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tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions...

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WP4C Dew Point PotentiaMeter Operator’s Manual METER Group, Inc. Version: April 16, 2018 — 09:16:14
Transcript
Page 1: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

Dew

Point

PotentiaM

eter

Operator’sMan

ual

ME

TE

RG

rou

p,

Inc.

Ver

sion

:A

pri

l16

,20

18—

09:1

6:14

Page 2: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

ME

TE

RG

rou

p,

Inc.

2365N

EH

opkin

sC

ourt

Pu

llman

WA

99163

Ph

one:

509-332-5600F

ax:

509-332-5158W

ebsite:

ww

w.m

etergroup

.comE

mail:

sup

port.en

viron

men

t@m

etergrou

p.com

orsales.en

viron

men

t@m

etergroup

.com

Tra

dem

ark

sc©

2018M

ET

ER

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tsR

eserved

ii

Page 3: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

IND

EX

WP

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ver,

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terf

ace

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le,

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orP

ress

ure

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dar

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ong

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imes

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pla

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atio

n,

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ify

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up

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iii

Page 4: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

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iv

Page 5: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

Ind

ex

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lts.

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hop

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nd

this

man

ual

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ativ

ean

dh

elp

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ific

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e.

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rchase

dyo

ur

WP

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thro

ugh

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uto

r,ple

ase

con

tact

them

for

ass

ista

nce

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Em

ail:

sup

por

t.en

vir

onm

ent@

met

ergr

oup

.com

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les.

envir

onm

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met

ergr

oup

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one:

509-

332-

5600

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:50

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1

Page 6: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

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OF

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ITY

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Certifi

cate

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ceab

ility

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TE

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rou

p,

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2365N

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opkin

sC

ourt

Pu

llman

WA

99163U

SA

Tel:

509-332

-5600

Fax

:509

-332-5158

sup

port.en

viron

men

t@m

etergroup

.com

Th

isN

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atM

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ER

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man

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WP

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accordin

gto

temp

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stan-

dard

sw

ithca

libra

tiontraceab

leto

the

Nation

alIn

stitute

ofS

tan-

dard

san

dT

echn

ology(N

IST

).

51

1IN

TR

OD

UC

TIO

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P4C

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Ab

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his

Manu

al

Please

readth

esein

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that

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ism

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alin

clud

esin

struction

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setting

up

,calib

rating,

and

main

tain

ing

the

WP

4C.

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readth

esein

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sb

eforeop

erating

WP

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reth

at

the

instru

men

tp

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ual

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one-year

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ranty

onp

artsan

dlab

or.Y

our

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atica

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lidated

up

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tof

the

instru

men

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iab

ility

Seller

warran

tsn

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tof

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nm

anu

facture

again

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work

man

ship

and

materials

fora

perio

dof

one

year

fromth

ed

ateof

receipt

ofeq

uip

men

t.

Note:

We

do

not

con

sider

the

results

of

ord

inary

wea

ran

dtea

r,n

eglect,m

isuse,

or

accid

ent

as

defects.

Th

eS

eller’sliab

ilityfor

defective

parts

shall

inn

oeven

tex

ceedth

efu

rnish

ing

ofrep

lacemen

tp

arts“freigh

ton

board

”th

efactory

wh

ereorigin

allym

anu

factured

.M

aterialan

deq

uip

men

tcovered

hereb

yw

hich

isn

otm

anu

factured

by

Seller

shall

be

coveredon

lyby

the

warran

tyof

itsm

anu

facturer.

Seller

shall

not

be

liable

toB

uyer

for

loss,dam

ageor

inju

riesto

person

s(in

clud

ing

dea

th),

orto

pro

perty

or

thin

gsof

wh

atsoever

kin

d(in

clud

ing,

bu

tn

otw

ithou

tlim

itation

,loss

ofan

ticipated

profi

ts),occasion

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orarisin

gou

tof

the

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lation,

operation

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non

use,

repair,

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lacemen

tof

saidm

aterialan

deq

uip

men

t,or

out

ofth

euse

ofan

ym

ethod

orp

rocess

2

Page 7: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

15D

EC

LA

RA

TIO

NO

FC

ON

FO

RM

ITY

WP

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15

Decl

ara

tion

of

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form

ity

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pli

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65/E

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ard

sto

wh

ich

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form

ity

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2

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ufa

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TE

RG

roup

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cU

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Hop

kin

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man

,W

A991

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men

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oint

Pot

enti

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Mod

elN

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ber

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anu

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oint

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enti

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anu

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ure

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p,

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orat

ion

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edin

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llm

an,

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h-

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on,

US

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eets

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ceed

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est

and

ard

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rC

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mpli

ance

asp

erth

eC

oun

cil

Dir

ecti

ves

not

edab

ove.

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inst

rum

ents

are

bu

ilt

at

the

fact

ory

atM

ET

ER

and

per

tin

ent

test

ing

docu

men

tati

onis

free

lyav

aila

ble

for

veri

fica

tion

.

50

WP

4C

1IN

TR

OD

UC

TIO

N

for

whic

hth

esa

me

may

be

emp

loye

d.

Th

eu

seof

this

equ

ipm

ent

con

-st

itu

tes

Bu

yer’

sac

cep

tan

ceof

the

term

sse

tfo

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inth

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arra

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her

ear

eno

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der

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din

gs,

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any

kin

d,

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pli

ed,

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uto

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other

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ncl

ud

ing,

bu

tw

ith

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mit

atio

n,

the

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lied

war

ranti

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chan

tab

ilit

yan

dfi

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ra

part

icula

rp

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otex

pre

ssly

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fort

hh

erei

n.

3

Page 8: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

14A

PP

EN

DIX

B

14

Ap

pen

dix

B

Tem

pera

ture

Corre

ctio

nof

ME

TE

R’s

Verifi

catio

nS

tan

dard

s

Tab

le3:

Water

Activ

ityof

Selected

Salt

Solu

tions

Tem

p.

H2 O

0.5

02.3

36.0

08.5

713.4

117.1

8

( ◦C)

mol/

kg

mol/

kg

mol/

kg

mol/

kg

mol/

kg

mol/

kg

KC

LN

aC

LN

aC

LL

iCl

LiC

lL

iCl

15.0

1.0

00

0.9

84

0.9

23

0.7

61

0.4

92

0.2

38

0.1

40

20.0

1.0

00

0.9

84

0.9

22

0.7

60

0.4

96

0.2

45

0.1

45

25.0

1.0

00

0.9

84

0.9

20

0.7

60

0.5

00

0.2

50

0.1

50

30.0

1.0

00

0.9

84

0.9

20

0.7

60

0.5

04

0.2

55

0.1

55

35.0

1.0

00

0.9

84

0.9

20

0.7

60

0.5

08

0.2

61

0.1

60

40.0

1.0

00

0.9

84

0.9

21

0.7

60

0.5

12

0.2

66

0.1

65

50.0

1.0

00

0.9

84

0.8

94

0.7

40

0.5

17

0.2

75

0.1

72

49

2A

BO

UT

TH

EW

P4C

WP

4C

2A

bou

tth

eW

P4C

2.1

Sp

ecifi

catio

ns

Ran

ge :0

to−

300M

Pa1

Accu

racy

:±0.05

MP

a1

from0

to−

5M

Pa

1%from

−5

to−

300M

Pa

Measu

remen

tT

ime:

∼10

to15

min

utes

form

ostsoil

samp

lesin

precise

mod

e∼

20m

in.

forp

lant

tissue

samp

les<

5m

inutes

infast

mod

e(red

uced

accuracy

)

Tem

peratu

reC

ontrol :

15to

40◦C

(±0.2

◦C)

Op

erating

Environ

men

t:5

to40

◦C(41

to104

◦F)

Sen

sorT

yp

e:A

chilled

-mirror

dew

poin

tsen

soran

dan

Infrared

temp

erature

sensor

Sam

ple

Cu

pC

apacity

:7

mL

recomm

end

ed(15

mL

full)

Dim

ension

s:24.1

x22.9

x8.9

cm(9.5

x9.0

x3.5

in)

Weigh

t :3.2

Kg

(7.1lb

s)

Case

Material:

Pow

der

Pain

tedA

lum

inu

m

Disp

lay:

20x

2alp

han

um

ericL

CD

with

back

lightin

g

Data

Com

mu

nication

:R

S232A

comp

atible,

8-data

bit

AS

CII

cod

e,9600

bau

d,

no

parity,

1stop

bit

Pow

er:110

VA

Cto

220V

AC

,50/60

Hz

Interface

Cab

le:S

tand

ardR

S232

toU

SB

cable

(inclu

ded

)

Com

patib

leS

tand

ards :

AS

TM

D6836-07

Warran

ty:

On

eyear

parts

and

labor

1Th

eW

P4C

(an

dall

vap

or

pressu

rein

strum

ents)

are

limited

by

accu

racy

inth

ew

eten

dof

the

water

poten

tial

ran

ge.

Th

era

nge

of

0to

−5

MP

ah

as

an

accu

racy

of

0.0

5M

Pa.

For

exam

ple,

am

easu

remen

tat−

0.1

MP

ah

as

an

accu

racy

of±

50%

of

the

read

ing

an

d−

1M

Pa

has

an

accu

racy

of±

5%

of

the

read

ing.

Th

eW

P4C

will

not

mea

sure

water

poten

tial

accu

rately

nea

rfield

cap

acity.

4

Page 9: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

13A

PP

EN

DIX

AW

P4C

13

Ap

pen

dix

A

13.1

Pre

pari

ng

Salt

Solu

tion

s

Foll

owin

gis

ata

ble

show

ing

the

wat

erp

oten

tial

atgi

ven

con

centr

a-

tion

sof

NaC

lan

dK

Cl

at20

◦ C.

Tab

le2:

Wat

erP

oten

tial

ofN

aCl

and

KC

lin

Meg

apas

cals

(MP

a)

Con

centr

atio

n(M

oles

/kg)

NaC

lK

Cl

0.0

5−

0.23

2−

0.23

20.1

0−

0.45

4−

0.45

20.2

0−

0.90

1−

0.88

80.3

0−

1.34

9−

1.32

60.4

0−

1.79

3−

1.76

00.5

0−

2.24

2−

2.19

00.6

0−

2.69

9−

2.62

20.7

0−

3.15

9−

3.06

10.8

0−

3.61

8−

3.50

10.9

0−

4.08

7−

3.93

11.0

0−

4.55

8−

4.37

2

48

WP

4C

2A

BO

UT

TH

EW

P4C

2.2

WP

4C

an

dW

ate

rP

ote

nti

al

Wat

erp

oten

tial

isa

mea

sure

men

tof

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ener

gyst

atu

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wate

rin

asy

stem

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ind

icat

esh

owti

ghtl

yw

ater

isb

oun

d,

stru

ctu

rally

orch

emic

ally

,w

ith

ina

sub

stan

ce.

Wat

erp

oten

tial

can

be

com

pu

ted

from

the

vap

orp

ress

ure

ofai

rin

equ

ilib

rium

wit

ha

sam

ple

ina

seal

edm

easu

rem

ent

cham

ber

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ora

mor

ed

etai

led

des

crip

tion

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ater

pot

enti

al,

ple

ase

refe

rto

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apte

r9,

titl

ed“T

heo

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ism

anu

al.

