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Assignment Envi Tinggal Anep Je

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    1.0 TRANSPORTATION

    Relevant statutory transport documentation must be accompanied with all wastes that been

    delivered to the site. This is to enable tracking of waste from the generators to the treatment

    facility. The used of curtain-sider trucks, tipper trucks, skip bin and IMO tanks for 1, 3, 8, 12 and

    20 tonnes will be comprised. Besides the mandatory colour requirement by DOE, the trucks are

    painted in the companys corporate colours. To meet European standards, the trucks are

    specially designed and are approved by the Malaysian Department of Environment. To ensure

    that scheduled wastes are safely transported from waste generators premises to the WMC, all

    trucks are then equipped with the necessary safety and communication equipment. All waste

    will not be accepted onto the site unless all criteria have been complies with and no adverse

    environmental, safety or health impacts will result from its treatment. To trace the movement of

    treated solidified waste from the treatment plant to the licensed disposal facility, similar

    documentation will be used.

    The packaging of the waste, labelling of containers, vehicle requirements and licensing

    including driver training, licensing and responsibilities, loading of the vehicle and securing of the

    load, placarding of the vehicle and transport documentation, are included in these transport

    requirements. For liquid or sludge hazardous substances are normally use tank containers and

    have to be specially designed to cope with such loads. Normally, packaged waste material is

    transported in open trucks or in large quantities on flatbed truck. It is of utmost importance that

    the compatibility of waste materials in a mixed should be observed since even a slight leak

    between non-compatible waste components may result in a fire on the vehicle or in worst case

    even an explosion in such instances. With regard to identification and placards for transport

    purposes, Hazardous Waste should be controlled in the same way as the hazardous

    substances. In addition, governments regulatory bodies have set three transport requirements

    which is waste card system, orange box and emergency response plan.

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    2.0 COLLECTION PROCEDURE

    HOW DO I FILL IN A STANDARD (SINGLE MOVEMENT) CONSIGNMENT NOTE?

    The description of the note in this guide is a description of the Environment Agency

    consignment note. Before the hazardous waste is collected from your site, you need to start

    filling in the top sheet (the Producers/Consignors/Holders Copy) of the consignment note. As

    you write on the top sheet, the information will be copied to the sheets below. Each of the

    consignment note copies is divided into five sections, parts A to E. We explain below how to fill

    in each part of a consignment note.

    Part A Notification details

    The producer or holder of the waste should fill in this section.

    1 Consignment note code

    We set the format of the consignment note code. You must follow this format; otherwise your

    consignment note will not be valid. The consignment note code must be unique. If you use acode for one load, you must not use that number again for another. The consignment note code

    depends on whether your site is exempt from registration or needs to be registered. You should

    look at HWR02ADo I need to notify my premises? if you are not sure.

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    If your site is exempt from registration, the consignment note code must be EXEAAA/YYYZZ (or

    FLYAAA/YYYZZ), where:

    - EXE shows that the collection is exempt (FLY shows that the waste was fly-tipped and

    breaking section 33 of the Environmental Protection Act 1990 as a result);

    - AAA can be any letters or numbers (for example, the first three letters of the name of the

    waste-collection business, or the postcode of the place the

    fly-tipping took place);

    - YYY is any letters or numbers showing the trading name for the premises; and

    - ZZ is any letters or numbers used to give the waste a unique code.

    For example, if Bobs Waste were collecting the waste from a company called E B

    Aardvark, the consignment note code could be EXEBOB/EBA01 or EXEBOB/EBAG1.

    If you need to register your site, the consignment note code must be REGNUM/YYYYY, where:

    - REGNUM is the registration number we gave you when you registered your premises with us

    it will have the format XXXNNN (X is a letter, N is a number), for example, ABC049; and

    - YYYYY is any letters or numbers (for example, HW02L).

    For example, the consignment note code could be ABC049/HW02L.

    2 The waste described below is to be removed from (name, address, postcode,

    telephone, email, facsimile):

    8 Environment Agency HWR03A Consignment notes - standard procedure

    These are the details of the place the hazardous waste is being removed from.

    If your premises are registered, the name, address and postcode on the form must match the

    details given to us when the site was registered..

    If the site is exempt from registration, the details must fully describe the place the waste is being

    removed from.

    You will need to provide a postcode for the consignment to be properly completed. If your site

    does not have a postcode, you must give the nearest known full postcode to the site.

    If you have a phone number, e-mail address or fax number, enter these details too.

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    3 Premises code (where applicable):

    If the premises are registered with us, you should enter the premises code here. This is the

    registration number we gave the premises when they were registered. If the premises are

    exempt from registration, write N/A or Exempt here.

    4 The waste willbe taken to (name, address & postcode):

    This provides details about the site the hazardous waste is going to be delivered to (that is, the

    consignee). You must provide full details of the consignee, and any consignee you choose to

    send waste to must either hold a permit to receive your waste or be exempt from holding a

    waste permit. You are responsible for making sure this is the case. If the consignee holds a

    waste permit, the name, address and postcode you give on the form should match the name,

    address and postcode on the consignees permit.

    5 The waste producer was (if different from 2) (name, address, postcode,

    telephone, e-mail, facsimile):

    If the waste producers details are the same as those in part A2, you can write As A2 here. If

    the producer is different, you must give the producers details. For example, if the waste is

    asbestos and a contractor produced it at your facility, you need to identify the asbestos

    contractor as the waste producer and enter their business address here.

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    Part B Description of the waste

    The producer or holder of the waste should fill in this section.

    You need to fill in part B for each type of hazardous waste that is being collected. You should

    use continuation sheets if necessary.

    1 Theprocess giving rise to the waste(s) was:

    You should provide a full written description of the process that created the waste. It is not

    enough to just enter Manufacturing. If you are moving more than one type of hazardous waste

    which has been produced by more than one process, you should describe the main production

    process involved in creating the waste.

