AZARDOUS H - s3-us-west-2.amazonaws.com

AZARDOUS

ASTE

AND

ATERIALS

ANAGEMENT

RAINING MANUAL

AUGUST 2020

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LEGAL NOTICE

These materials are intended to provide accurate and authoritative

information with regard to the subject matter covered. It is not within the

scope of these materials to analyze specific legal, policy, or technical issues

that may arise. Specific questions about particular matters should be

addressed in the context of the facts that underline them and the policies and

law in effect at the time. In furnishing theses materials, SET Environmental,

Inc. does not make any warranty or representation, either expressed or

implied, with respect to the accuracy, completeness, or utility of the

information contained in this document; nor does SET Environmental, Inc.

assume any liability of any kind whatsoever resulting from the use of or

reliance upon any information, procedure, conclusion, or opinion contained

in these materials.

TOPIC PAGE

RCRA Requirements

Hazardous Waste Classification T-2

Listed Wastes (e.g., F, K, P & U Codes) T-4

Characteristic Wastes T-7

Ignitability (D001) ..................................... T-7

Corrosivity (D002) .................................... T-8

Reactivity (D003) ...................................... T-8

Toxicity (D004 - D043) .............................. T-9

Generator Categories ............................................... T-13

EPA ID Numbers ....................................................... T-14

Training ................................................................. T-14

RCRA Container Requirements ............................... T-16

Preparedness and Prevention ................................. T-18

Emergency Procedures ............................................ T-19

Contingency Plan ..................................................... T-20

LQG Container Storage Area Closure .................... T-20

Satellite Accumulation Areas .................................. T-20

SQG Reduced Requirement Summary .................. T-22

Land Disposal Restriction ........................................ T-22

Universal Waste ....................................................... T-22

Episodic Generation ................................................. T-23

Consolidation VSQG to LQG ................................... T-24

Rejected Shipments ................................................. T-24

Hazardous Substance and Reportable Quantities "RQ" T-26

Hazardous Materials Classification T-29

Division 2.1 Flammable Gas ................................ T-31

Division 2.2 Non-Flammable Gas ....................... T-31

Division 2.3 Poisonous Gas ................................. T-31

Class 3 Flammable Liquid ............................ T-32

Division 4.1 Flammable Solids ............................ T-32

Division 4.2 Spontaneously Combustible .......... T-34

Division 4.3 Dangerous When Wet ..................... T-35

Division 5.1 Oxidizer ............................................ T-36

Division 5.2 Organic Peroxide ............................. T-37

Division 6.1 Poisons ............................................. T-37

Division 6.2 Infectious Substance ....................... T-40

Class 7 Radioactive Material ....................... T-42

Class 8 Corrosives ........................................ T-42

Combustible Liquid .................................................. T-44

Class 9 Other ................................................. T-44

Precedence of Hazards ............................................ T-45

HMT (Description of the Contents of Each Column) ......... T-48

Shipping Descriptions .......................................................... T-50

TOPIC PAGE

Proper Shipping Name Selection ........................... T-50

Authorized Modification of Shipping Names ........ T-53

Additional Descriptors ............................................. T-55

Packaging ............................................................................... T-61

Definitions ................................................................. T-61

Selection ................................................................... T-62

UN Specification Codes ........................................... T-64

Packaging Exceptions ........................................................... T-68

Limited Quantity ....................................................... T-68

Materials of Trade .................................................... T-69

Lab Pack .................................................................... T-72

Poison Pack ............................................................... T-74

Salvage Drums ......................................................... T-75

Salvage Cylinders .................................................... T-75

Overpacks ................................................................. T-77

Reuse of Non-Bulk Packaging ................................. T-78

Marking Requirements ......................................................... T-80

Labeling Requirements ........................................................ T-84

Segregation of Hazardous Materials .................................. T-86

Manifesting System .............................................................. T-90

Land Disposal Restriction Notification ............................... T-97

Placarding .............................................................................. T-99

Hazmat Security .................................................................. T-103

APPENDICIES NUMBER

Hazardous Waste Characteristics and Lists ............................. 1

Hazardous Materials Table ........................................................ 2

Hazardous Substance ................................................................ 3

Marine Pollutant Lists ................................................................ 4

Packaging Requirements ........................................................... 5

Special Provisions ...................................................................... 6

Poison Inhalation Hazard Table ................................................ 7

Hazardous Waste Treatment Standards .................................. 8

SET Environmental, Inc. T-1 Last Revision: June 24, 2020

HAZARDOUS WASTE & MATERIALS MANAGEMENT

OBJECTIVE:

The purpose of SET Environmental's training program in Hazardous Waste and Materials

Management is to provide instruction in the use of this manual and provide a high level of

understanding for the following topics:

1. Classification of Hazardous:

• Wastes

• Substances

• Materials

2. RCRA Generator Requirements

• Training

• Container Requirements

• Preparedness and Prevention

• Contingency Plan

• Land Disposal Restrictions

• Universal Waste

3. Prepare a Shipping Description

4. Select Authorized Packaging

5. Label and Mark a Package

6. The Manifest System

7. Land Disposal Restrictions

8. Segregating Incompatible Waste in a Shipment

9. Vehicle Placarding

10. Hazmat Security Awareness

When completed, this course will satisfy the annual RCRA refresher training for hazardous

waste generators (except for site specific emergency preparedness and contingency plan

requirements) under 40 CFR 262 Subpart M. This course will also satisfy DOT general

awareness, function specific, safety and security awareness training relevant to the specific

functions covered in this manual (e.g., selecting authorized packaging, labeling, marking,

shipping papers, placarding).

INTRODUCTION:

This training manual has been updated to incorporate applicable amendments to the Hazardous

Material regulations which were published in the Federal Register as of May 11, 2020.

Regulations presented in this manual are effective now; however, some of these regulations have

mandatory compliance dates set some time in the future.


RCRA HAZARDOUS WASTE CLASSIFICATION

When shipping wastes, there are three classifications (hazardous waste, hazardous substance and

hazardous materials) which must be conducted in order to assure compliance with the

Environmental Protection Agency (EPA) and Department of Transportation (DOT) regulations.

Hazardous Wastes are regulated by the EPA under the Resource Conservation and Recovery

Act (RCRA). In accordance with 40 CFR 262.11 all generators of waste are required to make an

accurate waste determination to ensure hazardous wastes are properly managed. If the material is

classified as a hazardous waste, the generator must comply with applicable RCRA regulations

located at 40 Code of Federal Regulations (CFR) Parts 240 - 299).

Hazardous Substances are regulated under the EPA Comprehensive Emergency Response

Compensation and Liability Act (CERCLA). If a hazardous substance is released to the

environment in a sufficient quantity (i.e., a reportable quantity (RQ)), the EPA requires that

immediate notification be made to the National Response Center and other entities that can assist

with the release. Although this notification is only required after a release has occurred, a

hazardous substance determination must be made prior to shipping, in order to comply with the

requirements of the EPA and the DOT.

Hazardous Materials regulations are enforced by the DOT under the Pipeline and Hazardous

Materials Safety Administration (PHMSA). The shipper (i.e., the manufacturer or generator not

the carrier/transporter) is required to ensure full compliance with Hazardous Materials

Regulations prior to offering a hazardous material for shipment. Hazardous material regulations

can be located at 49 CFR Parts 171 through 185.

Since the “hazardous waste” determination could affect the hazardous substance and hazardous

materials classifications, we will begin with hazardous waste classification procedures. The

waste determination must be made “at the point of generation.” When the waste is first

generated without being altered (e.g., as waste exits a process unit).

Solid Waste

Using the simplified waste determination flow chart, the first step in hazardous waste

classification is to determine if the waste meets the definition of a solid waste (40 CFR 261.2).

A solid waste is any discarded material that is not excluded by 40 CFR 261.4(a) (see Appendix

1, page 13 for exclusions). The term "solid waste" does not refer to the physical state of the

waste. An example of a waste excluded from the definition of a solid waste is:

"Spent sulfuric acid used to produce virgin sulfuric acid..."

If a waste is excluded from the solid waste definition it cannot be a hazardous waste. If the

material is a solid waste, the next step would be to determine if the solid waste is excluded from

the definition of a hazardous waste (40 CFR 261.4(b)) (see Appendix 1, page 26). An example

of a waste excluded from hazardous waste regulation is:

"Non-terne plated used oil filters that are not mixed with wastes listed in Subpart D of this part if these oil

filters have been gravity hot drained using one of the following methods:

(I) Puncturing the filter anti-drain back valve or the filter dome end and hot draining;


(ii) Hot draining and crushing;

(iii) Dismantling and hot draining; or

(iv) Any other equivalent hot-draining method that will remove used oil."

Hazardous Waste Determination

Simplified Flow Chart


Listed Waste

If the material is not excluded from the solid waste or hazardous waste definitions, the next step

will be to determine if the waste meets the definition of a listed hazardous waste and/or

characteristically hazardous waste. Lists of hazardous waste are located in 40 CFR:

§ 261.31 List of Waste from Non-specific Sources (F-List) - Appendix 1, p. A1-44),

§ 261.32 List of Waste from Specific Sources (K-List) - Appendix 1, p. A1-49) or

§ 261.33 Lists of Commercial Chemical Products (P- and U-List - Appendix 1, p. A1-60).

Characteristically hazardous wastes are defined at 40 CFR 261.21 through 261.24 (see Appendix

1 Pages A1-40 to A1-43):

§ 261.21 Characteristic of Ignitability (D001),

§ 261.22 Characteristic of Corrosivity (D002),

§ 261.23 Characteristic of Reactivity (D003) and/or

§ 261.24 Characteristic of Toxicity (D004 - D043);

Wastes Used in a Process

When making a hazardous waste determination, begin with the question: Is the waste spent or

has it been used?

The term "spent" is defined as "any material that has been used and as a result of contamination

can no longer serve the purpose for which it was produced without processing" 40 CFR 261.1

(c)(1)

If the waste is spent, the only "lists" of waste which would need to be referenced are the F and K-

Lists. If the material is unused, the only "lists" which would need to be referenced are the U and

P-Lists.

If the waste is spent or used in a process, one list you should consult is the K-list (Hazardous

Waste from Specific Sources). An example of a K-Listed waste is

K001 Bottom sediment sludge from the treatment of wastewaters from wood preserving

processes that use creosote and/or pentachlorophenol.

If the spent waste is not identified in the K-list, the next step will be to determine if the waste is

included in the F-list (Hazardous Waste from Non-Specific Sources). F-listed wastes can be

divided into six basic categories:

Spent Solvents F001 through F005

Plating Wastes F006 through F019

Dioxin Containing Waste F020 through F028

Wood Preserving Waste F030 through F035

Petroleum Refining Waste F037 and F038

Leachate F039.

For all practical purposes, the most common F-listed wastes are the spent solvents. The list of


spent solvents (F001 through F005) can also be found in Appendix 1.

"Spent solvent listings cover only those solvents that are used for their "solvent properties", that

is, to solubilize or mobilize other constituents. For example, solvents used in de-greasing,

cleaning, fabric scouring, as diluents, extractants, reaction and synthesis media." Federal

Register Vol. 55 No. 251 December 31, 1986, p. 53316

F001 Assign the RCRA waste code F001 if any one of the following six solvents or any

combination of the following six solvents and those solvents listed under F002, F004 or

F005) were used in a large-scale industrial degreasing operation such as cold cleaning or

vapor degreasing at a concentration of ≥10%.

Tetrachloroethylene 1,1,1-Trichloroethane Trichloroethylene

Carbon Tetrachloride Chlorinated Fluorocarbons Methylene Chloride

Example 1: If a 16% solution of Carbon tetrachloride was used in a cold vapor

degreasing unit to degrease tools, the waste from that process would be

assigned the RCRA waste code F001.

This waste would meet the definition of a hazardous waste because it

meets the definition of a solid waste, is not excluded from the hazardous

waste definition and is listed under 40 CFR 261 Subpart D.

Example 2: If the concentration used to degrease the tools was 9%, the waste from the

process would not be assigned the RCRA waste code F001, however the

waste may still be classified as a hazardous waste because it exhibits a

hazardous characteristic, which will be discussed later in this section.

Example 3: If a solution of 5% 1,1,1-Trichloroethane, and 7% Methylene chloride

were used to degrease tools; the waste would be assigned the RCRA waste

code F001.

Example 4: If a solution containing 5% Methylene chloride and 7% Toluene were

used to degrease tools, the waste would be assigned the RCRA waste

codes F001 and F005.

F002 The basic difference between the F001 and F002 listing is that to be classified as F001

the waste must be generated by the process of degreasing. The F002 waste code would

be assigned to small scale degreasing operations and all other processes generating spent

halogenated solvents. Note that Carbon tetrachloride and the group of solvents referred

to as chlorofluorocarbons are the only F001 listed solvents that are not also listed under

F002. There are also a few additional solvents listed under F002.

Assign the RCRA waste code F002 if any one of the following nine solvents or any

combination of the following nine solvents and those solvents listed under F001, F004 or

F005) were used at a concentration of ≥10%.


Tetrachloroethylene Methylene chloride Trichloroethylene

o-Dichlorobenzene 1,1,1-Trichloroethane Trichlorofluoromethane

Chlorobenzene 1,1,2-Trichloroethane

1,1,2-Trichloro-1,2,2- trifluoroethane

F003 Where F001 and F002 solvents are halogenated and listed for their toxicity, F003

solvents are non-halogenated and are listed only for their ignitability.

The primary difference between F003 and the other F-solvent listings is that the solvent

used in the process generating F003 waste must be at a 100% concentration when used.

Assign the RCRA waste code F003 if any one or more of the following nine solvents

were used at a concentration of 100%.

Xylene Methyl isobutyl ketone Acetone

n-Butyl alcohol Ethyl acetate Cyclohexanone

Ethyl benzene Methanol Ethyl ether

The tricky part: Also assign the RCRA waste code F003 if you assigned the RCRA waste

code F001, F002, F004 or F005 and the waste contains some quantity of the nine F003

solvents.

Example 1: Xylene at 100% concentration is used to clean out a reactor vessel. All

waste generated from this cleaning process is assigned the RCRA waste

code F003.

Example 2: A mixture of 50% Xylene and 50% Methanol is used to clean out a reactor

vessel. All waste generated from this process is assigned the RCRA waste

code F003.

Example 3: A mixture of 50% Xylene and 50% Ethanol is used to clean out a reactor

vessel. This waste would not be assigned the RCRA waste code F003;

however, it may exhibit a hazardous waste characteristic.

Example 4: A mixture of 50% Xylene a 10% Methylene chloride are used to clean out

a reactor vessel. This waste would be assigned the RCRA waste codes

F003 and F002.

Example 5: A mixture of 50% Xylene a 5% Methylene chloride are used to clean out a

reactor vessel. This waste would not be assigned a RCRA waste code;

however, this waste may exhibit a hazardous characteristic.


F004 F004 and F005 solvents are also non-halogenated however they are listed because of their

toxicity and ignitability.

Assign the RCRA waste code F004 if any one of the following three solvents or any

combination of the following three solvents and those solvents listed under F001, F002 or

F005 were used at a concentration of ≥ 10%.

Cresols Nitrobenzene Cresylic Acid

F005 Assign the RCRA waste code F005 if any one of the following eight solvents or any

combination of the following eight solvents and those solvents listed under F001, F002 or

F004 were used at a concentration of ≥ 10%.

Toluene Pyridine Methyl Ethyl Ketone

Benzene Carbon Disulfide 2-Ethoxyethanol

Isobutanol 2-Nitropropane

Unused Commercial Chemical Products and Spill Residues

If the material was unused, the next step is to determine if the waste is listed as a commercial

chemical product: P-Listed (acute hazardous waste) or U-Listed (toxic hazardous waste). The

regulatory site for P and U-listed waste is at 40 CFR 261.33. The P-list begins on page A1-60

and the U-List begins on page A1-69.

U and P-listed wastes include commercially pure grades, technical grades, or any formulation in

which the listed chemical is the sole active ingredient. It does not include spent or used wastes.

P-listed wastes were listed due to their acute toxicity. They either exhibit an oral LD50 < 50

mg/kg, an inhalation LC50 <2 mg/l or a Dermal LD50 <200 mg/kg.

Characteristically Hazardous Waste

Regardless of whether or not the waste falls under the classification of a listed waste, the next

step is to determine if the waste exhibits a hazardous characteristic (D-coded waste). The four

categories of characteristic wastes are: ignitability, corrosivity, reactivity and toxicity. The

regulatory site for characteristic definitions are at 40 §§CFR 261.21, 261.22, 261.23 and 261.24

respectively and are summarized below (hazardous characteristic definitions, in regulatory text,

can also be found in Appendix 1).

Characteristic of Ignitability - D001

Under the characteristic of ignitability there are four definitions:

1. Definition: A liquid that exhibits a flash point of less than 140°F.

NOTE: Wastes in a solid physical state (i.e., no liquids) do not meet this definition.

Examples: Ethanol, Mineral Spirits, Gasoline, Acetic Acid


2. Definition: A waste that is not a liquid and is capable under normal conditions of causing a

fire through friction, contact with water, or spontaneous chemical changes and, when ignited,

burns so vigorously and persistently that it creates a hazard.

Examples: Sodium Metal, Dinitrophenylhydrazine, Picric Acid, Silver Nitride,

Aluminum Borohydride.

3. Definition: Ignitable compressed gas that is classed as a flammable gas (2.1) by the

Department of Transportation.

Examples: Acetylene, Propane, Methane, Methyl Mercaptan

4. Definition: It is classed as an oxidizer (5.1) or organic peroxide (5.2) by the Department of

Transportation.

Examples: Potassium Permanganate, Ceric Ammonium Sulfate, Lead Nitrate, Potassium

Perchlorate, Sodium Chromate, Hydrogen Peroxide, Oxygen.

Characteristic of Corrosivity - D002

Under the characteristic of corrosivity there are two definitions.

1. Definition: An aqueous waste with a pH of ≤ 2 or ≥ 12.5.

A material in a solid physical state would not be assigned the code (D002)

Examples: Acetic Acid, Sulfuric Acid, Hydrochloric Acid, Titanium Tetrachloride,

Acetyl Chloride, Ethylamine, Sodium Hydroxide, Hydrazine Hydrated.

2. Definition: It is a liquid that corrodes steel at a rate greater than 6.35mm (0.25 inches) per

year at a test temperature of 55°C (130°F).

Characteristic of Reactivity - D003

Under the characteristic of reactivity there are eight definitions which deal with water reactives,

pyrophorics, cyanide and sulfide bearing wastes, shock sensitive compounds and explosives.

1. "It is normally unstable and readily undergoes change without detonating".

Examples: Aluminum Chloride Anhydrous, Dimethyl Allyl Arsine, Benzoyl Peroxide,

Acetyl Nitrate, Acetaldehyde

2. "Reacts violently with water".

Examples: Sodium Metal, Potassium Metal, Calcium Carbide, Titanium tetrachloride,

Acetyl Chloride, Sodium Amide

3. "It forms potentially explosive mixtures with water".


Examples: Boron Tribromide, Cadmium Amide, Cesium Silicide, Lead Imide, Calcium

Carbide

4. "When mixed with water it generates toxic gasses, vapors or fumes in quantity sufficient to

present a danger to human health and the environment".

Examples: Phosphorous Pentasulfide, Calcium Cyanide

5. "It is a cyanide or sulfide bearing waste, and when exposed to a pH between 2 and 12.5 can

generate toxic gasses, vapors, or fumes in quantity sufficient enough to present a danger to

human health and the environment".

Examples: Phosphorous Cyanide, Calcium Cyanide

6. "It is capable of detonation or explosive reaction if it is subjected to a strong initiating source

or if heated under confinement".

Examples: Allene, Ammonium Picrate, Trinitrotoluene, Chlorodinitrotoluene.

7. "It is readily capable of detonation or explosive decomposition or reaction at standard

temperature and pressure".

Examples: Cupric Azide, Diacetyl Peroxide, Mercuric Chlorite, Methyl Perchlorate,

Anhydrous Perchloric Acid

8. It is a forbidden explosive, Class A explosive or a Class B explosive as defined in 49 CFR

173.

Examples: Acetylene Silver Nitrate, Ammonium Azide, Benzoyl Azide, 2,4-Dinitro-

1,3,5-trimethylbenzene, Dinitroethane, Hydrazine Perchlorate, Mercury Acetylide, Dry

Silver Azide, Trinitromethane

Characteristic of Toxicity - D004 through D043

Wastes which exhibit the characteristic of toxicity contain a specific chemical constituent which

exceeds a prescribed regulatory level. The EPA hazardous waste numbers, specific chemical

constituents and regulatory levels for the toxicity characteristics (TC) are as follows:

EPA Waste No. Contaminant Regulatory Level (mg/l)

D004 Arsenic 5.0

D005 Barium 100.0

D006 Cadmium 1.0

D007 Chromium 5.0

D008 Lead 5.0

D009 Mercury 0.2

D010 Selenium 1.0

D011 Silver 5.0

D012 Endrin 0.02

D013 Lindane 0.4

D014 Methoxychlor 10.0

D015 Toxaphene 0.5


EPA Waste No. Contaminant Regulatory Level (mg/l)

D016 2,4-D 10.0

D017 2,4,5-TP Silvex 1.0

D018 Benzene 0.5

D019 Carbon tetrachloride 0.5

D020 Chlordane 0.03

D021 Chlorobenzene 100.0

D022 Chloroform 6.0

D023 o-Cresol 200.0

D024 m-Cresol 200.0

D025 p-Cresol 200.0

D026 Cresol 200.0

D027 1,4-Dichlorobenzene 7.5

D028 1,2-Dichloroethane 0.5

D029 1,1-Dichloroethylene 0.7

D030 2,4-Dinitrotoluene 0.13

D031 Heptachlor (and its epoxide) 0.008

D032 Hexachlorobenzene 0.13

D033 Hexachlorobutadiene 0.5

D034 Hexachloroethane 3.0

D035 Methyl Ethyl Ketone 200.0

D036 Nitrobenzene 2.0

D037 Pentachlorophenol 100.0

D038 Pyridine 5.0

D039 Tetrachloroethylene 0.7

D040 Trichloroethylene 0.5

D041 2,4,5-Trichlorophenol 400.0


D043 Vinyl Chloride 0.2

The generator may use knowledge to determine if a waste meets the characteristic of toxicity;

however, if this knowledge is insufficient, the generator should analyze the waste by a method

known as the Toxicity Characteristic Leachate Procedure (TCLP) (See Test Methods for

Evaluating Solid Waste, Physical/Chemical Methods, SW846 Method 1311). However, the

generator may base their hazardous waste determination on knowledge of the waste. Using

either method, the generator must maintain documentation on how the hazardous waste

determination was made.

It is acceptable to assign the toxicity characteristic hazardous waste number if the chemical

constituent is suspected to be present in the waste above the regulatory level without conducting

analysis. For example, in the hazardous waste determinations of lab pack waste, it would not be

prudent to run costly TCLP analysis on each individual bottle in the lab pack. In this case, if the

chemical contains any of the above constituents then assume that it exceeds the regulatory level

and assign the appropriate characteristic code.

If the waste is not listed and does not exhibit a hazardous characteristic, the waste is not a

hazardous waste under RCRA; however, this waste may still be subject to regulation by state and

local governments.

If a RCRA waste code was assigned in this process, the waste is a hazardous waste and there is

one more step to consider – Underlying Hazardous Constituents (UHC). UHCs are chemical

constituents in a waste that are listed in 40 CFR 268.48 (see Appendix 8) at a concentration

above its treatment standard and are not identified in the treatment standards for the EPA


hazardous waste numbers assigned to the waste. UHCs can be defined as:

1. Characteristically hazardous waste (i.e., a D-code was assigned during the waste

determination);

2. Have a treatment standard that includes the phrase “…and meet 268.48 standards” and

3. Contain a chemical listed in 268.48 not specifically associated with a listed RCRA waste

code.

Under the land disposal restrictions, the last two columns of the treatment standards table

identify treatment standards for wastewaters and non-wastewater. A wastewater is defined as

containing <1% Total Organic Carbon (TOC) and < 1% Total Suspended Solids (TSS). If the

waste does not meet the definition of a wastewater it is a non-wastewater. These treatment

standards can be technology based (CMBST = Combustion), numeric or both. When

developing these treatment standards, EPA consulted companies that treat waste to evaluate

the Best Available Treatment Technology (BDAT). The treatment standards are often

different for wastewater and non-wastewaters. Because of the low concentration of

contaminants in wastewaters, wastewater treatment standards are often lower than non-

wastewater treatment standards.

Scenario: A hazardous waste is assigned the waste Code D001 (high TOC ignitable

subcategory) and D035 (toxicity characteristic for Methyl ethyl ketone) and contains 20%

MEK and 10% Naphthalene.

Question: Is Naphthalene a UHC?

The waste is characteristically hazardous (D001 and D035),

The treatment standard for D035 non-wastewater (NWW) includes the phrase “and

meet 268.48 standards”, and

Naphthalene is listed in 268.48 with a NWW treatment standard of 5.6 mg/kg.

Answer: Since all three of the requirements above have been met and there is more than 5.6

mg/kg Naphthalene in the waste (10% = 100,000 mg/kg), Naphthalene is a UHC.

The UHC must be identified on the Land Disposal Restriction Notification to the disposal

facility.

RCRA HAZARDOUS WASTE DETERMINATION GENERAL RULES

1. Prior to assigning EPA hazardous waste numbers, remember to ask the question: Is the

material used/spent?

If used/spent, the only lists which need be referenced are the K and F-lists.

If not used, the only lists which need be referenced are the U and P lists.

2. Whether or not the waste is "listed", the generator must also determine whether or not the

waste exhibits a hazardous characteristic (D-Codes).

3. F, K, P and U-codes are known as listed wastes. Because of the "derived from rule", once a

waste has been classified as a listed waste, the listed waste and any other waste derived from

it will remain a hazardous waste. This rule does not apply to characteristically hazardous


waste (D-coded wastes). Once the hazardous characteristic is removed from waste it is no

longer a hazardous waste.

3. Listed wastes are specific. For example, 1,2-Dichlorobenzene has the EPA hazardous waste

number U070 where 1,3-Dichlorobenzene has the EPA hazardous waste number U071.

4. Be aware of synonyms. Methylene chloride has the EPA hazardous waste number U080

where Dichloromethane is not listed. However, Dichloromethane is another name (a

synonym) for Methylene chloride. Therefore, Dichloromethane would be assigned the EPA

hazardous waste number U080.

5. For a single chemical do not assign different types of EPA hazardous waste numbers. For

example:

(1) Spent acetone is listed as F003 if it was used at 100% concentration;

(2) Unused acetone is listed as U002; and

(3) An unused mixture, containing acetone (not as the sole active ingredient), that

exhibits a flash point of less than 140°F, would be assigned the EPA hazardous

waste number D001.

Only one EPA hazardous waste number would be assigned in each case. See number 7 below

for an exception to this rule when mixtures of wastes are involved.

6. For any single waste, multiple D-codes can be applied. For example, concentrated chromic

acid would receive the EPA hazardous waste numbers:

• D001 for its oxidizing properties,

• D002 for its corrosive properties, and

• D007 because it exceeds the regulatory level for the chromium toxicity characteristic.

7. Only when you have a mixture of waste or have a listed waste that exhibits a characteristic

which is unaccounted for in the treatment standard should multiple codes of different types

be assigned. For Example: a 10 percent solution of spent methylene chloride and 90 percent

ethanol which exhibits a flash point of less than 140°F would receive the hazardous waste

numbers F002 and D001.

8. Classify spilled waste just as it would have been classified prior to being spilled. For

example, soil contaminated with unused acetone would receive the RCRA waste code U002

rather than F003 for spent Acetone.


Additional RCRA Requirements for Generators of Hazardous Waste

The specific RCRA regulations that a hazardous waste generator must follow, may be dependent

on the volume of hazardous waste generated in a calendar month. Once the hazardous waste has

been classified and the amount generated in a calendar month is determined, what additional

regulations must the hazardous waste generator follow?

Generator Category Determinations

In accordance with 40 CFR 261.13, a generator of hazardous waste must calculate the volume of

hazardous waste generated in a calendar month and use this data to determine their generator

category. The generator category may change from month to month depending on the volume of

hazardous waste generated. There are three types of generators: Very Small Quantity Generator

(VSQG), Small Quantity Generator (SQG) and Large Quantity Generator (LQG). Definitions for

each generator category are located at 40 CFR 260.10. The generator category is based on the

volume of hazardous waste generated in a calendar month and as summarized in the table below.

Generator Category Hazardous Waste Quantity

Limits

VSQG

≤100 kg (220 lb)

≤ 1 kg Acute

<100 kg Acute Spill Waste

SQG

100 to ≤1000 kg (2200 lb)

≤ 1 kg Acute

≤100 kg Acute Spill Waste

LQG

>1000 kg (2200 lb)

> 1 kg Acute

>100 kg Acute Spill Waste

Certain wastes are not counted towards the generator category determination. These include:

• Material in legitimate production processes per 261.4(c),

• Samples per 261.4(d),

• Treatability Study Samples per 261.4(e),

• Samples Undergoing Treatability Studies at Testing Facilities per 261.4(f),

• Hazardous recyclable material 261.6(a)(3),

• Residues in Empty Containers per 261.7,

• PCBs regulated under TSCA per 261.8,

• Elementary neutralization waste, wastewater treatment units, or totally enclosed treatment

facilities as defined in 40 CFR 260.10;

• Waste recycled, without prior storage or accumulation, only in an on-site process subject to

regulation under 40 CFR 261.6(c)(2);

• Used oil managed under the requirements of 40 CFR 261.6(a)(4) and 40 CFR part 279;

• Spent lead-acid batteries managed under the requirements of 40 CFR part 266 subpart G;

• Universal waste managed under 40 CFR 261.9 and 40 CFR part 273;

• Unused commercial chemical products generated solely as a result of a laboratory clean-out

conducted at an eligible academic entity pursuant to §262.213; or


• Is managed as part of an episodic event in compliance with the conditions of 40 CFR Subpart

L.

• Is a hazardous waste pharmaceutical, as defined in §266.500, that is subject to or managed in

accordance with 40 CFR part 266 subpart P or is a hazardous waste pharmaceutical that is

also a Drug Enforcement Administration controlled substance and is conditionally exempt

under §266.506.

EPA Identification Numbers

SQG and LQGs are required to obtain an EPA identification number before they treat, store,

dispose of, transport, or offer for transportation, hazardous waste. The EPA ID number is site

specific. The identification number remains with the location not the business.

• By September 1 of 2021 and every four years thereafter a small quantity generator

must re-notify EPA using EPA Form 8700-12. This re-notification must be submitted

by September 1st of each year in which re-notifications are required.

• A large quantity generator must re-notify EPA by March 1 of each even-numbered

year thereafter using EPA Form 8700-12. A large quantity generator may submit this

re-notification as part of its Biennial Report required under §262.41.

This highlights one of the primary differences between LQGs and SQGs. The SQG is not

required to submit a biennial report.

VSQG’s are not required to obtain an EPA ID number and are exempt from most of the RCRA

generator requirements.

Other conditions for exemption for a very small quantity generator are located at 40 CFR 262.14.

Conditions for exemption applicable to small and large quantity generators are located at 40 CFR

262.16 and 262.17, respectively.

Training

Both small and large quantity generators are required to train their employees.

Large quantity generators must train their employees in a manner that ensures the company’s

compliance with applicable RCRA regulations.

At a minimum EPA requires a training program designed to ensure that facility personnel are

able to respond effectively to emergencies by familiarizing them with emergency procedures,

emergency equipment, and emergency systems, including where applicable:

1. Procedures for using, inspecting, repairing, and replacing facility emergency and monitoring

equipment;

2. Key parameters for automatic waste feed cut-off systems;

3. Communications or alarm systems;

4. Response to fires or explosions;

5. Response to ground-water contamination incidents; and

6. Shutdown of operations.


Although not detailed in the training regulation, other topics that should be considered to ensure

RCRA compliance may include but are not limited to:

1. Accumulation time limits (e.g., LQG 90-day storage and satellite accumulation limits)

2. Container/tank management

3. Hazardous waste regulations

4. Inspections

5. Hazardous waste determinations

6. Manifesting, labeling, marking and placarding

7. Chemical and physical properties of waste

8. Reporting and recordkeeping

9. Waste minimization

10. Packaging

Initial training must be provided within 6 months of employment and must be reviewed each

year. Training records must be kept for all current employees. Training records for all former

employees must be retained for at least three years. Training records for LQGs must include:

1. The job title and name of the employee

2. Written job description

3. Written description of the type and amount of initial and annual review training that will be

provided for each position. This training documentation requirement is what sets a

generators amount of required training (e.g., number of hours of initial and annual review

training). Federal regulations do not specify the number of hours that employees must be

trained.

4. Records that indicate the required training has been provided.

Small Quantity Generators are required to provide initial training but are not required to provide

annual review training. This highlights one of the primary differences between LQGs and SQGs.

The amount and type of initial training is also potentially different (e.g., less) from the LQG.

The bar that the SQG must hurdle is lower than the LQG. An SQG is required to “ensure that all

employees are thoroughly familiar with proper waste handling and emergency procedures,

relevant to their responsibilities during normal facility operations and emergencies.”

262.16(b)(9)(iii)

Hazardous Waste Manifest

Small and Large Quantity Generators must use a uniform hazardous waste manifest when

shipping hazardous waste off site.

A manifest is not required when transporting hazardous wastes on a public or private right-of-

way within or along the border of contiguous property.

The Federal government does not require the use of a Hazardous Waste Manifest for:

• Non-hazardous Waste

• VSQG Hazardous Waste

• Universal “Hazardous” Waste


However, State regulations may require the use of a manifest for these wastes. The manifest

system will be discussed later in this manual.

The DOT does not consider material to be a hazardous waste if it is not required to be

manifested. Further, if the material does not meet the definition of Hazard Class 1 – 8, it is not a

hazardous material (i.e., it is not Class 9).

Pre-Transport Requirements

In accordance with 40 CFR 262 Subpart C, hazardous waste generators must comply with the

following Department of Transportation (DOT) hazardous materials regulations.

1. Packaging

2. Labeling

3. Marking

4. Placarding

Each of these regulations will be discussed in detail later in this manual. 40 CFR 262 Subpart C

RCRA Container Requirements

Although there are additional storage requirements for tanks, drip pads, and containment

buildings not included in this training material see 40 CFR 262.16 and 262.17; this section will

focus on the more common container storage requirements. VSQG, SQG and LQGs are exempt

from certain requirements under RCRA as long as the conditions for the exemption are complied

with. For example, a large quantity generator is allowed to store hazardous waste up to 90 days

without obtaining a permit as long as the following conditions are met. Requirements applicable

to container management are summarized below.

1. The container is in good condition. If it is in poor condition or begins to leak the waste is

transferred to a container in good condition.

2. Compatibility: The container is compatible with its contents; waste is not added to a

container with incompatible residue and incompatible waste is not placed in the same

container.

3. The container is kept closed except when adding or removing waste or for safety reasons

(over pressurization).

4. The container is not handled in a way that would cause it to rupture or leak.

5. Container storage areas are inspected at least once each week. Inspecting for items such as:

a. Leaking containers

b. Containers in poor condition

c. Open containers

d. Containers stored over 90 days

e. Container grounding

f. Labeling and marking

g. Emergency equipment

6. Containers of ignitable or reactive waste must be stored at least 50 feet from the company’s

property line. Under the generator improvement rule, this requirement can be waived if

written approval is obtained from the authority having jurisdiction over the local fire code


allowing hazardous waste accumulation to occur within this restricted area.

7. Individual containers of incompatible waste must be separated with the use of walls, curbs or

other devices.

8. Take precautions to prevent accidental ignition or reaction of ignitable or reactive waste by

separating and protecting waste from sources of ignition or reaction this includes but not

limited to: open flames, smoking, cutting and welding, hot surfaces, frictional heat, sparks

(static, electrical, or mechanical), spontaneous ignition, and radiant heat). While ignitable or

reactive waste is being handled, the large quantity generator must confine smoking and open

flame to specially designated locations. “No Smoking” signs must be conspicuously placed

wherever there is a hazard from ignitable or reactive waste.

9. Containers of hazardous waste greater than 5-gallon capacity must be free of any openings

and authorized by the DOT. This will ensure compliance with air emissions standards under

40 CFR Subpart CC. Additional air emission requirements may apply to containers greater

than 119-gallon capacity.

10. The date of accumulation is clearly marked on the container and is visible for inspection.

11. The container is clearly marked with the words “Hazardous Waste”.

12. The container is marked in a manner that indicates the hazards. Options include but are not

limited to:

a. Hazardous waste characteristic(s) - Ignitable, corrosive, reactive, and/or toxic;

b. DOT Hazardous material communication - labeling or placarding;

c. OSHA/GHS hazard statement or pictogram;

d. NFPA 704 Chemical hazard label

13. Storage time limits are not exceeded. This highlights one of the primary differences between

the generator categories.

Generator Category Time Limit

VSQG None

SQG 180/270 Days

LQG 90 Days

Universal Waste 1 Year

14. Accumulation limits do not define the generator category. If the VSQG exceeds their non-

acute accumulation limits, they must manage all accumulated waste as if they were an SQG

but they are not required to change their generator category. If the VSQG exceeds their acute

hazardous waste accumulation limits, they must ship all accumulated waste off-site within 90

days and comply with LQG requirements in 40 CFR 262.17. If the SQG exceeds their 6000

kg accumulation limit, they must change to an LQG or obtain a permit to store waste.

Generator Category Hazardous Waste Accumulation

Limit

VSQG 1000 kg (2200 pounds) Non-Acute

1 kg Acute

100 kg Acute Spill Waste

SQG 6000 kg (13,200 pounds)

LQG None


15. SQG and LQG comply with the Preparedness and prevention requirements. In addition,

LQG complies with the Contingency Plan requirements of 40 CFR 262 Subpart M.

The following table summarizes Satellite Accumulation Area (SAA) and Centralized

Accumulation Area (CAA) container management requirements for each generator category. The

numbers in this table match the requirements enumerated above.

Container Management Table

SAA VSQG CAA

SQG LQG Container Storage Requirements

X X X 1 Containers in Good Condition

X X X 2 Container is and contents (including residues) are compatible

X X X 3 Container closed except when adding waste or for safety X X 4 Container Handled Safely X X 5 Inspected Weekly X 6 Ignitable and Reactive Waste > 50 ft from property line X 7 Protected from sources of ignition

X X X 8 Segregate Incompatible Waste X 9 Comply with 40 CFR Subpart CC

Excess X X 10 Mark Accumulation Date (excess = date SAA limits are exceeded)

X X X 11 Mark Hazardous Waste

X X X 12 Mark/Label Indicating Hazards

Unlimited 180/270 90 13 Storage Time Limits (days) 1000* 6000 None 14 *Non-acute Hazardous Waste Accumulation limits (kg)

X X X 15 Preparedness and Prevention + (Contingency Plan for LQG)

X 16 Close solid waste management units

40 CFR§§ 262.17 for LQG, 262.16 for SQG

* The VSQG may also not accumulate (i.e., store) more than 1kg of acute hazardous waste (e.g., P-coded waste)

or 100 kg of spill material contaminated with acute hazardous waste.

Preparedness and Prevention

SQG must comply with the preparedness and prevention requirements in 40 CFR 262.16(b)(8)

and LQGs must comply with the emergency procedures in 40 CFR 262 Subpart M which include

the same preparedness and prevention requirements applicable to the SQG; however, the LQG

must also comply with the written contingency plan requirements in Subpart M. Preparedness

and prevention elements include:

1. Minimize the possibility of fire, explosion or release of hazardous waste.

2. Where the hazards presented by the waste would warrant the need for emergency response

equipment, the CAA must be equipped with the following:

a. Internal Communication or alarm system capable of providing immediate emergency

instruction to employees. All employees must have immediate access to this

equipment when hazardous waste is being handled.

b. A means, immediately available at the scene of operations, to contact local authorities

for emergency assistance.

c. Portable fire extinguishers.

d. Spill control equipment.

e. Decontamination Equipment.


f. Adequate water supply and pressure for fire hoses and sprinkler systems or other

automated fire suppression equipment.

This equipment must be tested and maintained to ensure proper operation.

3. Maintaining aisle space to allow unobstructed movement of personnel and equipment to any

area involved in an emergency.

4. Attempt to make arrangements with police, fire department and emergency response teams,

hospitals to familiarize them with:

a. Layout of the facility

b. Properties and hazardous of waste handled

c. Places where employees would normally be working

d. Entrances to roads inside the facility and

e. Possible evacuation routes.

Records of attempts or actual agreements must be maintained.

5. Familiarizing local hospitals with properties of hazardous waste handled and the types of

injuries or illnesses which could occur from fires, explosions or releases.

SQG Emergency Procedures

Where hazardous waste is generated and accumulated:

1. At all times there must be at least one emergency coordinator either on the premises or on

call (i.e., available to respond to an emergency by reaching the facility within a short period

of time) with the responsibility for coordinating the following emergency response measures

emergency coordinator.

a. In the event of a fire, call the fire department or attempt to extinguish it using a fire

extinguisher;

b. In the event of a spill, contain the flow of hazardous waste to the extent possible, and as

soon as is practicable, cleaning up the hazardous waste and any contaminated materials or

soil. Containment and cleanup can be conducted either by the SQG or by a contractor;

c. In the event of a fire, explosion, or other release that could threaten human health outside

the facility or when the SQG has knowledge that a spill has reached surface water, the

SQG must immediately notify the National Response Center (using their 24-hour toll free

number 800/424-8802). The report must include the following information:

• The name, address, and U.S. EPA identification number of the small quantity

generator;

• Date, time, and type of incident (e.g., spill or fire);

• Quantity and type of hazardous waste involved in the incident;

• Extent of injuries, if any; and

• Estimated quantity and disposition of recovered materials, if any.

2. The small quantity generator must post the following information next to telephones or in

areas directly involved in the generation and accumulation of hazardous waste:

• The name and emergency telephone number of the emergency coordinator;

• Location of fire extinguishers and spill control material, and, if present, fire alarm;

and

• The telephone number of the fire department, unless the facility has a direct alarm.

3. Ensure that all employees are thoroughly familiar with proper waste handling and emergency

procedures, relevant to their responsibilities during normal facility operations and

emergencies. NOTE this is the only reference to training for SQGs.


LQG Emergency Procedures – Contingency Plan

1) Describe the actions facility personnel must take to minimize hazards to human health or the

environment from fires, explosions, or any unplanned sudden or non-sudden release of

hazardous waste or hazardous waste constituents to air, soil, or surface water and in the event

of an emergency:

a) Activate internal facility alarms or communication systems, where applicable, to notify

all facility personnel;

b) Notify appropriate state or local agencies with designated response roles if their help is

needed.

c) Immediately identify the character, exact source, amount, and areal extent of any released

materials

d) Concurrently, assess possible hazards to human health or the environment

e) If a release, fire, or explosion could threaten human health, or the environment, outside

the facility, the emergency coordinator must report the findings as follows:

i) Notify appropriate local authorities if evacuation of local area is advisable or provide

assistance to appropriate officials in making this decision; and

ii) Immediately notify either the government official designated as the on-scene

coordinator for that geographical area, or the National Response Center (using their

24-hour toll free number 800/424-8802). The report must include:

(1) Name and telephone number of reporter;

(2) Name and address of the generator;

(3) Time and type of incident (e.g., release, fire);

(4) Name and quantity of material(s) involved, to the extent known;

(5) The extent of injuries, if any; and

(6) The possible hazards to human health, or the environment, outside the facility.

f) During an emergency, take all reasonable measures necessary to ensure that fires,

explosions, and releases do not occur, recur, or spread to other hazardous waste at the

generator's facility. These measures must include, where applicable, stopping processes

and operations, collecting and containing released hazardous waste, and removing or

isolating containers

g) If the generator stops operations, monitor for leaks, pressure buildup, gas generation, or

ruptures in valves, pipes, or other equipment, wherever this is appropriate

h) Immediately after an emergency

i) Provide for treating, storing, or disposing of recovered waste,

ii) Ensure that no hazardous waste that may be incompatible with the released material is

treated, stored, or disposed of until cleanup procedures are completed; and all

emergency equipment is cleaned and fit for its intended use before operations are

resumed.

iii) Within 15 days note in the operating record submit a written report on the incident to

the Regional Administrator. The report must include:

(1) Name, address, and telephone number of the generator;

(2) Date, time, and type of incident (e.g., fire, explosion);

(3) Name and quantity of material(s) involved;

(4) The extent of injuries, if any;

(5) An assessment of actual or potential hazards to human health or the environment,

where this is applicable; and


(6) Estimated quantity and disposition of recovered material that resulted from the

incident.

2) The plan must describe arrangements agreed to with the local police department, fire

department, other emergency response teams, emergency response contractors, equipment

suppliers, local hospitals or, if applicable, the Local Emergency Planning Committee.

3) The plan must list names and emergency telephone numbers of all persons qualified to act as

emergency. Where more than one person is listed, one must be named as primary emergency

coordinator and others must be listed in the order in which they will assume responsibility as

alternates

4) The plan must include a list of all emergency, the location and a physical description of each

item on the list, and a brief outline of its capabilities.

5) The plan must include an evacuation plan for generator personnel where there is a possibility

that evacuation could be necessary.

Closure Requirements for LQGs

Under the generator improvement rule closure requirements now apply to LQGs accumulating

hazardous waste in containers. Regulations previously only required closure for tanks, drip pads,

and containment buildings.

The LQG may either:

1) Place a notice in the operating record within 30 days after closure identifying the location of

the unit within the facility. If the waste accumulation unit is subsequently reopened, the

generator may remove the notice from file; or

2) Notify EPA using form 8700-12 of the intention to close the facility 30 days before initiating

closure, and notify EPA using form 8700-12 within 90 days after closing the facility

declaring that closure performance standards have been met or the unit will be closed as a

landfill.

The closure requirements do not apply to satellite accumulation areas.

Satellite Accumulation Areas (SAA)

Satellite accumulation containers are exempt from the container storage requirements above and

the accumulation time limits (90/180/270-day clock) as long as the following requirements are

met. 40 CFR 262.15

1. Container size does not exceed 55-gallons for hazardous waste or 1-quart (liquids) or 1-

kiliogram (solids) for acutely toxic hazardous waste.

2. The container is at or near the point of generation.

3. The container is under control of the process operator.

4. The generator complies with items 1 through 3, 8, 11, 12 and 15 in the Container

Management Table above.

When the SAA limits are exceeded mark the container with the accumulation start date. Within

three days of exceeding SAA quantity limits move the container to the CAA and comply with all

other applicable container requirements.


Reduced Requirements for Small Quantity Generators

The small quantity generator (SQG) may store hazardous waste up to 180 days (or 270 days if

they ship their waste to TSDF over 200 miles away). As long as the SQG follows all conditions

for exemption in 262.16 (e.g. accumulation limit of 6,000 kg. The SQG is not required to follow

the following requirements applicable to LQGs.

• Annual RCRA training.

• Prepare a written contingency plan.

• Prepare and submit a Biennial Report.

• Notification for closure of waste management units or the facility.

• Submit an exception report, if a manifest with handwritten signature is not received from

the designated facility within 45 days. The SQG basically has to do this but they have 60

days to submit the3 information.

The SQG does not have to maintain a detailed contingency plan nor comply with the same level

of training requirements for the large quantity generator.

Land Disposal Restriction Notifications 40 CFR 268

Small and large quantity generators must comply with the land disposal restriction notification

requirements in 40 CFR 268.7(a)(5). This information must be retained for at least 3 years and

include:

1. EPA Hazardous Waste Number (F, K, P, U and D-Codes)

2. The US EPA 12-digit identification number

3. Constituents of concern which are specific chemical names for:

a. F-Code Solvents

b. Underlying Hazardous Constituents. These are chemical constituents listed in 40

CFR 268.48 (see tab 10) above a certain level that are not identified in the

treatment standards for the EPA hazardous waste numbers assigned to the waste.

4. Whether the waste is a wastewater (<1% TOC and <1% TSS) or Non-wastewater.

5. Waste analysis data, if available.

Universal Waste Reduced Requirements

Types of Universal Waste

Universal waste includes hazardous waste:

1. Batteries

2. Certain Pesticides

3. Mercury Containing Equipment, and

4. Lamps

5. Aerosol Cans

Reduced RCRA Requirements

Companies that accumulate less than 11,000 pounds of universal waste are Small Quantity


Handlers and must manage their universal waste as follows:

1. Universal waste may be stored up to one year.

2. The generator of universal waste must be able to demonstrate the length of time that the

universal waste has been accumulated. For example, mark the date the waste was

removed from service. The date on the waste or container should represent the oldest

item placed in the container. Other specific methods are allowed under 273.15.

3. Containers that are closed, structurally sound and compatible with the material must be

used for:

a. Batteries in poor condition or batteries that could leak if not containerized.

b. Pesticides,

c. Mercury containing equipment in poor condition or equipment that could leak if

not containerized. This package must be designed to prevent the escape of

mercury into the environment by volatilization.

d. Lamps (broken or whole).

4. Mark the container “Universal Waste” and the type of universal waste (e.g., Universal

Waste - Aerosol Cans,” “Waste Aerosol Cans,” or “Used Aerosol Cans.

5. Train employees how to properly handle universal waste and emergency procedures.

6. Immediately contain any universal waste releases.

Companies that accumulate more than 11,000 pounds of universal waste at any time are Large

Quantity Handlers and must manage their universal waste as follows:

1. Follow the same requirements as the small quantity handler, and

2. Track universal waste shipments by keeping a record of each shipment (e.g., shipping

paper) and retain the record for at least three years.

Episodic Generation Reduced Requirements 40 CFR 262 Subpart L

This section applies to VSQG and SQG. This alternative regulation allows the VSQG or SQG to

exceed their generator category limits without changing their generator category.

There are two types of episodic events: planned and unplanned. “Planned episodic event means

an episodic event that the generator planned and prepared for, including regular maintenance,

tank cleanouts, short-term projects, and removal of excess chemical inventory.

Unplanned episodic event means an episodic event that the generator did not plan or reasonably

did not expect to occur, including production process upsets, product recalls, accidental spills, or

“acts of nature,” such as tornado, hurricane, or flood.”

The generator is allowed one episodic event per year with the ability to petition for a second

episodic event of a different type. If the first event was unplanned, the generator can request a

second event, but it must be planned and vice versa.

Notify EPA 30 days before a planned event using form 8700-12.

Notify EPA 72 hours after an unplanned event by phone or e-mail then using form 8700-12.

The episodic event notice shall include:


1. Start date and end date

2. Reason(s) for the event,

3. Types and estimated quantities of hazardous waste expected to be generated,

4. Facility contact and emergency coordinator with 24-hour telephone access.

If the VSQG does not already have one, an EPA ID number must be obtained using form 8700-

12.

Mark containers “Episodic Hazardous Waste” and indication of the hazards and the date the

episodic event began.

Within 60 days of the start of the episodic event ship waste off-site for disposal to a designated

facility authorized to receive the waste.

Use a hazardous waste manifest when shipping the waste off-site.

Maintain records of the episodic event for three years.

Consolidation of Waste Shipments from VSQG to LQG Sites

In accordance with 40 CFR 262.14 (a)(5) a very small quantity generator is allowed to ship

hazardous waste to a large quantity generator in the same company and 40 CFR 262.17(f) allows

the LQG to receive that waste.

The VSQG marks containers in the same manner as required for container located in a SAA (i.e.,

the words “Hazardous Waste” and indication of the hazards).

The receiving LQG must notify the EPA using form 8700-12 of the intent to receive waste from

the VSQG 30 days in advance of the first shipment. Form 8700-12 must also be updated within

30 days if the name or address of the VSQG changes.

Upon receipt, the LQG marks the date of receipt on the container. Within 90 days of that date,

ship the waste off-site for treatment or disposal.

The LQG is allowed to consolidate VSQG waste or waste from multiple VSQGs with their own

waste. If this occurs, the date of the earliest generated or received waste must be marked on the

container.

Records of the receipt must be maintained for 3 years. The easiest method for this would be

copies of the shipping paper and 8700-12 notice.

Rejected Shipments

In the event that hazardous waste is rejected by the designated facility and returned to the SQG

or LQG, the generator must:

1. Sign section 18 (if the original manifest is used for the rejected shipment) or section 20

(if a new manifest is created for the rejected waste) and return the signed copy to the

rejecting facility.


2. Manage the returned waste under all conditions for exemption applicable to their

generator category.


HAZARDOUS SUBSTANCES AND REPORTABLE QUANTITIES (RQ)

The U.S. EPA is the agency responsible for the establishment of regulations regarding hazardous

substances; however, the DOT has been given the responsibility of enforcing these regulations

while the waste is in the transportation system. The hazardous substance list is located at

Appendix 3 in this manual.

There is one primary difference between the DOT and EPA with respect to hazardous substance

regulations. The DOT only considers the volume of waste in a single package when determining

if the material meets the definition of a hazardous substance; while the EPA is concerned with

the total quantity of waste released to the environment. For example, a 5-gallon pail of carbon

disulfide weighing 52 pounds would not be described as a hazardous substance on a shipping

paper since the RQ for carbon disulfide is 100 pounds. However, if two of these pails were

released to the environment in a 24-hour period, a CERCLA hazardous substance release would

have occurred.

STEP BY STEP HAZARDOUS SUBSTANCE DETERMINATION PROCEDURES

A material is regulated as a hazardous substance by the DOT if it is identified in Appendix A of

the 49 CFR 172.101 Hazardous Materials Table and the quantity of the material in the

container equals or exceeds the RQ.

1. The first step in making a hazardous substance determination is to:

Identify the specific chemical name(s) and quantity(s) of each potential hazardous

substance in the waste, and

Identify the appropriate EPA hazardous waste code(s) (excluding U and P codes)

and total quantity of waste in the container.

2. Listed Chemicals*

If the waste is composed of a single chemical identified by name in the hazardous

substance table, then it is hazardous substance if the quantity of the chemical in the

container, is equal to or greater than its RQ value.

EXAMPLE

A 500-pound container of carbon disulfide would be a hazardous substance since its RQ

is 100 pounds. If 100 pounds of this material were released to the environment in a 24-

hour period a reportable quantity release under CERCLA would have occurred.

3. Unlisted Chemicals*

If the waste is composed of a single chemical which is not identified by name in the

hazardous substance table but exhibits a hazardous characteristic (D-Coded) identified in

the hazardous substance table, then it is a hazardous substance if the entire weight of the

waste in the container equals or exceeds the RQ value for the characteristic.

EXAMPLE

A 500-pound container of ethanol which exhibits the hazardous characteristic of


ignitability (D001) is a hazardous substance since the RQ for D001 is 100 pounds. If 100

pounds of this material were released to the environment in a 24-hour period a reportable

quantity release under CERCLA would have occurred.

4. a. Listed Chemicals in Mixtures with Quantities Known

If the waste is composed of a mixture of chemicals which are all identified by

name in the hazardous substance table and the quantity of each chemical in the

waste is known, then it is a hazardous substance if the weight of any chemical in

the container equals or exceeds its RQ. In this case you must determine the

weight of each chemical in the container.

EXAMPLE

A container of 450 pounds of Carbon tetrachloride and 50 pounds of 1,1,2-

Trichloroethane would be a hazardous substance for Carbon tetrachloride since its

RQ is 10 pounds but would not be a hazardous substance for 1,1,2-

Trichloroethane since its RQ is 100 pounds. If 11.1 pounds of this mixture was

released to the environment in a 24-hour period, then a hazardous substance

release under CERCLA would have occurred.

NOTE: The equation for determining a CERCLA release is: (the weight of entire waste ÷

weight of one component) x (that components RQ value). In the example above: (500 pounds ÷

450 pounds) x 10 pounds = 11.1 pounds

b. Listed Chemicals in Mixtures with Quantities Unknown

If the waste is composed of a mixture of chemicals which are all identified by

name in the hazardous substance table and the quantity of each chemical in the

waste is unknown, then it is a hazardous substance if the entire weight of the

waste equals or exceeds the RQ value for any chemical in the waste. In this case

you assume that each chemical in the waste is 100% of the waste.

EXAMPLE

A 500-pound container of Carbon tetrachloride and 1,1,2-Trichloroethane would

be a hazardous substance for Carbon tetrachloride and 1,1,2-Trichloroethane since

the weight of the waste exceeds the RQs for both chemicals. In this case if 10

pounds of the mixture were released to the environment in a 24-hour period then a

hazardous substance release under CERCLA would have occurred.


5. Unlisted Chemicals in Mixtures

If the waste is composed of a mixture of unlisted constituents, and the waste exhibits

more than one hazardous characteristic, it is a hazardous substance if the entire weight of

the waste exceeds the RQ for any characteristic.

EXAMPLE

A 200-pound container of Ethanol and Lead oxide which exhibited the hazardous

characteristic of ignitability (D001, RQ=100 pounds) and toxicity (D008, RQ=10

pounds) would be a hazardous substance for both D001 and D008 since the weight of the

waste in the container exceeds the RQs for both hazardous characteristics. If 10 pounds

of this mixture was released to the environment in a 24-hour period a hazardous

substance release under CERCLA would have occurred.

6. Mixtures of Listed and Unlisted Compounds

If the waste is composed of a mixture of chemicals specifically listed in the hazardous

substance table and unlisted chemicals which cause the waste to exhibit a hazardous

characteristic, it is a hazardous substance if either the weight of any listed constituent

exceeds its RQ or if the entire weight of the waste exceeds the RQ for any hazardous

characteristic.

EXAMPLE

A container of 200 pounds of acetone (listed, RQ = 5000 pounds) and 200 pounds of

ethanol (unlisted, exhibits the characteristic ignitability, RQ = 100 pounds) would be a

hazardous substance for D001.

If a reportable quantity release has occurred, you must IMMEDIATELY notify the National

Response Center at 800-424-8802. As is the case in Texas, you may also have to report a

release of this nature to several other agencies. These agencies should be identified in the

company's contingency plan.

* The term "listed" hazardous substances refers to chemicals identified by name in the

hazardous substance table and the term "unlisted" hazardous substances refers to

characteristically hazardous wastes (D001 through D043) also identified in the hazardous

substance table.

REFERENCES: 1. FR50, No. 65, April 4, 1985, p. 13463

2. 40 CFR 302.5

3. 40 CFR 302.6

4. 49 CFR 171.8

5. 49 CFR 172.101 (c) (8)

6. 49 CFR 172.101 Appendix A

7. 49 CFR 172.203 (c)


DOT HAZARDOUS MATERIALS CLASSIFICATION

After the hazardous waste and hazardous substance classifications are completed, the third and

last step in the complete classification of a waste is to conduct the hazardous materials

classification. In this classification step you will determine the hazard class or division and the

packing group of the material as defined in 49 CFR 173.

The first place you must reference to make a hazardous material determination is the Hazardous

Materials Table located at 49 CFR 172.101 (Appendix 2). The shipping name (either a chemical

name or more generic description) will appear in column 2. The primary hazard class or division

will appear directly to the right in Column 3; the packing group in column 5; and subsidiary

hazard(s) in column 6 (labels column).

If the chemical name does not appear in column 2, you must determine if the chemical meets the

definition of one or more of the 21 hazard classes or divisions listed below. For this step you

should be able to use some of the information gathered while making the hazardous waste

determination. In addition to identifying the appropriate hazard class or division, you must also

determine the degree of hazard presented by each class or division. For example Class 3

(flammable liquids) is further divided into three packing groups (I, II or III), Division 5.2

(organic peroxides) is further divided into seven types (A through G) and division 2.3 is divided

into four hazard zones (A, B, C and D).

Hazard

Class

Division Name of Class or Division Citation

None Forbidden materials 173.21

None Forbidden explosives 173.54

1 1.1 Explosives (with a mass explosion hazard) 173.50

1 1.2 Explosives (with a projection hazard) 173.50

1 1.3 Explosives (with predominately a fire hazard) 173.50

1 1.4 Explosives (with no significant blast hazard) 173.50

1 1.5 Very insensitive explosives; blasting agents 173.50

1 1.6 Extremely insensitive detonating substances 173.50

2 2.1 Flammable gas 173.115

2 2.2 Non-flammable compressed gas 173.115

2 2.3 Poisonous gas 173.115

3 Flammable and combustible liquid 173.120

4 4.1 Flammable solid 173.124

4 4.2 Spontaneously combustible material 173.124

4 4.3 Dangerous when wet material 173.124

5 5.1 Oxidizer 173.128

5 5.2 Organic peroxide 173.128

6 6.1 Poisonous materials 173.132

6 6.2 Infectious substance (Etiologic agent) 173.134

7 Radioactive material 173.403

8 Corrosive material 173.136

9 Miscellaneous hazardous material 173.140

None Other regulated material: ORM-D 173.144


Except for forbidden material (§173.21), explosives (§§173.54 and 173.56(e)), self-reactive samples (§173.224(c)) and

organic peroxide samples (§173.225(c)), "a material that is considered to be a hazardous waste or a sample of a

material for which the hazard class is uncertain and must be determined by testing may be assigned a tentative proper

shipping name, hazard class, identification number and packing group, if applicable, based on the shipper's tentative

determination according to:”

(1) Hazard Class/Division Definitions,

(2) Hazard precedence, and

(3) Shippers knowledge of the material

(4) For samples, the following must be met:

(A) The word "Sample" must be entered in association with the basic description on the shipping paper

unless already part of the shipping name;

(B) Provisions for technical names do not apply if the primary constituent(s) for which the tentative

classification is based are not known; and

(C) A sample must be transported in a combination packaging which conforms to the requirements of this

subchapter that are applicable to the tentative packing group assigned, and may not exceed a net mass of

2.5 kg. (5.5 pounds) per package.

Note to Paragraph (c)(11): For the transportation of samples of self-reactive materials, organic peroxides, explosives or

lighters, see §§173.224(c)(3), 173.225(c)(2), 173.56(d) or 173.308(b)(2) of 49 CFR Subchapter C, respectively.

§172.101(c)(11)

FORBIDDEN MATERIAL

Materials that may not be offered for transportation. Many of these materials are identified in

the Hazardous Materials Table. Additional forbidden materials are identified in §173.54.

CLASS I (Explosives)

Definition - Explosives are defined as any substance, article, or device designed to function by

explosion (i.e. an extremely rapid release of gas or heat) or which, by chemical reaction within

itself, is able to function in a similar manner even if not designed to function by explosion.

CLASS 1 DIVISIONS

1.1 Explosives (with mass explosion hazard) §173.50(b)(1)

1.2 Explosives (with a projection hazard) §173.50(b)(2)

1.3 Explosives (with predominately a fire hazard) §173.50(b)(3)

1.4 Explosives (with no significant blast hazard) §173.50(b)(4)

1.5 Very insensitive detonating substances; blasting agents §173.50(b)(5)

1.6 Extremely insensitive detonating substances §173.50(b)(6)


CLASS 2 DIVISION 2.1 FLAMMABLE GAS

Definition: Any material which is a gas at 68°F or less and 14.7 psi [atmospheric pressure] of

pressure and is ignitable when in a mixture of 13 percent or less by volume with air or has a

flammable range with air of at least 12 percent at 14.7 psia and 68°F. §173.115(a)

Examples: Butane, Acetylene, Ethylamine

CLASS 2 DIVISION 2.2 NON-FLAMMABLE GAS

Definition: (1) Exerts in the packaging a gauge pressure of 200 kPa (29 psig) or greater at 20 °C

(68 °F), is a liquefied gas or is a cryogenic liquid, and (2) Does not meet the definition of

Division 2.1 or 2.3. (§173.115(b)). These include compressed gas, liquefied gas, pressurized

cryogenic gas, compressed gas in solution, asphyxiant gas and oxidizing gas).

Asphyxiant Gas: “a gas which dilutes or replaces oxygen normally in the atmosphere."

Oxidizing gas: "a gas which may, generally by providing oxygen, cause or contribute to the

combustion of other material more than air does."

Examples: Oxygen, Argon, Carbon Dioxide, Chlorodifluoromethane, Nitrogen, Nitrous Oxide.

CLASS 2 DIVISION 2.3 POISONOUS GAS

Definition: A gas poisonous by inhalation is any material which is a gas at 68°F at 14.7 psi and

which is known to be so toxic to humans as to pose a hazard during transportation or in the

absence of human toxicity data it has an LC50 < 5000 ml/m3. See Appendix 7 for a list of

division 2.3 materials with appropriate hazard classes or divisions and hazard zones.

§173.115(c).

Hazard Zone Determination and Examples:

In addition to classifying poisonous gases as Division 2.3, the hazard zone must also be

determined.

Hazard Zone LC50 (ppm) Examples

A <200 Arsine, Boron Trichloride, Cyanogen Chloride

B >200 <1000 Boron Trifluoride, Cyanogen, Chlorine

C >1000 <3000 Anhydrous Hydrogen Bromide, Sulfur Dioxide

D >3000 <5000 Anhydrous Ammonia, Carbon Monoxide, Silicon Tetrafluoride


CLASS 3 FLAMMABLE LIQUIDS

A flammable liquid is any liquid with a flash point < 140°F. §173.120 (a)

Packing Group Designations and Examples:

In addition to determining if the material meets the definition of a Class 3, you must also

determine the packing group.

Packing

Group

Flash Point

(closed cup)

Initial Boiling

Point

Examples

I <95°F Acetaldehyde

II < 73°F >95°F Acetone, Benzene, Hexane

III > 73°F < 140°F >95°F Kerosene, Diesel Fuel

CLASS 4 DIVISION 4.1 FLAMMABLE SOLID

There are three (3) definitions of flammable solids

Definition 1: Desensitized (e.g., wetted) explosive which has been identified as a Division 4.1

material in the hazardous materials table. §173.124 (a) (1)

Definition 2: Pursuant to §173.124(a)(2)(I) "Self-reactive materials are materials that are

thermally unstable and that can undergo a strongly exothermic decomposition even without

participation of oxygen (air). A material is excluded from this definition if any of the following

applies."

The material meets the definition of an explosive, in which case it must be described as an

explosive.

The material is forbidden.

The material meets the definition of an oxidizer or an organic peroxide and is classed

accordingly.

The material meets one or more of the following conditions:

- Its heat of decomposition is less than 300J/g; or

- Its self-accelerating decomposition temperature (SADT) is greater than 167°F.

Division 4.1 self-reactive materials are assigned to a generic system consisting of seven types (A

through G). Type A would present the greatest amount of danger and Type G the least amount

of danger. Type A Self Reactive Materials can detonate or deflagrate rapidly and are forbidden

from being transported. Whereas Type G Self Reactive Material: will not detonate in the

cavitated state, will not deflagrate, shows no effect when heated under confinement, nor shows

any explosive power.

A self-reactive substance identified by technical name in the Self-Reactive Material Table in §


173.224 is assigned to a generic type in accordance with that table. Any chemical which meets

the criteria of a self-reactive substance which is not identified by name in the 173.224 table must

not be shipped until the information specified in §173.124 (a)(2)(iii) is submitted to the associate

Administrator for Hazardous Materials Safety and written approval is received.

To determine the generic type, reference the chemical name of the self-reactive substance in the

§173.224 table (See Appendix 5). Follow across to column 2 and choose the identification

number that corresponds to the concentration for the self-reactive substance. Then go to the

hazardous materials table and look up the identification number in column 4 which appears to

the right of the shipping name "self-reactive...type..." in column 2.

Definition 3: Readily combustible solids are defined as:

"Material that may cause fire through friction, such as matches" §173.124(a)(3)(I)

"Powdered, granular or pasty materials that show a burning rate greater than 2.2 mm/s."

§173.124(a)(3)(ii) or

"Powders of metals or metal alloys that can be ignited and the reaction spreads over the

whole length of the sample in 10 minutes or less. §173.124 (a)(3)(iii)

Division 4.1 Packing Group Criteria and Examples

Packing

Group

Definition Examples

I As identified in the Hazardous Materials

Table

Nitrocellulose > 25% water

Picric acid > 10% in water

Trinitrotoluene > 30% water

Ammonium picrate > 10% water

Barium azide > 50% water

II Readily combustible material, other than for

metal powders, is assigned to Packing Group

II, if the burning time is less than 45 seconds

and the flame passes the wetted zone.

Decaborane

III Readily combustible material, other than

metal powders, are assigned to Packing

Group III, if the burning time is less than 45

seconds and the flame stops at the wetted

zone for at least four minutes.

Camphor (synthetic), magnesium, matches,

naphthalene, paraformaldehyde, phosphorous

(amorphous)

II Readily combustible metal powders are

assigned to Packing Group II if the zone of

reaction spreads over the whole length of the

sample in 5 minutes or less.

Coated aluminum powder, titanium powder with >

25% water

III Readily combustible metal powders are

assigned to Packing Group III if the zone of

reaction spreads over the whole length of the

sample in more than 5 minutes but not more

than 10 minutes.

The packing groups for materials which cause fire through friction are determined through

analogy with the hazardous materials table.


CLASS 4 DIVISION 4.2 SPONTANEOUSLY COMBUSTIBLE MATERIAL

There are two definitions for Division 4.2 materials.

Definition 1: Liquid or solid materials which are pyrophoric (ignite in contact with air)

§173.124 (b) (1)

Definition 2: A self heating material is defined as a material that when in contact with air is

liable to self heat. §173.124 (b) (2)

Division 4.2 Packing Group Criteria and Examples:

Packing

Group

Definition

Examples

I Pyrophoric material. Aluminum alkyls

Dimethyl zinc

Magnesium diphenyl

Pentaborane

Phosphorous (white)

Titanium powder (dry)

II Self heating materials which give a positive test result when tested

with a 25 mm3 sample at 140 C.

Potassium dithionite

Calcium hydrosulfite

Magnesium diamide

Sodium methylate

Fish meal

III A positive test result is obtained in a test using a 100 cm3 at 140 C

and a negative test result is obtained with a 25 mm3 sample at 140 C

and the substance is transported in packagings with a volume of more

than 3 m3; or

A positive test result is obtained in a test using a 100 cm3 at 120 C


and the substance is transported in packagings with a volume of more

than 450 liters; or

A positive test result is obtained in a test using a 100 cm3 at 100 C


and the substance is transported in packagings with a volume less

than 450 liters.

Activated carbon

Charcoal

Iron oxide


CLASS 4 DIVISION 4.3 DANGEROUS WHEN WET

Definition: Any material which when in contact with water is liable to become spontaneously

flammable or give-off a flammable or toxic gas at a rate >1 liter per Kg of material per hour.

§173.124(c)

Packing Group Designation and Examples:

Packing

Group

Definition Examples

I If the material reacts vigorously with water at ambient

temperatures and demonstrates a tendency for the gas

produced to ignite spontaneously, or which reacts

readily with water at ambient temperatures such that

the rate of evolution of flammable gases is equal or

greater than 10 liters per kilogram of material over any

one minute.

Aluminum hydride

Aluminum phosphide

Calcium carbide*

Calcium hydride

Calcium phosphide

Cesium

Ethyl dichlorosilane

Lithium

Lithium Aluminum Hydride

Lithium borohydride

Lithium nitride

Potassium

Potassium borohydride

Sodium

Trichlorosilane

II If the material reacts readily with water at ambient

temperatures such that the maximum rate of evolution

of flammable gases is equal to or greater than 20 liters

per kilogram of material per hour, and which does not

meet the criteria for Packing Group I.

Aluminum carbide

Aluminum Powder (uncoated)

Barium

Calcium

Calcium carbide*

Phosphorous pentasulfide

Sodium aluminum hydride

III If the material reacts slowly with water at ambient

temperatures such that the maximum rate of evolution

of flammable gases is greater than 1 liter per kilogram

of material per hour, and which does not meet the

criteria for Packing Group I or II.

Calcium cyanamide (with > 0.1%

calcium carbide)

Calcium manganese silicon


CLASS 5 DIVISION 5.1 OXIDIZERS

5.1 Solids Definition:

Any material which may cause or enhance the combustion of other materials by yielding

oxygen. A solid meets the definition of Division 5.1. if, when tested in accordance with the

UN Manual of Tests and Criteria, its mean burning time is less than or equal to the burning

time of a 3:7 potassium bromate/cellulose mixture. §173.127 (a)

5.1 Liquids Definition

A liquid is classified as a Division 5.1 material if, when tested in accordance with the UN

Manual of Tests and Criteria, it spontaneously ignites or its mean time for a pressure rise from

690 kPa to 2070 kPa gauge is less than the time of a 1:1 nitric acid (65 percent)/cellulose

mixture.

Packing Group Criteria for Division 5.1 Solids and Liquids

Packing

Group

Definition:

Examples

I For solids, any material which, in either concentration tested

exhibits a mean burning time less than the mean burning time

of a 3:2 potassium bromate/cellulose mixture.

Bromine trifluoride

Potassium peroxide

Potassium superoxide

Sodium peroxide

Tetranitromethane For liquids, any material which spontaneously ignites when

mixed with cellulose in a 1:1 ratio; or any material which

exhibits a mean pressure rise time less than the pressure rise

time of a 1:1 perchloric acid (50 percent)/cellulose mixture.

II For solids, any material which, in either concentration tested

exhibits a mean burning time less than or equal to the mean

burning time of a 2:3 potassium bromate/cellulose mixture

and the criteria for Packing Group I are not met

Ammonium dichromate

Calcium perchlorate

Calcium permanganate

Chromic acid

Chromium trioxide

Lead nitrate

Magnesium chlorate

Magnesium peroxide

Perchloric acid

Potassium chlorate

Potassium permanganate

Strontium perchlorate

For liquids, any material, which exhibits a mean pressure rise

time less than or equal to the pressure rise time of a 1:1

aqueous sodium chlorate solution (40 percent)/cellulose

mixture and the criteria for Packing Group I are not met.

III For solids, any material which, in either concentration tested

exhibits a mean burning time less than or equal to the mean

burning time of a 3:7 potassium bromate/cellulose mixture

and the criteria for Packing Group I and II are not met."

Ammonium nitrate

Ammonium persulfate

Calcium nitrate

Lead dioxide

Nickel nitrate

Potassium nitrate

Potassium persulfate

Sodium nitrate

For liquids, any material, which exhibits a mean pressure rise

time less than or equal to the pressure rise time of a 1:1 nitric

acid (65 percent)/cellulose mixture and the criteria for

Packing Group I and II are not met.


CLASS 5 DIVISION 5.2 ORGANIC PEROXIDES

Definition: Division 5.2 materials are defined as any organic compound containing oxygen

(o) in a bivalent -0-0- structure and which may be considered a derivative of hydrogen

peroxide, where one or more of the hydrogen molecules are replaced with organic radicals.

§173.128 (a)

In addition to determining if the material meets the definition of Division 5.2, you must also

determine the "general type". There are 7 general types (A-G) see §173.128 (b).

To determine the general type, reference the chemical name of the organic peroxide in the

173.225 table (See Appendix 5). Follow across to column 2 and choose the identification

number that corresponds to the concentration, percent diluent, and/or percent water for the

organic peroxide. Then go to the hazardous materials table and look up the identification

number in column 4 which will appear to the right of the shipping name "organic

peroxide...type...." in column 2.

Note: You may only ship the organic peroxide if it meets all the conditions specified in the

173.128 table.

However; "mixtures of organic peroxides individually identified in the Organic Peroxide

Table...may be classified as the same type of organic peroxide as that of the most dangerous

component and be transported under the conditions for transportation given this type..."

[Added: December 29, 1994 in HM-215a)

CLASS 6 DIVISION 6.1 POISONOUS MATERIAL

Definition: A division 6.1 poisonous material is defined as any "material other than a gas

which is known to be so toxic to humans as to afford a hazard to health during transportation,

or which, in the absence of adequate data on human toxicity" (§173.132 (a) (1):

1. Is presumed to be toxic to humans because it falls into one of the following categories

when tested on laboratory animals (albino rats)

a. Oral toxicity LD50/14 < 500 mg/kg for liquids or acute oral toxicity LD50/14 < 200

mg/kg for solids

b. Dermal toxicity LD50/14 < 1000 mg/kg

c. i. Inhalation toxicity LC50/14 < 10 mg/l for dusts and mists or

ii. A material which has a saturated vapor concentration in air (at 68°F) of 1/5

the LC50/14 for acute toxicity on inhalation of vapors and with an LC50/14 for

acute toxicity on inhalation of vapors of not more than 5000 ml/m3

2. It is an irritating material with properties similar to tear gas which causes extreme

irritation especially in confined spaces (i.e., Methylene chloride).


Division 6.1 Packing Group Determinations Designations and Examples:

Packing

Group

Definitions

Examples Oral toxicity

LD50 (mg/kg)

Dermal toxicity

LD50 (mg/kg)

Inhalation toxicity by

dusts and mists LC50

(mg/l)

I < 5.0 < 50 < 0.2

Acetone cyanohydrin

Acrolein

Allylamine

Arsenic trichloride

Barium cyanide

Mercuric potassium cyanide

Nickel carbonyl

Potassium cyanide

Tetraethyl lead

II > 5.0, < 50 > 50, < 200 > 0.2 < 2.0

Aldrin

Aniline

Arsenic bromide

Arsenic trioxide

Beryllium

Bromoacetone

Cacodylic acid

Calcium arsenate

Carbon tetrachloride

Chloroaniline

Chloroform

Copper cyanide

Cresols (o,m,p-)

Dichloropropanol

Dinitrobenzene

Dinitrotoluene

Ferric arsenate

Lead cyanide

Mercuric arsenate

Mercury cyanide

beta-Naphthylamine

Phenol

Silver cyanide

III > 50 < 300

> 200 < 1000 > 2.0 < 4.0

Acrylamide

Ammonium fluoride

Aniline hydrochloride

Antimony

Barium oxide

Bromoform

Carbon tetrabromide

Dichloromethane

Furfuryl alcohol

Lead acetate

Nitrophenol (omp-)


Packing Group Determinations for Division 6.1 Based on Inhalation of Vapors

In order to determine the packing group and hazard zone for liquids which were determined to

meet the definition of division 6.1 based on inhalation of vapors (definition 1.c.ii. above) use

Figure 1 in 49 CFR 173.133.

Example: Methyl Isocyanate

Given Vapor pressure (VP) @ 20°C is 300 mmHg

Total pressure (TP) @ 20°C is 760 mmHg

LC50 for a 4 hour exposure is 5 ml/m3

VP X 106 = V (saturated vapor concentration ml/m3)

TP

Therefore

300 X 106 = 394,737 ml/m3

760

The LC50 data for this definition is based on administering the material by inhalation for 1 hour

in which death occurs in 14 days or less. According to 49 CFR 173.132 (3)(ii) if the LC50 is

based on a 4 hour exposure then multiply that value by two (2) to obtain an equivalent LC50 for 1

hour.

Therefore

LC50 5 ml/m3 x 2 = LC50 10 ml/m3

The next step is to go to Figure 1 in 49 CFR 173.133 and note the location where the LC50 (10

ml/m3) and the volatility (394,737 ml/m3) meet. In this case, Packing Group I, Hazard Zone A.

Packing Group Determination for Mixtures of Division 6.1 Material

The following provisions have been added to §173.132 (c) for the purpose of classifying and

assigning packing groups to mixtures of compounds, which by themselves, meet the definition of

a poison based on dermal or oral toxicity data.

This is only one of two situations that the DOT allows the shipper to "assume a worst case

scenario" in assigning packing group criteria to a hazardous material. It should be noted that

"assuming worst case" under the following guidelines should be your "last resort".

If a mixture contains more than one active constituent reliable accurate acute oral and dermal

toxicity data on the actual mixture should be used to classify the material and assign packing

groups.

If reliable, accurate data on the actual mixture is not available:

classify the formulation according to the most hazardous constituent of the mixture as if the

constituent were present in the same concentration as the total concentration of all active


constituents; or

apply the formula

TM = 100 Where

C = the % concentration of constituent A, B...Z in the mixture

T = the oral LD50 values of constituent A, B...Z

TM = the oral LD50 value of the mixture.

CA + CB + CZ

TA TB TZ

This formula will take into account the additive effect that two toxic materials may present;

however, it will not take into account potentiation, synergism, or antagonism.

Division 6.1 Packing Group I Hazard Zone Determinations

In order to determine the hazard zone for material listed in the 172.101 Hazardous Materials

Table, look up the chemical name and follow across to Column 7 (special provisions). If the first

number in this column is a 1, or 2, the hazard zones are A and B, respectively.

See Appendix 7 for a list of poison inhalation hazards with hazard classes or divisions,

identification numbers, packing groups and hazard zones.

CLASS 6 DIVISION 6.2 INFECTIOUS SUBSTANCE

Definition:

(1) Division 6.2 (Infectious substance) means a material known or reasonably expected to

contain a pathogen. A pathogen is a microorganism (including bacteria, viruses,

rickettsiae, parasites, fungi) or other agent, such as a proteinaceous infectious particle

(prion) that can cause disease in humans or animals. An infectious substance must be

assigned the identification number UN 2814, UN 2900, UN 3373, or UN 3291 as

appropriate, and must be assigned to one of the following categories:

(i) Category A: An infectious substance in a form capable of causing permanent

disability or life-threatening or fatal disease in otherwise healthy humans or

animals when exposure to it occurs. An exposure occurs when an infectious

substance is released outside of its protective packaging, resulting in physical

contact with humans or animals. A Category A infectious substance must be

assigned to identification number UN 2814 or UN 2900, as appropriate.

Assignment to UN 2814 or UN 2900 must be based on the known medical history

or symptoms of the source patient or animal, endemic local conditions, or

professional judgment concerning the individual circumstances of the source

human or animal.

(ii) Category B: An infectious substance that is not in a form generally capable of

causing permanent disability or life-threatening or fatal disease in otherwise

healthy humans or animals when exposure to it occurs. This includes Category B

infectious substances transported for diagnostic or investigational purposes. A

Category B infectious substance must be described as “Biological substance,

Category B” and assigned identification number UN 3373. This does not include


regulated medical waste, which must be assigned identification number UN 3291.

(2) Biological product means a virus, therapeutic serum, toxin, antitoxin, vaccine, blood,

blood component or derivative, allergenic product, or analogous product, or

arsphenamine or derivative of arsphenamine (or any other trivalent arsenic compound)

applicable to the prevention, treatment, or cure of a disease or condition of human beings

or animals. A biological product includes a material subject to regulation under 42 U.S.C.

262 or 21 U.S.C. 151-159. Unless otherwise excepted, a biological product known or

reasonably expected to contain a pathogen that meets the definition of a Category A or B

infectious substance must be assigned the identification number UN 2814, UN 2900, or

UN 3373, as appropriate.

(3) Culture means an infectious substance containing a pathogen that is intentionally

propagated. Culture does not include a human or animal patient specimen as defined in

paragraph (a)(4) of this section.

(4) Patient specimen means human or animal material collected directly from humans or

animals and transported for research, diagnosis, investigational activities, or disease

treatment or prevention. Patient specimen includes excreta, secreta, blood and its

components, tissue and tissue swabs, body parts, and specimens in transport media (e.g.,

transwabs, culture media, and blood culture bottles).

(5) Regulated medical waste or clinical waste or (bio) medical waste means a waste or

reusable material derived from the medical treatment of an animal or human, which

includes diagnosis and immunization, or from biomedical research, which includes the

production and testing of biological products. Regulated medical waste or clinical waste

or (bio) medical waste containing a Category A infectious substance must be classed as

an infectious substance, and assigned to UN2814 or UN2900, as appropriate.

(6) Sharps means any object contaminated with a pathogen or that may become contaminated

with a pathogen through handling or during transportation and also capable of cutting or

penetrating skin or a packaging material. Sharps includes needles, syringes, scalpels,

broken glass, culture slides, culture dishes, broken capillary tubes, broken rigid plastic,

and exposed ends of dental wires.

(7) Toxin means a Division 6.1 material from a plant, animal, or bacterial source. A toxin

containing an infectious substance or a toxin contained in an infectious substance must be

classed as Division 6.2, described as an infectious substance, and assigned to UN 2814 or

UN 2900, as appropriate.

(8) Used health care product means a medical, diagnostic, or research device or piece of

equipment, or a personal care product used by consumers, medical professionals, or

pharmaceutical providers that does not meet the definition of a patient specimen,

biological product, or regulated medical waste, is contaminated with potentially

infectious body fluids or materials, and is not decontaminated or disinfected to remove or

mitigate the infectious hazard prior to transportation.

For exceptions to the definition of Division 6.2 see 49 CFR 173.134(b) and (c)


CLASS 7 RADIOACTIVE MATERIAL

Definition: Any material containing radionuclides where both the activity concentration and the

total activity in the consignment exceed the values for the radioactive isotope specified in the

table in §173.436 or values derived according to the instructions in §173.433. There are two part

to the definition which must be met before the material meets the definition of Class 7. The first

part of the definition is met if the activity concentration is exceeded. The second Part of the

definition is met if the activity/exempt consignment is exceeded. The activity concentration is

measured in Curies (Ci) or Becquerels (Bq) per gram of material. Becquerels is the SI unit of

radioactivity. The activity/consignment is determined by multiplying the specific activity by the

amount of material in the package and comparing to the exempt consignment activity in 49 CFR

173.436.

Radioactive isotopes of concern with Oil and Gas TENORM waste are Radium-226, Radium-

228, Thorium-228, Lead-210, Polonium-210. The activity concentration is 270 picocuries per

gram of material (pCi/gm) for each of these isotopes except for Th-228 which has an exempt

specific activity concentration of 27 pCi/gm. The activity concentration for an exempt

consignment is 270,000 pCi for all isotopes except Ra-228 and Po-210 which is 2,700,000 pCi.

In TENORM waste the presence of a specific radioactive isotope and its activity can only be

determined through laboratory analysis (this analysis is referred NORM Analysis, Radioassay or

Radioactive Chemistry). Radioassay will typically report TENORM specific activity in

picocuries/gm (pCi/gm). One Picocurie is equivalent to 10-12 Ci.

For example, if analysis identifies that the waste contains 8000 pCi/gm Pb-210 (i.e. it exceeds

the exempt activity concentration of 270 pCi/gm) the material meets the first part of the Class 7

definition. The second part of the definition involves multiplying activity concentration 8000

pCi/gm times the number of grams in the package and comparing to the exempt consignment

activity of 270,000 pCi. Another way to look at this is by dividing the exempt consignment

activity by the specific activity obtained from lab analysis (270,000 ÷ 8,000 = 32 grams of

material).

Examples: TENORM/NORM, Thorium nitrate, Uranyl acetate

CLASS 8 CORROSIVE MATERIAL

Definition: The definition for Class 8 material is a liquid or solid that causes full thickness

destruction of human skin at the site of contact within a specified period of time.

Packing Group Assignments and Examples:

Packing

Group Material that cause full thickness destruction of

intact skin tissue within an observation period of

up to:

Examples

I 60 minutes starting after the exposure

time of three minutes or less.

Chlorosulfonic acid

Hydrofluoric acid >60%

Fuming sulfuric acid


II 14 days starting after the exposure time

of more than three minutes but not more

than 60 minutes."

Acetic acid

Acetic anhydride

Acetyl bromide

Acrylic acid

Aluminum bromide

Antimony trichloride

Benzoyl chloride

Chloroacetic acid

Chromic acid

Butyl amine

Formic acid

Hydrazine

Hydrochloric acid

Hydrofluoric acid

Lithium hydroxide

Potassium bifluoride

Potassium hydroxide

Sulfuric acid

III 14 days starting after the exposure time

of more than 60 minutes but not more

than 4 hours; or

That do not cause full thickness

destruction of intact skin tissue but

exhibit a corrosion rate on steel or

aluminum surfaces exceeding 6.25 mm

(0.25 inch) a year at 131°F.

Aluminum bromide

Aluminum chloride

Butyric acid

Calcium oxide

Caproic acid

Chloropropionic acid

Copper chloride

Ferric chloride

Mercury


COMBUSTIBLE LIQUID

Definition: A combustible liquid is any liquid with a flash point between 141 and 200°F and

does not meet the definition of any other hazard class other than Class 9.

§173.120 (b)

Packing Group Designations:

Combustible liquids will be assigned to packing group III.

CLASS 9 MISCELLANEOUS HAZARDOUS MATERIAL

Definition: Is a material which has an anesthetic, noxious or other similar property which could

cause extreme annoyance or discomfort to a flight crew member so as to prevent the correct

performance of assigned duties and does not meet the definition of any other hazard class or

division; or

It is a material which meets the definition of a hazardous substance, hazardous waste or a Marine

Pollutant and does not meet the definition of any other hazard class or division. §173.140

Packing group assignment for class 9 material will be determined by the hazardous materials

table.

ORM-D

Definition: Any material such as a consumer commodity which although otherwise subject to

the hazardous materials regulations, presents a limited hazard during transportation due to its

form quantity and packaging. §173.144


HAZARD CLASS OR DIVISION PRECEDENCE

If the material is not specifically listed in the 172.101 table and meets the definition of more than

one hazard class, use the following hierarchy or Precedence Table to determine which hazard

class takes precedence. §173.2a

Class 1 (explosives), division 5.2 (organic peroxides), 6.2 infectious substances and division 4.1

(wetted explosives) are not part of the hierarchy list due to their unique properties. §173.2a(c).

If the hazardous material meets the definition of one of these hazard classes or divisions, then

that class or division takes precedence.

Hierarchy Class/Div. Description

1. 7 Radioactive Material

2. 2.3 Poisonous gases

3. 2.1 Flammable gas

4. 2.2 Nonflammable gas

5. 6.1 Poison inhalation hazard, liquids (PG I)

6. 4.2 Pyrophoric material

7. 4.1 Self reactive material

8. The Precedence of Hazard Table, shown on the following page, must be used for any

material meeting the Hazard Class or Division definitions of more than one of the

following "Hierarchy 8" materials:

3 Flammable liquids,

8 Corrosive materials,

4.1 Flammable solids,

4.2 Spontaneously combustible materials,

4.3 Dangerous when wet,

5.1 Oxidizers,

6.1 Poisonous liquids and solids,

9. Combustible liquids

10. 9 Miscellaneous hazardous materials

If the primary Hazard Class or Division is not determined properly, the shipping description,

labeling, marking, and possibly packaging and placarding will also be wrong.


PRECEDENCE OF HAZARD TABLE §173.2(b)

4.2 4.3 5.1

I 5.1

II 5.1

III 6.1

I,D 6.1

I,O 6.1

II 6.1

III 8,I

liq 8,I

sol 8,II

liq 8,II

sol 8,III

liq 8,III

sol

3,I ♠ 4.3 3 3 3 3 3 ♣ 3 ♣ 3 ♣

3,II ♠ 4.3 3 3 3 3 8 ♣ 3 ♣ 3 ♣

3,III ♠ 4.3 6.1 6.1 6.1 3♦ 8 ♣ 8 ♣ 3 ♣

4.1,II ♠ 4.2 4.3 5.1 4.1 4.1 6.1 6.1 4.1 4.1 ♣ 8 ♣ 4.1 ♣ 4.1

4.1,III ♠ 4.2 4.3 5.1 4.1 4.1 6.1 6.1 6.1 4.1 ♣ 8 ♣ 8 ♣ 4.1

4.2,II 4.3 5.1 4.2 4.2 6.1 6.1 4.2 4.2 8 8 4.2 4.2 4.2 4.2

4.2,III 4.3 5.1 5.1 4.2 6.1 6.1 6.1 4.2 8 8 8 8 4.2 4.2

4.3,I 5.1 4.3 4.3 6.1 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3

4.3,II 5.1 4.3 4.3 6.1 4.3 4.3 4.3 8 8 4.3 4.3 4.3 4.3

4.3,III 5.1 5.1 4.3 6.1 6.1 6.1 4.3 8 8 8 8 4.3 4.3

5.1,I 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1

5.1,II 6.1 5.1 5.1 5.1 8 8 5.1 5.1 5.1 5.1

5.1,III 6.1 6.1 6.1 5.1 8 8 8 8 5.1 5.1

6.1,I, Dermal 8 6.1 6.1 6.1 6.1 6.1

6.1,I Oral 8 6.1 6.1 6.1 6.1 6.1

6.1,II, Inhal 8 6.1 6.1 6.1 6.1 6.1

6.1,II, Dermal 8 6.1 8 6.1 6.1 6.1

6.1,II, Oral 8 8 8 6.1 6.1 6.1

6.1,III 8 8 8 8 8 8

KEY

♠ Materials of Division 4.1 other than self-reactive substances and solid desensitized explosives, and materials of Class 3 other

than liquid desensitized explosives.

♣ Denotes an impossible combination.

♦ Division 6.1 takes precedence for pesticides only.

D Dermal

O Oral

I Packing group I, II and III respectively.

Note 1: The most stringent packing group assigned to a hazard of the material takes precedence over other packing groups; for

example, a material meeting Class 3 PGII and Division 6.1 PGI (oral toxicity) is classified as Class 3 PG1.

Note 2: A material which meets the definition of Class 8 and has an inhalation toxicity by dusts and mists which meets the

criteria for packing group I specified in §173.133(a)(1) must be classed as Division 6.1 if the oral or dermal toxicity

meets criteria for Packing group I or II, If the oral or dermal toxicity meets the criteria for Packing Group III or less,

the material must be classified as Class 8.


HAZARD PRECEDENCE EXAMPLES

1. The primary hazard class for a liquid meeting the definition of a Class 8 PGII and a Class

3 PGII would be 3.

2. The primary hazard class for a liquid with a flash point of 80°F, and a boiling point

105°F (Class 3 PG III) that also had an oral toxicity LD50 of 49 mg/kg (Division 6.1 PG

II) would be 6.1.

3. The same procedure would be used to determine the primary hazard class for a hazardous

material that met the definition of three hazard classes or divisions under "hierarchy 8".

The following table may assist in ranking the hazard classes or divisions when the

hazardous material meets the definition of three hazard classes or divisions.

If a liquid met the definition of: Division 6.1, PGII (based on oral toxicity data); 8, PG II; and 3,

PG II; the primary hazard class would be 3. Division 6.1 and Class 8 would be subsidiary

hazards.

Classification + Classification

Different Order

= Primary Hazard (Whichever hazard class or division shows up twice

that’s the primary hazard)

6.1, PGII + 8, PGII = 8

8, PGII + 3, PGII = 3

3, PGII + 6.1, PG II = 3

DOT HAZARDOUS MATERIALS CLASSIFICATION GENERAL RULES

1. First reference the hazardous material in the Hazardous Materials Table (HMT) (Appendix 2)

you r work may be done for you.

2. If the material is a diluted mixture or solution make sure it presents the same hazards as the

listing in the HMT. “One drop of Hydrochloric acid in a billion gallons of water is water, not

a Class 8).

3. If the material is not listed in the HMT, research the chemical properties and determine if the

material meets the definition of one or more of the 21 different hazard classes or divisions.

4. If the material meets the definition of more than one hazard class, use the hierarchy list and

precedence of hazard table to determine what the primary hazard is.

5. If the material is a waste and was classified as a hazardous waste, it will also be regulated as

a hazardous material. Remember, the definitions for hazard class 9 was a hazardous waste

that does not meet the definition of any other hazard class is class 9. A HAZARDOUS

WASTE IS ALWAYS A HAZARDOUS MATERIAL unless the hazardous waste is not

required to be manifested by the EPA and it does not meet the definition of Classes 1 through

8.


DOT SHIPPING DESCRIPTION PREPARATION

THE HAZARDOUS MATERIALS TABLE

After the Hazardous Waste, Substance and Materials classifications have been completed, the

next step is to bring the three classifications together and prepare a shipping description. The

parts of the shipping description will be obtained with the use of the HMT. This section will

describe the information found in each column of the table.

COLUMN 1 – Symbols Column contains five symbols (+, A, D, I, W)

+ The plus (+) sign fixes the proper shipping name, hazard class and packing group for that

entry without regard to whether the material meets the definition of that class, packing

group or any other hazard class definition. When the plus sign is assigned to a proper

shipping name in Column (1) of the § 172.101 Table, it means that the material is known

to pose a risk to humans. When a plus sign is assigned to mixtures or solutions containing

a material where the hazard to humans is significantly different from that of the pure

material or where no hazard to humans is posed, the material may be described using an

alternative shipping name that represents the hazards posed by the material.

A The letter ‘‘A’’ denotes a material that regulated when shipped by aircraft, unless the

material is a hazardous substance or a hazardous waste in which case it is regulated by all

modes of transportation.

W The letter ‘‘W’’ denotes a material that is regulated when shipped by vessel, unless the

material is a hazardous substance or a hazardous waste in which case it is regulated by all

modes of transportation.

D The letter “D” identifies proper shipping names which are appropriate for describing

materials for domestic transportation.

I The letter “I” identifies proper shipping names which are appropriate for describing

materials in international transportation as well as domestic transportation.

G The letter “G” identifies proper shipping names for which one or more technical names

must be entered in parentheses, in association with the basic description.

COLUMN 2 – This column identifies the proper shipping name in roman type. As will be

discussed later, the shipping name must appear on shipping papers and package markings just as

shown in the table unless specifically authorized to be modified.

COLUMN 3 – This column identifies the primary hazard class or division. If the material meets

the definition of more than one hazard class, subsidiary hazards will be shown in column 6. If

the entry is “Forbidden” it may not be transported.

COLUMN 4 – Shows the identification number. UN stands for United Nations and identifies

shipping names appropriate for international shipments. NA stands for North America identifies

proper shipping names for domestically and to and from Canada.


COLUMN 5 – This column lists the packing group. Class 2, 7, Division 6.2 and ORM-D do

not have packing group designations. PACKING GROUPS I, II, AND III INDICATE

THE DEGREE OF DANGER PRESENTED BY THE MATERIAL IN THAT

HAZARD CLASS (GREAT, MEDUIM AND MINOR RESPECTIVELY). Hazardous

substances with a shipping name preceded by an “A” or a “W” in the symbols column will be

assigned to packing group III. The correct hazard communication information and packaging

is determined by selecting the proper Hazard Class or Division and packing group. §172.101

(f).

COLUMN 6 – Lists the labels which are required to be placed on the package. The fist label

listed represents the primary hazard and the second label listed represents the subsidiary

hazard. §172.101(g) NOTE: ADDITIONAL LABELING MAY ALSO BE REQUIRED.

COLUMN 7 – specifies provisions applicable to hazardous materials. Special provisions are

located in §172.102 (see Appendix 6). The numerical codes apply to all nodes of

transportation, where the alpha numeric codes generally apply as follows:

A Air transportation only

B Bulk packagings

H Highway transportation only

IB Intermediate Bulk Container

IP Intermediate Bulk Packaging

N Non bulk packaging only

R Rail Only

T IM portable tanks only

W Water transportation only

For example: the shipping name “bromine” has 16 special provisions. If a 1-pint bottle of

bromine was to be shipped by highway, the only applicable provisions that must be referenced

are 1, N34 and N43:

1 “This material is poisonous by inhalation, meets the criteria in 173.133(a) (2) of

this subchapter for division 2.3, Hazard Zone A or division 6.1 PG I Hazard Zone

A and must be described as an inhalation hazard under the provisions of this

subchapter.”

N34 “Aluminum construction materials are not authorized for any part of a packaging

which is normally in contact with the hazardous material.”

N43 “Metal drums are permitted as single packaging only of nickel or monel.”

COLUMN 8 – Identifies the regulatory site (regulations included in Appendix 5) for

authorized packaging of the material identified in Column 2. The regulatory site will be 49

CFR 173.***, where *** identifies the specific section of the regulations that describe

required packaging. This column is broken into three sub columns as follows: 8A identifies

the regulatory site for exceptions to authorized packaging; 8B identifies the regulatory site for

non-bulk packaging (e.g., <119 gallons) and 8C identifies the regulatory site for bulk

packaging (e.g., > 119 gallons).


COLUMN 9 – Refers to quantity limitations for transportation by passenger or cargo aircraft.

The word forbidden in column 9A means that the material may not be shipped by passenger

aircraft or rail. If the word forbidden also appears in Column 9 B the material may not be

shipped by cargo aircraft. If the word forbidden appears in 9A but a quantity limit appears in

9B then the material may be shipped by cargo aircraft only. See page T-84 (Item 7) of this

text for an additional labels that must be affixed to the package. To ship any hazardous

material by air, you must also comply with: the “general requirement for transportation by

aircraft” at 49 CFR §173.27; the International Air Transport Association (IATA) Dangerous

Goods Regulations and specific requirements of the carrier such as UPS and Federal Express.

COLUMN 10 - Refers to the storage requirements aboard vessels.

THE PROPER SHIPPING DESCRIPTION

Now that we have covered the hazardous materials table we can begin to prepare the proper

shipping description.

The proper shipping description consists of six (7) distinct parts. Items 1 through 5 must

appear in the following order with nothing interspersed other than technical names authorized

to be placed within parenthesis between the shipping name and the hazard class/division.

§172.202(b) and (d).

1. Identification Number

2. Proper Shipping Name

3. Hazard Class or Division Number

4. Subsidiary Hazard Class or Division

5. Packing Group shown in Roman Numerals (May be preceded by the letter PG)

6. Additional Descriptors

7. Volume (quantity and units, number of container and container type)

THE PROPER SHIPPING NAME

A proper shipping description begins by choosing the correct shipping name. If the wrong

shipping name is chosen, the entire shipping description will be wrong. The basic rule in

choosing the correct shipping name is to choose the most descriptive shipping name without

providing misleading information. Choosing the most descriptive shipping name will enable

hazardous materials responders to react properly to an incident.

Use the following order to choose the proper shipping name.

1. Pure or Technically Pure Chemicals

If the chemical for which the shipping description is being prepared is technically pure or

a commercial grade and that chemical is listed in column2, then that is the proper shipping

name.

Example: The proper shipping name for Hexane would be “Hexane”.

• Isomers


As long as an isomer is not specifically listed in the HMT, the listed shipping name in

column 2 of the hazardous materials table can be used for all isomers of the listed

shipping name that have the same primary hazard class, subsidiary hazard class, and

packing group. §172.101(c)(14)

Example 1: When to Use

p-Dibromobenzene, o-Dibromobenzene and m-Dibrombenzene could all be

shipped under the shipping name Dibromobenzene.

Example2: When Not to Use

p-Dichlorobenzene could not be shipped under the shipping name o-

Dichlorobenzene since o-Dichlorobenzene is a specific isomer listed in the

HMT.

Hydrates

As long as a hydrate is not specifically listed in the HMT, the listed shipping name of an

anhydrous material in column 2 of the HMT can be used for hydrates of the anhydrous

material that have the same primary hazard class, subsidiary hazard class, and packing

group. §172.101(c)(15)

2. Mixtures or Solutions

If the chemical for which the shipping description is being prepared is a combination of a

chemical identified in column 2 and one or more non-hazardous chemicals then the chemical

name in column 2 followed by the word mixture or solution is the correct choice

(172.101(c)(10). If this option is used the following conditions apply:

a. The packaging specified in column 8 is appropriate for the physical state (package

approved for solids and not liquids) of the material.

If the material is a liquid but the authorized packaging applies to solids under

§§173.211,212,213,240 or 242, then you may use the alternate authorized packagings

for liquids under §§173.201,202,203,241 or 243 respectively §172.101(I)(4).

b. The shipping description does not indicate that the proper shipping name applies

to only pure or technically pure material.

c. The material meets the definition of the primary and subsidiary hazards and the

packing group.

d. There is not a significant change in the emergency response measures to be taken.

e. The material continues to meet the definition of a poison inhalation hazard if it

was identified as a poison inhalation hazard in column 7 of the hazardous material

table.


f. The material can be more appropriately described under a generic intended

application name such as “Coating Solution”, “Extracts Flavoring”, “Compound

cleaning liquid”.

Example: A mixture of hexane lubrication oil and water with a flash point <73°F and

a boiling point >95°F would have the proper shipping name “Waste

hexane mixture”.

Do not use the “mixture or solution” description if the mixture or solution contains more

than one hazardous material or if the mixture does not meet the criteria (a through e)

above.

Example: If would be incorrect to identify a solution of ethanol and water that was

so dilute that it exhibited a flash point of 180°F as “Waste ethanol

solution, 3, UN1170, PGII”.

Example: It would also be incorrect to describe a corrosive solution of hydrochloric

acid and hexane if it exhibited a flash point of 73°F and a boiling point

>95°F as only “Waste hydrochloric acid, 8, (3), UN1789, PHII” because

the flammability hazard would not have been disclosed in the shipping

name entry. A more descriptive shipping name could be chosen in each

case (see number 7 below).

5. Chemical Usage Name

If the technical name is not identified in column 2 but the shipping name which describes the

intended application is, then that is the correct choice. §172.101(c) (10)(I)(F)

Example: Coating Solution, or Compound Cleaning Liquid

6. Generic Descriptions

If the chemical name is not identified in column 2 or it consists of more than one hazardous

material and can best be described by a generic chemical name then that is the correct choice.

§172.101 (c)(12)(ii)

Example: An alcohol not specifically listed in column 2 would be best described as

“Waste Alcohols, n.o.s.”

7. Multiple Hazardous Materials

If the material is not identified by chemical name, usage name or generic chemical name in

column 2 and/or meets the definition of one or more than one hazard class then a generic

shipping name corresponding to the primary and subsidiary hazard class or divisions is the

correct choice. §172.102 (c) (12) (iii)

Example: The solution of hydrochloric acid and hexane described above would have the

proper shipping name “Waste flammable liquid, corrosive, n.o.s., 3, UN2924,

PGII” (Assuming that the material causes full thickness destruction of intact


skin tissue within an observation period of up to 14 days starting after the

exposure time of more than three minutes but not more than 60 minutes, has a

flash point between 73°F and 141°F and a boiling point>95°F).

When using generic shipping names you may also have to select a shipping name with the

words, “organic”, “inorganic”, “acid”, “base”, (i.e., Corrosive liquid, acidic, inorganic, n.o.s.)

These terms have the following meaning:

• Organic “a compound with carbon atoms bonded to other carbon, nitrogen or

hydrogen atoms”

• Inorganic “any pure element or any compound that does not have carbon atoms

bonded to other carbon nitrogen of hydrogen atoms.”

• Acid A substance which meets the definition of a corrosive material and for

aqueous solutions a substance which reveals a pH at the lower end of the

pH scale.

• Base A substance which meets the definition of a corrosive material and for

aqueous solutions a substance which reveals a pH at the upper end of the

pH scale.

Authorized Modifications of the Shipping Name

Only shipping names that are identified in column 2 may be used. The shipping name must

appear just like it is shown in column 2 with the following exceptions. §172.101 (c).

1. Either the singular or plural, lower case or capital letters may be used. §172.101(c)(1).

2. Punctuation marks and words in italics are not part of the shipping name and can be

omitted on shipping papers and container markings. §172.101(c)(1).

3. When the word “or” in italics is used between two names in Roman type either shipping

name may be used. §172.101 (c) (2).

Example: The Column 2 the entry Bromotrifluoromethane or Refrigerant gas, R13B1

would be entered on the shipping paper as:

Bromotrifluoromethane, 2.2, UN1009 or

Refrigerant gas, R13B1, 2.1, UN1009; but not as

Bromotrifluoromethane or Refrigerant gas, R13B1, 2.2, UN1009

4. The word poison or poisonous may be used interchangeably with the word toxic for

domestic transportation. §172.101(c)(3)

5. The abbreviation "n.o.i" which means "not otherwise indexed" or "n.o.i.b.n." which means

"not otherwise indexed by name" may be used interchangeably with "n.o.s." which means

"not otherwise specified". §172.101 (c) (3)


6. When one entry references another entry by the use of the word "see", either entry may be

used as the proper shipping name as long as both entries are in Roman type. §172.101 (c) (5)

Example: For the "Carbolic acid see Phenol, solid or Phenol, molten entry, the

shipping name Carbolic acid could not be used because it is in italics.

Example: For the Ethyl alcohol see Ethanol entry either shipping name could be

used.

7. When the shipping name includes a concentration range the actual concentration may be used

if it falls within the range specified. §172.101 (c) (6)

8. The prefix "mono" is optional. §172.101 (c) (7)

9. The word "liquid" or "solid" may be added to a proper shipping name when a hazardous

material specifically listed by name may, due to differing physical states, be a liquid or solid.

When the packaging specified in Column 8 is inappropriate for the physical state of the

material, the following table should be used to determine the appropriate packaging section.

§172.101(c)(8) and §172.101(I)(4).

10. The word "waste" must always precede the shipping name for shipments of hazardous waste

(as defined by RCRA) unless the word waste is already part of the proper shipping name

(§172.101 (c)(9)). The word waste must not precede the shipping name if it does not meet

the definition of a hazardous waste. The easiest way to remember when to add the word

waste is: “if you assigned a RCRA waste code (e.g., D001, F001, and U001), then add the

word waste to the beginning of the shipping name”.

Example: (1) Waste phenol, (2) Hazardous waste, solid, n.o.s.

HAZARD CLASS AND IDENTIFICATION NUMBERS

Once the proper shipping name and technical names have been determined, the next step is to

add the primary hazard class the packing group and identification numbers. If the proper

shipping name was chosen, this step is easy. The hazard class or division will appear in Column

3, the identification number in column 4 and the packing group in Column 5 directly to the right

of the proper shipping name in Column 2.


ADDITIONAL DESCRIPTORS

Additional descriptors are an integral part of the shipping description. There are eight additional

descriptors that we will cover in this course.

1. Special Permit Notations

Each shipping description associated with a Special Permit must bear the notation "DOT-

SP" followed by the special permit number assigned. This notation must clearly identify

which shipping description on the manifest it represents. To this end, the exemption

notation may appear in section 14 of the Uniform Hazardous Waste Manifest with a

reference to the line (9b#) with which it is associated; or, the exemption notation may be

placed at the end of each shipping description it applies to. §172.203 (a)

Each shipping paper issued in connection with a shipment made under an exemption or

special permit issued prior to October 1, 2007, may bear the notation "DOT-E" followed

by the number assigned.

2. Limited quantities

The description for a material offered for transportation as "limited quantity, must include

the words "Limited Quantity'' or "Ltd Qty'' following the basic description. §172.203(b).

See page 64 of this text for a discussion on how to ship material as a “Limited Quantity.

3. Empty Packaging Notations

The proper shipping description for empty containers which once held a hazardous

material may include the words "Residue: Last Contained" at the end of the shipping

description. §172.203 (e)

4. Technical Names

Technical names are those names that are commonly used in technical and scientific

texts, journals, and handbooks. §172.203 (k)

Technical names are required for:

Hazardous Substances

N.O.S. and other Generic Descriptions

Marine Pollutants, and

The same technical name need not be repeated (i.e., once for generic descriptions and

again because it is a hazardous substance).

When a technical name is required, it must appear in parenthesis after the shipping name

or at the end of the basic description. Although the hazardous materials regulations allow

the technical name to be added after the shipping name or at the end of the basic

description, when shipping by air the technical name may only be placed after the

shipping name. For this reason it is recommended that the technical name for generic


descriptions always be placed after the shipping name.

Technical Names must be added to shipping descriptions for each shipping name

preceded by the letter "G" in the symbols column of the Hazardous Materials Table.

If a waste contains only one hazardous material, and the technical name is not part of the

shipping name, then only list one technical name.

If the waste contains more than one hazardous material, then list at least two technical

names which represent the predominant hazards:

Example: UN2924, Waste flammable liquids, corrosive, n.o.s.

(Hexane, Hydrochloric Acid),

3 (8), PGII

In this example, since the hazardous material represents two different hazards

(flammability and corrosivity), identify the technical name most predominantly causing

each hazard (i.e., one chemical name for class 3 and another for class 8). Although DOT

does not express this requirement clearly in the regulations, it is a requirement of the UN

Recommendations from which DOT establishes the Hazardous Material Regulations.

The technical name rule for generic descriptions does not apply to:

a. Lab Packs; (Note: shipping descriptions for lab packs must still include technical

names for hazardous substances as described above) §173.12 (d)

b. Hazardous substances properly described as "Environmentally hazardous

substances liquid or solid, n.o.s. with the general hazard class 9 provided the

material is described as required for hazardous substances as discussed previously

or at 49 CFR 172.203 (c). §172.203 (k) (4) (I)

or,

Hazardous wastes properly described as "Hazardous waste liquid or, solid, n.o.s.

with the general hazard class 9, provided the EPA hazardous waste number (D-

code) or waste stream number (F-code or K-code) in association with the basic

description.

Example: RQ NA3077, Hazardous waste solid, n.o.s., 9, PGIII, (D008).

c. Samples shipped for analysis in order to determine the hazard class.

§172.203(k)(4)(ii)

d. Chemical element or chemical group n.o.s. descriptions when the chemical

element or group is primarily responsible for the material meeting the hazard class

or division. For example, if the shipping name "Cyanides, inorganic, n.o.s." was

used you would not have to include the specific technical names for the inorganic

cyanides in the container. §172.203(k)(4)(iii)


5. Hazardous Substances and Reportable Quantities (RQ)

If the material meets the definition of a hazardous substance then the letters "RQ" must

precede the shipping name or follow the basic description as shown below. If the

technical name of the hazardous substance does not appear as part of the shipping name,

the technical name or EPA code identifying the hazardous substance must appear in

parenthesis after the shipping name or basic description as shown below. §172.203(c)

The shipper must identify at least two hazardous substances, if the hazardous material is

composed of two or more hazardous substances. If the hazardous material is composed

of more than two hazardous substances, the two hazardous substances with the lowest

reportable quantities must be identified. Federal Register Volume 61, Number 105,

Thursday, May 30, 1996, page 27167.

The hazardous substance notation can be disclosed in the shipping description in two

ways:

a. RQ <Identification Number>, <Shipping Name>, <Hazardous Substance

Technical Name(s)>, <Hazard Class>, <Packing Group> or

b. <Identification Number>, <Shipping Name>, <Hazard Class>, <Packing Group>

RQ <Hazardous Substance Technical Names or EPA Code>

6. Marine Pollutants

A marine pollutant is defined as "A hazardous material which is listed in Appendix B to

the 172.101 Hazardous Material Table (See Appendix 4) and when in a mixture or

solution of one or more marine pollutants equals or exceeds the following concentrations:

a. One percent by weight for severe marine pollutants or

b. Ten percent by weight for other marine pollutants.

Except for motor vehicle transportation of non-bulk packagings, if the proper shipping

name does not identify the component which makes it a marine pollutant, then the name

of the component which makes the material a marine pollutant must be added after the

shipping name in parenthesis. If there is more than 1 marine pollutant in the waste, then

identify at least two marine pollutants in greatest quantity or that present the greatest

hazard.

If the material meets the definition of a marine pollutant then the words "Marine

Pollutant" must be added at the end of the shipping description. §172.203(l)

7. Poison-Inhalation Hazards

If the outer drum holds any quantity of a material meeting the definition of a poison-

inhalation hazard, the words "Toxic Inhalation Hazard" and "Zone A, B, C or D" for gasses

or "Zone A or B" for liquids must be added after the basic description. To determine if the

material is a PIH, look up the shipping name in column 2 of the hazardous materials table


(Tab 2) and follow across to column 7. The numbers 1, 2, 3 and 4 appearing in column 7,

mean the material is a poison inhalation hazard in Zones A, B, C and D respectively. Special

provisions 5, 6 and 13 also refer to poison inhalation hazard requirements. Chemicals that

are identified as Poison Inhalation Hazard are also summarized in Appendix 7. Note: the

technical name for the poison-inhalation hazard must also be added to the basic description in

parenthesis if the letter “G” appears in the symbols column of the HMT. §172.203 (m) (3)

8. Organic Peroxides and Self Reactive Material

In addition to the technical name requirements for these hazardous materials (i.e., shipping

names for these hazardous materials are preceded by the letter "G" in column 1 of the

Hazardous materials table), you must also include the following information.

Control and Emergency Temperatures

The control temperature and emergency temperatures must be included on the shipping paper

for any Division 5.2 (organic peroxide) or 4.1 (self reactive) which is required to be shipped

under controlled temperature.

Concentration or Concentration Range

When §§173.224 and 173.225 identify a self reactive material or organic peroxide with more

than one concentration, the appropriate concentration range or specific concentration must be

included next to the technical name for the self reactive material or organic peroxide. (49

CFR 173)

Competent Authority and Samples

See §172.203(o) for uncommon additional description requirements (i.e., competent

authority approval statement and the word sample) for self-reactive material and organic

peroxides.

9. Samples

Although addition of the word “sample” is a required “modification of the shipping name”

and not “an additional descriptor as found in §172.230) it would be applied like an

additional descriptor, and has been included in this section of this manual for that reason.

The word “Sample” must be added to the end of the shipping name or basic description for

samples shipped in accordance with 49 CFR 172.101(c)(11).

There are more additional descriptor requirements for: radioactive material, transportation by

air, transportation by rail, transportation of cargo tanks by highway, transportation by water,

and transportation of elevated temperature material; which can be referenced at §173.203 (d),

(f), (g), (h), (I), and (n) respectively.


EXAMPLE FOR FUN

If a 55-gallon drum of unused waste (500 pounds) contained the following mixture:

1. Acetone ............................................................................................................................... 50% (250 pounds)

2. Sodium cyanide ....................................................................................................................... 5% (25 pounds)

3. Sodium hydroxide ............................................................................................................... 40% (200 pounds)

4. Lead oxide ............................................................................................................................... 5% (25 pounds)

And exhibits or is believed (based on knowledge of the waste) to exhibit the following characteristics:

1. Flash point = 70°F, Boiling point = 105°F

2. Believed to exhibit an oral LD50 of 4 mg/kg

3. Believed to exhibit virtually the same corrosive properties as Sodium hydroxide alone

4. TCLP analysis for lead = 15 mg/l

5. Analysis of reactive cyanides = 1000 ppm

HAZARDOUS WASTE CLASSIFICATION

The waste would be classified as:

1. D001 (Flash point < 140°F)

2. D002 (pH > 12.5)

3. D003 (Reactive cyanides > 250 ppm)

4. D008 (TCLP for lead > 5 mg/l)

Note: F and K codes would not apply since the material is unused and U and P codes do not apply because

no one constituent is the sole active ingredient.

HAZARDOUS SUBSTANCE DETERMINATION

The reportable quantities for each constituent would be:

Constituent Weight of

Entire

Waste

Weight of

Each

Constituent

RQ for Each

Constituent DOT Hazardous Substance

(Y or N)

Does Column 3 equal or

exceed column 4?

Quantity required to be

released for CERCLA

reporting

((Column 2÷3) x Column 4)

1 2 3 4 5 6

Acetone 500 250 5000 No 10,000

Sodium cyanide 500 25 10 Yes 200

Sodium hydroxide 500 200 1000 No 2,500

Lead Oxide 500 25 Not listed N/A N/A

In this case reporting under CERCLA would be required when 200 pounds of the material were released to the

environment which equates to releasing 10 pounds of Sodium cyanide. Since the container holds more than 10

pounds of Sodium cyanide (25 pounds are in the container) Sodium cyanide must be identified as a hazardous

substance on the shipping paper and as will be discussed later must be marked on the drum. Remember you must

also consider the reportable quantities associated with EPA waste codes.


The reportable quantity for hazardous characteristics would be:

Characteristic RQ Is this characteristic caused

by only listed hazardous

substances?

Weight of

Characteristic in

Container

Hazardous Substance?

(Yes or No)

(If the answer in column 3

is "No" does column 4

exceed column 2?

1 2 3 4 5

D001 100 Yes (Acetone)

500

N/A

D002 100 Yes (Sodium hydroxide) N/A

D003 100 Yes (Sodium cyanide) N/A

D008 10 No (Lead oxide) Yes

With this information, reporting under CERCLA would be required when 10 pounds of the material is released to

the environment. Note that the reporting threshold for D008 in this waste is much lower than that required for the

Sodium cyanide component. Since the container holds more than 1 pound of D008 material (i.e., drum of waste

contains 500 pounds of D008 waste) the code D008 must be identified as hazardous substance on the shipping

paper. In addition, as will be discussed later, the letters RQ and D008 must also be marked on the container.

Therefore the hazardous substances in this container would be:

1. Sodium cyanide

2. D008

HAZARDOUS MATERIALS DETERMINATION

The waste would meet the hazard class or divisions:

1. 3, Packing Group II (Flash point < 73°F and boiling point > 95°F)

2. 8, Packing Group II (Waste believed to have the same corrosive properties as Sodium hydroxide)

3. 6.1, Packing Group I (Oral LD50 5 mg/kg)

The order of precedence would be:

Primary: 3

Subsidiary: 6.1 and 8

Therefore the proper shipping description would be:

RQ UN1992, waste flammable liquid, toxic, corrosive n.o.s.

(Acetone, Sodium cyanide, Sodium hydroxide)

3, (6.1, 8), PGI, (D008).

or

UN1992, Waste flammable liquid, toxic, corrosive n.o.s.

(Acetone, Sodium hydroxide)

3, (6.1, 8), PGI, RQ (D008, Sodium Cyanide).


PACKAGING

INTRODUCTION

Prior to the adoption of the HM-181 regulations, packagings had to be constructed to detailed

specifications; however, HM-181 regulations incorporate performance oriented packaging

standards or "POPs". This means that packagings must perform to certain minimum standards

without failing. Packagings may be subject to drop, leakproofness, hydrostatic pressure,

stacking, and vibration tests among others. Packagings intended to contain PGI materials must

pass more strenuous tests than either PGII or PGIII material. For example in the drop test, a

package rated to hold PGI material must be dropped from a height of 5.9 feet while drums rated

for PGII and PGIII material are required to be dropped from a height of 3.9 and 2.6 feet

respectively.

While it is not normally the responsibility of the shipper to ensure that the appropriate tests have

been performed on the packaging, it is the responsibility of the shipper to select a package that is

authorized for the hazardous material to be placed therein.

It is also the responsibility of the shipper to perform all functions necessary to bring the package

into compliance with 40 CFR parts 173 and 178, as identified by the packaging manufacturer or

subsequent distributor. Your package distributor should provide you with instructions on how to

properly close their packaging (e.g., the required amount of torque for a bung closure). The

shipper must follow these instructions. It is recommended that the shipper keep a copy of these

instructions on file for reference and in case an inspector requests to see them.

This section will cover the following topics:

Definitions

Packaging Selection,

Lab Pack Exceptions,

Salvage Drum Exception,

Overpack Exception and

Reuse of Packagings.

DEFINITIONS

Non-bulk Packaging - Has an internal volume of ≤ 119 gallons.

Intermediate Bulk Container (IBC) - means a rigid or flexible portable packaging, other than a

cylinder or portable tank, which is designed for mechanical handling.

Bulk Packaging - > 119 Gallons


Large Packaging - “ a packaging that (1) Consists of an outer packaging that contains articles

or inner packagings; (2) Is designated for mechanical handling; (3) Exceeds 400 kg net mass or

450 liters (118.9 gallons) capacity; (4) Has a volume of not more than 3 cubic meters (m3)

(see § 178.801(i) of this subchapter); and (5) Conforms to the requirements as specified in §

173.36, and subparts P and Q of part 178 of this subchapter, as applicable.”

Consumer Commodity - "a material that is packaged and distributed in a form intended or

suitable for sale through retail sales agencies or instrumentalities for consumption by individuals

for purposes of personal care or household use. This term also includes drugs and medicine.

Combination Packaging - One or more inner packagings secured in a non-bulk outer packaging.

Single Packaging - A non-bulk packaging other than a combination packaging.

Composite Packaging - Consists of an outer package and an inner receptacle so that the outer

package and inner receptacle form an integral packaging (e.g., Fiber drum with poly liner).

Overpack - A closure used to provide protection or convenience in handling a package or to

consolidate two or more packages.

Salvage Packaging - "a special packaging conforming to §173.3 of this subchapter into which

damaged defective or leaking hazardous materials packages, or hazardous materials that have

spilled or leaked, are placed for purposes of transport for recovery or disposal."

Strong outer packaging - “ the outermost enclosure that provides protection against the

unintentional release of its contents. It is a packaging that is sturdy, durable, and constructed so

that it will retain its contents under normal conditions of transportation. In addition, a strong

outer packaging must meet the general packaging requirements of subpart B of part 173 of this

subchapter but need not comply with the specification packaging requirements in part 178 of the

subchapter.”

SELECTION

Once the proper shipping name is determined in Column 2 of the hazardous materials table

follow the table across to Column 8B (non-bulk packaging) or 8C (bulk packaging) for the

regulatory site of the packaging authorizations. In order to determine the authorized packaging

you must determine the packing group for the material to be shipped in addition to determining

the most descriptive shipping name.

In Column 8B or 8C you will see a number (e.g. 306) which represents the section in Part 173

where you will find a list of the authorized packages and any conditions which must be met. The

word "none" in either column signifies that the type of packaging (bulk or non-bulk) is not

authorized unless authorized in the special provisions column. Authorized packagings will be

represented in the form of a two, three or four character packaging identification code such as

1A1. The packaging identification code identifies (1) type of package (e.g. 1=Drum); (2)

material of construction (e.g. A=Metal); and (3) when appropriate, the category of packaging

(e.g. the numeral 1 following the codes 1A means the drum has a non-removable head. For each

proper shipping name there will be a variety of packaging identification codes. Authorized

packagings for some hazardous materials will be very general while others will be very specific.


Typically the more hazardous a chemical, the more specific will be the packaging.

Example 1:

You wish to ship 110 gallons of a liquid paint waste in a non-bulk packaging. After analyzing

the waste you determined that the paint exhibited a flashpoint of 96°F and a boiling point of

180°F.

With this information you determined that the proper shipping description is:

RQ UN1263, Waste paint,

3; PGIII (D001)

The regulatory site for the authorized packaging in column 8(b) of the Hazardous Material Table

is 173.173. 173.173 references authorized packagings in 173.203 for this material. There are 34

authorized single packagings identified in 173.203(c) including 1A1 or 1A2.

Example 2:

You wish to ship pyrophoric material which is not specifically identified by chemical name in

the hazardous materials table. You determined that the most descriptive shipping description is:

UN2845, Waste pyrophoric liquids, organic, n.o.s.

4.2; PGI

Column 8 (b) of the Hazardous Materials Table identifies the regulatory site §173.181 for the

packaging authorizations. 173.181 authorizes the use of 1A2 steel drums with strong tight inner

metal cans not over 1 gallon capacity each closed by positive means not friction.

In addition the following requirements must be met:

1. Inner packagings must have no opening exceeding 1 inch diameter and must be

surrounded by a noncombustible cushioning material.

2. Net quantity of pyrophoric liquids may not exceed 2/3 of the rated capacity of the outer

drum. For example a 55 gallon drum may not contain more than 36 gallons of

pyrophoric liquids.

3. Each layer of inner containers must be separated by a metal plate in addition to

cushioning material.

Other Considerations in Package Selection

Even though a certain type of packaging is authorized under 49 CFR 173 it is the responsibility

of the shipper to ensure that the packaging is compatible with the hazardous material it will hold.

For example: 1A1 (closed-head steel drum) is an authorized packaging under §173.202 for the

shipping name Hydrochloric acid; however, Hydrochloric acid would corrode a steel drum

relatively quickly.


UN SPECIFICATION CODES

The following is a list of descriptions which will help you to determine if the container meets the

packaging specifications for the material to be shipped.

Numerals indicating the type of package are as follows:

1 - Drum

2 - Wooden barrel

3 - Jerrican (metal/plastic packaging of rectangular or polygonal cross-section)

4 - Box

5 - Bag

6 - Composite package

7 - Pressure receptacle

A capital letter indicates material of construction.

A - steel

B - aluminum

C - natural wood

D - plywood

F - reconstituted wood

G - fiberboard

H - plastic

L - textile

M - paper (multiwall)

N - metal (other than steel or aluminum)

P - glass, porcelain or stoneware

The following numerals after 1A, 1B, 1H, 3A, 3H, 1N indicate:

1 - closed head

2 - open head

The following numerals after 2C indicate:

1 - bung type

2 - slack type (removable head)

The following numerals after 4C indicate:

1 - ordinary

2 - sift proof walls

The following numerals after 4H indicate:

1 - expanded plastic

2 - solid plastic

The following numerals after 5H or 5L woven plastic or textile bags indicate:

1 - unlined or non-coated

2 - sift proof

3 - water resistant


The following numerals after 5M indicate:

1 - multi-wall

2 - multi-wall water-resistant

For composite packagings (i.e. a metal drum with a plastic liner to form a single packaging) two

letters will follow the first number. The first letter refers to the material of the inner receptacle

and the second for the material of the outer receptacle. Example - 6HA1 stands for composite

package consisting of a plastic receptacle within a protective steel drum.

For combination packagings only the code number for the outer packaging is used.

Once you have determined the authorized packaging you can verify that the drum you want to

use meets those specifications by the markings on the packagings. These markings may be

found on the top (non-removable head drums only), side or bottom of the packaging. Pursuant to

§178.3 for packages with a gross mass more than 30 kg, markings (as described below) must

appear on the top or side of the packaging.

Every reusable packaging liable to undergo a reconditioning process which might obliterate the

packaging marks must bear the marks specified in 178.503 (a)(1) through (a)(6) and (a)(9) [Items

1-6 and 9 below] in a permanent form (e.g., embossed) able to withstand the reconditioning

process.

1. The United Nations symbol

2. A packaging identification code designating the type of packaging (i.e. 1 = Drum), the

material of construction (i.e., A = Steel) and, when appropriate, the category of packaging

under 178.504 through 178.523 of this subpart within the type to which the packaging

belongs (i.e., 1 = Closed head). The letter "V" must follow the packaging identification code

on combination packagings selectively tested in accordance with 178.601(g)(2); for example,

"4GV". The letter "W" must follow the packaging identification code on packagings that

have undergone approved alternate test in accordance with §178.601(h).

3. A letter identifying the performance standard under which the packaging design type has

been successfully tested, as follows:

X--for packagings meeting Packing Group I, II and III tests;

Y--for packagings meeting Packing Group II and III tests; or

Z--for packagings only meeting Packing Group III tests;

4. A designation of the specific gravity or mass for which the packaging design type has been

tested, as follows:

For packagings, without inner packagings, intended to contain liquids, the

designation shall be the specific gravity rounded down to the first decimal but

may be omitted when the specific gravity does not exceed 1.2; and

U n


U n

For packagings intended to contain solids or inner packagings, the designation

shall be the maximum gross mass in kilograms;

5. For single and composite packagings intended to contain liquids, the test pressure in

kilopascals rounded down to the nearest 10 kPa of the hydrostatic pressure test that the

packaging design type has successfully passed; or

For packagings intended to contain solids or inner packagings, the letter "S";

6. The last two digits of the year of manufacture. Packagings of types 1H and 3H shall also be

marked with the month of manufacture in any appropriate manner; this may be marked on

the packaging in a different place from the remainder of the markings;

7. The state authorizing allocation of the mark. The letters "USA' indicate that the packaging is

manufactured and marked in the United States in compliance with the provisions of this

subchapter;

8. The name and address or symbol of the manufacturer or the approval agency certifying

compliance with subpart L and subpart M of this part. Symbols, if used, must be registered

with the Associate Administrator for Hazardous Materials Safety;

9. For metal or plastic drums or jerricans intended for reuse or reconditioning as single

packagings or the outer packagings of a composite packaging intended for reuse or

reconditioning, the thickness of the packaging material expressed in millimeters (rounded to

the nearest 0.1 mm) as follows:

i. Metal drums or jerricans must be marked with the nominal thickness of the metal used in

the body. The marked nominal thickness must not exceed the minimum thickness of the

steel used by more than one thickness tolerance stated in ISO Standard 3574. The unit of

measure is not required to be marked. When the nominal thickness of either head of a

metal drum is thinner than that of the body, the nominal thickness of the top head, body,

and bottom head must be marked (e.g., 1.0-1.2-1.0)

ii. Plastic drums or jerricans must be marked with the minimum thickness of the packaging

material.

10. In addition to the markings described above, every new metal drum having a capacity greater

than 100 liters must bear the marks described under items 1 through 6 and 9.i. in a permanent

form on the bottom. The markings on the top head or side need not be permanent, and need

not include the thickness mark described in item 9

11. Rated capacity of the packaging expressed in liters may be marked.

Examples:

1A1/Y1.4/150/83

USA/VL824

1 MM


U n

Applies to drums, steel, closed head, which meet the requirements for PG II and III, is

designed for liquids with a specific gravity of 1.4 or less, and was tested to a pressure of 150

kPa, was manufactured in 1983 who's mark was authorized in the U.S.A. with the

manufacturers or approval agencies mark VL824, and may be reconditioned as long as the

minimum thickness of the drum is ∃ 1 mm.

.

1A2/Z150/S/83

USA/VL825

Applies to drums, steel, open head, which meet the requirements for PG III, which are rated

for a gross mass of 150 kilograms, is authorized to contain solids only, was manufactured in

1983, who's mark was authorized in USA with the manufacturers or approval agencies mark

VC825.


LIMITED QUANTITIES EXCEPTION

A limited quantity is the maximum amount of material for which there is a specific labeling or

packaging exception. To qualify as a limited quantity:

1. Identify the proper shipping name in column 2 of the Hazardous Materials Table,

2. Follow across to column 8a and note if there are any packaging exceptions identified. If

there are no packaging exceptions, the material may not be shipped as a limited quantity.

3. If a packaging exception is identified in column 8a, go to the regulatory site in section 173.

4. The limited quantity paragraph in the referenced section will identify what regulations the

limited quantity would be excepted from and the specific requirements which must be met in

order to ship the material as a limited quantity.

5. Pursuant to 49 CFR 172.31: packages containing limited quantities are not required to be

marked with the shipping name if it is marked with the appropriate identification number

within a white square on point border. The border must be at least 2mm and the ID number

must be at least 6mm high.

Example: Shipping fluorescent lamps which are not managed as universal waste.

Florescent lamps which exhibit the toxicity characteristic for mercury are hazardous wastes. All

hazardous wastes, which are not excluded from the manifesting requirements, are hazardous

materials subject to DOTs Hazardous Materials Regulations.

1. The proper shipping name would be: Hazardous waste solid, n.o.s.

2. Exceptions identified in column 8a are located at §173.155.

3. §173.155 Exceptions for Class 9 (miscellaneous hazardous materials)

Specific Requirements:

Each package must conform to the packaging requirements of Subpart B (e.g. the

packaging must compatible with its contents, the package must not leak).

Gross weight of the package must not exceed 30 kg (66 pounds).

Each inner container must not exceed 1.3 gallons (for liquids) or 11 pounds (for

solids.

Regulations Excepted From:

If these specific requirements are met, the shipper does not have to:

Label the package with a Class 9 diamond label (unless shipped by air)

Comply with specification packaging requirements or

Placard the transport vehicle (for the limited quantity material).


MATERIALS OF TRADE EXCEPTION §173.6

A material of trade is defined as "a hazardous material, other than a hazardous waste, that is

carried on a motor vehicle:

(1) for the purpose of protecting the health and safety of the motor vehicle operator or

passengers;

(2) for the purpose of supporting the operation or maintenance of a motor vehicle (including

its auxiliary equipment); or

(3) by a private motor carrier (including vehicles operated by a rail carrier) in direct support

of a principal business that is other than transportation by motor vehicle.

When transported by motor vehicle a material of trade is not subject to any other requirements of

the Hazardous materials regulations except those specified below.

Materials and Amounts

A material of trade is limited to the following:

(1) A class 3, 8, 9, Division 4.1, 5.1, 6.1, or ORM-D material contained in a packaging

having a gross mass or capacity not over-

(I) 0.5 kg (1 pound) or 0.5 L (1 pint) for a Packing Group I material;

(ii) 30 kg (66 pounds) or 30 L (8 gallons) for a Packing Group II, Packing Group III,

or ORM-D material;

(iii)1500 L (400 gallons) for a diluted mixture, not to exceed 2 percent concentration,

of a Class 9 material;

(2) A Division 2.1 or 2.2 material in a cylinder with a gross weight not over 100 kg (220

pounds), in a Dewar flask meeting the requirements of § 173.320, or a permanently

mounted tank manufactured to the ASME Code of not more than 70 gallon water

capacity for a non-liquefied Division 2.2 material with no subsidiary hazard.; or

(3) A Division 4.3 material in Packing Group II or III contained in a packaging having a

gross capacity not exceeding 30 ml (1 ounce).

(4) A Division 6.2 material, other than a Risk Group 4 material, that is a diagnostic

specimen, biological product, or regulated medical waste. The material must be contained

in a combination packaging. For liquids, the inner packaging must be leak tight, and the

outer packaging must contain sufficient absorbent material to absorb the entire contents

of the inner packaging. For sharps, the inner packaging must be constructed of a rigid

material resistant to punctures and leaks. For all Division 6.2 materials, the outer

packaging must be a strong, tight packaging securely closed and secured against

movement.


(i) For a diagnostic specimen or biological product, combination packagings must

conform to the following capacity limitations:

(A) One or more inner packagings where the gross mass or capacity of each

inner packaging does not exceed 0.5 kg (1.1 pound), or 0.5 L (17 ounces),

and an outer packaging having a gross mass or capacity not exceeding 4

kg (8.8 pounds) or 4 L (1 gallon); or

(B) A single inner packaging with a gross mass or capacity not exceeding 16

kg (35.2 pounds) or 16 L (4.2 gallons) in a single outer packaging.

(ii) For a regulated medical waste, a combination packaging must consist of one or

more inner packagings having a gross mass or capacity not exceeding 4 kg (8.8

pounds) or 4 L (1 gallon), and an outer packaging having a gross mass or capacity

not exceeding 16 kg (35.2 pounds) or 16 L (4.2 gallons).

(5) This section does not apply to a hazardous material that is self-reactive (see §173.124),

poisonous by inhalation (see §173.133), or a hazardous waste.

Packaging

(1) Packagings must be leak tight for liquids and gases, sift proof for solids, and be securely

closed, secured against movement, and protected against damage.

(2) Each material must be packaged in the manufacturer's original packaging, or a packaging

of equal or greater strength and integrity.

(3) Outer packagings are not required for receptacles (e.g., cans and bottles) that are secured

against movement in cages, carts, bins, boxes or compartments.

(4) For gasoline, a packaging must be made of metal or plastic and conform to requirements

of this subchapter or requirements of the Occupational Safety and Health Administration

of the Department of Labor contained in 29 CFR 1910.106.

(5) A cylinder or other pressure vessel containing a Division 2.1 or 2.2 material must

conform to packaging, qualification, maintenance, and use requirements of this

subchapter, except that outer packagings are not required. Manifolding of cylinders is

authorized provided all valves are tightly closed.

Hazard communication

(1) A non-bulk packaging other than a cylinder (including a receptacle transported without

an outer packaging) must be marked with a common name or proper shipping name to

identify the material it contains, including the letters "RQ" if it contains a reportable

quantity of a hazardous substance.

(2) A bulk packaging containing a diluted mixture of a Class 9 material must be marked on

two opposing sides with the four-digit identification number of the material. The


identification number must be displayed on orange panels or, alternatively, a white

square-on-point configuration having the same outside dimensions as a placard (at least

273 mm (10.8 inches) on a side), in the manner specified in §172.332(b) and (c) of this

subchapter. Each digit in the identification number marking must be at least 25 mm (one

inch) high and 6 mm (0.24 inch) wide.

(3) A DOT specification cylinder (except DOT specification 39) must be marked and labeled

as prescribed in this subchapter. Each DOT-39 cylinder must display the markings

specified in §178.65(I).

(4) The operator of a motor vehicle that contains a material of trade must be informed of the

presence of the hazardous material (including whether the package contains a reportable

quantity) and must be informed of the requirements of this section.

Aggregate gross weight

Except for permanently mounted tanks authorized by paragraph (a)(1)(iii) of this section, the

aggregate gross weight of all materials of trade on a motor vehicle may not exceed 200 kg (440

pounds). A material of trade may be transported on a motor vehicle under the provisions of this

section with other hazardous materials without affecting its eligibility for exceptions provided by

this section.


LAB PACK EXCEPTION §173.12(b)

Just as for Pre HM-181, there is also an exception for lab packs under HM-181 regulations. This

is the "Exception for Shipment of Waste Material" located in §173.12(b). If material is not

shipped under this exception or another exception, packaging is determined by referring to

column 8 (b) of the Hazardous Materials Table.

Authorized Materials

This packaging exception only applies to material assigned the hazard class or division 3, 4.1,

4.2, 4.3, 5.1, 5.2, 6.1, 8 or 9.

Prohibited Materials

Alternately, the following hazard classes or divisions may not be packaged under this exception:

1.1, 1.2, 1.3, 1.4, 1.5, 1.6, 2.1, 2.2, 2.3, 6.2, and 7. In addition, Division 6.1, packing group I

(PGI), Chloric acid, Oleum (fuming sulfuric acid) and material poisonous by inhalation may not

be packaged under this exception.

Authorized Outer Packaging

1. For all authorized classes and divisions except 4.2 PGI, this exception authorizes the use of

UN specification 1A2, 1B2 or 1N2 metal drums, 1D plywood drums, 1G fiber drums, and

1H2 plastic drums tested and marked for at least the packing group III performance level. A

higher performance level may be required for certain material when using this exception to

segregate incompatible materials (see section on segregation on the following page).

2. 4.2 PGI material must be packed in a container authorized for PGI material (i.e., X-rated).

3. At a minimum, a double-walled UN 4G fiberboard box made out of 500 pound burst-strength

fiberboard fitted with a polyethylene liner at least 3 mils (0.12 inches) thick and when filled

during testing to 95 percent capacity with a solid material, successfully passes the tests

prescribed for packing group II (i.e., Y-rated); or

4. A UN 11G fiberboard intermediate bulk container (IBC) or a UN 11HH2 composite IBC,

fitted with a polyethylene liner at least 6 mils (0.24 inches) thick, rated for Packing Group II.

The UN 11HH2 is composed of multiple layers of encapsulated corrugated fiberboard

between inner and outer layers of woven coated polypropylene.

General Rules

In order to qualify for this exception you must follow some general rules:

1. Inner glass packagings must not exceed 1 gallon and inner metal or plastic containers must

not exceed 5.3 gallon capacity. Additional inner container limits apply when using this

exception to segregate incompatible material (see section on segregation below).

2. Inner containers of liquids must be surrounded by an absorbent material capable of absorbing

the total liquid contents of the package.

3. The gross weight of the package may not exceed 452 pounds.

4. Waste may only be transported by highway, rail or cargo vessel.


Shipping Descriptions

1. This exception also authorizes the use of generic shipping descriptions identified in the

hazardous materials table when 2 or more compatible chemicals of the same hazard class are

placed in the same outer packaging.

2. Technical names are not required for lab packs packaged under this exception, except for

packages containing a hazardous substance.

Segregation

If properly packaged under this exception these packages are not subject to the segregation

requirements as long as:

1. The packages of incompatible material are separated from each other by a minimum distance

of 4 feet and the packages are loaded at least 4 inches off the floor.

2. The vehicle does not contain Class 1 explosives, Class 7 radioactive material or

uncontainerized hazardous material. AND

3. When Shipping: Acids with cyanides. Division 4.2 with Class 8 Liquids Division 6.1 PGI, Zone A with 3,

4.1, 4.2, 4.3, 5.1 5.2 and 8 liquids.

Class 8 liquids must be in lab packs or in authorized single packaging with a capacity ≤ 55 gallons.

Cyanides and cyanide mixtures

limited to 4.4 pounds net

weight/inner packaging and 22

pounds net weight/outer package.

4.2 limited to 4.4 pounds net

weight/inner container and 22

pounds net weight/ outer package.

The PIH must be packed in

accordance with § 49 CFR

173.226(c) and further overpacked

in a steel or plastic drum rated for

PGI (X-rated)

Cyanide solutions limited to 0.6

gallons/ inner packaging and 3

gallons/ outer package.

4.2 limited to 4.4 pounds net weight

per inner packaging and 22 pounds

net weight/outer package.




Aggregate net weight of 5.1 on

vehicle may not exceed 220 pounds.



pounds net weight/ outer package.

5.2 Type B limited to 1.1 pounds net

weight/inner packaging and 5.5


Aggregate net weight of 5.2 on

vehicle may not exceed 110 pounds.

Overpacks

If lab packs are overpacked (e.g., shrink wrapped on a pallet) the overpack requirement at 49

CFR 173.25(a)(2) does not apply. Specifically, the outside of the overpack does not have to be

marked with the proper shipping name(s) or identification number(s). However, representative

diamond labels must be placed on two opposing sides and the shrink wrapped pallet must be

marked with the word “Overpack”.


§173.13 "POISON PACK" EXCEPTION

Hazardous material in hazard class or division: 3, 4.1, 4.2, 4.3, 5.1, 6.1 (except for poison inhalation hazards), 8 and

9 are excepted from labeling (except for the cargo aircraft only label) and placarding requirements (this also

automatically exempts the packages from segregation requirements) if the following conditions are met.

1. For liquids:

INNER PACKAGING - The hazardous material must be placed in tightly closed glass, plastic or metal

inner packaging with a maximum of 1.2 liters. The net quantity of a liquid in the inner container must not

exceed 1 liter when measured at 20°C.

HERMETICALLY SEALED BARRIER BAG -The inner packaging must be placed in a hermetically-

sealed barrier bag which is impervious to the material in the inner container.

NON-REACTIVE ABSORBENT - The inner container enclosed in the barrier bag must be wrapped in a

non-reactive absorbent material of sufficient quantity to absorb the contents of the inner packaging.

Alternately the absorbent may be placed in the barrier bag.

METAL CAN - The packaging described above must be placed in a snugly fitting securely closed metal

can.

For liquid in division 4.2 or 4.3, the metal can must be hermetically sealed.

For liquids in division 4.2 of packing group I, the metal can must be tested and marked at the PGI

performance level.

FIBERBOARD BOX - The metal can must then be placed in a fiberboard box.

HERMETICALLY SEALED BARRIER BAG - The fiberboard box (this is intermediate packaging)

must be placed in a hermetically sealed barrier bag which is impervious to the material in the inner

container.

§173.201 PACKAGING - The intermediate packaging must be placed in a package authorized under

§173.201 "Non-bulk Packagings for Liquid Hazardous Material in Packing Group I". No more than 4

intermediate packages may be placed in this container.

2. For Solids

INNER PACKAGING - The hazardous material must be placed in tightly closed glass, plastic or metal

inner packaging with a maximum net quantity of 6.25 pounds.

HERMETICALLY SEALED BARRIER BAG -The inner packaging must be placed in a hermetically-


FIBERBOARD BOX - The metal can must then be placed in a fiberboard box.

HERMETICALLY SEALED BARRIER BAG - The fiberboard box must be placed in a hermetically


§173.211 PACKAGING - The intermediate packaging (described above) must be placed in a package

authorized under §173.211 "Non-bulk Packagings for Solids Hazardous Materials in Packing Group I". No

more than four intermediate packagings may be placed in the outer packaging.

3. The outside of the package must be marked with the words "This package conforms to §173.13" in association

(after) the shipping name.


SALVAGE DRUMS §173.3

Packages of hazardous materials that are damaged, defective, or leaking; packages found to be

not conforming to the requirements of this subchapter after having been placed in transportation;

and, hazardous materials that have spilled or leaked may be placed in a metal or plastic

removable head salvage drum that is compatible with the lading and shipped for repackaging or

disposal under the following conditions:

1. The salvage drum must be a UN specification 1A2, 1B2, 1N2, or 1H2 tested and marked for

at least packing group III performance standards for liquids or solids and a leak proof test of

20 kPa (3psi) or a drum manufactured and marked salvage drum prior to October 1, 1993.

2. The salvage drum may not exceed 119 gallon capacity.

3. Absorbent material must be used to cushion the drum in order to prevent excessive

movement and to absorb all free liquids present at the time of closure.

4. The salvage drum must be marked and labeled in the same manner as for a non-overpacked

drum. In addition the drum must be marked with the words "SALVAGE DRUM".

SALVAGE CYLINDERS §173.3(d)

Cylinders of hazardous materials that are damaged or leaking may be overpacked in a non-DOT

specification full opening hinged head or fully removable head steel salvage cylinder under the

following conditions:

1. Only a cylinder containing a Division 2.1, 2.2, 2.3, 3, 6.1, or a Class 8 material may be

overpacked in a salvage cylinder. A cylinder containing acetylene may not be overpacked in

a salvage cylinder.

2. Each salvage cylinder-

(i) Must be designed, constructed and marked in accordance with Section VIII, Division

I of the ASME Code (IBR, see § 171.7 of this subchapter) with a minimum design

margin of 4 to 1. Salvage cylinders may not be equipped with a pressure relief device.

Damaged cylinders must be securely positioned in the salvage cylinder to prevent

excessive movement. The overpack requirements of § 173.25 of this part do not apply

to salvage cylinders used in accordance with this section.

(ii) Must have a maximum water capacity of 450 L (119 gallons).

(iii)Except for liquefied nitrous oxide and carbon dioxide, contents of the damaged or

leaking cylinder must be limited in pressure and volume so that if totally discharged

into the salvage cylinder, the pressure in the salvage cylinder will not exceed 5/4 of

the MAWP at 55°C (131 °F).

(iv) Must have gaskets, valves and fittings that are compatible with the hazardous

materials contained within.


3. Each salvage cylinder must be plainly and durably marked. Unless otherwise specified, the

markings below must be in the same area on any portion of the upper end:

(i) The proper shipping name of the hazardous material contained inside the packaging;

(ii) The name and address of the consignee or consignor;

(iii) The name and address or registered symbol of the manufacturer; and

(iv) The words "SALVAGE CYLINDER" in letters at least 50 mm (2.0 inches) high on

opposite sides near the middle of the cylinder; stamping on the sidewall is not

authorized.

4. Each salvage cylinder must be labeled for the hazardous material contained inside the

packaging.

5. The shipper must prepare shipping papers in accordance with subpart C of part 172 of this

subchapter.

6. Transportation is authorized by motor vehicle only.

7. Each salvage cylinder must be cleaned and purged after each use.

8. In addition to the training requirements of §§172.700 through 172.704 of this subchapter, a

person who loads, unloads or transports a salvage cylinder must be trained in handling,

loading and unloading the salvage cylinder.

9. Cylinder Requalification: At least once every five years, each cylinder must be visually

inspected (internally and externally) in accordance with CGA Pamphlet C-6 (IBR, see §

171.7 of this subchapter) and pressure tested. A minimum test pressure of at least 1 ½ times

MAWP must be maintained for at least 30 seconds. The cylinder must be examined under

test pressure and removed from service if a leak or a defect is found.

(i) The retest and inspection must be performed by a person familiar with salvage cylinders

and trained and experienced in the use of the inspection and testing equipment.

(ii) Each salvage cylinder that is successfully requalified must be durably and legibly marked

with the word "Tested" followed by the requalification date (month/year), e.g., "Tested

9/04." The marking must be in letters and numbers at least 12 mm (0.5 inches) high. The

requalification marking may be placed on any portion of the upper end of the cylinder

near the marking required in (d)(3) of this section or on a metal plate permanently

secured to the cylinder. Stamping on the cylinder sidewall is not authorized.

10. Record retention: The owner of each salvage cylinder or his authorized agent shall retain

a record of the most recent visual inspection and pressure test until the salvage cylinder is

requalified. The records must be made available to a DOT representative upon request.


OVERPACKS §173.25

Hazardous materials in authorized packagings may be placed in a strong overpack if all of the

following conditions are met:

1. The package must meet the requirements of 49 CFR 173.21 and 173.24

2. The overpack must be marked and labeled for each hazardous material contained therein

unless the markings on the container are visible.

3. When liquids are placed in the overpack, the containers must be oriented with the closures

upward and the drum must be marked "THIS SIDE UP" or” THIS END UP" and with

appropriate orientation arrows.

4. The overpack is marked with the word "OVERPACK" when specification packagings are

required, unless specification markings on the inside packages are visible.

5. Packages containing Class 8 materials in packing group I or Division 5.1 materials in

packing group I may not be overpacked with any other materials.

Shrink-wrapped or stretch-wrapped trays may be used as outer packagings for inner packagings

prepared in accordance with the limited quantity provisions or consumer commodity provisions

of this subchapter, provided that:

1. Inner packagings are not fragile, liable to break or be easily punctured, such as those made of

glass, porcelain, stoneware or certain plastics; and

2. Each complete package does not exceed 20 kg (44 lbs) gross weight.


REUSE OF NON BULK PACKAGINGS §173.28

Packagings used more than once must be in such condition, including closure devices and

cushioning material that they conform to all requirements for authorized packagings. Before

reuse, each package must be inspected and may not be reused unless free from incompatible

residue, rupture or other damage which reduces its structural integrity.

A non-bulk packaging used more than once must conform to the following provisions and

limitations:

1. Any packaging showing signs of loss of integrity may not be reused until it is reconditioned

in accordance with §173.28(c).

2. A leak proofness test must be performed in accordance with 49 CFR 178.604 on any

container intended to contain liquids. The package must be marked by the authorized tester

with the letter ``L'', the name and address or symbol of the person conducting the test, and the

last two digits of the year the test was conducted. Note: Internal air pressure (gauge) not less

than 48 kPa (7 psi) must be applied for packaging designated to contain Packing Group I

material (pressures for PGII and PGII packaging are specified in §178.604).

3. Packagings made of paper, plastic film or textile may not be reused.

4. Metal and plastic drums used as a single or composite packaging are authorized for reuse if

the minimum thickness (in millimeters) is permanently (embossed) marked on the packaging

and conforms to the construction criteria in 173.28(b)(4) (e.g., a 55 gallon metal drum would

have to have a minimum thickness of 0.92 mm and a 55 gallon plastic drum would have to

have a minimum thickness of 2.2 mm).

5. Plastic inner receptacles of composite packagings must have a minimum thickness of 1.0

mm.

6. If all conditions above are met, with the exception of item 2, a packaging may be reused

without being leakproofness tested with air provided the packaging-

Is refilled with a material which is compatible with the previous lading:

Is refilled and offered for transportation by the original filler;

Is transported in a transport vehicle or freight container under the exclusive use of the

refilled of the packaging; and

Is constructed of-

(A) Stainless steel, monel or nickel with a thickness not less than one and one-half

times the minimum thickness prescribed in paragraph (b)(4) of this section;

(B) Plastic, provided the packaging is not refilled for reuse on a date more than

five years from the date of manufacture marked on the packaging in

accordance with §178.503(a)(6) of this subchapter; or

(C) another material or thickness when approved under the conditions established

by the Associate Administrator for Hazardous Materials Safety for reuse

without retesting.


7. A previously used non-bulk packaging may be reused for the shipment of waste material

transported for disposal or recovery, provided

The packaging is authorized for the material to be shipped,

Transportation is by highway only,

The package is loaded by the shipper and unloaded by the consignee, unless the

motor carrier is a private or contract carrier.

The package has been filled 24 hours or more before being offered for shipment,

The package is inspected for leaks just before offering it for shipment, and

The package is reused only once.


PACKAGE MARKING REQUIREMENTS

GENERAL MARKING REQUIREMENTS:

1. Package markings must be:

2. "Durable;

3. In English and printed on or affixed to the surface of a package or on a label, tag, or sign;

4. Displayed on a background of sharply contrasting color;

5. Unobscured by labels or attachments; and

6. Must be located away from any other markings (such as advertising) that could

substantially reduce its effectiveness." §172.304

MARKING REQUIREMENTS FOR CONTAINERS WITH RESIDUALS

An "empty package" ( 119 gallons) that last contained a hazardous material and has not been

cleaned and purged of all residue that could present a hazard, (in other words a package which is

not empty by DOT standards) must be marked as required above except the word waste need not

be displayed (assuming the drum is RCRA empty). §173.29

MARKING REQUIREMENTS FOR NON-BULK PACKAGING AND IBCs

The following table identifies marking requirements for non-bulk packages and intermediate

bulk containers. Additional marking requirements are located at §§ 172.325, 172.326, 172.328,

and 172.330 for elevated temperature material, portable tanks, cargo tanks, and tank cars and

multi-unit tank car tanks respectively.

REQUIRED FOR NON-

BULK PACKAGES MARKING

REQUIRED FOR

INTERMEDIATE BULK

CONTAINERS (IBC)

X Shipping Name

X14 Identification Number X1,2a and 3a or 2b and 3b (IBCs only)

X4 Technical Names

X5 Special Permits (DOT-SP...) X2

X6 Shippers Name and Address

X7 Orientation Arrows

X8 Inhalation Hazard X2, 8, 9

X10 Poison

X11 ORM-D

X12 Marine Pollutant X1, 12

X13 RQ

MARKING TABLE FOOTNOTES


1. The required marking must be placed on two opposing sides if the capacity of the container is

less than 1000 gallons or on each side and each end if the capacity of the package is greater

than or equal to 1000 gallons.

2a. The size of markings must be at least 4.0 mm wide and 25mm (one inch) high. §172.302(b)

2b. For non-bulk packaging, beginning 1/1/17, the identification number must be at least 0.47”

high for packaging with a capacity > 8 Gallons and 0.24” high for packaging with a capacity

between 1.32 and 8 Gallons.

UN1993 UN1993

3a. Identification numbers must be displayed on orange panels, placards as specified in §172.332

or on the white square on point configuration as specified in §172.336.

3b. For IBC’s only, the shipping name and identification number may be marked on the package

just as would be required for any other non-bulk package instead of being displayed on

orange panels, placards or the white square on point configuration as long as the package is

labeled as required for any non-bulk package. July 20, 2011.

4. Technical names must be marked in parenthesis, in association with the shipping name. This

includes technical names for N.O.S. Descriptions (§172.203(k)), Marine Pollutants

(§172.203(l), Hazardous Substances (§172.203 (c) and Poisons (§172.203(m).

5. The outside of each package authorized by a special permit must be plainly and durably

marked "DOT-SP" followed by the special permit number assigned. Packages authorized by

an exemption issued prior to October 1, 2007, may be plainly and durably marked "DOT-E"

in lieu of "DOT-SP" followed by the number assigned as specified in the most recent version

of that exemption.

6. The package must be marked with the name and address of the shipper or consignee except

(if shipping by air both must be marked on the package) when the package is (§172.301(d)):

a. Transported by highway and will not be transferred from one motor carrier to another,

or

b. Part of a carload lot , truckload lot, or freight container load, and the entire contents

of the rail car, truck of freight container are shipped from one generator to one

receiver, or

c. A portable tank, cargo tank, or tank car.

NOTE: Under RCRA, for hazardous waste containers <119 gallons, the generator’s

name and address must be marked on the drum.

7. The orientation markings must be placed on two opposing vertical sides of the

container for combination packagings in which inner containers hold liquids.


§172.312

8. The words "Inhalation Hazard" must be marked on the container. This is not

required, if the "Inhalation Hazard" label is affixed to the package and the words

"Inhalation Hazard" are displayed on the label or placard. §172.313(a)

9. The inhalation hazard marking must be placed on two opposing sides of the package.

§172.313(a)

10. Each non-bulk plastic outer packaging used as a single or composite package shall be

permanently marked by embossment or other durable means, with the word "POISON"

within six inches of the package closure. §172.313 (b) NOTE: This would not be required

for lab packs since lab packs are combination packagings.

11. A package of an Other Regulated Material (ORM-D) such as a consumer commodity must be

marked immediately following or below the proper shipping name with the letters ORM-D or

ORM-D-AIR (for shipments of packages prepared for shipment by air in accordance with

§173.27). The ORM designation must be placed within a rectangle that is approximately 6.3

mm (0.25 inches) larger on each side than the designation.

12. The marine pollutant mark is required for non-bulk packagings transported

by vessel and all bulk packagings containing marine pollutant(s).

13. The hazardous substance notation RQ must be marked on the package in

association with the shipping description.

TRANSPORT VEHICLE MARKING REQUIREMENTS

1. Pursuant to 49 CFR 172.331 if a transport vehicle is loaded with a hazardous material in a

bulk packaging (e.g. intermediate bulk containers (IBCs) otherwise referred to as totes) and

the identification number on the bulk packaging is not visible, the transport vehicle must be

marked on each side and each end with the appropriate identification number. This form of

marking is required to be supplied by the shipper.

2. Large quantities of a single hazardous material in non-bulk packages.

IF the transport vehicle is loaded at one loading facility:

With a single hazardous material in non-bulk packages (i.e. each package is

marked with the same proper shipping name and identification number);

With an aggregate gross weight, for the hazardous material, of 4,000 kg (8,820

pounds) or more; and

The transport vehicle or freight container contains no other material, hazardous or


otherwise;

the transport vehicle must be marked, on each side and each end with the identification

number using orange panels, placards or the white square on point configuration.

§172.301(a)(3)

If one container with one different shipping name is loaded at the same loading facility, this

requirement does not apply.

3. Large quantities of Poison Inhalation Hazards in non-bulk packages.

"A transport vehicle or freight container that is loaded at one loading facility with 1,000 kg

(2,305 pounds) aggregate gross weight of non-bulk packages containing materials poisonous

by inhalation in hazard Zones A and B having the same proper shipping name and

identification number; shall be marked on each end and each side with the identification

number using orange panels, placards with identification numbers or the white square on

point configuration. §172.313(c).

However, if the transport vehicle or freight container contains more than one Zone A or B,

poison inhalation hazard, exceeding 1000 kg, the transport vehicle shall be marked with the

identification number for one material, determined as follows:

For different materials in the same hazard zone, with the identification number of

the material having the greatest aggregate gross weight; and

For different materials in both Hazard Zones A and B, with the identification

number for the Hazard Zone A material.

USEPA CONTAINER MARKING REQUIREMENTS (40 CFR 262.32)

Before offering a hazardous waste for transport, each container of 110 gallons or less must be

marked with:

1. The words "HAZARDOUS WASTE",

2. The statement "Federal law prohibits improper disposal. If found, contact the nearest

police or public safety authority or the U.S Environmental Protection Agency.”

3. The container is marked in a manner that indicates the hazards. Option include but are

not limited to:

a. Hazardous waste characteristic(s) - Ignitable, corrosive, reactive, and/or toxic;

b. DOT Hazardous material communication - labeling or placarding;

c. OSHA/GHS hazard statement or pictogram;

d. NFPA 704 Chemical hazard label

4. The 12 digit manifest tracking number.

5. Name and address of the generator (shipper in DOT terms)

6. Generators 12 Digit U.S. EPA Identification Number

7. RCRA Waste Codes


DRUM LABELING REQUIREMENTS

DOT requires specific drum labeling for hazardous materials. The DOT labels must be of the

size, color, durability etc., as specified in §172.407.

Container labels must be:

1. Placed on or affixed to the package next to the proper shipping name,

2. Placed next to each other (within 6 inches) when there is more than one label,

3. Affixed to a background of contrasting color, or must have a dotted or solid line outer

border

4. Unobscured from markings or attachments. §172.406

The following is a description of DOT labeling requirements for hazardous materials offered for

transportation.

1. Labels are not required for a packaging classified as ORM-D or combustible liquid.

§172.400

2. The hazard class or division number must be displayed in the lower corner of a primary

hazard label and a subsidiary hazard label. A subsidiary label that does not show the

hazard class or division number in the bottom corner may no longer be used. §172.402(b)

3. For other than Class 1 and 2 materials, if the material is not specifically listed in the

§172.101 Hazardous Materials table the following chart must be used to determine if a

subsidiary label is required: §172.402

SUBSIDIARY

HAZARD LEVEL

(Packing Group)

SUBSIDIARY HAZARD

(Class or Division)

3 4.1 4.2 4.3 5.1 6.1 8

I

II

III

X

X

*

***

X

X

***

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X Required for all modes of transportation.

* If the flash point of a material is at or above 38°C (100°F), required for transport

by air or vessel only.

*** Impossible to have a subsidiary hazard.

For example: If the primary hazard class is something other than Class 1 or 2 and the

subsidiary hazard class is 8 in PG III then a corrosive subsidiary label is required.

4. A Division 2.2 material (Non-flammable gas) that also meets the definition of an

oxidizing gas [Oxidizing gas means a gas which may, generally by providing oxygen,

cause or contribute to the combustion of other material more than air does.] must be

labeled with a subsidiary oxidizer label. §172.402 (f)


5. A Division 2.3 material (poisonous gas) that also meets the definition of Division 2.1, 5.1

or Class 8 must be labeled flammable gas, oxidizer and corrosive respectively. §172.402

(g)

6. For domestic shipment the "poison" label may be used in place of the "Keep Away From

Food" label for material meeting the definition of Division 6.1, Packing Group III.

7. A package prohibited from transportation by

passenger aircraft that is destined for air shipment

must be labeled with a CARGO AIRCRAFT ONLY

label in addition to any other required labels.

§172.402(c).

8. When shipping lithium batteries the following label

must be used. “Labels conforming to requirements in place

on December 31, 2016 may continue to be used until December

31, 2018.”


SEGREGATION OF HAZARDOUS MATERIALS

Hazardous materials may not be loaded, transported, or stored together except as provided in the segregation table

(see following page).

You must consider the primary and subsidiary hazards when determining proper segregation. However, material of

the same primary hazard class may be shipped together without regard to the subsidiary hazard class if the materials

are not capable of reacting dangerously with each other.

In addition to the segregation requirements presented on the following table, cyanides, cyanide mixtures or solutions

may not be stored, loaded and transported with acids if a mixture of the materials would generate hydrogen cyanide,

and Division 4.2 materials may not be stored, loaded and transported with Class 8 liquids. §177.848(c).

Exceptions from segregation requirements §173.12(e)

The segregation requirements do not apply to:

1. Waste cyanides or waste cyanide mixtures or solutions stored, loaded, or transported with acids in accordance

with the following:

(i) Waste cyanides must be lab packed see 173.12(b)

(ii) Class 8 acids must be lab packed or in authorized single packagings not exceeding 55 gallon capacity;

(iii) Waste cyanides or cyanide mixtures may not exceed 2 kg (4.4 pounds) per inner receptacle and may

not exceed 10 kg (22 pounds) per outer packaging; waste cyanide solutions may not exceed 2 L (0.6

gallon) per inner receptacle and may not exceed 10 L (3.0 gallons) per outer packaging.

(iv) The waste cyanides or waste cyanide mixtures or solutions must be-

(A) Separated from the acids by a minimum horizontal distance of 1.2 m (4 feet); and

(B) Loaded at least 100 mm (4 inches) off the floor of the freight container, unit load device,

transport vehicle or rail car.

2. Waste Division 4.2 materials stored, loaded or transported with Class 8 liquids in accordance with the

following:

(i) Waste Division 4.2 materials lab packed;

(ii) Class 8 liquids are lab packed or in authorized single packagings not exceeding 55 gallons capacity;

(iii) Waste Division 4.2 materials may not exceed 2 kg (4.4 pounds) per inner receptacle and may not

exceed 10 kg (22 pounds) per outer packaging;

(iv) Waste Division 4.2 materials must be separated from the Class 8 liquids by a minimum horizontal

distance of 1.2 m (4 feet);

(v) Waste Division 4.2 materials and the Class 8 liquids are loaded at least 100 mm (4 inches) off the floor

of the freight container, unit load device, transport vehicle or rail car.


Division 4.2 (self-heating liquid) material. §177.838(i)

Notwithstanding the segregation requirements of §177.848(d), the following Division 4.2 (self-heating) materials

may be transported on the same transport vehicle with Class 8 (corrosive) materials. The hazardous materials

must be palletized with a minimum height of 100 mm (4 inches) off the floor of the vehicle, and the self-heating

material must be separated from the corrosive material by a minimum horizontal distance of 1.2 m (4 feet).

(1) Sodium hydrosulfite or sodium dithionite, UN1384, in PG II or III packaged in UN 1A2 steel drums that

meet the Packing Group II performance requirements of subpart M of part 178 of this title.

(2) Thiourea dioxide, UN3341, in PG II or III packaged in UN 1G fiber drums meeting packing group II

performance requirements of subpart M of part 178 of this subchapter.

(3) Self-heating, solid, organic, n.o.s., UN3088, in PG II or III packaged in UN 1G fiber drums meeting the

Packing Group II performance level requirements of subpart M of part 178 of this subchapter.

Cylinders containing material classed as Division 2.3, Hazard Zone A. 178.140(a)(3)

(i) Notwithstanding the segregation requirements of §177.848(d), a cylinder containing a Division 2.3, Hazard

Zone A materials may be transported on the same transport vehicle with materials classed as Division 2.1,

Class 3, Class 4, Class 5, and Class 8 if all of the following requirements are met:

(A) The Division 2.3, Hazard Zone A material must be packaged as authorized by this subchapter. In

addition, each package must be placed in a plastic bag which is taped closed and then overpacked in a

UN 1A2 steel drum tested and marked for a PG II or higher performance level with insulation material

inside to protect the cylinders from fire. The outside of the overpack must be marked with an indication

that the inner packagings conform to the prescribed specifications.

(B) A Division 2.1 material requiring strong non-bulk outer packagings in accordance with §173.301(a)(9)

of this subchapter [i.e., Specification 2P, 2Q, 3E, 3HT, spherical 4BA, 4D, 4DA, 4DS, and 39 cylinders

] must be overpacked in a UN 1A2 steel or 1H2 plastic drum tested and marked for a PG II or higher

performance level. The outside of the overpack must be marked with an indication that the inner

packagings conform to the prescribed specifications.

(C) Packages containing Division 2.3 Hazard Zone A material must be separated within the transport

vehicle from packages containing Division 2.1, Class 3, Class 4, Class 5, and Class 8 materials by a

minimum horizontal distance of 1.2 m (4 feet). In addition, all steel or plastic overpacks containing

packages of Division 2.3, Hazard Zone A or Division 2.1 material must be placed on pallets within the

transport vehicle.

(ii) Notwithstanding the segregation requirements of §177.848(d), Division 2.3, Hazard Zone A material may be

transported on the same transport vehicle with non-bulk packagings and IBCs meeting a UN performance

standard containing only the residue of Division 2.1, 4.3, 5.1, and Class 3 and 8 materials if all of the

following requirements are met:

(A) The materials are transported in enclosed trailers equipped with inlet and outlet vent openings with a

minimum total area of one square foot per 1,000 cubic feet of trailer volume. Electrical systems within

the trailer's interior must be non-sparking or explosion proof.

(B) Cylinders must be transported in an upright position and securely restrained within the trailer, or loaded

into racks, secured to pallets, or packed in wooden or fiberboard boxes or crates to prevent the cylinders

from shifting or overturning within the motor vehicle under normal transportation conditions. If

cylinders are secured to a pallet, the pallet must be designed to transport 1,590 kg (3,500 lbs.) per pallet

and the cylinders must be secured within the pallet by a web strap rated at 4,545 kg (10,000 lbs.).

(C) A cylinder containing Division 2.3 Hazard Zone A materials must be separated from non-bulk


packagings and IBCs meeting a UN performance standard containing the residue of materials in

Division 2.1, 4.3, or 5.1, or Class 3 or 8 by a minimum horizontal distance of 3 m (10 feet). The

maximum gross weight of Division 2.3 Hazard Zone A material carried on one vehicle must not exceed

3,636 kg (8,000 lbs.).

(D) Motor carriers must have a satisfactory safety rating as prescribed in 49 CFR part 385.

Division 6.1 and Division 2.3 materials. §177.841(f)

Notwithstanding the segregation requirements of §177.848(d), when transported by highway by private or

contract motor carrier, Division 6.1 PG I, Hazard Zone A toxic-by-inhalation (TIH) materials meeting the

definition of a hazardous waste as provided in §171.8 of this subchapter, may be transported on the same

transport vehicle with materials classed as Class 3, Class 4, Class 5, and Class 8. The Division 6.1 PG I, Hazard

Zone A materials must be loaded on pallets and separated from the Class 3, Class 4, Class 5, and Class 8

materials by a minimum horizontal distance of 2.74 m (9 feet) when in conformance with the following:

(1) The TIH materials are packaged in combination packagings as prescribed in §173.226(c) of this subchapter.

(2) The combination packages containing TIH materials must be:

(i) Filled and packed by the offeror's hazmat employees;

(ii) Be placed on pallets, when in a transport vehicle; and

(iii) Separated from hazardous materials classed as Class 3, Class 8 or Divisions 4.1, 4.2, 4.3, 5.1, or 5.2 by

a nine-foot (minimum distance) buffer zone, when in a transport vehicle. The buffer zone maybe

established by:

(A) A load lock;

(B) Empty drums;

(C) Drums containing hazardous materials (e.g., Class 9) that are compatible with materials in all other

drums immediately around them; or

(D) Drums containing non-hazardous materials that are compatible with materials in all other drums

immediately around them.