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WP

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work

s

Th

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dm

irro

rd

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oint

tech

niq

ue

tom

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reth

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ater

pot

enti

al

ofa

sam

ple

.In

this

typ

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inst

rum

ent,

the

sam

ple

iseq

uil

ibra

ted

wit

hth

eh

ead

spac

eof

ase

aled

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ber

that

conta

ins

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ran

da

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ns

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nden

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onon

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mir

-ro

r.A

teq

uil

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um

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ater

pot

enti

alof

the

air

inth

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the

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eas

the

wat

erp

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mp

le.

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ir-

ror

tem

per

atu

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olle

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elti

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er.

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hot

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lld

etec

tsth

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act

poi

nt

at

wh

ich

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den

-sa

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pea

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ror.

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ects

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ep

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od

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ctor

sen

ses

the

chan

gein

refl

ecta

nce

wh

enco

nd

ensa

tion

occ

urs

onth

em

irro

r.A

ther

moco

up

leat

tach

edto

the

mir

ror

then

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rds

the

tem

per

atu

reat

wh

ich

con

den

sati

onocc

urs

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alu

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egin

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ed

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icat

ing

that

init

ial

mea

sure

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tsar

eb

ein

gta

ken

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then

sign

als

you

by

flas

hin

ga

gree

nL

ED

and

/or

bee

pin

gw

hen

itre

ach

esth

efi

nal

valu

es.

Th

ein

stru

men

tw

ill

dis

pla

yth

efi

nal

wat

erp

oten

tial

and

tem

per

atu

reof

the

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ple

.

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dit

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ete

chn

iqu

ed

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P4C

use

san

inte

r-n

alfa

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atci

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mp

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erto

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eto

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easu

rin

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oth

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nt

and

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ple

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ace

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per

atu

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ult

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ym

easu

red

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lete

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mal

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m.

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the

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ple

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atu

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rnal

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mo-

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esa

mp

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lock

tem

per

atu

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cord

ing

toh

owit

isse

t.

5

Page 10: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

12F

UR

TH

ER

RE

AD

ING

•C

lassifi

catio

nof

Expa

nsive

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usin

gth

eW

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the

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u.

6

Page 11: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

12F

UR

TH

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AD

ING

WP

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12

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pb

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.,G

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pp.

1-22

.

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pli

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on

troll

ing

Wate

rA

ctiv

ity.

46

WP

4C

3G

ET

TIN

GS

TA

RT

ED

3G

ett

ing

Sta

rted

3.1

Com

pon

ents

of

you

rW

P4C

You

rW

P4C

shou

ldh

ave

ship

ped

wit

hth

efo

llow

ing

item

s.

•W

P4C

Mai

nU

nit

•Q

uic

kst

art

Gu

ide

•C

erti

fica

teof

Cal

ibra

tion

•P

ower

Cor

d•

RS

-232

toU

SB

Cab

le•

25P

last

icS

amp

leC

up

san

dL

ids

•10

Sta

inle

ssS

teel

Sam

ple

Cu

ps

•O

per

ator

’sM

anu

al•

12V

ials

of0.

50m

ol/k

gK

Cl

•C

lean

ing

Kit

3.2

Ch

oosi

ng

aL

oca

tion

To

ensu

reth

atyo

ur

WP

4Cop

erat

esco

rrec

tly

and

con

sist

entl

y,p

lace

iton

ale

vel

surf

ace.

Th

isre

du

ces

the

chan

ceth

at

sam

ple

mate

rial

wil

lsp

ill

and

conta

min

ate

the

insi

de

ofth

ein

stru

men

t.T

op

rote

ctth

ein

tern

alel

ectr

ical

com

pon

ents

,an

dto

avoi

din

accu

rate

read

ings

,p

lace

you

rW

P4C

ina

loca

tion

wh

ere

the

tem

per

atu

rere

mai

ns

fair

lyst

able

.T

his

loca

tion

shou

ldb

ew

ell

away

from

air

con

dit

ion

eran

dh

eate

rve

nts

,op

enw

ind

ows,

outs

ide

door

s,re

frig

erat

or

exh

aust

s,or

oth

erit

ems

that

may

cau

sera

pid

tem

per

atu

refl

uct

uat

ion

.

7

Page 12: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

11T

RO

UB

LE

SH

OO

TIN

G

Th

eP

erforman

ceE

valuation

screengives

youfou

rvalu

es.T

he

top

leftvalu

eis

the

value

the

therm

ocou

ple

isread

ing.

Itis

basica

llyth

ed

ifferen

cein

temp

erature

betw

eenth

eb

lock

and

the

mirror.

Ifth

isis

zero,th

ereis

someth

ing

wron

gw

ithth

eth

ermocou

ple.

Th

etop

right

valu

eis

the

value

readby

the

therm

opile,

wh

ichis

the

temp

er-atu

red

ifferen

ceb

etween

the

blo

ckan

dw

hat

it“sees”

below

it(th

esam

ple,

wh

enrea

din

g).T

his

value

isvariab

le,b

ut

shou

ldn

everb

ezero.

Th

eb

ottomleft

value

isth

eb

lock

temp

erature.

This

valu

esh

ould

be

aroun

dam

bien

ttem

peratu

re.

Th

eb

ottomrig

ht

value

isth

em

irrorrefl

ectance

voltage,in

un

itsof

volts.T

his

value

shou

ldn

ormally

be

aroun

d0.5

orab

ove,b

ut

ifit

drop

sb

elow0.3,

there

issom

ethin

gw

rong.

You

cann

otch

ange

anyth

ing

inth

isscreen

,b

ut

itw

illin

dicate

com-

pon

ent

perfo

rman

ce.If

youn

oticeth

atan

yof

these

values

are

not

wh

atth

eysh

ould

be,

contact

ME

TE

RS

up

port

forfu

rther

instru

c-tion

.P

ressth

eb

utton

nex

tto

Exit

toget

back

toth

em

ainm

enu

.

45

3G

ET

TIN

GS

TA

RT

ED

WP

4C

3.3

Featu

res

Figu

re1:

Fron

tV

iewof

WP

4C

Figu

re2:

Back

View

ofW

P4C

3.4

Pre

parin

gth

eW

P4C

for

Op

era

tion

After

fin

din

ga

good

location

foryou

rW

P4C

,p

lug

the

pow

ercord

into

the

back

of

the

un

it.B

eforetu

rnin

git

on,

pu

llop

enth

esa

mp

led

rawer

(turn

the

kn

obto

the

OP

EN

/LO

AD

position

).Y

ouu

sually

place

anem

pty

disp

osable

samp

lecu

pu

psid

e-dow

nin

the

draw

erto

8

Page 13: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

11T

RO

UB

LE

SH

OO

TIN

GW

P4C

Ifth

eb

lock

isp

rop

erly

plu

gged

into

the

mot

her

board

an

dth

ism

essa

geap

pea

rs,

itis

like

lyth

aton

eor

more

ofth

eco

mp

o-

nen

tshav

efa

iled

onth

eb

lock

circ

uit

boa

rd.

7.

PR

OB

LE

M:

Th

e“S

etT

”op

tion

does

not

app

ear

anym

ore

inth

eW

P4C

Syst

emC

onfi

gura

tion

men

u.

SO

LU

TIO

N:

Th

ete

mp

erat

ure

contr

olm

od

ule

insi

de

the

WP

4Cis

bro

ken

orn

ot

fun

ctio

nin

gco

rrec

tly.

Wh

enth

ein

stru

men

tse

nse

sth

at

ther

eis

ap

rob

lem

wit

hth

ete

mp

erat

ure

contr

olm

od

ule

,it

rem

oves

that

fun

c-ti

onas

anop

tion

toth

eu

ser

asa

pre

cau

tion

.C

onta

ctM

ET

ER

for

serv

ice

info

rmat

ion

.

11.2

Sen

sor

Perf

orm

an

ceS

creen

If,

afte

rcl

ean

ing

you

rin

stru

men

tan

dre

vie

win

gth

etr

oub

lesh

oot

ing

item

s,you

hav

ere

ason

tob

elie

veth

aton

eof

the

com

pon

ents

ofyo

ur

WP

4Cm

ayb

eca

usi

ng

mea

sure

men

ter

ror,

you

can

acce

ssa

scre

enth

atw

ill

dis

pla

yva

lues

for

com

pon

ent

per

form

ance

.A

cces

sth

issc

reen

by

hol

din

gd

own

the

low

erri

ght

bu

tton

wh

ile

turn

ing

onth

ein

stru

men

t.A

fter

itin

itia

lize

s,it

wil

lb

eep

an

dco

me

toth

eP

erfo

rman

ceE

valu

atio

nsc

reen

.

44

WP

4C

3G

ET

TIN

GS

TA

RT

ED

pro

tect

itd

uri

ng

ship

men

t.R

emov

eth

issa

mple

cup

and

turn

the

inst

rum

ent

on.

Th

eO

N/O

FF

swit

chis

loca

ted

onth

elo

wer

righ

tco

rner

ofth

eW

P4C

bac

kp

anel

.T

he

mod

elan

dth

enth

em

ain

men

uw

ill

app

ear

onth

eL

CD

.

Th

en:

Th

isis

the

Mai

nm

enu

,d

isp

layin

gth

ew

ater

pote

nti

alin

bot

hM

ega-

Pas

cals

(MP

a)an

dp

F,an

dth

esa

mp

lete

mp

erat

ure

in◦ C

.In

ord

erto

pro

vid

eth

em

ost

accu

rate

read

ings

,W

P4C

shou

ldid

eall

yb

eall

owed

aw

arm

-up

per

iod

of15

to30

min

ute

saf

ter

turn

ing

iton

.W

hen

you

inse

rta

sam

ple

into

the

cham

ber

dra

wer

and

turn

the

dra

wer

kn

obto

the

RE

AD

pos

itio

n,

the

inst

rum

ent

wil

lb

egin

the

read

cycl

eto

mea

sure

the

wat

erp

oten

tial

ofyo

ur

sam

ple

.

3.5

Port

ab

ilit

y

On

occ

asio

nyo

um

ayw

ant

tota

kew

ater

pot

enti

alm

easu

rem

ents

inth

efi

eld

wher

eit

isn

otfe

asib

leto

take

sam

ple

san

dre

turn

toth

ela

b.

Th

efo

llow

ing

isa

pro

ced

ure

for

pow

erin

gyo

ur

WP

4Cu

sin

gyo

ur

veh

icle

asa

pow

erso

urc

eat

site

sw

her

eA

Cp

ower

isn

otre

adil

yav

aila

ble

.

1.P

urc

has

ea

por

tab

lep

ower

inve

rter

that

plu

gsin

toth

e12

Vou

tpu

t(c

igar

ette

ligh

ter)

ofyo

ur

veh

icle

.T

he

inver

ter

shou

ldh

ave

aco

nti

nu

ous

outp

ut

ofat

leas

t14

0W

atts

.

9

Page 14: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

11T

RO

UB

LE

SH

OO

TIN

G

5.

PR

OB

LE

M:

Asm

alltrian

gleap

pears

inth

eu

pp

errigh

tcorn

erafter

readin

g:

SO

LU

TIO

N:

Th

em

irrorn

eeds

tob

eclean

ed,

along

with

the

restof

the

sam

ple

cham

ber,

until

itd

isapp

ears.T

his

triangle

isa

mirror

perform

an

cein

dicator.