    2 SIC for the process giving rise to the waste:

    The SIC (or Standard Industrial Classification) is a coding scheme that classifies businesses

    and other economic activities. You must provide the most detailed SIC code from the 2003

    version of the scheme for the main activity that produced (or holds) the waste. If the premises

    are registered with us, you need to give the SIC code for the main waste-producing activity on

    the premises. The SIC you give on the consignment note is not necessarily the code you were

    given at the time you registered the premises, but is the code used for the actual process that

    created the hazardous waste described on the note. If you are moving more than one type of

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    waste which has been produced by more than one process, you should give the SIC for the

    main production process involved in creating the waste.

    For more details on the SIC 2003 code, see

    www.environment-agency.gov.uk/business/topics/waste/32198.

    10 Environment Agency HWR03A Consignment notes - standard procedure

    3 WASTE DETAILS

    You must fill in all of the following for each type of hazardous waste you are having collected.

    Description of waste

    If you are using a consignment note your contractor has provided, this section might be called

    The waste is:.

    You need to provide a written description of every type of hazardous waste you are having

    collected.

    The description must not simply reproduce the description from the List of Waste Regulations

    (LoWR), which is the catalogue of all types of waste. You must provide a full description. For

    example, it is not enough to describe a waste acid from a pickling process as pickling acids

    (the description in the LoWR for code 11 01 05). You should instead write something like

    sulphuric acid used for pickling.

    You must not write Laboratory chemicals as a type of waste. Instead, you must separately

    identify each chemical in the hazardous waste. If you do not have enough space to record all of

    the details on one row of the table, use both rows. You can use continuation sheets for other

    types of hazardous waste you are having collected.

    List of Wastes (EWC) code (6 digits):

    You should choose an appropriate EWC code for each type of hazardous waste. The code

    should match the description of the waste and the business or process that produced it. You

    can get help on choosing an EWC code from our guide WM2 -

    Interpretation of the definition and classification of hazardous waste, which you can find at

    www.environment-agency.gov.uk/static/documents/GEHO0603BIRB-e-e.pdf

    Quantity (kg):

    You must give the quantity (total weight), in kilograms, of each type of hazardous waste that has

    an EWC code. This should be the total weight of the waste the carrier is actually collecting. If

    the hazardous waste is a liquid, you can show the weight in kilograms by using a suitable

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    method to convert the volume of the liquid to its equivalent weight. If you do not have a suitable

    method for doing this, convert one litre into one kilogram.

    The chemical/biological components of the waste and their concentrations are:

    You should give details of all the relevant chemical or biological parts (components) of the

    waste and their concentrations so that carriers, consignees or other people can see what is in

    each type of hazardous waste. This will also include parts of the waste that do not make it

    hazardous (for example, metals such as iron in pickling acids).

    Properly describing all the components of the waste is important in choosing how to dispose of

    the waste.

    Physical form (gas, liquid, solid, powder, sludge or mixed)

    You should write either Gas, Liquid, Solid, Powder, Sludge or Mixed for each type of

    waste that has an EWC code.

    Hazard code(s)

    You must give this information for all of the hazards appropriate to each hazardous waste. The

    hazardous properties are set out in appendix B. You must provide the correct hazards for each

    type of the wasteit is not enough to put H1 toH14.

    Container type, number and size

    You must give the number and size of each container of hazardous waste (for example, 4 x 45

    gallon drums, 1 x 14 cubic yard skip).

    UN identification number(s), Proper shipping name(s), UN Class(es),

    Packing group(s) and Special handling requirements

    You need to fill in these sections if the hazardous waste is also dangerous for carriage. See

    appendix C for more details.

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    1 Carrier name:, On behalf of (name,address, postcode, telephone, e-mail,

    facsimile):

    The carrier must give their name, the name of their business and all appropriate address and

    contact details.

    2 Carrier registration no./reason for exemption:

    A carrier must either be registered or exempt from registration. The carrier must give their

    registration number if they have one. If the carrier is exempt, they should give the reason for the

    exemption (for example, a waste producer can transport their own 12 Environment Agency

    HWR03A Consignment notes - standard procedure waste without being a registered waste

    carrier). However, producers of construction and demolition waste must always be registered as

    a carrier. It is good practice to regularly check that the details the carrier has given are correct.

    A carrier registration is valid for three years, and we may revoke (cancel) it in certain

    circumstances. You can check if the carrier has a valid registration by looking at the online

    electronic public register on our website or by contacting us on 08708 506506.

    The carriers registration details must be those of the actual carrier. So, if a subcontractor has

    been used, the subcontractors registration details must be given, not the main contractors

    details.

    3 Vehicle registration no. (or mode of transport, if not road):

    The carrier must enter the registration number of the vehicle they are using to collect the

    hazardous waste. If the waste is not being carried by road, the carrier must identify which

    method of transport they are using (for example, railway, canal barge and so on).

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    Part D Consignors certificate

    After they have filled in part C, the carrier should give you the consignment notes back. You, as

    the consignor, should then sign part D of the note.

    There is a declaration in part D. You need to check that you have filled in parts A and B

    correctly and that the carrier has filled in part C. In part C the carrier writes his carrier

    registration numberby signing part D, you are declaring that you have checked the carrier is

    registered.

    You are also declaring that the waste is packaged and labelled correctly. If you are aware of any

    particular issues relating to how the waste should be handled, you should tell the carrier about

    them.

    Note: You should not fill in part D before the carrier has arrived to collect the waste and has

    given you copies of the consignment note, with part C filled in, for you to check.

    1 Consignor name:, On behalf of (name, address, postcode, telephone, e-mail,

    facsimile):

    Environment Agency HWR03A Consignment notes - standard procedure 13

    You must give your name, the name of your business and all appropriate address and contact

    details. If these are the same as in part A2, you can write As A2. When you have checked and

    filled in the details above, you should sign part D. You can then enter the date and time (using

    the 24-hour clock) that you signed the form.