SET Environmental, Inc. 89 Last Revision: June 24, 2020

SEGREGATION OF HAZARDOUS MATERIALS

Class or Division Notes 1.2 1.3 1.4 1.5 1.6 2.1 2.2 2.3

Zone A 2.3

Zone B 3 4.1 4.2 4.3 5.1 5.2 6.1

liquids

PG 1

Zone A

7 8

liquids

only

Explosives 1.1 and 1.2 A * * * * * X X X X X X X X X X X X X

Explosives 1.3 * * * * * X X X X X X X X X X

Explosives 1.4 * * * * * O O O O O O O

Very insensitive explosives 1.5 A * * * * * X X X X X X X X X X X X X

Extremely insensitive explosives 1.6 * * * * * Flammable gases 2.1 X X O X X O O O Non-toxic, non-flammable gases 2.2 X X Poisonous gas Zone A 2.3 X X O X X X X X X X X X

Poisonous gas Zone B 2.3 X X O X O O O O O O O O

Flammable liquids 3 X X O X X O O X Flammable solids 4.1 X X X O X O

Spontaneously combustible materials 4.2 X X O X X O X X

Dangerous when wet materials 4.3 X X X X O X O

Oxidizers 5.1 A X X X X O O X 0

Organic peroxides 5.2 X X X X O X O

Poisonous liquids PG 1 Zone A 6.1 X X O X O X X X X X X X

Radioactive materials 7 X X O Corrosive liquids 8 X X O X X O O X O O O X

The absence of any hazard class or division or blank space in the table signifies that no restrictions apply.

X The letter "X" in the table signifies that the two hazard classes or divisions may not be shipped together in the same vehicle or stored together while in the

transportation system.

O The letter "O" in the table signifies that the two hazard classes or divisions may only be shipped together if separated in a manner that in the event of

leakage from packages under conditions normally incident to transportation, commingling of hazardous materials would not occur. 49 CFR 177.848 (e)

(3). Notwithstanding the methods of separation employed, Class 8 (corrosive) liquids may not be loaded above or adjacent to Class 4 (flammable) or Class

5 (oxidizing) materials; except that shippers may load truckload shipments of such materials together when it is known that the mixture of contents would

not cause a fire or a dangerous evolution of heat or gas.

* An "*" in the table refers to segregation of explosive materials, see 177.848(f).

A The Note "A" in Column 2 of the table is associated with shipments of ammonium nitrate fertilizer.


MANIFEST SYSTEM

When preparing a hazardous waste manifest the first step is to choose the proper shipping form.

A bill of lading may be used for any material which does not meet the definition of a hazardous

waste. A uniform hazardous waste manifest must be used for any material meeting the definition

of a hazardous waste, excluding universal waste. Some states may require the use of state waste

codes and or require the submittal of manifest copies to the state agency. The Texas

Commission on Environmental Quality requires a Texas Waste Code to be placed in section 13

in two of the boxes reserved for US EPA RCRA waste codes. Entries on any shipping paper

must be legible.

This Not This

MANIFEST DISTRIBUTION

The manifest is a "cradle to grave" tracking paper and consists of five copies. Each copy of the

manifest and continuation sheet indicates how the copy must be distributed, as indicated below.

Certification

When the manifest is completed: the generator will sign the manifest in section 15 and make the

following certifications:

“…the content of this consignment are fully and accurately described above by the proper

shipping name, and are classified, packaged, marked and labeled/placarded, and are in all

respects in proper condition for transport according to applicable international governmental

regulations.” And

1. For Large Quantity Generators

“I have a program in place to reduce the volume and toxicity of waste generated to the

degree I have determined to be economically practicable and I have selected the

practicable method of treatment, storage or disposal currently available to me which

minimizes the present and future threat to human health or the environment.”

2. For Small Quantity Generators

“I have made a good faith effort to minimize my waste generation and select the best

waste management method that is available to me and that I can afford.”


Use of the Manifest (Tracking System)

1. The generator will also obtain the signature and date of acceptance from the first

transporter in line 1 of section 17. This acts like a receipt that the transporter has accepted

the hazardous waste – the first step in cradle to grave tracking. The generator must retain

this copy until the copy with a hand written signature of the receiving facility is obtained.

2. The first transporter will take the rest of the copies with the shipment. If the first

transporter delivers the waste to a second transporter, the second transporter will sign line

2 of section 17 and the first transporter will retain a photo copy as their receipt for a

period of at least three years. This process would be repeated for additional transporters;

however transporter 3 and beyond will sign section 33 or 34 of the continuation sheet.

3. The last transporter will deliver the hazardous waste to the facility designated in section 8

of the manifest. The facility will sign section 20 of the manifest acknowledging

acceptance of the waste and provide the remaining bottom copy (5th copy) to the last

transporter.

4. The designated facility will retain the remaining bottom copy (4th copy) for their records.

Within 30 days of receipt, the designated facility will mail the remaining bottom copy

(3rd copy) to the generators mailing address specified in section 5 of the manifest.

Large quantity generators that do not receive the signed copy of the manifest within

35 days must contact the transporter or designated facility to determine the status of

the waste.

If the generator does not receive the signed copy of the manifest within 45 days (60

days for small quantity generators) they must submit an exception report to the

EPA.

5. When the generator receives the signed copy for the designated facility this completes the

cradle to grave tracking.

6. The remaining two copies may be distributed as indicated below, if required by the

origination state or receiving state:

Page 1: Designated facility to destination State

Page 2: Designated facility to generator State.

Retention of other Hazardous Material Shipping Papers

NOTE: All other shipping papers (e.g., hazardous materials bill of lading) used in conjunction

with the transportation of hazardous materials that are not hazardous wastes must be retained

by the hazmat receiver (this is the transporter) for at least one year and be retained by the

hazmat shipper for at least two years.


Completing the Hazardous Waste Manifest

The instructions for completing the uniform hazardous waste manifest can be found on the

reverse side of the form.

ITEM 1 Enter the generator's U.S. EPA twelve digit identification number or the State

generator identification number if the generator site does not have an EPA

identification number. The U.S. EPA identification number is not required for

shipments of non-regulated waste or waste generated by a Very Small quantity

generators (VSQG). For shipments from VSQGs to facilities in Texas enter the State

abbreviation followed by the acronym VSQG e.g., TXVSQG.

ITEM 2 Enter the total number of pages used to complete the manifest. If a manifest

continuation sheet is not used, enter the number "1" in this section.

ITEM 3 Enter the emergency response telephone number as required by the DOT.

The emergency number must be placed after the shipping description or in another

prominent, readily identifiable, and clearly visible location if it applies to all

hazardous materials on the shipping paper. The prominent location on the manifest is

top enter of page 1. This number must be monitored at all times the hazardous

material is in the transportation system. The person answering the phone (or a person

immediately accessible) must have comprehensive emergency response and accident

mitigation information including but not limited to:

1. The basic shipping description and technical names,

2. Immediate hazards to health,

3. Risks of fire or explosion

4. Immediate precautions to be taken in the event of an accident or

spill.

5. Immediate methods for handling small or large fires.

6. Initial methods for handling spills or leaks in the absence of fires.

7. Preliminary first aid measures.

A telephone number that requires a call back (such as an answering service,

answering machine, or beeper device) does not meet the requirements. §172.604

This emergency response information must be cross referenced to the manifest and

maintained in the same manner on board the vehicle as the shipping paper. This

would typically be in the form of an SDS or printed current Emergency Response

Guidebook.

ITEM 4 Displays the preprinted manifest tracking number.

ITEM 5 Enter the generators name and mailing address and site address if different and phone

number.

ITEM 6 Enter the name and U.S. EPA identification number of the first transporter.


ITEM 7 If applicable, enter the name and U.S. EPA identification number of the second

transporter. If there are more than two transporters, use a continuation sheet.

ITEM 8 Enter the receiving facility's name, site address, phone number and U.S. EPA

identification number.

ITEM 9a If the wastes identified in Item 9b consist of both hazardous and nonhazardous

materials, then distinguish the hazardous materials by entering an "X" in the box next

to the corresponding hazardous material identified in Item 9b.

ITEM 9b Enter the proper shipping description including the shipping name, hazard class,

packing group, identification number and any applicable additional descriptors.

If additional space is needed for waste descriptions, enter these additional

descriptions in Item 27 on the Continuation Sheet (EPA Form 8700-22A). Number

these lines consecutively starting with the next consecutive number following the last

number from the previous page.

ITEM 10 Enter the number of containers for each waste and the appropriate abbreviation from

Table I (below) for the type of container.

Table I.-Types of Containers

Code Description

BA Burlap, cloth, paper, or plastic bags.

CF Fiber or plastic boxes, cartons, cases.

CM Metal boxes, cartons, cases (including roll-offs).

CW Wooden boxes, cartons, cases.

CY Cylinders.

DF Fiberboard or plastic drums, barrels, kegs.

DM Metal drums, barrels, kegs.

DT Dump truck.

DW Wooden drums, barrels, kegs.

HG Hopper or gondola cars.

TC Tank cars.

TP Portable tanks.

TT Cargo tanks (tank trucks).

ITEM 11 Enter, in designated boxes, the total quantity of waste. Round partial units to the

nearest whole unit, and do not enter decimals or fractions. To the extent practical,

report quantities using appropriate units of measure that will allow you to report

quantities with precision. Waste quantities entered should be based on actual

measurements or reasonably accurate estimates of actual quantities shipped.

Container capacities are not acceptable as estimates.

ITEM 12 Enter, in designated boxes, the appropriate abbreviation from Table II (below) for

the unit of measure.

Table II.-Units of Measure

Code Description

G Gallons (liquids only).

K Kilograms.

L Liters (liquids only).


Table II.-Units of Measure

Code Description

M Metric Tons (1000 kilograms).

N Cubic Meters.

P Pounds.

T Tons (2000 pounds).

Y Cubic Yards.

Note: Tons, Metric Tons, Cubic Meters, and Cubic Yards should only be reported

in connection with very large bulk shipments, such as rail cars, tank trucks, or

barges.

ITEM 13 Enter up to six federal and state waste codes to describe each waste stream

identified in Item 9b. State waste codes that are not redundant with federal codes

must be entered here, in addition to the federal waste codes which are most

representative of the properties of the waste. For waste shipped to Texas, enter

up to four RCRA Waste Codes and One Texas Waste Code per line.

ITEM 14

1. Generators may enter any special handling or shipment-specific information

necessary for the proper management or tracking of the materials under the

generator's or other handler's business processes, such as waste profile numbers,

container codes, bar codes, or response guide numbers. Generators also may use

this space to enter additional descriptive information about their shipped

materials, such as chemical names, constituent percentages, physical state, or

specific gravity of wastes identified with volume units in Item 12.

2. This space may be used to record limited types of federally required information

for which there is no specific space provided on the manifest, including any

alternate facility designations; the manifest tracking number of the original

manifest for rejected wastes and residues that are re-shipped under a second

manifest; and the specification of PCB waste descriptions and PCB out-of-service

dates required under 40 CFR 761.207. Generators, however, cannot be required to

enter information in this space to meet state regulatory requirements.

ITEM 15

1. The generator must read, sign, and date the waste minimization certification

statement. In signing the waste minimization certification statement, those

generators who have not been exempted by statute or regulation from the duty to

make a waste minimization certification under section 3002(b) of RCRA are also

certifying that they have complied with the waste minimization requirements.

The Generator's Certification also contains the required attestation that the

shipment has been properly prepared and is in proper condition for transportation

(the shipper's certification). The content of the shipper's certification statement is

as follows: "I hereby declare that the contents of this consignment are fully and

accurately described above by the proper shipping name, and are classified,

packaged, marked, and labeled/placarded, and are in all respects in proper


condition for transport by highway according to applicable international and

national governmental regulations.

When a party other than the generator prepares the shipment for transportation,

this party may also sign the shipper's certification statement as the offeror of the

shipment.

2. Generator or Offeror personnel may preprint the words, "On behalf of" in the

signature block or may hand write this statement in the signature block prior to

signing the generator/offeror certification, to indicate that the individual signs as

the employee or agent of the named principal.

ITEM 16. International Shipments

For export shipments, the primary exporter must check the export box, and enter

the point of exit (city and state) from the United States. For import shipments, the

importer must check the import box and enter the point of entry (city and state)

into the United States. For exports, the transporter must sign and date the manifest

to indicate the day the shipment left the United States. Transporters of hazardous

waste shipments must deliver a copy of the manifest to the U.S. Customs when

exporting the waste across U.S. borders.

ITEM 17 Enter the name of the first transporter accepting the waste. The transporter

acknowledges the acceptance of the waste described on the manifest by signing

and entering the date of receipt.

If applicable, complete for second transporter. Additional transporters may be

disclosed on continuation sheets.

Only one signature per transportation company is required. Signatures are not

required to track the movement of wastes in and out of transfer facilities, unless

there is a change of custody between transporters.

ITEM 18a This space must be completed by the disposal facility if there are any significant

discrepancies between the waste described on the manifest and the waste actually

received. Significant discrepancies include variation in piece count (10% for bulk

loads or 1 container for drum shipments) and variations of waste composition.

For rejected loads and residues, the TSDF will check the appropriate box if the

shipment is a rejected load (i.e., rejected by the designated and/or alternate facility

and is sent to an alternate facility or returned to the generator) or a regulated

residue that cannot be removed from a container. Enter the reason for the rejection

or the inability to remove the residue and a description of the waste. Also,

reference the manifest tracking number for any additional manifests being used to

track the rejected waste or residue shipment on the original manifest. Indicate the

original manifest tracking number in Item 14, the Special Handling Block and

Additional Information Block of the additional manifests.


ITEM 18b Alternate Facility (or Generator) for Receipt of Full Load Rejections

Enter the name, address, phone number, and EPA Identification Number of the

Alternate Facility which the rejecting TSDF has designated, after consulting with

the generator, to receive a fully rejected waste shipment. In the event that a fully

rejected shipment is being returned to the generator, the rejecting TSDF may enter

the generator's site information in this space. This field is not to be used to

forward partially rejected loads or residue waste shipments.

ITEM 18c Alternate Facility (or Generator) Signature

The authorized representative of the alternate facility (or the generator in the

event of a returned shipment) must sign and date this field of the form to

acknowledge receipt of the fully rejected wastes or residues identified by the

initial TSDF.

ITEM 19 Hazardous Waste Report Management Method Codes

Enter the most appropriate Hazardous Waste Report Management Method code

for each waste listed in Item 9. The Hazardous Waste Report Management

Method code is to be entered by the first treatment, storage, or disposal facility

(TSDF) that receives the waste and is the code that best describes the way in

which the waste is to be managed when received by the TSDF.

ITEM 20 Designated Facility Owner or Operator Certification of Receipt (Except as Noted

in Item 18a)

Enter the name of the person receiving the waste on behalf of the owner or

operator of the facility. That person must acknowledge receipt or rejection of the

waste described on the Manifest by signing and entering the date of receipt or

rejection where indicated. Since the Facility Certification acknowledges receipt of

the waste except as noted in the Discrepancy Space in Item 18a, the certification

should be signed for both waste receipt and waste rejection, with the rejection

being noted and described in the space provided in Item 18a. Fully rejected wastes

may be forwarded or returned using Item 18b after consultation with the

generator. Enter the name of the person accepting the waste on behalf of the

owner or operator of the alternate facility or the original generator. That person

must acknowledge receipt or rejection of the waste described on the Manifest by

signing and entering the date they received or rejected the waste in Item 18c.

Partially rejected wastes and residues must be re-shipped under a new manifest, to

be initiated and signed by the rejecting TSDF as offeror of the shipment.


NOTIFICATIONS FOR WASTE RESTRICTED FROM LAND DISPOSAL

A Notification for Waste Restricted from Land Disposal is required for shipments of hazard

waste identified in 40 CFR 268 that are restricted from land disposal.

A notification is only required to be submitted with the first shipment of the waste. Re-

notification would only be required if the waste was shipped to a different facility or a change in

the waste occurred which would cause a change in the treatment standard for the waste. NOTE:

Since this change, by the federal government, is considered less restrictive than current

regulations, the generator may still be required to submit a notification with each shipment.

Pursuant to 40 CFR 268.7(a), if the waste is restricted from land disposal, the notification must

include the following information:

1. The manifest document number associated with the first shipment of the waste. According

to Federal Regulations this is the generators USEPA Identification number plus the unique

five digit number assigned to the manifest by the generator. According to Texas Regulations,

this is the pre-printed number found in section A. of the manifest.

2. EPA hazardous waste number(s).

3. The appropriate subcategory if applicable. Subcategories are identified in column 2 of the

Treatment Standards Table (Appendix 9).

4. The constituents of concern for F001-F005 waste or characteristically hazardous waste

required to be treated for Underlying Hazardous Constituent.*

5. Whether the waste is a wastewater or a non-wastewater. Wastewaters are wastes that

contain less than 1% by weight Total Organic Carbon (TOC) and less than 1% by weight

Total Suspended Solids (TSS). Therefore, non-wastewaters contain more than either

1%TOC or TSS.*

6. Waste analysis data, when available.*

7. For contaminated soil subject to LDRs as provided in 268.49(a), the constituents subject to

treatment** as described in 268.49(d), and the following statement: This contaminated soil [

]does, or [ ]does not] contain listed hazardous waste and [ ] does, or [ ]does not exhibit a

characteristic of hazardous waste and [ ] is subject to, or [ ] complies with the soil treatment

standards as provided by §264.49(c) or the universal treatment standards.

8. In addition to the information required above, one of the following certification may also be

required.

Restricted Waste That Meets the Treatment Standards at the Point of Generation

I certify under penalty of law that I personally have examined and am familiar with the waste

through analysis and testing or through knowledge of the waste to support this certification

that the waste complies with the treatment standards specified in 40 CFR part 268 subpart D.

I believe that the information I submitted is true, accurate, and complete. I am aware that

there are significant penalties for submitting a false certification, including the possibility of


a fine and imprisonment.

Certification for the Alternative Lab Pack Treatment Standard

I certify under penalty of law that I personally have examined and am familiar with the waste

and that the lab pack contains only wastes that have not been excluded under appendix IV to

40 CFR part 268 and that this lab pack will be sent to a combustion facility in compliance

with the alternative treatment standards for lab packs at 40 CFR 268.42(c). I am aware that

there are significant penalties for submitting a false certification, including the possibility of

fine or imprisonment.

Certification for De-characterized Wastes Requiring Treatment for Underlying

Hazardous Constituents

I certify under penalty of law that the waste has been treated in accordance with the

requirements of 40 CFR 268.40 to remove the hazardous characteristic. This decharacterized

waste contains underlying hazardous constituents that require further treatment to meet

universal treatment standards. I am aware that there are significant penalties for submitting a

false certification, including the possibility of fine and imprisonment.

NOTE: Additional certifications are required for waste subject the land disposal restriction

treatment standards which have been treated to meet the treatment standards - see 40 CFR

268.7(a)(3), 268.7(b)(4), 268.7(d)(3).

* Items marked with an "*" are not required to be placed on a notification for waste which

is managed under the alternative lab pack treatment standard.

** For contaminated soil "Constituents subject to treatment means any constituent listed in

40 CFR 268.48, Table UTS - Universal Treatment Standards that are reasonable expected

to be present in any given volume of contaminated soil, except fluoride, selenium,

sulfides, vanadium, and zinc, and are present at concentrations greater than ten time the

universal treatment standard." 40 CFR 268.49(d)

California List Waste

The notification requirements for identifying California List waste were removed in the Phase IV

May 12, 1997 Federal Register; however, this change is also less restrictive than current

standards and cannot be omitted by the generator until their state agency adopts and is authorized

to implement the change.


PLACARDING

For Non Bulk Packaging Shipments

Once all manifests for a shipment of hazardous materials have been completed, the next step is to

determine how to placard the transport vehicle. To make this determination, reference 49 CFR

Part 172 Subpart F.

KEEP IT SIMPLE

IF THE HAZARD IS ON THE VEHICLE PLACARD FOR THE HAZARD

TABLE 1 PLACARDING RULE

1. Placard Any Quantity

If the vehicle contains any quantity of hazardous material identified in Table 1, placard for

that hazard.

TABLE 1

Category of material (Hazard class or division number and

additional description, as appropriate)

Placard Name Placard design

section

reference (§)

1.1

1.2

1.3

2.3

4.3

5.2 (Organic peroxide, Type B, liquid or solid, temperature controlled)

6.1 (PG I, inhalation hazard, Zone A and B)

7 (Radioactive Yellow III label only)

EXPLOSIVES 1.1

EXPLOSIVES 1.2

EXPLOSIVES 1.3

POISON GAS

DANGEROUS WHEN WET

ORGANIC PEROXIDE

POISON

RADIOACTIVE1

172.522

172.522

172.522

172.540

172.548

172.552

172.554

172.556

1RADIOACTIVE placard also required for exclusive use shipments of low specific activity material in accordance with 173.425 (b) or (c)

of this subchapter. [56 FR 66260, Dec. 20, 1991, effective Oct. 1, 1991]

2. Subsidiary Placarding Requirement

Placarding is based on the primary hazard. However, there are two subsidiary hazards that

will affect the required placarding on a vehicle. If the subsidiary hazard is an toxic

inhalation hazard in Zone A or B the subsidiary hazard and its primary hazard must be

placarded. If the subsidiary hazard is 4.3 you must placard for the subsidiary hazard

but are not required to placard for its primary hazard, unless the gross mass of the

primary hazard is over 2500 pounds.


TABLE 2 PLACARDING RULES

If the vehicle contains any of the hazardous material identified in Table 2, the following criteria

must be used to determine the correct placarding.

TABLE 2

Category of material (Hazard class or division number

and additional description, as appropriate)

Placard Name Placard design

section

reference (§)

1.4

1.5

1.6

2.1

2.2

3

Combustible liquid

4.1

4.2

5.1

5.2 (Other than Organic peroxide, Type B, Temp. Controlled)

6.1 (PG I or II, other than PG I inhalation hazard)

6.1 (PG III)

6.2

8

9

ORM-D

EXPLOSIVE 1.4

EXPLOSIVE 1.5

EXPLOSIVE 1.6

FLAMMABLE GAS

NON-FLAMMABLE GAS

FLAMMABLE

COMBUSTIBLE

FLAMMABLE SOLID

SPONTANEOUSLY COMBUSTIBLE

OXIDIZER

ORGANIC PEROXIDE

POISON

KEEP AWAY FROM FOOD

(None)

CORROSIVE

CLASS 9 (See §172.504(f)(9))

(None)

172.523

172.524

172.525

172.532

172.528

172.542

172.544

172.546

172.547

172.550

172.552

172.554

172.553

172.558

172.560

1. Bulk Packaging

If any of the material identified in Table 2 is contained within a bulk packaging, the vehicle

must be placarded for the specific primary hazard.

2. Add up the weights of all hazardous material in non-bulk packaging shown on Table 2.

If the weight of all Table 2 material, in non-bulk packaging is less than 1001 pounds, no

Table 2 placards or the Dangerous placard is required.

If the weight of all Table 2 hazardous material, in non-bulk packaging, exceeds 1001 pounds,

all material offered for transportation must be “represented” by a placard. This means that

the shipper may be able to use a dangerous placard or they may be required to display

placard(s) for specific hazards.

3. Add Up the Aggregate Gross Weights for Each Primary Hazard Class or Division

Determine the aggregate gross weight (i.e., weight of the hazardous material and packaging)

for each individual primary hazard class in non-bulk packaging identified in Table 2.

4. Shipper Offers 1,001 Pounds of Only One Hazard Class or Division

If the shipper offers only one hazardous class or division in non-bulk packaging, from Table

2 and the quantity equals or exceeds 1,001 pounds, the specific placard for that hazard must

be displayed.


5. Any Single Primary Hazard Class Over 2,205 Pounds

If the shipper offers 2,205 pounds or more of any individual hazard class, the specific placard

for that hazard must be properly displayed.

6. Two of More Hazard Classes Each Less Than 2,205 Pounds

If the shipper offers two or more hazard classes or divisions from Table 2 in non-bulk

packaging and each individual hazard class or division is less than 2,205 pounds, a

“DANGEROUS PLACARD” may be used in place of specific placards. 49 CFR 172.504(b)

7. Additional Responsibility for the Carrier (AKA: The Transporter)

After properly placarding as described above for individual shippers, if the carrier collects

hazardous material from more than one shipper, additional SPECIFIC or DANGEROUS

placards may be required.

Once the aggregate gross weight of all Table 2 material in non-bulk packaging from multiple

pick-ups equals or exceeds 1001 pounds all hazardous materials on the vehicle must be

“represented” by a placard, even if each individual shipper offered less than 1001 pounds

of hazardous material.

If there are two or more hazard classes or divisions in non-bulk packaging from Table 2 that

have not already been placarded (i.e., not already required), a DANGEROUS placard may be

used.

If there is only one hazard class or division in the vehicle and the vehicle is not already

placarded (e.g., multiple shippers offered less than 1001 pounds of Class 3 material in non-

bulk packaging) the specific placard for that hazard must be displayed.

Example 1: The shipper offers 900 pounds of Class 3 and 500 pounds of a Class 8. In this

case, the combined weights of all Table 2 hazardous material exceeds 1001

pounds so all hazardous material offered for transportation must be

represented by a placard. Since neither hazard class exceeds 2,205 pounds,

DANGEROUS placards could be used. The shipper could have also used

Flammable Liquid and Corrosive placards.

Example 2: The shipper offers 3000 pounds of Class 3 and 500 pounds of Class 8. In this

case the shipper must placard FLAMMABLE LIQUID because the quantity of

Class 3 exceeds 2205 pounds. Since the shipper offered more than 1001

pounds of hazardous material, all hazardous material must be represented by a

placard. A DANGEROUS placard cannot be used because this placard must

represent two or more hazards. In this scenario we only have one hazard left

to placard. Since there is only one more placard needed you should display

the specific CORROSIVE placard rather than the DANGEROUS placard.


AFFIXING PLACARDS

Each placard required must be placed on each side and each end of the vehicle.

EMPTY CONTAINERS

Weights of empty non-bulk packagings that contain only residue of a hazardous material from

Table 2 need not be included in determining placarding requirements.

ADDITIONAL PLACARDING EXCEPTIONS

1. If a transport vehicle has been properly placarded “Flammable Gas” or ‘Oxygen”, a Non-

Flammable Gas” placard is not required. 172.504(f)(3)

2. For domestic transportation of oxygen, compressed or oxygen, refrigerated liquid, the

OXYGEN placard in §172.530 of this subpart may be used in place of a

NON-FLAMMABLE GAS placard.172.504(f)(7)

3. For domestic transportation, a POISON INHALATION HAZARD placard is not required on

a transport vehicle or freight container that is already placarded with the POISON GAS

placard.172.504(f)(8)

4. Class 9 placards are not required for domestic transportation; however, bulk packages of

class 9 material must display the identification number. Remember, one method of

displaying the identification number is on a placard. §172.504(f)(9).

5. For Division 6.1, PG III materials, a POISON placard may be modified to display the text

"PG III" below the mid line of the placard.172.504(f)(10)

PROHIBITED PLACARDING

1. It is a violation of the Hazardous Materials Regulations to affix a placard to a transport

vehicle that does not contain a hazardous material represented by that placard. §172.502(a)

2. You may no longer affix to a package or transport vehicle any sign, advertisement, slogan

(such as Drive safely) or device that, by its color, design, shape or content, could be confused

with any placard prescribed in this subpart. §172.502(a)(2) This prohibited form of

placarding is not mandatory until October 1, 2001 if the safety sign was permanently marked

on a transport vehicle on or before August 21, 1997. §172.502(b)(3).

3. A subsidiary placard must also display the hazard class or division number.


HAZMAT SECURITY PLANS

172.800 Purpose and applicability.

This purpose of the Hazmat Security Plan is to address security risks related to the transportation

of hazardous materials in commerce.

By September 25, 2003, each person who offers for transportation in commerce or transports in

commerce one or more of the following hazardous materials must develop and adhere to a

security plan for hazardous materials. This list of hazardous materials requiring a security plan

was revised and became effective October 1, 2010. The term “large bulk quantity” in the

following table means than 3,000 kg (6,614 pounds) for solids or 3,000 liters (792 gallons) for

liquids and gases in a single packaging.

Class or

Division

Quantity Requiring Security Plan

1.1 Any quantity.

1.2 Any quantity.

1.3 Any quantity.

1.4 Placarded quantity.



2.1 A large bulk quantity.

2.2 A large bulk quantity of materials with an oxidizer subsidiary.

2.3 Any quantity.

3 PG I and II A large bulk quantity; placarded quantity desensitized explosives.

4.1 Placarded quantity desensitized explosives.

4.2 PGI and II A large bulk quantity.

4.3 Any quantity.

5.1 Division 5.1 materials in PG I and II, and PG III perchlorates, ammonium nitrate, ammonium

nitrate fertilizers, or ammonium nitrate emulsions or suspensions or gels in a large bulk

quantity.

5.2 Any quantity of Organic peroxide, Type B, liquid or solid, temperature controlled.

6.1 Any quantity PIH or a large bulk quantity of a material that is not a PIH.

6.2 CDC or USDA list of select agents.

7 IAEA Categories 1 & 2; HRCQ; known radionuclides in forms listed as RAM–QC by NRC; or

a quantity of uranium hexafluoride requiring placarding under § 172.505(b).

8 A large bulk quantity.

Components of a security plan. 49 CFR 172.802

The security plan must include an assessment of possible transportation security risks for

shipments of the hazardous materials listed above and appropriate measures to address the

assessed risks. Specific measures put into place by the plan may vary commensurate with the

level of threat at a particular time. At a minimum, a security plan must include the following

elements:

(1) Personnel security. Measures to confirm information provided by job applicants hired for

positions that involve access to and handling of the hazardous materials covered by the

security plan. Such confirmation system must be consistent with applicable Federal and State

laws and requirements concerning employment practices and individual privacy.


(2) Unauthorized access. Measures to address the assessed risk that unauthorized persons may

gain access to the hazardous materials covered by the security plan or transport conveyances

being prepared for transportation of the hazardous materials covered by the security plan.

(3) En route security. Measures to address the assessed security risks of shipments of hazardous

materials covered by the security plan en route from origin to destination, including

shipments stored incidental to movement.

The security plan must be in writing and must be retained for as long as it remains in effect.

Copies of the security plan, or portions thereof, must be available to the employees who are

responsible for implementing it, consistent with personnel security clearance or background

investigation restrictions and a demonstrated need to know. The security plan must be revised

and updated as necessary to reflect changing circumstances. When the security plan is updated or

revised, all copies of the plan must be maintained as of the date of the most recent revision.

Training 49 CFR 172.704(a)(4) and (5).

Security awareness training.

No later than the date of the first scheduled recurrent training after March 25, 2003, and in no

case later than March 24, 2006, each hazmat employee must receive training that provides an

awareness of security risks associated with hazardous materials transportation and methods

designed to enhance transportation security. This training must also include a component

covering how to recognize and respond to possible security threats. After March 25, 2003, new

hazmat employees must receive the security awareness training required by this paragraph within

90 days after employment.

In-depth security training.

By December 22, 2003, each hazmat employee of a person required to have a security plan must

be trained concerning the security plan and its implementation. Security training must include

company security objectives, specific security procedures, employee responsibilities, actions to

take in the event of a security breach, and the organizational security structure.

APPENDIX 1

HAZARDOUS WASTE CLASSIFICATION

Site Topic Page

40 CFR 261.1 Purpose and Scope ........................................................................................ A1-1

40 CFR 261.2 Solid Waste Definition ................................................................................... A1-3

40 CFR 261.3 Hazardous Waste Definition .......................................................................... A1-6

40 CFR 261.4(a) Exclusions from Solid Waste Definition .................................................... A1-13

40 CFR 261.4(b) Exclusions from Hazardous Waste Definition ........................................... A1-25

40 CFR 261.4(d) Samples ........................................................................................................ A1-30

40 CFR 261.5 Removed and replaced CESQG to 262.14 .................................................. A1-35

40 CFR 261.6 Recyclable Materials .................................................................................... A1-35

40 CFR 261.7 Residues of Hazardous Waste in Empty Containers ................................. A1-38

40 CFR 261.9 Universal Waste ........................................................................................... A1-40

40 CFR 261.21 Characteristic of Ignitability (D001) ............................................................ A1-40

40 CFR 261.22 Characteristic of Corrosivity (D002) ............................................................ A1-41

40 CFR 261.23 Characteristic of Reactivity (D003) .............................................................. A1-42

40 CFR 261.24 Toxicity Characteristic (D004 - D043) ......................................................... A1-42

40 CFR 261.31 Hazardous waste from Non-specific Sources (F-Codes) .......................... A1-44

40 CFR 261.32 Hazardous Waste from Specific Sources (K-Codes) ................................. A1-49

40 CFR 261.33 Commercial Chemical Products (U and P-Codes) ..................................... A1-60

SET Environmental, Inc. A1-1 40 CFR §261.20 - §261.33

Characteristics and Lists of Hazardous Wastes Last Revision: December 9, 2019

40 CFR Subpart A—General

§261.1 Purpose and scope.

(a) This part identifies those solid wastes which are subject to regulation as hazardous wastes under parts 262

through 265, 268, and parts 270, 271, and 124 of this chapter and which are subject to the notification

requirements of section 3010 of RCRA. In this part:

(1) Subpart A defines the terms ``solid waste'' and ``hazardous waste'', identifies those wastes which are

excluded from regulation under parts 262 through 266, 268 and 270 and establishes special management

requirements for hazardous waste produced by conditionally exempt small quantity generators and

hazardous waste which is recycled.

(2) Subpart B sets forth the criteria used by EPA to identify characteristics of hazardous waste and to list

particular hazardous wastes.

(3) Subpart C identifies characteristics of hazardous waste.

(4) Subpart D lists particular hazardous wastes.

(b) (1) The definition of solid waste contained in this part applies only to wastes that also are hazardous for

purposes of the regulations implementing subtitle C of RCRA. For example, it does not apply to materials (such

as non-hazardous scrap, paper, textiles, or rubber) that are not otherwise hazardous wastes and that are recycled.

(2) This part identifies only some of the materials which are solid wastes and hazardous wastes under sections

3007, 3013, and 7003 of RCRA. A material which is not defined as a solid waste in this part, or is not a

hazardous waste identified or listed in this part, is still a solid waste and a hazardous waste for purposes of

these sections if:

(i) In the case of sections 3007 and 3013, EPA has reason to believe that the material may be a solid waste

within the meaning of section 1004(27) of RCRA and a hazardous waste within the meaning of section

1004(5) of RCRA; or

(ii) In the case of section 7003, the statutory elements are established.

(c) For the purposes of §§261.2 and 261.6:

(1) A ``spent material'' is any material that has been used and as a result of contamination can no longer serve

the purpose for which it was produced without processing;

(2) ``Sludge'' has the same meaning used in §260.10 of this chapter;

(3) A ``by-product'' is a material that is not one of the primary products of a production process and is not

solely or separately produced by the production process. Examples are process residues such as slags or

distillation column bottoms. The term does not include a co-product that is produced for the general

public's use and is ordinarily used in the form it is produced by the process.

(4) A material is ``reclaimed'' if it is processed to recover a usable product, or if it is regenerated. Examples are

recovery of lead values from spent batteries and regeneration of spent solvents.

(5) A material is `ùsed or reused'' if it is either:

(i) Employed as an ingredient (including use as an intermediate) in an industrial process to make a

product (for example, distillation bottoms from one process used as feedstock in another process).

However, a material will not satisfy this condition if distinct components of the material are recovered

as separate end products (as when metals are recovered from metal-containing secondary materials); or

(ii) Employed in a particular function or application as an effective substitute for a commercial product

(for example, spent pickle liquor used as phosphorous precipitant and sludge conditioner in wastewater



treatment).

(6) ``Scrap metal'' is bits and pieces of metal parts (e.g.,) bars, turnings, rods, sheets, wire) or metal pieces that

may be combined together with bolts or soldering (e.g., radiators, scrap automobiles, railroad box cars),

which when worn or superfluous can be recycled.

(7) A material is ``recycled'' if it is used, reused, or reclaimed.

(8) A material is `àccumulated speculatively'' if it is accumulated before being recycled. A material is not

accumulated speculatively, however, if the person accumulating it can show that the material is potentially

recyclable and has a feasible means of being recycled; and that-during the calendar year (commencing on

January 1)-the amount of material that is recycled, or transferred to a different site for recycling, equals at

least 75 percent by weight or volume of the amount of that material accumulated at the beginning of the

period. In calculating the percentage of turnover, the 75 percent requirement is to be applied to each

material of the same type (e.g., slags from a single smelting process) that is recycled in the same way (i.e.,

from which the same material is recovered or that is used in the same way). Materials accumulating in units

that would be exempt from regulation under §261.4(c) are not to be included in making the calculation.

(Materials that are already defined as solid wastes also are not to be included in making the calculation.)

Materials are no longer in this category once they are removed from accumulation for recycling, however.

(9) `Èxcluded scrap metal'' is processed scrap metal, unprocessed home scrap metal, and unprocessed prompt

scrap metal.

(10) ̀ `Processed scrap metal'' is scrap metal which has been manually or physically altered to either separate it

into distinct materials to enhance economic value or to improve the handling of materials. Processed scrap

metal includes, but is not limited to scrap metal which has been baled, shredded, sheared, chopped,

crushed, flattened, cut, melted, or separated by metal type (i.e., sorted), and, fines, drosses and related

materials which have been agglomerated. (Note: shredded circuit boards being sent for recycling are not

considered processed scrap metal. They are covered under the exclusion from the definition of solid waste

for shredded circuit boards being recycled (§261.4(a)(14)).

(11) ̀ `Home scrap metal'' is scrap metal as generated by steel mills, foundries, and refineries such as turnings,

cuttings, punchings, and borings.

(12) ̀ `Prompt scrap metal'' is scrap metal as generated by the metal working/fabrication industries and includes

such scrap metal as turnings, cuttings, punchings, and borings. Prompt scrap is also known as industrial or

new scrap metal.



261.2 Definition of solid waste.

(a) (1) A solid waste is any discarded material that is not excluded by §261.4 (a) or that is not excluded by

variance granted under §§260.30 and 260.31.

(2) A discarded material is any material which is:

(i) Abandoned, as explained in paragraph (b) of this section; or

(ii) Recycled, as explained in paragraph (c) of this section; or

(iii) Considered inherently waste-like, as explained in paragraph (d) of this section; or

(iv) A military munition identified as a solid waste in 40 CFR 266.202.

(b) Materials are solid waste if they are abandoned by being:

(1) Disposed of; or

(2) Burned or incinerated; or

(3) Accumulated, stored, or treated (but not recycled) before or in lieu of being abandoned by being

disposed of, burned, or incinerated.

(c) Materials are solid wastes if they are recycled or accumulated, stored, or treated before recycling as

specified in paragraphs (c)(1) through (4) of this section.

(1) Used in a manner constituting disposal.

(i) Materials noted with a ``*'' in Column 1 of Table I are solid wastes when they are:

(A) Applied to or placed on the land in a manner that constitutes disposal; or

(B) Used to produce products that are applied to or placed on the land or are otherwise contained

in products that are applied to or placed on the land (in which cases the product itself remains

a solid waste).

(ii) However, commercial chemical products listed in §261.33 are not solid wastes if they are applied

to the land and that is their ordinary manner of use.

(2) Burning for energy recovery.

(i) Materials noted with a ``*'' in column 2 of Table 1 are solid wastes when they are:

(A) Burned to recover energy;

(B) Used to produce a fuel or are otherwise contained in fuels (in which cases the fuel itself

remains a solid waste).

(ii) However, commercial chemical products listed in §261.33 are not solid wastes if they are

themselves fuels.

(3) Reclaimed. Materials noted with a "*" in column 3 of Table 1 are solid wastes when reclaimed (except

as provided under 40 CFR §261.4(a)(15)). Materials noted with a " - " in column 3 of Table 1 are not

solid wastes when reclaimed.

(4) Accumulated speculatively. Materials noted with a ``*'' in column 4 of Table 1 are solid wastes when

accumulated speculatively.



TABLE 1

Use

constituting

disposal

§261.2(c)(1)

Energy

Recovery/fu

el

§261.2(c)(2)

Reclamation

(§261.2(c)(3))

(except as

provided in

261.4(a)(17) for

mineral

processing

secondary

materials)

Speculative

Acccumulatio

n

§261.1(c)(3)

Spent Materials * * * *

Sludges (listed in §261.31 or §261.32) * * * *

Sludges exhibiting the characteristic of a

hazardous waste * * - *

By-products (listed in §261.31 or §261.32) * * * *

By-products exhibiting a characteristic of

hazardous waste * * - *

Commercial chemical products listed in

261.33 * * - -

Scrap metal that is not excluded under

§261.4(a)(13) * * * *

Note: The terms "spent materials," "sludges," "by-products," and "scrap metal" and "processed scrap metal" are

defined in § 261.1.

(d) Inherently waste-like materials. The following materials are solid wastes when they are recycled in any manner:

(1) Hazardous Waste Nos. F020, F021 (unless used as an ingredient to make a product at the site of

generation), F022, F023, F026, and F028.

(2) Secondary materials fed to a halogen acid furnace that exhibit a characteristic of a hazardous waste or are

listed as a hazardous waste as defined in subparts C or D of this part, except for brominated material that

meets the following criteria:

(i) The material must contain a bromine concentration of at least 45%; and

(ii) The material must contain less than a total of 1% of toxic organic compounds listed in appendix VIII;

and

(iii) The material is processed continually on-site in the halogen acid furnace via direct conveyance (hard

piping).

(3) The Administrator will use the following criteria to add wastes to that list:

(i) (A) The materials are ordinarily disposed of, burned, or incinerated; or

(B) The materials contain toxic constituents listed in appendix VIII of part 261 and these constituents

are not ordinarily found in raw materials or products for which the materials substitute (or are

found in raw materials or products in smaller concentrations) and are not used or reused during the

recycling process; and

(ii) The material may pose a substantial hazard to human health and the environment when recycled.

(e) Materials that are not solid waste when recycled.

(1) Materials are not solid wastes when they can be shown to be recycled by being:

(i) Used or reused as ingredients in an industrial process to make a product, provided the materials are not



being reclaimed; or

(ii) Used or reused as effective substitutes for commercial products; or

(iii) In cases where the materials are generated and reclaimed within the primary mineral processing

industry, the conditions of the exclusion found at § 261.4(a)(15) apply rather than this provision.

(2) The following materials are solid wastes, even if the recycling involves use, reuse, or return to the original

process (described in paragraphs (e)(1) (i) through (iii) of this section):

(i) Materials used in a manner constituting disposal, or used to produce products that are applied to the

land; or

(ii) Materials burned for energy recovery, used to produce a fuel, or contained in fuels; or

(iii) Materials accumulated speculatively; or

(iv) Materials listed in paragraphs (d)(1) and (d)(2) of this section.

(f) Documentation of claims that materials are not solid wastes or are conditionally exempt from regulation.

Respondents in actions to enforce regulations implementing Subtitle C of RCRA who raise a claim that a

certain material is not a solid waste, or is conditionally exempt from regulation, must demonstrate that there is a

known market or disposition for the material, and that they meet the terms of the exclusion or exemption. In

doing so, they must provide appropriate documentation (such as contracts showing that a second person uses the

material as an ingredient in a production process) to demonstrate that the material is not a waste, or is exempt

from regulation. In addition, owners or operators of facilities claiming that they actually are recycling materials

must show that they have the necessary equipment to do so.



261.3 Definition of hazardous waste.

(a) A solid waste, as defined in § 261.2, is a hazardous waste if:

(1) It is not excluded from regulation as a hazardous waste under § 261.4 (b); and

(2) It meets any of the following criteria:

(i) It exhibits any of the characteristics of hazardous waste identified in subpart C of this part. However,

any mixture of a waste from the extraction, beneficiation, and processing of ores and minerals

excluded under § 261.4(b)(7) and any other solid waste exhibiting a characteristic of hazardous waste

under subpart C is a hazardous waste only if it exhibits a characteristic that would not have been

exhibited by the excluded waste alone if such mixture had not occurred, or if it continues to exhibit any

of the characteristics exhibited by the non-excluded wastes prior to mixture. Further, for the purposes

of applying the Toxicity Characteristic to such mixtures, the mixture is also a hazardous waste if it

exceeds the maximum concentration for any contaminant listed in table I to § 261.24 that would not

have been exceeded by the excluded waste alone if the mixture had not occurred or if it continues to

exceed the maximum concentration for any contaminant exceeded by the nonexempt waste prior to

mixture.

(ii) It is listed in subpart D of this part and has not been excluded from the lists in subpart D of this part

under §§ 260.20 and 260.22 of this chapter.

(iii) [Reserved]

(iv) It is a mixture of solid waste and one or more hazardous wastes listed in subpart D of this part and has

not been excluded from paragraph (a)(2) of this section under 40 CFR 260.20 and 260.22, paragraph

(g) of this section, or paragraph (h) of this section; however, the following mixtures of solid wastes and

hazardous wastes listed in subpart D of this part are not hazardous wastes (except by application of

paragraph (a)(2)(i) or (ii) of this section) if the generator can demonstrate that the mixture consistsof

wastewater the discharge of which is subject to regulation under either section 402 or section 307(b) of

the Clean Water Act (including wastewater at facilities which have eliminated the discharge of

wastewater) and;

(A) One or more of the following spent solvents listed in § 261.31-benzene, carbon tetrachloride,

tetrachloroethylene, trichloroethylene or the scrubber waters derived-from the combustion of these

spent solvents-Provided, That the maximum total weekly usage of these solvents (other than the

amounts that can be demonstrated not to be discharged to wastewater) divided by the average

weekly flow of wastewater into the headworks of the facility's wastewater treatment or

pretreatment system does not exceed 1 part per million, OR the total measured concentration of

these solvents entering the headworks of the facility's wastewater treatment system (at facilities

subject to regulation under the Clean Air Act, as amended, at 40 CFR parts 60, 61, or 63, or at

facilities subject to an enforceable limit in a federal operating permit that minimizes fugitive

emissions), does not exceed 1 part per million on an average weekly basis. Any facility that uses

benzene as a solvent and claims this exemption must use an aerated biological wastewater

treatment system and must use only lined surface impoundments or tanks prior to secondary

clarification in the wastewater treatment system. Facilities that choose to measure concentration

levels must file a copy of their sampling and analysis plan with the Regional Administrator, or

State Director, as the context requires, or an authorized representative ("Director" as defined in 40

CFR 270.2). A facility must file a copy of a revised sampling and analysis plan only if the initial

plan is rendered inaccurate by changes in the facility's operations. The sampling and analysis plan

must include the monitoring point location (headworks), the sampling frequency and

methodology, and a list of constituents to be monitored. A facility is eligible for the direct

monitoring option once they receive confirmation that the sampling and analysis plan has been

received by the Director. The Director may reject the sampling and analysis plan if he/she finds

that, the sampling and analysis plan fails to include the above information; or the plan parameters

would not enable the facility to calculate the weekly average concentration of these chemicals

accurately. If the Director rejects the sampling and analysis plan or if the Director finds that the

facility is not following the sampling and analysis plan, the Director shall notify the facility to



cease the use of the direct monitoring option until such time as the bases for rejection are

corrected; or

(B) One or more of the following spent solvents listed in § 261.31-methylene chloride, 1,1,1-

trichloroethane, chlorobenzene, o-dichlorobenzene, cresols, cresylic acid, nitrobenzene, toluene,

methyl ethyl ketone, carbon disulfide, isobutanol, pyridine, spent chlorofluorocarbon solvents, 2-

ethoxyethanol, or the scrubber waters derived-from the combustion of these spent solvents-

Provided That the maximum total weekly usage of these solvents (other than the amounts that can

be demonstrated not to be discharged to wastewater) divided by the average weekly flow of

wastewater into the headworks of the facility's wastewater treatment or pretreatment system does

not exceed 25 parts per million, OR the total measured concentration of these solvents entering the

headworks of the facility's wastewater treatment system (at facilities subject to regulation under

the Clean Air Act as amended, at 40 CFR parts 60, 61, or 63, or at facilities subject to an

enforceable limit in a federal operating permit that minimizes fugitive emissions), does not exceed

25 parts per million on an average weekly basis. Facilities that choose to measure concentration

levels must file a copy of their sampling and analysis plan with the Regional Administrator, or

State Director, as the context requires, or an authorized representative ("Director" as defined in 40

CFR 270.2). A facility must file a copy of a revised sampling and analysis plan only if the initial

plan is rendered inaccurate by changes in the facility's operations. The sampling and analysis plan

must include the monitoring point location (headworks), the sampling frequency and

methodology, and a list of constituents to be monitored. A facility is eligible for the direct

monitoring option once they receive confirmation that the sampling and analysis plan has been

received by the Director. The Director may reject the sampling and analysis plan if he/she finds

that, the sampling and analysis plan fails to include the above information; or the plan parameters

would not enable the facility to calculate the weekly average concentration of these chemicals

accurately. If the Director rejects the sampling and analysis plan or if the Director finds that the

facility is not following the sampling and analysis plan, the Director shall notify the facility to

cease the use of the direct monitoring option until such time as the bases for rejection are

corrected; or

(C) One of the following wastes listed in § 261.32, provided that the wastes are discharged to the

refinery oil recovery sewer before primary oil/water/solids separation - heat exchanger bundle

cleaning sludge from the petroleum refining industry (EPA Hazardous Waste No. K050), crude oil

storage tank sediment from petroleum refining operations (EPA Hazardous Waste No. K169),

clarified slurry oil tank sediment and/or in-line filter/separation solids from petroleum refining

operations (EPA Hazardous Waste No. K170), spent hydrotreating catalyst (EPA Hazardous

Waste No. K171), and spent hydrorefining catalyst (EPA Hazardous Waste No. K172); or

(D) A discarded hazardous waste, commercial chemical product, or chemical intermediate listed in § §

261.31 through 261.33, arising from de minimis losses of these materials. For purposes of this

paragraph (a)(2)(iv)(D), de minimis losses are inadvertent releases to a wastewater treatment

system, including those from normal material handling operations (e.g., spills from the unloading

or transfer of materials from bins or other containers, leaks from pipes, valves or other devices

used to transfer materials); minor leaks of process equipment, storage tanks or containers; leaks

from well maintained pump packings and seals; sample purgings; relief device discharges;

discharges from safety showers and rinsing and cleaning of personal safety equipment; and rinsate

from empty containers or from containers that are rendered empty by that rinsing. Any

manufacturing facility that claims an exemption for de minimis quantities of wastes listed in § §

261.31 through 261.32, or any nonmanufacturing facility that claims an exemption for de minimis

quantities of wastes listed in subpart D of this part must either have eliminated the discharge of

wastewaters or have included in its Clean Water Act permit application or submission to its

pretreatment control authority the constituents for which each waste was listed (in 40 CFR 261

appendix VII) of this part; and the constituents in the table "'Treatment Standards for Hazardous

Wastes"' in 40 CFR 268.40 for which each waste has a treatment standard (i.e., Land Disposal

Restriction constituents). A facility is eligible to claim the exemption once the permit writer or

control authority has been notified of possible de minimis releases via the Clean Water Act permit

application or the pretreatment control authority submission. A copy of the Clean Water permit

application or the submission to the pretreatment control authority must be placed in the facility's

on-site files; or



(E) Wastewater resulting from laboratory operations containing toxic (T) wastes listed in Subpart D of

this part, Provided, That the annualized average flow of laboratory wastewater does not exceed

one percent of total wastewater flow into the headworks of the facility's wastewater treatment or

pre-treatment system, or provided the wastes, combined annualized average concentration does

not exceed one part per million in the headworks of the facility's wastewater treatment or

pre-treatment facility. Toxic (T) wastes used in laboratories that are demonstrated not to be

discharged to wastewater are not to be included in this calculation; or

(F) One or more of the following wastes listed in § 261.32-wastewaters from the production of

carbamates and carbamoyl oximes (EPA Hazardous Waste No. K157)-Provided that the maximum

weekly usage of formaldehyde, methyl chloride, methylene chloride, and triethylamine (including

all amounts that cannot be demonstrated to be reacted in the process, destroyed through treatment,

or is recovered, i.e., what is discharged or volatilized) divided by the average weekly flow of

process wastewater prior to any dilution into the headworks of the facility's wastewater treatment

system does not exceed a total of 5 parts per million by weight OR the total measured

concentration of these chemicals entering the headworks of the facility's wastewater treatment

system (at facilities subject to regulation under the Clean Air Act as amended, at 40 CFR parts 60,

61, or 63, or at facilities subject to an enforceable limit in a federal operating permit that

minimizes fugitive emissions), does not exceed 5 parts per million on an average weekly basis.

Facilities that choose to measure concentration levels must file copy of their sampling and analysis

plan with the Regional Administrator, or State Director, as the context requires, or an authorized

representative ("Director" as defined in 40 CFR 270.2). A facility must file a copy of a revised

sampling and analysis plan only if the initial plan is rendered inaccurate by changes in the

facility's operations. The sampling and analysis plan must include the monitoring point location

(headworks), the sampling frequency and methodology, and a list of constituents to be monitored.

A facility is eligible for the direct monitoring option once they receive confirmation that the

sampling and analysis plan has been received by the Director. The Director may reject the

sampling and analysis plan if he/she finds that, the sampling and analysis plan fails to include the

above information; or the plan parameters would not enable the facility to calculate the weekly

average concentration of these chemicals accurately. If the Director rejects the sampling and

analysis plan or if the Director finds that the facility is not following the sampling and analysis

plan, the Director shall notify the facility to cease the use of the direct monitoring option until

such time as the bases for rejection are corrected; or

(G) Wastewaters derived-from the treatment of one or more of the following wastes listed in §

261.32-organic waste (including heavy ends, still bottoms, light ends, spent solvents, filtrates, and

decantates) from the production of carbamates and carbamoyl oximes (EPA Hazardous Waste No.

K156).-Provided, that the maximum concentration of formaldehyde, methyl chloride, methylene

chloride, and triethylamine prior to any dilutions into the headworks of the facility's wastewater

treatment system does not exceed a total of 5 milligrams per liter OR the total measured

concentration of these chemicals entering the headworks of the facility's wastewater treatment

system (at facilities subject to regulation under the Clean Air Act as amended, at 40 CFR parts 60,

61, or 63, or at facilities subject to an enforceable limit in a federal operating permit that

minimizes fugitive emissions), does not exceed 5 milligrams per liter on an average weekly basis.

Facilities that choose to measure concentration levels must file copy of their sampling and analysis

plan with the Regional Administrator, or State Director, as the context requires, or an authorized

representative ("Director" as defined in 40 CFR 270.2). A facility must file a copy of a revised

sampling and analysis plan only if the initial plan is rendered inaccurate by changes in the

facility's operations. The sampling and analysis plan must include the monitoring point location

(headworks), the sampling frequency and methodology, and a list of constituents to be monitored.

A facility is eligible for the direct monitoring option once they receive confirmation that the

sampling and analysis plan has been received by the Director. The Director may reject the

sampling and analysis plan if he/she finds that, the sampling and analysis plan fails to include the

above information; or the plan parameters would not enable the facility to calculate the weekly

average concentration of these chemicals accurately. If the Director rejects the sampling and

analysis plan or if the Director finds that the facility is not following the sampling and analysis

plan, the Director shall notify the facility to cease the use of the direct monitoring option until

such time as the bases for rejection are corrected.



(v) Rebuttable presumption for used oil. Used oil containing more than 1000 ppm total halogens is

presumed to be a hazardous waste because it has been mixed with halogenated hazardous waste listed

in subpart D of part 261 of this chapter. Persons may rebut this presumption by demonstrating that the

used oil does not contain hazardous waste (for example, by using an analytical method from SW-846,

Third Edition, to show that the used oil does not contain significant concentrations of halogenated

hazardous constituents listed in appendix VIII of part 261 of this chapter). EPA Publication SW-846,

Third Edition, is available for the cost of $110.00 from the Government Printing Office,

Superintendent of Documents, PO Box 371954, Pittsburgh, PA 15250-7954. 202-783-3238 (document

number 955-001-00000-1).

(A) The rebuttable presumption does not apply to metalworking oils/fluids containing chlorinated

paraffins, if they are processed, through a tolling agreement, to reclaim metalworking oils/fluids.

The presumption does apply to metalworking oils/fluids if such oils/fluids are recycled in any

other manner, or disposed.

(B) The rebuttable presumption does not apply to used oils contaminated with chlorofluorocarbons

(CFCs) removed from refrigeration units where the CFCs are destined for reclamation. The

rebuttable presumption does apply to used oils contaminated with CFCs that have been mixed

with used oil from sources other than refrigeration units.

(b) A solid waste which is not excluded from regulation under paragraph (a)(1) of this section becomes a hazardous

waste when any of the following events occur:

(1) In the case of a waste listed in Subpart D of this part, when the waste first meets the listing description set

forth in subpart D of this part.

(2) In the case of a mixture of solid waste and one or more listed hazardous wastes, when a hazardous waste

listed in subpart D is first added to the solid waste.

(3) In the case of any other waste (including a waste mixture), when the waste exhibits any of the

characteristics identified in subpart C of this part.

(c) Unless and until it meets the criteria of paragraph (d) of this section:

(1) A hazardous waste will remain a hazardous waste.

(2) (i) Except as otherwise provided in paragraph (c)(2)(ii), (g) or (h) of this section, any solid waste

generated from the treatment, storage, or disposal of a hazardous waste, including any sludge, spill residue,

ash emission control dust, or leachate (but not including precipitation run-off) is a hazardous waste.

(However, materials that are reclaimed from solid wastes and that are used beneficially are not solid wastes

and hence are not hazardous wastes under this provision unless the reclaimed material is burned for energy

recovery or used in a manner constituting disposal.)

(ii) The following solid wastes are not hazardous even though they are generated from the treatment,

storage, or disposal of a hazardous waste, unless they exhibit one or more of the characteristics of

hazardous waste:

(A) Waste pickle liquor sludge generated by lime stabilization of spent pickle liquor from the iron and

steel industry (SIC Codes 331 and 332).

(B) Waste from burning any of the materials exempted from regulation by § 261.6(a)(3)(iii) and (iv).

(C) (1) Nonwastewater residues, such as slag, resulting from high temperature metals recovery

(HTMR) processing of K061, K062 or F006 waste, in units identified as rotary kilns, flame

reactors, electric furnaces, plasma arc furnaces, slag reactors, rotary hearth furnace/electric furnace

combinations or industrial furnaces (as defined in paragraphs (6), (7), and (13) of the definition for

`Ìndustrial furnace'' in 40 CFR 260.10), that are disposed in subtitle D units, provided that these

residues meet the generic exclusion levels identified in the tables in this paragraph for all



constituents, and exhibit no characteristics of hazardous waste. Testing requirements must be

incorporated in a facility's waste analysis plan or a generator's self-implementing waste analysis

plan; at a minimum, composite samples of residues must be collected and analyzed quarterly

and/or when the process or operation generating the waste changes. Persons claiming this

exclusion in an enforcement action will have the burden of proving by clear and convincing

evidence that the material meets all of the exclusion requirements.

Constituent (mg/l) Maximum for any single composite sample TCLP

Generic exclusion levels for K061 and K062 nonwastewater HTMR Residues

Antimony 0.10

Arsenic 0.50

Barium 7.6

Beryllium 0.010

Cadmium 0.050

Chromium (total) 0.33

Lead 0.15

Mercury 0.009

Nickel 1.0

Selenium 0.16

Silver 0.30

Thallium 0.020

Zinc 70

Constituent (mg/l) Maximum for any single composite sample TCLP

Generic exclusion levels for F006 nonwastewater HTMR residues

Antimony 0.10

Arsenic 0.50

Barium 7.6

Beryllium 0.010

Cadmium 0.050

Chromium (total) 0.33

Cyanide (total) (mg/kg) 1.8

Lead 0.15

Mercury 0.009

Nickel 1.0

Selenium 0.16

Silver 0.30

Thallium 0.020

Zinc 70

(2) A one-time notification and certification must be placed in the facility's files and sent to the EPA region or

authorized state for K061, K062 or F006 HTMR residues that meet the generic exclusion levels for all

constituents and do not exhibit any characteristics that are sent to subtitle D units. The notification and

certification that is placed in the generators or treaters files must be updated if the process or operation

generating the waste changes and/or if the subtitle D unit receiving the waste changes. However, the

generator or treater need only notify the EPA region or an authorized state on an annual basis if such

changes occur. Such notification and certification should be sent to the EPA region or authorized state by

the end of the calendar year, but no later than December 31. The notification must include the following

information: The name and address of the subtitle D unit receiving the waste shipments; the EPA

Hazardous Waste Number(s) and treatability group(s) at the initial point of generation; and, the treatment

standards applicable to the waste at the initial point of generation. The certification must be signed by an

authorized representative and must state as follows: `Ì certify under penalty of law that the generic

exclusion levels for all constituents have been met without impermissible dilution and that no characteristic

of hazardous waste is exhibited. I am aware that there are significant penalties for submitting a false

certification, including the possibility of fine and imprisonment.''



(D) Biological treatment sludge from the treatment of one of the following wastes listed in §

261.32-organic waste (including heavy ends, still bottoms, light ends, spent solvents, filtrates, and

decantates) from the production of carbamates and carbamoyl oximes (EPA Hazardous Waste No.

K156), and wastewaters from the production of carbamates and carbamoyl oximes (EPA

Hazardous Waste No. K157).

(E) Catalyst inert support media separated from one of the following wastes listed in § 261.32 - Spent

hydrotreating catalyst (EPA Hazardous Waste No. K171), and Spent hydrorefining catalyst (EPA

Hazardous Waste No. K172).

(d) Any solid waste described in paragraph (c) of this section is not a hazardous waste if it meets the following

criteria:

(1) In the case of any solid waste, it does not exhibit any of the characteristics of hazardous waste identified in

subpart C of this part.

(2) In the case of a waste which is a listed waste under subpart D of this part, contains a waste listed under

subpart D of this part or is derived from a waste listed in subpart D of this part, it also has been excluded

from paragraph (c) of this section under §§ 260.20 and 260.22 of this chapter.

(e) Reserved.

(f) Notwithstanding paragraphs (a) through (d) of this section and provided the debris as defined in part 268 of this

chapter does not exhibit a characteristic identified at subpart C of this part, the following materials are not

subject to regulation under 40 CFR parts 260, 261 to 266, 268, or 270:

(1) Hazardous debris as defined in part 268 of this chapter that has been treated using one of the required

extraction or destruction technologies specified in Table 1 of § 268.45 of this chapter; persons claiming this

exclusion in an enforcement action will have the burden of proving by clear and convincing evidence that

the material meets all of the exclusion requirements; or

(2) Debris as defined in part 268 of this chapter that the Regional Administrator, considering the extent of

contamination, has determined is no longer contaminated with hazardous waste.

(g) (1) A hazardous waste that is listed in subpart D of this part solely because it exhibits one or more

characteristics of ignitability as defined under § 261.21, corrosivity as defined under § 261.22, or reactivity

as defined under § 261.23 is not a hazardous waste, if the waste no longer exhibits any characteristic of

hazardous waste identified in subpart C of this part.

(2) The exclusion described in paragraph (g)(1) of this section also pertains to:

(i) Any mixture of a solid waste and a hazardous waste listed in subpart D of this part solely because it

exhibits the characteristics of ignitability, corrosivity, or reactivity as regulated under paragraph

(a)(2)(iv) of this section; and

(ii) Any solid waste generated from treating, storing, or disposing of a hazardous waste listed in subpart D

of this part solely because it exhibits the characteristics of ignitability, corrosivity, or reactivity as

regulated under paragraph (c)(2)(i) of this section.

(3) Wastes excluded under this section are subject to part 268 of this chapter (as applicable), even if they no

longer exhibit a characteristic at the point of land disposal.

(4) any mixture of a solid waste excluded from regulation under § 261.4(b)(7) and a hazardous waste listed in

subpart D of this part solely because it exhibits one or more of the characteristics of ignitability, corrosivity,

or reactivity as regulated under paragraph (a)(2)(iv) of this section is not a hazardous waste, if the mixture

no longer exhibits any characteristic of hazardous waste identified in subpart C of this part for which the

hazardous waste listed in subpart D of this part was listed.

(h) (1) Hazardous waste containing radioactive waste is no longer a hazardous waste when it meets the eligibility



criteria and conditions of 40 CFR part 266, Subpart N ("eligible radioactive mixed waste").

(2) The exemption described in paragraph (h)(1) of this section also pertains to:

(i) Any mixture of a solid waste and an eligible radioactive mixed waste; and

(ii) Any solid waste generated from treating, storing, or disposing of an eligible radioactive mixed waste.

(3) Waste exempted under this section must meet the eligibility criteria and specified conditions in 40 CFR

266.225 and 40 CFR 266.230 (for storage and treatment) and in 40 CFR 266.310 and 40 CFR 266.315 (for

transportation and disposal). Waste that fails to satisfy these eligibility criteria and conditions is regulated

as hazardous waste.



261.4 Exclusions.

(a) Materials which are not solid wastes. The following materials are not solid wastes for the purpose of this part:

(1) (i) Domestic sewage; and

(ii) Any mixture of domestic sewage and other wastes that passes through a sewer system to a

publicly-owned treatment works for treatment. ``Domestic sewage'' means untreated sanitary wastes

that pass through a sewer system.

(2) Industrial wastewater discharges that are point source discharges subject to regulation under section 402 of

the Clean Water Act, as amended.

[Comment: This exclusion applies only to the actual point source discharge. It does not exclude industrial

wastewaters while they are being collected, stored or treated before discharge, nor does it exclude sludges that

are generated by industrial wastewater treatment.]

(3) Irrigation return flows.

(4) Source, special nuclear or by-product material as defined by the Atomic Energy Act of 1954, as amended,

42 U.S.C. 2011 et seq.

(5) Materials subjected to in-situ mining techniques which are not removed from the ground as part of the

extraction process.

(6) Pulping liquors (i.e., black liquor) that are reclaimed in a pulping liquor recovery furnace and then reused

in the pulping process, unless it is accumulated speculatively as defined in §261.1 (c) of this chapter.

(7) Spent sulfuric acid used to produce virgin sulfuric acid, unless it is accumulated speculatively as defined in

§261.1 (c) of this chapter.

(8) Secondary materials that are reclaimed and returned to the original process or processes in which they were

generated where they are reused in the production process provided:

(i) Only tank storage is involved, and the entire process through completion of reclamation is closed by

being entirely connected with pipes or other comparable enclosed means of conveyance;

(ii) Reclamation does not involve controlled flame combustion (such as occurs in boilers, industrial

furnaces, or incinerators);

(iii) The secondary materials are never accumulated in such tanks for over twelve months without being

reclaimed; and

(iv) The reclaimed material is not used to produce a fuel, or used to produce products that are used in a

manner constituting disposal.

(9) (i) Spent wood preserving solutions that have been reclaimed and are reused for their original intended

purpose; and

(ii) Wastewaters from the wood preserving process that have been reclaimed and are reused to treat wood.

(iii) Prior to reuse, the wood preserving wastewaters and spent wood preserving solutions described in

paragraphs (a)(9)(i) and (a)(9)(ii) of this section, so long as they meet all of the following conditions:

(A) The wood preserving wastewaters and spent wood preserving solutions are reused on-site at water

borne plants in the production process for their original intended purpose;

(B) Prior to reuse, the wastewaters and spent wood preserving solutions are managed to prevent

release to either land or groundwater or both;



(C) Any unit used to manage wastewaters and/or spent wood preserving solutions prior to reuse can be

visually or otherwise determined to prevent such releases;

(D) Any drip pad used to manage the wastewaters and/or spent wood preserving solutions prior to

reuse complies with the standards in part 265, subpart W of this chapter, regardless of whether the

plant generates a total of less than 100 kg/month of hazardous waste; and

(E) Prior to operating pursuant to this exclusion, the plant owner or operator submits to the

appropriate Regional Administrator or State Director a one-time notification stating that the plant

intends to claim the exclusion, giving the date on which the plant intends to begin operating under

the exclusion, and containing the following language: "I have read the applicable regulation

establishing an exclusion for wood preserving wastewaters and spent wood preserving solutions

and understand it requires me to comply at all times with the conditions set out in the regulation."

The plant must maintain a copy of that document in its on-site records for a period of no less than

3 years from the date specified in the notice. The exclusion applies only so long as the plant meets

all of the conditions. If the plant goes out of compliance with any condition, it may apply to the

appropriate Regional Administrator or State Director for reinstatement. The Regional

Administrator or State Director may reinstate the exclusion upon finding that the plant has

returned to compliance with all conditions and that violations are not likely to recur.

(10) EPA Hazardous Waste Nos. K060, K087, K141, K142, K143, K144, K145, K147, and K148, and any

wastes from the coke by-products processes that are hazardous only because they exhibit the Toxicity

Characteristic (TC) specified in section 261.24 of this part when, subsequent to generation, these materials

are recycled to coke ovens, to the tar recovery process as a feedstock to produce coal tar, or mixed with

coal tar prior to the tar's sale or refining. This exclusion is conditioned on there being no land disposal of

the wastes from the point they are generated to the point they are recycled to coke ovens or tar recovery or

refining processes, or mixed with coal tar.

(11) Nonwastewater splash condenser dross residue from the treatment of K061 in high temperature metals

recovery units, provided it is shipped in drums (if shipped) and not land disposed before recovery.

(12) (i) Oil-bearing hazardous secondary materials (i.e., sludges, byproducts, or spent materials) that are

generated at a petroleum refinery (SIC code 2911) and are inserted into the petroleum refining process

(SIC code 2911 - including, but not limited to, distillation, catalytic cracking, fractionation,

gasification (as defined in 40 CFR 260.10) or thermal cracking units (i.e., cokers)) unless the material

is placed on the land, or speculatively accumulated before being so recycled. Materials inserted into

thermal cracking units are excluded under this paragraph, provided that the coke product also does not

exhibit a characteristic of hazardous waste. Oil-bearing hazardous secondary materials may be inserted

into the same petroleum refinery where they are generated, or sent directly to another petroleum

refinery, and still be excluded under this provision. Except as provided in paragraph (a)(12)(ii) of this

section, oil-bearing hazardous secondary materials generated elsewhere in the petroleum industry (i.e.,

from sources other than petroleum refineries) are not excluded under this section. Residuals generated

from processing or recycling materials excluded under this paragraph (a)(12)(i), where such materials

as generated would have otherwise met a listing under subpart D of this part, are designated as F037

listed wastes when disposed of or intended for disposal.

(ii) Recovered oil that is recycled in the same manner and with the same conditions as described in

paragraph (a)(12)(i) of this section. Recovered oil is oil that has been reclaimed from secondary

materials (including wastewater) generated from normal petroleum industry practices, including

refining, exploration and production, bulk storage, and transportation incident thereto (SIC codes 1311,

1321, 1381, 1382, 1389, 2911, 4612, 4613, 4922, 4923, 4789, 5171, and 5172.) Recovered oil does not

include oil-bearing hazardous wastes listed in subpart D of this part; however, oil recovered from such

wastes may be considered recovered oil. Recovered oil does not include used oil as defined in 40 CFR

279.1.

(13) Excluded scrap metal (processed scrap metal, unprocessed home scrap metal, and unprocessed prompt

scrap metal) being recycled.



(14) Shredded circuit boards being recycled provided that they are:

(i) Stored in containers sufficient to prevent a release to the environment prior to recovery; and

(ii) Free of mercury switches, mercury relays and nickel-cadmium batteries and lithium batteries.

(15) Condensates derived from the overhead gases from kraft mill steam strippers that are used to comply with

40 CFR 63.446(e). The exemption applies only to combustion at the mill generating the condensates.

(16) Secondary materials (i.e., sludges, by-products, and spent materials as defined in § 261.1) (other than

hazardous wastes listed in subpart D of this part) generated within the primary mineral processing industry

from which minerals, acids, cyanide, water or other values are recovered by mineral processing, provided

that:

(i) The secondary material is legitimately recycled to recover minerals, acids, cyanide, water or other

values;

(ii) The secondary material is not accumulated speculatively;

(iii) Except as provided in paragraph (a)(15)(iv) of this section, the secondary material is stored in tanks,

containers, or buildings meeting the following minimum integrity standards: a building must be an

engineered structure with a floor, walls, and a roof all of which are made of non-earthen materials

providing structural support (except smelter buildings may have partially earthen floors provided the

secondary material is stored on the non-earthen portion), and have a roof suitable for diverting

rainwater away from the foundation; a tank must be free standing, not be a surface impoundment (as

defined in 40 CFR 260.10), and be manufactured of a material suitable for containment of its contents;

a container must be free standing and be manufactured of a material suitable for containment of its

contents. If tanks or containers contain any particulate which may be subject to wind dispersal, the

owner/operator must operate these units in a manner which controls fugitive dust. Tanks, containers,

and buildings must be designed, constructed and operated to prevent significant releases to the

environment of these materials.

(iv) The Regional Administrator or the State Director may make a site-specific determination, after public

review and comment, that onlysolid mineral processing secondary materials may be placed on pads,

rather than in tanks, containers, or buildings. Solid mineral processing secondary materials do not

contain any free liquid. The decision-maker must affirm that pads are designed, constructed and

operated to prevent significant releases of the secondary material into the environment. Pads must

provide the same degree of containment afforded by the non-RCRA tanks, containers and buildings

eligible for exclusion.

(A) The decision-maker must also consider if storage on pads poses the potential for significant

releases via groundwater, surface water, and air exposure pathways. Factors to be considered for

assessing the groundwater, surface water, air exposure pathways are: the volume and physical and

chemical properties of the secondary material, including its potential for migration off the pad; the

potential for human or environmental exposure to hazardous constituents migrating from the pad

via each exposure pathway, and the possibility and extent of harm to human and environmental

receptors via each exposure pathway.

(B) Pads must meet the following minimum standards: be designed of non-earthen material that is

compatible with the chemical nature of the mineral processing secondary material, capable of

withstanding physical stresses associated with placement and removal, have run on/runoff

controls, be operated in a manner which controls fugitive dust, and have integrity assurance

through inspections and maintenance programs.

(C) Before making a determination under this paragraph, the Regional Administrator or State Director

must provide notice and the opportunity for comment to all persons potentially interested in the

determination. This can be accomplished by placing notice of this action in major local

newspapers, or broadcasting notice over local radio stations.



(v) The owner or operator provides a notice to the Regional Administrator or State Director, identifying

the following information: the types of materials to be recycled; the type and location of the storage

units and recycling processes; and the annual quantities expected to be placed in land-based units. This

notification must be updated when there is a change in the type of materials recycled or the location of

the recycling process.

(vi) For purposes of § 261.4(b)(7), mineral processing secondary materials must be the result of mineral

processing and may not include any listed hazardous wastes. Listed hazardous wastes and

characteristic hazardous wastes generated by non-mineral processing industries are not eligible for the

conditional exclusion from the definition of solid waste.

(16) Comparable fuels or comparable syngas fuels (i.e., comparable/syngas fuels) that meet the requirements of

§261.38.

(17) Spent materials (as defined in § 261.1) (other than hazardous wastes listed in subpart D of this part)

generated within the primary mineral processing industry from which minerals, acids, cyanide, water, or

other values are recovered by mineral processing or by beneficiation, provided that:

(i) The spent material is legitimately recycled to recover minerals, acids, cyanide, water or other values;

(ii) The spent material is not accumulated speculatively;

(iii) Except as provided in paragraph (a)(17)(iv) of this section, the spent material is stored in tanks,

containers, or buildings meeting the following minimum integrity standards: a building must be an

engineered structure with a floor, walls, and a roof all of which are made of non-earthen materials

providing structural support (except smelter buildings may have partially earthen floors provided the

secondary material is stored on the non-earthen portion), and have a roof suitable for diverting

rainwater away from the foundation; a tank must be free standing, not be a surface impoundment (as

defined in 40 CFR 260.10), and be manufactured of a material suitable for containment of its contents;

a container must be free standing and be manufactured of a material suitable for containment of its

contents. If tanks or containers contain any particulate which may be subject to wind dispersal, the

owner/operator must operate these units in a manner which controls fugitive dust. Tanks, containers,

and buildings must be designed, constructed and operated to prevent significant releases to the

environment of these materials.

(iv) The Regional Administrator or State Director may make a site-specific determination, after public

review andcomment, that only solid mineral processing spent material may be placed on pads rather

than tanks containers, or buildings. Solid mineral processing spent materials do not contain any free

liquid. The decision-maker must affirm that pads are designed, constructed and operated to prevent

significant releases of the secondary material into the environment. Pads must provide the same degree

of containment afforded by the non-RCRA tanks, containers and buildings eligible for exclusion.

(A) The decision-maker must also consider if storage on pads poses the potential for significant

releases via groundwater, surface water, and air exposure pathways. Factors to be considered for

assessing the groundwater, surface water, air exposure pathways are: The volume and physical and

chemical properties of the secondary material, including its potential for migration off the pad; the

potential for human or environmental exposure to hazardous constituents migrating from the pad

via each exposure pathway, and the possibility and extent of harm to human and environmental

receptors via each exposure pathway.

(B) Pads must meet the following minimum standards: Be designed of non-earthen material that is

compatible with the chemical nature of the mineral processing spent material, capable of

withstanding physical stresses associated with placement and removal, have run on/runoff

controls, be operated in a manner which controls fugitive dust, and have integrity assurance

through inspections and maintenance programs.

(C) Before making a determination under this paragraph, the Regional Administrator or State Director

must provide notice and the opportunity for comment to all persons potentially interested in the

determination. This can be accomplished by placing notice of this action in major local



newspapers, or broadcasting notice over local radio stations.

(v) The owner or operator provides notice to the Regional Administrator or State Director providing the

following information: The types of materials to be recycled; the type and location of the storage units

and recycling processes; and the annual quantities expected to be placed in land-based units. This

notification must be updated when there is a change in the type of materials recycled or the location of

the recycling process.

(vi) For purposes of paragraph (b)(7) of this section, mineral processing spent materials must be the result

of mineral processing and may not include any listed hazardous wastes. Listed hazardous wastes and

characteristic hazardous wastes generated by non-mineral processing industries are not eligible for the

conditional exclusion from the definition of solid waste.

(18) Petrochemical recovered oil from an associated organic chemical manufacturing facility, where the oil is to

be inserted into the petroleum refining process (SIC code 2911) along with normal petroleum refinery

process streams, provided:

(i) The oil is hazardous only because it exhibits the characteristic of ignitability (as defined in § 261.21)

and/or toxicity for benzene (§ 261.24, waste code D018); and

(ii) The oil generated by the organic chemical manufacturing facility is not placed on the land, or

speculatively accumulated before being recycled into the petroleum refining process. An "associated

organic chemical manufacturing facility" is a facility where the primary SIC code is 2869, but where

operations may also include SIC codes 2821, 2822, and 2865; and is physically co-located with a

petroleum refinery; and where the petroleum refinery to which the oil being recycled is returned also

provides hydrocarbon feedstocks to the organic chemical manufacturing facility. "Petrochemical

recovered oil" is oil that has been reclaimed from secondary materials (i.e., sludges, byproducts, or

spent materials, including wastewater) from normal organic chemical manufacturing operations, as

well as oil recovered from organic chemical manufacturing processes.

(19) Spent caustic solutions from petroleum refining liquid treating processes used as a feedstock to produce

cresylic or naphthenic acid unless the material is placed on the land, or accumulated speculatively as

defined in § 261.1(c).

(20) Hazardous secondary materials used to make zinc fertilizers, provided that the following conditions

specified are satisfied:

(i) Hazardous secondary materials used to make zinc micronutrient fertilizers must not be accumulated

speculatively, as defined in § 261.1(c)(8).

(ii) Generators and intermediate handlers of zinc-bearing hazardous secondary materials that are to be

incorporated into zinc fertilizers must:

(A) Submit a one-time notice to the Regional Administrator or State Director in whose jurisdiction the

exclusion is being claimed, which contains the name, address and EPA ID number of the generator

or intermediate handler facility, provides a brief description of the secondary material that will be

subject to the exclusion, and identifies when the manufacturer intends to begin managing

excluded, zinc-bearing hazardous secondary materials under the conditions specified in this

paragraph (a)(20).

(B) Store the excluded secondary material in tanks, containers, or buildings that are constructed and

maintained in a way that prevents releases of the secondary materials into the environment. At a

minimum, any building used for this purpose must be an engineered structure made of non-earthen

materials that provide structural support, and must have a floor, walls and a roof that prevent wind

dispersal and contact with rainwater. Tanks used for this purpose must be structurally sound and,

if outdoors, must have roofs or covers that prevent contact with wind and rain. Containers used for

this purpose must be kept closed except when it is necessary to add or remove material, and must

be in sound condition. Containers that are stored outdoors must be managed within storage areas

that:



(1) have containment structures or systems sufficiently impervious to contain leaks, spills and

accumulated precipitation; and

(2) provide for effective drainage and removal of leaks, spills and accumulated precipitation; and

(3) prevent run-on into the containment system.

(C) With each off-site shipment of excluded hazardous secondary materials, provide written notice to

the receiving facility that the material is subject to the conditions of this paragraph (a)(20).

(D) Maintain at the generator's or intermediate handlers's facility for no less than three years records of

all shipments of excluded hazardous secondary materials. For each shipment these records must at

a minimum contain the following information:

(1) Name of the transporter and date of the shipment;

(2) Name and address of the facility that received the excluded material, and documentation

confirming receipt of the shipment; and

(3) Type and quantity of excluded secondary material in each shipment.

(iii) Manufacturers of zinc fertilizers or zinc fertilizer ingredients made from excluded hazardous secondary

materials must:

(A) Store excluded hazardous secondary materials in accordance with the storage requirements for

generators and intermediate handlers, as specified in paragraph (a)(20)(ii)(B) of this section.

(B) Submit a one-time notification to the Regional Administrator or State Director that, at a minimum,

specifies the name, address and EPA ID number of the manufacturing facility, and identifies when

the manufacturer intends to begin managing excluded, zinc-bearing hazardous secondary materials

under the conditions specified in this paragraph (a)(20).

(C) Maintain for a minimum of three years records of all shipments of excluded hazardous secondary

materials received by the manufacturer, which must at a minimum identify for each shipment the

name and address of the generating facility, name of transporter and date the materials were

received, the quantity received, and a brief description of the industrial process that generated the

material.

(D) Submit to the Regional Administrator or State Director an annual report that identifies the total

quantities of all excluded hazardous secondary materials that were used to manufacture zinc

fertilizers or zinc fertilizer ingredients in the previous year, the name and address of each

generating facility, and the industrial process(s) from which they were generated.

(iv) Nothing in this section preempts, overrides or otherwise negates the provision in § 262.11 of this

chapter, which requires any person who generates a solid waste to determine if that waste is a

hazardous waste.

(v) Interim status and permitted storage units that have been used to store only zinc-bearing hazardous

wastes prior to the submission of the one-time notice described in paragraph (a)(20)(ii)(A) of this

section, and that afterward will be used only to store hazardous secondary materials excluded under

this paragraph, are not subject to the closure requirements of 40 CFR Parts 264 and 265.

(21) Zinc fertilizers made from hazardous wastes, or hazardous secondary materials that are excluded under

paragraph (a)(20) of this section, provided that:

(i) The fertilizers meet the following contaminant limits:

(A) For metal contaminants:



Constituent Maximum allowable Total

Concentration in Fertilizer, per

Unit (1%) of Zinc (ppm)

Arsenic 0.3

Cadmium 1.4

Chromium 0.6

Lead 2.8

Mercury 0.3

(B) For dioxin contaminants the fertilizer must contain no more than eight (8) parts per trillion of

dioxin, measured as toxic equivalent (TEQ).

(ii) The manufacturer performs sampling and analysis of the fertilizer product to determine compliance

with the contaminant limits for metals no less than every six months, and for dioxins no less than every

twelve months. Testing must also be performed whenever changes occur to manufacturing processes or

ingredients that could significantly affect the amounts of contaminants in the fertilizer product. The

manufacturer may use any reliable analytical method to demonstrate that no constituent of concern is

present in the product at concentrations above the applicable limits. It is the responsibility of the

manufacturer to ensure that the sampling and analysis are unbiased, precise, and representative of the

product(s) introduced into commerce.

(iii) The manufacturer maintains for no less than three years records of all sampling and analyses

performed for purposes of determining compliance with the requirements of paragraph (a)(21)(ii) of

this section. Such records must at a minimum include:

(A) The dates and times product samples were taken, and the dates the samples were analyzed;

(B) The names and qualifications of the person(s) taking the samples;

(C) A description of the methods and equipment used to take the samples;

(D) The name and address of the laboratory facility at which analyses of the samples were performed;

(E) A description of the analytical methods used, including any cleanup and sample preparation

methods; and

(F) All laboratory analytical results used to determine compliance with the contaminant limits

specified in this paragraph (a)(21).

(22) Used cathode ray tubes (CRTs)

(i) Used, intact CRTs as defined in § 260.10 of this chapter are not solid wastes within the United States

unless they are disposed, or unless they are speculatively accumulated as defined in § 261.1(c)(8) by

CRT collectors or glass processors.

(ii) Used, intact CRTs as defined in § 260.10 of this chapter are not solid wastes when exported for

recycling provided that they meet the requirements of § 261.40.

(iii) Used, broken CRTs as defined in § 260.10 of this chapter are not solid wastes provided that they meet

the requirements of § 261.39.

(iv) Glass removed from CRTs is not a solid waste provided that it meets the requirements of §261.39(c).

(23) Hazardous secondary material generated and legitimately reclaimed within the United States or its

territories and under the control of the generator, provided that the material complies with paragraphs

(a)(23)(i) and (ii) of this section:



(i)

(A) The hazardous secondary material is generated and reclaimed at the generating facility (for

purposes of this definition, generating facility means all contiguous property owned, leased, or

otherwise controlled by the hazardous secondary material generator); or

(B) The hazardous secondary material is generated and reclaimed at different facilities, if the

reclaiming facility is controlled by the generator or if both the generating facility and the

reclaiming facility are controlled by a person as defined in §260.10 of this chapter, and if the

generator provides one of the following certifications: “on behalf of [insert generator facility

name], I certify that this facility will send the indicated hazardous secondary material to [insert

reclaimer facility name], which is controlled by [insert generator facility name] and that [insert

name of either facility] has acknowledged full responsibility for the safe management of the

hazardous secondary material,” or “on behalf of [insert generator facility name], I certify that this

facility will send the indicated hazardous secondary material to [insert reclaimer facility name],

that both facilities are under common control, and that [insert name of either facility] has

acknowledged full responsibility for the safe management of the hazardous secondary material.”

For purposes of this paragraph, “control” means the power to direct the policies of the facility,

whether by the ownership of stock, voting rights, or otherwise, except that contractors who operate

facilities on behalf of a different person as defined in §260.10 shall not be deemed to “control”

such facilities. The generating and receiving facilities must both maintain at their facilities for no

less than three years records of hazardous secondary materials sent or received under this

exclusion. In both cases, the records must contain the name of the transporter, the date of the

shipment, and the type and quantity of the hazardous secondary material shipped or received under

the exclusion. These requirements may be satisfied by routine business records (e.g., financial

records, bills of lading, copies of DOT shipping papers, or electronic confirmations); or

(C) The hazardous secondary material is generated pursuant to a written contract between a tolling

contractor and a toll manufacturer and is reclaimed by the tolling contractor, if the tolling

contractor certifies the following: “On behalf of [insert tolling contractor name], I certify that

[insert tolling contractor name] has a written contract with [insert toll manufacturer name] to

manufacture [insert name of product or intermediate] which is made from specified unused

materials, and that [insert tolling contractor name] will reclaim the hazardous secondary materials

generated during this manufacture. On behalf of [insert tolling contractor name], I also certify that

[insert tolling contractor name] retains ownership of, and responsibility for, the hazardous

secondary materials that are generated during the course of the manufacture, including any

releases of hazardous secondary materials that occur during the manufacturing process”. The

tolling contractor must maintain at its facility for no less than three years records of hazardous

secondary materials received pursuant to its written contract with the tolling manufacturer, and the

tolling manufacturer must maintain at its facility for no less than three years records of hazardous

secondary materials shipped pursuant to its written contract with the tolling contractor. In both

cases, the records must contain the name of the transporter, the date of the shipment, and the type

and quantity of the hazardous secondary material shipped or received pursuant to the written

contract. These requirements may be satisfied by routine business records (e.g., financial records,

bills of lading, copies of DOT shipping papers, or electronic confirmations). For purposes of this

paragraph, tolling contractor means a person who arranges for the production of a product or

intermediate made from specified unused materials through a written contract with a toll

manufacturer. Toll manufacturer means a person who produces a product or intermediate made

from specified unused materials pursuant to a written contract with a tolling contractor.

(ii)

(A) The hazardous secondary material is contained as defined in §260.10 of this chapter. A hazardous

secondary material released to the environment is discarded and a solid waste unless it is

immediately recovered for the purpose of reclamation. Hazardous secondary material managed in

a unit with leaks or other continuing or intermittent unpermitted releases is discarded and a solid

waste.

(B) The hazardous secondary material is not speculatively accumulated, as defined in §261.1(c)(8).

(C) Notice is provided as required by §260.42 of this chapter.

(D) The material is not otherwise subject to material-specific management conditions under paragraph

(a) of this section when reclaimed, and it is not a spent lead-acid battery (see §266.80 and §273.2

of this chapter).

(E) Persons performing the recycling of hazardous secondary materials under this exclusion must

maintain documentation of their legitimacy determination on-site. Documentation must be a



written description of how the recycling meets all four factors in §260.43(a). Documentation must

be maintained for three years after the recycling operation has ceased.

(F) The emergency preparedness and response requirements found in subpart M of this part are met.

(24) Hazardous secondary material that is generated and then transferred to a verified reclamation facility for

the purpose of reclamation is not a solid waste, provided that:

(i) The material is not speculatively accumulated, as defined in §261.1(c)(8);

(ii) The material is not handled by any person or facility other than the hazardous secondary material

generator, the transporter, an intermediate facility or a reclaimer, and, while in transport, is not stored

for more than 10 days at a transfer facility, as defined in §260.10 of this chapter, and is packaged

according to applicable Department of Transportation regulations at 49 CFR parts 173, 178, and 179

while in transport;

(iii) The material is not otherwise subject to material-specific management conditions under this paragraph

(a) when reclaimed, and it is not a spent lead-acid battery (see §§266.80 and 273.2 of this chapter);

(iv) The reclamation of the material is legitimate, as specified under §260.43 of this chapter;

(v) The hazardous secondary material generator satisfies all of the following conditions:

(A) The material must be contained as defined in §260.10. A hazardous secondary material released to

the environment is discarded and a solid waste unless it is immediately recovered for the purpose

of recycling. Hazardous secondary material managed in a unit with leaks or other continuing

releases is discarded and a solid waste.

(B) The hazardous secondary material generator must arrange for transport of hazardous secondary

materials to a verified reclamation facility (or facilities) in the United States. A verified

reclamation facility is a facility that has been granted a variance under §260.31(d), or a

reclamation facility where the management of the hazardous secondary materials is addressed

under a RCRA Part B permit or interim status standards. If the hazardous secondary material will

be passing through an intermediate facility, the intermediate facility must have been granted a

variance under §260.31(d) or the management of the hazardous secondary materials at that facility

must be addressed under a RCRA Part B permit or interim status standards, and the hazardous

secondary material generator must make contractual arrangements with the intermediate facility to

ensure that the hazardous secondary material is sent to the reclamation facility identified by the

hazardous secondary material generator.

(C) The hazardous secondary material generator must maintain at the generating facility for no less

than three (3) years records of all off-site shipments of hazardous secondary materials. For each

shipment, these records must, at a minimum, contain the following information:


(2) Name and address of each reclaimer and, if applicable, the name and address of each

intermediate facility to which the hazardous secondary material was sent;

(3) The type and quantity of hazardous secondary material in the shipment.

(D) The hazardous secondary material generator must maintain at the generating facility for no less

than three (3) years confirmations of receipt from each reclaimer and, if applicable, each

intermediate facility for all off-site shipments of hazardous secondary materials. Confirmations of

receipt must include the name and address of the reclaimer (or intermediate facility), the type and

quantity of the hazardous secondary materials received and the date which the hazardous

secondary materials were received. This requirement may be satisfied by routine business records

(e.g.,financial records, bills of lading, copies of DOT shipping papers, or electronic confirmations

of receipt);

(E) The hazardous secondary material generator must comply with the emergency preparedness and

response conditions in subpart M of this part.

(vi) Reclaimers of hazardous secondary material excluded from regulation under this exclusion and

intermediate facilities as defined in §260.10 of this chapter satisfy all of the following conditions:

(A) The reclaimer and intermediate facility must maintain at its facility for no less than three (3) years

records of all shipments of hazardous secondary material that were received at the facility and, if

applicable, for all shipments of hazardous secondary materials that were received and

subsequently sent off-site from the facility for further reclamation. For each shipment, these

records must at a minimum contain the following information:


(2) Name and address of the hazardous secondary material generator and, if applicable, the name

and address of the reclaimer or intermediate facility which the hazardous secondary materials



were received from;

(3) The type and quantity of hazardous secondary material in the shipment; and

(4) For hazardous secondary materials that, after being received by the reclaimer or intermediate

facility, were subsequently transferred off-site for further reclamation, the name and address

of the (subsequent) reclaimer and, if applicable, the name and address of each intermediate

facility to which the hazardous secondary material was sent.

(B) The intermediate facility must send the hazardous secondary material to the reclaimer(s)

designated by the hazardous secondary materials generator.

(C) The reclaimer and intermediate facility must send to the hazardous secondary material generator

confirmations of receipt for all off-site shipments of hazardous secondary materials. Confirmations

of receipt must include the name and address of the reclaimer (or intermediate facility), the type

and quantity of the hazardous secondary materials received and the date which the hazardous

secondary materials were received. This requirement may be satisfied by routine business records

(e.g., financial records, bills of lading, copies of DOT shipping papers, or electronic confirmations

of receipt).

(D) The reclaimer and intermediate facility must manage the hazardous secondary material in a manner

that is at least as protective as that employed for analogous raw material and must be contained.

An “analogous raw material” is a raw material for which a hazardous secondary material is a

substitute and serves the same function and has similar physical and chemical properties as the

hazardous secondary material.

(E) Any residuals that are generated from reclamation processes will be managed in a manner that is

protective of human health and the environment. If any residuals exhibit a hazardous characteristic

according to subpart C of 40 CFR part 261, or if they themselves are specifically listed in subpart

D of 40 CFR part 261, such residuals are hazardous wastes and must be managed in accordance

with the applicable requirements of 40 CFR parts 260 through 272.

(F) The reclaimer and intermediate facility have financial assurance as required under subpart H of 40

CFR part 261,

(G) The reclaimer and intermediate facility have been granted a variance under §260.31(d) or have a

RCRA Part B permit or interim status standards that address the management of the hazardous

secondary materials; and

(vii) All persons claiming the exclusion under this paragraph (a)(24) of this section provide notification as

required under §260.42 of this chapter.

(25) [Reserved]

(26) Solvent-contaminated wipes that are sent for cleaning and reuse are not solid wastes from the point of

generation, provided that

(i) The solvent-contaminated wipes, when accumulated, stored, and transported, are contained in

nonleaking, closed containers that are labeled ‘‘Excluded Solvent- Contaminated Wipes.’’ The

containers must be able to contain free liquids, should free liquids occur. During accumulation, a

container is considered closed when there is complete contact between the fitted lid and the rim, except

when it is necessary to add or remove solvent-contaminated wipes. When the container is full, or when

the solvent-contaminated wipes are no longer being accumulated, or when the container is being

transported, the container must be sealed with all lids properly and securely affixed to the container

and all openings tightly bound or closed sufficiently to prevent leaks and emissions;

(ii) The solvent-contaminated wipes may be accumulated by the generator for up to 180 days from the start

date of accumulation for each container prior to being sent for cleaning;

(iii) At the point of being sent for cleaning on-site or at the point of being transported off-site for cleaning,

the solvent-contaminated wipes must contain no free liquids as defined in § 260.10 of this chapter.

(iv) Free liquids removed from the solvent-contaminated wipes or from the container holding the wipes

must be managed according to the applicable regulations found in 40 CFR parts 260 through 273;

(v) Generators must maintain at their site the following documentation:

(A) Name and address of the laundry or dry cleaner that is receiving the solvent-contaminated wipes;



(B) Documentation that the 180-day accumulation time limit in 40 CFR 261.4(a)(26)(ii) is being met;

(C) Description of the process the generator is using to ensure the solvent contaminated wipes contain

no free liquids at the point of being laundered or dry cleaned on-site or at the point of being

transported off-site for laundering or dry cleaning;

(vi) The solvent-contaminated wipes are sent to a laundry or dry cleaner whose discharge, if any, is

regulated under sections 301 and 402 or section 307 of the Clean Water Act.

(27) Hazardous secondary material that is generated and then transferred to another person for the purpose of

remanufacturing is not a solid waste, provided that:

(i) The hazardous secondary material consists of one or more of the following spent solvents: Toluene,

xylenes, ethylbenzene, 1,2,4-trimethylbenzene, chlorobenzene, n-hexane, cyclohexane, methyl tert-

butyl ether, acetonitrile, chloroform, chloromethane, dichloromethane, methyl isobutyl ketone, NN-

dimethylformamide, tetrahydrofuran, n-butyl alcohol, ethanol, and/or methanol;

(ii) The hazardous secondary material originated from using one or more of the solvents listed in

paragraph (a)(27)(i) of this section in a commercial grade for reacting, extracting, purifying, or

blending chemicals (or for rinsing out the process lines associated with these functions) in the

pharmaceutical manufacturing (NAICS 325412), basic organic chemical manufacturing (NAICS

325199), plastics and resins manufacturing (NAICS 325211), and/or the paints and coatings

manufacturing sectors (NAICS 325510).

(iii) The hazardous secondary material generator sends the hazardous secondary material spent solvents

listed in paragraph (a)(27)(i) of this section to a remanufacturer in the pharmaceutical manufacturing

(NAICS 325412), basic organic chemical manufacturing (NAICS 325199), plastics and resins

manufacturing (NAICS 325211), and/or the paints and coatings manufacturing sectors (NAICS

325510).

(iv) After remanufacturing one or more of the solvents listed in paragraph (a)(27)(i) of this section, the use

of the remanufactured solvent shall be limited to reacting, extracting, purifying, or blending chemicals

(or for rinsing out the process lines associated with these functions) in the pharmaceutical

manufacturing (NAICS 325412), basic organic chemical manufacturing (NAICS 325199), plastics and

resins manufacturing (NAICS 325211), and the paints and coatings manufacturing sectors (NAICS

325510) or to using them as ingredients in a product. These allowed uses correspond to chemical

functional uses enumerated under the Chemical Data Reporting Rule of the Toxic Substances Control

Act (40 CFR parts 704, 710-711), including Industrial Function Codes U015 (solvents consumed in a

reaction to produce other chemicals) and U030 (solvents become part of the mixture);

(v) After remanufacturing one or more of the solvents listed in paragraph (a)(27)(i) of this section, the use

of the remanufactured solvent does not involve cleaning or degreasing oil, grease, or similar material

from textiles, glassware, metal surfaces, or other articles. (These disallowed continuing uses

correspond to chemical functional uses in Industrial Function Code U029 under the Chemical Data

Reporting Rule of the Toxics Substances Control Act.); and

(vi) Both the hazardous secondary material generator and the remanufacturer must:

(A) Notify EPA or the State Director, if the state is authorized for the program, and update the

notification every two years per 40 CFR 260.42;

(B) Develop and maintain an up-to-date remanufacturing plan which identifies:

(1) The name, address and EPA ID number of the generator(s) and the remanufacturer(s),

(2) The types and estimated annual volumes of spent solvents to be remanufactured,

(3) The processes and industry sectors that generate the spent solvents,

(4) The specific uses and industry sectors for the remanufactured solvents, and

(5) A certification from the remanufacturer stating “on behalf of [insert remanufacturer facility

name], I certify that this facility is a remanufacturer under pharmaceutical manufacturing

(NAICS 325412), basic organic chemical manufacturing (NAICS 325199), plastics and resins

manufacturing (NAICS 325211), and/or the paints and coatings manufacturing sectors

(NAICS 325510), and will accept the spent solvent(s) for the sole purpose of remanufacturing

into commercial-grade solvent(s) that will be used for reacting, extracting, purifying, or

blending chemicals (or for rinsing out the process lines associated with these functions) or for

use as product ingredient(s). I also certify that the remanufacturing equipment, vents, and

tanks are equipped with and are operating air emission controls in compliance with the

appropriate Clean Air Act regulations under 40 CFR part 60, part 61 or part 63, or, absent



such Clean Air Act standards for the particular operation or piece of equipment covered by

the remanufacturing exclusion, are in compliance with the appropriate standards in 40 CFR

part 261, subparts AA (vents), BB (equipment) and CC (tank storage),”;

(C) Maintain records of shipments and confirmations of receipts for a period of three years from the

dates of the shipments;

(D) Prior to remanufacturing, store the hazardous spent solvents in tanks or containers that meet

technical standards found in subparts I and J of 40 CFR part 261, with the tanks and containers

being labeled or otherwise having an immediately available record of the material being stored;

(E) During remanufacturing, and during storage of the hazardous secondary materials prior to

remanufacturing, the remanufacturer certifies that the remanufacturing equipment, vents, and

tanks are equipped with and are operating air emission controls in compliance with the appropriate

Clean Air Act regulations under 40 CFR part 60, part 61 or part 63; or, absent such Clean Air Act

standards for the particular operation or piece of equipment covered by the remanufacturing

exclusion, are in compliance with the appropriate standards in 40 CFR part 261 subparts AA

(vents), BB (equipment) and CC (tank storage); and

(F) Meet the requirements prohibiting speculative accumulation per 40 CFR 261.1(c)(8).



(b) Solid wastes which are not hazardous wastes. The following solid wastes are not hazardous wastes:

(1) Household waste, including household waste that has been collected, transported, stored, treated, disposed,

recovered (e.g., refuse-derived fuel) or reused. ``Household waste'' means any material (including garbage,

trash and sanitary wastes in septic tanks) derived from households (including single and multiple

residences, hotels and motels, bunkhouses, ranger stations, crew quarters, campgrounds, picnic grounds and

day-use recreation areas). A resource recovery facility managing municipal solid waste shall not be deemed

to be treating, storing, disposing of, or otherwise managing hazardous wastes for the purposes of regulation

under this subtitle, if such facility:

(i) Receives and burns only

(A) Household waste (from single and multiple dwellings, hotels, motels, and other residential

sources) and

(B) Solid waste from commercial or industrial sources that does not contain hazardous waste; and

(ii) Such facility does not accept hazardous wastes and the owner or operator of such facility has

established contractual requirements or other appropriate notification or inspection procedures to

assure that hazardous wastes are not received at or burned in such facility.

(2) Solid wastes generated by any of the following and which are returned to the soils as fertilizers:

(i) The growing and harvesting of agricultural crops.

(ii) The raising of animals, including animal manures.

(3) Mining overburden returned to the mine site.

(4) Fly ash waste, bottom ash waste, slag waste, and flue gas emission control waste, generated primarily from

the combusion of coal or other fossil fuels, except as provided by §266.112 of this chapter for facilities that

burn or process hazardous waste.

(5) Drilling fluids, produced waters, and other wastes associated with the exploration, development, or

production of crude oil, natural gas or geothermal energy.

(6) (i) Wastes which fail the test for the Toxicity Characteristic because chromium is present or are listed in

subpart D due to the presence of chromium, which do not fail the test for the Toxicity Characteristic

for any other constituent or are not listed due to the presence of any other constituent, and which do not

fail the test for any other characteristic, if it is shown by a waste generator or by waste generators that:

(A) The chromium in the waste is exclusively (or nearly exclusively) trivalent chromium; and

(B) The waste is generated from an industrial process which uses trivalent chromium exlcusively (or

nearly exclusively) and the process does not generate hexavalent chromium; and

(C) The waste is typically and frequently managed in non-oxidizing environments.

(ii) Specific waste which meet the standard in paragraphs (b)(6)(i) (A), (B), and (C) (so long as they do not

fail the test for the toxicity characteristic for any other constituent, and do not exhibit any other

characteristic) are: * * *

(A) Chrome (blue) trimmings generated by the following subcategories of the leather tanning and

finishing industry; hair pulp/chrome tan/retan/wet finish; hair save/chrome tan/retan/wet finish;

retan/wet finish; no beamhouse; through-the-blue; and shearling.

(B) Chrome (blue) shavings generated by the following subcategories of the leather tanning and



finishing industry: Hair pulp/chrome tan/retan/wet finish; hair save/chrome tan/retan/wet finish;


(C) Buffing dust generated by the following subcategories of the leather tanning and finishing

industry; hair pulp/chrome tan/retan/wet finish; hair save/chrome tan/retan/wet finish; retan/wet

finish; no beamhouse; through-the-blue.

(D) Sewer screenings generated by the following subcategories of the leather tanning and finishing

industry: Hair pulp/chrome tan/retan/wet finish; hair save/chrome tan/retan/wet finish; retan/wet

finish; no beamhouse; through-the-blue; and shearling.

(E) Wastewater treatment sludges generated by the following subcategories of the leather tanning and



(F) Wastewater treatment sludges generated by the following subcategories of the leather tanning and


and through-the-blue.

(G) Waste scrap leather from the leather tanning industry, the shoe manufacturing industry, and other

leather product manufacturing industries.

(H) Wastewater treatment sludges from the production of TiO2 pigment using chromium-bearing ores

by the chloride process.

(7) Solid waste from the extraction, beneficiation, and processing of ores and minerals (including coal,

phosphate rock, and overburden from the mining of uranium ore), except as provided by § 266.112 of this

chapter for facilities that burn or process hazardous waste.

(i) For purposes of § 261.4(b)(7) beneficiation of ores and minerals is restricted to the following activities;

crushing; grinding; washing; dissolution; crystallization; filtration; sorting; sizing; drying; sintering;

pelletizing; briquetting; calcining to remove water and/or carbon dioxide; roasting, autoclaving, and/or

chlorination in preparation for leaching (except where the roasting (and/or autoclaving and/or

chlorination)/leaching sequence produces a final or intermediate product that does not undergo further

beneficiation or processing); gravity concentration; magnetic separation; electrostatic separation;

flotation; ion exchange; solvent extraction; electrowinning; precipitation; amalgamation; and heap,

dump, vat, tank, and in situ leaching.

(ii) For the purposes of § 261.4(b)(7), solid waste from the processing of ores and minerals includes only

the following wastes as generated:

(A) Slag from primary copper processing;

(B) Slag from primary lead processing;

(C) Red and brown muds from bauxite refining;

(D) Phosphogypsum from phosphoric acid production;

(E) Slag from elemental phosphorus production;

(F) Gasifier ash from coal gasification;

(G) Process wastewater from coal gasification;

(H) Calcium sulfate wastewater treatment plant sludge from primary copper processing;

(I) Slag tailings from primary copper processing;



(J) Fluorogypsum from hydrofluoric acid production;

(K) Process wastewater from hydrofluoric acid production;

(L) Air pollution control dust/sludge from iron blast furnaces;

(M) Iron blast furnace slag;

(N) Treated residue from roasting/leaching of chrome ore;

(O) Process wastewater from primary magnesium processing by the anhydrous process;

(P) Process wastewater from phosphoric acid production;

(Q) Basic oxygen furnace and open hearth furnace air pollution control dust/sludge from carbon steel

production;

(R) Basic oxygen furnace and open hearth furnace slag from carbon steel production;

(S) Chloride process waste solids from titanium tetrachloride production;

(T) Slag from primary zinc processing.

(iii) A residue derived from co-processing mineral processing secondary materials with normal

beneficiation raw materials remains excluded under paragraph (b) of this section if the owner or

operator:

(A) Processes at least 50 percent by weight normal beneficiation raw materials; and,

(B) Legitimately reclaims the secondary mineral processing materials.

(8) Cement kiln dust waste, except as provided by §266.112 of this chapter for facilities that burn or process

hazardous waste.

(9) Solid waste which consists of discarded arsenical-treated wood or wood products which fails the test for the

Toxicity Characteristic for Hazardous Waste Codes D004 through D017 and which is not a hazardous

waste for any other reason if the waste is generated by persons who utilize the arsenical-treated wood and

wood products for these materials' intended end use.

(10) Petroleum-contaminated media and debris that fail the test for the Toxicity Characteristic of §261.24

(Hazardous Waste Codes D018 through D043 only) and are subject to the corrective action regulations

under part 280 of this chapter.

(11) Injected groundwater that is hazardous only because it exhibits the Toxicity Characteristic (Hazardous

Waste Codes D018 through D043 only) in §261.24 of this part that is reinjected through an underground

injection well pursuant to free phase hydrocarbon recovery operations undertaken at petroleum refineries,

petroleum marketing terminals, petroleum bulk plants, petroleum pipelines, and petroleum transportation

spill sites until January 25, 1993. This extension applies to recovery operations in existence, or for which

contracts have been issued, on or before March 25, 1991. For groundwater returned through infiltration

galleries from such operations at petroleum refineries, marketing terminals, and bulk plants, until [insert

date six months after publication]. New operations involving injection wells (beginning after March 25,

1991) will qualify for this compliance date extension (until January 25, 1993) only if:

(i) Operations are performed pursuant to a written state agreement that includes a provision to assess the

groundwater and the need for further remediation once the free phase recovery is completed; and

(ii) A copy of the written agreement has been submitted to: Characteristics Section (OS-333), U.S.



Environmental Protection Agency, 401 M Street, SW., Washington, DC 20460.

(12) Used chlorofluorocarbon refrigerants from totally enclosed heat transfer equipment, including mobile air

conditioning systems, mobile refrigeration, and commercial and industrial air conditioning and refrigeration

systems that use chlorofluorocarbons as the heat transfer fluid in a refrigeration cycle, provided the

refrigerant is reclaimed for further use.

(13) Non-terne plated used oil filters that are not mixed with wastes listed in Subpart D of this part if these oil

filters have been gravity hot-drained using one of the following methods:

(i) Puncturing the filter anti-drain back valve or the filter dome end and hot-draining;

(ii) Hot-draining and crushing;

(iii) Dismantling and hot-draining; or

(iv) Any other equivalent hot-draining method that will remove used oil.

(14) Used oil re-refining distillation bottoms that are used as feedstock to manufacture asphalt products.

(15) Leachate or gas condensate collected from landfills where certain solid wastes have been disposed,

provided that:

(i) The solid wastes disposed would meet one or more of the listing descriptions for Hazardous Waste

Codes K169, K170, K171, K172, K174, K175, K176, K177, K178 and K181 if these wastes had been

generated after the effective date of the listing;

(ii) The solid wastes described in paragraph (b)(15)(i) of this section were disposed prior to the effective

date of the listing;

(iii) The leachate or gas condensate do not exhibit any characteristic of hazardous waste nor are derived

from any other listed hazardous waste;

(iv) Discharge of the leachate or gas condensate, including leachate or gas condensate transferred from the

landfill to a POTW by truck, rail, or dedicated pipe, is subject to regulation under sections 307(b) or

402 of the Clean Water Act.

(v) As of February 13, 2001, leachate or gas condensate derived from K169-K172 is no longer exempt if it

is stored or managed in a surface impoundment prior to discharge. As of November 21, 2003, leachate

or gas condensate derived from K176, K177, and K178 is no longer exempt if it is stored or managed

in a surface impoundment prior to discharge. After February 26, 2007, leachate or gas condensate

derived from K181 will no longer be exempt if it is stored or managed in a surface impoundment prior

to discharge. There is one exception: if the surface impoundment is used to temporarily store leachate

or gas condensate in response to an emergency situation (e.g., shutdown of wastewater treatment

system), provided the impoundment has a double liner, and provided the leachate or gas condensate is

removed from the impoundment and continues to be managed in compliance with the conditions of

this paragraph (b)(15)(v) after the emergency ends.

(16) Reserved

(17) Solid waste that would otherwise meet the definition of low-level mixed wastes (LLMW) pursuant to

§266.210 of this chapter that is generated at the Ortho-McNeil Pharmaceutical, Inc. (OMP Spring House)

research and development facility in Spring House, Pennsylvania and treated on-site using a bench-scale

high temperature catalytic oxidation unit is not a hazardous waste provided that:

(i) The total volume of LLMW generated and treated is no greater than 50 liters/year,

(ii) OMP Spring House submits a written report to the EPA Region III office once every six months

beginning six months after June 27, 2005, that must contain the following:

(A) Analysis demonstrating the destruction and removal efficiency of the treatment technology for all



organic components of the wastestream,

(B) Analysis demonstrating the capture efficiencies of the treatment technology for all radioactive

components of the wastestream and an estimate of the amount of radioactivity released during the

reporting period,

(C) Analysis (including concentrations of constituents, including inorganic constituents, present and

radioactivity) of the wastestream prior to and after treatment,

(D) Volume of the wastestream being treated per batch, as well as a total for the duration of the

reporting period, and

(E) Final disposition of the radioactive residuals from the treatment of the wastestream.

(iii) OMP Spring House makes no significant changes to the design or operation of the high temperature

catalytic oxidation unit or the wastestream.

(iv) This exclusion will remain in affect for 5 years from June 27, 2005.

(18) Solvent-contaminated wipes, except for wipes that are hazardous waste due to the presence of trichloroethylene,

that are sent for disposal are not hazardous wastes from the point of generation provided that

(i) The solvent-contaminated wipes, when accumulated, stored, and transported, are contained in non-leaking,

closed containers that are labeled ‘‘Excluded Solvent- Contaminated Wipes.’’ The containers must be able

to contain free liquids, should free liquids occur. During accumulation, a container is considered closed

when there is complete contact between the fitted lid and the rim, except when it is necessary to add or

remove solvent-contaminated wipes. When the container is full, or when the solvent-contaminated wipes

are no longer being accumulated, or when the container is being transported, the container must be sealed

with all lids properly and securely affixed to the container and all openings tightly bound or closed

sufficiently to prevent leaks and emissions;

(ii) The solvent-contaminated wipes may be accumulated by the generator for up to 180 days from the start date

of accumulation for each container prior to being sent for disposal;

(iii) At the point of being transported for disposal, the solvent-contaminated wipes must contain no free liquids

as defined in § 260.10 of this chapter.

(iv) Free liquids removed from the solvent-contaminated wipes or from the container holding the wipes must be

managed according to the applicable regulations found in 40 CFR parts 260 through 273;

(v) Generators must maintain at their site the following documentation:

(A) Name and address of the landfill or combustor that is receiving the solvent-contaminated wipes;

(B) Documentation that the 180 day accumulation time limit in 40 CFR 261.4(b)(18)(ii) is being met;

(C) Description of the process the generator is using to ensure solvent-contaminated wipes contain no free

liquids at the point of being transported for disposal;

(vi) The solvent-contaminated wipes are sent for disposal

(A) To a municipal solid waste landfill regulated under 40 CFR part 258, including 40 CFR 258.40, or to a

hazardous waste landfill regulated under 40 CFR parts 264 or 265; or

(B) To a municipal waste combustor or other combustion facility regulated under section 129 of the Clean Air Act

or to a hazardous waste combustor, boiler, or industrial furnace regulated under 40 CFR parts 264, 265, or 266

subpart H.

(c) Hazardous wastes which are exempted from certain regulations.

A hazardous waste which is generated in a product or raw material storage tank, a product or raw material transport

vehicle or vessel, a product or raw material pipeline, or in a manufacturing process unit or an associated

non-waste-treatment-manufacturing unit, is not subject to regulation under parts 262 through 265, 268, 270, 271 and

124 of this chapter or to the notification requirements of section 3010 of RCRA until it exits the unit in which it was

generated, unless the unit is a surface impoundment, or unless the hazardous waste remains in the unit more than 90



days after the unit ceases to be operated for manufacturing, or for storage or transportation of product or raw

materials.

(d) Samples.

(1) Except as provided in paragraph (d)(2) of this section, a sample of solid waste or a sample of water, soil, or

air, which is collected for the sole purpose of testing to determine its characteristics or composition, is not

subject to any requirements of this part or parts 262 through 268 or part 270 or part 124 of this chapter or to

the notification requirements of section 3010 of RCRA, when:

(i) The sample is being transported to a laboratory for the purpose of testing; or

(ii) The sample is being transported back to the sample collector after testing; or

(iii) The sample is being stored by the sample collector before transport to a laboratory for testing; or

(iv) The sample is being stored in a laboratory before testing; or

(v) The sample is being stored in a laboratory after testing but before it is returned to the sample collector;

or

(vi) The sample is being stored temporarily in the laboratory after testing for a specific purpose (for

example, until conclusion of a court case or enforcement action where further testing of the sample

may be necessary).

(2) In order to qualify for the exemption in paragraphs (d)(1) (i) and (ii) of this section, a sample collector

shipping samples to a laboratory and a laboratory returning samples to a sample collector must:

(i) Comply with U.S. Department of Transportation (DOT), U.S. Postal Service (USPS), or any other

applicable shipping requirements; or

(ii) Comply with the following requirements if the sample collector determines that DOT, USPS, or other

shipping requirements do not apply to the shipment of the sample:

(A) Assure that the following information accompanies the sample:

(1) The sample collector's name, mailing address, and telephone number;

(2) The laboratory's name, mailing address, and telephone number;

(3) The quantity of the sample;

(4) The date of shipment; and

(5) A description of the sample.

(B) Package the sample so that it does not leak, spill, or vaporize from its packaging.

(3) This exemption does not apply if the laboratory determines that the waste is hazardous but the laboratory is

no longer meeting any of the conditions stated in paragraph (d)(1) of this section.



(e) Treatability Study Samples.

(1) Except as provided in paragraph (e)(2) of this section, persons who generate or collect samples for the

purpose of conducting treatability studies as defined in section 260.10, are not subject to any requirement

of parts 261 through 263 of this chapter or to the notification requirements of Section 3010 of RCRA, nor

are such samples included in the quantity determinations of §261.5 and §262.34 (d) when:

(i) The sample is being collected and prepared for transportation by the generator or sample collector; or

(ii) The sample is being accumulated or stored by the generator or sample collector prior to transportation

to a laboratory or testing facility; or

(iii) The sample is being transported to the laboratory or testing facility for the purpose of conducting a

treatability study.

(2) The exemption in paragraph (e)(1) of this section is applicable to samples of hazardous waste being

collected and shipped for the purpose of conducting treatability studies provided that:

(i) The generator or sample collector uses (in ``treatability studies'') no more than 1000 kg of any

non-acute hazardous waste, 1 kg of acute hazardous waste, or 250 kg of soils, water, or debris

contaminated with acute hazardous waste for each process being evaluated for each generated waste

stream; and

(ii) The mass of each sample shipment does not exceed 1000 kg of non-acute hazardous waste, 1 kg of

acute hazardous waste, or 250 kg of soils, water, or debris contaminated with acute hazardous waste;

and

(iii) The sample must be packaged so that it will not leak, spill, or vaporize from its packaging during

shipment and the requirements of paragraph A or B of this subparagraph are met.

(A) The transportation of each sample shipment complies with U.S. Department of Transportation

(DOT), U.S. Postal Service (USPS), or any other applicable shipping requirements; or

(B) If the DOT, USPS, or other shipping requirements do not apply to the shipment of the sample, the

following information must accompany the sample:

(1) The name, mailing address, and telephone number of the originator of the sample;

(2) The name, address, and telephone number of the facility that will perform the treatability

study;

(3) The quantity of the sample;

(4) The date of shipment; and

(5) A description of the sample, including its EPA Hazardous Waste Number.

(iv) The sample is shipped to a laboratory or testing facility which is exempt under §261.4 (f) or has an

appropriate RCRA permit or interim status.

(v) The generator or sample collector maintains the following records for a period ending 3 years after

completion of the treatability study:

(A) Copies of the shipping documents;

(B) A copy of the contract with the facility conducting the treatability study;

(C) Documentation showing:



(1) The amount of waste shipped under this exemption;

(2) The name, address, and EPA identification number of the laboratory or testing facility that

received the waste;

(3) The date the shipment was made; and

(4) Whether or not unused samples and residues were returned to the generator.

(vi) The generator reports the information required under paragraph (e)(2)(v)(C) of this section in its

biennial report.

(3) The Regional Administrator, or State Director (if located in an authorized State), may grant requests, on a

case-by-case basis, for quantity limits in excess of those specified in paragraph (e)(2)(i) of this section, for

up to an additional 500 kg of non-acute hazardous waste, 1 kg of acute hazardous waste, and 250 kg of

soils, water, or debris contaminated with acute hazardous waste, to conduct further treatability study

evaluation when: There has been an equipment or mechanical failure during the conduct of a treatability

study; there is a need to verify the results of a previously conducted treatability study; there is a need to

study and analyze alternative techniques within a previously evaluated treatment process; or there is a need

to do further evaluation of an ongoing treatability study to determine final specifications for treatment. The

additional quantities allowed are subject to all the provisions in paragraphs (e)(1) and (e)(2)(ii)(vi) of this

section. The generator or sample collector must apply to the Regional Administrator in the Region where

the sample is collected and provide in writing the following information:

(i) The reason why the generator or sample collector requires additional quantity of sample for the

treatability study evaluation and the additional quantity needed;

(ii) Documentation accounting for all samples of hazardous waste from the waste stream which have been

sent for or undergone treatability studies including the data each previous sample from the waste

stream was shipped, the quantity of each previous shipment, the laboratory or testing facility to which

it was shipped, what treatability study processes were conducted on each sample shipped, and the

available results of each treatability study;

(iii) A description of the technical modifications or change in specifications which will be evaluated and

the expected results;

(iv) If such further study is being required due to equipment or mechanical failure, the applicant must

include information regarding the reason for the failure or breakdown and also include what

procedures or equipment improvements have been made to protect against further breakdowns; and

(v) Such other information that the Regional Administrator considers necessary.

(f) Samples Undergoing Treatability Studies at Laboratories and Testing Facilities.

Samples undergoing treatability studies and the laboratory or testing facility conducting such treatability studies

(to the extent such facilities are not otherwise subject to RCRA requirements) are not subject to any requirement

of this part, part 124, parts 262-266, 268, and 270, or to the notification requirements of Section 3010 of RCRA

provided that the conditions of paragraphs (f) (1) through (11) of this section are met. A mobile treatment unit

(MTU) may qualify as a testing facility subject to paragraphs (f) (1) through (11) of this section. Where a group

of MTUs are located at the same site, the limitations specified in (f) (1) through (11) of this section apply to the

entire group of MTUs collectively as if the group were one MTU.

(1) No less than 45 days before conducting treatability studies, the facility notifies the Regional Administrator,

or State Director (if located in an authorized State), in writing that it intends to conduct treatability studies

under this paragraph.

(2) The laboratory or testing facility conducting the treatability study has an EPA identification number.

(3) No more than a total of 250 kg of `às received'' hazardous waste is subjected to initiation of treatment in all



treatability studies in any single day. `Às received'' waste refers to the waste as received in the shipment

from the generator or sample collector.

(4) The quantity of `às received'' hazardous waste stored at the facility for the purpose of evaluation in

treatability studies does not exceed 1000 kg, the total of which can include 500 kg of soils, water, or debris

contaminated with acute hazardous waste or 1 kg of acute hazardous waste. This quantity limitation does

not include:

(i) Treatability study residues; and

(ii) Treatment materials (including nonhazardous solid waste) added to `às received'' hazardous waste.

(5) No more than 90 days have elapsed since the treatability study for the sample was completed, or no more

than one year has elapsed since the generator or sample collector shipped the sample to the laboratory or

testing facility, whichever date first occurs.

(6) The treatability study does not involve the placement of hazardous waste on the land or open burning of

hazardous waste.

(7) The facility maintains records for 3 years following completion of each study that show compliance with

the treatment rate limits and the storage time and quantity limits. The following specific information must

be included for each treatability study conducted:

(i) The name, address, and EPA identification number of the generator or sample collector of each waste

sample;

(ii) The date the shipment was received;

(iii) The quantity of waste accepted;

(iv) The quantity of `às received'' waste in storage each day;

(v) The date the treatment study was initiated and the amount of `às received'' waste introduced to

treatment each day;

(vi) The date the treatability study was concluded;

(vii) The date any unused sample or residues generated from the treatability study were returned to the

generator or sample collector or, if sent to a designated facility, the name of the facility and the EPA

identification number.

(8) The facility keeps, on-site, a copy of the treatability study contract and all shipping papers associated with

the transport of treatability study samples to and from the facility for a period ending 3 years from the

completion date of each treatability study.

(9) The facility prepares and submits a report to the Regional Administrator, or State Director (if located in an

authorized State), by March 15 of each year that estimates the number of studies and the amount of waste

expected to be used in treatability studies during the current year, and includes the following information

for the previous calendar year:

(i) The name, address, and EPA identification number of the facility conducting the treatability studies;

(ii) The types (by process) of treatability studies conducted;

(iii) The names and addresses of persons for whom studies have been conducted (including their EPA

identification numbers);

(iv) The total quantity of waste in storage each day;



(v) The quantity and types of waste subjected to treatability studies;

(vi) When each treatability study was conducted;

(vii) The final disposition of residues and unused sample from each treatability study.

(10) The facility determines whether any unused sample or residues generated by the treatability study are

hazardous waste under §261.3 and, if so, are subject to parts 261 through 268, and part 270 of this chapter,

unless the residues and unused samples are returned to the sample originator under the §261.4 (e)

exemption.

(11) The facility notifies the Regional Administrator, or State Director (if located in an authorized State), by

letter when the facility is no longer planning to conduct any treatability studies at the site.

(g) Dredged material that is not a hazardous waste. Dredged material that is subject to the requirements of a

permit that has been issued under 404 of the Federal Water Pollution Control Act (33 U.S.C.1344) or

section 103 of the Marine Protection, Research, and Sanctuaries Act of 1972 (33 U.S.C. 1413) is not a

hazardous waste. For this paragraph (g), the following definitions apply:

(1) The term dredged material has the same meaning as defined in 40 CFR 232.2;

(2) The term permit means:

(i) A permit issued by the U.S. Army Corps of Engineers (Corps) or an approved State under section

404 of the Federal Water Pollution Control Act (33 U.S.C. 1344);

(ii) A permit issued by the Corps under section 103 of the Marine Protection, Research, and

Sanctuaries Act of 1972 (33 U.S.C. 1413); or

(iii) In the case of Corps civil works projects, the administrative equivalent of the permits referred to in

paragraphs (g)(2)(i) and (ii) of this section, as provided for in Corps regulations (for example, see

33 CFR 336.1, 336.2, and 337.6).

(h) Carbon dioxide stream injected for geologic sequestration. Carbon dioxide streams that are captured and

transported for purposes of injection into an underground injection well subject to the requirements for

Class VI Underground Injection Control wells, including the requirements in 40 CFR Parts 144 and 146 of

the Underground Injection Control Program of the Safe Drinking Water Act, are not a hazardous waste,

provided the following conditions are met:

(1) Transportation of the carbon dioxide stream must be in compliance with U.S. Department of

Transportation requirements, including the pipeline safety laws (49 U.S.C. 60101 et seq.) and

regulations (49 CFR Parts 190-199) of the U.S. Department of Transportation, and pipeline safety

regulations adopted and administered by a state authority pursuant to a certification under 49 U.S.C.

60105, as applicable.

(2) Injection of the carbon dioxide stream must be in compliance with the applicable requirements for

Class VI Underground Injection Control wells, including the applicable requirements in 40 CFR Parts

144 and 146;

(3) No hazardous wastes shall be mixed with, or otherwise co-injected with, the carbon dioxide stream;

and

(4)

(i) Any generator of a carbon dioxide stream, who claims that a carbon dioxide stream is excluded

under this paragraph (h), must have an authorized representative (as defined in 40 CFR 260.10)

sign a certification statement worded as follows:

I certify under penalty of law that the carbon dioxide stream that I am claiming to be excluded

under 40 CFR 261.4(h) has not been mixed with hazardous wastes, and I have transported the

carbon dioxide stream in compliance with (or have contracted with a pipeline operator or

transporter to transport the carbon dioxide stream in compliance with) Department of

Transportation requirements, including the pipeline safety laws (49 U.S.C. 60101 et seq.) and

regulations (49 CFR Parts 190-199) of the U.S. Department of Transportation, and the pipeline



safety regulations adopted and administered by a state authority pursuant to a certification under

49 U.S.C. 60105, as applicable, for injection into a well subject to the requirements for the Class

VI Underground Injection Control Program of the Safe Drinking Water Act.

(ii) Any Class VI Underground Injection Control well owner or operator, who claims that a carbon

dioxide stream is excluded under paragraph (h) of this section, must have an authorized

representative (as defined in 40 CFR 260.10) sign a certification statement worded as follows:

I certify under penalty of law that the carbon dioxide stream that I am claiming to be excluded

under 40 CFR 261.4(h) has not been mixed with, or otherwise co-injected with, hazardous

waste at the Underground Injection Control (UIC) Class VI permitted facility, and that

injection of the carbon dioxide stream is in compliance with the applicable requirements for

UIC Class VI wells, including the applicable requirements in 40 CFR Parts 144 and 146.

(iii) The signed certification statement must be kept on-site for no less than three years, and must be

made available within 72 hours of a written request from the Administrator, Regional

Administrator, or state Director (if located in an authorized state), or their designee. The signed

certification statement must be renewed every year that the exclusion is claimed, by having an

authorized representative (as defined in 40 CFR 260.10) annually prepare and sign a new copy of

the certification statement within one year of the date of the previous statement. The signed

certification statement must also be readily accessible on the facility's publicly-available Web site

(if such Web site exists) as a public notification with the title of “Carbon Dioxide Stream

Certification” at the time the exclusion is claimed.

261.5 (Reserved) Conditions for exemption for a very small quantity generator (VSQG) are located at 40 CFR

262.14. The definition of a VSQG is located at 40 CFR 260.10.

261.6 Requirements for recyclable materials.

(a) (1) Hazardous wastes that are recycled are subject to the requirements for generators, transporters, and storage

facilities of paragraphs (b) and (c) of this section, except for the materials listed in paragraphs (a)(2) and

(a)(3) of this section. Hazardous wastes that are recycled will be known as “recyclable materials.”

(2) The following recyclable materials are not subject to the requirements of this section but are regulated

under subparts C through N of part 266 of this chapter and all applicable provisions in parts 268, 270, and

124 of this chapter.

(i) Recyclable materials used in a manner constituting disposal (40 CFR part 266, subpart C);

(ii) Hazardous wastes burned (as defined in section 266.100(a)) in boilers and industrial furnaces that are

not regulated under subpart O of part 264 or 265 of this chapter (40 CFR part 266, subpart H)

(iii) Recyclable materials from which precious metals are reclaimed (40 CFR part 266, subpart F);

(iv) Spent lead-acid batteries that are being reclaimed (40 CFR part 266, subpart G).

(v) U.S. Filter Recovery Services XL waste (40 CFR part 266, subpart O).

(3) The following recyclable materials are not subject to regulation under parts 262 through parts 268, 270 or

124 of this chapter, and are not subject to the notification requirements of section 3010 of RCRA:

(i) Industrial ethyl alcohol that is reclaimed except that, unless provided otherwise in an international

agreement as specified in §262.58:

(A) A person initiating a shipment for reclamation in a foreign country, and any intermediary

arranging for the shipment, must comply with the requirements applicable to a primary exporter in

§§262.53, 262.56 (a)(1)-(4), (6), and (b), and 262.57, export such materials only upon consent of

the receiving country and in conformance with the EPA Acknowledgment of Consent as defined

in subpart E of part 262, and provide a copy of the EPA Acknowledgment of Consent to the



shipment to the transporter transporting the shipment for export;

(B) Transporters transporting a shipment for export may not accept a shipment if he knows the

shipment does not conform to the EPA Acknowledgment of Consent, must ensure that a copy of

the EPA Acknowledgment of Consent accompanies the shipment and must ensure that it is

delivered to the facility designated by the person initiating the shipment.

(ii) Scrap metal that is not excluded under §261.4(a)(13);

(iii) Fuels produced from the refining of oil-bearing hazardous waste along with normal process streams at

a petroleum refining facility if such wastes result from normal petroleum refining, production, and

transportation practices (this exemption does not apply to fuels produced from oil recovered from oil-

bearing hazardous waste, where such recovered oil is already excluded under §261.4(a)(12);

(iv)

(A) Hazardous waste fuel produced from oil-bearing hazardous wastes from petroleum refining,

production, or transportation practices, or produced from oil reclaimed from such hazardous

wastes, where such hazardous wastes are reintroduced into a process that does not use distillation

or does not produce products from crude oil so long as the resulting fuel meets the used oil

specification under §279.11 of this chapter and so long as no other hazardous wastes are used to

produce the hazardous waste fuel;

(B) Hazardous waste fuel produced from oil-bearing hazardous waste from petroleum refining

production, and transportation practices, where such hazardous wastes are reintroduced into a

refining process after a point at which contaminants are removed, so long as the fuel meets the

used oil fuel specification under §279.11 of this chapter; and

(C) Oil reclaimed from oil-bearing hazardous wastes from petroleum refining, production, and

transportation practices, which reclaimed oil is burned as a fuel without reintroduction to a

refining process, so long as the reclaimed oil meets the used oil fuel specification under §279.11

of this chapter.

(4) Used oil that is recycled and is also a hazardous waste solely because it exhibits a hazardous characteristic

is not subject to the requirements of parts 260 through 268 of this chapter, but is regulated under part 279 of

this chapter. Used oil that is recycled includes any used oil which is reused, following its original use, for

any purpose (including the purpose for which the oil was originally used). Such term includes, but is not

limited to, oil which is re-refined, reclaimed, burned for energy recovery, or reprocessed.

(5) Hazardous waste that is exported to or imported from designated member countries of the Organization for

Economic Cooperation and Development (OECD) (as defined in §262.58(a)(1)) for purpose of recovery is

subject to the requirements of 40 CFR part 262, subpart H, if it is subject to either the Federal manifesting

requirements of 40 CFR Part 262, to the universal waste management standards of 40 CFR Part 273, or to

State requirements analogous to 40 CFR Part 273.

(b) Generators and transporters of recyclable materials are subject to the applicable requirements of parts 262 and

263 of this chapter and the notification requirements under section 3010 of RCRA, except as provided in

paragraph (a) of this section.

(c) (1) Owners and operators of facilities that store recyclable materials before they are recycled are regulated

under all applicable provisions of subparts A though L, AA, BB, and CC of parts 264 and 265, and under

parts 124, 266, 267, 268, and 270 of this chapter and the notification requirements under section 3010 of

RCRA, except as provided in paragraph (a) of this section. (The recycling process itself is exempt from

regulation except as provided in §261.6(d).)

(2) Owners or operators of facilities that recycle recyclable materials without storing them before they are

recycled are subject to the following requirements, except as provided in paragraph (a) of this section:

(i) Notification requirements under section 3010 of RCRA;



(ii) Sections 265.71 and 265.72 (dealing with the use of the manifest and manifest discrepancies) of this

chapter.

(iii) Section 261.6(d) of this chapter.

(d) Owners or operators of facilities subject to RCRA permitting requirements with hazardous waste management

units that recycle hazardous wastes are subject to the requirements of subparts AA and BB of part 264, 265 or

267 of this chapter.



261.7 Residues of hazardous waste in empty containers.

(a) (1) Any hazardous waste remaining in either:

(i) an empty container; or

(ii) an inner liner removed from an empty container, as defined in paragraph (b) of this section, is not

subject to regulation under parts 261 through 268, 270, or 124 of this chapter or to the notification

requirements of section 3010 of RCRA.

(2) Any hazardous waste in either a container that is not empty or an inner liner removed from a container that

is not empty, as defined in paragraph (b) of this section, is subject to regulation under parts 261 through

268, 270 and 124 of this chapter and to the notification requirements of section 3010 of RCRA.

(b) (1) A container or an inner liner removed from a container that has held any hazardous waste, except a waste

that is a compressed gas or that is identified as an acute hazardous waste listed in §§261.31 or 261.33(e) of

this chapter is empty if:

(i) All wastes have been removed that can be removed using the practices commonly employed to remove

materials from that type of container, e.g., pouring, pumping, and aspirating, and

(ii) No more than 2.5 centimeters (one inch) of residue remain on the bottom of the container or inner

liner, or

(iii) (A) No more than 3 percent by weight of the total capacity of the container remains in the container or

inner liner if the container is less than or equal to 119 gallons in size, or

(B) No more than 0.3 percent by weight of the total capacity of the container remains in the container

or inner liner if the container is greater than 119 gallons in size.

(2) A container that has held a hazardous waste that is a compressed gas is empty when the pressure in the

container approaches atmospheric.

(3) A container or an inner liner removed from a container that has held an acute hazardous waste listed in

§§261.31 or 261.33(e) is empty if:

(i) The container or inner liner has been triple rinsed using a solvent capable of removing the

commercial chemical product or manufacturing chemical intermediate;

(ii) The container or inner liner has been cleaned by another method that has been shown in the

scientific literature, or by tests conducted by the generator, to achieve equivalent removal; or

(iii) In the case of a container, the inner liner that prevented contact of the commercial chemical

product or manufacturing chemical intermediate with the container, has been removed.



261.8 PCB wastes regulated under Toxic Substance Control Act.

The disposal of PCB-containing dielectric fluid and electric equipment containing such fluid authorized for use and

regulated under part 761 of this chapter and that are hazardous only because they fail the test for the Toxicity

Characteristic (Hazardous Waste Codes D018 through D043 only) are exempt from regulation under parts 261

through 265, and parts 268, 270, and 124 of this chapter, and the notification requirements of section 3010 of

RCRA.

261.9 Requirements for Universal Waste.

The wastes listed in this section are exempt from regulation under parts 262 through 270 of this chapter except as

specified in part 273 of this chapter and, therefore are not fully regulated as hazardous waste. The wastes listed in

this section are subject to regulation under 40 CFR part 273:

(a) Batteries as described in 40 CFR 273.2;

(b) Pesticides as described in §273.3 of this chapter;

(c) Mercury-containing equipment as described in §273.4 of this chapter; and

(d) Lamps as described in §273.5 of this chapter.

(e) Aerosol cans as described §273.6 of this chapter.



40 CFR 261 SUBPART C CHARACTERISTICS OF HAZARDOUS WASTE

§261.20 General.

§261.21 Characteristic of ignitability.

§261.22 Characteristic of corrosivity.

§261.23 Characteristic of reactivity.

§261.24 Toxicity characteristic.

261.20 General.

(a) A solid waste, as defined in §261.2, which is not excluded from regulation as a hazardous waste under §261.4

(b), is a hazardous waste if it exhibits any of the characteristics identified in this subpart.

[Comment: §262.11 of this chapter sets forth the generator's responsibility to determine whether his waste

exhibits one or more of the characteristics identified in this subpart]

(b) A hazardous waste which is identified by a characteristic in this subpart is assigned every EPA Hazardous

Waste Number that is applicable as set forth in this subpart. This number must be used in complying with the

notification requirements of section 3010 of the Act and all applicable recordkeeping and reporting

requirements under parts 262 through 265, 268, and 270 of this chapter.

(c) For purposes of this subpart, the Administrator will consider a sample obtained using any of the applicable

sampling methods specified in appendix I to be a representative sample within the meaning of part 260 of this

chapter.

[Comment: Since the appendix I sampling methods are not being formally adopted by the Administrator, a

person who desires to employ an alternative sampling method is not required to demonstrate the

equivalency of his method under the procedures set forth in §§260.20 and 260.21.]

261.21 Characteristic of ignitability.

(a) A solid waste exhibits the characteristic of ignitability if a representative sample of the waste has any of the

following properties:

(1) It is a liquid, other than an aqueous solution containing less than 24 percent alcohol by volume and has

flash point less than 60°C (140°F), as determined by a Pensky-Martens Closed Cup Tester, using the test

method specified in ASTM Standard D-93-79 or D-93-80 (incorporated by reference, see §260.11), or a

Setaflash Closed Cup Tester, using the test method specified in ASTM Standard D-3278-78 (incorporated

by reference, see §260.11).

(2) It is not a liquid and is capable, under standard temperature and pressure, of causing fire through friction,

absorption of moisture or spontaneous chemical changes and, when ignited, burns so vigorously and

persistently that it creates a hazard.

(3) It is an ignitable compressed gas.

(i) The term "compressed gas" shall designate any material or mixture having in the container an absolute

pressure exceeding 40 p.s.i. at 70°F or, regardless of the pressure at 70 °F, having an absolute pressure

exceeding 104 p.s.i. at 130°F; or any liquid flammable material having a vapor pressure exceeding 40

p.s.i. absolute at 100°F as determined by ASTM Test D-323.

(ii) A compressed gas shall be characterized as ignitable if any one of the following occurs:

(A) Either a mixture of 13 percent or less (by volume) with air forms a flammable mixture or the

flammable range with air is wider than 12 percent regardless of the lower limit. These limits shall

be determined at atmospheric temperature and pressure. The method of sampling and test

procedure shall be acceptable to the Bureau of Explosives and approved by the director, Pipeline

and Hazardous Materials Technology, U.S. Department of Transportation (see Note 2).

(B) Using the Bureau of Explosives' Flame Projection Apparatus (see Note 1), the flame projects more



than 18 inches beyond the ignition source with valve opened fully, or, the flame flashes back and

burns at the valve with any degree of valve opening.

(C) Using the Bureau of Explosives' Open Drum Apparatus (see Note 1), there is any significant

propagation of flame away from the ignition source.

(D) Using the Bureau of Explosives' Closed Drum Apparatus (see Note 1), there is any explosion of

the vapor-air mixture in the drum.

(4) It is an oxidizer. An oxidizer for the purpose of this subchapter is a substance such as a chlorate,

permanganate, inorganic peroxide, or a nitrate, that yields oxygen readily to stimulate the combustion of

organic matter (see Note 4).

(i) An organic compound containing the bivalent -O-O- structure and which may be considered a derivative of

hydrogen peroxide where one or more of the hydrogen atoms have been replaced by organic radicals must

be classed as an organic peroxide unless:

(A) The material meets the definition of a Class A explosive or a Class B explosive, as defined in

§261.23(a)(8), in which case it must be classed as an explosive,

(B) The material is forbidden to be offered for transportation according to 49 CFR 172.101 and 49 CFR

173.21,

(C) It is determined that the predominant hazard of the material containing an organic peroxide is other

than that of an organic peroxide, or

(D) According to data on file with the Pipeline and Hazardous Materials Safety Administration in the U.S.

Department of Transportation (see Note 3), it has been determined that the material does not present a

hazard in transportation.

(b) A solid waste that exhibits the characteristic of ignitability has the EPA Hazardous Waste Number of D001.

Note 1: A description of the Bureau of Explosives' Flame Projection Apparatus, Open Drum Apparatus, Closed

Drum Apparatus, and method of tests may be procured from the Bureau of Explosives.

Note 2: As part of a U.S. Department of Transportation (DOT) reorganization, the Office of Hazardous Materials

Technology (OHMT), which was the office listed in the 1980 publication of 49 CFR 173.300 for the

purposes of approving sampling and test procedures for a flammable gas, ceased operations on February

20, 2005. OHMT programs have moved to the Pipeline and Hazardous Materials Safety Administration

(PHMSA) in the DOT.

Note 3: As part of a U.S. Department of Transportation (DOT) reorganization, the Research and Special Programs

Administration (RSPA), which was the office listed in the 1980 publication of 49 CFR 173.151a for the

purposes of determining that a material does not present a hazard in transport, ceased operations on

February 20, 2005. RSPA programs have moved to the Pipeline and Hazardous Materials Safety

Administration (PHMSA) in the DOT.

Note 4: The DOT regulatory definition of an oxidizer was contained in §173.151 of 49 CFR, and the definition of

an organic peroxide was contained in paragraph 173.151a. An organic peroxide is a type of oxidizer.

261.22 Characteristic of corrosivity.

(a) A solid waste exhibits the characteristic of corrosivity if a representative sample of the waste has either of the


(1) It is aqueous and has a pH less than or equal to 2 or greater than or equal to 12.5, as determined by a pH

meter using Method 9040C in "Test Methods for Evaluating Solid Waste, Physical/Chemical Methods,"

EPA Publication SW-846, as incorporated by reference in §260.11 of this chapter.



(2) It is a liquid and corrodes steel (SAE 1020) at a rate greater than 6.35 mm (0.250 inch) per year at a test

temperature of 55 °C (130 °F) as determined by Method 1110A in "Test Methods for Evaluating Solid

Waste, Physical/Chemical Methods," EPA Publication SW-846, and as incorporated by reference in

§260.11 of this chapter.

(b) A solid waste that exhibits the characteristic of corrosivity has the EPA Hazardous Waste Number of D002.

261.23 Characteristic of reactivity.

(a) A solid waste exhibits the characteristic of reactivity if a representative sample of the waste has any of the


(1) It is normally unstable and readily undergoes violent change without detonating.

(2) It reacts violently with water.

(3) It forms potentially explosive mixtures with water.

(4) When mixed with water, it generates toxic gases, vapors or fumes in a quantity sufficient to present a

danger to human health or the environment.

(5) It is a cyanide or sulfide bearing waste which, when exposed to pH conditions between 2 and 12.5, can

generate toxic gases, vapors or fumes in a quantity sufficient to present a danger to human health or the

environment.

(6) It is capable of detonation or explosive reaction if it is subjected to a strong initiating source or if heated

under confinement.

(7) It is readily capable of detonation or explosive decomposition or reaction at standard temperature and

pressure.

(8) It is a forbidden explosive as defined in 49 CFR 173.54, or is a Division 1.1, 1.2 or 1.3 explosive as defined

in 49 CFR 173.50 and 173.53

(b) A solid waste that exhibits the characteristic of reactivity has the EPA Hazardous Waste Number of D003.

261.24 Toxicity characteristic.

(a) A solid waste (except manufactured gas plant waste) exhibits the characteristic of toxicity if, using the

Toxicity Characteristic Leaching Procedure, test Method 1311 in "Test Methods for Evaluating Solid Waste,

Physical/Chemical Methods," EPA Publication SW-846, as incorporated by reference in § 260.11 of this

chapter, the extract from a representative sample of the waste contains any of the contaminants listed in table

1 at the concentration equal to or greater than the respective value given in that table. Where the waste

contains less than 0.5 percent filterable solids, the waste itself, after filtering using the methodology outlined

in Method 1311, is considered to be the extract for the purpose of this section.



(b) A solid waste that exhibits the characteristic of toxicity has the EPA Hazardous Waste Number specified in

Table I that corresponds to the toxic contaminant causing it to be hazardous.

Table 1 Maximum Concentration of Contaminants for the Toxicity Characteristic

EPA HW

No.1

Contaminant Regulatory

Level (mg/l)

D004 Arsenic 5.0

D005 Barium 100.0

D018 Benzene 0.5

D006 Cadmium 1.0

D019 Carbon tetrachloride 0.5

D020 Chlordane 0.03

D021 Chlorobenzene 100.0

D022 Chloroform 6.0

D007 Chromium 5.0.

D023 o-Cresol 200.03

D024 m-Cresol 200.03

D025 p-Cresol 200.03

D026 Cresol 200.03

D016 2,4-D 10.0

D027 1,4-Dichlorobenzene 7.5

D028 1,2-Dichloroethane 0.5

D029 1,1-Dichloroethylene 0.7

D030 2,4-Dinitrotoluene 0.132

D012 Endrin 0.02

D031 Heptachlor (and its epoxide) 0.008

D032 Hexachlorobenzene 0.132

D033 Hexachlorobutadiene 0.5

D034 Hexachloroethane 3.0

D008 Lead 5.0

D013 Lindane 0.4

D009 Mercury 0.2

D014 Methoxychlor 10.0

D035 Methyl ethyl ketone 200.0

D036 Nitrobenzene 2.0

D037 Pentachlorophenol 100.0

D038 Pyridine 5.02

D010 Selenium 1.0

D011 Silver 5.0

D039 Tetrachloroethylene 0.7

D015 Toxaphene 0.5

D040 Trichloroethylene 0.5



D017 2,4,5-TP (Silvex) 1.0

D043 Vinyl chloride 0.2

1. Hazardous waste number.

2. Quantitation limit is greater than the calculated regulatory level. The quantitation limit therefore becomes the

regulatory level.

3. If o-, m-, and p-Cresol concentrations cannot be differentiated, the total cresol (D026) concentration is used.

The regulatory level of total cresol is 200 mg/l.



261 Subpart D Lists of Hazardous Wastes

§261.30 General.

§261.31 Hazardous wastes from non-specific sources.

§261.32 Hazardous wastes from specific sources.

§261.33 Discarded commercial chemical products, off-specification species, container residues, and spill residues

thereof.

§261.35 Deletion of certain hazardous waste codes following equipment cleaning and replacement.

261.30 General.

(a) A solid waste is a hazardous waste if it is listed in this subpart, unless it has been excluded from this list under

§§260.20 and 260.22.

(b) The Administrator will indicate his basis for listing the classes or types of wastes listed in this subpart by

employing one or more of the following Hazard Codes:

Ignitable Waste (I)

Corrosive Waste (C)

Reactive Waste (R)

Toxicity Characteristic Waste (E)

Acute Hazardous Waste (H)

Toxic Waste (T)

Appendix VII identifies the constituent which caused the Administrator to list the waste as a Toxicity

Characteristic Waste (E) or Toxic Waste (T) in §§261.31 and 261.32.

(c) Each hazardous waste listed in this subpart is assigned an EPA Hazardous Waste Number which precedes the

name of the waste. This number must be used in complying with the notification requirements of Section 3010

of the Act and certain recordkeeping and reporting requirements under parts 262 through 265, 267, 268, and

270 of this chapter

(d) The following hazardous wastes listed in §261.31 are subject to the exclusion limits for acutely hazardous

wastes established in §261.5: EPA Hazardous Wastes Nos. F020, F021, F022, F023, F026 and F027

261.31 Hazardous wastes from non-specific sources.

(a) The following solid wastes are listed hazardous wastes from non-specific sources unless they are excluded

under §§260.20 and 260.22 and listed in appendix IX.

F001 ............................................................................................................................................................................ (T)

The following spent halogenated solvents used in degreasing: Tetrachloroethylene, trichloroethylene, methylene

chloride, 1,1,1- trichloroethane, carbon tetrachloride, and chlorinated fluorocarbons; all spent solvent

mixtures/blends used in degreasing containing, before use, a total of ten percent or more (by volume) of one or more

of the above halogenated solvents or those solvents listed in F002, F004, and F005; and still bottoms from the

recovery of these spent solvents and spent solvent mixtures

F002 ............................................................................................................................................................................ (T)

The following spent halogenated solvents: Tetrachloroethylene, methylene chloride, trichloroethylene, 1,

1,1-trichloroethane, chlorobenzene, 1,1,2-trichloro- 1,2,2-trifluoroethane, ortho- dichlorobenzene,

trichlorofluoromethane, and 1, 1,2-trichloroethane; all spent solvent mixtures/blends containing, before use, a total

of ten percent or more (by volume) of one or more of the above halogenated solvents or those listed in F001, F004,

or F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures

F003 ........................................................................................................................................................................... (I)*

The following spent non halogenated solvents: Xylene, acetone, ethyl acetate, ethyl benzene, ethyl ether, methyl

isobutyl ketone, n-butyl alcohol, cyclohexanone, and methanol; all spent solvent mixtures/blends containing, before



use, only the above spent non-halogenated solvents; and all spent solvent mixtures/blends containing, before use,

one or more of the above non- halogenated solvents, and, a total of ten percent or more (by volume) of one or more

of those solvents listed in F001, F002, F004, and F005; and still bottoms from the recovery of these spent solvents

and spent solvent mixtures

F004 ............................................................................................................................................................................ (T)

The following spent non-halogenated solvents: Cresols and cresylic acid, and nitrobenzene; all spent solvent

mixtures/blends containing, before use, a total of ten percent or more (by volume) of one or more of the above

non-halogenated solvents or those solvents listed in F001, F002, and F005; and still bottoms from the recovery of

these spent solvents and spent solvent mixtures

F005 ......................................................................................................................................................................... (I,T)

The following spent non-halogenated solvents: Toluene, methyl ethyl ketone, carbon disulfide, isobutanol, pyridine,

benzene, 2- ethoxyethanol, and 2- nitropropane; all spent solvent mixtures/blends containing, before use, a total of

ten percent or more (by volume) of one or more of the above non-halogenated solvents or those solvents listed in

F001, F002, or F004; and still bottoms from the recovery of these spent solvents and spent solvent mixtures

F006 .............................................................................................................................................................................. ()

Wastewater treatment sludges from electroplating operations except from the following processes:

(1) Sulfuric acid anodizing of aluminum; (2) tin plating on carbon steel; (3) zinc plating (segregated basis) on carbon

steel; (4) aluminum or zinc-aluminum plating on carbon steel; (5) cleaning/stripping associated with tin, zinc and

aluminum plating on carbon steel; and (6) chemical etching and milling of aluminum

F007 ........................................................................................................................................................................ (R,T)

Spent cyanide plating bath solutions from electroplating operations

F008 ........................................................................................................................................................................ (R,T)

Plating bath residues from the bottom of plating baths from electroplating operations where cyanides are used in the

process

F009 ........................................................................................................................................................................ (R,T)

Spent stripping and cleaning bath solutions from electroplating operations where cyanides are used in the process

F010 ........................................................................................................................................................................ (R,T)

Quenching bath residues from oil baths from metal heat treating operations where cyanides are used in the process

F011 ........................................................................................................................................................................ (R,T)

Spent cyanide solutions from salt bath pot cleaning from metal heat treating operations

F012 ............................................................................................................................................................................ (T)

Quenching waste water treatment sludges from metal heat treating operations where cyanides are used in the process

F019 ............................................................................................................................................................................ (T)

Wastewater treatment sludges from the chemical conversion coating of aluminum except from zirconium

phosphating in aluminum can washing when such phosphating is an exclusive conversion coating process.

Wastewater treatment sludges from the manufacturing of motor vehicles using a zinc phosphating process will not

be subject to this listing at the point of generation if the wastes are not placed outside on the land prior to shipment

to a landfill for disposal and are either: disposed in a Subtitle D municipal or industrial landfill unit that is equipped

with a single clay liner and is permitted, licensed or otherwise authorized by the state; or disposed in a landfill unit

subject to, or otherwise meeting, the landfill requirements in § 258.40, § 264.301 or § 265.301. For the purposes of

this listing, motor vehicle manufacturing is defined in paragraph (b)(4)(i) of this section and (b)(4)(ii) of this section

describes the recordkeeping requirements for motor vehicle manufacturing facilities.



F020 ........................................................................................................................................................................... (H)

Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production or

manufacturing use (as a reactant, chemical intermediate, or component in a formulating process) of tri- or

tetrachlorophenol, or of intermediates used to produce their pesticide derivatives. (This listing does not include

wastes from the production of Hexachlorophene from highly purified 2,4,5- trichlorophenol.)

F021 ........................................................................................................................................................................... (H)

Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production or

manufacturing use (as a reactant, chemical intermediate, or component in a formulating process) of

pentachlorophenol, or of intermediates used to produce its derivatives

F022 ........................................................................................................................................................................... (H)

Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the manufacturing use (as a

reactant, chemical intermediate, or component in a formulating process) of tetra-, penta-, or hexachlorobenzenes

under alkaline conditions

F023 ........................................................................................................................................................................... (H)

Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production of materials

on equipment previously used for the production or manufacturing use (as a reactant, chemical intermediate, or

component in a formulating process) of tri- and tetrachlorophenols. (This listing does not include wastes from

equipment used only for the production or use of Hexachlorophene from highly purified 2,4,5- trichlorophenol.)

F024 ............................................................................................................................................................................ (T)

Process wastes, including but not limited to, distillation residues, heavy ends, tars, and reactor clean-out wastes,

from the production of certain chlorinated aliphatic hydrocarbons by free radical catalyzed processes. These

chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and including five,

with varying amounts and positions of chlorine substitution. (This listing does not include wastewaters, wastewater

treatment sludges, spent catalysts, and wastes listed in §261.31 or §261.32.)

F025 ............................................................................................................................................................................ (T)

Condensed light ends, spent filters and filter aids, and spent desiccant wastes from the production of certain

chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are

those having carbon chain lengths ranging from one to and including five, with varying amounts and positions of

chlorine substitution

F026 ........................................................................................................................................................................... (H)

Wastes (except wastewater and spent carbon from hydrogen chloride purification) from the production of materials

on equipment previously used for the manufacturing use (as a reactant, chemical intermediate, or component in a

formulating process) of tetra-, penta-, or hexachlorobenzene under alkaline conditions

F027 ........................................................................................................................................................................... (H)

Discarded unused formulations containing tri-, tetra-, or pentachlorophenol or discarded unused formulations

containing compounds derived from these chlorophenols. (This listing does not include formulations containing

Hexachlorophene synthesized from prepurified 2, 4,5-trichlorophenol as the sole component.)

F028 ............................................................................................................................................................................ (T)

Residues resulting from the incineration or thermal treatment of soil contaminated with EPA Hazardous Waste Nos.

F020, F021, F022, F023, F026, and F027

F032 ............................................................................................................................................................................ (T)

Wastewaters (except those that have not come into contact with process contaminants), process residuals,

preservative drippage, and spent formulations from wood preserving processes generated at plants that currently use

or have previously used chlorophenolic formulations (except potentially cross-contaminated wastes that have had

the F032 waste code deleted in accordance with § 261.35 of this chapter or potentially cross- contaminated wastes

that are otherwise currently regulated as hazardous wastes (i.e., F034 or F035), and where the generator does not

resume or initiate use of chlorophenolic formulations). This listing does not include K001 bottom sediment sludge

from the treatment of wastewater from wood preserving processes that use creosote and/or pentachlorophenol



F034 ............................................................................................................................................................................ (T)


preservative drippage, and spent formulations from wood preserving processes generated at plants that use creosote

formulations. This listing does not include K001 bottom sediment sludge from the treatment of wastewater from

wood preserving processes that use creosote and/or pentachlorophenol

F035 ............................................................................................................................................................................ (T)


preservative drippage, and spent formulations from wood preserving processes generated at plants that use inorganic

preservatives containing arsenic or chromium. This listing does not include K001 bottom sediment sludge from the

treatment of wastewater from wood preserving processes that use creosote and/or pentachlorophenol

F037 ............................................................................................................................................................................ (T)

Petroleum refinery primary oil/water/solids separation sludge—Any sludge generated from the gravitational

separation of oil/water/solids during the storage or treatment of process wastewaters and oily cooling wastewaters

from petroleum refineries. Such sludges include, but are not limited to, those generated in oil/water/solids

separators; tanks and impoundments; ditches and other conveyances; sumps; and stormwater units receiving dry

weather flow. Sludge generated in stormwater units that do not receive dry weather flow, sludges generated from

non-contact once-through cooling waters segregated for treatment from other process or oily cooling waters, sludges

generated in aggressive biological treatment units as defined in §261.31(b)(2) (including sludges generated in one or

more additional units after wastewaters have been treated in aggressive biological treatment units) and K051 wastes

are not included in this listing. This listing does include residuals generated from processing or recycling oil-bearing

hazardous secondary materials excluded under §261.4(a)(12)(i), if those residuals are to be disposed of

F038 ............................................................................................................................................................................ (T)

Petroleum refinery secondary (emulsified) oil/water/solids separation sludge Any sludge and/or float generated from

the physical and/or chemical separation of oil/water/solids in process wastewaters and oily cooling wastewaters

from petroleum refineries. Such wastes include, but are not limited to, all sludges and floats generated in: induced

air flotation (IAF) units, tanks and impoundments, and all sludges generated in DAF units. Sludges generated in

stormwater units that do not receive dry weather flow, sludges generated from non- contact once-through cooling

waters segregated for treatment from other process or oily cooling waters, sludges and floats generated in aggressive

biological treatment units as defined in §261.31 (b)(2) (including sludges and floats generated in one or more

additional units after wastewaters have been treated in aggressive biological treatment units) and F037, K048, and

K051 wastes are not included in this listing

F039 ............................................................................................................................................................................ (T)

Leachate (liquids that have percolated through land disposed wastes) resulting from the disposal of more than one

restricted waste classified as hazardous under subpart D of this part. (Leachate resulting from the disposal of one or

more of the following EPA Hazardous Wastes and no other Hazardous Wastes retains its EPA Hazardous Waste

Number(s): F020, F021, F022, F026, F027, and/or F028.)

*(I,T) should be used to specify mixtures that are ignitable and contain toxic constituents.

1. The F032, F034, and F305 listings are administratively stayed with respect to the process area receiving

drippage of these wastes provided persons desiring to continue operating notify EPA by August 6, 1991 of their

intent to upgrade or install drip pads, and by November 6, 1991 provide evidence to EPA that they have

adequate financing to pay for drip pad upgrades or installation, as provided in the administrative stay. The stay

of the listings will remain in effect until February 6, 1992 for existing drip pads and until May 6, 1992 for new

drip pads.

(b) Listing Specific Definitions:

(1) For the purposes of the F037 and F038 listings, oil/water/solids is defined as oil and/or water and/or solids.

(2) (i) For the purposes of the F037 and F038 listings, aggressive biological treatment units are defined as

units which employ one of the following four treatment methods: activated sludge; trickling filter;

rotating biological contactor for the continuous accelerated biological oxidation of wastewaters; or

high-rate aeration. High-rate aeration is a system of surface impoundments or tanks, in which intense



mechanical aeration is used to completely mix the wastes, enhance biological activity, and (A) the

units employs a minimum of 6 hp per million gallons of treatment volume; and either (B) the hydraulic

retention time of the unit is no longer than 5 days; or (C) the hydraulic retention time is no longer than

30 days and the unit does not generate a sludge that is a hazardous waste by the Toxicity

Characteristic.

(ii) Generators and treatment, storage and disposal facilities have the burden of proving that their sludges

are exempt from listing as F037 and F038 wastes under this definition. Generators and treatment,

storage and disposal facilities must maintain, in their operating or other onsite records, documents and

data sufficient to prove that: (A) the unit is an aggressive biological treatment unit as defined in this

subsection; and (B) the sludges sought to be exempted from the definitions of F037 and/or F038 were

actually generated in the aggressive biological treatment unit.

(3) (i) For the purposes of the F037 listing, sludges are considered to be generated at the moment of

deposition in the unit, where deposition is defined as at least a temporary cessation of lateral particle

movement.

(ii) For the purposes of the F038 listing,

(A) sludges are considered to be generated at the moment of deposition in the unit, where deposition is

defined as at least a temporary cessation of lateral particle movement and

(B) floats are considered to be generated at the moment they are formed in the top of the unit.

(4) For the purposes of the F019 listing, the following apply to wastewater treatment sludges from the

manufacturing of motor vehicles using a zinc phosphating process.

(i) Motor vehicle manufacturing is defined to include the manufacture of automobiles and light

trucks/utility vehicles (including light duty vans, pick-up trucks, minivans, and sport utility

vehicles). Facilities must be engaged in manufacturing complete vehicles (body and chassis or

unibody) or chassis only.

(ii) Generators must maintain in their on-site records documentation and information sufficient to prove

that the wastewater treatment sludges to be exempted from the F019 listing meet the conditions of

the listing. These records must include: the volume of waste generated and disposed of off site;

documentation showing when the waste volumes were generated and sent off site; the name and

address of the receiving facility; and documentation confirming receipt of the waste by the

receiving facility. Generators must maintain these documents on site for no less than three years.

The retention period for the documentation is automatically extended during the course of any

enforcement action or as requested by the Regional Administrator or the state regulatory authority.



261.32 HAZARDOUS WASTES FROM SPECIFIC SOURCES.

a. The following solid wastes are listed hazardous wastes from specific sources unless they are excluded under

§§260.20 and 260.22 and listed in appendix IX.

Wood preservation:

K001 ........................................................................................................................................................................... (T)

Bottom sediment sludge from the treatment of wastewaters from wood preserving processes that use creosote and/or

pentachlorophenol

Inorganic pigments:

K002 ........................................................................................................................................................................... (T)

Wastewater treatment sludge from the production of chrome yellow and orange pigments

K003 ........................................................................................................................................................................... (T)

Wastewater treatment sludge from the production of molybdate orange pigments

K004 ........................................................................................................................................................................... (T)

Wastewater treatment sludge from the production of zinc yellow pigments

K005 ........................................................................................................................................................................... (T)

Wastewater treatment sludge from the production of chrome green pigments

K006 ........................................................................................................................................................................... (T)

Wastewater treatment sludge from the production of chrome oxide green pigments (anhydrous and hydrated)

K007 ........................................................................................................................................................................... (T)

Wastewater treatment sludge from the production of iron blue pigments

K008 ........................................................................................................................................................................... (T)

Oven residue from the production of chrome oxide green pigments

Organic chemicals:

K009 ........................................................................................................................................................................... (T)

Distillation bottoms from the production of acetaldehyde from ethylene

K010 ........................................................................................................................................................................... (T)

Distillation side cuts from the production of acetaldehyde from ethylene

K011 ....................................................................................................................................................................... (R,T)

Bottom stream from the wastewater stripper in the production of acrylonitrile

K013 ....................................................................................................................................................................... (R,T)

Bottom stream from the acetonitrile column in the production of acrylonitrile

K014 ........................................................................................................................................................................... (T)

Bottoms from the acetonitrile purification column in the production of acrylonitrile

K015 ........................................................................................................................................................................... (T)

Still bottoms from the distillation of benzyl chloride

K016 ........................................................................................................................................................................... (T)

Heavy ends or distillation residues from the production of carbon tetrachloride

K017 ........................................................................................................................................................................... (T)

Heavy ends (still bottoms) from the purification column in the production of epichlorohydrin



K018 ........................................................................................................................................................................... (T)

Heavy ends from the fractionation column in ethyl chloride production

K019 ........................................................................................................................................................................... (T)

Heavy ends from the distillation of ethylene dichloride in ethylene dichloride production

K020 ........................................................................................................................................................................... (T)

Heavy ends from the distillation of vinyl chloride in vinyl chloride monomer production

K021 ........................................................................................................................................................................... (T)

Aqueous spent antimony catalyst waste from fluoromethanes production

K022 ........................................................................................................................................................................... (T)

Distillation bottom tars from the production of phenol/acetone from cumene

K023 ........................................................................................................................................................................... (T)

Distillation light ends from the production of phthalic anhydride from naphthalene

K024 ........................................................................................................................................................................... (T)

Distillation bottoms from the production of phthalic anhydride from naphthalene

K025 ........................................................................................................................................................................... (T)

Distillation bottoms from the production of nitrobenzene by the nitration of benzene

K026 ........................................................................................................................................................................... (T)

Stripping still tails from the (T) production of methyl ethyl pyridines

K027 ....................................................................................................................................................................... (R,T)

Centrifuge and distillation residues from toluene diisocyanate production

K028 ........................................................................................................................................................................... (T)

Spent catalyst from the hydrochlorinator reactor in the production of 1,1,1- trichloroethane

K029 ........................................................................................................................................................................... (T)

Waste from the product steam stripper in the production of 1,1,1-trichloroethane

K030 ........................................................................................................................................................................... (T)

Column bottoms or heavy ends from the combined production of trichloroethylene and perchloroethylene

K083 ........................................................................................................................................................................... (T)

Distillation bottoms from aniline production

K085 ........................................................................................................................................................................... (T)

Distillation or fractionation column bottoms from the production of chlorobenzenes

K093 ........................................................................................................................................................................... (T)

Distillation light ends from the production of phthalic anhydride from ortho-xylene

K094 ........................................................................................................................................................................... (T)

Distillation bottoms from the production of phthalic anhydride from ortho-xylene

K095 ........................................................................................................................................................................... (T)

Distillation bottoms from the production of 1,1,1- trichloroethane

K096 ........................................................................................................................................................................... (T)

Heavy ends from the heavy ends column from the production of 1,1,1-trichloroethane

K103 ........................................................................................................................................................................... (T)



Process residues from aniline extraction from the production of aniline

K104 ........................................................................................................................................................................... (T)

Combined wastewater streams generated from nitrobenzene/aniline production

K105 ........................................................................................................................................................................... (T)

Separated aqueous stream from the reactor product washing step in the production of chlorobenzenes

K107 ....................................................................................................................................................................... (C,T)

Column bottoms from product separation from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic

acid hydrazides

K108 ........................................................................................................................................................................ (I,T)

Condensed column overheads from product separation and condensed reactor vent gases from the production of

1,1- dimethyl hydrazine (UDMH) from carboxylic acid hydrazides

K109 ........................................................................................................................................................................... (T)

Spent filter cartridges from product purification from the production of 1,1- dimethylhydrazine (UDMH) from

carboxylic acid hydrazides

K110 ........................................................................................................................................................................... (T)

Condensed column overheads from intermediate separation from the production of 1,1- dimethylhydrazine (UDMH)

from carboxylic acid hydrazides

K111 ....................................................................................................................................................................... (C,T)

Product washwaters from the production of dinitrotoluene via nitration of toluene

K112 ........................................................................................................................................................................... (T)

Reaction by-product water from the drying column in the production of toluene diamine via hydrogenation of

dinitrotoluene

K113 ........................................................................................................................................................................... (T)

Condensed liquid light ends from the purification of toluenediamine in the production of toluenediamine via

hydrogenation of dinitrotoluene

K114 ........................................................................................................................................................................... (T)

Vicinals from the purification of toluenediamine in the production of toluenediamine via hydrogenation of

dinitrotoluene

K115 ........................................................................................................................................................................... (T)

Heavy ends from the purification of toluenediamine in the production of toluenediamine via hydrogenation of

dinitrotoluene

K116 ........................................................................................................................................................................... (T)

Organic condensate from the solvent recovery column in the production of toluene diisocyanate via phosgenation of

toluenediamine

K117 ........................................................................................................................................................................... (T)

Wastewater from the reactor vent gas scrubber in the production of ethylene dibromide via bromination of ethene

K118 ........................................................................................................................................................................... (T)

Spent adsorbent solids from purification of ethylene dibromide in the production of ethylene dibromide via

bromination of ethene

K136 ........................................................................................................................................................................... (T)

Still bottoms from the purification of ethylene dibromide in the production of ethylene dibromide via bromination of

ethene



K140 On 3-17-2000 K140 was removed from the list of Hazardous Waste from Specific Sources.

K149 ........................................................................................................................................................................... (T)

Distillation bottoms from the production of alpha- (or methyl-) chlorinated toluenes, ring-chlorinated toluenes,

benzoyl chlorides, and compounds with mixtures of these functional groups, (This waste does not include still

bottoms from the distillation of benzyl chloride.)

K150 ........................................................................................................................................................................... (T)

Organic residuals, excluding spent carbon adsorbent, from the spent chlorine gas and hydrochloric acid recovery

processes associated with the production of alpha- (or methyl-) chlorinated toluenes, ring-chlorinated toluenes,

benzoyl chlorides, and compounds with mixtures of these functional groups

K151 ........................................................................................................................................................................... (T)

Wastewater treatment sludges,excluding neutralization and biological sludges, generated during the treatment of

wastewaters from the production of alpha- (or methyl-) chlorinated toluenes, ring-chlorinated toluenes, benzoyl

chlorides, and compounds with mixtures of these functional groups

K156 ........................................................................................................................................................................... (T)

Organic waste (including heavy ends, still bottoms, light ends, spent solvents, filtrates, and decantates) from the

production of carbamates and carbamoyl oximes. (This listing does not apply to wastes generated from the

manufacture of 3-iodo-2-propynyl n-butylcarbamate.)

K157 ........................................................................................................................................................................... (T)

Wastewaters (including scrubber waters, condenser waters, washwaters, and separation waters) from the production

of carbamates and carbamoyl oximes. (This listing does not apply to wastes generated from the manufacture of

3-iodo-2-propynyl n-butylcarbamate.)

K158 ........................................................................................................................................................................... (T)

Bag house dusts and filter/separation solids from the production of carbamates and carbamoyl oximes. (This listing

does not apply to wastes generated from the manufacture of 3-iodo-2-propynyl n-butylcarbamate.)