Wh

enth

eW

P4C

senses

that

the

mirro

rp

erform

ance

has

drop

ped

toun

acceptab

lelevels,

itw

illd

isplay

the

triangu

lar

warn

ing

signafter

measu

ring

the

samp

le.W

hen

this

app

ears,you

shou

ldstop

samp

ling

and

cleanth

ech

amb

er.If

the

triangle

isstill

onth

escreen

afterclean

ing,

the

mirror

ism

ostlikely

stilld

irtyan

dyo

uw

illn

eedto

cleanit

until

the

triangle

disap

pears.

6.

PR

OB

LE

M:

“Blo

ckfailu

re”m

essageap

pears

onscreen

.

SO

LU

TIO

N:

•T

he

blo

ckis

not

plu

ggedin

toth

em

otherb

oard.

Op

enth

ecase

and

check

tom

ake

sure

that

the

small

ribb

on

cable

that

conn

ectsth

eb

lock

toth

em

otherb

oardis

snap

ped

an

dlo

cked

inp

lace.

•O

ne

orm

orecom

pon

ents

has

failedon

the

blo

ckcircu

itb

oard.

43

3G

ET

TIN

GS

TA

RT

ED

WP

4C

2.P

laceth

eW

P4C

ona

levelsu

rface.C

aresh

ould

be

taken

tom

inim

izetem

peratu

regrad

ients

that

may

affect

the

instru

men

tw

hile

inth

efi

eld.

AS

tyrofoam

box

,for

exam

ple,

will

help

min

imize

temp

erature

effects.

3.P

lug

the

12-voltin

verterto

the

12-volt

outp

ut

ofth

eveh

icle,or

directly

toth

eb

atteryitself.

4.P

lug

the

WP

4Cto

the

inverter,

and

turn

iton

.W

hen

the

instru

men

tis

on,

itd

raws

up

to1

amp.

Ch

eckth

eratin

gof

your

battery

ifyou

wan

tto

kn

owh

owlon

git

will

pow

erth

ein

strum

ent

(forex

amp

le,if

your

battery

israted

for60

am

ph

ours,

itw

illw

orkfor

60h

ours

wh

enth

eveh

icleis

not

run

nin

g.

5.A

llowth

ein

strum

ent

tow

armu

pfor

15to

30

min

utes

asyou

wou

ldin

the

lab.

Ch

eckth

ecalib

rationof

the

instru

men

tb

efore

pro

ceedin

gw

ithread

ing.

10

Page 15: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

11T

RO

UB

LE

SH

OO

TIN

GW

P4C

fan

bla

de.

Th

isis

esp

ecia

lly

like

lyif

you

hav

eju

stcl

ean

edth

ech

amb

er.

Ifyo

usu

spec

tth

ism

ayh

ave

hap

pen

ed,

conta

ctM

ET

ER

for

det

ails

onre

pla

cem

ent.

3.

PR

OB

LE

M:

Wat

erp

oten

tial

read

ings

onK

Cl

stan

dar

ds

are

too

hig

hor

low

and

aca

lib

rati

onad

just

men

tca

nn

otb

em

ade

any

hig

her

orlo

wer

.

SO

LU

TIO

NS

:

•T

he

ther

mop

ile

inyo

ur

cham

ber

,w

hic

hm

easu

res

sam

ple

tem

-p

erat

ure

,m

ayh

ave

bec

ome

conta

min

ated

.R

efer

toC

hap

ter

10fo

rd

irec

tion

son

clea

nin

g.

•If

you

are

not

usi

ng

ME

TE

R’s

KC

lve

rifi

cati

on

stan

dar

ds,

hig

hre

adin

gsm

ayin

dic

ate

that

the

salt

solu

tion

you

are

usi

ng

isn

otin

equ

ilib

riu

m.

4.

PR

OB

LE

M:

Mes

sage

onsc

reen

dis

pla

ys

the

foll

owin

g(ex

amp

le):

SO

LU

TIO

N:

•T

he

sam

ple

isto

od

ryfo

rth

ein

stru

men

tto

read

acc

ura

tely

.If

you

rsa

mp

leh

asa

wat

erp

oten

tial

that

isab

ove

the

det

ecti

on

lim

its

ofth

ein

stru

men

t,th

ism

essa

gew

illco

me

up

.E

ssen

tial

ly,

itm

ean

sth

atth

ere

isn

oten

ough

sam

ple

moi

stu

reto

con

den

seon

the

mir

ror

and

pro

vid

ea

read

ing.

•T

he

mir

ror

may

be

dir

ty.

Try

clea

nin

gth

em

irro

ran

dch

amb

eran

dm

easu

rin

gth

esa

mp

leag

ain

.

42

WP

4C

4T

HE

ME

NU

S

4T

he

Menu

s

4.1

Th

eM

ain

Menu

Eve

ryti

me

you

turn

onyo

ur

WP

4C,

itw

ill

open

toth

issc

reen

.If

this

scre

endoes

not

app

ear,

refe

rto

Ch

apte

r12

for

trou

ble

shoot

ing

inst

ruct

ion

s.T

he

wat

erp

oten

tial

and

sam

ple

tem

per

atu

red

ispla

ys

onth

esc

reen

.O

nea

chsi

de

ofth

eL

CD

ther

ear

eb

utt

ons.

Eac

hb

utt

onp

erfo

rms

ad

iffer

ent

fun

ctio

nd

epen

din

gon

whic

hm

od

eyo

uw

ant.

Fig

ure

3p

rovid

esa

des

crip

tion

ofth

em

od

esan

dop

tion

syou

may

use

and

the

bu

tton

sth

atse

tth

em.

Fig

ure

3:M

ain

Men

uS

cree

n

4.1

.1C

han

gin

gL

an

gu

ages

Th

eW

P4C

com

esto

you

wit

hE

ngl

ish

asth

ed

efau

lton

-scr

een

use

rla

ngu

age

.If

you

pre

fer

not

tou

seE

ngl

ish

,yo

uca

nch

ange

itto

one

ofa

vari

ety

ofot

her

lan

guag

es:

Ger

man

,F

ren

ch,

Sp

anis

h,

Ital

ian

,S

wed

ish

,D

anis

h,

Nor

weg

ian

,C

zech

,P

ortu

gues

e,Jap

anes

e,P

olis

hor

11

Page 16: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

11T

RO

UB

LE

SH

OO

TIN

G

•C

heck

tom

akesu

reyou

rp

ower

cordis

securely

attached

toth

eb

ackof

the

instru

men

tan

dth

ep

ower

outlet.

•A

pow

ersu

rem

ayh

avecau

seda

fuse

tob

low.

Follow

steps

1th

rough

5to

chan

geth

efu

ses.

1.U

np

lug

the

pow

ercord

fromth

ew

allan

dth

ein

strum

ent.

2.L

ocate

the

pan

elw

here

the

pow

ercord

plu

gsin

.T

he

fuse

box

ison

the

right

side

ofth

atp

anel.

Press

inon

the

releasetab

and

pu

llth

efu

se-hold

erou

t.

3.P

ull

the

broken

fuse(s)

out

and

replace

with

a2.0

Am

p250

Vfu

se.C

aution

:D

on

otuse

any

other

kin

dof

fuse

oryou

will

riskd

amage

toyou

rin

strum

ent

and

voidyou

rw

arran

ty.

4.R

epla

ceth

efu

se-hold

eran

dp

ush

itin

toth

efu

se-well

until

the

releasetab

snap

sin

top

lace.

5.R

econn

ectth

ep

ower

cordan

dtu

rnyou

rin

strum

ent

on.

Ifth

efu

seb

lows

again,

afailed

comp

onen

tm

ayb

ecau

s-in

gth

ep

roblem

.C

ontact

ME

TE

Rto

make

arrangem

ents

for

repairs

ifyou

rp

roblem

persists.

2.

PR

OB

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Read

ings

areslow

orin

consisten

t.

SO

LU

TIO

N:

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he

samp

lech

amb

erm

ayb

ed

irty.R

eferto

Ch

apter

10of

the

manu

al

ford

irections

onclean

ing

the

samp

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amb

er.

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ome

samp

lesab

sorbor

desorb

moistu

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slowly,

cau

sing

measu

remen

tsto

takelon

gerth

anu

sual,

and

noth

ing

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one

tosp

eedu

pth

ep

rocess.

Refer

toC

hap

ter6

forfu

rther

exp

lanation

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•T

he

fan

blad

ein

side

the

blo

ckch

amb

erm

ayb

eb

roken.

Ifeven

the

KC

lstan

dard

takesa

long

time

toread

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dth

esam

ple

cham

ber

isclean

,you

may

hav

ea

broken

orb

ent

cham

ber

41

4T

HE

ME

NU

SW

P4C

Fin

nish

.C

han

gelan

guages

by

pressin

gth

eu

pp

errig

ht

bu

tton

of

the

instru

men

tw

hile

itis

not

readin

ga

samp

le.Y

ou

will

seeth

eL

angu

agescreen

with

defau

ltE

nglish

.

Press

the

up

per

right

keyagain

,an

dth

en

ext

langu

ageop

tion

(Ger-

man

)w

illap

pear.

Each

time

youp

ressth

erigh

tb

utton

,th

ed

isplay

will

scroll

toth

en

ext

langu

ageop

tion.

Select

the

langu

ageyou

prefer

and

press

the

lower

leftb

utton

toex

it.

4.1

.2R

ead

ing

Mod

es

Pre

cise

Mod

e

Wh

enyou

first

turn

onth

eW

P4C

,it

will

be

inp

recisem

od

e.T

he

WP

4Crep

eatssam

ple

measu

remen

tsu

ntil

successive

readin

gs

agree

with

ina

preset

tolerance

(0.03M

Pa

forΨ>

−40

MP

a;oth

erwise

0.3M

Pa).

Th

eW

P4C

alway

sstarts

inp

recisem

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e.T

otog

gleb

etween

the

precise,

contin

uou

san

dfast

mod

es,p

ressth

etop

leftb

utton

.T

he

disp

layw

illsh

owa

small

p,

cor

fto

the

leftof

the

water

poten

tialread

ings.(F

igure

4)

12

Page 17: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

11T

RO

UB

LE

SH

OO

TIN

GW

P4C

11

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ub

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ooti

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WP

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ah

igh

per

form

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inst

rum

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des

ign

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hav

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wm

ain

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nan

cean

dfe

wp

rob

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sif

use

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ith

care

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nfo

rtu

nate

ly,

som

e-ti

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even

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bes

top

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ors

usi

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bes

tin

stru

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cou

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chn

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Her

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som

ep

rob

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sth

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Ifyo

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ave

enco

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ap

rob

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that

isn

otad

dre

ssed

her

e,or

ifth

ese

rem

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lve

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rp

rob

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thos

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oma

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trib

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an

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efo

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ab

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pyo

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crip

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and

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toad

just

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angl

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up

per

righ

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m#

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lock

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lure

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pea

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scre

enaf

ter

turn

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m#

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ger

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on-

figu

rati

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enu

Pro

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m#

7

1.

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OB

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MW

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not

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on.

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LU

TIO

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:

40

WP

4C

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ME

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Fig

ure

4:M

ain

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uw

ith

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tinu

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sure

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pre

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tial

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eati

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mea

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men

tson

asa

mp

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Typ

ical

read

tim

esar

ew

ith

in10

to15

min

ute

s.T

he

gree

nL

ED

bli

nks

unti

lyou

turn

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dra

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kn

owto

the

OP

EN

/LO

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itio

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Conti

nu

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od

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tinu

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easu

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tial

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orin

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lon

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por

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ilib

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chas

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nt

sam

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dm

oist

soil

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ith

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-p

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and

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per

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pan

ied

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the

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ome

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WP

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ein

conti

nu

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erto

log

and

stor

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tim

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orin

stru

ctio

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hap

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8.

