately)
Density: 7.3 LB/US gal (880 g/l) (approximately)
Vapor density: Not available
Vapor pressure: less than 0.1 mmhg at 68f (20c)
Boiling point: 475f (246c) (minimum)
Freezing/melting point: Not available [pour point -22f (-30c) (maximum)].
Evaporation rate: Not available
Solubility in water: Insoluble
Flammable limits in air: LOWER: Not available UPPER: Not available
Autoignition temperature: Not available
Ph Value: Not applicable
Flash Point: 193 oc (380 of)
Viscosity: 28.8 mm2/s (33 cst) @ 40C (104F) Minimum
Polymerisation Reaction: Hazardous polymerization will not occur under
normal working conditions.
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3.3 SW 307Spent mineral oil-water emulsion
Physical and Chemical Properties
Physical state and appearance: Liquid. (Transparent water-white liquid)
Odor: Odorless.
Taste: Not available.
Molecular Weight: Varies.
Color: Clear
Boiling Point: 310C (590F)
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: 0.835 @ 15.6 C (Water = 1)
Vapor Pressure: 100c
Viscosity: @ 40 oC mm2/s: N. A.
Polymerisation Reaction: Polymerization will not occur.
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3.4 SW 309Oil-water mixture
Physical and Chemical Properties
The following information is for the Argon component of this gas mixture:
Gas density: 0.103 lb/cu ft (1.650 kg/m3)
Evaporation rate (nBuAc = 1): Not applicable.
Specific gravity (air = 1): 1.38
Freezing point: -189.2C (-308.9F)
Solubility in water: 0.056
Boiling point ( @ 1 atmos.): -185.9C (-302.6F)
Expansion ratio: Not applicable.
Specific volume (ft3/lb): 9.71
Odor threshold: Not applicable.
Molecular weight: 39.95
Vapor pressure (psia): Not applicable.
Coefficient water/oil distribution: Not applicable.
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The following information is for the Carbon Dioxide component of this gas mixture:
Gas density: 0.1144 lb/ft3 (1.833 kg/m3)
Evaporation rate (nBuAc = 1): Not applicable.
Specific gravity (air = 1): 0.90
Freezing point: -78.5C (-109.3F) [sublimation]
Solubility in water: 0.0491
Boiling point( @ 1 atmos.): Sublimes.
Expansion ratio: Not applicable.
Specific volume (ft3/lb): 8.741
Odor threshold: Not applicable.
Molecular weight: 44.01
Vapor pressure (psia): Not applicable.
Coefficient water/oil distribution: Not applicable.
The following information is pertinent to this product:
Appearance, odor and color: This gas mixture is colorless and odorless, or may have a
sharp odor (depending on the level of Carbon Dioxide).
How to detect this substance (warning properties): There are no distinct warning properties
of this gas mixture, unless the Carbon Dioxide is at a high concentration, when the odor may be
a warning property. In terms of leak detection, fittings and joints can be painted with a soap
solution to detect leaks, which will be indicated by a bubble formation.
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3.5 SW 312Oily residue from automotive workshop, service station oil or grease
interceptor
Physical and Chemical Properties
Physical State and Appearance: Black viscous liquid, hydrocarbon odor.
Boiling point: 350 to 1200F
Odor Threshold: Not available
Melting or Solid Point: Not applicable
Specific Gravity: 0.88-1.02 @ 60F (typical)
Vapor Density: >5 (Air=1)
Vapor Pressure:
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4.0 TREATMENT
4.1 Solidification
For inorganic wastes which do not fulfill the criteria for disposal directly into the Secured Landfill,
solidification process is used. The process is carried in the Solidification Plant. Such wastes are
typically metal hydroxide sludge containing heavy metals such as arsenic, barium, boron,
cadmium, chromium, copper, lead, mercury, nickel, selenium, silver, tin and zinc. The heavy
metals become insoluble during the solidification process therefore can be safely disposed off in
the Secured Landfill. Other that can also be treated at Solidification Plant is fly ash from the
Incinerator Plant.
Figure 4.1: Solidification Process
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4.2 Physical-chemical Treatment
The Physical-Chemical Treatment Plant (PCT) treats inorganic liquid waste such as acid,
alkaline, chromate and cyanide. Generally, waste is detoxified through chemical process like
neutralization, oxidation and reduction. There are 5 categories in Physical-Chemical Treatment
Plant (PCT):
Chromate waste
Acid waste
Miscellaneous waste
Alkaline waste
Cyanide waste
Figure 4.2: Physical-Chemical Treatment Process
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4.3 Incineration
Two main sections can be divided for the Incineration Process which is Operation of Organic
Waste Feed Preparations (or Pre-Treatment) and Incineration Process (or Thermal Destruction
Process). For Incineration Process (or Thermal Destruction Process), there are divided into 3
phases process which is Incineration / Combustion Phase, Heat Recovery Phase and Flue Gas
Cleaning Phase.