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    HAZARDOUS WASTE LABELLING AND MARKING

    A critical step in the safe handling of a hazardous waste is labelling and marking all containers

    accordingly. To ensure uniformity in the labelling and marking of containers while the waste is

    being accumulated to its ultimate disposal, both the US Department of Transportation (DOT)

    and US Environmental Protection Agency (EPA) offer specific regulatory guidance for

    hazardous waste generators to follow. It is important to note that these requirements are

    different from the OSHA hazardous communication standard (29 CFR 1910.1200), which offers

    labelling guidance for hazardous waste materials that have not been designated as waste.

    DOT Bulk vs. Non-bulk Packages

    Because the DOT hazardous waste labelling and marking requirements are different based on

    the size of the container, it is important to distinguish between bulk and non-bulk packages.

    Non-Bulk Packages

    Under 49 CFR 171.8 non-bulk packaging is defined as packaging which has:

    A maximum capacity of 450-liters (119-gallons) or less as a receptacle for a liquid

    A maximum net mass of 400-kilograms (882-pounds) or less and a maximum capacity of 450-

    liters (119-gallons) or less as a receptacle for a solid

    A water capacity of 454-kilograms (1,000-pounds) or less as a receptacle for a gas as defined

    in 49 CFR 173.115

    Bulk Packages

    Under 49 CFR 171.8, a bulk package is defined as a packaging, other than a vessel or a barge,

    including a transport vehicle or freight container, in which hazardous waste materials are loaded

    with no intermediate form of containment and which has:

    A maximum capacity greater than 450-liters (119-gallons) as a receptacle for a liquid

    A maximum net mass greater than 400-kilograms (882-pounds) and a maximum capacity

    greater than 450-liters (119-gallons) as a receptacle for a solid

    A water capacity greater than 454-kilograms (1,000-pounds) as a receptacle for a gas as

    defined in 49 CFR 173.115

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    While the DOT guidelines for properly labelling and marking non-bulk and bulk containers are

    similar, they are not the same. This document outlines the rules for non-bulk packaging.

    Hazardous Waste Labelling vs. Marking

    The DOT reference to a label is very specific. Labels refer to the diamond-shaped hazmat logos

    placed on non-bulk containers, and resemble bulk container placards. Everything else on a non-

    bulk package is a marking.

    Hazardous Waste Labelling

    The design and size of labels are based on international standards and are used to identify the

    hazards within the container. Each diamond (square-on-point) label measures at least 100mm

    (4" x 4") on each side as prescribed in 49 CFR 172.407(c)(1).

    DOT Hazardous Waste Label Examples:

    Placement of Hazardous Waste Labels

    The proper placement of labels is important. Labels must appear in their entirety because the

    specified size, print style, border, width, and color of labels. Labels should be located near any

    markings and on the same surface. Labels should not be placed on the bottom of containers.

    They should always be visible.

    http://www.grainger.com/search/material-handling/ecatalog/N-bih/Ntt-DOT+Labelhttp://www.grainger.com/search/material-handling/ecatalog/N-bih/Ntt-DOT+Label
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    Multiple Hazardous Waste Labels

    If the waste has multiple hazards associated with it multiple labels should be displayed next to

    each other. The DOT recommends a six- inch space (15 cm) between labels. The label

    designating the primary hazard should be above and to the left of the label designating the

    subsidiary hazard.

    Hazardous Waste Labels and Overpacking

    Whenever hazardous material packages are overpacked, the inner containers must be properly

    labelled. The same applies to the overpack container.

    Hazardous Waste Markings

    Marking is a critical process in preparing hazardous materials for transportation. A marking on a

    hazardous materials package contains important information about the identification and

    dangers of the hazardous material. While there is no standardized hazardous waste marker

    format, both the DOT and EPA have specific marking requirements.

    While there is no standardized hazardous waste marking format, the following general

    guidelines should be followed when placing markings on hazardous packages:

    Markings must be durable

    Markings must be in English

    Markings must be printed on or affixed on the surface or on a label, tag or sign

    Markings must be displayed on a contrasting color background

    Markings must not be obscured or covered up by other labels or attachments

    Markings must not be located next to any other markings (such as advertisement) that would

    limit their effectiveness

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    Hazardous Waste Markings and Overpacking

    As mentioned above with the labelling requirements, whenever hazardous material packages

    are overpacked, the inner containers must be properly marked. The same applies to the

    overpacking.

    DOT Hazardous Waste Marking Requirements

    There are five components of a DOT marking on a non-bulk package.

    Proper shipping name and identification number

    Technical name (if required)

    Special permit number

    Consignors or consignees name and address

    Special hazard warning

    Proper Shipping Name and Identification Number

    This information can be found in the hazardous materials table, 49 CFR 172.101. If the material

    is considered to be a hazardous waste, the word waste must be included with the proper

    shipping name. The format for properly displaying the shipping name for a hazardous waste is:

    Waste (shipping name), (hazard class), (UN or NA number), (packing group)

    Example: Waste Acetone, 3, UN1090, PGII

    Technical Name

    If the shipping name being used is a non-chemical specific shipping name, a technical name(s)

    is required for additional clarification. A non-chemical specific shipping name, as defined in 49

    CFR 172.203(k), can be easily identified by the shipping name. Any shipping name that ends in

    N.O.S. (not otherwise specified) must be marked with the technical name(s) in parentheses in

    association with the proper shipping name. The technical name should correspond to the

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    hazardous ingredients of the waste, which can be found on the Material Safety Data Sheet

    (MSDS).

    Example: Waste Flammable Liquids, n.o.s. (Xylene, Toluene), 3, UN1993, PGII

    Special Permit

    Occasionally, hazardous materials may be placed inside a package, which was issued under a

    special permit by the DOT. If a special permit package is used, the container should be marked

    DOT-SP followed by the special permit number assigned by the US DOT.

