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8/8/2019 Baldo LUMINESCENT SOLAR CONCENTRATORS
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LUMINESCENT SOLAR CONCENTRATORS
Marc Baldo Massachusetts Institute of Technology
&Department of Electrical Engineering Computer [email protected] edu
://http . .softsemi mit edu:// . . /http rle mit edu excitonics
World Bank May 20th , 2010
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InstallationInverter, charge
controller,breaker, cables,
mountingReal estateLabor
System integrator margins
Permitting, design,shipping
Warranty
Maintenance
65%
:COST BREAKDOWN FOR SOLAR ELECTRICITY
1MW system size
rend: Installation is an increasing fraction of installed costs….
Module costs reduced by lowcost manufacturing & cellefficiency.
Installation costs scale ~90% with area.Installation costs reduced by economies of scale and cell efficiency.
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65%
:COST BREAKDOWN FOR SOLAR ELECTRICITY
1MW system size
Three aims
1. High efficiency (helps both module & balance of system)
2. Low cost manufacturing (helps module cost)
3. Building integrated (helps balance of system)
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.1 HIGHER EFFICIENCY?
Problem: high efficiency technologies are harder to make and expensive
Obstacles
•Mechanical – adds cost andmaintenance•
•PV needs cooling•
•
Must be widely spaced to avoidshadowing•
•Needs direct sunlight
Solution? Use solar concentrator to get more electricity from small (expensive cells)
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. & .2 MANUFACTURING 3 BUILDING INTEGRATED?-LASS BASED SOLAR CONCENTRATORS
( )ed glass manufactured on a float or similar glass process
, & .icient cheap stable product
, ( - /ies on proven low cost $1 4 m2) manufacturing
, - .ss coupled with high performance surface mounted Si solar cells
/ . % .sently US glass capacity is 6M MT yr Running at 85 capacity
% . / .aining 15 US glass capacity equivalent to solar cell production of 13 5GW year
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GLASS IS LOCALLY MANUFACTURED
Like other building materials, manufacturing cost often less than shipping cost.
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glass
air
air
Use photons to transfer energy
:Simple construction dye in or on waveguide( )glass
solar radiation
dye
photoluminescence
PV PV
W. H. Weber and J. Lambe, Applied Optics 15, 2299 (1976)A. Goetzberger, W. Greubel, Applied Physics 14, 123 (1977)
- -A NON TRACKING GLASS BASED CONCENTRATOR – THE LUMINESCENT SOLAR CONCENTRATOR
wo fundamental parameters :η PL : ( /the photoluminescent efficiency of the dye photons out photons
)inη trap : (the trapping efficiency fraction of emitted photons confined
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e examples of luminescent solar concentration
- . .Our lab proto types are 10x10x0 1cm For ,characterization we attach a Sunpower Si PV cell
to one edge
ey m e t r i c s
G = ( )geometric gain area of face divided by area of edges
F = .flux gain Geometric gain corrected for losses in the collector
, , , & . .,Currie Mapel Heidel Goffri M B Science 3 2 1 , ( 226 2
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absorption emission
[ Wavelength λ ]
,
a b
s o
r p
t i
o n
e m
i s s
i o
n
Band gap
2
absorption emission
[ Wavelength λ ]
,
a b
s o
r p
t i
o n
e m
i s s
i o
n
Band gap
3
Solar cell 1
Solar cell 2
Solar cell 3
.abs emission
[ Wavelength λ ]
,
a
b s o
r p
t i
o n
e
m i
s s
i o
n
Band gap
1
‘ ’MULTIJUNCTIONS USING LUMINESCENT SOLAR CONCENTRATORS
. & ’Passive system that concentrates diffuse light doesn t need to track the su
. .2 Higher solar cell voltages due to increase in optical concentration
. : ’3 Lower the cost Don t use expensive semiconductors simply to gather light
. ~ = .1 Each solar cell pumped monochromatically at band edge minimal heating
. -5 Smoothes out non uniform optical excitation
.6 Tolerant of fabrication defects
Advantages
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: .Bullets 0 17 HMR FMJ( .)2375fps 4 mm diam
&Shot from an H R
~ .rifle at 50 feet
Optical concentrators show loss near bullet,hole