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stm

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esa

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mm

end

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rd

ryso

ilsa

mp

les

wit

hw

ater

pote

nti

al<

−40

MP

a. 13

Page 18: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

10R

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AIR

INS

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TIO

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on

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with

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men

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4.P

leaserev

iewth

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dverify

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ship

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illto

info

rmation

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tactnam

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descrip

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Ifan

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incorrect,

please

contact

aM

ET

ER

represen

tative.

5.T

ape

the

box

inb

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irections

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will

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brea

kop

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ship

men

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6.In

clud

eth

eR

MA

nu

mb

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the

attention

line

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label.

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ipto

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up

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c.A

TT

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RM

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sertyou

rR

MA

#)

2365N

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opkin

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Pu

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A99163

10.2

Rep

air

Costs

Man

ufactu

rersd

efectsan

din

strum

ents

with

inth

eon

e-yearw

arranty

will

be

repaired

atn

ocost.

For

non

-warran

tyrep

airs(in

clud

ing

cleanin

gsfor

instru

men

tsin

their

warran

typ

eriod

),costs

forp

arts,

labor,

and

ship

pin

gw

illb

eb

illedto

you.

We

have

am

inim

um

repair

charg

e,an

dan

extra

feew

illb

ech

argedfor

rush

work

.M

ET

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will

prov

ide

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atedrep

aircost,

ifreq

uested

.

10.3

Loan

er

Serv

ice

ME

TE

Rh

asloan

erin

strum

ents

tokeep

youm

easurin

gw

ateractiv

ityw

hile

you

rin

strum

ent

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eing

serviced

.If

your

WP

4Cis

stillu

nd

ercalib

rationw

arranty

oryou

have

aserv

iceplan

with

you

rin

strum

ent,

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isn

och

argefor

the

loaner

service.

39

4T

HE

ME

NU

SW

P4C

4.2

Syste

mC

on

figu

ratio

n

Ifyou

press

the

bottom

leftb

utton

wh

ilein

the

Main

men

u,

itw

illb

ring

youto

the

System

Con

figu

rationm

enu

.T

his

men

uallow

syou

tom

ake

min

orsy

stemch

anges.(F

igure

5an

d6)

Figu

re5:

Main

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uB

utton

s

You

canch

ange

how

the

beep

ersign

alsafter

eachread

ing

and

enter

the

calibration

men

uas

well.

Figu

re6:

System

Con

figu

rationM

enu

Ch

an

gin

gth

eB

eep

er

Wh

enyou

areread

ing,

the

WP

4Ch

astw

ow

ays

ofn

otifyin

gyo

uw

hen

itcom

pletes

the

water

poten

tialread

ing

foryou

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mp

le.It

will

notify

you

with

the

beep

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eb

eeper

and

afl

ashin

ggreen

LE

D,

14

Page 19: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

10R

EP

AIR

INS

TR

UC

TIO

NS

WP

4C

10

Rep

air

Inst

ruct

ion

s

Ifyo

ur

WP

4Cev

ern

eed

sto

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sent

info

rse

rvic

eor

rep

air,

call

ME

-T

ER

at50

9-33

2-56

00or

fax

us

at50

9-33

2-51

58.

We

wil

las

kyo

ufo

ryo

ur

add

ress

,p

hon

enu

mb

er,

and

seri

alnu

mb

er.

For

non

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ranty

rep

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,w

ew

ill

also

ask

for

apay

men

tm

eth

od

(su

chas

ap

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eor

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orcr

edit

card

nu

mb

er),

are

pai

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ud

get,

and

bil

lin

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dre

ss.

Note

:If

you

pu

rchase

dyo

ur

WP

4C

from

on

eof

ou

rin

tern

ati

on

al

dis

trib

uto

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ple

ase

con

tact

them

befo

reco

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hey

may

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eto

pro

vide

you

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hlo

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serv

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an

dhel

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med

yth

epro

blem

.

10.1

Sh

ipp

ing

Dir

ect

ion

s

Wh

enyo

ush

ipyo

ur

inst

rum

ent

bac

kto

us,

ple

ase

incl

ude

wit

hit

ad

ocu

men

tw

ith

the

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ple

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am

ean

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epart

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the

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rum

ent,

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(mos

tim

por

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y)

ad

escr

ipti

onof

the

pro

ble

m.

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isin

form

atio

nw

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ter

hel

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rte

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ns

and

our

ship

pin

gd

epar

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ent

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uin

good

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pa-

nie

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ith

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ater

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izat

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form

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tive

toob

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Foll

owst

eps

1th

rou

gh6

tosu

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sfu

lly

and

safe

lysh

ipyo

ur

in-

stru

men

tbac

kto

us.

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pos

sib

le,

ship

you

rW

P4C

bac

kin

its

orig

inal

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oxw

ith

foam

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Ifth

isis

not

pos

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le,

use

ab

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ath

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least

four

inch

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spac

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etw

een

you

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men

tan

dea

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all

ofth

eb

ox.

Ifyo

uar

en

otu

sin

gth

efo

amin

sert

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ack

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box

moder

atel

yti

ght

wit

hp

ackin

gm

ater

ial,

like

styro

foam

pea

nu

ts

2.P

ut

you

rin

stru

men

tin

ap

last

icb

agto

avoi

dd

isfi

gu

rin

gm

arks

from

the

pac

kagi

ng.

38

WP

4C

4T

HE

ME

NU

S

loca

ted

on

the

left

fron

tco

rner

ofth

eW

P4C

case

.In

fast

and

pre

-ci

sere

adin

gm

od

es,th

eL

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wil

lfl

ash

once

wh

ena

sam

ple

isst

arte

d.

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enit

isfi

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hed

the

LE

Dw

ill

flas

hco

nti

nu

ousl

yu

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lth

ekn

obis

mov

edto

the

OP

EN

/LO

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pos

itio

n(i

fn

otop

erat

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inco

nti

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mod

e).

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can

not

turn

offor

chan

geth

eL

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flash

ing

fun

ctio

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ree

diff

eren

tic

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rep

rese

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thre

eb

eep

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s.(F

igu

re7)

Fig

ure

7:D

efin

itio

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Bee

per

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s

you

can

turn

the

bee

per

offco

mp

lete

ly,

set

itto

bee

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omen

tari

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ou

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)w

hen

the

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pos

itio

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uh

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the

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tit

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the

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You

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15

Page 20: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

9C

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AN

ING

AN

DM

AIN

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9.3

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eck

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After

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calibratio

nch

ange

that

may

have

occu

rredd

urin

gclean

ing

pro

cedu

res.

Ch

eckth

ecalib

rationof

your

instru

men

tby

mea

surin

gth

ew

aterp

otential

ofth

eK

Cl

stand

ard.

Ifa

chan

geh

asoccu

rred,

referto

chap

ter5

ford

irections

onh

owto

recalibrate.

If,after

adju

sting

calibration

your

instru

men

tis

stilln

otread

ing

samp

lesco

rrectly,con

tactM

ET

ER

fortech

nical

sup

port.

37

4T

HE

ME

NU

SW

P4C

Th

eW

P4C

givesyou

the

ability

tom

anu

allyset

your

instru

men

tsam

ple

cham

ber

temp

erature.

To

setyou

rin

strum

ent

samp

lech

am-

ber

temp

erature,

press

the

lower

right

bu

ttonn

ext

toth

e“set

T”

inth

eS

ystem

Con

gu

rationm

enu

.T

he

followin

gscreen

will

app

ear:

Ad

justin

gth

eS

etp

oin

tT

em

pera

ture

Use

the

bu

ttons

nex

tto

+an

d−

toad

just

the

target

setpoin

ttem

-p

erature

(disp

layedin

the

lower

right

corner).

Ifyou

press

either

bu

ttonit

adju

stsin

increm

ents

of0.1

◦C.

Note:

Hold

ing

dow

nth

ebu

tton

will

rapid

lyin

cremen

tth

eva

lue.

Th

etarget

setpoin

ttem

peratu

rerou

ghly

correspon

ds

toth

etem

-p

erature

atw

hich

youw

ishth

esam

ple

toread

.A

dju

stth

esetp

oint

toth

etem

peratu

reth

atyou

wan

t,th

enb

eginm

easurem

ents

tosee

how

closeyou

rW

P4C

comes

toyou

rd

esiredtem

peratu

re(th

isw

ork

sb

estby

pu

tting

the

WP

4Cin

contin

uou

sm

od

e).A

ftersevera

lsa

m-

ples,

itsh

ould

show

consisten

ttem

peratu

reread

ings.

At

this

poin

t,m

akean

yn

eeded

adju

stmen

tto

the

setpoin

tin

dex

nu

mb

erto

reachyou

rd

esiredtem

peratu

re.Y

ouw

illb

eab

leto

adju

stth

ein

dex

nu

m-

ber

betw

een15

and

40◦C

.If

youp

ressth

e−b

utton

afteryou

reach15

◦C,

itw

illd

isable

the

temp

erature

control

fun

ctionu

ntil

youraise

the

ind

exnu

mb

eragain

.W

hen

the

temp

erature

contro

lis

disa

bled

the

disp

layw

illsh

ow‘off

’in

place

ofth

etem

peratu

resettin

g.

Imp

orta

nt

tips

with

the

WP

4C

•B

eforeread

ing,

wait

forap

prox

imately

30m

inu

testo

letth

ech

amb

ertem

peratu

restab

ilizeafter

turn

ing

iton

.

16

Page 21: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

9C

LE

AN

ING

AN

DM

AIN

TE

NA

NC

EW

P4C

Cle

an

itin

the

sam

em

ann

eras

des

crib

edab

ove

for

the

mir

ror.

4.C

lean

ing

the

Th

erm

opil

e

(a)

Wra

pa

new

Kim

wip

ear

oun

dth

een

dof

the

thin

pla

s-ti

cro

d(s

pat

ula

)an

dm

oist

enit

wit

his

opro

pyl

alc

ohol

orcl

ean

ing

solu

tion

.

(b)

WA

SH

–Sw

ipe

the

moi

sten

edK

imw

ipe

acro

ssth

erm

op

ile.

(Asi

ngl

esw

ipe

isu

sual

lysu

ffici

ent

tore

mov

eco

nta

mi-

nan

ts.)

(c)

RIN

SE

–Rep

eat

step

sa-

bu

sing

new

Kim

wip

esm

ois

ten

edw

ith

dei

oniz

edw

ater

inst

ead

ofcl

ean

ing

solu

tion

.

(d)

DR

Y–R

epea

tst

eps

a-b

bu

tu

sea

new

,d

ryK

imw

ipe

toh

elp

rem

ove

any

moi

stu

rere

mai

nin

gfr

omth

ecl

ean

ing.

(e)

Vis

uall

yin

spec

tth

eth

erm

opil

efo

rcl

ean

lin

ess.

Th

isse

n-

sor

must

be

free

ofal

ld

irt

and

lint.

Re-

clea

nif

nec

essa

ry.

5.In

sid

eC

ase

(a)

Cle

anth

esa

mple

dra

wer

and

dra

wer

base

asd

escr

ibed

abov

efo

rth

eth

erm

opil

e.R

emov

ean

yd

ebri

sth

at

may

hav

eco

llec

ted

insi

de

the

case

.