    Consignors or Consignees Name and Address

    The consignor is the party offering a hazardous material shipment for transportation. The

    consignee is the party receiving the hazardous material shipment.

    Special Hazard Warning

    When offering a hazardous material, which has a special hazard (e.g inhalation hazard, marine

    pollutant), the shipper must indicate this hazard on the marking.

    Other DOT Non-Bulk Package Markings

    Along with the hazardous waste marking requirements, there may be addition markers that are

    required. For example:

    This End Up Marking

    This marking is the package-orientation marking. It is applied to any package which holds inner

    containers of liquid hazardous materials. Inner packaging may be non-specification containers

    made of glass or earthenware, plastic or metal.

    All packages having inner packages containing liquid hazardous materials must be packed with

    their closures upward and legibly marked with package-orientation arrows on two opposite

    vertical sides and with the arrows pointing in the correct upright direction. Arrows for purposes

    other than indicating proper package orientation may not be displayed on a package containing

    a liquid hazardous material.

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    EPA Hazardous Waste Marking Requirements

    The EPA requires certain information to be shown on containers of 110 gallons or less used in

    transportation. This information is listed below.

    Hazardous Waste Warning Statement

    The following statement must be included on non-bulk packages: HAZARDOUS WASTE:

    FEDERAL LAW PROHIBITS IMPROPER DISPOSAL. IF FOUND, CONTACT THE NEAREST

    POLICE, OR PUBLIC SAFETY AUTHORITY, OR THE U.S. ENVIRONMENTAL PROTECTION

    AGENCY.

    Generators Name and Address

    This is the same as the consignors address.

    Generators EPA Identification Number

    This is a twelve-digit number assigned by the EPA to each hazardous waste generator. It is also

    included on the hazardous waste manifest.

    Manifest Document Number

    This is a five-digit number which is assigned by the generator. It is unique for each shipment.

    Accumulation Start Date

    This date is determined by the generator. It is the date that the generator first placed a

    hazardous waste inside the package. There are time limits related to the amount of time a

    generator can accumulate hazardous waste at its site. Consequently, this date is very important.

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    EPA Waste Codes

    In order for a hazardous material to be classified as a waste, it must carry an EPA waste code.

    Waste codes provide more information regarding the specific hazards associated with the

    waste. For more information on identifying the proper waste code, refer to 40 CFR 261.

    Example Hazardous Waste Marking:

    1. Hazardous warning statement

    2. Generator name and address

    3. Generator EPA ID number

    4. Accumulation start date

    5. EPA waste codes

    6. Manifest document number

    7. Proper shipping name, technical name, special hazard warning (if applicable) and DOT special

    permits (if applicable)

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    3.0 ANALYSIS

    The typical parameters analysed for the amount of oily waste were SW305(55.6%), SW306

    (9.3%), SW307 (7.4%), SW 309 (23.1%) and SW312 (4.6%) that includes heavy metal analysis,

    Toxicity Characteristic Leaching Procedure (TCLP), oil and grease, total organic carbon, pH

    value, total solids, total chlorine, calorific value, flash point, viscosity and polymerisation

    reaction.

    3.1 SW 305Spent lubricating oil

    Heavy Metal Analysis

    Elemental Analysis Atomic Absorption ppm (mg/l)

    Element Symbol Detection Limit (ppm)

    Sulphur S 8000

    Calcium Ca 1200

    Zinc Zn 650

    Lead Pb 40

    Phosphorous P 600

    Iron Fe 100

    Magnesium Mg 65Sodium Na 55

    Silicon Si 40

    Boron B 40

    Manganese Mn 10

    Copper Cu 40

    Molybdenum Mo 15

    Aluminum Al 15

    Tin, Chromium, Barium,

    Nickel, VanadiumSn, Cr, Ba, Ni, V

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    Physical and Chemical Properties

    Appearance: Transparent amber oil.

    Physical state: Liquid/Oil.

    Odor: Mineral oil odor

    Odor threshold (ppm): Not established

    Specific gravity (H2O=1): 0.870.90

    Solubility in water (20C): Negligible

    Solubility in fat: Not Determined.

    Coefficient of water/oil solubility: Not Determined.

    Partition coefficient (n-octanol/water): Not Determined.

    Melting point: Liquid.

    Boiling point: > 550F.

    Evaporation rate (Butyl Acetate=1): < 0.01

    Vapor Density (Air=1): > 5

    Vapor Pressure (mm Hg): < 0.01

    Oxidizing properties: Unknown.

    Flash Point: 415 - 475 F (COC), (PMCC) ASTM D 93 C >60.5

    (lower if contaminated with fuel or solvent)

    Viscosity: @ 40C ASTM D 445 mm2/s +/-80

    Polymerisation Reaction: Polymerisation is not known to occur under normal

    temperatures and pressures. Hazardous

    polymerisation will not occur.

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    3.2 SW 306Spent hydraulic oil

    Heavy Metal Analysis

    Absorption Elemental Analysis Atomic ppm (mg/l)

    Element Symbol Detection Limit (ppm)

    Copper Cu 0.003

    Magnesium Mg 0.0003

    Chromium Cr 0.006

    Tin Sn 0.1

    Lead Pb 0.01

    Iron Fe 0.006

    Zinc Zn 0.001

    Manganese Mn 0.002

    Cadmium Cd 0.002

    Physical and Chemical Properties

    Physical state, appearance, and odor: Liquid, amber, petroleum odor.

    Odor threshold: Not available

    Molecular weight: Not applicable

    Specific gravity: 0.88 (water = 7) (approximately)

    Density: 7.3 LB/US gal (880 g/l) (approximately)

    Vapor density: Not available

    Vapor pressure: less than 0.1 mmhg at 68f (20c)

    Boiling point: 475f (246c) (minimum)

    Freezing/melting point: Not available [pour point -22f (-30c) (maximum)].