Figure 4.3: Incineration Process
Incinerat
ion
Operation of Organic
Waste Feed Preparations(or Pre-Treatment)
Incineration Process (or
Thermal DestructionProcess)
Incineration / CombustionPhase
Heat Recovery Phase
Flue Gas Cleaning Phase
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4.3.1 Organic Waste Feed Preparations (Pre-treatment Facility)
The primary function of a feed preparation systems are:
1. To produce more uniform chemical properties such as moisture and organic content.
2. To avoid jamming of feeding mechanisms
Figure 4.4: Pre-Treatment Flow
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4.3.2 Thermal Destruction Process
For Thermal Destruction Process, the process can be divided into 3 phases :
1. Incineration / Combustion Phase
2. Heat Recovery Phase
3. Flue Gas Cleaning Phase
4.3.2.1 Incineration/Combustion Phase
The rotary kiln can operate in a wide range of conditions and therefore can handle a wide range
of wastes. The destruction of organics is determined by temperature, time and turbulence
factors.
TEMPERATURE
Temperaature iscritaical becauseit determines therate of organic
destruction.
TIME
Time refers tothe length oftime that thegases are presentor residencetime.
TURBULENCE
The ability of
the combustionsystem tosufficiently mixthe gases withoxygen tooxidise theorganicsreleased fromthe fuel andwastes.
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Figure 4.5: Rotary Kiln
4.3.2.2 Heat Recovery Phase
Basically, for Heat Recovery Phase, a series of process to cool down the Flue gas before Flue
gas cleaning process takes place. The Flue gas is then is cooled by using atomized water.
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4.3.2.3 Flue gas cleaning phase
Mainly, the Flue gas cleaning phase consists of Dry Absorption System (DAS) which includes a
reactor, fabric filter, ID fans and wet scrubbing system where the flue gas is cleaned and
released into the atmosphere via stack.
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5.0 DISPOSAL
Diposal of Waste Oil
There are many types of oils produced from heavy industries such as crude oils, lubricating oils,
heavier grades of fuel oil. If these oils are not managed well, these oils can cause harm tohuman, animals, plants and nature as these oils also consider as one of the hazardous wastes.
Disposal is included in five distinct steps of Waste Heirarchy. There are many options of
disposal are available but the actions taken is depend on the types of waste oil. As global
environmental awareness increases and regulatory requirements concerning waste disposal
become stricter, innovative and more creative ways of using, recycling or disposing of waste are
likely to be needed.
Below table showed a summary of the main options available for disposing waste oil:
Type of material Separation methods Disposal options
Non-emulsified oils
and waste water
Settling separation of free
water
Recovered water may require
further treatment/filtration
Use of recovered oil as fuel or
refinery feedstock
Return treated water to
source
Emulsified oils Emulsion broken to release water by:
Heat treatment
Emulsion-breaking chemicals
Use of recovered oil as fuel or
refinery feedstock
Stabilisation and reuse
Incineration
Oil mixed with sand Collection of liquid oil leaching
from sand during temporary
storage
Extraction of oil from sand by
washing with water or solvent
Removal of solid oils or
tarballs by sieving
Use of recovered liquid oil as
fuel or refinery feedstock
Return treated water to
source
Stabilisation and reuse
Degradation through land
farming or composting
Landfill
Incineration
Oil mixed with
cobbles, pebbles or
Collection of liquid oil leaching
from beach material during
Return cleaned stones to
source
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shingle temporary storage
Extraction of oil from beach
material by washing with water
or solvent
Stabilisation and reuse
Landfill
Oil mixed with wood,
plastics, seaweed,
shellfish and
sorbents
Collection of liquid oil leaching
during temporary storage
Flushing of oil from debris with
water
Removal of free water
Compression
Stabilisation and reuse the
following removal of plastics
and large debris
Degradation through land-
farming or composting for oil
mixed with seaweed, shellfish
or natural sorbents
Landfill
Incineration
Tarballs Separation from sand by
sieving
Stabilisation and reuse
Landfill
Incineration
But mostly the industries choose incineration as the main option for disposal of waste oil. The
advantage of this way is can be employed for many types of oiled material and permanent
storage not required which can reduce amount of wastes.