K159 ........................................................................................................................................................................... (T)

Organics from the treatment of thiocarbamate wastes

K161 ....................................................................................................................................................................... (R,T)

Purification solids (including filtration, evaporation, and centrifugation solids), bag house dust and floor sweepings

from the production of dithiocarbamate acids and their salts. (This listing does not include K125 or K126.)

K174 ........................................................................................................................................................................... (T)

Wastewater treatment sludges from the production of ethylene dichloride or vinyl chloride monomer (including

sludges that result from commingled ethylene dichloride or vinyl chloride monomer wastewater and other

wastewater), unless the sludges meet the following conditions: (i) they are disposed of in a subtitle C or non-

hazardous landfill licensed or permitted by the state or federal government; (ii) they are not otherwise placed on the

land prior to final disposal; and (iii) the generator maintains documentation demonstrating that the waste was either

disposed of in an on-site landfill or consigned to a transporter or disposal facility that provided a written

commitment to dispose of the waste in an off- site landfill. Respondents in any action brought to enforce the

requirements of subtitle C must, upon a showing by the government that the respondent managed wastewater

treatment sludges from the production of vinyl chloride monomer or ethylene dichloride, demonstrate that they meet

the terms of the exclusion set forth above. In doing so, they must provide appropriate documentation (e.g., contracts

between the generator and the landfill owner/ operator, invoices documenting delivery of waste to landfill, etc.) that

the terms of the exclusion were met.

K175 ........................................................................................................................................................................... (T)

Wastewater treatment sludges from the production of vinyl chloride monomer using mercuric chloride catalyst in an

acetylene-based process.

Inorganic chemicals:



K071 ........................................................................................................................................................................... (T)

Brine purification muds from the mercury cell process in chlorine production, where separately

prepurified brine is not used

K073 ........................................................................................................................................................................... (T)

Chlorinated hydrocarbon waste from the purification step of the diaphragm cell process using graphite anodes in

chlorine production

K106 ........................................................................................................................................................................... (T)

Wastewater treatment sludge from the mercury cell process in chlorine production

K176 ........................................................................................................................................................................... (E)

Baghouse filters from the production of antimony oxide, including filters from the production of intermediates (e.g.,

antimony metal or crude antimony oxide)

K177 ........................................................................................................................................................................... (T)

Slag from the production of antimony oxide that is speculatively accumulated or disposed, including slag from the

production of intermediates (e.g., antimony metal or crude antimony oxide)

K178 ........................................................................................................................................................................... (T)

Residues from manufacturing and manufacturing-site storage of ferric chloride from acids formed during the

production of titanium dioxide using the chloride-ilmenite process

K181 ........................................................................................................................................................................... (T)

Nonwastewaters from the production of dyes and/or pigments (including nonwastewaters commingled at the point

of generation with nonwastewaters from other processes) that, at the point of generation, contain mass loadings of

any of the constituents identified in paragraph (c) of this section that are equal to or greater than the corresponding

paragraph (c) levels, as determined on a calendar year basis. These wastes will not be hazardous if the

nonwastewaters are: (i) disposed in a Subtitle D landfill unit subject to the design criteria in § 258.40,(ii) disposed

in a Subtitle C landfill unit subject to either § 264.301 or § 265.301,(iii) disposed in other Subtitle D landfill units

that meet the design criteria in § 258.40, § 264.301, or § 265.301, or(iv) treated in a combustion unit that is

permitted under Subtitle C, or an onsite combustion unit that is permitted under the Clean Air Act. For the purposes

ofthis listing, dyes and/or pigments production is defined in paragraph (b)(1) of this section. Paragraph (d) of this

section describes the process for demonstrating that a facility's nonwastewaters are not K181. This listing does not

apply to wastes that are otherwise identified as hazardous under § § 261.21-261.24 and 261.31-261.33 at the point of

generation. Also, the listing does not apply to wastes generated before any annual mass loading limit is met

Pesticides:

K031 ........................................................................................................................................................................... (T)

By-product salts generated in the production of MSMA and cacodylic acid

K032 ........................................................................................................................................................................... (T)

Wastewater treatment sludge from the production of chlordane

K033 ........................................................................................................................................................................... (T)

Wastewater and scrub water from the chlorination of cyclopentadiene in the production of chlordane

K034 ........................................................................................................................................................................... (T)

Filter solids from the filtration of hexachlorocyclopentadiene in the production of chlordane

K035 ........................................................................................................................................................................... (T)

Wastewater treatment sludges generated in the production of creosote

K036 ........................................................................................................................................................................... (T)

Still bottoms from toluene reclamation distillation in the production of disulfoton



K037 ........................................................................................................................................................................... (T)

Wastewater treatment sludges from the production of disulfoton

K038 ........................................................................................................................................................................... (T)

Wastewater from the washing and stripping of phorate production

K039 ........................................................................................................................................................................... (T)

Filter cake from the filtration of diethylphosphorodithioic acid in the production of phorate

K040 ........................................................................................................................................................................... (T)

Wastewater treatment sludge from the production of phorate

K041 ........................................................................................................................................................................... (T)

Wastewater treatment sludge from the production of toxaphene

K042 ........................................................................................................................................................................... (T)

Heavy ends or distillation residues from the distillation of tetrachlorobenzene in the production of 2,4,5-T

K043 ........................................................................................................................................................................... (T)

2,6-Dichlorophenol waste from the production of 2,4-D

K097 ........................................................................................................................................................................... (T)

Vacuum stripper discharge from the chlordane chlorinator in the production of chlordane

K098 ........................................................................................................................................................................... (T)

Untreated process wastewater from the production of toxaphene

K099 ........................................................................................................................................................................... (T)

Untreated wastewater from the production of 2,4-D

K123 ........................................................................................................................................................................... (T)

Process wastewater (including supernates, filtrates, and washwaters) from the production of

ethylenebisdithiocarbamic acid and its salt

K124 ....................................................................................................................................................................... (C,T)

Reactor vent scrubber water from the production of ethylenebisdithiocarbamic acid and its salts

K125 ........................................................................................................................................................................... (T)

Filtration, evaporation, and centrifugation solids from the production of ethylenebisdithiocarbamic acid and its salts

K126 ........................................................................................................................................................................... (T)

Baghouse dust and floor sweepings in milling and packaging operations from the production or formulation of

ethylenebisdithiocarbamic acid and its salts

K131 ....................................................................................................................................................................... (C,T)

Wastewater from the reactor and spent sulfuric acid from the acid dryer from the production of methyl bromide

K132 ........................................................................................................................................................................... (T)

Spent absorbent and wastewater separator solids from the production of methyl bromide

Explosives:

K044 ...........................................................................................................................................................................(R)

Wastewater treatment sludges from the manufacturing and processing of explosives

K045 ...........................................................................................................................................................................(R)

Spent carbon from the treatment of wastewater containing explosives



K046 ........................................................................................................................................................................... (T)

Wastewater treatment sludges from the manufacturing, formulation and loading of lead-based initiating compounds

K047 ...........................................................................................................................................................................(R)

Pink/red water from TNT operations

Petroleum refining:

K048 ........................................................................................................................................................................... (T)

Dissolved air flotation (DAF)float from the petroleum refining industry

K049 ........................................................................................................................................................................... (T)

Slop oil emulsion solids from the petroleum refining industry

K050 ........................................................................................................................................................................... (T)

Heat exchanger bundle cleaning sludge from the petroleum refining industry

K051 ........................................................................................................................................................................... (T)

API separator sludge from the petroleum refining industry

K052 ........................................................................................................................................................................... (T)

Tank bottoms (leaded) from the petroleum refining industry

K169 ........................................................................................................................................................................... (T)

Crude oil storage tank sediment from petroleum refining operations

K170 ........................................................................................................................................................................... (T)

Clarified slurry oil tank sediment and/or in-line filter/separation solids from petroleum refining operations

K171 ........................................................................................................................................................................ (I,T)

Spent Hydrotreating catalyst from petroleum refining operations, including guard beds used to desulfurize feeds to

other catalytic reactors (this listing does not include inert support media)

K172 ........................................................................................................................................................................ (I,T)

Spent Hydrorefining catalyst from petroleum refining operations, including guard beds used to desulfurize feeds to

other catalytic reactors (this listing does not include inert support media).

Iron and steel:

K061 ........................................................................................................................................................................... (T)

Emission control dust/sludge from the primary production of steel in electric furnaces

K062 ....................................................................................................................................................................... (C,T)

Spent pickle liquor generated by steel finishing operations of facilities within the iron and steel industry (SIC Codes

331 and 332)

Primary aluminum:

K088 ........................................................................................................................................................................... (T)

Spent potliners from primary aluminum reduction

Secondary lead:

K069 ........................................................................................................................................................................... (T)

Emission control dust/sludge from secondary lead smelting. (Note: This listing is stayed administratively for sludge

generated from secondary acid scrubber systems. The stay will remain in effect until further administrative action is

taken. If EPA takes further action effecting this stay, EPA will publish a notice of the action in the Federal Register)



K100 ........................................................................................................................................................................... (T)

Waste leaching solution from acid leaching of emission control dust/sludge from secondary lead smelting

Veterinary pharmaceuticals:

K084 ........................................................................................................................................................................... (T)

Wastewater treatment sludges generated during the production of veterinary pharmaceuticals from arsenic or

organo-arsenic compounds

K101 ........................................................................................................................................................................... (T)

Distillation tar residues from the distillation of aniline- based compounds in the production of veterinary

pharmaceuticals from arsenic or organo-arsenic compounds

K102 ........................................................................................................................................................................... (T)

Residue from the use of activated carbon for decolorization in the production of veterinary pharmaceuticals from

arsenic or organo-arsenic compounds

Ink formulation:

K086 ........................................................................................................................................................................... (T)

Solvent washes and sludges, caustic washes and sludges, or water washes and sludges from cleaning tubs and

equipment used in the formulation of ink from pigments, driers, soaps, and stabilizers containing chromium and lead

Coking:

K060 ........................................................................................................................................................................... (T)

Ammonia still lime sludge from coking operations

K087 ........................................................................................................................................................................... (T)

Decanter tank tar sludge from coking operations

K141 ........................................................................................................................................................................... (T)

Process residues from the recovery of coal tar, including, but not limited to, collecting sump residues from the

production of coke from coal or the recovery of coke by-products produced from coal. This listing does not include

K087 (decanter tank tar sludges from coking operations).

K142 ........................................................................................................................................................................... (T)

Tar storage tank residues from the production of coke from coal or from the recovery of coke by-products produced

from coal.

K143 ........................................................................................................................................................................... (T)

Process residues from the recovery of light oil, including, but not limited to, those generated in stills, decanters, and

wash oil recovery units from the recovery of coke by-products produced from coal.

K144 ........................................................................................................................................................................... (T)

Wastewater sump residues from light oil refining, including, but not limited to, intercepting or contamination sump

sludges from the recovery of coke by-products produced from coal.

K145 ........................................................................................................................................................................... (T)

Residues from naphthalene collection and recovery operations from the recovery of coke by-products produced from

coal.

K147 ........................................................................................................................................................................... (T)

Tar storage tank residues from coal tar refining.

K148 ........................................................................................................................................................................... (T)

Residues from coal tar distillation, including but not limited to, still bottoms.



(b) Listing Specific Definitions:

(1) For the purposes of the K181 listing, dyes and/or pigments production is defined to include manufacture of

the following product classes: dyes, pigments, or FDA certified colors that are classified as azo,

triarylmethane, perylene or anthraquinone classes. Azo products include azo, monoazo, diazo, triazo,

polyazo, azoic, benzidine, and pyrazolone products. Triarylmethane products include both triarylmethane

and triphenylmethane products. Wastes that are not generated at a dyes and/or pigments manufacturing site,

such as wastes from the offsite use, formulation, and packaging of dyes and/or pigments, are not included

in the K181 listing.

(c) K181 Listing Levels.

Nonwastewaters containing constituents in amounts equal to or exceeding the following levels during any

calendar year are subject to the K181 listing, unless the conditions in the K181 listing are met.

Constituents Chemical Abstracts No. Mass levels

(kg/yr)

Aniline 62-53-3 9,300

o-Anisidine 90-04-0 110

4-Chloroaniline 106-47-8 4,800

p-Cresidine 120-71-8 660

2,4-Dimethylaniline 95-68-1 100

1,2-Phenylenediamine 95-54-5 710

1,3-Phenylenediamine 108-45-2 1,200

(d) Procedures for demonstrating that dyes and/or pigment nonwastewaters are not K181.

The procedures described in paragraphs (d)(1)-(d)(3) and (d)(5) of this section establish when nonwastewaters

from the production of dyes/pigments would not be hazardous (these procedures apply to wastes that are not

disposed in landfill units or treated in combustion units as specified in paragraph (a) of this section). If the

nonwastewaters are disposed in landfill units or treated in combustion units as described in paragraph (a) of this

section, then the nonwastewaters are not hazardous. In order to demonstrate that it is meeting the landfill

disposal or combustion conditions contained in the K181 listing description, the generator must maintain

documentation as described in paragraph (d)(4) of this section.

(1) Determination based on no K181 constituents. Generators that have knowledge (e.g., knowledge of

constituents in wastes based on prior sampling and analysis data and/or information about raw materials

used, production processes used, and reaction and degradation products formed) that their wastes contain

none of the K181 constituents (see paragraph (c) of this section) can use their knowledge to determine that

their waste is not K181. The generator must document the basis for all such determinations on an annual

basis and keep each annual documentation for three years.

(2) Determination for generated quantities of 1,000 MT/yr or less for wastes that contain K181 constituents. If

the total annual quantity of dyes and/or pigment nonwastewaters generated is 1,000 metric tons or less, the

generator can use knowledge of the wastes (e.g., knowledge of constituents in wastes based on prior

analytical data and/or information about raw materials used, production processes used, and reaction and

degradation products formed) to conclude that annual mass loadings for the K181 constituents are below

the listing levels of paragraph (c) of this section. To make this determination, the generator must:

(i) Each year document the basis for determining that the annual quantity of nonwastewaters expected to

be generated will be less than 1,000 metric tons.

(ii) Track the actual quantity of nonwastewaters generated from January 1 through December 31 of each



year. If, at any time within the year, the actual waste quantity exceeds 1,000 metric tons, the generator

must comply with the requirements of paragraph (d)(3) of this section for the remainder of the year.

(iii) Keep a running total of the K181 constituent mass loadings over the course of the calendar year.

(iv) Keep the following records on site for the three most recent calendar years in which the hazardous

waste determinations are made:

(A) The quantity of dyes and/or pigment nonwastewaters generated.

(B) The relevant process information used.

(C) The calculations performed to determine annual total mass loadings for each K181 constituent in

the nonwastewaters during the year.

(3) Determination for generated quantities greater than 1,000 MT/yr for wastes that contain K181 constituents.

If the total annual quantity of dyes and/or pigment nonwastewaters generated is greater than 1,000 metric

tons, the generator must perform all of the steps described in paragraphs ((d)(3)(i)-(d)(3)(xi) of this section)

in order to make a determination that its waste is not K181.

(i) Determine which K181 constituents (see paragraph (c) of this section) are reasonably expected to be

present in the wastes based on knowledge of the wastes (e.g., based on prior sampling and analysis

data and/or information about raw materials used, production processes used, and reaction and

degradation products formed).

(ii) If 1,2-phenylenediamine is present in the wastes, the generator can use either knowledge or sampling

and analysis procedures to determine the level of this constituent in the wastes. For determinations

based on use of knowledge, the generator must comply with the procedures for using knowledge

described in paragraph (d)(2) of this section and keep the records described in paragraph (d)(2)(iv) of

this section. For determinations based on sampling and analysis, the generator must comply with the

sampling and analysis and recordkeeping requirements described below in this section.

(iii) Develop a waste sampling and analysis plan (or modify an existing plan) to collect and analyze

representative waste samples for the K181 constituents reasonably expected to be present in the

wastes. At a minimum, the plan must include:

(A) A discussion of the number of samples needed to characterize the wastes fully;

(B) The planned sample collection method to obtain representative waste samples;

(C) A discussion of how the sampling plan accounts for potential temporal and spatial variability of

the wastes.

(D) A detailed description of the test methods to be used, including sample preparation, clean up (if

necessary), and determinative methods.

(iv) Collect and analyze samples in accordance with the waste sampling and analysis plan.

(A) The sampling and analysis must be unbiased, precise, and representative of the wastes.

(B) The analytical measurements must be sufficiently sensitive, accurate and precise to support any

claim that the constituent mass loadings are below the listing levels of paragraph (c) of this

section.

(v) Record the analytical results.

(vi) Record the waste quantity represented by the sampling and analysis results.

(vii) Calculate constituent-specific mass loadings (product of concentrations and waste quantity).

(viii)Keep a running total of the K181 constituent mass loadings over the course of the calendar year.

(ix) Determine whether the mass of any of the K181 constituents listed in paragraph (c) of this section

generated between January 1 and December 31 of any year is below the K181 listing levels.

(x) Keep the following records on site for the three most recent calendar years in which the hazardous

waste determinations are made:

(A) The sampling and analysis plan.

(B) The sampling and analysis results (including QA/QC data)

(C) The quantity of dyes and/or pigment nonwastewaters generated.

(D) The calculations performed to determine annual mass loadings.

(xi) Nonhazardous waste determinations must be conducted annually to verify that the wastes remain

nonhazardous.

(A) The annual testing requirements are suspended after three consecutive successful annual

demonstrations that the wastes are nonhazardous. The generator can then use knowledge of the

wastes to support subsequent annual determinations.

(B) The annual testing requirements are reinstated if the manufacturing or waste treatment processes

generating the wastes are significantly altered, resulting in an increase of the potential for the

wastes to exceed the listing levels.

(C) If the annual testing requirements are suspended, the generator must keep records of the process



knowledge information used to support a nonhazardous determination. If testing is reinstated, a

description of the process change must be retained.

(4) Recordkeeping for the landfill disposal and combustion exemptions. For the purposes of meeting the

landfill disposal and combustion condition set out in the K181 listing description, the generator must

maintain on site for three years documentation demonstrating that each shipment of waste was received

by a landfill unit that is subject to or meets the landfill design standards set out in the listing

description, or was treated in combustion units as specified in the listing description.

(5) Waste holding and handling. During the interim period, from the point of generation to completion of

the hazardous waste determination, the generator is responsible for storing the wastes appropriately. If

the wastes are determined to be hazardous and the generator has not complied with the subtitle C

requirements during the interim period, the generator could be subject to an enforcement action for

improper management.



261.33 Discarded commercial chemical products, off-specification species, container residues, and spill

residues thereof.

The following materials or items are hazardous wastes if and when they are discarded or intended to be discarded as

described in §261.2 (a)(2)(i), when they are mixed with waste oil or used oil or other material and applied to the land

for dust suppression or road treatment, when they are otherwise applied to the land in lieu of their original intended

use or when they are contained in products that are applied to the land in lieu of their original intended use, or when,

in lieu of their original intended use, they are produced for use as (or as a component of) a fuel, distributed for use as

a fuel, or burned as a fuel.

(a) Any commercial chemical product, or manufacturing chemical intermediate having the generic name listed in

paragraph (e) or (f) of this section.

(b) Any off-specification commercial chemical product or manufacturing chemical intermediate which, if it met

specifications, would have the generic name listed in paragraph (e) or (f) of this section.

(c) Any residue remaining in a container or in an inner liner removed from a container that has held any

commercial chemical product or manufacturing chemical intermediate having the generic name listed in

paragraphs (e) or (f) of this section, unless the container is empty as defined in §261.7 (b) of this chapter.

[Comment: Unless the residue is being beneficially used or reused, or legitimately recycled or reclaimed; or

being accumulated, stored, transported or treated prior to such use, re-use, recycling or reclamation, EPA

considers the residue to be intended for discard, and thus, a hazardous waste. An example of a legitimate re-use

of the residue would be where the residue remains in the container and the container is used to hold the same

commercial chemical product or manufacturing chemical intermediate it previously held. An example of the

discard of the residue would be where the drum is sent to a drum reconditioner who reconditions the drum but

discards the residue.]

(d) Any residue or contaminated soil, water or other debris resulting from the cleanup of a spill into or on any land

or water of any commercial chemical product or manufacturing chemical intermediate having the generic name

listed in paragraph (e) or (f) of this section, or any residue or contaminated soil, water or other debris resulting

from the cleanup of a spill, into or on any land or water, of any off-specification chemical product and

manufacturing chemical intermediate which, if it met specifications, would have the generic name listed in

paragraph (e) or (f) of this section.

[Comment: The phrase ``commercial chemical product or manufacturing chemical intermediate having the

generic name listed in . . .'' refers to a chemical substance which is manufactured or formulated for commercial

or manufacturing use which consists of the commercially pure grade of the chemical, any technical grades of

the chemical that are produced or marketed, and all formulations in which the chemical is the sole active

ingredient. It does not refer to a material, such as a manufacturing process waste, that contains any of the

substances listed in paragraph (e) or (f). Where a manufacturing process waste is deemed to be a hazardous

waste because it contains a substance listed in paragraph (e) or (f), such waste will be listed in either §261.31 or

§261.32 or will be identified as a hazardous waste by the characteristics set forth in subpart C of this part.]

(e) The commercial chemical products, manufacturing chemical intermediates or off-specification commercial

chemical products or manufacturing chemical intermediates referred to in paragraphs (a) through (d) of this

section, are identified as acute hazardous wastes (H) and are subject to the small quantity exclusion defined in

§261.5 (e).

[Comment: For the convenience of the regulated community the primary hazardous properties of these materials

have been indicated by the letters T (Toxicity), and R (Reactivity). Absence of a letter indicates that the

compound only is listed for acute toxicity]

These wastes and their corresponding EPA Hazardous Waste Numbers are:



Hazardous

waste No.

Chemical

abstracts No. Substance

P023 107-20-0 Acetaldehyde, chloro-

P002 591-08-2 Acetamide, N-(aminothioxomethyl)-

P057 640-19-7 Acetamide, 2-fluoro-

P058 62-74-8 Acetic acid, fluoro-, sodium salt

P002 591-08-2 1-Acetyl-2-thiourea

P003 107-02-8 Acrolein

P070 116-06-3 Aldicarb

P203 1646-88-4 Aldicarb sulfone.

P004 309-00-2 Aldrin

P005 107-18-6 Allyl alcohol

P006 20859-73-8 Aluminum phosphide (R,T)

P007 2763-96-4 5-(Aminomethyl)-3-isoxazolol

P008 504-24-5 4-Aminopyridine

P009 131-74-8 Ammonium picrate (R)

P119 7803-55-6 Ammonium vanadate

P099 506-61-6 Argentate(1-), bis(cyano-C)-, potassium

P010 7778-39-4 Arsenic acid H3 AsO4

P012 1327-53-3 Arsenic oxide As2 O3

P011 1303-28-2 Arsenic oxide As2 O5

P011 1303-28-2 Arsenic pentoxide

P012 1327-53-3 Arsenic trioxide

P038 692-42-2 Arsine, diethyl-

P036 696-28-6 Arsonous dichloride, phenyl-

P054 151-56-4 Aziridine

P067 75-55-8 Aziridine, 2-methyl-

P013 542-62-1 Barium cyanide

P024 106-47-8 Benzenamine, 4-chloro-

P077 100-01-6 Benzenamine, 4-nitro-

P028 100-44-7 Benzene, (chloromethyl)-

P042 51-43-4 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, (R)-

P046 122-09-8 Benzeneethanamine, alpha,alpha-dimethyl-

P014 108-98-5 Benzenethiol

P127 1563-66-2 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-, methylcarbamate.

P188 57-64-7 Benzoic acid, 2-hydroxy-, compd. with (3aS-cis)-1,2,3,3a,8,8a-hexahydro-1,3a,8-



Hazardous

waste No.

Chemical


trimethylpyrrolo[2,3-b]indol-5-yl methylcarbamate ester (1:1).

P001 181-81-2 2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenylbutyl)-, & salts, when present

at concentrations greater than 0.3%

P028 100-44-7 Benzyl chloride

P015 7440-41-7 Beryllium powder

P017 598-31-2 Bromoacetone

P018 357-57-3 Brucine

P045 39196-18-4 2-Butanone, 3,3-dimethyl-1-(methylthio)-,

O-[(methylamino)carbonyl] oxime

P021 592-01-8 Calcium cyanide

P021 592-01-8 Calcium cyanide Ca(CN)2

P189 55285-14-8 Carbamic acid, [(dibutylamino)- thio]methyl-, 2,3-dihydro-2,2-dimethyl- 7-

benzofuranyl ester.

P191 644-64-4 Carbamic acid, dimethyl-, 1-[(dimethyl-amino)carbonyl]- 5-methyl-1H- pyrazol-3-yl

ester.

P192 119-38-0 Carbamic acid, dimethyl-, 3-methyl-1- (1-methylethyl)-1H- pyrazol-5-yl ester.

P190 1129-41-5 Carbamic acid, methyl-, 3-methylphenyl ester.

P127 1563-66-2 Carbofuran.

P022 75-15-0 Carbon disulfide

P095 75-44-5 Carbonic dichloride

P189 55285-14-8 Carbosulfan.

P023 107-20-0 Chloroacetaldehyde

P024 106-47-8 p-Chloroaniline

P026 5344-82-1 1-(o-Chlorophenyl)thiourea

P027 542-76-7 3-Chloropropionitrile

P029 544-92-3 Copper cyanide

P029 544-92-3 Copper cyanide Cu(CN)

P202 64-00-6 m-Cumenyl methylcarbamate.

P030

Cyanides (soluble cyanide salts), not otherwise specified

P031 460-19-5 Cyanogen

P033 506-77-4 Cyanogen chloride

P033 506-77-4 Cyanogen chloride (CN)Cl

P034 131-89-5 2-Cyclohexyl-4,6-dinitrophenol

P016 542-88-1 Dichloromethyl ether

P036 696-28-6 Dichlorophenylarsine

P037 60-57-1 Dieldrin



Hazardous

waste No.

Chemical


P038 692-42-2 Diethylarsine

P041 311-45-5 Diethyl-p-nitrophenyl phosphate

P040 297-97-2 O,O-Diethyl O-pyrazinyl phosphorothioate

P043 55-91-4 Diisopropylfluorophosphate (DFP)

P004 309-00-2 1,4,5,8-Dimethanonaphthalene, 1,2,3,4,10,10-hexachloro-1,4,4a,5,8,8a,-hexahydro-,

(1alpha,4alpha,4abeta,5alpha,8alpha,8abeta)-

P060 465-73-6 1,4,5,8-Dimethanonaphthalene, 1,2,3,4,10,10-hexachloro-1,4,4a,5,8,8a-hexahydro-,

(1alpha,4alpha,4abeta,5beta,8beta,8abeta)-

P037 60-57-1 2,7:3,6-Dimethanonaphth[2,3-b]oxirene, 3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-

octahydro-, (1aalpha,2beta,2aalpha,3beta,6beta,6aalpha,7beta, 7aalpha)-

P051 172-20-8 2,7:3,6-Dimethanonaphth [2,3-b]oxirene, 3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-

octahydro-, (1aalpha,2beta,2abeta,3alpha,6alpha,6abeta,7beta, 7aalpha)-, &

metabolites

P044 60-51-5 Dimethoate

P046 122-09-8 alpha,alpha-Dimethylphenethylamine

P191 644-64-4 Dimetilan.

P047 1534-52-1 4,6-Dinitro-o-cresol, & salts

P048 51-28-5 2,4-Dinitrophenol

P020 88-85-7 Dinoseb

P085 152-16-9 Diphosphoramide, octamethyl-

P111 107-49-3 Diphosphoric acid, tetraethyl ester

P039 298-04-4 Disulfoton

P049 541-53-7 Dithiobiuret

P185 26419-73-8 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)- carbonyl]oxime.

P050 115-29-7 Endosulfan

P088 145-73-3 Endothall

P051 72-20-8 Endrin

P051 72-20-8 Endrin, & metabolites

P042 51-43-4 Epinephrine

P031 460-19-5 Ethanedinitrile

P194 23135-22-0 Ethanimidothioic acid, 2-(dimethylamino)-N-[[(methylamino) carbonyl]oxy]-2-oxo-,

methyl ester.

P066 16752-77-5 Ethanimidothioic acid,

N-[[(methylamino)carbonyl]oxy]-, methyl ester

P101 107-12-0 Ethyl cyanide

P054 151-56-4 Ethyleneimine

P097 52-85-7 Famphur



Hazardous

waste No.

Chemical


P056 7782-41-4 Fluorine

P057 640-19-7 Fluoroacetamide

P058 62-74-8 Fluoroacetic acid, sodium salt

P198 23422-53-9 Formetanate hydrochloride.

P197 17702-57-7 Formparanate.

P065 628-86-4 Fulminic acid, mercury(2+) salt (R,T)

P059 76-44-8 Heptachlor

P062 757-58-4 Hexaethyl tetraphosphate

P116 79-19-6 Hydrazinecarbothioamide

P068 60-34-4 Hydrazine, methyl-

P063 74-90-8 Hydrocyanic acid

P063 74-90-8 Hydrogen cyanide

P096 7803-51-2 Hydrogen phosphide

P060 465-73-6 Isodrin

P192 119-38-0 Isolan.

P202 64-00-6 3-Isopropylphenyl N-methylcarbamate.

P007 2763-96-4 3(2H)-Isoxazolone, 5-(aminomethyl)-

P196 15339-36-3 Manganese, bis(dimethylcarbamodithioato-S,S′)-,

P196 15339-36-3 Manganese dimethyldithiocarbamate.

P092 62-38-4 Mercury, (acetato-O)phenyl-

P065 628-86-4 Mercury fulminate (R,T)

P082 62-75-9 Methanamine, N-methyl-N-nitroso-

P064 624-83-9 Methane, isocyanato-

P016 542-88-1 Methane, oxybis[chloro-

P112 509-14-8 Methane, tetranitro- (R)

P118 75-70-7 Methanethiol, trichloro-

P198 23422-53-9 Methanimidamide, N,N-dimethyl-N′-[3-[[(methylamino)-carbonyl]oxy]phenyl]-,

monohydrochloride.

P197 17702-57-7 Methanimidamide, N,N-dimethyl-N′-[2-methyl-4-

[[(methylamino)carbonyl]oxy]phenyl]-

P050 115-29-7 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-

hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide

P059 76-44-8 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-

3a,4,7,7a-tetrahydro-

P199 2032-65-7 Methiocarb.

P066 16752-77-5 Methomyl



Hazardous

waste No.

Chemical


P068 60-34-4 Methyl hydrazine

P064 624-83-9 Methyl isocyanate

P069 75-86-5 2-Methyllactonitrile

P071 298-00-0 Methyl parathion

P190 1129-41-5 Metolcarb.

P128 315-8-4 Mexacarbate.

P072 86-88-4 alpha-Naphthylthiourea

P073 13463-39-3 Nickel carbonyl

P073 13463-39-3 Nickel carbonyl Ni(CO)4, (T-4)-

P074 557-19-7 Nickel cyanide

P074 557-19-7 Nickel cyanide Ni(CN)2

P075 154-11-5 Nicotine, & salts

P076 10102-43-9 Nitric oxide

P077 100-01-6 p-Nitroaniline

P078 10102-44-0 Nitrogen dioxide

P076 10102-43-9 Nitrogen oxide NO

P078 10102-44-0 Nitrogen oxide NO2

P081 55-63-0 Nitroglycerine (R)

P082 62-75-9 N-Nitrosodimethylamine

P084 4549-40-0 N-Nitrosomethylvinylamine

P085 152-16-9 Octamethylpyrophosphoramide

P087 20816-12-0 Osmium oxide OsO4, (T-4)-

P087 20816-12-0 Osmium tetroxide

P088 145-73-3 7-Oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid

P194 23135-22-0 Oxamyl.

P089 56-38-2 Parathion

P034 131-89-5 Phenol, 2-cyclohexyl-4,6-dinitro-

P048 51-28-5 Phenol, 2,4-dinitro-

P047 1534-52-1 Phenol, 2-methyl-4,6-dinitro-, & salts

P020 88-85-7 Phenol, 2-(1-methylpropyl)-4,6-dinitro-

P009 131-74-8 Phenol, 2,4,6-trinitro-, ammonium salt (R)

P128 315-18-4 Phenol, 4-(dimethylamino)-3,5-dimethyl-, methylcarbamate (ester).

P199 2032-65-7 Phenol, (3,5-dimethyl-4-(methylthio)-, methylcarbamate

P202 64-00-6 Phenol, 3-(1-methylethyl)-, methyl carbamate.

P201 2631-37-0 Phenol, 3-methyl-5-(1-methylethyl)-, methyl carbamate.



Hazardous

waste No.

Chemical


P092 62-38-4 Phenylmercury acetate

P093 103-85-5 Phenylthiourea

P094 298-02-2 Phorate

P095 75-44-5 Phosgene

P096 7803-51-2 Phosphine

P041 311-45-5 Phosphoric acid, diethyl 4-nitrophenyl ester

P039 298-04-4 Phosphorodithioic acid, O,O-diethyl

S-[2-(ethylthio)ethyl] ester

P094 298-02-2 Phosphorodithioic acid, O,O-diethyl

S-[(ethylthio)methyl] ester

P044 60-51-5 Phosphorodithioic acid, O,O-dimethyl S-[2-(methylamino)-2-oxoethyl] ester

P043 55-91-4 Phosphorofluoridic acid, bis(1-methylethyl) ester

P089 56-38-2 Phosphorothioic acid, O,O-diethyl O-(4-nitrophenyl) ester

P040 297-97-2 Phosphorothioic acid, O,O-diethyl O-pyrazinyl ester

P097 52-85-7 Phosphorothioic acid,

O-[4-[(dimethylamino)sulfonyl]phenyl] O,O-dimethyl ester

P071 298-00-0 Phosphorothioic acid, O,O,-dimethyl O-(4-nitrophenyl) ester

P204 57-47-6 Physostigmine.

P188 57-64-7 Physostigmine salicylate.

P110 78-00-2 Plumbane, tetraethyl-

P098 151-50-8 Potassium cyanide

P098 151-50-8 Potassium cyanide K(CN)

P099 506-61-6 Potassium silver cyanide

P201 2631-37-0 Promecarb

P070 116-06-3 Propanal, 2-methyl-2-(methylthio)-,

O-[(methylamino)carbonyl]oxime

P203 1646-88-4 Propanal, 2-methyl-2-(methyl-sulfonyl)-, O-[(methylamino)carbonyl] oxime.

P101 107-12-0 Propanenitrile

P027 542-76-7 Propanenitrile, 3-chloro-

P069 75-86-5 Propanenitrile, 2-hydroxy-2-methyl-

P081 55-63-0 1,2,3-Propanetriol, trinitrate (R)

P017 598-31-2 2-Propanone, 1-bromo-

P102 107-19-7 Propargyl alcohol

P003 107-02-8 2-Propenal

P005 107-18-6 2-Propen-1-ol

P067 75-55-8 1,2-Propylenimine



Hazardous

waste No.

Chemical


P102 107-19-7 2-Propyn-1-ol

P008 504-24-5 4-Pyridinamine

P075 154-11-5 Pyridine, 3-(1-methyl-2-pyrrolidinyl)-, (S)-, & salts

P204 57-47-6 Pyrrolo[2,3-b]indol-5-ol, 1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethyl-,

methylcarbamate (ester), (3aS-cis)-.

P114 12039-52-0 Selenious acid, dithallium(1+) salt

P103 630-10-4 Selenourea

P104 506-64-9 Silver cyanide

P104 506-64-9 Silver cyanide Ag(CN)

P105 26628-22-8 Sodium azide

P106 143-33-9 Sodium cyanide

P106 143-33-9 Sodium cyanide Na(CN)

P108 157-24-9 Strychnidin-10-one, & salts

P018 357-57-3 Strychnidin-10-one, 2,3-dimethoxy-

P108 157-24-9 Strychnine, & salts

P115 7446-18-6 Sulfuric acid, dithallium(1+) salt

P109 3689-24-5 Tetraethyldithiopyrophosphate

P110 78-00-2 Tetraethyl lead

P111 107-49-3 Tetraethyl pyrophosphate

P112 509-14-8 Tetranitromethane (R)

P062 757-58-4 Tetraphosphoric acid, hexaethyl ester

P113 1314-32-5 Thallic oxide

P113 1314-32-5 Thallium oxide Tl2 O3

P114 12039-52-0 Thallium(I) selenite

P115 7446-18-6 Thallium(I) sulfate

P109 3689-24-5 Thiodiphosphoric acid, tetraethyl ester

P045 39196-18-4 Thiofanox

P049 541-53-7 Thioimidodicarbonic diamide [(H2 N)C(S)]2 NH

P014 108-98-5 Thiophenol

P116 79-19-6 Thiosemicarbazide

P026 5344-82-1 Thiourea, (2-chlorophenyl)-

P072 86-88-4 Thiourea, 1-naphthalenyl-

P093 103-85-5 Thiourea, phenyl-

P185 26419-73-8 Tirpate.

P123 8001-35-2 Toxaphene



Hazardous

waste No.

Chemical


P118 75-70-7 Trichloromethanethiol

P119 7803-55-6 Vanadic acid, ammonium salt

P120 1314-62-1 Vanadium oxide V2 O5

P120 1314-62-1 Vanadium pentoxide

P084 4549-40-0 Vinylamine, N-methyl-N-nitroso-

P001 181-81-2 Warfarin, & salts, when present at concentrations greater than 0.3%

P205 137-30-4 Zinc, bis(dimethylcarbamodithioato-S,S′)-,

P121 557-21-1 Zinc cyanide

P121 557-21-1 Zinc cyanide Zn(CN)2

P122 1314-84-7 Zinc phosphide Zn3 P2, when present at concentrations greater than 10% (R,T)

P205 137-30-4 Ziram.



(f) The commercial chemical products, manufacturing chemical intermediates, or off-specification commercial

chemical products referred to in paragraphs (a) through (d) of this section, are identified as toxic wastes (T),

unless otherwise designated and are subject to the small quantity generator exclusion defined in §261.5 (a) and

(g).

[Comment: For the convenience of the regulated community, the primary hazardous properties of these

materials have been indicated by the letters T (Toxicity), R (Reactivity), I (Ignitability) and C (Corrosivity).

Absence of a letter indicates that the compound is only listed for toxicity.]

These wastes and their corresponding EPA Hazardous Waste Numbers are:

Hazardous

waste No.

Chemical


U394 30558-43-1 A2213.

U001 75-07-0 Acetaldehyde (I)

U034 75-87-6 Acetaldehyde, trichloro-

U187 62-44-2 Acetamide, N-(4-ethoxyphenyl)-

U005 53-96-3 Acetamide, N-9H-fluoren-2-yl-

U240 194-75-7 Acetic acid, (2,4-dichlorophenoxy)-, salts & esters

U112 141-78-6 Acetic acid ethyl ester (I)

U144 301-04-2 Acetic acid, lead(2+) salt

U214 563-68-8 Acetic acid, thallium(1+) salt

see F027 93-76-5 Acetic acid, (2,4,5-trichlorophenoxy)-

U002 67-64-1 Acetone (I)

U003 75-05-8 Acetonitrile (I,T)

U004 98-86-2 Acetophenone

U005 53-96-3 2-Acetylaminofluorene

U006 75-36-5 Acetyl chloride (C,R,T)

U007 79-06-1 Acrylamide

U008 79-10-7 Acrylic acid (I)

U009 107-13-1 Acrylonitrile

U011 61-82-5 Amitrole

U012 62-53-3 Aniline (I,T)

U136 75-60-5 Arsinic acid, dimethyl-

U014 492-80-8 Auramine

U015 115-02-6 Azaserine

U010 50-07-7 Azirino[2′,3′:3,4]pyrrolo[1,2-a]indole-4,7-dione, 6-amino-8-

[[(aminocarbonyl)oxy]methyl]-1,1a,2,8,8a,8b-hexahydro-8a-methoxy-5-methyl-,

[1aS-(1aalpha, 8beta,8aalpha,8balpha)]-

U280 101-27-9 Barban.

U278 22781-23-3 Bendiocarb.

U364 22961-82-6 Bendiocarb phenol.



Hazardous

waste No.

Chemical


U271 17804-35-2 Benomyl.

U157 56-49-5 Benz[j]aceanthrylene, 1,2-dihydro-3-methyl-

U016 225-51-4 Benz[c]acridine

U017 98-87-3 Benzal chloride

U192 23950-58-5 Benzamide, 3,5-dichloro-N-(1,1-dimethyl-2-propynyl)-

U018 56-55-3 Benz[a]anthracene

U094 57-97-6 Benz[a]anthracene, 7,12-dimethyl-

U012 62-53-3 Benzenamine (I,T)

U014 492-80-8 Benzenamine, 4,4′-carbonimidoylbis[N,N-dimethyl-

U049 3165-93-3 Benzenamine, 4-chloro-2-methyl-, hydrochloride

U093 60-11-7 Benzenamine, N,N-dimethyl-4-(phenylazo)-

U328 95-53-4 Benzenamine, 2-methyl-

U353 106-49-0 Benzenamine, 4-methyl-

U158 101-14-4 Benzenamine, 4,4′-methylenebis[2-chloro-

U222 636-21-5 Benzenamine, 2-methyl-, hydrochloride

U181 99-55-8 Benzenamine, 2-methyl-5-nitro-

U019 71-43-2 Benzene (I,T)

U038 510-15-6 Benzeneacetic acid, 4-chloro-alpha-(4-chlorophenyl)-alpha-hydroxy-, ethyl ester

U030 101-55-3 Benzene, 1-bromo-4-phenoxy-

U035 305-03-3 Benzenebutanoic acid, 4-[bis(2-chloroethyl)amino]-

U037 108-90-7 Benzene, chloro-

U221 25376-45-8 Benzenediamine, ar-methyl-

U028 117-81-7 1,2-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester

U069 84-74-2 1,2-Benzenedicarboxylic acid, dibutyl ester

U088 84-66-2 1,2-Benzenedicarboxylic acid, diethyl ester

U102 131-11-3 1,2-Benzenedicarboxylic acid, dimethyl ester

U107 117-84-0 1,2-Benzenedicarboxylic acid, dioctyl ester

U070 95-50-1 Benzene, 1,2-dichloro-



U060 72-54-8 Benzene, 1,1′-(2,2-dichloroethylidene)bis[4-chloro-

U017 98-87-3 Benzene, (dichloromethyl)-

U223 26471-62-5 Benzene, 1,3-diisocyanatomethyl- (R,T)

U239 1330-20-7 Benzene, dimethyl- (I)

U201 108-46-3 1,3-Benzenediol



Hazardous

waste No.

Chemical


U127 118-74-1 Benzene, hexachloro-

U056 110-82-7 Benzene, hexahydro- (I)

U220 108-88-3 Benzene, methyl-

U105 121-14-2 Benzene, 1-methyl-2,4-dinitro-

U106 606-20-2 Benzene, 2-methyl-1,3-dinitro-

U055 98-82-8 Benzene, (1-methylethyl)- (I)

U169 98-95-3 Benzene, nitro-

U183 608-93-5 Benzene, pentachloro-

U185 82-68-8 Benzene, pentachloronitro-

U020 98-09-9 Benzenesulfonic acid chloride (C,R)

U020 98-09-9 Benzenesulfonyl chloride (C,R)

U207 95-94-3 Benzene, 1,2,4,5-tetrachloro-

U061 50-29-3 Benzene, 1,1′-(2,2,2-trichloroethylidene)bis[4-chloro-

U247 72-43-5 Benzene, 1,1′-(2,2,2-trichloroethylidene)bis[4- methoxy-

U023 98-07-7 Benzene, (trichloromethyl)-

U234 99-35-4 Benzene, 1,3,5-trinitro-

U021 92-87-5 Benzidine

U278 22781-23-3 1,3-Benzodioxol-4-ol, 2,2-dimethyl-, methyl carbamate.

U364 22961-82-6 1,3-Benzodioxol-4-ol, 2,2-dimethyl-,

U203 94-59-7 1,3-Benzodioxole, 5-(2-propenyl)-

U141 120-58-1 1,3-Benzodioxole, 5-(1-propenyl)-

U367 1563-38-8 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-

U090 94-58-6 1,3-Benzodioxole, 5-propyl-

U064 189-55-9 Benzo[rst]pentaphene

U248 181-81-2 2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenyl-butyl)-, & salts, when present

at concentrations of 0.3% or less

U022 50-32-8 Benzo[a]pyrene

U197 106-51-4 p-Benzoquinone

U023 98-07-7 Benzotrichloride (C,R,T)

U085 1464-53-5 2,2′-Bioxirane

U021 92-87-5 [1,1′-Biphenyl]-4,4′-diamine

U073 91-94-1 [1,1′-Biphenyl]-4,4′-diamine, 3,3′-dichloro-

U091 119-90-4 [1,1′-Biphenyl]-4,4′-diamine, 3,3′-dimethoxy-

U095 119-93-7 [1,1′-Biphenyl]-4,4′-diamine, 3,3′-dimethyl-

U225 75-25-2 Bromoform



Hazardous

waste No.

Chemical


U030 101-55-3 4-Bromophenyl phenyl ether

U128 87-68-3 1,3-Butadiene, 1,1,2,3,4,4-hexachloro-

U172 924-16-3 1-Butanamine, N-butyl-N-nitroso-

U031 71-36-3 1-Butanol (I)

U159 78-93-3 2-Butanone (I,T)

U160 1338-23-4 2-Butanone, peroxide (R,T)

U053 4170-30-3 2-Butenal

U074 764-41-0 2-Butene, 1,4-dichloro- (I,T)

U143 303-34-4 2-Butenoic acid, 2-methyl-, 7-[[2,3-dihydroxy-

2-(1-methoxyethyl)-3-methyl-1-oxobutoxy]methyl]-

2,3,5,7a-tetrahydro-1H-pyrrolizin-1-yl ester,

[1S-[1alpha(Z),7(2S*,3R*),7aalpha]]-

U031 71-36-3 n-Butyl alcohol (I)

U136 75-60-5 Cacodylic acid

U032 13765-19-0 Calcium chromate

U372 10605-21-7 Carbamic acid, 1H-benzimidazol-2-yl, methyl ester.

U271 17804-35-2 Carbamic acid, [1-[(butylamino)carbonyl]-1H-benzimidazol-2-yl]-, methyl ester.

U280 101-27-9 Carbamic acid, (3-chlorophenyl)-, 4-chloro-2-butynyl ester.

U238 51-79-6 Carbamic acid, ethyl ester

U178 615-53-2 Carbamic acid, methylnitroso-, ethyl ester

U373 122-42-9 Carbamic acid, phenyl-, 1-methylethyl ester.

U409 23564-05-8 Carbamic acid, [1,2-phenylenebis (iminocarbonothioyl)]bis-, dimethyl ester.

U097 79-44-7 Carbamic chloride, dimethyl-

U389 2303-17-5 Carbamothioic acid, bis(1-methylethyl)-, S-(2,3,3-trichloro-2-propenyl) ester.

U387 52888-80-9 Carbamothioic acid, dipropyl-, S-(phenylmethyl) ester.

U114 1111-54-6 Carbamodithioic acid, 1,2-ethanediylbis-,

salts & esters

U062 2303-16-4 Carbamothioic acid, bis(1-methylethyl)-, S-(2,3-dichloro-2-propenyl) ester

U279 63-25-2 Carbaryl.

U372 10605-21-7 Carbendazim.

U367 1563-38-8 Carbofuran phenol.

U215 6533-73-9 Carbonic acid, dithallium(1+) salt

U033 353-50-4 Carbonic difluoride

U156 79-22-1 Carbonochloridic acid, methyl ester (I,T)

U033 353-50-4 Carbon oxyfluoride (R,T)

U211 56-23-5 Carbon tetrachloride



Hazardous

waste No.

Chemical


U034 75-87-6 Chloral

U035 305-03-3 Chlorambucil

U036 57-74-9 Chlordane, alpha & gamma isomers

U026 494-03-1 Chlornaphazin

U037 108-90-7 Chlorobenzene

U038 510-15-6 Chlorobenzilate

U039 59-50-7 p-Chloro-m-cresol

U042 110-75-8 2-Chloroethyl vinyl ether

U044 67-66-3 Chloroform

U046 107-30-2 Chloromethyl methyl ether

U047 91-58-7 beta-Chloronaphthalene

U048 95-57-8 o-Chlorophenol

U049 3165-93-3 4-Chloro-o-toluidine, hydrochloride

U032 13765-19-0 Chromic acid H2 CrO4, calcium salt

U050 218-01-9 Chrysene

U051

Creosote

U052 1319-77-3 Cresol (Cresylic acid)

U053 4170-30-3 Crotonaldehyde

U055 98-82-8 Cumene (I)

U246 506-68-3 Cyanogen bromide (CN)Br

U197 106-51-4 2,5-Cyclohexadiene-1,4-dione

U056 110-82-7 Cyclohexane (I)

U129 58-89-9 Cyclohexane, 1,2,3,4,5,6-hexachloro-,

(1alpha,2alpha,3beta,4alpha,5alpha,6beta)-

U057 108-94-1 Cyclohexanone (I)

U130 77-47-4 1,3-Cyclopentadiene, 1,2,3,4,5,5-hexachloro-

U058 50-18-0 Cyclophosphamide

U240 194-75-7 2,4-D, salts & esters

U059 20830-81-3 Daunomycin

U060 72-54-8 DDD

U061 50-29-3 DDT

U062 2303-16-4 Diallate

U063 53-70-3 Dibenz[a,h]anthracene

U064 189-55-9 Dibenzo[a,i]pyrene

U066 96-12-8 1,2-Dibromo-3-chloropropane



Hazardous

waste No.

Chemical


U069 84-74-2 Dibutyl phthalate

U070 95-50-1 o-Dichlorobenzene

U071 541-73-1 m-Dichlorobenzene

U072 106-46-7 p-Dichlorobenzene

U073 91-94-1 3,3′-Dichlorobenzidine

U074 764-41-0 1,4-Dichloro-2-butene (I,T)

U075 75-71-8 Dichlorodifluoromethane

U078 75-35-4 1,1-Dichloroethylene

U079 156-60-5 1,2-Dichloroethylene

U025 111-44-4 Dichloroethyl ether

U027 108-60-1 Dichloroisopropyl ether

U024 111-91-1 Dichloromethoxy ethane

U081 120-83-2 2,4-Dichlorophenol

U082 87-65-0 2,6-Dichlorophenol

U084 542-75-6 1,3-Dichloropropene

U085 1464-53-5 1,2:3,4-Diepoxybutane (I,T)

U108 123-91-1 1,4-Diethyleneoxide

U028 117-81-7 Diethylhexyl phthalate

U395 5952-26-1 Diethylene glycol, dicarbamate.

U086 1615-80-1 N,N′-Diethylhydrazine

U087 3288-58-2 O,O-Diethyl S-methyl dithiophosphate

U088 84-66-2 Diethyl phthalate

U089 56-53-1 Diethylstilbesterol

U090 94-58-6 Dihydrosafrole

U091 119-90-4 3,3′-Dimethoxybenzidine

U092 124-40-3 Dimethylamine (I)

U093 60-11-7 p-Dimethylaminoazobenzene

U094 57-97-6 7,12-Dimethylbenz[a]anthracene

U095 119-93-7 3,3′-Dimethylbenzidine

U096 80-15-9 alpha,alpha-Dimethylbenzylhydroperoxide (R)

U097 79-44-7 Dimethylcarbamoyl chloride

U098 57-14-7 1,1-Dimethylhydrazine

U099 540-73-8 1,2-Dimethylhydrazine

U101 105-67-9 2,4-Dimethylphenol

U102 131-11-3 Dimethyl phthalate



Hazardous

waste No.

Chemical


U103 77-78-1 Dimethyl sulfate

U105 121-14-2 2,4-Dinitrotoluene

U106 606-20-2 2,6-Dinitrotoluene

U107 117-84-0 Di-n-octyl phthalate

U108 123-91-1 1,4-Dioxane

U109 122-66-7 1,2-Diphenylhydrazine

U110 142-84-7 Dipropylamine (I)

U111 621-64-7 Di-n-propylnitrosamine

U041 106-89-8 Epichlorohydrin

U001 75-07-0 Ethanal (I)

U404 121-44-8 Ethanamine, N,N-diethyl-

U174 55-18-5 Ethanamine, N-ethyl-N-nitroso-

U155 91-80-5 1,2-Ethanediamine, N,N-dimethyl-N′-2-pyridinyl-N′-(2-thienylmethyl)-

U067 106-93-4 Ethane, 1,2-dibromo-

U076 75-34-3 Ethane, 1,1-dichloro-

U077 107-06-2 Ethane, 1,2-dichloro-

U131 67-72-1 Ethane, hexachloro-

U024 111-91-1 Ethane, 1,1′-[methylenebis(oxy)]bis[2-chloro-

U117 60-29-7 Ethane, 1,1′-oxybis-(I)

U025 111-44-4 Ethane, 1,1′-oxybis[2-chloro-

U184 76-01-7 Ethane, pentachloro-

U208 630-20-6 Ethane, 1,1,1,2-tetrachloro-

U209 79-34-5 Ethane, 1,1,2,2-tetrachloro-

U218 62-55-5 Ethanethioamide

U226 71-55-6 Ethane, 1,1,1-trichloro-

U227 79-00-5 Ethane, 1,1,2-trichloro-

U410 59669-26-0 Ethanimidothioic acid, N,N′- [thiobis[(methylimino)carbonyloxy]]bis-, dimethyl ester

U394 30558-43-1 Ethanimidothioic acid, 2-(dimethylamino)-N-hydroxy-2-oxo-, methyl ester.

U359 110-80-5 Ethanol, 2-ethoxy-

U173 1116-54-7 Ethanol, 2,2′-(nitrosoimino)bis-

U395 5952-26-1 Ethanol, 2,2′-oxybis-, dicarbamate.

U004 98-86-2 Ethanone, 1-phenyl-

U043 75-01-4 Ethene, chloro-

U042 110-75-8 Ethene, (2-chloroethoxy)-

U078 75-35-4 Ethene, 1,1-dichloro-



Hazardous

waste No.

Chemical


U079 156-60-5 Ethene, 1,2-dichloro-, (E)-

U210 127-18-4 Ethene, tetrachloro-

U228 79-01-6 Ethene, trichloro-

U112 141-78-6 Ethyl acetate (I)

U113 140-88-5 Ethyl acrylate (I)

U238 51-79-6 Ethyl carbamate (urethane)

U117 60-29-7 Ethyl ether (I)

U114 1111-54-6 Ethylenebisdithiocarbamic acid, salts & esters

U067 106-93-4 Ethylene dibromide

U077 107-06-2 Ethylene dichloride

U359 110-80-5 Ethylene glycol monoethyl ether

U115 75-21-8 Ethylene oxide (I,T)

U116 96-45-7 Ethylenethiourea

U076 75-34-3 Ethylidene dichloride

U118 97-63-2 Ethyl methacrylate

U119 62-50-0 Ethyl methanesulfonate

U120 206-44-0 Fluoranthene

U122 50-00-0 Formaldehyde

U123 64-18-6 Formic acid (C,T)

U124 110-00-9 Furan (I)

U125 98-01-1 2-Furancarboxaldehyde (I)

U147 108-31-6 2,5-Furandione

U213 109-99-9 Furan, tetrahydro-(I)

U125 98-01-1 Furfural (I)

U124 110-00-9 Furfuran (I)

U206 18883-66-4 Glucopyranose, 2-deoxy-2-(3-methyl-3-nitrosoureido)-, D-

U206 18883-66-4 D-Glucose, 2-deoxy-2-[[(methylnitrosoamino)-

carbonyl]amino]-

U126 765-34-4 Glycidylaldehyde

U163 70-25-7 Guanidine, N-methyl-N′-nitro-N-nitroso-

U127 118-74-1 Hexachlorobenzene

U128 87-68-3 Hexachlorobutadiene

U130 77-47-4 Hexachlorocyclopentadiene

U131 67-72-1 Hexachloroethane

U132 70-30-4 Hexachlorophene



Hazardous

waste No.

Chemical


U243 1888-71-7 Hexachloropropene

U133 302-01-2 Hydrazine (R,T)

U086 1615-80-1 Hydrazine, 1,2-diethyl-

U098 57-14-7 Hydrazine, 1,1-dimethyl-

U099 540-73-8 Hydrazine, 1,2-dimethyl-

U109 122-66-7 Hydrazine, 1,2-diphenyl-

U134 7664-39-3 Hydrofluoric acid (C,T)

U134 7664-39-3 Hydrogen fluoride (C,T)

U135 7783-06-4 Hydrogen sulfide

U135 7783-06-4 Hydrogen sulfide H2 S

U096 80-15-9 Hydroperoxide, 1-methyl-1-phenylethyl- (R)

U116 96-45-7 2-Imidazolidinethione

U137 193-39-5 Indeno[1,2,3-cd]pyrene

U190 85-44-9 1,3-Isobenzofurandione

U140 78-83-1 Isobutyl alcohol (I,T)

U141 120-58-1 Isosafrole

U142 143-50-0 Kepone

U143 303-34-4 Lasiocarpine

U144 301-04-2 Lead acetate

U146 1335-32-6 Lead, bis(acetato-O)tetrahydroxytri-

U145 7446-27-7 Lead phosphate

U146 1335-32-6 Lead subacetate

U129 58-89-9 Lindane

U163 70-25-7 MNNG

U147 108-31-6 Maleic anhydride

U148 123-33-1 Maleic hydrazide

U149 109-77-3 Malononitrile

U150 148-82-3 Melphalan

U151 7439-97-6 Mercury

U152 126-98-7 Methacrylonitrile (I, T)

U092 124-40-3 Methanamine, N-methyl- (I)

U029 74-83-9 Methane, bromo-

U045 74-87-3 Methane, chloro- (I, T)

U046 107-30-2 Methane, chloromethoxy-

U068 74-95-3 Methane, dibromo-



Hazardous

waste No.

Chemical


U080 75-09-2 Methane, dichloro-

U075 75-71-8 Methane, dichlorodifluoro-

U138 74-88-4 Methane, iodo-

U119 62-50-0 Methanesulfonic acid, ethyl ester

U211 56-23-5 Methane, tetrachloro-

U153 74-93-1 Methanethiol (I, T)

U225 75-25-2 Methane, tribromo-

U044 67-66-3 Methane, trichloro-

U121 75-69-4 Methane, trichlorofluoro-

U036 57-74-9 4,7-Methano-1H-indene, 1,2,4,5,6,7,8,8-octachloro-2,3,3a,4,7,7a-hexahydro-

U154 67-56-1 Methanol (I)

U155 91-80-5 Methapyrilene

U142 143-50-0 1,3,4-Metheno-2H-cyclobuta[cd]pentalen-2-one, 1,1a,3,3a,4,5,5,5a,5b,6-

decachlorooctahydro-

U247 72-43-5 Methoxychlor

U154 67-56-1 Methyl alcohol (I)

U029 74-83-9 Methyl bromide

U186 504-60-9 1-Methylbutadiene (I)

U045 74-87-3 Methyl chloride (I,T)

U156 79-22-1 Methyl chlorocarbonate (I,T)

U226 71-55-6 Methyl chloroform

U157 56-49-5 3-Methylcholanthrene

U158 101-14-4 4,4′-Methylenebis(2-chloroaniline)

U068 74-95-3 Methylene bromide

U080 75-09-2 Methylene chloride

U159 78-93-3 Methyl ethyl ketone (MEK) (I,T)

U160 1338-23-4 Methyl ethyl ketone peroxide (R,T)

U138 74-88-4 Methyl iodide

U161 108-10-1 Methyl isobutyl ketone (I)

U162 80-62-6 Methyl methacrylate (I,T)

U161 108-10-1 4-Methyl-2-pentanone (I)

U164 56-04-2 Methylthiouracil

U010 50-07-7 Mitomycin C

U059 20830-81-3 5,12-Naphthacenedione, 8-acetyl-10-[(3-amino-2,3,6-trideoxy)-alpha-L-lyxo-

hexopyranosyl)oxy]-7,8,9,10-tetrahydro-6,8,11-trihydroxy-1-methoxy-, (8S-cis)-



Hazardous

waste No.

Chemical


U167 134-32-7 1-Naphthalenamine

U168 91-59-8 2-Naphthalenamine

U026 494-03-1 Naphthalenamine, N,N′-bis(2-chloroethyl)-

U165 91-20-3 Naphthalene

U047 91-58-7 Naphthalene, 2-chloro-

U166 130-15-4 1,4-Naphthalenedione

U236 72-57-1 2,7-Naphthalenedisulfonic acid, 3,3′-[(3,3′-

dimethyl[1,1′-biphenyl]-4,4′-diyl)bis(azo)bis[5-amino-4-hydroxy]-, tetrasodium salt

U279 63-25-2 1-Naphthalenol, methylcarbamate.

U166 130-15-4 1,4-Naphthoquinone

U167 134-32-7 alpha-Naphthylamine

U168 91-59-8 beta-Naphthylamine

U217 10102-45-1 Nitric acid, thallium(1+) salt

U169 98-95-3 Nitrobenzene (I,T)

U170 100-02-7 p-Nitrophenol

U171 79-46-9 2-Nitropropane (I,T)

U172 924-16-3 N-Nitrosodi-n-butylamine

U173 1116-54-7 N-Nitrosodiethanolamine

U174 55-18-5 N-Nitrosodiethylamine

U176 759-73-9 N-Nitroso-N-ethylurea

U177 684-93-5 N-Nitroso-N-methylurea

U178 615-53-2 N-Nitroso-N-methylurethane

U179 100-75-4 N-Nitrosopiperidine

U180 930-55-2 N-Nitrosopyrrolidine

U181 99-55-8 5-Nitro-o-toluidine

U193 1120-71-4 1,2-Oxathiolane, 2,2-dioxide

U058 50-18-0 2H-1,3,2-Oxazaphosphorin-2-amine,

N,N-bis(2-chloroethyl)tetrahydro-, 2-oxide

U115 75-21-8 Oxirane (I,T)

U126 765-34-4 Oxiranecarboxyaldehyde

U041 106-89-8 Oxirane, (chloromethyl)-

U182 123-63-7 Paraldehyde

U183 608-93-5 Pentachlorobenzene

U184 76-01-7 Pentachloroethane

U185 82-68-8 Pentachloronitrobenzene (PCNB)



Hazardous

waste No.

Chemical


See F027 87-86-5 Pentachlorophenol

U161 108-10-1 Pentanol, 4-methyl-

U186 504-60-9 1,3-Pentadiene (I)

U187 62-44-2 Phenacetin

U188 108-95-2 Phenol

U048 95-57-8 Phenol, 2-chloro-

U039 59-50-7 Phenol, 4-chloro-3-methyl-

U081 120-83-2 Phenol, 2,4-dichloro-

U082 87-65-0 Phenol, 2,6-dichloro-

U089 56-53-1 Phenol, 4,4′-(1,2-diethyl-1,2-ethenediyl)bis-, (E)-

U101 105-67-9 Phenol, 2,4-dimethyl-

U052 1319-77-3 Phenol, methyl-

U132 70-30-4 Phenol, 2,2′-methylenebis[3,4,6-trichloro-

U411 114-26-1 Phenol, 2-(1-methylethoxy)-, methylcarbamate.

U170 100-02-7 Phenol, 4-nitro-

See F027 87-86-5 Phenol, pentachloro-

See F027 58-90-2 Phenol, 2,3,4,6-tetrachloro-

See F027 95-95-4 Phenol, 2,4,5-trichloro-

See F027 88-06-2 Phenol, 2,4,6-trichloro-

U150 148-82-3 L-Phenylalanine, 4-[bis(2-chloroethyl)amino]-

U145 7446-27-7 Phosphoric acid, lead(2+) salt (2:3)

U087 3288-58-2 Phosphorodithioic acid, O,O-diethyl S-methyl ester

U189 1314-80-3 Phosphorus sulfide (R)

U190 85-44-9 Phthalic anhydride

U191 109-06-8 2-Picoline

U179 100-75-4 Piperidine, 1-nitroso-

U192 23950-58-5 Pronamide

U194 107-10-8 1-Propanamine (I,T)

U111 621-64-7 1-Propanamine, N-nitroso-N-propyl-

U110 142-84-7 1-Propanamine, N-propyl- (I)

U066 96-12-8 Propane, 1,2-dibromo-3-chloro-

U083 78-87-5 Propane, 1,2-dichloro-

U149 109-77-3 Propanedinitrile

U171 79-46-9 Propane, 2-nitro- (I,T)

U027 108-60-1 Propane, 2,2′-oxybis[2-chloro-



Hazardous

waste No.

Chemical


U193 1120-71-4 1,3-Propane sultone

See F027 93-72-1 Propanoic acid, 2-(2,4,5-trichlorophenoxy)-

U235 126-72-7 1-Propanol, 2,3-dibromo-, phosphate (3:1)

U140 78-83-1 1-Propanol, 2-methyl- (I,T)

U002 67-64-1 2-Propanone (I)

U007 79-06-1 2-Propenamide

U084 542-75-6 1-Propene, 1,3-dichloro-

U243 1888-71-7 1-Propene, 1,1,2,3,3,3-hexachloro-

U009 107-13-1 2-Propenenitrile

U152 126-98-7 2-Propenenitrile, 2-methyl- (I,T)

U008 79-10-7 2-Propenoic acid (I)

U113 140-88-5 2-Propenoic acid, ethyl ester (I)

U118 97-63-2 2-Propenoic acid, 2-methyl-, ethyl ester

U162 80-62-6 2-Propenoic acid, 2-methyl-, methyl ester (I,T)

U373 122-42-9 Propham.

U411 114-26-1 Propoxur.

U387 52888-80-9 Prosulfocarb.

U194 107-10-8 n-Propylamine (I,T)

U083 78-87-5 Propylene dichloride

U148 123-33-1 3,6-Pyridazinedione, 1,2-dihydro-

U196 110-86-1 Pyridine

U191 109-06-8 Pyridine, 2-methyl-

U237 66-75-1 2,4-(1H,3H)-Pyrimidinedione, 5-[bis(2-

chloroethyl)amino]-

U164 56-04-2 4(1H)-Pyrimidinone, 2,3-dihydro-6-methyl-2-thioxo-

U180 930-55-2 Pyrrolidine, 1-nitroso-

U200 50-55-5 Reserpine

U201 108-46-3 Resorcinol

U203 94-59-7 Safrole

U204 7783-00-8 Selenious acid

U204 7783-00-8 Selenium dioxide

U205 7488-56-4 Selenium sulfide

U205 7488-56-4 Selenium sulfide SeS2 (R,T)

U015 115-02-6 L-Serine, diazoacetate (ester)

See F027 93-72-1 Silvex (2,4,5-TP)



Hazardous

waste No.

Chemical


U206 18883-66-4 Streptozotocin

U103 77-78-1 Sulfuric acid, dimethyl ester

U189 1314-80-3 Sulfur phosphide (R)

See F027 93-76-5 2,4,5-T

U207 95-94-3 1,2,4,5-Tetrachlorobenzene

U208 630-20-6 1,1,1,2-Tetrachloroethane

U209 79-34-5 1,1,2,2-Tetrachloroethane

U210 127-18-4 Tetrachloroethylene

See F027 58-90-2 2,3,4,6-Tetrachlorophenol

U213 109-99-9 Tetrahydrofuran (I)

U214 563-68-8 Thallium(I) acetate

U215 6533-73-9 Thallium(I) carbonate

U216 7791-12-0 Thallium(I) chloride

U216 7791-12-0 thallium chloride TlCl

U217 10102-45-1 Thallium(I) nitrate

U218 62-55-5 Thioacetamide

U410 59669-26-0 Thiodicarb.

U153 74-93-1 Thiomethanol (I,T)

U244 137-26-8 Thioperoxydicarbonic diamide [(H2 N)C(S)]2 S2, tetramethyl-

U409 23564-05-8 Thiophanate-methyl.

U219 62-56-6 Thiourea

U244 137-26-8 Thiram

U220 108-88-3 Toluene

U221 25376-45-8 Toluenediamine

U223 26471-62-5 Toluene diisocyanate (R,T)

U328 95-53-4 o-Toluidine

U353 106-49-0 p-Toluidine

U222 636-21-5 o-Toluidine hydrochloride

U389 2303-17-5 Triallate.

U011 61-82-5 1H-1,2,4-Triazol-3-amine

U226 71-55-6 1,1,1-Trichloroethane

U227 79-00-5 1,1,2-Trichloroethane

U228 79-01-6 Trichloroethylene

U121 75-69-4 Trichloromonofluoromethane

See F027 95-95-4 2,4,5-Trichlorophenol



Hazardous

waste No.

Chemical


See F027 88-06-2 2,4,6-Trichlorophenol

U404 121-44-8 Triethylamine.

U234 99-35-4 1,3,5-Trinitrobenzene (R,T)

U182 123-63-7 1,3,5-Trioxane, 2,4,6-trimethyl-

U235 126-72-7 Tris(2,3-dibromopropyl) phosphate

U236 72-57-1 Trypan blue

U237 66-75-1 Uracil mustard

U176 759-73-9 Urea, N-ethyl-N-nitroso-

U177 684-93-5 Urea, N-methyl-N-nitroso-

U043 75-01-4 Vinyl chloride

U248 181-81-2 Warfarin, & salts, when present at concentrations of 0.3% or less

U239 1330-20-7 Xylene (I)

U200 50-55-5 Yohimban-16-carboxylic acid, 11,17-dimethoxy-18-[(3,4,5-trimethoxybenzoyl)oxy]-,

methyl ester, (3beta,16beta,17alpha,18beta,20alpha)-

U249 1314-84-7 Zinc phosphide Zn3 P2, when present at concentrations of 10% or less

APPENDIX 2

HAZARDOUS MATERIALS TABLE

§172.101 Hazardous Materials Table

(172.102) Tab 6Excep

tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Accellerene, see p-Nitrosodimethylaniline

Accumulators, electric, see Batteries, wet etc

Accumulators, pressurized, pneumatic or hydraulic

(containing non-flamable gas), see Articles

pressurized, pneumatic or hydraulic (containing non-

flamable gas)

Acetal 3 UN1088 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E

Acetaldehyde 3 UN1089 I 3 B16, T11, TP2, TP7 None 201 243 Forbidden 30 L E

A Acetaldehyde ammonia 9 UN1841 III 9IB8, IP3, IP7, T1,

TP33155 204 240 200 kg 200 kg A 34

Acetaldehyde oxime 3 UN2332 III 3 B1, IB3, T4, TP1 150 203 242 60 L 220 L A

Acetic acid, glacial or Acetic acid solution, with more

than 80 percent acid, by mass8 UN2789 II 8, 3

A3, A7, A10, B2, IB2,

T7, TP2154 202 243 1 L 30 L A 53, 58

Acetic acid solution, not less than 50 percent but not

more than 80 percent acid, by mass8 UN2790 II 8

148, A3, A7, A10,

B2, IB2, T7, TP2154 202 242 1 L 30 L A 53, 58

Acetic acid solution, with more than 10 percent and

less than 50 percent acid, by mass8 UN2790 III 8 148, IB3, T4, TP1 154 203 242 5 L 60 L A 53, 58

Acetic anhydride 8 UN1715 II 8, 3A3, A7, A10, B2, IB2,

T7, TP2154 202 243 1 L 30 L A

40,

53, 58

Acetone 3 UN1090 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Acetone cyanohydrin, stabilized 6.1 UN1541 I 6.1

2, B9, B14, B32, B76,

B77, N34, T20, TP2,

TP13, TP38, TP45

None 227 244 Forbidden Forbidden D

25,

40,

52, 53

Acetone oils 3 UN1091 II 3 IB2, T4, TP1, TP8 150 202 242 5 L 60 L B

Acetonitrile 3 UN1648 II 3 IB2, T7, TP2 150 202 242 5 L 60 L B 40

Acetyl acetone peroxide with more than 9 percent by

mass active oxygenForbidden

Acetyl benzoyl peroxide, solid, or with more than 40

percent in solutionForbidden

Acetyl bromide 8 UN1716 II 8 B2, IB2, T8, TP2 154 202 242 1 L 30 L C40,

53, 58

Sym

bols(§173.***)

Quantity limitations

(see §§173.27 and 175.75)

PackagingVessel StowageSpecial Provisions

Hazardous materials descriptions and proper shipping

names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

SET Environmental, Inc. A2-1 Last Revision: May 11, 2020



tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Acetyl chloride 3 UN1717 II 3, 8A3, A7, IB1, N34, T8,

TP2150 202 243 1 L 5 L B

40,

53, 58

Acetyl cyclohexanesulfonyl peroxide, with more than 82

percent wetted with less than 12 percent waterForbidden

Acetyl iodide 8 UN1898 II 8B2, IB2, T7, TP2,

TP13154 202 242 1 L 30 L C

40,

53, 58

Acetyl methyl carbinol 3 UN2621 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Acetyl peroxide, solid, or with more than 25 percent in

solutionForbidden

Acetylene, dissolved 2.1 UN1001 2.1 N86, N88 None 303 None Forbidden 15 kg D25,

40, 57

Acetylene (liquefied) Forbidden

Acetylene silver nitrate Forbidden

Acetylene, solvent free Forbidden

Acetylene tetrabromide, see Tetrabromoethane

Acid butyl phosphate, see Butyl acid phosphate

Acid, sludge, see Sludge acid

Acridine 6.1 UN2713 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Acrolein dimer, stabilized 3 UN2607 III 3 387, B1, IB3, T2, TP1 150 203 242 60 L 220 L C 25, 40

Acrolein, stabilized 6.1 UN1092 I 6.1, 3

1, 380, 387, B9, B14,

B30, B42, B77, T22,

TP2, TP7, TP13,

TP38, TP44

None 226 244 Forbidden Forbidden D 25, 40

Acrylamide, solid 6.1 UN2074 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 12, 25

Acrylamide solution 6.1 UN3426 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 12, 25

Acrylic acid, stabilized 8 UN2218 II 8, 3 387, B2, IB2, T7, TP2 154 202 243 1 L 30 L C

25,

40,

53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Acrylonitrile, stabilized 3 UN1093 I 3, 6.1387, B9, T14, TP2,

TP13None 201 243 Forbidden 30 L D 25, 40

Actuating cartridge, explosive, see Cartridges, power

device

Adhesives, containing a flammable liquid 3 UN1133 I 3 T11, TP1, TP8, TP27 150 201 243 1 L 30 L B

II 3149, B52, IB2, T4,

TP1, TP8150 173 242 5 L 60 L B

III 3 B1, B52, IB3, T2, TP1 150 173 242 60 L 220 L A

Adiponitrile 6.1 UN2205 III 6.1 IB3, T3, TP1 153 203 241 60 L 220 L A

G Adsorbed gas, n.o.s 2.2 UN3511 2.2 None 302c None 75 kg 150 kg A

G Adsorbed gas, flammable, n.o.s 2.1 UN3510 2.1 None 302c None Forbidden 150 kg D 40

G Adsorbed gas, oxidizing, n.o.s 2.2 UN35132.2,

5.1None 302c None 75 kg 150 kg D

G Adsorbed gas, toxic, n.o.s. Inhalation hazard zone A 2.3 UN3512 2.3 1 None 302c None Forbidden Forbidden D 40

G Adsorbed gas, toxic, n.o.s. Inhalation hazard zone B 2.3 UN3512 2.3 2, B9, B14 None 302c None Forbidden Forbidden D 40

G Adsorbed gas, toxic, n.o.s. Inhalation hazard zone C 2.3 UN3512 2.3 3, B14 None 302c None Forbidden Forbidden D 40

G Adsorbed gas, toxic, n.o.s. Inhalation hazard zone D 2.3 UN3512 2.3 4 None 302c None Forbidden Forbidden D 40

GAdsorbed gas, toxic, corrosive, n.o.s. Inhalation hazard

zone A2.3 UN3516 2.3, 8 1, 379 None 302c None Forbidden Forbidden D 40


zone B2.3 UN3516 2.3, 8 2, 379, B9, B14 None 302c None Forbidden Forbidden D 40


zone C2.3 UN3516 2.3, 8 3, 379, B14 None 302c None Forbidden Forbidden D 40


zone D2.3 UN3516 2.3, 8 4, 379 None 302c None Forbidden Forbidden D 40

GAdsorbed gas, toxic, flammable, n.o.s. Inhalation

hazard zone A2.3 UN3514

2.3,

2.11 None 302c None Forbidden Forbidden D 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes


hazard zone B2.3 UN3514

2.3,

2.12, B9, B14 None 302c None Forbidden Forbidden D 40


hazard zone C2.3 UN3514

2.3,

2.13, B14 None 302c None Forbidden Forbidden D 40


hazard zone D2.3 UN3514

2.3,


GAdsorbed gas, toxic, flammable, corrosive, n.o.s.

Inhalation hazard zone A2.3 UN3517

2.3,

2.1, 81 None 302c None Forbidden Forbidden D 17, 40


Inhalation hazard zone B2.3 UN3517

2.3,

2.1, 82, B9, B14 None 302c None Forbidden Forbidden D 17, 40


Inhalation hazard zone C2.3 UN3517

2.3,

2.1, 83, B14 None 302c None Forbidden Forbidden D 17, 40


Inhalation hazard zone D2.3 UN3517

2.3,

2.1, 84 None 302c None Forbidden Forbidden D 17, 40

GAdsorbed gas, toxic, oxidizing, n.o.s. Inhalation hazard

zone A2.3 UN3515

2.3,



zone B2.3 UN3515

2.3,

5.12, B9, B14 None 302c None Forbidden Forbidden D 40


zone C2.3 UN3515

2.3,

5.13, B14 None 302c None Forbidden Forbidden D 40


zone D2.3 UN3515

2.3,


GAdsorbed gas, toxic, oxidizing, corrosive, n.o.s.

Inhalation hazard zone A2.3 UN3518

2.3,

5.1, 81 None 302c None Forbidden Forbidden D

40,

89, 90


Inhalation hazard zone B2.3 UN3518

2.3,

5.1, 82, B9, B14 None 302c None Forbidden Forbidden D

40,

89, 90


Inhalation hazard zone C2.3 UN3518

2.3,

5.1, 83, B14 None 302c None Forbidden Forbidden D

40,

89, 90


Inhalation hazard zone D2.3 UN3518

2.3,

5.1, 84 None 302c None Forbidden Forbidden D

40,

89, 90

Aerosols, corrosive, Packing Group II or III, (each not

exceeding 1 L capacity).2.2 UN1950 2.2, 8 A34 306 None None 75 kg 150 kg A

25,

87,

126




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Aerosols, flammable, (each not exceeding 1 L capacity) 2.1 UN1950 2.1 N82 306 None None 75 kg 150 kg A

25,

87,

126

Aerosols, flammable, n.o.s. (engine starting fluid)

(each not exceeding 1 L capacity)2.1 UN1950 2.1 N82 306 304 None Forbidden 150 kg A

25,

87,

126

Aerosols, non-flammable, (each not exceeding 1 L

capacity)2.2 UN1950 2.2 306 None None 75 kg 150 kg A

25,

87,

126

Aerosols, poison, Packing Group III (each not

exceeding 1 L capacity)2.2 UN1950

2.2,

6.1306 None None Forbidden Forbidden A

25,

87,

126

Air bag inflators, or Air bag modules, or Seat-belt

pretensioners, see Safety devices, electrically initiated

or Safety devices, pyrotechnic

Air, compressed 2.2 UN1002 2.2 78306,

307302 302 75 kg 150 kg A

Air, refrigerated liquid, (cryogenic liquid) 2.2 UN1003 2.2,

5.1T75, TP5, TP22 320 316

318,

319Forbidden Forbidden D 51

Air, refrigerated liquid, (cryogenic liquid) non-

pressurized2.2 UN1003

2.2,

5.1T75, TP5, TP22 320 316

318,


Aircraft engines (including turbines), see Engines,

internal combustion

Aircraft evacuation slides, see Life saving appliances

etc

Aircraft hydraulic power unit fuel tank (containing a

mixture of anhydrous hydrazine and monomethyl

hydrazine) (M86 fuel)

3 UN3165 I3,

6.1, 8None 172 None Forbidden 42 L E

21,

40,

49,

100

Aircraft survival kits, see Life saving appliances etc

G Alcoholates solution, n.o.s., in alcohol 3 UN3274 II 3, 8 IB2 150 202 243 1 L 5 L B




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Alcoholic beverages 3 UN3065 II 324, 149, B1, IB2, T4,

TP1150 202 242 5 L 60 L A

III 324, B1, IB3, N11, T2,

TP1150 203 242 60 L 220 L A

Alcohols, n.o.s. 3 UN1987 I 3172, T11, TP1, TP8,

TP274b 201 243 1 L 30 L E

II 3172, IB2, T7, TP1,

TP8, TP28

4b,

150202 242 5 L 60 L B

III 3172, B1, IB3, T4,

TP1, TP29

4b,

150203 242 60 L 220 L A

G Alcohols, flammable, toxic n.o.s 3 UN1986 I 3, 6.1T14, TP2, TP13,

TP27None 201 243 Forbidden 30 L E 40

II 3, 6.1 IB2, T11, TP2, TP27 150 202 243 1 L 60 L B 40

III 3, 6.1B1, IB3, T7, TP1,

TP28150 203 242 60 L 220 L A

Aldehydes, n.o.s. 3 UN1989 I 3 T11, TP1, TP27 None 201 243 1 L 30 L E

II 3IB2, T7, TP1, TP8,

TP28150 202 242 5 L 60 L B

III 3B1, IB3, T4, TP1,

TP29150 203 242 60 L 220 L A

G Aldehydes, flammable, toxic, n.o.s. 3 UN1988 I 3, 6.1T14, TP2, TP13,


II 3, 6.1 IB2, T11, TP2, TP27 150 202 243 1 L 60 L B 40

III 3, 6.1B1, IB3, T7, TP1,

TP28150 203 242 60 L 220 L A

Aldol 6.1 UN2839 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 12, 25

G Alkali metal alcoholates, self-heating, corrosive, n.o.s 4.2 UN3206 II 4.2, 864, A7, IB5, IP2, T3,

TP33, W31None 212 242 15 kg 50 kg B

III 4.2, 864, A7, IB8, IP3, T1,

TP33, W31None 213 242 25 kg 100 kg B

Alkali metal alloys, liquid, n.o.s 4.3 UN1421 I 4.3A2, A7, B48, N34,

W31None 201 244 Forbidden 1 L D

13,

52,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Alkali metal amalgam, liquid 4.3 UN1389 I 4.3 A2, A7, N34, W31 None 201 244 Forbidden 1 L D

13,

40,

52,

148

Alkali metal amalgam, solid 4.3 UN3401 I 4.3IB4, IP1, N40, T9,

TP7, TP33, W31None 211 242 Forbidden 15 kg D

13,

52,

148

Alkali metal amides 4.3 UN1390 II 4.3

A6, A7, A8, A19,

A20, IB7, IP2, IP21,

T3, TP33, W31, W40

151 212 241 15 kg 50 kg E

13,

40,

52,

148

Alkali metal dispersions, flammable or Alkaline earth

metal dispersions, flammable4.3 UN3482 I 4.3, 3 A2, A7, W31 None 201 244 Forbidden 1 L D

13,

52,

148

Alkali metal dispersions, or Alkaline earth metal

dispersions4.3 UN1391 I 4.3 A2, A7, W31 None 201 244 Forbidden 1 L D

13,

52,

148

Alkaline corrosive liquids, n.o.s., see Caustic alkali

liquids, n.o.s.

G Alkaline earth metal alcoholates, n.o.s 4.2 UN3205 II 4.265, A7, IB6, IP2, T3,

TP33, W31None 212 241 15 kg 50 kg B

III 4.265, A7, IB8, IP3, T1,

TP33, W31None 213 241 25 kg 100 kg B

Alkaline earth metal alloys, n.o.s 4.3 UN1393 II 4.3A19, IB7, IP2, IP4,

T3, TP33, W31, W40151 212 241 15 kg 50 kg E

13,

52,

148

Alkaline earth metal amalgams, liquid 4.3 UN1392 I 4.3 A19, N34, N40, W31 None 201 244 Forbidden 1 L E

13,

40,

52,

148

Alkaline earth metal amalgams, solid 4.3 UN3402 I 4.3A19, N34, N40, T9,


13,

52,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Alkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s. 6.1 UN3140 I 6.1 A4, T14, TP2, TP27 None 201 243 1 L 30 L A

II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L A

III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A

GAlkaloids, solid, n.o.s. or Alkaloid salts, solid, n.o.s.

poisonous6.1 UN1544 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid

with more than 5 percent free sulfuric acid8 UN2584 II 8

B2, IB2, T8, TP2,

TP13154 202 242 1 L 30 L B 53, 58

Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid

with not more than 5 percent free sulfuric acid8 UN2586 III 8 IB3, T4, TP1 154 203 241 5 L 60 L B 53, 58

Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid,

with more than 5 percent free sulfuric acid8 UN2583 II 8

IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A 53, 58

Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid

with not more than 5 percent free sulfuric acid8 UN2585 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 53, 58

Alkylphenols, liquid, n.o.s. (including C2-C12

homologues)8 UN3145 I 8 T14, TP2 None 201 243 0.5 L 2.5 L B

II 8 IB2, T11, TP2, TP27 154 202 242 1 L 30 L B

III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A

Alkylphenols, solid, n.o.s. (including C2-C12

homologues)8 UN2430 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg B

II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg B

III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A

Alkylsulfuric acids 8 UN2571 II 8B2, IB2, T8, TP2,

TP13, TP28154 202 242 1 L 30 L C

14,

53, 58

Allethrin, see Pesticides, liquid, toxic, n.o.s.

Allyl acetate 3 UN2333 II 3, 6.1 IB2, T7, TP1, TP13 150 202 243 1 L 60 L E 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Allyl alcohol 6.1 UN1098 I 6.1, 3

2, B9, B14, B32, B77,

T20, TP2, TP13,

TP38, TP45

None 227 244 Forbidden Forbidden D 40

Allyl bromide 3 UN1099 I 3, 6.1 T14, TP2, TP13 None 201 243 Forbidden 30 L B 40

Allyl chloride 3 UN1100 I 3, 6.1 T14, TP2, TP13 None 201 243 Forbidden 30 L E 40

Allyl chlorocarbonate, see Allyl chloroformate

Allyl chloroformate 6.1 UN1722 I6.1,

3, 8

2, B9, B14, B32, N41,

T20, TP2, TP13,

TP38, TP45


21,

40,

53,

58,

100

Allyl ethyl ether 3 UN2335 II 3, 6.1 IB2, T7, TP1, TP13 150 202 243 1 L 60 L E 40

Allyl formate 3 UN2336 I 3, 6.1 T14, TP2, TP13 None 201 243 Forbidden 30 L E 40

Allyl glycidyl ether 3 UN2219 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Allyl iodide 3 UN1723 II 3, 8A3, IB1, N34, T7,

TP2, TP13150 202 243 1 L 5 L B

40,

53, 58

Allyl isothiocyanate, stabilized 6.1 UN1545 II 6.1, 3387, A3, A7, IB2, T7,


Allylamine 6.1 UN2334 I 6.1, 3

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP45


Allyltrichlorosilane, stabilized 8 UN1724 II 8, 3

387, A7, B2, B6,

N34, T10, TP2, TP7,

TP13

None 206 243 Forbidden 30 L C

25,

40,

53, 58

Aluminum borohydride or Aluminum borohydride in

devices4.2 UN2870 I

4.2,

4.3B11, T21, TP7, TP33 None 181 244 Forbidden Forbidden D

13,

148

Aluminum bromide, anhydrous 8 UN1725 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A

40,

53, 58

Aluminum bromide, solution 8 UN2580 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 53, 58

Aluminum carbide 4.3 UN1394 II 4.3

A20, IB7, IP2, IP21,

N41, T3, TP33, W31,

W40

151 212 242 15 kg 50 kg A

13,

52,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Aluminum chloride, anhydrous 8 UN1726 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A

40,

53, 58

Aluminum chloride, solution 8 UN2581 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 53, 58

Aluminum dross, wet or hot Forbidden

Aluminum ferrosilicon powder 4.3 UN1395 II4.3,

6.1

A19, IB5, IP2, T3,

TP33, W31, W40151 212 242 15 kg 50 kg A

13,

39,

40,

52,

53,

85,

103,

148

III4.3,

6.1A19, A20, IB4 151 213 241 25 kg 100 kg A

13,

39,

40,

52,

53,

85,

103,

148

Aluminum hydride 4.3 UN2463 I 4.3 A19, N40, W31 None 211 242 Forbidden 15 kg E13,

148

D Aluminum, molten 9 NA9260 III 9 IB3, T1, TP3 None None 247 Forbidden Forbidden D

Aluminum nitrate 5.1 UN1438 III 5.1A1, A29, IB8, IP3,

T1, TP33152 213 240 25 kg 100 kg A

Aluminum phosphate solution, see Corrosive liquids,

etc

Aluminum phosphide 4.3 UN1397 I4.3,

6.1A8, A19, N40, W31 None 211 242 Forbidden 15 kg E

13,

40,

52,

85,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Aluminum phosphide pesticides 6.1 UN3048 I 6.1A8, IB7, IP1, T6,

TP33, W31None 211 242 Forbidden 15 kg E 40, 85

Aluminum powder, coated 4.1 UN1309 II 4.1IB8, IP2, IP21, T3,

TP33, W100151 212 240 15 kg 50 kg A

13,

39,

52,

53,

74,

101,

147,

148

III 4.1B134, IB8, IP21, T1,

TP33, W100151 213 240 25 kg 100 kg A

13,

39,

52,

53,

74,

101,

147,

148

Aluminum powder, uncoated 4.3 UN1396 II 4.3

A19, A20, IB7, IP2,

IP21, T3, TP33,

W31, W40

151 212 242 15 kg 50 kg A

13,

39,

52,

53,

148

III 4.3A19, A20, IB8, IP21,

T1, TP33, W31151 213 241 25 kg 100 kg A

13,

39,

52,

53,

148

Aluminum resinate 4.1 UN2715 III 4.1 IB6, T1, TP33 151 213 240 25 kg 100 kg A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Aluminum silicon powder, uncoated 4.3 UN1398 III 4.3A1, A19, B136, IB8,

IP4, T1, TP33, W31151 213 241 25 kg 100 kg A

13,

39,

40,

52,

53,

85,

103,

148

Aluminum smelting by-products or Aluminum

remelting by-products4.3 UN3170 II 4.3

128, B115, IB7, IP2,

IP21, T3, TP33,

W31, W40

None 212 242 15 kg 50 kg B

13,

85,

103,

148

III 4.3128, B115, IB8, IP21,

T1, TP33, W31None 213 241 25 kg 100 kg B

13,

85,

103,

148

Amatols, see Explosives, blasting, type B

GAmine, flammable, corrosive, n.o.s. or Polyamines,

flammable, corrosive, n.o.s3 UN2733 I 3, 8 T14, TP1, TP27 None 201 243 0.5 L 2.5 L D 40, 52

II 3, 8 IB2, T11, TP1, TP27 150 202 243 1 L 5 L B 40, 52

III 3, 8B1, IB3, T7, TP1,

TP28150 203 242 5 L 60 L A 40, 52

GAmine, liquid, corrosive, flammable, n.o.s. or

Polyamines, liquid, corrosive, flammable, n.o.s8 UN2734 I 8, 3 N34, T14, TP2, TP27 None 201 243 0.5 L 2.5 L A 52

II 8, 3 IB2, T11, TP2, TP27 None 202 243 1 L 30 L A 52

GAmines, liquid, corrosive, n.o.s. or Polyamines, liquid,

corrosive, n.o.s8 UN2735 I 8

B10, N34, T14, TP2,

TP27None 201 243 0.5 L 2.5 L A 52

II 8B2, IB2, T11, TP1,

TP27154 202 242 1 L 30 L A 52

III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 52

GAmines, solid, corrosive, n.o.s., or Polyamines, solid,

corrosive n.o.s.8 UN3259 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg A 52




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes


TP33154 212 240 15 kg 50 kg A 52

III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 52

2-Amino-4-chlorophenol 6.1 UN2673 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

2-Amino-5-diethylaminopentane 6.1 UN2946 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

2-Amino-4,6-Dinitrophenol, wetted with not less than

20 percent water by mass4.1 UN3317 I 4.1

23, A8, A19, A20,

N41, W31None 211 None 1 kg 15 kg E 28, 36

2-(2-Aminoethoxy) ethanol 8 UN3055 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 52

N-Aminoethylpiperazine 8 UN2815 III 8, 6.1 IB3, T4, TP1 154 203 241 5 L 60 L B

12,

25,

40, 52

+ Aminophenols (o-; m-; p- ) 6.1 UN2512 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Aminopropyldiethanolamine, see Amines, etc

n-Aminopropylmorpholine, see Amines, etc

Aminopyridines (o-; m-; p-) 6.1 UN2671 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B

12,

25,

40, 52

I Ammonia, anhydrous 2.3 UN1005 2.3, 8 4, 379, N87, T50 None 304314,

315Forbidden Forbidden D

40,

52, 57

D Ammonia, anhydrous 2.2 UN1005 2.2 13, 379, T50 None 304314,


40,

52, 57

Ammonia solution, relative density less than 0.880 at

15 degrees C in water, with more than 35 percent but

not more than 50 percent ammonia

2.2 UN2073 2.2 N87 306 304314,

315Forbidden 150 kg E

40,

52, 57

Ammonia solution, relative density between 0.880 and

0.957 at 15 degrees C in water, with more than 10

percent but not more than 35 percent ammonia

8 UN2672 III 8336, IB3, IP8, T7,

TP2154 203 241 5L 60L A

40,

52, 85

I


15 degrees C in water, with more than 50 percent

ammonia

2.3 UN3318 2.3, 8 4, N87, T50 None 304314,


40,

52, 57




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

D


15 degrees C in water, with more than 50 percent

ammonia

2.2 UN3318 2.2 13, T50 None 304314,


40,

52, 57

Ammonium arsenate 6.1 UN1546 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 53

Ammonium azide Forbidden

Ammonium bifluoride, solid, see Ammonium hydrogen

difluoride, solid

Ammonium bifluoride solution, see Ammonium

hydrogen difluoride, solution

Ammonium bromate Forbidden

Ammonium chlorate Forbidden

Ammonium dichromate 5.1 UN1439 II 5.1IB8, IP2, IP4, T3,

TP33152 212 242 5 kg 25 kg A 52

Ammonium dinitro-o-cresolate, solid 6.1 UN1843 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B

36,

65,

66, 77

Ammonium dinitro-o-cresolate solution 6.1 UN3424 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L B

36,

66,

78, 91

III 6.1 IB2, T7, TP2 153 203 241 60 L 220 L A

36,

66,

78, 91

Ammonium fluoride 6.1 UN2505 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52

Ammonium fluorosilicate 6.1 UN2854 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52

Ammonium fulminate Forbidden

Ammonium hydrogen sulfate 8 UN2506 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A

40,

53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Ammonium hydrogendifluoride, solid 8 UN1727 II 8IB8, IP2, IP4, N34,

T3, TP33154 212 240 15 kg 50 kg A

25,

40,

52,

53, 58

Ammonium hydrogendifluoride, solution 8 UN2817 II 8, 6.1IB2, N34, T8, TP2,

TP13154 202 243 1 L 30 L B

40,

53, 58

III 8, 6.1IB3, N3, T4, TP1,

TP13154 203 241 5 L 60 L B

40,

53,

58, 95

Ammonium hydrosulfide, solution, see Ammonium

sulfide solution

D Ammonium hydroxide, see Ammonia solutions, etc

Ammonium metavanadate 6.1 UN2859 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

44,

89,

100,

141

Ammonium nitrate based fertilizer 5.1 UN2067 III 5.152, 148, 150, B120,

IB8, IP3, T1, TP33152 213 240 25 kg 100 kg B

25,

59,

60,

66,

117,

124*

A W Ammonium nitrate based fertilizer 9 UN2071 III 9 132, B136, IB8, IP3 155 213 240 200 kg 200 kg A

Ammonium nitrate emulsion or Ammonium nitrate

suspension or Ammonium nitrate gel, intermediate for

blasting explosives

5.1 UN3375 II 5.1147, 148, 163, IB2,

IP16None 231 251 Forbidden Forbidden D

25,

59,

60,

66,

124

DAmmonium nitrate-fuel oil mixture containing only

prilled ammonium nitrate and fuel oil1.5D NA0331 1.5D 148 None 62 None Forbidden Forbidden 3

25,

19E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Ammonium nitrate, liquid (hot concentrated solution) 5.1 UN2426 5.1 148, B5, T7 None None 243 Forbidden Forbidden D

59,

60,

124

Ammonium nitrate, with more than 0.2 percent

combustible substances, including any organic

substance calculated as carbon, to the exclusion of any

other added substance

1.1D UN0222 1.1D 370 None 62 None Forbidden Forbidden 425,

19E

Ammonium nitrate, with not more than 0.2%

combustible substances, including any organic

substance calculated as carbon, to the exclusion of any

other added substance

5.1 UN1942 III 5.1148, A1, A29, B120,

IB8, IP3, T1, TP33152 213 240 25 kg 100 kg A

25,

59,

60,

66,

116,

124

Ammonium nitrite Forbidden

Ammonium perchlorate 1.1D UN0402 1.1D 107 None 62 None Forbidden Forbidden 425,

19E

Ammonium perchlorate 5.1 UN1442 II 5.1107, A9, IB6, IP2,

T3, TP33152 212 242 5 kg 25 kg E 58, 69

Ammonium permanganate Forbidden

Ammonium persulfate 5.1 UN1444 III 5.1A1, A29, IB8, IP3,

T1, TP33152 213 240 25 kg 100 kg A

Ammonium picrate, dry or wetted with less than 10

percent water, by mass1.1D UN0004 1.1D None 62 None Forbidden Forbidden 4

25,

5E,

19E

Ammonium picrate, wetted with not less than 10

percent water, by mass4.1 UN1310 I 4.1 23, A2, N41, W31 None 211 None 0.5 kg 0.5 kg D 28, 36

Ammonium polysulfide, solution 8 UN2818 II 8, 6.1 IB2, T7, TP2, TP13 154 202 243 1 L 30 L B

12,

25,

40, 52




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

III 8, 6.1 IB3, T4, TP1, TP13 154 203 241 5 L 60 L B

12,

25,

40, 52

Ammonium polyvanadate 6.1 UN2861 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

44,

89,

100,

141

Ammonium silicofluoride, see Ammonium

fluorosilicate

Ammonium sulfide solution 8 UN2683 II8,

6.1, 3IB1, T7, TP2, TP13 154 202 243 1 L 30 L B

12,

22,

25,

52,

100

Ammunition, blank, see Cartridges for weapons, blank

Ammunition, illuminating with or without burster,

expelling charge or propelling charge1.2G UN0171 1.2G 62 62 Forbidden Forbidden 3 25


expelling charge or propelling charge1.3G UN0254 1.3G 62 62 Forbidden Forbidden 3 25


expelling charge or propelling charge1.4G UN0297 1.4G 62 62 Forbidden 75 kg 2 25

Ammunition, incendiary liquid or gel, with burster,

expelling charge or propelling charge1.3J UN0247 1.3J 62 None Forbidden Forbidden 5

25,

23E

Ammunition, incendiary (water-activated contrivances)

with burster, expelling charge or propelling charge, see

Contrivances, water-activated, etc.

Ammunition, incendiary, white phosphorus, with

burster, expelling charge or propelling charge1.2H UN0243 1.2H 62 62 Forbidden Forbidden 5

25,

14E,

15E,

17E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Ammunition, incendiary, white phosphorus, with

burster, expelling charge or propelling charge1.3H UN0244 1.3H 62 62 Forbidden Forbidden 5

25,

14E,

15E,

17E

Ammunition, incendiary with or without burster,

expelling charge, or propelling charge1.2G UN0009 1.2G 62 62 Forbidden Forbidden 3 25


expelling charge, or propelling charge1.3G UN0010 1.3G 62 62 Forbidden Forbidden 3 25


expelling charge or propelling charge1.4G UN0300 1.4G 62 62 Forbidden 75 kg 2 25

Ammunition, practice 1.4G UN0362 1.4G 62 62 Forbidden 75 kg 2 25

Ammunition, practice 1.3G UN0488 1.3G 62 62 Forbidden Forbidden 3 25

Ammunition, proof 1.4G UN0363 1.4G 62 62 Forbidden 75 kg 2 25

Ammunition, rocket, see Warheads, rocket etc

Ammunition, SA (small arms), see Cartridges for

weapons, etc

Ammunition, smoke (water-activated contrivances),

white phosphorus, with burster, expelling charge or

propelling charge, see Contrivances, water-activated,

etc. (UN 0248)

Ammunition, smoke (water-activated contrivances),

without white phosphorus or phosphides, with burster,

expelling charge or propelling charge, see

Contrivances, water-activated, etc. (UN 0249)

Ammunition smoke, white phosphorus with burster,

expelling charge, or propelling charge1.2H UN0245 1.2H 62 62 Forbidden Forbidden 5

25,

14E,

15E,

17E

Ammunition, smoke, white phosphorus with burster,

expelling charge, or propelling charge1.3H UN0246 1.3H 62 62 Forbidden Forbidden 5

25,

14E,

15E,

17E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Ammunition, smoke with or without burster, expelling

charge or propelling charge1.2G UN0015 1.2G 62 62 Forbidden Forbidden 3

25,

17E


charge or propelling charge1.3G UN0016 1.3G 62 62 Forbidden Forbidden 3

25,

17E


charge or propelling charge1.4G UN0303 1.4G 62 62 Forbidden 75 kg 2

25,

14E,

15E,

17E

Ammunition, sporting, see Cartridges for weapons,

etc. (UN 0012; UN 0328; UN 0339)

Ammunition, tear-producing, non-explosive, without

burster or expelling charge, non-fuzed6.1 UN2017 6.1, 8 None 212 None Forbidden 50 kg E 13, 40

Ammunition, tear-producing with burster, expelling

charge or propelling charge1.2G UN0018

1.2G,

8, 6.162 62 Forbidden Forbidden 3

25,

17E



1.3G,

8, 6.162 62 Forbidden Forbidden 3

25,

17E



1.4G,

8, 6.162 62 Forbidden 75 kg 2

25,

14E,

15E,

17E

Ammunition, toxic, non-explosive, without burster or

expelling charge, non-fuzed6.1 UN2016 6.1 None 212 None Forbidden 100 kg E 13, 40

Ammunition, toxic (water-activated contrivances), with

burster, expelling charge or propelling charge, see

Contrivances, water-activated, etc

GAmmunition, toxic with burster, expelling charge, or

propelling charge1.2K UN0020

1.2K,

6.162 None Forbidden Forbidden 5

25,

14E,

15E,

17E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

GAmmunition, toxic with burster, expelling charge, or

propelling charge1.3K UN0021

1.3K,

6.162 None Forbidden Forbidden 5

25,

14E,

15E,

17E

Amyl acetates 3 UN1104 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Amyl acid phosphate 8 UN2819 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 53, 58

Amyl butyrates 3 UN2620 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Amyl chloride 3 UN1107 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Amyl formates 3 UN1109 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Amyl mercaptan 3 UN1111 II 3 A3, IB2, T4, TP1 None 202 242 5 L 60 L B95,

102

n-Amyl methyl ketone 3 UN1110 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Amyl nitrate 3 UN1112 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 40

Amyl nitrite 3 UN1113 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E 40

Amylamines 3 UN1106 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 52

III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A 52

Amyltrichlorosilane 8 UN1728 II 8A7, B2, B6, N34,

T10, TP2, TP7, TP13None 206 242 Forbidden 30 L C

40,

53, 58

Anhydrous ammonia, see Ammonia, anhydrous

Anhydrous hydrofluoric acid, see Hydrogen fluoride,

anhydrous

+ Aniline 6.1 UN1547 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40, 52

Aniline hydrochloride 6.1 UN1548 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Aniline oil, see Aniline

Anisidines 6.1 UN2431 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Anisole 3 UN2222 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Anisoyl chloride 8 UN1729 II 8B2, B4, IB8, IP2, IP4,

T3, TP33154 212 240 15 kg 50 kg A

40,

53, 58

Anti-freeze, liquid, see Flammable liquids, n.o.s.

Antimonous chloride, see Antimony trichloride

G Antimony compounds, inorganic, liquid, n.o.s 6.1 UN3141 III 6.135, IB3, T7, TP1,

TP28153 203 241 60 L 220 L A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Antimony compounds, inorganic, solid, n.o.s 6.1 UN1549 III 6.135, IB8, IP3, T1,

TP33153 213 240 100 kg 200 kg A

Antimony lactate 6.1 UN1550 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Antimony pentachloride, liquid 8 UN1730 II 8 B2, IB2, T7, TP2 None 202 242 1 L 30 L C40,

53, 58

Antimony pentachloride, solutions 8 UN1731 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L C40,

53, 58

III 8 IB3, T4, TP1 154 203 241 5 L 60 L C40,

53, 58

Antimony pentafluoride 8 UN1732 II 8, 6.1A3, A7, A10, IB2,

N3, N36, T7, TP2None 202 243 Forbidden 30 L D

40,

44,

53,

58,

89,

100,

141

Antimony potassium tartrate 6.1 UN1551 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Antimony powder 6.1 UN2871 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Antimony sulfide and a chlorate, mixtures of Forbidden

Antimony sulfide, solid, see Antimony compounds,

inorganic, n.o.s.

Antimony trichloride, liquid 8 UN1733 II 8 B2, IB2 154 202 242 1 L 30 L C40,

53, 58

Antimony trichloride, solid 8 UN1733 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A

40,

53, 58

Aqua ammonia, see Ammonia solution, etc

Argon, compressed 2.2 UN1006 2.2 306,

307302

314,

31575 kg 150 kg A

Argon, refrigerated liquid (cryogenic liquid) 2.2 UN1951 2.2 T75, TP5 320 316 318 50 kg 500 kg D

Arsenic 6.1 UN1558 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Arsenic acid, liquid 6.1 UN1553 I 6.1T20, TP2, TP7, TP13,

W31None 201 243 1 L 30 L B 46

Arsenic acid, solid 6.1 UN1554 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Arsenic bromide 6.1 UN1555 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

12,

25, 40

Arsenic chloride, see Arsenic trichloride

G

Arsenic compounds, liquid, n.o.s. inorganic, including

arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides,

n.o.s.; and organic compounds of arsenic, n.o.s

6.1 UN1556 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B

40,

137

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B

40,

137

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L B40,

137

G

Arsenic compounds, solid, n.o.s. inorganic, including

arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides,

n.o.s.; and organic compounds of arsenic, n.o.s

6.1 UN1557 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 137

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 137

III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 137

Arsenic pentoxide 6.1 UN1559 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Arsenic sulfide and a chlorate, mixtures of Forbidden

Arsenic trichloride 6.1 UN1560 I 6.1

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP45

None 227 244 Forbidden Forbidden B 40

Arsenic trioxide 6.1 UN1561 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Arsenic, white, solid, see Arsenic trioxide




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Arsenical dust 6.1 UN1562 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Arsenical pesticides, liquid, flammable, toxic, flash

point less than 23 degrees C3 UN2760 I 3, 6.1

T14, TP2, TP13,

TP27None 201 243 Forbidden 30 L B 40

II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40

Arsenical pesticides, liquid, toxic 6.1 UN2994 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40

Arsenical pesticides, liquid, toxic, flammable, flash

point not less than 23 degrees C6.1 UN2993 I 6.1, 3

T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1, 3B1, IB3, T7, TP2,

TP28153 203 242 60 L 220 L A 40

Arsenical pesticides, solid, toxic 6.1 UN2759 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Arsenious acid, solid, see Arsenic trioxide

Arsenious and mercuric iodide solution, see Arsenic

compounds, liquid, n.o.s.

Arsine 2.3 UN2188 2.3,

2.11 None 192 245 Forbidden Forbidden D 40

Arsine, adsorbed 2.3 UN35222.3,

2.11 None 302c None Forbidden Forbidden D

GArticles containing a substance liable to spontaneous

combustion, n.o.s4.2 UN3542 131, 391 None 214 214 Forbidden Forbidden

GArticles containing a substance which in contact with

water emits flammable gases, n.o.s4.3 UN3543 131, 391 None 214 214 Forbidden Forbidden

G Articles containing corrosive substance, n.o.s 8 UN3547 391 None 232 232 Forbidden Forbidden B




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Articles containing flammable gas, n.o.s 2.1 UN3537 391 None 232 232 Forbidden Forbidden D

G Articles containing flammable liquid, n.o.s 3 UN3540 391 None 232 232 Forbidden Forbidden B

G Articles containing flammable solid, n.o.s 4.1 UN3541 391 None 232 232 Forbidden Forbidden B

GArticles containing miscellaneous dangerous goods,

n.o.s9 UN3548 391 None 232 232 Forbidden Forbidden A

G Articles containing non-flammable, non-toxic gas, n.o.s 2.2 UN3538 391 None 232 232 Forbidden Forbidden A

G Articles containing organic peroxide, n.o.s 5.2 UN3545 131, 391 None 214 214 Forbidden Forbidden

G Articles containing oxidizing substance, n.o.s 5.1 UN3544 131, 391 None 214 214 Forbidden Forbidden

G Articles containing toxic gas, n.o.s 2.3 UN3539 131, 391 None 214 214 Forbidden Forbidden

G Articles containing toxic substance, n.o.s 6.1 UN3546 391 None 232 232 Forbidden Forbidden B

Articles, explosive, extremely insensitive or Articles,

EEI1.6N UN0486 1.6N None 62 None Forbidden Forbidden 3 25

G Articles, explosive, n.o.s 1.4S UN0349 1.4S 101, 148, 347, 382 None 62 None 25 kg 100 kg 1 25

G Articles, explosive, n.o.s. 1.4B UN0350 1.4B 101 None 62 None Forbidden Forbidden 5 25

G Articles, explosive, n.o.s. 1.4C UN0351 1.4C 101 None 62 None Forbidden 75 kg 2 25

G Articles, explosive, n.o.s. 1.4D UN0352 1.4D 101 None 62 None Forbidden 75 kg 2 25

G Articles, explosive, n.o.s. 1.4G UN0353 1.4G 101 None 62 None Forbidden 75 kg 2 25

G Articles, explosive, n.o.s. 1.1L UN0354 1.1L 101 None 62 None Forbidden Forbidden 2

25,

14E,

15E


25,

14E,

15E


25,

14E,

15E

G Articles, explosive, n.o.s 1.1C UN0462 1.1C 101 None 62 None Forbidden Forbidden 3 25

G Articles, explosive, n.o.s 1.1D UN0463 1.1D 101 None 62 None Forbidden Forbidden 3 25

G Articles, explosive, n.o.s 1.1E UN0464 1.1E 101 None 62 None Forbidden Forbidden 3 25

G Articles, explosive, n.o.s 1.1F UN0465 1.1F 101 None 62 None Forbidden Forbidden 3 25


G Articles, explosive, n.o.s 1.2D UN0467 1.2D 101 None 62 None Forbidden Forbidden 3 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Articles, explosive, n.o.s 1.2E UN0468 1.2E 101 None 62 None Forbidden Forbidden 3 25



G Articles, explosive, n.o.s. 1.4E UN0471 1.4E 101 None 62 None Forbidden 75 kg 3 25


Articles, pressurized pneumatic or hydraulic containing

non-flammable gas2.2 UN3164 2.2 371 306

302,

304None No limit No limit A

Articles, pyrophoric 1.2L UN0380 1.2L None 62 None Forbidden Forbidden 5

25,

14E,

15E,

17E

Articles, pyrotechnic for technical purposes 1.1G UN0428 1.1G None 62 None Forbidden Forbidden 3 25



Articles, pyrotechnic for technical purposes 1.4G UN0431 1.4G 381 None 62 None Forbidden 75 kg 2 25

Articles, pyrotechnic for technical purposes 1.4S UN0432 1.4S None 62 None 25 kg 100 kg 1 25

D Asbestos 9 NA2212 III 9 156, IB8, IP2, IP4 155 216216,

240200 kg 200 kg A 34, 40

G IAsbestos, amphibole amosite, tremolite, actinolite,

anthophyllite, or crocidolite9 UN2212 II 9

156, IB8, IP2, IP4,

T3, TP33155 216

216,

240Forbidden Forbidden A 34, 40

I Asbestos, chrysotile 9 UN2590 III 9156, IB8, IP2, IP3,

T1, TP33155 216

216,

240200 kg 200 kg A 34, 40

Ascaridole (organic peroxide) Forbidden

D Asphalt, at or above its flash point 3 NA1999 III 3 IB3, T1, TP3 150 203 247 Forbidden Forbidden D

D Asphalt, cut back, see Tars, liquid, etc

Automobile, motorcycle, tractor, other self-propelled

vehicle, engine, or other mechanical apparatus, see

Vehicles or Battery etc

A,

GAviation regulated liquid, n.o.s 9 UN3334 9 A35, A189 155 204 450 L 450 L A

A,

GAviation regulated solid, n.o.s 9 UN3335 9 A35 155 204 400 kg 400 kg A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Azaurolic acid (salt of) (dry) Forbidden

Azido guanidine picrate (dry) Forbidden

5-Azido-1-hydroxy tetrazole Forbidden

Azido hydroxy tetrazole (mercury and silver salts) Forbidden

3-Azido-1,2-Propylene glycol dinitrate Forbidden

Azidodithiocarbonic acid Forbidden

Azidoethyl nitrate Forbidden

1-Aziridinylphosphine oxide-(tris), see Tris-(1-aziridinyl)

phosphine oxide, solution

Azodicarbonamide 4.1 UN3242 II 4.1 38, IB8, T3, TP33 151 223 240 Forbidden Forbidden D2, 52,

53, 74

Azotetrazole (dry) Forbidden

Barium 4.3 UN1400 II 4.3A19, IB7, IP2, IP21,

T3, TP33, W31, W40151 212 241 15 kg 50 kg E

13,

52,

148

Barium alloys, pyrophoric 4.2 UN1854 I 4.2 T21, TP7, TP33, W31 None 181 None Forbidden Forbidden D13,

148

Barium azide, dry or wetted with less than 50 percent

water, by mass1.1A UN0224

1.1A,

6.1111, 117 None 62 None Forbidden Forbidden 5 25

Barium azide, wetted with not less than 50 percent

water, by mass4.1 UN1571 I

4.1,

6.1162, A2, W31 None 182 None Forbidden 0.5 kg D 28, 36

Barium bromate 5.1 UN2719 II5.1,

6.1

IB8, IP2, IP4, T3,

TP33152 212 242 5 kg 25 kg A 56, 58

Barium chlorate, solid 5.1 UN1445 II5.1,

6.1

A9, IB6, IP2, N34,

T3, TP33152 212 242 5 kg 25 kg A 56, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Barium chlorate, solution 5.1 UN3405 II5.1,

6.1

A9, IB2, N34, T4,

TP1152 202 243 1 L 5 L A

56,

58,

133

III5.1,

6.1

A9, IB2, N34, T4,

TP1152 203 242 2.5 L 30 L A

56,

58,

133

G Barium compounds, n.o.s 6.1 UN1564 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A


Barium cyanide 6.1 UN1565 I 6.1IB7, IP1, N74, N75,

T6, TP33, W31None 211 242 5 kg 50 kg A 40, 52

Barium hypochlorite with more than 22 percent

available chlorine5.1 UN2741 II

5.1,

6.1

A7, A9, IB8, IP2, IP4,

N34, T3, TP33152 212 None 5 kg 25 kg B

4, 52,

56,

58,

106

Barium nitrate 5.1 UN1446 II5.1,

6.1

IB8, IP2, IP4, T3,

TP33152 212 242 5 kg 25 kg A

Barium oxide 6.1 UN1884 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Barium perchlorate, solid 5.1 UN1447 II5.1,

6.1IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58

Barium perchlorate, solution 5.1 UN3406 II5.1,

6.1IB2, T4, TP1 152 202 243 1 L 5 L A

56,

58,

133

III5.1,

6.1IB2, T4, TP1 152 203 242 2.5 L 30 L A

56,

58,

133

Barium permanganate 5.1 UN1448 II5.1,

6.1IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg D

56,

58,

138




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Barium peroxide 5.1 UN1449 II5.1,

6.1

A9, IB6, IP2, T3,

TP33, W100152 212 242 5 kg 25 kg C

13,

52,

66,

75,

148

Barium selenate, see Selenates or Selenites

Barium selenite, see Selenates or Selenites

Batteries, containing sodium 4.3 UN3292 4.3 189 189 189 Forbidden No limit A13,

148

Batteries, dry, containing potassium hydroxide solid,

electric storage8 UN3028 8 237 None 213 None 25 kg 230 kg A 52

Batteries, dry, sealed, n.o.s. 130

W

Batteries, nickel-metal hydride see Batteries, dry,

sealed, n.o.s. for nickel-metal hydride batteries

transported by modes other than vessel

9 UN3496 9 340 A 25

Batteries, wet, filled with acid, electric storage 8 UN2794 8 A51 159 159 159 30 kg No limit A

53,

58,

146

Batteries, wet, filled with alkali, electric storage 8 UN2795 8 A51 159 159 159 30 kg No limit A52,

146

Batteries, wet, non-spillable, electric storage 8 UN2800 8 159a 159 159 No limit No limit A

Battery fluid, acid 8 UN2796 II 8A3, A7, B2, B15, IB2,

N6, N34, T8, TP2154 202 242 1 L 30 L B

Battery fluid, alkali 8 UN2797 II 8B2, IB2, N6, T7, TP2,

TP28154 202 242 1 L 30 L A 29

Battery lithium type, see Lithium batteries etc

Battery-powered vehicle or Battery-powered

equipment9 UN3171 9 134 220 220 None No limit No limit A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Battery, wet, filled with acid or alkali with vehicle or

mechanical equipment containing an internal

combustion engine, see Vehicle, etc. or Engines,

internal combustion, etc

+ Benzaldehyde 9 UN1990 III 9 IB3, T2, TP1 155 203 241 100 L 220 L A

Benzene 3 UN1114 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40

Benzene diazonium chloride (dry) Forbidden

Benzene diazonium nitrate (dry) Forbidden

Benzene phosphorus dichloride, see Phenyl

phosphorus dichloride

Benzene phosphorus thiodichloride, see Phenyl

phosphorus thiodichloride

Benzene sulfonyl chloride 8 UN2225 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 40

Benzene triozonide Forbidden

Benzenethiol, see Phenyl mercaptan

Benzidine 6.1 UN1885 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

1, 3, 2-Benzodioxaborole A210

Benzol, see Benzene

Benzonitrile 6.1 UN2224 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40, 52

Benzoquinone 6.1 UN2587 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Benzotrichloride 8 UN2226 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A40,

53, 58

Benzotrifluoride 3 UN2338 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40

Benzoxidiazoles (dry) Forbidden

Benzoyl azide Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Benzoyl chloride 8 UN1736 II 8B2, IB2, T8, TP2,

TP13154 202 242 1 L 30 L C

40,

53, 58

Benzyl bromide 6.1 UN1737 II 6.1, 8A3, A7, IB2, N33,

N34, T8, TP2, TP13None 202 243 1 L 30 L D

13,

40,

53, 58

Benzyl chloride 6.1 UN1738 II 6.1, 8

A3, A7, B70, IB2,

N33, N42, T8, TP2,

TP13

None 202 243 1 L 30 L D

13,

40,

53, 58

Benzyl chloride unstabilized 6.1 UN1738 II 6.1, 8

A3, A7, B8, B11, IB2,

N33, N34, N43, T8,

TP2, TP13

153 202 243 1 L 30 L D

13,

40,

53, 58

Benzyl chloroformate 8 UN1739 I 8B4, N41, T10, TP2,

TP13None 201 243 Forbidden 2.5 L D

40,

53, 58

Benzyl iodide 6.1 UN2653 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L B 12, 40

Benzyldimethylamine 8 UN2619 II 8, 3 B2, IB2, T7, TP2 154 202 243 1 L 30 L A25,

40, 52

Benzylidene chloride 6.1 UN1886 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L D 40

G Beryllium compounds, n.o.s 6.1 UN1566 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A


Beryllium nitrate 5.1 UN2464 II5.1,

6.1

IB8, IP2, IP4, T3,

TP33152 212 242 5 kg 25 kg A

Beryllium, powder 6.1 UN1567 II6.1,

4.1

IB8, IP2, IP4, T3,

TP33, W100153 212 242 15 kg 50 kg A

13,

147,

148

Bicyclo [2,2,1] hepta-2,5-diene, stabilized or 2,5-

Norbornadiene, stabilized3 UN2251 II 3 387, IB2, T7, TP2 150 202 242 5 L 60 L D 25

Biological substance, Category B 6.2 UN3373 A82 134 199 None 4 L or 4 kg 4 L or 4 kg A 40

Biphenyl triozonide Forbidden

Bipyridilium pesticides, liquid, flammable, toxic, flash


T14, TP2, TP13,

TP27None 201 243 Forbidden 30 L E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40

Bipyridilium pesticides, liquid, toxic 6.1 UN3016 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40

Bipyridilium pesticides, liquid, toxic, flammable, flash


T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 21, 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 21, 40

III 6.1, 3B1, IB3, T7, TP2,

TP28153 203 242 60 L 220 L A 21, 40

Bipyridilium pesticides, solid, toxic 6.1 UN2781 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Bis (Aminopropyl) piperazine, see Corrosive liquid,

n.o.s.

Bisulfate, aqueous solution 8 UN2837 II 8A7, B2, IB2, N34, T7,

TP2154 202 242 1 L 30 L A

III 8A7, IB3, N34, T4,

TP1154 203 241 5 L 60 L A

Bisulfites, aqueous solutions, n.o.s. 8 UN2693 III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 40, 52

Black powder, compressed or Gunpowder, compressed

or Black powder, in pellets or Gunpowder, in pellets1.1D UN0028 1.1D None 62 None Forbidden Forbidden 4 25

Black powder or Gunpowder, granular or as a meal 1.1D UN0027 1.1D None 62 None Forbidden Forbidden 4 25

D Black powder for small arms 4.1 NA0027 I 4.1 70 None 170 None Forbidden Forbidden E

Blasting agent, n.o.s., see Explosives, blasting etc




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Blasting cap assemblies, see Detonator assemblies,

non-electric, for blasting

Blasting caps, electric, see Detonators, electric for

blasting

Blasting caps, non-electric, see Detonators, non-

electric, for blasting

Bleaching powder, see Calcium hypochlorite mixtures,

etc

Bombs, photo-flash 1.1F UN0037 1.1F 62 None Forbidden Forbidden 3 25

Bombs, photo-flash 1.1D UN0038 1.1D 62 62 Forbidden Forbidden 3 25

Bombs, photo-flash 1.2G UN0039 1.2G 62 62 Forbidden Forbidden 3 25

Bombs, photo-flash 1.3G UN0299 1.3G 62 62 Forbidden Forbidden 3 25

Bombs, smoke, non-explosive, with corrosive liquid,

without initiating device8 UN2028 II 8 None 160 None Forbidden 50 kg E 40

Bombs, with bursting charge 1.1F UN0033 1.1F 62 None Forbidden Forbidden 3 25

Bombs, with bursting charge 1.1D UN0034 1.1D 62 62 Forbidden Forbidden 3 25

Bombs, with bursting charge 1.2D UN0035 1.2D 62 62 Forbidden Forbidden 3 25

Bombs, with bursting charge 1.2F UN0291 1.2F 62 None Forbidden Forbidden 3 25

Bombs with flammable liquid, with bursting charge 1.1J UN0399 1.1J 62 None Forbidden Forbidden 525,

23E

Bombs with flammable liquid, with bursting charge 1.2J UN0400 1.2J 62 None Forbidden Forbidden 525,

23E

Boosters with detonator 1.1B UN0225 1.1B None 62 None Forbidden Forbidden 5 25

Boosters with detonator 1.2B UN0268 1.2B None 62 None Forbidden Forbidden 5 25

Boosters, without detonator 1.1D UN0042 1.1D 148 None 62 None Forbidden Forbidden 3 25

Boosters, without detonator 1.2D UN0283 1.2D None 62 None Forbidden Forbidden 3 25

Borate and chlorate mixtures, see Chlorate and borate

mixtures

Borneol 4.1 UN1312 III 4.1A1, IB8, IP3, T1,

TP33None 213 240 25 kg 100 kg A

+ Boron tribromide 8 UN2692 I 8, 6.1

2, B9, B14, B32, N34,

T20, TP2, TP13,

TP38, TP45

None 227 244 Forbidden Forbidden C

12,

25,

53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Boron trichloride 2.3 UN1741 2.3, 8 3, B9, B14 None 304 314 Forbidden Forbidden D 25, 40

Boron trifluoride 2.3 UN1008 2.3, 8 2, 238, B9, B14 None 302314,


Boron trifluoride acetic acid complex, liquid 8 UN1742 II 8 B2, B6, IB2, T8, TP2 154 202 242 1 L 30 L A 53, 58

Boron trifluoride acetic acid complex, solid 8 UN3419 II 8B2, B6, IB8, IP2, IP4,

T3, TP33154 212 240 15 kg 50 kg A 53, 58

Boron trifluoride, adsorbed 2.3 UN3519 2.3, 8 2, B9, B14 None 302c None Forbidden Forbidden D 40

Boron trifluoride diethyl etherate 8 UN2604 I 8, 3 A19, T10, TP2, W31 None 201 243 0.5 L 2.5 L D40,

53, 58

Boron trifluoride dihydrate 8 UN2851 II 8 IB2, T7, TP2 154 212 240 15 kg 50 kg B

12,

25,

40,

53, 58

Boron trifluoride dimethyl etherate 4.3 UN2965 I4.3,

8, 3

A19, T10, TP2, TP7,

TP13, W31None 201 243 Forbidden 1 L D

21,

25,

40,

49,

100

Boron trifluoride propionic acid complex, liquid 8 UN1743 II 8 B2, IB2, T8, TP2 154 202 242 1 L 30 L A 53, 58

Boron trifluoride propionic acid complex, solid 8 UN3420 II 8B2, IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A 53, 58

Box toe gum, see Nitrocellulose etc

G Bromates, inorganic, aqueous solution, n.o.s 5.1 UN3213 II 5.1 350, IB2, T4, TP1 152 202 242 1 L 5 L B

56,

58,

133

III 5.1 350, IB2, T4, TP1 152 203 241 2.5 L 30 L B

56,

58,

133

G Bromates, inorganic, n.o.s 5.1 UN1450 II 5.1350, IB8, IP2, IP4,

T3, TP33152 212 242 5 kg 25 kg A 56, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

+ Bromine 8 UN1744 I 8, 6.1

1, B9, B85, N34,

N43, T22, TP2, TP10,

TP13


12,

25,

40,

53,

58,

66,

74,

89, 90

Bromine azide Forbidden

Bromine chloride 2.3 UN2901 2.3,

8, 5.12, B9, B14, N86 None 304

314,


40,

89, 90

+ Bromine pentafluoride 5.1 UN1745 I5.1,

6.1, 8

1, B9, B14, B30, T22,

TP2, TP13, TP38,

TP44


25,

40,

53,

58,

66, 90

+ Bromine solutions 8 UN1744 I 8, 6.1

1, B9, B85, N34,

N43, T22, TP2, TP10,

TP13


12,

25,

40,

53,

58,

66,

74,

89, 90

+ Bromine solutions 8 UN1744 I 8, 6.1

2, B9, B85, N34,

N43, T22, TP2, TP10,

TP13


12,

25,

40,

53,

58,

66,

74,

89, 90




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

+ Bromine trifluoride 5.1 UN1746 I5.1,

6.1, 8

2, B9, B14, B32, T22,

TP2, TP13, TP38,

TP45


25,

40,

53,

58,

66, 90

4-Bromo-1,2-dinitrobenzene Forbidden

4-Bromo-1,2-dinitrobenzene (unstable at 59 degrees C) Forbidden

1-Bromo-3-chloropropane 6.1 UN2688 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

1-Bromo-3-methylbutane 3 UN2341 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

1-Bromo-3-nitrobenzene (unstable at 56 degrees C ) Forbidden

2-Bromo-2-nitropropane-1,3-diol 4.1 UN3241 III 4.1 46, IB8, IP3 151 213 None 25 kg 50 kg C12,

25, 40

Bromoacetic acid, solid 8 UN3425 II 8A7, IB8, IP2, IP4,

N34, T3, TP33154 212 240 15 kg 50 kg A 53, 58

Bromoacetic acid solution 8 UN1938 II 8 A7, B2, IB2, T7, TP2 154 202 242 1 L 30 L A40,

53, 58

III 8 B2, IB3, T7, TP2 154 203 241 5 L 60 L A40,

53, 58

+ Bromoacetone 6.1 UN1569 II 6.1, 3 2, T20, TP2, TP13 None 193 245 Forbidden Forbidden D 40

Bromoacetyl bromide 8 UN2513 II 8 B2, IB2, T8, TP2 154 202 242 1 L 30 L C40,

53, 58

Bromobenzene 3 UN2514 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Bromobenzyl cyanides, liquid 6.1 UN1694 I 6.1 T14, TP2, TP13, W31 None 201 243 Forbidden 30 L D

12,

25,

40, 52

Bromobenzyl cyanides, solid 6.1 UN3449 I 6.1 T6, TP33, W31 None 211 242 5 kg 50 kg D

12,

25,

40, 52

1-Bromobutane 3 UN1126 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40

2-Bromobutane 3 UN2339 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Bromochloromethane 6.1 UN1887 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

2-Bromoethyl ethyl ether 3 UN2340 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40

Bromoform 6.1 UN2515 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A12,

25, 40

Bromomethylpropanes 3 UN2342 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

2-Bromopentane 3 UN2343 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Bromopropanes 3 UN2344 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40

III 3 IB3, T2, TP1 150 203 242 60 L 220 L A

3-Bromopropyne 3 UN2345 II 3 IB2, T4, TP1 150 202 242 5 L 60 L D 40

Bromosilane Forbidden

Bromotoluene-alpha, see Benzyl bromide

Bromotrifluoroethylene 2.1 UN2419 2.1 None 304314,

315Forbidden 150 kg B 40

Bromotrifluoromethane or Refrigerant gas, R 13B1. 2.2 UN1009 2.2 T50 306 304314,

31575 kg 150 kg A

Brucine 6.1 UN1570 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A

Bursters, explosive 1.1D UN0043 1.1D None 62 None Forbidden Forbidden 3 25

Butadienes, stabilized or Butadienes and Hydrocarbon

mixture, stabilized containing more than 40%

butadienes

2.1 UN1010 2.1 387, T50 306 304314,

315Forbidden 150 kg B 25, 40

Butane see also Petroleum gases, liquefied 2.1 UN1011 2.1 19, T50 306 304314,

315Forbidden 150 kg E 40

Butane, butane mixtures and mixtures having similar

properties in cartridges each not exceeding 500 grams,

see Receptacles, etc

Butanedione 3 UN2346 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

1,2,4-Butanetriol trinitrate Forbidden

Butanols 3 UN1120 II 3 IB2, T4, TP1, TP29 150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

tert-Butoxycarbonyl azide Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Butyl acetates 3 UN1123 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Butyl acid phosphate 8 UN1718 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 53, 58

Butyl acrylates, stabilized 3 UN2348 III 3 387, B1, IB3, T2, TP1 150 203 242 60 L 220 L C 25

Butyl alcohols, see Butanols

Butyl benzenes 3 UN2709 III 3 B1, IB3, T2, TP2 150 203 242 60 L 220 L A

n-Butyl bromide, see 1-Bromobutane

n-Butyl chloride, see Chlorobutanes

n-Butyl chloroformate 6.1 UN2743 I6.1,

8, 3

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP45

None 227 244 Forbidden Forbidden A

12,

13,

21,

25,

40,

53,

58,

100

Butyl ethers, see Dibutyl ethers

Butyl ethyl ether, see Ethyl butyl ether

n-Butyl formate 3 UN1128 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

tert-Butyl hydroperoxide, with more than 90 percent

with waterForbidden

tert-Butyl hypochlorite 4.2 UN3255 I 4.2, 8 None 211 243 Forbidden Forbidden D 40

N-n-Butyl imidazole 6.1 UN2690 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

tert-Butyl isocyanate 6.1 UN2484 I 6.1, 3

1, B9, B14, B30, T20,

TP2, TP13, TP38,

TP44


n-Butyl isocyanate 6.1 UN2485 I 6.1, 3

2, B9, B14, B32, B77,

T20, TP2, TP13,

TP38, TP45


Butyl mercaptan 3 UN2347 II 3 A3, IB2, T4, TP1 150 202 242 5 L 60 L D

52,

95,

102




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

n-Butyl methacrylate, stabilized 3 UN2227 III 3 387, B1, IB3, T2, TP1 150 203 242 60 L 220 L C 25

Butyl methyl ether 3 UN2350 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Butyl nitrites 3 UN2351 I 3 T11, TP1, TP8, TP27 150 201 243 1 L 30 L E 40

II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 40

tert-Butyl peroxyacetate, with more than 76 percent in

solutionForbidden

n-Butyl peroxydicarbonate, with more than 52 percent

in solutionForbidden

tert-Butyl peroxyisobutyrate, with more than 77 percent


Butyl phosphoric acid, see Butyl acid phosphate

Butyl propionates 3 UN1914 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

5-tert-Butyl-2,4,6-trinitro-m-xylene or Musk xylene 4.1 UN2956 III 4.1 159 None 223 None Forbidden Forbidden D

12,

25,

40,

127

Butyl vinyl ether, stabilized 3 UN2352 II 3 387, IB2, T4, TP1 150 202 242 5 L 60 L C 25, 40

n-Butylamine 3 UN1125 II 3, 8 IB2, T7, TP1 150 202 242 1 L 5 L B 40, 52

N-Butylaniline 6.1 UN2738 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 74

tert-Butylcyclohexylchloroformate 6.1 UN2747 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A12,

13, 25

Butylene see also Petroleum gases, liquefied 2.1 UN1012 2.1 19, T50 306 304314,


1,2-Butylene oxide, stabilized 3 UN3022 II 3 387, IB2, T4, TP1 150 202 242 5 L 60 L C25,

27, 49

Butyltoluenes 6.1 UN2667 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Butyltrichlorosilane 8 UN1747 II 8, 3A7, B2, B6, N34,


40,

53, 58

1,4-Butynediol 6.1 UN2716 III 6.1A1, IB8, IP3, T1,

TP33None 213 240 100 kg 200 kg C

52,

53, 70

Butyraldehyde 3 UN1129 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Butyraldoxime 3 UN2840 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Butyric acid 8 UN2820 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A

12,

25,

53, 58

Butyric anhydride 8 UN2739 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 53, 58

Butyronitrile 3 UN2411 II 3, 6.1 IB2, T7, TP1, TP13 150 202 243 1 L 60 L E 40

Butyryl chloride 3 UN2353 II 3, 8 IB2, T8, TP2, TP13 150 202 243 1 L 5 L C40,

53, 58

Cacodylic acid 6.1 UN1572 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg E

52,

53, 58

G Cadmium compounds 6.1 UN2570 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A


Caesium hydroxide 8 UN2682 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A

29,

52.

Caesium hydroxide solution 8 UN2681 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A 29, 52

III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 29, 52

Calcium 4.3 UN1401 II 4.3IB7, IP2, IP21, T3,

TP33, W31, W40151 212 241 15 kg 50kg E

13,

52,

148

Calcium arsenate 6.1 UN1573 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Calcium arsenate and calcium arsenite, mixtures, solid 6.1 UN1574 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Calcium bisulfite solution, see Bisulfites, aqueous

solutions, n.o.s.

Calcium carbide 4.3 UN1402 I 4.3

A1, A8, B55, B59,

IB4, IP1, N34, T9,

TP7, TP33, W31

None 211 242 Forbidden 15 kg B

13,

52,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II 4.3

A1, A8, B55, B59,

IB7, IP2, IP21, N34,

T3, TP33, W31, W40

151 212 241 15 kg 50 kg B

13,

52,

148

Calcium chlorate 5.1 UN1452 II 5.1A9, IB8, IP2, IP4,

N34, T3, TP33152 212 242 5 kg 25 kg A 56, 58

Calcium chlorate aqueous solution 5.1 UN2429 II 5.1A2, IB2, N41, T4,

TP1152 202 242 1 L 5 L B

56,

58,

133

III 5.1A2, IB2, N41, T4,

TP1152 203 241 2.5 L 30 L B

56,

68,

133

Calcium chlorite 5.1 UN1453 II 5.1A9, IB8, IP2, IP4,

N34, T3, TP33152 212 242 5 kg 25 kg A 56, 58

Calcium cyanamide with more than 0.1 percent of

calcium carbide4.3 UN1403 III 4.3

A1, A19, IB8, IP4,

T1, TP33, W31151 213 241 25 kg 100 kg A

13,

52,

148

Calcium cyanide 6.1 UN1575 I 6.1IB7, IP1, N79, N80,

T6, TP33, W31None 211 242 5 kg 50 kg A 40, 52

Calcium dithionite or Calcium hydrosulfite 4.2 UN1923 II 4.2A19, A20, IB6, IP2,

T3, TP33, W31None 212 241 15 kg 50 kg E 13

Calcium hydride 4.3 UN1404 I 4.3 A19, N40, W31 None 211 242 Forbidden 15 kg E

13,

52,

148

Calcium hydrosulfite, see Calcium dithionite

Calcium hypochlorite, dry, corrosive or Calcium

hypochlorite mixture, dry, corrosive with more than

39% available chlorine (8.8% available oxygen)

5.1 UN3485 II 5.1, 8

165, 166, A7, A9,

IB8, IP2, IP4, IP13,

N34, W9

152 212 None 5 kg 25 kg D

4, 25,

52,

56,

58,

69,

142




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Calcium hypochlorite, dry or Calcium hypochlorite

mixture dry with more than 39% available chlorine

(8.8% available oxygen)

5.1 UN1748 II 5.1

165, 166, A7, A9,

IB8, IP2, IP4, IP13,

N34, W9

152 212 None 5 kg 25 kg D

4, 25,

52,

56,

58,

69,

142

III 5.1

165, 171, A7, A9,

IB8, IP4, IP13, N34,

W9

152 213 240 25 kg 100 kg D

4, 25,

52,

56,

58,

69,

142

Calcium hypochlorite, hydrated, corrosive or Calcium

hypochlorite, hydrated mixture, corrosive with not less

than 5.5% but not more than 16% water

5.1 UN3487 II 5.1, 8165, IB8, IP2, IP4,

IP13, W9152 212 240 5 kg 25 kg D

4, 25,

52,

56,

58,

69,

142

III 5.1, 8 165, IB8, IP4, W9 152 213 240 25 kg 100 kg D

4, 25,

52,

56,

58,

69,

142

Calcium hypochlorite, hydrated or Calcium

hypochlorite, hydrated mixture, with not less than

5.5% but not more than 16% water

5.1 UN2880 II 5.1165, IB8, IP2, IP4,

IP13, W9152 212 240 5 kg 25 kg D

4, 25,

52,

56,

58,

69,

142




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

III 5.1165, 171, IB8, IP4,

IP13, W9152 213 240 25 kg 100 kg D

4, 25,

52,

56,

58,

69,

142

Calcium hypochlorite mixture, dry, corrosive with more

than 10% but not more than 39% available chlorine5.1 UN3486 III 5.1, 8

165, A1, A29, IB8,

IP3, IP13, N34, W9,

W10

152 213 240 5 kg 25 kg D

4, 25,

52,

56,

58,

69,

142

Calcium hypochlorite mixture, dry, with more than 10%

but not more than 39% available chlorine5.1 UN2208 III 5.1

165, A1, A29, IB8,

IP3, IP13, N34, W9,

W10

152 213 240 25 kg 100 kg D

4, 25,

52,

56,

58,

69,

142

Calcium manganese silicon 4.3 UN2844 III 4.3A1, A19, IB8, IP4,

T1, TP33, W31151 213 241 25 kg 100 kg A

13,

52,

85,

103,

148

Calcium nitrate 5.1 UN1454 III 5.134, B120, IB8, IP3,

T1, TP33152 213 240 25 kg 100 kg A

A Calcium oxide 8 UN1910 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A

Calcium perchlorate 5.1 UN1455 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58

Calcium permanganate 5.1 UN1456 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg D

56,

58,

138




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Calcium peroxide 5.1 UN1457 II 5.1IB6, IP2, T3, TP33,

W100152 212 242 5 kg 25 kg C

13,

52,

66,

75,

148

Calcium phosphide 4.3 UN1360 I4.3,

6.1A8, A19, N40, W31 None 211 242 Forbidden 15 kg E

13,

40,

52,

85,

148

Calcium, pyrophoric or Calcium alloys, pyrophoric 4.2 UN1855 I 4.2 W31 None 187 None Forbidden Forbidden D13,

148

Calcium resinate 4.1 UN1313 III 4.1A1, A19, IB6, T1,

TP33None 213 240 25 kg 100 kg A

Calcium resinate, fused 4.1 UN1314 III 4.1A1, A19, IB4, T1,

TP33None 213 240 25 kg 100 kg A

Calcium selenate, see Selenates or Selenites

Calcium silicide 4.3 UN1405 II 4.3A19, IB7, IP2, IP21,

T3, TP33, W31151 212 241 15 kg 50 kg B

13,

52,

85,

103,

148

III 4.3A1, A19, IB8, IP21,

T1, TP33, W31151 213 241 25 kg 100 kg B

13,

52,

85,

103,

148

Camphor oil 3 UN1130 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Camphor, synthetic 4.1 UN2717 III 4.1A1, IB8, IP3, T1,

TP33None 213 240 25 kg 100 kg A

Cannon primers, see Primers, tubular

Capacitor, asymmetric with an energy storage capacity

greater than 0.3 Wh9 UN3508 9 372 176 176 176 No limit No Limit A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Capacitor, electric double layer with an energy storage

capacity greater than 0.3 Wh9 UN3499 9 361 176 176 176 No limit No limit A

Caproic acid 8 UN2829 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 53, 58

Caps, blasting, see Detonators, etc

Carbamate pesticides, liquid, flammable, toxic, flash


T14, TP2, TP13,


II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40

Carbamate pesticides, liquid, toxic 6.1 UN2992 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40

Carbamate pesticides, liquid, toxic, flammable, flash


T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1, 3B1, IB3, T7, TP2,

TP28153 203 242 60 L 220 L A 40

Carbamate pesticides, solid, toxic 6.1 UN2757 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Carbolic acid, see Phenol, solid or Phenol, molten

Carbolic acid solutions, see Phenol solutions

I Carbon, activated 4.2 UN1362 III 4.2IB8, IP3, T1, TP33,

W31None 213 241 0.5 kg 0.5 kg A 12, 25

I Carbon, animal or vegetable origin 4.2 UN1361 II 4.2 IB6, T3, TP33 None 212 242 Forbidden Forbidden A 12, 25

III 4.2 IB8, IP3, T1, TP33 None 213 241 Forbidden Forbidden A 12, 25

Carbon bisulfide, see Carbon disulfide




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Carbon dioxide 2.2 UN1013 2.2 306302,

304

302,

314,

315

75 kg 150 kg A

Carbon dioxide, refrigerated liquid 2.2 UN2187 2.2 T75, TP5 306 304314,

31550 kg 500 kg D

A W Carbon dioxide, solid or Dry ice 9 UN1845 None 217 217 240 200 kg 200 kg C 40

Carbon disulfide 3 UN1131 I 3, 6.1B16, T14, TP2, TP7,

TP13, W31None 201 243 Forbidden Forbidden D

40,

78,

115

Carbon monoxide, compressed 2.3 UN1016 2.3,

2.14 None 302

314,

315Forbidden 25 kg D 40

D Carbon monoxide, refrigerated liquid (cryogenic liquid) 2.3 NA9202 2.3,

2.14, T75, TP5 None 316 318 Forbidden Forbidden D

Carbon tetrabromide 6.1 UN2516 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 25

Carbon tetrachloride 6.1 UN1846 II 6.1 IB2, N36, T7, TP2 153 202 243 5 L 60 L A 40

Carbonyl chloride, see Phosgene

Carbonyl fluoride 2.3 UN2417 2.3, 8 2 None 302 None Forbidden Forbidden D 40

Carbonyl sulfide 2.3 UN2204 2.3,

2.13, B14 None 304

314,


Cartridge cases, empty primed, see Cases, cartridge,

empty, with primer

Cartridges, actuating, for aircraft ejector seat catapult,

fire extinguisher, canopy removal or apparatus, see

Cartridges, power device

Cartridges, explosive, see Charges, demolition

Cartridges, sporting, see Cartridges for weapons, inert

projectile, or Cartridges, small arms

Cartridges, flash 1.1G UN0049 1.1G None 62 None Forbidden Forbidden 3 25

Cartridges, flash 1.3G UN0050 1.3G None 62 None Forbidden 75 kg 3 25

Cartridges for weapons, blank 1.1C UN0326 1.1C None 62 None Forbidden Forbidden 3 25

Cartridges for weapons, blank 1.2C UN0413 1.2C None 62 None Forbidden Forbidden 3 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Cartridges for weapons, blank or Cartridges, small

arms, blank1.3C UN0327 1.3C None 62 None Forbidden Forbidden 3 25


arms, blank1.4C UN0338 1.4C None 62 None Forbidden 75 kg 2 25


arms, blank or Cartridges for tools, blank1.4S UN0014 None 63 62 None 25 kg 100 kg 1 25

Cartridges for weapons, inert projectile 1.2C UN0328 1.2C None 62 62 Forbidden Forbidden 3 25

Cartridges for weapons, inert projectile or Cartridges,

small arms1.4S UN0012 None 63 62 None 25 kg 100 kg 1 25


small arms1.4C UN0339 1.4C None 62 None Forbidden 75 kg 2 25


small arms1.3C UN0417 1.3C None 62 None Forbidden Forbidden 3 25

Cartridges for weapons, with bursting charge 1.1F UN0005 1.1F None 62 None Forbidden Forbidden 3 25

Cartridges for weapons, with bursting charge 1.1E UN0006 1.1E None 62 62 Forbidden Forbidden 3 25


Cartridges for weapons, with bursting charge 1.2E UN0321 1.2E None 62 62 Forbidden Forbidden 3 25


Cartridges for weapons, with bursting charge 1.4E UN0412 1.4E None 62 62 Forbidden 75 kg 3 25

Cartridges, oil well 1.3C UN0277 1.3C None 62 62 Forbidden Forbidden 3 25

Cartridges, oil well 1.4C UN0278 1.4C None 62 62 Forbidden 75 kg 2 25

Cartridges, power device 1.3C UN0275 1.3C None 62 62 Forbidden 75 kg 3 25

Cartridges, power device 1.4C UN0276 1.4C 110 None 62 62 Forbidden 75 kg 2 25

Cartridges, power device 1.4S UN0323 1.4S 110, 347 63 62 62 25 kg 100 kg 1 25

Cartridges, power device 1.2C UN0381 1.2C None 62 62 Forbidden Forbidden 3 25

DCartridges power device (used to project fastening

devices)ORM-D None 222 63 None None 30 kg gross Forbidden A

Cartridges, safety, blank, see Cartridges for weapons,

blank (UN 0014)

Cartridges, safety, see Cartriges for weapons, inert

projectile, or Cartridges, small arms or Cartridges,

power device (UN 0323 )

Cartridges, signal 1.3G UN0054 1.3G None 62 None Forbidden 75 kg 3 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Cartridges, signal 1.4G UN0312 1.4G None 62 None Forbidden 75 kg 2 25

Cartridges, signal 1.4S UN0405 1.4S None 62 None 25 kg 100 kg 1 25

D Cartridges, small arms ORM-D None 222 63 None None 30 kg gross Forbidden A

Cartridges, starter, jet engine, see Cartridges, power

device

Cases, cartridge, empty with primer 1.4S UN0055 1.4S 50 63 62 None 25 kg 100 kg 1 25

Cases, cartridges, empty with primer 1.4C UN0379 1.4C 50 None 62 None Forbidden 75 kg 2 25

Cases, combustible, empty, without primer 1.4C UN0446 1.4C None 62 None Forbidden 75 kg 2 25

Cases, combustible, empty, without primer 1.3C UN0447 1.3C None 62 None Forbidden Forbidden 3 25

Casinghead gasoline see Gasoline

A WCastor beans or Castor meal or Castor pomace or

Castor flake9 UN2969 II None

IB8, IP2, IP4, T3,

TP33155 204 240 No limit No limit E

34,

40,

44,

122

Catecholborane A210

G Caustic alkali liquids, n.o.s. 8 UN1719 II 8B2, IB2, T11, TP2,

TP27154 202 242 1 L 30 L A 29, 52

III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 29, 52

Caustic potash, see Potassium hydroxide etc

Caustic soda, (etc.) see Sodium hydroxide etc

Cells, containing sodium 4.3 UN3292 4.3 189 189 189 25 kg No limit A

Celluloid, in block, rods, rolls, sheets, tubes, etc.,

except scrap4.1 UN2000 III 4.1 420 None 213 240 25 kg 100 kg A

Celluloid, scrap 4.2 UN2002 III 4.2 IB8, IP3 None 213 241 Forbidden Forbidden D

Cement, see Adhesives containing flammable liquid

Cerium, slabs, ingots, or rods 4.1 UN1333 II 4.1IB8, IP2, IP4, N34,

W100None 212 240 15 kg 50 kg A

13,

74,

91,

147,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Cerium, turnings or gritty powder 4.3 UN3078 II 4.3A1, IB7, IP2, IP21,

T3, TP33, W31, W40151 212 242 15 kg 50 kg E

13,

52,

148

Cesium or Caesium 4.3 UN1407 I 4.3A7, A19, IB4, IP1,

N34, N40, W31None 211 242 Forbidden 15 kg D

13,

52,

148

Cesium nitrate or Caesium nitrate 5.1 UN1451 III 5.1A1, A29, IB8, IP3,

T1, TP33152 213 240 25 kg 100 kg A

D Charcoal briquettes, shell, screenings, wood, etc. 4.2 NA1361 III 4.2 IB8, T1, TP33 151 213 240 25 kg 100 kg A 12

Charges, bursting, plastics bonded 1.1D UN0457 1.1D None 62 None Forbidden Forbidden 3 25

Charges, bursting, plastics bonded 1.2D UN0458 1.2D None 62 None Forbidden Forbidden 3 25

Charges, bursting, plastics bonded 1.4D UN0459 1.4D None 62 None Forbidden 75 kg 2 25

Charges, bursting, plastics bonded 1.4S UN0460 1.4S 347 None 62 None 25 kg 100 kg 1 25

Charges, demolition 1.1D UN0048 1.1D None 62 62 Forbidden Forbidden 3 25

Charges, depth 1.1D UN0056 1.1D None 62 62 Forbidden Forbidden 3 25

Charges, expelling, explosive, for fire extinguishers, see


Charges, explosive, commercial without detonator 1.1D UN0442 1.1D None 62 None Forbidden Forbidden 3 25

Charges, explosive, commercial without detonator 1.2D UN0443 1.2D None 62 None Forbidden Forbidden 3 25

Charges, explosive, commercial without detonator 1.4D UN0444 1.4D None 62 None Forbidden 75 kg 2 25

Charges, explosive, commercial without detonator 1.4S UN0445 1.4S 347 None 62 None 25 kg 100 kg 1 25

Charges, propelling 1.1C UN0271 1.1C None 62 None Forbidden Forbidden 3 25



Charges, propelling 1.4C UN0491 1.4C None 62 None Forbidden 75 kg 2 25

Charges, propelling, for cannon 1.3C UN0242 1.3C None 62 None Forbidden Forbidden 3 25



Charges, shaped, flexible, linear 1.4D UN0237 1.4D None 62 None Forbidden 75 kg 2 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Charges, shaped, flexible, linear 1.1D UN0288 1.1D None 62 None Forbidden Forbidden 4 25

Charges, shaped, without detonator 1.1D UN0059 1.1D None 62 None Forbidden Forbidden 3 25

Charges, shaped, without detonator 1.2D UN0439 1.2D None 62 None Forbidden Forbidden 3 25

Charges, shaped, without detonator 1.4D UN0440 1.4D None 62 None Forbidden 75 kg 2 25

Charges, shaped, without detonator 1.4S UN0441 1.4S 347 None 62 None 25 kg 100 kg 1 25

Charges, supplementary explosive 1.1D UN0060 1.1D None 62 None Forbidden Forbidden 3 25

D Chemical kit 8 NA1760 II 8 154 161 None 1 L 30 L B 40

Chemical kit 9 UN3316 9 15 161 161 None 10 kg 10 kg A

G Chemical under pressure, corrosive, n.o.s 2.2 UN3503 2.2, 8 362, T50, TP40 None 335313,


G Chemical under pressure, flammable, corrosive, n.o.s 2.1 UN3505 2.1, 8 362, T50, TP40 None 335313,


G Chemical under pressure, flammable, n.o.s 2.1 UN3501 2.1 362, T50, TP40 None 335313,


G Chemical under pressure, flammable, toxic, n.o.s 2.1 UN35042.1,

6.1362, T50, TP40 None 335

313,


G Chemical under pressure, n.o.s 2.2 UN3500 2.2 362, T50, TP40 None 335313,

31575 kg 150 kg B

G Chemical under pressure, toxic, n.o.s 2.2 UN35022.2,

6.1362, T50, TP40 None 335

313,


Chloral, anhydrous, stabilized 6.1 UN2075 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L D 40

Chlorate and borate mixtures 5.1 UN1458 II 5.1A9, IB8, IP2, IP4,

N34, T3, TP33152 212 240 5 kg 25 kg A 56, 58

III 5.1A9, IB8, IP3, N34,

T1, TP33152 213 240 25 kg 100 kg A 56, 58

Chlorate and magnesium chloride mixture solid 5.1 UN1459 II 5.1A9, IB8, IP2, IP4,

N34, T3, TP33152 212 240 5 kg 25 kg A 56, 58

III 5.1A9, IB8, IP3, N34,

T1, TP33152 213 240 25 kg 100 kg A 56, 58

Chlorate and magnesium chloride mixture solution 5.1 UN3407 II 5.1A9, IB2, N34, T4,

TP1152 202 242 1 L 5 L A

56,

58,

133




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

III 5.1A9, IB2, N34, T4,

TP1152 203 241 2.5 L 30 L A

56,

58,

133

Chlorate of potash, see Potassium chlorate

Chlorate of soda, see Sodium chlorate

G Chlorates, inorganic, aqueous solution, n.o.s 5.1 UN3210 II 5.1 351, IB2, T4, TP1 152 202 242 1 L 5 L B

56,

58,

133

III 5.1 351, IB2, T4, TP1 152 203 241 2.5 L 30 L B

56,

58,

133

G Chlorates, inorganic, n.o.s 5.1 UN1461 II 5.1351, A9, IB6, IP2,

N34, T3, TP33152 212 242 5 kg 25 kg A 56, 58

Chloric acid aqueous solution, with not more than 10

percent chloric acid5.1 UN2626 II 5.1 IB2, T4, TP1, W31 None 229 None Forbidden Forbidden D

53,

56, 58

Chloride of phosphorus, see Phosphorus trichloride

Chloride of sulfur, see Sulfur chloride

Chlorinated lime, see Calcium hypochlorite mixtures,

etc

Chlorine 2.3 UN1017 2.3,

5.1, 8

2, B9, B14, N86, T50,

TP19None 304

314,


40,

51,

55,

62,

68,

89, 90

Chlorine, adsorbed 2.3 UN35202.3,

5.1, 82, B9, B14, N86 None 302c None Forbidden Forbidden D

40,

89, 90

Chlorine azide Forbidden

D Chlorine dioxide, hydrate, frozen 5.1 NA9191 II5.1,

6.1 None 229 None Forbidden Forbidden E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Chlorine dioxide (not hydrate) Forbidden

Chlorine pentafluoride 2.3 UN2548 2.3,

5.1, 81, B7, B9, B14, N86 None 304 314 Forbidden Forbidden D

40,

89, 90

Chlorine trifluoride 2.3 UN1749 2.3,

5.1, 82, B7, B9, B14, N86 None 304 314 Forbidden Forbidden D

40,

89, 90

Chlorite solution 8 UN1908 II 8A3, A7, B2, IB2, N34,

T7, TP2, TP24154 202 242 1 L 30 L B

26,

44,

89,

100,

141

III 8A3, A7, B2, IB3, N34,

T4, TP2, TP24154 203 241 5 L 60 L B

26,

44,

89,

100,

141

G Chlorites, inorganic, n.o.s 5.1 UN1462 II 5.1352, A7, IB6, IP2,

N34, T3, TP33152 212 242 5 kg 25 kg A 56, 58

1-Chloro-1,1-difluoroethane or Refrigerant gas R 142b 2.1 UN2517 2.1 T50 306 304314,


3-Chloro-4-methylphenyl isocyanate, liquid 6.1 UN2236 II 6.1 IB2 153 202 243 5 L 60 L B 40

3-Chloro-4-methylphenyl isocyanate, solid 6.1 UN3428 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B 40

1-Chloro-1,2,2,2-tetrafluoroethaneor Refrigerant gas R

1242.2 UN1021 2.2 T50 306 304

314,

31575 kg 150 kg A

4-Chloro-o-toluidine hydrochloride, solid 6.1 UN1579 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

4-Chloro-o-toluidine hydrochloride, solution 6.1 UN3410 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

1-Chloro-2,2,2-trifluoroethane or Refrigerant gas R

133a2.2 UN1983 2.2 T50 306 304

314,

31575 kg 150 kg A

Chloroacetic acid, molten 6.1 UN3250 II 6.1, 8 IB1, T7, TP3, TP28 None 202 243 Forbidden Forbidden C40,

53, 58

Chloroacetic acid, solid 6.1 UN1751 II 6.1, 8A3, A7, IB8, IP2, IP4,

N34, T3, TP33153 212 242 15 kg 50 kg C

40,

53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Chloroacetic acid, solution 6.1 UN1750 II 6.1, 8A7, IB2, N34, T7,

TP2153 202 243 1 L 30 L C

40,

53, 58

Chloroacetone, stabilized 6.1 UN1695 I6.1,

3, 8

2, B9, B14, B32, N12,

N32, N34, T20, TP2,

TP13, TP38, TP45


21,

40,

100

Chloroacetone (unstabilized) Forbidden

+ Chloroacetonitrile 6.1 UN2668 I 6.1, 3

2, B9, B14, B32, IB9,

T20, TP2, TP13,

TP38, TP45


12,

25,

40, 52

Chloroacetophenone, liquid, (CN) 6.1 UN3416 II 6.1A3, IB2, N12, N32,

N33, T7, TP2, TP13None 202 243 Forbidden 60 L D

12,

25, 40

Chloroacetophenone, solid, (CN) 6.1 UN1697 II 6.1

A3, IB8, IP2, IP4,

N12, N32, N33, N34,

T3, TP2, TP13, TP33

None 212 None Forbidden 100 kg D12,

25, 40

Chloroacetyl chloride 6.1 UN1752 I 6.1, 8

2, B3, B8, B9, B14,

B32, B77, N34, N43,

T20, TP2, TP13,

TP38, TP45

None 227 244 Forbidden Forbidden D40,

53, 58

Chloroanilines, liquid 6.1 UN2019 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 52

Chloroanilines, solid 6.1 UN2018 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Chloroanisidines 6.1 UN2233 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Chlorobenzene 3 UN1134 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Chlorobenzol, see Chlorobenzene

Chlorobenzotrifluorides 3 UN2234 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 40

Chlorobenzyl chlorides, liquid 6.1 UN2235 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Chlorobenzyl chlorides, solid 6.1 UN3427 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Chlorobutanes 3 UN1127 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Chlorocresols solution 6.1 UN2669 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 12, 25

III 6.1 IB3, T7, TP2 153 203 241 60 L 220 L A 12, 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Chlorocresols, solid 6.1 UN3437 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 12, 25

Chlorodifluorobromomethane or Refrigerant gas R

12B12.2 UN1974 2.2 T50 306 304

314,

31575 kg 150 kg A

Chlorodifluoromethane and chloropentafluoroethane

mixture or Refrigerant gas R 502 with fixed boiling

point, with approximately 49 percent

chlorodifluoromethane

2.2 UN1973 2.2 T50 306 304314,

31575 kg 150 kg A

Chlorodifluoromethane or Refrigerant gas R 22 2.2 UN1018 2.2 T50 306 304314,

31575 kg 150 kg A

+ Chlorodinitrobenzenes, liquid. 6.1 UN1577 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L B 91

+ Chlorodinitrobenzenes, solid 6.1 UN3441 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 91

2-Chloroethanal 6.1 UN2232 I 6.1

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP45


Chloroform 6.1 UN1888 III 6.1 IB3, N36, T7, TP2 153 203 241 60 L 220 L A 40

G Chloroformates, toxic, corrosive, flammable, n.o.s 6.1 UN2742 II6.1,

8, 35, IB1, T7, TP2 153 202 243 1 L 30 L A

12,

13,

21,

25,

40,

53,

58,10

0

G Chloroformates, toxic, corrosive, n.o.s 6.1 UN3277 II 6.1, 8IB2, T8, TP2, TP13,

TP28153 202 243 1 L 30 L A

12,

13,

25,

40,

53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Chloromethyl chloroformate 6.1 UN2745 II 6.1, 8 IB2, T7, TP2, TP13 153 202 243 1 L 30 L A

12,

13,

25,

40,

53, 58

Chloromethyl ethyl ether 3 UN2354 II 3, 6.1 IB2, T7, TP1, TP13 150 202 243 1 L 60 L E 40

Chloronitroanilines 6.1 UN2237 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

+ Chloronitrobenzenes, liquid 6.1 UN3409 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

44,

89,

100,

141

+ Chloronitrobenzenes, solid 6.1 UN1578 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Chloronitrotoluenes, liquid 6.1 UN2433 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

44,

89,

100,

141

Chloronitrotoluenes, solid 6.1 UN3457 III 6.1 IB8, IP3,T1, TP33 153 213 240 25 kg 200 kg A

Chloropentafluoroethane or Refrigerant gas R 115 2.2 UN1020 2.2 T50 306 304314,

31575 kg 150 kg A

Chlorophenolates, liquid or Phenolates, liquid 8 UN2904 III 8 IB3 154 203 241 5 L 60 L A

Chlorophenolates, solid or Phenolates, solid 8 UN2905 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A

Chlorophenols, liquid 6.1 UN2021 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Chlorophenols, solid 6.1 UN2020 III 6.1IB8, IP3, T1, TP1,

TP33153 213 240 100 kg 200 kg A

Chlorophenyltrichlorosilane 8 UN1753 II 8A7, B2, B6, N34,

T10, TP2, TP7None 206 242 Forbidden 30 L C

40,

53, 58

+ Chloropicrin 6.1 UN1580 I 6.1

2, B7, B9, B14, B32,

B46, T22, TP2, TP13,

TP38, TP45


Chloropicrin and methyl bromide mixtures 2.3 UN1581 2.3 2, B9, B14, N86, T50 None 193314,

315Forbidden Forbidden D 25, 40

Chloropicrin and methyl chloride mixtures 2.3 UN1582 2.3 2, N86, T50 None 193 245 Forbidden Forbidden D 25, 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Chloropicrin mixture, flammable (pressure not

exceeding 14.7 psia at 115 degrees F flash point below

100 degrees F) see Toxic liquids, flammable, etc

G Chloropicrin mixtures, n.o.s 6.1 UN1583 I 6.1 5 None 201 243 Forbidden Forbidden C 40

II 6.1 IB2 153 202 243 Forbidden Forbidden C 40

III 6.1 IB3 153 203 241 Forbidden Forbidden C 40

D Chloropivaloyl chloride 6.1 NA9263 I 6.1, 8

2, B9, B14, B32, T20,

TP4, TP13, TP38,

TP45

None 227 244 Forbidden Forbidden B 40

Chloroplatinic acid, solid 8 UN2507 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 53, 58

Chloroprene, stabilized 3 UN1991 I 3, 6.1387, B57, T14, TP2,


Chloroprene, uninhibited Forbidden

1-Chloropropane 3 UN1278 II 3IB2, IP8, N34, T7,

TP2None 202 242 Forbidden 60 L E

2-Chloropropane 3 UN2356 I 3 N36, T11, TP2, TP13 150 201 243 1 L 30 L E

3-Chloropropanol-1 6.1 UN2849 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

2-Chloropropene 3 UN2456 I 3 N36, T11, TP2 150 201 243 1 L 30 L E

2-Chloropropionic acid 8 UN2511 III 8 IB3, T4, TP2 154 203 241 5 L 60 L A8, 53,

58

2-Chloropyridine 6.1 UN2822 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40

Chlorosilanes, corrosive, flammable, n.o.s 8 UN2986 II 8, 3T14, TP2, TP7, TP13,

TP27None 206 243 Forbidden 30 L C

40,

53, 58

Chlorosilanes, corrosive, n.o.s 8 UN2987 II 8B2, T14, TP2, TP7,

TP13, TP27None 206 242 Forbidden 30 L C

40,

53, 58

Chlorosilanes, flammable, corrosive, n.o.s 3 UN2985 II 3, 8T14, TP2, TP7, TP13,

TP27None 206 243 Forbidden 5 L B

40,

53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Chlorosilanes, toxic, corrosive, flammable, n.o.s 6.1 UN3362 II6.1,

8, 3

T14, TP2, TP7, TP13,


40,

53,

58,

125

G Chlorosilanes, toxic, corrosive, n.o.s 6.1 UN3361 II 6.1, 8T14, TP2, TP7, TP13,


40,

53, 58

Chlorosilanes, water-reactive, flammable, corrosive,

n.o.s4.3 UN2988 I

4.3,

3, 8

A2, T14, TP2, TP7,


13,

21,

40,

49,

53,

58,

100,

147,

148

+ Chlorosulfonic acid (with or without sulfur trioxide) 8 UN1754 I 8, 6.1

2, B9, B10, B14, B32,

T20, TP2, TP38,

TP45

None 227 244 Forbidden Forbidden C40,

53, 58

Chlorotoluenes 3 UN2238 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Chlorotoluidines, liquid 6.1 UN3429 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Chlorotoluidines, solid 6.1 UN2239 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Chlorotrifluoromethane and trifluoromethane

azeotropic mixture or Refrigerant gas R 503 with

approximately 60 percent chlorotrifluoromethane

2.2 UN2599 2.2 306 304314,

31575 kg 150 kg A

Chlorotrifluoromethane or Refrigerant gas R 13 2.2 UN1022 2.2 306 304314,

31575 kg 150 kg A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Chromic acid solution 8 UN1755 II 8 B2, IB2, T8, TP2 154 202 242 1 L 30 L C

40,

44,

53,

58,

89,

100,

141

III 8 IB3, T4, TP1 154 203 241 5 L 60 L C

40,

44,

53,

58,

89,

100,

141

Chromic anhydride, see Chromium trioxide, anhydrous

Chromic fluoride, solid 8 UN1756 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A

52,

53, 58

Chromic fluoride, solution 8 UN1757 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A 53, 58

III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 53, 58

III 8 IB3, T4, TP1 154 203 241 5 L 60 L A

Chromium nitrate 5.1 UN2720 III 5.1A1, A29, IB8, IP3,

T1, TP33152 213 240 25 kg 100 kg A

Chromium oxychloride 8 UN1758 I 8A7, B10, N34, T10,

TP2None 201 243 0.5 L 2.5 L C

40,

53,

58,

66,

74,

89, 90

Chromium trioxide, anhydrous 5.1 UN1463 II5.1,

6.1, 8

IB8, IP2, IP4, T3,

TP33, W31None 212 242 5 kg 25 kg A 66, 90




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Chromosulfuric acid 8 UN2240 I 8A7, B4, B6, N34,

T10, TP2, TP13None 201 243 0.5L 2.5L B

40,

53,

58,

66,

74,

89, 90

Chromyl chloride, see Chromium oxychloride

Cigar and cigarette lighters, charged with fuel, see

Lighters or Lighter refills containing flammable gas.

Coal briquettes, hot Forbidden

Coal gas, compressed 2.3 UN1023 2.3,

2.13 None 302

314,


Coal tar distillates, flammable 3 UN1136 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B


TP29150 203 242 60 L 220 L A

Coal tar dye, corrosive, liquid, n.o.s, see Dyes, liquid or

solid, n.o.s. or Dye intermediates, liquid or solid,

corrosive, n.o.s.

Coating solution (includes surface treatments or

coatings used for industrial or other purposes such as

vehicle undercoating, drum or barrel lining)

3 UN1139 I 3 T11, TP1, TP8, TP27 150 201 243 1 L 30 L E

II 3149, IB2, T4, TP1,

TP8150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Cobalt naphthenates, powder 4.1 UN2001 III 4.1A19, IB8, IP3, T1,

TP33151 213 240 25 kg 100 kg A

Cobalt resinate, precipitated 4.1 UN1318 III 4.1A1, A19, IB6, T1,

TP33151 213 240 25 kg 100 kg A

Coke, hot Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Collodion, see Nitrocellulose etc

D G Combustible liquid, n.o.s. Comb liq NA1993 III None 148, IB3, T1, TP1 150 203 241 60 L 220 L A

G Components, explosive train, n.o.s. 1.2B UN0382 1.2B 101 None 62 None Forbidden Forbidden 5 25

G Components, explosive train, n.o.s. 1.4B UN0383 1.4B 101 None 62 None Forbidden 75 kg 5 25

G Components, explosive train, n.o.s 1.4S UN0384 1.4S 101, 347 None 62 None 25 kg 100 kg 1 25

G Components, explosive train, n.o.s. 1.1B UN0461 1.1B 101 None 62 None Forbidden Forbidden 5 25

Composition B, see Hexolite, etc

D G Compounds, cleaning liquid 8 NA1760 I 8A7, B10, T14, TP2,

TP27None 201 243 0.5 L 2.5 L B 40

II 8386, B2, IB2, N37,

T11, TP2, TP27154 202 242 1 L 30 L B 40

III 8386, IB3, N37, T7,

TP1, TP28154 203 241 5 L 60 L A 40

D G Compounds, cleaning liquid 3 NA1993 I 3 T11, TP1 150 201 243 1 L 30 L E


TP28150 202 242 5 L 60 L B

III 3B1, B52, IB3, T4,

TP1, TP29150 203 242 60 L 220 L A

D GCompounds, tree killing, liquid or Compounds, weed

killing, liquid8 NA1760 I 8

A7, B10, T14, TP2,

TP27None 201 243 0.5 L 2.5 L B 40

II 8B2, IB2, N37, T11,

TP2, TP27154 202 242 1 L 30 L B 40

III 8IB3, N37, T7, TP1,

TP28154 203 241 5 L 60 L A 40


killing, liquid3 NA1993 I 3 T11, TP1 150 201 243 1 L 30 L E


TP28150 202 242 5 L 60 L B

III 3B1, B52, IB3, T4,

TP1, TP29150 203 242 60 L 220 L A


killing, liquid6.1 NA2810 I 6.1

T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A 40

G Compressed gas, flammable, n.o.s. 2.1 UN1954 2.1 306302,

305

314,


G Compressed gas, n.o.s 2.2 UN1956 2.2 306,

307

302,

305

314,

31575 kg 150 kg A

G Compressed gas, oxidizing, n.o.s. 2.2 UN3156 2.2,

5.1A14 306 302

314,

31575 kg 150 kg D

G ICompressed gas, toxic, corrosive, n.o.s. Inhalation

Hazard Zone A2.3 UN3304 2.3, 8 1 None 192 245 Forbidden Forbidden D 40


Hazard Zone B2.3 UN3304 2.3, 8 2, B9, B14 None

302,

305

314,



Hazard Zone C2.3 UN3304 2.3, 8 3, B14 None

302,

305

314,



Hazard Zone D2.3 UN3304 2.3, 8 4 None

302,

305

314,


G ICompressed gas, toxic, flammable, corrosive, n.o.s.