(b)

Ch

eck

once

mor

eto

mak

esu

reth

ere

isn

oco

nta

min

ati

onof

the

sam

ple

cham

ber

cavit

y.

(c)

Rep

lace

the

blo

ck,

and

inse

rtth

eri

bb

onca

ble

sock

etin

toto

the

20-p

inp

lug

onth

eb

lock

.L

ock

itin

pla

cew

ith

the

lock

ing

leve

rs.

(d)

Scr

ewth

eth

um

b-s

crew

son

the

blo

ckb

ack

inu

nti

lth

eyar

eh

and

-tig

ht.

(e)

Rep

lace

the

case

lid

and

secu

reth

eli

dsc

rew

.

6.C

onn

ect

the

WP

4Cp

ower

cord

.

36

WP

4C

4T

HE

ME

NU

S

•C

ool

sam

ple

sto

ate

mp

erat

ure

slig

htl

yb

elow

cham

ber

tem

per

-at

ure

bef

ore

star

tin

ga

read

ing.

•F

orsl

oweq

uil

ibra

tion

sam

ple

s,su

chas

pla

nt

and

moi

stso

ilsa

mp

les

(>−

0.5

MP

a),

pre

cise

read

ing

mod

em

ayyie

ldsm

all

erro

rs.

For

thes

ety

pes

ofsa

mple

s,W

ere

com

men

dyo

uu

seco

nti

nu

ous

mod

ean

dlo

gd

ata

over

tim

e(S

eeC

hap

ter

8)to

det

erm

ine

wh

eneq

uil

ibri

um

con

dit

ion

sar

ere

ach

ed.

•F

orsa

mp

les

wit

hve

ryli

ttle

wat

erh

old

ing

cap

acit

y(i

.e.

dry

san

dsa

mp

les)

,sm

all

leak

sin

the

sam

ple

cham

ber

can

cau

sew

ater

pot

enti

alto

dri

ftd

own

over

tim

e.F

ast

mod

eis

reco

m-

men

ded

for

thes

esa

mp

les.

•F

orb

est

resu

lts,

run

mos

tso

ilsa

mp

les

inp

reci

sem

od

efo

rb

est

resu

lts.

•N

ever

pla

cea

hot

orw

arm

sam

ple

ina

cool

edch

amb

er,b

ecau

seco

nd

ensa

tion

wil

lfo

rmin

sid

eth

ech

amb

er,

cau

sin

ger

rors

inre

adin

g.

4.3

Sam

ple

Equ

ilib

rati

on

Scr

een

To

see

the

tem

per

atu

red

iffer

ence

bet

wee

nyo

ur

sam

ple

an

dth

eW

P4C

,p

ress

the

low

erri

ght

bu

tton

atth

em

ain

men

u.

You

can

only

acc

ess

the

Tem

per

atu

reD

iffer

ence

scre

enw

hen

the

dra

wer

kn

obis

inth

eO

PE

N/L

OA

Dp

osit

ion

.

Th

issc

reen

show

sth

ete

mp

erat

ure

diff

eren

ceb

etw

een

the

sam

ple

(Ts)

an

dth

ech

amb

erb

lock

(Tb

).T

his

scre

enall

ows

you

toqu

ickly

chec

kif

the

sam

ple

isto

oh

ot,

wh

ich

may

cau

seco

nd

ensa

tion

insi

de

the

cham

ber

.P

ress

the

low

erri

ght

bu

tton

toex

it.

17

Page 22: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

9C

LE

AN

ING

AN

DM

AIN

TE

NA

NC

E

of

IPA

or

clean

ing

solu

tion

(the

IPA

or

clean

ing

solu

tion

will

becom

eco

nta

min

ated

).

(c)W

AS

H–C

leanall

surface

edges

ofth

esa

mp

lesch

amb

erin

-clu

din

gth

eed

gew

here

the

samp

lecu

pseals

toth

ech

am-

ber

blo

ck.

You

may

need

torep

laceth

eK

imw

ipe

ifit

becom

esto

od

irtyd

urin

gth

isp

rocess.

(d)

RIN

SE

–Rep

eatstep

sb

and

cu

sing

new

Kim

wip

esw

ithd

eionized

water.

(e)D

RY

–Rep

eatstep

sb

and

cu

sing

new

,d

ryK

imw

ipes

toh

elprem

ovean

ym

oisture

remain

ing

fromth

eclean

ing.

(f)V

isually

insp

ectth

esam

ple

cham

ber

forclean

liness.

Clean

againif

necessary.

Note:

Do

not

reuse

Kim

wipes.

2.C

leanin

gth

eM

irror

Note:

Wash

han

ds

with

soap

an

dw

ater

(topreven

toils

from

con

tam

inatin

gth

eK

imw

ipetissu

ean

dbein

gtra

nsferred

toth

em

irror).

(a)W

rapa

NE

WK

imw

ipe

aroun

dth

een

dof

the

thin

plas-

ticro

d(sp

atula)

and

moisten

itw

ithisop

ropyl

alcohol

orclean

ing

solution

.

(b)

WA

SH

–Carefu

llyclean

the

mirror

with

the

moist

Kim

wip

e.

(c)R

INS

E–R

epeat

steps

ban

dc

usin

gn

ewK

imw

ipes

with

deion

izedw

ater.

(d)

DR

Y–R

epeat

steps

ban

dc

usin

gn

ew,

dry

Kim

wip

esto

help

remove

any

moistu

rerem

ainin

gfrom

the

cleanin

g.

(e)V

isually

insp

ectth

em

irrorfor

cleanlin

ess.R

e-cleanif

necessary.

Note:

Do

not

reuse

Kim

wip

es.

3.C

lean

ing

the

Optical

Sen

sor

You

will

prob

ably

cleanth

eop

ticalsen

sorw

hile

youare

clean-

ing

the

mirror,

since

they

faceeach

other

ina

verysm

all

gap.

35

4T

HE

ME

NU

SW

P4C

Note:)

Itis

impo

rtan

tth

at

Ts−

Tb

isn

egative

inord

erto

preven

tco

nden

satio

nin

side

the

sam

ple

cham

ber.

18

Page 23: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

9C

LE

AN

ING

AN

DM

AIN

TE

NA

NC

EW

P4C

Fig

ure

10:

Vie

wof

Insi

de

Blo

ck

9.2

Cle

an

ing

Pro

ced

ure

Cle

anin

gyo

ur

WP

4Cis

am

ult

i-st

epp

roce

du

rew

hic

hin

volv

esw

ash

-in

g,ri

nsi

ng,

and

dry

ing

for

each

spec

ific

area

asou

tlin

edb

elow

:

1.C

lean

ing

the

Insi

de

Ch

amb

er

Note

:B

eex

trem

ely

care

ful

not

todam

age

the

fan

blades

inth

ech

am

ber.

The

fan

blades

are

very

fragi

le;

ifon

eof

them

brea

ks,

you

rin

stru

men

tw

ill

not

work

pro

perl

y.T

ake

extr

aca

rew

hen

clea

nin

gth

ispo

rtio

n.

(a)

Rem

ove

any

deb

ris

that

may

hav

eco

llec

ted

wit

hin

orar

oun

dth

esa

mp

lech

amb

er.

(b)

Wra

pa

new

Kim

wip

ear

oun

dth

een

dof

the

thin

pla

s-ti

cro

d(s

pat

ula

)an

dm

oist

enit

wit

his

opro

pyl

alc

ohol

orcl

ean

ing

solu

tion

.

Note

:D

on

ot

dip

au

sed

Kim

wip

ein

toyo

ur

con

tain

er

34

WP

4C

5C

AL

IBR

AT

ION

AN

DV

ER

IFIC

AT

ION

5C

ali

bra

tion

an

dV

eri

fica

tion

5.1

Veri

fica

tion

Th

eW

P4C

use

sth

ech

ille

dm

irro

rd

ewp

oint

tech

niq

ue

for

mea

-su

rin

gw

ater

pot

enti

al.

Th

isis

the

pri

mar

ym

easu

rem

ent

met

hod

,th

ough

inst

rum

ent

clea

nli

nes

sca

naff

ect

the

cali

bra

tion

.W

efi

xth

eca

lib

rati

onsl

ope

du

ring

fact

ory

cali

bra

tion

.T

he

use

rca

nad

just

the

zero

offse

tan

dca

lib

rate

succ

essf

ully

wit

han

yso

luti

onof

kn

own

wa-

ter

pot

enti

al.

We

reco

mm

end

usi

ng

the

0.5

mol

/kg

KC

lver

ifica

tion

stan

dar

dav

aila

ble

from

ME

TE

R.

5.2

Veri

fica

tion

Sta

nd

ard

s

Ver

ifica

tion

stan

dar

ds

are

spec

iall

yp

rep

ared

salt

solu

tion

sth

ath

ave

asp

ecifi

cm

olal

ity

and

wat

erp

oten

tial

.T

he

pot

assi

um

chlo

rid

e(K

Cl)

veri

fica

tion

stan

dard

sar

eac

cura

te,

easy

tou

se,

and

read

ily

avail

able

from

ME

TE

R.

Mos

tim

por

tantl

y,th

eygr

eatl

yre

du

cep

rep

arat

ion

erro

rs.

Th

est

an

dar

ds

are

pro

du

ced

un

der

ast

rict

qu

alit

yass

ura

nce

regi

me

and

are

shel

fst

able

for

one

yea

r.If

for

som

ere

ason

you

can

not

obta

inM

ET

ER

’sve

rifi

cati

onst

and

ard

san

dn

eed

tom

ake

asa

ltso

luti

onfo

rve

rifi

cati

on

,re

fer

toA

pp

end

ixA

.

Note

:T

oavo

idin

acc

ura

tew

ate

ract

ivit

yre

adin

gs,

veri

fica

tion

stan

-dard

ssh

ou

ldbe

use

don

ceim

med

iate

lyaft

erope

nin

gan

dn

ot

store

din

sam

ple

cups

for

repe

ate

du

se.

5.3

Wh

en

toV

eri

fyC

ali

bra

tion

Th

eca

lib

rati

onof

you

rW

P4C

shou

ldb

ech

ecke

dw

ith

the

KC

lst

an-

dar

db

efor

eea

chu

se.

Itca

nal

sob

ech

ecke

dby

mea

suri

ng

dis

till

edw

ater

,b

ut

this

isof

ten

not

ago

od

choi

cefo

rch

eckin

gca

lib

rati

on.

Wh

enu

sin

gd

isti

lled

wat

er,

the

hu

mid

ity

ofth

ech

amb

erap

pro

ach

es10

0%w

hic

hca

nca

use

con

den

sati

onto

occ

ur

ifth

esa

mp

leis

war

mer

than

the

cham

ber

.F

orb

atch

pro

cess

ing,

you

shou

ldre

gula

rly

chec

k

19

Page 24: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

9C

LE

AN

ING

AN

DM

AIN

TE

NA

NC

E

9C

lean

ing

an

dM

ain

ten

an

ce

Th

eaccu

racyof

your

WP

4Cis

vitally

dep

end

ent

onkeep

ing

your

instru

men

tclea

n.

Du

stan

dsam

ple

deb

riscan

conta

min

ateth

esam

-p

ling

cham

ber

and

mu

stth

ereforeb

eregu

larlyclean

edou

t.T

oclea

nyo

ur

instru

men

t,carefu

llyfollow

these

instru

ctions.