Oily wastes must be handled with care. The disposal of waste oils must be done according to
the local regulations. Consultation with regulatory and licensing authorities from outset of the
incident will assist with this important administrative component of the disposal process.
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6.0 RECYCLING AND RECOVERY
Collection Procedures for Recycling and Recovery of Scheduled Wastes
The recovery and reuse of materials from wastes is recycling. Solid waste recycling refers to the
reuse of manufactured goods from which resources such as steel, copper, or plastics can be
recovered and reused. Recycling and recovery is only one phase of an integrated approach to
solid waste management that also includes reducing the amount of waste produced, reuse
where possible, recycle the products at the end of their useful life, recover energy or material
from the waste stream, treatment of the waste product and lastly landfill disposal. Figure below
shows the hierarchy of recycle and recovery option where the lower is the least favoured option.
6.1. Collection Procedures for Recycling and Recovery of Scheduled Wastes
The process of solid waste management starts from scheduled waste at waste generators
(customer) premises. This waste sample is then will be sent to Schedule Waste Solution in
order to get advises from them upon recycling and recovery cost. Then, the customer will file
Scheduled Waste Information form, sign Scheduled Waste Recycling and Recovery Agreement
and Transportation from Waste Generator form. Before Schedule Waste Solution collects the
waste from the premises, the customer need to pack and labels the waste. This waste is then
will be transport to waste management center.
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Then, Schedule Waste Solution will conduct the conformity test on the waste. If the test meets
the sample sent, Schedule Waste Solution will issue an invoice to the customer within 15 days.
If the test does not meet the sample sent, Schedule Waste Solution will advice the customer
about the test result and cost for customers consent. If the customer agrees with the conformity
declaration, invoice will be issued within 15 days. If the customer objects the test result,
Schedule Waste Solution will return the waste to waste generators premises. The process flowof scheduled waste collection procedure is as below.
No
Schedule Waste Solution returns waste.
Customer bears costs incurred
Schedule Waste Solution advices customer on
test results and costs
Schedule Waste Solution invoices customer
15 days after collection
Conformity with Waste Declaration/results of
test
Schedule Waste Solution collects wastes and
transports to WMC*
Schedule Waste Solution conducts conformity
tests
Customer submit necessary forms for
processing; packs & labels waste
Schedule Waste Solution advises customer on
R&R costs
Waste Sample sent to Schedule Waste Solution
Scheduled wastes at Customers Premises
The Process Flow of Schedule Waste Collection Procedure
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7.0 RELATED REGULATIONS AND LEGAL REQUIREMENTS.
Constructing a new oily waste recovery plant needed regulations which sit under the
Environment Quality Act 1974 (EQA 1974). The legal requirements needed are as follows:
IN exercise of the powers conferred by sections 21 and 51 of the Environmental Quality Act 1974
[Act 127], the Minister, after consultation with the Environmental Quality Council, makes the
following regulations:
Citation and commencement
1. (1) These regulations may be cited as the Environmental Quality Act 1974
Interpretation
2. (1) In these Regulations, unless the context otherwise requires
"Scheduled wastes" means any waste falling within the categories of waste listed in
the First Schedule;
"Incompatible scheduled wastes" means scheduled wastes specified in the Fourth
Schedule which, when mixed, will produce hazardous situations through heat
generation, fires, explosions or the release of toxic substances;
"on-site treatment facility" means a facility, other than a scheduled wastes
incinerator or a land treatment facility, located on a waste generator's site and that is
used solely to deal with scheduled wastes produced on that site;
Contractor means any person licensed by the Director General of Environmental
Quality 3 under subsection 18(1A) of the Act;
Waste generator means any person who generate scheduled wastes;
Prescribed premises means premises prescribed by the Environmental Quality
(Prescribed Premises) (Scheduled Waste Treatment and Disposal Facilities) Order
1989 [P.U. (A) 140/1989].
(2) Words and expressions which are not defined in these Regulations shall have the
same meaning as assigned to them in the Act and in the Environmental Quality
(Prescribed Premises) (Scheduled Waste Treatment and Disposal Facilities)
Order 1989.
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Notification of the generation of scheduled wastes
3. (1) Every waste generator shall, within 30 days from the date of generation of
scheduled wastes, notify the Director General of the new categories and quantities of
scheduled wastes which are generated.
(2) The notification given under sub-regulation (1) shall include the information provided
in the Second Schedule.