Inhalation Hazard Zone A2.3 UN3305

2.3,

2.1, 81 None 192 245 Forbidden Forbidden D 17, 40


Inhalation Hazard Zone B2.3 UN3305

2.3,

2.1, 82, B9, B14 None

302,

305

314,



Inhalation Hazard Zone C2.3 UN3305

2.3,

2.1, 83, B14 None

302,

305

314,



Inhalation Hazard Zone D2.3 UN3305

2.3,

2.1, 84 None

302,

305

314,


GCompressed gas, toxic, flammable, n.o.s. Inhalation

hazard Zone A2.3 UN1953

2.3,



hazard Zone B2.3 UN1953

2.3,

2.12, B9, B14 None

302,

305

314,



Hazard Zone C2.3 UN1953

2.3,

2.13, B14 None

302,

305

314,



Hazard Zone D2.3 UN1953

2.3,

2.14 None

302,

305

314,


GCompressed gas, toxic, n.o.s. Inhalation Hazard Zone

A2.3 UN1955 2.3 1 None 192 245 Forbidden Forbidden D 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Compressed gas, toxic, n.o.s. Inhalation Hazard Zone B 2.3 UN1955 2.3 2, B9, B14 None302,

305

314,


G Compressed gas, toxic, n.o.s. Inhalation Hazard Zone C 2.3 UN1955 2.3 3, B14 None302,

305

314,


GCompressed gas, toxic, n.o.s. Inhalation Hazard Zone

D2.3 UN1955 2.3 4 None

302,

305

314,


G ICompressed gas, toxic, oxdizing, corrosive, n.o.s.


2.3,

5.1, 81 None 192 244 Forbidden Forbidden D

40,

89, 90

G ICompressed gas, toxic, oxidizing, corrosive, n.o.s.


2.3,

5.1, 82, B9, B14 None

302,

305

314,


40,

89, 90



2.3,

5.1, 83, B14 None

302,

305

314,


40,

89, 90



2.3,

5.1, 84 None

302,

305

314,


40,

89, 90

GCompressed gas, toxic, oxidizing, n.o.s. Inhalation

Hazard Zone A2.3 UN3303

2.3,



Hazard Zone B2.3 UN3303

2.3,

5.12, B9, B14 None

302,

305

314,




2.3,

5.13, B14 None

302,

305

314,




2.3,

5.14 None

302,

305

314,


D Consumer commodity ORM-D None 222156,

306

156,

306None 30 kg gross Forbidden A

Consumer commodity 9 ID8000 9 167 167 None 30 kg gross 30 kg gross

GContrivances, water-activated, with burster, expelling

charge or propelling charge1.2L UN0248 1.2L None 62 None Forbidden Forbidden 5

25,

14E,

15E,

17E

GContrivances, water-activated, with burster, expelling

charge or propelling charge1.3L UN0249 1.3L None 62 None Forbidden Forbidden 5

25,

14E,

15E,

17E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Copper acetoarsenite 6.1 UN1585 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Copper acetylide Forbidden

Copper amine azide Forbidden

Copper arsenite 6.1 UN1586 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Copper based pesticides, liquid, flammable, toxic, flash


T14, TP2, TP13,


II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40

Copper based pesticides, liquid, toxic 6.1 UN3010 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40

Copper based pesticides, liquid, toxic, flammable, flash


T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1, 3B1, IB3, T7, TP2,

TP28153 203 242 60 L 220 L A 40

Copper based pesticides, solid, toxic 6.1 UN2775 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Copper chlorate 5.1 UN2721 II 5.1A1, IB8, IP2, IP4, T3,

TP33152 212 242 5 kg 25 kg A 56, 58

Copper chloride 8 UN2802 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 53, 58

Copper cyanide 6.1 UN1587 II 6.1IB8, IP2, IP4, T3,

TP33153 204 242 25 kg 100 kg A 52




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Copper selenate, see Selenates or Selenites

Copper selenite, see Selenates or Selenites

Copper tetramine nitrate Forbidden

A,W Copra 4.2 UN1363 III 4.2 B136, IB8, IP3, IP7 None 213 241 Forbidden Forbidden A

13,

25,

119

Cord, detonating, flexible 1.1D UN0065 1.1D 102, 148 63(a) 62 None Forbidden Forbidden 3 25

Cord, detonating, flexible 1.4D UN0289 1.4D 148 None 62 None Forbidden 75 kg 2 25

Cord, detonating or Fuze, detonating metal clad 1.2D UN0102 1.2D None 62 None Forbidden Forbidden 3 25

Cord, detonating or Fuze, detonating metal clad 1.1D UN0290 1.1D None 62 None Forbidden Forbidden 3 25

Cord, detonating, mild effect or Fuse, detonating, mild

effect metal clad1.4D UN0104 1.4D None 62 None Forbidden 75 kg 2 25

Cord, igniter 1.4G UN0066 1.4G None 62 None Forbidden 75 kg 2 25

Cordeau detonant fuse, see Cord, detonating, etc;

Cord, detonating, flexible

Cordite, see Powder, smokeless

G Corrosive liquid, acidic, inorganic, n.o.s 8 UN3264 I 8 B10, T14, TP2, TP27 None 201 243 0.5 L 2.5 L B40,

53, 58

II 8386, B2, IB2, T11,

TP2, TP27154 202 242 1 L 30 L B

40,

53, 58

III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A40,

53, 58

G Corrosive liquid, acidic, organic, n.o.s 8 UN3265 I 8 B10, T14, TP2, TP27 None 201 243 0.5 L 2.5 L B40,

53, 58

II 8148, B2, IB2, T11,

TP2, TP27154 202 242 1 L 30 L B

40,

53, 58

III 8386, IB3, T7, TP1,

TP28154 203 241 5 L 60 L A

40,

53, 58

G Corrosive liquid, basic, inorganic, n.o.s 8 UN3266 I 8 T14, TP2, TP27 None 201 243 0.5 L 2.5 L B 40, 52

II 8386, B2, IB2, T11,

TP2, TP27154 202 242 1 L 30 L B 40, 52

III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 40, 52




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Corrosive liquid, basic, organic, n.o.s 8 UN3267 I 8 B10, T14, TP2, TP27 None 201 243 0.5 L 2.5 L B 40, 52

II 8B2, IB2, T11, TP2,

TP27154 202 242 1 L 30 L B 40, 52

III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 40, 52

G Corrosive liquid, self-heating, n.o.s 8 UN3301 I 8, 4.2 B10 None 201 243 0.5 L 2.5 L D

II 8, 4.2 B2, IB1 154 202 242 1 L 30 L D

G Corrosive liquids, flammable, n.o.s 8 UN2920 I 8, 3 B10, T14, TP2, TP27 None 201 243 0.5 L 2.5 L C 25, 40

II 8, 3B2, IB2, T11, TP2,

TP27154 202 243 1 L 30 L C 25, 40

G Corrosive liquids, n.o.s 8 UN1760 I 8A7, B10, T14, TP2,

TP27None 201 243 0.5 L 2.5 L B 40

II 8B2, IB2, T11, TP2,

TP27154 202 242 1 L 30 L B 40

III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 40

G Corrosive liquids, oxidizing, n.o.s 8 UN3093 I 8, 5.1 A7 None 201 243 Forbidden 2.5 L C 89

II 8, 5.1 A7, IB2 None 202 243 1 L 30 L C 89

G Corrosive liquids, toxic, n.o.s 8 UN2922 I 8, 6.1A7, B10, T14, TP2,

TP13, TP27None 201 243 0.5 L 2.5 L B 40

II 8, 6.1 B3, IB2, T7, TP2 154 202 243 1 L 30 L B 40

III 8, 6.1 IB3, T7, TP1, TP28 154 203 241 5 L 60 L B 40

G Corrosive liquids, water-reactive, n.o.s 8 UN3094 I 8, 4.3 A7 None 201 243 Forbidden 1 L E13,

148

II 8, 4.3 A7 None 202 243 1 L 5 L E13,

148

G Corrosive solid, acidic, inorganic, n.o.s 8 UN3260 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg B 53, 58


TP33154 212 240 15 kg 50 kg B 53, 58

III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 53, 58

G Corrosive solid, acidic, organic, n.o.s 8 UN3261 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg B 53, 58


TP33154 212 240 15 kg 50 kg B 53, 58

III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 53, 58

G Corrosive solid, basic, inorganic, n.o.s. 8 UN3262 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg B 52




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes


TP33154 212 240 15 kg 50 kg B 52


G Corrosive solid, basic, organic, n.o.s. 8 UN3263 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg B 52


TP33154 212 240 15 kg 50 kg B 52


G Corrosive solids, flammable, n.o.s. 8 UN2921 I 8, 4.1 IB6, T6, TP33 None 211 242 1 kg 25 kg B 12, 25

II 8, 4.1IB8, IP2, IP4, T3,

TP33None 212 242 15 kg 50 kg B 12, 25

G Corrosive solids, n.o.s. 8 UN1759 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg B

II 8128, IB8, IP2, IP4,

T3, TP33154 212 240 15 kg 50 kg A

III 8128, IB8, IP3, T1,

TP33154 213 240 25 kg 100 kg A

G Corrosive solids, oxidizing, n.o.s. 8 UN3084 I 8, 5.1 T6, TP33 None 211 242 1 kg 25 kg C

II 8, 5.1 IB6, IP2, T3, TP33 None 212 242 15 kg 50 kg C

G Corrosive solids, self-heating, n.o.s. 8 UN3095 I 8, 4.2 T6, TP33 None 211 243 1 kg 25 kg C

II 8, 4.2 IB6, IP2, T3, TP33 None 212 242 15 kg 50 kg C

G Corrosive solids, toxic, n.o.s 8 UN2923 I 8, 6.1 IB7, T6, TP33 None 211 242 1 kg 25 kg B 40

II 8, 6.1IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg B 40

III 8, 6.1 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg B 40

G Corrosive solids, water-reactive, n.o.s 8 UN3096 I 8, 4.3 IB4, IP1, T6, TP33 None 211 243 1 kg 25 kg D13,

148

II 8, 4.3IB6, IP2, T3, TP33,

W100None 212 242 15 kg 50 kg D

13,

148

D W Cotton 9 NA1365 9137, IB8, IP2, IP4,

W41None None None No limit No limit A

A W Cotton waste, oily 4.2 UN1364 III 4.2 IB8, IP3, IP7 None 213 None Forbidden Forbidden A 54

A I

WCotton, wet 4.2 UN1365 III 4.2 IB8, IP3, IP7 None 204 241 Forbidden Forbidden A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Coumarin derivative pesticides, liquid, flammable,

toxic, flash point less than 23 degrees C3 UN3024 I 3, 6.1

T14, TP2, TP13,


II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40

Coumarin derivative pesticides, liquid, toxic 6.1 UN3026 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A 40

Coumarin derivative pesticides, liquid, toxic,

flammable, flash point not less than 23 degrees C6.1 UN3025 I 6.1, 3

T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1, 3B1, IB3, T7, TP1,

TP28153 203 242 60 L 220 L A 40

Coumarin derivative pesticides, solid, toxic 6.1 UN3027 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Cresols, liquid 6.1 UN2076 II 6.1, 8 IB2, IP2, IP4, T7, TP2 153 202 243 1 L 30 L B

Cresols, solid 6.1 UN3455 II 6.1, 8IB8, IP2, IP4, T3,

TP33153 212 242 15 kg 50 kg B

Cresylic acid 6.1 UN2022 II 6.1, 8 IB2, T7, TP2, TP13 153 202 243 1 L 30 L B

Crotonaldehyde or Crotonaldehyde, stabilized 6.1 UN1143 I 6.1, 3

2, 175, 387, B9, B14,

B32, B77, T20, TP2,

TP13, TP38, TP45


Crotonic acid, liquid 8 UN3472 III 8 IB8, T1 154 203 241 5 L 60 L A

12,

25,

53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Crotonic acid, solid 8 UN2823 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A

12,

25,

53, 58

Crotonylene 3 UN1144 I 3 T11, TP2 150 201 243 1 L 30 L E

Cupriethylenediamine solution 8 UN1761 II 8, 6.1 IB2, T7, TP2 154 202 243 1 L 30 L A 52

III 8, 6.1 IB3, T7, TP1, TP28 154 203 242 5 L 60 L A 52, 95

Cutters, cable, explosive 1.4S UN0070 1.4S None 62 62 25 kg 100 kg 1 25

Cyanide or cyanide mixtures, dry, see Cyanides,

inorganic, solid, n.o.s.

G Cyanide solutions, n.o.s. 6.1 UN1935 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40, 52

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L A 40, 52

III 6.1IB3, T7, TP2, TP13,

TP28153 203 241 60 L 220 L A 40, 52

Cyanides, inorganic, solid, n.o.s. 6.1 UN1588 I 6.1IB7, IP1, N74, N75,

T6, TP33None 211 242 5 kg 50 kg A 52

II 6.1IB8, IP2, IP4, N74,

N75, T3, TP33153 212 242 25 kg 100 kg A 52

III 6.1IB8, IP3, N74, N75,

T1, TP33153 213 240 100 kg 200 kg A 52

Cyanogen 2.3 UN1026 2.3,


Cyanogen bromide 6.1 UN1889 I 6.1, 8A6, A8, T6, TP33,

W31None 211 242 1 kg 15 kg D 40, 52

Cyanogen chloride, stabilized 2.3 UN1589 2.3, 8 1, 387 None 192 245 Forbidden Forbidden D 25, 40

Cyanuric chloride 8 UN2670 II 8IB8, IP2, IP4, T3,

TP33None 212 240 15 kg 50 kg A

12,

25,

40,

53, 58

Cyanuric triazide Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Cyclobutane 2.1 UN2601 2.1 306 304314,


Cyclobutyl chloroformate 6.1 UN2744 II6.1,

8, 3IB1, T7, TP2, TP13 153 202 243 1 L 30 L A

12,

13,

21,

25,

40,

53,

58,

100

1,5,9-Cyclododecatriene 6.1 UN2518 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 40

Cycloheptane 3 UN2241 II 3 IB2, T4, TP2 150 202 242 5 L 60 L B 40

Cycloheptatriene 3 UN2603 II 3, 6.1 IB2, T7, TP1, TP13 150 202 243 1 L 60 L E 40

Cycloheptene 3 UN2242 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B

Cyclohexane 3 UN1145 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E

Cyclohexanone 3 UN1915 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Cyclohexene 3 UN2256 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E

Cyclohexenyltrichlorosilane 8 UN1762 II 8A7, B2, N34, T10,

TP2, TP7, TP13None 206 242 Forbidden 30 L C

40,

53, 58

Cyclohexyl acetate 3 UN2243 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Cyclohexyl isocyanate 6.1 UN2488 I 6.1, 3

2, B9, B14, B32, B77,

T20, TP2, TP13,

TP38, TP45


Cyclohexyl mercaptan 3 UN3054 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

40,

95,

102

Cyclohexylamine 8 UN2357 II 8, 3 IB2, T7, TP2 None 202 243 1 L 30 L A 40, 52

Cyclohexyltrichlorosilane 8 UN1763 II 8A7, B2, N34, T10,


40,

53, 58

Cyclonite and cyclotetramethylenetetranitramine

mixtures, wetted or desensitized see RDX and HMX

mixtures, wetted or desensitized etc




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Cyclonite and HMX mixtures, wetted or desensitized

see RDX and HMX mixtures, wetted or desensitized

etc

Cyclonite and octogen mixtures, wetted or desensitized


etc

Cyclonite, see Cyclotrimethylenetrinitramine, etc

Cyclooctadiene phosphines, see 9-

Phosphabicyclononanes

Cyclooctadienes 3 UN2520 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Cyclooctatetraene 3 UN2358 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Cyclopentane 3 UN1146 II 3 IB2, T7, TP1 150 202 242 5 L 60 L E

Cyclopentane, methyl, see Methylcyclopentane

Cyclopentanol 3 UN2244 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Cyclopentanone 3 UN2245 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Cyclopentene 3 UN2246 II 3 IB2, IP8, T7, TP2 150 202 242 5 L 60 L E

Cyclopropane 2.1 UN1027 2.1 T50 306 304314,


Cyclotetramethylene tetranitramine (dry or

unphlegmatized) (HMX)Forbidden

Cyclotetramethylenetetranitramine, desensitized or

Octogen, desensitized or HMX, desensitized1.1D UN0484 1.1D None 62 None Forbidden Forbidden 4 25

Cyclotetramethylenetetranitramine, wetted or HMX,

wetted or Octogen, wetted with not less than 15

percent water, by mass

1.1D UN0226 1.1D None 62 None Forbidden Forbidden 4 25

Cyclotrimethylenenitramine and octogen, mixtures,

wetted or desensitized see RDX and HMX mixtures,

wetted or desensitized, etc




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Cyclotrimethylenetrinitramine and

cyclotetramethylenetetranitramine mixtures, wetted

or desensitized see RDX and HMX mixtures, wetted or

desensitized etc

Cyclotrimethylenetrinitramine and HMX mixtures,

wetted or desensitized see RDX and HMX mixtures,

wetted or desensitized etc

Cyclotrimethylenetrinitramine, desensitized or

Cyclonite, desensitized or Hexogen, desensitized or

RDX, desensitized


Cyclotrimethylenetrinitramine, wetted or Cyclonite,

wetted or Hexogen, wetted or RDX, wetted with not

less than 15 percent water by mass


Cymenes 3 UN2046 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Dangerous Goods in Machinery or Dangerous Goods in

Apparatus9 UN3363 136, A105 None 222 None See A105 See A105 A.

Decaborane 4.1 UN1868 II4.1,

6.1

A19, A20, IB6, IP2,

T3, TP33, W31None 212 None Forbidden 50 kg A 74

Decahydronaphthalene 3 UN1147 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

n-Decane 3 UN2247 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Deflagrating metal salts of aromatic nitroderivatives,

n.o.s.1.3C UN0132 1.3C None 62 None Forbidden Forbidden 4 25, 5E

Delay electric igniter, see Igniters

D Denatured alcohol 3 NA1987 II 3 172, T8 150 202 242 5 L 60 L B

III 3 172, B1, T7 150 203 242 60 L 220 L A

Depth charges, see Charges, depth

G Desensitized explosive, liquid, n.o.s. 3 UN3379 I 3 164 None 201 None Forbidden Forbidden D 36

G Desensitized explosive, solid, n.o.s. 4.1 UN3380 I 4.1 164 None 211 None Forbidden Forbidden D 28, 36

Detonating relays, see Detonators, etc

Detonator assemblies, non-electric for blasting 1.1B UN0360 1.1B None 62 None Forbidden Forbidden 5 25

Detonator assemblies, non-electric, for blasting 1.4B UN0361 1.4B 103, 14863(f),

63(g)62 None Forbidden 75 kg 5 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Detonator assemblies, non-electric, for blasting 1.4S UN0500 1.4S 148, 34763(f),

63(g)62 None 25 kg 100 kg 1 25

Detonators, electric, for blasting 1.1B UN0030 1.1B 14863(f),

63(g)62 None Forbidden Forbidden 5 25

Detonators, electric, for blasting 1.4B UN0255 1.4B 103, 14863(f),


Detonators, electric for blasting 1.4S UN0456 1.4S 148, 34763(f),

63(g)62 None 25 kg 100 kg 1 25

Detonators for ammunition 1.1B UN0073 1.1B None 62 None Forbidden Forbidden 5 25

Detonators for ammunition 1.2B UN0364 1.2B None 62 None Forbidden Forbidden 5 25

Detonators for ammunition 1.4B UN0365 1.4B 103 None 62 None Forbidden 75 kg 5 25

Detonators for ammunition 1.4S UN0366 1.4S 347 None 62 None 25 kg 100 kg 1 25

Detonators, non-electric, for blasting 1.1B UN0029 1.1B None 62 None Forbidden Forbidden 5 25

Detonators, non-electric, for blasting 1.4B UN0267 1.4B 10363(f),


Detonators, non-electric, for blasting 1.4S UN0455 1.4S 148, 34763(f),

63(g)62 None 25 kg 100 kg 1 25

Deuterium, compressed 2.1 UN1957 2.1 N89 306 302 None Forbidden 150 kg E 40

Devices, small, hydrocarbon gas powered or

Hydrocarbon gas refills for small devices with release

device

2.1 UN3150 2.1 306 304 None 1 kg 15 kg B 40

Di-n-amylamine 3 UN2841 III 3, 6.1 B1, IB3, T4, TP1 150 203 242 60 L 220 L A 52

Di-n-butyl peroxydicarbonate, with more than 52


Di-n-butylamine 8 UN2248 II 8, 3 IB2, T7, TP2 None 202 243 1 L 30 L A 52

2,2-Di-(tert-butylperoxy) butane, with more than 55


Di-(tert-butylperoxy) phthalate, with more than 55


2,2-Di-(4,4-di-tert-butylperoxycyclohexyl) propane, with

more than 42 percent with inert solidForbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Di-2,4-dichlorobenzoyl peroxide, with more than 75

percent with waterForbidden

1,2-Di-(dimethylamino)ethane 3 UN2372 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Di-2-ethylhexyl phosphoric acid, see Diisooctyl acid

phosphate

Di-(1-hydroxytetrazole) (dry) Forbidden

Di-(1-naphthoyl) peroxide Forbidden

a,a′-Di-(nitroxy) methylether Forbidden

Di-(beta-nitroxyethyl) ammonium nitrate Forbidden

Diacetone alcohol 3 UN1148 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Diacetone alcohol peroxides, with more than 57

percent in solution with more than 9 percent hydrogen

peroxide, less than 26 percent diacetone alcohol and

less than 9 percent water; total active oxygen content

more than 9 percent by mass

Forbidden

Diacetyl, see Butanedione

Diacetyl peroxide, solid, or with more than 25 percent


Diallylamine 3 UN2359 II3,

6.1, 8IB2, T7, TP1 150 202 243 1 L 5 L B

21,

40,

52,

100

Diallylether 3 UN2360 II 3, 6.1IB2, N12, T7, TP1,

TP13150 202 243 1 L 60 L E 40

4,4′-Diaminodiphenyl methane 6.1 UN2651 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

p-Diazidobenzene Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

1,2-Diazidoethane Forbidden

1,1′-Diazoaminonaphthalene Forbidden

Diazoaminotetrazole (dry) Forbidden

Diazodinitrophenol (dry) Forbidden

Diazodinitrophenol, wetted with not less than 40

percent water or mixture of alcohol and water, by mass1.1A UN0074 1.1A 111, 117 None 62 None Forbidden Forbidden 5 25

Diazodiphenylmethane Forbidden

Diazonium nitrates (dry) Forbidden

Diazonium perchlorates (dry) Forbidden

1,3-Diazopropane Forbidden

Dibenzyl peroxydicarbonate, with more than 87 percent

with waterForbidden

Dibenzyldichlorosilane 8 UN2434 II 8B2, T10, TP2, TP7,

TP13154 206 242 Forbidden 30 L C

40,

53, 58

Diborane 2.3 UN1911 2.3,

2.11, N89 None 302 None Forbidden Forbidden D 40, 57

D Diborane mixtures 2.1 NA1911 2.1 5 None 302 245 Forbidden Forbidden D 40, 57

Dibromoacetylene Forbidden

1,2-Dibromobutan-3-one 6.1 UN2648 II 6.1 IB2 153 202 243 5 L 60 L B 40

Dibromochloropropane 6.1 UN2872 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

A Dibromodifluoromethane, R12B2 9 UN1941 III None T11, TP2 155 203 241 100 L 220 L A 25

1,2-Dibromoethane, see Ethylene dibromide




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Dibromomethane 6.1 UN2664 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Dibutyl ethers 3 UN1149 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Dibutylaminoethanol 6.1 UN2873 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

N,N′-Dichlorazodicarbonamidine (salts of) (dry) Forbidden

1,1-Dichloro-1-nitroethane 6.1 UN2650 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

12,

25,

40, 74

D 3,5-Dichloro-2,4,6-trifluoropyridine 6.1 NA9264 I 6.1

2, B9, B14, B32, T20,

TP4, TP13, TP38,

TP45

None 227 244 Forbidden Forbidden A 40

Dichloroacetic acid 8 UN1764 II 8A3, A7, B2, IB2, N34,

T8, TP2154 202 242 1 L 30 L A 53, 58

1,3-Dichloroacetone 6.1 UN2649 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B

12,

25, 40

Dichloroacetyl chloride 8 UN1765 II 8A3, A7, B2, B6, IB2,

N34, T7, TP2154 202 242 1 L 30 L D

40,

53, 58

Dichloroacetylene Forbidden

+ Dichloroanilines, liquid 6.1 UN1590 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40

Dichloroanilines, solid 6.1 UN3442 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40

+ o-Dichlorobenzene 6.1 UN1591 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

2,2′-Dichlorodiethyl ether 6.1 UN1916 II 6.1, 3IB2, N33, N34, T7,

TP2153 202 243 5 L 60 L A

Dichlorodifluoromethane and difluoroethane azeotropic

mixture or Refrigerant gas R 500 with approximately 74

percent dichlorodifluoromethane

2.2 UN2602 2.2 T50 306 304314,

31575 kg 150 kg A

Dichlorodifluoromethane or Refrigerant gas R 12 2.2 UN1028 2.2 T50 306 304314,

31575 kg 150 kg A

Dichlorodimethyl ether, symmetrical 6.1 UN2249 I 6.1, 3 None 201 243 Forbidden Forbidden 40

1,1-Dichloroethane 3 UN2362 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

1,2-Dichloroethane, see Ethylene dichloride

Dichloroethyl sulfide Forbidden

1,2-Dichloroethylene 3 UN1150 II 3 IB2, T7, TP2 150 202 242 5 L 60 L B

Dichlorofluoromethane or Refrigerant gas R21 2.2 UN1029 2.2 T50 306 304314,

31575 kg 150 kg A

Dichloroisocyanuric acid, dry or Dichloroisocyanuric

acid salts5.1 UN2465 II 5.1

28, IB8, IP2, IP4, T3,

TP33152 212 240 5 kg 25 kg A 13

Dichloroisopropyl ether 6.1 UN2490 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L B

Dichloromethane 6.1 UN1593 III 6.1IB3, IP8, N36, T7,

TP2153 203 241 60 L 220 L A

Dichloropentanes 3 UN1152 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Dichlorophenyl isocyanates 6.1 UN2250 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B 25, 40

Dichlorophenyltrichlorosilane 8 UN1766 II 8A7, B2, B6, N34,


40,

53, 58

1,2-Dichloropropane 3 UN1279 II 3 IB2, N36, T4, TP1 150 202 242 5 L 60 L B

1,3-Dichloropropanol-2 6.1 UN2750 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A12,

25, 40

Dichloropropene and propylene dichloride mixture, see

1,2- Dichloropropane

Dichloropropenes 3 UN2047 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Dichlorosilane 2.3 UN2189 2.3,

2.1, 82, B9, B14 None 304

314,


1,2-Dichloro-1,1,2,2- tetrafluoroethane or Refrigerant

gas R 1142.2 UN1958 2.2 T50 306 304

314,

31575 kg 150 kg A

Dichlorovinylchloroarsine Forbidden

Dicycloheptadiene, see Bicyclo [2,2,1] hepta-2,5-

diene, stabilized

Dicyclohexylamine 8 UN2565 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 52

Dicyclohexylammonium nitrite 4.1 UN2687 III 4.1 IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg A 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Dicyclopentadiene 3 UN2048 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Didymium nitrate 5.1 UN1465 III 5.1A1, IB8, IP3, T1,

TP33152 213 240 25 kg 100 kg A

D Diesel fuel 3 NA1993 III None144, B1, IB3, T4,

TP1, TP29150 203 242 60 L 220 L A

I Diesel fuel 3 UN1202 III 3 144, B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Diethanol nitrosamine dinitrate (dry) Forbidden

Diethoxymethane 3 UN2373 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E

3,3-Diethoxypropene 3 UN2374 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Diethyl carbonate 3 UN2366 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Diethyl cellosolve, see Ethylene glycol diethyl ether

Diethyl ether or Ethyl ether 3 UN1155 I 3 T11, TP2 150 201 243 1 L 30 L E 40

Diethyl ketone 3 UN1156 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Diethyl peroxydicarbonate, with more than 27 percent


Diethyl sulfate 6.1 UN1594 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L C

Diethyl sulfide 3 UN2375 II 3 IB2, T7, TP1, TP13 None 202 243 5 L 60 L E

Diethylamine 3 UN1154 II 3, 8A3, IB2, N34, T7,

TP1150 202 243 1 L 5 L E 40, 52

2-Diethylaminoethanol 8 UN2686 II 8, 3 B2, IB2, T7, TP2 None 202 243 1 L 30 L A 52

3-Diethyamino-propylamine 3 UN2684 III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A 52

+ N, N-Diethylaniline 6.1 UN2432 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Diethylbenzene 3 UN2049 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Diethyldichlorosilane 8 UN1767 II 8, 3A7, B6, N34, T10,


40,

53, 58

Diethylene glycol dinitrate Forbidden

Diethyleneglycol dinitrate, desensitized with not less

than 25 percent non-volatile water-insoluble

phlegmatizer, by mass

1.1D UN0075 1.1D None 62 None Forbidden Forbidden 425,

21E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Diethylenetriamine 8 UN2079 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A 40, 52

N,N-Diethylethylenediamine 8 UN2685 II 8, 3 IB2, T7, TP2 None 202 243 1 L 30 L A 52

Diethylgold bromide Forbidden

Diethylthiophosphoryl chloride 8 UN2751 II 8 B2, IB2, T7, TP2 None 212 240 15 kg 50 kg D

12,

25,

40,

53, 58

Difluorochloroethanes, see 1-Chloro-1,1-

difluoroethanes

1,1-Difluoroethane or Refrigerant gas R 152a 2.1 UN1030 2.1 T50 306 304314,


1,1-Difluoroethylene or Refrigerant gas R 1132a 2.1 UN1959 2.1 306 304 None Forbidden 150 kg E 40

Difluoromethane or Refrigerant gas R 32 2.1 UN3252 2.1 T50 306 302314,


Difluorophosphoric acid, anhydrous 8 UN1768 II 8A7, B2, IB2, N5, N34,

T8, TP2None 202 242 1 L 30 L A

40,

53, 58

2,3-Dihydropyran 3 UN2376 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

1,8-Dihydroxy-2,4,5,7-tetranitroanthraquinone

(chrysamminic acid)Forbidden

Diiodoacetylene Forbidden

Diisobutyl ketone 3 UN1157 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Diisobutylamine 3 UN2361 III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A 52

Diisobutylene, isomeric compounds 3 UN2050 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Diisooctyl acid phosphate 8 UN1902 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 53, 58

Diisopropyl ether 3 UN1159 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E 40

Diisopropylamine 3 UN1158 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 52

Diisopropylbenzene hydroperoxide, with more than 72


Diketene, stabilized 6.1 UN2521 I 6.1, 3

2, 387, B9, B14, B32,

T20, TP2, TP13,

TP38, TP45


25,

26,

27, 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

1,2-Dimethoxyethane 3 UN2252 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

1,1-Dimethoxyethane 3 UN2377 II 3 IB2, T7, TP1 150 202 242 5 L 60 L B

Dimethyl carbonate 3 UN1161 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Dimethyl chlorothiophosphate, see Dimethyl

thiophosphoryl chloride

2,5-Dimethyl-2,5-dihydroperoxy hexane, with more

than 82 percent with waterForbidden

Dimethyl disulfide 3 UN2381 II 3, 6.1IB2, T7, TP2, TP13,

TP39150 202 242 Forbidden Forbidden B 40

Dimethyl ether 2.1 UN1033 2.1 T50 306 304314,


Dimethyl-N-propylamine 3 UN2266 II 3, 8 IB2, T7, TP2, TP13 150 202 243 1 L 5 L B 40, 52

Dimethyl sulfate 6.1 UN1595 I 6.1, 8

2, B9, B14, B32, B77,

T20, TP2, TP13,

TP38, TP45


53, 58

Dimethyl sulfide 3 UN1164 II 3 IB2, IP8, T7, TP2 150 202 242 5 L 60 L E 40

Dimethyl thiophosphoryl chloride 6.1 UN2267 II 6.1, 8 IB2, T7, TP2 153 202 243 1 L 30 L B25,

53, 58

Dimethylamine, anhydrous 2.1 UN1032 2.1 N87, T50 None 304314,

315Forbidden 150 kg D 40, 52

Dimethylamine solution 3 UN1160 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 52

2-Dimethylaminoacetonitrile 3 UN2378 II 3, 6.1 IB2, T7, TP1 150 202 243 1 L 60 L A 40, 52

2-Dimethylaminoethanol 8 UN2051 II 8, 3 B2, IB2, T7, TP2 154 202 243 1 L 30 L A 52

2-Dimethylaminoethyl acrylate, stabilized 6.1 UN3302 II 6.1 387, IB2, T7, TP2 153 202 243 5 L 60 L D 25

2-Dimethylaminoethyl methacrylate 6.1 UN2522 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L B 40

N,N-Dimethylaniline 6.1 UN2253 II 6.1 IB1, T7, TP2 153 202 243 5 L 60 L A

2,3-Dimethylbutane 3 UN2457 II 3 IB2, T7, TP1 150 202 242 5 L 60 L E

1, 3-Dimethylbutylamine 3 UN2379 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 52

Dimethylcarbamoyl chloride 8 UN2262 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A40,

53, 58

Dimethylcyclohexanes 3 UN2263 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

N,N-Dimethylcyclohexylamine 8 UN2264 II 8, 3 B2, IB2, T7, TP2 154 202 243 1 L 30 L A 40, 52




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Dimethyldichlorosilane 3 UN1162 II 3, 8B77, T10, TP2, TP7,

TP13None 206 243 Forbidden Forbidden B 40

Dimethyldiethoxysilane 3 UN2380 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Dimethyldioxanes 3 UN2707 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

N,N-Dimethylformamide 3 UN2265 III 3 B1, IB3, T2, TP2 150 203 242 60 L 220 L A

Dimethylhexane dihydroperoxide (dry) Forbidden

Dimethylhydrazine, symmetrical 6.1 UN2382 I 6.1, 3

2, B9, B14, B32, B77,

T20, TP2, TP13,

TP38, TP45


40,

52,

74.

Dimethylhydrazine, unsymmetrical 6.1 UN1163 I6.1,

3, 8

2, B7, B9, B14, B32,

T20, TP2, TP13,

TP38, TP45


21,

38,

40,

52,

100.

2,2-Dimethylpropane 2.1 UN2044 2.1 306 304314,


Dinitro-o-cresol 6.1 UN1598 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

1,3-Dinitro-5,5-dimethyl hydantoin Forbidden

Dinitro-7,8-dimethylglycoluril (dry) Forbidden

1,3-Dinitro-4,5-dinitrosobenzene Forbidden

1,4-Dinitro-1,1,4,4-tetramethylolbutanetetranitrate

(dry)Forbidden

2,4-Dinitro-1,3,5-trimethylbenzene Forbidden

Dinitroanilines 6.1 UN1596 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 91

Dinitrobenzenes, liquid 6.1 UN1597 II 6.1 11, IB2, T7, TP2 153 202 243 5 L 60 L A 91




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

III 6.1 11, IB3, T7, TP2 153 203 241 60 L 220 L A 91

Dinitrobenzenes, solid 6.1 UN3443 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 91

Dinitrochlorobenzene, see Chlorodinitrobenzene

1,2-Dinitroethane Forbidden

1,1-Dinitroethane (dry) Forbidden

Dinitrogen tetroxide 2.3 UN1067 2.3,

5.1, 8

1, B7, B14, B45, B46,

B61, B66, B67, B77,

T50, TP21


89, 90

Dinitroglycoluril or Dingu 1.1D UN0489 1.1D None 62 None Forbidden Forbidden 4 25

Dinitromethane Forbidden

Dinitrophenol, dry or wetted with less than 15 percent

water, by mass1.1D UN0076

1.1D,

6.1None 62 None Forbidden Forbidden 4 25, 5E

Dinitrophenol solutions 6.1 UN1599 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 36

III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 36

Dinitrophenol, wetted with not less than 15 percent

water, by mass4.1 UN1320 I

4.1,

6.1

23, A8, A19, A20,


Dinitrophenolates alkali metals, dry or wetted with less

than 15 percent water, by mass1.3C UN0077

1.3C,

6.1None 62 None Forbidden Forbidden 4 25, 5E

Dinitrophenolates, wetted with not less than 15

percent water, by mass4.1 UN1321 I

4.1,

6.1

23, A8, A19, A20,


Dinitropropylene glycol Forbidden

Dinitroresorcinol, dry or wetted with less than 15

percent water, by mass1.1D UN0078 1.1D None 62 None Forbidden Forbidden 4 25, 5E

2,4-Dinitroresorcinol (heavy metal salts of) (dry) Forbidden

4,6-Dinitroresorcinol (heavy metal salts of) (dry) Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Dinitroresorcinol, wetted with not less than 15 percent

water, by mass4.1 UN1322 I 4.1

23, A8, A19, A20,


3,5-Dinitrosalicylic acid (lead salt) (dry) Forbidden

Dinitrosobenzene 1.3C UN0406 1.3C None 62 None Forbidden Forbidden 4 25

Dinitrosobenzylamidine and salts of (dry) Forbidden

2,2-Dinitrostilbene Forbidden

Dinitrotoluenes, liquid 6.1 UN2038 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

Dinitrotoluenes, molten 6.1 UN1600 II 6.1 T7, TP3 None 202 243 Forbidden Forbidden C

Dinitrotoluenes, solid 6.1 UN3454 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

1,9-Dinitroxy pentamethylene-2,4, 6,8-tetramine (dry) Forbidden

Dioxane 3 UN1165 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Dioxolane 3 UN1166 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40

Dipentene 3 UN2052 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Diphenylamine chloroarsine 6.1 UN1698 I 6.1 T6, TP33, W31 None 201 None Forbidden Forbidden D 40

Diphenylchloroarsine, liquid 6.1 UN1699 I 6.1

A8, B14, B32, N33,

N34, T14, TP2, TP13,

TP27, W31

None 201 243 Forbidden 30 L D 40

Diphenylchloroarsine, solid 6.1 UN3450 I 6.1IB7, IP1, T6, TP33,

W31None 211 242 5 kg 50 kg D 40

Diphenyldichlorosilane 8 UN1769 II 8A7, B2, N34, T10,


40,

53, 58

Diphenylmethyl bromide 8 UN1770 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg D

40,

53, 58

Dipicryl sulfide, dry or wetted with less than 10 percent

water, by mass1.1D UN0401 1.1D None 62 None Forbidden Forbidden 4 25

Dipicryl sulfide, wetted with not less than 10 percent


162, A2, N41, N84,

W31None 211 None Forbidden 0.5 kg D 28, 36

Dipicrylamine, see Hexanitrodiphenylamine




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Dipropionyl peroxide, with more than 28 percent in

solutionForbidden

Di-n-propyl ether 3 UN2384 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Dipropyl ketone 3 UN2710 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Dipropylamine 3 UN2383 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 25, 52

G Disinfectant, liquid, corrosive, n.o.s 8 UN1903 I 8A7, B10, T14, TP2,

TP27None 201 243 0.5 L 2.5 L B

G Disinfectants, liquid, corrosive n.o.s. 8 UN1903 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L B

III 8 IB3, T4, TP1 154 203 241 5 L 60 L A

G Disinfectants, liquid, toxic, n.o.s. 6.1 UN3142 I 6.1 A4, T14, TP2, TP27 None 201 243 1 L 30 L A 40

II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L A 40

III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A 40

G Disinfectants, solid, toxic, n.o.s. 6.1 UN1601 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Disodium trioxosilicate 8 UN3253 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 52

G Dispersant gases, n.o.s. see Refrigerant gases, n.o.s.

Divinyl ether, stabilized 3 UN1167 I 3 387, A7, T11, TP2 None 201 243 1 L 30 L E 25, 40

Dodecyltrichlorosilane 8 UN1771 II 8A7, B2, B6, N34,


40,

53, 58

Dry ice, see Carbon dioxide, solid

GDyes, liquid, corrosive, n.o.s. or Dye intermediates,

liquid, corrosive, n.o.s8 UN2801 I 8

11, B10, T14, TP2,

TP27None 201 243 0.5 L 2.5 L A

II 811, B2, IB2, T11,

TP2, TP27154 202 242 1 L 30 L A

III 811, IB3, T7, TP1,

TP28154 203 241 5 L 60 L A

GDyes, liquid, toxic, n.o.s. or Dye intermediates, liquid,

toxic, n.o.s.6.1 UN1602 I 6.1 None 201 243 1 L 30 L A

II 6.1 IB2 153 202 243 5 L 60 L A

III 6.1 IB3 153 203 241 60 L 220 L A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

GDyes, solid, corrosive, n.o.s. or Dye intermediates,

solid, corrosive, n.o.s.8 UN3147 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg A


TP33154 212 240 15 kg 50 kg A

III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A

GDyes, solid, toxic, n.o.s. or Dye intermediates, solid,

toxic, n.o.s.6.1 UN3143 I 6.1

A5, IB7, IP1, T6,

TP33None 211 242 5 kg 50 kg A

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A


Dynamite, see Explosive, blasting, type A

Electrolyte (acid or alkali) for batteries, see Battery

fluid, acid or Battery fluid, alkali

GElevated temperature liquid, flammable, n.o.s., with

flash point above 37.8 C, at or above its flash point3 UN3256 III 3 IB1, T3, TP3, TP29 None None 247 Forbidden Forbidden A

G

Elevated temperature liquid, n.o.s., at or above 100 C

and below its flash point (including molten metals,

molten salts, etc.)

9 UN3257 III 9 IB1, T3, TP3, TP29 None None 247 Forbidden Forbidden A 85

GElevated temperature solid, n.o.s., at or above 240 C,

see §173.247(h)(4)9 UN3258 III 9

247

(h)(4)None 247 Forbidden Forbidden A 85

Engine, internal combustion, flammable gas powered

or Engine, fuel cell, flammable gas powered or

Machinery, internal combustion, flammable gas

powered or Machinery, fuel cell, flammable gas

powered

2.1 UN3529 2.1 135, A200 220 220 220 Forbidden No limit E

Engine, internal combustion, flammable liquid powered

or Engine, fuel cell, flammable liquid powered or

Machinery, internal combustion, flammable liquid

powered or Machinery, fuel cell, flammable liquid

powered

3 UN3528 3 135, A200 220 220 220 No limit No limit E 149

Engine, internal combustion or Machinery, internal

combustion9 UN3530 9 135, A200 220 220 220 No limit No limit A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Environmentally hazardous substance, liquid, n.o.s. 9 UN3082 III 98, 146, 173, 335,

IB3, T4, TP1, TP29155 203 241 No limit No limit A

G Environmentally hazardous substance, solid, n.o.s 9 UN3077 III 9

8, 146, 335, 384,

A112, B54, B120,

IB8, IP3, N20, N91,

T1, TP33

155 213 240 No limit No limit A

Epibromohydrin 6.1 UN2558 I 6.1, 3 T14, TP2, TP13 None 201 243 Forbidden Forbidden D 40

+ Epichlorohydrin 6.1 UN2023 II 6.1, 3 IB2, T7, TP2, TP13 153 202 243 5 L 60 L A 40

1,2-Epoxy-3-ethoxypropane 3 UN2752 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Esters, n.o.s. 3 UN3272 II 3IB2, T7, TP1, TP8,

TP28150 202 242 5 L 60 L B


TP29150 203 242 60 L 220 L A

Etching acid, liquid, n.o.s., see Hydrofluoric acid, etc

Ethane 2.1 UN1035 2.1 306 304 302 Forbidden 150 kg E 40

D Ethane-Propane mixture, refrigerated liquid 2.1 NA1961 2.1 T75, TP5 None 316314,


Ethane, refrigerated liquid 2.1 UN1961 2.1 T75, TP5 None None 315 Forbidden Forbidden D 40

Ethanol amine dinitrate Forbidden

Ethanol and gasoline mixture or Ethanol and motor

spirit mixture or Ethanol and petrol mixture, with more

than 10% ethanol

3 UN3475 II 3144, 177, IB2, T4,

TP1150 202 242 5 L 60 L E

Ethanol or Ethyl alcohol or Ethanol solutions or Ethyl

alcohol solutions3 UN1170 II 3 24, IB2, T4, TP1

4b,

150202 242 5 L 60 L A

III 3 24, B1, IB3, T2, TP14b,

150203 242 60 L 220 L A

Ethanolamine or Ethanolamine solutions 8 UN2491 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 52

Ether, see Diethyl ether

Ethers, n.o.s. 3 UN3271 II 3IB2, T7, TP1, TP8,

TP28150 202 242 5 L 60 L B




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes


TP29150 203 242 60 L 220 L A

Ethyl acetate 3 UN1173 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Ethyl acrylate, stabilized 3 UN1917 II 3387, IB2, T4, TP1,

TP13150 202 242 5 L 60 L C 25, 40

Ethyl alcohol, see Ethanol

Ethyl aldehyde, see Acetaldehyde

Ethyl amyl ketone 3 UN2271 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

N-Ethylbenzyltoluidines, solid 6.1 UN3460 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

N-Ethyl-N-benzylaniline 6.1 UN2274 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Ethyl borate 3 UN1176 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Ethyl bromide 6.1 UN1891 II 6.1IB2, IP8, T7, TP2,

TP13153 202 243 5 L 60 L B 40, 85

Ethyl bromoacetate 6.1 UN1603 II 6.1, 3 IB2, T7, TP2 None 202 243 Forbidden Forbidden D 40

Ethyl butyl ether 3 UN1179 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B

Ethyl butyrate 3 UN1180 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Ethyl chloride 2.1 UN1037 2.1 B77, N86, T50 None 322314,


Ethyl chloroacetate 6.1 UN1181 II 6.1, 3 IB2, T7, TP2 153 202 243 5 L 60 L A

Ethyl chloroformate 6.1 UN1182 I6.1,

3, 8

2, B9, B14, B32, N34,

T20, TP2, TP13,

TP38, TP45


21,

40,

53,

58,

100

Ethyl 2-chloropropionate 3 UN2935 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

+ Ethyl chlorothioformate 8 UN2826 II8,

6.1, 3

2, B9, B14, B32, T20,

TP2, TP38, TP45None 227 244 Forbidden Forbidden A

40,

53, 58

Ethyl crotonate 3 UN1862 II 3 IB2, T4, TP2 150 202 242 5 L 60 L B

Ethyl ether, see Diethyl ether

Ethyl fluoride or Refrigerant gas R161 2.1 UN2453 2.1 306 304314,


Ethyl formate 3 UN1190 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Ethyl hydroperoxide Forbidden

Ethyl isobutyrate 3 UN2385 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

+ Ethyl isocyanate 6.1 UN2481 I 6.1, 3

1, B9, B14, B30, T20,

TP2, TP13, TP38,

TP44


Ethyl lactate 3 UN1192 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Ethyl mercaptan 3 UN2363 I 3 T11, TP2, TP13 None 201 243 Forbidden 30 L E95,

102

Ethyl methacrylate, stabilized 3 UN2277 II 3 387, IB2, T4, TP1 150 202 242 5 L 60 L C 25

Ethyl methyl ether 2.1 UN1039 2.1 None 201314,


Ethyl methyl ketone or Methyl ethyl ketone 3 UN1193 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Ethyl nitrite solutions 3 UN1194 I 3, 6.1 None 201 None Forbidden Forbidden E40,

105

Ethyl orthoformate 3 UN2524 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Ethyl oxalate 6.1 UN2525 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Ethyl perchlorate Forbidden

D Ethyl phosphonothioic dichloride, anhydrous 6.1 NA2927 I 6.1, 8

2, B9, B14, B32, T20,

TP4, TP12, TP13,

TP38, TP45


DEthyl phosphonous dichloride, anhydrous pyrophoric

liquid6.1 NA2845 I

6.1,

4.2

2, B9, B14, B32, T20,

TP4, TP12, TP13,

TP38, TP45


D Ethyl phosphorodichloridate 6.1 NA2927 I 6.1, 8

2, B9, B14, B32, T20,

TP4, TP12, TP13,

TP38, TP45


Ethyl propionate 3 UN1195 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Ethyl propyl ether 3 UN2615 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E

Ethyl silicate, see Tetraethyl silicate

Ethylacetylene, stabilized 2.1 UN2452 2.1 387, N88 None 304314,





tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Ethylamine 2.1 UN1036 2.1 B77, N87, T50 None 321314,

315Forbidden 150 kg D 40, 52

Ethylamine, aqueous solution with not less than 50

percent but not more than 70 percent ethylamine3 UN2270 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B

40,

52.

N-Ethylaniline 6.1 UN2272 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 52, 74

2-Ethylaniline 6.1 UN2273 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 52, 74

Ethylbenzene 3 UN1175 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

N-Ethylbenzyltoluidines liquid 6.1 UN2753 III 6.1 IB3, T7, TP1 153 203 241 60 L 220 L A

2-Ethylbutanol 3 UN2275 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

2-Ethylbutyl acetate 3 UN1177 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

2-Ethylbutyraldehyde 3 UN1178 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B

Ethyldichloroarsine 6.1 UN1892 I 6.1

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP45


Ethyldichlorosilane 4.3 UN1183 I4.3,

8, 3

A2, A7, N34, T14,

TP2, TP7, TP13, W31None 201 244 Forbidden 1 L D

21,

40,

49,

53,

58,

100

Ethylene, acetylene and propylene in mixture,

refrigerated liquid with at least 71.5 percent ethylene

with not more than 22.5 percent acetylene and not

more than 6 percent propylene

2.1 UN3138 2.1 T75, TP5 None 304314,


Ethylene chlorohydrin 6.1 UN1135 I 6.1, 3

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP45


Ethylene 2.1 UN1962 2.1 306 304 302 Forbidden 150 kg E 40

Ethylene diamine diperchlorate Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Ethylene dibromide 6.1 UN1605 I 6.1

2, B9, B14, B32, B77,

T20, TP2, TP13,

TP38, TP45


Ethylene dibromide and methyl bromide liquid

mixtures, see Methyl bromide and ethylene

dibromide, liquid mixtures

Ethylene dichloride 3 UN1184 II 3, 6.1 IB2, N36, T7, TP1 150 202 243 1 L 60 L B 40

Ethylene glycol diethyl ether 3 UN1153 II 3 IB2, T4, TP1 150 202 242 5 L 60 L A

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Ethylene glycol dinitrate Forbidden

Ethylene glycol monoethyl ether 3 UN1171 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Ethylene glycol monoethyl ether acetate 3 UN1172 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Ethylene glycol monomethyl ether 3 UN1188 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Ethylene glycol monomethyl ether acetate 3 UN1189 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Ethylene oxide and carbon dioxide mixture with more

than 87 percent ethylene oxide2.3 UN3300

2.3,

2.14 None 304

314,


Ethylene oxide and carbon dioxide mixtures with more

than 9 percent but not more than 87 percent ethylene

oxide

2.1 UN1041 2.1 T50 306 304314,


Ethylene oxide and carbon dioxide mixtures with not

more than 9 percent ethylene oxide2.2 UN1952 2.2 306 304

314,

31575 kg 150 kg A

Ethylene oxide and chlorotetrafluoroethane mixture

with not more than 8.8 percent ethylene oxide2.2 UN3297 2.2 T50 306 304

314,

31575 kg 150 kg A

Ethylene oxide and dichlorodifluoromethane mixture,

with not more than 12.5 percent ethylene oxide2.2 UN3070 2.2 T50 306 304

314,

31575 kg 150 kg A

Ethylene oxide and pentafluoroethane mixture with not

more than 7.9 percent ethylene oxide2.2 UN3298 2.2 T50 306 304

314,

31575 kg 150 kg A

Ethylene oxide and propylene oxide mixtures, with not

more than 30 percent ethylene oxide3 UN2983 I 3, 6.1

5, A11, N4, N34,

T14, TP2, TP7, TP13None 201 243 Forbidden 30 L E 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Ethylene oxide and tetrafluoroethane mixture with not

more than 5.6 percent ethylene oxide2.2 UN3299 2.2 T50 306 304

314,

31575 kg 150 kg A

Ethylene oxide or Ethylene oxide with nitrogen up to a

total pressure of 1 MPa (10 bar) at 50 degrees C2.3 UN1040

2.3,

2.14, 342, T50, TP20 None 323 323 Forbidden Forbidden D 40

Ethylene, refrigerated liquid (cryogenic liquid) 2.1 UN1038 2.1 T75, TP5 None 316318,


Ethylenediamine 8 UN1604 II 8, 3 IB2, T7, TP2 154 202 243 1 L 30 L A40,

52.

Ethyleneimine, stabilized 6.1 UN1185 I 6.1, 3

1, 387, B9, B14, B30,

B77, N25, N32, T22,

TP2, TP13, TP38,

TP44


Ethylhexaldehyde, see Octyl aldehydes etc

2-Ethylhexyl chloroformate 6.1 UN2748 II 6.1, 8 IB2, T7, TP2, TP13 153 202 243 1 L 30 L A

12,

13,

25,

40,

53, 58

2-Ethylhexylamine 3 UN2276 III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A 40, 52

Ethylphenyldichlorosilane 8 UN2435 II 8A7, B2, N34, T10,

TP2, TP7, TP13None 206 242 Forbidden 30 L C 53, 58

1-Ethylpiperidine 3 UN2386 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 52

N-Ethyltoluidines 6.1 UN2754 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

Ethyltrichlorosilane 3 UN1196 II 3, 8A7, N34, T10, TP2,

TP7, TP13None 206 243 Forbidden 5 L B 40

Etiologic agent, see Infectious substances, etc

Explosive articles, see Articles, explosive , n.o.s. etc

Explosive, blasting, type A 1.1D UN0081 1.1D 148 None 62 None Forbidden Forbidden 4

25,

19E,

21E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Explosive, blasting, type B 1.1D UN0082 1.1D None 62 None Forbidden Forbidden 425,

19E

Explosive, blasting, type B or Agent blasting, Type B 1.5D UN0331 1.5D 105, 106, 148 None 62 None Forbidden Forbidden 325,

19E

Explosive, blasting, type C 1.1D UN0083 1.1D 123 None 62 None Forbidden Forbidden 425,

22E

Explosive, blasting, type D 1.1D UN0084 1.1D None 62 None Forbidden Forbidden 4 25

Explosive, blasting, type E 1.1D UN0241 1.1D 148 None 62 None Forbidden Forbidden 425,

19E

Explosive, blasting, type E or Agent blasting, Type E 1.5D UN0332 1.5D 105, 106, 148 None 62 None Forbidden Forbidden 325,

19E

Explosive, forbidden. See §173.54 Forbidden

Explosive substances, see Substances, explosive,

n.o.s. etc

Explosives, slurry, see Explosive, blasting, type E

Explosives, water gels, see Explosive, blasting, type E

Extracts, aromatic, liquid 3 UN1169 II 3149, IB2, T4, TP1,

TP8150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Extracts, flavoring, liquid 3 UN1197 II 3149, IB2, T4, TP1,

TP8150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Fabric with animal or vegetable oil, see Fibers or

fabrics, etc

Ferric arsenate 6.1 UN1606 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Ferric arsenite 6.1 UN1607 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Ferric chloride, anhydrous 8 UN1773 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 53, 58

Ferric chloride, solution 8 UN2582 III 8 B15, IB3, T4, TP1 154 203 241 5 L 60 L A 53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Ferric nitrate 5.1 UN1466 III 5.1A1, A29, IB8, IP3,

T1, TP33152 213 240 25 kg 100 kg A

Ferrocerium 4.1 UN1323 II 4.159, A19, IB8, IP2,

IP4, T3, TP33, W100151 212 240 15 kg 50 kg A

13,

147,

148

Ferrosilicon with 30 percent or more but less than 90

percent silicon4.3 UN1408 III

4.3,

6.1

A1, A19, B6, IB8,

IP4, IP7, T1, TP33,

W100

151 213 240 25 kg 100 kg A

13,

40,

52,

53,

85,

103,

148

Ferrous arsenate 6.1 UN1608 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

D Ferrous chloride, solid 8 NA1759 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A

D Ferrous chloride, solution 8 NA1760 II 8B3, IB2, T11, TP2,

TP27154 202 242 1 L 30 L B 40

Ferrous metal borings or Ferrous metal shavings or

Ferrous metal turnings or Ferrous metal cuttings in a

form liable to self-heating

4.2 UN2793 III 4.2

A1, A19, B134,

B136, IB8, IP3, IP7,

IP21, W100

None 213 241 25 kg 100 kg A13,

148

Fertilizer ammoniating solution with free ammonia 2.2 UN1043 2.2 N87 306 304314,


A I

WFibers, animal or Fibers, vegetable burnt, wet or damp 4.2 UN1372 III 4.2 151 213 240 Forbidden Forbidden A

IW Fibers, vegetable, dry 4.1 UN3360 III 4.1 137 151 213 240 No Limit No Limit A

A WFibers or Fabrics, animal or vegetable or Synthetic,

n.o.s. with animal or vegetable oil4.2 UN1373 III 4.2

137, IB8, IP3, T1,

TP33, W31None 213 241 Forbidden Forbidden A

Fibers or Fabrics impregnated with weakly nitrated

nitrocellulose, n.o.s.4.1 UN1353 III 4.1 A1, IB8, IP3 None 213 240 25 kg 100 kg D

Films, nitrocellulose base, from which gelatine has

been removed; film scrap, see Celluloid scrap




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Films, nitrocellulose base, gelatine coated (except

scrap)4.1 UN1324 III 4.1 None 183 None 25 kg 100 kg D 28

Fire extinguisher charges, corrosive liquid 8 UN1774 II 8 N41 154 202 None 1 L 30 L A

Fire extinguisher charges, expelling, explosive, see


Fire extinguishers containing compressed or liquefied

gas2.2 UN1044 2.2 110 309 309 None 75 kg 150 kg A

Firelighters, solid with flammable liquid 4.1 UN2623 III 4.1 A1, A19 None 213 None 25 kg 100 kg A 52

Fireworks 1.1G UN0333 1.1G 108 None 62 None Forbidden Forbidden 3 25



Fireworks 1.4G UN0336 1.4G 108, 200 None 62 None Forbidden 75 kg 2 25

Fireworks 1.4S UN0337 1.4S 108 None 62 None 25 kg 100 kg 1 25

First aid kit 9 UN3316 9 15 161 161 None 10 kg 10 kg A

A,W Fish meal, stabilized or Fish scrap, stabilized 9 UN2216 III None155, B136, IB8, IP3,

T1, TP33155 218 218 Forbidden Forbidden B

25,

88,

122,

128

Fish meal, unstablized or Fish scrap, unstabilized 4.2 UN1374 II 4.2

155, A1, A19, IB8,

IP2, IP4, T3, TP33,

W31, W40

None 212 241 Forbidden Forbidden B

18,

25,

128

Flammable compressed gas, see Compressed or

Liquefied gas, flammable, etc

Flammable compressed gas (small receptacles not

fitted with a dispersion device, not refillable), see

Receptacles, etc

Flammable gas in lighters, see Lighters or lighter

refills, cigarettes, containing flammable gas

G Flammable liquid, toxic, corrosive, n.o.s. 3 UN3286 I3,

6.1, 8

T14, TP2, TP13,

TP27None 201 243 Forbidden 2.5 L E

21,

40,

100




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II3,

6.1, 8

IB2, T11, TP2, TP13,

TP27150 202 243 1 L 5 L B

21,

40,

100

G Flammable liquids, corrosive, n.o.s. 3 UN2924 I 3, 8 T14, TP2 None 201 243 0.5 L 2.5 L E 40

II 3, 8 IB2, T11, TP2, TP27 150 202 243 1 L 5 L B 40

III 3, 8B1, IB3, T7, TP1,

TP28150 203 242 5 L 60 L A 40

G Flammable liquids, n.o.s. 3 UN1993 I 3 T11, TP1, TP27 150 201 243 1 L 30 L E


TP28150 202 242 5 L 60 L B

III 3B1, B52, IB3, T4,

TP1, TP29150 203 242 60 L 220 L A

G Flammable liquids, toxic, n.o.s. 3 UN1992 I 3, 6.1T14, TP2, TP13,


II 3, 6.1 IB2, T7, TP2, TP13 150 202 243 1 L 60 L B 40

III 3, 6.1B1, IB3, T7, TP1,

TP28150 203 242 60 L 220 L A

G Flammable solid, corrosive, inorganic, n.o.s. 4.1 UN3180 II 4.1, 8A1, IB6, IP2, T3,

TP33151 212 242 15 kg 50 kg D 40

III 4.1, 8 A1, IB6, T1, TP33 151 213 242 25 kg 100 kg D 40

G Flammable solid, inorganic, n.o.s. 4.1 UN3178 II 4.1A1, IB8, IP2, IP4, T3,

TP33151 212 240 15 kg 50 kg B

III 4.1A1, IB8, IP3, T1,

TP33151 213 240 25 kg 100 kg B

G Flammable solid, organic, molten, n.o.s. 4.1 UN3176 II 4.1 IB1, T3, TP3, TP26 151 212 240 Forbidden Forbidden C

III 4.1 IB1, T1, TP3, TP26 151 213 240 Forbidden Forbidden C

G Flammable solid, oxidizing, n.o.s. 4.1 UN3097 II4.1,

5.1131 None 214 214 Forbidden Forbidden E 40

III4.1,

5.1131, T1, TP33 None 214 214 Forbidden Forbidden D 40

G Flammable solid, toxic, inorganic, n.o.s. 4.1 UN3179 II4.1,

6.1

A1, IB6, IP2, T3,

TP33151 212 242 15 kg 50 kg B 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

III4.1,

6.1A1, IB6, T1, TP33 151 213 242 25 kg 100 kg B 40

G Flammable solids, corrosive, organic, n.o.s. 4.1 UN2925 II 4.1, 8A1, IB6, IP2, T3,

TP33None 212 242 15 kg 50 kg D 40

III 4.1, 8 A1, IB6, T1, TP33 151 213 242 25 kg 100 kg D 40

G Flammable solids, organic, n.o.s. 4.1 UN1325 II 4.1A1, IB8, IP2, IP4, T3,

TP33151 212 240 15 kg 50 kg B

III 4.1A1, IB8, IP3, T1,

TP33151 213 240 25 kg 100 kg B

G Flammable solids, toxic, organic, n.o.s. 4.1 UN2926 II4.1,

6.1

A1, IB6, IP2, T3,

TP33151 212 242 15 kg 50 kg B 40

III4.1,

6.1A1, IB6, T1, TP33 151 213 242 25 kg 100 kg B 40

Flares, aerial 1.3G UN0093 1.3G None 62 None Forbidden 75 kg 3 25

Flares, aerial 1.4G UN0403 1.4G None 62 None Forbidden 75 kg 2 25

Flares, aerial 1.4S UN0404 1.4S None 62 None 25 kg 100 kg 1 25

Flares, aerial 1.1G UN0420 1.1G None 62 None Forbidden Forbidden 3 25

Flares, aerial 1.2G UN0421 1.2G None 62 None Forbidden Forbidden 3 25

Flares, airplane, see Flares, aerial

Flares, signal, see Cartridges, signal

Flares, surface 1.3G UN0092 1.3G None 62 None Forbidden 75 kg 3 25

Flares, surface 1.1G UN0418 1.1G None 62 None Forbidden Forbidden 3 25

Flares, surface 1.2G UN0419 1.2G None 62 None Forbidden Forbidden 3 25

Flares, water-activated, see Contrivances, water-

activated, etc

Flash powder 1.1G UN0094 1.1G None 62 None Forbidden Forbidden 3 25

Flash powder 1.3G UN0305 1.3G None 62 None Forbidden Forbidden 3 25

Flue dusts, poisonous, see Arsenical dust

Fluoric acid, see Hydrofluoric acid, etc

Fluorine, compressed 2.3 UN1045 2.3,

5.1, 81, N86 None 302 None Forbidden Forbidden D

40,

89, 90

Fluoroacetic acid 6.1 UN2642 I 6.1 IB7, IP1, T6, TP33 None 211 242 1 kg 15 kg E 53, 58

Fluoroanilines 6.1 UN2941 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Fluorobenzene 3 UN2387 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Fluoroboric acid 8 UN1775 II 8A7, B2, B15, IB2, N3,

N34, T7, TP2154 202 242 1 L 30 L A 53, 58

Fluorophosphoric acid anhydrous 8 UN1776 II 8A7, B2, IB2, N3, N34,

T8, TP2None 202 242 1 L 30 L A 53, 58

G Fluorosilicates, n.o.s 6.1 UN2856 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52

Fluorosilicic acid 8 UN1778 II 8A7, B2, B15, IB2, N3,

N34, T8, TP2None 202 242 1 L 30 L A 53, 58

Fluorosulfonic acid 8 UN1777 I 8A7, A10, B6, B10,

N3, N36, T10, TP2None 201 243 0.5 L 2.5 L D

40,

53, 58

Fluorotoluenes 3 UN2388 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40

Forbidden materials. See §173.21 Forbidden

Formaldehyde solutions, flammable 3 UN1198 III 3, 8 176, B1, IB3, T4, TP1 150 203 242 5 L 60 L A 40

Formaldehyde solutions (with not less than 10% and

less than 25% formaldehyde), see Aviation regulated

liquid, n.o.s. or Other regulated substances, liquid,

n.o.s.

Formaldehyde solutions, with not less than 25 percent

formaldehyde8 UN2209 III 8 IB3, T4, TP1 154 203 241 5 L 60

Formalin, see Formaldehyde, solutions

Formic acid with not less than 10% but not more than

85% acid by mass8 UN3412 II 8 IB2, T7, TP2 154 202 242 1 L 30 L A

40,

53, 58

Formic acid with not less than 5% but less than 10%

acid by mass8 UN3412 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A

40,

53, 58

Formic acid with more than 85% acid by mass 8 UN1779 II 8, 3 B2, B28, IB2, T7, TP2 154 202 242 1 L 30 L A40,

53, 58

Fracturing devices, explosive, without detonators for

oil wells1.1D UN0099 1.1D None 62 62 Forbidden Forbidden 3 25

Fuel, aviation, turbine engine 3 UN1863 I 3144, T11, TP1, TP8,

TP28150 201 243 1 L 30 L E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II 3144, IB2, T4, TP1,

TP8150 202 242 5 L 60 L B

III 3 144, B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Fuel cell cartridges or Fuel cell cartridges contained in

equipment or Fuel cell cartridges packed with

equipment, containing corrosive substances

8 UN3477 8 328 230 230 230 5 kg 50 kg A



equipment, containing flammable liquids

3 UN3473 3 328 230 230 230 5 kg 50 kg A



equipment, containing hydrogen in metal hydride

2.1 UN3479 2.1 328 230 230 230 1 kg 15 kg B



equipment, containing liquefied flammable gas

2.1 UN3478 2.1 328 230 230 230 1 kg 15 kg B



equipment, containing water-reactive substances

4.3 UN3476 4.3 328 230 230 230 5 kg 50 kg A13,

148

D Fuel oil (No. 1, 2, 4, 5, or 6) 3 NA1993 III 3144, B1, IB3, T4,

TP1, TP29150 203 242 60 L 220 L A

Fuel system components (including fuel control units

(FCU), carburetors, fuel lines, fuel pumps) see

Dangerous Goods in Apparatus or Dangerous Goods in

Machinery

Fulminate of mercury (dry) Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Fulminate of mercury, wet, see Mercury fulminate,

etc

Fulminating gold Forbidden

Fulminating mercury Forbidden

Fulminating platinum Forbidden

Fulminating silver Forbidden

Fulminic acid Forbidden

Fumaryl chloride 8 UN1780 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L C8, 40,

53, 58

Fumigated lading, see §§172.302(g), 173.9 and

176.76(h)

Fumigated transport vehicle or freight container see

§173.9

Furaldehydes 6.1 UN1199 II 6.1, 3 IB2, T7, TP2 153 202 243 5 L 60 L A

Furan 3 UN2389 I 3 T12, TP2, TP13 None 201 243 1 L 30 L E 40

Furfuryl alcohol 6.1 UN2874 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 52, 74

Furfurylamine 3 UN2526 III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A 40, 52

Fuse, detonating, metal clad, see Cord, detonating,

metal clad

Fuse, detonating, mild effect, metal clad, see Cord,

detonating, mild effect, metal clad

Fuse, igniter tubular metal clad 1.4G UN0103 1.4G None 62 None Forbidden 75 kg 2 25

Fuse, non-detonating instantaneous or quickmatch 1.3G UN0101 1.3G None 62 None Forbidden Forbidden 3 25

Fuse, safety 1.4S UN0105 1.4S None 62 None 25 kg 100 kg 1 25

D Fusee (railway or highway) 4.1 NA1325 II 4.1 381 None 184 None 15 kg 50 kg B

Fusel oil 3 UN1201 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Fuses, tracer, see Tracers for ammunition

Fuzes, combination, percussion and time, see Fuzes,

detonating (UN0257, UN0367); Fuzes, igniting

(UN0317, UN0368)

Fuzes, detonating 1.1B UN0106 1.1B None 62 None Forbidden Forbidden 5 25

Fuzes, detonating 1.2B UN0107 1.2B None 62 None Forbidden Forbidden 5 25

Fuzes, detonating 1.4B UN0257 1.4B 116 None 62 None Forbidden 75 kg 5 25

Fuzes, detonating 1.4S UN0367 1.4S 116, 347 None 62 None 25 kg 100 kg 1 25

Fuzes, detonating, with protective features 1.1D UN0408 1.1D None 62 None Forbidden Forbidden 3 25

Fuzes, detonating, with protective features 1.2D UN0409 1.2D None 62 None Forbidden Forbidden 3 25

Fuzes, detonating, with protective features 1.4D UN0410 1.4D 116 None 62 None Forbidden 75 kg 2 25

Fuzes, igniting 1.3G UN0316 1.3G None 62 None Forbidden Forbidden 3 25

Fuzes, igniting 1.4G UN0317 1.4G None 62 None Forbidden 75 kg 2 25

Fuzes, igniting 1.4S UN0368 1.4S None 62 None 25 kg 100 kg 1 25

Galactsan trinitrate Forbidden

Gallium 8 UN2803 III 8 T1, TP33 None 162 240 20 kg 20 kg B 25

Gas cartridges, (flammable) without a release device,

non-refillable2.1 UN2037 2.1 306 304 None 1 kg 15 kg B 40

D Gas identification set 2.3 NA9035 2.3 6 None 194 None Forbidden Forbidden D

Gas oil 3 UN1202 III 3 144, B1, IB3, T2, TP1 150 203 242 60 L 220 L A

GGas, refrigerated liquid, flammable, n.o.s. (cryogenic

liquid)2.1 UN3312 2.1 T75, TP5 None 316 318 Forbidden Forbidden D 40

G Gas, refrigerated liquid, n.o.s. (cryogenic liquid) 2.2 UN3158 2.2 T75, TP5 320 316 318 50 kg 500 kg D

GGas, refrigerated liquid, oxidizing, n.o.s. (cryogenic

liquid)2.2 UN3311

2.2,

5.1T75, TP5, TP22 320 316 318 Forbidden Forbidden D

Gas sample, non-pressurized, flammable, n.o.s., not

refrigerated liquid2.1 UN3167 2.1 306

302,

304None 1 L 5 L D

Gas sample, non-pressurized, toxic, flammable, n.o.s.,

not refrigerated liquid2.3 UN3168

2.3,

2.16 306 302 None Forbidden 1 L D

Gas sample, non-pressurized, toxic, n.o.s., not

refrigerated liquid2.3 UN3169 2.3 6 306

302,

304None Forbidden 1 L D D




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Gasoline includes gasoline mixed with ethyl alcohol,

with not more than 10% alcohol3 UN1203 II 3

144, 177, B1, B33,

IB2, T4150 202 242 5 L 60 L E

Gasoline, casinghead, see Gasoline

Gelatine, blasting, see Explosive, blasting, type A

Gelatine dynamites, see Explosive, blasting, type A

Germane 2.3 UN2192 2.3,


Germane, adsorbed 2.3 UN35232.3,


Glycerol-1,3-dinitrate Forbidden

Glycerol gluconate trinitrate Forbidden

Glycerol lactate trinitrate Forbidden

Glycerol alpha-monochlorohydrin 6.1 UN2689 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Glyceryl trinitrate, see Nitroglycerin, etc

Glycidaldehyde 3 UN2622 II 3, 6.1 IB2, IP8, T7, TP1 150 202 243 1 L 60 L A 40

Grenades, hand or rifle, with bursting charge 1.1D UN0284 1.1D 62 None Forbidden Forbidden 3 25

Grenades, hand or rifle, with bursting charge 1.2D UN0285 1.2D 62 None Forbidden Forbidden 3 25

Grenades, hand or rifle, with bursting charge 1.1F UN0292 1.1F 62 None Forbidden Forbidden 3 25

Grenades, hand or rifle, with bursting charge 1.2F UN0293 1.2F 62 None Forbidden Forbidden 3 25

Grenades, illuminating, see Ammunition, illuminating,

etc

Grenades, practice, hand or rifle 1.4S UN0110 1.4S 62 None 25 kg 100 kg 1 25

Grenades, practice, hand or rifle 1.3G UN0318 1.3G 62 None Forbidden Forbidden 3 25

Grenades, practice, hand or rifle 1.2G UN0372 1.2G 62 None Forbidden Forbidden 3 25

Grenades practice, hand or rifle 1.4G UN0452 1.4G 62 None Forbidden 75 kg 2 25

Grenades, smoke, see Ammunition, smoke, etc

Guanidine nitrate 5.1 UN1467 III 5.1A1, IB8, IP3, T1,

TP33152 213 240 25 kg 100 kg A 73




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Guanyl nitrosaminoguanylidene hydrazine (dry) Forbidden

Guanyl nitrosaminoguanylidene hydrazine, wetted

with not less than 30 percent water, by mass1.1A UN0113 1.1A 111, 117 None 62 None Forbidden Forbidden 5 25

Guanyl nitrosaminoguanyltetrazene (dry) Forbidden

Guanyl nitrosaminoguanyltetrazene, wetted or

Tetrazene, wetted with not less than 30 percent water

or mixture of alcohol and water, by mass

1.1A UN0114 1.1A 111, 117 None 62 None Forbidden Forbidden 5 25

Gunpowder, compressed or Gunpowder in pellets, see

Black powder (UN 0028)

Gunpowder, granular or as a meal, see Black powder

(UN 0027)

Hafnium powder, dry 4.2 UN2545 I 4.2 W31 None 211 242 Forbidden Forbidden D13,

148

II 4.2A19, A20, IB6, IP2,

N34, T3, TP33, W31None 212 241 15 kg 50 kg D

13,

148

III 4.2B135, IB8, IP21, T1,

TP33, W31None 213 241 25 kg 100 kg D

13,

148

Hafnium powder, wetted with not less than 25 percent

water (a visible excess of water must be present) (a)

mechanically produced, particle size less than 53

microns; (b) chemically produced, particle size less than

840 microns

4.1 UN1326 II 4.1

A6, A19, A20, IB6,

IP2, N34, T3, TP33,

W31, W40

None 212 241 15 kg 50 kg E 74

Hand signal device, see Signal devices, hand

Hazardous substances, liquid or solid, n.o.s., see

Environmentally hazardous substances, etc

D G Hazardous waste, liquid, n.o.s. 9 NA3082 III 9 IB3, T2, TP1 155 203 241 No limit No limit A

D G Hazardous waste, solid, n.o.s. 9 NA3077 III 9B54, IB8, IP2, T1,

TP33155 213 240 No limit No limit A

Heating oil, light 3 UN1202 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Helium, compressed 2.2 UN1046 2.2 306 302302,

31475 kg 150 kg A 85

Helium, refrigerated liquid (cryogenic liquid) 2.2 UN1963 2.2 T75, TP5 320 316 318 50 kg 500 kg D

Heptafluoropropane or Refrigerant gas R 227 2.2 UN3296 2.2 T50 306 304314,

31575 kg 150 kg A

n-Heptaldehyde 3 UN3056 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Heptanes 3 UN1206 II 3 IB2, T4, TP2 150 202 242 5 L 60 L B

n-Heptene 3 UN2278 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Hexachloroacetone 6.1 UN2661 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L B 12, 40

Hexachlorobenzene 6.1 UN2729 III 6.1B3, IB8, IP3, T1,

TP33153 203 241 60 L 220 L A

Hexachlorobutadiene 6.1 UN2279 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Hexachlorocyclopentadiene 6.1 UN2646 I 6.1

2, B9, B14, B32, B77,

T20, TP2, TP13,

TP38, TP45


Hexachlorophene 6.1 UN2875 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Hexadecyltrichlorosilane 8 UN1781 II 8A7, B2, B6, N34,


40,

53, 58

Hexadienes 3 UN2458 II 3 IB2, T4, TP1 None 202 242 5 L 60 L B

Hexaethyl tetraphosphate and compressed gas

mixtures2.3 UN1612 2.3 3 None 334 None Forbidden Forbidden D 40

Hexaethyl tetraphosphate, liquid 6.1 UN1611 II 6.1 IB2, N76, T7, TP2 153 202 243 5 L 60 L E 40

Hexaethyl tetraphosphate, solid 6.1 UN1611 II 6.1 IB8, IP2, IP4, N76 153 212 242 25 kg 100 kg E 40

Hexafluoroacetone 2.3 UN2420 2.3, 8 2, B9, B14 None 304314,


Hexafluoroacetone hydrate, liquid 6.1 UN2552 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L B 40

Hexafluoroacetone hydrate, solid 6.1 UN3436 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B 40

Hexafluoroethane, or Refrigerant gas R 116 2.2 UN2193 2.2 306 304314,

31575 kg 150 kg A

Hexafluorophosphoric acid 8 UN1782 II 8A7, B2, IB2, N3, N34,

T8, TP2None 202 242 1 L 30 L A 53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Hexafluoropropylene compressed or Refrigerant gas R

12162.2 UN1858 2.2 T50 306 304

314,

31575 kg 150 kg A

Hexaldehyde 3 UN1207 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Hexamethylene diisocyanate 6.1 UN2281 II 6.1 IB2, T7, TP2, TP13 153 202 243 5 L 60 L C 13, 40

Hexamethylene triperoxide diamine (dry) Forbidden

Hexamethylenediamine, solid 8 UN2280 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A12,

25, 52

Hexamethylenediamine solution 8 UN1783 II 8 IB2, T7, TP2 None 202 242 1 L 30 L A 52

III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 52

Hexamethyleneimine 3 UN2493 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 40

Hexamethylenetetramine 4.1 UN1328 III 4.1A1, IB8, IP3, T1,

TP33151 213 240 25 kg 100 kg A

Hexamethylol benzene hexanitrate Forbidden

Hexanes 3 UN1208 II 3 IB2, T4, TP2 150 202 242 5 L 60 L E

2,2′,4,4′,6,6′- Hexanitro-3,3′-dihydroxyazobenzene

(dry)Forbidden

Hexanitroazoxy benzene Forbidden

N,N′-(hexanitrodiphenyl) ethylene dinitramine (dry) Forbidden

Hexanitrodiphenyl urea Forbidden

2,2′,3′,4,4′,6-Hexanitrodiphenylamine Forbidden

Hexanitrodiphenylamine or Dipicrylamine or Hexyl 1.1D UN0079 1.1D None 62 None Forbidden Forbidden 4 25

2,3′,4,4′,6,6′-Hexanitrodiphenylether Forbidden

Hexanitroethane Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Hexanitrooxanilide Forbidden

Hexanitrostilbene 1.1D UN0392 1.1D None 62 None Forbidden Forbidden 4 25

Hexanoic acid, see Corrosive liquids, n.o.s.

Hexanols 3 UN2282 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 74

1-Hexene 3 UN2370 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E

Hexogen and cyclotetramethylenetetranitramine

mixtures, wetted or desensitized see RDX and HMX

mixtures, wetted or desensitized etc

Hexogen and HMX mixtures, wetted or desensitized


etc

Hexogen and octogen mixtures, wetted or desensitized


etc

Hexogen, see Cyclotrimethylenetrinitramine, etc

Hexolite, or Hexotol dry or wetted with less than 15

percent water, by mass1.1D UN0118 1.1D None 62 None Forbidden Forbidden 4 25

Hexotonal 1.1D UN0393 1.1D None 62 None Forbidden Forbidden 4 25

Hexyl, see Hexanitrodiphenylamine

Hexyltrichlorosilane 8 UN1784 II 8A7, B2, B6, N34,


40,

53, 58

High explosives, see individual explosives' entries

HMX, see Cyclotetramethylenete tranitramine, etc

Hydrazine, anhydrous 8 UN2029 I8, 3,

6.1

A7, A10, B7, B16,

B53None 201 243 Forbidden 2.5 L D

40,

52,

125

Hydrazine, aqueous solution, with not more than 37

percent hydrazine, by mass6.1 UN3293 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 52




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Hydrazine aqueous solution, flammable with more

than 37% hydrazine, by mass8 UN3484 I

8, 3,

6.1

B16, B53, T10, TP2,


40,

52,

125

Hydrazine aqueous solution, with more than 37%

hydrazine, by mass8 UN2030 I 8, 6.1

B16, B53, T10, TP2,

TP13None 201 243 Forbidden 2.5 L D 40, 52

II 8, 6.1B16, B53, IB2, T7,

TP2, TP13None 202 243 Forbidden 30 L D 40, 52

III 8, 6.1B16, B53, IB3, T4,

TP1154 203 241 5 L 60 L D 40, 52

Hydrazine azide Forbidden

Hydrazine chlorate Forbidden

Hydrazine dicarbonic acid diazide Forbidden

Hydrazine perchlorate Forbidden

Hydrazine selenate Forbidden

Hydriodic acid, anhydrous, see Hydrogen iodide,

anhydrous

Hydriodic acid 8 UN1787 II 8A3, B2, IB2, N41, T7,

TP2154 202 242 1 L 30 L C

III 8 IB3, T4, TP1 154 203 241 5 L 60 L C 8

Hydrobromic acid, anhydrous, see Hydrogen bromide,

anhydrous

Hydrobromic acid, with more than 49 percent

hydrobromic acid8 UN1788 II 8

B2, B15, IB2, N41,

T7, TP2154 202 242 Forbidden Forbidden C 53, 58

III 8 IB3, T4, TP1 154 203 241 Forbidden Forbidden C8, 53,

58

Hydrobromic acid, with not more than 49 percent

hydrobromic acid8 UN1788 II 8

A3, B2, B15, IB2,

N41, T7, TP2154 202 242 1 L 30 L C

III 8 A3, IB3, T4, TP1 154 203 241 5 L 60 L C 8




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Hydrocarbon gas mixture, compressed, n.o.s. 2.1 UN1964 2.1 306 302314,


Hydrocarbon gas mixture, liquefied, n.o.s. 2.1 UN1965 2.1 T50 306 304314,


Hydrocarbons, liquid, n.o.s. 3 UN3295 I 3144, T11, TP1, TP8,

TP28150 201 243 1 L 30 L E

II 3144, IB2, T7, TP1,

TP8, TP28150 202 242 5 L 60 L B

III 3144, B1, IB3, T4,

TP1, TP29150 203 242 60 L 220 L A

Hydrochloric acid, anhydrous, see Hydrogen chloride,

anhydrous

Hydrochloric acid 8 UN1789 II 8

386, A3, B3, B15,

B133, IB2, N41, T8,

TP2

154 202 242 1 L 30 L C 53, 58

III 8 A3, IB3, T4, TP1 154 203 241 5 L 60 L C8, 53,

58

Hydrocyanic acid, anhydrous, see Hydrogen cyanide

etc

Hydrocyanic acid, aqueous solutions or Hydrogen

cyanide, aqueous solutions with not more than 20

percent hydrogen cyanide

6.1 UN1613 I 6.12, B61, B65, B77,

B82, T20, TP2, TP13None 195 244 Forbidden Forbidden D 40

DHydrocyanic acid, aqueous solutions with less than 5

percent hydrogen cyanide6.1 NA1613 II 6.1

IB1, T14, TP2, TP13,

TP27None 195 243 Forbidden 5 L D 40

Hydrocyanic acid, liquefied, see Hydrogen cyanide, etc

Hydrocyanic acid (prussic), unstabilized Forbidden

Hydrofluoric acid and Sulfuric acid mixtures 8 UN1786 I 8, 6.1A7, B15, B23, N5,

N34, T10, TP2, TP13None 201 243 Forbidden 2.5 L D

40,

53, 58

Hydrofluoric acid, anhydrous, see Hydrogen fluoride,

anhydrous




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Hydrofluoric acid, with more than 60 percent strength 8 UN1790 I 8, 6.1

A7, B4, B15, B23,

N5, N34, T10, TP2,

TP13

None 201 243 0.5 L 2.5 L D

12,

25,

40,

53, 58

Hydrofluoric acid, with not more than 60 percent

strength8 UN1790 II 8, 6.1

A7, B15, IB2, N5,

N34, T8, TP2154 202 243 1 L 30 L D

12,

25,

40,

53, 58

Hydrofluoroboric acid, see Fluoroboric acid

Hydrofluorosilicic acid, see Fluorosilicic acid

Hydrogen and Methane mixtures, compressed 2.1 UN2034 2.1 N89 306 302

302,

314,

315

Forbidden 150 kg E 40, 57

Hydrogen bromide, anhydrous 2.3 UN1048 2.3, 8 3, B14, N86, N89 None 304314,


Hydrogen chloride, anhydrous 2.3 UN1050 2.3, 8 3, N86, N89 None 304 None Forbidden Forbidden D 40

Hydrogen chloride, refrigerated liquid 2.3 UN2186 2.3, 8 3, B6 None None314,

315Forbidden Forbidden B 40

Hydrogen, compressed 2.1 UN1049 2.1 N89 306 302302,

314Forbidden 150 kg E 40, 57

Hydrogen cyanide, solution in alcohol with not more

than 45 percent hydrogen cyanide6.1 UN3294 I 6.1, 3

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP45


Hydrogen cyanide, stabilized with less than 3 percent

water6.1 UN1051 I 6.1, 3

1, 387, B35, B61,

B65, B77, B82None 195 244 Forbidden Forbidden D 25, 40

Hydrogen cyanide, stabilized, with less than 3 percent

water and absorbed in a porous inert material6.1 UN1614 I 6.1 5, 387 None 195 None Forbidden Forbidden D 25, 40

Hydrogen fluoride, anhydrous 8 UN1052 I 8.6.13, B7, B46, B77, N86,

T10, TP2None 163 244 Forbidden Forbidden D

40,

53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Hydrogen in a metal hydride storage system or

Hydrogen in a metal hydride storage system contained

in equipment or Hydrogen in a metal hydride storage

system packed with equipment

2.1 UN3468 2.1 167 None 311 None Forbidden 100 kg D

Hydrogen iodide, anhydrous 2.3 UN2197 2.3, 8 3, B14, N86, N89 None 304314,


Hydrogen iodide solution, see Hydriodic acid

Hydrogen peroxide and peroxyacetic acid mixtures,

stabilized with acids, water, and not more than 5

percent peroxyacetic acid

5.1 UN3149 II 5.1, 8

145, A2, A3, B53,

IB2, IP5, T7, TP2,

TP6, TP24

None 202 243 1 L 5 L D25,

66, 75

Hydrogen, peroxide, aqueous solutions with more than

40 percent but not more than 60 percent hydrogen

peroxide (stabilized as necessary)

5.1 UN2014 II 5.1, 8

12, A60, B53, B80,

B81, B85, IB2, IP5,

T7, TP2, TP6, TP24,

TP37


66, 75

Hydrogen peroxide, aqueous solutions with not less

than 20 percent but not more than 40 percent

hydrogen peroxide (stabilized as necessary)

5.1 UN2014 II 5.1, 8

A2, A3, B53, IB2,

IP5, T7, TP2, TP6,

TP24, TP37

None 202 243 1 L 5 L D25,

66, 75

Hydrogen, peroxide, aqueous solutions with not less

than 8 percent but less than 20 percent hydrogen

peroxide (stabilized as necessary)

5.1 UN2984 III 5.1

A1, IB2, IP5, T4,

TP1, TP6, TP24,

TP37

152 203 241 2.5 L 30 L B25,

66, 75

Hydrogen peroxide, stabilized or Hydrogen peroxide

aqueous solutions, stabilized with more than 60

percent hydrogen peroxide

5.1 UN2015 I 5.1, 8

12, B53, B80, B81,

B85, T9, TP2, TP6,

TP24, TP37


25,

66,

75.

Hydrogen, refrigerated liquid (cryogenic liquid) 2.1 UN1966 2.1 T75, TP5 None 316318,


Hydrogen selenide, adsorbed 2.3 UN35262.3,


Hydrogen selenide, anhydrous 2.3 UN2202 2.3,


Hydrogen sulfate, see Sulfuric acid

Hydrogen sulfide 2.3 UN1053 2.3,

2.12, B9, B14, N89 None 304

314,





tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Hydrogendifluoride, solid, n.o.s 8 UN1740 II 8IB8, IP2, IP4, N3,

N34, T3, TP33None 212 240 15 kg 50 kg A

25,

40,

52,

53, 58

III 8IB8, IP3, N3, N34,

T1, TP33154 213 240 25 kg 100 kg A

25,

40,

52,

53, 58

Hydrogendifluoride solution, n.o.s 8 UN3471 II 8, 6.1 IB2, T7, TP2 154 202 242 1 L 30 L A

25,

40,

52.

III 8, 6.1 IB3, T4, TP1 154 203 241 5 L 60 L A

25,

40,

52.

Hydrosilicofluoric acid, see Fluorosilicic acid

1-Hydroxybenzotriazole, anhydrous, dry or wetted with

less than 20 percent water, by mass1.3C UN0508 1.3C None 62 None Forbidden Forbidden 4 25

1-Hydroxybenzotriazole, monohydrate 4.1 UN3474 I 4.1 N90 None 211 None 0.5 kg 0.5 kg D 28, 36

Hydroxyl amine iodide Forbidden

Hydroxylamine sulfate 8 UN2865 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A52,

53, 58

Hypochlorite solutions 8 UN1791 II 8

148, A7, B2, B15,

IB2, IP5, N34, T7,

TP2, TP24

154 202 242 1 L 30 L B26,

53, 58

III 8386, IB3, N34, T4,

TP2, TP24154 203 241 5 L 60 L B

26,

53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Hypochlorites, inorganic, n.o.s 5.1 UN3212 II 5.1349, A9, IB8, IP2,

IP4, T3, TP33152 212 240 5 kg 25 kg D

4, 25,

52,

56,

58,

69,

116,

118

Hyponitrous acid Forbidden

Igniter fuse, metal clad, see Fuse, igniter, tubular,

metal clad

Igniters 1.1G UN0121 1.1G None 62 None Forbidden Forbidden 3 25



Igniters 1.4G UN0325 1.4G None 62 None Forbidden 75 kg 2 25

Igniters 1.4S UN0454 1.4S None 62 None 25 kg 100 kg 1 25

3,3′-Iminodipropylamine 8 UN2269 III 8 IB3, T4, TP2 154 203 241 5 L 60 L A 52

G Infectious substances, affecting animals only 6.2 UN2900 6.2 A82 134 196 None50 mL or 50

g4 L or 4 kg B 40

G Infectious substances, affecting humans 6.2 UN 2814 6.2 A82 134 196 None50 mL or 50

g4 L or 4 kg B 40

Inflammable, see Flammable

Initiating explosives (dry) Forbidden

Inositol hexanitrate (dry) Forbidden

G Insecticide gases, n.o.s. 2.2 UN1968 2.2 306 304314,

31575 kg 150 kg A

G Insecticide gases, flammable, n.o.s. 2.1 UN3354 2.1 T50 306 304314,


GInsecticide gases, toxic, flammable, n.o.s. Inhalation

hazard Zone A2.3 UN3355

2.3,





tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes


hazard Zone B2.3 UN3355

2.3,

2.12, B9, B14 None

302,

305

314,



hazard Zone C2.3 UN3355

2.3,

2.13, B14 None

302,

305

314,



hazard Zone D2.3 UN3355

2.3,

2.14 None

302,

305

314,


G Insecticide gases, toxic, n.o.s. 2.3 UN1967 2.3 3 None193,

334245 Forbidden Forbidden D 40

Inulin trinitrate (dry) Forbidden

+ Iodine 8 UN3495 III 8, 6.1 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg B 40, 55

Iodine azide (dry) Forbidden

Iodine monochloride, liquid 8 UN3498 II 8 IB2, T7, TP2 154 202 242 1 L 30 L D

40,

53,

58,

66,

74,

89, 90

Iodine monochloride, solid 8 UN1792 II 8B6, IB8, IP2, IP4,

N41, T7, TP2None 212 240 Forbidden 50 kg D

40,

53,

58,

66, 74

Iodine pentafluoride 5.1 UN2495 I5.1,

6.1, 8None 205 243 Forbidden Forbidden D

25,

40,

52,

53,

58,

66, 90

2-Iodobutane 3 UN2390 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Iodomethylpropanes 3 UN2391 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Iodopropanes 3 UN2392 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Iodoxy compounds (dry) Forbidden

Iridium nitratopentamine iridium nitrate Forbidden

Iron chloride, see Ferric chloride

Iron oxide, spent, or Iron sponge, spent obtained from

coal gas purification4.2 UN1376 III 4.2

B18, B134, IB8, IP21,

T1, TP33, W100None 213 240 Forbidden Forbidden E

13,

148

Iron pentacarbonyl 6.1 UN1994 I 6.1, 3

1, B9, B14, B30, B77,

T22, TP2, TP13,

TP38, TP44


Iron sesquichloride, see Ferric chloride

Irritating material, see Tear gas substances, etc

Isobutane see also Petroleum gases, liquefied 2.1 UN1969 2.1 19, T50 306 304314,


Isobutanol or Isobutyl alcohol 3 UN1212 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Isobutyl acetate 3 UN1213 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Isobutyl acrylate, stabilized 3 UN2527 III 3 387, B1, IB3, T2, TP1 150 203 242 60 L 220 L C 25

Isobutyl alcohol, see Isobutanol

Isobutyl aldehyde, see Isobutyraldehyde

Isobutyl formate 3 UN2393 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Isobutyl isobutyrate 3 UN2528 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

+ Isobutyl isocyanate 6.1 UN2486 I 6.1, 31, B9, B14, B30, T20,

TP2, TP13, TP27None 226 244 Forbidden Forbidden D 40

Isobutyl methacrylate, stabilized 3 UN2283 III 3 387, B1, IB3, T2, TP1 150 203 242 60 L 220 L C 25

Isobutyl propionate 3 UN2394 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L B

Isobutylamine 3 UN1214 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 40, 52

Isobutylene see also Petroleum gases, liquefied 2.1 UN1055 2.1 19, T50 306 304314,


Isobutyraldehyde or Isobutyl aldehyde 3 UN2045 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Isobutyric acid 3 UN2529 III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A

Isobutyronitrile 3 UN2284 II 3, 6.1 IB2, T7, TP2, TP13 150 202 243 1 L 60 L E 40

Isobutyryl chloride 3 UN2395 II 3, 8 IB1, T7, TP2 150 202 243 1 L 5 L C40,

53, 58

G

Isocyanates, flammable, toxic, n.o.s. or Isocyanate

solutions, flammable, toxic, n.o.s. flash point less than

23 degrees C

3 UN2478 II 3, 6.1

5, A3, A7, IB2, T11,

TP2, TP13, TP27,

W31

150 202 243 1 L 60 L D 40

III 3, 6.1

5, A3, A7, IB3, T7,

TP1, TP13, TP28,

W31

150 203 242 60 L 220 L A

G

Isocyanates, toxic, flammable, n.o.s. or Isocyanate

solutions, toxic, flammable, n.o.s., flash point not less

than 23 degrees C but not more than 61 degrees C and

boiling point less than 300 degrees C

6.1 UN3080 II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 25, 40

G

Isocyanates, toxic, n.o.s. or Isocyanate solutions,

toxic, n.o.s., flash point more than 61 degrees C and

boiling point less than 300 degrees C

6.1 UN2206 II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L E 25, 40

III 6.1IB3, T7, TP1, TP13,

TP28153 203 241 60 L 220 L E 25, 40

Isocyanatobenzotrifluorides 6.1 UN2285 II 6.1, 3 5, IB2, T7, TP2 153 202 243 5 L 60 L D 25, 40

Isoheptenes 3 UN2287 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Isohexenes 3 UN2288 II 3 IB2, IP8, T11, TP1 150 202 242 5 L 60 L E

Isooctane, see Octanes

Isooctenes 3 UN1216 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Isopentane, see Pentane

Isopentanoic acid, see Corrosive liquids, n.o.s.

Isopentenes 3 UN2371 I 3 T11, TP2 150 201 243 1 L 30 L E

Isophorone diisocyanate 6.1 UN2290 III 6.1 IB3, T4, TP2 153 203 241 60 L 220 L B 40

Isophoronediamine 8 UN2289 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 52

Isoprene, stabilized 3 UN1218 I 3 387, T11, TP2 150 201 243 1 L 30 L D 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Isopropanol or Isopropyl alcohol 3 UN1219 II 3 IB2, T4, TP14b,

150202 242 5 L 60 L B

Isopropenyl acetate 3 UN2403 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Isopropenylbenzene 3 UN2303 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Isopropyl acetate 3 UN1220 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Isopropyl acid phosphate 8 UN1793 III 8 IB2, T4, TP1 154 213 240 25 kg 100 kg A 53, 58

Isopropyl alcohol, see Isopropanol

Isopropyl butyrate 3 UN2405 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Isopropyl chloroacetate 3 UN2947 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Isopropyl chloroformate 6.1 UN2407 I6.1,

3, 8

2, B9, B14, B32, B77,

T20, TP2, TP13,

TP38, TP44


21,

40,

53,

58,

100

Isopropyl 2-chloropropionate 3 UN2934 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Isopropyl isobutyrate 3 UN2406 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

+ Isopropyl isocyanate 6.1 UN2483 I 6.1, 3

1, B9, B14, B30, T20,

TP2, TP13, TP38,

TP44


Isopropyl mercaptan, see Propanethiols

Isopropyl nitrate 3 UN1222 II 3 IB9 150 202 None 5 L 60 L D

Isopropyl phosphoric acid, see Isopropyl acid

phosphate

Isopropyl propionate 3 UN2409 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Isopropylamine 3 UN1221 I 3, 8 T11, TP2 None 201 243 0.5 L 2.5 L E 52

Isopropylbenzene 3 UN1918 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Isopropylcumyl hydroperoxide, with more than 72


Isosorbide dinitrate mixture with not less than 60

percent lactose, mannose, starch or calcium hydrogen

phosphate

4.1 UN2907 II 4.1 IB6, IP2, N85 None 212 None 15 kg 50 kg E 28, 36




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Isosorbide-5-mononitrate 4.1 UN3251 III 4.1 66, 159, IB8 151 223 240 Forbidden Forbidden D

12,

25,

40, 84

Isothiocyanic acid Forbidden

Jet fuel, see Fuel aviation, turbine engine

D Jet perforating guns, charged oil well with detonator 1.1D NA0124 1.1D 55, 56 None 62 None Forbidden Forbidden 325,

154

D Jet perforating guns, charged oil well, with detonator 1.4D NA0494 1.4D 55, 56 None 62 None Forbidden Forbidden 225,

154

Jet perforating guns, charged, oil well, without

detonator1.4D UN0494 1.4D 55, 114 None 62 None Forbidden 300 kg 2

25,

154

Jet perforating guns, charged oil well without detonator 1.1D UN0124 1.1D 55 None 62 None Forbidden Forbidden 325,

154

Jet perforators, see Charges, shaped, etc

Jet tappers, without detonator, see Charges, shaped,

etc

Jet thrust igniters, for rocket motors or Jato, see

Igniters

Jet thrust unit (Jato), see Rocket motors

Kerosene 3 UN1223 III 3 144, B1, IB3, T2, TP2 150 203 242 60 L 220 L A

G Ketones, liquid, n.o.s. 3 UN1224 I 3 T11, TP1, TP8, TP27 None 201 243 1 L 30 L E


TP28150 202 242 5 L 60 L B


TP29150 203 242 60 L 220 L A

Krill meal 4.2 UN3497 II 4.2155, IB6, IP2, T3,

TP33None 212 242 15 kg 50 kg B

25,

88,

128

III 4.2155, IB8, IP3, T1,

TP33None 213 242 25 kg 100 kg A 128

Krypton, compressed 2.2 UN1056 2.2 306, 307 302 None 75 kg 150 kg A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Krypton, refrigerated liquid (cryogenic liquid) 2.2 UN1970 2.2 T75, TP5 320 None None 50 kg 500 kg D

Lacquer base or lacquer chips, nitrocellulose, dry, see

Nitrocellulose, etc. (UN 2557)

Lacquer base or lacquer chips, plastic, wet with alcohol

or solvent, see Nitrocellulose (UN2059, UN2555,

UN2556, UN2557) or Paint etc.(UN1263)

Lead acetate 6.1 UN1616 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Lead arsenates 6.1 UN1617 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Lead arsenites 6.1 UN1618 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Lead azide (dry) Forbidden

Lead azide, wetted with not less than 20 percent water

or mixture of alcohol and water, by mass1.1A UN0129 1.1A 111, 117 None 62 None Forbidden Forbidden 5 25

G Lead compounds, soluble, n.o.s 6.1 UN2291 III 6.1138, IB8, IP3, T1,

TP33153 213 240 100 kg 200 kg A

Lead cyanide 6.1 UN1620 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 52

Lead dioxide 5.1 UN1872 III 5.1A1, IB8, IP3, T1,

TP33152 213 240 25 kg 100 kg A

Lead dross, see Lead sulfate, with more than 3 percent

free acid

Lead nitrate 5.1 UN1469 II5.1,

6.1

IB8, IP2, IP4, T3,

TP33152 212 242 5 kg 25 kg A

Lead nitroresorcinate (dry) Forbidden

Lead perchlorate, solid 5.1 UN1470 II5.1,

6.1IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58

Lead perchlorate, solution 5.1 UN3408 II5.1,

6.1IB2, T4, TP1 152 202 243 1 L 5 L A 56, 58

III5.1,

6.1IB2, T4, TP1 152 203 242 2.5 L 30 L A 56, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Lead peroxide, see Lead dioxide

Lead phosphite, dibasic 4.1 UN2989 II 4.1IB8, IP2, IP4, T3,

TP33None 212 240 15 kg 50 kg B 34

III 4.1 IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg B 34

Lead picrate (dry) Forbidden

Lead styphnate (dry) Forbidden

Lead styphnate, wetted or Lead trinitroresorcinate,

wetted with not less than 20 percent water or mixture

of alcohol and water, by mass


Lead sulfate with more than 3 percent free acid 8 UN1794 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A 53, 58

Lead trinitroresorcinate, see Lead styphnate, etc

Life-saving appliances, not self inflating containing

dangerous goods as equipment9 UN3072 None 182 None 219 None No limit No limit A 122

Life-saving appliances, self inflating 9 UN2990 None 338 None 219 None No limit No limit A 122

Lighters containing flammable gas 2.1 UN1057 2.1 168 ##### ##### None 1 kg 15 kg B 40

Lighters, new or empty, purged of all residual fuel and

vapors 168

Lighters, non-pressurized, containing flammable liquid, 3 NA1057 II 3 168 21 None None Forbidden Forbidden B 40

Lighter refills containing flammable gas not exceeding

4 fluid ounces (7.22 cubic inches) and 65 grams of

flammable gas

2.1 UN1057 2.1 169 306 306 None 1 kg 15 kg B 40

Lighter replacement cartridges containing liquefied

petroleum gases see Lighter refills containing

flammable gas. Etc.

Lighters, fuse 1.4S UN0131 1.4S None 62 None 25 kg 100 kg 1 25

Lime, unslaked, see Calcium oxide

G Liquefied gas, flammable, n.o.s. 2.1 UN3161 2.1 T50 306 304314,





tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Liquefied gas, n.o.s. 2.2 UN3163 2.2 T50 306 304314,

31575 kg 150 kg A

G Liquefied gas, oxidizing, n.o.s. 2.2 UN3157 2.2,

5.1A14 306 304

314,

31575 kg 150 kg D

G ILiquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard

Zone A2.3 UN3308 2.3, 8 1 None 192 245 Forbidden Forbidden D 40


Zone B2.3 UN3308 2.3, 8 2, B9, B14 None 304

314,



Zone C2.3 UN3308 2.3, 8 3, B14 None 304

314,



Zone D2.3 UN3308 2.3, 8 4 None 304

314,


G ILiquefied gas, toxic, flammable, corrosive, n.o.s.


2.3,

2.1, 81 None 192 245 Forbidden Forbidden D 17, 40

G ILiquefied gas toxic, flammable, corrosive, n.o.s.


2.3,

2.1, 82, B9, B14 None 304

314,




2.3,

2.1, 83, B14 None 304

314,




2.3,

2.1, 84 None 304

314,


GLiquefied gas, toxic, flammable, n.o.s. Inhalation

Hazard Zone A2.3 UN3160

2.3,



Hazard Zone B2.3 UN3160

2.3,

2.12, B9, B14 None 304

314,




2.3,

2.13, B14 None 304

314,




2.3,

2.14 None 304

314,


G Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone A 2.3 UN3162 2.3 1 None 192 245 Forbidden Forbidden D 40

G Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone B 2.3 UN3162 2.3 2, B9, B14 None 304314,





tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone C 2.3 UN3162 2.3 3, B14 None 304314,


G Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone D 2.3 UN3162 2.3 4 None 304314,


G ILiquefied gas, toxic, oxidizing, corrosive, n.o.s.


2.3,


40,

89, 90



2.3,

5.1, 82, B9, B14 None 304

314,


40,

89, 90



2.3,

5.1, 83, B14 None 304

314,


40,

89, 90



2.3,

5.1, 84 None 304

314,


40,

89, 90

GLiquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard

Zone A2.3 UN3307

2.3,



Zone B2.3 UN3307

2.3,

5.12, B9, B14 None 304

314,



Zone C2.3 UN3307

2.3,

5.13, B14 None 304

314,



Zone D2.3 UN3307

2.3,

5.14 None 304

314,


Liquefied gases, non-flammable charged with

nitrogen, carbon dioxide or air2.2 UN1058 2.2 306 304 None 75 kg 150 kg A

Liquefied hydrocarbon gas, see Hydrocarbon gas

mixture, liquefied, n.o.s.

Liquefied natural gas, see Methane, etc. (UN 1972)

Liquefied petroleum gas see Petroleum gases,

liquefied

Lithium 4.3 UN1415 I 4.3

A7, A19, IB4, IP1,

N45, T9, TP7, TP33,

W31

151 211 244 Forbidden 15 kg D

13,

52,

148

Lithium acetylide ethylenediamine complex, see Water

reactive solid etc




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Lithium aluminum hydride 4.3 UN1410 I 4.3 A19, W31 None 211 242 Forbidden 15 kg E

13,

52,

148

Lithium aluminum hydride, ethereal 4.3 UN1411 I 4.3, 3 A2, A11, N34 None 201 244 Forbidden 1 L D

13,

40,

148

Lithium batteries installed in cargo transport unit

lithium ion batteries or lithium metal batteries9 UN3536 389 Forbidden Forbidden A

Lithium borohydride 4.3 UN1413 I 4.3 A19, N40, W31 None 211 242 Forbidden 15 kg E

13,

52,

148

Lithium ferrosilicon 4.3 UN2830 II 4.3A19, IB7, IP2, IP21,

T3, TP33, W31, W40151 212 241 15 kg 50 kg E

13,

40,

85,

103,

148

Lithium hydride 4.3 UN1414 I 4.3 A19, N40, W31 None 211 242 Forbidden 15 kg E

13,

52,

148

Lithium hydride, fused solid 4.3 UN2805 II 4.3A8, A19, A20, IB4,

T3, TP33, W31, W40151 212 241 15 kg 50 kg E

13,

52,

148

Lithium hydroxide 8 UN2680 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A 52

Lithium hydroxide, solution 8 UN2679 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A29,

52.

III 8 IB3, T4, TP2 154 203 241 5 L 60 L A

29,

52,

96.




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Lithium hypochlorite, dry or Lithium hypochlorite

mixture5.1 UN1471 II 5.1

A9, IB8, IP2, IP4,

N34, T3, TP33152 212 240 5 kg 25 kg A

4, 25,

52,

56,

58,

69,

106,

116

III 5.1IB8, IP3, N34, T1,

TP33152 213 240 25 kg 100 kg A

4, 25,

52,

56,

58,

69,

106,

116

Lithium in cartridges, see Lithium

Lithium ion batteries including lithium ion polymer

batteries9 UN3480 9 388, 422, A54, A100 185 185 185 Forbidden 35 kg A

Lithium ion batteries contained in equipment including

lithium ion polymer batteries9 UN3481 9 181, 388, 422, A54 185 185 185 5 kg 35 kg A

Lithium ion batteries packed with equipment including

lithium ion polymer batteries9 UN3481 9 181, 388, 422, A54 185 185 185 5 kg 35 kg A

Lithium metal batteries including lithium alloy batteries 9 UN3090 9 388, 422, A54 185 185 185 Forbidden 35 kg A

Lithium metal batteries contained in equipment

including lithium alloy batteries9 UN3091 9

181, 388, 422, A54,

A101185 185 185 5 kg 35 kg A

Lithium metal batteries packed with equipment

including lithium alloy batteries9 UN3091 9 181, 388, 422, A54 185 185 185 5 kg 35 kg A

Lithium nitrate 5.1 UN2722 III 5.1A1, IB8, IP3, T1,

TP33152 213 240 25 kg 100 kg A

Lithium nitride 4.3 UN2806 I 4.3A19, IB4, IP1, N40,

W31None 211 242 Forbidden 15 kg E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Lithium peroxide 5.1 UN1472 II 5.1A9, IB6, IP2, N34,

T3, TP33, W100152 212 None 5 kg 25 kg C

13,

52,

66,

75,

148

Lithium silicon 4.3 UN1417 II 4.3

A19, A20, IB7, IP2,

IP21, T3, TP33,

W31, W40

151 212 241 15 kg 50 kg A

13,

85,

103,

148

LNG, see Methane etc. (UN 1972)

London purple 6.1 UN1621 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

LPG, see Petroleum gases, liquefied

Lye, see Sodium hydroxide, solutions

Magnesium aluminum phosphide 4.3 UN1419 I4.3,

6.1A19, N34, N40, W31 None 211 242 Forbidden 15 kg E

13,

40,

52,

85,

148

+ Magnesium arsenate 6.1 UN1622 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Magnesium bisulfite solution, see Bisulfites, aqueous

solutions, n.o.s.

Magnesium bromate 5.1 UN1473 II 5.1A1, IB8, IP2, IP4, T3,

TP33152 212 242 5 kg 25 kg A 56, 58

Magnesium chlorate 5.1 UN2723 II 5.1IB8, IP2, IP4, T3,

TP33152 212 242 5 kg 25 kg A 56, 58

Magnesium diamide 4.2 UN2004 II 4.2A8, A19, A20, IB6,

T3, TP33, W31None 212 241 15 kg 50 kg C

13,

148

Magnesium dross, wet or hot Forbidden

Magnesium fluorosilicate 6.1 UN2853 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Magnesium granules, coated, particle size not less

than 149 microns4.3 UN2950 III 4.3

A1, A19, IB8, IP4,

T1, TP33, W100151 213 240 25 kg 100 kg A

13,

52,

148

Magnesium hydride 4.3 UN2010 I 4.3 A19, N40, W31 None 211 242 Forbidden 15 kg E

13,

52,

148

Magnesium or Magnesium alloys with more than 50

percent magnesium in pellets, turnings or ribbons4.1 UN1869 III 4.1

A1, B134, IB8, IP21,

T1, TP33, W100151 213 240 25 kg 100 kg A

13,

39,

52,

53,

74,

101,

147,

148

Magnesium nitrate 5.1 UN1474 III 5.1332, A1, B120, IB8,

IP3, T1, TP33152 213 240 25 kg 100 kg A

Magnesium perchlorate 5.1 UN1475 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58

Magnesium peroxide 5.1 UN1476 II 5.1IB6, IP2, T3, TP33,

W100152 212 242 5 kg 25 kg C

13,

52,

66,

75,

148

Magnesium phosphide 4.3 UN2011 I4.3,

6.1A19, N40, W31 None 211 None Forbidden 15 kg E

13,

40,

52,

85,

148

Magnesium, powder or Magnesium alloys, powder 4.3 UN1418 I4.3,

4.2A19, B56, W31 None 211 244 Forbidden 15 kg A

13,

39,

52,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II4.3,

4.2

A19, B56, IB5, IP2,

T3, TP33, W31, W40None 212 241 15 kg 50 kg A

13,

39,

52,

148

III4.3,

4.2

A19, B56, IB8, IP4,

T1, TP33, W31None 213 241 25 kg 100 kg A

13,

39,

52,

148

Magnesium scrap, see Magnesium, etc. (UN 1869)

Magnesium silicide 4.3 UN2624 II 4.3

A19, A20, IB7, IP2,

IP21, T3, TP33,

W31, W40

151 212 241 15 kg 50 kg B

13,

85,

103,

148

Magnetized material, see §173.21

Maleic anhydride 8 UN2215 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A

53,

58,

95,

102

Maleic anhydride, molten 8 UN2215 III 8 T4, TP3 None 213 240 Forbidden Forbidden A

53,

58,

95,

102

Malononitrile 6.1 UN2647 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 12, 25

Mancozeb (manganese ethylenebisdithiocarbamate

complex with zinc) see Maneb

Maneb or Maneb preparations with not less than 60

percent maneb4.2 UN2210 III

4.2,

4.3

57, A1, A19, IB6, T1,

TP33, W100None 213 242 25 kg 100 kg A

13,

34,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Maneb stabilized or Maneb preparations, stabilized

against self-heating4.3 UN2968 III 4.3

54, A1, A19, IB8,

IP4, T1, TP33, W100151 213 242 25 kg 100 kg B

13,

34,

52,

148

Manganese nitrate 5.1 UN2724 III 5.1A1, IB8, IP3, T1,

TP33152 213 240 25 kg 100 kg A

Manganese resinate 4.1 UN1330 III 4.1 A1, IB6, T1, TP33 151 213 240 25 kg 100 kg A

Mannitan tetranitrate Forbidden

Mannitol hexanitrate (dry) Forbidden

Mannitol hexanitrate, wetted or Nitromannite, wetted

with not less than 40 percent water, or mixture of

alcohol and water, by mass

1.1D UN0133 1.1D 121 None 62 None Forbidden Forbidden 4 25

Marine pollutants, liquid or solid, n.o.s., see

Environmentally hazardous substances, liquid or solid,

n.o.s.

Matches, block, see Matches, 'strike anywhere'

Matches, fusee 4.1 UN2254 III 4.1 186 186 None Forbidden Forbidden A

Matches, safety (book, card or strike on box) 4.1 UN1944 III 4.1 186 186 None 25 kg 100 kg A

Matches, strike anywhere 4.1 UN1331 III 4.1 186 186 None Forbidden Forbidden B

Matches, wax, Vesta 4.1 UN1945 III 4.1 186 186 None 25 kg 100 kg B

Matting acid, see Sulfuric acid

Medicine, liquid, flammable, toxic, n.o.s 3 UN3248 II 3, 6.1 IB2 150 202 243 1 L 60 L B 40

III 3, 6.1 IB3 150 203 242 60 L 220 L A

Medicine, liquid, toxic, n.o.s 6.1 UN1851 II 6.1 153 202 243 5 L 60 L C 40

III 6.1 153 203 241 60 L 220 L C 40

Medicine, solid, toxic, n.o.s 6.1 UN3249 II 6.1 T3, TP33 153 212 242 25 kg 100 kg C 40

III 6.1 T3, TP33 153 213 240 100 kg 200 kg C 40

Memtetrahydrophthalic anhydride, see Corrosive

liquids, n.o.s.

Mercaptans, liquid, flammable, n.o.s. or Mercaptan

mixture, liquid, flammable, n.o.s3 UN3336 I 3 T11, TP2 150 201 243 1 L 30 L E

95,

102




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes


TP28150 202 242 5 L 60 L B

95,

102

III 3B1, B52, IB3, T4,

TP1, TP29150 203 241 60 L 220 L B

95,

102

Mercaptans, liquid, flammable, toxic, n.o.s. or

Mercaptan mixtures, liquid, flammable, toxic, n.o.s3 UN1228 II 3, 6.1 IB2, T11, TP2, TP27 None 202 243 Forbidden 60 L B

40,

95,

102

III 3, 6.1B1, IB3, T7, TP1,

TP28150 203 242 5 L 220 L A

40,

95,

102

Mercaptans, liquid, toxic, flammable, n.o.s. or

Mercaptan mixtures, liquid, toxic, flammable, n.o.s.,

flash point not less than 23 degrees C

6.1 UN3071 II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L C

40,

102,

121

5-Mercaptotetrazol-1-acetic acid 1.4C UN0448 1.4C None 62 None Forbidden 75 kg 2 25

Mercuric arsenate 6.1 UN1623 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Mercuric chloride 6.1 UN1624 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Mercuric compounds, see Mercury compounds, etc

Mercuric nitrate 6.1 UN1625 II 6.1IB8, IP2, IP4, N73,

T3, TP33153 212 242 25 kg 100 kg A

+ Mercuric potassium cyanide 6.1 UN1626 I 6.1IB7, IP1, N74, N75,

T6, TP33, W31None 211 242 5 kg 50 kg A 52

Mercuric sulfocyanate, see Mercury thiocyanate

Mercurol, see Mercury nucleate

Mercurous azide Forbidden

Mercurous compounds, see Mercury compounds, etc

Mercurous nitrate 6.1 UN1627 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

A W Mercury 8 UN2809 III 8, 6.1 365 164 164 240 35 kg 35 kg B 40, 97




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Mercury acetate 6.1 UN1629 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Mercury acetylide Forbidden

Mercury ammonium chloride 6.1 UN1630 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Mercury based pesticides, liquid, flammable, toxic,

flash point less than 23 degrees C3 UN2778 I 3, 6.1

T14, TP2, TP13,


II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40

Mercury based pesticides, liquid, toxic 6.1 UN3012 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40

Mercury based pesticides, liquid, toxic, flammable,

flash point not less than 23 degrees C6.1 UN3011 I 6.1, 3

T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1, 3 IB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40

Mercury based pesticides, solid, toxic 6.1 UN2777 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Mercury benzoate 6.1 UN1631 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Mercury bromides 6.1 UN1634 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

G Mercury compound, liquid, n.o.s 6.1 UN2024 I 6.1 None 201 243 1 L 30 L B 40

II 6.1 IB2 153 202 243 5 L 60 L B 40

III 6.1 IB3 153 203 241 60 L 220 L B 40

G Mercury compound, solid, n.o.s 6.1 UN2025 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A


A W Mercury contained in manufactured articles 8 UN3506 8, 6.1 A191 164 None None No limit No limit B 40, 97

Mercury cyanide 6.1 UN1636 II 6.1IB8, IP2, IP4, N74,

N75, T3, TP33153 212 242 25 kg 100 kg A 52

Mercury fulminate, wetted with not less than 20

percent water, or mixture of alcohol and water, by

mass


Mercury gluconate 6.1 UN1637 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Mercury iodide 6.1 UN1638 II 6.1IB2, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Mercury iodide aquabasic ammonobasic (Iodide of

Millon's base)Forbidden

Mercury nitride Forbidden

Mercury nucleate 6.1 UN1639 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Mercury oleate 6.1 UN1640 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Mercury oxide 6.1 UN1641 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Mercury oxycyanide Forbidden

Mercury oxycyanide, desensitized 6.1 UN1642 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 52, 91

Mercury potassium iodide 6.1 UN1643 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Mercury salicylate 6.1 UN1644 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

+ Mercury sulfates 6.1 UN1645 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Mercury thiocyanate 6.1 UN1646 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Mesityl oxide 3 UN1229 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

G Metal carbonyls, liquid, n.o.s. 6.1 UN3281 I 6.15, T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A 40

G Metal carbonyls, solid, n.o.s. 6.1 UN3466 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg D 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B 40

III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg B 40

G Metal catalyst, dry 4.2 UN2881 I 4.2N34, T21, TP7, TP33,

W31None 187 None Forbidden Forbidden C

13,

147,

148

II 4.2IB6, IP2, N34, T3,

TP33, W31None 187 242 Forbidden 50 kg C

13,

147,

148

III 4.2B135, IB8, IP21,

N34, T1, TP33, W31None 187 241 25 kg 100 kg C

13,

147,

148

G Metal catalyst, wetted with a visible excess of liquid 4.2 UN1378 II 4.2A2, A8, IB1, N34, T3,

TP33, W31, W40None 212 None Forbidden 50 kg C

Metal hydrides, flammable, n.o.s 4.1 UN3182 II 4.1A1, IB4, T3, TP33,

W31, W40151 212 240 15 kg 50 kg E

III 4.1A1, IB4, T1, TP33,

W31151 213 240 25 kg 100 kg E

G Metal hydrides, water reactive, n.o.s 4.3 UN1409 I 4.3 A19, N34, N40, W31 None 211 242 Forbidden 15 kg D

13,

52,

148

II 4.3A19, IB4, N34, N40,

T3, TP33, W31, W40151 212 242 15 kg 50 kg D

13,

52,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Metal powder, self-heating, n.o.s 4.2 UN3189 II 4.2IB6, IP2, T3, TP33,

W31None 212 241 15 kg 50 kg C

13,

148

III 4.2B135, IB8, IP4, T1,

TP33, W31None 213 241 25 kg 100 kg C

13,

148

Metal powders, flammable, n.o.s 4.1 UN3089 II 4.1IB8, IP2, IP4, T3,

TP33, W100151 212 240 15 kg 50 kg B

13,

74,

147,

148

III 4.1IB8, IP2, IP4, T1,

TP33, W100151 213 240 25 kg 100 kg B

13,

74,

147,

148

Metal salts of methyl nitramine (dry) Forbidden

G Metal salts of organic compounds, flammable, n.o.s 4.1 UN3181 II 4.1A1, IB8, IP2, IP4, T3,

TP33, W31151 212 240 15 kg 50 kg B 40

III 4.1A1, IB8, IP3, T1,

TP33, W31151 213 240 25 kg 100 kg B 40

III 4.1A1, IB8, IP3, T1,

TP33151 213 240 25 kg 100 kg B 40

Metaldehyde 4.1 UN1332 III 4.1A1, IB8, IP3, T1,

TP33151 213 240 25 kg 100 kg A

G Metallic substance, water-reactive, n.o.s 4.3 UN3208 I 4.3 A7, IB4, W31 None 211 242 Forbidden 15 kg E

13,

40,

148

II 4.3A7, IB7, IP2, IP21,

T3, TP33, W31, W40151 212 242 15 kg 50 kg E

13,

40,

148

III 4.3A7, IB8, IP21, T1,

TP33, W31151 213 241 25 kg 100 kg E

13,

40,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Metallic substance, water-reactive, self-heating, n.o.s 4.3 UN3209 I4.3,

4.2A7, W31 None 211 242 Forbidden 15 kg E

13,

40,

148

II4.3,

4.2

A7, IB5, IP2, T3,

TP33, W31, W40None 212 242 15 kg 50 kg E

13,

40,

148

III4.3,

4.2

A7, IB8, IP4, T1,

TP33, W31None 213 242 25 kg 100 kg E

13,

40,

148

Methacrylaldehyde, stabilized 3 UN2396 II 3, 6.145, 387, IB2, T7,

TP1, TP13150 202 243 1 L 60 L D 25, 40

Methacrylic acid, stabilized 8 UN2531 II 841, 387, IB2, T7,

TP1, TP18, TP30154 202 242 1 L 30 L C

25,

40,

53, 58

+ Methacrylonitrile, stabilized 6.1 UN3079 I 6.1, 3

2, 387, B9, B14, B32,

T20, TP2, TP13,

TP38, TP45


25, 40

Methallyl alcohol 3 UN2614 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Methane and hydrogen, mixtures, see Hydrogen and

methane, mixtures, etc

Methane, compressed or Natural gas, compressed

(with high methane content)2.1 UN1971 2.1 306 302 302 Forbidden 150 kg E 40

Methane, refrigerated liquid (cryogenic liquid) or

Natural gas, refrigerated liquid (cryogenic liquid), with

high methane content)

2.1 UN1972 2.1 T75, TP5 None None 318 Forbidden Forbidden D 40

Methanesulfonyl chloride 6.1 UN3246 I 6.1, 8

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP45


53, 58

+ I Methanol 3 UN1230 II 3, 6.1 IB2, T7, TP2 150 202 242 1 L 60 L B 40

D Methanol 3 UN1230 II 3 IB2, T7, TP2 150 202 242 1 L 60 L B 40

Methazoic acid Forbidden

4-Methoxy-4-methylpentan-2-one 3 UN2293 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

1-Methoxy-2-propanol 3 UN3092 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

+ Methoxymethyl isocyanate 6.1 UN2605 I 6.1, 3

1, B9, B14, B30, T20,

TP2, TP13, TP38,

TP44


Methyl acetate 3 UN1231 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Methyl acetylene and propadiene mixtures, stabilized 2.1 UN1060 2.1 387, N88, T50 306 304314,


Methyl acrylate, stabilized 3 UN1919 II 3387, IB2, T4, TP1,

TP13150 202 242 5 L 60 L C 25

Methyl alcohol, see Methanol

Methyl allyl chloride 3 UN2554 II 3 IB2, T4, TP1, TP13 150 202 242 5 L 60 L E

Methyl amyl ketone, see Amyl methyl ketone

Methyl bromide 2.3 UN1062 2.3 3, B14, N86, T50 None 193314,


Methyl bromide and chloropicrin mixtures with more

than 2 percent chloropicrin, see Chloropicrin and

methyl bromide mixtures

Methyl bromide and chloropicrin mixtures with not

more than 2 percent chloropicrin, see Methyl bromide

Methyl bromide and ethylene dibromide mixtures,

liquid6.1 UN1647 I 6.1

2, B9, B14, B32, N65,

T20, TP2, TP13,

TP38, TP44


Methyl bromoacetate 6.1 UN2643 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L D 40

2-Methylbutanal 3 UN3371 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

2-Methyl-1-butene 3 UN2459 I 3 T11, TP2 None 201 243 1 L 30 L E

2-Methyl-2-butene 3 UN2460 II 3 IB2, IP8, T7, TP1 None 202 242 5 L 60 L E

3-Methyl-1-butene 3 UN2561 I 3 T11, TP2 None 201 243 1 L 30 L E

Methyl tert-butyl ether 3 UN2398 II 3 IB2, T7, TP1 150 202 242 5 L 60 L E

Methyl butyrate 3 UN1237 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Methyl chloride or Refrigerant gas R 40 2.1 UN1063 2.1 N86, T50 306 304314,

3155 kg 100 kg D 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Methyl chloride and chloropicrin mixtures, see

Chloropicrin and methyl chloride mixtures

Methyl chloride and methylene chloride mixtures 2.1 UN1912 2.1 N86, T50 306 304314,


Methyl chloroacetate 6.1 UN2295 I 6.1, 3 T14, TP2, TP13 None 201 243 1 L 30 L D

Methyl chlorocarbonate, see Methyl chloroformate

Methyl chloroform, see 1,1,1-Trichloroethane

Methyl chloroformate 6.1 UN1238 I6.1,

3, 8

1, B9, B14, B30, N34,

T22, TP2, TP13,

TP38, TP44


21,

40,

53,

58,

100

Methyl chloromethyl ether 6.1 UN1239 I 6.1, 3

1, B9, B14, B30, T22,

TP2, TP13, TP38,

TP44


Methyl 2-chloropropionate 3 UN2933 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Methyl dichloroacetate 6.1 UN2299 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Methyl ethyl ether, see Ethyl methyl ether

Methyl ethyl ketone, see Ethyl methyl ketone

Methyl ethyl ketone peroxide, in solution with more

than 9 percent by mass active oxygenForbidden

2-Methyl-5-ethylpyridine 6.1 UN2300 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Methyl fluoride, or Refrigerant gas R 41 2.1 UN2454 2.1 306 304314,


Methyl formate 3 UN1243 I 3 T11, TP2 150 201 243 1 L 30 L E

2-Methyl-2-heptanethiol 6.1 UN3023 I 6.1, 3

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP45


102

Methyl iodide 6.1 UN2644 I 6.1

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP45


25, 40

Methyl isobutyl carbinol 3 UN2053 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Methyl isobutyl ketone 3 UN1245 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Methyl isobutyl ketone peroxide, in solution with more

than 9 percent by mass active oxygenForbidden

Methyl isocyanate 6.1 UN2480 I 6.1, 3

1, B9, B14, B30, T22,

TP2, TP13, TP38,

TP44


Methyl isopropenyl ketone, stabilized 3 UN1246 II 3 387, IB2, T4, TP1 150 202 242 5 L 60 L C 25

Methyl isothiocyanate 6.1 UN2477 I 6.1, 3

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP45


Methyl isovalerate 3 UN2400 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Methyl magnesium bromide, in ethyl ether 4.3 UN1928 I 4.3, 3 None 201 243 Forbidden 1 L D13,

148

Methyl mercaptan 2.3 UN1064 2.3,

2.1

3, B7, B9, B14, N89,

T50None 304

314,


Methyl mercaptopropionaldehyde, see 4-Thiapentanal

Methyl methacrylate monomer, stabilized 3 UN1247 II 3 387, IB2, T4, TP1 150 202 242 5 L 60 L C 25, 40

Methyl nitramine (dry) Forbidden

Methyl nitrate Forbidden

Methyl nitrite Forbidden

Methyl norbornene dicarboxylic anhydride, see

Corrosive liquids, n.o.s.

Methyl orthosilicate 6.1 UN2606 I 6.1, 3

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP45


D Methyl phosphonic dichloride 6.1 NA9206 I 6.1, 8

2, B9, B14, B32, N34,

N43, T20, TP4, TP13,

TP38, TP45

None 227 244 Forbidden Forbidden C




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Methyl phosphonothioic dichloride, anhydrous, see

Corrosive liquid, n.o.s.

D Methyl phosphonous dichloride, pyrophoric liquid 6.1 NA2845 I6.1,

4.2

2, B9, B14, B16, B32,

T20, TP4, TP12,

TP13, TP38, TP45


Methyl picric acid (heavy metal salts of) Forbidden

Methyl propionate 3 UN1248 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Methyl propyl ether 3 UN2612 II 3 IB2, IP8, T7, TP2 150 202 242 5 L 60 L E 40

Methyl propyl ketone 3 UN1249 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Methyl sulfate, see Dimethyl sulfate

Methyl sulfide, see Dimethyl sulfide

Methyl trichloroacetate 6.1 UN2533 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Methyl trimethylol methane trinitrate Forbidden

Methyl vinyl ketone, stabilized 6.1 UN1251 I6.1,

3, 8

1, 387, B9, B14, B30,

T22, TP2, TP13,

TP38, TP44


21,

25,

40,

100

Methylal 3 UN1234 II 3 IB2, IP8, T7, TP2 None 202 242 5 L 60 L E

Methylamine, anhydrous 2.1 UN1061 2.1 N87, T50 306 304314,


Methylamine, aqueous solution 3 UN1235 II 3, 8 B1, IB2, T7, TP1 150 202 243 1 L 5 L E52,

135.

Methylamine dinitramine and dry salts thereof Forbidden

Methylamine nitroform Forbidden

Methylamine perchlorate (dry) Forbidden

Methylamyl acetate 3 UN1233 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

N-Methylaniline 6.1 UN2294 III 6.1 IB3, T4, TP2 153 203 241 60 L 220 L A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

alpha-Methylbenzyl alcohol, liquid 6.1 UN2937 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

alpha-Methylbenzyl alcohol, solid 6.1 UN3438 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

3-Methylbutan-2-one 3 UN2397 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

N-Methylbutylamine 3 UN2945 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 40, 52

Methylchlorosilane 2.3 UN2534 2.3,

2.1, 82, B9, B14, N34 None 226

314,


Methylcyclohexane 3 UN2296 II 3 B1, IB2, T4, TP2 150 202 242 5 L 60 L B

Methylcyclohexanols, flammable 3 UN2617 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Methylcyclohexanone 3 UN2297 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Methylcyclopentane 3 UN2298 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

D Methyldichloroarsine 6.1 NA1556 I 6.12, T20, TP4, TP13,

TP38, TP45None 192 None Forbidden Forbidden D 40

Methyldichlorosilane 4.3 UN1242 I4.3,

8, 3

A2, A7, B6, B77,

N34, T14, TP2, TP7,

TP13, W31

None 201 243 Forbidden 1 L D

21,

40,

49,

53,

58,

100

Methylene chloride, see Dichloromethane

Methylene glycol dinitrate Forbidden

2-Methylfuran 3 UN2301 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E

a-Methylglucoside tetranitrate Forbidden

a-Methylglycerol trinitrate Forbidden

5-Methylhexan-2-one 3 UN2302 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Methylhydrazine 6.1 UN1244 I6.1,

3, 8

1, B7, B9, B14, B30,

B77, N34, T22, TP2,

TP13, TP38, TP44


21,

40,

49, 52

and

100

4-Methylmorpholine or n-methylmorpholine 3 UN2535 II 3, 8 B6, IB2, T7, TP1 150 202 243 1 L 5 L B 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Methylpentadienes 3 UN2461 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E

2-Methylpentan-2-ol 3 UN2560 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Methylpentanes, see Hexanes

Methylphenyldichlorosilane 8 UN2437 II 8 T10, TP2, TP7, TP13 None 206 242 Forbidden 30 L C40,

53, 58

1-Methylpiperidine 3 UN2399 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 52

Methyltetrahydrofuran 3 UN2536 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Methyltrichlorosilane 3 UN1250 II 3, 8A7, B6, B77, N34,

T10, TP2, TP7, TP13None 206 243 Forbidden 5 L B

40,

53, 58

alpha-Methylvaleraldehyde 3 UN2367 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B

Mine rescue equipment containing carbon dioxide, see

Carbon dioxide

Mines with bursting charge 1.1F UN0136 1.1F 62 None Forbidden Forbidden 3 25

Mines with bursting charge 1.1D UN0137 1.1D 62 62 Forbidden Forbidden 3 25

Mines with bursting charge 1.2D UN0138 1.2D 62 62 Forbidden Forbidden 3 25

Mines with bursting charge 1.2F UN0294 1.2F 62 None Forbidden Forbidden 3 25

Mixed acid, see Nitrating acid, mixtures etc

Mobility aids, see Battery powered equipment or

Battery powered vehicle'

D Model rocket motor 1.4C NA0276 1.4C 51 None 62 None Forbidden 75 kg 2 25

D Model rocket motor 1.4S NA0323 1.4S 51 None 62 None 25 kg 100 kg 1 25

Molybdenum pentachloride 8 UN2508 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg C40,

53, 58

Monochloroacetone (unstabilized) Forbidden

Monochloroethylene, see Vinyl chloride, stabilized

Monoethanolamine, see Ethanolamine, solutions

Monoethylamine, see Ethylamine

Morpholine 8 UN2054 I 8, 3 T10, TP2 None 201 243 0.5 L 2.5 L A

Morpholine, aqueous, mixture, see Corrosive liquids,

n.o.s.




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Motor fuel anti-knock compounds see Motor fuel anti-

knock mixtures

+ Motor fuel anti-knock mixture, flammable 6.1 UN3483 I 6.1, 3 14, T14, TP2, TP13 None 201 244 Forbidden Forbidden D 25, 40

+ Motor fuel anti-knock mixtures 6.1 UN1649 I 6.114, B9, B90, T14,

TP2, TP13None 201 244 Forbidden 30 L D 25, 40

Motor spirit, see Gasoline

Muriatic acid, see Hydrochloric acid

Musk xylene, see 5-tert-Butyl-2,4,6-trinitro-m-xylene

Naphtha see Petroleum distillates n.o.s.

Naphthalene, crude or Naphthalene, refined 4.1 UN1334 III 4.1A1, B120,IB8, IP3,

T1, TP33151 213 240 25 kg 100 kg A

Naphthalene diozonide Forbidden

beta-Naphthylamine, solid 6.1 UN1650 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

beta-Naphthylamine solution 6.1 UN3411 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

III 6.1 IB2, T7, TP2 153 203 241 60 L 220 L A

alpha-Naphthylamine 6.1 UN2077 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Naphthalene, molten 4.1 UN2304 III 4.1 IB1, T1, TP3 151 213 241 Forbidden Forbidden C

Naphthylamineperchlorate Forbidden

Naphthylthiourea 6.1 UN1651 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Naphthylurea 6.1 UN1652 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Natural gases (with high methane content), see

Methane, etc. (UN 1971, UN 1972)

Neohexane, see Hexanes

Neon, compressed 2.2 UN1065 2.2306,

307302 None 75 kg 150 kg A

Neon, refrigerated liquid (cryogenic liquid) 2.2 UN1913 2.2 T75, TP5 320 316 None 50 kg 500 kg D




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

New explosive or explosive device, see §§173.51 and

173.56

Nickel carbonyl 6.1 UN1259 I 6.1, 3 1 None 198 None Forbidden Forbidden D 40, 78

Nickel cyanide 6.1 UN1653 II 6.1IB8, IP2, IP4, N74,

N75, T3, TP33153 212 242 25 kg 100 kg A 52

Nickel nitrate 5.1 UN2725 III 5.1A1, IB8, IP3, T1,

TP33152 213 240 25 kg 100 kg A

Nickel nitrite 5.1 UN2726 III 5.1A1, IB8, IP3, T1,

TP33152 213 240 25 kg 100 kg A 56, 58

Nickel picrate Forbidden

Nicotine 6.1 UN1654 II 6.1 IB2 153 202 243 5 L 60 L A

GNicotine compounds, liquid, n.o.s. or Nicotine

preparations, liquid, n.o.s6.1 UN3144 I 6.1 A4 None 201 243 1 L 30 L B 40

II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L B 40

GNicotine compounds, solid, n.o.s. or Nicotine

preparations, solid, n.o.s6.1 UN1655 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A


Nicotine compounds, solid, n.o.s. or Nicotine

preparations, solid, n.o.s.6.1 UN1655 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A


Nicotine hydrochloride liquid or solution 6.1 UN1656 II 6.1 IB2 153 202 243 5 L 60 L A

III 6.1 IB3 153 203 241 60 L 220 L A

Nicotine hydrochloride, solid 6.1 UN3444 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Nicotine salicylate 6.1 UN1657 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Nicotine sulfate solution 6.1 UN1658 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

III 6.1 IB3, T7, TP2 153 203 241 60 L 220 L A

Nicotine sulphate, solid 6.1 UN3445 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Nicotine tartrate 6.1 UN1659 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Nitrated paper (unstable) Forbidden

Nitrates, inorganic, aqueous solution, n.o.s. 5.1 UN3218 II 5.1 58, IB2, T4, TP1 152 202 242 1 L 5 L B

56,

58,

133

III 5.1 58, IB2, T4, TP1 152 203 241 2.5 L 30 L B

56,

58,

133

Nitrates, inorganic, n.o.s. 5.1 UN1477 II 5.1IB8, IP2, IP4, T3,

TP33152 212 240 5 kg 25 kg A 56, 58

III 5.1 IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 56, 58

Nitrates of diazonium compounds Forbidden

Nitrating acid mixtures, spent with more than 50

percent nitric acid8 UN1826 I 8, 5.1 A7, T10, TP2, TP13 None 158 243 Forbidden 2.5 L D

40,

53,

58, 66

Nitrating acid mixtures spent with not more than 50

percent nitric acid8 UN1826 II 8 A7, B2, IB2, T8, TP2 None 158 242 Forbidden 30 L D

40,

53, 58

Nitrating acid mixtures with more than 50 percent nitric

acid8 UN1796 I 8, 5.1 A7, T10, TP2, TP13 None 158 243 Forbidden 2.5 L D

40,

53,

58, 66

Nitrating acid mixtures with not more than 50 percent

nitric acid8 UN1796 II 8

A7, B2, IB2, T8, TP2,

TP13None 158 242 Forbidden 30 L D

40,

53, 58

Nitric acid other than red fuming, with at least 65

percent, but not more than 70 percent nitric acid8 UN2031 II 8, 5.1

B2, B47, B53, IB2,

IP15, T8, TP2None 158 242 Forbidden 30 L D

53,

58,

66,

74,

89, 90




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Nitric acid other than red fuming, with more than 20

percent and less than 65 percent nitric acid8 UN2031 II 8

A212, B2, B47, B53,

IB2, IP15, T8, TP2None 158 242 Forbidden 30 L D

44,

53,

58,

66,

74,

89, 90

Nitric acid other than red fuming with not more than 20

percent nitric acid8 UN2031 II 8

B2, B47, B53, IB2,

T8, TP2None 158 242 1 L 30 L D 53, 58

+ Nitric acid, red fuming 8 UN2032 I

8,

5.1,

6.1

2, B9, B32, T20, TP2,

TP13, TP38, TP45None 227 244 Forbidden Forbidden D

40,

53,

58,

66,

74,

89, 90

Nitric acid other than red fuming, with more than 70

percent nitric acid8 UN2031 I 8, 5.1

B47, B53, T10, TP2,

TP12, TP13None 158 243 Forbidden 2.5 L D

44,

53,

58,

66,

89,

90,

110,

111

Nitric oxide, compressed 2.3 UN1660 2.3,

5.1, 81, B77 None 337 None Forbidden Forbidden D

40,

89, 90

Nitric oxide and dinitrogen tetroxide mixtures or Nitric

oxide and nitrogen dioxide mixtures2.3 UN1975

2.3,

5.1, 81, B77 None 337 None Forbidden Forbidden D

40,

89, 90

G Nitriles, flammable, toxic, n.o.s. 3 UN3273 I 3, 6.1T14, TP2, TP13,

TP27None 201 243 Forbidden 30 L E 40, 52

II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40, 52




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Nitrites, inorganic, aqueous solution, n.o.s 5.1 UN3219 II 5.1 148, IB1, T4, TP1 152 202 242 1 L 5 L B

46,

56,

58,

133

III 5.1 IB2, T4, TP1 152 203 241 2.5 L 30 L B

46,

56,

58,

133

G Nitrites, inorganic, n.o.s 5.1 UN2627 II 5.133, IB8, IP2, IP4, T3,

TP33152 212 None 5 kg 25 kg A

46,

56,

58, 13

G Nitriles, liquid, toxic, n.o.s. 6.1 UN3276 I 6.15, T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 52

II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B 52

III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A 52

G Nitriles, solid, toxic, n.o.s. 6.1 UN3439 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg D 52

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B 52


G Nitriles, toxic, flammable, n.o.s. 6.1 UN3275 I 6.1, 35, T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40, 52

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40, 52

3-Nitro-4-chlorobenzotrifluoride 6.1 UN2307 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40

6-Nitro-4-diazotoluene-3-sulfonic acid (dry) Forbidden

Nitro isobutane triol trinitrate Forbidden

N-Nitro-N-methylglycolamide nitrate Forbidden

2-Nitro-2-methylpropanol nitrate Forbidden

Nitro urea 1.1D UN0147 1.1D None 62 None Forbidden Forbidden 4 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

N-Nitroaniline Forbidden

+ Nitroanilines (o-; m-; p-; ) 6.1 UN1661 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Nitroanisole, liquid 6.1 UN2730 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Nitroanisoles, solid 6.1 UN3458 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

+ Nitrobenzene 6.1 UN1662 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40

m-Nitrobenzene diazonium perchlorate Forbidden

Nitrobenzenesulfonic acid 8 UN2305 II 8B2, B4, IB8, IP2, IP4,

T3, TP33154 202 242 1 L 30 L A 53, 58

Nitrobenzol, see Nitrobenzene

5-Nitrobenzotriazol 1.1D UN0385 1.1D None 62 None Forbidden Forbidden 4 25

Nitrobenzotrifluorides, liquid 6.1 UN2306 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40

Nitrobenzotrifluorides, solid 6.1 UN3431 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40

Nitrobromobenzenes, liquid 6.1 UN2732 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Nitrobromobenzenes, solid 6.1 UN3459 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Nitrocellulose, dry or wetted with less than 25 percent

water (or alcohol), by mass1.1D UN0340 1.1D None 62 None Forbidden Forbidden 4

25,

27E

Nitrocellulose, with not more than 12.6 percent

nitrogen, by dry mass mixture with or without

plasticizer, with or without pigment

4.1 UN2557 II 4.1 44, W31 151 212 240 1 kg 15 kg D 28, 36

Nitrocellulose membrane filters, with not more than

12.6% nitrogen, by dry mass4.1 UN3270 II 4.1 43, A1 151 212 240 1 kg 15 kg D

Nitrocellulose, plasticized with not less than 18 percent

plasticizing substance, by mass1.3C UN0343 1.3C None 62 None Forbidden Forbidden 4 25

Nitrocellulose, solution, flammable with not more than

12.6 percent nitrogen, by mass, and not more than 55

percent nitrocellulose

3 UN2059 I 3198, T11, TP1, TP8,

TP27None 201 243 1 L 30 L E

II 3198, IB2, T4, TP1,

TP8150 202 242 5 L 60 L B




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

III 3 198, B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Nitrocellulose, unmodified or plasticized with less than

18 percent plasticizing substance, by mass1.1D UN0341 1.1D None 62 None Forbidden Forbidden 4

25,

27E

Nitrocellulose, wetted with not less than 25 percent

alcohol, by mass1.3C UN0342 1.3C None 62 None Forbidden Forbidden 4 25

Nitrocellulose with alcohol with not less than 25 percent

alcohol by mass, and with not more than 12.6 percent

nitrogen, by dry mass

4.1 UN2556 II 4.1 W31 151 212 None 1 kg 15 kg D

12,

25,

28, 36

Nitrocellulose with water with not less than 25 percent

water by mass4.1 UN2555 II 4.1 W31 151 212 None 15 kg 50 kg E 28, 36

Nitrochlorobenzene, see Chloronitrobenzenes etc

Nitrocresols, liquid 6.1 UN3434 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Nitrocresols, solid 6.1 UN2446 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Nitroethane 3 UN2842 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Nitroethyl nitrate Forbidden

Nitroethylene polymer Forbidden

Nitrogen, compressed 2.2 UN1066 2.2 306,

307302

314,

31575 kg 150 kg A

Nitrogen dioxide, see Dinitrogen tetroxide

Nitrogen fertilizer solution, see Fertilizer ammoniating

solution etc

Nitrogen peroxide, see Dinitrogen tetroxide

Nitrogen, refrigerated liquid cryogenic liquid 2.2 UN1977 2.2 345, 346, T75, TP5 320 316 318 50 kg 500 kg D

Nitrogen tetroxide and nitric oxide mixtures, see Nitric

oxide and nitrogen tetroxide mixtures

Nitrogen tetroxide, see Dinitrogen tetroxide

Nitrogen trichloride Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Nitrogen trifluoride 2.2 UN2451 2.2,

5.1 None 302 None 75 kg 150 kg D 40

Nitrogen triiodide Forbidden

Nitrogen triiodide monoamine Forbidden

Nitrogen trioxide 2.3 UN2421 2.3,


40,

89, 90

Nitroglycerin, desensitized with not less than 40

percent non-volatile water insoluble phlegmatizer, by

mass

1.1D UN01431.1D,

6.1125 None 62 None Forbidden Forbidden 4

25,

21E

Nitroglycerin, liquid, not desensitized Forbidden

Nitroglycerin mixture, desensitized, liquid, flammable,

n.o.s. with not more than 30 percent nitroglycerin, by

mass

3 UN3343 3 129 None 214 None Forbidden Forbidden D

Nitroglycerin mixture, desensitized, liquid, n.o.s. with

not more than 30% nitroglycerin, by mass3 UN3357 II 3 142 None 202 243 5 L 60 L E

Nitroglycerin mixture, desensitized, solid, n.o.s. with

more than 2 percent but not more than 10 percent

nitroglycerin, by mass

4.1 UN3319 II 4.1 118 None None None Forbidden 0.5 kg E

Nitroglycerin, solution in alcohol, with more than 1

percent but not more than 5 percent nitroglycerin3 UN3064 II 3 N8 None 202 None Forbidden 5 L E

Nitroglycerin, solution in alcohol, with more than 1

percent but not more than 10 percent nitroglycerin1.1D UN0144 1.1D None 62 None Forbidden Forbidden 4

25,

21E

Nitroglycerin solution in alcohol with not more than 1

percent nitroglycerin3 UN1204 II 3 IB2, N34 150 202 None 5 L 60 L B

Nitroguanidine nitrate Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Nitroguanidine or Picrite, dry or wetted with less than

20 percent water, by mass1.1D UN0282 1.1D None 62 None Forbidden Forbidden 4 25

Nitroguanidine, wetted or Picrite, wetted with not less

than 20 percent water, by mass4.1 UN1336 I 4.1

23, A8, A19, A20,


1-Nitrohydantoin Forbidden

Nitrohydrochloric acid 8 UN1798 I 8B10, N41, T10, TP2,


40,

53,

58,

66,

74,

89, 90

Nitromannite (dry) Forbidden

Nitromannite, wetted, see Mannitol hexanitrate, etc

Nitromethane 3 UN1261 II 3 150 202 None Forbidden 60 L A

Nitromuriatic acid, see Nitrohydrochloric acid

Nitronaphthalene 4.1 UN2538 III 4.1A1, IB8, IP3, T1,

TP33151 213 240 25 kg 100 kg A

+ Nitrophenols (o-; m-; p-; ) 6.1 UN1663 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

m-Nitrophenyldinitro methane Forbidden

4-Nitrophenylhydrazine, with not less than 30 percent


162, A8, A19, A20,

N41, W31None 211 None Forbidden 15 kg E 28, 36

Nitropropanes 3 UN2608 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

p-Nitrosodimethylaniline 4.2 UN1369 II 4.2A19, A20, IB6, IP2,

N34, T3, TP33None 212 241 15 kg 50 kg D 34

Nitrostarch, dry or wetted with less than 20 percent


Nitrostarch, wetted with not less than 20 percent


23, A8, A19, A20,

N41, W31None 211 None 1 kg 15 kg D 28, 36




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Nitrosugars (dry) Forbidden

Nitrosyl chloride 2.3 UN1069 2.3, 8 3, B14 None 304314,


Nitrosylsulfuric acid, liquid 8 UN2308 II 8A3, A7, B2, IB2, N34,

T8, TP2154 202 242 1 L 30 L D

40,

53,

58,

66,

74,

89, 90

Nitrosylsulphuric acid, solid 8 UN3456 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg D

40,

53,

58,

66,

74,

89, 90

Nitrotoluenes, liquid 6.1 UN1664 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

Nitrotoluenes, solid 6.1 UN3446 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Nitrotoluidines (mono) 6.1 UN2660 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Nitrotriazolone or NTO 1.1D UN0490 1.1D None 62 None Forbidden Forbidden 4 25

Nitrous oxide 2.2 UN1070 2.2,

5.1A14 306 304

314,

31575 kg 150 kg A 40

Nitrous oxide, refrigerated liquid 2.2 UN2201 2.2,

5.1B6, T75, TP5, TP22 None 304

314,


Nitroxylenes, liquid 6.1 UN1665 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

Nitroxylenes, solid 6.1 UN3447 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Nitroxylol, see Nitroxylenes

Nonanes 3 UN1920 III 3 B1, IB3, T2, TP2 150 203 242 60 L 220 L A

Non-flammable gas, n.o.s., see Compressed gas, etc.

or Liquefied gas, etc

Nonliquefied gases, see Compressed gases, etc




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Nonliquefied hydrocarbon gas, see Hydrocarbon gas

mixture, compressed, n.o.s.

Nonyltrichlorosilane 8 UN1799 II 8A7, B2, B6, N34,


40,

53,

Nordhausen acid, see Sulfuric acid, fuming etc

2,5-Norbornadiene, stabilized, see Bicyclo [2,2,1]

hepta-2,5-diene, stabilized

Octadecyltrichlorosilane 8 UN1800 II 8A7, B2, B6, N34,


40,

53, 58

Octadiene 3 UN2309 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B

1,7-Octadine-3,5-diyne-1,8-dimethoxy-9-octadecynoic

acidForbidden

Octafluorobut-2-ene or Refrigerant gas R 1318 2.2 UN2422 2.2 None 304314,

31575 kg 150 kg A

Octafluorocyclobutane, or Refrigerant gas RC 318 2.2 UN1976 2.2 T50 None 304314,

31575 kg 150 kg A

Octafluoropropaneor Refrigerant gas R 218 2.2 UN2424 2.2 T50 None 304314,

31575 kg 150 kg A

Octanes 3 UN1262 II 3 IB2, T4, TP2 150 202 242 5 L 60 L B

Octogen, etc. see Cyclotetramethylene tetranitramine,

etc.

Octolite or Octol, dry or wetted with less than 15


Octonal 1.1D UN0496 1.1D None 62 None Forbidden Forbidden 4 25

Octyl aldehydes 3 UN1191 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Octyltrichlorosilane 8 UN1801 II 8A7, B2, B6, N34,


40,

53, 58

Oil gas, compressed 2.3 UN1071 2.3,

2.16 None 304

314,


Oleum, see Sulfuric acid, fuming

Organic peroxide type A, liquid or solid Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Organic peroxide type B, liquid 5.2 UN3101 5.2, 1 53 152 225 None Forbidden Forbidden D

12,

25,

52, 53

G Organic peroxide type B, liquid, temperature controlled 5.2 UN3111 5.2, 1 53 None 225 None Forbidden Forbidden D2, 25,

52, 53

G Organic peroxide type B, solid 5.2 UN3102 5.2, 1 53 152 225 None Forbidden Forbidden D

12,

25,

52, 53

G Organic peroxide type B, solid, temperature controlled 5.2 UN3112 5.2, 1 53 None 225 None Forbidden Forbidden D2, 25,

52, 53

G Organic peroxide type C, liquid 5.2 UN3103 5.2 152 225 None 5 L 10 L D

12,

25,

52, 53

G Organic peroxide type C, liquid, temperature controlled 5.2 UN3113 5.2 None 225 None Forbidden Forbidden D2, 25,

52, 53

G Organic peroxide type C, solid 5.2 UN3104 5.2 152 225 None 5 kg 10 kg D

12,

25,

52, 53

G Organic peroxide type C, solid, temperature controlled 5.2 UN3114 5.2 None 225 None Forbidden Forbidden D2, 25,

52, 53

G Organic peroxide type D, liquid 5.2 UN3105 5.2 152 225 None 5 L 10 L D

12,

25,

52, 53

G Organic peroxide type D, liquid, temperature controlled 5.2 UN3115 5.2 None 225 None Forbidden Forbidden D2, 25,

52, 53

G Organic peroxide type D, solid 5.2 UN3106 5.2 152 225 None 5 kg 10 kg D

12,

25,

52, 53

G Organic peroxide type D, solid, temperature controlled 5.2 UN3116 5.2 None 225 None Forbidden Forbidden D2, 25,

52, 53

G Organic peroxide type E, liquid 5.2 UN3107 5.2 A61 152 225 None 10 L 25 L D

12,

25,

52, 53




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Organic peroxide type E, liquid, temperature controlled 5.2 UN3117 5.2 None 225 None Forbidden Forbidden D2, 25,

52, 53

G Organic peroxide type E, solid 5.2 UN3108 5.2 152 225 None 10 kg 25 kg D

12,

25,

52, 53

G Organic peroxide type E, solid, temperature controlled 5.2 UN3118 5.2 None 225 None Forbidden Forbidden D2, 25,

52, 53

G Organic peroxide type F, liquid 5.2 UN3109 5.2 A61, IP5 152 225 225 10 L 25 L D

12,

25,

52, 53

G Organic peroxide type F, liquid, temperature controlled 5.2 UN3119 5.2 IP5 None 225 225 Forbidden Forbidden D2, 25,

52, 53

G Organic peroxide type F, solid 5.2 UN3110 5.2 TP33 152 225 225 10 kg 25 kg D

12,

25,

52, 53

G Organic peroxide type F, solid, temperature controlled 5.2 UN3120 5.2 TP33 None 225 225 Forbidden Forbidden D2, 25,

52, 53

D

Organic phosphate, mixed with compressed gas or

Organic phosphate compound, mixed with compressed

gas or Organic phosphorus compound, mixed with

compressed gas

2.3 NA1955 2.3 3 None 334 None Forbidden Forbidden D 40

Organic pigments, self-heating 4.2 UN3313 II 4.2IB8, IP2, IP4, T3,

TP33None 212 241 15 kg 50 kg C

III 4.2 IB8, IP3, T1, TP33 None 213 241 25 kg 100 kg C

G Organoarsenic compound, liquid, n.o.s. 6.1 UN3280 I 6.15, T14, TP2, TP13,

TP27None 201 242 1 L 30 L B

II 6.1 IB2, T11, TP2, TP27 153 202 242 5 L 60 L B

III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A

G Organoarsenic compound, solid, n.o.s. 6.1 UN3465 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B





tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Organochlorine pesticides liquid, flammable, toxic,


T14, TP2, TP13,


II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40

Organochlorine pesticides, liquid, toxic 6.1 UN2996 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40

Organochlorine pesticides, liquid, toxic, flammable,


T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1, 3B1, IB3, T7, TP2,

TP28153 203 242 60 L 220 L A 40

Organochlorine pesticides, solid, toxic 6.1 UN2761 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


G Organometallic compound, liquid, toxic, n.o.s 6.1 UN3282 I 6.1T14, TP2, TP13,

TP27None 201 242 1 L 30 L B

II 6.1 IB2, T11, TP2, TP27 153 202 242 5 L 60 L B

III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A

G Organometallic compound, solid, toxic, n.o.s 6.1 UN3467 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B


G Organometallic substance, liquid, pyrophoric 4.2 UN3392 I 4.2B11, T21, TP2, TP7,

TP36None 181 244 Forbidden Forbidden D

13,

78,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

GOrganometallic substance, liquid, pyrophoric, water-

reactive4.2 UN3394 I

4.2,

4.3

B11, T21, TP2, TP7,

TP36, TP47None 181 244 Forbidden Forbidden D

13,

52,

78,

148

G Organometallic substance, liquid, water-reactive 4.3 UN3398 I 4.3T13, TP2, TP7, TP36,


13,

40,

52,

148

II 4.3

IB1, IP2, T7, TP2,

TP7, TP36, TP47,

W31

None 202 243 1 L 5 L D

13,

40,

52,

148

III 4.3

IB2, IP4, T7, TP2,

TP7, TP36, TP47,

W31

None 203 242 5 L 60 L E

13,

40,

52,

148

GOrganometallic substance, liquid, water-reactive,

flammable4.3 UN3399 I 4.3, 3

T13, TP2, TP7, TP36,


13,

40,

52,

148

II 4.3, 3

IB1, IP2, T7, TP2,

TP7, TP36, TP47,

W31

None 202 243 1 L 5 L D

13,

40,

52,

148

III 4.3, 3

IB2, IP4, T7, TP2,

TP7, TP36, TP47,

W31

None 203 242 5 L 60 L E

13,

40,

52,

148

G Organometallic substance, solid, pyrophoric 4.2 UN3391 I 4.2T21, TP7, TP33,

TP36None 187 244 Forbidden Forbidden D

13,

148

GOrganometallic substance, solid, pyrophoric, water-

reactive4.2 UN3393 I

4.2,

4.3

B11, T21, TP7, TP33,

TP36, TP47None 187 244 Forbidden Forbidden D

13,

52,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Organometallic substance, solid, self-heating 4.2 UN3400 II 4.2 IB6, T3, TP33, TP36 None 212 242 15 kg 50 kg C

III 4.2 IB8, T1, TP33, TP36 None 213 242 25 kg 100 kg C

G Organometallic substance, solid, water-reactive 4.3 UN3395 I 4.3N40, T9, TP7, TP33,

TP36, TP47, W31None 211 242 Forbidden 15 kg E

13,

40,

52,

148

II 4.3IB4, T3, TP33, TP36,

TP47, W31151 212 242 15 kg 50 kg E

13,

40,

52,

148

III 4.3IB6, T1, TP33, TP36,

TP47, W31151 213 241 25 kg 100 kg E

13,

40,

52,

148

GOrganometallic substance, solid, water-reactive,

flammable4.3 UN3396 I

4.3,

4.1

N40, T9, TP7, TP33,


13,

40,

52,

148

II4.3,

4.1

IB4, T3, TP33, TP36,

TP47, W31151 212 242 15 kg 50 kg E

13,

40,

52,

148

III4.3,

4.1

IB6, T1, TP33, TP36,

TP47, W31151 213 241 25 kg 100 kg E

13,

40,

52,

148

GOrganometallic substance, solid, water-reactive, self-

heating4.3 UN3397 I

4.3,

4.2

N40, T9, TP7, TP33,


13,

40,

52,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II4.3,

4.2

IB4, T3, TP33, TP36,

TP47, W31None 212 242 15 kg 50 kg E

13,

40,

52,

148

III4.3,

4.2

IB6, T1, TP33, TP36,

TP47, W31None 213 241 25 kg 100 kg E

13,

40,

52,

148

Organophosphorus compound, toxic, flammable, n.o.s. 6.1 UN3279 I 6.1, 35, T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

G Organophosphorus compound, liquid, toxic, n.o.s 6.1 UN3278 I 6.15, T14, TP2, TP13,

TP27None 201 243 1 L 30 L B

II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B

III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A

G Organophosphorus compound, solid, toxic, n.o.s 6.1 UN3464 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B


Organophosphorus pesticides, liquid, flammable, toxic,


T14, TP2, TP13,


II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40

Organophosphorus pesticides, liquid, toxic 6.1 UN3018 I 6.1N76, T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1IB2, N76, T11, TP2,

TP13, TP27153 202 243 5 L 60 L B 40

III 6.1IB3, N76, T7, TP2,

TP28153 203 241 60 L 220 L A 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Organophosphorus pesticides, liquid, toxic, flammable,


N76, T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, N76, T11, TP2,

TP13, TP27153 202 243 5 L 60 L B 40

III 6.1, 3B1, IB3, N76, T7,

TP2, TP28153 203 242 60 L 220 L A 40

Organophosphorus pesticides, solid, toxic 6.1 UN2783 I 6.1IB7, IP1, N77, T6,

TP33None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, N77,

T3, TP33153 212 242 25 kg 100 kg A 40

III 6.1IB8, IP3, N77, T1,

TP33153 213 240 100 kg 200 kg A 40

Organotin compounds, liquid, n.o.s 6.1 UN2788 I 6.1N33, N34, T14, TP2,

TP13, TP27None 201 243 1 L 30 L B 40

II 6.1

A3, IB2, N33, N34,

T11, TP2, TP13,

TP27

153 202 243 5 L 60 L A 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40

Organotin compounds, solid, n.o.s. 6.1 UN3146 I 6.1A5, IB7, IP1, T6,

TP33None 211 242 5 kg 50 kg B 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Organotin pesticides, liquid, flammable, toxic, flash


T14, TP2, TP13,


II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40

Organotin pesticides, liquid, toxic 6.1 UN3020 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Organotin pesticides, liquid, toxic, flammable, flash


T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1, 3B1, IB3, T7, TP2,

TP28153 203 242 60 L 220 L A 40

Organotin pesticides, solid, toxic 6.1 UN2786 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Orthonitroaniline, see Nitroanilines etc

Osmium tetroxide 6.1 UN2471 I 6.1A8, IB7, IP1, N33,

N34, T6, TP33, W31None 211 242 5 kg 50 kg B 40

D G Other regulated substances, liquid, n.o.s 9 NA3082 III 9 A189, IB3, T2, TP1 155 203 241 No limit No limit A

D G Other regulated substances, solid, n.o.s 9 NA3077 III 9384, B54, IB8, IP2,

T1, TP33155 213 240 No limit No limit A

G Oxidizing liquid, corrosive, n.o.s 5.1 UN3098 I 5.1, 8 62 None 201 244 Forbidden 2.5 L D

13,

56,

58,

138

II 5.1, 8 62, IB1 None 202 243 1 L 5 L B

13,

56,

58,

138

III 5.1, 8 62, IB2 152 203 242 2.5 L 30 L B

13,

56,

58,

138

G Oxidizing liquid, n.o.s 5.1 UN3139 I 5.1 62, 127, A2 None 201 243 Forbidden 2.5 L D

56,

58,

138




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II 5.1 62, 127, 148, A2, IB2 152 202 242 1 L 5 L B

56,

58,

138

III 5.1 62, 127, 148, A2, IB2 152 203 241 2.5 L 30 L B

56,

58,

138

G Oxidizing liquid, toxic, n.o.s 5.1 UN3099 I5.1,

6.162 None 201 244 Forbidden 2.5 L D

56,

58,

138

II5.1,

6.162, IB1 152 202 243 1 L 5 L B

56,

58,

95,

138

III5.1,

6.162, IB2 152 203 242 2.5 L 30 L B

56,

58,

95,

138

G Oxidizing solid, corrosive, n.o.s 5.1 UN3085 I 5.1, 8 62 None 211 242 1 kg 15 kg D

13,

56,

58,

138

II 5.1, 862, IB6, IP2, T3,

TP33152 212 242 5 kg 25 kg B

13,

34,

56,

58,

138

III 5.1, 862, IB8, IP3, T1,

TP33152 213 240 25 kg 100 kg B

13,

34,

56,

58,

138




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Oxidizing solid, flammable, n.o.s 5.1 UN3137 I5.1,

4.162 None 214 214 Forbidden Forbidden

13,

147,

148

G Oxidizing solid, n.o.s. 5.1 UN1479 I 5.1 62, IB5, IP1 None 211 242 1 kg 15 kg D

56,

58,

106,

138

II 5.162, IB8, IP2, IP4, T3,

TP33152 212 240 5 kg 25 kg B

56,

58,

106,

138

III 5.162, 148, IB8, IP3, T1,

TP33152 213 240 25 kg 100 kg B

56,

58,

106,

138

G Oxidizing solid, self-heating, n.o.s. 5.1 UN3100 I5.1,


II5.1,


G Oxidizing solid, toxic, n.o.s. 5.1 UN3087 I5.1,

6.162 None 211 242 1 kg 15 kg D

56,

58,

138

II5.1,

6.1

62, IB6, IP2, T3,

TP33152 212 242 5 kg 25 kg B

56,

58,

138

III5.1,

6.1

62, IB8, IP3, T1,

TP33152 213 240 25 kg 100 kg B

56,

58,

138

G Oxidizing solid, water reactive, n.o.s 5.1 UN31215.1,


13,

148

Oxygen, compressed 2.2 UN1072 2.2,

5.1110, A14 306 302

314,

31575 kg 150 kg A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Oxygen difluoride, compressed 2.3 UN2190 2.3,

5.1, 81, N86 None 304 None Forbidden Forbidden D

13,

40,

89, 90

Oxygen generator, chemical (including when contained

in associated equipment, e.g., passenger service units

(PSUs), portable breathing equipment (PBE), etc)

5.1 UN3356 5.1 None 168 None Forbidden 25 kg D

56,

58,

69,

106

+ Oxygen generator, chemical, spent 9 NA3356 III 9 61 None 213 None Forbidden Forbidden A

Oxygen, refrigerated liquid (cryogenic liquid) 2.2 UN1073 2.2,

5.1T75, TP5, TP22 320 316 318 Forbidden Forbidden D

Paint including paint, lacquer, enamel, stain, shellac

solutions, varnish, polish, liquid filler and liquid lacquer

base

3 UN1263 I 3367, T11, TP1, TP8,

TP27150 201 243 1 L 30 L E

II 3

149, 367, B52, B131,

IB2, T4, TP1, TP8,

TP28

150 173 242 5 L 60 L B

III 3367, B1, B52, B131,

IB3, T2, TP1, TP29150 173 242 60 L 220 L A

Paint or Paint related material 8 UN3066 II 8367, B2, IB2, T7,

TP2, TP28154 173 242 1 L 30 L A 40

III 8367, B52, IB3, T4,

TP1, TP29154 173 241 5 L 60 L A 40

Paint, corrosive, flammable (including paint, lacquer,

enamel, stain, shellac, varnish, polish, liquid filler, and

liquid lacquer base)

8 UN3470 II 8, 3367, IB2, T7, TP2,

TP8, TP28154 202 243 1 L 30 L B 40

Paint, flammable, corrosive, (including paint , lacquer,

enamel, stain, shellac, varnish, polish, liquid filler and

liquid lacquer base)

3 UN3469 I 3, 8 367, T11, TP2, TP27 None 201 243 0.5 L 2.5 L E 40

II 3, 8367, IB2, T7, TP2,

TP8, TP28150 202 243 1 L 5 L B 40

III 3, 8367, IB3, T4, TP1,

TP29150 203 242 5 L 60 L A 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Paint related material including paint thinning, drying,

removing, or reducing compound3 UN1263 I 3

367, T11, TP1, TP8,

TP27150 201 243 1 L 30 L E

II 3

149, 367, B52, B131,

IB2, T4, TP1, TP8,

TP28

150 173 242 5 L 60 L B

III 3367, B1, B52, B131,

IB3, T2, TP1, TP29150 173 242 60 L 220 L A

Paint related material corrosive, flammable (including

paint thinning or reducing compound)8 UN3470 II 8, 3

367, IB2, T7, TP2,

TP8, TP28154 202 243 1 L 30 L B 40

Paint related material, flammable, corrosive (including

paint thinning or reducing compound)3 UN3469 I 3, 8 367, T11, TP2, TP27 None 201 243 0.5 L 2.5 L E 40

II 3, 8367, IB2, T7, TP2,

TP8, TP28150 202 243 1 L 5 L B 40

III 3, 8367, IB3, T4, TP1,

TP29150 203 242 5 L 60 L A 40

Paper, unsaturated oil treated incompletely dried

(including carbon paper)4.2 UN1379 III 4.2 IB8, IP3, W31 None 213 241 Forbidden Forbidden A

Paraformaldehyde 4.1 UN2213 III 4.1A1, B120, IB8, IP3,

T1, TP33151 213 240 25 kg 100 kg A

Paraldehyde 3 UN1264 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Paranitroaniline, solid, see Nitroanilines etc

D Parathion and compressed gas mixture 2.3 NA1967 2.3 3 None 334 245 Forbidden Forbidden E 40

Paris green, solid, see Copper acetoarsenite

PCB, see Polychlorinated biphenyls

+ Pentaborane 4.2 UN1380 I4.2,

6.11 None 205 245 Forbidden Forbidden D

13,

148

Pentachloroethane 6.1 UN1669 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40

Pentachlorophenol 6.1 UN3155 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Pentaerythrite tetranitrate (dry) Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Pentaerythrite tetranitrate mixture, desensitized, solid,

n.o.s. or Pentaerythritol tetranitrate mixture,

desensitized, solid, n.o.s. or PETN mixture,

desensitized, solid, n.o.s., with more than 10 percent

but not more than 20 percent PETN, by mass

4.1 UN3344 II 4.1 118, N85 None 214 None Forbidden Forbidden E

Pentaerythrite tetranitrate or Pentaerythritol

tetranitrate or PETN, with not less than 7 percent wax

by mass


Pentaerythrite tetranitrate, wetted or Pentaerythritol

tetranitrate, wetted, or PETN, wetted with not less

than 25 percent water, by mass, or Pentaerythrite

tetranitrate, or Pentaerythritol tetranitrate or PETN,

desensitized with not less than 15 percent

phlegmatizer by mass


Pentaerythritol tetranitrate, see Pentaerythrite

tetranitrate, etc

Pentafluoroethane or Refrigerant gas R 125 2.2 UN3220 2.2 T50 306 304314,

31575 kg 150 kg A

Pentamethylheptane 3 UN2286 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Pentane-2,4-dione 3 UN2310 III 3, 6.1 B1, IB3, T4, TP1 150 203 242 60 L 220 L A

Pentanes 3 UN1265 I 3 T11, TP2 150 201 243 1 L 30 L E

II 3 IB2, IP8, T4, TP1 150 202 242 5 L 60 L E

Pentanitroaniline (dry) Forbidden

Pentanols 3 UN1105 II 3 IB2, T4, TP1, TP29 150 202 242 5 L 60 L B

III 3 B1, B3, IB3, T2, TP1 150 203 242 60 L 220 L A

1-Pentene (n-amylene) 3 UN1108 I 3 T11, TP2 150 201 243 1 L 30 L E

1-Pentol 8 UN2705 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L B 26, 27

Pentolite, dry or wetted with less than 15 percent





tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Pepper spray, see Aerosols, etc. or Self-defense spray,

non-pressurized

Perchlorates, inorganic, aqueous solution, n.o.s. 5.1 UN3211 II 5.1 IB2, T4, TP1 152 202 242 1 L 5 L B

56,

58,

133

III 5.1 IB2, T4, TP1 152 202 241 2.5 L 30 L B

56,

58,

69,

133

Perchlorates, inorganic, n.o.s. 5.1 UN1481 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58

III 5.1 IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 56, 58

Perchloric acid, with more than 72 percent acid by mass Forbidden

Perchloric acid with more than 50 percent but not more

than 72 percent acid, by mass5.1 UN1873 I 5.1, 8 A2, N41, T10, TP1 None 201 243 Forbidden 2.5 L D

53,

58, 66

Perchloric acid with not more than 50 percent acid by

mass8 UN1802 II 8, 5.1 IB2, N41, T7, TP2 None 202 243 Forbidden 30 L C

53,

58, 66

Perchloroethylene, see Tetrachloroethylene

Perchloromethyl mercaptan 6.1 UN1670 I 6.1

2, B9, B14, B32, N34,

T20, TP2, TP13,

TP38, TP45


Perchloryl fluoride 2.3 UN3083 2.3,

5.12, B9, B14 None 302

314,


Percussion caps, see Primers, cap type

Perfluoro-2-butene, see Octafluorobut-2-ene

Perfluoro(ethyl vinyl ether) 2.1 UN3154 2.1 306

302,

304,

305

314,


Perfluoro(methyl vinyl ether) 2.1 UN3153 2.1 T50 306

302,

304,

305

314,


Perfumery products with flammable solvents 3 UN1266 II 3149, IB2, T4, TP1,

TP8150 202 242 15 L 60 L B




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

G Permanganates, inorganic, aqueous solution, n.o.s 5.1 UN3214 II 5.1 26, 353, IB2, T4, TP1 152 202 242 1 L 5 L D

56,

58,

133,

138

G Permanganates, inorganic, n.o.s 5.1 UN1482 II 5.126, 353, A30, IB6,

IP2, T3, TP33152 212 242 5 kg 25 kg D

56,

58,

138

III 5.126, 353, A30, IB8,

IP3, T1, TP33152 213 240 25 kg 100 kg D

56,

58, 13

Permeation devices for calibrating air quality

monitoring equipment See §173.175

Peroxides, inorganic, n.o.s 5.1 UN1483 II 5.1

A7, A20, IB6, IP2,

N34, T3, TP33,

W100

None 212 242 5 kg 25 kg C

13,

52,

66,

75,

148

III 5.1

A7, A20, B134, IB8,

IP21, N34, T1, TP33,

W100

152 213 240 25 kg 100 kg C

13,

52,

66,

75,

148

Peroxyacetic acid, with more than 43 percent and with

more than 6 percent hydrogen peroxideForbidden

Persulfates, inorganic, aqueous solution, n.o.s 5.1 UN3216 III 5.1 IB2, T4, TP1, TP29 152 203 241 2.5 L 30 L A

56,

58,

133

Persulfates, inorganic, n.o.s. 5.1 UN3215 III 5.1 IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 56, 58

GPesticides, liquid, flammable, toxic, flash point less than

23 degrees C3 UN3021 I 3, 6.1

B5, T14, TP2, TP13,


II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

GPesticides, liquid, toxic, flammable, n.o.s. flash point

not less than 23 degrees C6.1 UN2903 I 6.1, 3

T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1, 3 B1, IB3, T7, TP2 153 203 242 60 L 220 L A 40

G Pesticides, liquid, toxic, n.o.s. 6.1 UN2902 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40

G Pesticides, solid, toxic, n.o.s. 6.1 UN2588 I 6.1 IB7, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


PETN, see Pentaerythrite tetranitrate

PETN/TNT, see Pentolite, etc

Petrol, see Gasoline

Petroleum crude oil 3 UN1267 I 3144, 357, T11, TP1,

TP8150 201 243 1 L 30 L E

II 3144, 357, IB2, T4,

TP1, TP8150 202 242 5 L 60 L B

III 3144, 357, B1, IB3,

T2, TP1150 203 242 60 L 220 L A

Petroleum distillates, n.o.s. or Petroleum products,

n.o.s.3 UN1268 I 3 144, T11, TP1, TP8 150 201 243 1 L 30 L E

II 3144, IB2, T7, TP1,

TP8, TP28150 202 242 5 L 60 L B

III 3144, B1, IB3, T4,

TP1, TP29150 203 242 60 L 220 L A

Petroleum gases, liquefied or Liquefied petroleum gas 2.1 UN1075 2.1 T50, N95 306 304314,


D Petroleum oil 3 NA1270 I 3 144, T11, TP1 None 201 243 1 L 30 L E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II 3144, IB2, T7, TP1,

TP8, TP28150 202 242 5 L 60 L B

III 3144, B1, IB3, T4,

TP1, TP29150 203 242 60 L 220 L A

I Petroleum sour crude oil, flammable, toxic 3 UN3494 I 3, 6.1 343, T14, TP2, TP13 None 201 243 Forbidden 30 L D 40

II 3, 6.1 343, IB2, T7, TP2 150 202 243 1 L 60 L D 40

III 3, 6.1 343, IB3, T4, TP1 150 203 242 60 L 220 L C 40

Phenacyl bromide 6.1 UN2645 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B 40

+ Phenetidines 6.1 UN2311 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Phenol, molten 6.1 UN2312 II 6.1 B14, T7, TP3 None 202 243 Forbidden Forbidden B 40

+ Phenol, solid 6.1 UN1671 II 6.1IB8, IP2, IP4, N78,

T3, TP33153 212 242 25 kg 100 kg A

Phenol solutions 6.1 UN2821 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Phenolsulfonic acid, liquid 8 UN1803 II 8 B2, IB2, N41, T7, TP2 154 202 242 1 L 30 L C14,

53, 58

Phenoxyacetic acid derivative pesticide, liquid,

flammable, toxic flash point less than 23 degrees C3 UN3346 I 3, 6.1

T14, TP2, TP13,


II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40

Phenoxyacetic acid derivative pesticide, liquid, toxic 6.1 UN3348 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40

Phenoxyacetic acid derivative pesticide, liquid, toxic,


T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1, 3 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Phenoxyacetic acid derivative pesticide, solid, toxic 6.1 UN3345 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Phenyl chloroformate 6.1 UN2746 II 6.1, 8 IB2, T7, TP2, TP13 153 202 243 1 L 30 L A

12,

13,

25,

40,

53, 58

Phenyl isocyanate 6.1 UN2487 I 6.1, 3

2, B9, B14, B32, B77,

N33, N34, T20, TP2,

TP13, TP38, TP45


Phenyl mercaptan 6.1 UN2337 I 6.1, 3

2, B9, B14, B32, B77,

T20, TP2, TP13,

TP38, TP45


Phenyl phosphorus dichloride 8 UN2798 II 8 B2, B15, IB2, T7, TP2 154 202 242 Forbidden 30 L B40,

53, 58

Phenyl phosphorus thiodichloride 8 UN2799 II 8 B2, B15, IB2, T7, TP2 154 202 242 Forbidden 30 L B40,

53, 58

Phenyl urea pesticides, liquid, toxic 6.1 UN3002 I 6.1 T14, TP2 TP27 None 201 243 1 L 30 L B 40

II 6.1 T7, TP2 None 202 243 5 L 60 L B 40

III 6.1 T4, TP1 153 203 241 60 L 220 L A 40

Phenylacetonitrile, liquid 6.1 UN2470 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 52

Phenylacetyl chloride 8 UN2577 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L C40,

53, 58

Phenylcarbylamine chloride 6.1 UN1672 I 6.1

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP45


m-Phenylene diaminediperchlorate (dry) Forbidden

+ Phenylenediamines (o-; m-; p-;) 6.1 UN1673 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Phenylhydrazine 6.1 UN2572 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40

Phenylmercuric acetate 6.1 UN1674 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

G Phenylmercuric compounds, n.o.s. 6.1 UN2026 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A


Phenylmercuric hydroxide 6.1 UN1894 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Phenylmercuric nitrate 6.1 UN1895 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Phenyltrichlorosilane 8 UN1804 II 8A7, B6, N34, T10,


40,

53, 58

Phosgene 2.3 UN1076 2.3, 8 1, B7, B46, N86 None 192 314 Forbidden Forbidden D 40

9-Phosphabicyclononanes or Cyclooctadiene

phosphines4.2 UN2940 II 4.2

A19, IB6, IP2, T3,

TP33, W31None 212 241 15 kg 50 kg A

Phosphine 2.3 UN2199 2.3,


Phosphine, adsorbed 2.3 UN35252.3,


Phosphoric acid solution 8 UN1805 III 8A7, IB3, N34, T4,

TP1154 203 241 5 L 60 L A 53, 58

Phosphoric acid, solid 8 UN3453 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 53, 58

Phosphoric acid triethyleneimine, see Tris-(1-

aziridiyl)phosphine oxide, solution

Phosphoric anhydride, see Phosphorus pentoxide

Phosphorous acid 8 UN2834 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A25,

53, 58

Phosphorus, amorphous 4.1 UN1338 III 4.1

A1, A19, B1, B9,

B26, IB8, IP3, T1,

TP33

None 213 243 25 kg 100 kg A 74




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Phosphorus bromide, see Phosphorus tribromide

Phosphorus chloride, see Phosphorus trichloride

Phosphorus heptasulfide, free from yellow or white

phosphorus4.1 UN1339 II 4.1

A20, IB4, N34, T3,

TP33, W31None 212 240 15 kg 50 kg B

13,

74,

147,

148

Phosphorus oxybromide 8 UN1939 II 8B8, IB8, IP2, IP4,

N41, N43, T3, TP33None 212 240 Forbidden 50 kg C

12,

25,

40,

53, 58

Phosphorus oxybromide, molten 8 UN2576 II 8B2, B8, IB1, N41,

N43, T7, TP3, TP13None 202 242 Forbidden Forbidden C

40,

53, 58

+ Phosphorous oxychloride 6.1 UN1810 I 6.1, 8

2, B9, B14, B32, B77,

N34, T20, TP2, TP13,

TP38, TP45


53, 58

Phosphorus pentabromide 8 UN2691 II 8A7, IB8, IP2, IP4,

N34, T3, TP33154 212 240 Forbidden 50 kg B

12,

25,

40,

53,

55, 58

Phosphorus pentachloride 8 UN1806 II 8A7, IB8, IP2, IP4,

N34, T3, TP33None 212 240 Forbidden 50 kg C

40,

44,

53,

58,

89,

100,

141

Phosphorus Pentafluoride 2.3 UN2198 2.3, 8 2, B9, B14 None302,

304

314,


Phosphorus pentafluoride, adsorbed 2.3 UN3524 2.3, 8 2, B9, B14 None 302c None Forbidden Forbidden D 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Phosphorus pentasulfide, free from yellow or white

phosphorus4.3 UN1340 II

4.3,

4.1

A20, B59, IB4, T3,

TP33, W31, W40151 212 242 15 kg 50 kg B

13,

74,

148

Phosphorus pentoxide 8 UN1807 II 8A7, IB8, IP2, IP4,

N34, T3, TP33154 212 240 15 kg 50 kg A 53, 58

Phosphorus sesquisulfide, free from yellow or white


A20, IB4, N34, T3,

TP33, W31None 212 240 15 kg 50 kg B 74

Phosphorus tribromide 8 UN1808 II 8A3, A7, B2, B25, IB2,

N34, N43, T7, TP2None 202 242 Forbidden 30 L C

40,

53, 58

Phosphorus trichloride 6.1 UN1809 I 6.1, 8

2, B9, B14, B15, B32,

B77, N34, T20, TP2,

TP13, TP38, TP45

None 227 244 Forbidden Forbidden C40,

53, 58

Phosphorus trioxide 8 UN2578 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A

12,

25,

53, 58

Phosphorus trisulfide, free from yellow or white


A20, IB4, N34, T3,

TP33, W31None 212 240 15 kg 50 kg B

13,

74,

147,

148

Phosphorus, white dry or Phosphorus, white, under

water or Phosphorus white, in solution or Phosphorus,

yellow dry or Phosphorus, yellow, under water or

Phosphorus, yellow, in solution

4.2 UN1381 I4.2,

6.1

B9, B26, N34, T9,

TP3, TP31, W31None 188 243 Forbidden Forbidden E

Phosphorus white, molten 4.2 UN2447 I4.2,

6.1

B9, B26, N34, T21,

TP3, TP7, TP26None 188 243 Forbidden Forbidden D

Phosphorus (white or red) and a chlorate, mixtures of Forbidden

Phosphoryl chloride, see Phosphorus oxychloride




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Phthalic anhydride with more than .05 percent maleic

anhydride8 UN2214 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 53, 58

Picolines 3 UN2313 III 3 B1, IB3, T4, TP1 150 203 242 60 L 220 L A 40

Picric acid, see Trinitrophenol, etc

Picrite, see Nitroguanidine, etc

Picryl chloride, see Trinitrochlorobenzene

Pine oil 3 UN1272 III 3 B1, IB3, T2, TP2 150 203 242 60 L 220 L A

alpha-Pinene 3 UN2368 III 3 B1, IB3, T2, TP2 150 203 242 60 L 220 L A

Piperazine 8 UN2579 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A12,

25, 52

Piperidine 8 UN2401 I 8, 3 A10, T10, TP2 None 201 243 0.5 L 2.5 L B 52

Pivaloyl chloride, see Trimethylacetyl chloride

Plastic molding compound in dough, sheet or extruded

rope form evolving flammable vapor9 UN3314 III 9 32, IB8, IP3, IP7 155 221 221 100 kg 200 kg E

21,

25,

87,

144

Plastic solvent, n.o.s., see Flammable liquids, n.o.s.