You

rin

stru-

men

tsh

ips

with

aclean

ing

kit

that

shou

ldlast

one

yearw

ithregu

larclean

ings.

ME

TE

Rh

asad

dition

alclean

ing

kits

available

forp

ur-

chase

with

sup

plies

toclean

your

WP

4C.

Note:

Kim

wipe

R©are

inclu

ded

inth

eW

P4C

Clea

nin

gK

it.T

hey

are

idea

lfo

rclea

nin

gbeca

use

they

do

not

leave

mu

chof

alin

tresid

ue

likem

ost

tissues.

They

also

do

not

have

an

yoth

erco

mpo

un

ds

inth

etissu

eth

at

may

con

tam

inate

the

senso

rsin

the

WP

4C

block.N

everu

seco

tton

swabs

toclea

nth

eblock

senso

rs.M

ost

cotto

nsw

abs

con

-ta

inadhesives

an

doth

erco

mpo

un

ds

that

are

released

an

dtra

nsferred

toth

em

irror

an

doth

ersu

rfaces,

con

tam

inatin

gth

em.

9.1

Acce

ssing

the

Blo

ck

1.U

np

lug

your

WP

4C

2.R

emov

eth

ecase

lidscrew

located

onth

eb

ackp

anel.

Carefu

llyrem

oveth

elid

by

pu

lling

the

back

ofth

elid

upw

ard

and

then

slidin

gth

elid

back

(away

fromth

efron

tof

the

case)an

doff

.

3.U

nscrew

the

two

thu

mb

screws

that

secure

the

senso

rb

lock

.

4.U

np

lug

the

cable

with

the

20-pin

socket

that

attaches

the

blo

ckto

the

main

circuit

board

by

releasing

the

two

lock

ing

levers

that

areon

either

side

ofth

eso

cket.

5.C

arefully

liftth

eb

lock

straight

up

fromits

mou

nt.

Tu

rnth

eb

lock

overto

exp

oseth

ech

amb

ercav

ityas

show

nin

the

illus-

tration:

33

5C

AL

IBR

AT

ION

AN

DV

ER

IFIC

AT

ION

WP

4C

the

instru

men

tagain

stth

eK

Cl

stand

ard.

Th

isw

illalert

youto

the

possib

ilityof

contam

ination

ofth

eu

nit

orsh

iftsin

the

calib

ration

fromoth

ercau

ses.

5.4

How

toV

erify

an

dC

alib

rate

the

WP

4C

Sin

ceerro

rsin

the

calibration

value

result

inerrors

inall

valu

essu

b-

sequ

ently

measu

red,

caresh

ould

be

takento

do

itrig

ht.

Ch

eck

ing

an

dA

dju

sting

Calib

ratio

n

•P

ressth

eu

pp

errigh

tb

utton

inth

eS

ystem

Con

figu

ration

men

uto

enter

the

calibration

men

u.

You

will

be

guid

edth

rough

the

calibration

routin

eb

eginn

ing

with

instru

ction

sto

place

you

rsta

nd

ard.

•E

mp

tyth

ew

hole

vial

ofK

Cl

solution

into

asam

ple

cup

and

place

itin

the

WP

4Csam

ple

draw

er.M

akesu

reyo

ucalib

rateu

sing

the

same

typ

eof

samp

lecu

p(p

lasticor

stain

lesssteel)

that

youw

illm

akesu

bseq

uen

tm

easurem

ents

with

.

•C

arefully

slide

the

draw

erclosed

,b

eing

especially

carefulso

the

solution

does

not

splash

orsp

illan

dcon

tamin

ateth

ech

am

ber.

Ch

eckto

be

sure

the

samp

letem

peratu

reis

below

cham

ber

temp

erature

(lower

right

bu

tton).

•T

urn

the

draw

erkn

obto

the

RE

AD

position

tom

akea

read

ing.

Wh

enth

eread

ing

iscom

plete,

the

followin

gscreen

will

app

ear:

20

Page 25: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

8T

HE

OR

Y:

WA

TE

RP

OT

EN

TIA

LW

P4C

that

are

nea

rsa

tura

tion

(lik

em

any

soil

sam

ple

s).

Asa

mp

leth

at

iscl

ose

to0.

00M

Pa

and

ison

lysl

ightl

yw

arm

erth

an

the

sen

sor

blo

ckw

ill

con

den

sew

ater

wit

hin

the

blo

ck.

Th

isw

ill

cau

seer

rors

inth

em

easu

rem

ent,

and

insu

bse

qu

ent

mea

sure

men

tsu

nti

lth

eco

nd

ensa

-ti

on

dis

app

ears

.T

he

Ts-

Tb

fun

ctio

nh

elp

sth

eu

ser

ensu

reth

at

the

sam

ple

wil

ln

otco

nd

ense

onth

ese

nso

rb

lock

.

8.4

Est

imati

ng

Osm

oti

cP

ote

nti

al

Th

eW

P4C

mea

sure

sth

esu

mof

osm

otic

and

matr

icp

ote

nti

al.

An

app

roxim

ate

valu

efo

rth

eos

mot

icp

oten

tial

can

be

fou

nd

by

mea

-su

rin

gth

eel

ectr

ical

con

du

ctiv

ity

(EC

)of

the

satu

rati

onex

tract

ofth

eso

il.

Th

eos

mot

icp

oten

tial

ofth

esa

tura

tion

extr

act

isco

mp

ute

dfr

om:

Ψos(M

Pa)

=−

0.03

6EC

(dS/m

)(2

)

Th

eos

mot

icco

mp

onen

tof

the

wat

erp

oten

tial

isth

enco

mp

ute

dfr

om:

Ψ=

Ψos(θ

s θ)

(3)

wh

ereθ

isth

evo

lum

etri

cw

ater

conte

nt

ofth

esa

mp

lean

dθ s

isth

evo

lum

etri

cw

ater

conte

nt

atsa

tura

tion

.T

he

mat

ric

pot

enti

al

isth

eto

tal

pot

enti

alm

inu

sth

eos

mot

ic. 32

WP

4C

5C

AL

IBR

AT

ION

AN

DV

ER

IFIC

AT

ION

Note

:T

he

WP

4C

wil

lau

tom

ati

call

ysh

ift

topre

cise

sam

pli

ng

mod

efo

rth

eve

rifi

cati

on

/ca

libr

ati

on

.

Th

ere

adin

gsh

ould

be

wit

hin

±0.

05M

Pa

ofth

eco

rrec

tre

adin

gof

the

KC

lst

andar

dat

that

tem

per

atu

re.

At

20◦ C

this

shou

ldb

e−

2.19

MP

a.A

t25

◦ Cth

issh

ould

be−

2.22

MP

a.

•If

you

rW

P4C

isre

adin

gw

ith

in0.

05M

Pa

ofth

eK

Cl

solu

tion

,p

ress

Exit

and

pro

ceed

wit

hre

adin

g.If

itis

not

,a

chan

gein

cali

bra

tion

may

hav

eocc

urr

ed,

orth

ese

nso

rch

amb

erm

ayb

eco

nta

min

ate

d.

For

clea

nin

gin

stru

ctio

ns,

see

Ch

ap

ter

10.

Aft

ercl

ean

ing,

rep

eat

thes

ein

stru

ctio

ns.

•If

,af

ter

clea

nin

g,you

consi

sten

tly

get

read

ings

that

diff

erfr

om

the

corr

ect

wat

erp

oten

tial

ofth

eK

Cl

by

mor

eth

an±

0.0

5M

Pa,

ach

ange

inca

lib

rati

onh

asp

rob

ably

occ

urr

ed.

Pre

ssth

eu

pp

erri

ght

bu

tton

tom

ove

the

valu

eu

p,

the

low

erri

ght

bu

t-to

nto

mov

eit

dow

n.

Wh

enit

isat

the

corr

ect

valu

efo

rth

eve

rifi

cati

onst

and

ard

,p

ress

the

Exit

bu

tton

.T

he

valu

ew

ill

be

stor

ed.

Note

:T

his

isth

eon

lym

enu

wher

eth

ese

butt

on

sca

nch

an

geth

eca

libr

ati

on

,so

you

wil

ln

ot

hu

rtan

ythin

gby

pre

ssin

gth

ese

butt

on

sin

oth

erm

enu

s.

•R

ead

the

KC

lst

and

ard

agai

nin

the

nor

mal

read

ing

mod

e.It

shou

ldre

adth

ep

rop

erva

lue.

•If

afte

rad

just

ing

the

cali

bra

tion

and

clea

nin

gth

ech

amb

eryou

stil

lar

ege

ttin

gin

corr

ect

read

ings

wh

enre

adin

gth

eK

Cl,

con

-ta

ctM

ET

ER

at50

9-33

2-56

00fo

rfu

rth

erin

stru

ctio

ns.

21

Page 26: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

8T

HE

OR

Y:

WA

TE

RP

OT

EN

TIA

L

ofa

closedch

amb

er,th

enm

easurin

gth

evap

or

pressu

reof

that

head

space.

Inth

eW

P4C

,a

samp

leis

placed

ina

sam

ple

cup

,w

hich

issealed

against

asen

sorb

lock

.In

side

the

sensor

blo

ckis

afan

,a

dew

poin

tsen

sor,

atem

peratu

resen

sor,an

dan

infrared

therm

ome-

ter.T

he

dew

poin

tsen

sorm

easures

the

dew

poin

ttem

peratu

reof

the

air,an

dth

ein

fraredth

ermom

eterm

easures

the

samp

letem

per-

ature.

Th

ep

urp

oseof

the

fanis

tosp

eedeq

uilib

rium

and

tocon

trolth

eb

oun

dary

layer

cond

uctan

ceof

the

dew

poin

tsen

sor.

From

these

measu

remen

ts,th

eW

P4C

comp

utes

the

vapor

pressu

reof

the

airin

the

head

space

asth

esatu

rationvap

orp

ressure

at

dew

poin

ttem

peratu

re.W

hen

the

water

poten

tialof

the

sam

ple

an

dth

eh

eadsp

aceair

arein

equ

ilibriu

m,

the

measu

remen

tof

the

hea

dsp

acevap

orp

ressure

and

samp

letem

peratu

re(from

wh

ichsatu

rationva

-p

orp

ressure

iscalcu

lated)

givesth

ew

aterp

otentia

lof

the

sam

ple.

Inad

dition

toeq

uilib

rium

betw

eenth

eliq

uid

ph

asew

aterin

the

samp

lean

dth

evap

orp

hase,

the

intern

aleq

uilib

rium

of

the

samp

leitself

isim

portan

t.If

the

samp

leis

not

atin

ternal

equ

ilibriu

m,

one

migh

tm

easure

astead

yvap

orp

ressure

(overth

ep

eriod

ofm

easure-

men

t)w

hich

isn

otth

etru

ew

aterp

otential

ofth

esa

mp

le.

8.3

Eff

ect

of

Tem

pera

ture

on

Wate

rP

ote

ntia

l

Tem

peratu

rep

lays

acritical

rolein

water

poten

tial

determ

ination

s.M

ostcritica

lis

the

measu

remen

tof

the

diff

erence

betw

eensam

ple

and

dew

poin

ttem

peratu

re.If

this

temp

erature

diff

erence

were

inerror

by

1◦C

,an

errorof

8M

Pa

wou

ldresu

lt.In

order

forw

aterp

oten

tialm

easurem

ents

tob

eaccu

rateto

0.05

MP

a,

temp

erature

diff

erence

measu

remen

tsn

eedto

be

accurate

to0.006

◦C.