but light collection at.edges remains strong
…MORE ROBUST THAN CONVENTIONAL PV BULLET DAMAGE TESTS
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( & )BUILDING INTEGRATED APPLICATIONS WINDOWS SKYLIGHTS
(Luminescent concentrators have better aesthetics color tunability and image).transmission
.No need for metal oxide transparent contacts
: - ‘ ’Existing technology semitransparent a Si or waffle windows
- %a Si typically 6 efficiency% . .10 transmission Very expensive
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and Yb +3 is well known solid state laser material, ( >evel system very transparent to own radiation expect concentration factors 10
-RARE EARTH BASED SOLAR CONCENTRATORS FOR SI SOLAR CELLS(with Harry Tuller, MIT DMSE)
100
80
60
40
20
0
( % )
E x
t e
r n
a l
Q u
a n
t u
m
E f f i
c i
e n
c y
400 500 600 700 800 900 1000 1100 1200
( ) Wavelength nm
300
Sunpower EQE
:Nd glassabsorption
:Nd glassemission
.Needs sensitization to complete spectral coverage
. ( -sion compatible with high performance Si solar cells much cheaper than III V c
.Extremely robust and stable
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evelopment of Nd laser glass was driven( ) .y National Ignition Facility NIF
. , = ,NIF now contains approx 10 000 pieces 3 000m2
-of Nd based glass
‘ ’Nd is a rare earth but actually Nd is the 27th most abundant material in
’earth s crust(~ & )half as abundant as copper zinc
Nd2O3 ( ) . / % .the relevant form is approx $10 kg at 99 purity
,Annual production 15 000 t
> %.nsitization the expected power efficiency 10.e competitive with First Solar CdTe solar cells
- …NEODYMIUM BASED SOLAR CONCENTRATORS FOR SI SOLAR CELLS cont
…looks practical
Beam lines at the NIF
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absorption
totalemission
edgeemission
faceemission
ation spectrum of Nd + % in phosphate glass
O p
t i
c a l
q u
a n
t u m
e f f i
c i e
n c y
.1 0
.0 8
.0 6
.0 4
.0 2
.0 0
( ) Wavelength nm800 900700600500
:DATA Nd +3 phosphate glass
~ %Observed quantum yield 90
~ %Power efficiency only 3 due to poor overlap with solarspectrum
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DATA
Projected power efficiency
E x
t e
r n
a l
q u
a n
t u m
e f f i
c i
e n
c y
.0 3
.0 5
.0 4
.0 6
.0 7%15
%13
%11
%9
%7
%5
Geometric Gain0 50 100 150 200500 600 700 800 900
0
5
10
15
20
25
( ) Wavelength nm
(
A b
s o
r p
t i
o n
c o e
f f
i
c i
e n
t
c m
- 1 ) - ,Sensitized Nd glass 4 mm thick
400
PROJECTIONS
Sensitized glass
700 800 900 1000
2000
4000
6000
8000
Wavelength (nm)
Coun
ts(a
.u.)
Sensitizer luminescence
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CONCLUSIONS
•Separate solar energy conversion into optical and electrical parts.••Use conventional solar cells for electrical part.
••Pre-process sunlight using excitonic systems & materials
absorption emission
[ Wavelength λ ]
,
a b
s o
r
p t
i o
n
e m
i s s
i o
n
Band gap 2
absorption emission
[ Wavelength λ ]
,
a
b s o
r p
t i
o n
e
m i
s s
i o
n
Band gap
3
Solar cell 1
Solar cell 2
Solar cell 3
.abs emission
[ Wavelength λ ]
,
a b
s o
r p
t i
o n
e m
i s s
i o
n
Band gap
1
ample : ‘ ’Multijunctions using luminescent solar concentrator
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Use metric $/W p :
(cost of PV cell divided by power
generated at peak solar illumination)
Best option? Improve efficiency. 1% increase in efficiency = $0.10 / W pIncluding installation costs: 1% increase in efficiency > $0.30 / W p
New semiconductors/fabrication techniques alone will not achieve large cost savings.
PV cost$
p
p
W
Lη
=
WHAT ABOUT CHEAP BUT LOW EFFICIENCY SOLAR CELLS?
η p: power efficiency
L: solar power
Example:The CdTe process at First Solar
(>300 MW/year of 10% modules, throughput = 4µ m thick films every 40s)
* See Zweibel, Solar Energy Materials & Solar Cells, 59, 1-18 (1999)† Latest production data from First Solar
CdTe associated costs < 10% of manufacturing cost.Remainder dominated by substrate (glass) and module costs (labor, wiring etc..).
Capital cost of CdTe evaporation = $0.04/W p* Semiconductor cost = $0.04/W p*
shipping crate = $0.02/W p*
Total manufacturing cost = $1.00/W p†