Plastics, nitrocellulose-based, self-heating, n.o.s. 4.2 UN2006 III 4.2 None 213 None Forbidden Forbidden C

Poisonous gases, n.o.s., see Compressed or liquefied

gases, flammable or toxic, n.o.s.

Polyalkylamines, n.o.s., see Amines, etc

Polyamines, flammable, corrosive, n.o.s. see Amines,

flammable, corrosive, n.o.s

Polyamines, liquid, corrosive, n.o.s. see Amines,

liquid, corrosive, n.o.s

Polyamines, liquid, corrosive, flammable, n.o.s. see

Amines, liquid, corrosive, flammable, n.o.s

Polychlorinated biphenyls, liquid 9 UN2315 II 99, 81, 140, IB3, T4,

TP1155 202 241 100 L 220 L A 95

Polychlorinated biphenyls, solid 9 UN3432 II 99, 81,140, IB8, IP2,

IP4, T3, TP33155 212 240 100 kg 200 kg A 95




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Polyester resin kit, liquid base material 3 UN3269 3 40, 149 165 165 None 5 kg 5 kg B

Polyester resin kit, solid base material 4.1 UN3527 4.1 40, 157 165 165 None 5 kg 5 kg B

Polyhalogenated biphenyls, liquid or Halogenated

monomethyldiphenyl-methanes, liquid or

Polyhalogenated terphenyls, liquid

9 UN3151 II 9 IB2 155 204 241 100 L 220 L A 95

Polyhalogenated biphenyls, solid or Halogenated

monomethyldiphenyl-methanes, solid or

Polyhalogenated terphenyls, solid

9 UN3152 II 9IB8, IP2, IP4, T3,

TP33155 204 241 100 kg 200 kg A 95

Polymeric beads expandable, evolving flammable

vapor9 UN2211 III 9

32, IB8, IP3, IP7, T1,

TP33155 221 221 100 kg 200 kg E

21,

25,

87,

144

G Polymerizing substance, liquid, stabilized, n.o.s 4.1 UN3532 III 4.1387, 421, IB3, IP19,

N92, T7, TP4, TP6None 203 241 10 L 25 L D

25,

52, 53

GPolymerizing substance, liquid, temperature controlled,

n.o.s4.1 UN3534 III 4.1

387, 421, IB3, IP19,

N92, T7, TP4, TP6None 203 241 Forbidden Forbidden D

2, 25,

52, 53

G Polymerizing substance, solid, stabilized, n.o.s 4.1 UN3531 III 4.1

387, 421, IB7, IP19,

N92, T7, TP4, TP6,

TP33

None 213 240 10 kg 25 kg D25,

52, 53

GPolymerizing substance, solid, temperature controlled,

n.o.s4.1 UN3533 III 4.1

387, 421, IB7, IP19,

N92, T7, TP4, TP6,

TP33

None 213 240 Forbidden Forbidden D2, 25,

52, 53

Potassium 4.3 UN2257 I 4.3

A7, A19, A20, B27,

IB4, IP1, N6, N34,

T9, TP7, TP33, W31


13,

52,

148

Potassium arsenate 6.1 UN1677 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Potassium arsenite 6.1 UN1678 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Potassium bisulfite solution, see Bisulfites, aqueous

solutions, n.o.s.




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Potassium borohydride 4.3 UN1870 I 4.3 A19, N40, W31 None 211 242 Forbidden 15 kg E

13,

52,

148

Potassium bromate 5.1 UN1484 II 5.1IB8, IP2, IP4, T3,

TP33152 212 242 5 kg 25 kg A 56, 58

Potassium carbonyl Forbidden

Potassium chlorate 5.1 UN1485 II 5.1A9, IB8, IP2, IP4,

N34, T3, TP33152 212 242 5 kg 25 kg A 56, 58

Potassium chlorate, aqueous solution 5.1 UN2427 II 5.1 A2, IB2, T4, TP1 152 202 241 1 L 5 L B

56,

58,

133

III 5.1 A2, IB2, T4, TP1 152 203 241 2.5 L 30 L B

56,

58,

69,

133

Potassium chlorate mixed with mineral oil, see

Explosive, blasting, type C

Potassium cuprocyanide 6.1 UN1679 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 52

Potassium cyanide, solid 6.1 UN1680 I 6.1

B69, B77, IB7, IP1,

N74, N75, T6, TP33,

W31

None 211 242 5 kg 50 kg B 52

Potassium cyanide solution 6.1 UN3413 I 6.1B69, B77, N74, N75,

T14, TP2, TP13, W31None 201 243 1 L 30 L B 52

II 6.1

B69, B77, IB2, N74,

N75, T11, TP2, TP13,

TP27, W31

153 202 243 5 L 60 L B 52

III 6.1

B69, B77, IB3, N74,

N75, T7, TP2, TP13,

TP28, W31

153 203 241 60 L 220 L A 52




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Potassium dichloro isocyanurate or Potassium dichloro-

s-triazinetrione, see Dichloroisocyanuric acid, dry or

Dichloroisocyanuric acid salts etc

Potassium dithionite or Potassium hydrosulfite 4.2 UN1929 II 4.2A8, A19, A20, IB6,

IP2, T3, TP33, W31None 212 241 15 kg 50 kg E 13

Potassium fluoride, solid 6.1 UN1812 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52

Potassium fluoride solution 6.1 UN3422 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 52

Potassium fluoroacetate 6.1 UN2628 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg E

Potassium fluorosilicate 6.1 UN2655 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52

Potassium hydrate, see Potassium hydroxide, solid

Potassium hydrogen fluoride, see Potassium hydrogen

difluoride

Potassium hydrogen fluoride solution, see Corrosive

liquid, n.o.s.

Potassium hydrogen sulfate 8 UN2509 II 8A7, IB8, IP2, IP4,

N34, T3, TP33154 212 240 15 kg 50 kg A 53, 58

Potassium hydrogendifluoride solid 8 UN1811 II 8, 6.1IB8, IP2, IP4, N3,

N34, T3, TP33154 212 240 15 kg 50 kg A

25,

40,

52,

53, 58

Potassium hydrogendifluoride solution 8 UN3421 II 8, 6.1IB2, N3, N34, T7,

TP2154 202 243 1 L 30 L A

25,

40,

52,

53, 58

III 8, 6.1IB3, N3, N34, T4,

TP1154 203 241 5 L 60 L A

40,

52,

53, 58

Potassium hydrosulfite, see Potassium dithionite

Potassium hydroxide, liquid, see Potassium hydroxide

solution




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Potassium hydroxide, solid 8 UN1813 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A 52

Potassium hydroxide, solution 8 UN1814 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A 52

III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 52

Potassium hypochlorite, solution, see Hypochlorite

solutions, etc

Potassium, metal alloys, liquid 4.3 UN1420 I 4.3A7, A19, A20, B27,

W31None 201 244 Forbidden 1 L E

13,

40,

52,

148

Potassium, metal alloys, solid 4.3 UN3403 I 4.3

A19, A20, B27, IB4,

IP1, T9, TP7, TP33,

W31

None 211 244 Forbidden 15 kg D

13,

52,

148

Potassium metavanadate 6.1 UN2864 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Potassium monoxide 8 UN2033 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A

29,

52.

Potassium nitrate 5.1 UN1486 III 5.1A1, A29, B120 IB8,

IP3, T1, TP33, W1152 213 240 25 kg 100 kg A

Potassium nitrate and sodium nitrite mixtures 5.1 UN1487 II 5.1B78, IB8, IP2, IP4,

T3, TP33152 212 240 5 kg 25 kg A 56, 58

Potassium nitrite 5.1 UN1488 II 5.1IB8, IP2, IP4, T3,

TP33152 212 242 5 kg 25 kg A 56, 58

Potassium perchlorate 5.1 UN1489 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58

Potassium permanganate 5.1 UN1490 II 5.1IB8, IP2, IP4, T3,

TP33152 212 240 5 kg 25 kg D

56,

58,

138

Potassium peroxide 5.1 UN1491 I 5.1 A20, IB6, IP1, N34 None 211 None Forbidden 15 kg C

13,

52,

66,

75,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Potassium persulfate 5.1 UN1492 III 5.1A1, A29, IB8, IP3,

T1, TP33152 213 240 25 kg 100 kg A

58,

145

Potassium phosphide 4.3 UN2012 I4.3,


13,

40,

52,

85,

148

Potassium selenate, see Selenates or Selenites

Potassium selenite, see Selenates or Selenites

Potassium sodium alloys, liquid 4.3 UN1422 I 4.3

A7, A19, B27, N34,

N40, T9, TP3, TP7,

TP31, W31

None 201 244 Forbidden 1 L E

13,

40,

52,

148

Potassium sodium alloys, solid 4.3 UN3404 I 4.3A19, B27, N34, N40,

T9, TP7, TP33, W31None 211 244 Forbidden 15 kg D

13,

52,

148

Potassium sulfide, anhydrous or Potassium sulfide

with less than 30 percent water of crystallization4.2 UN1382 II 4.2

A19, A20, B16, IB6,

IP2, N34, T3, TP33,

W31, W40

None 212 241 15 kg 50 kg A 52

Potassium sulfide, hydrated with not less than 30

percent water of crystallization8 UN1847 II 8

IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A 52

Potassium superoxide 5.1 UN2466 I 5.1 A20, IB6, IP1 None 211 None Forbidden 15 kg D

13,

52,

66,

75,

148

Powder cake, wetted or Powder paste, wetted with

not less than 17 percent alcohol by mass1.1C UN0433 1.1C None 62 None Forbidden Forbidden 4 25

Powder cake, wetted or Powder paste, wetted with

not less than 25 percent water, by mass1.3C UN0159 1.3C None 62 None Forbidden Forbidden 4 25

Powder paste, see Powder cake, etc

Powder, smokeless 1.1C UN0160 1.1C None 62 None Forbidden Forbidden 425,

26E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Powder, smokeless 1.3C UN0161 1.3C None 62 None Forbidden Forbidden 425,

26E

Powder, smokeless 1.4C UN0509 1.4C 16 171 62 None Forbidden 75 kg 2 25

Power device, explosive, see Cartridges, power device

Primers, cap type 1.4S UN0044 None None 62 None 25 kg 100 kg 1 25

Primers, cap type 1.1B UN0377 1.1B None 62 None Forbidden Forbidden 5 25

Primers, cap type 1.4B UN0378 1.4B None 62 None Forbidden 75 kg 5 25

Primers, small arms, see Primers, cap type

Primers, tubular 1.3G UN0319 1.3G None 62 None Forbidden Forbidden 3 25

Primers, tubular 1.4G UN0320 1.4G None 62 None Forbidden 75 kg 2 25

Primers, tubular 1.4S UN0376 None None 62 None 25 kg 100 kg 1 25

Printing ink, flammable or Printing ink related material

(including printing ink thinning or reducing compound),

flammable

3 UN1210 I 3 367, T11, TP1, TP8 150 173 243 1 L 30 L E

II 3149, 367, IB2, T4,

TP1, TP8150 173 242 5 L 60 L B

III 3 367, B1, IB3, T2, TP1 150 173 242 60 L 220 L A

Projectiles, illuminating, see Ammunition, illuminating,

etc

Projectiles, inert with tracer 1.4S UN0345 1.4S 62 62 25 kg 100 kg 1 25

Projectiles, inert, with tracer 1.3G UN0424 1.3G 62 62 Forbidden Forbidden 3 25

Projectiles, inert, with tracer 1.4G UN0425 1.4G 62 62 Forbidden 75 kg 2 25

Projectiles, with burster or expelling charge 1.2D UN0346 1.2D 62 62 Forbidden Forbidden 3 25

Projectiles, with burster or expelling charge 1.4D UN0347 1.4D 62 62 Forbidden 75 kg 2 25

Projectiles, with burster or expelling charge 1.2F UN0426 1.2F 62 None Forbidden Forbidden 3 25

Projectiles, with burster or expelling charge 1.4F UN0427 1.4F 62 None Forbidden Forbidden 3 25

Projectiles, with burster or expelling charge 1.2G UN0434 1.2G 62 62 Forbidden Forbidden 3 25

Projectiles, with burster or expelling charge 1.4G UN0435 1.4G 62 62 Forbidden 75 kg 2 25

Projectiles, with bursting charge 1.1F UN0167 1.1F 62 None Forbidden Forbidden 3 25

Projectiles, with bursting charge 1.1D UN0168 1.1D 62 62 Forbidden Forbidden 3 25

Projectiles, with bursting charge 1.2D UN0169 1.2D 62 62 Forbidden Forbidden 3 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Projectiles, with bursting charge 1.2F UN0324 1.2F 62 None Forbidden Forbidden 3 25

Projectiles, with bursting charge 1.4D UN0344 1.4D 62 62 Forbidden 75 kg 2 25

Propadiene, stabilized 2.1 UN2200 2.1 387 None 304314,


Propadiene mixed with methyl acetylene, see Methyl

acetylene and propadiene mixtures, stabilized

Propane, see also Petroleum gases, liquefied 2.1 UN1978 2.1 19, T50, N95 306 304314,


Propanethiols 3 UN2402 II 3 IB2, T4, TP1, TP13 150 202 242 5 L 60 L E95,

102

n-Propanol or Propyl alcohol, normal 3 UN1274 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Propellant, liquid 1.3C UN0495 1.3C 37 None 62 None Forbidden Forbidden 4 25

Propellant, liquid 1.1C UN0497 1.1C 37 None 62 None Forbidden Forbidden 4 25

Propellant, solid 1.1C UN0498 1.1C None 62 None Forbidden Forbidden 425,

26E

Propellant, solid 1.3C UN0499 1.3C None 62 None Forbidden Forbidden 425,

26E

Propellant, solid 1.4C UN0501 1.4C None 62 None Forbidden 75 kg 2 25

Propionaldehyde 3 UN1275 II 3 IB2, T7, TP1 150 202 242 5 L 60 L E

Propionic acid with not less than 90% acid by mass 8 UN3463 II 8, 3 IB2, T7, TP2 154 202 243 1 L 30 L A 53, 58

Propionic acid with not less than 10% and less than 90%

acid by mass8 UN1848 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 53, 58

Propionic anhydride 8 UN2496 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 53, 58

Propionitrile 3 UN2404 II 3, 6.1 IB2, T7, TP1, TP13 None 202 243 Forbidden 60 L E 40

Propionyl chloride 3 UN1815 II 3, 8 IB1, T7, TP1 150 202 243 1 L 5 L B40,

53, 58

n-Propyl acetate 3 UN1276 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Propyl alcohol, see Propanol

n-Propyl benzene 3 UN2364 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

n-Propyl chloroformate 6.1 UN2740 I6.1,

3, 8

2, B9, B14, B32, B77,

N34, T20, TP2, TP13,

TP38, TP44


21,

40,

53,

58,

100

Propyl chloride see 1-Chloropropane

Propyl formates 3 UN1281 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

n-Propyl isocyanate 6.1 UN2482 I 6.1, 3

1, B9, B14, B30, T20,

TP2, TP13, TP38,

TP44


Propyl mercaptan, see Propanethiols

n-Propyl nitrate 3 UN1865 II 3 IB9 150 202 None 5 L 60 L D

44,

89,

90,

100

Propylamine 3 UN1277 II 3, 8A7, IB2, N34, T7,

TP1150 202 243 1 L 5 L E 40, 52

Propylene see also Petroleum gases, liquefied 2.1 UN1077 2.1 19, T50 306 304314,


Propylene chlorohydrin 6.1 UN2611 II 6.1, 3 IB2, T7, TP2, TP13 153 202 243 5 L 60 L A12,

25, 40

Propylene oxide 3 UN1280 I 3 N34, T11, TP2, TP7 None 201 243 1 L 30 L E 40

Propylene tetramer 3 UN2850 III 3 B1, IB3, T2, TP2 150 203 242 60 L 220 L A

1,2-Propylenediamine 8 UN2258 II 8, 3A3, IB2, N34, T7,

TP2None 202 243 1 L 30 L A 40, 52

Propyleneimine, stabilized 3 UN1921 I 3, 6.1 N34, T14, TP2, TP13 None 201 243 1 L 30 L D 40

Propyltrichlorosilane 8 UN1816 II 8, 3A7, B2, B6, N34,


40,

53, 58

Prussic acid, see Hydrogen cyanide

Pyrethroid pesticide, liquid, flammable, toxic, flash


T14, TP2, TP13,





tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40

Pyrethroid pesticide, liquid toxic 6.1 UN3352 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1 IB2, T11, TP2, TP27 153 202 243 5L 60L B 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60L 220L A 40

Pyrethroid pesticide, liquid, toxic, flammable, flash


T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1, 3 IB3, T7, TP2, TP28 153 203 241 60 L 220 L B 40

Pyrethroid pesticide, solid, toxic 6.1 UN3349 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Pyridine 3 UN1282 II 3 IB2, T4, TP2 None 202 242 5 L 60 L B21,

100

Pyridine perchlorate Forbidden

G Pyrophoric liquid, inorganic, n.o.s 4.2 UN3194 I 4.2 None 181 244 Forbidden Forbidden D

13,

78,

148

G Pyrophoric liquids, organic, n.o.s 4.2 UN2845 I 4.2B11, T22, TP2, TP7,

W31None 187 244 Forbidden Forbidden D

13,

78,

148

G Pyrophoric metals, n.o.s., or Pyrophoric alloys, n.o.s 4.2 UN1383 I 4.2B11, T21, TP7, TP33,

W31None 187 242 Forbidden Forbidden D

13,

148

G Pyrophoric solid, inorganic, n.o.s 4.2 UN3200 I 4.2 T21, TP7, TP33, W31 None 187 242 Forbidden Forbidden D13,

148

G Pyrophoric solids, organic, n.o.s 4.2 UN2846 I 4.2 W31 None 187 242 Forbidden Forbidden D13,

148

Pyrosulfuryl chloride 8 UN1817 II 8 B2, IB2, T8, TP2 154 202 242 1 L 30 L C40,

53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Pyroxylin solution or solvent, see Nitrocellulose

Pyrrolidine 3 UN1922 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 40, 52

Quebrachitol pentanitrate Forbidden

Quicklime, see Calcium oxide

Quinoline 6.1 UN2656 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 12, 25

R 12, see Dichlorodifluoromethane

R 12B1, see Chlorodifluorobromomethane

R 13, see Chlorotrifluoromethane

R 13B1, see Bromotrifluoromethane

R 14, see Tetrafluoromethane

R 21, see Dichlorofluoromethane

R 22, see Chlorodifluoromethane

R 114, see Dichlorotetrafluoroethane

R 115, see Chloropentafluoroethane

R 116, see Hexafluoroethane

R 124, see Chlorotetrafluoroethane

R 133a, see Chlorotrifluoroethane

R 152a, see Difluoroethane

R 500, see Dichlorodifluoromethane and difluorethane,

etc

R 502, see Chlorodifluoromethane and

chloropentafluoroethane mixture, etc

R 503, see Chlorotrifluoromethane and

trifluoromethane, etc

Radioactive material, excepted package-articles

manufactured from natural uranium or depleted

uranium or natural thorium

7 UN2909 None 422,

426

422,

426

422,

426 A

Radioactive material, excepted package-empty

packaging7 UN2908

Empt

y368

422,

428

422,

428

422,

428A

Radioactive material, excepted package-instruments

or articles7 UN2911 None

422,

424

422,

424 A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Radioactive material, excepted package-limited

quantity of material7 UN2910 None 368

421,

422

421,

422

421,

422A

Radioactive material, low specific activity (LSA-I) non

fissile or fissile-excepted7 UN2912 7

325, A56, T5, TP4,

W7

421,

422,

428

427 427 A95,

129

Radioactive material, low specific activity (LSA-II) non

fissile or fissile-excepted7 UN3321 7

325, A56, T5, TP4,

W7

421,

422,

428

427 427 A95,

129

Radioactive material, low specific activity (LSA-III) non

fissile or fissile excepted7 UN3322 7

325, A56, T5, TP4,

W7

421,

422,

428

427 427 A95,

150

Radioactive material, surface contaminated objects

(SCO-I or SCO-II) non fissile or fissile-excepted7 UN2913 7 325, A56

421,

422,

428

427 427 A 95

Radioactive material, transported under special

arrangement, non fissile or fissile excepted7 UN2919 7 325, A56, 139 A

95,

105

Radioactive material, transported under special

arrangement, fissile7 UN3331 7 A56, 139 A

95,

105

Radioactive material, Type A package, fissile non-

special form7 UN3327 7 A56, W7, W8 453 417 417 A

95,

105,

131

Radioactive material, Type A package non-special

form, non fissile or fissile-excepted7 UN2915 7 325, A56, W7, W8 None

415,

418,

419

415,

418,

419

A95,

130

Radioactive material, Type A package, special form

non fissile or fissile-excepted7 UN3332 7 A56, W7, W8

415,

476

415,

476 A 95

Radioactive material, Type A package, special form,

fissile7 UN3333 7 A56, W7, W8 453

417,

476

417,

476 A

95,

105

Radioactive material, Type B(M) package, fissile 7 UN3329 7 A56 453 417 417 A95,

105

Radioactive material, Type B(M) package non fissile or

fissile-excepted7 UN2917 7 325, A56 416 416 A

95,

105




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Radioactive material, Type B(U) package, fissile 7 UN3328 7 A56 453 417 417 A95,

105

Radioactive material, Type B(U) package non fissile or

fissile-excepted7 UN2916 7 325, A56 416 416 A

95,

105

Radioactive material, uranium hexafluoride non fissile

or fissile-excepted7 UN2978

7,

6.1, 8423

420,

427

420,

427B

40,

74,

95,

132,

151,

153

Radioactive material, uranium hexafluoride, fissile 7 UN29777,

6.1, 8453

417,

420

417,

420B

40,

74,

95,

132,

151,

153

A W Rags, oily 4.2 UN1856 III 4.2 151 213 240 Forbidden Forbidden A

Railway torpedo, see Signals, railway track, explosive

RC 318, see Octafluorocyclobutane

RDX and cyclotetramethylenetetranitramine, wetted or

desensitized see RDX and HMX mixtures, wetted or

desensitized

RDX and HMX mixtures, wetted with not less than 15

percent water by mass or RDX and HMX mixtures,

desensitized with not less than 10 percent

phlegmatizer by mass


RDX and Octogen mixtures, wetted or desensitized see

RDX and HMX mixtures, wetted or desensitized etc

RDX, see Cyclotrimethylene trinitramine, etc




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Receptacles, small, containing gas or gas cartridges

(flammable) without release device, not refillable and

not exceeding 1 L capacity

2.1 UN2037 2.1 306 304 None 1 kg 15 kg B 40


(non-flammable) without release device, not refillable

and not exceeding 1 L capacity

2.2 UN2037 2.2 306 304 None 1 kg 15 kg B 40


(oxidizing) without release device, not refillable and not

exceeding 1 L capacity

2.2 UN2037 2.2,

5.1A14 306 304 None 1 kg 15 kg B 40

Red phosphorus, see Phosphorus, amorphous

Refrigerant gas R 404A 2.2 UN3337 2.2 T50 306 304314,

31575 kg 150 kg A

Refrigerant gas R 407A 2.2 UN3338 2.2 T50 306 304314,

31575 kg 150 kg A

Refrigerant gas R 407B 2.2 UN3339 2.2 T50 306 304314,

31575 kg 150 kg A

Refrigerant gas R 407C 2.2 UN3340 2.2 T50 306 304314,

31575 kg 150 kg A

G Refrigerant gases, n.o.s. 2.2 UN1078 2.2 T50 306 304314,

31575 kg 150 kg A

D Refrigerant gases, n.o.s. or Dispersant gases, n.o.s. 2.1 NA1954 2.1 T50 306 304314,


Refrigerating machines, containing flammable, non-

toxic, liquefied gas2.1 UN3358 2.1

306,

307306 306 Forbidden Forbidden D 40

Refrigerating machines, containing non-flammable,

non-toxic gases, or ammonia solutions (UN2672)2.2 UN2857 2.2 A53

306,

307306

306,

307450 kg 450 kg A

Regulated medical waste, n.o.s. or Clinical waste,

unspecified, n.o.s. or (BIO) Medical waste, n.o.s., or

Biomedical waste, n.o.s. or Medical waste, n.o.s

6.2 UN3291 II 6.2 41, A13, 337 134 197 197 No limit No limit B 40

Release devices, explosive 1.4S UN0173 1.4S None 62 62 25 kg 100 kg 1 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Resin Solution, flammable 3 UN1866 I 3B52, T11, TP1, TP8,

TP28150 201 243 1 L 30 L E

II 3149, B52, IB2, T4,

TP1, TP8150 173 242 5 L 60 L B

III 3 B1, B52, IB3, T2, TP1 150 173 242 60 L 220 L A

Resorcinol 6.1 UN2876 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Rifle grenade, see Grenades, hand or rifle, etc

Rifle powder, see Powder, smokeless (UN 0160)

Rivets, explosive 1.4S UN0174 1.4S None 62 62 25 kg 100 kg 1 25

Road asphalt or tar liquid, see Tars, liquid, etc

Rocket motors 1.3C UN0186 1.3C 109 None 62 62 Forbidden 220 kg 3 25

Rocket motors 1.1C UN0280 1.1C 109 None 62 62 Forbidden Forbidden 3 25

Rocket motors 1.2C UN0281 1.2C 109 None 62 62 Forbidden Forbidden 4 25

Rocket motors 1.4C UN0510 1.4C 109 None 62 62 Forbidden 75 kg 2 25

Rocket motors, liquid fueled 1.2J UN0395 1.2J 109 None 62 None Forbidden Forbidden 525,

23E

Rocket motors, liquid fueled 1.3J UN0396 1.3J 109 None 62 None Forbidden Forbidden 525,

23E

Rocket motors with hypergolic liquids with or without

an expelling charge1.3L UN0250 1.3L 109 None 62 None Forbidden Forbidden 5

25,

14E,

15E

Rocket motors with hypergolic liquids with or without

an expelling charge1.2L UN0322 1.2L 109 None 62 None Forbidden Forbidden 5

25,

14E,

15E

Rockets, line-throwing 1.2G UN0238 1.2G None 62 None Forbidden Forbidden 3 25

Rockets, line-throwing 1.3G UN0240 1.3G None 62 None Forbidden 75 kg 3 25

Rockets, line-throwing 1.4G UN0453 1.4G None 62 None Forbidden 75 kg 2 25

Rockets, liquid fueled with bursting charge 1.1J UN0397 1.1J None 62 None Forbidden Forbidden 525,

23E

Rockets, liquid fueled with bursting charge 1.2J UN0398 1.2J None 62 None Forbidden Forbidden 525,

23E

Rockets, with bursting charge 1.1F UN0180 1.1F None 62 None Forbidden Forbidden 3 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Rockets, with bursting charge 1.1E UN0181 1.1E None 62 62 Forbidden Forbidden 3 25

Rockets, with bursting charge 1.2E UN0182 1.2E None 62 62 Forbidden Forbidden 3 25

Rockets, with bursting charge 1.2F UN0295 1.2F None 62 None Forbidden Forbidden 3 25

Rockets, with expelling charge 1.2C UN0436 1.2C None 62 62 Forbidden Forbidden 3 25

Rockets, with expelling charge 1.3C UN0437 1.3C None 62 62 Forbidden Forbidden 3 25

Rockets, with expelling charge 1.4C UN0438 1.4C None 62 62 Forbidden 75 kg 2 25

Rockets, with inert head 1.3C UN0183 1.3C None 62 62 Forbidden Forbidden 3 25

Rockets, with inert head 1.2C UN0502 1.2C None 62 62 Forbidden Forbidden 3 25, 5E

Rosin oil 3 UN1286 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Rubber solution 3 UN1287 II 3149, IB2, T4, TP1,

TP8150 202 242 5 L 60 L B

III B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Rubber scrap or shoddy, powdered or granulated, not

exceeding 840 microns and rubber contend exceeding

45%

4.1 UN1345 II 4.1IB8, IP2, IP4, T3,

TP33151 212 240 15 kg 50 kg A

Rubidium 4.3 UN1423 I 4.3

22, A7, A19, IB4,

IP1, N34, N40, N45,

W31

None 211 242 Forbidden 15 kg D

13,

52,

148

Rubidium hydroxide 8 UN2678 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A

29,

52.

Rubidium hydroxide solution 8 UN2677 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A29,

52.

III 8 IB3, T4, TP1 154 203 241 5 L 60 L A29,

52.

Safety devices, electrically initiated 9 UN3268 9 160, A200 166 166 166 25 kg 100 kg A

Safety devices, pyrotechnic 1.4G UN0503 1.4G A200 None 62 None Forbidden 75 kg 2 25

Safety fuse, see Fuse, safety

G Samples, explosive, other than initiating explosives UN0190 113 None 62 None Forbidden Forbidden 5 25

Sand acid, see Fluorosilicic acid




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Seed cake, containing vegetable oil solvent extractions

and expelled seeds, with not more than 10 percent of

oil and when the amount of moisture is higher than 11

percent, with not more than 20 percent of oil and

moisture combined

4.2 UN1386 III NoneB136, IB8, IP3, IP7,

N7None 213 241 Forbidden Forbidden A 13, 25

ISeed cake with more than 1.5 percent oil and not more

than 11 percent moisture4.2 UN1386 III None

B136, IB8, IP3, IP7,

N7None 213 241 Forbidden Forbidden E 13, 25

ISeed cake with not more than 1.5 percent oil and not

more than 11 percent moisture4.2 UN2217 III None

B136, IB8, IP3, IP7,

N7None 213 241 Forbidden Forbidden A

13,

25,

120

G Selenates or Selenites 6.1 UN2630 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg E

Selenic acid 8 UN1905 I 8IB7, IP1, N34, T6,

TP33None 211 242 Forbidden 25 kg A 53, 58

G Selenium compound, liquid, n.o.s 6.1 UN3440 I 6.1 T14, TP2, TP27 None 201 243 1 L 30 L B

II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B

III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A

G Selenium compound, solid, n.o.s 6.1 UN3283 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B


Selenium disulfide 6.1 UN2657 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Selenium hexafluoride 2.3 UN2194 2.3, 8 1 None 302 None Forbidden Forbidden D 40

Selenium nitride Forbidden

Selenium oxychloride 8 UN2879 I 8, 6.1A7, N34, T10, TP2,

TP13None 201 243 0.5 L 2.5 L E

40,

53, 58

Self-defense spray, aerosol, see Aerosols, etc

+ A

DSelf-defense spray, non-pressurized 9 NA3334 III 9 A37 155 203 None No limit No limit A

G Self-heating liquid, corrosive, inorganic, n.o.s 4.2 UN3188 II 4.2, 8 IB2, W31 None 202 243 1 L 5 L C

III 4.2, 8 IB2, W31 None 203 241 5 L 60 L C




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Self-heating liquid, corrosive, organic, n.o.s 4.2 UN3185 II 4.2, 8 IB2, W31 None 202 243 1 L 5 L C

III 4.2, 8 IB2, W31 None 203 241 5 L 60 L C

G Self-heating liquid, inorganic, n.o.s 4.2 UN3186 II 4.2 IB2, W31 None 202 242 1 L 5 L C

III 4.2 IB2, W31 None 203 241 5 L 60 L C

G Self-heating liquid, organic, n.o.s 4.2 UN3183 II 4.2 IB2, W31 None 202 242 1 L 5 L C

III 4.2 IB2, W31 None 203 241 5 L 60 L C

G Self-heating liquid, toxic, inorganic, n.o.s 4.2 UN3187 II4.2,

6.1IB2, W31 None 202 243 1 L 5 L C

III4.2,

6.1IB2, W31 None 203 241 5 L 60 L C

G Self-heating liquid, toxic, organic, n.o.s 4.2 UN3184 II4.2,

6.1IB2, W31 None 202 243 1 L 5 L C

III4.2,

6.1IB2, W31 None 203 241 5 L 60 L C

G Self-heating solid, corrosive, inorganic, n.o.s. 4.2 UN3192 II 4.2, 8 IB5, IP2, T3, TP33 None 212 242 15 kg 50 kg C

III 4.2, 8 IB8, IP3, T1, TP33 None 213 242 25 kg 100 kg C

G Self-heating solid, corrosive, organic, n.o.s 4.2 UN3126 II 4.2, 8 IB5, IP2, T3, TP33 None 212 242 15 kg 50 kg C

III 4.2, 8 IB8, IP3, T1, TP33 None 213 242 25 kg 100 kg C

G Self-heating solid, inorganic, n.o.s 4.2 UN3190 II 4.2IB6, IP2, T3, TP33,

W31None 212 241 15 kg 50 kg C

III 4.2IB8, IP3, T1, TP33,

W31None 213 241 25 kg 100 kg C

G Self-heating solid, organic, n.o.s 4.2 UN3088 II 4.2IB6, IP2, T3, TP33,

W31None 212 241 15 kg 50 kg C

III 4.2B116, B130, IB8, IP3,

T1, TP33, W31None 213 241 25 kg 100 kg C

G Self-heating solid, oxidizing, n.o.s. 4.2 UN3127 4.2,


G Self-heating solid, toxic, inorganic, n.o.s. 4.2 UN3191 II4.2,

6.1IB5, IP2, T3, TP33 None 212 242 15 kg 50 kg C

III4.2,





tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Self-heating solid, toxic, organic, n.o.s 4.2 UN3128 II4.2,


III4.2,


Self-propelled vehicle, see Engines or Batteries etc

G Self-reactive liquid type B 4.1 UN3221 4.1 53 151 224 None Forbidden Forbidden D

25,

52,

53,

127

G Self-reactive liquid type B, temperature controlled 4.1 UN3231 4.1 53 None 224 None Forbidden Forbidden D2, 25,

52, 53

G Self-reactive liquid type C 4.1 UN3223 4.1 151 224 None 5 L 10 L D25,

52, 53

G Self-reactive liquid type C, temperature controlled 4.1 UN3233 4.1 None 224 None Forbidden Forbidden D2, 25,

52, 53

G Self-reactive liquid type D 4.1 UN3225 4.1 151 224 None 5 L 10 L D25,

52, 53

G Self-reactive liquid type D, temperature controlled 4.1 UN3235 4.1 None 224 None Forbidden Forbidden D2, 25,

52, 53

G Self-reactive liquid type E 4.1 UN3227 4.1 151 224 None 10 L 25 L D25,

52, 53

G Self-reactive liquid type E, temperature controlled 4.1 UN3237 4.1 None 224 None Forbidden Forbidden D2, 25,

52, 53

G Self-reactive liquid type F 4.1 UN3229 4.1 151 224 None 10 L 25 L D25,

52, 53

G Self-reactive liquid type F, temperature controlled 4.1 UN3239 4.1 None 224 None Forbidden Forbidden D2, 25,

52, 53

G Self-reactive solid type B 4.1 UN3222 4.1 53 151 224 None Forbidden Forbidden D

25,

52,

53,

127




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Self-reactive solid type B, temperature controlled 4.1 UN3232 4.1 53 None 224 None Forbidden Forbidden D2, 25,

52, 53

G Self-reactive solid type C 4.1 UN3224 4.1 151 224 None 5 kg 10 kg D25,

52, 53

G Self-reactive solid type C, temperature controlled 4.1 UN3234 4.1 None 224 None Forbidden Forbidden D2, 25,

52, 53

G Self-reactive solid type D 4.1 UN3226 4.1 151 224 None 5 kg 10 kg D25,

52, 53

G Self-reactive solid type D, temperature controlled 4.1 UN3236 4.1 None 224 None Forbidden Forbidden D2, 25,

52, 53

G Self-reactive solid type E 4.1 UN3228 4.1 151 224 None 10 kg 25 kg D25,

52, 53

G Self-reactive solid type E, temperature controlled 4.1 UN3238 4.1 None 224 None Forbidden Forbidden D2, 25,

52, 53

G Self-reactive solid type F 4.1 UN3230 4.1 151 224 None 10 kg 25 kg D25,

52, 53

G Self-reactive solid type F, temperature controlled 4.1 UN3240 4.1 None 224 None Forbidden Forbidden D2, 25,

52, 53

Shale oil 3 UN1288 I 3 T11, TP1, TP8, TP27 None 201 243 1 L 30 L B

II 3 IB2, T4, TP1, TP8 150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Shaped charges, see Charges, shaped, etc

Signal devices, hand 1.4G UN0191 1.4G 381 None 62 None Forbidden 75 kg 2 25

Signal devices, hand 1.4S UN0373 1.4S 381 None 62 None 25 kg 100 kg 1 25

Signals, distress, ship 1.1G UN0194 1.1G None 62 None Forbidden Forbidden 3 25

Signals, distress, ship 1.3G UN0195 1.3G None 62 None Forbidden 75 kg 3 25

Signals, distress, ship 1.4G UN0505 1.4G None 62 None Forbidden 75 kg 2 25

Signals, distress, ship 1.4S UN0506 1.4S None 62 None 25 kg 100 kg 1 25

Signals, highway, see Signal devices, hand

Signals, railway track, explosive 1.1G UN0192 1.1G None 62 None Forbidden Forbidden 3 25

Signals, railway track, explosive 1.4S UN0193 1.4S 381 None 62 None 25 kg 100 kg 1 25

Signals, railway track, explosive 1.3G UN0492 1.3G None 62 None Forbidden Forbidden 3 25

Signals, railway track, explosive 1.4G UN0493 1.4G None 62 None Forbidden 75 kg 2 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Signals, ship distress, water-activated, see

Contrivances, water-activated, etc

Signals, smoke 1.1G UN0196 1.1G None 62 None Forbidden Forbidden 3 25

Signals, smoke 1.4G UN0197 1.4G None 62 None Forbidden 75 kg 2 25



Signals, smoke 1.4S UN0507 1.4S None 62 None 25 kg 100 kg 1 25

Silane 2.1 UN2203 2.1 None 302 None Forbidden Forbidden E

40,

57,

104

Silicofluoric acid, see Fluorosilicic acid

Silicon chloride, see Silicon tetrachloride

Silicon powder, amorphous 4.1 UN1346 III 4.1A1, IB8, IP3, T1,

TP33None 213 240 25 kg 100 kg A 74

Silicon tetrachloride 8 UN1818 II 8A3, B2, B6, T10, TP2,

TP7, TP13None 202 242 Forbidden 30 L C

40,

53, 58

Silicon tetrafluoride 2.3 UN1859 2.3, 8 2 None 302 None Forbidden Forbidden D 40

Silicon tetrafluoride, adsorbed 2.3 UN3521 2.3, 8 2 None 302c None Forbidden Forbidden D 40

Silver acetylide (dry) Forbidden

Silver arsenite 6.1 UN1683 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Silver azide (dry) Forbidden

Silver chlorite (dry) Forbidden

Silver cyanide 6.1 UN1684 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40, 52

Silver fulminate (dry) Forbidden

Silver nitrate 5.1 UN1493 II 5.1IB8, IP2, IP4, T3,

TP33152 212 242 5 kg 25 kg A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Silver oxalate (dry) Forbidden

Silver picrate (dry) Forbidden

Silver picrate, wetted with not less than 30 percent

water, by mass4.1 UN1347 I 4.1 23, W31 None 211 None Forbidden Forbidden D 28, 36

Sludge, acid 8 UN1906 II 8A3, A7, B2, IB2, N34,

T8, TP2, TP28None 202 242 Forbidden 30 L C

14,

53, 58

D Smokeless powder for small arms (100 pounds or less ) 4.1 NA3178 I 4.1 16 None 171 None Forbidden 7.3 kg A

Soda lime with more than 4 percent sodium hydroxide 8 UN1907 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 52

Sodium 4.3 UN1428 I 4.3

A7, A8, A19, A20,

B9, B48, B68, IB4,

IP1, N34, T9, TP7,

TP33, TP46, W31


13,

52,

148

A Sodium aluminate, solid 8 UN2812 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A

Sodium aluminate, solution 8 UN1819 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A 52

III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 52

Sodium aluminum hydride 4.3 UN2835 II 4.3A8, A19, A20, IB4,

T3, TP33, W31, W40151 212 242 Forbidden 50 kg E

13,

52,

148

Sodium ammonium vanadate 6.1 UN2863 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Sodium arsanilate 6.1 UN2473 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Sodium arsenate 6.1 UN1685 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Sodium arsenite, aqueous solutions 6.1 UN1686 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

III 6.1 IB3, T4, TP2 153 203 241 60 L 220 L A

Sodium arsenite, solid 6.1 UN2027 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Sodium azide 6.1 UN1687 II 6.1 IB8, IP2, IP4 153 212 242 25 kg 100 kg A36,

52, 91




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Sodium bifluoride, see Sodium hydrogendifluoride

Sodium bisulfite, solution, see Bisulfites, aqueous

solutions, n.o.s.

Sodium borohydride 4.3 UN1426 I 4.3 N40, W31 None 211 242 Forbidden 15 kg E

13,

52,

148

Sodium borohydride and sodium hydroxide solution,

with not more than 12 percent sodium borohydride and

not more than 40 percent sodium hydroxide by mass

8 UN3320 II 8 B2, IB2, N34, T7, TP2 154 202 242 1 L 30 L A 52

III 8 B2, IB3, N34, T4, TP2 154 203 241 5 L 60 L A 52

Sodium bromate 5.1 UN1494 II 5.1IB8, IP2, IP4, T3,

TP33152 212 242 5 kg 25 kg A 56, 58

Sodium cacodylate 6.1 UN1688 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 52

Sodium carbonate peroxyhydrate 5.1 UN3378 II 5.1B120, IB8, IP2, IP4,

T3, TP33152 212 240 5 kg 25 kg A

13,

25, 75

III 5.1B120, IB8, IP3, T1,

TP33152 213 240 25 kg 100 kg A

13,

25, 75

Sodium chlorate 5.1 UN1495 II 5.1A9, IB8, IP2, IP4,

N34, T3, TP33152 212 240 5 kg 25 kg A 56, 58

Sodium chlorate, aqueous solution 5.1 UN2428 II 5.1 A2, IB2, T4, TP1 152 202 241 1 L 5 L B

56,

58,

133

III 5.1 A2, IB2, T4, TP1 152 203 241 2.5 L 30 L B

56,

58,

69,

133

Sodium chlorate mixed with dinitrotoluene, see

Explosive blasting, type C




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Sodium chlorite 5.1 UN1496 II 5.1A9, IB8, IP2, IP4,

N34, T3, TP33None 212 242 5 kg 25 kg A 56, 58

Sodium chloroacetate 6.1 UN2659 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

Sodium cuprocyanide, solid 6.1 UN2316 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 52

Sodium cuprocyanide, solution 6.1 UN2317 I 6.1 T14, TP2, TP13 None 201 243 1 L 30 L B 40, 52

Sodium cyanide, solid 6.1 UN1689 I 6.1B69, B77, IB7, N74,

N75, T6, TP33, W31None 211 242 5 kg 50 kg B 52

Sodium cyanide solution 6.1 UN3414 I 6.1B69, B77, N74, N75,

T14, TP2, TP13, W31None 201 243 1 L 30 L B 52

II 6.1

B69, B77, IB2, N74,

N75, T11, TP2, TP13,

TP27, W31

153 202 243 5 L 60 L B 52

III 6.1

B69, B77, IB3, N74,

N75, T7, TP2, TP13,

TP28, W31

153 203 241 60 L 220 L A 52

Sodium dichloroisocyanurate or Sodium dichloro-s-

triazinetrione, see Dichloroisocyanuric acid etc

Sodium dinitro-o-cresolate, dry or wetted with less than

15 percent water, by mass1.3C UN0234 1.3C None 62 None Forbidden Forbidden 4 25, 5E

Sodium dinitro-o-cresolate, wetted with not less than

10% water, by mass4.1 UN3369 I 4.1

162, A8, A19, N41,

N84, W31None 211 None 0.5 kg 0.5 kg E 28, 36

Sodium dinitro-o-cresolate, wetted with not less than

15 percent water, by mass4.1 UN1348 I

4.1,

6.1

23, A8, A19, A20,


Sodium dithionite or Sodium hydrosulfite 4.2 UN1384 II 4.2A19, A20, IB6, IP2,

T3, TP33, W31None 212 241 15 kg 50 kg E 13

Sodium fluoride, solid 6.1 UN1690 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52

Sodium fluoride solution 6.1 UN3415 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 52

Sodium fluoroacetate 6.1 UN2629 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg E

Sodium fluorosilicate 6.1 UN2674 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52

Sodium hydrate, see Sodium hydroxide, solid




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Sodium hydride 4.3 UN1427 I 4.3 A19, N40, W31 None 211 242 Forbidden 15 kg E

13,

52,

148

Sodium hydrogendifluoride 8 UN2439 II 8IB8, IP2, IP4, N3,

N34, T3, TP33154 212 240 15 kg 50 kg A

12,

25,

40,

52,

53, 58

Sodium hydrosulfide, with less than 25 percent water

of crystallization4.2 UN2318 II 4.2

A7, A19, A20, IB6,

IP2, T3, TP33, W31None 212 241 15 kg 50 kg A 52

Sodium hydrosulfide with not less than 25 percent

water of crystallization8 UN2949 II 8

A7, IB8, IP2, IP4, T7,

TP2154 212 240 15 kg 50 kg A 52

Sodium hydrosulfite, see Sodium dithionite

Sodium hydroxide, solid 8 UN1823 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A 52

Sodium hydroxide solution 8 UN1824 II 8 B2, IB2, N34, T7, TP2 154 202 242 1 L 30 L A 52

III 8 IB3, N34, T4, TP1 154 203 241 5 L 60 L A 52

Sodium hypochlorite, solution, see Hypochlorite

solutions etc

Sodium metal, liquid alloy, see Alkali metal alloys,

liquid, n.o.s.

Sodium methylate 4.2 UN1431 II 4.2, 8A7, A19, IB5, IP2,

T3, TP33, W31None 212 242 15 kg 50 kg B

Sodium methylate solutions in alcohol 3 UN1289 II 3, 8 IB2, T7, TP1, TP8 150 202 243 1 L 5 L B

III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A

Sodium monoxide 8 UN1825 II 8IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A 52

Sodium nitrate 5.1 UN1498 III 5.1A1, A29, B120, IB8,

IP3, T1, TP33, W1152 213 240 25 kg 100 kg A

Sodium nitrate and potassium nitrate mixtures 5.1 UN1499 III 5.1A1, A29, B120, IB8,

IP3, T1, TP33, W1152 213 240 25 kg 100 kg A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Sodium nitrite 5.1 UN1500 III5.1,

6.1

A1, A29, IB8, IP3,

T1, TP33152 213 240 25 kg 100 kg A 56, 58

Sodium pentachlorophenate 6.1 UN2567 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Sodium perborate monohydrate 5.1 UN3377 III 5.1B120, IB8, IP3, T1,

TP33152 213 240 25 kg 100 kg A

13,

25, 75

Sodium perchlorate 5.1 UN1502 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58

Sodium permanganate 5.1 UN1503 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg D

56,

58,

138

Sodium peroxide 5.1 UN1504 I 5.1 A20, IB5, IP1, N34 None 211 None Forbidden 15 kg C

13,

52,

66,

75,

148

Sodium peroxoborate, anhydrous 5.1 UN3247 II 5.1IB8, IP2, IP4, T3,

TP33152 212 240 5 kg 25 kg A 13, 25

Sodium persulfate 5.1 UN1505 III 5.1A1, IB8, IP3, T1,

TP33152 213 240 25 kg 100 kg A

58,

145

Sodium phosphide 4.3 UN1432 I4.3,


13,

40,

52,

85,

148

Sodium picramate, dry or wetted with less than 20

percent water, by mass1.3C UN0235 1.3C None 62 None Forbidden Forbidden 4 25, 5E

Sodium picramate, wetted with not less than 20

percent water, by mass4.1 UN1349 I 4.1

23, A8, A19, N41,

W31None 211 None Forbidden 15 kg E 28, 36

Sodium picryl peroxide Forbidden

Sodium potassium alloys, see Potassium sodium alloys

Sodium selenate, see Selenates or Selenites




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Sodium sulfide, anhydrous or Sodium sulfide with less

than 30 percent water of crystallization4.2 UN1385 II 4.2

A19, A20, IB6, IP2,

N34, T3, TP33, W31,

W40

None 212 241 15 kg 50 kg A 52

Sodium sulfide, hydrated with not less than 30 percent

water8 UN1849 II 8

IB8, IP2, IP4, T3,

TP33154 212 240 15 kg 50 kg A 52

Sodium superoxide 5.1 UN2547 I 5.1 A20, IB6, IP1, N34 None 211 None Forbidden 15 kg D

13,

52,

66,

75,

148

Sodium tetranitride Forbidden

G Solids containing corrosive liquid, n.o.s. 8 UN3244 II 8 49, IB5, T3, TP33 154 212 240 15 kg 50 kg B 40

G Solids containing flammable liquid, n.o.s. 4.1 UN3175 II 4.147, IB6, IP2, T3,

TP33151 212 240 15 kg 50 kg B

G Solids containing toxic liquid, n.o.s. 6.1 UN3243 II 6.1 48, IB2, T2, TP33 153 212 240 25 kg 100 kg B 40

Sounding devices, explosive 1.2F UN0204 1.2F None 62 62 Forbidden Forbidden 3 25

Sounding devices, explosive 1.1F UN0296 1.1F None 62 62 Forbidden Forbidden 3 25

Sounding devices, explosive 1.1D UN0374 1.1D None 62 62 Forbidden Forbidden 3 25

Sounding devices, explosive 1.2D UN0375 1.2D None 62 62 Forbidden Forbidden 3 25

Spirits of salt, see Hydrochloric acid

Squibs, see Igniters etc

Stannic chloride, anhydrous 8 UN1827 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L C 53, 58

Stannic chloride pentahydrate 8 UN2440 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 53, 58

Stannic phosphide 4.3 UN1433 I4.3,

6.1A19, N40, W31 None 211 242 Forbidden 15 kg E

13,

40,

52,

85,

148

Steel swarf, see Ferrous metal borings, etc

Stibine 2.3 UN2676 2.3,

2.11 None 304 None Forbidden Forbidden D 40

Storage batteries, wet, see Batteries, wet etc




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Strontium arsenite 6.1 UN1691 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Strontium chlorate 5.1 UN1506 II 5.1A1, A9, IB8, IP2, IP4,

N34, T3, TP33152 212 242 5 kg 25 kg A 56, 58

Strontium nitrate 5.1 UN1507 III 5.1A1, A29, IB8, IP3,

T1, TP33152 213 240 25 kg 100 kg A

Strontium perchlorate 5.1 UN1508 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58

Strontium peroxide 5.1 UN1509 II 5.1IB6, IP2, T3, TP33,

W100152 212 242 5 kg 25 kg C

13,

52,

66,

75,

148

Strontium phosphide 4.3 UN2013 I4.3,


13,

40,

52,

85,

148

Strychnine or Strychnine salts 6.1 UN1692 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

Styphnic acid, see Trinitroresorcinol, etc

Styrene monomer, stabilized 3 UN2055 III 3 387, B1, IB3, T2, TP1 150 203 242 60 L 220 L C 25

G Substances, explosive, n.o.s. 1.1L UN0357 1.1L 101 None 62 None Forbidden Forbidden 5

25,

14E,

15E


25,

14E,

15E


25,

14E,

15E

G Substances, explosive, n.o.s. 1.1A UN0473 1.1A 101, 111 None 62 None Forbidden Forbidden 5 25

G Substances, explosive, n.o.s. 1.1C UN0474 1.1C 101 None 62 None Forbidden Forbidden 4 25

G Substances, explosive, n.o.s. 1.1D UN0475 1.1D 101 None 62 None Forbidden Forbidden 4 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Substances, explosive, n.o.s. 1.1G UN0476 1.1G 101 None 62 None Forbidden Forbidden 3 25

G Substances, explosive, n.o.s. 1.3C UN0477 1.3C 101 None 62 None Forbidden Forbidden 4 25

G Substances, explosive, n.o.s. 1.3G UN0478 1.3G 101 None 62 None Forbidden Forbidden 3 25

G Substances, explosive, n.o.s. 1.4C UN0479 1.4C 101 None 62 None Forbidden 75 kg 2 25

G Substances, explosive, n.o.s. 1.4D UN0480 1.4D 101 None 62 None Forbidden 75 kg 2 25

G Substances, explosive, n.o.s 1.4S UN0481 1.4S 101, 347 None 62 None 25 kg 75 kg 1 25

G Substances, explosive, n.o.s. 1.4G UN0485 1.4G 101 None 62 None Forbidden 75 kg 2 25

GSubstances, explosive, very insensitive, n.o.s. or

Substances, EVI, n.o.s.1.5D UN0482 1.5D 101 None 62 None Forbidden Forbidden 3 25

Substituted nitrophenol pesticides, liquid, flammable,

toxic, flash point less than 23 degrees C3 UN2780 I 3, 6.1

T14, TP2, TP13,


II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40

Substituted nitrophenol pesticides, liquid, toxic 6.1 UN3014 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40

Substituted nitrophenol pesticides, liquid, toxic,


T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1, 3B1, IB3, T7, TP2,

TP28153 203 242 60 L 220 L A 40

Substituted nitrophenol pesticides, solid, toxic 6.1 UN2779 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Sucrose octanitrate (dry) Forbidden

Sulfamic acid 8 UN2967 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

D Sulfur 9 NA1350 III 9 30, B120, IB8, IP2 None None 240 No Limit No Limit A 25, 74

I Sulfur 4.1 UN1350 III 4.130, B120, IB8, IP3,

T1, TP33None None 240 25 kg 100 kg A 25, 74

Sulfur and chlorate, loose mixtures of Forbidden

Sulfur chlorides 8 UN1828 I 85, A7, A10, B10,

B77, N34, T20, TP2None 201 243 Forbidden 2.5 L C

40,

53, 58

Sulfur dichloride, see Sulfur chlorides

Sulfur dioxide 2.3 UN1079 2.3, 8 3, B14, T50, TP19 None 304314,


Sulfur dioxide solution, see Sulfurous acid

Sulfur hexafluoride 2.2 UN1080 2.2 306 304314,

31575 kg 150 kg A

D Sulfur, molten 9 NA2448 III 930,B13, IB3, R1, T1,

TP3None 213 247 Forbidden Forbidden C 61

I Sulfur, molten 4.1 UN2448 III 4.130, B13, IB1, R1, T1,

TP3None 213 247 Forbidden Forbidden C 74

Sulfur tetrafluoride 2.3 UN2418 2.3, 8 1 None 302 245 Forbidden Forbidden D 40, 52

+ Sulfur trioxide, stabilized 8 UN1829 I 8, 6.1

2, 387, B9, B14, B32,

B49, B77, N34, T20,

TP4, TP13, TP25,

TP26, TP38, TP45


25,

40,

53, 58

Sulfuretted hydrogen, see Hydrogen sulfide

Sulfuric acid, fuming with less than 30 percent free

sulfur trioxide8 UN1831 I 8

A7, N34, T20,

TP2,TP13None 201 243 Forbidden 2.5 L C

14,

40,

53, 58

Sulfuric acid, fuming with 30 percent or more free

sulfur trioxide8 UN1831 I 8, 6.1

2, B9, B14, B32, B77,

B84, N34, T20, TP2,

TP12, TP13

None 227 244 Forbidden Forbidden C 53, 58

Sulfuric acid, spent 8 UN1832 II 8

A3, A7, B2, B83,

B84, IB2, N34, T8,

TP2

None 202 242 Forbidden 30 L C14,

53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Sulfuric acid with more than 51 percent acid 8 UN1830 II 8

A3, A7, B3, B83,

B84, IB2, N34, T8,

TP2

154 202 242 1 L 30 L C14,

53, 58

Sulfuric acid with not more than 51% acid 8 UN2796 II 8

386, A3, A7, B2,

B15, IB2, N6, N34,

T8, TP2

154 202 242 1 L 30 L B 53, 58

Sulfuric and hydrofluoric acid mixtures, see

Hydrofluoric and sulfuric acid mixtures

Sulfuric anhydride, see Sulfur trioxide, stabilized

Sulfurous acid 8 UN1833 II 8 B3, IB2, T7, TP2 154 202 242 1 L 30 L B40,

53, 58

+ Sulfuryl chloride 6.1 UN1834 I 6.1, 8

1, B6, B9, B10, B14,

B30, B77, N34, T22,

TP2, TP13, TP38,

TP44


53, 58

Sulfuryl fluoride 2.3 UN2191 2.3 4 None 304314,


Tars, liquid including road oils and cutback bitumens 3 UN1999 II 3149, B13, IB2, T3,

TP3, TP29150 202 242 5 L 60 L B

III 3 B1, B13, IB3, T1, TP3 150 203 242 60 L 220 L A

Tear gas candles 6.1 UN17006.1,

4.1None 340 None Forbidden 50 kg D 40

Tear gas cartridges, see Ammunition, tear-producing,

etc

DTear gas devices with more than 2 percent tear gas

substances, by mass6.1 NA1693 I 6.1 None 340 None Forbidden Forbidden D 40

II 6.1 None 340 None Forbidden Forbidden D 40

Tear gas devices, with not more than 2 percent tear

gas substances, by mass, see Aerosols, etc

Tear gas grenades, see Tear gas candles

G Tear gas substances, liquid, n.o.s 6.1 UN1693 I 6.1 W31 None 201 None Forbidden Forbidden D 40

II 6.1 IB2, W31 None 202 None Forbidden 5 L D 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Tear gas substance, solid, n.o.s 6.1 UN3448 I 6.1 T6, TP33, W31 None 211 242 Forbidden Forbidden D 40

II 6.1IB8, IP2, IP4, T3,

TP33, W31None 212 242 Forbidden 25 kg D 40

G Tellurium compound, n.o.s 6.1 UN3284 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B


Tellurium hexafluoride 2.3 UN2195 2.3, 8 1 None 302 None Forbidden Forbidden D 40

Terpene hydrocarbons, n.o.s. 3 UN2319 III 3B1, IB3, T4, TP1,

TP29150 203 242 60 L 220 L A

Terpinolene 3 UN2541 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Tetraazido benzene quinone Forbidden

Tetrabromoethane 6.1 UN2504 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

1,1,2,2-Tetrachloroethane 6.1 UN1702 II 6.1 IB2, N36, T7, TP2 153 202 243 5 L 60 L A 40

Tetrachloroethylene 6.1 UN1897 III 6.1 IB3, N36, T4, TP1 153 203 241 60 L 220 L A 40

Tetraethyl dithiopyrophosphate 6.1 UN1704 II 6.1 IB2, T7, TP2 153 212 242 25 kg 100 kg D 40

Tetraethyl silicate 3 UN1292 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Tetraethylammonium perchlorate (dry) Forbidden

Tetraethylenepentamine 8 UN2320 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 52

1,1,1,2-Tetrafluoroethane or Refrigerant gas R 134a 2.2 UN3159 2.2 T50 306 304314,

31575 kg 150 kg A

Tetrafluoroethylene, stabilized 2.1 UN1081 2.1 387 306 304 None Forbidden 150 kg E 25, 40

Tetrafluoromethane or Refrigerant gas R 14 2.2 UN1982 2.2 None 302 None 75 kg 150 kg A

1,2,3,6-Tetrahydrobenzaldehyde 3 UN2498 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Tetrahydrofuran 3 UN2056 II 3 IB2, T4, TP1 None 202 242 5 L 60 L B

Tetrahydrofurfurylamine 3 UN2943 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Tetrahydrophthalic anhydrides with more than 0.05

percent of maleic anhydride8 UN2698 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 53, 58

1,2,3,6-Tetrahydropyridine 3 UN2410 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Tetrahydrothiophene 3 UN2412 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Tetramethylammonium hydroxide, solid 8 UN3423 II 8B2, IB8, IP2, IP4, T3,

TP33154 213 240 15 kg 50 kg A 52

Tetramethylammonium hydroxide solution 8 UN1835 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A 52

III 8 B2, IB3, T7, TP2 154 203 241 5 L 60 L A 52

Tetramethylene diperoxide dicarbamide Forbidden

Tetramethylsilane 3 UN2749 I 3 A7, T14, TP2 None 201 243 Forbidden 30 L D

Tetranitro diglycerin Forbidden

Tetranitroaniline 1.1D UN0207 1.1D None 62 None Forbidden Forbidden 4 25

+ Tetranitromethane 6.1 UN1510 I6.1,

5.1

2, B32, T20, TP2,

TP13, TP38, TP44None 227 None Forbidden Forbidden D 40, 6

2,3,4,6-Tetranitrophenol Forbidden

2,3,4,6-Tetranitrophenyl methyl nitramine Forbidden

2,3,4,6-Tetranitrophenylnitramine Forbidden

Tetranitroresorcinol (dry) Forbidden

2,3,5,6-Tetranitroso-1,4-dinitrobenzene Forbidden

2,3,5,6-Tetranitroso nitrobenzene (dry) Forbidden

Tetrapropylorthotitanate 3 UN2413 III 3 B1, IB3, T4, TP1 150 203 242 60 L 220 L A

Tetrazene, see Guanyl nitrosaminoguanyltetrazene

Tetrazine (dry) Forbidden

Tetrazol-1-acetic acid 1.4C UN0407 1.4C None 62 None Forbidden 75 kg 2 25

1H-Tetrazole 1.1D UN0504 1.1D None 62 None Forbidden Forbidden 4 25, 5E

Tetrazolyl azide (dry) Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Tetryl, see Trinitrophenylmethylnitramine

A I

WTextile waste, wet 4.2 UN1857 III 4.2 151 213 240 Forbidden Forbidden A

Thallium chlorate 5.1 UN2573 II5.1,

6.1IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58

G Thallium compounds, n.o.s 6.1 UN1707 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Thallium nitrate 6.1 UN2727 II6.1,

5.1IB6, IP2, T3, TP33 153 212 242 5 kg 25 kg A

4-Thiapentanal 6.1 UN2785 III 6.1 IB3, T4, TP1, W31 153 203 241 60 L 220 L D 25, 49

Thioacetic acid 3 UN2436 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Thiocarbamate pesticide, liquid, flammable, toxic,


T14, TP2, TP13,


II 3, 6.1 IB2, T11, TP13, TP27 150 202 243 1 L 60 L B 40

Thiocarbamate pesticide, liquid, toxic, flammable,

flash point not less than 23 degrees C6.1 UN3005 I 6.1, 3 T14, TP2, TP13 None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1, 3 IB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40

Thiocarbamate pesticide, liquid, toxic 6.1 UN3006 I 6.1 T14, TP2, TP13 None 201 243 1 L 30 L B 40

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40

Thiocarbamate pesticides, solid, toxic 6.1 UN2771 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Thiocarbonylchloride, see Thiophosgene

Thioglycol 6.1 UN2966 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

Thioglycolic acid 8 UN1940 II 8A7, B2, IB2, N34, T7,

TP2154 202 242 1 L 30 L A 53, 58




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Thiolactic acid 6.1 UN2936 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

Thionyl chloride 8 UN1836 I 8B6, B10, N34, T10,

TP2, TP13None 201 243 Forbidden Forbidden C

40,

53, 58

Thiophene 3 UN2414 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40

+ Thiophosgene 6.1 UN2474 I 6.1

2, B9, B14, B32, N33,

N34, T20, TP2, TP13,

TP38, TP45


Thiophosphoryl chloride 8 UN1837 II 8A3, A7, B2, B8, B25,

IB2, N34, T7, TP2None 202 242 Forbidden 30 L C

40,

53, 58

Thiourea dioxide 4.2 UN3341 II 4.2IB6, IP2, T3, TP33,

W31None 212 241 15 kg 50 kg D

III 4.2IB8, IP3, T1, TP33,

W31None 213 241 25 kg 100 kg D

Tin chloride, fuming, see Stannic chloride, anhydrous

Tin perchloride or Tin tetrachloride, see Stannic

chloride, anhydrous

Tinctures, medicinal 3 UN1293 II 3 IB2, T4, TP1, TP8 150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Tinning flux, see Zinc chloride

Tires and tire assemblies, see Air, compressed or

Nitrogen, compressed

Titanium disulphide 4.2 UN3174 III 4.2IB8, IP3, T1, TP33,

W31None 213 241 25 kg 100 kg A

Titanium hydride 4.1 UN1871 II 4.1A19, A20, IB4, N34,

T3, TP33, W31, W40None 212 241 15 kg 50 kg E

Titanium powder, dry 4.2 UN2546 I 4.2 W31 None 211 242 Forbidden Forbidden D13,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II 4.2

A19, A20, IB6, IP2,

N5, N34, T3, TP33,

W31

None 212 241 15 kg 50 kg D13,

148

III 4.2B135, IB8, IP21, T1,

TP33, W31None 213 241 25 kg 100 kg D

13,

148

Titanium powder, wetted with not less than 25 percent

water (a visible excess of water must be present) (a)

mechanically produced, particle size less than 53

microns; (b) chemically produced, particle size less than

840 microns

4.1 UN1352 II 4.1

A19, A20, IB6, IP2,

N34, T3, TP33, W31,

W40

None 212 240 15 kg 50 kg E 74

Titanium sponge granules or Titanium sponge powders 4.1 UN2878 III 4.1A1, B134, IB8, IP21,

T1, TP33, W100None 213 240 25 kg 100 kg D

13,

74,

147,

148

+ Titanium tetrachloride 6.1 UN1838 I 6.1, 8

2, B7, B9, B14, B32,

B77, T20, TP2, TP13,

TP38, TP45


53, 58

Titanium trichloride mixtures 8 UN2869 II 8A7, IB8, IP2, IP4,

N34, T3, TP33154 212 240 15 kg 50 kg A

40,

53, 58

III 8A7, IB8, IP3, N34,

T1, TP33154 213 240 25 kg 100 kg A

40,

53, 58

Titanium trichloride, pyrophoric or Titanium trichloride

mixtures, pyrophoric4.2 UN2441 I 4.2, 8 N34, W31 None 181 244 Forbidden Forbidden D

13,

40,

148

TNT mixed with aluminum, see Tritonal

TNT, see Trinitrotoluene, etc

Toluene 3 UN1294 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

+ Toluene diisocyanate 6.1 UN2078 II 6.1 IB2, T7, TP2, TP13 153 202 243 5 L 60 L D 25, 40

Toluene sulfonic acid, see Alkyl, or Aryl sulfonic acid

etc

+ Toluidines, liquid 6.1 UN1708 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

Toluidines, solid 6.1 UN3451 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

2,4-Toluylenediamine, solid or 2,4-Toluenediamine,

solid6.1 UN1709 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A

2,4-Toluylenediamine solution or 2,4-Toluenediamine

solution6.1 UN3418 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Torpedoes, liquid fueled, with inert head 1.3J UN0450 1.3J 62 None Forbidden Forbidden 525,

23E

Torpedoes, liquid fueled, with or without bursting

charge1.1J UN0449 1.1J 62 None Forbidden Forbidden 5

25,

23E

Torpedoes with bursting charge 1.1E UN0329 1.1E 62 62 Forbidden Forbidden 3 25

Torpedoes with bursting charge 1.1F UN0330 1.1F 62 None Forbidden Forbidden 3 25

Torpedoes with bursting charge 1.1D UN0451 1.1D 62 62 Forbidden Forbidden 3 25

G

Toxic by inhalation liquid, flammable, corrosive, n.o.s.

with an LC50 lower than or equal to 200 ml/m3 and

saturated vapor concentration greater than or equal to

500 LC50

6.1 UN3488 I6.1,

3, 8

1, B9, B14, B30, T22,

TP2, TP13, TP27,

TP38, TP44


125

G

Toxic by inhalation liquid, flammable, corrosive, n.o.s.

with an LC50 lower than or equal to 1000 ml/m3 and


10 LC50

6.1 UN3489 I6.1,

3, 8

2, B9, B14, B32, T20,

TP2, TP13, TP27,

TP38, TP45


125

G

Toxic by inhalation liquid, n.o.s. with an LC50 lower

than or equal to 200 ml/m3

and saturated vapor

concentration greater than or equal to 500 LC50

6.1 UN3381 I 6.1

1, B9, B14, B30, T22,

TP2, TP13, TP27,

TP38, TP44


G

Toxic by inhalation liquid, n.o.s. with an LC50 lower

than or equal to 1000 ml/m3

and saturated vapor


6.1 UN3382 I 6.1

2, B9, B14, B32, T20,

TP2, TP13, TP27,

TP38, TP45


G

Toxic by inhalation liquid, flammable, n.o.s. with an

LC50 lower than or equal to 200 ml/m3

and saturated

vapor concentration greater than or equal to 500 LC50

6.1 UN3383 I 6.1, 3

1, B9, B14, B30, T22,

TP2, TP13, TP27,

TP38, TP44





tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G

Toxic by inhalation liquid, flammable, n.o.s. with an

LC50 lower than or equal to 1000 ml/m3

and


10 LC50

6.1 UN3384 I 6.1, 3

2, B9, B14, B32, T20,

TP2, TP13, TP27,

TP38, TP45


G

Toxic by inhalation liquid, water-reactive, n.o.s. with

an LC50 lower than or equal to 200 ml/m3

and


500 LC50

6.1 UN3385 I6.1,

4.3

1, B9, B14, B30, T22,

TP2, TP13, TP38,

TP44


13,

40,

148

G

Toxic by inhalation liquid, water-reactive, n.o.s. with

an LC50 lower than or equal to 1000 ml/m3

and


10 LC50

6.1 UN3386 I6.1,

4.3

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP44


13,

40,

148

G

Toxic by inhalation liquid, water-reactive, flammable,

n.o.s. with an LC50 lower than or equal to 200 ml/ m3

and saturated vapor concentration greater than or

equal to 500 LC50

6.1 UN3490 I6.1,

4.3, 3

1, B9, B14, B30, T22,

TP2, TP13, TP27,

TP38, TP44


13,

21,

40,

49,

148

G

Toxic by inhalation liquid, water-reactive, flammable,

n.o.s. with an LC50 lower or equal to 1000 ml/m3 and


10 LC50

6.1 UN3491 I6.1,

4.3, 3

2, B9, B14, B32, T20,

TP2, TP13, TP27,

TP38, TP45


13,

21,

28,

40,

49,

148

G

Toxic by inhalation liquid, oxidizing, n.o.s. with an LC50

lower than or equal to 200 ml/m3

and saturated vapor


6.1 UN3387 I6.1,

5.1

1, B9, B14, B30, T22,

TP2, TP13, TP38,

TP44


G

Toxic by inhalation liquid, oxidizing, n.o.s. with an LC50


and saturated


6.1 UN3388 I6.1,

5.1

2, B9, B14, B32, T20,

TP2, TP13, TP38,

TP44





tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G

Toxic by inhalation liquid, corrosive, n.o.s. with an LC50


and saturated vapor


6.1 UN3389 I 6.1, 8

1, B9, B14, B30, T22,

TP2, TP13, TP27,

TP38, TP44


G

Toxic by inhalation liquid, corrosive, n.o.s. with an LC50


and saturated


6.1 UN3390 I 6.1, 8

2, B9, B14, B32, T20,

TP2, TP13, TP27,

TP38, TP45


G Toxic liquid, corrosive, inorganic, n.o.s 6.1 UN3289 I 6.1, 8T14, TP2, TP13,

TP27None 201 243 0.5 L 2.5 L A 40

II 6.1, 8 IB2, T11, TP2, TP27 153 202 243 1 L 30 L A 40

G Toxic liquid, inorganic, n.o.s 6.1 UN3287 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L A 40

II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L A 40

III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A 40

G Toxic liquids, corrosive, organic, n.o.s. 6.1 UN2927 I 6.1, 8T14, TP2, TP13,

TP27None 201 243 0.5 L 2.5 L B 40

II 6.1, 8 IB2, T11, TP2, TP27 153 202 243 1 L 30 L B 40

G Toxic liquids, flammable, organic, n.o.s. 6.1 UN2929 I 6.1, 3T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

G Toxic, liquids, organic, n.o.s. 6.1 UN2810 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A 40

G Toxic liquids, oxidizing, n.o.s. 6.1 UN3122 I6.1,

5.1A4 None 201 243 Forbidden 2.5 L C

II6.1,

5.1IB2 153 202 243 1 L 5 L C

G Toxic liquids, water-reactive, n.o.s 6.1 UN3123 I6.1,

4.3A4 None 201 243 Forbidden 1 L E

13,40,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II6.1,

4.3IB2 None 202 243 1 L 5 L E

13,

40,

148

G Toxic solid, corrosive, inorganic, n.o.s 6.1 UN3290 I 6.1, 8 IB7, T6, TP33 None 211 242 1 kg 25 kg A 40

II 6.1, 8 IB6, IP2, T3, TP33 153 212 242 15 kg 50 kg A 40

G Toxic solid, flammable, inorganic, n.o.s 6.1 UN3535 I6.1.

4.1IB6, T6, TP33 None 211 242 1 kg 15 kg B

II6.1,

4.1

IB8, IP2, IP4, T3,

TP33153 212 242 15 kg 50 kg B

G Toxic solid, inorganic, n.o.s. 6.1 UN3288 I 6.1 IB7, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


G Toxic solids, corrosive, organic, n.o.s. 6.1 UN2928 I 6.1, 8 IB7, T6, TP33 None 211 242 1 kg 25 kg B 40

II 6.1, 8 IB6, IP2, T3, TP33 153 212 242 15 kg 50 kg B 40

G Toxic solids, flammable, organic, n.o.s. 6.1 UN2930 I6.1,

4.1IB6, T6, TP33 None 211 242 1 kg 15 kg B

II6.1,

4.1

IB8, IP2, IP4, T3,

TP33153 212 242 15 kg 50 kg B

G Toxic solids, organic, n.o.s. 6.1 UN2811 I 6.1 IB7, T6, TP33 None 211 242 5 kg 50 kg B

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B


G Toxic solids, oxidizing, n.o.s. 6.1 UN3086 I6.1,

5.1T6, TP33 None 211 242 1 kg 15 kg C

II6.1,

5.1IB6, IP2, T3, TP33 153 212 242 15 kg 50 kg C

G Toxic solids, self-heating, n.o.s. 6.1 UN3124 I6.1,

4.2A5, T6, TP33 None 211 242 5 kg 15 kg D 40

II6.1,

4.2IB6, IP2, T3, TP33 None 212 242 15 kg 50 kg D 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Toxic solids, water-reactive, n.o.s 6.1 UN3125 I6.1,

4.3A5, T6, TP33, W100 None 211 242 5 kg 15 kg D

13,

40,

148

G Toxins, extracted from living sources, liquid, n.o.s. 6.1 UN3172 I 6.1 141 None 201 243 1 L 30 L B 40

II 6.1 141, IB2 None 202 243 5 L 60 L B 40

III 6.1 141, IB3 153 203 241 60 L 220 L B 40

G Toxins, extracted from living sources, solid, n.o.s. 6.1 UN3462 I 6.1141, IB7, IP1, T6,

TP33None 211 243 5 kg 50 kg B

II 6.1141, IB8, IP2, IP4, T3

TP33None 212 243 25 kg 100 kg B

III 6.1141, IB8, IP3, T1

TP33153 213 241 100 kg 200 kg A

D Toy Caps 1.4S NA0337 1.4S None 62 None 25 kg 100 kg 1 25

Tracers for ammunition 1.3G UN0212 1.3G None 62 None Forbidden Forbidden 3 25

Tracers for ammunition 1.4G UN0306 1.4G None 62 None Forbidden 75 kg 2 25

Tractors, see Vehicle, etc

Tri-(b-nitroxyethyl) ammonium nitrate Forbidden

Triallyl borate 6.1 UN2609 III 6.1 IB3 153 203 241 60 L 220 L A 13

Triallylamine 3 UN2610 III 3, 8 B1, IB3, T4, TP1 None 203 242 5 L 60 L A 40, 52

Triazine pesticides, liquid, flammable, toxic, flash point

less than 23 degrees C3 UN2764 I 3, 6.1

T14, TP2, TP13,


II 3, 6.1IB2, T11, TP2, TP13,

TP27150 202 243 1 L 60 L B 40

Triazine pesticides, liquid, toxic 6.1 UN2998 I 6.1T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40

II 6.1IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40

Triazine pesticides, liquid, toxic, flammable, flash point

not less than 23 degrees C6.1 UN2997 I 6.1, 3

T14, TP2, TP13,

TP27None 201 243 1 L 30 L B 40




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II 6.1, 3IB2, T11, TP2, TP13,

TP27153 202 243 5 L 60 L B 40

III 6.1, 3 IB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40

Triazine pesticides, solid, toxic 6.1 UN2763 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A 40


Tributylamine 6.1 UN2542 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

Tributylphosphane 4.2 UN3254 I 4.2 T21, TP7, TP33 None 211 242 Forbidden Forbidden D 136

Trichloro-s-triazinetrione dry, with more than 39

percent available chlorine, see Trichloroisocyanuric

acid, dry

Trichloroacetic acid 8 UN1839 II 8A7, IB8, IP2, IP4,

N34, T3, TP33154 212 240 15 kg 50 kg A 53, 58

Trichloroacetic acid, solution 8 UN2564 II 8A3, A7, B2, IB2, N34,

T7, TP2154 202 242 1 L 30 L B 53, 58

III 8A3, A7, IB3, N34, T4,

TP1154 203 241 5 L 60 L B

8, 53,

58

+ Trichloroacetyl chloride 8 UN2442 II 8, 6.1

2, B9, B14, B32, N34,

T20, TP2, TP38,

TP45


53, 58

Trichlorobenzenes, liquid 6.1 UN2321 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Trichlorobutene 6.1 UN2322 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 25, 40

1,1,1-Trichloroethane 6.1 UN2831 III 6.1 IB3, N36, T4, TP1 153 203 241 60 L 220 L A 40

Trichloroethylene 6.1 UN1710 III 6.1 IB3, N36, T4, TP1 153 203 241 60 L 220 L A 40

Trichloroisocyanuric acid, dry 5.1 UN2468 II 5.1IB8, IP2, IP4, T3,

TP33152 212 240 5 kg 25 kg A 13

Trichloromethyl perchlorate Forbidden




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Trichlorosilane 4.3 UN1295 I4.3,

3, 8

N34, T14, TP2, TP7,

TP13, W31None 201 244 Forbidden Forbidden D

21,

40,

49,

53,

58,

100

Tricresyl phosphate with more than 3 percent ortho

isomer6.1 UN2574 II 6.1

A3, IB2, N33, N34,

T7, TP2153 202 243 5 L 60 L A

Triethyl phosphite 3 UN2323 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Triethylamine 3 UN1296 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 40

Triethylenetetramine 8 UN2259 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L B 40, 52

Trifluoroacetic acid 8 UN2699 I 8A7, B4, N3, N34,

N36, T10, TP2None 201 243 0.5 L 2.5 L B

12,

25,

40,

53, 58

Trifluoroacetyl chloride 2.3 UN3057 2.3, 82, B7, B9, B14, T50,

TP21None 304

314,


Trifluorochloroethylene, stabilized or Refrigerant gas R

11132.3 UN1082

2.3,

2.13, 387, B14, T50 None 304

314,


Trifluoromethane or Refrigerant gas R 23 2.2 UN1984 2.2 306 304314,

31575 kg 150 kg A

Trifluoromethane, refrigerated liquid 2.2 UN3136 2.2 T75, TP5 306 None314,

31550 kg 500 kg D

1,1,1-Trifluoroethane or Refrigerant gas, R 143a 2.1 UN2035 2.1 T50 306 304314,


2-Trifluoromethylaniline 6.1 UN2942 III 6.1 IB3 153 203 241 60 L 220 L A

3-Trifluoromethylaniline 6.1 UN2948 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40

Triformoxime trinitrate Forbidden

Triisobutylene 3 UN2324 III 3 B1, IB3, T4, TP1 150 203 242 60 L 220 L A

Triisopropyl borate 3 UN2616 II 3 IB2, T4, TP1 150 202 242 5 L 60 L A

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

D Trimethoxysilane 6.1 NA9269 I 6.1, 3

2, B9, B14, B32, T20,

TP4, TP13, TP38,

TP45

None 227 244 Forbidden Forbidden E 40

Trimethyl borate 3 UN2416 II 3 IB2, T7, TP1 150 202 242 5 L 60 L B

Trimethyl phosphite 3 UN2329 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

1,3,5-Trimethyl-2,4,6-trinitrobenzene Forbidden

Trimethylacetyl chloride 6.1 UN2438 I6.1,

8, 3

2, B3, B9, B14, B32,

N34, T20, TP2, TP13,

TP38, TP45


21,

25,

40,

53,

58,

100

Trimethylamine, anhydrous 2.1 UN1083 2.1 N87, T50 306 304314,


Trimethylamine, aqueous solutions with not more than

50 percent trimethylamine by mass3 UN1297 I 3, 8 T11, TP1 None 201 243 0.5 L 2.5 L D

40,

52,

135

II 3, 8 B1, IB2, T7, TP1 150 202 243 1 L 5 L B40,

41, 52

III 3, 8 B1, IB3, T7, TP1 150 203 242 5 L 60 L A40,

41, 52

1,3,5-Trimethylbenzene 3 UN2325 III 3 B1, IB3, T2, TP2 150 203 242 60 L 220 L A

Trimethylchlorosilane 3 UN1298 II 3, 8A3, A7, B77, N34,

T10, TP2, TP7, TP13None 206 243 Forbidden 5 L E

40,

53, 58

Trimethylcyclohexylamine 8 UN2326 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 52

Trimethylene glycol diperchlorate Forbidden

Trimethylhexamethylene diisocyanate 6.1 UN2328 III 6.1 IB3, T4, TP2, TP13 153 203 241 60 L 220 L B

Trimethylhexamethylenediamines 8 UN2327 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 52

Trimethylol nitromethane trinitrate Forbidden

Trinitro-m-cresol 1.1D UN0216 1.1D None 62 None Forbidden Forbidden 4 25, 5E




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

2,4,6-Trinitro-1,3-diazobenzene Forbidden

2,4,6-Trinitro-1,3,5-triazido benzene (dry) Forbidden

Trinitroacetic acid Forbidden

Trinitroacetonitrile Forbidden

Trinitroamine cobalt Forbidden

Trinitroaniline or Picramide 1.1D UN0153 1.1D None 62 None Forbidden Forbidden 4 25

Trinitroanisole 1.1D UN0213 1.1D None 62 None Forbidden Forbidden 4 25

Trinitrobenzene, dry or wetted with less than 30


Trinitrobenzene, wetted, with not less than 10% water,

by mass4.1 UN3367 I 4.1

162, A8, A19, N41,


Trinitrobenzene, wetted with not less than 30 percent


23, A2, A8, A19,


Trinitrobenzenesulfonic acid 1.1D UN0386 1.1D None 62 None Forbidden Forbidden 4 25, 5E

Trinitrobenzoic acid, dry or wetted with less than 30


Trinitrobenzoic acid, wetted with not less than 10%

water by mass4.1 UN3368 I 4.1

162, A8, A19, N41,


Trinitrobenzoic acid, wetted with not less than 30

percent water, by mass4.1 UN1355 I 4.1

23, A2, A8, A19,


Trinitrochlorobenzene or Picryl chloride 1.1D UN0155 1.1D None 62 None Forbidden Forbidden 4 25

Trinitrochlorobenzene (picryl chloride), wetted, with

not less than 10% water by mass4.1 UN3365 I 4.1

162, A8, A19, N41,


Trinitroethanol Forbidden

Trinitroethylnitrate Forbidden

Trinitrofluorenone 1.1D UN0387 1.1D None 62 None Forbidden Forbidden 4 25




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Trinitromethane Forbidden

1,3,5-Trinitronaphthalene Forbidden

Trinitronaphthalene 1.1D UN0217 1.1D None 62 None Forbidden Forbidden 4 25

Trinitrophenetole 1.1D UN0218 1.1D None 62 None Forbidden Forbidden 4 25

Trinitrophenol (picric acid), wetted, with not less than

10 percent water by mass4.1 UN3364 I 4.1

23, A8, A19, N41,


Trinitrophenol or Picric acid, dry or wetted with less

than 30 percent water, by mass1.1D UN0154 1.1D None 62 None Forbidden Forbidden 4 25, 5E

Trinitrophenol, wetted with not less than 30 percent


162, A8, A19, N41,

W31None 211 None 1 kg 15 kg E 28, 36

2,4,6-Trinitrophenyl guanidine (dry) Forbidden

2,4,6-Trinitrophenyl nitramine Forbidden

2,4,6-Trinitrophenyl trimethylol methyl nitramine

trinitrate (dry)Forbidden

Trinitrophenylmethylnitramine or Tetryl 1.1D UN0208 1.1D None 62 None Forbidden Forbidden 4 25

Trinitroresorcinol or Styphnic acid, dry or wetted with

less than 20 percent water, or mixture of alcohol and

water, by mass

1.1D UN0219 1.1D None 62 None Forbidden Forbidden 4 25, 5E

Trinitroresorcinol, wetted or Styphnic acid, wetted with

not less than 20 percent water, or mixture of alcohol

and water by mass

1.1D UN0394 1.1D 385 None 62 None Forbidden Forbidden 4 25, 5E

2,4,6-Trinitroso-3-methyl nitraminoanisole Forbidden

Trinitrotetramine cobalt nitrate Forbidden

Trinitrotoluene and Trinitrobenzene mixtures or TNT

and trinitrobenzene mixtures or TNT and

hexanitrostilbene mixtures or Trinitrotoluene and

hexanitrostilnene mixtures





tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Trinitrotoluene mixtures containing Trinitrobenzene and

Hexanitrostilbene or TNT mixtures containing

trinitrobenzene and hexanitrostilbene


Trinitrotoluene or TNT, dry or wetted with less than 30


Trinitrotoluene (TNT), wetted, with not less than 10

percent water by mass4.1 UN3366 I 4.1

162, A8, A19, N41,


Trinitrotoluene, wetted or TNT, wetted, with not less

than 30 percent water by mass4.1 UN1356 I 4.1

23, A2, A8, A19,


Tripropylamine 3 UN2260 III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A 40, 52

Tripropylene 3 UN2057 II 3 IB2, T4, TP2 150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP2 150 203 242 60 L 220 L A

Tris-(1-aziridinyl)phosphine oxide, solution 6.1 UN2501 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A

Tris, bis-bifluoroamino diethoxy propane (TVOPA) Forbidden

Tritonal 1.1D UN0390 1.1D None 62 None Forbidden Forbidden 4 25

Tungsten hexafluoride 2.3 UN2196 2.3, 8 2, N86 None 338 None Forbidden Forbidden D 40

Turpentine 3 UN1299 III 3 B1, IB3, T2, TP2 150 203 242 60 L 220 L A

Turpentine substitute 3 UN1300 I 3 T11, TP1, TP8, TP27 None 201 243 1 L 30 L B

II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Undecane 3 UN2330 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Uranium hexafluoride, radioactive material, excepted

package, less than 0.1 kg per package, non-fissile or

fissile-excepted

6.1 UN3507 I6.1,

7, 8369 420 None None

Less than .1

kg

Less than .1

kgA

132,

152

Urea hydrogen peroxide 5.1 UN1511 III 5.1, 8A1, A7, A29, IB8,

IP3, T1, TP33152 213 240 25 kg 100 kg A 13

Urea nitrate, dry or wetted with less than 20 percent

water, by mass1.1D UN0220 1.1D 119 None 62 None Forbidden Forbidden 4 25

Urea nitrate, wetted, with not less than 10 percent

water by mass4.1 UN3370 I 4.1

162, A8, A19, N41,





tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Urea nitrate, wetted with not less than 20 percent


23, 39, A8, A19,


Urea peroxide, see Urea hydrogen peroxide

Valeraldehyde 3 UN2058 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

Valeric acid, see Corrosive liquids, n.o.s.

Valeryl chloride 8 UN2502 II 8, 3A3, A7, B2, IB2, N34,

T7, TP2154 202 243 1 L 30 L C

40,

53, 58

G Vanadium compound, n.o.s 6.1 UN3285 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B

II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg B

III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg

Vanadium oxytrichloride 8 UN2443 II 8A3, A7, B2, B16, IB2,

N34, T7, TP2154 202 242 Forbidden 30 L C

40,

53, 58

Vanadium pentoxide, non-fused form 6.1 UN2862 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40

Vanadium tetrachloride 8 UN2444 I 8A7, B4, N34, T10,

TP2None 201 243 Forbidden 2.5 L C

40,

53, 58

Vanadium trichloride 8 UN2475 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A40,

53, 58

Vanadyl sulfate 6.1 UN2931 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Vehicle, flammable gas powered or Vehicle, fuel cell,

flammable gas powered9 UN3166 9 135, A200 220 220 220 Forbidden No limit A

Vehicle, flammable liquid powered or Vehicle, fuel cell,

flammable liquid powered9 UN3166 9 135, A200 220 220 220 No limit No limit A

Very signal cartridge, see Cartridges, signal

Vinyl acetate, stabilized 3 UN1301 II 3 387, IB2, T4, TP1 150 202 242 5 L 60 L C 25

Vinyl bromide, stabilized 2.1 UN1085 2.1 387, N86, T50 306 304314,


Vinyl butyrate, stabilized 3 UN2838 II 3 387, IB2, T4, TP1 150 202 242 5 L 60 L C 25

Vinyl chloride, stabilized 2.1 UN1086 2.121, 387, B44, N86,

T50306 304

314,


Vinyl chloroacetate 6.1 UN2589 II 6.1, 3 IB2, T7, TP2 153 202 243 5 L 60 L A

Vinyl ethyl ether, stabilized 3 UN1302 I 3 387, T11, TP2 None 201 243 1 L 30 L D




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Vinyl fluoride, stabilized 2.1 UN1860 2.1 387, N86 306 304314,

315Forbidden 150 kg E 25, 40

Vinyl isobutyl ether, stabilized 3 UN1304 II 3 387, IB2, T4, TP1 150 202 242 5 L 60 L C 25

Vinyl methyl ether, stabilized 2.1 UN1087 2.1 387, B44, T50 306 304314,


Vinyl nitrate polymer Forbidden

Vinylidene chloride, stabilized 3 UN1303 I 3 387, T12, TP2, TP7 150 201 243 1 L 30 L D 25, 40

Vinylpyridines, stabilized 6.1 UN3073 II6.1,

3, 8

387, IB1, T7, TP2,

TP13153 202 243 1 L 30 L B

21,

25,

40,

52,

100

Vinyltoluenes, stabilized 3 UN2618 III 3 387, B1, IB3, T2, TP1 150 203 242 60 L 220 L C 25

Vinyltrichlorosilane 3 UN1305 II 3, 8A3, A7, B6, N34,

T10, TP2, TP7, TP13None 206 243 Forbidden 5 L B

40,

53, 58

Warheads, rocket with burster or expelling charge 1.4D UN0370 1.4D None 62 62 Forbidden 75 kg 2 25

Warheads, rocket with burster or expelling charge 1.4F UN0371 1.4F None 62 None Forbidden Forbidden 3 25

Warheads, rocket with bursting charge 1.1D UN0286 1.1D None 62 62 Forbidden Forbidden 3 25

Warheads, rocket with bursting charge 1.2D UN0287 1.2D None 62 62 Forbidden Forbidden 3 25

Warheads, rocket with bursting charge 1.1F UN0369 1.1F None 62 None Forbidden Forbidden 3 25

Warheads, torpedo with bursting charge 1.1D UN0221 1.1D None 62 62 Forbidden Forbidden 3 25

G Water-reactive liquid, corrosive, n.o.s 4.3 UN3129 I 4.3, 8 T14, TP2, TP7, TP13 None 201 243 Forbidden 1 L D13,

148

II 4.3, 8 IB1, T11, TP2, TP7 None 202 243 1 L 5 L E

13,

85,

148

III 4.3, 8 IB2, T7, TP2, TP7 None 203 242 5 L 60 L E13,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Water-reactive liquid, n.o.s 4.3 UN3148 I 4.3T13, TP2, TP7, TP41,

W31None 201 244 Forbidden 1 L E

13,

40,

148

II 4.3IB1, T7, TP2, TP7,

W31None 202 243 1 L 5 L E

13,

40,

148

III 4.3IB2, T7, TP2, TP7,

W31None 203 242 5 L 60 L E

13,

40,

148

G Water-reactive liquid, toxic, n.o.s 4.3 UN3130 I4.3,

6.1A4 None 201 243 Forbidden 1 L D

13,

148

II4.3,

6.1IB1 None 202 243 1 L 5 L E

13,

85,

148

III4.3,

6.1IB2 None 203 242 5 L 60 L E

13,

85,

148

G Water-reactive solid, corrosive, n.o.s 4.3 UN3131 I 4.3, 8IB4, IP1, N40, T9,


13,

148

II 4.3, 8IB6, IP2, T3, TP33,

W31, W40151 212 242 15 kg 50 kg E

13,

85,

148

III 4.3, 8IB8, IP4, T1, TP33,

W31151 213 241 25 kg 100 kg E

13,

85,

148

G Water-reactive solid, flammable, n.o.s 4.3 UN3132 I4.3,

4.1IB4, N40, W31 None 211 242 Forbidden 15 kg D

13,

148

II4.3,

4.1

IB4, T3, TP33, W31,

W40151 212 242 15 kg 50 kg E

13,

148

III4.3,

4.1IB6, T1, TP33, W31 151 213 241 25 kg 100 kg E

13,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

G Water-reactive solid, n.o.s 4.3 UN2813 I 4.3IB4, N40, T9, TP7,

TP33, W31None 211 242 Forbidden 15 kg E

13,

40,

148

II 4.3B132, IB7, IP2, IP21,

T3, TP33, W31, W40151 212 242 15 kg 50 kg E

13,

40,

148

III 4.3B132, IB8, IP21, T1,

TP33, W31151 213 241 25 kg 100 kg E

13,

40,

148

G Water-reactive, solid, oxidizing, n.o.s 4.3 UN3133 II4.3,

5.1None 214 214 Forbidden Forbidden E

13,

40,

148

III4.3,

5.1None 214 214 Forbidden Forbidden E

13,

40,

148

G Water-reactive solid, self-heating, n.o.s 4.3 UN3135 I4.3,

4.2N40, W31 None 211 242 Forbidden 15 kg E

13,

148

II4.3,

4.2

IB5, IP2, T3, TP33,

W31, W40None 212 242 15 kg 50 kg E

13,

148

III4.3,

4.2

IB8, IP4, T1, TP33,

W31None 213 241 25 kg 100 kg E

13,

148

G Water-reactive solid, toxic, n.o.s 4.3 UN3134 I4.3,

6.1

A8, IB4, IP1, N40,

W31None 211 242 Forbidden 15 kg D

13,

148

II4.3,

6.1

IB5, IP2, T3, TP33,

W31, W40151 212 242 15 kg 50 kg E

13,

85,

148

III4.3,

6.1

IB8, IP4, T1, TP33,

W31151 213 241 25 kg 100 kg E

13,

85,

148

Wheel chair, electric, see Battery powered vehicle or

Battery powered equipment

White acid, see Hydrofluoric acid




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Wood preservatives, liquid 3 UN1306 II 3149, IB2, T4, TP1,

TP8150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 40

A I

WWool waste, wet 4.2 UN1387 III 4.2 151 213 240 Forbidden Forbidden A

Xanthates 4.2 UN3342 II 4.2IB6, IP2, T3, TP33,

W31None 212 241 15 kg 50 kg D 40

III 4.2IB8, IP3, T1, TP33,

W31None 213 241 25 kg 100 kg D 40

Xenon, compressed 2.2 UN2036 2.2 306,

307302 None 75 kg 150 kg A

Xenon, refrigerated liquid (cryogenic liquids) 2.2 UN2591 2.2 T75, TP5 320 None None 50 kg 500 kg D

Xylenes 3 UN1307 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B

III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A

Xylenols, solid 6.1 UN2261 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Xylenols, liquid 6.1 UN3430 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

Xylidines, liquid 6.1 UN1711 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A

Xylidines, solid 6.1 UN3452 II 6.1IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Xylyl bromide, liquid 6.1 UN1701 II 6.1A3, A7, IB2, N33, T7,

TP2, TP13, W31None 340 None Forbidden 60 L D 40

Xylyl bromide, solid 6.1 UN3417 II 6.1A3, A6, A7, IB8, IP2,

IP4, N33, T3, TP33None 340 None 25 kg 100 kg B 40

p-Xylyl diazide Forbidden

Zinc ammonium nitrite 5.1 UN1512 II 5.1 IB8, IP4, T3, TP33 None 212 242 5 kg 25 kg E

Zinc arsenate or Zinc arsenite or Zinc arsenate and zinc

arsenite mixtures6.1 UN1712 II 6.1

IB8, IP2, IP4, T3,

TP33153 212 242 25 kg 100 kg A

Zinc ashes 4.3 UN1435 III 4.3A1, A19, B136, IB8,

IP4, T1, TP33, W100151 213 241 25 kg 100 kg A

13,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Zinc bisulfite solution, see Bisulfites, aqueous solutions,

n.o.s.

Zinc bromate 5.1 UN2469 III 5.1A1, A29, IB8, IP3,

T1, TP33152 213 240 25 kg 100 kg A 56, 58

Zinc chlorate 5.1 UN1513 II 5.1A9, IB8, IP2, IP4,

N34, T3, TP33152 212 242 5 kg 25 kg A 56, 58

Zinc chloride, anhydrous 8 UN2331 III 8 IB8, IP3, T1, TP33 None 213 240 25 kg 100 kg A 53, 58

Zinc chloride, solution 8 UN1840 III 8 IB3, T4, TP2 154 203 241 5 L 60 L A 53, 58

Zinc cyanide 6.1 UN1713 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 52

Zinc dithionite or Zinc hydrosulfite 9 UN1931 III None IB8, IP3, T1, TP33 155 204 240 100 kg 200 kg A

13,

26,

123

Zinc fluorosilicate 6.1 UN2855 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52

Zinc hydrosulfite, see Zinc dithionite

Zinc muriate solution, see Zinc chloride, solution

Zinc nitrate 5.1 UN1514 II 5.1IB8, IP2, IP4, T3,

TP33152 212 240 5 kg 25 kg A

Zinc permanganate 5.1 UN1515 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg D

56,

58,

138

Zinc peroxide 5.1 UN1516 II 5.1IB6, IP2, T3, TP33,

W100152 212 242 5 kg 25 kg C

13,

52,

66,

75,

148

Zinc phosphide 4.3 UN1714 I4.3,


13,

40,

52,

85,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

Zinc powder or Zinc dust 4.3 UN1436 I4.3,

4.2

A19, IB4, IP1, N40,

W31None 211 242 Forbidden 15 kg A

13,

52,

53,

148

II4.3,

4.2

A19, IB7, IP2, T3,

TP33, W31, W40None 212 242 15 kg 50 kg A

13,

52,

53,

148

III4.3,

4.2

IB8, IP4, T1, TP33,

W31None 213 242 25 kg 100 kg A

13,

52,

53,

148

Zinc resinate 4.1 UN2714 III 4.1 A1, IB6, T1, TP33 151 213 240 25 kg 100 kg A

Zinc selenate, see Selenates or Selenites

Zinc selenite, see Selenates or Selenites

Zinc silicofluoride, see Zinc fluorosilicate

Zirconium, dry, coiled wire, finished metal sheets, strip

(thinner than 254 microns but not thinner than 18

microns)

4.1 UN2858 III 4.1 A1, W100 151 213 240 25 kg 100 kg A

13,

147,

148

Zirconium, dry, finished sheets, strip or coiled wire 4.2 UN2009 III 4.2 A1, A19, W31 None 213 240 25 kg 100 kg D13,

148

Zirconium hydride 4.1 UN1437 II 4.1A19, A20, IB4, N34,

T3, TP33, W31, W40None 212 240 15 kg 50 kg E

Zirconium nitrate 5.1 UN2728 III 5.1A1, A29, IB8, IP3,

T1, TP33152 213 240 25 kg 100 kg A

Zirconium picramate, dry or wetted with less than 20

percent water, by mass1.3C UN0236 1.3C None 62 None Forbidden Forbidden 4 25, 5E

Zirconium picramate, wetted with not less than 20

percent water, by mass4.1 UN1517 I 4.1 23, N41, W31 None 211 None 1 kg 15 kg D 28, 36

Zirconium powder, dry 4.2 UN2008 I 4.2 T21, TP7, TP33, W31 None 211 242 Forbidden Forbidden D13,

148




tions

Non-

bulkBulk

Passenger

aircraft/rail

Cargo aircraft

onlyLocation Other

(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B)

Sym

bols(§173.***)


(see §§173.27 and 175.75)



names

Primary

Hazard

Class or

Division

ID

NumbersPG

Label

Codes

II 4.2

A19, A20, IB6, IP2,

N5, N34, T3, TP33,

W31

None 212 241 15 kg 50 kg D13,

148

III 4.2B135, IB8, IP4, T1,

TP33, W31None 213 241 25 kg 100 kg D

13,

148

Zirconium powder, wetted with not less than 25

percent water (a visible excess of water must be

present) (a) mechanically produced, particle size less

than 53 microns; (b) chemically produced, particle size

less than 840 microns

4.1 UN1358 II 4.1

A19, A20, IB6, IP2,

N34, T3, TP33, W31,

W40

None 212 241 15 kg 50 kg E

13,

74,

147,

148

Zirconium scrap 4.2 UN1932 III 4.2B135, IB8, IP21,

N34, T1, TP33, W31None 213 240 Forbidden Forbidden D

13,

148

Zirconium suspended in a liquid 3 UN1308 I 3 None 201 243 Forbidden Forbidden B

II 3 IB2 None 202 242 5 L 60 L B

III 3 B1, IB2 150 203 242 60 L 220 L B

Zirconium tetrachloride 8 UN2503 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 53, 58



Hazardous materials descriptions and proper shipping namesPrimary

Hazard

Substances, explosive, n.o.s. 1.1A

Boosters with detonator 1.1B

Components, explosive train, n.o.s. 1.1B

Detonator assemblies, non-electric for blasting 1.1B

Detonators, electric, for blasting 1.1B

Detonators for ammunition 1.1B

Detonators, non-electric, for blasting 1.1B

Fuzes, detonating 1.1B

Primers, cap type 1.1B

Articles, explosive, n.o.s 1.1C

Cartridges for weapons, blank 1.1C

Charges, propelling 1.1C

Charges, propelling, for cannon 1.1C

Powder cake, wetted or Powder paste, wetted with not less than 17 percent alcohol by mass 1.1C

Powder, smokeless 1.1C

Propellant, liquid 1.1C

Propellant, solid 1.1C

Rocket motors 1.1C

Substances, explosive, n.o.s. 1.1C

Articles, explosive, n.o.s 1.1D

Black powder, compressed or Gunpowder, compressed or Black powder, in pellets or Gunpowder, in pellets 1.1D

Black powder or Gunpowder, granular or as a meal 1.1D

Bombs, photo-flash 1.1D

Bombs, with bursting charge 1.1D

Boosters, without detonator 1.1D

Bursters, explosive 1.1D

Charges, bursting, plastics bonded 1.1D

Charges, demolition 1.1D

Charges, depth 1.1D

Charges, explosive, commercial without detonator 1.1D

Charges, shaped, flexible, linear 1.1D

Charges, shaped, without detonator 1.1D

Charges, supplementary explosive 1.1D

Cord, detonating, flexible 1.1D

Cord, detonating or Fuze, detonating metal clad 1.1D

Explosive, blasting, type A 1.1D

Explosive, blasting, type B 1.1D

Explosive, blasting, type C 1.1D

Explosive, blasting, type D 1.1D

Explosive, blasting, type E 1.1D

Fracturing devices, explosive, without detonators for oil wells 1.1D

Fuzes, detonating, with protective features 1.1D

This list is sorted by primary hazard class then subsidiary hazard class. Use this table after you have determined all hazard classes or

divisions for the material and after you have determined which hazard class or division takes precedence. Next find the most descriptive

shipping name that matches the primary and subsidiary hazards for the material. Then look up the shipping name in the Hazardous

Materials Table and continue.

The purpose of this table is to assist in identifying shipping names that do not identify a single specific chemical. It only contains a fraction of

the shipping names found in the 49 CFR 172.101 Hazardous Materials Table. Specific chemical names or chemical groups that would easily be

identified if referencing chemical names are not included in this list.

Subsidiary Hazards







Grenades, hand or rifle, with bursting charge 1.1D

Jet perforating guns, charged oil well with detonator 1.1D

Jet perforating guns, charged oil well without detonator 1.1D

Mines with bursting charge 1.1D

Projectiles, with bursting charge 1.1D

Sounding devices, explosive 1.1D

Substances, explosive, n.o.s. 1.1D

Torpedoes with bursting charge 1.1D

Warheads, rocket with bursting charge 1.1D

Warheads, torpedo with bursting charge 1.1D

Articles, explosive, n.o.s 1.1E

Cartridges for weapons, with bursting charge 1.1E

Rockets, with bursting charge 1.1E

Torpedoes with bursting charge 1.1E

Articles, explosive, n.o.s 1.1F

Bombs, photo-flash 1.1F

Bombs, with bursting charge 1.1F

Cartridges for weapons, with bursting charge 1.1F

Grenades, hand or rifle, with bursting charge 1.1F

Mines with bursting charge 1.1F

Projectiles, with bursting charge 1.1F

Rockets, with bursting charge 1.1F

Sounding devices, explosive 1.1F

Torpedoes with bursting charge 1.1F

Warheads, rocket with bursting charge 1.1F

Articles, pyrotechnic for technical purposes 1.1G

Cartridges, flash 1.1G

Fireworks 1.1G

Flares, aerial 1.1G

Flares, surface 1.1G

Flash powder 1.1G

Igniters 1.1G

Signals, distress, ship 1.1G

Signals, railway track, explosive 1.1G

Signals, smoke 1.1G

Substances, explosive, n.o.s. 1.1G

Bombs with flammable liquid, with bursting charge 1.1J

Rockets, liquid fueled with bursting charge 1.1J

Torpedoes, liquid fueled, with or without bursting charge 1.1J

Articles, explosive, n.o.s. 1.1L

Substances, explosive, n.o.s. 1.1L

Boosters with detonator 1.2B





Cartridges for weapons, blank 1.2C







Cartridges for weapons, inert projectile 1.2C

Cartridges, power device 1.2C



Rocket motors 1.2C

Rockets, with expelling charge 1.2C

Rockets, with inert head 1.2C

Articles, explosive, n.o.s 1.2D

Bombs, with bursting charge 1.2D

Boosters, without detonator 1.2D




Cord, detonating or Fuze, detonating metal clad 1.2D


Grenades, hand or rifle, with bursting charge 1.2D

Mines with bursting charge 1.2D

Projectiles, with burster or expelling charge 1.2D


Sounding devices, explosive 1.2D

Warheads, rocket with bursting charge 1.2D

Articles, explosive, n.o.s 1.2E


Rockets, with bursting charge 1.2E


Bombs, with bursting charge 1.2F


Grenades, hand or rifle, with bursting charge 1.2F

Mines with bursting charge 1.2F

Projectiles, with burster or expelling charge 1.2F

Projectiles, with bursting charge 1.2F

Rockets, with bursting charge 1.2F

Sounding devices, explosive 1.2F

Ammunition, illuminating with or without burster, expelling charge or propelling charge 1.2G

Ammunition, incendiary with or without burster, expelling charge, or propelling charge 1.2G

Ammunition, smoke with or without burster, expelling charge or propelling charge 1.2G


Bombs, photo-flash 1.2G

Fireworks 1.2G

Flares, aerial 1.2G


Grenades, practice, hand or rifle 1.2G

Igniters 1.2G

Projectiles, with burster or expelling charge 1.2G

Rockets, line-throwing 1.2G

Signals, smoke 1.2G

Ammunition, tear-producing with burster, expelling charge or propelling charge 1.2G 8 6.1







Ammunition, incendiary, white phosphorus, with burster, expelling charge or propelling charge 1.2H

Ammunition smoke, white phosphorus with burster, expelling charge, or propelling charge 1.2H

Bombs with flammable liquid, with bursting charge 1.2J

Rocket motors, liquid fueled 1.2J

Rockets, liquid fueled with bursting charge 1.2J

Ammunition, toxic with burster, expelling charge, or propelling charge 1.2K 6.1


Articles, pyrophoric 1.2L

Contrivances, water-activated, with burster, expelling charge or propelling charge 1.2L

Rocket motors with hypergolic liquids with or without an expelling charge 1.2L



Cartridges for weapons, blank or Cartridges, small arms, blank 1.3C

Cartridges for weapons, inert projectile or Cartridges, small arms 1.3C

Cartridges, oil well 1.3C


Cases, combustible, empty, without primer 1.3C



Deflagrating metal salts of aromatic nitroderivatives, n.o.s. 1.3C

Powder cake, wetted or Powder paste, wetted with not less than 25 percent water, by mass 1.3C


Propellant, liquid 1.3C


Rocket motors 1.3C


Rockets, with inert head 1.3C



Ammunition, incendiary with or without burster, expelling charge, or propelling charge 1.3G

Ammunition, practice 1.3G



Bombs, photo-flash 1.3G

Cartridges, flash 1.3G

Cartridges, signal 1.3G

Fireworks 1.3G

Flares, aerial 1.3G


Flash powder 1.3G

Fuse, non-detonating instantaneous or quickmatch 1.3G

Fuzes, igniting 1.3G

Grenades, practice, hand or rifle 1.3G

Igniters 1.3G

Primers, tubular 1.3G

Projectiles, inert, with tracer 1.3G










Signals, smoke 1.3G


Tracers for ammunition 1.3G


Ammunition, incendiary, white phosphorus, with burster, expelling charge or propelling charge 1.3H

Ammunition, smoke, white phosphorus with burster, expelling charge, or propelling charge 1.3H

Ammunition, incendiary liquid or gel, with burster, expelling charge or propelling charge 1.3J

Rocket motors, liquid fueled 1.3J

Torpedoes, liquid fueled, with inert head 1.3J

Ammunition, toxic with burster, expelling charge, or propelling charge 1.3K 6.1


Contrivances, water-activated, with burster, expelling charge or propelling charge 1.3L

Rocket motors with hypergolic liquids with or without an expelling charge 1.3L


Articles, explosive, n.o.s. 1.4B


Detonator assemblies, non-electric, for blasting 1.4B

Detonators, electric, for blasting 1.4B


Detonators, non-electric, for blasting 1.4B


Primers, cap type 1.4B

Articles, explosive, n.o.s. 1.4C

Cartridges for weapons, blank or Cartridges, small arms, blank 1.4C

Cartridges for weapons, inert projectile or Cartridges, small arms 1.4C

Cartridges, oil well 1.4C


Cases, cartridges, empty with primer 1.4C

Cases, combustible, empty, without primer 1.4C


Model rocket motor 1.4C



Rocket motors 1.4C



Articles, explosive, n.o.s. 1.4D



Charges, shaped, flexible, linear 1.4D


Cord, detonating, flexible 1.4D

Cord, detonating, mild effect or Fuse, detonating, mild effect metal clad 1.4D


Jet perforating guns, charged oil well, with detonator 1.4D







Jet perforating guns, charged, oil well, without detonator 1.4D

Projectiles, with burster or expelling charge 1.4D


Substances, explosive, n.o.s. 1.4D

Warheads, rocket with burster or expelling charge 1.4D

Articles, explosive, n.o.s. 1.4E




Projectiles, with burster or expelling charge 1.4F

Warheads, rocket with burster or expelling charge 1.4F


Ammunition, incendiary with or without burster, expelling charge or propelling charge 1.4G

Ammunition, practice 1.4G

Ammunition, proof 1.4G


Articles, explosive, n.o.s. 1.4G


Cartridges, signal 1.4G

Cord, igniter 1.4G

Fireworks 1.4G

Flares, aerial 1.4G

Fuse, igniter tubular metal clad 1.4G

Fuzes, igniting 1.4G

Grenades practice, hand or rifle 1.4G

Igniters 1.4G

Primers, tubular 1.4G

Projectiles, inert, with tracer 1.4G

Projectiles, with burster or expelling charge 1.4G


Safety devices, pyrotechnic 1.4G

Signal devices, hand 1.4G



Signals, smoke 1.4G


Tracers for ammunition 1.4G


Articles, explosive, n.o.s 1.4S

Articles, pyrotechnic for technical purposes 1.4S

Cartridges, power device 1.4S

Cartridges, signal 1.4S

Cases, cartridge, empty with primer 1.4S

Charges, bursting, plastics bonded 1.4S

Charges, explosive, commercial without detonator 1.4S

Charges, shaped, without detonator 1.4S

Components, explosive train, n.o.s 1.4S







Cutters, cable, explosive 1.4S

Detonator assemblies, non-electric, for blasting 1.4S

Detonators, electric for blasting 1.4S

Detonators for ammunition 1.4S

Detonators, non-electric, for blasting 1.4S

Fireworks 1.4S

Flares, aerial 1.4S

Fuse, safety 1.4S

Fuzes, detonating 1.4S

Fuzes, igniting 1.4S

Grenades, practice, hand or rifle 1.4S

Igniters 1.4S

Lighters, fuse 1.4S

Model rocket motor 1.4S

Projectiles, inert with tracer 1.4S

Release devices, explosive 1.4S

Rivets, explosive 1.4S

Signal devices, hand 1.4S

Signals, distress, ship 1.4S

Signals, railway track, explosive 1.4S

Signals, smoke 1.4S

Substances, explosive, n.o.s 1.4S

Toy Caps 1.4S

Explosive, blasting, type B or Agent blasting, Type B 1.5D

Explosive, blasting, type E or Agent blasting, Type E 1.5D

Substances, explosive, very insensitive, n.o.s. or Substances, EVI, n.o.s. 1.5D

Articles, explosive, extremely insensitive or Articles, EEI 1.6N

Adsorbed gas, flammable, n.o.s 2.1

Aerosols, flammable, (each not exceeding 1 L capacity) 2.1

Aerosols, flammable, n.o.s. (engine starting fluid) (each not exceeding 1 L capacity) 2.1

Butadienes, stabilized or Butadienes and Hydrocarbon mixture, stabilized containing more than 40%

butadienes2.1

Chemical under pressure, flammable, n.o.s 2.1

Compressed gas, flammable, n.o.s. 2.1

Devices, small, hydrocarbon gas powered or Hydrocarbon gas refills for small devices with release device 2.1

Engine, internal combustion, flammable gas powered or Engine, fuel cell, flammable gas powered or Machinery,

internal combustion, flammable gas powered or Machinery, fuel cell, flammable gas powered2.1

Fuel cell cartridges or Fuel cell cartridges contained in equipment or Fuel cell cartridges packed with

equipment, containing hydrogen in metal hydride2.1


equipment, containing liquefied flammable gas2.1

Gas cartridges, ( flammable) without a release device, non-refillable 2.1

Gas, refrigerated liquid, flammable, n.o.s. (cryogenic liquid) 2.1

Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid 2.1

Hydrogen in a metal hydride storage system or Hydrogen in a metal hydride storage system contained in

equipment or Hydrogen in a metal hydride storage system packed with equipment2.1

Insecticide gases, flammable, n.o.s. 2.1

Lighters containing flammable gas 2.1







Lighter refills containing flammable gas not exceeding 4 fluid ounces (7.22 cubic inches) and 65 grams of

flammable gas2.1

Liquefied gas, flammable, n.o.s. 2.1

Methyl acetylene and propadiene mixtures, stabilized 2.1

Receptacles, small, containing gas or gas cartridges ( flammable) without release device, not refillable and

not exceeding 1 L capacity2.1

Refrigerant gases, n.o.s. or Dispersant gases, n.o.s. 2.1

Refrigerating machines, containing flammable, non-toxic, liquefied gas 2.1

Chemical under pressure, flammable, toxic, n.o.s 2.1 6.1

Chemical under pressure, flammable, corrosive, n.o.s 2.1 8

Adsorbed gas, n.o.s 2.2

Aerosols, non-flammable, (each not exceeding 1 L capacity) 2.2

Articles, pressurized pneumatic or hydraulic containing non-flammable gas 2.2

Chemical under pressure, n.o.s 2.2

Compressed gas, n.o.s 2.2

Fire extinguishers containing compressed or liquefied gas 2.2

Gas, refrigerated liquid, n.o.s. (cryogenic liquid) 2.2

Insecticide gases, n.o.s. 2.2

Liquefied gas, n.o.s. 2.2

Liquefied gases, non-flammable charged with nitrogen, carbon dioxide or air 2.2

Receptacles, small, containing gas or gas cartridges (non-flammable) without release device, not refillable

and not exceeding 1 L capacity2.2

Refrigerant gases, n.o.s. 2.2

Refrigerating machines, containing non-flammable, non-toxic gases, or ammonia solutions (UN2672) 2.2

Adsorbed gas, oxidizing, n.o.s 2.2 5.1

Compressed gas, oxidizing, n.o.s. 2.2 5.1

Gas, refrigerated liquid, oxidizing, n.o.s. (cryogenic liquid) 2.2 5.1

Liquefied gas, oxidizing, n.o.s. 2.2 5.1

Receptacles, small, containing gas or gas cartridges (oxidizing) without release device, not refillable and not

exceeding 1 L capacity2.2 5.1

Aerosols, poison, Packing Group III (each not exceeding 1 L capacity) 2.2 6.1

Chemical under pressure, toxic, n.o.s 2.2 6.1

Aerosols, corrosive, Packing Group II or III, ( each not exceeding 1 L capacity). 2.2 8

Chemical under pressure, corrosive, n.o.s 2.2 8

Adsorbed gas, toxic, flammable, n.o.s. Inhalation hazard zone A 2.3 2.1

Adsorbed gas, toxic, flammable, n.o.s. Inhalation hazard zone B 2.3 2.1

Adsorbed gas, toxic, flammable, n.o.s. Inhalation hazard zone C 2.3 2.1

Adsorbed gas, toxic, flammable, n.o.s. Inhalation hazard zone D 2.3 2.1

Compressed gas, toxic, flammable, n.o.s. Inhalation hazard Zone A 2.3 2.1

Compressed gas, toxic, flammable, n.o.s. Inhalation hazard Zone B 2.3 2.1

Compressed gas, toxic, flammable, n.o.s. Inhalation Hazard Zone C 2.3 2.1

Compressed gas, toxic, flammable, n.o.s. Inhalation Hazard Zone D 2.3 2.1

Gas sample, non-pressurized, toxic, flammable, n.o.s., not refrigerated liquid 2.3 2.1

Insecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone A 2.3 2.1

Insecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone B 2.3 2.1

Insecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone C 2.3 2.1

Insecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone D 2.3 2.1

Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone A 2.3 2.1







Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone B 2.3 2.1

Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone C 2.3 2.1

Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone D 2.3 2.1

Adsorbed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation hazard zone A 2.3 5.1 8

Adsorbed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation hazard zone B 2.3 5.1 8

Adsorbed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation hazard zone C 2.3 5.1 8

Adsorbed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation hazard zone D 2.3 5.1 8

Compressed gas, toxic, oxdizing, corrosive, n.o.s. Inhalation Hazard Zone A 2.3 5.1 8

Compressed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone B 2.3 5.1 8

Compressed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone C 2.3 5.1 8

Compressed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone D 2.3 5.1 8

Liquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone A 2.3 5.1 8

Liquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone B 2.3 5.1 8

Liquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone C 2.3 5.1 8

Liquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone D 2.3 5.1 8

Adsorbed gas, toxic, oxidizing, n.o.s. Inhalation hazard zone A 2.3 5.1

Adsorbed gas, toxic, oxidizing, n.o.s. Inhalation hazard zone B 2.3 5.1

Adsorbed gas, toxic, oxidizing, n.o.s. Inhalation hazard zone C 2.3 5.1

Adsorbed gas, toxic, oxidizing, n.o.s. Inhalation hazard zone D 2.3 5.1

Compressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone A 2.3 5.1

Compressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone B 2.3 5.1

Compressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone C 2.3 5.1

Compressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone D 2.3 5.1

Liquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone A 2.3 5.1

Liquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone B 2.3 5.1

Liquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone C 2.3 5.1

Liquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone D 2.3 5.1

Adsorbed gas, toxic, corrosive, n.o.s. Inhalation hazard zone A 2.3 8

Adsorbed gas, toxic, corrosive, n.o.s. Inhalation hazard zone B 2.3 8

Adsorbed gas, toxic, corrosive, n.o.s. Inhalation hazard zone C 2.3 8

Adsorbed gas, toxic, corrosive, n.o.s. Inhalation hazard zone D 2.3 8

Compressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone A 2.3 8

Compressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone B 2.3 8

Compressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone C 2.3 8

Compressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone D 2.3 8

Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone A 2.3 8

Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone B 2.3 8

Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone C 2.3 8

Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone D 2.3 8

Adsorbed gas, toxic, n.o.s. Inhalation hazard zone A 2.3

Adsorbed gas, toxic, n.o.s. Inhalation hazard zone B 2.3

Adsorbed gas, toxic, n.o.s. Inhalation hazard zone C 2.3

Adsorbed gas, toxic, n.o.s. Inhalation hazard zone D 2.3

Compressed gas, toxic, n.o.s. Inhalation Hazard Zone A 2.3

Compressed gas, toxic, n.o.s. Inhalation Hazard Zone B 2.3

Compressed gas, toxic, n.o.s. Inhalation Hazard Zone C 2.3

Compressed gas, toxic, n.o.s. Inhalation Hazard Zone D 2.3







Gas identification set 2.3

Gas sample, non-pressurized, toxic, n.o.s., not refrigerated liquid 2.3

Insecticide gases, toxic, n.o.s. 2.3

Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone A 2.3

Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone B 2.3

Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone C 2.3

Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone D 2.3

Organic phosphate, mixed with compressed gas or Organic phosphate compound, mixed with compressed gas

or Organic phosphorus compound, mixed with compressed gas2.3

Adsorbed gas, toxic, flammable, corrosive, n.o.s. Inhalation hazard zone A 2.3 2.1 8

Adsorbed gas, toxic, flammable, corrosive, n.o.s. Inhalation hazard zone B 2.3 2.1 8

Adsorbed gas, toxic, flammable, corrosive, n.o.s. Inhalation hazard zone C 2.3 2.1 8

Adsorbed gas, toxic, flammable, corrosive, n.o.s. Inhalation hazard zone D 2.3 2.1 8

Compressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone A 2.3 2.1 8

Compressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone B 2.3 2.1 8

Compressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone C 2.3 2.1 8

Compressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone D 2.3 2.1 8

Liquefied gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone A 2.3 2.1 8

Liquefied gas toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone B 2.3 2.1 8

Liquefied gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone C 2.3 2.1 8

Liquefied gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone D 2.3 2.1 8

Adhesives, containing a flammable liquid 3

Alcoholic beverages 3

Alcohols, n.o.s. 3

Aldehydes, n.o.s. 3

Amyl acetates 3

Amyl formates 3

Asphalt, at or above its flash point 3

Coal tar distillates, flammable 3

Coating solution ( includes surface treatments or coatings used for industrial or other purposes such as

vehicle undercoating, drum or barrel lining)3

Compounds, cleaning liquid 3

Compounds, tree killing, liquid or Compounds, weed killing, liquid 3

Cymenes 3

Desensitized explosive, liquid, n.o.s. 3

Elevated temperature liquid, flammable, n.o.s., with flash point above 37.8 C, at or above its flash point 3

Engine, internal combustion, flammable liquid powered or Engine, fuel cell, flammable liquid powered or

Machinery, internal combustion, flammable liquid powered or Machinery, fuel cell, flammable liquid powered3

Esters, n.o.s. 3

Ethanol and gasoline mixture or Ethanol and motor spirit mixture or Ethanol and petrol mixture, with more

than 10% ethanol3

Ethers, n.o.s. 3

Extracts, aromatic, liquid 3

Flammable liquids, n.o.s. 3

Fuel, aviation, turbine engine 3


equipment, containing flammable liquids3

Fuel oil (No. 1, 2, 4, 5, or 6) 3







Fusel oil 3

Gas oil 3

Heating oil, light 3

Hydrocarbons, liquid, n.o.s. 3

Ketones, liquid, n.o.s. 3

Lighters, non-pressurized, containing flammable liquid, 3

Mercaptans, liquid, flammable, n.o.s. or Mercaptan mixture, liquid, flammable, n.o.s 3

Nonanes 3

Paint including paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid filler and liquid

lacquer base3

Paint related material including paint thinning, drying, removing, or reducing compound 3

Pentanols 3

Petroleum crude oil 3

Petroleum distillates, n.o.s. or Petroleum products, n.o.s. 3

Polyester resin kit, liquid base material 3

Printing ink, flammable or P rinting ink related material ( including printing ink thinning or reducing

compound), flammable3

Resin Solution, flammable 3

Rosin oil 3

Rubber solution 3

Shale oil 3

Tars, liquid including road oils and cutback bitumens 3

Tinctures, medicinal 3

Turpentine substitute 3

Wood preservatives, liquid 3

Alcohols, flammable, toxic n.o.s 3 6.1

Aldehydes, flammable, toxic, n.o.s. 3 6.1

Arsenical pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1

Bipyridilium pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1

Carbamate pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1

Copper based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1

Coumarin derivative pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1

Flammable liquids, toxic, n.o.s. 3 6.1

Isocyanates, flammable, toxic, n.o.s. or Isocyanate solutions, flammable, toxic, n.o.s. flash point less than 23

degrees C3 6.1

Medicine, liquid, flammable, toxic, n.o.s 3 6.1

Mercaptans, liquid, flammable, toxic, n.o.s. or Mercaptan mixtures, liquid, flammable, toxic, n.o.s 3 6.1

Mercury based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1

Nitriles, flammable, toxic, n.o.s. 3 6.1

Organochlorine pesticides liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1

Organophosphorus pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1

Organotin pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1

Pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1

Petroleum sour crude oil, flammable, toxic 3 6.1

Phenoxyacetic acid derivative pesticide, liquid, flammable, toxic flash point less than 23 degrees C 3 6.1

Pyrethroid pesticide, liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1

Substituted nitrophenol pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1

Thiocarbamate pesticide, liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1







Triazine pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 6.1

Aircraft hydraulic power unit fuel tank (containing a mixture of anhydrous hydrazine and monomethyl

hydrazine) (M86 fuel)3 6.1 8

Flammable liquid, toxic, corrosive, n.o.s. 3 6.1 8

Alcoholates solution, n.o.s., in alcohol 3 8

Amine, flammable, corrosive, n.o.s. or Polyamines, flammable, corrosive, n.o.s 3 8

Amylamines 3 8

Flammable liquids, corrosive, n.o.s. 3 8

Paint, flammable, corrosive, ( including paint , lacquer, enamel, stain, shellac, varnish, polish, liquid filler 3 8

Paint related material, flammable, corrosive ( including paint thinning or reducing compound) 3 8

Sodium methylate solutions in alcohol 3 8

Black powder for small arms 4.1

Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap 4.1

Desensitized explosive, solid, n.o.s. 4.1

Fibers, vegetable, dry 4.1

Fibers or Fabrics impregnated with weakly nitrated nitrocellulose, n.o.s. 4.1

Films, nitrocellulose base, gelatine coated (except scrap) 4.1

Firelighters, solid with flammable liquid 4.1

Flammable solid, inorganic, n.o.s. 4.1

Flammable solid, organic, molten, n.o.s. 4.1

Flammable solids, organic, n.o.s. 4.1

Fusee ( railway or highway) 4.1

Matches, fusee 4.1

Matches, safety (book, card or strike on box) 4.1

Matches, wax, Vesta 4.1

Metal hydrides, flammable, n.o.s 4.1

Metal powders, flammable, n.o.s 4.1

Metal salts of organic compounds, flammable, n.o.s 4.1

Polymerizing substance, liquid, stabilized, n.o.s 4.1

Polymerizing substance, liquid, temperature controlled, n.o.s 4.1

Polymerizing substance, solid, stabilized, n.o.s 4.1

Polymerizing substance, solid, temperature controlled, n.o.s 4.1

Rubber scrap or shoddy, powdered or granulated, not exceeding 840 microns and rubber contend exceeding

45%4.1

Self-reactive liquid type B 4.1

Self-reactive liquid type B, temperature controlled 4.1

Self-reactive liquid type C 4.1

Self-reactive liquid type C, temperature controlled 4.1

Self-reactive liquid type D 4.1

Self-reactive liquid type D, temperature controlled 4.1

Self-reactive liquid type E 4.1

Self-reactive liquid type E, temperature controlled 4.1

Self-reactive liquid type F 4.1

Self-reactive liquid type F, temperature controlled 4.1

Self-reactive solid type B 4.1

Self-reactive solid type B, temperature controlled 4.1

Self-reactive solid type C 4.1

Self-reactive solid type C, temperature controlled 4.1







Self-reactive solid type D 4.1

Self-reactive solid type D, temperature controlled 4.1

Self-reactive solid type E 4.1

Self-reactive solid type E, temperature controlled 4.1

Self-reactive solid type F 4.1

Self-reactive solid type F, temperature controlled 4.1

Smokeless powder for small arms (100 pounds or less ) 4.1

Solids containing flammable liquid, n.o.s. 4.1

Flammable solid, oxidizing, n.o.s. 4.1 5.1

Flammable solid, toxic, inorganic, n.o.s. 4.1 6.1

Flammable solids, toxic, organic, n.o.s. 4.1 6.1

Flammable solid, corrosive, inorganic, n.o.s. 4.1 8

Flammable solids, corrosive, organic, n.o.s. 4.1 8

Alkaline earth metal alcoholates, n.o.s 4.2

Barium alloys, pyrophoric 4.2

Calcium, pyrophoric or Calcium alloys, pyrophoric 4.2

Celluloid, scrap 4.2

Charcoal briquettes, shell, screenings, wood, etc. 4.2

Cotton waste, oily 4.2

Cotton, wet 4.2

Fibers, animal or Fibers, vegetable burnt, wet or damp 4.2

Fibers or Fabrics, animal or vegetable or Synthetic, n.o.s. with animal or vegetable oil 4.2

Fish meal, unstablized or Fish scrap, unstabilized 4.2

Metal catalyst, dry 4.2

Metal catalyst, wetted with a visible excess of liquid 4.2

Metal powder, self-heating, n.o.s 4.2

Organic pigments, self-heating 4.2

Organometallic substance, liquid, pyrophoric 4.2

Organometallic substance, solid, pyrophoric 4.2

Organometallic substance, solid, self-heating 4.2

Paper, unsaturated oil treated incompletely dried ( including carbon paper) 4.2

Plastics, nitrocellulose-based, self-heating, n.o.s. 4.2

Pyrophoric liquid, inorganic, n.o.s 4.2

Pyrophoric liquids, organic, n.o.s 4.2

Pyrophoric metals, n.o.s., or Pyrophoric alloys, n.o.s 4.2

Pyrophoric solid, inorganic, n.o.s 4.2

Pyrophoric solids, organic, n.o.s 4.2

Rags, oily 4.2

Self-heating liquid, inorganic, n.o.s 4.2

Self-heating liquid, organic, n.o.s 4.2

Self-heating solid, inorganic, n.o.s 4.2

Self-heating solid, organic, n.o.s 4.2

Textile waste, wet 4.2

Wool waste, wet 4.2

Zirconium scrap 4.2

Organometallic substance, liquid, pyrophoric, water-reactive 4.2 4.3

Organometallic substance, solid, pyrophoric, water-reactive 4.2 4.3







Self-heating solid, oxidizing, n.o.s. 4.2 5.1

Self-heating liquid, toxic, inorganic, n.o.s 4.2 6.1

Self-heating liquid, toxic, organic, n.o.s 4.2 6.1

Self-heating solid, toxic, inorganic, n.o.s. 4.2 6.1

Self-heating solid, toxic, organic, n.o.s 4.2 6.1

Alkali metal alcoholates, self-heating, corrosive, n.o.s 4.2 8

Self-heating liquid, corrosive, inorganic, n.o.s 4.2 8

Self-heating liquid, corrosive, organic, n.o.s 4.2 8

Self-heating solid, corrosive, inorganic, n.o.s. 4.2 8

Self-heating solid, corrosive, organic, n.o.s 4.2 8

Alkali metal alloys, liquid, n.o.s 4.3

Alkali metal amalgam, liquid 4.3

Alkali metal amalgam, solid 4.3

Alkali metal amides 4.3

Alkali metal dispersions, or Alkaline earth metal dispersions 4.3

Alkaline earth metal alloys, n.o.s 4.3

Alkaline earth metal amalgams, liquid 4.3

Alkaline earth metal amalgams, solid 4.3

Batteries, containing sodium 4.3

Cells, containing sodium 4.3


equipment, containing water-reactive substances4.3

Metal hydrides, water reactive, n.o.s 4.3

Metallic substance, water-reactive, n.o.s 4.3

Organometallic substance, liquid, water-reactive 4.3

Organometallic substance, solid, water-reactive 4.3

Potassium, metal alloys, solid 4.3

Potassium sodium alloys, solid 4.3

Water-reactive liquid, n.o.s 4.3

Water-reactive solid, n.o.s 4.3

Alkali metal dispersions, flammable or Alkaline earth metal dispersions, flammable 4.3 3

Organometallic substance, liquid, water-reactive, flammable 4.3 3

Chlorosilanes, water-reactive, flammable, corrosive, n.o.s 4.3 3 8

Organometallic substance, solid, water-reactive, flammable 4.3 4.1

Water-reactive solid, flammable, n.o.s 4.3 4.1

Metallic substance, water-reactive, self-heating, n.o.s 4.3 4.2

Organometallic substance, solid, water-reactive, self-heating 4.3 4.2

Water-reactive solid, self-heating, n.o.s 4.3 4.2

Water-reactive, solid, oxidizing, n.o.s 4.3 5.1

Water-reactive liquid, toxic, n.o.s 4.3 6.1

Water-reactive solid, toxic, n.o.s 4.3 6.1

Water-reactive liquid, corrosive, n.o.s 4.3 8

Water-reactive solid, corrosive, n.o.s 4.3 8

Ammonium nitrate based fertilizer 5.1

Bromates, inorganic, aqueous solution, n.o.s 5.1

Bromates, inorganic, n.o.s 5.1

Chlorate and borate mixtures 5.1







Chlorate and magnesium chloride mixture solid 5.1

Chlorates, inorganic, aqueous solution, n.o.s 5.1

Chlorates, inorganic, n.o.s 5.1

Chlorites, inorganic, n.o.s 5.1

Hypochlorites, inorganic, n.o.s 5.1

Nitrates, inorganic, aqueous solution, n.o.s. 5.1

Nitrates, inorganic, n.o.s. 5.1

Nitrites, inorganic, aqueous solution, n.o.s 5.1

Nitrites, inorganic, n.o.s 5.1

Oxidizing liquid, n.o.s 5.1

Oxidizing solid, n.o.s. 5.1

Perchlorates, inorganic, aqueous solution, n.o.s. 5.1

Perchlorates, inorganic, n.o.s. 5.1

Permanganates, inorganic, aqueous solution, n.o.s 5.1

Permanganates, inorganic, n.o.s 5.1

Peroxides, inorganic, n.o.s 5.1

Persulfates, inorganic, aqueous solution, n.o.s 5.1

Persulfates, inorganic, n.o.s. 5.1

Oxidizing solid, flammable, n.o.s 5.1 4.1

Oxidizing solid, self-heating, n.o.s. 5.1 4.2

Oxidizing solid, water reactive, n.o.s 5.1 4.3

Oxidizing liquid, toxic, n.o.s 5.1 6.1

Oxidizing solid, toxic, n.o.s. 5.1 6.1

Oxidizing liquid, corrosive, n.o.s 5.1 8

Oxidizing solid, corrosive, n.o.s 5.1 8

Organic peroxide type C, liquid 5.2

Organic peroxide type C, liquid, temperature controlled 5.2

Organic peroxide type C, solid 5.2

Organic peroxide type C, solid, temperature controlled 5.2

Organic peroxide type D, liquid 5.2

Organic peroxide type D, liquid, temperature controlled 5.2

Organic peroxide type D, solid 5.2

Organic peroxide type D, solid, temperature controlled 5.2

Organic peroxide type E, liquid 5.2

Organic peroxide type E, liquid, temperature controlled 5.2

Organic peroxide type E, solid 5.2

Organic peroxide type E, solid, temperature controlled 5.2

Organic peroxide type F, liquid 5.2

Organic peroxide type F, liquid, temperature controlled 5.2

Organic peroxide type F, solid 5.2

Organic peroxide type F, solid, temperature controlled 5.2

Organic peroxide type B, liquid 5.2 1

Organic peroxide type B, liquid, temperature controlled 5.2 1

Organic peroxide type B, solid 5.2 1

Organic peroxide type B, solid, temperature controlled 5.2 1

Alkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s. 6.1

Alkaloids, solid, n.o.s. or Alkaloid salts, solid, n.o.s. poisonous 6.1







Aluminum phosphide pesticides 6.1

Ammunition, toxic, non-explosive, without burster or expelling charge, non-fuzed 6.1

Anisidines 6.1

Antimony compounds, inorganic, liquid, n.o.s 6.1

Antimony compounds, inorganic, solid, n.o.s 6.1

Arsenic compounds, liquid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides,

n.o.s.; and organic compounds of arsenic, n.o.s6.1

Arsenic compounds, solid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides,

n.o.s.; and organic compounds of arsenic, n.o.s6.1

Arsenical pesticides, liquid, toxic 6.1

Arsenical pesticides, solid, toxic 6.1

Barium compounds, n.o.s 6.1

Beryllium compounds, n.o.s 6.1

Bipyridilium pesticides, liquid, toxic 6.1

Bipyridilium pesticides, solid, toxic 6.1

Butyltoluenes 6.1

Cadmium compounds 6.1

Carbamate pesticides, liquid, toxic 6.1

Carbamate pesticides, solid, toxic 6.1

Chloroanilines, liquid 6.1

Chloroanilines, solid 6.1

Chlorocresols solution 6.1

Chloronitroanilines 6.1

Chloronitrotoluenes, liquid 6.1

Chlorophenols, liquid 6.1

Chlorophenols, solid 6.1

Chloropicrin mixtures, n.o.s 6.1

Chlorotoluidines, solid 6.1

Compounds, tree killing, liquid or Compounds, weed killing, liquid 6.1

Copper based pesticides, liquid, toxic 6.1

Copper based pesticides, solid, toxic 6.1

Coumarin derivative pesticides, liquid, toxic 6.1

Coumarin derivative pesticides, solid, toxic 6.1

Cyanide solutions, n.o.s. 6.1

Cyanides, inorganic, solid, n.o.s. 6.1

Dichlorophenyl isocyanates 6.1

Disinfectants, liquid, toxic, n.o.s. 6.1

Disinfectants, solid, toxic, n.o.s. 6.1

Dyes, liquid, toxic, n.o.s. or Dye intermediates, liquid, toxic, n.o.s. 6.1

Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s. 6.1

Fluorosilicates, n.o.s 6.1

Isocyanates, toxic, n.o.s. or Isocyanate solutions, toxic, n.o.s., flash point more than 61 degrees C and boiling

point less than 300 degrees C6.1

Lead compounds, soluble, n.o.s 6.1

London purple 6.1

Medicine, liquid, toxic, n.o.s 6.1

Medicine, solid, toxic, n.o.s 6.1

Mercury based pesticides, liquid, toxic 6.1







Mercury based pesticides, solid, toxic 6.1

Mercury bromides 6.1

Mercury compound, liquid, n.o.s 6.1

Mercury compound, solid, n.o.s 6.1

Metal carbonyls, liquid, n.o.s. 6.1

Metal carbonyls, solid, n.o.s. 6.1

Nicotine compounds, liquid, n.o.s. or Nicotine preparations, liquid, n.o.s 6.1

Nicotine compounds, solid, n.o.s. or Nicotine preparations, solid, n.o.s 6.1

Nitriles, liquid, toxic, n.o.s. 6.1

Nitriles, solid, toxic, n.o.s. 6.1

Nitrocresols, solid 6.1

Organoarsenic compound, liquid, n.o.s. 6.1

Organoarsenic compound, solid, n.o.s. 6.1

Organochlorine pesticides, liquid, toxic 6.1

Organochlorine pesticides, solid, toxic 6.1

Organometallic compound, liquid, toxic, n.o.s 6.1

Organometallic compound, solid, toxic, n.o.s 6.1

Organophosphorus compound, liquid, toxic, n.o.s 6.1

Organophosphorus compound, solid, toxic, n.o.s 6.1

Organophosphorus pesticides, liquid, toxic 6.1

Organophosphorus pesticides, solid, toxic 6.1

Organotin compounds, liquid, n.o.s 6.1

Organotin compounds, solid, n.o.s. 6.1

Organotin pesticides, liquid, toxic 6.1

Organotin pesticides, solid, toxic 6.1

Pesticides, liquid, toxic, n.o.s. 6.1

Pesticides, solid, toxic, n.o.s. 6.1

Phenoxyacetic acid derivative pesticide, liquid, toxic 6.1

Phenoxyacetic acid derivative pesticide, solid, toxic 6.1

Phenyl urea pesticides, liquid, toxic 6.1

Phenylmercuric compounds, n.o.s. 6.1

Pyrethroid pesticide, liquid toxic 6.1

Pyrethroid pesticide, solid, toxic 6.1

Selenates or Selenites 6.1

Selenium compound, liquid, n.o.s 6.1

Selenium compound, solid, n.o.s 6.1

Solids containing toxic liquid, n.o.s. 6.1

Substituted nitrophenol pesticides, liquid, toxic 6.1

Substituted nitrophenol pesticides, solid, toxic 6.1

Tear gas devices with more than 2 percent tear gas substances, by mass 6.1

Tear gas substances, liquid, n.o.s 6.1

Tear gas substance, solid, n.o.s 6.1

Tellurium compound, n.o.s 6.1

Thallium compounds, n.o.s 6.1

Thiocarbamate pesticide, liquid, toxic 6.1

Thiocarbamate pesticides, solid, toxic 6.1







Toxic by inhalation liquid, n.o.s. with an LC50 lower than or equal to 200 ml/m 3 and saturated vapor

concentration greater than or equal to 500 LC506.1

Toxic by inhalation liquid, n.o.s. with an LC50 lower than or equal to 1000 ml/m 3 and saturated vapor

concentration greater than or equal to 10 LC506.1

Toxic liquid, inorganic, n.o.s 6.1

Toxic, liquids, organic, n.o.s. 6.1

Toxic solid, inorganic, n.o.s. 6.1

Toxic solids, organic, n.o.s. 6.1

Toxins, extracted from living sources, liquid, n.o.s. 6.1

Toxins, extracted from living sources, solid, n.o.s. 6.1

Triazine pesticides, liquid, toxic 6.1

Triazine pesticides, solid, toxic 6.1

Vanadium compound, n.o.s 6.1

Arsenical pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Bipyridilium pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Carbamate pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Copper based pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Coumarin derivative pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Isocyanates, toxic, flammable, n.o.s. or Isocyanate solutions, toxic, flammable, n.o.s., flash point not less than

23 degrees C but not more than 61 degrees C and boiling point less than 300 degrees C6.1 3

Mercaptans, liquid, toxic, flammable, n.o.s. or Mercaptan mixtures, liquid, toxic, flammable, n.o.s., flash point

not less than 23 degrees C6.1 3

Mercury based pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Nitriles, toxic, flammable, n.o.s. 6.1 3

Organochlorine pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Organophosphorus compound, toxic, flammable, n.o.s. 6.1 3

Organophosphorus pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Organotin pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Pesticides, liquid, toxic, flammable, n.o.s. flash point not less than 23 degrees C 6.1 3

Phenoxyacetic acid derivative pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Pyrethroid pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Substituted nitrophenol pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Thiocarbamate pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Toxic by inhalation liquid, flammable, n.o.s. with an LC50 lower than or equal to 200 ml/m 3 and saturated

vapor concentration greater than or equal to 500 LC506.1 3

Toxic by inhalation liquid, flammable, n.o.s. with an LC50 lower than or equal to 1000 ml/m 3 and saturated


Toxic liquids, flammable, organic, n.o.s. 6.1 3

Triazine pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 3

Toxic by inhalation liquid, flammable, corrosive, n.o.s. with an LC50 lower than or equal to 200 ml/m3 and

saturated vapor concentration greater than or equal to 500 LC506.1 3 8

Toxic by inhalation liquid, flammable, corrosive, n.o.s. with an LC50 lower than or equal to 1000 ml/m3 and

saturated vapor concentration greater than or equal to 10 LC506.1 3 8

Tear gas candles 6.1 4.1

Toxic solids, flammable, organic, n.o.s. 6.1 4.1

Toxic solids, self-heating, n.o.s. 6.1 4.2

Toxic by inhalation liquid, water-reactive, n.o.s. with an LC50 lower than or equal to 200 ml/m 3 and

saturated vapor concentration greater than or equal to 500 LC506.1 4.3

Toxic by inhalation liquid, water-reactive, n.o.s. with an LC50 lower than or equal to 1000 ml/m 3 and

saturated vapor concentration greater than or equal to 10 LC506.1 4.3







Toxic liquids, water-reactive, n.o.s 6.1 4.3

Toxic solids, water-reactive, n.o.s 6.1 4.3

Toxic by inhalation liquid, water-reactive, flammable, n.o.s. with an LC50 lower than or equal to 200 ml/ m3

and saturated vapor concentration greater than or equal to 500 LC506.1 4.3 3

Toxic by inhalation liquid, water-reactive, flammable, n.o.s. with an LC50 lower or equal to 1000 ml/m3 and

saturated vapor concentration greater than or equal to 10 LC506.1 4.3 3

Toxic by inhalation liquid, oxidizing, n.o.s. with an LC50 lower than or equal to 200 ml/m 3 and saturated

vapor concentration greater than or equal to 500 LC506.1 5.1

Toxic by inhalation liquid, oxidizing, n.o.s. with an LC50 lower than or equal to 1000 ml/m 3 and saturated

vapor concentration greater than or equal to 10 LC506.1 5.1

Toxic liquids, oxidizing, n.o.s. 6.1 5.1

Toxic solids, oxidizing, n.o.s. 6.1 5.1

Ammunition, tear-producing, non-explosive, without burster or expelling charge, non-fuzed 6.1 8

Chloroformates, toxic, corrosive, n.o.s 6.1 8

Chlorosilanes, toxic, corrosive, n.o.s 6.1 8

Toxic by inhalation liquid, corrosive, n.o.s. with an LC50 lower than or equal to 200 ml/m 3 and saturated


Toxic by inhalation liquid, corrosive, n.o.s. with an LC50 lower than or equal to 1000 ml/m 3 and saturated


Toxic liquid, corrosive, inorganic, n.o.s 6.1 8

Toxic liquids, corrosive, organic, n.o.s. 6.1 8

Toxic solid, corrosive, inorganic, n.o.s 6.1 8

Toxic solids, corrosive, organic, n.o.s. 6.1 8

Chloroformates, toxic, corrosive, flammable, n.o.s 6.1 8 3

Chlorosilanes, toxic, corrosive, flammable, n.o.s 6.1 8 3

Biological substance, Category B 6.2

Infectious substances, affecting animals only 6.2

Infectious substances, affecting humans 6.2

Regulated medical waste, n.o.s. or Clinical waste, unspecified, n.o.s. or (BIO) Medical waste, n.o.s., or

Biomedical waste, n.o.s. or Medical waste, n.o.s6.2

Radioactive material, excepted package-empty packaging Empty

Radioactive material, low specific activity (LSA-I) non fissile or fissile-excepted 7

Radioactive material, low specific activity (LSA-II) non fissile or fissile-excepted 7

Radioactive material, low specific activity (LSA-III) non fissile or fissile excepted 7

Radioactive material, surface contaminated objects (SCO-I or SCO-II) non fissile or fissile-excepted 7

Radioactive material, transported under special arrangement, non fissile or fissile excepted 7

Radioactive material, transported under special arrangement, fissile 7

Radioactive material, Type A package, fissile non-special form 7

Radioactive material, Type A package non-special form, non fissile or fissile-excepted 7

Radioactive material, Type A package, special form non fissile or fissile-excepted 7

Radioactive material, Type A package, special form, fissile 7

Radioactive material, Type B(M) package, fissile 7

Radioactive material, Type B(M) package non fissile or fissile-excepted 7

Radioactive material, Type B(U) package, fissile 7

Radioactive material, Type B(U) package non fissile or fissile-excepted 7

Radioactive material, uranium hexafluoride non fissile or fissile-excepted 7 6.1 8

Radioactive material, uranium hexafluoride, fissile 7 6.1 8

Alkylphenols, liquid, n.o.s. ( including C2-C12 homologues) 8

Alkylphenols, solid, n.o.s. ( including C2-C12 homologues) 8







Amines, liquid, corrosive, n.o.s. or Polyamines, liquid, corrosive, n.o.s 8

Amines, solid, corrosive, n.o.s., or Polyamines, solid, corrosive n.o.s. 8

Batteries, dry, containing potassium hydroxide solid, electric storage 8

Batteries, wet, filled with acid, electric storage 8

Batteries, wet, filled with alkali, electric storage 8

Batteries, wet, non-spillable, electric storage 8

Battery fluid, acid 8

Battery fluid, alkali 8

Bombs, smoke, non-explosive, with corrosive liquid, without initiating device 8

Caustic alkali liquids, n.o.s. 8

Chemical kit 8

Chlorophenolates, liquid or Phenolates, liquid 8

Chlorophenolates, solid or Phenolates, solid 8

Chlorosilanes, corrosive, n.o.s 8

Compounds, cleaning liquid 8

Compounds, tree killing, liquid or Compounds, weed killing, liquid 8

Corrosive liquid, acidic, inorganic, n.o.s 8

Corrosive liquid, acidic, organic, n.o.s 8

Corrosive liquid, basic, inorganic, n.o.s 8

Corrosive liquid, basic, organic, n.o.s 8

Corrosive liquids, n.o.s 8

Corrosive solid, acidic, inorganic, n.o.s 8

Corrosive solid, acidic, organic, n.o.s 8

Corrosive solid, basic, inorganic, n.o.s. 8

Corrosive solid, basic, organic, n.o.s. 8

Corrosive solids, n.o.s. 8

Disinfectant, liquid, corrosive, n.o.s 8

Disinfectants, liquid, corrosive n.o.s. 8

Dyes, liquid, corrosive, n.o.s. or Dye intermediates, liquid, corrosive, n.o.s 8

Dyes, solid, corrosive, n.o.s. or Dye intermediates, solid, corrosive, n.o.s. 8

Fire extinguisher charges, corrosive liquid 8


equipment, containing corrosive substances8

Hypochlorite solutions 8

Nitrating acid mixtures spent with not more than 50 percent nitric acid 8

Nitrating acid mixtures with not more than 50 percent nitric acid 8

Paint or Paint related material 8

Solids containing corrosive liquid, n.o.s. 8

Amine, liquid, corrosive, flammable, n.o.s. or Polyamines, liquid, corrosive, flammable, n.o.s 8 3

Chlorosilanes, corrosive, flammable, n.o.s 8 3

Corrosive liquids, flammable, n.o.s 8 3

Paint, corrosive, flammable ( including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler, and

liquid lacquer base)8 3

Paint related material corrosive, flammable ( including paint thinning or reducing compound) 8 3

Corrosive solids, flammable, n.o.s. 8 4.1

Corrosive liquid, self-heating, n.o.s 8 4.2

Corrosive solids, self-heating, n.o.s. 8 4.2

Corrosive liquids, water-reactive, n.o.s 8 4.3







Corrosive solids, water-reactive, n.o.s 8 4.3

Corrosive liquids, oxidizing, n.o.s 8 5.1

Corrosive solids, oxidizing, n.o.s. 8 5.1

Nitrating acid mixtures, spent with more than 50 percent nitric acid 8 5.1

Nitrating acid mixtures with more than 50 percent nitric acid 8 5.1

Corrosive liquids, toxic, n.o.s 8 6.1

Corrosive solids, toxic, n.o.s 8 6.1

Mercury contained in manufactured articles 8 6.1

Asbestos, amphibole amosite, tremolite, actinolite, anthophyllite, or crocidolite 9

Aviation regulated liquid, n.o.s 9

Aviation regulated solid, n.o.s 9

Batteries, nickel-metal hydride see Batteries, dry, sealed, n.o.s. for nickel-metal hydride batteries transported

by modes other than vessel9

Battery-powered vehicle or Battery-powered equipment 9

Capacitor, asymmetric with an energy storage capacity greater than 0.3 W h 9

Capacitor, electric double layer with an energy storage capacity greater than 0.3 W h 9

Chemical kit 9

Cotton 9

Dangerous Goods in Machinery or Dangerous Goods in Apparatus 9

Elevated temperature liquid, n.o.s., at or above 100 C and below its flash point ( including molten metals,

molten salts, etc.)9

Elevated temperature solid, n.o.s., at or above 240 C, see §173.247(h)(4) 9

Engine, internal combustion or Machinery, internal combustion 9

Environmentally hazardous substance, liquid, n.o.s. 9

Environmentally hazardous substance, solid, n.o.s 9

First aid kit 9

Hazardous waste, liquid, n.o.s. 9

Hazardous waste, solid, n.o.s. 9

Lithium ion batteries including lithium ion polymer batteries 9

Lithium ion batteries contained in equipment including lithium ion polymer batteries 9

Lithium ion batteries packed with equipment including lithium ion polymer batteries 9

Lithium metal batteries including lithium alloy batteries 9

Lithium metal batteries contained in equipment including lithium alloy batteries 9

Lithium metal batteries packed with equipment including lithium alloy batteries 9

Other regulated substances, liquid, n.o.s 9

Other regulated substances, solid, n.o.s 9

Plastic molding compound in dough, sheet or extruded rope form evolving flammable vapor 9

Polyhalogenated biphenyls, liquid or Halogenated monomethyldiphenyl-methanes, liquid or

Polyhalogenated terphenyls, liquid9

Polyhalogenated biphenyls, solid or Halogenated monomethyldiphenyl-methanes, solid or Polyhalogenated

terphenyls, solid9

Polymeric beads expandable, evolving flammable vapor 9

Safety devices, electrically initiated 9

Self-defense spray, non-pressurized 9

Vehicle, flammable gas powered or Vehicle, fuel cell, flammable gas powered 9

Vehicle, flammable liquid powered or Vehicle, fuel cell, flammable liquid powered 9


APPENDIX 3

HAZARDOUS SUBSTANCE

Appendix A to 172.101 List of Hazardous Substances and Reportable QuantitiesTable - 1 Hazardous Substances

Other than Radionuclides

SET Environmental, Inc. A3-1 Last Revision: June 27, 2011

Hazardous Substance

5000 A2213100 Acenaphthene

5000 Acenaphthylene1000 Acetaldehyde1000 Acetaldehyde, chloro-5000 Acetaldehyde, trichloro-100 Acetamide

1000 Acetamide, N-(aminothioxomethyl)-100 Acetamide, N-(4-ethoxyphenyl)-

1 Acetamide, N-9H-fluoren-2-yl-100 Acetamide, 2-fluoro-

5000 Acetic acid100 Acetic acid, (2,4-dichlorophenoxy)-, salts & esters

5000 Acetic acid, ethyl ester10 Acetic acid, fluoro-, sodium salt10 Acetic acid, lead(2+) salt

100 Acetic acid, thallium(1+) salt1000 Acetic acid, (2,4,5-trichlorophenoxy)-5000 Acetic anhydride5000 Acetone

10 Acetone cyanohydrin5000 Acetonitrile5000 Acetophenone

1 2-Acetylaminofluorene5000 Acetyl bromide5000 Acetyl chloride1000 1-Acetyl-2-thiourea

1 Acrolein5000 Acrylamide5000 Acrylic acid100 Acrylonitrile

5000 Adipic acid1 Aldicarb

100 Aldicarb sulfone1 Aldrin

100 Allyl alcohol1000 Allyl chloride100 Aluminum phosphide

5000 Aluminum sulfate1 4-Aminobiphenyl

1000 5-(Aminomethyl)-3-isoxazolol1000 4-Aminopyridine

10 Amitrole100 Ammonia

5000 Ammonium acetate5000 Ammonium benzoate5000 Ammonium bicarbonate

10 Ammonium bichromate100 Ammonium bifluoride

5000 Ammonium bisulfite

RQpounds




Hazardous SubstanceRQpounds

5000 Ammonium carbamate5000 Ammonium carbonate5000 Ammonium chloride

10 Ammonium chromate5000 Ammonium citrate, dibasic

10 Ammonium dichromate @5000 Ammonium fluoborate100 Ammonium fluoride

1000 Ammonium hydroxide5000 Ammonium oxalate

10 Ammonium picrate1000 Ammonium silicofluoride5000 Ammonium sulfamate100 Ammonium sulfide

5000 Ammonium sulfite5000 Ammonium tartrate5000 Ammonium thiocyanate1000 Ammonium vanadate5000 Amyl acetate

.....iso-Amyl acetate

.....sec-Amyl acetate

.....tert-Amyl acetate5000 Aniline100 o-Anisidine

5000 Anthracene5000 Antimony♣1000 Antimony pentachloride100 Antimony potassium tartrate

1000 Antimony tribromide1000 Antimony trichloride1000 Antimony trifluoride1000 Antimony trioxide

1 Argentate(1-), bis(cyano-C)-, potassium1 Aroclor 10161 Aroclor 12211 Aroclor 12321 Aroclor 12421 Aroclor 12481 Aroclor 12541 Aroclor 12601 Aroclors1 Arsenic♣1 Arsenic acid H3AsO41 Arsenic disulfide1 Arsenic oxide As2O31 Arsenic oxide As2O51 Arsenic pentoxide1 Arsenic trichloride1 Arsenic trioxide1 Arsenic trisulfide





1 Arsine, diethyl-1 Arsinic acid, dimethyl-1 Arsonous dichloride, phenyl-1 Asbestos♠

100 Auramine1 Azaserine1 Aziridine1 Aziridine, 2-methyl-

10 Azirino[2',3':3,4]pyrrolo[1,2-a]indole-4,7-dione, 6-amino-8- [[(aminocarbonyl)oxy]methyl]-1,1a,2,8,8a,8b-hexahydro-8a- methoxy-5-methyl-, [1aS-(1aalpha,8beta,8aalpha, 8balpha)]-

10 Barban10 Barium cyanide

100 Bendiocarb1000 Bendiocarb phenol

10 Benomyl10 Benz[j]aceanthrylene, 1,2-dihydro-3-methyl-

100 Benz[c]acridine5000 Benzal chloride5000 Benzamide, 3,5-dichloro-N-(1,1-dimethyl-2-propynyl)-

10 Benz[a]anthracene10 1,2-Benzanthracene1 Benz[a]anthracene, 7,12-dimethyl-

5000 Benzenamine100 Benzenamine, 4,4'-carbonimidoylbis (N,N dimethyl-

1000 Benzenamine, 4-chloro-100 Benzenamine, 4-chloro-2-methyl-, hydrochloride10 Benzenamine, N,N-dimethyl-4-(phenylazo)-

100 Benzenamine, 2-methyl-100 Benzenamine, 4-methyl-10 Benzenamine, 4,4'-methylenebis[2-chloro-

100 Benzenamine, 2-methyl-, hydrochloride100 Benzenamine, 2-methyl-5-nitro-

5000 Benzenamine, 4-nitro-10 Benzene10 Benzeneacetic acid, 4-chloro-[alpha]-(4-chlorophenyl)- [alpha]-hydroxy-, ethyl ester

100 Benzene, 1-bromo-4-phenoxy-10 Benzenebutanoic acid, 4-[bis(2-chloroethyl)amino]-

100 Benzene, chloro-100 Benzene, (chloromethyl)-10 Benzenediamine, ar-methyl-

100 1,2-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester10 1,2-Benzenedicarboxylic acid, dibutyl ester

1000 1,2-Benzenedicarboxylic acid, diethyl ester5000 1,2-Benzenedicarboxylic acid, dimethyl ester5000 1,2-Benzenedicarboxylic acid, dioctyl ester100 Benzene, 1,2-dichloro-100 Benzene, 1,3-dichloro-100 Benzene, 1,4-dichloro-

1 Benzene, 1,1'-(2,2-dichloroethylidene) bis[4-chloro-5000 Benzene, (dichloromethyl)-





100 Benzene, 1,3-diisocyanatomethyl-100 Benzene, dimethyl-

5000 1,3-Benzenediol1000 1,2-Benzenediol,4-[1-hydroxy-2-(methylamino) ethyl]-5000 Benzeneethanamine, alpha,alpha-dimethyl-

10 Benzene, hexachloro-1000 Benzene, hexahydro-1000 Benzene, methyl-

10 Benzene, 1-methyl-2,4-dinitro-100 Benzene, 2-methyl-1,3-dinitro-

5000 Benzene, (1-methylethyl)-1000 Benzene, nitro-

10 Benzene, pentachloro-100 Benzene, pentachloronitro-100 Benzenesulfonic acid chloride100 Benzenesulfonyl chloride

5000 Benzene,1,2,4,5-tetrachloro-100 Benzenethiol

1 Benzene,1,1'-(2,2,2-trichloroethylidene) bis[4-chloro-1 Benzene,1,1'-(2,2,2-trichloroethylidene) bis[4-methoxy-

10 Benzene, (trichloromethyl)-10 Benzene, 1,3,5-trinitro-1 Benzidine

100 1,2-Benzisothiazol-3(2H)-one, 1,1-dioxide, & salts Removed June 27, 201110 Benzo[a]anthracene

100 1,3-Benzodioxole, 5-(1-propenyl)-1100 1,3-Benzodioxole, 5-(2-propenyl)-10 1,3-Benzodioxole, 5-propyl-

1000 1,3-Benzodioxol-4-ol, 2,2-dimethyl-100 1,3-Benzodioxol-4-ol, 2,2-dimethyl-, methyl carbamate

1 Benzo[b]fluoranthene5000 Benzo(k)fluoranthene

10 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-10 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-, methylcarbamate.