    Evaporation rate: Not available

    Solubility in water: Insoluble

    Flammable limits in air: LOWER: Not available UPPER: Not available

    Autoignition temperature: Not available

    Ph Value: Not applicable

    Flash Point: 193 oc (380 of)

    Viscosity: 28.8 mm2/s (33 cst) @ 40C (104F) Minimum

    Polymerisation Reaction: Hazardous polymerization will not occur under

    normal working conditions.

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    3.3 SW 307Spent mineral oil-water emulsion

    Physical and Chemical Properties

    Physical state and appearance: Liquid. (Transparent water-white liquid)

    Odor: Odorless.

    Taste: Not available.

    Molecular Weight: Varies.

    Color: Clear

    Boiling Point: 310C (590F)

    Melting Point: Not available.

    Critical Temperature: Not available.

    Specific Gravity: 0.835 @ 15.6 C (Water = 1)

    Vapor Pressure: 100c

    Viscosity: @ 40 oC mm2/s: N. A.

    Polymerisation Reaction: Polymerization will not occur.

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    3.4 SW 309Oil-water mixture

    Physical and Chemical Properties

    The following information is for the Argon component of this gas mixture:

    Gas density: 0.103 lb/cu ft (1.650 kg/m3)

    Evaporation rate (nBuAc = 1): Not applicable.

    Specific gravity (air = 1): 1.38

    Freezing point: -189.2C (-308.9F)

    Solubility in water: 0.056

    Boiling point ( @ 1 atmos.): -185.9C (-302.6F)

    Expansion ratio: Not applicable.

    Specific volume (ft3/lb): 9.71

    Odor threshold: Not applicable.

    Molecular weight: 39.95

    Vapor pressure (psia): Not applicable.

    Coefficient water/oil distribution: Not applicable.

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    The following information is for the Carbon Dioxide component of this gas mixture:

    Gas density: 0.1144 lb/ft3 (1.833 kg/m3)

    Evaporation rate (nBuAc = 1): Not applicable.

    Specific gravity (air = 1): 0.90

    Freezing point: -78.5C (-109.3F) [sublimation]

    Solubility in water: 0.0491

    Boiling point( @ 1 atmos.): Sublimes.

    Expansion ratio: Not applicable.

    Specific volume (ft3/lb): 8.741

    Odor threshold: Not applicable.

    Molecular weight: 44.01

    Vapor pressure (psia): Not applicable.

    Coefficient water/oil distribution: Not applicable.

    The following information is pertinent to this product:

    Appearance, odor and color: This gas mixture is colorless and odorless, or may have a

    sharp odor (depending on the level of Carbon Dioxide).

    How to detect this substance (warning properties): There are no distinct warning properties

    of this gas mixture, unless the Carbon Dioxide is at a high concentration, when the odor may be

    a warning property. In terms of leak detection, fittings and joints can be painted with a soap

    solution to detect leaks, which will be indicated by a bubble formation.

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    3.5 SW 312Oily residue from automotive workshop, service station oil or grease

    interceptor

    Physical and Chemical Properties

    Physical State and Appearance: Black viscous liquid, hydrocarbon odor.

    Boiling point: 350 to 1200F

    Odor Threshold: Not available

    Melting or Solid Point: Not applicable

    Specific Gravity: 0.88-1.02 @ 60F (typical)

    Vapor Density: >5 (Air=1)

    Vapor Pressure:

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    4.0 TREATMENT

    4.1 Solidification

    For inorganic wastes which do not fulfill the criteria for disposal directly into the Secured Landfill,

    solidification process is used. The process is carried in the Solidification Plant. Such wastes are

    typically metal hydroxide sludge containing heavy metals such as arsenic, barium, boron,

    cadmium, chromium, copper, lead, mercury, nickel, selenium, silver, tin and zinc. The heavy

    metals become insoluble during the solidification process therefore can be safely disposed off in

    the Secured Landfill. Other that can also be treated at Solidification Plant is fly ash from the

    Incinerator Plant.

    Figure 4.1: Solidification Process

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    4.2 Physical-chemical Treatment

    The Physical-Chemical Treatment Plant (PCT) treats inorganic liquid waste such as acid,

    alkaline, chromate and cyanide. Generally, waste is detoxified through chemical process like

    neutralization, oxidation and reduction. There are 5 categories in Physical-Chemical Treatment

    Plant (PCT):

    Chromate waste

    Acid waste

    Miscellaneous waste

    Alkaline waste

    Cyanide waste

    Figure 4.2: Physical-Chemical Treatment Process

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    4.3 Incineration

    Two main sections can be divided for the Incineration Process which is Operation of Organic

    Waste Feed Preparations (or Pre-Treatment) and Incineration Process (or Thermal Destruction

    Process). For Incineration Process (or Thermal Destruction Process), there are divided into 3

    phases process which is Incineration / Combustion Phase, Heat Recovery Phase and Flue Gas

    Cleaning Phase.

    Figure 4.3: Incineration Process

    Incinerat

    ion

    Operation of Organic

    Waste Feed Preparations(or Pre-Treatment)

    Incineration Process (or

    Thermal DestructionProcess)

    Incineration / CombustionPhase

    Heat Recovery Phase

    Flue Gas Cleaning Phase

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    4.3.1 Organic Waste Feed Preparations (Pre-treatment Facility)

    The primary function of a feed preparation systems are:

    1. To produce more uniform chemical properties such as moisture and organic content.

    2. To avoid jamming of feeding mechanisms

    Figure 4.4: Pre-Treatment Flow

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    4.3.2 Thermal Destruction Process

    For Thermal Destruction Process, the process can be divided into 3 phases :

    1. Incineration / Combustion Phase

    2. Heat Recovery Phase

    3. Flue Gas Cleaning Phase

    4.3.2.1 Incineration/Combustion Phase

    The rotary kiln can operate in a wide range of conditions and therefore can handle a wide range

    of wastes. The destruction of organics is determined by temperature, time and turbulence

    factors.