Th

eW

P4C

infrared

therm

ometer

measu

resth

ed

ifferen

cein

tem-

peratu

reb

etween

the

samp

lean

dth

eb

lock

.It

iscarefu

llycalib

ratedto

min

imize

temp

erature

errors,b

ut

achiev

ing

0.006

◦Caccu

racyis

diffi

cult

wh

entem

peratu

red

ifferen

cesare

large.

Best

accura

cyis

therefore

obtain

edw

hen

the

samp

leis

near

cham

ber

temp

eratu

re.

An

other

effect

oftem

peratu

reon

water

poten

tialoccu

rsw

ithsam

ples

31

6S

AM

PL

EP

RE

PA

RA

TIO

NW

P4C

6S

am

ple

Pre

para

tion

You

rW

P4C

will

contin

ually

prov

ide

accurate

water

poten

tialm

ea-

surem

ents

aslon

gas

itsin

ternal

sensors

aren

otcon

tamin

ated.

Care-

ful

prep

arationan

dload

ing

ofsam

ples

will

length

entim

eb

etween

cleanin

gsan

dw

illh

elpyou

avoidd

owntim

ean

drep

airs.

6.1

Ch

oosin

ga

Sam

ple

Cu

p

Th

eW

P4C

comes

with

two

typ

esof

samp

lescu

ps:

disp

osable

pla

s-tic

cup

san

dstain

lesssteel

cup

s.T

he

disp

osable

plastic

cup

sare

ad

equ

atefor

most

samp

les,b

ut

aren

otgo

od

forsam

ples

inth

ew

eten

d.

Ifyou

are

measu

ring

samp

lesw

ithw

aterp

otentia

lw

etterth

an

−1

MP

a,you

shou

ldu

seth

estain

lesssteel

samp

lecu

ps.

You

canalso

ovend

rysoil

samp

lesd

irectlyin

the

stainless

steelcu

ps

tod

e-term

ine

water

conten

tgrav

imetrically,

wh

ichis

conven

ient

ifyou

aregen

erating

soilm

oisture

characteristic

curves.

Itis

imp

ortant

ton

oteth

atyou

mu

stth

orough

lyclean

the

stainless

steelcu

ps

usin

gd

eionized

water

betw

eenu

sesto

preven

tsolu

tesfro

mcon

tamin

ating

sub

sequ

ent

sam

ples

and

causin

gartifi

ciallyn

egativeosm

oticp

oten-

tial.F

inally,

ifyou

calibrate

the

WP

4C(see

chap

ter5),

be

sure

tocalib

rate

usin

gth

esam

ety

pe

ofsam

ple

cup

that

youin

tend

tou

sefor

sub

sequ

ent

mea

surem

ents.

6.2

Pre

parin

gth

eS

am

ple

First,

place

the

samp

lein

ad

isposab

lesam

ple

cup

,com

pletely

cov-

ering

the

bottom

ofth

ecu

p,

ifp

ossible.W

P4C

may

not

be

ab

leto

accu

ratelym

easure

asam

ple

that

does

not

(orcan

not)

coverth

eb

ottomof

the

cup

.A

largersam

ple

surface

areasp

eeds

up

the

read-

ing

by

shorten

ing

the

time

need

edto

reachvap

or

equ

ilibriu

m.

Italso

increases

instru

men

taccu

racyby

prov

idin

gm

oresta

ble

infra

redsam

ple

temp

erature

measu

remen

ts.

Do

not

fill

the

samp

lecu

pm

oreth

anh

alffu

ll.O

verfilled

cup

sm

aycon

tamin

ateth

esen

sorsin

the

cham

ber,

remem

ber

more

isn

ot

nec-

essarilyb

etter.

22

Page 27: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

8T

HE

OR

Y:

WA

TE

RP

OT

EN

TIA

LW

P4C

8T

heory

:W

ate

rP

ote

nti

al

8.1

Wate

rP

ote

nti

al

Wat

erp

oten

tial

isd

efined

asth

ep

oten

tial

ener

gy

per

un

itvo

lum

eof

wat

erin

asa

mp

le.

Th

eto

talw

ater

pot

enti

alof

asa

mp

leis

the

sum

of

fou

rco

mp

onen

tp

oten

tial

s:gr

avit

atio

nal

,m

atri

c,os

mot

ic,

and

pre

s-su

re.

Gra

vit

atio

nal

pot

enti

ald

epen

ds

onth

ep

osit

ion

ofth

ew

ater

ina

grav

itat

ion

al

fiel

d.

Mat

ric

pot

enti

ald

epen

ds

on

the

ad

sorp

tive

forc

esb

ind

ing

wat

erto

am

atri

x.

Osm

otic

pot

enti

ald

epen

ds

on

the

con

centr

atio

nof

dis

solv

edsu

bst

ance

inth

ew

ater

.P

ress

ure

pot

enti

al

dep

end

son

the

hyd

rost

atic

orp

neu

mat

icp

ress

ure

on

the

wat

er.

Th

eW

P4C

mea

sure

sth

esu

mof

the

osm

otic

and

mat

ric

pote

nti

als

ina

sam

ple

.O

ften

one

orth

eot

her

ofth

ese

pot

enti

als

wil

lb

eth

ed

omi-

nan

tfa

ctor

ind

eter

min

ing

the

tota

lp

oten

tial

.F

orex

amp

le,so

luti

ons

like

the

KC

lca

lib

rati

onst

and

ard

hav

eon

lyan

osm

otic

com

pon

ent.

Soi

lsb

ind

wat

erm

ain

lyth

rou

ghm

atri

cfo

rces

,an

dth

eref

ore

hav

em

ain

lya

mat

ric

com

pon

ent

(th

ough

salt

-aff

ecte

dso

ils

can

hav

ea

sign

ifica

nt

osm

otic

com

pon

ent)

.

8.2

Measu

rin

gW

ate

rP

ote

nti

al

Th

ew

ater

pot

enti

alof

aso

lid

orli

qu

idsa

mp

leca

nb

efo

un

dby

rela

tin

gth

esa

mp

lew

ater

pot

enti

alre

adin

gto

the

vap

orp

ress

ure

ofai

rin

equ

ilib

riu

mw

ith

the

sam

ple

.T

he

rela

tion

ship

bet

wee

nth

esa

mp

lew

ater

pot

enti

al(Ψ

)an

dth

eva

por

pre

ssu

reof

the

air

is:

Ψ=RT

M∗l

np po

(1)

wh

erep

isth

eva

por

pre

ssu

reof

the

air,po

isth

esa

tura

tion

vap

orp

ress

ure

atsa

mp

lete

mp

erat

ure

,R

isth

ega

sco

nst

ant

(8.3

1J/m

olK

),T

isth

eK

elvin

tem

per

atu

reof

the

sam

ple

,an

dM

isth

em

olec

-u

lar

mas

sof

wat

er.

Th

eva

por

pre

ssu

reof

the

air

can

be

mea

sure

du

sin

ga

chil

led

mir

ror,

andpo

isco

mp

ute

dfr

omsa

mp

lete

mp

eratu

re.

Th

eW

P4C

mea

sure

sw

ater

pot

enti

alby

equ

ilib

rati

ng

the

liqu

idp

has

ew

ate

rof

the

sam

ple

wit

hth

eva

por

ph

ase

wat

erin

the

hea

dsp

ace

30

WP

4C

6S

AM

PL

EP

RE

PA

RA

TIO

N

Mak

esu

reth

at

the

rim

and

outs

ide

ofth

esa

mp

lecu

pare

clea

n.

Wip

eany

exce

sssa

mp

lem

ater

ialfr

omth

eri

mof

the

cup

wit

ha

clea

nti

ssu

e.M

ater

ial

left

onth

eri

mor

the

outs

ide

ofth

ecu

pw

ill

con

-ta

min

ate

the

sen

sor

cham

ber

and

wil

lb

etr

ansf

erre

dto

sub

sequ

ent

sam

ple

s.T

he

rim

ofth

ecu

pfo

rms

ava

por

seal

wit

hth

ese

nso

rb

lock

wh

enth

ed

raw

erkn

obis

turn

edto

the

RE

AD

pos

itio

n.

Th

eref

ore,

any

sam

ple

mate

rial

left

onth

ecu

pri

mw

ill

be

tran

sfer

red

toth

eb

lock

,p

reve

nti

ng

this

seal

and

conta

min

atin

gfu

ture

sam

ple

s.

Ifa

sam

ple

wil

lb

ere

adat

som

efu

ture

tim

e,p

ut

the

sam

ple

cup

dis

pos

able

lid

onth

ecu

pto

rest

rict

wat

ertr

ansf

er.

For

shor

t-te

rmst

orage

(<3

hou

rs)

the

cup

lid

isac

cep

table

.If

itw

ill

be

alo

ng

tim

eb

efor

eth

em

easu

rem

ent

ism

ade,

seal

the

lid

wit

hta

pe

orP

arafi

lmR ©

com

ple

tely

aro

un

dth

ecu

pan

dli

dju

nct

ion

.

6.3

Dry

Sam

ple

s

Sam

ple

sth

ath

ave

aw

ater

pot

enti

ald

rier

than

abou

t−

300

MP

aca

nn

otb

eac

cura

tely

mea

sure

dw

ith

the

WP

4C.

How

ever

,sa

mp

les

wit

hsu

chd

ryw

ater

pot

enti

alva

lues

are

rare

.W

hen

asa

mp

lew

ater

pot

enti

alva

lue

isd

rier

than

abou

t−

300

MP

a,W

P4C

wil

ld

isp

lay

aner

ror

mes

sage

ind

icat

ing

the

low

est

read

ing

itco

uld

mak

eon

that

par

ticu

lar

sam

ple

.F

orex

ample

,if

you

wer

em

easu

rin

ga

dry

sam

ple

and

the

follow

ing

scre

enap

pea

red

:

Th

issc

reen

ind

icat

esth

atth

ela

stw

ater

pot

enti

alre

adin

gth

eW

P4C

mea

sure

don

this

sam

ple

was

−30

1.8

Meg

apas

cals

.T

her

efore

,th

eac

-tu

alw

ater

pot

enti

alof

the

sam

ple

islo

wer

than

the

inst

rum

ent

can

mea

sure

.

23

Page 28: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

7C

OM

PU

TE

RIN

TE

RFA

CE

!N

op

arity!

1sto

pb

it!

Flow

control

setto

non

e

After

successfu

llycon

nectin

gth

eW

P4C

toyou

rcom

pu

teran

du

pon

comp

letionof

aw

ateractiv

ityread

ing,

the

data

will

be

disp

layedin

the

termin

alp

rogramin

the

format

asfollow

s:m

easurem

ent

time

(min

utes),

samp

letem

peratu

re,an

dw

aterp

otential

(inb

othM

ega-P

ascals

and

pF

).F

igure

9sh

ows

asam

ple

return

.

Figu

re9:

Sam

ple

Data

Retu

rn

29

6S

AM

PL

EP

RE

PA

RA

TIO

NW

P4C

6.4

Sam

ple

san

dT

em

pera

ture

Ifsam

ples

arew

armer

than

the

cham

ber

wh

enth

eyare

pla

cedin

it(T

s-Tb

isa

positive

nu

mb

er),con

den

sationm

ayoccu

ran

dm

oisture

may

cond

ense

insid

eth

eb

lock

.In

order

top

revent

this,

follow

steps

1an

d2.