Disposal of scheduled wastes
4. (1) Scheduled wastes shall be disposed of at prescribed premises only.
(2) Scheduled wastes shall, as far as is practicable, be rendered innocuous prior to
disposal.
Treatment of scheduled wastes
5. (1) Scheduled wastes shall be treated at prescribed premises or at on-site treatment
facilities only.
(2) Residuals from treatment of scheduled wastes shall be treated or disposed of at 4
prescribed premises.
Recovery of material or product from scheduled wastes
6. (1) Recovery of material or product from scheduled wastes shall be done at prescribed
premises or at on-site recovery facilities.
(2) Residuals from recovery of material or product from scheduled wastes shall be
treated or disposed of at prescribed premises.
Application for special management of scheduled wastes
7. (1) A waste generator may apply to the Director General in writing to have the
scheduled wastes generated from their particular facility or process excluded from being
treated, disposed of or recovered in premises or facilities other than at the prescribed
premises or on-site treatment or recovery facilities.
(2) An application under sub-regulation (1) shall be submitted to the Director General in
accordance with the guidelines for special management of scheduled wastes as prescribed
by the Director General and shall be accompanied by fee of three hundred ringgit and shall
not be refunded.
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(3) If the Director General is satisfied with the application made under subregulation (1),
the Director General may grant a written approval either with or without conditions.
Responsibility of waste generator
8. (1) Every waste generator shall ensure that scheduled wastes generated by him are
properly stored, treated on-site, recovered on-site for material or product from such
scheduled wastes or delivered to and received at prescribed premises for treatment,
disposal or recovery of material or product from scheduled wastes.
(2) Every waste generator shall ensure that scheduled wastes that are subjected to
movement or transfer to be package, labelled and transported in accordance with the
guidelines prescribed by the Director General.
Storage of scheduled wastes
9. (1) Scheduled wastes shall be stored in containers which are compatible with the
scheduled wastes to be stored, durable and which are able to prevent spillage or leakage of
the scheduled wastes into the environment.
(2) Incompatible scheduled wastes shall be stored in separate containers, and such
containers shall be placed in separate secondary containment areas.
(3) Containers containing scheduled wastes shall always be closed during storage
except when it is necessary to add or remove the scheduled wastes.
(4) Areas for the storage of the containers shall be designed, constructed and
maintained adequately in accordance with the guidelines prescribed by the Director General
to prevent spillage or leakage of scheduled wastes into the environment.
(5) Any person may store scheduled wastes generated by him for 180 days or less after
its generation provided that
(a) the quantity of scheduled wastes accumulated on site shall not exceed 20
metric tonnes; and
(b) the Director General may at any time, direct the waste generator to send any
scheduled wastes for treatment, disposal or recovery of material or product from
the scheduled wastes up to such quantity as he deems necessary.
(6) A waste generator may apply to the Director General in writing to store more than
20 metric tonnes of scheduled wastes.
(7) If the Director General is satisfied with the application made under sub-regulation
(6), the Director General may grant a written approval either with or without conditions.
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Labelling of scheduled wastes
10. (1) The date when the scheduled wastes are first generated, name, address and
telephone number of the waste generator shall be clearly labelled on the containers that are
used to store the scheduled wastes.
(2) Containers of scheduled wastes shall be clearly labelled in accordance with the
types applicable to them as specified in the Third Schedule and marked with the scheduled
waste code as specified in the First Schedule for identification and warning purposes.
(3) No person is allowed to alter the markings and labels mentioned in sub-regulations
(1) and (2).
Waste generator shall keep an inventory of scheduled wastes
11. A waste generator shall keep accurate and up-to-date inventory in accordance with the
Fifth Schedule of the categories and quantities of scheduled wastes being generated,
treated and disposed of and of materials or product recovered from such scheduled wastes
for a period up to three years from the date the scheduled wastes was generated.
Information to be provided by waste generator, contractor and occupier of prescribed
premises
12. (1) A waste generator, contractor and occupier of the prescribed premises shall provide
information in accordance with the Sixth Schedule in the manner provided in this regulation.
(2) A waste generator shall complete Part I of the Sixth Schedule in six copies and
hand over the six copies of the Schedule to the contractor when the scheduled wastes are
delivered to him.
(3) The contractor shall, upon receiving scheduled wastes from a waste generator,
complete Part II of the Sixth Schedule in the six copies given to him by the waste generator
and shall thereafter immediately hand over two copies of the Schedule to the waste
generator who in turn shall submit a copy to the Director General within 30 days from the
date of transportation of the scheduled wastes.