    TEMPERATURE

    Temperaature iscritaical becauseit determines therate of organic

    destruction.

    TIME

    Time refers tothe length oftime that thegases are presentor residencetime.

    TURBULENCE

    The ability of

    the combustionsystem tosufficiently mixthe gases withoxygen tooxidise theorganicsreleased fromthe fuel andwastes.

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    Figure 4.5: Rotary Kiln

    4.3.2.2 Heat Recovery Phase

    Basically, for Heat Recovery Phase, a series of process to cool down the Flue gas before Flue

    gas cleaning process takes place. The Flue gas is then is cooled by using atomized water.

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    4.3.2.3 Flue gas cleaning phase

    Mainly, the Flue gas cleaning phase consists of Dry Absorption System (DAS) which includes a

    reactor, fabric filter, ID fans and wet scrubbing system where the flue gas is cleaned and

    released into the atmosphere via stack.

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    5.0 DISPOSAL

    Diposal of Waste Oil

    There are many types of oils produced from heavy industries such as crude oils, lubricating oils,

    heavier grades of fuel oil. If these oils are not managed well, these oils can cause harm tohuman, animals, plants and nature as these oils also consider as one of the hazardous wastes.

    Disposal is included in five distinct steps of Waste Heirarchy. There are many options of

    disposal are available but the actions taken is depend on the types of waste oil. As global

    environmental awareness increases and regulatory requirements concerning waste disposal

    become stricter, innovative and more creative ways of using, recycling or disposing of waste are

    likely to be needed.

    Below table showed a summary of the main options available for disposing waste oil:

    Type of material Separation methods Disposal options

    Non-emulsified oils

    and waste water

    Settling separation of free

    water

    Recovered water may require

    further treatment/filtration

    Use of recovered oil as fuel or

    refinery feedstock

    Return treated water to

    source

    Emulsified oils Emulsion broken to release water by:

    Heat treatment

    Emulsion-breaking chemicals

    Use of recovered oil as fuel or

    refinery feedstock

    Stabilisation and reuse

    Incineration

    Oil mixed with sand Collection of liquid oil leaching

    from sand during temporary

    storage

    Extraction of oil from sand by

    washing with water or solvent

    Removal of solid oils or

    tarballs by sieving

    Use of recovered liquid oil as

    fuel or refinery feedstock

    Return treated water to

    source

    Stabilisation and reuse

    Degradation through land

    farming or composting

    Landfill

    Incineration

    Oil mixed with

    cobbles, pebbles or

    Collection of liquid oil leaching

    from beach material during

    Return cleaned stones to

    source

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    shingle temporary storage

    Extraction of oil from beach

    material by washing with water

    or solvent

    Stabilisation and reuse

    Landfill

    Oil mixed with wood,

    plastics, seaweed,

    shellfish and

    sorbents

    Collection of liquid oil leaching

    during temporary storage

    Flushing of oil from debris with

    water

    Removal of free water

    Compression

    Stabilisation and reuse the

    following removal of plastics

    and large debris

    Degradation through land-

    farming or composting for oil

    mixed with seaweed, shellfish

    or natural sorbents

    Landfill

    Incineration

    Tarballs Separation from sand by

    sieving

    Stabilisation and reuse

    Landfill

    Incineration

    But mostly the industries choose incineration as the main option for disposal of waste oil. The

    advantage of this way is can be employed for many types of oiled material and permanent

    storage not required which can reduce amount of wastes.

    Oily wastes must be handled with care. The disposal of waste oils must be done according to

    the local regulations. Consultation with regulatory and licensing authorities from outset of the

    incident will assist with this important administrative component of the disposal process.

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    6.0 RECYCLING AND RECOVERY

    Collection Procedures for Recycling and Recovery of Scheduled Wastes

    The recovery and reuse of materials from wastes is recycling. Solid waste recycling refers to the

    reuse of manufactured goods from which resources such as steel, copper, or plastics can be

    recovered and reused. Recycling and recovery is only one phase of an integrated approach to

    solid waste management that also includes reducing the amount of waste produced, reuse

    where possible, recycle the products at the end of their useful life, recover energy or material

    from the waste stream, treatment of the waste product and lastly landfill disposal. Figure below

    shows the hierarchy of recycle and recovery option where the lower is the least favoured option.

    6.1. Collection Procedures for Recycling and Recovery of Scheduled Wastes

    The process of solid waste management starts from scheduled waste at waste generators

    (customer) premises. This waste sample is then will be sent to Schedule Waste Solution in

    order to get advises from them upon recycling and recovery cost. Then, the customer will file

    Scheduled Waste Information form, sign Scheduled Waste Recycling and Recovery Agreement

    and Transportation from Waste Generator form. Before Schedule Waste Solution collects the

    waste from the premises, the customer need to pack and labels the waste. This waste is then

    will be transport to waste management center.

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    Then, Schedule Waste Solution will conduct the conformity test on the waste. If the test meets

    the sample sent, Schedule Waste Solution will issue an invoice to the customer within 15 days.

    If the test does not meet the sample sent, Schedule Waste Solution will advice the customer

    about the test result and cost for customers consent. If the customer agrees with the conformity

    declaration, invoice will be issued within 15 days. If the customer objects the test result,

    Schedule Waste Solution will return the waste to waste generators premises. The process flowof scheduled waste collection procedure is as below.

    No

    Schedule Waste Solution returns waste.