5000 Benzoic acid100 Benzoic acid, 2-hydroxy-, compd. with (3aS-cis)- 1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethylpyrrolo [2,3-

b]indol-5-yl methylcarbamate ester (1:1)5000 Benzonitrile

10 Benzo[rst]pentaphene5000 Benzo[ghi]perylene100 2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenylbutyl)-, & salts

1 Benzo[a]pyrene1 3,4-Benzopyrene

10 p-Benzoquinone10 Benzotrichloride

1000 Benzoyl chloride100 Benzyl chloride10 Beryllium♣1 Beryllium chloride1 Beryllium fluoride





1 Beryllium nitrate10 Beryllium powder♣10 alpha-BHC1 beta-BHC1 delta-BHC1 gamma-BHC

10 2,2'-Bioxirane100 Biphenyl

1 [1,1'-Biphenyl]-4,4'-diamine1 [1,1'-Biphenyl]-4,4'-diamine,3,3'-dichloro-

100 [1,1'-Biphenyl]-4,4'-diamine,3,3'-dimethoxy-10 [1,1'-Biphenyl]-4,4'-diamine,3,3'-dimethyl-

1000 Bis(2-chloroethoxy) methane10 Bis(2-chloroethyl) ether10 Bis(chloromethyl) ether

100 Bis(2-ethylhexyl) phthalate1000 Bromoacetone100 Bromoform

1000 Bromomethane100 4-Bromophenyl phenyl ether100 Brucine10 1,3-Butadiene1 1,3-Butadiene, 1,1,2,3,4,4-hexachloro-

10 1-Butanamine, N-butyl-N-nitroso-5000 1-Butanol5000 2-Butanone100 2-Butanone, 3,3-dimethyl-1(methylthio)-, O [(methylamino) carbonyl] oxime10 2-Butanone peroxide

100 2-Butenal1 2-Butene, 1,4-dichloro-

10 2-Butenoic acid, 2-methyl-, 7-[[2,3-dihydroxy-2-(1- methoxyethyl)-3-methyl-1-oxobutoxy] methyl]-2,3,5,7a- tetrahydro-1H-pyrrolizin-1-yl ester, [1S-[1alpha(Z), 7(2S*,3R*),7aalpha]]-

5000 Butyl acetate.....iso-Butyl acetate.....sec-Butyl acetate.....tert-Butyl acetate

5000 n-Butyl alcohol1000 Butylamine

.....iso-Butylamine

.....sec-Butylamine

.....tert-Butylamine100 Butyl benzyl phthalate10 n-Butyl phthalate

5000 Butyric acid.....iso-Butyric acid

1 Cacodylic acid10 Cadmium♣10 Cadmium acetate10 Cadmium bromide10 Cadmium chloride





1 Calcium arsenate1 Calcium arsenite

10 Calcium carbide10 Calcium chromate

1000 Calcium cyanamide10 Calcium cyanide Ca(CN)2

1000 Calcium dodecylbenzenesulfonate10 Calcium hypochlorite10 Captan10 Carbamic acid, 1H-benzimidazol-2-yl, methyl ester10 Carbamic acid, [1-[(butylamino)carbonyl]-1H-benzimidazol-2- yl]-, methyl ester10 Carbamic acid, (3-chlorophenyl)-, 4-chloro-2-butynyl ester.

1000 Carbamic acid, [(dibutylamino)-thio]methyl-, 2,3-dihydro- 2,2-dimethyl-7-benzofuranyl ester1 Carbamic acid, dimethyl-,1-[(dimethyl-amino)carbonyl]-5- methyl-1H-pyrazol-3-yl ester

100 Carbamic acid, dimethyl-, 3-methyl-1-(1-methylethyl)-1H- pyrazol-5-yl ester100 Carbamic acid, ethyl ester

1000 Carbamic acid, methyl-, 3-methylphenyl ester1 Carbamic acid, methylnitroso-, ethyl ester

10 Carbamic acid, [1,2-phenylenebis(iminocarbonothioyl)] bis-, dimethyl ester1000 Carbamic acid, phenyl-, 1-methylethyl ester

1 Carbamic chloride, dimethyl-5000 Carbamodithioic acid, 1,2-ethanediylbis-, salts & esters100 Carbamothioic acid, bis(1-methylethyl)-, S-(2,3-dichloro-2- propenyl) ester100 Carbamothioic acid, bis(1-methylethyl)-, S-(2,3,3-trichloro- 2-propenyl) ester

5000 Carbamothioic acid, dipropyl-, S-(phenylmethyl) ester100 Carbaryl10 Carbendazim10 Carbofuran10 Carbofuran phenol

100 Carbon disulfide100 Carbonic acid, dithallium(1+) salt10 Carbonic dichloride

1000 Carbonic difluoride1000 Carbonochloridic acid, methyl ester1000 Carbon oxyfluoride

10 Carbon tetrachloride100 Carbonyl sulfide

1000 Carbosulfan100 Catechol

5000 Chloral100 Chloramben10 Chlorambucil1 Chlordane1 Chlordane, alpha & gamma isomers1 CHLORDANE (TECHNICAL MIXTURE AND METABOLITES)1 Chlorinated camphene

10 Chlorine100 Chlornaphazine

1000 Chloroacetaldehyde100 Chloroacetic acid





100 2-Chloroacetophenone1000 p-Chloroaniline100 Chlorobenzene10 Chlorobenzilate

5000 p-Chloro-m-cresol100 Chlorodibromomethane100 1-Chloro-2,3-epoxypropane100 Chloroethane

1000 2-Chloroethyl vinyl ether10 Chloroform

100 Chloromethane10 Chloromethyl methyl ether

5000 beta-Chloronaphthalene5000 2-Chloronaphthalene100 2-Chlorophenol100 o-Chlorophenol

5000 4-Chlorophenyl phenyl ether100 1-(o-Chlorophenyl)thiourea100 Chloroprene

1000 3-Chloropropionitrile1000 Chlorosulfonic acid100 4-Chloro-o-toluidine, hydrochloride

1 Chlorpyrifos1000 Chromic acetate

10 Chromic acid10 Chromic acid H2CrO4, calcium salt

1000 Chromic sulfate5000 Chromium♣1000 Chromous chloride100 Chrysene

1000 Cobaltous bromide1000 Cobaltous formate1000 Cobaltous sulfamate

1 Coke Oven Emissions5000 Copper♣

10 Copper chloride @10 Copper cyanide Cu(CN)10 Coumaphos1 Creosote

100 Cresol (cresylic acid)100 m-Cresol100 o-Cresol100 p-Cresol100 Cresols (isomers and mixture)100 Cresylic acid (isomers and mixture)100 Crotonaldehyde

5000 Cumene10 m-Cumenyl methylcarbamate

100 Cupric acetate1 Cupric acetoarsenite





10 Cupric chloride100 Cupric nitrate100 Cupric oxalate10 Cupric sulfate

100 Cupric sulfate, ammoniated100 Cupric tartrate10 Cyanides (soluble salts and complexes) not otherwise specified

100 Cyanogen1000 Cyanogen bromide (CN)Br

10 Cyanogen chloride (CN)Cl10 2,5-Cyclohexadiene-1,4-dione

1000 Cyclohexane1 Cyclohexane, 1,2,3,4,5,6-hexachloro-, (1[alpha], 2[alpha], 3[beta]-, 4[alpha], 5[alpha], 6[beta]

5000 Cyclohexanone100 2-Cyclohexyl-4,6-dinitrophenol10 1,3-Cyclopentadiene, 1,2,3,4,5,5-hexachloro-10 Cyclophosphamide

100 2,4-D Acid100 2,4-D Ester100 2,4-D, salts and esters10 Daunomycin1 DDD1 4,4'-DDD1 DDE (72-55-9) #

5000 DDE (3547-04-4) #1 4,4'-DDE1 DDT1 4,4'-DDT

100 DEHP100 Diallate

1 Diazinon100 Diazomethane

1 Dibenz[a,h]anthracene1 1,2:5,6-Dibenzanthracene1 Dibenzo[a,h]anthracene

100 Dibenzofuran10 Dibenzo[a,i]pyrene1 1,2-Dibromo-3-chloropropane1 Dibromoethane

10 Dibutyl phthalate10 Di-n-butyl phthalate

1000 Dicamba100 Dichlobenil

1 Dichlone100 Dichlorobenzene100 1,2-Dichlorobenzene100 1,3-Dichlorobenzene100 1,4-Dichlorobenzene100 m-Dichlorobenzene100 o-Dichlorobenzene





100 p-Dichlorobenzene1 3,3'-Dichlorobenzidine

5000 Dichlorobromomethane1 1,4-Dichloro-2-butene

5000 Dichlorodifluoromethane1000 1,1-Dichloroethane100 1,2-Dichloroethane100 1,1-Dichloroethylene

1000 1,2-Dichloroethylene10 Dichloroethyl ether

1000 Dichloroisopropyl ether1000 Dichloromethane1000 Dichloromethoxyethane

10 Dichloromethyl ether100 2,4-Dichlorophenol100 2,6-Dichlorophenol

1 Dichlorophenylarsine1000 Dichloropropane

.....1,1-Dichloropropane

.....1,3-Dichloropropane1000 1,2-Dichloropropane100 Dichloropropane-Dichloropropene (mixture)100 Dichloropropene

.....2,3-Dichloropropene100 1,3-Dichloropropene

5000 2,2-Dichloropropionic acid10 Dichlorvos10 Dicofol1 Dieldrin

10 1,2:3,4-Diepoxybutane100 Diethanolamine100 Diethylamine

1000 N,N-Diethylaniline1 Diethylarsine

5000 Diethylene glycol, dicarbamate100 1,4-Diethyleneoxide100 Diethylhexyl phthalate10 N,N'-Diethylhydrazine

5000 O,O-Diethyl S-methyl dithiophosphate100 Diethyl-p-nitrophenyl phosphate

1000 Diethyl phthalate100 O,O-Diethyl O-pyrazinyl phosphorothioate

1 Diethylstilbestrol10 Diethyl sulfate10 Dihydrosafrole

100 Diisopropylfluorophosphate (DFP)1 1,4:5,8-Dimethanonaphthalene, 1,2,3,4,10,10-hexachloro- 1,4,4a,5,8,8a-hexahydro-, (1alpha, 4alpha,

4abeta, 5alpha, 8alpha, 8abeta)-1,4:5,8-Dimethanonaphthalene, 1,2,3,4,10,10-hexachloro- 1,4,4a,5,8,8a-hexahydro-, (1alpha, 4alpha, 4abeta, 5beta, 8beta, 8abeta)-1 (0.454)





1 2,7:3,6-Dimethanonaphth[2,3-b]oxirene,3,4,5,6,9,9- hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-, (1aalpha, 2beta, 2aalpha, 3beta, 6beta, 6aalpha, 7beta, 7aalpha)-

1 2,7:3,6-Dimethanonaphth[2, 3-b]oxirene,3,4,5,6,9,9- hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-, (1aalpha, 2beta, 2abeta, 3alpha, 6alpha, 6abeta, 7beta, 7aalpha)-, & metabolites

10 Dimethoate100 3,3'-Dimethoxybenzidine

1000 Dimethylamine10 Dimethyl aminoazobenzene10 p-Dimethylaminoazobenzene

100 N,N-Dimethylaniline1 7,12-Dimethylbenz[a]anthracene

10 3,3'-Dimethylbenzidine10 alpha,alpha-Dimethylbenzylhydroperoxide1 Dimethylcarbamoyl chloride

100 Dimethylformamide10 1,1-Dimethylhydrazine1 1,2-Dimethylhydrazine

10 Dimethylhydrazine, unsymmetrical @5000 alpha,alpha-Dimethylphenethylamine100 2,4-Dimethylphenol

5000 Dimethyl phthalate100 Dimethyl sulfate

1 Dimetilan100 Dinitrobenzene (mixed)

.....m-Dinitrobenzene

.....o-Dinitrobenzene

.....p-Dinitrobenzene10 4,6-Dinitro-o-cresol, and salts10 Dinitrogen tetroxide @10 Dinitrophenol

.....2,5-Dinitrophenol

.....2,6-Dinitrophenol10 2,4-Dinitrophenol10 Dinitrotoluene

.....3,4-Dinitrotoluene10 2,4-Dinitrotoluene

100 2,6-Dinitrotoluene1000 Dinoseb5000 Di-n-octyl phthalate100 1,4-Dioxane10 1,2-Diphenylhydrazine

100 Diphosphoramide, octamethyl-10 Diphosphoric acid, tetraethyl ester

5000 Dipropylamine10 Di-n-propylnitrosamine

1000 Diquat1 Disulfoton

100 Dithiobiuret100 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime100 Diuron





1000 Dodecylbenzenesulfonic acid1 Endosulfan1 alpha-Endosulfan1 beta-Endosulfan1 Endosulfan sulfate

1000 Endothall1 Endrin1 Endrin aldehyde1 Endrin, & metabolites

100 Epichlorohydrin1000 Epinephrine100 1,2-Epoxybutane

1000 Ethanal5000 Ethanamine, N,N-diethyl-

1 Ethanamine, N-ethyl-N-nitroso-5000 1,2-Ethanediamine, N,N-dimethyl-N'-2-pyridinyl-N'-(2- thienylmethyl)-

1 Ethane, 1,2-dibromo-1000 Ethane, 1,1-dichloro-100 Ethane, 1,2-dichloro-100 Ethanedinitrile100 Ethane, hexachloro-

1000 Ethane, 1,1'-[methylenebis(oxy)]bis[2-chloro-100 Ethane, 1,1'-oxybis-10 Ethane, 1,1'-oxybis[2-chloro-10 Ethane, pentachloro-

100 Ethane, 1,1,1,2-tetrachloro-100 Ethane, 1,1,2,2-tetrachloro-10 Ethanethioamide

1000 Ethane, 1,1,1-trichloro-100 Ethane, 1,1,2-trichloro-

5000 Ethanimidothioic acid, 2-(dimethylamino)-N-hydroxy-2-oxo-, methyl ester100 Ethanimidothioic acid, 2-(dimethylamino)-N-[[(methylamino) carbonyl]oxy]-2-oxo-, methyl ester100 Ethanimidothioic acid, N-[[(methylamino) carbonyl]oxy]-, methyl ester100 Ethanimidothioic acid, N,N'[thiobis[(methylimino)carbonyloxy]] bis-, dimethyl ester

1000 Ethanol, 2-ethoxy-1 Ethanol, 2,2'-(nitrosoimino)bis-

5000 Ethanol, 2,2'-oxybis-, dicarbamate5000 Ethanone, 1-phenyl-

1 Ethene, chloro-1000 Ethene, (2-chloroethoxy)-100 Ethene, 1,1-dichloro-

1000 Ethene, 1,2-dichloro-(E)100 Ethene, tetrachloro-100 Ethene, trichloro-10 Ethion

5000 Ethyl acetate1000 Ethyl acrylate1000 Ethylbenzene100 Ethyl carbamate100 Ethyl chloride





10 Ethyl cyanide5000 Ethylenebisdithiocarbamic acid, salts & esters5000 Ethylenediamine5000 Ethylenediamine-tetraacetic acid (EDTA)

1 Ethylene dibromide100 Ethylene dichloride

5000 Ethylene glycol1000 Ethylene glycol monoethyl ether

10 Ethylene oxide10 Ethylenethiourea1 Ethylenimine

100 Ethyl ether1000 Ethylidene dichloride1000 Ethyl methacrylate

1 Ethyl methanesulfonate5000 Ethyl methyl ketone @

1000 Famphur1000 Ferric ammonium citrate1000 Ferric ammonium oxalate1000 Ferric chloride100 Ferric fluoride

1000 Ferric nitrate1000 Ferric sulfate1000 Ferrous ammonium sulfate100 Ferrous chloride

1000 Ferrous sulfate100 Fluoranthene

5000 Fluorene10 Fluorine

100 Fluoroacetamide10 Fluoroacetic acid, sodium salt

100 Formaldehyde100 Formetanate hydrochloride

5000 Formic acid100 Formparanate10 Fulminic acid, mercury(2+)salt

5000 Fumaric acid100 Furan

5000 2-Furancarboxyaldehyde5000 2,5-Furandione1000 Furan, tetrahydro-5000 Furfural100 Furfuran

1 Glucopyranose, 2-deoxy-2-(3-methyl-3-nitrosoureido)-, D-1 D-Glucose, 2-deoxy-2-[[(methylnitrosoamino)-carbonyl]amino]-

10 Glycidylaldehyde10 Guanidine, N-methyl-N'-nitro-N-nitroso-1 Guthion1 Heptachlor1 Heptachlor epoxide





10 Hexachlorobenzene1 Hexachlorobutadiene

10 Hexachlorocyclopentadiene100 Hexachloroethane100 Hexachlorophene

1000 Hexachloropropene100 Hexaethyl tetraphosphate100 Hexamethylene-1,6-diisocyanate

1 Hexamethylphosphoramide5000 Hexane5000 Hexone

1 Hydrazine100 Hydrazinecarbothioamide10 Hydrazine, 1,2-diethyl-10 Hydrazine, 1,1-dimethyl-1 Hydrazine, 1,2-dimethyl-

10 Hydrazine, 1,2-diphenyl-10 Hydrazine, methyl-

5000 Hydrochloric acid10 Hydrocyanic acid

100 Hydrofluoric acid5000 Hydrogen chloride

10 Hydrogen cyanide100 Hydrogen fluoride100 Hydrogen phosphide100 Hydrogen sulfide H2S10 Hydroperoxide, 1-methyl-1-phenylethyl-

100 Hydroquinone10 2-Imidazolidinethione

100 Indeno(1,2,3-cd)pyrene100 Iodomethane

5000 1,3-Isobenzofurandione5000 Isobutyl alcohol

1 Isodrin100 Isolan

5000 Isophorone100 Isoprene

1000 Isopropanolamine dodecylbenzenesulfonate10 3-Isopropylphenyl N-methylcarbamate

100 Isosafrole1000 3(2H)-Isoxazolone, 5-(aminomethyl)-

1 Kepone10 Lasiocarpine10 Lead♣10 Lead acetate1 Lead arsenate

10 Lead, bis(acetato-O)tetrahydroxytri-10 Lead chloride10 Lead fluoborate10 Lead fluoride





10 Lead iodide10 Lead nitrate10 Lead phosphate10 Lead stearate10 Lead subacetate10 Lead sulfate10 Lead sulfide10 Lead thiocyanate1 Lindane1 Lindane (all isomers)

10 Lithium chromate100 Malathion

5000 Maleic acid5000 Maleic anhydride5000 Maleic hydrazide1000 Malononitrile

10 Manganese, bis(dimethylcarbamodithioato-S,S')-10 Manganese dimethyldithiocarbamate

5000 MDI5000 MEK

1 Melphalan10 Mercaptodimethur1 Mercuric cyanide

10 Mercuric nitrate10 Mercuric sulfate10 Mercuric thiocyanate10 Mercurous nitrate1 Mercury

100 Mercury, (acetato-O)phenyl-10 Mercury fulminate

1000 Methacrylonitrile1000 Methanamine, N-methyl-

10 Methanamine, N-methyl-N-nitroso-1000 Methane, bromo-100 Methane, chloro-10 Methane, chloromethoxy-

1000 Methane, dibromo-1000 Methane, dichloro-5000 Methane, dichlorodifluoro-100 Methane, iodo-10 Methane, isocyanato-10 Methane, oxybis(chloro-

100 Methanesulfenyl chloride, trichloro-1 Methanesulfonic acid, ethyl ester

10 Methane, tetrachloro-10 Methane, tetranitro-

100 Methanethiol100 Methane, tribromo-10 Methane, trichloro-

5000 Methane, trichlorofluoro-





100Methanimidamide, N,N-dimethyl-N'-[3-[[(methylamino) carbonyl] oxy] phenyl]-, monohydrochloride

100 Methanimidamide, N,N-dimethyl-N'-[2-methyl-4- [[(methylamino)carbonyl] oxy]phenyl]-1

6,9-Methano-2,4,3-benzodioxathiepin,6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide1 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a- tetrahydro-1 4,7-Methano-1H-indene, 1,2,4,5,6,7,8,8-octachloro- 2,3,3a,4,7,7a-hexahydro-

5000 Methanol5000 Methapyrilene

1 1,3,4-Metheno-2H-cyclobuta[cd]pentalen-2-one, 1,1a,3,3a,4,5,5,5a,5b,6-decachlorooctahydro-10 Methiocarb

100 Methomyl1 Methoxychlor

5000 Methyl alcohol100 Methylamine @

1 2-Methyl aziridine1000 Methyl bromide100 1-Methylbutadiene100 Methyl chloride

1000 Methyl chlorocarbonate1000 Methyl chloroform1000 Methyl chloroformate @

10 Methyl chloromethyl ether @10 3-Methylcholanthrene10 4,4'-Methylenebis(2-chloroaniline)

1000 Methylene bromide1000 Methylene chloride

10 4,4'-Methylenedianiline5000 Methylene diphenyl diisocyanate5000 Methyl ethyl ketone

10 Methyl ethyl ketone peroxide10 Methyl hydrazine

100 Methyl iodide5000 Methyl isobutyl ketone

10 Methyl isocyanate10 2-Methyllactonitrile

100 Methyl mercaptan1000 Methyl methacrylate100 Methyl parathion

5000 4-Methyl-2-pentanone1000 Methyl tert-butyl ether

10 Methylthiouracil1000 Metolcarb

10 Mevinphos1000 Mexacarbate

10 Mitomycin C10 MNNG

100 Monoethylamine100 Monomethylamine10 Naled





10 5,12-Naphthacenedione, 8-acetyl-10-[(3-amino-2,3,6-trideoxy- alpha-L-lyxo-hexopyranosyl)oxy]-7,8,9,10-tetrahydro-6,8,11- trihydroxy-1-methoxy-, (8S-cis)-

100 1-Naphthalenamine10 2-Naphthalenamine

100 Naphthalenamine, N,N'-bis(2-chloroethyl)-100 Naphthalene

5000 Naphthalene, 2-chloro-5000 1,4-Naphthalenedione

10 2,7-Naphthalenedisulfonic acid, 3,3'-[(3,3'-dimethyl-(1,1'- biphenyl)-4,4'-diyl)-bis(azo)]bis(5-amino-4-hydroxy)- tetrasodium salt

100 1-Naphthalenol, methylcarbamate100 Naphthenic acid

5000 1,4-Naphthoquinone100 alpha-Naphthylamine10 beta-Naphthylamine

100 alpha-Naphthylthiourea100 Nickel♣100 Nickel ammonium sulfate10 Nickel carbonyl Ni(CO)4, (T-4)-

100 Nickel chloride10 Nickel cyanide Ni(CN)210 Nickel hydroxide

100 Nickel nitrate100 Nickel sulfate100 Nicotine, & salts

1000 Nitric acid100 Nitric acid, thallium (1+) salt10 Nitric oxide

5000 p-Nitroaniline1000 Nitrobenzene

10 4-Nitrobiphenyl10 Nitrogen dioxide10 Nitrogen oxide NO10 Nitrogen oxide NO210 Nitroglycerine

100 Nitrophenol (mixed).....m-Nitrophenol.

100 o-Nitrophenol100 p-Nitrophenol100 2-Nitrophenol100 4-Nitrophenol10 2-Nitropropane10 N-Nitrosodi-n-butylamine1 N-Nitrosodiethanolamine1 N-Nitrosodiethylamine

10 N-Nitrosodimethylamine100 N-Nitrosodiphenylamine

1 N-Nitroso-N-ethylurea1 N-Nitroso-N-methylurea1 N-Nitroso-N-methylurethane





10 N-Nitrosomethylvinylamine1 N-Nitrosomorpholine

10 N-Nitrosopiperidine1 N-Nitrosopyrrolidine

1000 Nitrotoluene.....m-Nitrotoluene.....o-Nitrotoluene.....p-Nitrotoluene

100 5-Nitro-o-toluidine100 Octamethylpyrophosphoramide

1000 Osmium oxide OsO4, (T-4)-1000 Osmium tetroxide1000 7-Oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid100 Oxamyl10 1,2-Oxathiolane, 2,2-dioxide10 2H-1,3,2-Oxazaphosphorin-2-amine, N,N-bis(2-chloroethyl) tetrahydro-, 2-oxide10 Oxirane10 Oxiranecarboxyaldehyde

100 Oxirane, (chloromethyl)-1000 Paraformaldehyde1000 Paraldehyde

10 Parathion1 PCBs

100 PCNB10 Pentachlorobenzene10 Pentachloroethane

100 Pentachloronitrobenzene10 Pentachlorophenol

100 1,3-Pentadiene100 Perchloroethylene100 Perchloromethyl mercaptan @100 Phenacetin

5000 Phenanthrene1000 Phenol100 Phenol, 2-chloro-

5000 Phenol, 4-chloro-3-methyl-100 Phenol, 2-cyclohexyl-4,6-dinitro-100 Phenol, 2,4-dichloro-100 Phenol, 2,6-dichloro-

1 Phenol, 4,4'-(1,2-diethyl-1,2-ethenediyl)bis-, (E)100 Phenol, 2,4-dimethyl-

1000 Phenol, 4-(dimethylamino)-3,5-dimethyl-, methylcarbamate (ester)10 Phenol, (3,5-dimethyl-4-(methylthio)-, methylcarbamate10 Phenol, 2,4-dinitro-

100 Phenol, methyl-10 Phenol, 2-methyl-4,6-dinitro-, & salts

100 Phenol, 2,2'-methylenebis[3,4,6-trichloro-100 Phenol, 2-(1-methylethoxy)-, methylcarbamate10 Phenol, 3-(1-methylethyl)-, methyl carbamate

1000 Phenol, 3-methyl-5-(1-methylethyl)-, methyl carbamate





1000 Phenol, 2-(1-methylpropyl)-4,6-dinitro-100 Phenol, 4-nitro-10 Phenol, pentachloro-10 Phenol, 2,3,4,6-tetrachloro-10 Phenol, 2,4,5-trichloro-10 Phenol, 2,4,6-trichloro-10 Phenol, 2,4,6-trinitro-, ammonium salt1 L-Phenylalanine, 4-[bis(2-chloroethyl)amino]-

5000 p-Phenylenediamine100 Phenyl mercaptan @100 Phenylmercury acetate100 Phenylthiourea10 Phorate10 Phosgene

100 Phosphine5000 Phosphoric acid100 Phosphoric acid, diethyl 4-nitrophenyl ester10 Phosphoric acid, lead(2+) salt (2:3)1 Phosphorodithioic acid, O,O-diethyl S-[2-(ethylthio)ethyl] ester

10 Phosphorodithioic acid, O,O-diethyl S-[(ethylthio)methyl] ester5000 Phosphorodithioic acid, O,O-diethyl S-methyl ester

10 Phosphorodithioic acid, O,O-dimethyl S-[2-(methylamino)-2- oxoethyl] ester100 Phosphorofluoridic acid, bis(1-methylethyl) ester10 Phosphorothioic acid, O,O-diethyl O-(4-nitrophenyl) ester

100 Phosphorothioic acid, O,O-diethyl O-pyrazinyl ester1000 Phosphorothioic acid, O-[4-[(dimethylamino) sulfonyl]phenyl] O,O-dimethyl ester100 Phosphorothioic acid, O,O-dimethyl O-(4-nitrophenyl) ester.

1 Phosphorus1000 Phosphorus oxychloride100 Phosphorus pentasulfide100 Phosphorus sulfide

1000 Phosphorus trichloride5000 Phthalic anhydride100 Physostigmine100 Physostigmine salicylate

5000 2-Picoline10 Piperidine, 1-nitroso-10 Plumbane, tetraethyl-1 POLYCHLORINATED BIPHENYLS1 Potassium arsenate1 Potassium arsenite

10 Potassium bichromate10 Potassium chromate10 Potassium cyanide K(CN)

1000 Potassium hydroxide100 Potassium permanganate

1 Potassium silver cyanide1000 Promecarb5000 Pronamide100 Propanal, 2-methyl-2-(methyl-sulfonyl)-, O- [(methylamino)carbonyl] oxime





1 Propanal, 2-methyl-2-(methylthio)-, O- [(methylamino)carbonyl] oxime5000 1-Propanamine5000 1-Propanamine, N-propyl-

10 1-Propanamine, N-nitroso-N-propyl-1 Propane, 1,2-dibromo-3-chloro-

1000 Propane, 1,2-dichloro-1000 Propanedinitrile

10 Propanenitrile1000 Propanenitrile, 3-chloro-

10 Propanenitrile, 2-hydroxy-2-methyl-10 Propane, 2-nitro-

1000 Propane, 2,2'-oxybis[2-chloro-10 1,3-Propane sultone10 1,2,3-Propanetriol, trinitrate

100 Propanoic acid, 2-(2,4,5-trichlorophenoxy)-10 1-Propanol, 2,3-dibromo-, phosphate (3:1)

5000 1-Propanol, 2-methyl-5000 2-Propanone1000 2-Propanone, 1-bromo-

10 Propargite1000 Propargyl alcohol

1 2-Propenal5000 2-Propenamide100 1-Propene, 1,3-dichloro-

1000 1-Propene, 1,1,2,3,3,3-hexachloro-100 2-Propenenitrile

1000 2-Propenenitrile, 2-methyl-5000 2-Propenoic acid1000 2-Propenoic acid, ethyl ester1000 2-Propenoic acid, 2-methyl-, ethyl ester1000 2-Propenoic acid, 2-methyl-, methyl ester100 2-Propen-1-ol

1000 Propham10 beta-Propiolactone

1000 Propionaldehyde5000 Propionic acid5000 Propionic anhydride100 Propoxur (Baygon)

5000 n-Propylamine1000 Propylene dichloride100 Propylene oxide

1 1,2-Propylenimine1000 2-Propyn-1-ol5000 Prosulfocarb5000 Pyrene

1 Pyrethrins5000 3,6-Pyridazinedione, 1,2-dihydro-1000 4-Pyridinamine1000 Pyridine5000 Pyridine, 2-methyl-





100 Pyridine, 3-(1-methyl-2-pyrrolidinyl)-, (S)-, & salts10 2,4-(1H,3H)-Pyrimidinedione, 5-[bis(2-chloroethyl)amino]-10 4(1H)-Pyrimidinone, 2,3-dihydro-6-methyl-2-thioxo-1 Pyrrolidine, 1-nitroso-

100Pyrrolo[2,3-b] indol-5-ol,1,2,3,3a,8,8a-hexahydro-1,3a,8- trimethyl-, methylcarbamate (ester), (3aS-cis)-

5000 Quinoline10 Quinone

100 Quintobenzene5000 Reserpine5000 Resorcinol100 Saccharin & salts Removed June 27, 2011100 Safrole10 Selenious acid

1000 Selenious acid, dithallium (1+) salt100 Selenium♣10 Selenium dioxide10 Selenium oxide10 Selenium sulfide SeS2

1000 Selenourea1 L-Serine, diazoacetate (ester)

1000 Silver♣1 Silver cyanide Ag(CN)1 Silver nitrate

100 Silvex (2,4,5-TP)10 Sodium1 Sodium arsenate1 Sodium arsenite

1000 Sodium azide10 Sodium bichromate

100 Sodium bifluoride5000 Sodium bisulfite

10 Sodium chromate10 Sodium cyanide Na(CN)

1000 Sodium dodecylbenzenesulfonate1000 Sodium fluoride5000 Sodium hydrosulfide1000 Sodium hydroxide100 Sodium hypochlorite

1000 Sodium methylate100 Sodium nitrite

5000 Sodium phosphate, dibasic5000 Sodium phosphate, tribasic100 Sodium selenite

1 Streptozotocin10 Strontium chromate10 Strychnidin-10-one, & salts

100 Strychnidin-10-one, 2,3-dimethoxy-10 Strychnine, & salts

1000 Styrene





100 Styrene oxide1000 Sulfur chlorides @1000 Sulfuric acid100 Sulfuric acid, dimethyl ester100 Sulfuric acid, dithallium (1+) salt

1000 Sulfur monochloride100 Sulfur phosphide

1000 2,4,5-T1000 2,4,5-T acid5000 2,4,5-T amines1000 2,4,5-T esters1000 2,4,5-T salts

1 TCDD1 TDE

5000 1,2,4,5-Tetrachlorobenzene1 2,3,7,8-Tetrachlorodibenzo-p-dioxin

100 1,1,1,2-Tetrachloroethane100 1,1,2,2-Tetrachloroethane100 Tetrachloroethylene10 2,3,4,6-Tetrachlorophenol10 Tetraethyl pyrophosphate10 Tetraethyl lead

100 Tetraethyldithiopyrophosphate1000 Tetrahydrofuran

10 Tetranitromethane100 Tetraphosphoric acid, hexaethyl ester100 Thallic oxide

1000 Thallium♣100 Thallium (I) acetate100 Thallium (I) carbonate100 Thallium chloride TlCl100 Thallium (I) nitrate100 Thallium oxide Tl2O3

1000 Thallium (I) selenite100 Thallium (I) sulfate10 Thioacetamide

100 Thiodicarb100 Thiodiphosphoric acid, tetraethyl ester100 Thiofanox100 Thioimidodicarbonic diamide [(H2N)C(S)]2NH.100 Thiomethanol10 Thioperoxydicarbonic diamide [(H2N)C(S)]2S2, tetramethyl-10 Thiophanate-methyl

100 Thiophenol100 Thiosemicarbazide10 Thiourea

100 Thiourea, (2-chlorophenyl)-100 Thiourea, 1-naphthalenyl-100 Thiourea, phenyl-10 Thiram





100 Tirpate1000 Titanium tetrachloride1000 Toluene

10 Toluenediamine10 2,4-Toluene diamine

100 Toluene diisocyanate100 2,4-Toluene diisocyanate100 o-Toluidine100 p-Toluidine100 o-Toluidine hydrochloride

1 Toxaphene100 2,4,5-TP acid100 2,4,5-TP esters100 Triallate10 1H-1,2,4-Triazol-3-amine

100 Trichlorfon100 1,2,4-Trichlorobenzene

1000 1,1,1-Trichloroethane100 1,1,2-Trichloroethane100 Trichloroethylene100 Trichloromethanesulfenyl chloride

5000 Trichloromonofluoromethane10 Trichlorophenol

.....2,3,4-Trichlorophenol



.....3,4,5-Trichlorophenol10 2,4,5-Trichlorophenol10 2,4,6-Trichlorophenol

1000 Triethanolamine dodecylbenzenesulfonate5000 Triethylamine

10 Trifluralin100 Trimethylamine

1000 2,2,4-Trimethylpentane10 1,3,5-Trinitrobenzene

1000 1,3,5-Trioxane, 2,4,6-trimethyl-10 Tris(2,3-dibromopropyl) phosphate10 Trypan blue

100 D001 Unlisted Hazardous Wastes Characteristic of Ignitability100 D002 Unlisted Hazardous Wastes Characteristic of Corrosivity100 D003 Unlisted Hazardous Wastes Characteristic of Reactivity

D004-D043 Unlisted Hazardous Wastes Characteristic of Toxicity:1 .....Arsenic (D004)

1000 .....Barium (D005)10 .....Benzene (D018)10 .....Cadmium (D006)10 .....Carbon tetrachloride (D019)1 .....Chlordane (D020)

100 .....Chlorobenzene (D021)10 .....Chloroform (D022)





10 .....Chromium (D007)100 .....o-Cresol (D023)100 .....m-Cresol (D024)100 .....p-Cresol (D025)100 .....Cresol (D026)100 .....2,4-D (D016)100 .....1,4-Dichlorobenzene (D027)100 .....1,2-Dichloroethane (D028)100 .....1,1-Dichloroethylene (D029)10 .....2,4-Dinitrotoluene (D030)1 .....Endrin (D012)1 .....Heptachlor (and epoxide) (D031)

10 .....Hexachlorobenzene (D032)1 .....Hexachlorobutadiene (D033)

100 .....Hexachloroethane (D034)10 .....Lead (D008)1 .....Lindane (D013)1 .....Mercury (D009)1 .....Methoxychlor (D014)

5000 .....Methyl ethyl ketone (D035)1000 .....Nitrobenzene (D036)

10 .....Pentachlorophenol (D037)1000 .....Pyridine (D038)

10 .....Selenium (D010)1 .....Silver (D011)

100 .....Tetrachloroethylene (D039)1 .....Toxaphene (D015)

100 .....Trichloroethylene (D040)10 .....2,4,5-Trichlorophenol (D041)10 .....2,4,6-Trichlorophenol (D042)

100 .....2,4,5-TP (D017)1 .....Vinyl chloride (D043)

10 Uracil mustard100 Uranyl acetate100 Uranyl nitrate

1 Urea, N-ethyl-N-nitroso-1 Urea, N-methyl-N-nitroso-

100 Urethane1000 Vanadic acid, ammonium salt1000 Vanadium oxide V2O51000 Vanadium pentoxide1000 Vanadyl sulfate5000 Vinyl acetate5000 Vinyl acetate monomer

10 Vinylamine, N-methyl-N-nitroso-100 Vinyl bromide

1 Vinyl chloride100 Vinylidene chloride100 Warfarin, & salts100 Xylene





1000 m-Xylene1000 o-Xylene100 p-Xylene100 Xylene (mixed)100 Xylenes (isomers and mixture)

1000 Xylenol5000 Yohimban-16-carboxylic acid,11,17-dimethoxy-18-[(3,4,5- trimethoxybenzoyl)oxy]-, methyl ester

(3beta,16beta,17alpha,18beta, 20alpha)1000 Zinc♣1000 Zinc acetate1000 Zinc ammonium chloride

10 Zinc, bis(dimethylcarbamodithioato-S,S')-1000 Zinc borate1000 Zinc bromide1000 Zinc carbonate1000 Zinc chloride

10 Zinc cyanide Zn(CN)21000 Zinc fluoride1000 Zinc formate1000 Zinc hydrosulfite1000 Zinc nitrate5000 Zinc phenolsulfonate100 Zinc phosphide Zn3P2

5000 Zinc silicofluoride1000 Zinc sulfate

10 Ziram5000 Zirconium nitrate1000 Zirconium potassium fluoride5000 Zirconium sulfate5000 Zirconium tetrachloride

10 F001100 .....(a) Tetrachloroethylene100 .....(b) Trichloroethylene

1000 .....(c) Methylene chloride1000 .....(d) 1,1,1-Trichloroethane

10 .....(e) Carbon tetrachloride5000 .....(f) Chlorinated fluorocarbons

10 F002100 .....(a) Tetrachloroethylene

1000 .....(b) Methylene chloride100 .....(c) Trichloroethylene

1000 .....(d) 1,1,1-Trichloroethane100 .....(e) Chlorobenzene

5000 .....(f) 1,1,2-Trichloro-1,2,2-trifluoroethane100 .....(g) o-Dichlorobenzene

5000 .....(h) Trichlorofluoromethane100 .....(i) 1,1,2-Trichloroethane100 F003

1000 .....(a) Xylene5000 .....(b) Acetone





5000 .....(c) Ethyl acetate1000 .....(d) Ethylbenzene100 .....(e) Ethyl ether

5000 .....(f) Methyl isobutyl ketone5000 .....(g) n-Butyl alcohol5000 .....(h) Cyclohexanone5000 .....(i) Methanol100 F004100 .....(a) Cresols/Cresylic acid

1000 .....(b) Nitrobenzene100 F005

1000 .....(a) Toluene5000 .....(b) Methyl ethyl ketone100 .....(c) Carbon disulfide

5000 .....(d) Isobutanol1000 .....(e) Pyridine

10 F00610 F00710 F00810 F00910 F01010 F01110 F01210 F0191 F0201 F0211 F0221 F0231 F0241 F0251 F0261 F0271 F0281 F0321 F0341 F0351 F0371 F0381 F0391 K001

10 K00210 K00310 K00410 K00510 K00610 K00710 K00810 K00910 K01010 K011





10 K0135000 K014

10 K0151 K016

10 K0171 K0181 K0191 K020

10 K0211 K022

5000 K0235000 K024

10 K0251000 K026

10 K0271 K0281 K0291 K0301 K031

10 K03210 K03310 K0341 K0351 K0361 K037

10 K03810 K03910 K0401 K041

10 K04210 K04310 K04410 K04510 K04610 K04710 K04810 K04910 K05010 K05110 K0521 K060

10 K06110 K06210 K06410 K06510 K06610 K0691 K071

10 K073100 K083





1 K08410 K08510 K086

100 K08710 K08810 K09010 K091

5000 K0935000 K094100 K095100 K096

1 K0971 K098

10 K09910 K1001 K1011 K102

100 K10310 K10410 K1051 K106

10 K10710 K10810 K10910 K11010 K11110 K11210 K11310 K11410 K11510 K1161 K1171 K118

10 K12310 K12410 K12510 K126

100 K1311000 K132

1 K1361 K1411 K1421 K1431 K1441 K1451 K1471 K148

10 K14910 K15010 K151





10 K15610 K15710 K15810 K1591 K161

10 K1691 K1701 K1711 K1721 K1741 K1751 K176

5000 K1771000 K178

1 K181

FOOTNOTES

@ Indicates that the name was added by PHMSA because (1) the name is a synonym for a specific hazardous substance and (2) the name appears in the Hazardous Materials Table as a proper shipping name.

# To provide consistency with EPA regulations, two entries with different CAS numbers are provided. Refer to the EPA Table 302.4--List of Hazardous Substances and Reportable Quantities for an explanation of the two entries.

♣The RQ for these hazardous substances is limited to those pieces of the metal having a diameter smaller than 100 micrometers (0.004 inches).

♠The RQ for asbestos is limited to friable forms only.

Instructors Note: From USEPA Superfund Reportabe Quantity Website: "What Releases Are Excluded From CERCLA Reporting? If a metal is released in solid form at or above its RQ, is it considered a reportable release?The Agency allows a reporting exception for massive forms of certain solid metals (antimony, arsenic, beryllium, cadmium, chromium, copper, lead, nickel, selenium, silver, thallium, and zinc) when the diameter of the released metal equals or exceeds 100 micrometers (0.004 inches) (50 FR 13461, April 4, 1985). The Agency deliberately set the cutoff size 10 times larger than the maximum size considered by EPA to be respirable dust to ensure that the government would be notified of releases containing small, inhalable particles of metals.

APPENDIX 4

MARINE POLLUTANTS

49 CFR 172.101 Appendix B A4- 1 SET Environmental, Inc. Marine Pollutant List Last Revision: March 30, 2017

172.101 APPENDIX B

List of Marine Pollutants

1. See § 171.4 of this subchapter for applicability to marine pollutants. This appendix lists potential

marine pollutants as defined in § 171.8 of this subchapter. 2. Marine pollutants listed in this appendix are not necessarily listed by name in the § 172.101

Table. If a marine pollutant not listed by name or by synonym in the § 172.101 Table meets the definition of any hazard Class 1 through 8, then you must determine the class and division of the material in accordance with § 173.2a of this subchapter. You must also select the most appropriate hazardous material description and proper shipping name. If a marine pollutant not listed by name or by synonym in the § 172.101 Table does not meet the definition of any Class 1 through 8, then you must offer it for transportation under the most appropriate of the following two Class 9 entries: "Environmentally hazardous substances, liquid, n.o.s.," UN3082, or "Environmentally hazardous substances, solid, n.o.s." UN3077.

3. This appendix contains two columns. The first column, entitled ``S.M.P.'' (for severe marine

pollutants), identifies whether a material is a severe marine pollutant. If the letters ``PP'' appear in this column for a material, the material is a severe marine pollutant, otherwise it is not. The second column, entitled ``Marine Pollutant'' , lists the marine pollutants.

4. If a material is not listed in this appendix and meets the criteria for a marine pollutant as provided

in Chapter 2.9 of the IMDG Code, (incorporated by reference; see Sec. 171.7 of this subchapter), the material may be transported as a marine pollutant in accordance with the applicable requirements of this subchapter.

5. If a material or a solution meeting the definition of a marine pollutant in Sec. 171.8 of this

subchapter does not meet the criteria for a marine pollutant as provided in section 2.9.3.3 and 2.9.3.4 of the IMDG Code, (incorporated by reference; see Sec. 171.7 of this subchapter), it may be excepted from the requirements of this subchapter as a marine pollutant if that exception is approved by the Associate Administrator.

The Marine Pollutant additional descriptor and marking requirements do not apply to shipments of non- bulk packagings unless some portion of the transportation will be by vessel. [49 CFR §172.203(l)(4) and §171.4] If the material is shipped in bulk packaging and contains a Marine Pollutant include the technical names of the marine pollutant in the shipping description (§172.203(l)(1)), and add the words "Marine Pollutant" at the end of the shipping description (§172.203(l)(2)). If the bulk packaging is less than 1000 gallons affix the Marine Pollutant mark on two opposing sides (§172.322(b)(1)). If the capacity of the packaging is greater than 1000 gallons affix the Marine Pollutant mark on both sides and both ends (§173.322(b)(2)).


S.M.P. Marine Pollutant

Acetone cyanohydrin, stabilized Acetylene tetrabromide Acetylene tetrachloride Acraldehyde, inhibited Acroleic acid, stabilized Acrolein, inhibited Acrolein, stabilized Acrylic acid, stabilized Acrylic aldehyde, inhibited Alcohol C-12 - C-16 poly(1-6) ethoxylate Alcohol C-6 - C-17 (secondary)poly(3-6) ethoxylate Aldicarb PP Aldrin Alkyl (c12-c14) dimethylamine Alkyl (c7-c9) nitrates Alkybenzenesulphonates, branched and straight chain (excluding C11-C13 straight chain or branched

chain homologues) Allyl alcohol Allyl bromide ortho-Aminoanisole Aminobenzene Aminocarb Ammonia, anhydrous (I) Ammonia solution, relative density less than 0.880 at 15 degrees C in water, with more than 50 percent

ammonia Ammonia solution relative density less than 0.880 at 15 degrees C in water, with more than 35% but not

more than 50% ammonia Ammonia solution, relative density between 0.880 and 0.957 at 15 degrees C in water, with more than 10

percent but not more than 35 percent ammonia, by mass Ammonium dinitro-o-cresolate n-Amylbenzene Aniline Aniline oil PP Azinphos-ethyl PP Azinphos-methyl Barium cyanide Bendiocarb Benomyl Benquinox Benzyl chlorocarbonate Benzyl chloroformate PP Binapacryl N,N-Bis (2-hydroxyethyl) oleamide (LOA) Bleaching powder PP Brodifacoum


S.M.P. Marine Pollutant Bromine cyanide Bromoacetone Bromoallylene Bromobenzene ortho-Bromobenzyl cyanide Bromocyane Bromoform PP Bromophos-ethyl 3-Bromopropene Bromoxynil Butanedione 2-Butenal, stabilized Butyl benzyl phthalate Butylbenzenes N-tert-butyl-N-cyclopropyl-6-methylthio-1,3,5-triazine-2,4-diamine 2,4-Di-tert-butylphenol PP 2, 6-Di-tert-Butylphenol para-tertiary-butyltoluene PP Cadmium compounds Cadmium sulphide Calcium arsenate Calcium arsenate and calcium arsenite, mixtures, solid Calcium cyanide Calcium hypochlorite, dry with more than 39% available chlorine (8.8% available oxygen) Calcium hypochlorite mixture, dry with more than 10% but not more than 39% available chlorine Calcium hypochlorite mixture, dry with more than 39% available chlorine (8.8% available oxygen) Calcium hypochlorite mixture, dry, corrosive with more than 10% but not more than 39% available

chlorine Calcium hypochlorite mixture, dry, corrosive with more than 39% available chlorine (8.8% available

oxygen) Calcium hypochlorite, hydrated with not less than 5.5% but not more than 16% water Calcium hypochlorite, hydrated, corrosive with not less than 5.5% but not more than 16% water Calcium hypochlorite, hydrated mixture with not less than 5.5% but not more than 16% water Calcium hypochlorite, hydrated mixture, corrosive with not less than 5.5% but not more than 16% water PP Camphechlor Carbaryl Carbendazim Carbofuran Carbon tetrabromide Carbon tetrachloride PP Carbophenothion Cartap hydrochloride PP Chlordane Chlorfenvinphos PP Chlorinated paraffins (C-10 - C-13)


S.M.P. Marine Pollutant PP Chlorinated paraffins (C14-C17), with more than 1% shorter chain length Chlorine Chlorine cyanide, inhibited Chlormephos Chloroacetone, stabilized 1-Chloro-2,3-Epoxypropane 2-Chloro-6-nitrotoluene 4-Chloro-2-nitrotoluene Chloro-ortho-nitrotoluene 2-Chloro-5-trifluoromethylnitrobenzene para-Chlorobenzyl chloride, liquid or solid Chlorodinitrobenzenes, liquid or solid 1-Chloroheptane 1-Chlorohexane Chloronitroanilines Chloronitrotoluenes, liquid Chloronitrotoluenes, solid 1-Chlorooctane PP Chlorophenolates, liquid PP Chlorophenolates, solid Chlorophenyltrichlorosilane Chloropicrin alpha-Chloropropylene ortho-Chlorotoluene PP Chlorpyriphos PP Chlorthiophos Cocculus Coconitrile Copper acetoarsenite Copper arsenite PP Copper chloride PP Copper chloride solution PP Copper cyanide PP Copper metal powder PP Copper sulphate, anhydrous, hydrates Coumachlor PP Coumaphos Creosote salts PP Cresyl diphenyl phosphate Crotonaldehyde, stabilized Crotonic aldehyde, stabilized Crotoxyphos Cupric arsenite PP Cupric chloride


S.M.P. Marine Pollutant PP Cupric cyanide PP Cupric sulfate Cupriethylenediamine solution PP Cuprous chloride Cyanide mixtures Cyanide solutions Cyanides, inorganic, n.o.s. Cyanogen bromide Cyanogen chloride, inhibited Cyanogen chloride, stabilized Cyanophos PP 1,5,9-Cyclododecatriene Cycloheptane PP Cyhexatin PP Cymenes (o-;m-;p-) PP Cypermethrin Decyl acrylate PP DDT Decycloxytetrahydrothiophene dioxide DEF Desmedipham Di-allate Di-n-Butyl phthalate PP Dialifos 4,4′-Diaminodiphenylmethane PP Diazinon 1,3-Dibromobenzene PP Dichlofenthion Dichloroanilines 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorobenzene (meta-; para-) 2,2-Dichlorodiethyl ether Dichlorodimethyl ether, symmetrical Di-(2-chloroethyl) ether 1,1-Dichloroethylene, inhibited 1,6-Dichlorohexane 2,4-Dichlorophenol Dichlorophenyltrichlorosilane 1,3-Dichloropropene PP Dichlorvos PP Diclofop-methyl Dicrotophos PP Dieldrin


S.M.P. Marine Pollutant Diisopropylbenzenes Diisopropylnaphthalenes, mixed isomers PP Dimethoate Dimethyl disulphide PP N,N-Dimethyldodecylamine Dimethylhydrazine, symmetrical Dimethylhydrazine, unsymmetrical Dinitro-o-cresol, solid Dinitro-o-cresol, solution Dinitrochlorobenzenes, liquid or solid Dinitrophenol, dry or wetted with less than 15 per cent water, by mass Dinitrophenol solutions Dinitrophenol, wetted with not less than 15 per cent water, by mass Dinitrophenolates alkali metals, dry or wetted with less than 15 per cent water, by mass Dinitrophenolates, wetted with not less than 15 per cent water, by mass Dinitrotoluenes, liquid Dinitrotoluenes, molton Dintrotoluenes, solid Dinobuton Dinoseb Dinoseb acetate Dioxacarb Dioxathion Dipentene Diphacinone Diphenyl PP Diphenylamine chloroarsine PP Diphenylchloroarsine, solid or liquid Disulfoton 1,4-Di-tert-butylbenzene DNOC DNOC (pesticide) Dodecene Dodecyl diphenyl oxide disulphonate PP Dodecyl hydroxypropyl sulfide 1-Dodecylamine PP Dodecylphenol Drazoxolon Edifenphos PP Endosulfan PP Endrin Epibromohydrin Epichlorohydrin PP EPN


S.M.P. Marine Pollutant PP Esfenvalerate PP Ethion Ethoprophos Ethyl fluid Ethyl mercaptan 2-Ethylhexyl nitrate 2-Ethyl-3-propylacrolein Ethyl tetraphosphate Ethyldichloroarsine Ethylene dibromide and methyl bromide mixtures, liquid 2-Ethylhexaldehyde Fenamiphos PP Fenbutatin oxide PP Fenchlorazole-ethyl PP Fenitrothion PP Fenoxapro-ethyl PP Fenoxaprop-P-ethyl PP Fenpropathrin Fensulfothion PP Fenthion PP Fentin acetate PP Fentin hydroxide Ferric arsenate Ferric arsenite Ferrous arsenate PP Fonofos Formetanate PP Furathiocarb (ISO) PP gamma-BHC Gasoline, leaded PP Heptachlor Heptanes Heptenophos n-Heptaldehyde n-Heptylbenzene normal-Heptyl chloride PP Hexachlorobutadiene PP 1,3-Hexachlorobutadiene Hexaethyl tetraphosphate liquid Hexaethyl tetraphosphate, solid Hexane normal-Hexyl chloride n-Hexylbenzene Hydrocyanic acid, anhydrous, stabilized, containing less than 3% water


S.M.P. Marine Pollutant Hydrocyanic acid, anhydrous, stabilized, containing less than 3% water and absorbed in a porous inert

material Hydrocyanic acid, aqueous solutions not more than 20% hydrocyanic acid Hydrogen cyanide solution in alcohol, with not more than 45% hydrogen cyanide Hydrogen cyanide, stabilized with less than 3% water Hydrogen cyanide, stabilized with less than 3% water and absorbed in a porous inert material Hydroxydimethylbenzenes, liquid or solid Hypochlorite solutions Ioxynil Isobenzan Isobutyl butyrate Isobutylbenzene Isodecyl acrylate Isodecyl diphenyl phosphate Isofenphos Isooctane Isooctyl nitrate Isoprene, stabilized Isoprocarb Isotetramethylbenzene PP Isoxathion Lead acetate Lead arsenates Lead arsenites Lead compounds, soluble, n.o.s. Lead cyanide Lead nitrate Lead perchlorate, solid or solution Lead tetraethyl Lead tetramethyl PP Lindane Linuron London Purple Magnesium arsenate Malathion Mancozeb (ISO) Maneb Maneb preparations with not less than 60% maneb Maneb preparation, stabilized against self-heating Maneb stabilized or Maneb preparations, stabilized against self-heating Manganese ethylene-1,2-bis dithiocarbamate Manganese ethylene-1,2-bis-dithiocarbamate, stabilized against self-heating Mecarbam Mephosfolan


S.M.P. Marine Pollutant Mercaptodimethur PP Mercuric acetate PP Mercuric ammonium chloride PP Mercuric arsenate PP Mercuric benzoate PP Mercuric bisulphate PP Mercuric bromide PP Mercuric chloride PP Mercuric cyanide PP Mercuric gluconate Mercuric iodide PP Mercuric nitrate PP Mercuric oleate PP Mercuric oxide PP Mercuric oxycyanide, desensitized PP Mercuric potassium cyanide PP Mercuric Sulphate PP Mercuric thiocyanate PP Mercurol PP Mercurous acetate PP Mercurous bisulphate PP Mercurous bromide PP Mercurous chloride PP Mercurous nitrate PP Mercurous salicylate PP Mercurous sulphate PP Mercury acetates PP Mercury ammonium chloride PP Mercury based pesticide, liquid, flammable, toxic PP Mercury based pesticides, liquid, toxic, flammable PP Mercury based pesticides, liquid, toxic PP Mercury based pesticides, solid, toxic PP Mercury benzoate PP Mercury bichloride PP Mercury bisulphates PP Mercury bromides PP Mercury compounds, liquid, n.o.s. PP Mercury compounds, solid, n.o.s. PP Mercury cyanide PP Mercury gluconate PP Mercury (I) (mercurous) compounds (pesticides) PP Mercury (II) (mercuric) compounds (pesticides) Mercury iodide PP Mercury nucleate


S.M.P. Marine Pollutant PP Mercury oleate PP Mercury oxide PP Mercury oxycyanide, desensitized PP Mercury potassium cyanide PP Mercury potassium iodide PP Mercury salicylate PP Mercury sulfates PP Mercury thiocyanate Mesitylene Metam-sodium Methamidophos Methanethiol Methidathion Methomyl ortho-Methoxyaniline N-Methylaniline Methyl bromide and ethylene dibromide mixtures, liquid Methyl disulphide Methyl mercaptan 2-Methyl-2-phenylpropane 3-Methylacroleine, stabilized Methylchlorobenzenes Methylcyclohexane Methyldinitrobenzenes, liquid Methyldinitrobenzenes, molten Methyldinitrobenzenes, solid Methyldithiomethane 2-Methylheptane Methylnitrophenols 2-Methylpentane 3-Methylpyradine Methyltrithion Methylvinylbenzenes, inhibited PP Mevinphos Mexacarbate Mirex Monocrotophos Motor fuel anti-knock mixtures Motor fuel anti-knock mixtures or compounds Nabam Naled Naphthalene, crude or Naphthalene, refined Napthalene, molten PP Nickel carbonyl


S.M.P. Marine Pollutant PP Nickel cyanide PP Nickel tetracarbonyl 3-Nitro-4-chlorobenzotrifluoride Nitrobenzene Nitrobenzotrifluorides, liquid or solid Nonanes Nonylphenol normal-Octaldehyde Octanes Oleylamine PP Organotin compounds, liquid, n.o.s. PP Organotin compounds (pesticides) PP Organotin compounds, solid, n.o.s. PP Organotin pesticides, liquid, flammable, toxic, n.o.s., flash point less than 23deg C PP Organotin pesticides, liquid, toxic, flammable, n.o.s. PP Organotin pesticides, liquid, toxic, n.o.s. PP Organotin pesticides, solid, toxic, n.o.s. Orthoarsenic acid PP Osmium tetroxide Oxamyl Oxydisulfoton Paraoxon PP Parathion PP Parathion-methyl PP PCBs. Pentachloroethane PP Pentachlorophenol Pentalin n-Pentylbenzene Perchloroethylene Perchloromethylmercaptan Petrol, leaded PP Phenarsazine chloride d-Phenothrin PP Phenthoate Phenylamine 1-Phenylbutane 2-Phenylbutane Phenylcyclohexane PP Phenylmercuric acetate PP Phenylmercuric compounds, n.o.s. PP Phenylmercuric hydroxide PP Phenylmercuric nitrate PP Phorate


S.M.P. Marine Pollutant PP Phosalone Phosmet PP Phosphamidon PP Phosphorus, white, molten PP Phosphorus, white or yellow dry or under water or in solution PP Phosphorus white, or yellow, molten PP Phosphorus, yellow, molten Pindone (and salts of) Pine Oil alpha-Pinene Pirimicarb PP Pirimiphos-ethyl PP Polychlorinated biphenyls PP Polyhalogenated biphenyls, liquid or Terphenyls liquid PP Polyhalogenated biphenyls, solid or Terphenyls, solid PP Potassium cuprocyanide Potassium cyanide, solid Potassium cyanide, solution PP Potassium cyanocuprate (I) PP Potassium cyanomercurate PP Potassium mercuric iodide Promecarb Propachlor Propaphos Propenal, inhibited Propenoic acid, stabilized Propenyl alcohol Propoxur Propylene tetramer Prothoate Prussic acid, anhydrous, stabilized Prussic acid, anhydrous, stabilized, absorbed in a porous inert material PP Pyrazophos Quinalphos PP Quizalofop PP Quizalofop-p-ethyl Rotenone Salithion PP Silafluofen Silver arsenite Silver cyanide Silver orthoarsenite PP Sodium copper cyanide, solid PP Sodium copper cyanide solution


S.M.P. Marine Pollutant PP Sodium cuprocyanide, solid PP Sodium cuprocyanide, solution Sodium cyanide, solid Sodium cyanide, solution Sodium dinitro-o-cresolate, dry or wetted with less than 15 per cent water, by mass Sodium dinitro-ortho-cresolate, wetted with not less than 15 per cent water, by mass Sodium hypochlorite solution PP Sodium pentachlorophenate Strychnine or Strychnine salts Sulfotep PP Sulprophos Tallow nitrile Temephos TEPP PP Terbufos Tetrabromoethane Tetrabromomethane 1,1,2,2-Tetrachloroethane Tetrachloroethylene Tetrachloromethane Tetraethyl dithiopyrophosphate PP Tetraethyl lead, liquid Tetramethrin Tetramethyllead Tetrapropylene Thallium chlorate Thallium compounds, n.o.s. Thallium compounds (pesticides) Thallium nitrate Thallium sulfate Thallous chlorate Thiocarbonyl tetrachloride Toluidines, liquid Toluidines, solid Triaryl phosphates, isopropylated PP Triaryl phosphates, n.o.s. Triazophos Tribromomethane PP Tributyltin compounds Trichlorfon PP 1,2,3—Trichlorobenzene Trichlorobenzenes, liquid Trichlorobutene Trichlorobutylene


S.M.P. Marine Pollutant Trichloromethane sulphuryl chloride Trichloromethyl sulphochloride Trichloronat Tricresyl phosphate (less than 1% ortho-isomer) PP Tricresyl phosphate, not less than 1% ortho-isomer but not more than 3% orthoisomer PP Tricresyl phosphate with more than 3 per cent ortho isomer Triethylbenzene Triisopropylated phenyl phosphates 1,3,5-Trimethylbenzene Trimethylene dichloride 2,2,4-Trimethylpentane PP Triphenylphosphate Triphenyl phosphate/tert-butylated triphenyl phosphates mixtures containing 5% to 10% triphenyl

phosphates PP Triphenyl phosphate/tert-butylated triphenyl phosphates mixtures containing 10% to 48% triphenyl

phosphates PP Triphenyltin compounds Tripropylene Tritolyl phosphate (less than 1% ortho-isomer) PP Tritolyl phosphate (not less than 1% ortho-isomer) Trixylenyl phosphate Turpentine Vinylidene chloride, stabilized Warfarin (and salts of) PP White phosphorus, dry PP White phosphorus, wet White spirit, low (15-20%) aromatic PP Yellow phosphorus, dry PP Yellow phosphorus, wet Zinc bromide Zinc chloride, anhydrous Zinc chloride solution Zinc cyanide

APPENDIX 5

PART 173

SHIPPERS-GENERAL REQUIREMENTS FOR SHIPMENTS AND PACKAGINGS

Subpart Regulatory Site and Topic Page

B Preparation of Hazardous Materials for Transportation (173.21 - 173.40) ................................. A5-1

§173.21 Forbidden materials and packages. ........................................................................................ A5-1 §173.22 Shipper’s responsibility. ......................................................................................................... A5-3 §173.22a Use of packagings authorized under special permits. .............................................................. A5-5 §173.23 Previously authorized packaging. ............................................................................................ A5-5 §173.24 General requirements for packagings and packages. .............................................................. A5-6 §173.24a Additional general requirements for non-bulk packagings and packages. ............................... A5-9 §173.24b Additional general requirements for bulk packagings............................................................. A5-11 §173.25 Authorized packagings and overpacks. ................................................................................. A5-12 §173.26 Quantity limitations. .............................................................................................................. A5-13 §173.27 General requirements for transportation by aircraft. ............................................................. A5-14 §173.28 Reuse, reconditioning and remanufacture of packagings. .................................................... A5-20 §173.29 Empty packagings. ................................................................................................................ A5-23 §173.30 Loading and unloading of transport vehicles. ....................................................................... A5-24 §173.31 Use of tank cars. ................................................................................................................... A5-24 §173.32 Requirements for use of portable tanks. ............................................................................... A5-29 §173.33 Hazardous materials in cargo tank motor vehicles. ............................................................... A5-34 §173.35 Hazardous materials in IBCs. ................................................................................................ A5-37 §173.36 Hazardous Materials in Large Packagings. ........................................................................... A5-39 §173.37 Hazardous Materials in Flexible Bulk Containers ................................................................... A5-40 §173.40 General packaging requirements for toxic materials packaged in cylinders. .......................... A5-41

D Exceptions Other Than Class 1 and Class 7 (173.150 - 173.156) ................................................... A5-43

§173.150 Exceptions for Class 3 (flammable) and combustible liquids. .......................................... A5-43

§173.151 Exceptions for Class 4. ....................................................................................................... A5-46

§173.152 Exceptions for Division 5.1 (oxidizers) and Division 5.2 (organic peroxides). ................. A5-47

§173.153 Exceptions for Division 6.1 (poisonous materials). ........................................................... A5-48

§173.154 Exceptions for Class 8 (corrosive materials). ..................................................................... A5-48

§173.155 Exceptions for Class 9 (miscellaneous hazardous materials). .......................................... A5-49

§173.156 Exceptions for ORM materials ............................................................................................ A5-50

E Non-bulk Packaging Other Than Class 1 and Class 7 (173.158 - 173.229) ................................ A5-52

§173.158 Nitric acid............................................................................................................................. A5-52

§173.159 Batteries, wet. ...................................................................................................................... A5-54

§173.159a Exceptions for non-spillable batteries. ............................................................................... A5-58

§173.160 Bombs, smoke, non-explosive (corrosive). ........................................................................ A5-58

§173.161 Chemical kits and first aid kits. ........................................................................................... A5-59

§173.162 Gallium. ............................................................................................................................... A5-60

§173.163 Hydrogen fluoride. .............................................................................................................. A5-61

§173.164 Mercury (metallic and articles containing mercury). ......................................................... A5-61

§173.165 Polyester resin kits .............................................................................................................. A5-63

§173.166 Safety Devices. .................................................................................................................... A5-64

§173.167 Consumer commodities...................................................................................................... A5-67

§173.168 Oxygen Generators ............................................................................................................. A5-68

§173.170 Black powder for small arms. ............................................................................................ A5-70

§173.171 Smokeless powder for small arms. ................................................................................... A5-70

§173.172 Aircraft hydraulic power unit fuel tank............................................................................... A5-71

§173.173 Paint, paint-related material, adhesives, ink and resins. ................................................... A5-71

§173.174 Refrigerating machines. ...................................................................................................... A5-71

§173.175 Permeation devices ............................................................................................................. A5-71

§173.176 Capacitors ............................................................................................................................ A5-72

§173.181 Pyrophoric materials (liquids). ........................................................................................... A5-73

§173.182 Barium azide–50 percent or more water wet. .................................................................... A5-74

§173.183 Nitrocellulose base film. ..................................................................................................... A5-74

§173.184 Highway or rail fusee. ......................................................................................................... A5-75

§173.185 Lithium batteries and cells. ................................................................................................. A5-75

§173.186 Matches. ............................................................................................................................. A5-85

§173.187 Pyrophoric solids, metals or alloys, n.o.s. ......................................................................... A5-86

§173.188 White or yellow phosphorus .............................................................................................. A5-86

§173.189 Batteries containing sodium or cells containing sodium. ................................................. A5-87

§173.192 Packaging for certain toxic gases in Hazard Zone A. ........................................................ A5-88

§173.194 Gas identification sets. ....................................................................................................... A5-89

§173.195 Hydrogen cyanide, anhydrous, stabilized (hydrocyanic acid, aqueous solution). .......... A5-90

§173.196 Infectious substances. ......................................................................................................... A5-90

§173.197 Regulated medical waste. .................................................................................................. A5-91

§173.198 Nickel carbonyl. ................................................................................................................... A5-94

§173.199 Category B Infectious Substance ....................................................................................... A5-94

§173.201 Non-bulk packagings for liquid hazardous materials in Packing Group I......................... A5-97

§173.202 Non-bulk packagings for liquid hazardous materials in Packing Group II. ...................... A5-98

§173.203 Non-bulk packagings for liquid hazardous materials in Packing Group III. ..................... A5-99

§173.204 Non-bulk, non-specification packagings for certain hazardous materials. .................... A5-100

§173.205 Specification cylinders for liquid hazardous materials. ................................................. A5-100

§173.206 Packaging Requirements for Chlorosilanes ..................................................................... A5-101

§173.211 Non-bulk packagings for solid hazardous materials in Packing Group I. ...................... A5-101

§173.212 Non-bulk packagings for solid hazardous materials in Packing Group II. ..................... A5-102

§173.213 Non-bulk packagings for solid hazardous materials in Packing Group III. .................... A5-103

§173.214 Packagings which require approval by the Associate Administrator. ............................ A5-105

§173.216 Asbestos, blue, brown or white. ....................................................................................... A5-105

§173.217 Carbon dioxide, solid (dry ice). ......................................................................................... A5-105

§173.218 Fish meal or fish scrap. .................................................................................................... A5-106

§173.219 Life-saving appliances. ..................................................................................................... A5-107

§173.220 Internal combustion engines, self-propelled vehicles, mechanical equipment containing

internal Combustion engines, and battery powered vehicles or equipment. ................ A5-108

§173.221 Polymeric beads, expandable and Plastic molding compound. .................................... A5-110

§173.222 Dangerous goods in equipment, machinery or apparatus. ........................................... A5-111

§173.223 Packaging for certain flammable solids ........................................................................... A5-112

§173.224 Packaging and control and emergency temperatures for self-reactive materials. ........ A5-112

§173.225 Packaging requirements and other provisions for organic peroxides ........................... A5-117

§173.226 Materials poisonous by inhalation, Division 6.1, Packing Group I, Hazard Zone A. ...... A5-140

§173.227 Materials poisonous by inhalation. Division 6.1, Packing Group I, Hazard Zone B. ...... A5-142

§173.228 Bromine pentafluoride or bromine trifluoride. ................................................................ A5-143

§173.229 Chloric acid solution or chlorine dioxide hydrate, frozen. ............................................. A5-143

§173.230 Fuel cell cartridges containing flammable liquids ........................................................... A5-143

§173.231 Ammonium nitrate emulsion, suspension or gel ............................................................ A5-147

§173.232 Articles containing hazardous materials, n.o.s. ............................................................... A5-148

F Bulk Packaging Other Than Class 1 and Class 7 (173.240 - 173.249) ................................. A5-150 §173.240 Bulk packaging for certain low hazard solid materials. .................................................. A5-150

§173.241 Bulk packagings for certain low hazard liquid and solid materials. ............................... A5-151

§173.242 Bulk packagings for certain medium hazard liquids and solids...................................... A5-152

§173.243 Bulk packaging for certain high hazard liquids and dual hazard materials which pose a

moderate hazard. .............................................................................................................. A5-154

§173.244 Bulk packaging for certain pyrophoric liquids (Division 4.2), dangerous when wet (Division

4.3) materials, and poisonous liquids with inhalation hazards (Division 6.1). .............. A5-155

§173.245 Bulk packaging for extremely hazardous materials such as poisonous gases (2.3). .... A5-155

§173.247 Bulk packaging for certain elevated temperature materials. .......................................... A5-155

§173.249 Bromine. ........................................................................................................................... A5-158

§173.251 Bulk Packaging for ammonium nitrate emulsion, suspension or gel ............................. A5-159

49 CFR 173 Subpart D A5-1 SET Environmental, Inc. Exceptions: Other Than For Class 1 and 7 Last Revision: May 11, 2020

Chapter I - Pipeline and Hazardous Materials Safety Administration, DOT

Subchapter C—Hazardous Materials Regulations

Part 173—Shippers—General Requirements For Shipments and Packagings

Subpart B—Preparation of Hazardous Materials for Transportation §173.21 Forbidden materials and packages. Unless otherwise provided in this subchapter, the offering for transportation or transportation of the following is forbidden: (a) Materials that are designated “Forbidden” in Column 3 of the § 172.101 Table. (b) Forbidden explosives as defined in § 173.54 of this part. (c) Electrical devices which are likely to create sparks or generate a dangerous quantity of heat, unless

packaged in a manner which precludes such an occurrence. (d) For carriage by aircraft, any package which has a magnetic field of more than 0.00525 gauss

measured at 4.5 m (15 feet) from any surface of the package. (e) A material in the same packaging, freight container, overpack, or transport vehicle with another

material, the mixing of which is likely to cause a dangerous evolution of heat, produce flammable or poisonous gases or vapors, or produce corrosive materials.

(f) A package containing a material which is likely to decompose with a self-accelerated decomposition

temperature (SADT) of 50 °C (122 °F) or less, or polymerize at a temperature of 54 °C (130 °F) or less with an evolution of a dangerous quantity of heat or gas when decomposing or polymerizing, unless the material is stabilized or inhibited in a manner to preclude such evolution. The SADT may be determined by any of the test methods described in Part II of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter).

(1) A package containing a material which is likely to decompose with a self-accelerated

decomposition temperature (SADT) or polymerize with a self-accelerated polymerization temperature (SAPT) of 50 °C (122 °F) or less, with an evolution of a dangerous quantity of heat or gas when decomposing or polymerizing, unless the material is stabilized or inhibited in a manner to preclude such evolution. The SADT and SAPT may be determined by any of the test methods described in Part II of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter). (1) A package meeting the criteria of paragraph (f) of this section may be required to be shipped under controlled temperature conditions. The control temperature and emergency temperature for a package shall be as specified in the table in this paragraph (f)(1) based upon the SADT or SAPT of the material. The control temperature is the temperature above which a package of the material may not be offered for transportation or transported. The emergency temperature is the temperature at which, due to imminent danger, emergency measures must be initiated.

Section 173.21 Table: Method of Determining Control and Emergency Temperature.

SADT/SAPT1 Control temperatures Emergency temperature SADT/SAPT ≤ 20° C (68° F) 20° C (36° F) below SADT/SAPT 10° C (18°F) below SADT/SAPT

20°C (68°F) < SADT/SAPT ≤ 35°C (95°F) 15°C (27°F) below SADT/SAPT 10°C (18°F) below SADT/SAPT

35°C (95°F) < SADT/SAPT ≤ 50°C (122°F) 10°C (18°F) below SADT/SAPT 5°C (9°F) below SADT/SAPT

50°C (122°F) <SADT/SAPT (2) (2)

1 Self-accelerating decomposition temperature.


2 Temperature control not required.

(2) For self-reactive materials listed in § 173.224(b) Table control and emergency temperatures, where required are shown in Columns 5 and 6, respectively. For organic peroxides listed in The Organic Peroxides Table in § 173.225 control and emergency temperatures, where required, are shown in Columns 7a and 7b, respectively.

(3) Refrigeration may be used as a means of stabilization only when approved by the Associate Administrator. Approvals issued by the Bureau of Explosives are no longer valid (see Sec. 171.19 of this subchapter). Methods of stabilization approved by the Associate Administrator are as follows:

(i) For highway transportation:

(A) A material meeting the criteria of this paragraph (f) may be transported only in a transport

vehicle, freight container, or motor vehicle equipped with a mechanical refrigeration unit, or loaded with a consumable refrigerant, capable of maintaining the inside temperature of the hazardous material at or below the control temperature required for the material during transportation.

(B) Each package containing a material meeting the criteria of this paragraph (f) must be

loaded and maintained at or below the control temperature required for the material. The temperature of the material must be determined by appropriate means and entered on a written record at the time the packaging is loaded.

(C) The vehicle operator shall monitor the inside temperature of the transport vehicle, freight

container, or motor vehicle and enter that temperature on a written record at the time the package is loaded and thereafter at intervals not exceeding two hours. Alternatively, a transport vehicle, freight container, or motor vehicle may be equipped with a visible or audible warning device that activates when the inside temperature of the transport vehicle, freight container, or motor vehicle exceeds the control temperature required for the material. The warning device must be readily visible or audible, as appropriate, from the vehicle operator’s seat in the vehicle.

(D) The carrier shall advise the vehicle operator of the emergency temperature for the

material, and provide the vehicle operator with written procedures that must be followed to assure maintenance of the control temperature inside the transport vehicle, freight container, or motor vehicle. The written procedures must include instructions for the vehicle operator on actions to take if the inside temperature exceeds the control temperature and approaches or reaches the emergency temperature for the material. In addition, the written temperature-control procedures must identify enroute points where the consumable refrigerant may be procured, or where repairs to, or replacement of, the mechanical refrigeration unit may be accomplished.

(E) The vehicle operator shall maintain the written temperature-control procedures, and the

written record of temperature measurements specified in paragraph (f)(3)(i)(C) of this section, if applicable, in the same manner as specified in § 177.817 of this subchapter for shipping papers.

(F) If the control temperature is maintained by use of a consumable refrigerant (e.g., dry ice

or liquid nitrogen), the quantity of consumable refrigerant must be sufficient to maintain the control temperature for twice the average transit time under normal conditions of transportation.

(G) A material that has a control temperature of 40 °C (104 °F) or higher may be transported

by common carrier. A material that has a control temperature below 40 °C (104 °F) must be transported by a private or contract carrier.

(ii) For transportation by vessel, shipments are authorized in accordance with the control

temperature requirements in 7.3.7 of the IMDG Code (IBR, see § 171.7 of this subchapter).


(g) Packages which give off a flammable gas or vapor, released from a material not otherwise subject to

this subchapter, likely to create a flammable mixture with air in a transport vehicle. (h) Packages containing materials (other than those classed as explosive) which will detonate in a fire.

(1) For purposes of this paragraph, “detonate” means an explosion in which the shock wave travels through the material at a speed greater than the speed of sound.

(2) When tests are required to evaluate the performance of a package under the provisions of this

paragraph, the testing must be done or approved by one of the agencies specified in § 173.56. (i) Except for a package containing a lighter design sample that meets the requirements of

§ 173.308(b)(2), a package containing a lighter (see § 171.8 of this subchapter) containing a Division 2.1 material, of a design that has not been examined and successfully tested by an authorized person under the criteria specified in § 173.308(a)(4)or, a lighter design containing a Class 3 material, that has not been approved by the Associate Administrator.

(j) An organic peroxide of the “ketone peroxide” category which contains more than 9 percent available

oxygen as calculated using the equation in § 173.128(a)(4)(ii). The category, ketone peroxide, includes, but is not limited to:

Acetyl acetone peroxide Cyclohexanone peroxide(s) Diacetone alcohol peroxides Methylcyclohexanone peroxide(s) Methyl ethyl ketone peroxide(s) Methyl isobutyl ketone peroxide(s)

(k) Notwithstanding any other provision of this subchapter, including subpart C of part 171 and

175.10(a)(2) of this subchapter, an oxygen generator (chemical) as cargo on a passenger-carrying aircraft. This prohibition does not apply to an oxygen generator for medical or personal use of a passenger that meets the requirements of § 175.10(a)(7) of this subchapter.

[Amdt. 173-224, 55 FR 52609, Dec. 21, 1990, as amended at 56 FR 66265, Dec. 20, 1991; Amdt. 173-234, 58 FR 51532, Oct. 1, 1993; Amdt. 173-241, 59 FR 67490, Dec. 29, 1994; Amdt. 173-254, 61 FR 26419, May 24, 1996; Amdt. 173-253, 61 FR 27174, May 30, 1996; 62 FR 24719, May 6, 1997; 66 FR 8647, Feb. 1, 2001; 66 FR 45379, 45381, Aug. 28, 2001; 67 FR 61013, Sept. 27, 2002; 68 FR 45032, July 31, 2003; 68 FR 75742, Dec. 31, 2003; 71 FR 3427, Jan. 23, 2006; 72 FR 25176, May 3, 2007] §173.22 Shipper’s responsibility. (a) Except as otherwise provided in this part, a person may offer a hazardous material for transportation

in a packaging or container required by this part only in accordance with the following:

(1) The person shall class and describe the hazardous material in accordance with parts 172 and 173 of this subchapter, and

(2) The person shall determine that the packaging or container is an authorized packaging, including

part 173 requirements, and that it has been manufactured, assembled, and marked in accordance with:

(i) Section 173.7(a) and parts 173, 178, or 179 of this subchapter; (ii) A specification of the Department in effect at the date of manufacture of the packaging or

container; (iii) National or international regulations based on the UN Recommendations (IBR, see § 171.7 of

this subchapter), as authorized in § 173.24(d)(2);


(iv) An approval issued under this subchapter; or (v) An exemption or special permit issued under subchapter A of this chapter.

(3) In making the determination under paragraph (a)(2) of this section, the person may accept:

(i) Except for the marking on the bottom of a metal or plastic drum with a capacity over 100 L

which has been reconditioned, remanufactured or otherwise converted, the manufacturer's certification, specification, approval, or exemption or special permit marking (see §§ 178.2 and 179.1 of this subchapter); or

(ii) With respect to cargo tanks provided by a carrier, the manufacturer's identification plate or a

written certification of specification or exemption or special permit provided by the carrier.

(4) (i) For a DOT Specification or UN standard packaging subject to the requirements of part 178 of

this subchapter, a person must perform all functions necessary to bring the package into compliance with parts 173 and 178 of this subchapter, as identified by the packaging manufacturer or subsequent distributor (for example, applying closures consistent with the manufacturer's closure instructions) in accordance with §178.2 of this subchapter.

(ii) For other than a bulk package or a cylinder, a person must retain a copy of the

manufacturer's notification, including closure instructions (see §178.2(c) of this subchapter). For a bulk package or a cylinder, a person must retain a copy of the manufacturer's notification, including closure instructions (see §178.2(c) of this subchapter), unless permanently embossed or printed on the package. A copy of the manufacturer's notification, including closure instructions (see §178.2(c) of this subchapter), unless permanently embossed or printed on the package when applicable, must be made available for inspection by a representative of the Department upon request for at least 90 days once the package is offered to the initial carrier for transportation in commerce. Subsequent offerors of a filled and otherwise properly prepared unaltered package are not required to maintain manufacturer notification (including closure instructions).

(iii) When applicable, a person must retain a copy of any supporting documentation used to

determine an equivalent level of performance under the selective testing variation in §178.601(g)(1) of this subchapter. Such documentation is to be retained by the person certifying compliance with §178.601(g)(1), as prescribed in §178.601(l), and retained as prescribed in paragraph (a)(4)(ii) of this section.

(b) No person may offer a motor carrier any hazardous material specified in 49 CFR 385.403 unless that

motor carrier holds a safety permit issued by the Federal Motor carrier Safety Administration. (c) Prior to each shipment of fissile radioactive materials, and Type B or highway route controlled

quantity packages of radioactive materials (see § 173.403), the shipper shall notify the consignee of the dates of shipment and expected arrival. The shipper shall also notify each consignee of any special loading/unloading instructions prior to his first shipment. For any shipment of irradiated reactor fuel, the shipper shall provide physical protection in compliance with a plan established under:

(1) Requirements prescribed by the U.S. Nuclear Regulatory Commission, or (2) Equivalent requirements approved by the Associate Administrator.

[Amdt. 173-100, 42 FR 2689, Jan. 13, 1977, and Amdt. 173-143, 46 FR 5316, Jan. 19, 1981, as amended by Amdt. 173-161, 48 FR 2655, Jan. 20, 1983; Amdt. 173-162, 48 FR 10226, Mar. 10, 1983; Amdt. 173-161, 48 FR 17094, Apr. 21, 1983; 53 FR 16992, May 12, 1988; Amdt. 173-212, 54 FR 25005, June 12, 1989; 55 FR 37048, Sept. 7, 1990; Amdt. 173-224, 55 FR 52610, Dec. 21, 1990; 56 FR 66265, Dec. 20, 1991; 57 FR 45460, Oct. 1, 1992; Amdt. 173-233, 58 FR 33305, June 16, 1993; Amdt. 173-234, 58 FR 51532, Oct. 1, 1993; Amdt. 172-241, 59 FR 67491, Dec. 29, 1994; 66 FR 45379, 45380, 45381, Aug. 28, 2001; 68 FR 75742, Dec. 31, 2003; 70 FR 56098, Sept. 23, 2005;


70 FR 73165, Dec. 9, 2005; 72 FR 55692, Oct. 1, 2007] §173.22a Use of packagings authorized under special permits. (a) Except as provided in paragraph (b) of this section, no person may offer a hazardous material for

transportation in a packaging the use of which is dependent upon an exemption or special permit issued under subpart B of part 107 of this title, unless that person is the holder of or a party to the exemption or special permit.

(b) If an exemption or special permit authorizes the use of a packaging for the transportation of a

hazardous material by any person or class of persons other than or in addition to the holder of the exemption or special permit, that person or a member of that class of persons may use the packaging for the purposes authorized in the exemption or special permit subject to the terms specified therein. Copies of exemptions and special permits may be obtained by accessing the Hazardous Materials Safety Web site at http://hazmat.dot.gov/specialpermits-index.htm or by writing to the Associate Administrator for Hazardous Materials Safety, U.S. Department of Transportation, East Building, 1200 New Jersey Avenue, SE., Washington, DC 20590-0001, Attention: Records Center.

(c) When an exemption or special permit issued to a person who offers a hazardous material contains

requirements that apply to a carrier of the hazardous material, the offeror shall furnish a copy of the current exemption or special permit to the carrier before or at the time a shipment is tendered. [Amdt. 173-93, 41 FR 3478, Jan. 23, 1976, as amended by Amdt. 173-121, 43 FR 48643, Oct. 19, 1978; Amdt. 173-223, 55 FR 39981, Oct. 1, 1990; Amdt. 173-224, 56 FR 66279, Dec. 20, 1991; Amdt. 173-233, 58 FR 33305, June 16, 1993; Amdt. 173.249, 61 FR 21102, May 9, 1996; Amdt.173-249, 61 FR 51242, Oct. 1, 1996; 66 FR 45381, Aug. 28, 2001; 70 FR 3309, Jan. 24, 2005; 70 FR 73165, Dec. 9, 2005; 72 FR 55692, Oct. 1, 2007]

§173.23 Previously authorized packaging. (a) When the regulations specify a packaging with a specification marking prefix of “DOT,” a packaging

marked prior to January 1, 1970, with the prefix of “ICC” may be used in its place if the packaging otherwise conforms to applicable specification requirements.

(b) [Reserved] (c) After July 2, 1982, a seamless aluminum cylinder manufactured in conformance with and for use

under DOT special permit (SP) or exemption (E) 6498, 7042, 8107, 8364 or 8422 may be continued in use if marked before or at the time of the next retest with either the specification identification “3AL” immediately above the special permit or exemption number, or the DOT mark (e.g., DOT 3AL 1800) in proximity to the special permit or exemption marking.

(d) Cylinders (spheres) manufactured and marked under DOT special permit (SP) or exemption (E) 6616

prior to January 1, 1983, may be continued in use if marked before or at the time of the next retest with the specification identification “4BA” near the special permit or exemption marking.

(e) After October 1, 1984, cylinders manufactured for use under special permit (SP) or exemption (E)

6668 or 8404 may be continued in use, and must be marked “DOT–4LXXXYY” (XXX to be replaced by the service pressure, YY to be replaced by the letters “AL” , if applicable) in compliance with Specification 4L (§ 178.57 of this subchapter) on or before January 1, 1986. The “DOT–4LXXXYY” must appear in proximity to other required special permit or exemption markings.

(f) An MC 331 cargo tank motor vehicle must conform to structural integrity requirements in § 178.337-3

or to corresponding requirements in effect at the time of manufacture. (g) A non-bulk packaging manufactured, tested, marked, and certified on or before September 30, 1996,

in accordance with the applicable provisions of subparts L and M of part 178 of this subchapter in effect on September 30, 1995, may be used as authorized by this subchapter if the packaging conforms to all requirements applicable at the time of manufacture. In addition, such a packaging may be reused as authorized by § 173.28 without a nominal thickness marking, if it conforms to the


minimum thickness criteria prescribed in § 173.28(b)(4). (h) An exemption packaging or shipping paper that is permanently marked “DOT-E” prior to October 1,

2007, may continue in use as long as the exemption or special permit remains valid, unless otherwise specified in the exemption or special permit.

[Amdt. 173-3, 33 FR 14921, Oct. 4, 1968; 70 FR 73165, Dec. 9, 2005] §173.24 General requirements for packagings and packages. (a) Applicability. Except as otherwise provided in this subchapter, the provisions of this section apply to–

(1) Bulk and non-bulk packagings; (2) New packagings and packagings which are reused; and (3) Specification and non-specification packagings.

(b) Each package used for the shipment of hazardous materials under this subchapter shall be designed, constructed, maintained, filled, its contents so limited, and closed, so that under conditions normally incident to transportation—

(1) Except as otherwise provided in this subchapter, there will be no identifiable (without the use of

instruments) release of hazardous materials to the environment; (2) The effectiveness of the package will not be substantially reduced; for example, impact

resistance, strength, packaging compatibility, etc. must be maintained for the minimum and maximum temperatures, changes in humidity and pressure, and shocks, loadings and vibrations, normally encountered during transportation;

(3) There will be no mixture of gases or vapors in the package which could, through any credible

spontaneous increase of heat or pressure, significantly reduce the effectiveness of the packaging; (4) There will be no hazardous material residue adhering to the outside of the package during

transport. (c) Authorized packagings.

(1) A packaging is authorized for a hazardous material only if—

(i) The packaging is prescribed or permitted for the hazardous material in a packaging section specified for that material in Column 8 of the §172.101 table and conforms to applicable requirements in the special provisions of Column 7 of the §172.101 table and, for specification packagings (but not including UN standard packagings manufactured outside the United States), the specification requirements in parts 178 and 179 of this subchapter; or

(ii) The packaging is permitted under, and conforms to, provisions contained in subparts B or C of part 171 of this subchapter or §§173.3, 173.4, 173.4a, 173.4b, 173.5, 173.5a, 173.6, 173.7, 173.8, 173.27, or §176.11 of this subchapter.

(2) The use of supplementary packagings within an outer packaging (e.g., an intermediate packaging

or a receptacle inside a required inner packaging) additional to what is required by this subchapter is authorized provided all applicable requirements of this subchapter are met and, when necessary, suitable cushioning is used to prevent movement within the packaging.

(d) Specification packagings and UN standard packagings manufactured outside the U.S.

(1) Specification packagings. A specification packaging, including a UN standard packaging manufactured in the United States, must conform in all details to the applicable specification or standard in part 178 or part 179 of this subchapter.


(2) UN standard packagings manufactured outside the United States. A UN standard packaging

manufactured outside the United States, in accordance with national or international regulations based on the UN Recommendations (IBR, see § 171.7 of this subchapter), may be imported and used and is considered to be an authorized packaging under the provisions of paragraph (c)(1) of this section, subject to the following conditions and limitations:

(i) The packaging fully conforms to applicable provisions in the UN Recommendations and the

requirements of this subpart, including reuse provisions; (ii) The packaging is capable of passing the prescribed tests in part 178 of this subchapter

applicable to that standard; and (iii) The competent authority of the country of manufacture provides reciprocal treatment for UN

standard packagings manufactured in the U.S. (e) Compatibility.

(1) Even though certain packagings are specified in this part, it is, nevertheless, the responsibility of the person offering a hazardous material for transportation to ensure that such packagings are compatible with their lading. This particularly applies to corrosivity, permeability, softening, premature aging and embrittlement.

(2) Packaging materials and contents must be such that there will be no significant chemical or

galvanic reaction between the materials and contents of the package. (3) Plastic packagings and receptacles.

(i) Plastic used in packagings and receptacles must be of a type compatible with the lading and may not be permeable to an extent that a hazardous condition is likely to occur during transportation, handling or refilling.

(ii) Each plastic packaging or receptacle which is used for liquid hazardous materials must be

capable of withstanding without failure the procedure specified in appendix B of this part (“Procedure for Testing Chemical Compatibility and Rate of Permeation in Plastic Packagings and Receptacles” ). The procedure specified in appendix B of this part must be performed on each plastic packaging or receptacle used for Packing Group I materials. The maximum rate of permeation of hazardous lading through or into the plastic packaging or receptacles may not exceed 0.5 percent for materials meeting the definition of a Division 6.1 material according to § 173.132 and 2.0 percent for other hazardous materials, when subjected to a temperature no lower than–

(A) 18 °C (64 °F) for 180 days in accordance with Test Method 1 in appendix B of this part; (B) 50 °C (122 °F) for 28 days in accordance with Test Method 2 in appendix B of this part; or (C) 60 °C (140 °F) for 14 days in accordance with Test Method 3 in appendix B of this part.

(iii) Alternative procedures or rates of permeation are permitted if they yield a level of safety

equivalent to or greater than that provided by paragraph (e)(3)(ii) of this section and are specifically approved by the Associate Administrator.

(4) Mixed contents. Hazardous materials may not be packed or mixed together in the same outer

packaging with other hazardous or nonhazardous materials if such materials are capable of reacting dangerously with each other and causing–

(i) Combustion or dangerous evolution of heat; (ii) Evolution of flammable, poisonous, or asphyxiant gases; or


(iii) Formation of unstable or corrosive materials.

(5) Packagings used for solids, which may become liquid at temperatures likely to be encountered

during transportation, must be capable of containing the hazardous material in the liquid state. (f) Closures.

(1) Closures on packagings shall be so designed and closed that under conditions (including the effects of temperature, pressure and vibration) normally incident to transportation—

(i) Except as provided in paragraph (g) of this section, there is no identifiable release of

hazardous materials to the environment from the opening to which the closure is applied; and (ii) The closure is leakproof and secured against loosening. For air transport, stoppers, corks or

other such friction closures must be held in place by positive means.

(2) Except as otherwise provided in this subchapter, a closure (including gaskets or other closure components, if any) used on a specification packaging must conform to all applicable requirements of the specification and must be closed in accordance with information, as applicable, provided by the manufacturer's notification required by § 178.2 of this subchapter.

(g) Venting. Venting of packagings, to reduce internal pressure which may develop by the evolution of

gas from the contents, is permitted only when—

(1) Transportation by aircraft is not involved; (2) Except as otherwise provided in this subchapter, the evolved gases are not poisonous, likely to

create a flammable mixture with air or be an asphyxiant under normal conditions of transportation;

(3) The packaging is designed so as to preclude an unintentional release of hazardous materials

from the receptacle; (4) For bulk packagings, other than IBCs, venting is authorized for the specific hazardous material by

a special provision in the § 172.101 table or by the applicable bulk packaging specification in part 178 of this subchapter; and

(5) Intermediate bulk packagings (IBCs) may be vented when required to reduce internal pressure

that may develop by the evolution of gas subject to the requirements of paragraphs (g)(1) through (g)(3) of this section. The IBC must be of a type that has successfully passed (with the vent in place) the applicable design qualification tests with no release of hazardous material.

(h) Outage and filling limits

(1) General. When filling packagings and receptacles for liquids, sufficient ullage (outage) must be left to ensure that neither leakage nor permanent distortion of the packaging or receptacle will occur as a result of an expansion of the liquid caused by temperatures likely to be encountered during transportation. Requirements for outage and filling limits for non-bulk and bulk packagings are specified in §§ 173.24a(d) and 173.24b(a), respectively.

(2) Compressed gases and cryogenic liquids. Filling limits for compressed gases and cryogenic

liquids are specified in §§ 173.301 through 173.306 for cylinders and §§ 173.314 through 173.319 for bulk packagings.

(i) Air transportation. Except as provided in subpart C of part 171 of this subchapter, packages prepared

under § 173.167 of this part, or packages prepared under Packing Instruction Y963 of the ICAO Technical Instructions, packages offered or intended for transportation by aircraft must conform to the


general requirements for transportation by aircraft in § 173.27. §173.24a Additional general requirements for non-bulk packagings and packages. (a) Packaging design. Except as provided in § 172.312 of this subchapter:

(1) Inner packaging closures. A combination packaging containing liquid hazardous materials must be packed so that closures on inner packagings are upright.

(2) Friction. The nature and thickness of the outer packaging must be such that friction during

transportation is not likely to generate an amount of heat sufficient to alter dangerously the chemical stability of the contents.

(3) Securing and cushioning. Inner packagings of combination packagings must be so packed,

secured and cushioned to prevent their breakage or leakage and to control their shifting within the outer packaging under conditions normally incident to transportation. Cushioning material must not be capable of reacting dangerously with the contents of the inner packagings or having its protective properties significantly weakened in the event of leakage.

(4) Metallic devices. Nails, staples and other metallic devices shall not protrude into the interior of the

outer packaging in such a manner as to be likely to damage inner packagings or receptacles. (5) Vibration. Each non-bulk package must be capable of withstanding, without rupture or leakage,

the vibration test procedure specified in § 178.608 of this subchapter. (b) Non-bulk packaging filling limits.

(1) A single or composite non-bulk packaging may be filled with a liquid hazardous material only when the specific gravity of the material does not exceed that marked on the packaging, or a specific gravity of 1.2 if not marked, except as follows:

(i) A Packing Group I packaging may be used for a Packing Group II material with a specific

gravity not exceeding the greater of 1.8, or 1.5 times the specific gravity marked on the packaging, provided all the performance criteria can still be met with the higher specific gravity material;

(ii) A Packing Group I packaging may be used for a Packing Group III material with a specific

gravity not exceeding the greater of 2.7, or 2.25 times the specific gravity marked on the packaging, provided all the performance criteria can still be met with the higher specific gravity material; and

(iii) A Packing Group II packaging may be used for a Packing Group III material with a specific

gravity not exceeding the greater of 1.8, or 1.5 times the specific gravity marked on the packaging, provided all the performance criteria can still be met with the higher specific gravity material.

(2) Except as otherwise provided in this section, a non-bulk packaging may not be filled with a

hazardous material to a gross mass greater than the maximum gross mass marked on the packaging.

(3) A single or composite non-bulk packaging which is tested and marked for liquid hazardous

materials may be filled with a solid hazardous material to a gross mass, in kilograms, not exceeding the rated capacity of the packaging in liters, multiplied by the specific gravity marked on the packaging, or 1.2 if not marked. In addition:

(i) A single or composite non-bulk packaging which is tested and marked for Packing Group I

liquid hazardous materials may be filled with a solid Packing Group II hazardous material to a gross mass, in kilograms, not exceeding the rated capacity of the packaging in liters,


multiplied by 1.5, multiplied by the specific gravity marked on the packaging, or 1.2 if not marked.

(ii) A single or composite non-bulk packaging which is tested and marked for Packing Group I

liquid hazardous materials may be filled with a solid Packing Group III hazardous material to a gross mass, in kilograms, not exceeding the rated capacity of the packaging in liters, multiplied by 2.25, multiplied by the specific gravity marked on the packaging, or 1.2 if not marked.

(iii) A single or composite non-bulk packaging which is tested and marked for Packing Group II

liquid hazardous materials may be filled with a solid Packing Group III hazardous material to a gross mass, in kilograms, not exceeding the rated capacity of the packaging in liters, multiplied by 1.5, multiplied by the specific gravity marked on the packaging, or 1.2 if not marked.

(4) Packagings tested as prescribed in § 178.605 of this subchapter and marked with the hydrostatic

test pressure as prescribed in § 178.503(a)(5) of this subchapter may be used for liquids only when the vapor pressure of the liquid conforms to one of the following:

(i) The vapor pressure must be such that the total pressure in the packaging (i.e., the vapor

pressure of the liquid plus the partial pressure of air or other inert gases, less 100 kPa (15 psia)) at 55 °C (131 °F), determined on the basis of a maximum degree of filling in accordance with paragraph (d) of this section and a filling temperature of 15 °C (59 °F)), will not exceed two-thirds of the marked test pressure;

(ii) The vapor pressure at 50 °C (122 °F) must be less than four-sevenths of the sum of the

marked test pressure plus 100 kPa (15 psia); or (iii) The vapor pressure at 55 °C (131 °F) must be less than two-thirds of the sum of the marked

test pressure plus 100 kPa (15 psia).

(5) No hazardous material may remain on the outside of a package after filling. (c) Mixed contents.

(1) An outer non-bulk packaging may contain more than one hazardous material only when–

(i) The inner and outer packagings used for each hazardous material conform to the relevant packaging sections of this part applicable to that hazardous material;

(ii) The package as prepared for shipment meets the performance tests prescribed in part 178 of

this subchapter for the packing group indicating the highest order of hazard for the hazardous materials contained in the package;

(iii) Corrosive materials (except ORM-D) in bottles are further packed in securely closed inner

receptacles before packing in outer packagings; and (iv) For transportation by aircraft, the total net quantity does not exceed the lowest permitted

maximum net quantity per package as shown in Column (9a) or (9b), as appropriate, of the § 172.101 Table. The permitted maximum net quantity must be calculated in kilograms if a package contains both a liquid and a solid. These requirements do not apply to limited quantity hazardous materials packaged in accordance with § 173.27(f)(2) of this part.

(2) A packaging containing inner packagings of Division 6.2 materials may not contain other

hazardous materials except-

(i) Refrigerants, such as dry ice or liquid nitrogen, as authorized under the HMR; (ii) Anticoagulants used to stabilize blood or plasma; or


(iii) Small quantities of Class 3, Class 8, Class 9, or other materials in Packing Groups II or III

used to stabilize or prevent degradation of the sample, provided the quantity of such materials does not exceed 30 mL (1 ounce) or 30 g (1 ounce) in each inner packaging. The maximum quantity in an outer package, including a hazardous material used to preserve or stabilize a sample, may not exceed 4 L (1 gallon) or 4 kg (8.8 pounds). Such preservatives are not subject to the requirements of this subchapter.

(d) Liquids must not completely fill a receptacle at a temperature of 55 °C (131 °F) or less. [Amdt. 173-224, 55 FR 52611, Dec. 21, 1990, as amended at 56 FR 66265, Dec. 20, 1991; 57 FR 45460, Oct. 1, 1992; 58 FR 51532, Oct. 1, 1993; Amdt. 173-255, 61 FR 50624, Sept. 26, 1996; 66 FR 45380, Aug. 28, 2001; 68 FR 61941, Oct. 30, 2003; 71 FR 32258, June 2, 2006] §173.24b Additional general requirements for bulk packagings. (a) Outage and filling limits.

(1) Except as otherwise provided in this subchapter, liquids and liquefied gases must be so loaded that the outage is at least five percent for materials poisonous by inhalation, or at least one percent for all other materials, of the total capacity of a cargo tank, portable tank, tank car (including dome capacity), multi-unit tank car tank, or any compartment thereof, at the following reference temperatures–

(i) 46 °C (115 °F) for a noninsulated tank; (ii) 43 °C (110 °F) for a tank car having a thermal protection system, incorporating a metal jacket

that provides an overall thermal conductance at 15.5 °C (60 °F) of no more than 10.22 kilojoules per hour per square meter per degree Celsius (0.5 Btu per hour/per square foot/per degree F) temperature differential; or

(iii) 41 °C (105 °F) for an insulated tank.

(2) Hazardous materials may not be loaded into the dome of a tank car. If the dome of the tank car

does not provide sufficient outage, vacant space must be left in the shell to provide the required outage.

(b) Equivalent steel. For the purposes of this section, the reference stainless steel is stainless steel with

a guaranteed minimum tensile strength of 51.7 deka newtons per square millimeter (75,000 psi) and a guaranteed elongation of 40 percent or greater. Where the regulations permit steel other than stainless steel to be used in place of a specified stainless steel (for example, as in § 172.102 of this subchapter, special provision B30), the minimum thickness for the steel must be obtained from one of the following formulas, as appropriate:

Formula for metric units: e1 = (12.74e0)/(Rm1 A1)1/3 Formula for non-metric units: e1 = (144.2e0)/(Rm1 A1)1/3 where: e0 = Required thickness of the reference stainless steel in millimeters or inches respectively; e1 = Equivalent thickness of the steel used in millimeters or inches respectively; Rm1 = Specified minimum tensile strength of the steel used in deka-newtons per square

millimeter or pounds per square inch respectively; and A1 = Specified minimum percentage elongation of the steel used multiplied by 100 (for example,

20 percent times 100 equals 20). Elongation values used must be determined from a 50 mm or 2 inch test specimen.

(c) Air pressure in excess of ambient atmospheric pressure may not be used to load or unload any lading

which may create an air-enriched mixture within the flammability range of the lading in the vapor


space of the tank. (d) A bulk packaging may not be loaded with a hazardous material that:

(1) Is at a temperature outside of the packaging’s design temperature range; or (2) Except as otherwise provided in this subchapter, exceeds the maximum weight of lading marked

on the specification plate. (e) Stacking of IBCs and Large Packagings. (1) IBCs and Large Packagings not designed and tested to

be stacked. No packages or freight (hazardous or otherwise) may be stacked upon an IBC or a Large Packaging that was not designed and tested to be stacked upon. (2) IBCs and Large Packagings designed and tested to be stacked. The superimposed weight placed upon an IBC or a Large Packaging designed to be stacked may not exceed the maximum permissible stacking test mass marked on the packaging.

(f) UN portable tanks.

(1) A UN portable tank manufactured in the United States must conform in all details to the applicable requirements in parts 172, 173, 178 and 180 of this subchapter.

(2) UN portable tanks manufactured outside the United States. A UN portable tank manufactured

outside the United States, in accordance with national or international regulations based on the UN Recommendations (IBR, see § 171.7 of this subchapter), which is an authorized packaging under § 173.24 of this subchapter, may be filled, offered and transported in the United States, if the § 172.101 Table of this subchapter authorizes the hazardous material for transportation in the UN portable tank and it conforms to the applicable T codes, and tank provision codes, or other special provisions assigned to the hazardous material in Column (7) of the Table. In addition, the portable tank must—

(i) Conform to applicable provisions in the UN Recommendations (IBR, see § 171.7 of this

subchapter) and the requirements of this subpart; (ii) Be capable of passing the prescribed tests and inspections in part 180 of this subchapter

applicable to the UN portable tank specification; (iii) Be designed and manufactured according to the ASME Code (IBR, see § 171.7 of this

subchapter) or a pressure vessel design code approved by the Associate Administrator; (iv) Be approved by the Associate Administrator when the portable tank is designed and

constructed under the provisions of an alternative arrangement (see § 178.274(a)(2) of this subchapter); and

(v) The competent authority of the country of manufacture must provide reciprocal treatment for

UN portable tanks manufactured in the United States. [Amdt. 173-224, 55 FR 52612, Dec. 21, 1990, as amended at 56 FR 66266, Dec. 20, 1991; Amdt.

173-234, 58 FR 51532, Oct. 1, 1993; Amdt. 173-243, 60 FR 40038, Aug. 4, 1995; Amdt. 173-252, 61 FR 28676, June 5, 1996; Amdt. 173-255, 61 FR 50624, Sept. 26, 1996; 66 FR 33426, June 21, 2001; 67 FR 15743, April 3, 2002; 68 FR 75742, Dec. 31, 2003]

§173.25 Authorized packagings and overpacks. (a) Authorized packages containing hazardous materials may be offered for transportation in an

overpack as defined in § 171.8 of this subchapter, if all of the following conditions are met:

(1) The package meets the requirements of §§ 173.21 and 173.24 of this subchapter. (2) The overpack is marked with the proper shipping name and identification number, when


applicable, and is labeled as required by this subchapter for each hazardous material contained therein, unless marking and labels representative of each hazardous material in the overpack are visible.

(3) Each package subject to the orientation marking requirements of § 172.312 of this subchapter is

packed in the overpack with its filling holes up and the overpack is marked with package orientation marking arrows on two opposite vertical sides of the overpack with the arrows pointing in the correct direction of orientation.

(4) The overpack is marked with the word “OVERPACK” when specification packagings are required,

or for Class 7 (radioactive) material when a Type A, Type B(U), Type B(M) or industrial package is required. The “OVERPACK” marking is not required when the required markings representative of each package type contained in the overpack are visible from outside of the overpack. The lettering on the “OVERPACK” marking must be at least 12 mm (0.5 inches) high.Show citation box

(i) Transitional exception. A marking in conformance with the requirements of this paragraph in effect on December 31, 2014, may continue to be used until December 31, 2016.

(ii) For domestic transportation, an overpack marked prior to January 1, 2017 and in conformance with the requirements of this paragraph in effect on December 31, 2014, may continue in service until the end of its useful life.

(5) Packages containing Class 8 (corrosive) materials in Packing Group I or Division 5.1 (oxidizing)

materials in Packing Group I may not be overpacked with any other materials.

(6) For limited quantities and ORM material, the overpack is marked with a limited quantity marking prescribed in § 172.315 of this subchapter or, the ORM marking prescribed in § 172.316 of this subchapter, unless a limited quantity or ORM marking representative of the hazardous material in the overpack is visible.

(7) For excepted quantities, the overpack is marked with the required marking of § 173.4a of this part

unless visible. (b) Shrink-wrapped or stretch-wrapped trays may be used as outer packagings for inner packagings

prepared in accordance with the limited quantity provisions or consumer commodity provisions of this subchapter, provided that—

(1) Inner packagings are not fragile, liable to break or be easily punctured, such as those made of

glass, porcelain, stoneware or certain plastics; and (2) Each complete package does not exceed 20 kg (44 lbs) gross weight.

(c) Hazardous materials which are required to be labeled POISON may be transported in the same

motor vehicle with material that is marked or known to be foodstuffs, feed or any edible material intended for consumption by humans or animals provided the hazardous material is marked, labeled, and packaged in accordance with this subchapter, conforms to the requirements of paragraph (a) of this section and is overpacked as specified in § 177.841(e) of this subchapter or in an overpack which is a UN 1A2, 1B2, or 1N2 drum tested and marked for a Packing Group II or higher performance level.

[Amdt. 173-165, 48 FR 28099, June 20, 1983, as amended by Amdt. 173-224, 55 FR 52612 Dec. 21,

1990; 56 FR 66266, Dec. 20, 1991; Amdt. 173-234, 58 FR 51532, Oct. 1, 1993; Amdt. 173-214, 59 FR 67491, Dec. 29, 1994; 64 FR 10776, March 5, 1999; 68 FR 45032, July 31, 2003; 69 FR 76155, Dec. 20, 2004; 70 FR 34397, June 14, 2005]

§173.26 Quantity limitations. When quantity limitations do not appear in the packaging requirements of this subchapter, the permitted gross weight or capacity authorized for a packaging is as shown in the packaging specification or standard in part 178 or 179, as applicable, of this subchapter. [Amdt. 173-224, 55 FR 52612, Dec. 21, 1990]


§173.27 General requirements for transportation by aircraft. (a) The requirements of this section are in addition to requirements prescribed elsewhere under this part

and apply to packages offered or intended for transportation aboard aircraft. Except for materials not subject to performance packaging requirements in subpart E of this part, a packaging containing a Packing Group III material with a primary or subsidiary risk of Division 4.1, 4.2, 4.3, 5.1, or Class 8 must meet the Packing Group II performance level when offered for transportation by aircraft.

(b) Packages authorized on board aircraft.

(1) When Column 9a of the § 172.101 Table indicates that a material is “Forbidden” , that material may not be offered for transportation or transported aboard passenger-carrying aircraft.

(2) When Column 9b of the § 172.101 Table indicates that a material is “Forbidden” , that material

may not be offered for transportation or transported aboard aircraft. (3) The maximum quantity of hazardous material in a package that may be offered for transportation

or transported aboard a passenger-carrying aircraft or cargo aircraft may not exceed that quantity prescribed for the material in Column 9a or 9b, respectively, of the § 172.101 Table.

(4) A package containing a hazardous material which is authorized aboard cargo aircraft but not

aboard passenger aircraft must be labeled with the CARGO AIRCRAFT ONLY label required by § 172.402(c) of this subchapter and may not be offered for transportation or transported aboard passenger-carrying aircraft.

(c) Pressure requirements.

(1) Packagings must be designed and constructed to prevent leakage that may be caused by changes in altitude and temperature during transportation aboard aircraft.

(2) Packagings for which retention of liquid is a basic function must be capable of withstanding

without leakage the greater of–

(i) An internal pressure which produces a gauge pressure of not less than 75 kPa (11 psig) for liquids in Packing Group III of Class 3 or Division 6.1. or 95 kPa (14 psig) for other liquids; or

(ii) A pressure related to the vapor pressure of the liquid to be conveyed, determined by one of

the following: (A) The total gauge pressure measured in the receptacle (i.e., the vapor pressure of the

material and the partial pressure of air or other inert gases, less 100 kPa (15 psia)) at 55 °C (131 °F), multiplied by a safety factor of 1.5; determined on the basis of a filling temperature of 15 °C (59 °F) and a degree of filling such that the receptacle is not completely liquid full at a temperature of 55 °C (131 °F) or less;

(B) 1.75 times the vapor pressure at 50 °C (122 °F) less 100 kPa (15 psia); or (C) 1.5 times the vapor pressure at 55 °C (131 °) less 100 kPa (15 psia).

(3) Notwithstanding the provisions of paragraph (c)(2) of this section–

(i) Hazardous materials may be contained in an inner packaging which does not itself meet the

pressure requirement provided that the inner packaging is packed within a supplementary packaging which does meet the pressure requirement and other applicable packaging requirements of this subchapter.

(ii) Packagings which are subject to the hydrostatic pressure test and marking requirements of

§§ 178.605 and 178.503(a)(5), respectively, of this subchapter must have a marked test


pressure of not less than 250 kPa (36 psig) for liquids in Packing Group I, 80 kPa (12 psig) for liquids in Packing Group III of Class 3 or Division 6.1, and 100 kPa (15 psig) for other liquids.

(d) Closures. The body and closure of any packaging must be constructed to be able to adequately resist

the effects of temperature and vibration occurring in conditions normally incident to air transportation. Inner packaging or receptacle closures of combination packages containing liquids must be held securely, tightly and effectively in place by secondary means. Examples of such secondary methods include: Adhesive tape, friction sleeves, welding or soldering, locking wires, locking rings, induction heat seals, and child-resistant closures. The closure device must be designed so that it is unlikely that it can be incorrectly or incompletely closed. Closures must be as follows:

(1) Packing Group I. An inner packaging containing liquids of Packing Group I must have a

secondary means of closure applied and packed in accordance with paragraph (e) of this section. (2) Packing Groups II and III. When a secondary means of closure cannot be applied or is

impracticable to apply to an inner packaging containing liquids of Packing Groups II and III, this requirement may be satisfied by securely closing the inner packaging and placing it in a leakproof liner or bag before placing the inner packaging in its outer packaging.

(e) Absorbent materials. Except as otherwise provided in this subchapter, Packing Group I liquid

hazardous materials of Classes 3, 4, or 8, or Divisions 5.1 or 6.1 that are packaged in combination packagings and offered for air transport in glass, earthenware, plastic, or metal inner packagings must be packed using absorbent material as follows: (1) Inner packagings must be packed in a rigid and leakproof receptacle or intermediate packaging

containing sufficient absorbent material to absorb the entire contents of the inner packaging before packing the inner packaging in its outer package.

(2) Absorbent material must not react dangerously with the liquid (see §§ 173.24 and 173.24a.).

(f) Combination packagings.

(1) Excepted quantities. For authorized materials and inner and outer package quantity limits for combination packages of excepted quantities intended for transportation by aircraft, see §173.4a of this part. Unless otherwise specified in this part, or in Subpart C of part 171 of this subchapter, when combination packagings are intended for transportation aboard an aircraft, inner packagings must conform to the quantity limitations set forth in table 1 of this paragraph for transport aboard passenger-carrying aircraft and table 2 of this paragraph for transport aboard cargo-only aircraft.

(2) Limited quantities.

(i) Unless otherwise specified in this part, or in subpart C of part 171 of this subchapter, when a limited quantity of hazardous material packaged in a combination packaging is intended for transportation aboard an aircraft, the inner and outer packagings must conform to the quantity limitations set forth in Table 3 of this paragraph. Materials and articles must be authorized for transportation aboard a passenger-carrying aircraft (see Column (9A) of the § 172.101 Hazardous Materials Table of this subchapter). Not all unauthorized materials or articles may be indicated in this table. For mixed content packages of limited quantity material, the total net quantity must not exceed the lowest permitted maximum net quantity (for each of the hazard classes or divisions represented in the package) per outer package set forth in Table 3 of this paragraph. The permitted maximum net quantity must be calculated in kilograms for a package that contains both a solid and a liquid. Unless otherwise excepted, packages must be marked and labeled in accordance with this section and any additional requirements in subparts D and E, respectively, of part 172 of this subchapter. Materials or articles not authorized as limited quantity by aircraft are:

(A) Those in Packing Group I;


(B) Class 1 (explosive) material (see§ 173.63(b) of this part for exceptions provided to certain articles of Division 1.4S) and Class 7 (radioactive) material (see §§ 173.421 through 173.425 of this part, as applicable, for exceptions provided to certain substances, instruments or articles of Class 7);

(C) Divisions 2.1 (flammable gas) (except Aerosols (UN1950) and Receptacles, small (UN2037) without subsidiary risk) and Division 2.3 (toxic gas);

(D) Divisions 4.1 (self-reactive), 4.2 (spontaneously combustible) (primary or subsidiary risk), and 4.3 (dangerous when wet) (liquids);

(E) Division 5.2 (organic peroxide) (except when contained in a Chemical or First aid kit (UN3316) or Polyester resin kit (UN3269) (Types D, E and F non-temperature controlled only));

(F) Class 8 (corrosive) materials UN2794, UN2795, UN2803, UN2809, UN3028, UN3506; and

(G) All Class 9 (miscellaneous) materials except for UN1941, UN1990, UN2071, UN3077, UN3082, UN3316, UN3334, UN3335, and ID8000.

(ii) Effective January 1, 2012, packages must be marked with the limited quantity “Y” mark as

prescribed in §172.315 of this part when conforming to Table 3 of this paragraph. Until December 31, 2012, a package may instead be marked with the proper shipping name “Consumer commodity” and “ORM–D–AIR” (including “Charcoal, NA1361) if it contains a consumer commodity, as authorized by this subchapter in effect on October 1, 2010.

(iii) Strong outer packagings are required and a completed package may not exceed 30 kg (66 lbs) gross weight.

(iv) A secondary means of closure required for all liquids contained in inner packagings. If this requirement cannot be satisfied, the use of an intermediate and leakproof form of containment, such as a liner, is required.

(v) Packages must be capable of passing a 1.2 m drop test on to a rigid, non-resilient, flat and horizontal surface, in the position most likely to cause damage. The criteria for passing the test is that the outer packaging must not exhibit any damage affecting safety in transport and there must be no leakage from the inner packagings.

(vi) Each package must be capable of withstanding, without breakage or leakage of any inner packaging, a force applied to the top surface for a duration of 24 hours equivalent to the total weight of identical packages if stacked to a height of 3 m (including the test sample).

(vii) Except for UN3082, inner packagings of combination packagings containing liquids must be capable of passing the appropriate pressure differential test prescribed in paragraph (c) of this section.

(3) The tables are as follows:

Table 1.—Maximum Net Capacity of Inner Packaging for Transportation on Passenger-Carrying

Aircraft

Maximum net quantity per package from Column 9a of the § 172.101 Table

Maximum authorized net capacity of each inner packaging

Glass, earthen-ware or fiber inner packagings

Metal or plastic inner packagings

Liquids:

Not greater than 0.5L 0.5L 0.5L.

Greater than 0.5L. not greater than lL 0.5L lL.

Greater than 1L, not greater than 5L 1L 5L.

Greater than 5L, not greater than 60L 2.5L 10L.


Greater than 220L No limit No limit.

Solids:

Not greater than 5 kg 0.5 kg 1 kg.

Greater than 5 kg, not greater than 25 kg 1 kg 2.5 kg.

Greater than 25 kg, not greater than 200 kg 5 kg 10 kg.

Greater than 200 kg No limit No limit

. Table 2.—Maximum Net Capacity of Inner Packaging for Transportation on Cargo Aircraft


Maximum net quantity per package from Column 9b of the § 172.101 Table

Maximum authorized net capacity of each inner packaging

Glass, earthenware or fiber inner packagings


Liquids:

Not greater than 2.5L 1L 1L.

Greater than 2.5L, not greate than 30L 2.5L 2.5L.



Greater than 220L No limit No limit.

Solid:

Not greater than 15 kg 1kg 2.5 kg.

Greater than 15 kg, not greater than 50 kg 2.5 kg 5 kg.

Greater than 50 kg, not greater than 200 kg 5 kg 10 kg.

Greater than 200 kg No limit No limit.

Table 3—Maximum Net Quantity of Each Inner Packaging for Materials Authorized for

Transportation as Limited Quantity by Aircraft

Hazard class or

division

Maximum authorized net quantity of each inner packaging

Maximum authorized net

quantity of each outer package

Notes Glass,

earthenware or fiber inner

packagings


Class 1 Forbidden (See note)

See § 173.63(b) of this part for exceptions provided to certain articles of Division 1.4S.

Class 2 30 kg Gross Authorized materials: Aerosols (UN1950) in Divisions 2.1 and 2.2, and Receptacles, small (UN2037) in Divisions 2.1 and 2.2 without subsidiary risk and Fuel cells cartridges (UN3478, UN3479), see §173.230 of this part.

Class 3 PG I: Forbidden PG II: 0.5L

PG II: 0.5L PG II: 1L* *Maximum net quantity per outer package with corrosive subsidiary risk (e.g., UN2924, UN3286) is 0.5L. For Class 3 base materials as part of a Polyester resin kit (UN3269), see § 173.165 of this part for additional requirements, as applicable. Inner packaging limit for UN3269 base material is 1.0 L. For Fuel cell cartridges containing flammable liquids (UN3473), see § 173.230 of this part.

PG III: 2.5L* *Corrosive subsidiary risk ( e.g., UN2924) or toxic ( e.g., UN1992) is 1L

PG III: 5.0L* *Corrosive subsidiary risk ( e.g., UN2924) or toxic ( e.g., UN1992) is 1L

PG III: 10L* *Maximum net quantity per outer package with corrosive subsidiary risk (e.g., UN2924) is 1L and toxic subsidiary risk (e.g., UN1992) is 2L. For Class 3 base materials as part of a Polyester resin kit (UN3269), see § 173.165 of this part for additional requirements, as applicable. Inner packaging limit for UN3269


Hazard class or

division




Notes Glass,


packagings


base material is 1.0 L.

Division 4.1 (does not include self-reactive material)

PG I: Forbidden

PG II: 0.5 kg PG II: 0.5 kg PG II: 5 kg* *Maximum net quantity per outer package with toxic subsidiary risk ( e.g., UN3179) is 1 kg.

PG III: 1 kg PG III: 1 kg PG III: 10 kg* *Maximum net quantity per outer package with corrosive subsidiary risk ( e.g., UN3180) is 5 kg.

Division 4.2 (Primary or subsidiary)

Forbidden* 25 kg (net mass)*

*Until December 31, 2012, Charcoal (NA1361), PG III, may be transported as a limited quantity and may be renamed Consumer commodity and reclassed ORM–D–AIR, if eligible.

Division 4.3 (solid material only)

PG I solids and all liquids regardless of Packing Group: Forbidden

PG II: 0.5 kg PG II: 0.5 kg PG II: 5 kg* *Maximum net quantity per outer package with toxic subsidiary risk ( e.g., UN3134) is 1 kg. For fuel cell cartridges containing water reactive substances (UN3476), see §173.230 of this part.

PG III: 1 kg PG III: 1 kg PG III: 10 kg* *Maximum net quantity per outer package with corrosive or flammable subsidiary risk ( e.g., UN3131 or UN3132, respectively) is 5 kg.

Division 5.1 (Liquid or solid material)

PG I: Forbidden

Division 5.1 (liquid material)

PG II: 0.1L PG II: 0.1L PG II: 0.5L

PG III: 0.5L PGIII: 0.5L PG III: 1.0L

Division 5.1 (solid material)

PG II: 0.5 kg PG II: 0.5 kg PG II: 2.5 kg* *Maximum net quantity per outer package with toxic subsidiary risk ( e.g., UN3087) is 1 kg.

PG III: 1.0 kg PG III: 1.0 kg PG III: 10 kg* *Maximum net quantity per outer package with corrosive subsidiary risk ( e.g., UN3085) is 1 kg.


30 mL 30 ml 1 kg Authorized materials: Types D, E and F are authorized only as part of a Chemical or First aid kit (UN3316) in accordance with §173.161 of this part or a Polyester resin kit (UN3269) in accordance with §173.165 of this part. See §§ 173.161 and 173.165, as applicable, for


Hazard class or

division




Notes Glass,


packagings


additional requirements.

Division 5.2 (solid material)

100 g 100 g 1kg Solid activators of Types D, E and F are limited to 100 g per inner packaging for UN3316 and UN3269. See §§ 173.161 and 173.165, as applicable, for additional requirements.

Division 6.1 PG I (Inhalation or otherwise): Forbidden


PG II: 0.1L PG II: 0.1L PG II: 1.0L* *Maximum net quantity per outer package with corrosive subsidiary risk ( e.g., UN3289) is 0.5L.

PG III: 0.5L PG III: 0.5L PG III: 2.0L

Class 7 Forbidden (See Note)

See §§ 173.421 through 173.425 of this part, as applicable, for exceptions provided to certain substances, instruments or articles of Class 7.

Class 8 (liquid material)

PGI: Forbidden

PG II: 0.1L PG II: 0.1L PG II: 0.5L* For “Fuel cell cartridges containing corrosive substances” (UN3477), see §173.230 of this part.

PG III: 0.5L PG III: 0.5L PG III: 1.0L

Class 8 (solid) PG II: 0.5 kg PG II: 0.5 kg PG II: 5.0 kg* *Maximum net quantity per outer package for UN2430 is 1.0 kg. UN2794, UN2795, UN2803, UN2809, UN3028 are not authorized as limited quantity.

PG III: 1 kg PG III: 1 kg PG III: 5.0 kg*

Class 9 (liquid material)

30 mL (UN3316); 5.0L (UN1941, UN1990, UN3082, UN3334).

30 mL (UN3316); 5.0L (UN1941, UN1990, UN3082, UN3334).

1 kg (UN3316); 30 kg gross (all other authorized Class 9 material).

Authorized materials: UN1941, UN1990, UN2071, UN3077, UN3082, UN3334, and UN3335. Additionally, Consumer commodity (ID8000) in accordance with § 173.167 of this part and Chemical kit or First aid kit (UN3316) in accordance with § 173.161 of this part are authorized.

Class 9 (solid material)

100 g (UN3316); 5.0 kg (UN2071, UN3077)

100 g (UN3316); 5.0 kg (UN2071, UN3077)

1 kg (UN3316); 30 kg gross (all other authorized Class 9 material).

(g) Cylinders. For any cylinder containing hazardous materials and incorporating valves, sufficient

protection must be provided to prevent operation of, and damage to, the valves during transportation, by one of the following methods:

(1) By equipping each cylinder with securely attached valve caps or protective headrings; or (2) By boxing or crating the cylinder.

(h) Tank cars and cargo tanks. Any tank car or cargo tank containing a hazardous material may not be transported aboard aircraft.

(i) Effective October 1, 2006, each person who offers a hazardous material for transportation by aircraft


must include the certification statement specified in § 172.204(c)(3). §173.28 Reuse, reconditioning and remanufacture of packagings. (a) General. Packagings and receptacles used more than once must be in such condition, including

closure devices and cushioning materials, that they conform in all respects to the prescribed requirements of this subchapter. Before reuse, each packaging must be inspected and may not be reused unless free from incompatible residue, rupture, or other damage which reduces its structural integrity. Packagings not meeting the minimum thickness requirements prescribed in paragraph (b)(4)(i) of this section may not be reused, reconditioned, or remanufactured for reuse.

(b) Reuse of non-bulk packaging. A non-bulk packaging used more than once must conform to the

following provisions and limitations:

(1) A non-bulk packaging which, upon inspection, shows evidence of a reduction in integrity may not be reused unless it is reconditioned in accordance with paragraph (c) of this section.

(2) Before reuse, packagings subject to the leakproofness test with air prescribed in § 178.604 of this

subchapter shall be–

(i) Retested without failure in accordance with § 178.604 of this subchapter using an internal air pressure (gauge) of at least 48 kPa (7.0 psig) for Packing Group I and 20 kPa (3.0 psig) for Packing Group II and Packing Group III; and

(ii) Marked with the letter “L” , with the name and address or symbol of the person conducting the test, and the last two digits of the year the test was conducted. Symbols, if used, must be registered with the Associate Administrator

(3) Packagings made of paper (other than fiberboard), plastic film, or textile are not authorized for

reuse; (4) Metal and plastic drums and jerricans used as single packagings or the outer packagings of

composite packagings are authorized for reuse only when they are marked in a permanent manner (e.g., embossed) in millimeters with the nominal (for metal packagings) or minimum (for plastic packagings) thickness of the packaging material, as required by § 178.503(a)(9) of this subchapter, and–

(i) Except as provided in paragraph (b)(4)(ii) of this section, conform to the following minimum

thickness criteria:

Maximum capacity not over

Minimum thickness of packaging material

Metal drum or jerrican Plastic drum or jerrican

20 L 0.63 mm (0.025 inch) 1.1 mm (0.043 inch).

30 L 0.73 mm (0.029 inch) 1.1 mm (0.043 inch).

40 L 0.73 mm (0.029 inch) 1.8 mm (0.071 inch).

60 L 0.92 mm (0.036 inch) 1.8 mm (0.071 inch).

120 L 0.92 mm (0.036 inch) 2.2 mm (0.087 inch).

220 L 0.92 mm (0.036 inch)1 2.2 mm (0.087 inch).

450 L 1.77 mm (0.070 inch) 5.0 mm (0.197 inch).

1 Metal drums or jerricans with a minimum thickness of 0.82 mm body and 1.09 mm heads which

are manufactured and marked prior to January 1, 1997 may be reused. Metal drums or jerricans manufactured and marked on or after January 1, 1997, and intended for reuse, must be constructed with a minimum thickness of 0.82 mm body and 1.11 mm heads.

(ii) For stainless steel drums and jerricans, conform to a minimum wall thickness as determined

by the following equivalence formula:

Formula for Metric Units


E1 = (21.4 x e0) ) (cube root of Rm1 x A1) Formula for U.S. Standard Units

E1 = (21.4 x e0) ) (cube root of Rm1 x A1 ) 145) where: e1=required equivalent wall thickness of the metal to be used (in mm or, for U.S. Standard

units, use inches). e0=required minimum wall thickness for the reference steel (in mm or, for U.S. Standard

units, use inches). Rm1=guaranteed minimum tensile strength of the metal to be used (in N/mm2 or for U.S.

Standard units, use psi). A1=guaranteed minimum elongation (as a percentage) of the metal to be used on fracture

under tensile stress (see paragraph (c)(1) of this section).

(5) Plastic inner receptacles of composite packagings must have a minimum thickness of 1.0 mm (0.039 inch).

(6) A previously used non-bulk packaging may be reused for the shipment of hazardous waste, not

subject to the reconditioning and reuse provisions of this section, in accordance with § 173.12(c). (7) Notwithstanding the provisions of paragraph (b)(2) of this section, a packaging otherwise

authorized for reuse may be reused without being leakproofness tested with air provided the packaging–

(i) Is refilled with a material which is compatible with the previous lading: (ii) Is refilled and offered for transportation by the original filler; (iii) Is transported in a transport vehicle or freight container under the exclusive use of the refiller

of the packaging; and (iv) Is constructed of–

(A) Stainless steel, monel or nickel with a thickness not less than one and one-half times the

minimum thickness prescribed in paragraph (b)(4) of this section; (B) Plastic, provided the packaging is not refilled for reuse on a date more than five years

from the date of manufacture marked on the packaging in accordance with § 178.503(a)(6) of this subchapter; or

(C) Another material or thickness when approved under the conditions established by the

Associate Administrator for reuse without retesting. (c) Reconditioning of non-bulk packaging.

(1) For the purpose of this subchapter, reconditioning of metal drums is:

(i) Cleaning to base material of construction, with all former contents, internal and external corrosion, and any external coatings and labels removed;

(ii) Restoring to original shape and contour, with chimes (if any) straightened and sealed, and all

non-integral gaskets replaced: and (iii) Inspecting after cleaning but before painting, Packagings that have visible pitting, significant

reduction in material thickness, metal fatigue, damaged threads or closures, or other


significant defects, must be rejected.

(2) For the purpose of this subchapter, reconditioning of a non-bulk packaging other than a metal drum includes:

(i) Removal of all former contents, external coatings and labels, and cleaning to the original

materials of construction; (ii) Inspection after cleaning with rejection of packagings with visible damage such as tears,

creases or cracks, or damaged threads or closures, or other significant defects; (iii) Replacement of all non-integral gaskets and closure devices with new or refurbished parts,

and cushioning and cushioning materials; and components including gaskets, closure devices and cushioning and cushioning material. (For a UN 1H1 plastic drum, replacing a removable gasket or closure device with another of the same design and material that provides equivalent performance does not constitute reconditioning); and

(iv) Ensuring that the packagings are restored to a condition that conforms in all respects with the

prescribed requirements of this subchapter.

(3) A person who reconditions a packaging manufactured and marked under the provisions of subpart L of part 178 of this subchapter, shall mark that packaging as required by § 178.503(c) and (d) of this subchapter. The marking is the certification of the reconditioner that the packaging conforms to the standard for which it is marked and that all functions performed by the reconditioner which are prescribed by this subchapter have been performed in compliance with this subchapter.

(4) The markings applied by the reconditioner may be different from those applied by the

manufacturer at the time of original manufacture, but may not identify a greater performance capability than that for which the original design type had been tested (for example, the reconditioner may mark a drum which was originally marked as 1A1/Y1.8 as 1A1/Y1.2 or 1A1/Z2.0).

(5) Packagings which have significant defects which cannot be repaired may not be reused.

(d) Remanufacture of non-bulk packagings. For the purpose of this subchapter, remanufacture is the

conversion of a non-specification, non-bulk packaging to a DOT specification or U.N. standard, the conversion of a packaging meeting one specification or standard to another specification or standard (for example, conversion of 1A1 non-removable head drums to 1A2 removable head drums) or the replacement of integral structural packaging components (such as non-removable heads on drums). A person who remanufactures a non-bulk packaging to conform to a specification or standard in part 178 of this subchapter is subject to the requirements of part 178 of this subchapter as a manufacturer.

(e) Non-reusable containers. A packaging marked as NRC according to the DOT specification or UN

standard requirements of part 178 of this subchapter may be reused for the shipment of any material not required by this subchapter to be shipped in a DOT specification or UN standard packaging.

(f) A Division 6.2 packaging to be reused must be disinfected prior to reuse by any means effective for

neutralizing the infectious substance the packaging previously contained. A secondary packaging or outer packaging conforming to the requirements of § 173.196 or § 173.199 need not be disinfected prior to reuse if no leakage from the primary receptacle has occurred. Drums or jerricans not meeting the minimum thickness requirements prescribed in paragraph (b)(4)(i) of this section may not be reused, reconditioned, or remanufactured for reuse.

[Amdt. 173-224, 55 FR 52614, Dec. 21, 1990, as amended at 56 FR 66266, Dec. 20, 1991; 57 FR

45460, Oct. 1, 1992; Amdt. 173-241, 59 FR 67491, 67492, Dec. 29, 1994; 60 FR 7627, Feb. 8, 1995; Amdt. 173-241, 60 FR 26805, 26806, May 18, 1995 Amdt. 173-255, 61 FR 50624, 50265, Sept. 26, 1996; 61 FR 51495, Oct. 2, 1996; 62 14334, Mar. 26, 1997; 64 FR 10776, March 5, 1999; 64 FR


44428, Aug. 16, 1999; 66 FR 45183, 45379, 45380, Aug. 28, 2001; 67 FR 53138, Aug. 14, 2002; 69 FR 76155, Dec. 20, 2004; 70 FR 34075, June 13, 2005]

§173.29 Empty packagings. (a) General. Except as otherwise provided in this section, an empty packaging containing only the

residue of a hazardous material shall be offered for transportation and transported in the same manner as when it previously contained a greater quantity of that hazardous material.

(b) Notwithstanding the requirements of paragraph (a) of this section, an empty packaging is not subject

to any other requirements of this subchapter if it conforms to the following provisions:

(1) Any hazardous material shipping name and identification number markings, any hazard warning labels or placards, and any other markings indicating that the material is hazardous (e.g., RQ, INHALATION HAZARD) are removed, obliterated, or securely covered in transportation. This provision does not apply to transportation in a transport vehicle or a freight container if the packaging is not visible in transportation and the packaging is loaded by the shipper and unloaded by the shipper or consignee;

(2) The packaging–

(i) Is unused; (ii) Is sufficiently cleaned of residue and purged of vapors to remove any potential hazard; (iii) Is refilled with a material which is not hazardous to such an extent that any residue remaining

in the packaging no longer poses a hazard; or (iv) Contains only the residue of–

(A) An ORM-D material; or (B) A Division 2.2 non-flammable gas, other than ammonia, anhydrous, and with no

subsidiary hazard, at an absolute pressure less than 280 kPa (40.6 psia); at 20° C (68° F); and

(3) Any material contained in the packaging does not meet the definitions in § 171.8 of this

subchapter for a hazardous substance, a hazardous waste, or a marine pollutant. (c) A non-bulk packaging containing only the residue of a hazardous material covered by Table 2 of

§ 172.504 of this subchapter that is not a material poisonous by inhalation or its residue shipped under the subsidiary placarding provisions of § 172.505–

(1) Does not have to be included in determining the applicability of the placarding requirements of

subpart F of part 172 of this subchapter; and (2) Is not subject to the shipping paper requirements of this subchapter when collected and

transported by a contract or private carrier for reconditioning, remanufacture or reuse. (d) Notwithstanding the stowage requirements in Column 10a of the § 172.101 Table for transportation

by vessel, an empty drum or cylinder may be stowed on deck or under deck. (e) Specific provisions for describing an empty packaging on a shipping paper appear in § 172.203(e) of this subchapter. (f) [Reserved] (g) A package which contains a residue of an elevated temperature material may remain marked in the

same manner as when it contained a greater quantity of the material even though it no longer meets


the definition in § 171.8 of this subchapter for an elevated temperature material. (h) A package that contains a residue of a hazardous substance, Class 9, listed in the § 172.101 Table,

Appendix A, Table I, that does not meet the definition of another hazard class and is not a hazardous waste or marine pollutant, may remain marked, labeled and, if applicable, placarded in the same manner as when it contained a greater quantity of the material even though it no longer meets the definition in § 171.8 of this subchapter for a hazardous substance.

[Amdt. 173-224, 55 FR 52614, Dec. 21, 1990, as amended by Amdt. 173-227, 56 FR 49989, Oct. 2,

1991; Amdt. 173-231, 57 FR 52939, Nov. 5, 1992; Amdt. 173-251, 61 FR 28676, June 5, 1996; 62 FR 1217, Jan. 08, 1997; 64 FR 10776, March 5, 1999; 69 FR 64473, Nov. 4, 2004]

§173.30 Loading and unloading of transport vehicles. A person who is subject to the loading and unloading regulations in this subchapter must load or unload hazardous materials into or from a transport vehicle or vessel in conformance with the applicable loading and unloading requirements of parts 174, 175, 176, and 177 of this subchapter. [Amdt. 173-94, 41 FR 16064, Apr. 15, 1976; 68 FR 61941, Oct. 30, 2003] §173.31 Use of tank cars. (a) General.

(1) No person may offer a hazardous material for transportation in a tank car unless the tank car meets the applicable specification and packaging requirements of this subchapter or, when this subchapter authorizes the use of an non-DOT specification tank car, the applicable specification to which the tank was constructed.

(2) Tank cars and appurtenances may be used for the transportation of any commodity for which

they are authorized in this part and specified on the certificate of construction (AAR Form 4-2 or by addendum on Form R-1). See § 179.5 of this subchapter. Transfer of a tank car from one specified service on its certificate of construction to another may be made only by the owner or with the owner’s authorization. A tank car proposed for a commodity service other than specified on its certificate of construction must be approved for such service by the AAR’s Tank Car Committee.

(3) No person may fill a tank car overdue for periodic inspection with a hazardous material and then

offer it for transportation. Any tank car marked as meeting a DOT specification and any non-specification tank car transporting a hazardous material must have a periodic inspection and test conforming to Subpart F of Part 180 of this subchapter.

(4) No railroad tank car, regardless of its construction date, may be used for the transportation in

commerce of any hazardous material unless the air brake equipment support attachments of such tank car conform to the standards for attachments set forth in §§ 179.100-16 and 179.200-19 of this subchapter.

(5) No railroad tank car, regardless of its construction date, may be used for the transportation in

commerce of any hazardous material with a self-energized manway located below the liquid level of the lading.

(6) Unless otherwise specifically provided in this part:

(i) When the tank car delimiter is an “A,” offerors may also use tank cars with a delimiter “S,” “J”

or “T” . (ii) When the tank car delimiter is an “S,” offerors may also use tank cars with a delimiter “J” or

“T” .


(iii) When a tank car delimiter is a “T” offerors may also use tank cars with a delimiter of “J” . (iv) When a tank car delimiter is a “J” , offerors may not use a tank car with any other delimiter.

(7) A class DOT-103 or DOT-104 tank car may continue to be used for the transportation of a

hazardous material if it meets the requirements of this subchapter and the design requirements in Part 179 of this subchapter in effect on September 30, 2003; however, no new construction is authorized.

(8) A tank car authorized by the Transport Canada TDG Regulations (IBR, see § 171.7 of this

subchapter) may be used provided it conforms to the applicable requirements in § 171.12 of this subchapter.

(b) Safety systems—(1) Coupler vertical restraint. Each tank car conforming to a DOT specification and

any other tank car used for transportation of a hazardous material must be equipped with a coupler vertical restraint system that meets the requirements of § 179.14 of this subchapter.

(2) Pressure relief devices.

(i) Pressure relief devices on tank cars must conform to Part 179 of this subchapter.

(ii) A single-unit tank car transporting a Division 6.1 PG I or II, or Class 2, 3, or 4 material must have a reclosing pressure relief device. However, a single-unit tank car built before January 1, 1991, and equipped with a non-reclosing pressure relief device may be used to transport a Division 6.1 PG I or II material or a Class 4 liquid provided such materials do not meet the definition of a material poisonous by inhalation.

(3) Tank-head puncture-resistance requirements. The following tank cars must have a tank-head

puncture-resistance system that conforms to the requirements in § 179.16 of this subchapter, or to the corresponding requirements in effect at the time of installation:

(i) Tank cars transporting a Class 2 material. (ii) Tank cars constructed from aluminum or nickel plate that are used to transport hazardous

material. (iii) Except as provided in paragraph (b)(3)(iv) of this section, those tank cars specified in

paragraphs (b)(3)(i) and (ii) of this section not requiring a tank-head puncture resistance system prior to July 1, 1996, must have a tank-head puncture resistance system installed no later than July 1, 2006.

(iv) Class DOT 105A tank cars built prior to September 1, 1981, having a tank capacity less than

70 kl (18,500 gallons), and used to transport a Division 2.1 (flammable gas) material, must have a tank-head puncture-resistant system installed no later than July 1, 2001.

(4) Thermal protection requirements. The following tank cars must have thermal protection that

conforms to the requirements of § 179.18 of this subchapter:

(i) Tank cars transporting a Class 2 material, except for a class 106, 107A, 110, and 113 tank car. A tank car equipped with a thermal protection system conforming to § 179.18 of this subchapter, or that has an insulation system having an overall thermal conductance of no more than 0.613 kilojoules per hour, per square meter, per degree Celsius temperature differential (0.03 BTU per square foot, per hour, per degree Fahrenheit temperature differential), conforms to this requirement.

(ii) A tank car transporting a Class 2 material that was not required to have thermal protection

prior to July 1, 1996, must be equipped with thermal protection no later than July 1, 2006.

(5) Bottom-discontinuity protection requirements. No person may offer for transportation a hazardous


material in a tank car with bottom-discontinuity protection unless the tank car has bottom-discontinuity protection that conforms to the requirements of E9.00 and E10.00 of the AAR Specifications for Tank Cars (IBR, see § 171.7 of this subchapter). Tank cars not requiring bottom-discontinuity protection under the terms of Appendix Y of the AAR Specifications for Tank Cars as of July 1, 1996, must conform to these requirements no later than July 1, 2006, except that tank cars transporting a material that is hazardous only because it meets the definition of an elevated temperature material or because it is molten sulfur do not require bottom discontinuity protection. Tank cars modified before July 1, 1996, may conform to the bottom-discontinuity protection requirements of appendix Y, instead of paragraphs E9.00 or E10.00 of the AAR Specifications for Tank Cars.

(6) Scheduling of modifications and progress reporting. The date of conformance for the continued

use of tank cars subject to paragraphs (b)(3), (b)(4), (b)(5), (e)(2), and (f) of this section and §§ 173.314(j) and 173.323(c)(1) is subject to the following conditions and limitations.

(i) Each tank car owner shall modify, reassign, retire, or remove at least 50 percent of their in-

service tank car fleet within the first half of the compliance period and the remainder of their in-service tank car fleet during the second half of the compliance period.

(ii) By October 1 of each year, each owner of a tank car subject to this paragraph (b)(6) shall

submit to the Federal Railroad Administration, Hazardous Materials Division, Office of Safety Assurance and Compliance, 1120 Vermont Avenue, Mail Stop 25, Washington, DC 20590, a progress report that shows the total number of in-service tank cars that need head protection, thermal protection, or bottom-discontinuity protection; the number of new or different tank cars acquired to replace those tank cars required to be upgraded to a higher service pressure; and the total number of tank cars modified, reassigned, acquired, retired, or removed from service the previous year.

(c) Tank car test pressure. A tank car used for the transportation of a hazardous material must have a

tank test pressure equal to or greater than the greatest of the following:

(1) Except for shipments of carbon dioxide, anhydrous hydrogen chloride, vinyl fluoride, ethylene, or hydrogen, 133 percent of the sum of lading vapor pressure at the reference temperature of 46 °C (115 °F) for non-insulated tank cars or 41 °C (105 °F) for insulated tank cars plus static head, plus gas padding pressure in the vacant space of a tank car;

(2) 133 percent of the maximum loading or unloading pressure, whichever is greater; (3) 20.7 Bar (300 psig) for materials that are poisonous by inhalation (see § 173.31(e)(2)(ii) for

compliance dates); (4) The minimum pressure prescribed by the specification in Part 179 of this subchapter; or (5) The minimum test pressure prescribed for the specific hazardous material in the applicable

packaging section in Subpart F or G of this Part. (d) Examination before shipping.

(1) No person may offer for transportation a tank car containing a hazardous material or a residue of a hazardous material unless that person determines that the tank car is in proper condition and safe for transportation. As a minimum, each person offering a tank car for transportation must perform an external visual inspection that includes:

(i) Except where insulation or a thermal protection system precludes an inspection, the tank

shell and heads for abrasion, corrosion, cracks, dents, distortions, defects in welds, or any other condition that makes the tank car unsafe for transportation;

(ii) The piping, valves, fittings, and gaskets for corrosion, damage, or any other condition that


makes the tank car unsafe for transportation; (iii) For missing or loose bolts, nuts, or elements that make the tank car unsafe for transportation; (iv) All closures on tank cars and determine that the closures and all fastenings securing them

are properly tightened in place by the use of a bar, wrench, or other suitable tool; (v) Protective housings for proper securement; (vi) The pressure relief device, including a careful inspection of the rupture disc in non-reclosing

pressure relief devices, for corrosion or damage that may alter the intended operation of the device;

(vii) Each tell-tale indicator after filling and prior to transportation to ensure the integrity of the

rupture disc; (viii) The external thermal protection system, tank-head puncture resistance system, coupler

vertical restraint system, and bottom discontinuity protection for conditions that make the tank car unsafe for transportation.

(ix) The required markings on the tank car for legibility; and (x) The periodic inspection date markings to ensure that the inspection and test intervals are

within the prescribed intervals.

(2) Closures on tank cars are required, in accordance with this subchapter, to be designed and closed so that under conditions normally incident to transportation, including the effects of temperature and vibration, there will be no identifiable release of a hazardous material to the environment. In any action brought to enforce this section, the lack of securement of any closure to a tool-tight condition, detected at any point, will establish a rebuttable presumption that a proper inspection was not performed by the offeror of the car. That presumption may be rebutted by any evidence indicating that the lack of securement resulted from a specific cause not within the control of the offeror.

(e) Special requirements for materials poisonous by inhalation—

(1) Interior heater coils. Tank cars used for materials poisonous by inhalation may not have interior heater coils.

(2) Tank car specifications. A tank car used for a material poisonous by inhalation must have a tank

test pressure of 20.7 Bar (300 psig) or greater, head protection, and a metal jacket (e.g., DOT 105S300W), except that–

(i) A higher test pressure is required if otherwise specified in this subchapter; and (ii) Other than as provided in paragraph (b)(6) of this section, a tank car which does not conform

to the requirements of this paragraph (e)(2), and was authorized for the material poisonous by inhalation under the regulations in effect on June 30, 1996, may continue in use until July 1, 2006.

(f) Special requirements for hazardous substances.

(1) A tank car used for a hazardous substance listed in paragraph (f)(2) of this section must have a tank test pressure of at least 13.8 Bar (200 psig), head protection and a metal jacket, except that–

(i) No metal jacket is required if–

(A) The tank test pressure is 23.4 Bar (340 psig) or higher; or


(B) The tank shell and heads are manufactured from AAR steel specification TC-128,

normalized;

(ii) A higher test pressure is required if otherwise specified in this subchapter; and (iii) Other than as provided in paragraph (b)(6) of this section, a tank car which does not conform

to the requirements of this paragraph (f)(1), and was authorized for a hazardous substance under the regulations in effect on June 30, 1996, may continue in use until July 1, 2006.

(2) List of hazardous substances. Hazardous substances for which the provisions of this paragraph

(f) apply are as follows: Aldrin Allyl chloride alpha-BHC beta-BHC delta-BHC gamma-BHC Bis(2-chloroethyl) ether Bromoform Carbon tetrachloride Chlordane p-Chloroaniline Chlorobenzene Chlorobenzilate p-Chloro-m-cresol 2-Chloroethyl vinyl ether Chloroform 2-Chloronapthalene o-Chlorophenol 3-Chloropropionitrile DDE DDT 1,2-Dibromo-3-chloropropane m-Dichlorobenzene o-Dichlorobenzene p-Dichlorobenzene 3,3´-Dichlorobenzidine 1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethylene Dichloroisopropyl ether Dichloromethane 2,4-Dichlorophenol 2,6-Dichlorophenol 1,2-Dichloropropane 1,3-Dichloropropene Dieldrin alpha-Endosulfan

beta-Endosulfan Endrin Endrin aldehyde Heptachlor Heptachlor epoxide Hexachlorobenzene Hexachlorobutadiene Hexachloroethane Hexachlorophene Hexachloropropene Isodrin Kepone Methoxychlor 4,4´-Methylenebis(2-chloroaniline) Methylene bromide Pentachlorobenzene Pentachloroethane Pentachloronitrobenzene (PCNB) Pentachlorophenol Polychlorinated biphenyls (PCBs) Pronamide Silvex (2,4,5-TP) 2,4,5-T TDE 1,2,4,5-Tetrachlorobenzene 2,3,7,8-Tetrachlorodibenzo-p-dioxin

(TCDD) Tetrachloroethane Tetrachloroethylene 2,3,4,6-Tetrachlorophenol Toxaphene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethylene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol Tris(2,3-dibromopropyl)phosphate

(g) Tank car loading and unloading. When placed for loading or unloading and before unsecuring any

closure, a tank car must be protected against movement or coupling as follows:

(1) Each hazmat employee who is responsible for loading or unloading a tank car must secure access to the track to prevent entry by other rail equipment, including motorized service vehicles. Derails, lined and locked switches, portable bumper blocks, or other equipment that provides an

49 CFR 173 Subpart D A5-29 SET Environmental, Inc. Exceptions: Other Than for Class 1 and 7 Last Revision: May 11, 2020

equivalent level of security may be used to satisfy this requirement. (2) Caution signs must be displayed on the track or on the tank cars to warn persons approaching

the cars from the open end of the track and must be left up until after all closures are secured and the cars are in proper condition for transportation. The caution signs must be of metal or other durable material, rectangular, at 30.48 cm (12 inches) high by 38.10 cm (15 inches) wide, and bear the word "STOP." The word "STOP" must appear in letters at least 10.16 cm (4 inches) high. The letters must be white on a blue background. Additional words, such as "Tank Car Connected" or "Crew at Work," may also appear in white letters under the word "STOP."

(3) At least one wheel on the tank car must be blocked against movement in both directions, and the

hand brakes must be set. If multiple tank cars are coupled together, sufficient hand brakes must be set and wheels blocked to prevent movement in both directions.

§173.32 Requirements for the use of portable tanks. (a) General requirements. No person may offer a hazardous material for transportation in a portable tank

except as authorized by this subchapter.

(1) Except as otherwise provided in this subpart, no person may use a portable tank for the transportation of a hazardous material unless it meets the requirements of this subchapter.

(2) No person may fill and offer for transportation a portable tank when the prescribed periodic test or

inspection under subpart G of part 180 of this subchapter has become due until the test or inspection has been successfully completed. This requirement does not apply to any portable tank filled prior to the test or inspection due date.

(3) When a portable tank is used as a cargo tank motor vehicle, it must conform to all the

requirements prescribed for cargo tank motor vehicles. (See § 173.33.) (b) Substitute packagings. A particular Specification portable tank may be substituted for another

portable tank as follows:

(1) An IM or UN portable tank may be used whenever an IM or UN portable tank having less stringent requirements is authorized provided the portable tank meets or exceeds the requirements for pressure-relief devices, bottom outlets and any other special provisions specified in § 172.102(c)(7)(vi) of this subchapter.

(2) Where a Specification IM101 or IM102 portable tank is prescribed, a UN portable tank or

Specification 51 portable tank otherwise conforming to the special commodity requirements of § 172.102(c)(7) of this subchapter for the material to be transported may be used.

(3) A DOT Specification 51 portable tank may be used whenever a DOT Specification 56, 57, or 60

portable tank is authorized. A DOT Specification 60 portable tank may be used whenever a DOT Specification 56 or 57 portable tank is authorized. A higher integrity tank used instead of a specified portable tank must meet the same design profile; for example, a DOT Specification 51 portable tank must be lined if used instead of a lined DOT Specification 60 portable tank.

(4) A portable tank authorized by the Transport Canada TDG Regulations (IBR, see § 171.7 of this

subchapter) may be used provided it conforms to the applicable requirements in § 171.12 of this subchapter.

(c) Grandfather provisions for portable tanks—

(1) Continued use of Specification 56 and 57 portable tanks. Continued use of an existing portable tank constructed to DOT Specification 56 or 57 is authorized only for a portable tank constructed before October 1, 1996. A stainless steel portable tank internally lined with polyethylene that was constructed on or before October 1, 1996, and that meets all requirements of DOT Specification


57 except for being equipped with a polypropylene discharge ball valve and polypropylene secondary discharge opening closure, may be marked as a Specification 57 portable tank and used in accordance with the provisions of this section.

(2) A DOT Specification 51, IM 101, or IM 102 portable tank may not be manufactured after January

1, 2003; however, such tanks may continue to be used for the transportation of a hazardous material provided they meet the requirements of this subchapter, including the specification requirements and the requirements of this subchapter for the transportation of the particular hazardous material according to the T codes in effect on September 30, 2001 or the new T codes in § 172.102(c)(7)(i), and provided the portable tanks conform to the periodic inspection and tests specified for the particular portable tank in subpart G of part 180 of this subchapter. After January 1, 2003, all newly manufactured portable tanks must conform to the requirements for the design, construction and approval of UN portable tanks as specified in §§ 178.273, 178.274, 178.275, 178.276, 178.277 and part 180, subpart G, of this subchapter.

(3) A DOT Specification portable tank manufactured prior to January 1, 1992 that is equipped with a

non-reclosing pressure relief device may continue in service for the hazardous materials for which it is authorized. Except for a DOT Specification 56 or 57 portable tank, a DOT Specification portable tank manufactured after January 1, 1992, used for materials meeting the definition for Division 6.1 liquids, Packing Group I or II, Class 2 gases, or Class 3 or 4 liquids, must be equipped with a reclosing pressure relief valve having adequately sized venting capacity unless otherwise specified in this subchapter (see §§ 178.275(f)(1) and 178.277 of this subchapter).

(4) Any portable tank container constructed prior to May 15, 1950, complying with the requirements

of either the ASME Code for Unfired Pressure Vessels, 1946 Edition, or the API ASME Code for Unfired Pressure Vessels, 1943 Edition, may be used for the transportation of liquefied compressed gas, provided it fulfills all the requirements of the part and specifications for the particular gas or gases to be transported. Such portable tanks must be marked “ICC Specification 51X” on the plate required by the specification, except as modified by any or all of the following:

(i) Portable tanks designed and constructed in accordance with Pars. U–68, U–69, or U–201 of

the ASME Code, 1943 and 1946 editions, may be used. Portable tanks designed and constructed in accordance with Par. U–68 or Par. U–69 may be re-rated at a working pressure 25 percent in excess of the design pressure for which the portable tank was originally constructed. If the portable tank is re-rated, the re-rated pressure must be marked on the plate as follows: “Re-rated working pressure—psig” .

Note to Paragraph (c)(4)(i): For purposes of setting safety relief valves, pressure control

valves, establishing retest pressure and maximum and minimum design pressures, the re-rated working pressure must be considered as the equivalent of the design pressure as defined in the specification.

(ii) Loading and unloading accessories, valves, piping, fittings, safety and gauging devices, do

not have to comply with the requirements for the particular location on the portable tank.

(5) Any ICC Specification 50 portable tank fulfilling the requirements of that specification may be continued in service for transportation of a liquefied petroleum gas if it is retested every five years in accordance with the requirements in § 180.605 of this subchapter. Use of existing portable tanks is authorized. New construction is not authorized.

(d) Determination of an authorized portable tank. Prior to filling and offering a portable tank for

transportation, the shipper must ensure that the portable tank conforms to the authorized specification and meets the applicable requirements in this subchapter for the hazardous material. The shipper must ensure that the MAWP, design pressure or test pressure of the portable tank, as applicable, is appropriate for the hazardous material being transported. Determination of the applicable pressure must take into account the maximum pressure used to load or unload the hazardous material, the vapor pressure, static head and surge pressures of the hazardous material and the temperatures that the hazardous material will experience during transportation.


(e) External inspection prior to filling. Each portable tank must be given a complete external inspection prior to filling. Any unsafe condition must be corrected prior to its being filled and offered for transportation. The external inspection shall include a visual inspection of:

(1) The shell, piping, valves and other appurtenances for corroded areas, dents, defects in welds and

other defects such as missing, damaged, or leaking gaskets; (2) All flanged connections or blank flanges for missing or loose nuts and bolts; (3) All emergency devices for corrosion, distortion, or any damage or defect that could prevent their

normal operation; (4) All required markings on the tank for legibility; and (5) Any device for tightening manhole covers to ensure such devices are operative and adequate to

prevent leakage at the manhole cover. (f) Loading requirements.

(1) A hazardous material may not be loaded into a portable tank if the hazardous material would:

(i) Damage the portable tank; (ii) React with the portable tank; or (iii) Otherwise compromise its product retention capability.

(2) A hazardous material may not be loaded in a DOT Specification 51, DOT Specification 60, an IM

or UN portable tank unless the portable tank has a pressure relief device that provides total relieving capacity meeting the requirements of this subchapter.

(3) Except during a pressure test, a portable tank may not be subjected to a pressure greater than its marked maximum allowable working pressure or, when appropriate, its marked design pressure.

(4) A portable tank may not be loaded to a gross mass greater than the maximum allowable gross

mass specified on its identification plate. (5) Except for a non-flowable solid or a liquid with a viscosity of 2,680 centistokes (millimeters

squared per second) or greater at 20C (68F), an IM or UN portable tank, or compartment thereof, having a volume greater than 7,500 L (1,980 gallons) may not be loaded to a filling density of more than 20% and less than 80% by volume. This filling restriction does not apply if a portable tank is divided by partitions or surge plates into compartments of not more than 7,500 L (1,980 gallons) capacity; this portable tank must not be offered for transportation in an ullage condition liable to produce an unacceptable hydraulic force due to surge.

(6) The outage for a portable tank may not be less than 2% at a temperature of 50 °C (122 °F)

unless otherwise specified in this subchapter. For UN portable tanks, the applicable maximum filling limits apply as specified according to the assigned TP codes in Column (7) of the § 172.101 Table of this subchapter except when transported domestically.

(7) Each tell-tale indicator or pressure gauge located in the space between a frangible disc and a

safety relief valve mounted in series must be checked after the tank is filled and prior to transportation to ensure that the frangible disc is leak free. Any leakage through the frangible disc must be corrected prior to offering the tank for transportation.

(8) During filling, the temperature of the hazardous materials shall not exceed the limits of the design

temperature range of the portable tank. (9) The maximum mass of liquefied compressed gas per liter (gallon) of shell capacity (kg/L or


lbs./gal.) may not exceed the density of the liquefied compressed gas at 50 °C (122 °F). The portable tank must not be liquid full at 60 °C (140 °F).

(g) Additional requirements for specific modal transport. In addition to other applicable requirements, the

following apply:

(1) A portable tank containing a hazardous material may not be loaded onto a highway or rail transport vehicle unless loaded entirely within the horizontal outline of the vehicle, without overhang or projection of any part of the tank assembly.

(2) An IM or UN portable tank used for the transportation of flammable liquids by rail may not be

fitted with non-reclosing pressure relief devices except in series with reclosing pressure relief valves.

(3) A portable tank or Specification 106A or 110A multi-unit tank car containing a hazardous material

may not be offered for transportation aboard a passenger vessel unless:

(i) The vessel is operating under a change to its character of vessel certification as defined in § 171.8 of this subchapter; and

(ii) The material is permitted to be transported aboard a passenger vessel in the § 172.101 Table

of this subchapter. (h) Additional general commodity-specificrequirements. In addition to other applicable requirements, the

following requirements apply:

(1) Each uninsulated portable tank used for the transportation of a liquefied compressed gas must have an exterior surface finish that is significantly reflective, such as a light-reflecting color if painted, or a bright reflective metal or other material if unpainted.

(2) If a hazardous material is being transported in a molten state, the portable tank must be thermally

insulated with suitable insulation material of sufficient thickness that the overall thermal conductance is not more than 0.080 Btu per hour per square foot per degree Fahrenheit differential.

(3) No person may offer a liquid hazardous material of Class 3, PG I or II, or PG III with a flash point

of less than 100 °F (38 °C); Division 5.1, PG I or II; or Division 6.1, PG I or II, in an IM or UN portable tank that is equipped with a bottom outlet as authorized in Column (7) of the § 172.101 Table of this subchapter by assignment of a T Code in the appropriate proper shipping name entry, for unloading to a facility while it remains on a transport vehicle with the power unit attached unless—

(i) The tank outlets conform to § 178.275(d)(3) of this subchapter; or (ii) The facility at which the IM or UN portable tank is to be unloaded conforms to the

requirements in § 177.834(o) of this subchapter. (i) Additional requirements for portable tanks other than IM specification and UN portable tanks.

(1) The bursting strength of any piping and fittings must be at least four times the design pressure of the tank, and at least four times the pressure to which, in any instance, it may be subjected in service by the action of a pump or other device (not including safety relief valves) that may subject piping to pressures greater than the design pressure of the tank.

(2) Pipe joints must be threaded, welded or flanged. If threaded pipe is used, the pipe and pipe

fittings must not be lighter than Schedule 80 weight. Where copper tubing is permitted, joints must be brazed or be of equally strong metal union type. The melting point of brazing material may not be lower than 1,000 °F (537.8 °C). The method of joining tubing must not decrease the strength of the tubing such as by the cutting of threads.


(3) Non-malleable metals may not be used in the construction of valves or fittings. (4) Suitable provision must be made in every case to allow for expansion, contraction, jarring and

vibration of all pipe. Slip joints may not be used for this purpose. (5) Piping and fittings must be grouped in the smallest practicable space and must be protected from

damage as required by the specification. (6) All piping, valves and fittings on every portable tank must be leakage tested with gas or air after

installation and proved tight at not less than the design pressure of the portable tank on which they are used. In the event of replacement, all such piping, valves, or fittings must be tested in accordance with the requirements of this section before the portable tank is returned to transportation service. The requirements of this section apply to all hoses used on portable tanks, except that hoses may be tested either before or after installation on the portable tank.

(7) All materials used in the construction of portable tanks and their appurtenances may not be

subject to destructive attack by the contents of the portable tank. (8) No aluminum, copper, silver, zinc or their alloys may be used. Brazed joints may not be used. All

parts of a portable tank and its appurtenances used for anhydrous ammonia must be steel. (9) Each outlet of a portable tank used for the transportation of non-refrigerated liquefied compressed

gases, except carbon dioxide, must be provided with a suitable automatic excess-flow valve (see definition in § 178.337–1(g) of this subchapter). The valve must be located inside the portable tank or at a point outside the portable tank where the line enters or leaves the portable tank. The valve seat must be located inside the portable tank or may be located within a welded flange or its companion flange, or within a nozzle or within a coupling. The installation must be made in such a manner as to reasonably assure that any undue strain which causes failure requiring functioning of the valve shall cause failure in such a manner that it will not impair the operation of the valve.

(i) A safety device connection or liquid level gauging device that is constructed so that the

outward flow of the tank contents will not exceed that passed by an opening of 0.1397 cm (0.0550 inches) is not required to be equipped with excess-flow valves.

(ii) An excess-flow valve must close automatically if the flow reaches the rated flow of gas or

liquid specified by the original valve manufacturer when piping mounted directly on the valve is sheared off before the first valve, pump, or fitting downstream from the excess flow valve.

(iii) An excess-flow valve may be designed with a by-pass, not to exceed a 0.1016 cm (0.040

inches) diameter opening to allow equalization of pressure. (iv) Filling and discharge lines must be provided with manually operated shut-off valves located

as close to the tank as practical. Unless this valve is manually operable at the valve, the line must also have a manual shut-off valve. The use of “Stop-Check” valves to satisfy with one valve the requirements of this section is forbidden. For portable tanks used for refrigerated liquefied gases, a “stop check” valve may be used on the vapor side of the pressure buildup circuit.

(10) Each portable tank used for carbon dioxide or nitrous oxide must be lagged with a suitable

insulation material of such thickness that the overall thermal conductance is not more than 0.08 Btu per square foot per degree Fahrenheit differential in temperature per hour. The conductance must be determined at 60° Fahrenheit. Insulation material used on portable tanks for nitrous oxide must be noncombustible.

(11) Refrigerating or heating coils must be installed in portable tanks used for carbon dioxide and

nitrous oxide. Such coils must be tested externally to at least the same pressure as the test pressure of the portable tank. The coils must also be tested internally to at least twice the working


pressure of the heating or refrigerating system to be used, but in no case less than the test pressure of the portable tank. Such coils must be securely anchored. In the event of leakage, the refrigerant or heating medium to be circulated through the coil or coils must have no adverse chemical reaction with the portable tank or its contents.

(12) Excess flow valves are not required for portable tanks used for the transport of refrigerated

liquefied gases.

§173.33 Hazardous materials in cargo tank motor vehicles.

NOTE: Pursuant to 49 CFR 171.8 Cargo tank means a bulk packaging that: (1) Is a tank intended primarily for the carriage of liquids or gases and includes appurtenances, reinforcements, fittings, and closures (for the definition of a tank, see 49 CFR 178.320, 178.337-1, or 178.338-1, as applicable); (2) Is permanently attached to or forms a part of a motor vehicle, or is not permanently attached to a motor vehicle but which, by reason of its size, construction or attachment to a motor vehicle is loaded or unloaded without being removed from the motor vehicle; and (3) Is not fabricated under a specification for cylinders, intermediate bulk containers, multi-unit

tank car tanks, portable tanks, or tank cars. Cargo tank motor vehicle means a motor vehicle with one or more cargo tanks permanently attached to or forming an integral part of the motor vehicle.

(a) General requirements.

(1) No person may offer or accept a hazardous material for transportation in a cargo tank motor vehicle except as authorized by this subchapter.

(2) Two or more materials may not be loaded or accepted for transportation in the same cargo tank

motor vehicle if, as a result of any mixture of the materials, an unsafe condition would occur, such as an explosion, fire, excessive increase in pressure or heat, or the release of toxic vapors.

(3) No person may fill and offer for transportation a specification cargo tank motor vehicle for which

the prescribed periodic retest or reinspection under subpart E of part 180 of this subchapter is past due until the retest or inspection has been successfully completed. This requirement does not apply to a cargo tank supplied by a motor carrier who is other than the person offering the hazardous material for transportation (see § 180.407(a)(1) of this subchapter), or to any cargo tank filled prior to the retest or inspection due date.

(b) Loading requirements.

(1) A hazardous material may not be loaded in a cargo tank if during transportation any part of the tank in contact with the hazardous material lading would have a dangerous reaction with the hazardous material.

(2) A cargo tank may not be loaded with a hazardous material that will have an adverse effect on the

tank’s integrity or–

(i) May combine chemically with any residue or contaminants in the tank to produce an explosion, fire, excessive increase in pressure, release of toxic vapors or other unsafe condition.

(ii)— (iii) [Reserved] (iv) May severely corrode or react with the tank material at any concentration and temperature


that will exist during transportation. (v) Is prohibited by § 173.21 or § 173.24 of this subchapter.

(3) Air pressure in excess of ambient atmospheric pressure may not be used to load or unload any

lading which may create an air-enriched mixture within the flammability range of the lading in the vapor space of the tank.

(4) To prevent cargo tank rupture in a loading or unloading accident, the loading or unloading rate

used must be less than or equal to that indicated on the cargo tank specification plate, except as specified in § 173.318(b)(6). If no loading or unloading rate is marked on the specification plate, the loading or unloading rate and pressure used must be limited such that the pressure in the tank may not exceed 130% of the MAWP.

(c) Maximum Lading Pressure.