1.P

laceyou

rsam

ple

inth

ech

amb

er,slid

eth

ed

rawer

closedan

dp

ressth

elow

errigh

tb

utton

toaccess

the

samp

letem

peratu

rescreen

and

look

atth

etem

peratu

red

ifferen

ce.If

the

sam

ple

temp

erature

issh

own

tob

ea

positive

nu

mb

er,take

the

sam

ple

out

imm

ediately

and

letit

cool

ona

coldsu

rfacew

ithth

ecu

plid

onit

top

reserve

the

moistu

re.D

on

otco

ol

the

sam

ple

too

mu

ch,

orth

eeq

uilib

rium

time

will

be

length

ened

(ideally

the

Ts-T

bw

illb

eb

etween

−0.5

and

0).

2.A

fterco

oling

itfor

am

inu

teor

so,p

laceth

esam

ple

back

inan

dn

oteth

etem

peratu

red

ifferen

ce.If

itis

close

enou

gh

toth

eb

lock

temp

erature,

turn

the

kn

obto

the

RE

AD

position

tob

eginread

ing.

Th

ereis

alin

earrelation

ship

betw

eenth

esam

ple

dew

poin

ttem

per-

ature

and

itsw

aterp

otential.

Th

ed

ewp

oint

decreases

−0.12

◦Cp

erM

Pa.

For

exam

ple,

avery

dry

samp

leat−

40M

Pa

canb

e4.8

◦C(−.12∗−

40)ab

oveth

ech

amb

ertem

peratu

rew

ithou

tcon

den

s-in

g.A

samp

leat−

1M

Pa

(fairlyd

ryfor

most

soils)ca

nb

e0.1

2◦C

above

the

cham

ber

temp

erature

with

out

cond

ensin

g.T

herefore,

ifyou

kn

owth

egen

eralran

geof

your

samp

lew

aterp

otentia

l,you

canga

uge

at

wh

ichtem

peratu

reit

will

cond

ense

moistu

re.F

orsam

ples

that

arem

oreth

an1

◦Cb

elowch

amb

ertem

peratu

re,th

eW

P4C

waits

until

their

temp

erature

increases

to1

◦Cb

elowch

am

ber

tem-

peratu

reto

starta

readin

g.R

eadin

gsare

therefore

sped

up

ifsa

mp

letem

peratu

reis

just

alittle

below

cham

ber

temp

erature.

24

Page 29: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

7C

OM

PU

TE

RIN

TE

RFA

CE

WP

4C

Fig

ure

8:A

qu

aLin

kS

cree

nS

hot

7.2

Usi

ng

aC

om

mu

nic

ati

on

Pro

gra

m

Th

ere

are

seve

ral

term

inal

pro

gram

opti

ons.

ME

TE

Rh

asit

sow

nte

rmin

alp

rogr

am(D

ecaT

erm

)w

hic

hca

nb

ed

own

load

edfr

om:

htt

p:/

/sof

twar

e.m

eter

grou

p.c

om/D

ecaT

erm

.zip

.T

wo

oth

erop

tion

sar

eT

eraT

erm

,w

hic

his

afr

eep

rogr

amth

atca

nb

efo

un

don

the

Inte

rnet

and

Hyp

erte

rmin

alw

hic

hca

me

stan

dar

dw

ith

Win

dow

sp

rior

toW

ind

ows

7.

To

use

any

ofth

ese

term

inal

pro

gram

sw

ith

you

rW

P4C

,fo

llow

the

inst

ruct

ion

sfo

rth

ep

rogr

amw

ith

the

foll

owin

gse

ttin

gs.

Be

sure

top

ower

onth

eW

P4C

pri

orto

con

nec

tin

gth

eU

SB

inte

rfac

eca

ble

toyo

ur

com

pu

ter.

•C

hoos

eco

rrec

tC

omp

ort

•S

et/V

erif

yC

omP

rop

erti

es

!B

its

per

seco

nd

9600

!8

Dat

abit

s

28

WP

4C

6S

AM

PL

EP

RE

PA

RA

TIO

N

6.5

Measu

rin

gP

lant

Sam

ple

s

Th

eW

P4C

can

be

use

dto

mea

sure

the

wat

erp

ote

nti

alof

leav

esan

dpla

nt

mat

eria

l.P

leas

ere

fer

toth

eap

pli

cati

onn

ote:

Mea

sure

-m

ent

ofL

eaf

Wat

erP

oten

tial

Usi

ng

the

WP

4,w

hic

hca

nb

efo

un

dat

ww

w.m

eter

grou

p.c

om.

6.6

Takin

ga

Read

ing

On

ceyo

uh

ave

pre

par

edyou

rsa

mp

le,

you

are

read

yto

take

read

ings.

Fol

low

step

s1

thro

ugh

5to

take

read

ings

.

1.T

urn

the

sam

ple

dra

wer

kn

obto

the

OP

EN

/LO

AD

pos

itio

nan

dp

ull

the

dra

wer

open

.

2.P

lace

you

rp

rep

ared

sam

ple

inth

ed

raw

er.

Chec

kth

eto

pli

pof

the

cup

tom

ake

sure

itis

free

from

sam

ple

resi

du

e(r

emem

-b

er,

anov

er-fi

lled

sam

ple

cup

wil

lco

nta

min

ate

the

cham

ber

sen

sors

).

3.C

aref

ull

ysl

ide

the

dra

wer

clos

ed,

bei

ng

esp

ecia

lly

care

fulif

you

hav

ea

liqu

idsa

mp

leth

atm

aysp

lash

orsp

ill

and

conta

min

ate

the

cham

ber

.

4.A

cces

sth

esa

mp

lete

mp

erat

ure

men

u(p

ress

low

erri

ght

bu

tton

)to

watc

hth

ete

mp

erat

ure

diff

eren

ceb

etw

een

the

sam

ple

an

dth

ein

stru

men

t.

5.T

urn

the

sam

ple

dra

wer

kn

obto

the

RE

AD

pos

itio

nto

sealth

esa

mp

lecu

pw

ith

the

cham

ber

.T

he

inst

rum

ent

wil

lb

eep

on

ce,

and

the

gree

nli

ght

wil

lfl

ash

once

toin

dic

ate

that

the

read

ing

cycl

eh

asst

arte

d.

Inab

out

40se

cond

s,th

efi

rst

mea

sure

men

tw

ill

be

dis

pla

yed

.

6.7

How

WP

4C

takes

Read

ings

Th

eW

P4C

cool

edm

irro

ris

contr

olle

dat

the

cham

ber

dew

poin

tan

dit

ste

mp

erat

ure

ism

easu

red

..W

hen

the

inst

rum

ent

has

fin

ish

edit

sre

adcy

cle,

the

wat

erp

oten

tial

isd

isp

laye

d,

acco

mp

an

ied

by

the

LE

Dfl

ash

and

bee

per

(if

you

hav

eth

eb

eep

eren

able

d).

25

Page 30: tiaMetermanuals.decagon.com/Manuals/13588_WP4C_Print.pdf · WP4C B B Correction Standards Solutions emp. H 2 O 0.50 2.33 6.00 8.57 13.41 17.18 ( C) mol/kg mol/kg mol/kg mol/kg mol/kg

WP

4C

7C

OM

PU

TE

RIN

TE

RFA

CE

7C

om

pu

ter

Inte

rface

You

rW

P4C

comes

with

aR

S-232

toU

SB

Serial

cab

le.U

sing

this

cable,

youcan

conn

ectto

your

WP

4Can

dsen

dw

ateractiv

ityd

atato

acom

pu

terfor

furth

eran

alysis

and

storage.T

he

interface

isru

nth

rough

the

Aqu

aLin

k4

Softw

areor

aterm

inal

com

mu

nication

pro-

gram

.

Note:

Ifyo

uco

mpu

terdoes

not

have

aU

SB

port,

you

can

use

aU

SB

toR

S-2

32

adapter.

7.1

Aqu

aL

ink

4S

oftw

are

An

option

alsoftw

arep

rogram,

Aqu

aLin

k4,

isavailab

lefor

use

with

you

rW

P4C

.A

qu

aLin

k4

isa

Win

dow

sb

asedp

rogramd

esigned

for

data

collectionan

dcu

stomized

report

generatio

n.

Aqu

aL

ink

4logs

water

activity,

temp

erature,

time

ofm

easurem

ent,

and

date

stamp

salon

gw

ithoth

erin

formation

.A

quaL

ink

4also

has

sam

ple

iden

ti-fi

cationan

dcom

men

tfi

elds

that

youcan

use

toh

elpan

notate

the

data

your

WP

4Cis

gatherin

g.

A30

day

trialU

SB

ofth

isp

rogramis

attached

toth

efron

tcover

ofth

ism

anu

al.If

youare

interested

inp

urch

asing

alicen

seof

Aqu

aLin

k4,

contact

ME

TE

Ror

your

local

distrib

utor.

On

the

nex

tp

ageis

asam

ple

pictu

reof

the

Aqu

aLin

k4

program

:

27

6S

AM

PL

EP

RE

PA

RA

TIO

NW

P4C

Cau

tion

s

•N

ever

leave

asa

mp

lein

your

WP

4C

afte

ra

read

ing

has

fin

ished

.T

he

sam

ple

may

spill

an

dconta

min

ate

the

instru

ment

cham

ber

ifth

ein

strum

ent

isaccid

enta

llym

oved

or

jolte

d.

•N

ever

tryto

move

you

rin

strum

ent

afte

rlo

ad

ing

asa

m-

ple

.M

ovem

ent

may

cau

seth

esa

mp

lem

ate

rial

tosp

illan

dconta

min

ate

the

sam

ple

cham

ber.

•T

ake

specia

lcare

not

tom

ove

the

sam

ple

dra

wer

too

qu

ickly

wh

en

load

ing

or

un

load

ing

liqu

idsa

mp

les,

inord

er

toavoid

spillin

g.

•If

asa

mp

leh

as

ate

mp

era

ture

that

ish

igh

er

than

the

WP

4C

cham

ber

(Ts-T

bis

ap

ositiv

enu

mb

er),

take

the

sam

ple

ou

tim

med

iate

ly,

pu

ta

cap

on

it,an

dcool

it.W

arm

sam

ple

scan

cau

secon

den

satio

nin

the

cham

ber

an

dad

verse

lyaff

ect

sub

sequ

ent

read

ings.

•T

he

physic

al

tem

pera

ture

of

the

instru

ment

shou

ldb

eb

etw

een

5◦C

an

d40

◦C.T

he

WP

4C

will

measu

resa

m-

ple

sb

etw

een

this

ran

ge

qu

ickly

an

daccu

rate

ly.

•If

you

are

read

ing

an

da

trian

gu

lar

warn

ing

sym

bol

ap

pears

inth

eto

prig

ht

corn

er

of

the

disp

lay,

this

in-

dic

ate

sth

at

the

mirro

rh

as

becom

eto

od

irtyto

giv

eaccu

rate

measu

rem

ents.

You

will

need

tocle

an

the

mirro

ran

dch

am

ber

befo

recontin

uin

gto

sam

ple

.For

more

deta

ilsab

ou

tth

issy

mb

ol,

ple

ase

refe

rto

Ch

ap

ter

12.

For

cle

an

ing

instru

ctio

ns,

refe

rto

Ch

ap

ter

10.

26


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