    Customer bears costs incurred

    Schedule Waste Solution advices customer on

    test results and costs

    Schedule Waste Solution invoices customer

    15 days after collection

    Conformity with Waste Declaration/results of

    test

    Schedule Waste Solution collects wastes and

    transports to WMC*

    Schedule Waste Solution conducts conformity

    tests

    Customer submit necessary forms for

    processing; packs & labels waste

    Schedule Waste Solution advises customer on

    R&R costs

    Waste Sample sent to Schedule Waste Solution

    Scheduled wastes at Customers Premises

    The Process Flow of Schedule Waste Collection Procedure

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    7.0 RELATED REGULATIONS AND LEGAL REQUIREMENTS.

    Constructing a new oily waste recovery plant needed regulations which sit under the

    Environment Quality Act 1974 (EQA 1974). The legal requirements needed are as follows:

    IN exercise of the powers conferred by sections 21 and 51 of the Environmental Quality Act 1974

    [Act 127], the Minister, after consultation with the Environmental Quality Council, makes the

    following regulations:

    Citation and commencement

    1. (1) These regulations may be cited as the Environmental Quality Act 1974

    Interpretation

    2. (1) In these Regulations, unless the context otherwise requires

    "Scheduled wastes" means any waste falling within the categories of waste listed in

    the First Schedule;

    "Incompatible scheduled wastes" means scheduled wastes specified in the Fourth

    Schedule which, when mixed, will produce hazardous situations through heat

    generation, fires, explosions or the release of toxic substances;

    "on-site treatment facility" means a facility, other than a scheduled wastes

    incinerator or a land treatment facility, located on a waste generator's site and that is

    used solely to deal with scheduled wastes produced on that site;

    Contractor means any person licensed by the Director General of Environmental

    Quality 3 under subsection 18(1A) of the Act;

    Waste generator means any person who generate scheduled wastes;

    Prescribed premises means premises prescribed by the Environmental Quality

    (Prescribed Premises) (Scheduled Waste Treatment and Disposal Facilities) Order

    1989 [P.U. (A) 140/1989].

    (2) Words and expressions which are not defined in these Regulations shall have the

    same meaning as assigned to them in the Act and in the Environmental Quality

    (Prescribed Premises) (Scheduled Waste Treatment and Disposal Facilities)

    Order 1989.

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    Notification of the generation of scheduled wastes

    3. (1) Every waste generator shall, within 30 days from the date of generation of

    scheduled wastes, notify the Director General of the new categories and quantities of

    scheduled wastes which are generated.

    (2) The notification given under sub-regulation (1) shall include the information provided

    in the Second Schedule.

    Disposal of scheduled wastes

    4. (1) Scheduled wastes shall be disposed of at prescribed premises only.

    (2) Scheduled wastes shall, as far as is practicable, be rendered innocuous prior to

    disposal.

    Treatment of scheduled wastes

    5. (1) Scheduled wastes shall be treated at prescribed premises or at on-site treatment

    facilities only.

    (2) Residuals from treatment of scheduled wastes shall be treated or disposed of at 4

    prescribed premises.

    Recovery of material or product from scheduled wastes

    6. (1) Recovery of material or product from scheduled wastes shall be done at prescribed

    premises or at on-site recovery facilities.

    (2) Residuals from recovery of material or product from scheduled wastes shall be

    treated or disposed of at prescribed premises.

    Application for special management of scheduled wastes

    7. (1) A waste generator may apply to the Director General in writing to have the

    scheduled wastes generated from their particular facility or process excluded from being

    treated, disposed of or recovered in premises or facilities other than at the prescribed

    premises or on-site treatment or recovery facilities.

    (2) An application under sub-regulation (1) shall be submitted to the Director General in

    accordance with the guidelines for special management of scheduled wastes as prescribed

    by the Director General and shall be accompanied by fee of three hundred ringgit and shall

    not be refunded.

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    (3) If the Director General is satisfied with the application made under subregulation (1),

    the Director General may grant a written approval either with or without conditions.

    Responsibility of waste generator

    8. (1) Every waste generator shall ensure that scheduled wastes generated by him are

    properly stored, treated on-site, recovered on-site for material or product from such

    scheduled wastes or delivered to and received at prescribed premises for treatment,

    disposal or recovery of material or product from scheduled wastes.

    (2) Every waste generator shall ensure that scheduled wastes that are subjected to

    movement or transfer to be package, labelled and transported in accordance with the

    guidelines prescribed by the Director General.

    Storage of scheduled wastes

    9. (1) Scheduled wastes shall be stored in containers which are compatible with the

    scheduled wastes to be stored, durable and which are able to prevent spillage or leakage of

    the scheduled wastes into the environment.

    (2) Incompatible scheduled wastes shall be stored in separate containers, and such

    containers shall be placed in separate secondary containment areas.

    (3) Containers containing scheduled wastes shall always be closed during storage

    except when it is necessary to add or remove the scheduled wastes.

    (4) Areas for the storage of the containers shall be designed, constructed and

    maintained adequately in accordance with the guidelines prescribed by the Director General

    to prevent spillage or leakage of scheduled wastes into the environment.

    (5) Any person may store scheduled wastes generated by him for 180 days or less after

    its generation provided that

    (a) the quantity of scheduled wastes accumulated on site shall not exceed 20

    metric tonnes; and

    (b) the Director General may at any time, direct the waste generator to send any

    scheduled wastes for treatment, disposal or recovery of material or product from

    the scheduled wastes up to such quantity as he deems necessary.

    (6) A waste generator may apply to the Director General in writing to store more than

    20 metric tonnes of scheduled wastes.

    (7) If the Director General is satisfied with the application made under sub-regulation

    (6), the Director General may grant a written approval either with or without conditions.

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    Labelling of scheduled wastes

    10. (1) The date when the scheduled wastes are first generated, name, address and

    telephone number of the waste generator shall be clearly labelled on the containers that are

    used to store the scheduled wastes.

    (2) Containers of scheduled wastes shall be clearly labelled in accordance with the

    types applicable to them as specified in the Third Schedule and marked with the scheduled

    waste code as specified in the First Schedule for identification and warning purposes.