(1) Prior to loading and offering a cargo tank motor vehicle for transportation with material that requires the use of a specification cargo tank, the person must confirm that the cargo tank motor vehicle conforms to the specification required for the lading and that the MAWP of the cargo tank is greater than or equal to the largest pressure obtained under the following conditions:

(i) For compressed gases and certain refrigerated liquids that are not cryogenic liquids, the

pressure prescribed in § 173.315 of this subchapter. (ii) For cryogenic liquids, the pressure prescribed in § 173.318 of this subchapter. (iii) For liquid hazardous materials loaded in DOT specification cargo tanks equipped with a 1

psig normal vent, the sum of the tank static head plus 1 psig. In addition, for hazardous materials loaded in these cargo tanks, the vapor pressure of the lading at 115°F must be not greater than 1 psig, except for gasoline transported in accordance with Special Provision B33 in § 172.102(c)(3) of this subchapter.

(iv) For liquid hazardous materials not covered in paragraph (c)(1)(i), (ii), or (iii) of this section,

the sum of the vapor pressure of the lading at 115 °F, plus the tank static head exerted by the lading, plus any pressure exerted by the gas padding, including air in the ullage space or dome.

(v) The pressure prescribed in subpart B, D, E, F, G, or H of this part, as applicable. (vi) The maximum pressure in the tank during loading or unloading.

(2) Any Specification MC 300, MC 301, MC 302, MC 303, MC 305, MC 306 or MC 312, cargo tank

motor vehicle with no marked design pressure or marked with a design pressure of 3 psig or less may be used for an authorized lading where the pressure derived from § 173.33(c)(1) is less than or equal to 3 psig. After December 31, 1990, a cargo tank may not be loaded and offered for transportation unless marked or remarked with an MAWP or design pressure in accordance with 49 CFR 180.405(k).

(3) Any Specification MC 310 or MC 311 cargo tank motor vehicle may be used for an authorized

lading where the pressure derived from § 173.33(c)(1) is less than or equal to the MAWP or MWP, respectively, as marked on the specification plate.

(4) Any cargo tank marked or certified before August 31, 1995, marked with a design pressure rather

than an MAWP may be used for an authorized lading where the largest pressure derived from § 173.33(c)(1) is less than or equal to the design pressure marked on the cargo tank.

(5) Any material that meets the definition of a Division 6.1, Packing Group I or II (poisonous liquid)

material must be loaded in a cargo tank motor vehicle having a MAWP of 25 psig or greater.


(6) Substitute packagings. Unless otherwise specified, where MC 307, MC 312, DOT 407 or DOT

412 cargo tanks are authorized, minimum tank design pressure is 172.4 kPa (25 psig) for any Packing Group I or Packing Group II liquid lading that meets more than one hazard class definition.

(d) Relief system.

(1) Non-reclosing pressure relief devices are not authorized in any cargo tank except when in series

with a reclosing pressure relief device. However, a cargo tank marked or certified before August 31, 1995 which is fitted with non-reclosing pressure relief devices may continue to be used in any hazardous material service for which it is authorized. The requirements in this paragraph do not apply to MC 330, MC 331 and MC 338 cargo tanks.

(2) Each cargo tank motor vehicle used to transport a liquid hazardous material with a gas pad must

have a pressure relief system that provides the venting capacity prescribed in § 178.345-10(e) of this subchapter. The requirements in this paragraph do not apply to MC 330, MC 331 and MC 338 cargo tanks.

(3) A cargo tank motor vehicle made to a specification listed in column 1 may have pressure relief

devices or outlets conforming to the applicable specification to which the tank was constructed, or the pressure relief devices or outlets may be modified to meet the applicable requirement for the specification listed in column 2 without changing the markings on the tank specification plate. The venting capacity requirements of the original DOT cargo tank specification must be met whenever a pressure relief valve is modified.

Column 1 Column 2

MC 300, MC 301, MC 302, MC 303, MC 305. MC 306 or DOT 406.

MC 306 DOT 406

MC 304 MC307 or DOT 407

MC307 DOT 407

MC310, MC311 MC 312 or DOT 412

MC 312 DOT 412

MC 330 MC 331

(e) Retention of hazardous materials in product piping during transportation. DOT specification cargo

tanks used for the transportation of any material that is a Division 6.1 (poisonous liquid) material, oxidizer liquid, liquid organic peroxide or corrosive liquid (corrosive to skin only) may not be transported with hazardous materials lading retained in the piping, unless the cargo tank motor vehicle is equipped with bottom damage protection devices meeting the requirements of § 178.337-10 or § 178.345-8(b) of this subchapter, or the accident damage protection requirements of the specification under which it was manufactured. This requirement does not apply to a residue which remains after the piping is drained. A sacrificial device (see § 178.345-1 of this subchapter) may not be used to satisfy the accident damage protection requirements of this paragraph.

(f) An MC 331 type cargo tank may be used where MC 306, MC 307, MC 312, DOT 406, DOT 407

or DOT 412 type cargo tanks are authorized. An MC 307, MC 312, DOT 407 or DOT 412 type cargo tank may be used where MC 306 or DOT 406 type cargo tanks are authorized. A higher integrity tank used instead of a specified tank must meet the same design profile (for example, an MC 331 cargo tank must be lined if used in place of a lined MC 312 cargo tank.)


(g) Remote control of self-closing stop valves— MC 330, MC 331 and MC 338 cargo tanks. Each liquid or vapor discharge opening in an MC 330 or MC 331 cargo tank and each liquid filling and liquid discharge line in an MC 338 cargo tank must be provided with a remotely controlled internal self-closing stop valve, except when an MC 330 or MC 331 cargo tank is marked and used exclusively to transport carbon dioxide, or except when an MC 338 is used to transport argon, carbon dioxide, helium, krypton, neon, nitrogen, and xenon. However, if the cargo tank motor vehicle was certified before January 1, 1995, this requirement is applicable only when an MC 330 or MC 331 cargo tank is used to transport a flammable liquid, flammable gas, hydrogen chloride (refrigerated liquid), or anhydrous ammonia; or when an MC 338 cargo tank is used to transport flammable ladings.

(h) A cargo tank motor vehicle authorized by the Transport Canada TDG Regulations (IBR, see §

171.7 of this subchapter) may be used provided it conforms to the applicable requirements in § 171.12 of this subchapter.

§173.34 [Removed] §173.35 Hazardous materials in IBCs. (a) No person may offer or accept a hazardous material for transportation in an IBC except as authorized

by this subchapter. Each IBC used for the transportation of hazardous materials must conform to the requirements of its specification and regulations for the transportation of the particular commodity. A specification IBC, for which the prescribed periodic retest or inspection under subpart D of part 180 of this subchapter is past due, may not be filled and offered for transportation until the retest or inspection have been successfully completed. This requirement does not apply to any IBC filled prior to the retest or inspection due date.

(b) Initial use and reuse of IBCs. (Also see § 180.352 of this subchapter.) An IBC other than a multiwall

paper IBC (13M1 and 13M2) may be reused. If an inner liner is required, the inner liner must be replaced before each reuse. Before an IBC is filled and offered for transportation, the IBC and its service equipment must be given an external visual inspection, by the person filling the IBC, to ensure that:

(1) The IBC is free from corrosion, contamination, cracks, cuts, or other damage which would render

it unable to pass the prescribed design type test to which it is certified and marked; and (2) The IBC is marked in accordance with requirements in § 178.703 of this subchapter. Additional

marking allowed for each design type may be present. Required markings that are missing, damaged or difficult to read must be restored or returned to original condition.

(c) A metal IBC, or a part thereof, subject to thinning by mechanical abrasion or corrosion due to the

lading, must be protected by providing a suitable increase in thickness of material, a lining or some other suitable method of protection. Increased thickness for corrosion or abrasion protection must be added to the wall thickness specified in § 178.705(c)(1)(iv) of this subchapter.

(d) Notwithstanding requirements in § 173.24b of this subpart, when filling an IBC with liquids, sufficient

ullage must be left to ensure that, at the mean bulk temperature of 50 °C (122 °F), the IBC is not filled to more than 98 percent of its water capacity.

(e) Where two or more closure systems are fitted in series, the system nearest to the hazardous material

being carried must be closed first. (f) During transportation–

(1) No hazardous material may remain on the outside of the IBC; and (2) Each IBC must be securely fastened to or contained within the transport unit.

(g) Each IBC used for transportation of solids which may become liquid at temperatures likely to be


encountered during transportation must also be capable of containing the substance in the liquid state.

(h) Liquid hazardous materials may only be offered for transportation in a metal, rigid plastic, or

composite IBC that is appropriately resistant to an increase of internal pressure likely to develop during transportation.

(1) A rigid plastic or composite IBC may only be filled with a liquid having a vapor pressure less than

or equal to the greater of the following two values: the first value is determined from any of the methods in paragraphs (h)(1) (i), (ii) or (iii) of this section. The second value is determined by the method in paragraph (h)(1)(iv) of this section.

(i) The gauge pressure (pressure in the IBC above ambient atmospheric pressure) measured in

the IBC at 55 °C (131 °F). This gauge pressure must not exceed two-thirds of the marked test pressure and must be determined after the IBC was filled and closed at 15 °C (60 °F) to less than or equal to 98 percent of its capacity.

(ii) The absolute pressure (vapor pressure of the hazardous material plus atmospheric pressure)

in the IBC at 50 °C (122 °F). This absolute pressure must not exceed four-sevenths of the sum of the marked test pressure and 100 kPa (14.5 psia).

(iii) The absolute pressure (vapor pressure of the hazardous material plus atmospheric pressure)

in the IBC at 55 °C (131 °F). This absolute pressure must not exceed two-thirds of the sum of the marked test pressure and 100 kPa (14.5 psia).

(iv) Twice the static pressure of the substance, measured at the bottom of the IBC. This value

must not be less than twice the static pressure of water.

(2) Liquids having a vapor pressure greater than 110 kPa (16 psig) at 50 °C (122 °F) or 130 kPa (18.9 psig) at 55 °C (131 °F) may not be transported in metal IBCs.

(i) The requirements in this section do not apply to DOT–56 or -57 portable tanks. (j) No IBC may be filled with a Packing Group I liquid. Rigid plastic, composite, flexible, wooden or

fiberboard IBCs used to transport Packing Group I solid materials may not exceed 1.5 cubic meters (53 cubic feet) capacity. For Packing Group I solids, a metal IBC may not exceed 3 cubic meters (106 cubic feet) capacity.

(k) When an IBC is used for the transportation of liquids with a flash point of 60 °C (140 °F) (closed cup)

or lower, or powders with the potential for dust explosion, measures must be taken during product loading and unloading to prevent a dangerous electrostatic discharge.

(l) IBC filling limits.

(1) Except as provided in this section, an IBC may not be filled with a hazardous material in excess of the maximum gross mass marked on that container.

(2) An IBC which is tested and marked for Packing Group II liquid materials may be filled with a

Packing Group III liquid material to a gross mass not exceeding 1.5 times the maximum gross mass marked on that container, if all the performance criteria can still be met at the higher gross mass.

(3) An IBC which is tested and marked for liquid hazardous materials may be filled with a solid

hazardous material to a gross mass not exceeding the maximum gross mass marked on that container. In addition, an IBC intended for the transport of liquids which is tested and marked for Packing Group II liquid materials may be filled with a Packing Group III solid hazardous material to a gross mass not exceeding the marked maximum gross mass multiplied by 1.5 if all the performance criteria can still be met at the higher gross mass.


(4) An IBC which is tested and marked for Packing Group I solid materials may be filled with a Packing Group II solid material to a gross mass not exceeding the maximum gross mass marked on that container, multiplied by 1.5, if all the performance criteria can be met at the higher gross mass; or a Packing Group III solid material to a gross mass not exceeding the maximum gross mass marked on the IBC, multiplied by 2.25, if all the performance criteria can be met at the higher gross mass. An IBC which is tested and marked for Packing Group II solid materials may be filled with a Packing Group III solid material to a gross mass not exceeding the maximum gross mass marked on the IBC, multiplied by 1.5.

§ 173.36 Hazardous materials in Large Packagings. (a) No person may offer or accept a hazardous material for transportation in a Large Packaging except

as authorized by this subchapter. Except as otherwise provided in this subchapter, no Large Packaging may be filled with a Packing Group I or II material. Each Large Packaging used for the transportation of hazardous materials must conform to the requirements of its specification and regulations for the transportation of the particular commodity.

(b) Packaging design.

(1) Inner packaging closures. A Large Packaging containing liquid hazardous materials must be

packed so that closures on inner packagings are upright. (2) Flexible Large Packagings. Flexible Large Packagings (e.g., 51H) are only authorized for use with

flexible inner packagings. (3) Friction. The nature and thickness of the outer packaging must be such that friction during

transportation is not likely to generate an amount of heat sufficient to dangerously alter the chemical stability of the contents.

(4) Securing and cushioning. Inner packagings of Large Packagings must be packed, secured and

cushioned to prevent their breakage or leakage and to control their shifting within the outer packaging under conditions normally incident to transportation. Cushioning material must not be capable of reacting dangerously with the contents of the inner packagings or having its protective properties significantly weakened in the event of leakage.

(5) Metallic devices. Nails, staples and other metallic devices must not protrude into the interior

of the outer packaging in such a manner as to be likely to damage inner packagings or receptacles.

(c) Initial use and reuse of Large Packagings. A Large Packaging may be reused. If an inner packaging

is constructed of paper or flexible plastic, the inner packaging must be replaced before each reuse. Before a Large Packaging is filled and offered for transportation, the Large Packaging must be given an external visual inspection, by the person filling the Large Packaging, to ensure:

(1) The Large Packaging is free from corrosion, contamination, cracks, cuts, or other damage which

would render it unable to pass the prescribed design type test to which it is certified and marked; and

(2) The Large Packaging is marked in accordance with requirements in § 178.910 of this subchapter.

Additional marking allowed for each design type may be present. Required markings that are missing, damaged or difficult to read must be restored or returned to original condition.

(d) During transportation—

(1) No hazardous material may remain on the outside of the Large Packaging; and (2) Each Large Packaging must be securely fastened to or contained within the transport unit.

(e) Each Large Packaging used for transportation of solids which may become liquid at temperatures


likely to be encountered during transportation may not be transported in paper or fiber inner packagings. The inner packagings must be capable of containing the substance in the liquid state.

(f) Liquid hazardous materials may only be offered for transportation in inner packagings appropriately

resistant to an increase of internal pressure likely to develop during transportation. (g) A Large Packaging used to transport hazardous materials may not exceed 3 cubic meters (106 cubic

feet) capacity. (h) Mixed contents.

(1) An outer Large Packaging may contain more than one hazardous material only when—

(i) The inner and outer packagings used for each hazardous material conform to the relevant packaging sections of this part applicable to that hazardous material, and not result in a violation of § 173.21;

(ii) The package as prepared for shipment meets the performance tests prescribed in part 178 of

this subchapter for the hazardous materials contained in the package; (iii) Corrosive materials (except ORM–D) in bottles are further packed in securely closed inner

receptacles before packing in outer packagings; and (iv) For transportation by aircraft, the total net quantity does not exceed the lowest permitted

maximum net quantity per package as shown in Column 9a or 9b, as appropriate, of the § 172.101 table. The permitted maximum net quantity must be calculated in kilograms if a package contains both a liquid and a solid.

(2) A packaging containing inner packagings of Division 6.2 materials may not contain other

hazardous materials, except dry ice.

(i) When a Large Packaging is used for the transportation of liquids with a flash point of 60.5 °C (141 °F) (closed cup) or lower, or powders with the potential for dust explosion, measures must be taken during product loading and unloading to prevent a dangerous electrostatic discharge.

§ 173.37 Hazardous Materials in Flexible Bulk Containers. (a) No person may offer or accept a hazardous material for transportation in a Flexible Bulk Container

except as authorized by this subchapter. Each Flexible Bulk Container used for the transportation of hazardous materials must conform to the requirements of its specification and regulations for the transportation of the particular commodity.

(b) Initial use and reuse of Flexible Bulk Containers. A Flexible Bulk Container may be reused. Before a Flexible Bulk Container is filled and offered for transportation, the Flexible Bulk Container must be given an external visual inspection by the person filling the Flexible Bulk Container to ensure: (1) The Flexible Bulk Container is free from corrosion, contamination, cracks, cuts, or other damage

that would render it unable to pass the prescribed design type test to which it is certified and marked; and

(2) The Flexible Bulk Container is marked in accordance with requirements in § 178.1010 of this subchapter. Required markings that are missing, damaged or difficult to read must be restored or returned to original condition.

(3) The following components must be examined to determine structural serviceability: (i) Textile slings; (ii) Load-bearing structure straps; (iii) Body fabric; and (iv) Lock device parts including metal and textile parts are free from protrusions or damage.

(4) The use of Flexible Bulk Containers for the transport of hazardous materials is permitted for a period not to exceed two years from the date of manufacture of the Flexible Bulk Container.

(c) During transportation— (1) No hazardous material may remain on the outside of the Flexible Bulk Container; and (2) Each Flexible Bulk Container must be securely fastened to or contained within the transport unit.


(3) If restraints such as banding or straps are used, these straps must not be over-tightened to an extent that causes damage or deformation to the Flexible Bulk Container.

(4) Flexible Bulk Containers must be transported in a conveyance with rigid sides and ends that extend at least two-thirds of the height of the Flexible Bulk Container.

(5) Flexible Bulk Containers must not be stacked for highway or rail transportation. (6) Flexible Bulk Containers must not be transported in cargo transport units when offered for

transportation by vessel. (7) Flexible Bulk Containers when transported by barge must be stowed in such a way that there are

no void spaces between the Flexible Bulk Containers in the barge. If the Flexible Bulk Containers do not completely fill the barge, adequate measures must be taken to avoid shifting of cargo. The maximum permissible height of the stack of Flexible Bulk Containers must not exceed 3 containers high.

(d) A Flexible Bulk Container used to transport hazardous materials may not exceed 15 cubic meters (530 cubic feet) capacity.

§173.40 General packaging requirements for toxic materials packaged in cylinders. When this section is referenced for a Hazard Zone A or B hazardous material elsewhere in this subchapter, the requirements in this section are applicable to cylinders used for that material. (a) Authorized cylinders.

(1) A cylinder must conform to a DOT specification or UN standard prescribed in subpart C of part 178 of this subchapter, or a TC, CTC, CRC, or BTC cylinder authorized in § 171.12 of this subchapter, except that acetylene cylinders and non-refillable cylinders are not authorized. The use of UN tubes and MEGCs is prohibited for Hazard Zone A materials.

(2) The use of a specification 3AL cylinder made of aluminum alloy 6351-T6 is prohibited for a

Division 2.3 Hazard Zone A material or a Division 6.1 Hazard Zone A material. (3) A UN composite cylinder certified to ISO-11119-3 is not authorized for a Division 2.3 Hazard

Zone A or B material. (4) For UN seamless cylinders used for Hazard Zone A materials, the maximum water capacity is 85

(b) Outage and pressure requirements. For DOT specification cylinders, the pressure at 55 °C (131 °F) of

Hazard Zone A and Hazard Zone B materials may not exceed the service pressure of the cylinder. Sufficient outage must be provided so that the cylinder will not be liquid full at 55 °C (131 °F).

(c) Closures. Each cylinder containing a Hazard Zone A material must be closed with a plug or valve

conforming to the following:

(1) Each plug or valve must have a taper-threaded connection directly to the cylinder and be capable of withstanding the test pressure of the cylinder without damage or leakage. For UN pressure receptacles, each valve must be capable of withstanding the test pressure of the pressure receptacle and be connected directly to the pressure receptacle by either a taper thread or other means which meets the requirements of ISO 10692–2: (IBR, see §171.7 of this subchapter).

(2) Each valve must be of the packless type with non-perforated diaphragm, except that, for

corrosive materials, a valve may be of the packed type with an assembly made gas-tight by means of a seal cap with gasketed joint attached to the valve body or the cylinder to prevent loss of material through or past the packing.

(3) Each valve outlet must be sealed by a threaded cap or threaded solid plug and inert gasketing

material. (4) The materials of construction for the cylinder, valves, plugs, outlet caps, luting, and gaskets must

be compatible with each other and with the lading.


(d) Additional handling protection. Each cylinder or cylinder overpack combination offered for transportation containing a Division 2.3 or 6.1 Hazard Zone A or B material must conform to the valve damage protection performance requirements of this section. In addition to the requirements of this section, overpacks must conform to the overpack provisions of § 173.25.

(1) DOT specification cylinders must conform to the following:

(i) Each cylinder with a wall thickness at any point of less than 2.03 mm (0.08 inch) and each

cylinder that does not have fitted valve protection must be overpacked in a box. The box must conform to overpack provisions in § 173.25. Box and valve protection must be of sufficient strength to protect all parts of the cylinder and valve, if any, from deformation and breakage resulting from a drop of 2.0 m (7 ft) or more onto a non-yielding surface, such as concrete or steel, impacting at an orientation most likely to cause damage. "Deformation"means a cylinder or valve that is bent, distorted, mangled, misshapen, twisted, warped, or in a similar condition.

(ii) Each cylinder with a valve must be equipped with a protective metal or plastic cap, other

valve protection device, or an overpack which is sufficient to protect the valve from breakage or leakage resulting from a drop of 2.0 m (7 ft) onto a non-yielding surface, such as concrete or steel. Impact must be at an orientation most likely to cause damage.

(2) Each UN cylinder containing a Hazard Zone A or Hazard Zone B material must have a minimum test pressure in accordance with P200 of the UN Recommendations (IBR, see § 171.7 of this subchapter). For Hazard Zone A gases, the cylinder must have a minimum wall thickness of 3.5 mm if made of aluminum alloy or 2 mm if made of steel or, alternatively, cylinders may be packed in a rigid outer packaging that meets the Packing Group I performance level when tested as prepared for transport, and that is designed and constructed to protect the cylinder and valve from puncture or damage that may result in release of the gas.

(e) Interconnection. Cylinders may not be manifolded or connected. This provision does not apply to

MEGCs containing Hazard Zone B materials in accordance with § 173.312.


Exceptions for Hazardous Materials other than Class 1 and Class 7 (a portion of Subpart D) 173.150 Exceptions for Class 3 (flammable and combustible liquids). (a) General. Exceptions for hazardous materials shipments in the following paragraphs are permitted

only if this section is referenced for the specific hazardous material in the § 172.101 Table of this subchapter.

(b) Limited quantities. Limited quantities of flammable liquids (Class 3) and combustible liquids are

excepted from labeling requirements, unless the material is offered for transportation or transported by aircraft, and are excepted from the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. For transportation by aircraft, the package must also conform to applicable requirements of §173.27 of this part ( e.g., authorized materials, inner packaging quantity limits and closure securement) and only hazardous material authorized aboard passenger-carrying aircraft may be transported as a limited quantity. A limited quantity package that conforms to the provisions of this section is not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or is offered for transportation and transported by aircraft or vessel, and is eligible for the exceptions provided in §173.156 of this part. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. Except for transportation by aircraft, the following combination packagings are authorized: (1) For flammable liquids in Packing Group I, inner packagings not over 0.5 L (0.1 gallon) net

capacity each, packed in a strong outer packaging; (2) For flammable liquids in Packing Group II, inner packagings not over 1.0 L (0.3 gallons)

net capacity each, packed in a strong outer packaging. (3) For flammable liquids in Packing Group III and combustible liquids, inner packagings not

over 5.0 L (1.3 gallons) net capacity each, packed in a strong outer packaging. (c) Consumer commodities. Until December 31, 2013, a limited quantity package containing a

“consumer commodity” as defined in §171.8 of this subchapter, may be renamed “Consumer commodity” and reclassed as ORM–D or, until December 31, 2012, ORM–D–AIR material and offered for transportation and transported in accordance with the applicable provisions of this subchapter in effect on October 1, 2010.

(d) Alcoholic beverages.

(1) An alcoholic beverage (wine and distilled spirits as defined in 27 CFR 4.10 and 5.11), when transported via motor vehicle, vessel, or rail, is not subject to the requirements of this subchapter if the alcoholic beverage: (i) Contains 24 percent or less alcohol by volume; (ii) Is contained in an inner packaging of 5 L (1.3 gallons) or less; or (iii) Is a Packing Group III alcoholic beverage contained in a packaging 250 liters (66

gallons) or less; (2) An alcoholic beverage (wine and distilled spirits as defined in 27 CFR 4.10 and 5.11),

when transported via aircraft, is not subject to the requirements of this subchapter if the alcoholic beverage: (i) Contains 24 percent or less alcohol by volume; (ii) For transportation aboard a passenger-carrying aircraft, contains more than 24%

but not more than 70% alcohol by volume when in unopened retail packagings not exceeding 5 liters (1.3 gallons) carried in carry-on or checked baggage, with a total net quantity per person of 5 liters (1.3) gallons (See § 175.10(a)(4) of this subchapter); or

(iii) When carried as cargo, contains more than 24% but not more than 70% alcohol by volume in an inner packaging not exceeding 5 L (1.3 gallons).


(e) Aqueous solutions of alcohol. An aqueous solution containing 24 percent or less alcohol by

volume and no other hazardous material-

(1) May be reclassed as a combustible liquid. (2) Is not subject to the requirements of this subchapter if it contains no less than 50 percent

water. (f) Combustible liquids.

(1) A flammable liquid with a flash point at or above 38 C (100 F) that does not meet the definition of any other hazard class may be reclassed as a combustible liquid. This provision does not apply to transportation by vessel or aircraft, except where other means of transportation is impracticable.

(2) The requirements in this subchapter do not apply to a material classed as a combustible

liquid in a non-bulk packaging unless the combustible liquid is a hazardous substance, a hazardous waste, or a marine pollutant.

(3) A combustible liquid that is in a bulk packaging or a combustible liquid that is a

hazardous substance, a hazardous waste, or a marine pollutant is not subject to the requirements of this subchapter except those pertaining to:

(i) Shipping papers, waybills, switching orders, and hazardous waste manifests; (ii) Marking of packages; (iii) Display of identification numbers on bulk packages; (iv) Placarding requirements of subpart F of part 172 of this subchapter; (iv) Carriage aboard aircraft and vessels (for packaging requirements for transport by

vessel, see §176.340 of this subchapter); (vi) Reporting incidents as prescribed by §§171.15 and 171.16 of this subchapter; (vii) Packaging requirements of subpart B of this part and, in addition, non-bulk

packagings must conform with requirements of §173.203; and (viii) The requirements of § § 173.1, 173.21, 173.24, 173.24a, 173.24b, 174.1,

177.804, 177.817, 177.834(j), and 177.837(d) of this subchapter; (ix) The training requirements of subpart H of part 172 of this subchapter; (x) Emergency response information requirements of subpart G of part 172; and (xi) For bulk packagings only, registration requirements of subpart G of part 107 of

this subchapter.

(4) A combustible liquid that is not a hazardous substance, a hazardous waste, or a marine pollutant is not subject to the requirements of this subchapter if it is a mixture of one or more components that-

(i) Has a flash point at or above 93 C (200 F),

(ii) Comprises at least 99 percent of the volume of the mixture, and

(iii) Is not offered for transportation or transported as a liquid at a temperature at or

above its flash point.


(g) Limited quantities of retail products containing ethyl alcohol.

(1) Beverages, food, cosmetics and medicines, medical screening solutions, and concentrates sold as retail products containing ethyl alcohol classed as a flammable liquid or flammable solid containing not more than 70% ethyl alcohol by volume for liquids, by weight for solids are excepted from the HMR provided that: (i) For non-glass inner packagings:

(A) The volume does not exceed 16 fluid ounces in capacity for liquids; or (B) For volumes greater than 16 fluid ounces but not exceeding 1 gallon the

company name and the words “Contains Ethyl Alcohol” are marked on the package;

(C) Solids containing ethyl alcohol may be packaged in non-glass inner packagings not exceeding 1 pounds capacity;

(D) For weight greater than one pound up to 8 pounds the company name and the words “Contains Ethyl Alcohol” are marked on the package.

(ii) For glass inner packagings: (A) The volume does not exceed 8 fluid ounces in capacity; or (B) For volumes greater than 8 fluid ounces to 16 fluid ounces the company

name and the words “Contains Ethyl Alcohol” are marked on the package;

(C) Solids containing ethyl alcohol may be packaged in glass inner packagings not exceeding1/2pound;

(D) For weight greater than1/2pound up to 1 pound the company name and the words “Contains Ethyl Alcohol” are marked on the package.

(iii) The net liquid contents of all inner packagings in any single outer packaging may not exceed 192 fluid ounces. The net solid contents of all inner packagings in any single outer packaging may not exceed 32 pounds. The gross weight of any single outer package shipped may not exceed 65 pounds; Inner packagings must secured and cushioned within the outer package to prevent breakage, leakage, and movement.

(2) Beverages, food, cosmetics and medicines, medical screening solutions, and concentrates sold as retail products containing ethyl alcohol classed as a flammable liquid or flammable solid containing more than 70% ethyl alcohol by volume, by weight for solids are excepted from the HMR provided that: (i) For inner packagings containing liquids the volume does not exceed 8 fluid

ounces in capacity; (ii) Solids containing ethyl alcohol are not packed in inner packagings

exceeding1/2pound in weight; (iii) The net liquid contents of all inner packagings in any single outer packaging may

not exceed 192 fluid ounces. The net solid contents of all inner packagings in any single outer packaging may not exceed 32 pounds. The gross weight of any single outer package shipped may not exceed 65 pounds. Inner packagings must be secured and cushioned within the outer package to prevent breakage, leakage, and movement.Show citation box

(3) For transportation by passenger or cargo aircraft, no outer package may be transported which contains an inner packaging exceeding: (i) 16 fluid ounces of flammable liquid, or (ii) 1 pound of solids containing flammable liquid.

(h) Diesel fuel (NA1993) and Gasoline (UN1203) may be transported one way, by motor vehicle, directly from the loading location to an equipment repair facility, in a non-DOT specification, non-bulk packaging, known as a gasoline dispenser, that has been removed from service at a fueling station under the following conditions: (1) Prior to loading, each dispenser must be prepared for transportation by capping or

plugging all product inlet and outlet piping, so that no fluid may be released during transportation;

(2) No dispenser may contain more than 2 gallons of gasoline; and (3) Each dispenser must be blocked, braced or strapped to the motor vehicle in accordance

with the requirements of this subchapter to prevent shifting during transportation.


173.151 Exceptions for Class 4. (a) General. Exceptions for hazardous materials shipments in the following paragraphs are permitted

only if this section is referenced for the specific hazardous material in the §172.101 Table of this subchapter.

(b) Limited quantities of Division 4.1.

(1) Limited quantities of flammable solids (Division 4.1) in Packing Groups II and III and, where authorized by this section, charcoal briquettes (Division 4.2) in Packing Group III, are excepted from labeling requirements unless the material is offered for transportation or transported by aircraft, and are excepted from the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. If authorized for transportation by aircraft, the package must also conform to applicable requirements of §173.27 of this part (e.g., authorized materials, inner packaging quantity limits and closure securement) and only hazardous material authorized aboard passenger-carrying aircraft may be transported as a limited quantity. A limited quantity package that conforms to the provisions of this section is not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or is offered for transportation and transported by aircraft or vessel, and is eligible for the exceptions provided in §173.156 of this part. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. Except for transportation by aircraft, the following combination packagings are authorized: (i) For flammable solids in Packing Group II, inner packagings not over 1.0 kg (2.2 pounds)

net capacity each, packed in a strong outer packaging. (ii) For flammable solids in Packing Group III, inner packagings not over 5.0 kg (11 pounds)

net capacity each, packed in a strong outer packaging. (2) For transportation by highway or rail, Charcoal briquettes (NA1361) may be packaged as a

limited quantity in accordance with paragraph (b) of this section in packagings not exceeding 30 kg gross weight and are eligible for the exceptions provided in §173.156.

(c) Consumer commodities. Until December 31, 2013, a limited quantity package (including Charcoal briquettes (NA1361)) containing a “consumer commodity” as defined in §171.8 of this subchapter, may be renamed “Consumer commodity” and reclassed as ORM–D or, until December 31, 2012, ORM–D–AIR material and offered for transportation and transported in accordance with the applicable provisions of this subchapter in effect on October 1, 2010. For transportation by aircraft, the maximum net mass for Charcoal briquettes (NA1361) is 25 kg per package.

(d) Limited quantities of Division 4.3. Limited quantities of dangerous when wet solids (Division 4.3)

in Packing Groups II and III are excepted from labeling requirements, unless the material is offered for transportation or transported by aircraft, and are excepted from the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. For transportation by aircraft, the package must also conform to applicable requirements of §173.27 of this part ( e.g., authorized materials, inner packaging quantity limits and closure securement) and only hazardous material authorized aboard passenger-carrying aircraft may be transported as a limited quantity. A limited quantity package that conforms to the provisions of this section is not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or is offered for transportation and transported by aircraft or vessel. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. Except for transportation by aircraft, the following combination packagings are authorized: (1) For dangerous when wet solids in Packing Group II, inner packagings not over 0.5 kg

(1.1 pounds) net capacity each, packed in a strong outer packaging. (2) For dangerous when wet solids in Packing Group III, inner packagings not over 1.0 kg


(2.2 pounds) net capacity each, packed in a strong outer packaging.

(e) For transportation by motor vehicle only, Lithium (UN1415), Potassium (UN2257), and Sodium (UN1428) with a net quantity of material per inner packaging not exceeding 25 grams, are excepted from the labeling requirements of part 172, subpart E and the placarding requirements of part 172, subpart F of this subchapter, when offered for transportation in the following packagings under the following conditions: (1) Packaging.

(i) The hazardous material is placed in a tightly closed plastic bottle after being submerged in mineral oil;

(ii) The plastic bottle is placed inside a plastic bag that is securely closed to prevent leaks or punctures;

(iii) The bagged bottle is then be placed inside a metal can with all void spaces filled with an oil-absorbing material and sealed tight; and

(iv) The can is then placed into a heat sealed barrier bag. (2) Marking. Each inner plastic bottle, outer metal can, and barrier bag must be marked with:

Chemical name; quantity; and the name and address of the offeror. Each outer packaging must be marked with the proper shipping name and identification number in conformance with §172.301. Additionally, each outer packaging must be marked, “FOR TRANSPORT BY MOTOR VEHICLE ONLY.”

(3) Recordkeeping.

(i) Records of the preparation, packaging, and marking of each chemical must be documented and all components in each package must be noted; and

(ii) Records must be retained for a minimum of 5 years and be accessible at or through the shipper's principal place of business and be made available, upon request, to the Associate Administrator or designated official.

173.152 Exceptions for Division 5.1 (oxidizers) and Division 5.2 (organic peroxides). (a) General. Exceptions for hazardous materials shipments in the following paragraphs are permitted


(b) Limited quantities. Limited quantities of oxidizers (Division 5.1) in Packing Group II and III and

organic peroxides (Division 5.2) are excepted from labeling requirements, unless the material is offered for transportation or transported by aircraft, and are excepted from the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. For transportation by aircraft, the package must also conform to applicable requirements of §173.27 of this part ( e.g., authorized materials, inner packaging quantity limits and closure securement) and only hazardous material authorized aboard passenger-carrying aircraft may be transported as a limited quantity. A limited quantity package that conforms to the provisions of this section is not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or is offered for transportation and transported by aircraft or vessel, and is eligible for the exceptions provided in §173.156 of this part. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. Except for transportation by aircraft, the following combination packagings are authorized: (1) For oxidizers in Packing Group II, inner packagings not over 1.0 L (0.3 gallon) net

capacity each for liquids or not over 1.0 kg (2.2 pounds) net capacity each for solids, packed in a strong outer packaging.

(2) For oxidizers in Packing Group III, inner packagings not over 5 L (1.3 gallons) net


capacity each for liquids or not over 5.0 kg (11 lbs) net capacity each for solids, packed in a strong outer packaging.

(3) For organic peroxides that do not require temperature control during transportation— (i) Except for transportation by aircraft, for Type B or C organic peroxides, inner

packagings not over 25 mL (0.845 ounces) net capacity each for liquids or 100 g (3.528 ounces) net capacity for solids, packed in a strong outer packaging.

(ii) For Type D, E, or F organic peroxides, inner packagings not over 125 mL (4.22 ounces) net capacity each for liquids or 500 g (17.64 ounces) net capacity for solids, packed in a strong outer packaging.

(c) Consumer commodities. Until December 31, 2013, a limited quantity package containing a


173.153 Exceptions for Division 6.1 (poisonous materials). (a) General. Exceptions for hazardous materials shipments in the following paragraphs are permitted


(b) Limited quantities. The exceptions in this paragraph do not apply to poison-by-inhalation

materials. Limited quantities of poisonous material (Division 6.1) in Packing Groups II and III are excepted from the labeling requirements, unless the material is offered for transportation or transported by aircraft, and are excepted from the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. For transportation by aircraft, the package must also conform to applicable requirements of §173.27 of this part ( e.g., authorized materials, inner packaging quantity limits and closure securement) and only hazardous material authorized aboard passenger-carrying aircraft may be transported as a limited quantity. A limited quantity package that conforms to the provisions of this section is not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or is offered for transportation and transported by aircraft or vessel, and is eligible for the exceptions provided in §173.156 of this part. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. Except for transportation by aircraft, the following combination packagings are authorized: (1) For poisonous materials in Packing Group II, inner packagings not over 100 mL (3.38

ounces) each for liquids or 0.5 kg (1.1 pounds) each for solids, packed in a strong outer packaging. Inner packagings containing a liquid poisonous material which is also a drug or medicine in Packing Group II may be increased to not over 250 mL (8 ounces) each and packed in a strong outer packaging.

(2) For poisonous materials in Packing Group III, inner packagings not over 5 L (1.3 gallons) each for liquids or 5.0 kg (11 pounds) each for solids, packed in a strong outer packaging.

(c) Consumer commodities. Until December 31, 2013, a limited quantity package of poisonous

material in Packing Group III or a drug or medicine in Packing Group II and III that is also a “consumer commodity” as defined in §171.8 of this subchapter, may be renamed “Consumer commodity” and reclassed as ORM–D or, until December 31, 2012, ORM–D–AIR material and offered for transportation and transported in accordance with the applicable provisions of this subchapter in effect on October 1, 2010.

173.154 Exceptions for Class 8 (corrosive materials). (a) General. Exceptions for hazardous materials shipments in the following paragraphs are permitted

only if this section is referenced for the specific hazardous material in the §172.101 Table of this


subchapter. (b) Limited quantities. Limited quantities of corrosive material (Class 8) in Packing Groups II and III

are excepted from labeling requirements, unless the material is offered for transportation or transported by aircraft, and are excepted from the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. For transportation by aircraft, the package must also conform to the applicable requirements of §173.27 of this part ( e.g., authorized materials, inner packaging quantity limits and closure securement) and only hazardous material authorized aboard passenger-carrying aircraft may be transported as a limited quantity. A limited quantity package that conforms to the provisions of this section is not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or is offered for transportation and transported by aircraft or vessel, and is eligible for the exceptions provided in §173.156 of this part. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. Except for transportation by aircraft, the following combination packagings are authorized:

(1) For corrosive materials in Packing Group II, inner packagings not over 1.0 L (0.3 gallon)

net capacity each for liquids or not over 1.0 kg (2.2 pounds) net capacity each for solids, packed in a strong outer packaging.

(2) For corrosive materials in Packing Group III, inner packagings not over 5.0 L (1.3 gallons) net capacity each for liquids or not over 5.0 kg (11 lbs) net capacity each for solids, packed in a strong outer packaging.



(d) Materials corrosive to aluminum or steel only. Except for a hazardous substance, a hazardous

waste, or a marine pollutant, a material classed as a Class 8, Packing Group III, material solely because of its corrosive effect-

(1) On aluminum is not subject to any other requirements of this subchapter when

transported by motor vehicle or rail car in a packaging constructed of materials that will not react dangerously with or be degraded by the corrosive material; or

(2) On steel is not subject to any other requirements of this subchapter when transported by

motor vehicle or rail car in a bulk packaging constructed of materials that will not react dangerously with or be degraded by the corrosive material.

173.155 Exceptions for Class 9 (miscellaneous hazardous materials). (a) General. Exceptions for hazardous materials shipments in the following paragraphs are permitted


(b) Limited quantities of Class 9 materials. Limited quantities of miscellaneous hazardous materials

in Packing Groups II and III are excepted from labeling requirements, unless the material is offered for transportation or transported by aircraft, and are excepted from the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. Unless otherwise specified in paragraph (c) of this section, packages of limited quantities intended for transportation by aircraft must conform to the applicable requirements ( e.g., authorized materials, inner packaging quantity limits and closure securement) of §173.27 of this part. A limited quantity package that conforms to the provisions of this section is not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the


material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or is offered for transportation and transported by aircraft or vessel, and is eligible for the exceptions provided in §173.156 of this part. In addition, packages of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. Except for transportation by aircraft, the following combination packagings are authorized:

(1) For miscellaneous materials in Packing Group II, inner packagings not over 1.0 L (0.3

gallon) net capacity each for liquids or not over 1.0 kg (2.2 pounds) net capacity each for solids, packed in a strong outer packaging.

(2) For miscellaneous materials in Packing Group III, inner packagings not over 5.0 L (1.3 gallons) net capacity each for liquids or not over 5.0 kg (11 lbs) net capacity each for solids, packed in a strong outer packaging.



173.156 Exceptions for ORM materials. (a) Exceptions for hazardous materials shipments in the following paragraphs are permitted only if

this section is referenced for the specific hazardous material in the §172.101 Table or in a packaging section in this part.

(b) Packagings for limited quantity and ORM–D are specified according to hazard class in §§173.150 through 173.155 and in §173.306. In addition to other exceptions provided for limited quantity and ORM–D materials in this part:

(1) Strong outer packagings as specified in this part, marking requirements specified in

subpart D of part 172 of this subchapter, and the 30 kg (66 pounds) gross weight limitation when— (i) Unitized in cages, carts, boxes or similar overpacks; (ii) Offered for transportation or transported by:

(A) Rail; (B) Private or contract motor carrier; or (C) Common carrier in a vehicle under exclusive use for such service; and

(iii) Transported to or from a manufacturer, a distribution center, or a retail outlet, or transported to a disposal facility from one offeror.

(2) The 30 kg (66 pounds) gross weight limitation does not apply to packages of limited

quantity materials marked in accordance with §172.315 of this subchapter, or, until December 31, 2013, materials classed and marked as ORM–D and described as a Consumer commodity, as defined in §171.8 of this subchapter, when offered for transportation or transported by highway or rail between a manufacturer, a distribution center, and a retail outlet provided— (i) Inner packagings conform to the quantity limits for inner packagings specified in

§§173.150(b), 173.152(b), 173.154(b), 173.155(b) and 173.306 (a) and (b), as appropriate;

(ii) The inner packagings are packed into corrugated fiberboard trays to prevent them from moving freely;

(iii) The trays are placed in a fiberboard box which is banded and secured to a wooden pallet by metal, fabric, or plastic straps, to form a single palletized unit;

(iv) The package conforms to the general packaging requirements of subpart B of this part; andShow citation box

(v) The maximum net quantity of hazardous material permitted on one palletized unit is 250 kg (550 pounds).

(vi) The package is properly marked in accordance with §172.315 or, until December


31, 2013, §172.316 of this subchapter.

(c) Display packs. Display packs, as defined in §171.8 of this subchapter, of consumer commodity or limited quantity packages that exceed 30 kg gross weight limitation may be transported by container/trailer in trailer-on-flatcar (TOFC) or container-on-flat-car (COFC) service, roadrailer and/or railrunner trailers, motor vehicle, or cargo vessel under the following conditions: (1) Packaging. Combination packages must conform to the requirements of subpart B of this

part and meet the following, as appropriate: (i) Primary containers must conform to the quantity limits for inner packagings

prescribed in §§173.150(b), 173.152(b), 173.154(b), 173.155(b) and 173.306(a) and (b), as appropriate;

(ii) Primary containers must be packed into trays that secure individual containers from shifting inside the completed combination package during transportation;

(iii) Tray(s) must be placed into a fiberboard box, and the fiberboard box must be banded and secured to a pallet by metal, fabric, or plastic straps to form a single palletized unit; and

(iv) The maximum net quantity of hazardous material permitted in one palletized unit is 550 kg (1,210 lbs.).

(2) Marking. The outside of each package must be plainly and durably marked in accordance

with one of the following, as appropriate: (i) As a consumer commodity as prescribed in §172.316 of this subchapter; or (ii) As a limited quantity as prescribed in §172.315 of this subchapter.

(d) Exceptions for waste limited quantities and ORM-D materials. Exceptions for certain waste limited quantity and ORM-D materials are prescribed in §173.12(h).


SUBPART E NON-BULK PACKAGING FOR HAZARDOUS MATERIALS OTHER THAN CLASS 1 AND 7

173.158 Nitric acid. (a) Nitric acid exceeding 40 percent concentration may not be packaged with any other material. (b) Nitric acid in any concentration which does not contain sulfuric acid or hydrochloric acid as

impurities, when offered for transportation or transported by rail, highway, or water shall be packaged in specification containers as follows:

(1) 1A1 stainless steel drums are authorized, subject to the following limitations:

Nominal (marked) capacity (in liters) of 1A1 drum

Minimum thickness (in millimeters of stainless teel)

55 0.9

115 1.2

210 1.5

450 2.0

(i) Stainless steel used in drums must conform to the following thicknesses:

(ii) Drums weighing less than 85 percent of their original tare weight may not be

used. (iii) Type 304 or other grades of equivalent corrosion-resistant steels in the

as-welded condition are permissible for nitric acid concentrations up to and including 78 percent.

(iv) For all concentrations of nitric acid, the following are permissible:

(A) Type 304 heat-treated (quenched in water at 1040 C (1900 F)),

(B) Stabilized Type 347 in the as-welded condition,

(C) Stabilized Type 347 stress-relieved (845-900 C (1550-1650 F)),

(D) Stabilized Type 347 heat-treated (quenched in water at 1040 C (1900

F)), or

(E) Other grades of equivalent corrosion resistance.

(iv) All parts of drum exposed to lading must be capable of withstanding the corrosive effect of nitric acid to the extent that 65 percent boiling nitric acid does not penetrate the metal more than 0.0381 mm (0.002 inches) per month. (ASTM A 262 may be used for a suitable corrosion test procedure.)

(vi) In addition to marking required by §178.503 of this subchapter, the following

marks, in lettering of at least 12.7 mm (0.5 inch) height, must be placed on drums used to transport nitric acid:

(A) The type of steel used in body and head sheets as identified by

American Iron and Steel Institute type number, and, in addition, the letters ``HT'' following the steel designation on containers subject to stress relieving or heat treatment during manufacture.

(B) The thickness in millimeters of metal in thinnest part. When the thickness

of metal in the body differs from that in the head, both must be indicated


with slanting line between and with the gauge of the body indicated first.

(C) Original tare weight in kilograms, preceded by the letters ``TW.''

An example of the markings required by paragraphs (b)(1)(vi) (A), (B), and (C) of this section is ``304HT/1.9/2.7/TW55.''

(2) In combination packagings with 1A2, 1B2, 1N2, 1D, 1G, 1H2, 3H2, 4A, 4B, 4N or 4G

outer packagings with inner glass packagings of 2.5 L (0.66 gallons) or less capacity cushioned with a non-reactive, absorbent material and packed within a tightly closed intermediate packaging of metal or plastic.

(c) Nitric acid of 80 percent or greater concentration which does not contain sulfuric acid or

hydrochloric acid as impurities, when offered for transportation or transported by rail, highway, or water may be packaged in 1B1 aluminum drums.

(d) Nitric acid of 90 percent or greater concentration, when offered for transportation or transported

by rail, highway, or water may be packaged as follows:

(1) In 4C1, 4C2, 4D or 4F wooden boxes with inner packagings consisting of glass bottles further individually overpacked in tightly closed metal packagings. Glass bottles must be of 2.5 L (0.66 gallon) or less capacity and cushioned with a non-reactive, absorbent material within the metal packagings.

(2) In combination packagings with 1A2, 1B2, 1D, 1G, 1H2, 3H2 or 4G outer packagings with

inner glass packagings of 2.5 L (0.66 gallons) or less capacity cushioned with a non-reactive, absorbent material and packed within a tightly closed intermediate packaging of metal or plastic.

(e) Nitric acid of less than 90 percent concentration, when offered for transportation or transported by

rail, highway, or water may be packaged in 4A, 4B, or 4N metal boxes, 4G fiberboard boxes or 4C1, 4C2, 4D or 4F wooden boxes with inside glass packagings of not over 2.5 L (0.66 gallon) capacity each. When placed in wooden or fiberboard outer packagings, the glass inner packagings must be packed in tightly-closed, intermediate packagings, cushioned with an absorbent material. The intermediate packaging and absorbent material must be compatible with the nitric acid. See § 173.24(e).

(f) Nitric acid of 70 percent or less concentration, when offered for transportation or transported by

rail, highway, or water, may be packaged as follows:

(1) In composite packagings 6PA1, 6PA2, 6PB1, 6PB2, 6PC, 6PD1, 6PH1, or 6PH2. 6HH1 and 6HA1 composite packaging with plastic inner receptacles meeting the compatibility requirements §173.24(e) (e.g., PFA Teflon) are authorized.

(2) In 4H1 expanded plastic boxes with inner glass packagings of not over 2.5 L (0.66 gallon)

each.

(3) In combination packagings with 1A2, 1B2, 1N2, 1D, 1G, 1H2, 3H2, 4C1, 4C2, 4D, 4F, 4G, 4A, 4B or 4N outer packagings and plastic inner packagings not over 2.5 L (0.66 gallon) capacity further individually overpacked in tightly closed metal packagings.

(g) Nitric acid of more than 70 percent concentration, when offered for transportation or transported

by cargo aircraft only, must be packaged in combination packagings with 1A2, 1B2, 1N2, 1D, 1G, 1H2, 3H2, 4C1, 4C2, 4D, 4F, 4G, 4A, 4B or 4N outer packagings with glass or earthenware inner packagings of not over 1 L (0.3 gallon) or glass ampoules of not over 0.5 L (0.1 gallon).

(h) Nitric acid of less than 70 percent concentration, when offered for transportation in cargo aircraft

only must be packaged in combination packagings with 1A2, 1B2, 1N2, 1D, 1G, 1H2, 3H2, 4C1, 4C2, 4D, 4F, 4G, 4A, 4B or 4N outer packagings with inner packagings of—


(1) Glass or earthenware not over 2.5 L (0.66 gallon) capacity;

(2) Plastic not over 2.5 L (0.66 gallon) capacity further individually overpacked in tightly

closed metal packagings; or

(3) Glass ampoule not over 0.5 L (0.1 gallon) capacity. (i) Nitric acid solutions of concentrations up to 40%, nitric acid by weight when offered for transportation

or transported by rail, highway, or cargo vessel, may be packaged in a UN1H1 non-removable head plastic drum, tested and marked at the PG II performance level for liquids with a specific gravity of at least 1.8, and a hydrostatic test pressure appropriate for the hazardous material. (1) Each drum may only be used one time and must be destroyed after emptying. (2) Each drum must be permanently and legibly marked “Single Trip Only” and “Must be Destroyed

When Empty.” (j) Nitric acid solutions, other than red fuming, with more than 70% nitric acid and Nitric acid solutions,

other than red fuming, with not more than 70% nitric acid, when offered for transportation or transported by rail, highway, cargo vessel, or cargo-only aircraft may be packaged in a UN 4G outer fiberboard box meeting the Packing Group I or II performance level, as appropriate, subject to the following conditions: (1) Inner packaging: A plastic (“fluorinated ethylene-propylene” [FEP] polymers, “perfluoroalkoxy”

[PFA] polymers or similar materials) bottle with lined screw closure meeting the compatibility requirements of §173.24(e) of this section and having a net capacity not greater than 2.5 liters (0.66 gallon) each. For cargo-only aircraft, the inner packaging for PG I material may not exceed 1 L (0.3 gal) capacity. The wall thickness of the bottle must not be less than 0.020”.

(2) Intermediate packaging: (i) A tightly closed rigid-foam plastic receptacle each containing one inner packaging; or (ii) A plastic bag containing one inner packaging and placed inside a heavy-wall polypropylene

bag lined with polypropylene absorbent material of sufficient capacity to completely absorb the liquid contents of each inner package. Both bags must be tightly sealed with either plastic tape, a wire tie or a cable tie.

173.159 Batteries, wet. (a) Electric storage batteries, containing electrolyte acid or alkaline corrosive battery fluid (wet batteries),

may not be packed with other materials except as provided in paragraphs (g) and (h) of this section and in §§ 173.220 and 173.222; and any battery or battery powered device must be prepared and packaged for transport in a manner to prevent:

(1) A dangerous evolution of heat (i.e., an amount of heat sufficient to be dangerous to packaging or

personal safety to include charring of packaging, melting of packaging, scorching of packaging, or other evidence);

(2) Short circuits, including, but not limited to:

(i) Packaging each battery or each battery-powered device when practicable, in fully enclosed

inner packagings made of electrically nonconductive material; (ii) Separating or packaging batteries and battery-powered devices in a manner to prevent

contact with other batteries, devices or electrically conductive materials (e.g., metal) in the packagings; or

(iii) Ensuring exposed terminals are protected with electrically nonconductive caps, electrically nonconductive tape, or by other appropriate means; and

(3) Damage to terminals. If not impact resistant, the outer packaging must not be used as the sole

means of protecting the battery terminals from damage or short circuiting. Batteries must be securely cushioned and packed to prevent shifting which could loosen terminal caps or reorient


the terminals. Batteries contained in devices must be securely installed. Terminal protection methods include but are not limited to:

(i) Securely attaching covers of sufficient strength to protect the terminals; (ii) Packaging the battery in a rigid plastic packaging; or (iii) Constructing the battery with terminals that are recessed or otherwise protected so that the

terminals will not be subjected to damage if the package is dropped. (b) For transportation by aircraft:

(1) The packaging for wet batteries must incorporate an acid- or alkali-proof liner, or include a supplementary packaging with sufficient strength and adequately sealed to prevent leakage of electrolyte fluid in the event of spillage; and

(2) Any battery-powered device, equipment or vehicle must be packaged for transport in a manner to

prevent unintentional activation or must have an independent means of preventing unintentional activation (e.g., packaging restricts access to activation switch, switch caps or locks, recessed switches, trigger locks, temperature sensitive circuit breakers, etc.).

(c) The following specification packagings are authorized for batteries packed without other materials

provided all requirements of paragraph (a) of this section, and for transportation by aircraft, paragraph (b) of this section are met:

(1) Wooden box: 4C1, 4C2, 4D, or 4F. (2) Fiberboard box: 4G. (3) Plywood drum: 1D. (4) Fiber drum: 1G. (5) Plastic drum: 1H2. (6) Plastic jerrican: 3H2. (7) Plastic box: 4H2.

(d) The following non-specification packagings are authorized for batteries packed without other

materialsprovided all requirements of paragraph (a) of this section, and for transportation by aircraft, paragraph (b) of this section are met:

(1) Electric storage batteries are firmly secured to skids or pallets capable of withstanding the shocks

normally incident to transportation are authorized for transportation by rail, highway, or vessel. The height of the completed unit must not exceed 11⁄2 times the width of the skid or pallet. The unit must be capable of withstanding, without damage, a superimposed weight equal to two times the weight of the unit or, if the weight of the unit exceeds 907 kg (2,000 pounds), a superimposed weight of 1,814 kg (4,000 pounds). Battery terminals must not be relied upon to support any part of the superimposed weight and must not short out if an electrically conductive material is placed in direct contact with them.

(2) Electric storage batteries weighing 225 kg (500 pounds) or more, consisting of carriers’

equipment, may be shipped by rail when mounted on suitable skids. Such shipments may not be offered in interchange service.

(3) One to three batteries not over 11.3 kg (25 pounds) each, packed in strong outer boxes. The

maximum authorized gross weight is 34 kg (75 pounds). (4) Not more than four batteries not over 7 kg (15 pounds) each, packed in strong outer fiberboard or

wooden boxes. The maximum authorized gross weight is 30 kg (65 pounds). (5) Not more than five batteries not over 4.5 kg (10 pounds) each, packed in strong outer fiberboard

or wooden boxes. The maximum authorized gross weight is 30 kg (65 pounds).


(6) Single batteries not exceeding 34 kg (75 pounds) each, packed in 5-sided slip covers or in completely closed fiberboard boxes. Slip covers and boxes must be of solid or double-faced corrugated fiberboard of at least 91 kg (200 pounds) Mullen test strength. The slip cover or fiberboard box must fit snugly and provide inside top clearance of at least 1.3 cm (0.5 inch) above battery terminals and filler caps with reinforcement in place. Assembled for shipment, the bottom edges of the slipcover must come to within 2.5 cm (1 inch) of the bottom of the battery. The completed package (battery and box or slip cover) must be capable of withstanding a top-to-bottom compression test of at least 225 kg (500 pounds) without damage to battery terminal caps, cell covers or filler caps.

(7) Single batteries exceeding 34 kg (75 pounds) each may be packed in completely closed

fiberboard boxes. Boxes must be of double-wall corrugated fiberboard of at least 181 kg (400 pounds) test, or solid fiberboard testing at least 181 kg (400 pounds); a box may have hand holes in its ends provided that the hand holes will not materially weaken the box. Sides and ends of the box must have cushioning between the battery and walls of the box; combined thickness of cushioning material and walls of the box must not be less than 1.3 cm (0.5 inch); and cushioning must be excelsior pads, corrugated fiberboard, or other suitable cushioning material. The bottom of the battery must be protected by a minimum of one excelsior pad or by a double-wall corrugated fiberboard pad. The top of the battery must be protected by a wood frame, corrugated trays or scored sheets of corrugated fiberboard having minimum test of 91 kg (200 pounds), or other equally effective cushioning material. Top protection must bear evenly on connectors and/or edges of the battery cover to facilitate stacking of batteries. No more than one battery may be placed in one box. The maximum authorized gross weight is 91 kg (200 pounds).

(e) When transported by highway or rail, electric storage batteries containing electrolyte, acid, or alkaline

corrosive battery fluid and electric storage batteries packed with electrolyte, acid, or alkaline corrosive battery fluid, are not subject to any other requirements of this subchapter, if all of the following are met:

(1) No other hazardous materials may be transported in the same vehicle; (2) The batteries must be loaded or braced so as to prevent damage and short circuits in transit; (3) Any other material loaded in the same vehicle must be blocked, braced, or otherwise secured to

prevent contact with or damage to the batteries; and (4) Except for the purpose of consolidating shipments of batteries for recycling, the transport vehicle

may not carry material shipped by any person other than the shipper of the batteries; and (5) Shipments made under this paragraph are subject to the incident reporting requirements in

§171.15. (f) Batteries can be considered as nonspillable provided they are capable of withstanding the following

two tests, without leakage of battery fluid from the battery:

(1) Vibration test. The battery must be rigidly clamped to the platform of a vibration machine, and a simple harmonic motion having an amplitude of 0.8 mm (0.03 inches) with a 1.6 mm (0.063 inches) maximum total excursion must be applied. The frequency must be varied at the rate of 1 Hz/min between the limits of 10 Hz to 55 Hz. The entire range of frequencies and return must be traversed in 95 } 5 minutes for each mounting position (direction of vibrator) of the battery. The battery must be tested in three mutually perpendicular positions (to include testing with fill openings and vents, if any, in an inverted position) for equal time periods.

(2) Pressure differential test. Following the vibration test, the battery must be stored for six hours at

24 °C ± 4 °C (75°F ± 7 °F) while subjected to a pressure differential of at least 88 kPa (13 psig). The battery must be tested in three mutually perpendicular positions (to include testing with fill openings and vents, if any, in an inverted position) for at least six hours in each position.


(g) Electrolyte, acid or alkaline corrosive battery fluid, packed with batteries wet or dry, must be packed in one of the following specification packagings:

(1) In 4C1, 4C2, 4D, or 4F wooden boxes with inner receptacles of glass, not over 4.0 L (1 gallon)

each with not over 8.0 L (2 gallons) total in each outside container. Inside containers must be well-cushioned and separated from batteries by a strong solid wooden partition. The completed package must conform to Packing Group III requirements.

(2) Electrolyte, acid, or alkaline corrosive battery fluid included with electric storage batteries and

filling kits may be packed in strong rigid outer packagings when shipments are made by, for, or to the Departments of the Army, Navy, or Air Force of the United States. Packagings must conform to military specifications. The electrolyte, acid, or alkaline corrosive battery fluid must be packed in polyethylene bottles of not over 1.0 L (0.3 gallon) capacity each. Not more than 24 bottles, securely separated from electric storage batteries and kits, may be offered for transportation or transported in each package.

(3) In 4G fiberboard boxes with not more than 12 inside packagings of polyethylene or other material

resistant to the lading, each not over 2.0 L (0.5 gallon) capacity each. Completed packages must conform to Packing Group III requirements. Inner packagings must be adequately separated from the storage battery. The maximum authorized gross weight is 29 kg (64 pounds). These packages are not authorized for transportation by aircraft.

(h) (1) Dry batteries or battery charger devices may be packaged in 4G fiberboard boxes with inner

receptacles containing battery fluid. Completed packages must conform to the Packing Group III performance level. Not more than 12 inner receptacles may be packed in one outer box. The maximum authorized gross weight for the completed package is 34 kg (75 pounds).

(2) Battery fluid, acid (UN2796) may be packaged in a UN6HG2 composite packaging further packed in a UN4G fiberboard box with a dry storage battery. The UN6HG2 composite packaging may not exceed 8.0 liters in capacity. Completed packages must conform to the Packing Group III performance level. The maximum authorized gross weight for the completed package is 37.0 kg (82.0 lbs).

(i) When approved by the Associate Administrator, electric storage batteries, containing electrolyte or

corrosive battery fluid in a separate reservoir from which fluid is injected into the battery cells by a power device cartridge assembled with the battery, and which meet the criteria of paragraph (f) are not subject to any other requirements of this subchapter.

(j) Nickel cadmium batteries containing liquid potassium hydroxide solution. Nickel-cadmium batteries

that contain no more than 10 ml of liquid potassium hydroxide solution (UN1814) in each battery are not subject to the requirements of this subchapter under the following conditions: (1) Each battery must be sealed in a heat sealed bag, packaged to prevent short circuits, and placed

in the center of an outer packaging surrounded with a foam-in-place packaging material; (2) The completed package must meet the Packing Group II performance level; (3) The gross weight of the package may not exceed 15.2 kg (33.4 pounds); and (4) The cumulative amount of potassium hydroxide solution in all of the batteries in each package

may not exceed 4 ounces (0.11 kg). (k) Damaged wet electric storage batteries.

(1) Damaged batteries incapable of retaining battery fluid inside the outer casing during transportation may be transported by highway or rail provided the batteries are transported in non-bulk packaging, meet the requirements of paragraph (a) of this section, and are prepared for transport under one or more of the following conditions: (i) Drain the battery of fluid to eliminate the potential for leakage during transportation; (ii) Individually pack the battery in a leak proof intermediate package with sufficient compatible

absorbent material capable of absorbing the release of any electrolyte and place the intermediate packaging in a leakproof outer packaging that conforms to the general packaging requirements of subpart B of this part;

(iii) Pack the battery in a salvage packaging in accordance with the provisions of §173.3(c); or


(iv) When packaged with other batteries or materials (e.g., on pallets or non-skid rails) and secured to prevent movement during transport, pack the battery in leakproof packaging to prevent leakage of battery fluid from the packaging under conditions normally incident to transportation.

(2) Shipment of damage batteries in accordance with this paragraph is eligible for exception under

paragraph (e) of this section. § 173.159a Exceptions for non-spillable batteries. (a) Exceptions for hazardous materials shipments in the following paragraphs are permitted only if this

section is referenced for the specific hazardous material in the § 172.101 table or in a packaging section in this part.

(b) Non-spillable batteries offered for transportation or transported in accordance with this section are

subject to the incident reporting requirements. For transportation by aircraft, a telephone report in accordance with § 171.15(a) is required if a fire, violent rupture, explosion or dangerous evolution of heat (i.e., an amount of heat sufficient to be dangerous to packaging or personal safety to include charring of packaging, melting of packaging, scorching of packaging, or other evidence) occurs as a direct result of a non-spillable battery. For all modes of transportation, a written report in accordance with § 171.16(a) is required if a fire, violent rupture, explosion or dangerous evolution of heat occurs as a direct result of a non-spillable battery.

(c) Non-spillable batteries are excepted from the packaging requirements of § 173.159 under the

following conditions:

(1) Non-spillable batteries must be securely packed in strong outer packagings or secured to skids or pallets capable of withstanding the shocks normally incident to transportation. The batteries must meet the requirements of § 173.159(a), be loaded or braced so as to prevent damage and short circuits in transit, and any other material loaded in the same vehicle must be blocked, braced, or otherwise secured to prevent contact with or damage to the batteries. A non-spillable battery which is an integral part of and necessary for the operation of mechanical or electronic equipment must be securely fastened in the battery holder on the equipment.

(2) The battery and outer packaging must be plainly and durably marked ‘‘NONSPILLABLE’’ or

‘‘NONSPILLABLE BATTERY.’’ The requirement to mark the outer package does not apply when the battery is installed in a piece of equipment that is transported unpackaged.

(d) Non-spillable batteries are excepted from all other requirements of this subchapter when offered for

transportation and transported in accordance with paragraph (c) of this section and the following:

(1) At a temperature of 55 °C (131 °F), the battery must not contain any unabsorbed free-flowing liquid, and must be designed so that electrolyte will not flow from a ruptured or cracked case; and

(2) For transport by aircraft, when contained in a battery-powered device, equipment or vehicle must

be prepared and packaged for transport in a manner to prevent unintentional activation in conformance with § 173.159(b)(2) of this Subpart.

(3) For transport by aircraft, must be transported as cargo and may not be carried onboard an aircraft

by passengers or crewmembers in carry-on baggage, checked baggage, or on their person unless specifically excepted by § 175.10.

173.160 Bombs, smoke, non-explosive (corrosive). Bombs, smoke, non-explosive may be shipped provided they are without ignition elements, bursting charges, detonating fuses or other explosive components. They must be packaged in metal (4A, 4B, 4N), wooden (4C1, 4C2), plywood (4D), or reconstituted wood (4F), fiberboard (4G) or solid plastic (4H2) boxes, or metal (1A2, 1B2, 1N2), plastic (1H2), plywood drums (1D), or fiber (1G) drums that meet Packing Group II requirements.


173.161 Chemical kits. (a) Applicability. Chemical kits and first aid kits contain one or more compatible items of hazardous

materials in boxes, cases, etc. that, for example, are used for medical, analytical, diagnostic, testing, or repair purposes.

(b) Authorized materials. (1) The kits may only contain hazardous materials for which packaging exceptions are provided in

column 8(A) of the §172.101 Hazardous Materials Table in this subchapter. For transportation by aircraft, the kits may only contain quantities of hazardous materials authorized as excepted quantities or as limited quantities in §§173.4a and 173.27(f) of this part, respectively. Materials forbidden for transportation by passenger aircraft or cargo aircraft may not be included in the kits.

(2) The packing group assigned to the chemical kit and first aid kit as a whole must be the most stringent packing group assigned to any individual substance in the kit. The packing group must be shown on th shipping paper. Where the kit contains only hazardous materials to which no packing group is assigned, the packagings shall meet the Packing Group II performance level. Where the kit contains only hazardous materials to which no packing group is assigned, the packing group does not have to be indicated on the shipping paper.

(c) Packaging. Except for transportation by aircraft or vessel, chemical kits and first aid kits must be packaged in combination packagings conforming to the packaging requirements of subpart B of this part. For transportation by aircraft or vessel, chemical kits and first aid kits must be packaged in specification combination packagings based on the performance level of the most stringent packing group of material contained within the kit. For transportation by aircraft, friction-type closures must be secured by secondary means and inner packagings intended to contain liquids must be capable of meeting the pressure differential requirements prescribed in §173.27(c) of this subchapter. Inner and outer packaging quantity limits for packages are as follows: (1) Except for liquids of Division 5.2 (organic peroxide), inner packagings containing not

more than 250 mL. Except for transportation by aircraft, for Division 5.2 (organic peroxide) liquids of Type B and C, inner packagings containing not more than 25 mL and for Division 5.2 (organic peroxide) liquids of Type D, E and F, inner packagings containing not more than 125 mL. For transportation by aircraft, for Division 5.2 (organic peroxide) liquids of Type D, E and F (only), inner packagings containing not more than 125 mL;

(2) Except for solids of Division 5.2 (organic peroxide) of Type B and C, inner packagings containing not more than 250 g. Except for transportation by aircraft, for a Division 5.2 (organic peroxide) solid of Type B and C, inner packagings containing not more than 100 g. For transportation by aircraft, for a Division 5.2 (organic peroxide) solid of Type D, E and F (only), inner packagings containing not more than 250 g;

(3) No more than 10 L or 10 kg of hazardous material may be contained in one outer package (excluding dry ice). For transportation by aircraft, no more than 1 L or 1 kg of hazardous material may be contained in one kit (excluding dry ice);

(4) Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight;

(5) Except for Carbon dioxide, solid (Dry ice), UN1845, no other hazardous materials may be packed within the same outer packaging as the kits. Dry ice must be packaged in accordance with §173.217 of this subchapter;

(6) The kits must include sufficient absorbent material to completely absorb the contents of any liquid hazardous materials contained in the kits. The contents must be separated, placed, or packed, and closed with cushioning material to protect them from damage; and

(7) The contents of the kits must be packed so there will be no possibility of the mixture of contents causing dangerous evolution of heat or gas.

(d) Exceptions. (1)

(i) hemical kits and first aid kits are eligible for the excepted quantity exceptions provided in §§173.4 and 173.4a of this part. For transportation by aircraft, chemical kits and first aid kits are eligible for the limited quantity provisions provided in


§173.27(f) of this part. For inner packaging quantity limits, see §173.27(f), Table 3. (ii) A package conforming to the provisions of this section is not subject to the shipping

paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or is offered for transportation and transported by aircraft or vessel. Chemical kits and First aid kits conforming to this section may be marked as a limited quantity as prescribed in §172.315 of this subchapter and, if applicable, are eligible for the exceptions provided in §173.156 of this part. Additionally, chemical and first aid kits conforming to this section are not subject to part 174 (carriage by rail) or part 177 (carriage by highway) of this subchapter when marked in accordance with §172.315 of this subchapter.

(2) Consumer commodities. Until December 31, 2013, a limited quantity package

containing a “consumer commodity” as defined in §171.8 of this subchapter may be renamed “Consumer commodity” and reclassed as ORM–D or, until December 31, 2012, ORM–D–AIR material and offered for transportation and transported in accordance with the applicable provisions of this subchapter in effect on October 1, 2010.

(3) Kits that are carried on board transport vehicles for first aid or operating purposes are not subject to the requirements of this subchapter.

173.162 Gallium. (a) Except when packaged in cylinders or steel flasks, gallium must be packaged in packagings

which meet the requirements of part 178 of this subchapter at the Packing Group I performance level for transportation by aircraft, and at the Packing Group III performance level for transport by highway, rail or vessel, as follows:

(1) In combination packagings intended to contain liquids consisting of glass, earthenware or

rigid plastic inner packagings with a maximum net mass of 15 kg (33 pounds) each. The inner packagings must be packed in wood boxes (4C1, 4C2, 4D, 4F), fiberboard boxes (4G), plastic boxes (4H1, 4H2), fiber drums (1G) or steel, metal, other than steel or aluminum, and plastic drums or jerricans (1A1, 1A2, 1N1, 1N2, 1H1, 1H2, 3A2 or 3H2) with sufficient cushioning materials to prevent breakage. Either the inner packagings or the outer packagings must have an inner liner that is leakproof or bags of strong leakproof and puncture-resistant material impervious to the contents and completely surrounding the contents to prevent it from escaping from the package, irrespective of its position.

(2) In packagings intended to contain liquids consisting of semi-rigid plastic inner packagings

of not more than 2.5 kg (5.5 pounds) net capacity each, individually enclosed in a sealed, leak-tight bag of strong puncture-resistant material. The sealed bags must be packed in wooden (4C1, 4C2), plywood (4D), reconstituted wood (4F), fiberboard (4G), plastic (4H1, 4H2) or metal, other than steel or aluminum (4N) boxes or in fiber (1G), steel (1A1, 1A2), metal, other than steel or aluminum (1N1, 1N2), or plastic (1H1 or 1H2) drums, that are lined with leak-tight, puncture-resistant material. Bags and liner material must be chemically resistant to gallium.

(3) Cylinders and steel flasks with vaulted bottoms are also authorized.

(b) When it is necessary to transport gallium at low temperatures in order to maintain it in a

completely solid state, the above packagings may be overpacked in a strong, water-resistant outer packaging which contains dry ice or other means of refrigeration. If a refrigerant is used, all of the above materials used in the packaging of gallium must be chemically and physically resistant to the refrigerant and must have impact resistance at the low temperatures of the refrigerant employed. If dry ice is used, the outer packaging must permit the release of carbon dioxide gas.


(c) Manufactured articles or apparatuses, each containing not more than 100 mg (0.0035 ounce) of

gallium and packaged so that the quantity of gallium per package does not exceed 1 g (0.35 ounce) are not subject to the requirements of this subchapter. For transportation by aircraft, such articles and apparatuses must be transported as cargo and may not be carried onboard an aircraft by passengers or crewmembers in carry-on baggage, checked baggage, or on their person unless specifically excepted by § 175.10.

173.163 Hydrogen fluoride. (a) Hydrogen fluoride (hydrofluoric acid, anhydrous) must be packaged as follows:

(1) In specification 3, 3A, 3AA, 3B, 3BN, or 3E cylinders; or in specification 4B, 4BA, or 4BW cylinders except that brazed 4B, 4BA, and 4BW cylinders are not authorized. The filling density may not exceed 85 percent of the cylinder's water weight capacity. In place of the periodic volumetric expansion test, cylinders used in exclusive service may be given a complete external visual inspection in conformance with part 180, subpart C, of this subchapter, at the time such requalification becomes due.

(2) In a UN cylinder, as specified in part 178 of this subchapter, having a minimum test

pressure of 10 bar and a maximum filling ratio of 0.84. (b) A cylinder removed from hydrogen fluoride service must be condemned in accordance with

180.205 of this subchapter. Alternatively, at the direction of the owner, the requalifier may render the cylinder incapable of holding pressure.

173.164 Mercury (metallic and articles containing mercury). (a) For transportation by aircraft, mercury must be packaged in packagings which meet the

requirements of part 178 of this subchapter at the Packing Group I performance level, as follows:

(1) In inner packagings of earthenware, glass or plastic containing not more than 3.5 kg (7.7 pounds) of mercury, or inner packagings that are glass ampoules containing not more than 0.5 kg (1.1 pounds) of mercury, or iron or steel quicksilver flasks containing not more than 35 kg (77 pounds) of mercury. The inner packagings or flasks must be packed in steel drums (1A1, 1A2), metal, other than steel or aluminum drums (1N1, 1N2), steel jerricans (3A2), wooden boxes (4C1, 4C2), plywood boxes (4D), reconstituted wood boxes (4F), fiberboard boxes (4G), metal, other than steel or aluminum boxes (4N), plastic boxes (4H2), plywood drums (1D) or fiber drums (1G).

(2) [Reserved]

(3) When inner packagings of earthenware, glass or plastic are used,they must be packed in

the outer packaging with sufficient cushioning material to prevent breakage.

(4) Either the inner packagings or the outer packagings must have inner linings or bags of strong leakproof and puncture-resistant material impervious to mercury, completely surrounding the contents, so that the escape of mercury will be prevented irrespective of the position of the package.

(5) Reserved

(b) Manufactured articles or apparatuses, each containing not more than 100 mg (0.0035 ounce) of

mercury and packaged so that the quantity of mercury per package does not exceed 1 g (0.035 ounce) are not subject to the requirements of this subchapter.

(c) Manufactured articles or apparatuses containing mercury are excepted from the specification

packaging requirements of this subchapter when packaged as follows:


(1) Manufactured articles or apparatuses of which metallic mercury is a component part,

such as manometers, pumps, thermometers, switches, etc. (for electron tubes, mercury vapor tubes and similar tubes, see paragraph (c)(3) of this section), must be in strong outer packagings, having sealed inner liners or bags of strong leakproof and puncture-resistant material impervious to mercury, which will prevent the escape of mercury from the package irrespective of its position. Mercury switches and relays are excepted from these packaging requirements, if they are totally enclosed, leakproof and in sealed metal or plastic units.

(2) When transported as cargo, thermometers, switches and relays, each containing a total

quantity of not more than 15 g (0.53 ounces) of mercury, are excepted from the requirements of this subchapter if installed as an integral part of a machine or apparatus and so fitted that shock of impact damage, leading to leakage of mercury, is unlikely to occur under conditions normally incident to transport.

(3) Electron tubes, mercury vapor tubes and similar tubes must be packaged as follows:

(i) Tubes which are packed in strong outer packagings with all seams and joints

sealed with self-adhesive, pressure-sensitive tape which will prevent the escape of mercury from the package, are authorized up to a total net quantity of 450 g (15.9 ounces) of mercury per package;

(ii) Tubes with more than 450 g (15.9 ounces) of mercury are authorized only when

packed in strong outer packagings, having sealed inner liners or bags of strong leakproof and puncture-resistant material impervious to mercury which will prevent escape of mercury from the package irrespective of its position;

(iii) Tubes which do not contain more than 5 g (0.2 ounce) of mercury each and

which are packed in the manufacturer's original packagings, are authorized up to a total net quantity of 30 g (1.1 ounces) of mercury per package;

(iv) Tubes which are completely jacketed in sealed leakproof metal cases are

authorized in the manufacturer's original packagings.

(4) A person offering for transportation electron tubes, mercury vapor tubes, and similar tubes shall indicate the quantity of mercury therein on the shipping paper.

(5) Mercurial barometers conforming to paragraph (c)(1) of this section, which are loaded

and unloaded from an aircraft under the supervision of, and accompanied in flight by, a National Weather Service official or similar United States agency official, are excepted from any other requirements of this subchapter.

(d) For transportation by other than aircraft, mercury must be packaged-

(1) In any packaging which meets the requirements of part 178 of this subchapter at the Packing Group III performance level; or

(2) In non-specification reusable metal packagings.

(e) Except for a hazardous substance or a hazardous waste or for transportation by aircraft or vessel,

packages containing less than 0.45 kg (1.0 pound) net weight of mercury are not subject to the requirements of this subchapter.

(f) For vessel transport, manufactured articles or instruments containing less than 0.45 kg (1.0

pound) of mercury are not subject to the requirements of this subchapter.


173.165 Polyester resin kits

(a) Polyester resin kits consisting of a base material component (Class 3, Packing Group II or III) and

an activator component (Type D, E, or F organic peroxide that does not require temperature control)— (1) The organic peroxide component must be packed in inner packagings not over 125 mL

(4.22 fluid ounces) net capacity each for liquids or 500 g (17.64 ounces) net capacity each for solids.

(2) (i) Except for transportation by aircraft, the flammable liquid component must be packaged in suitable inner packagings.

(ii) For transportation by aircraft, a Packing Group II base material is limited to a quantity of 5 L (1.3 gallons) in metal or plastic inner packagings and 1 L (0.3 gallons) in glass inner packagings. A Packing Group III base material is limited to a quantity of 10 L (2.6 gallons) in metal or plastic inner packagings and 2.5 L (0.66 gallons) in glass inner packagings.

(3) If the flammable liquid component and the organic peroxide component will not interact dangerously in the event of leakage, they may be packed in the same outer packaging.

(4) The Packing Group assigned will be II or III, according to the criteria for Class 3, applied to the base material. Additionally, polyester resin kits must be packaged in specification combination packagings, based on the performance level required of the base material (II or III) contained within the kit, as prescribed in §§173.202 or 173.203 of this subchapter, as appropriate.

(5) For transportation by aircraft, the following additional requirements apply: (i) Closures on inner packagings containing liquids must be secured by secondary

means; (ii) Inner packagings containing liquids must be capable of meeting the pressure

differential requirements prescribed in §173.27(c); and (iii) The total quantity of activator and base material may not exceed 5 kg (11 lbs) per

package for a Packing Group II base material. The total quantity of activator and base material may not exceed 10 kg (22 lbs) per package for a Packing Group III base material. The total quantity of polyester resin kits per package is calculated on a one-to-one basis (i.e., 1 L equals 1 kg).

(b) Polyester resin kits are eligible for the Small Quantity exceptions in §173.4 and the Excepted Quantity exceptions in §173.4a, as applicable.

(c) Limited quantities. Limited quantity packages of polyester resin kits are excepted from labeling requirements, unless the material is offered for transportation or transported by aircraft, and are excepted from the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. For transportation by aircraft, only hazardous material authorized aboard passenger-carrying aircraft may be transported as a limited quantity. A limited quantity package that conforms to the provisions of this section is not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or is offered for transportation and transported by aircraft or vessel, and is eligible for the exceptions provided in §173.156 of this part. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the general packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight.

(1) For other than transportation by aircraft, the organic peroxide component must be packed in inner packagings not over 125 mL (4.22 fluid ounces) net capacity each for liquids or 500 g (17.64 ounces) net capacity each for solids. For transportation by aircraft, the organic peroxide component must be packed in inner packagings not over 30 mL (4.22 fluid ounces) net capacity each for liquids or 100 g (17.64 ounces) net capacity each for solids.

(2) Except for transportation by aircraft, the flammable liquid component must be packed in inner packagings not over 5 L (1.3 gallons) net capacity each for a Packing Group II and Packing Group III liquid. For transportation by aircraft, the flammable liquid component must be packed in inner packagings not over 1 L (0.26 gallons) net capacity each for a Packing Group II material. The flammable liquid component must be packed in metal or plastic inner packagings not over 5.0 L (1.3 gallons) net capacity each or glass inner


packagings not over 2.5 L (0.66 gallons) net capacity each for a Packing Group III material.

(3) If the flammable liquid component and the organic peroxide component will not interact dangerously in the event of leakage, they may be packed in the same outer packaging.

(4) For transportation by aircraft, the following additional requirements apply: (i) Closures on inner packagings containing liquids must be secured by secondary

means as prescribed in §173.27(d); (ii) Inner packagings containing liquids must be capable of meeting the pressure

differential requirements prescribed in §173.27(c); (iii) The total quantity of activator and base material may not exceed 1 kg (2.2 lbs) per

package for a Packing Group II base material. The total quantity of activator and base material may not exceed 5 kg (11 lbs) per package for a Packing Group III base material. The total quantity of polyester resin kits per package is calculated on a one-to-one basis (i.e., 1 L equals 1 kg);

(iv) Drop test capability. Fragile inner packagings must be packaged to prevent failure under conditions normally incident to transport. Packages of consumer commodities must be capable of withstanding a 1.2 m drop on solid concrete in the position most likely to cause damage; and

(v) Stack test capability. Packages of consumer commodities must be capable of withstanding, without failure or leakage of any inner packaging and without any significant reduction in effectiveness, a force applied to the top surface for a duration of 24 hours equivalent to the total weight of identical packages if stacked to a height of 3.0 m (including the test sample).

(d) Consumer commodities. Until December 31, 2020, a limited quantity package of polyester resin kits that are also consumer commodities as defined in §171.8 of this subchapter may be renamed “Consumer commodity” and reclassed as ORM-D or, until December 31, 2012, as ORM-D-AIR material and offered for transportation and transported in accordance with the applicable provisions of this subchapter in effect on October 1, 2010.

173.166 Safety devices. For the purpose of this section, safety devices are articles which contain pyrotechnic substances or hazardous materials of other classes and are used in vehicles, vessels or aircraft to enhance safety to persons. Examples are: air bag inflators, air bag modules, seat-belt pretensioners and pyromechanical devices. Pyromechanical devices are assembled components for tasks such as but not limited to separation, locking, release-and-drive or occupant restraint. The term includes “Safety devices, pyrotechnic.” (a) Definitions. An air bag inflator (consisting of a casing containing an igniter, a booster material, a gas

generant and, in some cases, a pressure receptacle (cylinder)) is a gas generator used to inflate an air bag in a supplemental restraint system in a motor vehicle. An air bag module is the air bag inflator plus an inflatable bag assembly. A seat-belt pretensioner contains similar hazardous materials and is used in the operation of a seat-belt restraining system in a motor vehicle.

(b) Classification. (1) Safety devices, excluding those which contain flammable or toxic gases or mixtures thereof, may be classed as Class 9 (UN3268) if the safety device, or if more than a single safety device is involved then the representative of the maximum parameters of each design type, is examined and successfully tested by a person or agency who is authorized by the Associate Administrator to perform examination and testing of explosives under §173.56(b)(1), and who: (i) Does not manufacture or market explosives or safety devices, is not owned in whole or in part, or

is not financially dependent upon any entity that manufactures or markets explosives or safety devices;

(ii) Performs all examination and testing in accordance with the applicable requirements as specified in special provision 160 (see §172.102 of this subchapter); and

(iii) Maintains records in accordance with paragraph (g) of this section. (iv) By adhering to all the provisions specified in paragraph (b)(1) of this section, a Class 9 (UN3268)

air bag inflator, air bag module or seat-belt pretensioner design is not required to be submitted to the Associate Administrator for approval or assigned an EX number. All other Class 9 (UN3268) safety device designs are required to be submitted to the Associate Administrator for approval and assigned an EX number; (2) A safety device may be classed as Division 1.4G if the maximum parameters of each design


type have been examined and successfully tested by a person or agency who is authorized by the Associate Administrator to perform such examination and testing of explosives under §173.56(b)(1). As a Class 1 explosive, the manufacturer must submit to the Associate Administrator a report of the examination and assignment of a recommended shipping description, division, and compatibility group, and if the Associate Administrator finds the approval request meets the regulatory criteria, the explosive may be approved in writing and assigned an EX number; or

(3) The manufacturer has submitted an application, including a classification issued by the competent authority of a foreign government to the Associate Administrator, and received written notification from the Associate Administrator that the device has been approved for transportation and assigned an EX number.

(c) EX numbers.

(1) When a safety device is classed and approved as a Division 1.4G and offered for transportation, the shipping paper must contain the EX number or product code for each approved device in association with the basic description required by §172.202(a) of this subchapter. Product codes must be traceable to the specific EX number assigned to the device by the Associate Administrator. Further, if the EX number or product code is contained on the shipping paper then it is not required to be marked on the outside package.

(2) A safety device, when classed as a Class 9 (UN3268), is excepted from the EX number, or product code shipping paper requirements of paragraph (c) of this section.

(d) Exceptions. (1) A safety device that is classed as a Class 9 (UN3268) under the terms of paragraph (b)(1) of this

section and is installed in a motor vehicle, aircraft, boat or other transport conveyance or its completed components, such as steering columns or door panels, is not subject to the requirements of this subchapter. A safety device that has been classed as a Division 1.4G and approved by the Associate Administrator and is installed in a motor vehicle, aircraft, boat or other transport conveyance or its completed components, such as steering columns or door panels, is not subject to the requirements of this subchapter.

(2) An air bag module containing an inflator that has been previously approved by the Associate Administrator for transportation is not required to be submitted for further examination or approval. For classifications granted after July 30, 2013, if the Class 9 designation for the inflator is contingent upon packaging or other special means specified by the authorized testing agency, the modules must be tested and certified separately to determine if they can be shipped as “UN3268, Safety Devices, 9, PG III”.

(3) An air bag module containing an inflator that has previously been approved by the Associate Administrator as a Division 2.2 material is not required to be submitted for further examination to be reclassed as a Class 9 material.

(4) Shipments to recycling or waste disposal facilities. When offered for domestic transportation by highway, rail freight, cargo vessel or cargo aircraft, a serviceable safety device classed as either Class 9 (UN3268) or Division 1.4G removed from a motor vehicle that was manufactured as required for use in the United States may be offered for transportation and transported without compliance with the shipping paper requirement prescribed in paragraph (c) of this section. However, when these articles are shipped to a recycling facility, the word “Recycled” must be entered on the shipping paper immediately after the basic description prescribed in §172.202 of this subchapter. No more than one device is authorized in the packaging prescribed in paragraph (e)(1), (2) or (3) of this section. The device must be cushioned and secured within the package to prevent movement during transportation.

(5) An air bag inflator, air bag module, or seat-belt pretensioner that was classed and approved for transportation prior to January 1, 2015 may continue to be transported under the terms of the existing approval, using the appropriate proper shipping name “Safety Devices” or “Safety Devices, Pyrotechnic” based on the classification of the device as assigned by PHMSA or the authorized person or agency that examined and tested the design type.

(6) Until January 1, 2016, for domestic transportation by highway, rail, and vessel, packages containing air bag inflators, air bag modules, or seat-belt pretensioners may be; (i) Marked with either the appropriate proper shipping name, or an appropriate proper shipping

name authorized by §172.101 in effect on December 31, 2014; and (ii) Described on a shipping paper with either the appropriate proper shipping name, or an

appropriate proper shipping name authorized by §172.101 in effect on December 31, 2014.


(e) Packagings. Rigid, outer packagings, meeting the general packaging requirements of part 173 are authorized as follows. Additionally, the UN specification packagings listed in paragraphs (e)(1), (2), and (3) of this section must meet the packaging specification and performance requirements of part 178 of this subchapter at the Packing Group III performance level. The packagings must be designed and constructed to prevent movement of the articles and inadvertent activation. Further, if the Class 9 designation is contingent upon packaging specified by the authorized testing agency, shipments of the safety device must be in compliance with the prescribed packaging. (1) 1A2, 1B2, 1N2, 1D, 1G, or 1H2 drums. (2) 3A2, 3B2, or 3H2 jerricans. (3) 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, or 4H2 boxes. (4) Reusable high-strength containers or dedicated handling devices.

(i) Reusable containers manufactured from high-strength plastic, metal, or other suitable material, or other dedicated handling devices are authorized for shipment of safety devices from a manufacturing facility to the assembly facility, subject to the following conditions: (A) The gross weight of the containers or handling devices may not exceed 1000 kg (2205

pounds). Containers or handling devices must provide adequate support to allow stacking at least three units high with no resultant damage;

(B) If not completely enclosed by design, the container or handling device must be covered with plastic, fiberboard, metal, or other suitable material. The covering must be secured to the container by banding or other comparable methods; and

(C) Internal dunnage must be sufficient to prevent movement of the devices within the container.

(ii) Reusable containers manufactured from high-strength plastic, metal, or other suitable material, or other dedicated handling devices are authorized for shipment of safety devices only to, between, and from, intermediate handling locations, provided they meet the conditions specified in paragraphs (e)(4)(i)(A) through (C) of this section and: (A) The packages may be opened and re-packed by an intermediate handler as long as no

modifications or changes are made to the packagings; and (B) Transportation must be made by private or contract carrier.

(5) Packagings which were previously authorized in an approval issued by the Associate Administrator may continue to be used, provided a copy of the approval is maintained while such packaging is being used.

(6) Safety devices removed from a vehicle. When removed from, or were intended to be used in, a motor vehicle that was manufactured as required for use in the United States and offered for domestic transportation by highway or cargo vessel to Recycling or Waste Disposal facilities, a serviceable safety device classed as Class 9 UN3268 may be offered for transportation and transported in the following additional packaging: (i) Specification and non-specification steel drums with a wall and lid thickness not less than 20

gauge. The lid must be securely affixed with a lever-locking or bolted-ring assembly. The lid of the drum must provide ventilation of the drum contents in a fire. The drum may be filled with any combination of safety devices to a capacity not greater than fifty (50) percent of the drum's total volume. In addition, inner packagings or cushioning may not be used to fill the void space; or

(ii) Outer packaging consisting of 4H2 solid plastic boxes or non-specification rugged reusable plastic outer packaging and inner static-resistant plastic bags or trays. If not completely enclosed by design, the container or handling device must be covered with plastic, fiberboard, metal or other suitable material. The covering must be secured to the container by banding or other comparable methods. The articles must be packed to prevent movement within the container during transportation.

(f) Labeling. Notwithstanding the provisions of §172.402, each package or handling device must display a CLASS 9 label. Additional labeling is not required when the package contains no hazardous materials other than the devices.

(g) Recordkeeping requirements. (1) Following the examination of each new design type classed as a Class 9 in accordance with

paragraph (b)(1) of this section, the person that conducted the examination must prepare a test report and provide the test report to the manufacturer of the safety device. At a minimum, the test report must contain the following information: (i) Name and address of the test facility; (ii) Name and address of the applicant;


(iii) Manufacturer of the device. For a foreign manufacturer, the U.S. agent or importer must be identified;

(iv) A test report number, drawing of the device, and description of the safety device in sufficient detail to ensure that the test report is traceable (e.g. a unique product identifier) to a specific design;

(v) The tests conducted and the results; and (vi) A certification that the safety device is classed as a Class 9 (UN3268).

(2) For at least fifteen (15) years after testing, a copy of each test report must be maintained by the authorizing testing agency. For as long as any safety device design is being manufactured, and for at least fifteen (15) years thereafter, a copy of each test report must be maintained by the manufacturer of the product.

(3) Test reports must be made available to a representative of the Department upon request. 173.167 Consumer commodities. (a) Effective January 1, 2013, a “consumer commodity” (see §171.8 of this subchapter) when offered for

transportation by aircraft may only include articles or substances of Class 2 (non-toxic aerosols only), Class 3 (Packing Group II and III only), Division 6.1 (Packing Group III only), UN3077, UN3082, UN3175, UN3334, and UN3335, provided such materials do not have a subsidiary risk and are authorized aboard a passenger-carrying aircraft. Consumer commodities are excepted from the specification outer packaging requirements of this subchapter. Packages prepared under the requirements of this section are excepted from labeling and shipping papers when transported by highway or rail. Except as indicated in §173.24(i), each completed package must conform to §§173.24 and 173.24a of this subchapter. Additionally, except for the pressure differential requirements in §173.27(c), the requirements of §173.27 do not apply to packages prepared in accordance with this section. Packages prepared under the requirements of this section may be offered for transportation and transported by all modes. As applicable, the following apply: (1) Inner and outer packaging quantity limits.

(i) Non-toxic aerosols, as defined in §171.8 of this subchapter and constructed in accordance with §173.306 of this part, in non-refillable, non-metal containers not exceeding 120 mL (4 fluid ounces) each, or in non-refillable metal containers not exceeding 820 mL (28 ounces) each, except that flammable aerosols may not exceed 500 mL (16.9 ounces) each;

(ii) Liquids, in inner packagings not exceeding 500 mL (16.9 ounces) each. Liquids must not completely fill an inner packaging at 55 °C;

(iii) Solids, in inner packagings not exceeding 500 g (1.0 pounds) each; or (iv) Any combination thereof not to exceed 30 kg (66 pounds) gross weight as prepared for

shipment. (2) Closures. Friction-type closures must be secured by positive means. The body and closure of any

packaging must be constructed so as to be able to adequately resist the effects of temperature and vibration occurring in conditions normally incident to air transportation. The closure device must be so designed that it is unlikely that it can be incorrectly or incompletely closed.

(3) Absorbent material. Inner packagings must be tightly packaged in strong outer packagings. Absorbent and cushioning material must not react dangerously with the contents of inner packagings. Glass or earthenware inner packagings containing liquids of Class 3 or Division 6.1, sufficient absorbent material must be provided to absorb the entire contents of the largest inner packaging contained in the outer packaging. Absorbent material is not required if the glass or earthenware inner packagings are sufficiently protected as packaged for transport that it is unlikely a failure would occur and, if a failure did occur, that it would be unlikely that the contents would leak from the outer packaging.

(4) Drop test capability. Breakable inner packagings (e.g., glass, earthenware, or brittle plastic) must be packaged to prevent failure under conditions normally incident to transport. Packages of consumer commodities as prepared for transport must be capable of withstanding a 1.2 m drop on solid concrete in the position most likely to cause damage. In order to pass the test, the outer packaging must not exhibit any damage liable to affect safety during transport and there must be no leakage from the inner packaging(s).

(5) Stack test capability. Packages of consumer commodities must be capable of withstanding, without failure or leakage of any inner packaging and without any significant reduction in effectiveness, a force applied to the top surface for a duration of 24 hours equivalent to the total


weight of identical packages if stacked to a height of 3.0 m (including the test sample). (b) When offered for transportation by aircraft:

(1) Packages prepared under the requirements of this section are to be marked as a limited quantity in accordance with §172.315(b)(1) and labeled as a Class 9 article or substance, as appropriate, in accordance with subpart E of part 172 of this subchapter; and

(2) Pressure differential capability: Except for UN3082, inner packagings intended to contain liquids must be capable of meeting the pressure differential requirements (75 kPa) prescribed in §173.27(c) of this part. The capability of a packaging to withstand an internal pressure without leakage that produces the specified pressure differential should be determined by successfully testing design samples or prototypes.

49 CFR 173.168 Oxygen Generators An oxygen generator, chemical (defined in § 171.8 of this subchapter) may be transported only under the following conditions: (a) Approval. A chemical oxygen generator that is shipped with an explosive or non-explosive means

of initiation attached must be classed and approved by the Associate Administrator in accordance with the procedures specified in § 173.56 of this subchapter.

(b) Impact resistance. A chemical oxygen generator, without any packaging, must be capable of

withstanding a 1.8 meter drop onto a rigid, non-resilient, flat and horizontal surface, in the position most likely to cause actuation or loss of contents.

(c) Protection against inadvertent actuation. A chemical oxygen generator must incorporate one of

the following means of preventing inadvertent actuation:

(1) A chemical oxygen generator that is not installed in protective breathing equipment (PBE):

(i) Mechanically actuated devices:

(A) Two pins, installed so that each is independently capable of preventing

the actuator from striking the primer; (B) One pin and one retaining ring, each installed so that each is

independently capable of preventing the actuator from striking the primer; or

(C) A cover securely installed over the primer and a pin installed so as to

prevent the actuator from striking the primer and cover.

(ii) Electrically actuated devices: The electrical leads must be mechanically shorted and the mechanical short must be shielded in metal foil.

(iii) Devices with a primer but no actuator: A chemical oxygen generator that has a

primer but no actuating mechanism must have a protective cover over the primer to prevent actuation from external impact.

(2) A chemical oxygen generator installed in a PBE must contain a pin installed so as to

prevent the actuator from striking the primer, and be placed in a protective bag, pouch, case or cover such that the protective breathing equipment is fully enclosed in such a manner that the protective bag, pouch, case or cover prevents unintentional actuation of the oxygen generator.

(d) Packaging. A chemical oxygen generator and a chemical oxygen generator installed in

equipment, (e.g., a PBE) must be placed in a rigid outer packaging that-

(1) Conforms to the requirements of either:


(i) Part 178, subparts L and M, of this subchapter at the Packing Group I or II

performance level; or (ii) The performance criteria in Air Transport Association (ATA) Specification No.

300 for a Category I Shipping Container.

(2) With its contents, is capable of meeting the following additional requirements when transported by cargo-only aircraft:

(i) The Flame Penetration Resistance Test specified in Appendix E to part 178 of

this subchapter; (ii) The Thermal Resistance Test specified in Appendix D to part 178 of this

subchapter.

(e) Equipment marking. The outside surface of a chemical oxygen generator must be marked to indicate the presence of an oxygen generator (e.g., "oxygen generator, chemical"). The outside surface of equipment containing a chemical oxygen generator that is not readily apparent (e.g., a sealed passenger service unit) must be clearly marked to indicate the presence of the oxygen generator (example: "Oxygen Generator Inside").

(f) Items forbidden in air transportation.

(1) A chemical oxygen generator is forbidden for transportation on board a passenger-carrying aircraft.

(2) A chemical oxygen generator is forbidden for transportation by both passenger-carrying and

cargo-only aircraft after:

(i) The manufacturer's expiration date; or (ii) he contents of the generator have been expended.

(g) Exceptions. An unapproved chemical oxygen generator with only one positive means of preventing

unintentional actuation of the generator, and without the required approval number marked on the outside of the package, may be transported by motor vehicle, railcar, and cargo vessel only under the following conditions: (1) Packaging.

(i) The one positive means of preventing unintentional actuation of the generator shall be installed in such a manner that the percussion primer is so completely protected from its firing pin that it cannot be physically actuated or the electric firing circuit is so completely isolated from the electric match that it cannot be electrically actuated.

(ii) Inner packaging. Except as provided in paragraph (g)(1)(iii) of this section below, an unapproved chemical oxygen generator, or unapproved chemical oxygen generator installed in smaller size equipment such as a PBE shall be packaged in a combination packaging consisting of a non-combustible inner packaging that fully encloses the chemical oxygen generator or piece of equipment inside an outer packaging which meets the requirements in paragraph (d)(1) of this section.

(iii) Impractical size packaging. If the piece of equipment in which the unapproved chemical oxygen generator is installed is so large (e.g., an aircraft seat) as to not be practically able to be fully enclosed in the packaging prescribed in paragraph (g)(1)(ii) of this section, then a visible and durable warning tag must be securely attached to the piece of equipment stating “THIS ITEM CONTAINS A CHEMICAL OXYGEN GENERATOR.”

(2) Testing. Each unapproved chemical oxygen generator, without its packaging, must be capable of

withstanding a 1.8 meter drop onto a rigid, non-resilient, flat and horizontal surface, in the position most likely to cause damage, with no actuation or loss of contents.


(3) Marking. (i) If the unapproved chemical oxygen generator is inside a piece of equipment which is sealed

or difficult to determine if an oxygen generator is present, for example—a closed sealed passenger service unit, then a visible and durable warning sign must be attached to the piece of equipment stating: “THIS ITEM CONTAINS A CHEMICAL OXYGEN GENERATOR”; and (ii) Each outer package, and overpack if used, must be visibly and durably marked with the

following statement: “THIS PACKAGE IS NOT AUTHORIZED FOR TRANSPORTATION ABOARD AIRCRAFT”.

173.170 Black powder for small arms. Black powder for small arms that has been classed in Division 1.1 may be reclassed as a Division 4.1 material, for domestic transportation by motor vehicle, rail freight, and cargo vessel only, subject to the following conditions: (a) The powder must be examined and approved for Division 1.1 and Division 4.1 classification in

accordance with §§173.56 and 173.58; (b) The total quantity of black powder in one transport vehicle or freight container may not exceed

45.4 kg (100 pounds) net mass. No more than four freight containers may be on board one cargo vessel;

(c) The black powder must be packed in inner metal or heavy wall conductive plastic receptacles not

over 454 g (16 ounces) net capacity each, with no more than 25 cans in one outer UN 4G fiberboard box. The inner packagings must be arranged and protected so as to prevent simultaneous ignition of the contents. The complete package must be of the same type which has been examined as required in §173.56;

(d) Each completed package must be marked ``BLACK POWDER FOR SMALL ARMS'' and ``NA

0027''; and (e) Each package must bear the FLAMMABLE SOLID label. 173.171 Smokeless powder for small arms. Smokeless powder for small arms which has been classed in Division 1.3 or Division 1.4 may be reclassed in Division 4.1, for domestic transportation by motor vehicle, rail car, vessel, or cargo-only aircraft, subject to the following conditions: (a) Powders that have been approved as Division 1.3C or Division 1.4C may be reclassed to Division

4.1 in accordance with §§173.56 and 173.58 of this part. (b) The total quantity of smokeless powder may not exceed 45.4 kg (100 pounds) net mass in:

(1) One transport vehicle or cargo only aircraft; or

(2) One freight container on a vessel, not to exceed four freight containers per vessel. (c) Only combination packagings with inner packagings not exceeding 3.6 kg (8 pounds) net mass

are authorized. Inner packagings must be arranged and protected so as to prevent simultaneous ignition of the contents. The complete package must be of the same type which has been examined as required in §173.56 of this part.

(d) Inside packages that have been examined and approved by the Associate Administrator may be

packaged in UN 4G fiberboard boxes meeting the Packing Group I performance level, provided all inside containers are packed to prevent shifting and the net weight of smokeless powder in any one box does not exceed 7.3 kg (16 pounds).


173.172 Aircraft hydraulic power unit fuel tank. Aircraft hydraulic power unit fuel tanks containing a mixture of anhydrous hydrazine and monomethyl hydrazine (M86 fuel) and designed for installation as complete units in aircraft are excepted from the specification packaging requirements of this subchapter when they conform to either of the following conditions: (a) The unit must consist of an aluminum pressure vessel made from tubing and having welded

heads. Primary containment of the fuel within this vessel must consist of a welded aluminum bladder having a maximum internal volume of 46 L (12 gallons). The outer vessel must have a minimum design gauge pressure of 1.275 kPa (185 psig) and a minimum burst gauge pressure of 2,755 kPa (400 psig). Each vessel must be leak-checked during manufacture and before shipment and must be found leakproof. The complete inner unit must be securely packed in non-combustible cushioning material, such as vermiculite, in a strong outer tightly closed metal packaging which will adequately protect all fittings. Maximum quantity of fuel per unit and package is 42 L (11 gallons); or

(b) The unit must consist of an aluminum pressure vessel. Primary containment of the fuel within this

vessel must consist of a welded hermetically sealed fuel compartment with an elastomeric bladder having a maximum internal volume of 46 L (12 gallons). The pressure vessel must have a minimum design gauge pressure of 5,170 kPa (750 psig). Each vessel must be leak-checked during manufacture and before shipment and must be securely packed in non-combustible cushioning material, such as vermiculite, in a strong outer tightly closed metal packaging which will adequately protect all fittings. Maximum quantity of fuel per unit and package is 42 L (11 gallons).

173.173 Paint, paint-related material, adhesives, ink and resins. (a) When the §172.101 Table specifies that a hazardous material be packaged under this section,

the following requirements apply. Except as otherwise provided in this part, the description ``Paint'' is the proper shipping name for paint, lacquer, enamel, stain, shellac, varnish, liquid aluminum, liquid bronze, liquid gold, liquid wood filler, and liquid lacquer base. The description ``Paint-related material'' is the proper shipping name for a paint thinning, drying, reducing or removing compound. However, if a more specific description is listed in the §172.101 Table of this subchapter, that description must be used.

(b) Paint, paint-related material, adhesives, ink and resins must be packaged as follows:

(1) As prescribed in §173.202 of this part if it is a Packing Group II material or §173.203 of this part if it is a Packing Group III material; or

(2) In inner glass packagings of not over 1 L (0.3 gallon) capacity each or inner metal

packagings of not over 5 L (1 gallon) each, packed in a strong outer packaging. Packages must conform to the packaging requirements of subpart B of this part but need not conform to the requirements of part 178 of this subchapter.

173.174 Refrigerating machines. A refrigerating machine assembled for shipment and containing 7 kg (15 pounds) or less of a flammable liquid for its operation in a strong, tight receptacle is excepted from labeling (except when offered for transportation or transported by air) and the specification packaging requirements of this subchapter. In addition. shipments are not subject to subpart F of part 172 of this subchapter (Placarding), to part 174 of this subchapter (Carriage by rail) except §174.24 (Shipping papers) and to part 177 (Carriage by highway) of this subchapter except §177.817 (Shipping papers). § 173.175 Permeation devices. Permeation devices that contain hazardous materials and that are used for calibrating air quality monitoring devices are not subject to the requirements of this subchapter provided the following


requirements are met: (a) Each device must be constructed of a material compatible with the hazardous materials it contains; (b) The total contents of hazardous materials in each device is limited to 2 ml (0.07 ounces) and the

device must not be liquid full at 55 °C (131 °F); (c) Each permeation device must be placed in a sealed, high impact resistant, tubular inner packaging of

plastic or equivalent material. Sufficient absorbent material must be contained in the inner packaging to completely absorb the contents of the device. The closure of the inner packaging must be securely held in place with wire, tape or other positive means;

(d) Each inner packaging must be contained in a secondary packaging constructed of metal, or plastic

having a minimum thickness of 1.5 mm (0.06 inches). The secondary packaging must be hermetically sealed;

(e) The secondary packaging must be securely packed in strong outer packaging. The completed

package must be capable of withstanding, without breakage or leakage of any inner packaging and without significant reduction in effectiveness:

(1) The following free drops onto a rigid, non resilient, flat and horizontal surface from a height of 1.8

m (5.9 feet): (i) One drop flat on the bottom; (ii) One drop flat on the top; (iii) One drop flat on the long side; (iv) One drop flat on the short side; (v) One drop on a corner at the junction of three intersecting edges; and

(2) A force applied to the top surface for a duration of 24 hours, equivalent to the total weight of

identical packages if stacked to a height of 3 m (10 feet) (including the test sample). (3) Each of the above tests may be performed on different but identical packages.

(f) The gross mass of the completed package must not exceed 30 kg. (g) For transportation by aircraft, permeation devices must be transported as cargo and may not be

carried onboard an aircraft by passengers or crewmembers in carry-on baggage, checked baggage, or on their person unless specifically excepted by § 175.10.

§ 173.176 Capacitors. (a) Capacitors, including capacitors containing an electrolyte that does not meet the definition of any

hazard class or division as defined in this part, must conform to the following requirements: (1) Except for asymmetric capacitors, capacitors not installed in equipment must be transported in an

uncharged state. (2) Each capacitor or module must be protected against a potential short circuit hazard in transport

as follows: (i) Except for asymmetric capacitors, when a capacitor's energy storage capacity is less than or

equal to 10 Wh or when the energy storage capacity of each capacitor in a module is less than or equal to 10 Wh, the capacitor or module must be protected against short circuit or be fitted with a metal strap connecting the terminals; or

(ii) Except for asymmetric capacitors, when the energy storage capacity of a capacitor or a capacitor in a module is more than 10 Wh, the capacitor or module must be fitted with a metal strap connecting the terminals.

(iii) When an asymmetric capacitor's energy storage capacity is greater than 0.3 Wh, or when the energy storage capacity of each capacitor in a module is greater than 0.3 Wh, the capacitor or module must be protected against short circuit.

(3) Capacitors containing an electrolyte that meets the definition of one or more hazard class or division as defined in this part, must be designed to withstand a 95 kPa (0.95 bar, 14 psi)


pressure differential. (4) Capacitors must be designed and constructed to safely relieve pressure that may build up in use,

through a vent or a weak point in the capacitor casing. Any liquid that is released upon venting must be contained by the packaging or by the equipment in which a capacitor is installed.

(5) Except for asymmetric capacitors, capacitors manufactured after December 31, 2013, or asymmetric capacitors manufactured after December 31, 2015, must be marked with the energy storage capacity in Wh.

(b) Capacitors must be packed in strong outer packagings. For transport by air, capacitors must be securely cushioned within the outer packagings. Capacitors installed in equipment may be offered for transport unpackaged or on pallets, when the capacitors are afforded equivalent protection by the equipment in which they are contained.

(c) Capacitors containing an electrolyte not meeting the definition of any hazard class or division as defined in this part, including when configured in a module or when installed in equipment, are not subject to any other requirements of this subchapter.

(d) Except for asymmetric capacitors, capacitors containing an electrolyte that meets the definition of one or more hazard class or division as defined in this part, with an energy storage capacity of 10 Wh or less are not subject to any other requirements of this subchapter, when they are capable of withstanding a 1.2 m (3.9 feet) drop test unpackaged onto a rigid, non-resilient, flat and horizontal surface without loss of contents.

(e) Asymmetric capacitors containing an electrolyte that meets the definition of one or more hazard class or division as defined in this part, with an energy storage capacity of 20 Wh or less, including when configured in a module, are not subject to other provisions of this subchapter when the capacitors are capable of withstanding a 1.2 meter (3.9 feet) drop test unpackaged onto a rigid, non-resilient, flat and horizontal surface without loss of contents.

(f) Except for asymmetric capacitors, capacitors containing an electrolyte meeting the definition of one or more hazard class or division as defined in this part, that are not installed in equipment, and with an energy storage capacity of more than 10 Wh are subject to the requirements of this subchapter.

(g) Asymmetric capacitors containing an electrolyte meeting the definition of one or more hazard class or division as defined in this part, that are not installed in equipment, and with an energy storage capacity of more than 20 Wh are to the requirements of this subchapter.

(h) Capacitors installed in equipment and containing an electrolyte meeting the definition of one or more hazard class or division as defined in this part, are not subject to any other requirements of this subchapter, provided the equipment is packaged in a strong outer packaging and in such a manner as to prevent accidental functioning of the capacitors during transport. Large, robust equipment containing capacitors may be offered for transport unpackaged or on pallets when the capacitors are afforded equivalent protection by the equipment in which they are contained.

173.181 Pyrophoric materials (liquids). When the §172.101 Table specifies that a hazardous material be packaged under this section, only the following non-bulk packagings are authorized: (a) Authorized cylinders.

(1) A specification steel or nickel cylinder prescribed for any compressed gas, except acetylene, having a minimum design pressure of 1206 kPa (175 psig).

(2) DOT 3AL cylinders constructed of aluminum alloy 6061-T6 with a minimum marked service pressure of 1,800 psig and a maximum water capacity of 49 liters (13 gal) may be used for the transportation of inorganic pyrophoric liquids (UN3194). Any preheating or heating of the DOT 3AL cylinder must be limited to a maximum temperature of 79.4 °C (175 °F).

(3) Cylinders authorized under paragraphs (a)(1) and (a)(2) of this section equipped with valves must be: (i) Equipped with steel valve protection caps or collars; or (ii) Overpacked in a wooden box (4C1, 4C2, 4D or 4F); fiberboard box (4G), or

plastic box (4H1 or 4H2). Cylinders must be secured to prevent shifting in the box and, when offered for transportation or transported, must be so loaded that pressure relief devices remain in the vapor space of the cylinder. (See §177.838(h) of this subchapter.)


(b) Steel boxes (4A), aluminum boxes (4B), metal boxes, other than steel or aluminum (4N), wooden boxes (4C1, 4C2, 4D, or 4F) or fiberboard boxes (4G); steel drums (1A1 or 1A2), aluminum drums (1B1 or 1B2), metal drums, other than steel or aluminum (1N1 or 1N2), plywood drums (1D), or fiber drums (1G); or steel jerricans (3A1 or 3A2) or aluminum jerricans (3B1 or 3B2) enclosing not more than four strong, tight metal cans with inner receptacles of glass or metal, not over 1 L (0.3 gallon) capacity each, having positive screwcap closures adequately gasketed. Inner packagings must be cushioned on all sides with dry, absorbent, incombustible material in a quantity sufficient to absorb the entire contents. The strong, tight metal cans must be closed by positive means, not by friction.

(c) Steel drums (1A1 or 1A2), aluminum drums (1B1 or 1B2), metal drums, other than steel or

aluminum (1N1 or 1N2) or fiber drums (1G); steel jerricans (3A1 or 3A2) or aluminum jerricans (3B1 or 3B2); or steel boxes (4A), aluminum boxes (4B) or metal boxes, other than steel or aluminum (4N) not exceeding 220 L (58 gallons) capacity each with strong, tight inner metal cans not over 4.0 L (1 gallon) capacity each. The strong, tight metal cans must be closed by positive means, not friction. (1) Inner packagings must have no opening exceeding 25 mm (1 inch) diameter and must be

surrounded with noncombustible cushioning material. (2) Net quantity of pyrophoric liquids may not exceed two-thirds of the rated capacity of the

outer drum. For example, a 220 L (58 gallons) outer drum may contain no more than 147 L (39 gallons) of pyrophoric liquids.

(3) Each layer of inner containers must be separated by a metal plate separator in addition to cushioning material.

(d) Combination packagings consisting of the following:

(1) Inner packaging. A 10 liter or 20 liter UN1A1 drum which has been certified to PG I of subpart M of part 178 of this subchapter. Each inner drum must— (i) Have minimum wall thickness of 1.9 mm; (ii) Have 4 NPT or VCR openings, each with a diameter of 6.3 mm; (iii) Be fabricated from stainless steel; and (iv) On the upper head, be fitted with a center opening with a maximum diameter of 68.3 mm and

the opening sealed with a threaded closure fabricated from 316 stainless steel. No more than two (2) inner drums may be placed inside the outer drum.

(2) Outer packaging. A UN1A2 drum that has been certified to the PG I performance level of subpart M of part 178 of this subchapter and a capacity not to exceed 208 L (55 gal). The drum must have a minimum wall thickness of 1.0 mm and the top head must be closed with a steel closing ring with a minimum thickness of 2.4 mm. No more than two (2) inner drums described in paragraph (d)(1) of this section may be placed inside the outer drum.

173.182 Barium azide-50 percent or more water wet. Barium azide-50 percent or more water wet, must be packed in wooden boxes (4C1, 4C2, 4D, or 4F) or fiber drums (1G) with inner glass packagings not over 0.5 kg (1.1 pounds) capacity each. Packagings must have rubber stoppers wire tied for securement. If transportation is to take place when and where freezing weather is possible, a suitable antifreeze solution must be used to prevent freezing. Each packaging must conform to the requirements of part 178 of this subchapter at the Packing Group I performance level. 173.183 Nitrocellulose base film. Films, nitrocellulose base, must be packaged in packagings conforming to the requirements of part 178 of

this subchapter at the Packing Group III performance level, as follows: (a) In steel drums (1A2), aluminum drums (1B2), other metal drums (4A2), steel jerricans (3A2),

aluminum jerricans (3B2), steel, aluminum or other metal (4A, 4B, 4N) boxes, wooden (4C1, 4C2), plywood (4D) or reconstituted wood (4F) boxes or plywood drums (1D) with each reel in a tightly closed metal can, polypropylene canister, or strong cardboard or fiberboard inner packaging with cover held in place by adhesive tape or paper; or


(b) In fiberboard (4G) boxes or fiber drums (1G) with a single tightly closed metal can, polypropylene canister, or strong cardboard or fiberboard inner packaging with cover held in place by adhesive tape or paper; authorized only for not over 600 m (1969 feet) of film.

173.184 Highway or rail fusee. (a) A fusee is a device designed to burn at a controlled rate and to produce visual effects for signaling

purposes. The composition of the fusee must be such that the fusee will not ignite spontaneously or undergo marked decomposition when subjected to a temperature of 75 C (167 F) for 48 consecutive hours.

(b) Fusees (highway and railway) must be packaged in steel (1A2), aluminum (1B2) or other metal (1N2)

drums, steel (3A2) or aluminum (3B2) jerricans, steel (4A), aluminum (4B) or other metal (4N) boxes, wooden (4C1, 4C2), plywood (4D) or reconstituted wood (4F) boxes or in fiberboard boxes (4G), plywood (1D) or fiber (1G) drums. If the fusees are equipped with spikes packagings must have reinforced ends to prevent penetration of spikes through the outer packagings; packages must be capable of passing drop test requirements (§ 178.603 of this subchapter), including at least one drop with spike in a downward position, and other requirements of part 178 of this subchapter, at the Packing Group II performance level.

(c) For transportation by highway, railroad flagging kits are not subject any other requirements of this

subchapter when all of the following conditions are met: (1) The flagging kits may only contain fusees and railroad torpedoes as follows:

(i) Fusee (rail or highway) (NA1325, Division 4.1, PG II). (ii) Articles, pyrotechnic (UN0431, Division 1.4G, PG II). (iii) Signal devices, hand (UN0373, Division 1.4S, PG II). (iv) Signal devices, hand (UN0191, Division 1.4G, PG II). (v) Signals, railway track, explosive (UN0193, Division 1.4S, PG II).

(2) Fusees and railroad torpedoes must be transported in compartmented metal containers. Each compartment must have a cover with a latching device. Compartments for railroad torpedoes must be equipped with a spring-loaded positive locking device. Each compartment may only contain one type of device.

(3) Each flagging kit may contain a maximum of 36 fusees and 36 railroad torpedoes. No more than six (6) flagging kits may be transported at one time on any motor vehicle.

(4) Flagging kits may only be transported on railroad motor vehicles including privately owned motor vehicles under the direct control of on-duty railroad employees.

(5) The fusees and railroad torpedoes must be kept in the closed flagging kits whenever they are not being used on the railroad right-of-way, while the motor vehicle is being driven, or whenever the motor vehicle is located on other than railroad property.

(6) When left in unattended motor vehicles on non-railroad property, a flagging kit must be locked inside the motor vehicle, or stored in a locked compartment on the motor vehicle.

173.185 Lithium batteries and cells.

As used in this section, consignment means one or more packages of hazardous materials

accepted by an operator from one shipper at one time and at one address, receipted for in one lot

and moving to one consignee at one destination address. Equipment means the device or

apparatus for which the lithium cells or batteries will provide electrical power for its operation.

Lithium cell(s) or battery(ies) includes both lithium metal and lithium ion chemistries. Medical

device means an instrument, apparatus, implement, machine, contrivance, implant, or in vitro

reagent, including any component, part, or accessory thereof, which is intended for use in the

diagnosis of disease or other conditions, or in the cure, mitigation, treatment, or prevention of

disease, of a person.

(a) Classification. (1) Each lithium cell or battery must be of the type proven to meet the criteria

in part III, sub-section 38.3 of the UN Manual of Tests and Criteria (IBR; see §171.7 of this


subchapter). Lithium cells and batteries are subject to these tests regardless of whether the

cells used to construct the battery are of a tested type. A single cell battery as defined in part

III, sub-section 38.3 of the UN Manual of Tests and Criteria is considered a “cell” and must

be offered for transportation in accordance with the requirements for cells.

(i) Cells and batteries manufactured according to a type meeting the requirements of sub-

section 38.3 of the UN Manual of Tests and Criteria, Revision 3, Amendment 1 or

any subsequent revision and amendment applicable at the date of the type testing may

continue to be transported, unless otherwise provided in this subchapter.

(ii) Cell and battery types only meeting the requirements of the UN Manual of Tests and

Criteria, Revision 3, are no longer valid. However, cells and batteries manufactured in

conformity with such types before July 2003 may continue to be transported if all

other applicable requirements are fulfilled.

(2) Each person who manufactures lithium cells or batteries must create a record of

satisfactory completion of the testing (e.g. test report) required by this paragraph prior to

offering the lithium cell or battery for transport and must:

(i) Maintain this record for as long as that design is offered for transportation and for one

year thereafter; and

(ii) Make this record available to an authorized representative of the Federal, state or

local government upon request.

(3) Beginning January 1, 2022 each manufacturer and subsequent distributor of lithium cells

or batteries manufactured on or after January 1, 2008, must make available a test

summary. The test summary must include the following elements:

(i) Name of cell, battery, or product manufacturer, as applicable;

(ii) Cell, battery, or product manufacturer's contact information to include address,

telephone number, email address, and website for more information;

(iii) Name of the test laboratory, to include address, telephone number, email address,

and website for more information;

(iv) A unique test report identification number;

(v) Date of test report;

(vi) Description of cell or battery to include at a minimum;

(A) Lithium ion or lithium metal cell or battery;

(B) Mass of cell or battery;

(C) Watt-hour rating, or lithium content;


(D) Physical description of the cell/battery; and

(E) Cell or battery model number or, alternatively, if the test summary is established

for a product containing a cell or battery, the product model number.

(vii) List of tests conducted and results (i.e., pass/fail);

(viii) Reference to assembled battery testing requirements (if applicable);

(ix) Reference to the revised edition of the UN Manual of Tests and Criteria used and to

amendments thereto, if any; and

(x) Signature with name and title of signatory as an indication of the validity of

information provided.

(4) Except for cells or batteries meeting the requirements of paragraph (c) of this section,

each lithium cell or battery must:

(i) Incorporate a safety venting device or be designed to preclude a violent rupture under

conditions normally incident to transport;

(ii) Be equipped with means of preventing external short circuits; and

(iii) Be equipped with a means of preventing dangerous reverse current flow (e.g., diodes

or fuses) if a battery contains cells, or a series of cells that are connected in parallel.

(b) Packaging. (1) Each package offered for transportation containing lithium cells or batteries,

including lithium cells or batteries packed with, or contained in, equipment, must meet all

applicable requirements of subpart B of this part.

(2) Lithium cells or batteries, including lithium cells or batteries packed with, or contained

in, equipment, must be packaged in a manner to prevent:

(i) Short circuits;

(ii) Damage caused by movement or placement within the package; and

(iii) Accidental activation of the equipment.

(3) For packages containing lithium cells or batteries offered for transportation:

(i) The lithium cells or batteries must be placed in non-metallic inner packagings that

completely enclose the cells or batteries, and separate the cells or batteries from

contact with equipment, other devices, or electrically conductive materials (e.g.,

metal) in the packaging.

(ii) The inner packagings containing lithium cells or batteries must be placed in one of

the following packagings meeting the requirements of part 178, subparts L and M, of

this subchapter at the Packing Group II level:


(A) Metal (4A, 4B, 4N), wooden (4C1, 4C2, 4D, 4F), fiberboard (4G), or solid plastic

(4H1, 4H2) box;

(B) Metal (1A2, 1B2, 1N2), plywood (1D), fiber (1G), or plastic (1H2) drum;

(C) Metal (3A2, 3B2) or plastic (3H2) jerrican.

(iii) When packed with equipment, lithium cells or batteries must:

(A) Be placed in inner packagings that completely enclose the cell or battery, then

placed in an outer packaging. The completed package for the cells or batteries

must meet the Packing Group II performance requirements as specified in

paragraph (b)(3)(ii) of this section; or

(B) Be placed in inner packagings that completely enclose the cell or battery, then

placed with equipment in a package that meets the Packing Group II performance

requirements as specified in paragraph (b)(3)(ii) of this section.

(4) When lithium cells or batteries are contained in equipment:

(i) The outer packaging, when used, must be constructed of suitable material of adequate

strength and design in relation to the capacity and intended use of the packaging,

unless the lithium cells or batteries are afforded equivalent protection by the

equipment in which they are contained;

(ii) Equipment must be secured to prevent damage caused by movement within the outer

packaging and be packed so as to prevent accidental operation during transport; and

(iii) Any spare lithium cells or batteries packed with the equipment must be packaged in

accordance with paragraph (b)(3) of this section.

(5) Lithium batteries that weigh 12 kg (26.5 pounds) or more and have a strong, impact-

resistant outer casing and assemblies of such batteries, may be packed in strong outer

packagings; in protective enclosures (for example, in fully enclosed or wooden slatted

crates); or on pallets or other handling devices, instead of packages meeting the UN

performance packaging requirements in paragraphs (b)(3)(ii) and (b)(3)(iii) of this

section. Batteries or battery assemblies must be secured to prevent inadvertent

movement, and the terminals may not support the weight of other superimposed

elements. Batteries or battery assemblies packaged in accordance with this paragraph

may be transported by cargo aircraft if approved by the Associate Administrator.

(6) Except for transportation by aircraft, the following rigid large packagings are authorized

for a single battery, and for a single item of equipment containing batteries, meeting

provisions in paragraphs (b)(1) and (2) of this section and the requirements of part 178,

subparts P and Q, of this subchapter at the Packing Group II level:

(i) Metal (50A, 50B, 50N) metal packagings must be fitted with an electrically non-

conductive lining material (e.g., plastics) of adequate strength for the intended use;


(ii) Rigid plastic (50H);

(iii) Wooden (50C, 50D, 50F);

(iv) Rigid fiberboard (50G).

(7) For transportation by aircraft, lithium cells and batteries must not be packed in the same

outer packaging with substances and articles of Class 1 (explosives) other than Division

1.4S, Division 2.1 (flammable gases), Class 3 (flammable liquids), Division 4.1

(flammable solids), or Division 5.1 (oxidizers).

(c) Exceptions for smaller cells or batteries. Other than as specifically stated below, a package

containing lithium cells or batteries, or lithium cells or batteries packed with, or contained in,

equipment, that meets the conditions of this paragraph is excepted from the requirements in

subparts C through H of part 172 of this subchapter and the UN performance packaging

requirements in paragraphs (b)(3)(ii) and (iii) of this section under the following conditions

and limitations.

(1) Size limits. (i) The Watt-hour (Wh) rating may not exceed 20 Wh for a lithium ion cell or

100 Wh for a lithium ion battery. After December 31, 2015, each lithium ion battery

subject to this provision must be marked with the Watt-hour rating on the outside case.

(ii) The lithium content may not exceed 1 g for a lithium metal cell or 2 g for a lithium

metal battery.

(iii) Except when lithium cells or batteries are packed with or contained in equipment in

quantities not exceeding 5 kg net weight, the outer package that contains lithium cells

or batteries must be appropriately marked: “PRIMARY LITHIUM BATTERIES—

FORBIDDEN FOR TRANSPORT ABOARD PASSENGER AIRCRAFT”,

“LITHIUM METAL BATTERIES—FORBIDDEN FOR TRANSPORT ABOARD

PASSENGER AIRCRAFT”, “LITHIUM ION BATTERIES—FORBIDDEN FOR

TRANSPORT ABOARD PASSENGER AIRCRAFT” or labeled with a “CARGO

AIRCRAFT ONLY” label specified in §172.448 of this subchapter.

(iv) For transportation by highway or rail only, the lithium content of the cell and battery

may be increased to 5 g for a lithium metal cell or 25 g for a lithium metal battery and

60 Wh for a lithium ion cell or 300 Wh for a lithium ion battery, provided the outer

package is marked: “LITHIUM BATTERIES—FORBIDDEN FOR TRANSPORT

ABOARD AIRCRAFT AND VESSEL.”

(v) The marking specified in paragraphs (c)(1)(iii) and (iv) of this section must have a

background of contrasting color, and the letters in the marking must be:

(A) At least 6 mm (0.25 inch) in height on packages having a gross weight of 30 kg

(66 pounds) or less, except that smaller font may be used as necessary when

package dimensions so require.

(B) At least 12 mm (0.5 inch) in height on packages having a gross weight of more

than 30 kg (66 pounds).


(vi) Except when lithium cells or batteries are packed with, or contained in, equipment,

each package must not exceed 30 kg (66 pounds) gross weight.

(2) Packaging. Lithium cells and batteries must be packed in inner packagings that

completely enclose the cell or battery then placed in a strong rigid outer package unless

the cell or battery is contained in equipment and is afforded equivalent protection by the

equipment in which it is contained. Except when lithium cells or batteries are contained

in equipment, each package of lithium cells or batteries, or the completed package when

packed with equipment, must be capable of withstanding a 1.2 meter drop test, in any

orientation, without damage to the cells or batteries contained in the package, without

shifting of the contents that would allow battery-to-battery (or cell-to-cell) contact, and

without release of the contents of the package.

(3) Hazard communication. Each package must display the lithium battery mark except when

a package contains button cell batteries installed in equipment (including circuit boards),

or no more than four lithium cells or two lithium batteries contained in equipment, where

there are not more than two packages in the consignment.

(i) The mark must indicate the UN number: “UN3090” for lithium metal cells or

batteries; or “UN3480” for lithium ion cells or batteries. Where the lithium cells or

batteries are contained in, or packed with, equipment, the UN number “UN3091” or

“UN3481,” as appropriate, must be indicated. Where a package contains lithium cells

or batteries assigned to different UN numbers, all applicable UN numbers must be

indicated on one or more marks. The package must be of such size that there is

adequate space to affix the mark on one side without the mark being folded.

(A) The mark must be in the form of a rectangle with hatched edging. The mark must

be not less than 120 mm (4.7 inches) wide by 110 mm (4.3 inches) high and the

minimum width of the hatching must be 5 mm (0.2 inches), except marks of 105

mm (4.1 inches) wide by 74 mm (2.9 inches) high may be used on a package

containing lithium batteries when the package is too small for the larger mark;

(B) The symbols and letters must be black on white or suitable contrasting

background and the hatching must be red;


(C) The “*” must be replaced by the appropriate UN number(s) and the “**” must be

replaced by a telephone number for additional information; and

(D) Where dimensions are not specified, all features shall be in approximate

proportion to those shown.

(ii) [Reserved]

(iii) When packages are placed in an overpack, the lithium battery mark shall either be

clearly visible through the overpack or be reproduced on the outside of the overpack

and the overpack shall be marked with the word “OVERPACK”. The lettering of the

“OVERPACK” mark shall be at least 12 mm (0.47 inches) high.

(4) Air transportation.

(i) For transportation by aircraft, lithium cells and batteries may not exceed the limits in the

following Table 1 to paragraph (c)(4)(i). The limits on the maximum number of batteries

and maximum net quantity of batteries in the following table may not be combined in the

same package:

Contents

Lithium metal cells and/or batteries

with a lithium content not

more than 0.3 g

Lithium metal cells with a lithium content more than 0.3 g but not more than

1g

Lithium metal batteries with a lithium content more than 0.3 g

but not more than 2 g

Lithium ion cells and/or batteries with a Watt-hour rating not more

than 2.7 Wh

Lithium ion cells with a Watt-hour

rating more than 2.7 Wh but not more than 20

Wh

Lithium ion batteries with a Watt-hour rating more than 2.7 Wh but not

more than 100 Wh

Maximum number of cells/batteries per package

No Limit 8 cells 2 batteries No Limit 8 cells 2 batteries.

Maximum net quantity (mass) per package

2.5 kg 2.5 kg

(ii) Not more than one package prepared in accordance with this paragraph (c)(4) may be

placed into an overpack. When a package is required to display the “CARGO

AIRCRAFT ONLY” label, the paragraph (c)(1)(iii) mark, or the paragraph (c)(3)(i)

lithium battery mark and the package is placed in an overpack, the appropriate label

or mark must either be clearly visible through the overpack, or the label or mark must

also be affixed on the outside of the overpack, and the overpack must be marked with

the word “OVERPACK”. The lettering of the “OVERPACK” mark shall be at least

12 mm (0.47 inches) high.

(iii) A shipper is not permitted to offer for transport more than one package prepared in

accordance with the provisions of this paragraph in any single consignment.

(iv) Each shipment with packages required to display the paragraph (c)(3)(i) lithium

battery mark must include an indication on the air waybill of compliance with this

paragraph (c)(4) (or the applicable ICAO Technical Instructions Packing Instruction),

when an air waybill is used.


(v) Packages and overpacks of lithium batteries prepared in accordance with this

paragraph (c)(4) must be offered to the operator separately from cargo which is not

subject to the requirements of this subchapter and must not be loaded into a unit load

device before being offered to the operator.

(vi) For lithium batteries packed with, or contained in, equipment, the number of batteries

in each package is limited to the minimum number required to power the piece of

equipment, plus two spare sets, and the total net quantity (mass) of the lithium cells or

batteries in the completed package must not exceed 5 kg. A “set” of cells or batteries

is the number of individual cells or batteries that are required to power each piece of

equipment.

(vii) Each person who prepares a package for transport containing lithium cells or

batteries, including cells or batteries packed with, or contained in, equipment in

accordance with the conditions and limitations of this paragraph (c)(4), must receive

instruction on these conditions and limitations, corresponding to their functions.

(viii) Lithium cells and batteries must not be packed in the same outer packaging with

other hazardous materials. Packages prepared in accordance with this paragraph

(c)(4) must not be placed into an overpack with packages containing hazardous

materials and articles of Class 1 (explosives) other than Division 1.4S, Division 2.1

(flammable gases), Class 3 (flammable liquids), Division 4.1 (flammable solids) or

Division 5.1 (oxidizers).

(5) For transportation by aircraft, a package that exceeds the number or quantity (mass) limits

in the table shown in paragraph (c)(4)(i) of this section, the overpack limit described in

paragraph (c)(4)(ii) of this section, or the consignment limit described in paragraph

(c)(4)(iii) of this section is subject to all applicable requirements of this subchapter,

except that a package containing no more than 2.5 kg lithium metal cells or batteries or

10 kg lithium ion cells or batteries is not subject to the UN performance packaging

requirements in paragraph (b)(3)(ii) of this section when the package displays both the

lithium battery mark in paragraph (c)(3)(i) and the Class 9 Lithium Battery label

specified in §172.447 of this subchapter. This paragraph does not apply to batteries or

cells packed with or contained in equipment.

(d) Lithium cells or batteries shipped for disposal or recycling. A lithium cell or battery,

including a lithium cell or battery contained in equipment, that is transported by motor

vehicle to a permitted storage facility or disposal site, or for purposes of recycling, is

excepted from the testing and record keeping requirements of paragraph (a) and the UN

performance packaging requirements in paragraphs (b)(3)(ii), (b)(3)(iii) and (b)(6) of this

section, when packed in a strong outer packaging conforming to the applicable requirements

of subpart B of this part. A lithium cell or battery that meets the size, packaging, and hazard

communication conditions in paragraph (c)(1)-(3) of this section is excepted from subparts C

through H of part 172 of this subchapter.

(e) Low production runs and prototypes. Low production runs (i.e., annual production runs

consisting of not more than 100 lithium cells or batteries), prototype lithium cells or batteries

transported for purposes of testing, and equipment containing such cells or batteries are


excepted from the testing and record keeping requirements of paragraph (a) of this section,

provided:

(1) Except as provided in paragraph (e)(5) of this section, each cell or battery is individually

packed in a non-metallic inner packaging, inside an outer packaging, and is surrounded

by cushioning material that is non-combustible and electrically non-conductive, or

contained in equipment. Equipment must be constructed or packaged in a manner as to

prevent accidental operation during transport;

(2) Appropriate measures shall be taken to minimize the effects of vibration and shocks and

prevent movement of the cells or batteries within the package that may lead to damage

and a dangerous condition during transport. Cushioning material that is non-combustible

and electrically non-conductive may be used to meet this requirement;

(3) The lithium cells or batteries are packed in inner packagings or contained in equipment.

The inner packaging or equipment is placed in one of the following outer packagings that

meet the requirements of part 178, subparts L and M, of this subchapter at the Packing

Group I level. Cells and batteries, including equipment of different sizes, shapes or

masses must be placed into an outer packaging of a tested design type listed in this

section provided the total gross mass of the package does not exceed the gross mass for

which the design type has been tested. A cell or battery with a net mass of more than 30

kg is limited to one cell or battery per outer packaging;

(i) Metal (4A, 4B, 4N), wooden (4C1, 4C2, 4D, 4F), or solid plastic (4H2) box;

(ii) Metal (1A2, 1B2, 1N2), plywood (1D), or plastic (1H2) drum.

(4) For a single battery, and for a single item of equipment containing cells or batteries, the

following rigid large packagings are authorized:

(i) Metal (50A, 50B, 50N) metal packagings must be fitted with an electrically non-

conductive lining material (e.g., plastics) of adequate strength for the intended use;

(ii) Rigid plastic (50H);

(iii) Plywood (50D).

(5) Lithium batteries, including lithium batteries contained in equipment, that weigh 12 kg

(26.5 pounds) or more and have a strong, impact-resistant outer casing or assemblies of

such batteries, may be packed in strong outer packagings, in protective enclosures (for

example, in fully enclosed or wooden slatted crates), or on pallets or other handling

devices, instead of packages meeting the UN performance packaging requirements in

paragraphs (b)(3)(ii) and (iii) of this section. The battery or battery assembly must be

secured to prevent inadvertent movement, and the terminals may not support the weight

of other superimposed elements;

(6) Irrespective of the limit specified in column (9B) of the §172.101 Hazardous Materials

Table, the battery or battery assembly prepared for transport in accordance with this


paragraph may have a mass exceeding 35 kg gross weight when transported by cargo

aircraft;

(7) Batteries or battery assemblies packaged in accordance with this paragraph are not

permitted for transportation by passenger-carrying aircraft, and may be transported by

cargo aircraft only if approved by the Associate Administrator prior to transportation; and

(8) Shipping papers must include the following notation: “Transport in accordance with

§173.185(e).”

(f) Damaged, defective, or recalled cells or batteries. Lithium cells or batteries that have been

damaged or identified by the manufacturer as being defective for safety reasons, that have the

potential of producing a dangerous evolution of heat, fire, or short circuit (e.g., those being

returned to the manufacturer for safety reasons) may be transported by highway, rail or

vessel only, and must be packaged as follows:

(1) Each cell or battery must be placed in individual, non-metallic inner packaging that

completely encloses the cell or battery;

(2) The inner packaging must be surrounded by cushioning material that is non-combustible,

electrically non-conductive, and absorbent; and

(3) Each inner packaging must be individually placed in one of the following packagings

meeting the applicable requirements of part 178, subparts L, M, P, and Q of this

subchapter at the Packing Group I level:

(i) Metal (4A, 4B, 4N), wooden (4C1, 4C2, 4D, 4F), or solid plastic (4H2) box;

(ii) Metal (1A2, 1B2, 1N2), plywood (1D), or plastic (1H2) drum; or

(iii) For a single battery, and for a single item of equipment containing cells or batteries,

the following rigid large packagings are authorized:

(A) Metal (50A, 50B, 50N);

(B) Rigid plastic (50H);

(C) Plywood (50D); and

(4) The outer package must be marked with an indication that the package contains a

“Damaged/defective lithium ion battery” and/or “Damaged/defective lithium metal

battery” as appropriate. The marking required by this paragraph must be in characters at

least 12 mm (0.47 inches) high.

(g) Limited exceptions to restrictions on air transportation of medical device batteries.

Irrespective of the quantity limitations described in column 9A of the §172.101 Hazardous

Materials Table of this subchapter, up to two replacement lithium cells or batteries

specifically used for a medical device as defined in this section may be transported as cargo

on a passenger aircraft. Packages containing these cells or batteries are not subject to the


marking requirement in paragraph (c)(1)(iii) of this section or the “CARGO AIRCRAFT

ONLY” label required by §172.402(c) of this subchapter and may be transported as cargo on

a passenger aircraft when approved by the Associate Administrator and provided the

following conditions are met:

(1) The intended destination of the cells or batteries is not serviced daily by cargo aircraft if a

cell or battery is required for medically necessary care; and

(2) Lithium ion cells or batteries for medical devices are excepted from the state of charge

limitations in §172.102, special provision A100, of this subchapter, provided each cell or

battery is:

(i) Individually packed in an inner packaging that completely encloses the cell or battery;

(ii) Placed in a rigid outer packaging; and

(iii) Protected to prevent short circuits.

(h) Approval. A lithium cell or battery that does not conform to the provisions of this subchapter

may be transported only under conditions approved by the Associate Administrator.

173.186 Matches. (a) Matches must be of a type which will not ignite spontaneously or undergo marked decomposition

when subjected for 8 consecutive hours to a temperature of 93 C (200 F). (b) Definitions.

(1) Fusee matches are matches the heads of which are prepared with a friction-sensitive igniter composition and a pyrotechnic composition which burns with little or no flame, but with intense heat.

(2) Safety matches are matches combined with or attached to the box, book or card that can

be ignited by friction only on a prepared surface.

(3) Strike anywhere matches are matches that can be ignited by friction on a solid surface.

(4) Wax ``Vesta'' matches are matches that can be ignited by friction either on a prepared surface or on a solid surface.

(c) Safety matches and wax ``Vesta'' matches must be tightly packed in securely closed inner

packagings to prevent accidental ignition under conditions normally incident to transportation, and further packed in outer fiberboard, wooden, or other equivalent-type packagings. These matches in outer packagings not exceeding 23 kg (50 pounds) gross weight are not subject to any other requirement (except marking) of this subchapter. These matches may be packed in the same outer packaging with materials not subject to this subchapter.

(d) Strike-anywhere matches may not be packed in the same outer packaging with any material other

than safety matches or wax ``Vesta'' matches, which must be packed in separate inner packagings.

(e) Packagings. Strike-anywhere matches must be tightly packed in securely closed chipboard,

fiberboard, wooden, or metal inner packagings to prevent accidental ignition under conditions normally incident to transportation. Each inner packaging may contain no more than 700 strike-anywhere matches and must be packed in outer steel drums (1A1, 1A2), aluminum drums (1B1,


1B2), other metal drums (1N1, 1N2), steel jerricans (3A1, 3A2), aluminum jerricans (3B1, 3B2), steel (4A), aluminum (4N), other metal (4N) boxes, wooden (4C1, 4C2), plywood (4D), reconstituted wood (4F) or fiberboard (4G) boxes, plywood (1D) or fiber (1G) drums. Gross weight of fiberboard boxes (4G) must not exceed 30 kg (66 pounds). Gross weight of other outer packagings must not exceed 45 kg (100 pounds).

173.187 Pyrophoric solids, metals or alloys, n.o.s. Packagings for pyrophoric solids, metals, or alloys, n.o.s. must conform to the requirements of part 178 of this subchapter at the packing group performance level specified in the § 172.101 Table. These materials must be packaged as follows: (a) In steel, aluminum or other metal boxes (4A, 4B or 4N) and contain no more than 15 kg (33

pounds) each. (b) In wooden boxes (4C1, 4C2, 4D, or 4F) with inner metal receptacles which have a positive (not

friction) means of closure and contain not more than 15 kg (33 pounds) each. (c) In fiberboard boxes (4G) with inner metal receptacles which have a positive (not friction) means

of closure and contain not more than 7.5 kg (17 pounds) each. (d) In steel, aluminum or other metal drums (1A1, 1A2, 1B1, 1B2, 1N1 or 1N2) with a gross mass

not exceeding 150 kg (331 pounds) per drum. (e) In plywood drums (1D) with inner metal receptacles which have a positive (not friction) means of

closure and contain not more than 15 kg (33 pounds) each. (f) In fiber drums (1G) with inner metal receptacles which have a positive (not friction) means of

closure and contain not more than 15 kg (33 pounds) each. (g) In specification cylinders, as prescribed for any compressed gas, except for Specifications 8 and

3HT. 173.188 White or yellow phosphorus. Phosphorus, white or yellow, when offered for transportation or transported by rail, highway, or water, must be packaged in water or dry in packagings conforming to the requirements of part 178 of this subchapter at the Packing Group I performance level, as follows: (a) When placed in water, it must be packaged in specification packagings as follows:

(1) Steel, aluminum or other metal boxes (4A, 4B or 4N) or wooden boxes (4C1, 4C2, 4D, or 4F) with:

(i) Inner hermetically sealed (soldered) metal cans, enclosed in other hermetically

sealed (soldered) metal cans, or

(ii) Inner water-tight metal cans containing not over 0.5 kg (1 pound) of phosphorus with screw-top closures; or

(2) Steel, aluminum or other metal drums (1A1, 1B1 or 1N1) not over 250 L (66 gallons)

capacity each or steel, aluminum or other metal drums (1A2, 1B2, or 1N2) not over 115 L (30 gallons) capacity each.

(3)

(i) A 115 L (30 gallon) UN1A2 steel drum certified to the PG I performance level for solids and the PG I or PG II performance level for liquids and dual marked, at a minimum, as a UN1A2/X400/S (for solid) and UN1A2 X(or Y)/1.4/150 (for liquids) subject to the following conditions:


(ii) Enough water must be present in each drum to ensure that the phosphorous is covered by water at all times during transportation, in any orientation of the drum;

(iii) Drums must be held and observed for a minimum of 24-hours before transportation. Any leaking or otherwise unsuitable drums must be replaced prior to transportation;

(iv) Packages must be destroyed and may not be reused; (v) The net mass of the material and water, in kilograms, must not exceed the mass

that would be permitted by calculating the volume of the packaging in liters multiplied by the specific gravity indicated on the package certification;

(vi) Transportation is by private or contract motor carrier only; and (vii) Transportation is authorized from the offeror's location to a facility where it must

be unloaded by the consignee. (b) When dry, it must be cast solid and shipped in packagings as follows:

(1) Steel, aluminum or other metal drums (1A2, 1B2 or 1N2) not over 115 L (30 gallons) capacity each, or

(2) In projectiles or bombs when shipped by, for, or to the Departments of the Army, Navy, or

Air Force of the United States Government, without bursting elements. 173.189 Batteries containing sodium or cells containing sodium. (a) Batteries and cells may not contain any hazardous material other than sodium, sulfur or sodium

compounds (e.g., sodium polysulfides, sodium tetrachloroaluminate, etc.). Cells not forming a component of a completed battery may not be offered for transportation at a temperature at which any liquid sodium is present in the cell. Batteries may only be offered for transportation, or transported, at a temperature at which any liquid sodium present in the battery conforms to the conditions prescribed in paragraph (d) of this section.

(b) Cells must be protected against short circuit and must consist of hermetically sealed metal

casings that fully enclose the hazardous materials and that are so constructed and closed as to prevent the release of the hazardous materials under normal conditions of transport. Cells must be placed in suitable outer packagings with sufficient cushioning material to prevent contact between cells and between cells and the internal surfaces of the outer packaging, and to ensure that no dangerous shifting of the cells within the outer packaging occurs in transport. Cells must be packaged in 1A2, 1B2, 1N2, 1D, 1G, 1H2, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2, 3A2, 3B2 or 3H2) outer packagings that meet the requirements of part 178 of this subchapter at the Packing Group II performance level.

(c) Batteries must consist of cells secured within, and fully enclosed by a metal casing so

constructed and closed as to prevent the release of the hazardous materials under normal conditions of transport. Batteries may be offered for transportation, and transported, unpacked or in protective packagings that are not subject to the requirements of part 178 of this subchapter.

(d) Batteries containing any liquid sodium may not be offered for transportation, or transported, by

aircraft. Batteries containing liquid sodium may be transported by motor vehicle, rail car or vessel under the following conditions:

(1) Batteries must be equipped with an effective means of preventing external short circuits,

such as by providing complete electrical insulation of battery terminals or other external electrical connectors. Battery terminals or other electrical connectors penetrating the heat insulation fitted in battery casings must be provided with thermal insulation sufficient to prevent the temperature of the exposed surfaces of such devices from exceeding 55 C (130°F).

(2) No battery may be offered for transportation if the temperature at any point on the

external surface of the battery exceeds 55 C (130 F).


(3) If any external source of heating is used during transportation to maintain sodium in

batteries in a molten state, means must be provided to ensure that the internal temperature of the battery does not reach or exceed 400 C (752 F).

(4) When loaded in a transport vehicle or freight container:

(i) Batteries must be secured so as to prevent significant shifting within the transport

vehicle or freight container under conditions normally incident to transportation;

(ii) Adequate ventilation and/or separation between batteries must be provided to ensure that the temperature at any point on the external surface of the battery casing will not exceed 240 C (464 F) during transportation; and

(iii) No other hazardous materials, with the exception of cells containing sodium, may

be loaded in the same transport vehicle or freight container. Batteries must be separated from all other freight by a distance of not less than 0.5 meters (1.6 feet).

(e) Vehicles, machinery and equipment powered by sodium batteries must be consigned under the

entry ‘‘Battery-powered vehicle or Battery-powered equipment.’’ 173.192 Packaging for certain toxic gases in Hazard Zone A. When 172.101 of this subchapter specifies a toxic material must be packaged under this section, only the following cylinders are authorized: (a) Specification 3A1800, 3AA1800, 3AL1800, 3E1800, or seamless UN cylinders with a minimum

test pressure in accordance with P200 of the UN Recommendations (IBR, see 171.7 of this subchapter).

(1) Specification 3A, 3AA, or 3AL cylinders may not exceed 57 kg (125 lb) water capacity

(nominal). (2) Specification 3AL cylinders may only be offered for transportation or transported by

highway and rail. (b) Packagings must conform to the requirements of § 173.40. (c) For cylinders used for phosgene:

(1) The filling density may not exceed 125 percent; (2) A cylinder may not contain more than 68 kg (150 lb) of phosgene; and (3) Each cylinder containing phosgene must be tested for leakage before it is offered for

transportation or transported and must show no leakage. The leakage test must consist of immersing the cylinder and valve, without the protective cap attached, in a bath of water at a temperature of approximately 66° C (150° F) for at least 30 minutes, during which time frequent examinations must be made to note any escape of gas. The valve of the cylinder may not be loosened after this test. Suitable safeguards must be provided to protect personnel and facilities should failure occur during the test. As an alternative, each cylinder containing phosgene may be tested for leakage by a method approved in writing by the Associate Administrator.

173.193 Bromoacetone, methyl bromide, chloropicrin and methyl bromide or methyl

chloride mixtures, etc. (a) Bromoacetone must be packaged as follows in metal boxes (4A, 4B or 4N) or wooden boxes

(4C1, 4C2, 4D or 4F) with inner glass receptacles or tubes in hermetically sealed metal receptacles in corrugated fiberboard cartons. Bottles may not contain over 500 g (17.6 ounces) of liquid each and must be cushioned in cans with at least 12.7 mm (0.5 inch) of absorbent material.


Total amount of liquid in the outer box must not exceed 11 kg (24 pounds). Packagings must conform to the requirements of part 178 of this subchapter at the Packing Group I performance level.

(b) Bromoacetone, methyl bromide, chloropicrin and methyl bromide mixtures, chloropicrin and

methyl chloride mixtures, and chloropicrin mixtures charged with non-flammable, non-liquefied compressed gas must be packed in Specification 3A, 3AA, 3B, 3C, 3E, 4A, 4B, 4BA, 4BW, or 4C cylinders having not over 113 kg (250 pounds) water capacity (nominal) except: (1) DOT Specification 4BW cylinders containing chloropicrin and methyl bromide mixtures

may not exceed 453 kg (1000 pounds); and (2) The capacity limit of this paragraph does not apply to shipments of methyl bromide.

(c) Methyl bromide mixtures containing up to 2% chloropicrin must be packaged in 4G fiberboard

boxes with inside metal cans containing not over one pound each, or inside metal cans with a minimum wall thickness of 0.007 inch containing not over 1\3/4\ pounds each. The one-pound can must be capable of withstanding an internal pressure of 130 psig without leakage or permanent distortion. Vapor pressure of the contents must not exceed 130 psig at 55 C (130 F). The 1\3/4\-pound can must be capable of withstanding an internal pressure of 140 psig without leakage or permanent distortion. Vapor pressure of the contents must not exceed 140 psig at 55 C (130 F). Cans must not be liquid full at 130 F. Cans must be constructed of tinplate or lined with suitable material and must have concave or pressure ends.

(d) Cylinders, except those containing methyl bromide, must conform to §173.40 of this part. 173.194 Gas identification sets. Gas identification sets containing poisonous material must be packaged in packagings conforming to the requirements of part 178 of this subchapter at the Packing Group I performance level, as follows: (a) In glass inner receptacles, hermetically sealed, of not over 40 ml (1.4 fluid ounces) each. Each

glass inner receptacle must in turn be placed in a sealed fiberboard receptacle, cushioned with absorbent material. Not more than 12 fiberboard receptacles must in turn be placed in a 4G fiberboard box. No more than four boxes, well-cushioned, may in turn be placed in a steel cylinder. The cylinder must have a wall thickness of at least 3.7 mm (0.146 inch) and must have a hermetically sealed steel closure.

(b) When the poisonous material is absorbed in a medium such as activated charcoal or silical gel,

gas identification sets may be shipped as follows:

(1) If the poisonous material does not exceed 5 mL (0.2 fluid ounce) if a liquid or 5 g (0.2 ounce) if a solid, it may be packed in glass inner receptacles of not over 120 mL (4.1 fluid ounces) each. Each glass receptacle, cushioned with absorbent material must be packed in a hermetically sealed metal can of not less than 0.30 mm (0.012 inch) wall thickness. Metal cans, surrounded on all sides by at least 25 mm (1 inch) of dry sawdust, must be packed in 4A, 4B or 4N metal boxes or 4C1, 4C2, 4D or 4F wooden boxes. Not more than 100 mL (3.4 fluid ounces) or 100 g (3.5 ounces) of poisonous materials may be packed in one outer box.

(2) If the poisonous material does not exceed 5 mL (0.2 fluid ounce) if a liquid or 20 g (0.7

ounce) if a solid, it may be packed in glass inner receptacles with screw-top closures of not less than 60 mL (2 fluid ounces), hermetically sealed. Twelve bottles containing poisonous material, not to exceed 100 mL (3.4 fluid ounces) or 100 g (3.5 ounces), or both, may be placed in a plastic carrying case, each glass receptacle surrounded by absorbent cushioning and each separated from the other by sponge rubber partitions. The plastic carrying case must be placed in a tightly fitting fiberboard box which in turn


must be placed in a tightly fitting 4A, 4B or 4N metal box or 4C1, 4C2, 4D or 4F wooden box.

173.195 Hydrogen cyanide, anhydrous, stabilized (hydrocyanic acid, aqueous solution). (a) Hydrogen cyanide, anhydrous, stabilized, must be packed in specification cylinders or UN

pressure receptacles as follows:

(1) As prescribed in 173.192; (2) Specification 3A480, 3A480X, 3AA480, or 3A1800 metal cylinders of not over 126 kg

(278 pounds) water capacity (nominal); (3) Shipments in 3AL cylinders are authorized only when transported by highway and rail; or (4) UN cylinders, as specified in part 178, with a minimum test pressure of 100 bar and a

maximum filling ratio of 0.55. The use of UN tubes and MEGCs is not authorized. (b) Cylinders may not be charged with more than 0.27 kg (0.6 pound) of liquid per 0.45 kg (1 pound)

water capacity of cylinder. Each filled cylinder must be tested for leakage before being offered for transportation or transported and must show absolutely no leakage; this test must consist of passing a piece of Guignard's sodium picrate paper over the closure of the cylinder, without the protection cap attached, to detect any escape of hydrogen cyanide from the cylinder. Other equally efficient test methods may be used in place of sodium picrate paper.

(c) Packagings for hydrogen cyanide must conform to §173.40. 173.196 Category A infectious substances. (a) Category A infectious substances packaging. A packaging for a Division 6.2 material that is a

Category A infectious substance must meet the test standards of § 178.609 of this subchapter and must be marked in conformance with § 178.503(f) of this subchapter. A packaging for a Category A infectious substance is a triple packaging consisting of the following components:

(1) A leekproof primary receptacle. (2) A leekproof secondary packaging. If multiple fragile primary receptacles are placed in a

single secondary packaging, they must be either wrapped individually or separated to prevent contact between them.

(3) A rigid outer packaging of adequate strength for its capacity, mass and intended use;

including, drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G); boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); or jerricans (3A1, 3A2, 3B1, 3B2, 3H1, 3H2). The outer packaging must measure not less than 100 mm (3.9 inches) at its smallest overall external dimension.

(4) For a liquid infectious substance, an absorbent material placed between the primary

receptacle and the secondary packaging. The absorbent material must be sufficient to absorb the entire contents of all primary receptacles.

(5) An itemized list of contents enclosed between the secondary packaging and the outer

packaging. (6) The primary receptacle or secondary packaging used for infectious substances must be

capable of withstanding, without leakage, an internal pressure producing a pressure differential of not less than 95 kPa (0.95 bar, 14 psi).

(7) The primary receptacle or secondary packaging used for infectious substances must be

capable of withstanding without leakage temperatures in the range of –40°C to +55°C (–


40°F to +131°F). (b) Additional requirements for packaging Category A infectious substances. Category A infectious

substances must be packaged according to the following requirements, depending on the physical state and other characteristics of the material.

(1) Infectious substances shipped at ambient temperatures or higher. Primary receptacles

must be made of glass, metal, or plastic. Positive means of ensuring a leakproof seal must be provided, such as heat seal, skirted stopper, or metal crimp seal. If screw caps are used, they must be secured by positive means, such as with adhesive tape, paraffin sealing tape, or manufactured locking closure. Lyophilized substances may also be transported in primary receptacles that are flame-sealed with glass ampoules or rubber-stoppered glass vials fitted with metal seals.

(2) Infectious substances shipped refrigerated or frozen (ice, pre-frozen packs, dry ice). Ice,

dry ice, or other refrigerant must be placed around the secondary packagings or in an overpack with one or more complete packages marked in accordance with § 178.503 of this subchapter. Interior supports must be provided to secure the secondary packagings in the original position after the ice or dry ice has dissipated. If ice is used, the outer packaging or overpack must be leakproof. If dry ice is used, the outer packaging or overpack must permit the release of carbon dioxide gas and otherwise meet the provisions in § 173.217. The primary receptacle and the secondary packaging must maintain their integrity at the temperature of the refrigerant used, as well as the temperatures and pressures of transport by aircraft to which they could be subjected if refrigeration were lost.

(3) Infectious substances shipped in liquid nitrogen. The primary receptacle and the

secondary packaging must maintain their integrity at the temperature of the liquid nitrogen as well as the temperatures and pressures of transport by aircraft to which they could be subjected if refrigeration were lost. Refrigerated liquid nitrogen packagings must be metal vacuum insulated vessels or flasks vented to the atmosphere to prevent any increase in pressure within the packaging. The use of safety relief valves, check valves, frangible discs, or similar devices in the vent lines is prohibited. Fill and discharge openings must be protected against the entry of foreign materials that might cause an increase in the internal pressure. The package orientation markings specified in § 172.312(a) of this subchapter must be marked on the packaging. The packaging must be designed to prevent the release of any refrigerated liquid nitrogen irrespective of the packaging orientation.

(c) Live animals may not be used to transport infectious substances unless such substances cannot

be sent by any other means. An animal containing or contaminated with an infectious substance must be transported under terms and conditions approved by the Associate Administrator for Hazardous Materials Safety.

(d) Body parts, organs or whole bodies meeting the definition of Division 6.2 material must be

packaged as follows:

(1) In Division 6.2 packaging, as specified in paragraphs (a) and (b) of this section; or (2) In packaging meeting the requirements of § 173.197.

173.197 Regulated medical waste. (a) General provisions. Non-bulk packagings, Large Packagings, and non-specification bulk outer

packagings used for the transportation of regulated medical waste or clinical waste or (bio) medical waste must be rigid containers meeting the provisions of subpart B of this part.

(b) Non-bulk packagings. Except as provided in § 173.134(c) of this subpart, non-bulk packagings


for regulated medical waste or clinical waste or (bio) medical waste must be UN standard packagings conforming to the requirements of Part 178 of this subchapter at the Packing Group II performance level. A non-bulk packaging used as a sharps container must be puncture-resistant for sharps and sharps with residual fluid as demonstrated by conducting the performance tests in Part 178, subpart M, of this subchapter on packagings containing materials representative of the sharps and fluids (such as sterile sharps) intended to be transported in the packagings. Sharps containers must be securely closed to prevent leaks or punctures in conformance with the instructions provided by the packaging manufacturer in accordance with § 178.2(c) of this subchapter.

(c) Large Packagings. Large Packagings constructed, tested, and marked in accordance with the

requirements of the UN Recommendations (IBR, see § 171.7 of this subchapter) and conforming to other requirements of this paragraph (c) may be used for the transportation of regulated medical waste, provided the waste is contained in inner packagings conforming to the requirements of paragraph (e) of this section. Each Large Packaging design must be capable of meeting the vibration test specified in § 178.819 of this subchapter. Each Large Packaging is subject to the periodic design requalification requirements for IBCs in § 178.801(e) of this subchapter, and to the proof of compliance requirements of § 178.801(j) and record retention requirements of § 178.801(l) of this subchapter. Inner packagings used for liquids must be rigid.

(1) Authorized packagings. Only the following Large Packagings are authorized for the

transportation of liquid or solid regulated medical waste:

(i) Metal: 50A, 50B, or 50N. (ii) Rigid plastic: 50H.

(2) Additional requirements. Each Large Packaging used to transport liquid regulated

medical waste must contain absorbent material in sufficient quantity and appropriate location to absorb the entire amount of liquid present in the event of an unintentional release of contents. Each Large Packaging design intended for the transportation of sharps containers must be puncture resistant and capable of retaining liquids. The design must also be tested and certified as meeting the performance tests specified for intermediate bulk containers intended for the transportation of liquids in subpart O of part 178 of this subchapter.

(d) Non-specification bulk packaging. A wheeled cart (Cart) or bulk outer packaging (BOP) is

authorized as an outer packaging for the transportation of regulated medical waste in accordance with the provisions of this paragraph (d).

(1) General requirements. The following requirements apply to the transportation of

regulated medical waste in Carts or BOPs:

(i) Regulated medical waste in each Cart or BOP must be contained in nonbulk inner packagings conforming to paragraph (e) of this section.

(ii) Each Cart or BOP must have smooth, non-porous interior surfaces free of

cracks, crevices, and other defects that could damage plastic film inner packagings or impede disinfection operations.

(iii) Except as otherwise provided in this paragraph (d), each Cart or BOP must be

used exclusively for the transportation of regulated medical waste. Prior to reuse, each Cart or BOP must be disinfected by any means effective for neutralizing the infectious substance the packaging previously contained.

(iv) Untreated concentrated stock cultures of infectious substances containing

Category A materials may not be transported in a Cart or BOP. (v) Division 6.1 toxic waste or Class 7 radioactive waste, with the exception of


chemotherapeutic waste, may not be transported in a Cart or BOP. (vi) Division 6.1 or Class 7 chemotherapeutic waste; untreated concentrated stock

cultures of infectious substances containing Category B infectious substances; unabsorbed liquids; and sharps containers may be transported in a Cart or BOP only if packaged in rigid non-bulk packagings conforming to paragraph (a) of this section.

(2) Wheeled cart (Cart). A Cart is authorized as an outer packaging for the transportation of

regulated medical waste if it conforms to the following requirements:

(i) Each Cart must consist of a solid, one-piece body with a nominal volume not exceeding 1,655 L (437 gallons).

(ii) Each Cart must be constructed of metal, rigid plastic, or fiberglass fitted with a lid

to prevent leakage during transport. (iii) Each Cart must be capable of meeting the requirements of § 178.810 (drop test)

at the Packing Group II performance level. (iv) Inner packagings must be placed into a Cart and restrained in such a manner as

to minimize the risk of breakage. (3) Bulk outer packaging (BOP). A BOP is authorized as an outer packaging for regulated

medical waste if it conforms to the following requirements:

(i) Each BOP must be constructed of metal or fiberglass and have a capacity of at least 3.5 cubic meters (123.6 cubic feet) and not more than 45 cubic meters (1,590 cubic feet).

(ii) Each BOP must have bottom and side joints of fully welded or seamless

construction and a rigid, weatherproof top to prevent the intrusion of water (e.g., rain or snow).

(iii) Each opening in a BOP must be fitted with a closure to prevent the intrusion of

water or the release of any liquid during all loading, unloading, and transportation operations.

(iv) In the upright position, each BOP must be leakproof and able to contain a liquid

quantity of at least 300 liters (79.2 gallons) with closures open. (v) Inner packagings must be placed in a BOP in such a manner as to minimize the

risk of breakage. Rigid inner packagings may not be placed in the same BOP with plastic film bag inner packagings unless separated from each other by rigid barriers or dividers to prevent damage to the packagings caused by load shifting during normal conditions of transportation.

(vi) Division 6.1 or Class 7 chemotherapeutic waste, untreated concentrated stock

cultures of infectious substances containing Category B infectious substances, unabsorbed liquids, and sharps may be transported in a BOP only if separated and secured as required in paragraph (d)(3)(v) of this section.

(e) Inner packagings authorized for Large Packagings, Carts, and BOPs. After September 30, 2003,

inner packagings must be durably marked or tagged with the name and location (city and state) of the offeror, except when the entire contents of the Large Packaging, Cart, or BOP originates at a single location and is delivered to a single location.

(1) Solids. A plastic film bag is authorized as an inner packaging for solid regulated medical

waste transported in a Cart, Large Packaging, or BOP. Waste material containing


absorbed liquid may be packaged as a solid in a plastic film bag if the bag contains sufficient absorbent material to absorb and retain all liquid during transportation.

(i) The film bag may not exceed a volume of 175 L (46 gallons). The film bag must

be marked and certified by its manufacturer as having passed the tests prescribed for tear resistance in ASTM D 1922, "Standard Test Method for Propagation Tear Resistance of Plastic Film and Thin Sheeting by Pendulum Method" (IBR, § 171.7 of this subchapter) and for impact resistance in ASTM D 1709, "Standard Test Methods for Impact Resistance of Plastic Film by the Free-Falling Dart Method" (IBR, § 171.7 of this subchapter). The film bag must meet an impact resistance of 165 grams and a tearing resistance of 480 grams in both the parallel and perpendicular planes with respect to the length of the bag.

(ii) The plastic film bag must be closed with a minimum of entrapped air to prevent

leakage in transportation. The bag must be capable of being held in an inverted position with the closed end at the bottom for a period of 5 minutes without leakage.

(iii) When used as an inner packaging for Carts or BOPs, a plastic film bag may not

weigh more than 10 kg (22 lbs.) when filled. (2) Liquids. Liquid regulated medical waste or clinical waste or (bio) medical waste

transported in a Large Packaging, Cart, or BOP must be packaged in a rigid inner packaging conforming to the provisions of subpart B of this part. Liquid materials are not authorized for transportation in inner packagings having a capacity greater than 19 L (5 gallons).

(3) Sharps. Sharps transported in a Large Packaging, Cart, or BOP must be packaged in a

puncture-resistant inner packaging (sharps container). Each sharps container must be securely closed to prevent leaks or punctures in conformance with instructions provided by the packaging manufacturer. Each sharps container exceeding 76 L (20 gallons) in volume must be capable of passing the performance tests in Part 178, subpart M, of this subchapter at the Packing Group II performance level. A sharps container may be reused only if it conforms to the following criteria:

(i) The sharps container is specifically approved and certified by the U.S. Food and

Drug Administration as a medical device for reuse. (ii) The sharps container must be permanently marked for reuse. (iii) The sharps container must be disinfected prior to reuse by any means effective

for the infectious substance the container previously contained. (iv) The sharps container must have a capacity greater than 7.57 L (2 gallons) and

not greater than 151.42 L (40 gallons) in volume. 173.198 Nickel carbonyl. (a) Nickel carbonyl must be packed in specification steel or nickel cylinders as prescribed for any

compressed gas except acetylene. A cylinder used exclusively for nickel carbonyl may be given a complete external visual inspection instead of the pressure test required by § 180.205 of this subchapter. Visual inspection must be in accordance with CGA Pamphlet C-6 (incorporated by reference; see § 171.7 of this subchapter).

(b) Packagings for nickel carbonyl must conform to §173.40. 173.199 Category B infectious substances. (a) Category B infectious substances. Except as provided in this paragraph (a), Category B infectious


substances are excepted from all other requirements of this subchapter when offered for transportation or transported in accordance with this section. Category B infectious substances offered for transportation or transported under the provisions of this section are subject to the incident reporting requirements in § § 171.15 and 171.16 of this subchapter and to the requirements in § 175.75(b) of this subchapter concerning cargo location. Except as provided in paragraph (a)(9) of this section, a Category B infectious substance meeting the definition of a hazard class other than Division 6.2 must be offered for transportation or transported in accordance with applicable requirements of this subchapter.

(1) A Category B infectious substance must be packaged in a triple packaging consisting of a

primary receptacle, a secondary packaging, and a rigid outer packaging. (2) Primary receptacles must be packed in secondary packaging in such a way that, under

normal conditions of transport, they cannot break, be punctured, or leak their contents into the secondary packaging.

(3) Secondary packagings must be secured in rigid outer packagings with suitable

cushioning material such that any leakage of the contents will not impair the protective properties of the cushioning material or the outer packaging.

(4) The completed package must be designed, constructed, maintained, filled, its contents

limited, and closed so that under conditions normally encountered in transportation, including removal from a pallet or overpack for subsequent handling, there will be no release of hazardous material into the environment. Package effectiveness must not be substantially reduced for minimum and maximum temperatures, changes in humidity and pressure, and shocks, loadings and vibrations normally encountered during transportation. The packaging must be capable of successfully passing the drop test in § 178.609(d) of this subchapter at a drop height of at least 1.2 meters (3.9 feet). Following the drop test, there must be no leakage from the primary receptacle, which must remain protected by absorbent material, when required, in the secondary packaging. At least one surface of the outer packaging must have a minimum dimension of 100 mm by 100 mm (3.9 inches).

(5) (5) The following square-on-point mark must be displayed on the outer packaging on a

background of contrasting color. The width of the line forming the border must be at least 2 mm (0.08 inches) and the letters and numbers must be at least 6 mm (0.24 inches) high. The size of the mark must be such that no side of the diamond is less than 50 mm (1.97 inches) in length as measured from the outside of the lines forming the border. The proper shipping name “Biological substances, Category B” must be marked on the outer packaging adjacent to the diamond-shaped mark in letters that are at least 6 mm (0.24 inches) high.

(i) Transitional exception—A marking in conformance with the requirements of this

paragraph in effect on December 31, 2014, may continue to be used until December 31, 2016.

(ii) For domestic transportation, a packaging marked prior to January 1, 2017 and in conformance with the requirements of this paragraph in effect on December 31, 2014, may continue in service until the end of its useful life.


(6) When packages are placed in an overpack, the package markings required by this

section must be either clearly visible or reproduced on the outside of the overpack. (7) The name and telephone number of a person who is either knowledgeable about the

material being shipped and has comprehensive emergency response and incident mitigation information for the material, or has immediate access to a person who possesses such knowledge and information, must be included on a written document (such as an air waybill or bill of lading) or on the outer packaging.