(4) The contractor shall, within 10 days from the date of receipt of the scheduled
wastes, deliver the scheduled wastes to the occupier of any prescribed premises and hand
over the remaining four copies of the Sixth Schedule to the occupier.
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(5) The occupier of any prescribed premises shall, upon receiving scheduled wastes
from the contractor, complete Part III of all the remaining four copies of the Sixth
Schedule handed over to him by the contractor and shall, upon completion, retain one
copy and return a copy each to the contractor, the waste generator and the Director
General, within 20 days from the date of receipt of the scheduled wastes.
(6) If the waste generator fails to receive his copy of the Sixth Schedule from the
occupier of the prescribed premises referred to in sub-regulation (5) within 30 days from the
date of delivery of the scheduled wastes to the contractor referred to in subregulation (2),
he shall notify the Director General immediately and shall investigate and inform the
Director General of the result of his investigation.
(7) The waste generator, contractor or occupier of the prescribed premises shall
keep a copy each of the Sixth Schedule. The Sign copy of Sixth Schedule must be
retained as a record for at least three years from the date the scheduled wastes are
accepted by the prescribed premises.
Scheduled wastes transported outside wastes generators premises to be accompanied
by information
13. (1) Every waste generator shall provide information in accordance with the Seventh
Schedule in respect of each category of scheduled wastes to be delivered to the contractor
and shall give the Schedule to the contractor upon delivery of the waste to him.
(2) The waste generator shall inform the contractor of the purpose and use of the
Seventh Schedule.
(3) The contractor shall carry with him the Seventh Schedule for each category of
scheduled wastes being transported and shall observe and comply with the instructions
contained therein.
(4) The contractor shall, in the selection of transportation routes, as far as possible
avoid densely populated areas, water catchment areas and other environmentally
sensitive areas.
(5) The contractor shall ensure that all his employees that are involved in the
handling, transportation and storage of scheduled wastes attend training programmes.
(6) The contractor shall ensure that during the training programme each employee is
well informed on the purpose and use of the Seventh Schedule.
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Spill or accidental discharge
14. (1) In the event of any spill or accidental discharge of any scheduled wastes, the
contractor responsible for the waste shall immediately inform the Director General of the
occurrence.
(2) The contractor shall do everything that is practicable to contain, cleanse or abate
the spill or accidental discharge and to recover substances involved in the spill or
accidental discharge.
(3) The waste generator shall provide technical expertise and supporting assistance
in any clean-up operation referred to in sub-regulation (2).
(4) The contractor shall undertake studies to determine the impact of the spillage or
accidental discharge on the environment over a period of time to be determined by the
Director General.
Training Programme
15. Every waste generator shall ensure that all his employees involved in the identification,
handling, labelling, transportation, storage and spill response of scheduled wastes, attend
training programme.
Compounding of offences
16. (1) Every offence which consists of any omission or neglect to comply with, or any act
done or attempted to be done contrary to these Regulations may be compounded under
section 45 of the Act.
(2) The compounding of offences referred to in sub-regulation (1) shall be in
accordance with the procedure prescribed in the Environmental Quality (Compounding of
Offences) Rules 1978 [P.U. (A) 281/1978].
Revocation
17. The Environmental Quality Act (Scheduled Wastes) SWS Regulations is hereby
repealed as from the commencement of these Regulations.
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REFERENCES
http://www.3rdi.co.uk/pdf/EA_standard_movements_consignment_notes_and_guide.pdf
http://www.grainger.com/content/qt-322-hazardous-waste
http://www.environment-agency.gov.uk/business/topics/waste/32196.aspx
http://www.itopf.com/information-
services/publications/documents/TIP9DisposalofOilandDebris.pdf
http://www.3rdi.co.uk/pdf/EA_standard_movements_consignment_notes_and_guide.pdfhttp://www.3rdi.co.uk/pdf/EA_standard_movements_consignment_notes_and_guide.pdfhttp://www.grainger.com/content/qt-322-hazardous-wastehttp://www.grainger.com/content/qt-322-hazardous-wastehttp://www.environment-agency.gov.uk/business/topics/waste/32196.aspxhttp://www.environment-agency.gov.uk/business/topics/waste/32196.aspxhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.environment-agency.gov.uk/business/topics/waste/32196.aspxhttp://www.grainger.com/content/qt-322-hazardous-wastehttp://www.3rdi.co.uk/pdf/EA_standard_movements_consignment_notes_and_guide.pdf