    (3) No person is allowed to alter the markings and labels mentioned in sub-regulations

    (1) and (2).

    Waste generator shall keep an inventory of scheduled wastes

    11. A waste generator shall keep accurate and up-to-date inventory in accordance with the

    Fifth Schedule of the categories and quantities of scheduled wastes being generated,

    treated and disposed of and of materials or product recovered from such scheduled wastes

    for a period up to three years from the date the scheduled wastes was generated.

    Information to be provided by waste generator, contractor and occupier of prescribed

    premises

    12. (1) A waste generator, contractor and occupier of the prescribed premises shall provide

    information in accordance with the Sixth Schedule in the manner provided in this regulation.

    (2) A waste generator shall complete Part I of the Sixth Schedule in six copies and

    hand over the six copies of the Schedule to the contractor when the scheduled wastes are

    delivered to him.

    (3) The contractor shall, upon receiving scheduled wastes from a waste generator,

    complete Part II of the Sixth Schedule in the six copies given to him by the waste generator

    and shall thereafter immediately hand over two copies of the Schedule to the waste

    generator who in turn shall submit a copy to the Director General within 30 days from the

    date of transportation of the scheduled wastes.

    (4) The contractor shall, within 10 days from the date of receipt of the scheduled

    wastes, deliver the scheduled wastes to the occupier of any prescribed premises and hand

    over the remaining four copies of the Sixth Schedule to the occupier.

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    (5) The occupier of any prescribed premises shall, upon receiving scheduled wastes

    from the contractor, complete Part III of all the remaining four copies of the Sixth

    Schedule handed over to him by the contractor and shall, upon completion, retain one

    copy and return a copy each to the contractor, the waste generator and the Director

    General, within 20 days from the date of receipt of the scheduled wastes.

    (6) If the waste generator fails to receive his copy of the Sixth Schedule from the

    occupier of the prescribed premises referred to in sub-regulation (5) within 30 days from the

    date of delivery of the scheduled wastes to the contractor referred to in subregulation (2),

    he shall notify the Director General immediately and shall investigate and inform the

    Director General of the result of his investigation.

    (7) The waste generator, contractor or occupier of the prescribed premises shall

    keep a copy each of the Sixth Schedule. The Sign copy of Sixth Schedule must be

    retained as a record for at least three years from the date the scheduled wastes are

    accepted by the prescribed premises.

    Scheduled wastes transported outside wastes generators premises to be accompanied

    by information

    13. (1) Every waste generator shall provide information in accordance with the Seventh

    Schedule in respect of each category of scheduled wastes to be delivered to the contractor

    and shall give the Schedule to the contractor upon delivery of the waste to him.

    (2) The waste generator shall inform the contractor of the purpose and use of the

    Seventh Schedule.

    (3) The contractor shall carry with him the Seventh Schedule for each category of

    scheduled wastes being transported and shall observe and comply with the instructions

    contained therein.

    (4) The contractor shall, in the selection of transportation routes, as far as possible

    avoid densely populated areas, water catchment areas and other environmentally

    sensitive areas.

    (5) The contractor shall ensure that all his employees that are involved in the

    handling, transportation and storage of scheduled wastes attend training programmes.

    (6) The contractor shall ensure that during the training programme each employee is

    well informed on the purpose and use of the Seventh Schedule.

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    Spill or accidental discharge

    14. (1) In the event of any spill or accidental discharge of any scheduled wastes, the

    contractor responsible for the waste shall immediately inform the Director General of the

    occurrence.

    (2) The contractor shall do everything that is practicable to contain, cleanse or abate

    the spill or accidental discharge and to recover substances involved in the spill or

    accidental discharge.

    (3) The waste generator shall provide technical expertise and supporting assistance

    in any clean-up operation referred to in sub-regulation (2).

    (4) The contractor shall undertake studies to determine the impact of the spillage or

    accidental discharge on the environment over a period of time to be determined by the

    Director General.

    Training Programme

    15. Every waste generator shall ensure that all his employees involved in the identification,

    handling, labelling, transportation, storage and spill response of scheduled wastes, attend

    training programme.

    Compounding of offences

    16. (1) Every offence which consists of any omission or neglect to comply with, or any act

    done or attempted to be done contrary to these Regulations may be compounded under

    section 45 of the Act.

    (2) The compounding of offences referred to in sub-regulation (1) shall be in

    accordance with the procedure prescribed in the Environmental Quality (Compounding of

    Offences) Rules 1978 [P.U. (A) 281/1978].

    Revocation

    17. The Environmental Quality Act (Scheduled Wastes) SWS Regulations is hereby

    repealed as from the commencement of these Regulations.

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    REFERENCES

    http://www.3rdi.co.uk/pdf/EA_standard_movements_consignment_notes_and_guide.pdf

    http://www.grainger.com/content/qt-322-hazardous-waste

    http://www.environment-agency.gov.uk/business/topics/waste/32196.aspx

    http://www.itopf.com/information-

    services/publications/documents/TIP9DisposalofOilandDebris.pdf

    http://www.3rdi.co.uk/pdf/EA_standard_movements_consignment_notes_and_guide.pdfhttp://www.3rdi.co.uk/pdf/EA_standard_movements_consignment_notes_and_guide.pdfhttp://www.grainger.com/content/qt-322-hazardous-wastehttp://www.grainger.com/content/qt-322-hazardous-wastehttp://www.environment-agency.gov.uk/business/topics/waste/32196.aspxhttp://www.environment-agency.gov.uk/business/topics/waste/32196.aspxhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.itopf.com/information-services/publications/documents/TIP9DisposalofOilandDebris.pdfhttp://www.environment-agency.gov.uk/business/topics/waste/32196.aspxhttp://www.grainger.com/content/qt-322-hazardous-wastehttp://www.3rdi.co.uk/pdf/EA_standard_movements_consignment_notes_and_guide.pdf

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