(8) For transportation by aircraft, each package, overpack, pallet, or unit load device

containing a Category B infectious substance must be inspected for leakage when it is unloaded from the aircraft. If evidence of leakage is found, the cargo compartment in which the package, overpack, pallet, or unit load device was transported must be disinfected. Disinfection may be by any means that will make the material released ineffective at transmitting disease.

(9) A packaging containing inner packagings of Category B infectious substances may not

contain other hazardous materials except-

(i) Refrigerants, such as dry ice or liquid nitrogen, as authorized under paragraph (d) of this section;

(ii) Anticoagulants used to stabilize blood or plasma; or (iii) Small quantities of Class 3, Class 8, Class 9, or other materials in Packing

Groups II and III used to stabilize or prevent degradation of the sample, provided the quantity of such materials does not exceed 30 mL (1 ounce) or 30 g (1 ounce) in each inner packaging. Such preservatives are not subject to the requirements of this subchapter.

(10) Clear instructions on filling and closing a packaging used to transport a Category B

infectious substance must be provided by the packaging manufacturer and subsequent distributors to the consignor or person who prepares the package to enable the package to be correctly prepared for transport. A copy or electronic image of these instructions must be retained by the manufacturer and subsequent distributors for at least one year from the date of issuance, and made available for inspection by a Federal or state government representative upon request. Packagings must be filled and closed in accordance with the information provided by the packaging manufacturer or subsequent distributor.

(b) Liquid Category B infectious substances. Liquid Category B infectious substances must be

packaged in conformance with the following provisions:

(1) The primary receptacle must be leakproof. (2) Absorbent material must be placed between the primary receptacle and secondary

packaging. If several fragile primary receptacles are placed in a single secondary packaging, they must be either individually wrapped or separated to prevent contact between them. The absorbent material must be of sufficient quantity to absorb the entire contents of the primary receptacles and not compromise the integrity of the cushioning material or the outer packaging.

(3) The secondary packaging must be leakproof. (4) For shipments by aircraft, the primary receptacle or the secondary packaging must be

capable of withstanding without leakage an internal pressure producing a pressure differential of not less than 95 kPa (0.95 bar, 14 psi).


(5) For shipments by aircraft, the maximum quantity contained in each primary receptacle,

including any material used to stabilize or prevent degradation of the sample, may not exceed 1 L (34 ounces), and the maximum quantity contained in each outer packaging, including any material used to stabilize or prevent degradation of the samples, may not exceed 4 L (1 gallon). The outer packaging limitation does not include ice, dry ice, or liquid nitrogen when used to maintain the integrity of the material.

(c) Solid Category B infectious substances. Solid Category B infectious substances must be

packaged in a triple packaging, consisting of a primary receptacle, secondary packaging, and outer packaging, conforming to the following provisions:

(1) The primary receptacle must be siftproof. (2) If several fragile primary receptacles are placed in a single secondary packaging, they

must be either individually wrapped or separated to prevent contact between them. (3) The secondary packaging must be siftproof. (4) If residual liquid may be present in the primary receptacle during transportation, then the

material must be transported in accordance with requirements in paragraph (b) of this section. A solid material that may become liquid during transportation must be transported in accordance with paragraph (b) of this section.

(5) Except for packages containing body parts, organs, or whole bodies, for shipment by

aircraft, the outer packaging may not contain more than 4 kg (8.8 pounds), including any material used to stabilize or prevent degradation of the samples. The outer packaging limitation does not include ice, dry ice, or liquid nitrogen when used to maintain the integrity of the material.

(d) Refrigerated or frozen specimens (ice, dry ice, and liquid nitrogen). In addition to complying with

the requirements in this paragraph (d), dry ice and liquid nitrogen must be offered for transportation or transported in accordance with the applicable requirements of this subchapter.

(1) Ice or dry ice must be placed outside the secondary packaging or in an overpack. Interior

supports must be provided to secure the secondary packagings in the original position. If ice is used, the outside packaging must be leakproof or must have a leakproof liner. If dry ice is used, the outside packaging must permit the release of carbon dioxide gas and otherwise meet the provisions in § 173.217. The primary receptacle and secondary packaging must maintain their integrity at the temperature of the refrigerant used, as well as the temperatures and pressures of transport by aircraft they could be subjected to if refrigeration were lost, and sufficient absorbent material must be provided to absorb all liquid, including melted ice.

(2) The package is marked "Carbon dioxide, solid" or "Dry ice" and an indication that the

material being refrigerated is used for diagnostic treatment purposes (e.g., frozen medical specimens).

(e) Training. Each person who offers or transports a Category B infectious substance under the

provisions of this section must know about the requirements of this section. 173.201 Non-bulk packagings for liquid hazardous materials in Packing Group I. (a) When §172.101 of this subchapter specifies that a liquid hazardous material be packaged under

this section, only non-bulk packagings prescribed in this section may be used for its transportation. Each packaging must conform to the general packaging requirements of subpart B of part 173, to the requirements of part 178 of this subchapter at the Packing Group I performance level, and to the requirements of the special provisions of Column 7 of the §172.101 Table.


(b) The following combination packagings are authorized:

Outer packagings: Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Metal drum other than steel or aluminum: 1N1 or 1N2 Plywood drum: 1D Fiber drum: 1G Plastic drum: 1H1 or 1H2 Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Steel box: 4A Aluminum box: 4B Natural wood box: 4C1 or 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Expanded plastic box: 4H1 Solid plastic box: 4H2 Metal box other than steel or aluminum: 4N Inner packagings: Glass or earthenware receptacles Plastic receptacles Metal receptacles Glass ampoules

(c) Except for transportation by passenger aircraft, the following single packagings are authorized:

Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Metal drum other than steel, or aluminum: 1N1 or 1N2 Plastic drum: 1H1 or 1H2 Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Plastic receptacle in steel, aluminum, fiber or plastic drum: 6HA1, 6HB1, 6HG1, 6HH1 Plastic receptacle in steel, aluminum, wooden, plywood or fiberboard box: 6HA2, 6HB2, 6HC, 6HD2 or 6HG2 Glass, porcelain or stoneware in steel, aluminum or fiber drum: 6PA1, 6PB1 or 6PG1 Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB2, 6PC or 6PG2 Glass, porcelain or stoneware in solid or expanded plastic packaging: 6PH1 or 6PH2 Cylinders, specification or UN standard, as prescribed for any compressed gas, except for Specifications 8 and 3HT and those described for Acetylene.

173.202 Non-bulk packagings for liquid hazardous materials in Packing Group II. (a) When §172.101 of this subchapter specifies that a liquid hazardous material be packaged under

this section, only non-bulk packagings prescribed in this section may be used for its transportation. Each packaging must conform to the general packaging requirements of subpart B of part 173, to the requirements of part 178 of this subchapter at the Packing Group I or II performance level (unless otherwise excepted), and to the particular requirements of the special provisions of Column 7 of the §172.101 Table.


Outer packagings: Steel drum: 1A1 or 1A2


Aluminum drum: 1B1 or 1B2 Metal drum other than steel or aluminum: 1N1 or 1N2 Plywood drum: 1D Fiber drum: 1G Plastic drum: 1H1 or 1H2 Wooden barrel: 2C2 Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Steel box: 4A Aluminum box: 4B Natural wood box: 4C1 or 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Expanded plastic box: 4H1 Solid plastic box: 4H2

Metal box other than steel or aluminum: 4N

Inner packagings: Glass or earthenware receptacles Plastic receptacles Metal receptacles Glass ampoules


Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Metal drum other than steel or aluminum: 1N1 or 1N2 Plastic drum: 1H1 or 1H2 Fiber drum: 1G (with liner) Wooden barrel: 2C1 Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Plastic receptacle in steel, aluminum, fiber or plastic drum: 6HA1, 6HB1, 6HG1 or 6HH1 Plastic receptacle in steel, aluminum, wooden, plywood or fiberboard box: 6HA2, 6HB2, 6HC, 6HD2 or 6HG2 Glass, porcelain or stoneware in steel, aluminum or fiber drum: 6PA1, 6PB1 or 6PG1 Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB2, 6PC or 6PG2 Glass, porcelain or stoneware in solid or expanded plastic packaging: 6PH1 or 6PH2 Plastic receptacle in plywood drum: 6HD1 Glass, porcelain or stoneware in plywood drum or wickerwork hamper: 6PDl or 6PD2 Cylinders, specification, as prescribed for any compressed gas, except for Specifications 8 and 3HT

173.203 Non-bulk packagings for liquid hazardous materials in Packing Group III. (a) When §172.101 of this subchapter specifies that a liquid hazardous material be packaged under

this section, only non-bulk packagings prescribed in this section may be used for its transportation. Each packaging must conform to the general packaging requirements of subpart B of part 173, to the requirements of part 178 of this subchapter at the Packing Group I, II or III performance level, and to the requirements of the special provisions of Column 7 of the §172.101 Table.



Outer packagings: Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Metal drum other than steel or aluminum: 1N1 or 1N2 Plywood drum: 1D Fiber drum: 1G Plastic drum: 1H1 or 1H2 Wooden barrel: 2C2 Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Steel box: 4A Aluminum box: 4B Natural wood box: 4C1 or 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Expanded plastic box: 4H1 Solid plastic box: 4H2



(c) The following single packagings are authorized:

Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Metal drum other than steel or aluminum: 1N1 Plastic drum: 1H1 or 1H2 Fiber drum: 1G (with liner) Wooden barrel: 2C1 Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Plastic receptacle in steel, aluminum, fiber or plastic drum: 6HA1, 6HB1, 6HG1 or 6HH1 Plastic receptacle in steel, aluminum, wooden, plywood or fiberboard box: 6HA2, 6HB2, 6HC, 6HD2 or 6HG2 Glass, porcelain or stoneware in steel, aluminum or fiber drum: 6PA1, 6PB1, or 6PG1 Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB2, 6PC or 6PG2 Glass, porcelain or stoneware in solid or expanded plastic packaging: 6PH1 or 6PH2 Plastic receptacle in plywood drum: 6HD1 Glass, porcelain or stoneware in plywood drum or wickerwork hamper: 6PD1 or 6PD2 Cylinders, as prescribed for any compressed gas, except for Specifications 8 and 3HT

173.204 Non-bulk, non-specification packagings for certain hazardous materials. When §172.101 of this subchapter specifies that a liquid or solid hazardous material be packaged under this section, any appropriate non-bulk packaging which conforms to the general packaging requirements of subpart B of part 173 may be used for its transportation. Packagings need not conform to the requirements of part 178 of this subchapter. 173.205 Specification cylinders for liquid hazardous materials.


When 172.101 of this subchapter specifies that a hazardous material must be packaged under this section, the use of any specification or UN cylinder, except those specified for acetylene, is authorized. Cylinders used for toxic materials in Division 6.1 or 2.3 must conform to the requirements of 173.40. 173.206 Packaging requirements for chlorosilanes.

(a) When § 172.101 of this subchapter specifies that a hazardous material be packaged under this section, only nonbulk packagings prescribed in this section may be used for its transportation. Each packaging must conform to the general packaging requirements of subpart B of part 173, to the requirements of part 178 of this subchapter at the Packing Group I or II performance level (unless otherwise excepted), and to the particular requirements of the special provisions of Column (7) of the § 172.101 Table.


Outer packagings: Steel drum: 1A2 Plastic drum: 1H2 Plywood drum: 1D Fiber drum: 1G Steel box: 4A Natural wood box: 4C1 or 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Expanded plastic box: 4H1 Solid plastic box: 4H2

Inner packagings:

Glass or Steel receptacle (c) Except for transportation by passenger aircraft, the following single packagings are authorized:

Steel drum: 1A1 Steel jerrican: 3A1 Plastic receptacle in steel drum: 6HA1 Cylinders (for liquids in PG I), specification or UN standard, as prescribed for any compressed gas, except Specification 3HT and those prescribed for acetylene. Cylinders (for liquids in PG II), specification, as prescribed for any compressed gas, except Specification 8 and 3HT cylinders.

173.211 Non-bulk packagings for solid hazardous materials in Packing Group I. (a) When §172.101 of this subchapter specifies that a solid hazardous material be packaged under

this section, only non-bulk packagings prescribed in this section may be used for its transportation. Each package must conform to the general packaging requirements of subpart B of part 173, to the requirements of part 178 of this subchapter at the Packing Group I performance level, and to the requirements of the special provisions of Column 7 of the §172.101 Table.


Outer packagings: Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Metal drum other than steel or aluminum: 1N1 or 1N2 Plywood drum: 1D Fiber drum: 1G


Plastic drum: 1H1 or 1H2 Wooden barrel: 2C2 Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Steel box: 4A Aluminum box: 4B Natural wood box: 4C1 or 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Solid plastic box: 4H2




Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Metal drum other than steel or aluminum: 1N1 or 1N2 Plastic drum: 1H1 or 1H2 Fiber drum: 1G Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Steel box with liner: 4A Aluminum box with liner: 4B

Metal box other than steel or aluminum: 4N Natural wood box, sift proof: 4C2 Plastic receptacle in steel, aluminum, plywood, fiber or plastic drum: 6HA1, 6HB1, 6HD1, 6HG1 or 6HH1 Glass, porcelain or stoneware in steel, aluminum, plywood or fiber drum: 6PA1, 6PB1, 6PD1 or 6PG1 Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB2, 6PC or 6PG2 Glass, porcelain or stoneware in expanded or solid plastic packaging: 6PH1 or 6PH2 Cylinders, as prescribed for any compressed gas, except for Specification 8 and 3HT

173.212 Non-bulk packagings for solid hazardous materials in Packing Group II. (a) When §172.101 of this subchapter specifies that a solid hazardous material be packaged under

this section, only non-bulk packagings prescribed in this section may be used for its transportation. Each package must conform to the general packaging requirements of subpart B of part 173, to the requirements of part 178 of this subchapter at the Packing Group I or II performance level, and to the requirements of the special provisions of Column 7 of the §172.101 Table.


Outer packagings: Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Metal drum other than steel or aluminum: 1N1 or 1N2 Plywood drum: 1D Fiber drum: 1G


Plastic drum: 1H1 or 1H2 Wooden barrel: 2C2 Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Steel box: 4A Aluminum box: 4B Natural wood box: 4C1 or 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Solid plastic box: 4H2




Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Plywood drum: 1D Plastic drum: 1H1 or 1H2 Fiber drum: 1G Metal drum other than steel or aluminum: 1N1 or 1N2 Wooden barrel: 2C1 or 2C2 Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Steel box: 4A Steel box with liner: 4A Aluminum box: 4B Aluminum box with liner: 4B

Metal box other than steel or aluminum: 4N Natural wood box: 4C1 Natural wood box, sift proof: 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Expanded plastic box: 4H1 Solid plastic box: 4H2 Bag, woven plastic: 5H1, 5H2 or 5H3 Bag, plastic film: 5H4 Bag, textile: 5L1, 5L2 or 5L3 Bag, paper, multiwall, water resistant: 5M2 Plastic receptacle in steel, aluminum, plywood, fiber or plastic drum: 6HA1, 6HB1, 6HD1, 6HG1 or 6HH1 Plastic receptacle in steel, aluminum, wood, plywood or fiberboard box: 6HA2, 6HB2, 6HC, 6HD2 or 6HG2 Glass, porcelain or stoneware in steel, aluminum, plywood or fiber drum: 6PA1, 6PB1, 6PD1 or 6PG1 Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB2, 6PC, or 6PG2 Glass, porcelain or stoneware in expanded or solid plastic packaging: 6PH1 or 6PH2 Cylinders, as prescribed for any compressed gas, except for Specification 8 and 3HT

173.213 Non-bulk packagings for solid hazardous materials in Packing Group III.


(a) When §172.101 of this subchapter specifies that a solid hazardous material be packaged under

this section, only non-bulk packagings prescribed in this section may be used for its transportation. Each package must conform to the general packaging requirements of subpart B of part 173, to the requirements of part 178 of this subchapter at the Packing Group I, II or III performance level, and to the requirements of the special provisions of Column 7 of the §172.101 Table.


Outer packagings: Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Metal drum other than steel or aluminum: 1N1 or 1N2 Plywood drum: 1D Fiber drum: 1G Plastic drum: 1H1 or 1H2 Wooden barrel: 2C2 Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Steel box: 4A Aluminum box: 4B Natural wood box: 4C1 or 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Solid plastic box: 4H2



(c) The following single packagings are authorized:

Steel drum: 1A1 or 1A2 Aluminum drum: 1B1 or 1B2 Plywood drum: 1D Plastic drum: 1H1 or 1H2 Fiber drum: 1G Metal drum other than steel or aluminum: 1N1 or 1N2 Wooden barrel: 2C1 or 2C2 Steel jerrican: 3A1 or 3A2 Plastic jerrican: 3H1 or 3H2 Aluminum jerrican: 3B1 or 3B2 Steel box: 4A Steel box with liner: 4A Aluminum box: 4B Aluminum box with liner: 4B

Metal box other than steel or aluminum: 4N Natural wood box: 4C1 Natural wood box, sift proof: 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Expanded plastic box: 4H1 Solid plastic box: 4H2


Bag, woven plastic: 5H1, 5H2 or 5H3 Bag, plastic film: 5H4 Bag, textile: 5L1, 5L2 or 5L3 Bag, paper, multiwall, water resistant: 5M2 Plastic receptacle in steel, aluminum, plywood, fiber or plastic drum: 6HA1, 6HB1, 6HD1, 6HG1 or 6HH1 Plastic receptacle in steel, aluminum, wood, plywood or fiberboard box: 6HA2, 6HB2, 6HC, 6HD2 or 6HG2 Glass, porcelain or stoneware in steel, aluminum, plywood or fiber drum: 6PA1, 6PB1, 6PD1 or 6PG1 Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB2, 6PC, or 6PG2 Glass, porcelain or stoneware in expanded or solid plastic packaging: 6PH1 or 6PH2 Cylinders, as prescribed for any compressed gas, except for Specification 8 and 3HT

173.214 Packagings which require approval by the Associate Administrator. When §172.101 of this subchapter specifies that a hazardous material be packaged under this section, packagings and method of shipment must be approved by the Associate Administrator prior to the first shipment. 173.216 Asbestos, blue, brown or white. (a) Asbestos, blue, brown or white, includes each of the following hydrated mineral silicates:

chrysolite, crocidolite, amosite, anthophyllite asbestos, tremolite asbestos, actinolite asbestos, and every product containing any of these materials.

(b) [Reserved] (c) Packagings for asbestos must conform to the general packaging requirements of subpart B of this

part but need not conform to the requirements of part 178 of this subchapter. Asbestos must be offered for transportation and transported in–

(1) Rigid, leaktight packagings,, such as metal, plastic or fiber drums, portable tanks, hopper-

type rail cars, hopper-type motor vehicles or additional bulk packagings authorized in § 173.240;

(2) Bags or other non-rigid packagings in closed freight containers, motor vehicles, or rail

cars that are loaded by and for the exclusive use of the consignor and unloaded by the consignee;

(3) Bags or other non-rigid packagings which are dust and sift proof must be placed in rigid

outer packagings or closed freight containers. 173.217 Carbon dioxide, solid (dry ice). (a) Carbon dioxide, solid (dry ice), when offered for transportation or transported by aircraft or water,

must be packed in packagings designed and constructed to permit the release of carbon dioxide gas to prevent a buildup of pressure that could rupture the packagings. Packagings must conform to the general packaging requirements of subpart B of this part but need not conform to the requirements of part 178 of this subchapter.

(b) For transportation by vessel:

(1) Each transport vehicle and freight container containing solid carbon dioxide must be conspicuously marked on two sides ``WARNING CO2 SOLID (DRY ICE).''


(2) Other packagings containing solid carbon dioxide must be marked ``CARBON DIOXIDE,

SOLID--DO NOT STOW BELOW DECKS.'' (c) For transportation by aircraft:

(1) In addition to the applicable marking requirements in subpart D of part 172, the net mass of the carbon dioxide, solid (dry ice) must be marked on the outside of the package. This provision also applies to unit load devices (ULDs) when the ULD contains dry ice and is considered the packaging.

(2) The shipper must make arrangements with the operator for each shipment. (3) The quantity limits per package shown in columns (9A) and (9B) of the Hazardous

Materials Table in § 172.101 of this subchapter are not applicable to dry ice being used as a refrigerant for other than hazardous materials loaded in a unit load device. In such a case, the unit load device must be identified to the operator and allow the venting of the carbon dioxide gas to prevent a dangerous build-up of pressure.

(4) Dry ice is excepted from the shipping paper requirements of subpart C of part 172 of this

subchapter provided alternative written documentation is supplied containing the following information: proper shipping name (Dry ice or Carbon dioxide, solid), class 9, UN number 1845, the number of packages, and the net quantity of dry ice in each package. The information must be included with the description of the materials.

(5) Carbon dioxide, solid (dry ice), in quantities not exceeding 2.5 kg (5.5 pounds) per

package and used as a refrigerant for the contents of the package is excepted from all other requirements of this subchapter if the requirements of paragraph (a) of this section are complied with and the package is marked ``Carbon dioxide, solid'' or ``Dry ice'', is marked with the name of the contents being cooled, and is marked with the net weight of the dry ice or an indication that the net weight is 2.5 kg (5.5 pounds) or less.

(d) Carbon dioxide, solid (dry ice), when used to refrigerate materials being shipped for diagnostic or

treatment purposes (e.g., frozen medical specimens), is excepted from the shipping paper and certification requirements of this subchapter if the requirements of paragraphs (a) and (c)(2) of this section are met and the package is marked ``Carbon dioxide, solid'' or ``Dry ice'' and is marked with an indication that the material being refrigerated is being transported for diagnostic or treatment purposes.

173.218 Fish meal or fish scrap. (a) Except as provided in Column (7) of the HMT in § 172.101 of this subchapter, fish meal or fish

scrap, containing at least 6%, but not more than 12% water, is authorized for transportation by vessel only when packaged as follows:

(1) Burlap (jute) bag;

(2) Multi-wall paper bag;

(3) Polyethylene-lined burlap or paper bag;

(4) Cargo tank;

(5) Portable tank;

(6) Rail car; or

(7) Freight container.


(b) [Reserved] (c) When fish scrap or fish meal is offered for transportation by vessel in bulk in freight containers,

the fish scrap or fish meal shall contain at least 50 ppm (mg/kg) of ethoxyquin, 100 ppm (mg/kg) of butylated hydroxytoluene (BHT) or 250 ppm (mg/kg) of tocopherol based antioxidant at the time of shipment

173.219 Life-saving appliances. (a) A life-saving appliance, self-inflating or non-self-inflating, containing small quantities of hazardous

materials that are required as part of the life-saving appliance must conform to the requirements of this section. Packagings must conform to the general packaging requirements of subpart B of this part but need not conform to the requirements of part 178 of this subchapter. The appliances must be packed, so that they cannot be accidentally activated and, except for life vests, the hazardous materials must be in inner packagings packed so as to prevent shifting within the outer packaging. The hazardous materials must be an integral part of the appliance and in quantities that do not exceed those appropriate for the actual appliance when in use.

(b) Life saving appliances may contain:

(1) Division 2.2 compressed or liquefied gases must be packaged in cylinders in accordance with the requirements of this subchapter;

(2) Signal devices (Class 1), which may include smoke and illumination signal flares;

(3) Electric storage batteries and lithium batteries (life-saving appliances containing lithium

batteries must be packed in accordance with §173.185 and Special Provisions A54 and A101 as applicable.);

(4) First aid or repair kits conforming to the applicable material and quantity limitations of §

173.161 of this subchapter;

(5) Strike-anywhere matches;

(6) For self-inflating life saving appliances only, cartridges power device of Division 1.4S, for purposes of the self-inflating mechanism provided that the quantity of explosives per appliance does not exceed 3.2 g; or

(7) Limited quantities of other hazardous materials.

(c) Hazardous materials in life saving appliances must be packaged as follows:

(1) Division 2.2 compressed or liquefied gases must be packaged in cylinders in accordance with the requirements of this subchapter;

(2) Signal devices (Class 1) must be in packagings that prevent them from being

inadvertently activated;

(3) Strike-anywhere matches must be cushioned to prevent movement or friction in a metal or composition receptacle with a screw-type closure in a manner that prevents them from being inadvertently activated;

(4) Limited quantities of other hazardous materials must be packaged in accordance with the

requirements of this subchapter; and

(5) Life-saving appliances containing no hazardous materials other than cylinders of Division 2.2 compressed or liquefied gases with no subsidiary risk, with a capacity not exceeding 120 mL, installed solely for the purpose of activating the appliance, are not subject to the provisions of this subchapter provided they are overpacked in rigid outer packagings with


a maximum gross mass of 40 kg. For transportation by aircraft, such appliances must be transported as cargo and may not be carried onboard an aircraft by passengers or crewmembers in carry-on baggage, checked baggage, or on their person unless specifically excepted by § 175.10.

173.220 Internal combustion engines, vehicles, machinery containing internal combustion engines, battery-powered equipment or machinery, fuel cell-powered equipment or machinery. (a) Applicability. An internal combustion engine, self-propelled vehicle, machinery containing an internal

combustion engine that is not consigned under the ‘‘Dangerous goods in machinery or apparatus’’ UN 3363 entry, a battery-powered vehicle or equipment, or a fuel cell-powered vehicle or equipment, or any combination thereof, is subject to the requirements of this subchapter when transported as cargo on a transport vehicle, vessel, or aircraft if— (1) The vehicle, engine, or machinery contains a liquid or gaseous fuel. Vehicles, engines, or

machinery may be considered as not containing fuel when the engine components and any fuel lines have been completely drained, sufficiently cleaned of residue, and purged of vapors to remove any potential hazard and the engine when held in any orientation will not release any liquid fuel;

(2) The fuel tank contains a liquid or gaseous fuel. A fuel tank may be considered as not containing fuel when the fuel tank and the fuel lines have been completely drained, sufficiently cleaned of residue, and purged of vapors to remove any potential hazard;

(3) It is equipped with a wet battery (including a non-spillable battery), a sodium battery or a lithium battery; or

(4) Except as provided in paragraph (f)(1) of this section, it contains other hazardous materials subject to the requirements of this subchapter.

(b) Requirements. Unless otherwise excepted in paragraph (b)(4) of this section, vehicles, engines, and

equipment are subject to the following requirements: (1) Flammable liquid fuel and fuels that are marine pollutants.

(i) A fuel tank containing a flammable liquid fuel must be drained and securely closed, except that up to 500 mL (17 ounces) of residual fuel may remain in the tank, engine components, or fuel lines provided they are securely closed to prevent leakage of fuel during transportation. Self-propelled vehicles containing diesel fuel are excepted from the requirement to drain the fuel tanks, provided that sufficient ullage space has been left inside the tank to allow fuel expansion without leakage, and the tank caps are securely closed.

(ii) Engines and machinery containing liquid fuels meeting the definition of a marine pollutant (see § 171.8 of this subchapter) and not meeting the classification criteria of any other Class or Division transported by vessel are subject to the requirements of § 176.906 of this subchapter.

(2) Flammable liquefied or compressed gas fuel. (i) For transportation by motor vehicle, rail car or vessel, fuel tanks and fuel systems containing

flammable liquefied or compressed gas fuel must be securely closed. For transportation by vessel, the requirements of §§ 176.78(k), 176.905, and 176.906 of this subchapter apply.

(ii) For transportation by aircraft: (A) Flammable gas-powered vehicles, machines, equipment or cylinders containing the

flammable gas must be completely emptied of flammable gas. Lines from vessels to gas regulators, and gas regulators themselves, must also be drained of all traces of flammable gas. To ensure that these conditions are met, gas shut-off valves must be left open and connections of lines to gas regulators must be left disconnected upon delivery of the vehicle to the operator. Shut-off valves must be closed and lines reconnected at gas regulators before loading the vehicle aboard the aircraft; or alternatively;

(B) Flammable gas powered vehicles, machines or equipment, which have cylinders (fuel tanks) that are equipped with electrically operated valves, may be transported under the following conditions: (1) The valves must be in the closed position and in the case of electrically operated

valves, power to those valves must be disconnected; (2) After closing the valves, the vehicle, equipment or machinery must be operated until

it stops from lack of fuel before being loaded aboard the aircraft; (3) In no part of the closed system shall the pressure exceed 5% of the maximum


allowable working pressure of the system or 290 psig (2000 kPa), whichever is less; and

(4) There must not be any residual liquefied gas in the system, including the fuel tank. (C) If a vehicle is powered by a flammable liquid and a flammable gas 2internal combustion

engine, the2 requirements of paragraphs (b)(1) of this section must also be met.

(3) Truck bodies or trailers on flat cars—flammable liquid or gas powered. Truck bodies or trailers with automatic heating or refrigerating equipment of the flammable liquid type may be shipped with fuel tanks filled and equipment operating or inoperative, when used for the transportation of other freight and loaded on flat cars as part of a joint rail and highway movement, provided the equipment and fuel supply conform to the requirements of § 177.834(l) of this subchapter.

(4) Modal exceptions. Quantities of flammable liquid fuel greater than 500 mL (17 ounces) may

remain in the fuel tank in self-propelled vehicles engines, and machinery only under the following conditions: (i) For transportation by motor vehicle or rail car, the fuel tanks must be securely closed. (ii) For transportation by vessel, the shipment must conform to § 176.905 of this subchapter for

self-propelled vehicles and § 176.906 of this subchapter for engines and machinery. (iii) For transportation by aircraft, when carried in aircraft designed or modified for vehicle ferry

operations when all the following conditions must be met: (A) Authorization for this type operation has been given by the appropriate authority in the

government of the country in which the aircraft is registered; (B) Each vehicle is secured in an upright position; (C) Each fuel tank is filled in a manner and only to a degree that will preclude spillage of fuel

during loading, unloading, and transportation; and (D) Each area or compartment in which a self-propelled vehicle is being transported is

suitably ventilated to prevent the accumulation of fuel vapors. (c) Battery-powered or installed. Batteries must be securely installed, and wet batteries must be

fastened in an upright position. Batteries must be protected against a dangerous evolution of heat, short circuits, and damage to terminals in conformance with § 173.159(a) and leakage; or must be removed and packaged separately under § 173.159. Battery-powered vehicles, machinery or equipment including battery-powered wheelchairs and mobility aids are not subject to any other requirements of this subchapter except § 173.21 when transported by rail, highway or vessel. Where a vehicle could possibly be handled in other than an upright position, the vehicle must be secured in a strong, rigid outer packaging. The vehicle must be secured by means capable of restraining the vehicle in the outer packaging to prevent any movement during transport which would change the orientation or cause the vehicle to be damaged.

(d) Lithium batteries. Except as provided in §172.102, special provision A101, of this subchapter,

vehicles, engines, and machinery powered by lithium metal batteries that are transported with these batteries installed are forbidden aboard passenger-carrying aircraft. Lithium batteries contained in vehicles, engines, or mechanical equipment must be securely fastened in the battery holder of the vehicle, engine, or mechanical equipment, and be protected in such a manner as to prevent damage and short circuits (e.g., by the use of non-conductive caps that cover the terminals entirely). Except for vehicles, engines, or machinery transported by highway, rail, or vessel with prototype or low production lithium batteries securely installed, each lithium battery must be of a type that has successfully passed each test in the UN Manual of Tests and Criteria (IBR, see §171.7 of this subchapter), as specified in §173.185, unless approved by the Associate Administrator. Where a vehicle could possibly be handled in other than an upright position, the vehicle must be secured in a strong, rigid outer packaging. The vehicle must be secured by means capable of restraining the vehicle in the outer packaging to prevent any movement during transport which would change the orientation or cause the vehicle to be damaged. Where the lithium battery is removed from the vehicle and is packed separate from the vehicle in the same outer packaging, the package must be consigned as “UN 3481, Lithium ion batteries packed with equipment” or “UN 3091, Lithium metal batteries packed with equipment” and prepared in accordance with the requirements specified in §173.185.

(e) Fuel cells. A fuel cell must be secured and protected in a manner to prevent damage to the fuel


cell. Equipment (other than vehicles, engines or mechanical equipment) such as consumer electronic devices containing fuel cells (fuel cell cartridges) must be described as ‘‘Fuel cell cartridges contained in equipment’’ and transported in accordance with § 173.230. Where a vehicle could possibly be handled in other than an upright position, the vehicle must be secured in a strong, rigid outer packaging. The vehicle must be secured by means capable of restraining the vehicle in the outer packaging to prevent any movement during transport which would change the orientation or cause the vehicle to be damaged.

(f) Other hazardous materials.

(1) Items containing hazardous materials, such as fire extinguishers, compressed gas accumulators, safety devices, and other hazardous materials that are integral components of the motor vehicle, engine, or mechanical equipment, and that are necessary for the operation of the vehicle, engine, or mechanical equipment, or for the safety of its operator or passengers, must be securely installed in the motor vehicle, engine, or mechanical equipment. Such items are not otherwise subject to the requirements of this subchapter. Equipment (other than vehicles, engines, or mechanical equipment), such as consumer electronic devices containing lithium batteries, must be described as ‘‘Lithium metal batteries contained in equipment’’ or ‘‘Lithium ion batteries contained in equipment,’’ as appropriate, and transported in accordance with § 173.185, and applicable special provisions. Equipment (other than vehicles, engines, or mechanical equipment), such as consumer electronic devices containing fuel cells (fuel cell cartridges), must be described as ‘‘Fuel cell cartridges contained in equipment’’ and transported in accordance with § 173.230.

(2) Other hazardous materials must be packaged and transported in accordance with the

requirements of this subchapter. (g) Additional requirements for internal combustion engines and vehicles with certain electronic

equipment when transported by aircraft or vessel. When an internal combustion engine that is not installed in a vehicle or equipment is offered for transportation by aircraft or vessel, all fuel, coolant or hydraulic systems remaining in the engine must be drained as far as practicable, and all disconnected fluid pipes that previously contained fluid must be sealed with leak-proof caps that are positively retained. When offered for transportation by aircraft, vehicles equipped with theft-protection devices, installed radio communications equipment or navigational systems must have such devices, equipment or systems disabled.

(h) Exceptions. Except as provided in paragraph (f)(2) of this section, shipments made under the

provisions of this section— (1) Are not subject to any other requirements of this subchapter for transportation by motor

vehicle or rail car; (2) Are not subject to the requirements of subparts D, E, and F (marking, labeling and

placarding, respectively) of part 172 of this subchapter or § 172.604 of this subchapter (emergency response telephone number) for transportation by aircraft. For transportation by aircraft, the provisions of § 173.159(b)(2) as applicable, the provisions of § 173.230(f), as applicable, other applicable requirements of this subchapter, including shipping papers, emergency response information, notification of pilot-in-command, general packaging requirements, and the requirements specified in § 173.27 must be met; and

(3) For exceptions for transportation by vessel; see § 176.905 of this subchapter for vehicles, and § 176.906 of this subchapter for engines and machinery.

173.221 Polymeric beads, expandable. (a) Non-bulk shipments of Polymeric beads (or granules), expandable evolving flammable vapor and

Plastic molding compound in dough, sheet or extruded rope form, evolving flammable vapor must be packed in: metal (4A, 4B, or 4N), wooden (4C1 or 4C2), plywood (4D), fiberboard (4G), reconstituted wood (4F), plastic (4H1 or 4H2) boxes, plywood drums (1D) or fiber drums (1G) with sealed inner plastic liners; in vapor tight metal or plastic drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1 or 1H2); in vapor tight metal or plastic jerricans (3A1, 3A2, 3B1, 3B2, 3H1, or 3H2); or packed in non-specification packagings when transported in dedicated vehicles or freight


containers. The packagings need not conform to the requirements for package testing in part 178 of this subchapter, but must be capable of containing any evolving gases from the contents during normal conditions of transportation.

(b) Bulk shipments of Polymeric beads (or granules), expandable, evolving flammable vapor or

Plastic molding compounds in dough, sheet or extruded rope, evolving flammable vapor may be packed in non-specification bulk packagings. Except for transportation by highway and rail, bulk packagings must be capable of containing any gases evolving from the contents during normal conditions of transportation.

(c) For transportation by vessel, the provisions of § 176.907 must be met. (d) Exceptions. When it can be demonstrated that no flammable vapor, resulting in a flammable

atmosphere, is evolved according to test U1 (Test method for substances liable to evolve flammable vapors) of Part III, subsection 38.4.4 of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter), polymeric beads, expandable need not be classed as Class 9 (UN2211). This test should only be performed when de-classification of a substance is considered.

173.222 Dangerous goods in equipment, machinery or apparatus. Hazardous materials in machinery or apparatus are excepted from the specification packaging requirements of this subchapter when packaged according to this section. Hazardous materials in machinery or apparatus must be packaged in strong outer packagings, unless the receptacles containing the hazardous materials are afforded adequate protection by the construction of the machinery or apparatus. Each package must conform to the packaging requirements of subpart B of this part, except for the requirements in §§ 173.24(a)(1) and 173.27(e), and the following requirements:

(a) If the machinery or apparatus contains more than one hazardous material, the materials must not be capable of reacting dangerously together.

(b) The nature of the containment must be as follows -

(1) Damage to the receptacles containing the hazardous materials during transport is

unlikely. However, in the event of damage to the receptacles containing the hazardous materials, no leakage of the hazardous materials from the machinery or apparatus is possible. A leakproof liner may be used to satisfy this requirement.

(2) Receptacles containing hazardous materials must be secured and cushioned so as to

prevent their breakage or leakage and so as to control their movement within the machinery or apparatus during normal conditions of transportation. Cushioning material must not react dangerously with the content of the receptacles. Any leakage of the contents must not substantially impair the protective properties of the cushioning material.

(3) Receptacles for gases, their contents and filling densities must conform to the applicable

requirements of this subchapter, unless otherwise approved by the Associate Administrator.

(c) Except for transportation by aircraft, the total net quantity of hazardous materials contained in one

item of machinery or apparatus must not exceed the following:

(i) In the case of solids or liquids, the limited quantity amount specified in the corresponding section referenced in Column (8A) of the §172.101 Table;

(ii) 0.5 kg (1.1 pounds) in the case of Division 2.2 gases. (iii) When machinery or apparatus contains multiple hazardous materials, the quantity of

each hazardous material must not exceed the quantity specified in the corresponding


section referenced in Column (8A) of the §172.101 Table, or for gases, paragraph (c)(1)(ii) of this section.

(2) For transportation by aircraft, the total net quantity of hazardous materials contained in

one item of machinery or apparatus must not exceed the following:

(i) 1 kg (2.2 pounds) in the case of solids; (ii) 0.5 L (0.1 gallons) in the case of liquids; (iii) 0.5 kg (1.1 pounds) in the case of Division 2.2 gases. Division 2.2 gases with subsidiary

risks and refrigerated liquefied gases are not authorized; (iv) A total quantity of not more than the aggregate of that permitted in paragraphs (c)(2)(i)

through (iii) of this section, for each category of material in the package, when a package contains hazardous materials in two or more of the categories in paragraphs (c)(2)(i) through (iii) of this section; and

(d) Except for transportation by aircraft, when a package contains hazardous materials in two or more of

the categories listed in paragraph (c)(1) of this section the total quantity required by §172.202(c) of this subchapter to be entered on the shipping paper must be either the aggregate quantity, or the estimated quantity, of all hazardous materials, expressed as net mass.

173.223 Packaging for certain flammable solids.

(a) Packagings for ‘‘Musk xylene,’’ ‘‘5- tert-Butyl-2,4,6-trinitro-m-xylene,’’ ‘‘Azodicarbonamide,’’ or ‘‘Isosorbide-5-mononitrate,’’ when offered for transportation or transported by rail, highway, or vessel, must conform to the general packaging requirements of subpart B of part 173, and to the requirements of part 178 of this subchapter at the Packing Group III performance level and may only be transported in the following packagings:

(1) Fiberboard box (4G) with a single inner plastic bag, and a maximum net mass of not

more than 50 kg (110 lbs). (2) Fiberboard box (4G) or fiber drum (1G), with a plastic inner packaging not exceeding 5 kg

(11 lbs), and a maximum net mass of not more than 25 kg (55 lbs). (3) Fiber drum (1G), and a maximum net mass of not more than 50 kg (110 lbs), that may be

fitted with a coating or lining. (b) [Reserved] 173.224 Packaging and control and emergency temperatures for self-reactive materials. (a) General. When the §172.101 Table of this subchapter specifies that a Division 4.1 material be

packaged in accordance with this section, only packagings which conform to the provisions of this section may be used. Each packaging must conform to the general packaging requirements of subpart B of this part and the applicable requirements of part 178 of this subchapter. Non-bulk packagings must meet Packing Group II performance levels. To avoid unnecessary confinement, metallic non-bulk packagings meeting Packing Group I are not authorized. Self-reactive materials which require temperature control are subject to the provisions of §173.21(f). Packagings required to bear a Class 1 subsidiary label must conform to §§173.60 through 173.62.

(b) Self-Reactive Materials Table. The Self-Reactive Materials Table specifies, by technical name,

those self-reactive materials that are authorized for transportation and not subject to the approval provisions of §173.124(a)(2)(iii). A self-reactive material identified by technical name in the following table is authorized for transportation only if it conforms to all applicable provisions of the


table. The column headings of the Self-Reactive Materials Table are as follows:

(1) Technical name. Column 1 specifies the technical name.

(2) ID number. Column 2 specifies the identification number which is used to identify the proper shipping name in the §172.101 Table.

(3) Concentration of self-reactive material. Column 3 specifies the concentration (percent)

limitations, if any, in mixtures or solutions for the self-reactive material. Limitations are given as minimums, maximums, or a range, as appropriate. A range includes the lower and upper limits (i.e., ``53-100'' means from, and including, 53 percent to, and including 100 percent).

(4) Packing method. Column 4 specifies the highest packing method which is authorized for

the self-reactive material. A packing method corresponding to a smaller package size may be used, but a packing method corresponding to a larger package size may not be used. The Table of Packing Methods in §173.225(d) defines the packing methods. Bulk packagings for Type F self-reactive substances are authorized by §173.225(f) for IBCs and §173.225(h) for bulk packagings other than IBCs. The formulations listed in §173.225(f) for IBCs and in §173.225(g) for portable tanks may also be transported packed in accordance with packing method OP8, with the same control and emergency temperatures, if applicable. Additional bulk packagings are authorized if approved by the Associate Administrator.

(5) Control temperature. Column 5 specifies the control temperature in °C. Temperatures are

specified only when temperature controls are required (see §173.21(f)). (6) Emergency temperature. Column 6 specifies the emergency temperature in °C.

Temperatures are specified only when temperature controls are required (see §173.21(f)).

(7) Notes. Column 7 specifies other applicable provisions, as set forth in notes following the

table.

Self-reactive substance ID No.

Concen-

tration

(%)

Packing

method Control Emergency Notes

Temperature°C

1 2 3 4 5 6 7

Acetone-pyrogallol copolymer 2-diazo-1-naphthol-5-

sulphonate 3228 100 OP8

Azodicarbonamide formulation type B, temperature

controlled 3232 <100 OP5 1

Azodicarbonamide formulation type C 3224 <100 OP6

Azodicarbonamide formulation type C, temperature


Azodicarbonamide formulation type D 3226 <100 OP7

Azodicarbonamide formulation type D, temperature


2,2′-Azodi(2,4-dimethyl-4-methoxyvaleronitrile) 3236 100 OP7 −5 5

2,2′-Azodi(2,4-dimethylvaleronitrile) 3236 100 OP7 10 15

2,2′-Azodi(ethyl 2-methylpropionate) 3235 100 OP7 20 25

1,1-Azodi(hexahydrobenzonitrile) 3226 100 OP7

2,2-Azodi(isobutyronitrile) 3234 100 OP6 40 45

2,2′-Azodi(isobutyronitrile) as a water based paste 3224 ≤50 OP6

2,2-Azodi(2-methylbutyronitrile) 3236 100 OP7 35 40



Concen-

tration

(%)

Packing


Temperature°C

1 2 3 4 5 6 7

Benzene-1,3-disulphonylhydrazide, as a paste 3226 52 OP7

Benzene sulphohydrazide 3226 100 OP7

4-(Benzyl(ethyl)amino)-3-ethoxybenzenediazonium

zinc chloride 3226 100 OP7

4-(Benzyl(methyl)amino)-3-ethoxybenzenediazonium

zinc chloride 3236 100 OP7 40 45

3-Chloro-4-diethylaminobenzenediazonium zinc

chloride 3226 100 OP7

2-Diazo-1-Naphthol sulphonic acid ester mixture 3226 <100 OP7 4

2-Diazo-1-Naphthol-4-sulphonyl chloride 3222 100 OP5

2-Diazo-1-Naphthol-5-sulphonyl chloride 3222 100 OP5

2,5-Dibutoxy-4-(4-morpholinyl)-Benzenediazonium,

tetrachlorozincate (2:1) 3228 100 OP8

2,5-Diethoxy-4-morpholinobenzenediazonium zinc

chloride 3236 67−100 OP7 35 40

2,5-Diethoxy-4-morpholinobenzenediazonium zinc

chloride 3236 66 OP7 40 45

2,5-Diethoxy-4-morpholinobenzenediazonium

tetrafluoroborate 3236 100 OP7 30 35

2,5-Diethoxy-4-(phenylsulphonyl)benzenediazonium

zinc chloride 3236 67 OP7 40 45

2,5-Diethoxy-4-(4-morpholinyl)-benzenediazonium

sulphate 3226 100 OP7

Diethylene glycol bis(allyl carbonate) +

Diisopropylperoxydicarbonate 3237

≥88 +

≤12 OP8 −10 0

2,5-Dimethoxy-4-(4-

methylphenylsulphony)benzenediazonium zinc

chloride

3236 79 OP7 40 45

4-Dimethylamino-6-(2-dimethylaminoethoxy)toluene-

2-diazonium zinc chloride 3236 100 OP7 40 45

4-(Dimethylamino)-benzenediazonium trichlorozincate

(-1) 3228 100 OP8

N,N′-Dinitroso-N, N′-dimethyl-terephthalamide, as a

paste 3224 72 OP6

N,N′-Dinitrosopentamethylenetetramine 3224 82 OP6 2

Diphenyloxide-4,4′-disulphohydrazide 3226 100 OP7

Diphenyloxide-4,4′-disulphonylhydrazide 3226 100 OP7

4-Dipropylaminobenzenediazonium zinc chloride 3226 100 OP7

2-(N,N-Ethoxycarbonylphenylamino)-3-methoxy-4-(N-

methyl-N- cyclohexylamino)benzenediazonium zinc

chloride

3236 63−92 OP7 40 45

2-(N,N-Ethoxycarbonylphenylamino)-3-methoxy-4-(N-

methyl-N- cyclohexylamino)benzenediazonium zinc

chloride

3236 62 OP7 35 40

N-Formyl-2-(nitromethylene)-1,3-perhydrothiazine 3236 100 OP7 45 50

2-(2-Hydroxyethoxy)-1-(pyrrolidin-1-yl)benzene-4-

diazonium zinc chloride 3236 100 OP7 45 50

3-(2-Hydroxyethoxy)-4-(pyrrolidin-1-

yl)benzenediazonium zinc chloride 3236 100 OP7 40 45



Concen-

tration

(%)

Packing


Temperature°C

1 2 3 4 5 6 7

2-(N,N-Methylaminoethylcarbonyl)-4-(3,4-dimethyl-

phenylsulphonyl)benzene diazonium zinc chloride 3236 96 OP7 45 50

4-Methylbenzenesulphonylhydrazide 3226 100 OP7

3-Methyl-4-(pyrrolidin-1-yl)benzenediazonium

tetrafluoroborate 3234 95 OP6 45 50

4-Nitrosophenol 3236 100 OP7 35 40

Phosphorothioic acid, O-[(cyanophenyl methylene)

azanyl] O,O-diethyl ester 3227

82−91

OP8 5

(Z

isomer)

Self-reactive liquid, sample 3223 OP2 3

Self-reactive liquid, sample, temperature control 3233 OP2 3

Self-reactive solid, sample 3224 OP2 3

Self-reactive solid, sample, temperature control 3234 OP2 3

Sodium 2-diazo-1-naphthol-4-sulphonate 3226 100 OP7

Sodium 2-diazo-1-naphthol-5-sulphonate 3226 100 OP7

Tetramine palladium (II) nitrate 3234 100 OP6 30 35

Notes 1. The emergency and control temperatures must be determined in accordance with §173.21(f). 2. With a compatible diluent having a boiling point of not less than 150 °C. 3. Samples may only be offered for transportation under the provisions of paragraph (c)(3) of this section. 4. This entry applies to mixtures of esters of 2-diazo-1-naphthol-4-sulphonic acid and 2-diazo-1-naphthol-5-sulphonic acid. 5. This entry applies to the technical mixture in n-butanol within the specified concentration limits of the (Z) isomer.

(c) New self-reactive materials, formulations and samples. ‘

(1) Except as provided for samples in paragraph (c)(3) or (4) of this section, no person may offer, accept for

transportation, or transport a self-reactive material which is not identified by technical name in the Self-Reactive Materials Table of this section, or a formulation of one or more self-reactive materials which are identified by technical name in the table, unless the self-reactive material is assigned a generic type and shipping description and

is approved by the Associate Administrator under the provisions of §173.124(a)(2)(iii).

(2) Except as provided by an approval issued under §173.124(a)(2)(iii), intermediate bulk and bulk packagings are not authorized.

(3) Samples of new self-reactive materials or new formulations of self-reactive materials identified

in the Self-Reactive Materials Table in paragraph (b) of this section, for which complete test


data are not available, and which are to be transported for further testing or product evaluation, may be assigned an appropriate shipping description for Self-reactive materials Type C, packaged and offered for transportation under the following conditions:

(i) Data available to the person offering the material for transportation must indicate that the

sample would pose a level of hazard no greater than that of a self-reactive material Type B and that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation;

(ii) The sample must be packaged in accordance with packing method OP2; (iii) Packages of the self-reactive material may be offered for transportation and transported

in a quantity not to exceed 10 kg (22 pounds) per transport vehicle; and (iv) One of the following shipping descriptions must be assigned:

(A) Self-reactive, liquid, type C, 4.1, UN 3223. (B) Self-reactive, solid, type C, 4.1, UN 3224. (C) Self-reactive, liquid, type C, temperature controlled, 4.1, UN 3233. (D) Self-reactive, solid, type C, temperature controlled, 4.1, UN 3234.

(4) Samples of organic substances carrying functional groups listed in tables A6.1 and/or A6.2 in

Annex 6 (Screening Procedures) of the UN Manual of Tests and Criteria (IBR, see §171.7 of this subchapter) may be transported under UN 3224 or UN 3223, as applicable, of Division 4.1 provided that:

(i) The samples do not contain any:

(A) Known explosives; (B) Substances showing explosive effects in testing; (C) Compounds designed with the view of producing a practical explosive or pyrotechnic

effect; (D) Components consisting of synthetic precursors of intentional explosives;

(ii) For mixtures, complexes or salts of inorganic oxidizing substances of Division 5.1 with organic material(s), the concentration of the inorganic oxidizing substance is: (A) Less than 15 percent, by mass, if assigned to Packing Group I or II; or (B) Less than 30 percent, by mass, if assigned to Packing Group III;

(iii) Available data does not allow a more precise classification; (iv) The sample is not packed together with other goods; (v) Must be packaged as follows:

(A) The quantity per individual inner cavity does not exceed 0.01 g for solids or 0.01 mL

for liquids and the maximum net quantity per outer packaging does not exceed 20 g for solids or 20 mL for liquids, or in the case of mixed packing the sum of grams and mL does not exceed 20:

(1) The samples are carried in microtiter plates or multi-titer plates made of plastics,


glass, porcelain or stoneware as an inner packaging;

(2) only combination packaging with outer packaging comprising boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1 and 4H2) are permitted; or

(B) The maximum content of each inner packaging does not exceed 1 g for solids or 1

mL for liquids and the maximum net quantity per outer packaging does not exceed 56 g for solids or 56 mL for liquids, or in the case of mixed packing the sum of grams and mL does not exceed 56:

(1) The individual substance is contained in an inner packaging of glass or plastics of

maximum capacity of 30 mL placed in an expandable polyethylene foam matrix of at least 130 mm thickness having a density of 18 ± 1 g/L;

(2) Within the foam carrier, inner packagings are segregated from each other by a

minimum distance of 40 mm and from the wall of the outer packaging by a minimum distance of 70 mm. The package may contain up to two layers of such foam matrices, each carrying up to twenty-eight inner packagings;

(3) The outer packaging consists only of corrugated fiberboard boxes (4G) having

minimum dimensions of 60 cm (length) by 40.5 cm (width) by 30 cm (height) and minimum wall thickness of 1.3 cm.

(vi) When dry ice or liquid nitrogen is optionally used as a coolant for quality control measures, all

applicable requirements of this subchapter must be met. Interior supports must be provided to secure the inner packagings in the original position after the ice or dry ice has dissipated. If ice is used, the outside packaging or overpack must be leakproof. If dry ice is used, the requirements in §173.217 must be met. The inner and outer packagings must maintain their integrity at the temperature of the refrigerant used as well as the temperatures and the pressures which could result if refrigeration were lost.

173.225 Packaging requirements and other provisions for organic peroxides. (a) General. When the § 172.101 table specifies that an organic peroxide must be packaged under

this section, the organic peroxide must be packaged and offered for transportation in accordance with the provisions of this section. Each packaging must conform to the general requirements of subpart B of part 173 and to the applicable requirements of part 178 of this subchapter. Non-bulk packagings must meet Packing Group II performance levels. To avoid unnecessary confinement, metallic non-bulk packagings meeting Packing Group I are not authorized. No used material, other than production residues or regrind from the same production process, may be used in plastic packagings. Organic peroxides that require temperature control are subject to the provisions of § 173.21(f). When an IBC or bulk packaging is authorized and meets the requirements of paragraph (f) or (h) of this section, respectively, lower control temperatures than those specified for non-bulk packaging may be required. An organic peroxide not identified in paragraph (c), (e), or (g) of this section by technical name, or not assigned to a generic type in accordance with the provisions in paragraph (b)(3) of this section, must conform to the provisions of paragraph (c) of § 173.128.

(b) New organic peroxides, formulations and samples.

(1) Except as provided for samples in paragraph (b)(2) of this section, no person may offer for transportation an organic peroxide that is not identified by technical name in the Organic Peroxides Table, Organic Peroxide IBC Table, or the Organic Peroxide Portable Tank Table of this section, or a formulation of one or more organic peroxides that are identified by technical name in one of those tables, unless the organic peroxide is assigned a generic type and shipping description and is approved by the Associate Administrator under the provisions of § 173.128(d) of this subchapter.

(2) Samples. Samples of new organic peroxides or new formulations of organic peroxides


identified in the Organic Peroxides Table in paragraph (c) of this section, for which complete test data are not available, and that are to be transported for further testing or product evaluation, may be assigned an appropriate shipping description for organic peroxide Type C, packaged and offered for transportation, under the following conditions:

(i) Data available to the person offering the material for transportation must indicate

that the sample would pose a level of hazard no greater than that of an organic peroxide Type B and that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation;

(ii) The sample must be packaged in accordance with packing method OP2, for a

liquid or solid, respectively;

(iii) Packages of the organic peroxide may be offered for transportation and transported in a quantity not to exceed 10 kg (22 pounds) per transport vehicle; and

(iv) One of the following shipping descriptions must be assigned:

(A) Organic peroxide Type C, liquid, 5.2, UN 3103;

(B) Organic peroxide Type C, solid, 5.2, UN 3104;

(C) Organic peroxide Type C, liquid, temperature controlled, 5.2, UN 3113;

or

(D) Organic peroxide Type C, solid, temperature controlled, 5.2, UN 3114.

(3) Mixtures. Mixtures of organic peroxides individually identified in the Organic Peroxides Table in paragraph (c) of this section may be classified as the same type of organic peroxide as that of the most dangerous component and be transported under the conditions for transportation given for this type. If the stable components form a thermally less stable mixture, the SADT of the mixture must be determined and the new control and emergency temperature derived under the provisions of § 173.21(f).

(c) Organic peroxides table. The following Organic Peroxides Table specifies by technical name

those organic peroxides that are authorized for transportation and not subject to the approval provisions of § 173.128 of this part. An organic peroxide identified by technical name in the following table is authorized for transportation only if it conforms to all applicable provisions of the table. The column headings of the Organic Peroxides Table are as follows:

(1) Technical name. The first column specifies the technical name.

(2) ID number. The second column specifies the identification (ID) number which is used to

identify the proper shipping name in the § 172.101 table. The word “ EXEMPT” appearing in the column denotes that the material is not regulated as an organic peroxide.

(3) Concentration of organic peroxide. The third column specifies concentration (mass

percent) limitations, if any, in mixtures or solutions for the organic peroxide. Limitations are given as minimums, maximums, or a range, as appropriate. A range includes the lower and upper limits (i.e., “ 53-100” means from, and including, 53% to, and including 100%). See introductory paragraph of § 172.203(k) of this subchapter for additional description requirements for an organic peroxide that may qualify for more than one generic listing, depending on its concentration.

(4) Concentration of diluents. The fourth column specifies the type and concentration (mass

percent) of diluent or inert solid, when required. Other types and concentrations of


diluents may be used if approved by the Associate Administrator.

(i) The required mass percent of “ Diluent type A” is specified in column 4a. A diluent type A is an organic liquid that does not detrimentally affect the thermal stability or increase the hazard of the organic peroxide and with a boiling point not less than 150 °C at atmospheric pressure. Type A diluents may be used for desensitizing all organic peroxides.

(ii) The required mass percent of “ Diluent type B” is specified in column 4b. A

diluent type B is an organic liquid which is compatible with the organic peroxide and which has a boiling point, at atmospheric pressure, of less than 150 °C (302 °F) but at least 60 °C (140 °F), and a flash point greater than 5 °C (41 °F). Type B diluents may be used for desensitizing all organic peroxides, when specified in the organic peroxide tables, provided that the boiling point is at least 60 °C (140 °F) above the SADT of the peroxide in a 50 kg (110 lbs) package. A type A diluent may be used to replace a type B diluent in equal concentration.

(iii) The required mass percent of “ Inert solid” is specified in column 4c. An inert

solid is a solid that does not detrimentally affect the thermal stability or hazard of the organic peroxide.

(5) Concentration of water. Column 5 specifies, in mass percent, the minimum amount of

water, if any, which must be in formulation.

(6) Packing method. Column 6 specifies the highest packing method (largest packaging capacity) authorized for the organic peroxide. Lower numbered packing methods (smaller packaging capacities) are also authorized. For example, if OP3 is specified, then OP2 and OP1 are also authorized. The Table of Packing Methods in paragraph (d) of this section defines the non-bulk packing methods.

(7) Temperatures. Column 7a specifies the control temperature. Column 7b specifies the

emergency temperature. Temperatures are specified only when temperature controls are required. (See § 173.21(f)).

(8) Notes. Column 8 specifies other applicable provisions, as set forth in notes following the

table.


Organic Peroxide Table

Technical name ID No. Concentration

(mass %)

Diluent (mass %) Water (mass

%)

Packing method

Temperature ( °C)

Notes A B I Control Emergency

(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8)

Acetyl acetone peroxide UN3105 ≤42 ≥48 ≥8 OP7 2

Acetyl acetone peroxide [as a paste] UN3106 ≤32 OP7 21

Acetyl cyclohexanesulfonyl peroxide UN3112 ≤82 ≥12 OP4 −10 0

Acetyl cyclohexanesulfonyl peroxide UN3115 ≤32 ≥68 OP7 −10 0

tert-Amyl hydroperoxide UN3107 ≤88 ≥6 ≥6 OP8

tert-Amyl peroxyacetate UN3105 ≤62 ≥38 OP7

tert-Amyl peroxybenzoate UN3103 ≤100 OP5

tert-Amyl peroxy-2-ethylhexanoate UN3115 ≤100 OP7 20 25

tert-Amyl peroxy-2-ethylhexyl carbonate UN3105 ≤100 OP7

tert-Amyl peroxy isopropyl carbonate UN3103 ≤77 ≥23 OP5

tert-Amyl peroxyneodecanoate UN3115 ≤77 ≥23 OP7 0 10

tert-Amyl peroxyneodecanoate UN3119 ≤47 ≥53 OP8 0 10

tert-Amyl peroxypivalate UN3113 ≤77 ≥23 OP5 10 15

tert-Amyl peroxypivalate UN3119 ≤32 ≥68 OP8 10 15

tert-Amyl peroxy-3,5,5-trimethylhexanoate UN3105 ≤100 OP7

tert-Butyl cumyl peroxide UN3109 >42−100 OP8 9

tert-Butyl cumyl peroxide UN3108 ≤52 ≥48 OP8 9

n-Butyl-4,4-di-(tert-butylperoxy)valerate UN3103 >52−100 OP5

n-Butyl-4,4-di-(tert-butylperoxy)valerate UN3108 ≤52 ≥48 OP8

tert-Butyl hydroperoxide UN3103 >79−90 ≥10 OP5 13

tert-Butyl hydroperoxide UN3105 ≤80 ≥20 OP7 4, 13

tert-Butyl hydroperoxide UN3107 ≤79 >14 OP8 13, 16

tert-Butyl hydroperoxide UN3109 ≤72 ≥28 OP8 13

tert-Butyl hydroperoxide [and] Di-tert-butylperoxide

UN3103 <82 + >9 ≥7 OP5 13

tert-Butyl monoperoxymaleate UN3102 >52−100 OP5



(mass %)


%)

Packing method

Temperature ( °C)


(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8)

tert-Butyl monoperoxymaleate UN3103 ≤52 ≥48 OP6

tert-Butyl monoperoxymaleate UN3108 ≤52 ≥48 OP8

tert-Butyl monoperoxymaleate [as a paste] UN3108 ≤52 OP8

tert-Butyl peroxyacetate UN3101 >52−77 ≥23 OP5

tert-Butyl peroxyacetate UN3103 >32−52 ≥48 OP6

tert-Butyl peroxyacetate UN3109 ≤32 ≥68 OP8

tert-Butyl peroxybenzoate UN3103 >77−100 OP5

tert-Butyl peroxybenzoate UN3105 >52−77 ≥23 OP7 1

tert-Butyl peroxybenzoate UN3106 ≤52 ≥48 OP7

tert-Butyl peroxybenzoate UN3109 ≤32 ≥68 OP8

tert-Butyl peroxybutyl fumarate UN3105 ≤52 ≥48 OP7

tert-Butyl peroxycrotonate UN3105 ≤77 ≥23 OP7

tert-Butyl peroxydiethylacetate UN3113 ≤100 OP5 20 25

tert-Butyl peroxy-2-ethylhexanoate UN3113 >52−100 OP6 20 25

tert-Butyl peroxy-2-ethylhexanoate UN3117 >32−52 ≥48 OP8 30 35

tert-Butyl peroxy-2-ethylhexanoate UN3118 ≤52 ≥48 OP8 20 25

tert-Butyl peroxy-2-ethylhexanoate UN3119 ≤32 ≥68 OP8 40 45

tert-Butyl peroxy-2-ethylhexanoate [and] 2,2-di-(tert-Butylperoxy)butane

UN3106 ≤12 + ≤14 ≥14 ≥60 OP7

tert-Butyl peroxy-2-ethylhexanoate [and] 2,2-di-(tert-Butylperoxy)butane

UN3115 ≤31 + ≤36 ≥33 OP7 35 40

tert-Butyl peroxy-2-ethylhexylcarbonate UN3105 ≤100 OP7

tert-Butyl peroxyisobutyrate UN3111 >52−77 ≥23 OP5 15 20

tert-Butyl peroxyisobutyrate UN3115 ≤52 ≥48 OP7 15 20

tert-Butylperoxy isopropylcarbonate UN3103 ≤77 ≥23 OP5

1-(2-tert-Butylperoxy isopropyl)-3-isopropenylbenzene

UN3105 ≤77 ≥23 OP7



(mass %)


%)

Packing method

Temperature ( °C)


(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8)

1-(2-tert-Butylperoxy isopropyl)-3-isopropenylbenzene

UN3108 ≤42 ≥58 OP8

tert-Butyl peroxy-2-methylbenzoate UN3103 ≤100 OP5

tert-Butyl peroxyneodecanoate UN3115 >77−100 OP7 −5 5

tert-Butyl peroxyneodecanoate UN3115 ≤77 ≥23 OP7 0 10

tert-Butyl peroxyneodecanoate [as a stable dispersion in water]

UN3119 ≤52 OP8 0 10

tert-Butyl peroxyneodecanoate [as a stable dispersion in water (frozen)]

UN3118 ≤42 OP8 0 10

tert-Butyl peroxyneodecanoate UN3119 ≤32 ≥68 OP8 0 10

tert-Butyl peroxyneoheptanoate UN3115 ≤77 ≥23 OP7 0 10

tert-Butyl peroxyneoheptanoate [as a stable dispersion in water]

UN3117 ≤42 OP8 0 10

tert-Butyl peroxypivalate UN3113 >67−77 ≥23 OP5 0 10

tert-Butyl peroxypivalate UN3115 >27−67 ≥33 OP7 0 10

tert-Butyl peroxypivalate UN3119 ≤27 ≥73 OP8 30 35

tert-Butylperoxy stearylcarbonate UN3106 ≤100 OP7

tert-Butyl peroxy-3,5,5-trimethylhexanoate UN3105 >37−100 OP7

tert-Butyl peroxy-3,5,5-trimethlyhexanoate UN3106 ≤42 ≥58 OP7

tert-Butyl peroxy-3,5,5-trimethylhexanoate UN3109 ≤37 ≥63 OP8

3-Chloroperoxybenzoic acid UN3102 >57−86 ≥14 OP1

3-Chloroperoxybenzoic acid UN3106 ≤57 ≥3 ≥40 OP7

3-Chloroperoxybenzoic acid UN3106 ≤77 ≥6 ≥17 OP7

Cumyl hydroperoxide UN3107 >90−98 ≤10 OP8 13

Cumyl hydroperoxide UN3109 ≤90 ≥10 OP8 13, 15

Cumyl peroxyneodecanoate UN3115 ≤87 ≥13 OP7 −10 0

Cumyl peroxyneodecanoate UN3115 ≤77 ≥23 OP7 −10 0



(mass %)


%)

Packing method

Temperature ( °C)


(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8)

Cumyl peroxyneodecanoate [as a stable dispersion in water]

UN3119 ≤52 OP8 −10 0

Cumyl peroxyneoheptanoate UN3115 ≤77 ≥23 OP7 −10 0

Cumyl peroxypivalate UN3115 ≤77 ≥23 OP7 −5 5

Cyclohexanone peroxide(s) UN3104 ≤91 ≥9 OP6 13

Cyclohexanone peroxide(s) UN3105 ≤72 ≥28 OP7 5

Cyclohexanone peroxide(s) [as a paste] UN3106 ≤72 OP7 5, 21

Cyclohexanone peroxide(s) Exempt ≤32 >68 Exempt 29

Diacetone alcohol peroxides UN3115 ≤57 ≥26 ≥8 OP7 40 45 5

Diacetyl peroxide UN3115 ≤27 ≥73 OP7 20 25 8,13

Di-tert-amyl peroxide UN3107 ≤100 OP8

([3R- (3R, 5aS, 6S, 8aS, 9R, 10R, 12S, 12aR**)]-Decahydro-10-methoxy-3, 6, 9-trimethyl-3, 12-epoxy-12H-pyrano [4, 3- j]-1, 2-benzodioxepin)

UN3106 ≤100 OP7

2,2-Di-(tert-amylperoxy)-butane UN3105 ≤57 ≥43 OP7

1,1-Di-(tert-amylperoxy)cyclohexane UN3103 ≤82 ≥18 OP6

Dibenzoyl peroxide UN3102 >52−100 ≤48 OP2 3

Dibenzoyl peroxide UN3102 >77−94 ≥6 OP4 3

Dibenzoyl peroxide UN3104 ≤77 ≥23 OP6

Dibenzoyl peroxide UN3106 ≤62 ≥28 ≥10 OP7

Dibenzoyl peroxide [as a paste] UN3106 >52−62 OP7 21

Dibenzoyl peroxide UN3106 >35−52 ≥48 OP7

Dibenzoyl peroxide UN3107 >36−42 ≥18 ≤40 OP8

Dibenzoyl peroxide [as a paste] UN3108 ≤56.5 ≥15 OP8

Dibenzoyl peroxide [as a paste] UN3108 ≤52 OP8 21

Dibenzoyl peroxide [as a stable dispersion in water]

UN3109 ≤42 OP8

Dibenzoyl peroxide Exempt ≤35 ≥65 Exempt 29



(mass %)


%)

Packing method

Temperature ( °C)


(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8)

Di-(4-tert-butylcyclohexyl)peroxydicarbonate UN3114 ≤100 OP6 30 35

Di-(4-tert-butylcyclohexyl)peroxydicarbonate [as a stable dispersion in water]

UN3119 ≤42 OP8 30 35

Di-(4-tert-butylcyclohexyl)peroxydicarbonate [as a paste]

UN3116 ≤42 OP7 35 40

Di-tert-butyl peroxide UN3107 >52−100 OP8

Di-tert-butyl peroxide UN3109 ≤52 ≥48 OP8 24

Di-tert-butyl peroxyazelate UN3105 ≤52 ≥48 OP7

2,2-Di-(tert-butylperoxy)butane UN3103 ≤52 ≥48 OP6

1,6-Di-(tert-butylperoxycarbonyloxy)hexane UN3103 ≤72 ≥28 OP5

1,1-Di-(tert-butylperoxy)cyclohexane UN3101 >80−100 OP5

1,1-Di-(tert-butylperoxy)cyclohexane UN3103 >52−80 ≥20 OP5

1,1-Di-(tert-butylperoxy)-cyclohexane UN3103 ≤72 ≥28 OP5 30

1,1-Di-(tert-butylperoxy)cyclohexane UN3105 >42−52 ≥48 OP7

1,1-Di-(tert-butylperoxy)cyclohexane UN3106 ≤42 ≥13 ≥45 OP7

1,1-Di-(tert-butylperoxy)cyclohexane UN3107 ≤27 ≥25 OP8 22

1,1-Di-(tert-butylperoxy)cyclohexane UN3109 ≤42 ≥58 OP8

1,1-Di-(tert-Butylperoxy) cyclohexane UN3109 ≤37 ≥63 OP8



1,1-Di-(tert-butylperoxy)cyclohexane + tert-Butyl peroxy-2-ethylhexanoate

UN3105 ≤43 + ≤16 ≥41 OP7

Di-n-butyl peroxydicarbonate UN3115 >27−52 ≥48 OP7 −15 −5

Di-n-butyl peroxydicarbonate UN3117 ≤27 ≥73 OP8 −10 0

Di-n-butyl peroxydicarbonate [as a stable dispersion in water (frozen)]

UN3118 ≤42 OP8 −15 −5

Di-sec-butyl peroxydicarbonate UN3113 >52−100 OP4 −20 −10 6

Di-sec-butyl peroxydicarbonate UN3115 ≤52 ≥48 OP7 −15 −5



(mass %)


%)

Packing method

Temperature ( °C)


(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8)

Di-(tert-butylperoxyisopropyl) benzene(s) UN3106 >42−100 ≤57 OP7 1, 9

Di-(tert-butylperoxyisopropyl) benzene(s) Exempt ≤42 ≥58 Exempt

Di-(tert-butylperoxy)phthalate UN3105 >42−52 ≥48 OP7

Di-(tert-butylperoxy)phthalate [as a paste] UN3106 ≤52 OP7 21

Di-(tert-butylperoxy)phthalate UN3107 ≤42 ≥58 OP8

2,2-Di-(tert-butylperoxy)propane UN3105 ≤52 ≥48 OP7

2,2-Di-(tert-butylperoxy)propane UN3106 ≤42 ≥13 ≥45 OP7

1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane

UN3101 >90−100 OP5


UN3103 >57−90 ≥10 OP5


UN3103 ≤77 ≥23 OP5


UN3103 ≤90 ≥10 OP5 30


UN3110 ≤57 ≥43 OP8


UN3107 ≤57 ≥43 OP8


UN3107 ≤32 ≥26 ≥42 OP8

Dicetyl peroxydicarbonate UN3120 ≤100 OP8 30 35

Dicetyl peroxydicarbonate [as a stable dispersion in water]

UN3119 ≤42 OP8 30 35

Di-4-chlorobenzoyl peroxide UN3102 ≤77 ≥23 OP5

Di-4-chlorobenzoyl peroxide Exempt ≤32 ≥68 Exempt 29

Di-2,4-dichlorobenzoyl peroxide [as a paste] UN3118 ≤52 OP8 20 25

Di-4-chlorobenzoyl peroxide [as a paste] UN3106 ≤52 OP7 21



(mass %)


%)

Packing method

Temperature ( °C)


(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8)

Dicumyl peroxide UN3110 >52−100 ≤48 OP8 9

Dicumyl peroxide Exempt ≤52 ≥48 Exempt 29

Dicyclohexyl peroxydicarbonate UN3112 >91−100 OP3 10 15

Dicyclohexyl peroxydicarbonate UN3114 ≤91 ≥9 OP5 10 15

Dicyclohexyl peroxydicarbonate [as a stable dispersion in water]

UN3119 ≤42 OP8 15 20

Didecanoyl peroxide UN3114 ≤100 OP6 30 35

2,2-Di-(4,4-di(tert-butylperoxy)cyclohexyl)propane UN3106 ≤42 ≥58 OP7

2,2-Di-(4,4-di(tert-butylperoxy)cyclohexyl)propane UN3107 ≤22 ≥78 OP8

Di-2,4-dichlorobenzoyl peroxide UN3102 ≤77 ≥23 OP5

Di-2,4-dichlorobenzoyl peroxide [as a paste with silicone oil]

UN3106 ≤52 OP7

Di-(2-ethoxyethyl) peroxydicarbonate UN3115 ≤52 ≥48 OP7 −10 0

Di-(2-ethylhexyl) peroxydicarbonate UN3113 >77−100 OP5 −20 −10

Di-(2-ethylhexyl) peroxydicarbonate UN3115 ≤77 ≥23 OP7 −15 −5

Di-(2-ethylhexyl) peroxydicarbonate [as a stable dispersion in water]

UN3119 ≤62 OP8 −15 −5

Di-(2-ethylhexyl) peroxydicarbonate [as a stable dispersion in water]

UN3119 ≤52 OP8 −15 −5

Di-(2-ethylhexyl) peroxydicarbonate [as a stable dispersion in water (frozen)]

UN3120 ≤52 OP8 −15 −5

2,2-Dihydroperoxypropane UN3102 ≤27 ≥73 OP5

Di-(1-hydroxycyclohexyl)peroxide UN3106 ≤100 OP7

Diisobutyryl peroxide UN3111 >32−52 ≥48 OP5 −20 −10

Diisobutyryl peroxide [as a stable dispersion in water]

UN3119 ≤42 OP8 −20 −10

Diisobutyryl peroxide UN3115 ≤32 ≥68 OP7 −20 −10

Diisopropylbenzene dihydroperoxide UN3106 ≤82 ≥5 ≥5 OP7 17



(mass %)


%)

Packing method

Temperature ( °C)


(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8)

Diisopropyl peroxydicarbonate UN3112 >52−100 OP2 −15 −5

Diisopropyl peroxydicarbonate UN3115 ≤52 ≥48 OP7 −20 −10

Diisopropyl peroxydicarbonate UN3115 ≤32 ≥68 OP7 −15 −5

Dilauroyl peroxide UN3106 ≤100 OP7

Dilauroyl peroxide [as a stable dispersion in water]

UN3109 ≤42 OP8

Di-(3-methoxybutyl) peroxydicarbonate UN3115 ≤52 ≥48 OP7 −5 5

Di-(2-methylbenzoyl)peroxide UN3112 ≤87 ≥13 OP5 30 35

Di-(4-methylbenzoyl)peroxide [as a paste with silicone oil]

UN3106 ≤52 OP7

Di-(3-methylbenzoyl) peroxide + Benzoyl (3-methylbenzoyl) peroxide + Dibenzoyl peroxide

UN3115 ≤20 + ≤18 + ≤4 ≥58 OP7 35 40

2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane UN3102 >82−100 OP5

2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane UN3106 ≤82 ≥18 OP7

2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane UN3104 ≤82 ≥18 OP5

2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane UN3103 >90−100 OP5

2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane UN3105 >52—90 ≥10 OP7

2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane UN3108 ≤77 ≥23 OP8

2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane UN3109 ≤52 ≥48 OP8

2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane [as a paste]

UN3108 ≤47 OP8

2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3 UN3101 >86−100 OP5

2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3 UN3103 >52−86 ≥14 OP5

2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3 UN3106 ≤52 ≥48 OP7

2,5-Dimethyl-2,5-di-(2-ethylhexanoylperoxy)hexane

UN3113 ≤100 OP5 20 25

2,5-Dimethyl-2,5-dihydroperoxyhexane UN3104 ≤82 ≥18 OP6

2,5-Dimethyl-2,5-di-(3,5,5-trimethylhexanoylperoxy)hexane

UN3105 ≤77 ≥23 OP7



(mass %)


%)

Packing method

Temperature ( °C)


(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8)

1,1-Dimethyl-3-hydroxybutylperoxyneoheptanoate

UN3117 ≤52 ≥48 OP8 0 10

Dimyristyl peroxydicarbonate UN3116 ≤100 OP7 20 25

Dimyristyl peroxydicarbonate [as a stable dispersion in water]

UN3119 ≤42 OP8 20 25

Di-(2-neodecanoylperoxyisopropyl)benzene UN3115 ≤52 ≥48 OP7 −10 0

Di-(2-neodecanoyl-peroxyisopropyl) benzene, as stable dispersion in water

UN3119 ≤42 OP8 −15 −5

Di-n-nonanoyl peroxide UN3116 ≤100 OP7 0 10

Di-n-octanoyl peroxide UN3114 ≤100 OP5 10 15

Di-(2-phenoxyethyl)peroxydicarbonate UN3102 >85−100 OP5

Di-(2-phenoxyethyl)peroxydicarbonate UN3106 ≤85 ≥15 OP7

Dipropionyl peroxide UN3117 ≤27 ≥73 OP8 15 20

Di-n-propyl peroxydicarbonate UN3113 ≤100 OP3 −25 −15

Di-n-propyl peroxydicarbonate UN3113 ≤77 ≥23 OP5 −20 −10

Disuccinic acid peroxide UN3102 >72−100 OP4 18

Disuccinic acid peroxide UN3116 ≤72 ≥28 OP7 10 15

Di-(3,5,5-trimethylhexanoyl) peroxide UN3115 >52−82 ≥18 OP7 0 10

Di-(3,5,5-trimethylhexanoyl)peroxide [as a stable dispersion in water]

UN3119 ≤52 OP8 10 15

Di-(3,5,5-trimethylhexanoyl) peroxide UN3119 >38−52 ≥48 OP8 10 15

Di-(3,5,5-trimethylhexanoyl)peroxide UN3119 ≤38 ≥62 OP8 20 25

Ethyl 3,3-di-(tert-amylperoxy)butyrate UN3105 ≤67 ≥33 OP7

Ethyl 3,3-di-(tert-butylperoxy)butyrate UN3103 >77−100 OP5

Ethyl 3,3-di-(tert-butylperoxy)butyrate UN3105 ≤77 ≥23 OP7

Ethyl 3,3-di-(tert-butylperoxy)butyrate UN3106 ≤52 ≥48 OP7

1-(2-ethylhexanoylperoxy)-1,3-Dimethylbutyl peroxypivalate

UN3115 ≤52 ≥45 ≥10 OP7 −20 −10

tert-Hexyl peroxyneodecanoate UN3115 ≤71 ≥29 OP7 0 10



(mass %)


%)

Packing method

Temperature ( °C)


(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8)

tert-Hexyl peroxypivalate UN3115 ≤72 ≥28 OP7 10 15

3-Hydroxy-1,1-dimethylbutyl peroxyneodecanoate UN3115 ≤77 ≥23 OP7 −5 5

3-Hydroxy-1,1-dimethylbutyl peroxyneodecanoate [as a stable dispersion in water]

UN3119 ≤52 OP8 −5 5

3-Hydroxy-1,1-dimethylbutyl peroxyneodecanoate UN3117 ≤52 ≥48 OP8 −5 5

Isopropyl sec-butyl peroxydicarbonat + Di-sec-butyl peroxydicarbonate + Di-isopropyl peroxydicarbonate

UN3111 ≤52 + ≤28 + ≤22

OP5 −20 −10

Isopropyl sec-butyl peroxydicarbonate + Di-sec-butyl peroxydicarbonate + Di-isopropyl peroxydicarbonate

UN3115 ≤32 + ≤15 −18 + ≤12 −15

≥38 OP7 −20 −10

Isopropylcumyl hydroperoxide UN3109 ≤72 ≥28 OP8 13

p-Menthyl hydroperoxide UN3105 >72−100 OP7 13

p-Menthyl hydroperoxide UN3109 ≤72 ≥28 OP8

Methylcyclohexanone peroxide(s) UN3115 ≤67 ≥33 OP7 35 40

Methyl ethyl ketone peroxide(s) UN3101 ≤52 ≥48 OP5 5, 13

Methyl ethyl ketone peroxide(s) UN3105 ≤45 ≥55 OP7 5

Methyl ethyl ketone peroxide(s) UN3107 ≤40 ≥60 OP8 7

Methyl isobutyl ketone peroxide(s) UN3105 ≤62 ≥19 OP7 5, 23

Methyl isopropyl ketone peroxide(s) UN3109 (See remark 31)

≥70 OP8 31

Organic peroxide, liquid, sample UN3103 OP2 12

Organic peroxide, liquid, sample, temperature controlled

UN3113 OP2 12

Organic peroxide, solid, sample UN3104 OP2 12

Organic peroxide, solid, sample, temperature controlled

UN3114 OP2 12

3,3,5,7,7-Pentamethyl-1,2,4-Trioxepane UN3107 ≤100 OP8

Peroxyacetic acid, type D, stabilized UN3105 ≤43 OP7 13, 20



(mass %)


%)

Packing method

Temperature ( °C)


(1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8)

Peroxyacetic acid, type E, stabilized UN3107 ≤43 OP8 13, 20

Peroxyacetic acid, type F, stabilized UN3109 ≤43 OP8 13, 20, 28

Peroxyacetic acid or peracetic acid [with not more than 7% hydrogen peroxide]

UN3107 ≤36 ≥15 OP8 13, 20, 28


Exempt ≤6 ≥60 Exempt 28


UN3109 ≤17 OP8 13, 20, 28

Peroxylauric acid UN3118 ≤100 OP8 35 40

1-Phenylethyl hydroperoxide UN3109 ≤38 ≥62 OP8

Pinanyl hydroperoxide UN3105 >56−100 OP7 13

Pinanyl hydroperoxide UN3109 ≤56 ≥44 OP8

Polyether poly-tert-butylperoxycarbonate UN3107 ≤52 ≥48 OP8

Tetrahydronaphthyl hydroperoxide UN3106 ≤100 OP7

1,1,3,3-Tetramethylbutyl hydroperoxide UN3105 ≤100 OP7

1,1,3,3-Tetramethylbutyl peroxy-2-ethylhexanoate UN3115 ≤100 OP7 15 20

1,1,3,3-Tetramethylbutyl peroxyneodecanoate UN3115 ≤72 ≥28 OP7 −5 5

1,1,3,3-Tetramethylbutyl peroxyneodecanoate [as a stable dispersion in water]

UN3119 ≤52 OP8 −5 5

1,1,3,3-tetramethylbutyl peroxypivalate UN3115 ≤77 ≥23 OP7 0 10

3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane UN3110 ≤17 ≥18 ≥65 OP8

3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane UN3105 ≤42 ≥58 OP7 26


Notes: 1. For domestic shipments, OP8 is authorized. 2. Available oxygen must be <4.7%. 3. For concentrations <80% OP5 is allowed. For concentrations of at least 80% but <85%, OP4 is allowed. For concentrations of at least 85%, maximum package size is OP2. 4. The diluent may be replaced by di-tert-butyl peroxide. 5. Available oxygen must be ≤9% with or without water. 6. For domestic shipments, OP5 is authorized. 7. Available oxygen must be ≤8.2% with or without water. 8. Only non-metallic packagings are authorized. 9. For domestic shipments this material may be transported under the provisions of paragraph (h)(3)(xii) of this section. 10. [Reserved] 11. [Reserved] 12. Samples may only be offered for transportation under the provisions of paragraph (b)(2) of this section. 13. “Corrosive” subsidiary risk label is required. 14. [Reserved] 15. No “Corrosive” subsidiary risk label is required for concentrations below 80%. 16. With <6% di-tert-butyl peroxide. 17. With ≤8% 1-isopropylhydroperoxy-4-isopropylhydroxybenzene. 18. Addition of water to this organic peroxide will decrease its thermal stability. 19. [Reserved] 20. Mixtures with hydrogen peroxide, water and acid(s). 21. With diluent type A, with or without water. 22. With ≥36% diluent type A by mass, and in addition ethylbenzene. 23. With ≥19% diluent type A by mass, and in addition methyl isobutyl ketone. 24. Diluent type B with boiling point >100 C. 25. No “Corrosive” subsidiary risk label is required for concentrations below 56%. 26. Available oxygen must be ≤7.6%.


27. Formulations derived from distillation of peroxyacetic acid originating from peroxyacetic acid in a concentration of not more than 41% with water, total active oxygen less than or equal to 9.5% (peroxyacetic acid plus hydrogen peroxide). 28. For the purposes of this section, the names “Peroxyacetic acid” and “Peracetic acid” are synonymous. 29. Not subject to the requirements of this subchapter for Division 5.2. 30. Diluent type B with boiling point >130 °C (266 °F). 31. Available oxygen ≤6.7%.


(d) Packing Method Table. Packagings for organicperoxides and self-reactive substances are listed in the Maximum Quantity per Packing Method Table. The packing methods are designated OP1 to OP8.

The quantities specified for each packing method represent the maximum that is authorized.

(1) The following types of packagings are authorized:

(i) Drums: 1A1, 1A2, 1B1, 1B2, 1D, 1G, 1H1, 1H2; (ii) Jerricans: 3A1, 3A2, 3B1, 3B2, 3H1, 3H2; (iii) Boxes: 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2, 4A, 4B; or (iv) Composite packagings with a plastic inner receptacle: 6HA1, 6HA2, 6HB1,

6HB2, 6HC, 6HD1, 6HD2, 6HG1, 6HG2, 6HH1, 6HH2.

(2) Metal packaging (including inner packagings of combination packagings and outer packagings of combination or composite packagings) are used only for packing methods OP7 and OP8.

(3) In combination packagings, glass receptacles are used only as inner packagings with a

maximum content of 0.5 kg for solids or 0.5 L for liquids. (4) The maximum quantity per packaging or package for Packing Methods OP1-OP8 must

be as follows:

MAXIMUM QUANTITY PER PACKAGING/PACKAGE FOR PACKING METHODS OP1 TO OP8

Maximum quantity Packing method

OP1 OP21 OP3 OP41 OP5 OP6 OP7 OP8

Solids and combination packagings (liquid and solid) (kg)

0.5 0.5/10 5 5/25 25 50 50 2400

Liquids (L) 0.5 …… 5 …… 30 60 60 3225

1If two values are given, the first applies to the maximum net mass per inner packaging and the second to the maximum net mass of the complete package.

2 60 kg for jerricans/200 kg for boxes and, for solids, 400 kg in combination packagings with outer packagings comprising boxes (4C1, 4C2, 4D, 4F, 4G, 4H1, and 4H2) and with inner packagings of plastics or fiber with a maximum net mass of 25 kg.

360 L for jerricans.

(e) Organic Peroxide IBC Table. The following Organic Peroxide IBC Table specifies, by technical name,

those organic peroxides that are authorized for transportation in certain IBCs and not subject to the approval provisions of §173.128 of this part. Additional requirements for authorized IBCs are found in paragraph (f) of this section.

Organic Peroxide IBC Table

UN No.

Organic peroxide Type of IBC

Maximum quantity (liters)

Control temperature

Emergency temperature

3109 ORGANIC PEROXIDE, TYPE F, LIQUID:

tert-Butyl cumyl peroxide 31HA1 1000

tert-Butyl hydroperoxide, not more than 72%

with water 31A 1250

31HA1 1000

tert-Butyl peroxyacetate, not more than 32% in

diluent type A 31A 1250

31HA1 1000


UN No.



Control temperature


tert-Butyl peroxybenzoate, not more than 32%

in diluent type A 31A 1250

tert-Butyl peroxy-3,5,5-trimethylhexanoate, not

more than 37% in diluent type A 31A 1250

31HA1 1000

Cumyl hydroperoxide, not more than 90% in

diluent type A 31HA1 1250

Dibenzoyl peroxide, not more than 42% as a

stable dispersion 31H1 1000

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane,

not more than 52% in diluent type A 31HA1 1000

Di-tert-butyl peroxide, not more than 52% in

diluent type B 31A 1250

31HA1 1000

1,1-Di-(tert-Butylperoxy) cyclohexane, not

more than 37% in diluent type A 31A 1250

1,1-Di-(tert-butylperoxy) cyclohexane, not

more than 42% in diluent type A 31H1 1000

Dicumyl peroxide, less than or equal to 100% 31A 1250

31HA1 1000

Dilauroyl peroxide, not more than 42%, stable

dispersion, in water 31HA1 1000

Isopropyl cumyl hydroperoxide, not more than

72% in diluent type A 31HA1 1250

p-Menthyl hydroperoxide, not more than 72%

in diluent type A 31HA1 1250

Peroxyacetic acid, stabilized, not more than

17% 31A 1500

31H1 1500

31H2 1500

31HA1 1500

Peroxyacetic acid, not more than 26%

hydrogen peroxide 31A 1500

31HA1 1500

Peroxyacetic acid, type F, stabilized 31A 1500

31HA1 1500

3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-

triperoxonane not more than 27% diluent type A

31HA1 1000

3110 ORGANIC PEROXIDE TYPE F, SOLID:

Dicumyl peroxide, less than or equal to 100% 31A 2000

31H1

31HA1

3119 ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED:

tert-Amyl peroxy-2-ethylhexanoate, not more

than 62% in a diluent type A 31HA1 1000 +15 °C +20 °C

tert-Amyl peroxypivalate, not more than 32%

in diluent type A 31A 1250 +10 °C +15 °C

tert-Butyl peroxy-2-ethylhexanoate, not more

than 32% in diluent type B 31HA1 1000 +30 °C +35 °C

31A 1250 +30 °C +35 °C

tert-Butyl peroxyneodecanoate, not more than 32% in diluent type A

31A 1250 0 °C +10 °C

tert-Butyl peroxyneodecanoate, not more than 31A 1250 −5 °C +5 °C


UN No.



Control temperature


52%, stable dispersion, in water tert-Butyl peroxypivalate, not more than 27%

in diluent type B 31HA1 1000 +10 °C +15 °C

31A 1250 +10 °C +15 °C

Cumyl peroxyneodecanoate, not more than 52%, stable dispersion, in water

31A 1250 −15 °C −5 °C

Di-(4-tert-butylcyclohexyl) peroxydicarbonate,

not more than 42%, stable dispersion, in water

31HA1 1000 +30 °C +35 °C

Dicetyl peroxydicarbonate, not more than

42%, stable dispersion, in water 31HA1 1000 +30 °C +35 °C

Dicyclohexylperoxydicarbonate, not more than

42% as a stable dispersion, in water 31A 1250 +10 °C +15 °C

Di-(2-ethylhexyl) peroxydicarbonate, not more

than 62%, stable dispersion, in water 31A 1250 −20 °C −10 °C

31HA1 1000 −20 °C −10 °C

Diisobutyryl peroxide, not more than 28% as a stable dispersion in water

31HA1 1000 −20 °C −10 °C

31A 1250 −20 °C −10 °C

Diisobutyryl peroxide, not more than 42% as a stable dispersion in water

31HA1 1000 −25 °C −15 °C

31A 1250 −25 °C −15 °C

Dimyristyl peroxydicarbonate, not more than 42%, stable dispersion, in water

31HA1 1000 +15 °C +20 °C

Di-(2-neodecanoylperoxyisopropyl) benzene,


31A 1250 −15 °C −5 °C

Di-(3,5,5-trimethylhexanoyl) peroxide, not

more than 52% in diluent type A 31HA1 1000 +10 °C +15 °C

31A 1250 +10 °C +15 °C

Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 52%, stable dispersion, in water

31A 1250 +10 °C +15 °C

3-Hydroxy-1,1-dimethylbutyl peroxy-

neodecanoate, not more than 52%, stable dispersion, in water

31A 1250 −15 °C −5 °C

1,1,3,3-Tetramethylbutyl peroxy-2-

ethylhexanoate, not more than 67%, in diluent type A

31HA1 1000 +15 °C +20 °C

1,1,3,3-Tetramethylbutyl peroxyneodecanoate,


31A 1250 −5 °C +5 °C

31HA1 1000 −5 °C +5 °C

(f) IBCs. IBCs are authorized subject to the conditions and limitations of this section if the IBC type is

authorized according to paragraph (e) of this section, as applicable, and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group II performance level. Type F organic peroxides or self-reactive substances are not authorized for transportation in IBCs other than those specified, unless approved by the Associate Administrator.

(1) IBCs shall be provided with a device to allow venting during transportation. The inlet

to the pressure relief device shall be sited in the vapor space of the IBC under maximum filling conditions during transportation.


(2) To prevent explosive rupture of metal IBCs or composite IBCs with a complete metal casing, the emergency-relief devices shall be designed to vent all the decomposition products and vapors evolved during self-accelerating decomposition or during a period of not less than one hour of complete fire-engulfment as calculated by the formula in paragraph (h)(3)(v) of this section. The control and emergency temperatures specified in the Organic Peroxide IBC Table are based on a non-insulated IBC.

(g) Organic Peroxide Portable Tank Table. The following Organic Peroxide Portable Tank Table

provides certain portable tank requirements and identifies, by technical name, those organic peroxides that are authorized for transportation in the bulk packagings listed in paragraph (h) of this section. Organic peroxides listed in this table, provided they meet the specific packaging requirements found in paragraph (h) of this section, are not subject to the approval provisions of §173.128 of this part. In addition, the formulations listed below may also be transported packed in accordance with packing method OP8 of this section, with the same control and emergency temperatures, if applicable.

49 CFR 173 Subpart E A5-137 SET Environmental, Inc. Non-Bulk Packaging Other than for Class 1 and 7 Last Revision: May 11, 2020

ORGANIC PEROXIDE PORTABLE TANK TABLE

UN No.

Hazardous Material Minimum Test

Pressure (bar)

Minimum shell thickness (mm - reference steel)

Bottom Opening Requirements

Pressure Relief Requirements

Filling Limits Control Temp °C

Emergency Temp°C

3109 ORGANIC PEROXIDE, TYPE F, LIQUID

tert-Butyl hydroperoxide, not more than 72% with water. *Provided that steps have been taken to achieve the safety equivalence of 65% tert-Butyl hydroperoxide and 35% water.

4 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) No more than 90% at 59°F (15°C)

Cumyl hydro-peroxide, not more than 90% in diluent type A.


Di-tert-butyl peroxide, not more than 32% in diluent type A.


Dicumyl peroxide, less than or equal to 100% indiluent type B.


Isopropyl cumyl hydroperoxide, not more than 72 % in diluent type A.


p-Menthyl hydroperoxide, not more than 72% in diluent type A.


Pinanyl hydroperoxide, not more than 56% in diluent type A.


3110 ORGANIC PEROXIDE TYPE F SOLID

Dicumyl peroxide less than or equal to 100% with inert solids. *Maximum quantity per portable tank 2,000 kg.


3119 ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLED.

tert-Amyl peroxyneodecanoate, not more than 47% in diluent type A.


-10 -5

tert-Butyl peroxy acetate, not more than 32% in diluent type B.


+30 +35

tert-Butyl peroxy-2-ethylhexanoate, not more than 32% in diluent type B.


+15 +20

tert-Butyl peroxypivalate, not more than 27% in diluent type B.


+5 +10

tert-Butyl peroxy-3,5,5-trimethyl hexanoate, not more than 32% in diluent type B.


+35 +40

Di(-3,5,5-trimethyl hexanoyl) peroxide, not more than 38% in diluent type A or type B.


0 +5

Peroxyacetic acid,distilled, stabilized, not more than 41%1.


+30 +35

Note: 1. ‘‘Corrosive’’ subsidiary risk placard is required.

49 CFR 173 Subpart F A5-138 SET Environmental, Inc. Non-Bulk Packaging Other Than For Class 1 and 7 Last Revision: May 11, 2020

(h) Bulk packagings other than IBCs. The following bulk packagings are authorized, subject to the

conditions and limitations of this section, if the organic peroxide is listed in the Organic Peroxide Portable Tank Table and bulk packagings are authorized, or if the organic peroxide is specifically authorized for transport in a bulk packaging by this paragraph (h), and the bulk packaging conforms to the requirements of this subchapter:

(1) Rail cars. Class DOT 103, 104, 105, 109, 111, 112, 114, 115, or 120 fusion-weld tank car

tanks are authorized. DOT 103W, 111A60F1 and 111A60W1 tank car tanks must have bottom outlets effectively sealed from inside. Gauging devices are required on DOT 103W tank car tanks. Riveted tank car tanks are not authorized.

(2) Cargo tanks. Specification MC 307, MC 310, MC 311, MC 312, DOT 407, and DOT 412

cargo tank motor vehicles with a tank design pressure of at least 172 kPa (25 psig) are authorized.

(3) Portable tanks. The following requirements apply to portable tanks intended for the

transport of organic peroxides or self-reactive substances. DOT 51, 57, IM 101 portable tanks, and UN portable tanks that conform to the requirements of paragraph (g) of this section, are authorized. Type F organic peroxide or self-reactive substance formulations other than those indicated in the Organic Peroxide Portable Tank Table may be transported in portable tanks if approved by the Associate Administrator. The following conditions also apply:

(i) The portable tank must be designed for a test pressure of at least 0.4 MPa (4

bar). (ii) The portable tank must be fitted with temperature-sensing devices. (iii) The portable tank must be fitted with pressure relief devices and

emergency-relief devices. Vacuum-relief devices may also be used. Pressure relief devices must operate at pressures determined according to both the properties of the hazardous material and the construction characteristics of the portable tank. Fusible elements are not allowed in the shell.

(iv) The pressure relief devices must consist of reclosing devices fitted to prevent

significant build-up within the portable tank of the decomposition products and vapors released at a temperature of 50 [deg]C (122 [deg]F). The capacity and start-to-discharge pressure of the relief devices must be in accordance with the applicable requirements of this subchapter specified for the portable tank. The pressure relief devices must not allow liquid to escape in the event the portable tank is overturned in a loaded condition.

(v)

(A) The emergency-relief devices may be of the reclosing or frangible types,

or a combination of the two, designed to vent all the decomposition products and vapors evolved during a period of not less than one hour of complete fire engulfment as calculated by the following formula:

q = 70961 FA0.82 Where: q = heat absorption (W) A = wetted area (m2) F = insulation factor (-)

(B) Insulation factor (F) in the formula in paragraph (h)(3)(v)(A) of this

section equals 1 for non-insulated vessels and for insulated vessels F is


calculated using the following formula:

F = U(923 - TPO)/47032 Where:

U = K/L = heat transfer coefficient of the insulation (W[middot]m-2[middot]K-1); where K = heat conductivity of insulation layer (W[middot]m-1[middot]K-1), and L = thickness of insulation layer (m).

TPO = temperature of material at relieving conditions (K).

(vi) The start-to-discharge pressure of emergency-relief devices must be higher than

that specified for the pressure relief devices in paragraph (h)(3)(iv) of this section. The emergency-relief devices must be sized and designed in such a way that the maximum pressure in the shell never exceeds the test pressure of the portable tank.

Note to Paragraph (h)(3)(vi): An example of a method to determine the size of

emergency-relief devices is given in Appendix 5 of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter). A second example of a test method for venting sizing is given in the American Institute of Chemical Engineers Process Safety Progress Journal, June 2002 issue (Vol. 21, No. 2) (Informational materials not requiring incorporation by reference, see § 171.7(b)).

(vii) For insulated portable tanks, the capacity and setting of emergency-relief devices

must be determined assuming a loss of insulation from 1% of the surface area. (viii) Vacuum-relief devices and reclosing devices on portable tanks used for

flammable hazardous materials must be provided with flame arresters. Any reduction of the relief capacity caused by the flame arrester must be taken into account and the appropriate relief capacity must be provided.

(ix) Service equipment such as devices and external piping must be designed and

constructed so that no hazardous material remains in them after filling the portable tank.

(x) Portable tanks may be either insulated or protected by a sun-shield. If the SADT

of the hazardous material in the portable tank is 55 [deg]C (131 [deg]F) or less, the portable tank must be completely insulated. The outer surface must be finished in white or bright metal.

(xi) The degree of filling must not exceed 90% at 15 [deg]C (59 [deg]F). (xii) DOT 57 metal portable tanks are authorized only for tert-butyl cumyl peroxide,

di-(2-tert-butylperoxyisopropyl-benzene(s)), dicumyl peroxide and mixtures of two or more of these peroxides. DOT 57 portable tanks must conform to the venting requirements of paragraph (f) of this section. These portable tanks are not subject to any other requirements of paragraph (h) of this section.

(4) For tertiary butyl hydroperoxide (TBHP), each tank car, cargo tank or portable tank must

contain 7.6 cm (3.0 inches) low density polyethylene (PE) saddles having a melt index of at least 0.2 grams per 10 minutes (for example see, ASTM D1238, condition E) as part of the lading, with a ratio of PE to TBHP over a range of 0.008 to 0.012 by mass. Alternatively, plastic or metal containers equipped with fusible plugs having a melting point between 69 [deg]C (156 [deg]F) and 71 [deg]C (160 [deg]F) and filled with a sufficient quantity of water to dilute the TBHP to 65% or less by mass may be used. The PE saddles must be visually inspected after each trip and, at a minimum, once every 12


months, and replaced when discoloration, fracture, severe deformation, or other indication of change is noted.

173.226 Materials poisonous by inhalation, Division 6.1, Packing Group I, Hazard Zone A. Division 6.1, Packing Group I, Zone A poisonous by inhalation (see § 173.133) must be packed in non-bulk packagings in accordance with the following paragraphs: (a) In seamless specification or UN cylinders conforming to the requirements of § 173.40. (b) In 1A1, 1B1, 1H1, 1N1, or 6HA1 drums further packed in a 1A2 or 1H2 drum. Both inner and

outer drums must conform to the performance test requirements of subpart M of part 178 of this subchapter at the Packing Group I performance level. The outer drums may be tested either as a package intended to contain inner packagings (combination package) or as a single packaging intended to contain solids or liquids at a mass corresponding to the mass of the assembled packaging system. All outer drums, even those tested to contain inner packaging or as single packagings for solids, must withstand a hydrostatic test pressure of 100 kPa (15 psig). The outer drum must have a minimum thickness of 1.35 mm (0.053 inch) for a 1A2 outer drum or 6.3 mm (0.248 inch) for a 1H2 outer drum. In addition, the inner drum must—

(1) Be capable of satisfactorily withstanding the hydrostatic pressure test in § 178.605 of this

subchapter at a test pressure of 300 kPa (45 psig); (2) Satisfactorily withstand the leakproofness test in § 178.604 of this subchapter using an

internal air pressure of at least twice the vapor pressure at 55 °C (131 °F) of the material to be packaged;

(3) Have screw-type closures that are–

(i) Closed and tightened to a torque prescribed by the closure manufacturer, using a properly calibrated device that is capable of measuring torque;

(ii) Physically held in place by any means capable of preventing back-off or

loosening of the closure by impact or vibration during transportation; and (iii) Provided with a cap seal that is properly applied in accordance with the cap seal

manufacturer's recommendations and is capable of withstanding an internal pressure of at least 100 kPa (15 psig).

(4) Have a minimum thickness as follows:

(i) For a 1A1 or 1N1 drum, 1.3 mm (0.051 inch); (ii) For a 1B1 drum, 3.9 mm (0.154 inch); (iii) For a 1H1 drum, 3.16 mm (0.124 inch); and (iv) For a 6HA1 drum, the plastic inner container shall be 1.58 mm (0.0622 inch) and

the outer steel drum shall be 0.96 mm (0.0378 inch). (5) Be isolated from the outer drum by a shock-mitigating, non-reactive material, which

completely surrounds the inner packaging on all sides. (c) In combination packagings, consisting of an inner packaging system and an outer packaging, as

follows:

(1) Outer packagings: Steel drum: 1A2 Aluminum drum: 1B2


Metal drum, other than steel or aluminum: 1N2 Plywood drum: 1D Fiber drum: 1G Plastic drum: 1H2 Steel box: 4A Aluminum box: 4B Natural wood box: 4C1 or 4C2 Plywood box: 4D Reconstituted wood box: 4F Fiberboard box: 4G Expanded plastic box: 4H1 Solid plastic box: 4H2 Metal box other than steel or aluminum: 4N

(2) Inner packaging system. The inner packaging system consists of two packagings:

(i) an impact-resistant receptacle of glass, earthenware, plastic or metal securely

cushioned with a non-reactive, absorbent material, and

(A) Capacity of each inner receptacle may not exceed 4 L (1 gallon).

(B) An inner receptacle that has a closure must have a closure which is physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation.

(ii) Packed within a leak-tight packaging of metal or plastic.

(iii) This combination packaging in turn is packed within the outer packaging.

(3) Additional requirements:

(i) The total amount of liquid contained in the outer packaging must not exceed 16 L

(4 gallons). (ii) The inner packaging system must conform to the performance test requirements

of subpart M of part 178 of this subchapter, at the Packaging Group I performance level when subjected to the following tests:

(A) § 178.603—Drop Test (B) § 178.604—Leakproofness Test (C) § 178.605—Hydrostatic PressureTest

(iii) The inner packaging system must meet the above tests without the benefit of the

outer packaging. (iv) The leakproofness and hydrostatic pressure test may be conducted on either the

inner receptacle or the outer packaging of the inner packaging system. (v) The outer package must conform to the performance test requirements of

subpart M of part 178 of this subchapter, at the Packaging Group I performance level as applicable for the type of package being used.

(d) If approved by the Associate Administrator, 1A1, 1B1, 1H1, 1N1, 6HA1 or 6HH1 drums described

in paragraph (b) of this section may be used without being further packed in a 1A2 or 1H2 drum if the shipper loads the material, palletizes the drums, blocks and braces the drums within the transport vehicle and seals the transport vehicle used. Drums may not be stacked (double decked) within the transport vehicle. Shipments must be from one origin to one destination only without any intermediate pickup or delivery.


(e) Prior to reuse, all authorized inner drums must be leakproofness tested and marked in accordance with § 173.28 using a minimum test pressure as indicated in paragraph (b)(2) of this section.

(f) Liquid hazardous materials in Division 6.1, PG I, Hazard Zone A, are excepted from the

segregation requirements of §§174.81, 176.83, and 177.848(d) of this subchapter when packaged as follows: (1) Inner packaging system. The inner packaging system must consist of three packagings:

(i) A glass, plastic or metal receptacle, with a capacity of not more than 1 liter (1 quart), securely cushioned with a non-reactive, absorbent material. The receptacle must have a closure that is held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation.

(ii) The receptacle must be packed within a leak-tight packaging of metal, with a capacity of not less than 4 liters (1 gallon); and

(iii) The metal packaging must be securely cushioned with a nonreactive absorbent material and packed in a leak-tight UN 1A2 steel drum or UN 1H2 plastic drum, with a capacity of not less than 19 liters (5 gallons).

(2) Outer packaging. The inner packaging system must be placed in a UN 1A2 steel drum or UN 1H2 plastic drum, with a capacity of not less than 114 liters (30 gallons). The inner packaging system must be securely cushioned with a non-reactive, absorbent material. The total amount of liquid contained in the outer packaging may not exceed 1 liter (1 quart).

(3) Both the inner packaging system and the outer packaging must conform to the performance test requirements of subpart M of part 178 of this subchapter at the PG I performance level. The inner packaging system must meet these tests without benefit of the outer packaging.

173.227 Materials poisonous by inhalation. Division 6.1, Packing Group I, Hazard Zone B. (a) In packagings as authorized in § 173.226 and seamless and welded specification cylinders or UN

seamless cylinders conforming to the requirements of § 173.40. (b) 1A1, 1B1, 1H1, 1N1, 6HA1, or 6HH1 drums further packed in a 1A2 or 1H2 drum. Both the inner

and outer drums must conform to the performance test requirements of subpart M of part 178 of this subchapter at the Packing Group I performance level. The outer drums may be tested either as a package intended to contain inner packagings (combination package) or as a single packaging intended to contain solids or liquids at a mass corresponding to the mass of the assembled packaging system. The outer drum must have a minimum thickness of 1.35 mm (0.053 inches) for a 1A2 outer drum or 6.30 mm (0.248 inches) for a 1H2 outer drum. Outer 1A2 and 1H2 drums must withstand a hydrostatic test pressure of 100 kPa (15 psig). Capacity of the inner drum may not exceed 220 liters. In addition, the inner drum must conform to all of the following requirements:

(1) Satisfactorily withstand the leakproofness test in § 178.604 of this subchapter using an

internal air pressure of at least two times the vapor pressure at 55 °C (131 °F) of the material to be packaged;

(2) Have screw closures that are—

(i) Closed and tightened to a torque prescribed by the closure manufacturer, using a

properly calibrated device that is capable of measuring torque; (ii) Physically held in place by any means capable of preventing back-off or

loosening of the closure by impact or vibration during transportation; and (iii) Provided with a cap seal that is properly applied in accordance with the cap seal

manufacturer’s recommendations and is capable of withstanding an internal pressure of at least 100 kPa (15 psig).


(3) Have a minimum thickness as follows:

(i) For a 1A1 drum, 0.69 mm (0.027 inch); (ii) For a 1B1 drum, 2.79 mm (0.110 inch); (iii) For a 1H1 drum, 1.14 mm (0.045 inch); or (iv) For a 6HA1 drum, the plastic inner container shall be 1.58 mm (0.0625 inch), the

outer steel drum shall be 0.70 mm (0.027 inch).

(4) Be isolated from the outer drum by a shock-mitigating, non-reactive material which completely surrounds the inner packaging on all sides.

(5) Prior to reuse, all authorized inner drums must be leakproofness tested and marked in

accordance with § 173.28 using a minimum test pressure as indicated in paragraph (b)(1) of this section.

(c) 1A1, 1B1, 1H1, 1N1, 6HA1 or 6HH1 drums described in paragraph (b) of this section may be

used without being further packed in a 1A2 or 1H2 drum if the shipper loads the material, blocks and braces the drums within the transport vehicle and seals the transport vehicle used. Drums may not be stacked (double decked) within the transport vehicle. Shipments must be from one origin to one destination only without any intermediate pickup or delivery.

173.228 Bromine pentafluoride or bromine trifluoride. The following packagings are authorized for bromine pentafluoride and bromine trifluoride: (a) Bromine pentafluoride and bromine trifluoride are authorized in packagings as follows:

(1) Specification 3A150, 3AA150, 3B240, 3BN150, 4B240, 4BA240, 4BW240, and 3E1800 cylinders.

(2) UN cylinders as specified in part 178 of this subchapter, except acetylene cylinders and

non-refillable cylinders, with a minimum test pressure of 10 bar and a minimum outage of 8 percent by volume. The use of UN tubes and MEGCs is not authorized.

(3) The use of a pressure relief device is not authorized.

(b) A material in Hazard Zone A must be transported in a seamless specification cylinder conforming

to the requirements of § 173.40. However, a welded cylinder filled before October 1, 2002, in accordance with the requirements of this subchapter in effect at the time of filling, may be transported for reprocessing or disposal of the cylinder's contents until December 31, 2003. No cylinder may be equipped with a pressure relief device.

173.229 Chloric acid solution or chlorine dioxide hydrate, frozen. When the §172.101 Table specifies that a hazardous material be packaged in accordance with this section, only 4G fiberboard boxes, with inner packagings of polyethylene or other suitable material, are authorized. Fiberboard boxes must be reinforced and insulated and sufficient dry ice must be used to maintain the hydrate or acid in a frozen state during transportation. Each packaging must conform to the general packaging requirements of subpart B of part 173, and to the requirements of part 178 of this subchapter at the Packing Group I performance level. Transportation is authorized only by private or contract carrier by motor vehicle. 173.230 Fuel cell cartridges containing flammable liquids.


(a) Requirements for Fuel Cell Cartridges. Fuel cell cartridges, including when contained in or packed with equipment, must be designed and constructed to prevent fuel leakage under normal conditions of transportation. Fuel cell cartridge design types using liquids as fuels must pass an internal pressure test at a gauge pressure of 100 kPa (15 psig) without leakage. Except for fuel cell cartridges containing hydrogen in metal hydride which must be in conformance with paragraph (d) of this section, each fuel cell cartridge design type including when contained in or packed with equipment, must pass a 1.2 meter (3.9 feet) drop test onto anunyielding surface in the orientation most likely to result in the failure of the containment system with no loss of contents. Fuel cell cartridges installed in or integral to a fuel cell system are regarded as contained in equipment. Fuel cell cartridges containing a Division 2.1, Division 4.3 or Class 8 material must meet the following additional requirements.

(b) A fuel cell cartridge designed to contain a Division 4.3 or a Class 8 material may contain an

activator provided it is fitted with two independent means of preventing unintended mixing with the fuel during transport.

(c) Each fuel cell cartridge designed to contain a liquefied flammable gas must:

(1) Be capable of withstanding, without leakage or bursting, a pressure of at least two times the equilibrium pressure of the contents at 55 °C (131 °F);

(2) Contain no more than 200 mL of liquefied flammable gas with a vapor pressure not

exceeding 1,000 kPa (150 psig) at 55 °C (131 °F); and (3) Pass the hot water bath test prescribed in accordance with § 173.306(a)(3)(v).

(d) Each fuel cell cartridge designed to contain hydrogen in a metal hydride must conform to the

following:

(1) Each fuel cell cartridge must have a water capacity less than or equal to 120 mL (4 fluid ounces).

(2) Each fuel cell cartridge must be a design type that has been subjected, without leakage

or bursting, a pressure of at least two times the design pressure of the cartridge at 55 °C (131 °F) or 200 kPa (30 psig) more than the design pressure of the cartridge at 55 °C (131 °F), whichever is greater. The pressure at which the test is conducted is referred to as the ‘‘minimum shell burst pressure.’’ The pressure within the fuel cell cartridge must not exceed 5 MPa (725 psig) at 55 °C (131 °F).

(3) Each fuel cell cartridge must be filled in accordance with the procedure provided by the

manufacturer. The manufacturer must provide the following information with each fuel cell cartridge:

(i) Inspection procedures to be carried out before initial filling and before refilling of

the fuel cell cartridge; (ii) Safety precautions and potential hazards to be aware of; (iii) A method of determining when the rated capacity has been achieved; (iv) Minimum and maximum pressure range; (v) Minimum and maximum temperature range; and (vi) Any other requirements to be met for initial filling and refilling including the type of

equipment to be used.

(4) Each fuel cell cartridge must be permanently marked with the following information:


(i) The rated charging pressure in megapascals (MPa); (ii) The manufacturer’s serial number of the fuel cell cartridges or unique

identification number; and (iii) The expiration date based on the maximum service life (yyyy/mm).

(5) Design type tests: Each fuel cell cartridge design type must be subjected to and pass the

following tests (this includes cartridges integral to a fuel cell):

(i) Drop test. A 1.8 m (5.9 feet) drop test onto an unyielding surface must be performed. There must be no leakage. Leakage must be determined using a soap bubble solution or other equivalent means on all possible leak locations, when the fuel cell cartridge is charged to its rated charging pressure. The fuel cell cartridge must then be hydrostatically pressurized to destruction. The burst pressure must be greater than 85% of the minimum shell burst pressure. The drop must be performed in the following four different orientations:

(A) Vertically, on the end containing the shut-off valve assembly; (B) Vertically, on the end opposite to the shut-off valve assembly; (C) Horizontally, onto a steel apex with a diameter of 3.8 cm (9.7 in), with the

steel apex in the upward position; and (D) At a 45° angle on the end containing the shut-off valve assembl.

(ii) Fire test. A fuel cell cartridge filled to rated capacity (with hydrogen) must be

subjected to a fire engulfment test. The cartridge design (including design types with an integral vent feature) is deemed to pass the fire test if:

(A) The internal pressure vents to zero gauge pressure without the rupture of

the cartridge; or (B) The cartridge withstands the fire for a minimum of 20 minutes without

rupture. (iii) Hydrogen cycling test. A fuel cell cartridge must be subjected to a hydrogen

cycling test to ensure that the design stress limits are not exceeded during use. The fuel cell cartridge must be cycled from not more than 5% rated hydrogen capacity to not less than 95% rated hydrogen capacity and back to not more than 5% rated hydrogen capacity. The rated charging pressure must be used for charging and temperatures must be within the operating temperature range. The cycling must be continued for at least 100 cycles. Following the cycling test the fuel cell cartridge must be charged and the water volume displaced by the cartridge must be measured. The cartridge design is deemed to pass the test if the water volume displaced by the cycled cartridge does not exceed the water volume displaced by an uncycled cartridge charged to 95% rated capacity and pressurized to 75% of its minimum shell burst pressure.

(6) Production leak test. Each fuel cell cartridge must be tested for leaks at 15 °C ± 5 °C (59

°F ± 9 °F) while pressurized to its rated charging pressure. There must be no leakage. Leakage must be determined using a soap bubble solution or other equivalentmeans on all possible leak locations.

(e) The following packagings are authorized provided the general packaging requirements subpart B

of part 173 of this subchapter are met:


(1) For fuel cell cartridges, rigid packagings conforming to the requirements of part 178 of this subchapter at the packing group II performance level; and

(2) Strong outer packagings for fuel cell cartridges contained in equipment or packed with

equipment. Large equipment containing fuel cell cartridges may be transported unpackaged if the equipment provides an equivalent level of protection.

(i) Fuel cell cartridges packed with equipment must be packed with cushioning material

or divider(s) or inner packagings so that the fuel cell cartridges are protected against damage that may be caused by the shifting or placement of the equipment and cartridges within the packaging.

(ii) For fuel cell cartridges contained in equipment, the entire fuel cell system must be

protected against short circuits and unintentional activation. The equipment must be securely cushioned in the outer packaging.

(f) For transportation by aircraft, the following additional provisions apply:

(1) The package must comply with the applicable provisions of §173.27 of this subchapter;

(2) For fuel cell cartridges contained in equipment, fuel cell systems must not charge

batteries during transport; (3) For transportation aboard passenger aircraft, for fuel cell cartridges contained in

equipment, each fuel cell system and fuel cell cartridge must conform to to IEC 62282-6-100 and IEC 62282-6-100 Amend. 1 (IBR, see § 171.7 of this subchapter) or a standard approved by the Associate Administrator;

(4) When packed with equipment, fuel cell cartridges must be packed in an intermediate

packaging along with the equipment they are capable of powering, and the intermediate packagings packed in a strong outer packaging. The maximum number of fuel cell cartridges in the intermediate packaging may not be more than the number required to power the equipment, plus two spares;

(5) Large robust articles containing fuel cells may be transported unpackaged when

approved by the Associate Administrator; and (6) The mass of a fuel cell cartridge containing a Division 4.3 or Class 8 materials must be

not more than 1 kg (2.2 lbs). (7) Fuel cell cartridges intended for transportation in carry-on baggage on board passenger

aircraft must comply with paragraphs (a), (b), (c), (d) in this section and the applicable provisions prescribed in § 175.10 of this subchapter.

(g) Limited quantities. Limited quantities of hazardous materials contained in fuel cell cartridges are

excepted from the labeling requirements, unless the cartridges are offered for transportation or transported by aircraft, and from the placarding and specification packaging requirements of this subchapter when packaged according to this section. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. Except as authorized in paragraph (h) of this section, a package containing a limited quantity of fuel cell cartridges must be marked as specified in §172.315 of this subchapter and, for transportation by highway or rail, is not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, or marine pollutant, and are eligible for the exceptions provided in §173.156 of part. For transportation by highway, rail and vessel, the following combination packagings are authorized: (1) For flammable liquids, in fuel cell cartridges containing not more than 1.0 L (0.3 gallon)

per cartridge, packed in strong outer packaging.


(2) For water-reactive substances (Division 4.3 Dangerous when wet material), in fuel cell cartridges containing not more than 0.5 L (16.9 fluid ounces) for liquids or not over 0.5 kg (1.1 pound) for solids per cartridge, packed in strong outer packaging.

(3) For corrosive materials, in fuel cell cartridges containing not more than 1.0 L (0.3 gallon) for liquids or not more than 1.0 kg (2.2 pounds) for solids per cartridge, packed in strong outer packaging.

(4) For liquefied (compressed) flammable gas, in fuel cell cartridges not over 120 mL (4 fluid ounces) net capacity per cartridge, packed in strong outer packaging.

(5) For hydrogen in metal hydride, in fuel cell cartridges not over 120 mL (4 fluid ounces) net capacity per cartridge, packed in strong outer packaging.

(6) For transportation by aircraft, the following combination packagings are authorized: (i) For flammable liquids, in fuel cell cartridges containing not more than 0.5 L (16.9

fluid ounces) per cartridge, packed in strong outer packaging. Additionally, each package may contain no more than 2.5 kg (net mass) of fuel cell cartridges.

(ii) For water-reactive substances (Division 4.3 Dangerous when wet material), in fuel cell cartridges containing not more than 200 g (0.4 pounds) of solid fuel per cartridge, packed in strong outer packaging. Additionally, each package may contain no more than 2.5 kg (net mass) of fuel cell cartridges.

(iii) For corrosive materials, in fuel cell cartridges containing not more than 200 mL (6.7 fluid ounces) for liquids or not more than 200 g (0.4 pounds) for solids per cartridge packed in strong outer packaging. Additionally, each package may contain no more than 2.5 kg (net mass) of fuel cell cartridges.

(iv) For liquefied (compressed) flammable gas, in fuel cell cartridges not over 120 mL (4 fluid ounces) net capacity per cartridge, packed in strong outer packaging. Additionally, each package may contain no more than 0.5 kg (net mass) of fuel cell cartridges.

(v) For hydrogen in metal hydride, in fuel cell cartridges not over 120 mL (4 fluid ounces) net capacity per cartridge, packed in strong outer packaging. Additionally, each package may contain no more than 0.5 kg (net mass) of fuel cell cartridges.

(h) Consumer commodities. Until December 31, 2013, except for transportation by aircraft, a limited quantity that conforms to the provisions of paragraph (g) of this section and is also a “consumer commodity” as defined in §171.8 of this subchapter on October 1, 2010 may be renamed “Consumer commodity” and reclassed as ORM–D. Shipments of ORM–D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, and are eligible for the exceptions provided in §173.156 of this part.

173.231 Ammonium nitrate emulsion, suspension or gel. (a) Packagings for non-bulk shipments of Ammonium nitrate emulsions, suspensions and gels must

conform to the general packaging requirements of subpart B of part 173, to the requirements of part 178 of this subchapter at the Packing Group I or II performance level, and the requirements of the special provisions of column 7 of the §172.101 table. (1) The following combination packagings are authorized:

Outer packagings:

• Drums: 1B2, 1G, 1N2, 1H2 or 1D

• Boxes: 4B, 4C1, 4C2, 4D, 4G or 4H2

• Jerricans: 3B2 of 3H2 Inner Packagings:

• Glass, plastic or metal inner receptacles (2) For combination packagings, the capacity of each inner packaging must not exceed 5 liters (1.3

gallons) and the maximum authorized net weight of each outer packaging must not exceed 125 kg (275 pounds).

(3) The following single packagings are authorized:

• Drums: 1B1, 1B2, 1H1 or 1H2 with a maximum capacity of 250 liters (66 gallons).

• Jerricans: 3B1, 3B2, 3H1 or 3H2 with a maximum capacity of 60 liters (15.9 gallons).

• Plastic receptacle in aluminum, fiber, plastic or plywood drum: 6HB1, 6HG1, 6HH1 or 6HD1with the outer drum having a maximum capacity of 250 liters (66 gallons).


• Plastic receptacle in aluminum wood, plywood, fiberboard, or solid plastic box: 6HB2, 6HC, 6HD2, 6HG2, or 6HH2 with the outer box having a maximum capacity of 60 liters (15.9 gallons).

• Glass receptacle in aluminum, fiber, or plywood drum: 6PB1, 6PF1 or 6PD1 with the outer drum having a maximum capacity of 60 liters (15.9 gallons).

• Glass receptacle in expanded plastic or solid plastic packaging: 6PH1 or 6PH2 with the outer packaging having a maximum capacity of 60 liters (15.9 gallons).

• Glass receptacle in aluminum, wood, or fiberboard box, or wickerwork hamper: 6PB2, 6PC, 6PG2 or 6PD2 with the outer box or hamper having a maximum capacity of 60 liters (15.9 gallons).

(b) [Reserved]

§173.232 Articles containing hazardous materials, n.o.s.

(a) Articles containing hazardous materials may be classified as otherwise provided by this subchapter under the proper shipping name for the hazardous materials they contain or in accordance with this section. For the purposes of this section, “article” means machinery, apparatus, or other devices containing one or more hazardous materials (or residues thereof) that are an integral element of the article, necessary for its functioning, and that cannot be removed for the purpose of transport. An inner packaging is not an article. For articles that do not have an existing proper shipping name and that contain only hazardous materials within the permitted limited quantity amounts specified in column (8A) of the §172.101 Table, see UN3363, Dangerous goods in machinery or apparatus, as prescribed in §172.102(c)(1), Special provision 136, and §173.222.

(b) Such articles may contain batteries. Lithium batteries that are integral to the article must be of a type

proven to meet the testing requirements of the UN Manual of Tests and Criteria, Part III, subsection 38.3 (IBR, see §171.7 of this subchapter), except when otherwise specified by this subchapter.

(c) This section does not apply to articles for which a more specific proper shipping name already exists

in the §172.101 Table. This section does not apply to hazardous materials of Class 1, Division 6.2, Class 7, or radioactive material contained in articles.

(d) Articles containing hazardous materials must be assigned to the appropriate class or division

determined by the hazards present using, where applicable, the precedence criteria prescribed in §173.2a for each of the hazardous materials contained in the article. If hazardous materials classified as Class 9 are contained within the article, all other hazardous materials present in the article must be considered to present a higher hazard.

(e) Subsidiary hazards must be representative of the primary hazard posed by the other hazardous

materials contained within the article. When only one item of hazardous materials is present in the article, the subsidiary hazard(s), if any, is the subsidiary hazard(s) identified in column 6 of the §172.101 Table. If the article contains more than one item of hazardous materials and these could react dangerously with one another during transport, each of the hazardous materials must be enclosed separately.

(f) (1) Packagings must conform to the Packing Group II performance level. The following packagings

are authorized:

(i) Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); (ii) Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); and (iii) Jerricans (3A2, 3B2, 3H2).

(2) In addition, for robust articles, the following non-specification packagings are authorized:

(i) Strong outer packagings constructed of suitable material and of adequate strength and design

in relation to the packaging capacity and its intended use. Each package must conform to the packaging requirements of subpart B of this part, except for the requirements in


§§173.24(a)(1) and 173.27(e). (ii) Articles may be transported unpackaged or on pallets when the hazardous materials are

afforded equivalent protection by the article in which they are contained. (g) The nature of the containment must be as follows—

(1) In the event of damage to the receptacles containing the hazardous materials, no leakage of the hazardous materials from the machinery or apparatus is possible. A leakproof liner may be used to satisfy this requirement.

(2) Receptacles containing hazardous materials must be secured and cushioned so as to prevent

their breakage or leakage and to control their movement within the machinery or apparatus during normal conditions of transportation. Cushioning material must not react dangerously with the content of the receptacles. Any leakage of the contents must not substantially impair the protective properties of the cushioning material.

(3) Receptacles for gases, their contents, and filling densities must conform to the applicable

requirements of this subchapter, unless otherwise approved by the Associate Administrator.


SUBPART F - BULK PACKAGING FOR HAZARDOUS MATERIALS OTHER THAN CLASS 1 AND 7 173.240 Bulk packaging for certain low hazard solid materials. When §172.101 of this subchapter specifies that a hazardous material be packaged under this section, only the following bulk packagings are authorized, subject to the requirements of subparts A and B of part 173 of this subchapter and the special provisions specified in Column 7 of the §172.101 Table. (a) Rail cars: Class DOT 103, 104, 105, 109, 111, 112, 114, 115, or 120 tank car tanks; Class 106 or

110 multi-unit tank car tanks; and metal non-DOT specification, sift-proof tank car tanks and sift-proof closed cars.

(b) Motor vehicles: Specification MC 300, MC 301, MC 302, MC 303, MC 304, MC 305, MC 306, MC

307, MC 310, MC 311, MC 312, MC 330, MC 331, DOT 406, DOT 407, and DOT 412 cargo tank motor vehicles; non-DOT specification, sift-proof cargo tank motor vehicles; and sift-proof closed vehicles.

(c) Portable tanks and closed bulk bins: DOT 51, 56, 57 and 60 portable tanks; IMO type 1, 2 and 5,

and IM 101 and IM 102 portable tanks; UN portable tanks, marine portable tanks conforming to 46 CFR part 64; and sift-proof non-DOT Specification portable tanks and closed bulk bins are authorized.

(d) IBCs. IBCs are authorized subject to the conditions and limitations of this section provided the

IBC type is authorized according to the IBC packaging code specified for the specific hazardous material in Column (7) of the § 172.101 Table of this subchapter and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group performance level as specified in column 5 of the §172.101 Table of this subchapter for the material being transported.

(1) IBCs may not be used for the following hazardous materials:

(i) Packing Group I liquids; and (ii) Packing Group I solids that may become liquid during transportation.

(2) The following IBCs may not be used for Packing Group II and III solids that may become liquid during transportation: (i) Wooden: 11C, 11D and 11F; (ii) Fiberboard: 11G; (iii) Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, (iv) Composite: 11HZ2 and 21HZ2.

(e) Large Packagings. Large Packagings are authorized subject to the conditions and limitations of this

section provided the Large Packaging type is authorized according to the IBC packaging code specified for the specific hazardous material in Column (7) of the § 172.101 Table of this subchapter and the Large Packaging conforms to the requirements in subpart Q of part 178 of this subchapter at the Packing Group performance level as specified in Column (5) of the § 172.101 Table for the material being transported.

(1) Except as specifically authorized in this subchapter, Large Packagings may not be used for

Packing Group I or II hazardous materials. (2) Large Packagings with paper or fiberboard inner receptacles may not be used for solids that may

become liquid in transportation.

(f) Flexible Bulk Containers. Flexible Bulk Containers are authorized subject to the conditions and limitations of this section provided the use of a Flexible Bulk Container is authorized by the inclusion of bulk packaging code B120 in Column (7) of the § 172.101 Hazardous Materials Table of this subchapter and the Flexible Bulk Container conforms to the requirements in subpart S of part 178 of

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this subchapter. Flexible Bulk Containers may not be used for Packing Group I or II hazardous materials.

173.241 Bulk packagings for certain low hazard liquid and solid materials. When §172.101 of this subchapter specifies that a hazardous material be packaged under this section, only the following bulk packagings are authorized, subject to the requirements of subparts A and B of part 173 of this subchapter and the special provisions specified in Column 7 of the §172.101 Table. (a) Rail cars: Class DOT 103, 104, 105, 109, 111, 112, 114, 115, or 120 tank car tanks; Class 106 or

110 multi-unit tank car tanks and AAR Class 203W, 206W, and 211W tank car tanks. (b) Cargo tanks: DOT specification MC 300, MC 301, MC 302, MC 303, MC 304, MC 305, MC 306,

MC 307, MC 310, MC 311, MC 312, MC 330, MC 331, DOT 406, DOT 407, and DOT 412 cargo tank motor vehicles; and non-DOT specification cargo tank motor vehicles suitable for transport of liquids.

(c) Portable tanks: DOT Specification 51, 56, 57 and 60 portable tanks; IMO type 1, 2 and 5, and IM

101 and IM 102 portable tanks; Un portable tanks, marine portable tanks conforming to 46 CFR part 64; and non-DOT Specification portable tanks suitable for transport of liquids are authorized. For transportation by vessel, also see § 176.340 of this subchapter.

(d) Intermediate bulk containers (IBCs).

IBCs are authorized subject to the conditions and limitations of this section provided the IBC type is authorized according to the IBC packaging code specified for the specific hazardous material in Column (7) of the § 172.101 Table of this subchapter and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group performance level as specified in Column 5 of the §172.101 Table for the material being transported.


(i) Packing Group I liquids; and (ii) Packing Group I solids that may become liquid during transportation.

(2) The following IBCs may not be used for Packing Group II and III solids that may become liquid during transportation: (i) Wooden: 11C, 11D and 11F; (ii) Fiberboard: 11G; (iii) Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4,13M1 and

13M2; and (iv) Composite: 11HZ2 and 21HZ2.







173.242 Bulk packagings for certain medium hazard liquids and solids, including solids with dual hazards.

When §172.101 of this subchapter specifies that a hazardous material be packaged under this section, only the following bulk packagings are authorized, subject to the requirements of subparts A and B of part 173 of this subchapter and the special provisions specified in Column 7 of the §172.101 Table. (a) Rail cars: Class DOT 103, 104, 105, 109, 111, 112, 114, 115, or 120 tank car tanks; Class 106 or

110 multi-unit tank car tanks and AAR Class 206W tank car tanks. (b) Cargo tanks: Specification MC 300, MC 301, MC 302, MC 303, MC 304, MC 305, MC 306, MC

307, MC 310, MC 311, MC 312, MC 330, MC 331, DOT 406, DOT 407, and DOT 412 cargo tank motor vehicles. Cargo tanks used to transport Class 3, Packing Group I or II, or Packing Group III with a flash point of less than 38 C (100 F); Class 6, Packing Group I or II; and Class 8, Packing Group I or II materials must conform to the following special requirements:

(1) Pressure relief system: Except as provided by §173.33(d), each cargo tank must be

equipped with a pressure relief system meeting the requirements of §178.346-3 or §178.347-4 of this subchapter. However, pressure relief devices on MC 310, MC 311 and MC 312 cargo tanks must meet the requirements for a Specification MC 307 cargo tank (except for Class 8, Packing Group I and II). Pressure relief devices on MC 330 and MC 331 cargo tanks must meet the requirement in §178.337-9 of this subchapter.

(2) Bottom outlets: DOT 406, DOT 407 and DOT 412 must be equipped with stop-valves

meeting the requirements of §178.345-11 of this subchapter; MC 304, MC 307, MC 310, MC 311, and MC 312 cargo tanks must be equipped with stop-valves capable of being remotely closed within 30 seconds of actuation by manual or mechanic means and (except for Class 8, Packing Group I and II) by a closure activated at a temperature not over 121 C (250 F); MC 330 and MC 331 cargo tanks must be equipped with internal self-closing stop-valves meeting the requirements in §178.337-11 of this subchapter.

(c) Portable tanks: DOT Specification 51, 56, 57 and 60 portable tanks; Specification IM 101 amd IM

102 and UN portable tanks when a T Code is specified in Column (7) of the § 172.101 Hazardous Materials Table for a specific hazardous material; and marine portable tanks conforming to 46 CFR part 64 are authorized. DOT Specification 57 portable tanks used for the transport by vessel of Class 3, Packaging Group II, materials must conform to the following:

(1) Minimum design pressure. Each tank must have a minimum design pressure of 62 kPa

(9 psig); and

(2) Pressure relief devices. Each tank must be equipped with at least one pressure relief device, such as a spring-loaded valve or fusible plug, conforming to the following:

(i) Each pressure relief device must communicate with the vapor space of the tank

when the tank is in a normal transportation attitude. Shutoff valves may not be installed between the tank opening and any pressure relief device. Pressure relief devices must be mounted, shielded, or drained to prevent the accumulation of any material that could impair the operation or discharge capability of the device;

(ii) Frangible devices are not authorized;

(iii) No pressure relief device may open at less than 34.4 kPa (5 psig);

(iv) If a fusible device is used for relieving pressure, the device must have a minimum

area of 1.25 square inches. The device must function at a temperature between 104°C. and 149°C. (220°F. and 300°F.) and at a pressure less than the design test pressure of the tank, unless this latter function is accomplished by a separate device; and


(v) No relief device may be used which would release flammable vapors under

normal conditions of transportation (temperature up to and including 54°C. (130°F); and

(3) Venting capacity. The minimum venting capacity for pressure activated vents must be

6,000 cubic feet of free air per hour (measured at 101.3 kPa (14.7 psi) and 15.6°C. (60°F.)) at not more than 34.4 kPa (5 psi). The total emergency venting capacity (cu. ft./hr.) of each portable tank must be at least that determined from the following table:

Total surface area feet2 Cubic feet free air per hour

20 15,800

30 23,700

40 31,600

50 39,500

60 47,400

70 55,300

80 63,300

90 71,200

100 79,100

120 94,900

140 110,700

160 126,500

1 Interpolate for intermediate sizes.

(d) IBCs.

IBCs are authorized subject to the conditions and limitations of this section provided the IBC type is authorized according to the IBC packaging code specified for the specific hazardous material in Column (7) of the § 172.101 Table of this subchapter and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group performance level specified in Column (5) of the § 172.101 Table of this subchapter for the material being transported.


(I) Packing Group I liquids; and (ii) Packing Group I solids that may become liquid during transportation.

(2) The following IBCs may not be used for Packing Group II and III solids that may become liquid during transportation: (I) Wooden: 11C, 11D and 11F; (ii) Fiberboard: 11G; (iii) Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4,13M1 and








173.243 Bulk packaging for certain high hazard liquids and dual hazard materials which pose a moderate hazard.

When §172.101 of this subchapter specifies that a hazardous material be packaged under this section, only the following bulk packagings are authorized, subject to the requirements of subparts A and B of part 173 of this subchapter and the special provisions specified in Column 7 of the §172.101 Table. (a) Rail cars: Class DOT 103, 104, 105, 109, 111, 112, 114, 115, or 120 fusion-welded tank car

tanks; and Class 106 or 110 multi-unit tank car tanks. (b) Cargo tanks. Specification MC 304, MC 307, MC 330, MC 331 cargo tank motor vehicles; and

MC 310, MC 311, MC 312, DOT 407, and DOT 412 cargo tank motor vehicles with tank design pressure of at least 172.4 kPa (25 psig). Cargo tanks used to transport Class 3 or Division 6.1 materials, or Class 8, Packing Group I or II materials must conform to the following special requirements:

(1) Pressure relief system: Except as provided by §173.33(d), each cargo tank must be equipped with a pressure relief system meeting the requirements of §178.346-3 or 178.347-4 of this subchapter. However, pressure relief devices on MC 310, MC 311 and MC 312 cargo tanks must meet the requirements for a Specification MC 307 cargo tank (except for Class 8, Packing Group I and II). Pressure relief devices on MC 330 and MC 331 cargo tanks must meet the requirement in §178.337-9 of this subchapter.

(2) Bottom outlets: DOT 407 and DOT 412 cargo tanks must be equipped with stop-valves

meeting the requirements of §178.345-11 of this subchapter; MC 304, MC 307, MC 310, MC 311, and MC 312 cargo tanks must be equipped with stop-valves capable of being remotely closed within 30 seconds of actuation by manual or mechanic means and (except for Class 8, Packing Group I and II) by a closure activated at a temperature not over 121 C (250 F); MC 330 and MC 331 cargo tanks must be equipped with internal self-closing stop-valves meeting the requirements in §178.337-11 of this subchapter.

(c) Portable tanks. DOT Specification 51 and 60 portable tanks; UN portable tanks and IM101 and IM

102 portable tanks when a T code is specified in Column (7) of the § 172.101 Table of this subchapter for a specific hazardous material; and marine portable tanks conforming to 46 CFR part 64 with design pressure of at least 172.4 kPa (25 psig) are authorized.

(d) IBCs. IBCs are authorized subject to the conditions and limitations of this section provided the

IBC type is authorized according to the IBC packaging code specified for the specific hazardous material in Column (7) of the § 172.101 Table of this subchapter and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group performance level as specified in Column (5) of the § 172.101 Table of this subchapter for the material being transported.


(I) Packing Group I liquids; and (ii) Packing Group I solids that may become liquid during transportation.

(2) The following IBCs may not be used for Packing Group II and III solids that may become liquid during transportation: (I) Wooden: 11C, 11D and 11F; (ii) Fiberboard: 11G; (iii) Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and


(e) A dual hazard material may be packaged in accordance with §173.242 if:

(1) The subsidiary hazard is Class 3 with a flash point greater than 38 C (100 F); or


(2) The subsidiary hazard is Division 6.1, Packing Group III; or

(3) The subsidiary hazard is Class 8, Packaging Group, III. 173.244 Bulk packaging for certain pyrophoric liquids (Division 4.2), dangerous when wet

(Division 4.3) materials, and poisonous liquids with inhalation hazards (Division 6.1).

When §172.101 of this subchapter specifies that a hazardous material be packaged under this section, only the following bulk packagings are authorized, subject to the requirements of subparts A and B of part 173 of this subchapter and the special provisions specified in Column 7 of the §172.101 Table. (a) Rail cars: Class DOT 105, 109, 112, 114, or 120 fusion-welded tank car tanks; and Class 106 or

110 multi-unit tank car tanks. (b) Cargo tanks: Specifications MC 330 and MC 331 cargo tank motor vehicles and, except for

Division 4.2 materials, MC 312 and DOT 412 cargo tank motor vehicles. (c) Portable tanks: DOT 51 portable tanks and UN portable tanks that meet the requirements of this

subchapter, when a T code is specified in Column (7) of the § 172.101 Table of this subchapter for the specific hazardous material, are authorized. Additionally, a DOT 51 or UN portable tank used for Division 6.1 liquids, Hazard Zone A or B, must be certified and stamped to the ASME Code as specified in § 178.273(b)(6) of this subchapter.

173.245 Bulk packaging for extremely hazardous materials such as poisonous gases

(Division 2.3). When §172.101 of this subchapter specifies that a hazardous material be packaged under this section, only the following bulk packagings are authorized, subject to the requirements of subparts A and B of part 173 of this subchapter and the special provisions specified in Column 7 of the §172.101 Table. (a) Tank car tanks and multi-unit tank car tanks, when approved by the Associate Administrator. (b) Cargo tank motor vehicles and portable tanks, when approved by the Associate Administrator. 173.247 Bulk packaging for certain elevated temperature materials. When §172.101 of this subchapter specifies that a hazardous material be packaged under this section, only the following bulk packagings are authorized, subject to the requirements of subparts A and B of part 173 of this subchapter and the special provisions in Column 7 of the §172.101 Table. On or after October 1, 1993, authorized packagings must meet all requirements in paragraph (g) of this section, unless otherwise excepted. (a) Rail cars: Class DOT 103, 104, 105, 109, 111, 112, 114, 115, or 120 tank car tanks; Class DOT

106, 110 multi-unit tank car tanks; AAR Class 203W, 206W, 211W tank car tanks; and non-DOT specification tank car tanks equivalent in structural design and accident damage resistance to specification packagings.

(b) Cargo tanks: Specification MC 300, MC 301, MC 302, MC 303, MC 304, MC 305, MC 306, MC

307, MC 310, MC 311, MC 312, MC 330, MC 331 cargo tank motor vehicles; DOT 406, DOT 407, DOT 412 cargo tank motor vehicles; and non-DOT specification cargo tank motor vehicles equivalent in structural design and accident damage resistance to specification packagings. A non-DOT specification cargo tank motor vehicle constructed of carbon steel which is in elevated temperature material service is excepted from §178.345-7(d)(5) of this subchapter.

(c) Portable tanks. DOT Specification 51, 56, 57 and 60 portable tanks; IM 101 and IM 102 portable

tanks; UN portable tanks; marine portable tanks conforming to 46 CFR part 64; metal IBCs and


non-specification portable tanks equivalent in structural design and accident damage resistance to specification packagings are authorized.

(d) Crucibles: Nonspecification crucibles designed and constructed such that the stress in the

packaging does not exceed one fourth (0.25) of the ultimate strength of the packaging material at any temperature within the design temperature range. Stress is determined under a load equal to the sum of the static or working pressure in combination with the loads developed from accelerations and decelerations incident to normal transportation. For highway transportation, these forces are assumed to be ``1.7g'' vertical, ``0.75g'' longitudinal, and ``0.4g'' transverse, in reference to the axes of the transport vehicle. Each accelerative or decelerative load may be considered separately.

(e) Kettles: A kettle, for the purpose of this section, is a bulk packaging (portable tank or cargo tank)

having a capacity not greater than 5678 L (1500 gallons) with an integral heating apparatus used for melting various bituminous products such as asphalt. Kettles used for the transport of asphalt or bitumen are subject to the following requirements:

(1) Low stability kettles. Kettles with a ratio of track-width to fully loaded center of gravity

(CG) height less than 2.5 must meet all requirements of paragraph (g) of this section (track-width is the distance measured between the outer edge of the kettle tires; CG height is measured perpendicular from the road surface).

(2) High stability kettles.

(i) Kettles with a total capacity of less than 2650 L (700 gallons) and a ratio of

track-width to fully loaded CG height of 2.5 or more are excepted from all requirements of paragraph (g)(2) of this section and the rollover protection requirements of paragraph (g)(6) of this section, if closures meet the requirements of paragraph (e)(2)(iii) of this section.

(ii) Kettles with a total capacity of 2650 L (700 gallons) or more and a ratio of

track-width to fully loaded CG height of 2.5 or more are excepted from the ``substantially leak tight'' requirements of paragraph (g)(2) of this section and the rollover protection requirements of paragraph (g)(6) of this section if closures meet the requirements of paragraph (e)(2)(iii) of this section.

(iii) Closures must be securely closed during transportation. Closures also must be

designed to prevent opening and the expulsion of lading in a rollover accident. (f) Other bulk packagings: Bulk packagings, other than those specified in paragraphs (a) through (e)

of this section, which are used for the transport of elevated temperature materials, must conform to all requirements of paragraph (g) of this section on or after October 1, 1993.

(g) General requirements. Bulk packagings authorized or used for transport of elevated temperature

materials must conform to the following requirements:

(1) Pressure and vacuum control equipment. When pressure or vacuum control equipment is required on a packaging authorized in this section, such equipment must be of a self-reclosing design, must prevent package rupture or collapse due to pressure, must prevent significant release of lading due to packaging overturn or splashing or surging during normal transport conditions, and may be external to the packaging.

(i) Pressure control equipment is not required if pressure in the packaging would

increase less than 10 percent as a result of heating the lading from the lowest design operating temperature to a temperature likely to be encountered if the packaging were engulfed in a fire. When pressure control equipment is required, it must prevent rupture of the packaging from heating, including fire engulfment.

(ii) Vacuum control equipment is not required if the packaging is designed to


withstand an external pressure of 100 kPa (14.5 psig) or if pressure in the packaging would decrease less than 10 percent as a result of the lading cooling from the highest design operating temperature to the lowest temperature incurred in transport. When vacuum control equipment is required, it must prevent collapse of the packaging from a cooling-induced pressure differential.

(iii) When the regulations require a reclosing pressure relief device, the lading must

not render the devices inoperable (i.e. from clogging, freezing, or fouling). If the lading affects the proper operation of the device, the packaging must have:

(A) A safety relief device incorporating a frangible disc or a permanent

opening, each having a maximum effective area of 22 cm\2\ (3.4 in.\2\), for transportation by highway;

(B) For transportation of asphalt by highway, a safety relief device

incorporating a frangible disc or a permanent opening, each having a maximum effective area of 48 cm\2\ (7.4 in\2\); or

(C) For transportation by rail, a non reclosing pressure relief device

incorporating a rupture disc, conforming to the requirements of §179.15 of this subchapter.

(iv) Reclosing pressure relief devices, frangible discs or permanent openings must

not allow the release of lading during normal transportation conditions (i.e., due to splashing or surging).

(2) Closures. All openings, except permanent vent openings authorized in paragraph

(g)(1)(iii) of this section, must be securely closed during transportation. Packagings must be substantially leak-tight so as not to allow any more than dripping or trickling of a non-continuous flow when overturned. Closures must be designed and constructed to withstand, without exceeding the yield strength of the packaging, twice the static loading produced by the lading in any packaging orientation and at all operating temperatures.

(3) Strength. Each packaging must be designed and constructed to withstand, without

exceeding the yield strength of the packaging, twice the static loading produced by the lading in any orientation and at all operating temperatures.

(4) Compatibility. The packaging and lading must be compatible over the entire operating

temperature range.

(5) Markings. In addition to any other markings required by this subchapter, each packaging must be durably marked in a place readily accessible for inspection in characters at least 4.8 mm (3/16 inch) with the manufacturer's name, date of manufacture, design temperature range, and maximum product weight (or ``load limit'' for tank cars) or volumetric capacity.

(6) Accident damage protection. For transportation by highway, external loading and

unloading valves and closures must be protected from impact damage resulting from collision or overturn. Spraying equipment and the road oil application portion of a packaging are excepted from this requirement.

(7) New construction. Specification packagings that are being manufactured for the transport

of elevated temperature materials must be authorized for current construction. (h) Exceptions.

(1) General. Packagings manufactured for elevated temperature materials service prior to October 1, 1993, which are not in full compliance with the requirements in paragraph (g) of this section, may continue in service if they meet the applicable requirements of


subparts A and B of this part and meet the closure requirements in paragraph (g)(2) of this section by March 30, 1995.

(2) Kettles. Kettles in service prior to October 1, 1993, which are used to transport asphalt or

bitumen, are excepted from specific provisions of this section as follows:

(i) Kettles with a total capacity of less than 2650 L (700 gallons), which are not in full compliance with the requirements of paragraph (g) of this section, may continue in elevated temperature material service if they meet the applicable requirements of subparts A and B of this part and if, after March 30, 1995, closures are secured during transport to resist opening in an overturn.

(ii) Kettles with a total capacity of 2650 L (700 gallons) or more, which are not in full

compliance with the requirements of paragraph (g) of this section, may continue in elevated temperature material service if they meet the applicable requirements of subparts A and B of this part and if, after March 30, 1995, closures are secured during transport to resist opening in an overturn and no opening exceeds 46 cm\2\ (7.1 in\2\).

(3) Molten metals and molten glass. This section does not apply to packagings used for

transportation of molten metals and molten glass by rail when movement is restricted to operating speeds less than 15 miles per hour. (See §172.203(g)(3) of this subchapter for shipping paper requirements.)

(4) Solid elevated temperature materials. A material which meets the definition of a solid

elevated temperature material is excepted from all requirements of this subchapter except §172.325 of this subchapter.

173.249 Bromine When §172.101 of this subchapter specifies that a hazardous material be packaged under this section, only the following bulk packagings are authorized, subject to the requirements of subparts A and B of part 173 of this subchapter and the special provisions specified in Column 7 of the §172.101 Table. (a) Class DOT 105A300W or 105A500W tank cars. Class 105A500W tank cars may be equipped

with manway cover plates, pressure relief valves, vent valves, and loading/unloading valves that are required on Class 105A-300W tank cars. Tank cars must conform with paragraphs (d) through (f) of this section.

(b) Specification MC 310, MC 311, MC 312 or DOT 412 cargo tank motor vehicles conforming with

paragraphs (d) through (f) of this section. Except when transported as a residue, the total quantity in one tank may not be less than 88 percent or more than 96 percent of the volume of the tank. Cargo tanks in bromine service built prior to August 31, 1991, may continue in service under the requirements contained in § 173.252(a)(4) of this part in effect on September 30, 1991.

(c) UN portable tanks conforming to tank code T22 (see § 172.102 of this subchapter) or

specification IM 101 portable tanks conforming with paragraphs (d) through (f) of this section. Except when transported as a residue, the total quantity in one tank may not be less than 88% nor more than 92% of the volume of the tank.

(d) The tank must be made from nickel-clad or lead-lined steel plate. Nickel cladding or lead lining

must be on the inside of the tank. Nickel cladding must comprise at least 20 percent of the required minimum total thickness. Nickel cladding must conform to ASTMB 162 (IBR, see § 171.7 of this subchapter). Lead lining must be at least 4.763 mm (0.188 inch) thick. All tank equipment and appurtenances in contact with the lading must be lined or made from metal not subject to deterioration by contact with lading.

(e) Maximum filling density is 300 percent of the tank's water capacity. Minimum filling density is 287

percent of the tank's water capacity. Maximum water capacity is 9,253 kg (20,400 pounds) for


DOT 105A300W tank cars. Maximum quantity of lading in DOT 105A300W tank cars is 27,216 kg (60,000 pounds). Maximum water capacity is 16,964 kg (37,400 pounds) for DOT 105A500W tank cars and DOT 105A500W tank cars equipped as described in paragraph (a) of this section. Maximum quantity of lading in DOT 105A500W tank cars is 49,895 kg (110,000 pounds).

(f) Tank shell and head thickness for cargo tank motor vehicles and portable tanks must be at least

9.5 mm (0.375 inch) excluding lead lining. 173.251 Bulk packaging for ammonium nitrate emulsion, suspension, or gel. When §172.101 of this subchapter specifies that a hazardous material be packaged under this section, only the following bulk packagings are authorized, subject to the requirements of subparts A and B of part 173 of this subchapter and the special provisions specified in column 7 of the §172.101 table. (a) IBCs. IBCs are authorized subject to the conditions and limitations of this section provided:

(1) The IBC type is authorized according to the IBC packaging code for the specific hazardous material in Column (7) of the §172.101 Table;

(2) The IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group performance level in Column (5) of the §172.101 Table for the material being transported.

(b) [Reserved]

APPENDIX 6

SPECIAL PROVISIONS

49 CFR 172.102

Topic Page

Special Provisions applicable to all modes and packaging (Numeric) ............................................ A6-2

Special provisions applicable to transportation by air (A) only. ..................................................... A6-25

Special provisions applicable to bulk (B) packaging only ............................................................... A6-29

Special provisions applicable to intermediate bulk (IB and IP) packaging. ................................... A6-35

Special provisions applicable to non-bulk (N) packaging only ....................................................... A6-38

Special provisions applicable to transportation by rail (R) only. .................................................... A6-40

Special provisions applicable to intermodal portable tanks (T and TP) ........................................ A6-41

Special provisions applicable to transportation by water (W) ........................................................ A6-48


172.102 SPECIAL PROVISIONS (a) General. When Column 7 of the §172.101 Table refers to a special provision for a hazardous

material, the meaning and requirements of that provision are as set forth in this section. When a special provision specifies packaging or packaging requirements-

(1) The special provision is in addition to the standard requirements for all packagings prescribed

in §173.24 of this subchapter and any other applicable packaging requirements in subparts A and B of part 173 of this subchapter; and

(2) To the extent a special provision imposes limitations or additional requirements on the

packaging provisions set forth in Column 8 of the §172.101 Table, packagings must conform to the requirements of the special provision.

(b) Description of codes for special provisions. Special provisions contain packaging provisions,

prohibitions, exceptions from requirements for particular quantities or forms of materials and requirements or prohibitions applicable to specific modes of transportation, as follows:

(1) A code consisting only of numbers (for example, “ 11” ) is multi-modal in application and may

apply to bulk and non-bulk packagings. (2) A code containing the letter “A” refers to a special provision which applies only to

transportation by aircraft. (3) A code containing the letter “B” refers to a special provision that applies only to bulk

packaging requirements. Unless otherwise provided in this subchapter, these special provisions do not apply to UN, IM Specification portable tanks or IBCs.

(4) A code containing the letters “IB” or “IP” refers to a special provision that applies only to

transportation in IBCs. (5) A code containing the letter “N” refers to a special provision which applies only to non-bulk

packaging requirements. (6) A code containing the letter “R” refers to a special provision which applies only to

transportation by rail. (7) A code containing the letter “T” refers to a special provision which applies only to

transportation in UN or IM Specification portable tanks. (8) A code containing the letters “TP” refers to a portable tank special provision for UN or IM

Specification portable tanks that is in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter.

(9) A code containing the letter “W” refers to a special provision that applies only to

transportation by water. (c) Tables of special provisions. The following tables list, and set forth the requirements of, the special

provisions referred to in Column 7 of the §172.101 Table.


(1) Numeric provisions. These provisions are multi-modal and apply to bulk and non-bulk packagings:

Code Special Provision 1 This material is poisonous by inhalation (see §171.8 of this subchapter) in Hazard Zone A (see

§173.116(a) or §173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter.

2 This material is poisonous by inhalation (see §171.8 of this subchapter) in Hazard Zone B (see

§173.116(a) or §173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter.

3 This material is poisonous by inhalation (see §171.8 of this subchapter) in Hazard Zone C (see

§173.116(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter.

4 This material is poisonous by inhalation (see §171.8 of this subchapter) in Hazard Zone D (see

§173.116(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter.

5 If this material meets the definition for a material poisonous by inhalation (see §171.8 of this

subchapter), a shipping name must be selected which identifies the inhalation hazard, in Division 2.3 or Division 6.1, as appropriate.

6 This material is poisonous-by-inhalation and must be described as an inhalation hazard under the

provisions of this subchapter. 7 Removed: DOT 68 FR 44992 07/31/03. 8 A hazardous substance that is not a hazardous waste may be shipped under the shipping

description `Òther regulated substances, liquid or solid, n.o.s.'', as appropriate. In addition, for solid materials, special provision B54 applies.

9 Packaging for certain PCBs for disposal and storage is prescribed by EPA in 40 CFR 761.60 and

761.65. 10 Removed: DOT 68 FR 44992 07/31/03. 11 The hazardous material must be packaged as either a liquid or a solid, as appropriate, depending

on its physical form at 55 C (131 F) at atmospheric pressure. 12 In concentrations greater than 40 percent, this material has strong oxidizing properties and is

capable of starting fires in contact with combustible materials. If appropriate, a package containing this material must conform to the additional labeling requirements of §172.402 of this subchapter.

13 The words `Ìnhalation Hazard'' shall be entered on each shipping paper in association with the

shipping description, shall be marked on each non-bulk package in association with the proper shipping name and identification number, and shall be marked on two opposing sides of each bulk package. Size of marking on bulk package must conform to §172.302(b) of this subchapter. The requirements of §§172.203(m) and 172.505 of this subchapter do not apply.


14 Motor fuel antiknock mixtures are: a. Mixtures of one or more organic lead mixtures (such as tetraethyl lead, triethylmethyl lead,

diethyldimethyl lead, ethyltrimethyl lead, and tetramethyl lead) with one or more halogen compounds (such as ethylene dibromide and ethylene dichloride), hydrocarbon solvents or other equally efficient stabilizers; or

b. tetraethyl lead. 15 This entry applies to ``Chemical kits'' and ``First aid kits'' containing one or more compatible items

of hazardous materials in boxes, cases, etc. that, for example, are used for medical, analytical, diagnostic, testing, or repair purposes. Kits that are carried on board transport vehicles for first aid or operating purposes are not subject to the requirements of this subchapter.

16 This description applies to smokeless powder and other propellant powders that are used as

powder for small arms and have been classed as Division 1.3C and 1.4C and reclassed to Division 4.1 in accordance with § 173.56 and § 173.58 of this subchapter..

19 For domestic transportation only, the identification number `ÙN1075'' may be used in place of

the identification number specified in Column (4) of the §172.101 Table. The identification number used must be consistent on package markings, shipping papers and emergency response information.

21 This material must be stabilized by appropriate means (e.g., addition of chemical inhibitor,

purging to remove oxygen) to prevent dangerous polymerization (see §173.21(f) of this subchapter).

22 If the hazardous material is in dispersion in organic liquid, the organic liquid must have a flash

point above 50 C (122 F). 23 This material may be transported under the provisions of Division 4.1 only if it is so packed that

the percentage of diluent will not fall below that stated in the shipping description at any time during transport. Quantities of not more than 500 g per package with not less than 10 percent water by mass may also be classed in Division 4.1, provided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria.

24 Alcoholic beverages containing more than 70 percent alcohol by volume must be transported as

materials in Packing Group II. Alcoholic beverages containing more than 24 percent but not more than 70 percent alcohol by volume must be transported as materials in Packing Group III.

26 This entry does not include ammonium permanganate, the transport of which is prohibited except

when approved by the Associate Administrator for Hazardous Materials Safety. 28 The dihydrated sodium salt of dichloroisocyanuric acid does not meet the criteria for inclusion in

Division 5.1 (Oxidizer) and is not subject to the requirements of this subchapter unless meeting the criteria for inclusion in another class or division.

30 Sulfur is not subject to the requirements of this subchapter if transported in a non-bulk packaging

or if formed to a specific shape (for example, prills, granules, pellets, pastilles, or flakes). A bulk packaging containing sulfur is not subject to the placarding requirements of subpart F of this part, if it is marked with the appropriate identification number as required by subpart D of this part. Molten sulfur must be marked as required by § 172.325 of this subchapter.

31 Materials which have undergone sufficient heat treatment to render them non-hazardous are not

subject to the requirements of this subchapter. 32 Polymeric beads and molding compounds may be made from polystyrene, poly(methyl

methacrylate) or other polymeric material.


33 Ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt are prohibited. 34 The commercial grade of calcium nitrate fertilizer, when consisting mainly of a double salt

(calcium nitrate and ammonium nitrate) containing not more than 10 percent ammonium nitrate and at least 12 percent water of crystallization, is not subject to the requirements of this subchapter.

35 Antimony sulphides and oxides which do not contain more than 0.5 percent of arsenic calculated

on the total mass do not meet the definition of Division 6.1. 37 Unless it can be demonstrated by testing that the sensitivity of the substance in its frozen state is

no greater than in its liquid state, the substance must remain liquid during normal transport conditions. It must not freeze at temperatures above -15 C (5 F).

38 If this material shows a violent effect in laboratory tests involving heating under confinement, the

labeling requirements of Special Provision 53 apply, and the material must be packaged in accordance with packing method OP6 in §173.225 of this subchapter. If the SADT of the technically pure substance is higher than 75 C, the technically pure substance and formulations derived from it are not self-reactive materials and, if not meeting any other hazard class, are not subject to the requirements of this subchapter.

39 This substance may be carried under provisions other than those of Class 1 only if it is so packed

that the percentage of water will not fall below that stated at any time during transport. When phlegmatized with water and inorganic inert material, the content of urea nitrate must not exceed 75 percent by mass and the mixture should not be capable of being detonated by test 1(a)(i) or test 1(a) (ii) in the UN Recommendations Tests and Criteria.

40 Polyester resin kits consist of two components: A base material (either Class 3 or Division 4.1,

Packing Group II or III) and an activator (organic peroxide), each separately packed in an inner packaging. The organic peroxide must be type D, E, or F, not requiring temperature control. The components may be placed in the same outer packaging provided they will not interact dangerously in the event of leakage. The Packing Group assigned will be II or III, according to the classification criteria for either Class 3 or Division 4.1, as appropriate, applied to the base material. Additionally, unless otherwise excepted in this subchapter, polyester resin kits must be packaged in specification combination packagings based on the performance level of the base material contained within the kit.

41 This material at the Packing Group II hazard criteria level may be transported in Large

Packagings. 43 The membrane filters, including paper separators and coating or backing materials, that are

present in transport, must not be able to propagate a detonation as tested by one of the tests described in the UN Manual of Tests and Criteria, Part I, Test series 1(a) (see § 171.7 of this subchapter). On the basis of the results of suitable burning rate tests, and taking into account the standard tests in the UN Manual of Tests and Criteria, Part III, subsection 33.2.1 (see § 171.7 of this subchapter), nitrocellulose membrane filters in the form in which they are to be transported that do not meet the criteria for a Division 4.1 material are not subject to the requirements of this subchapter. Packagings must be so constructed that explosion is not possible by reason of increased internal pressure. Nitrocellulose membrane filters covered by this entry, each with a mass not exceeding 0.5 g, are not subject to the requirements of this subchapter when contained individually in an article or a sealed packet.

44 The formulation must be prepared so that it remains homogeneous and does not separate during

transport. Formulations with low nitrocellulose contents and neither showing dangerous properties when tested for their ability to detonate, deflagrate or explode when heated under defined confinement by the appropriate test methods and criteria in the UN Recommendations, Tests and Criteria, nor classed as a Division 4.1 (flammable solid) when tested in accordance


with the procedures specified in § 173.124 of this subchapter (chips, if necessary, crushed and sieved to a particle size of less than 1.25 mm) are not subject to the requirements of this subchapter.

45 Temperature should be maintained between 18°C (64.4°F) and 40°C (104°F). Tanks containing

solidified methacrylic acid must not be reheated during transport. 46 This material must be packed in accordance with packing method OP6 (see §173.225 of this

subchapter). During transport, it must be protected from direct sunshine and stored (or kept) in a cool and well-ventilated place, away from all sources of heat.

47 Mixtures of solids that are not subject to this subchapter and flammable liquids may be

transported under this entry without first applying the classification criteria of Division 4.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Except when the liquids are fully absorbed in solid material contained in sealed bags, for single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. Small inner packagings consisting of sealed packets and articles containing less than 10 mL of a Class 3 liquid in Packing Group II or III absorbed onto a solid material are not subject to this subchapter provided there is no free liquid in the packet or article.

48 Mixtures of solids that are not subject to this subchapter and toxic liquids may be transported

under this entry without first applying the classification criteria of Division 6.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. This entry may not be used for solids containing a Packing Group I liquid.

49 Mixtures of solids which are not subject to this subchapter and corrosive liquids may be

transported under this entry without first applying the classification criteria of Class 8, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level.

50 Cases, cartridge, empty with primer which are made of metallic or plastic casings and meeting

the classification criteria of Division 1.4 are not regulated for domestic transportation. 51 This description applies to items previously described as "Toy propellant devices, Class C" and

includes reloadable kits. Model rocket motors containing 30 grams or less propellant are classed as Division 1.4S and items containing more than 30 grams of propellant but not more than 62.5 grams of propellant are classed as Division 1.4C.

52 This entry may only be used for substances that are too insensitive for acceptance into Class 1

(explosive) when tested in accordance with Test Series 2 in the UN Manual of Tests and Criteria, Part I (incorporated by reference; see §171.7 of this subchapter).

53 Packages of these materials must bear the subsidiary risk label, ‘‘EXPLOSIVE’’, and the

subsidiary hazard class/division must be entered in parentheses immediately following the primary hazard class in the shipping description, unless otherwise provided in this subchapter or through an approval issued by the Associate Administrator, or the competent authority of the country of origin. A copy of the approval shall accompany the shipping papers.

54 Maneb or maneb preparations not meeting the definition of Division 4.3 or any other hazard class

are not subject to the requirements of this subchapter when transported by motor vehicle, rail car, or aircraft.

55 This device must be approved in accordance with §173.56 of this subchapter by the Associate


Administrator for Hazardous Materials Safety. 56 A means to interrupt and prevent detonation of the detonator from initiating the detonating cord

must be installed between each electric detonator and the detonating cord ends of the jet perforating guns before the charged jet perforating guns are offered for transportation.

57 Maneb or Maneb preparations stabilized against self-heating need not be classified in Division

4.2 when it can be demonstrated by testing that a volume of 1 m3 of substance does not self-ignite and that the temperature at the center of the sample does not exceed 200 C, when the sample is maintained at a temperature of not less than 75 C 2 C for a period of 24 hours, in accordance with procedures set forth for testing self-heating materials in the UN Manual of Tests and Criteria.

58 Aqueous solutions of Division 5.1 inorganic solid nitrate substances are considered as not

meeting the criteria of Division 5.1 if the concentration of the substances in solution at the minimum temperature encountered in transport is not greater than 80% of the saturation limit.

59 Ferrocerium, stabilized against corrosion, with a minimum iron content of 10 percent is not

subject to the requirements of this subchapter. 61 A chemical oxygen generator is spent if its means of ignition and all or a part of its chemical

contents have been expended. 62 Oxygen generators (see Sec. 171.8 of this subchapter) are not authorized for transportation

under this entry. 64 The group of alkali metals includes lithium, sodium, potassium, rubidium, and caesium. 65 The group of alkaline earth metals includes magnesium, calcium, strontium, and barium. 66 Formulations of these substances containing not less than 30 percent non-volatile,

non-flammable phlegmatizer are not subject to this subchapter. 70 Black powder that has been classed in accordance with the requirements of §173.56 of this

subchapter may be reclassed and offered for domestic transportation as a Division 4.1 material if it is offered for transportation and transported in accordance with the limitations and packaging requirements of §173.170 of this subchapter.

74 During transport, this material must be protected from direct sunshine and stored or kept in a cool and well-ventilated place, away from all sources of heat.

78 This entry may not be used to describe compressed air which contains more than 23.5 percent

oxygen. Compressed air containing greater than 23.5 percent oxygen must be shipped using the description ``Compressed gas, oxidizing, n.o.s., UN3156.''

79 This entry may not be used for mixtures that meet the definition for oxidizing gas. 81 Polychlorinated biphenyl items, as defined in 40 CFR 761.3, for which specification packagings

are impractical, may be packaged in non-specification packagings meeting the general packaging requirements of subparts A and B of part 173 of this subchapter. Alternatively, the item itself may be used as a packaging if it meets the general packaging requirements of subparts A and B of part 173 of this subchapter.

101 The name of the particular substance or article must be specified. 102 The ends of the detonating cord must be tied fast so that the explosive cannot escape. The

articles may be transported as in Division 1.4 Compatibility Group D (1.4D) if all of the conditions


specified in §173.63(a) of this subchapter are met. 103 Detonators which will not mass detonate and undergo only limited propagation in the shipping

package may be assigned to 1.4B classification code. Mass detonate means that more than 90 percent of the devices tested in a package explode practically simultaneously. Limited propagation means that if one detonator near the center of a shipping package is exploded, the aggregate weight of explosives, excluding ignition and delay charges, in this and all additional detonators in the outside packaging that explode may not exceed 25 grams.

105 The word "Agents" may be used instead of "Explosives" when approved by the Associate

Administrator for Hazardous Materials Safety. 106 The recognized name of the particular explosive may be specified in addition to the type. 107 The classification of the substance is expected to vary especially with the particle size and

packaging but the border lines have not been experimentally determined; appropriate classifications should be verified following the test procedures in §§173.57 and 173.58 of this subchapter.

108 Fireworks must be so constructed and packaged that loose pyrotechnic composition will not be

present in packages during transportation. 109 Rocket motors must be nonpropulsive in transportation unless approved in accordance with

§173.56 of this subchapter. A rocket motor to be considered ``nonpropulsive'' must be capable of unrestrained burning and must not appreciably move in any direction when ignited by any means.

110 Fire extinguishers transported under UN1044 and oxygen cylinders transported for emergency

use under UN1072 may include installed actuating cartridges (cartridges, power device of Division 1.4C or 1.4S), without changing the classification of Division 2.2, provided the aggregate quantity of deflagrating (propellant) explosives does not exceed 3.2 grams per cylinder. Oxygen cylinders with installed actuating cartridges as prepared for transportation must have an effective means of preventing inadvertent activation.

111 Explosive substances of Division 1.1 Compatibility Group A (1.1A) are forbidden for transportation

if dry or not desensitized, unless incorporated in a device. 113 The sample must be given a tentative approval by an agency or laboratory in accordance with

§173.56 of this subchapter. 114 Jet perforating guns, charged, oil well, without detonator may be reclassed to Division 1.4

Compatibility Group D (1.4D) if the following conditions are met: a. The total weight of the explosive contents of the shaped charges assembled in the guns does

not exceed 90.5 kg (200 pounds) per vehicle; and b. The guns are packaged in accordance with Packing Method US 1 as specified in §173.62 of

this subchapter. 115 Boosters with detonator, detonator assemblies and boosters with detonators in which the total

explosive charge per unit does not exceed 25 g, and which will not mass detonate and undergo only limited propagation in the shipping package may be assigned to 1.4B classification code. Mass detonate means more than 90 percent of the devices tested in a package explode practically simultaneously. Limited propagation means that if one booster near the center of the package is exploded, the aggregate weight of explosives, excluding ignition and delay charges, in this and all additional boosters in the outside packaging that explode may not exceed 25 g.

116 Fuzes, detonating may be classed in Division 1.4 if the fuzes do not contain more than 25 g of

explosive per fuze and are made and packaged so that they will not cause functioning of other fuzes, explosives or other explosive devices if one of the fuzes detonates in a shipping packaging

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