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Biochar Characterization Source Material pH Particle Size Density % carbonization Pore size &...

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Biochar Biochar Characterization Characterization Source Material Source Material pH pH Particle Size Particle Size Density Density % carbonization % carbonization Pore size & Pore size & density density Proximate Proximate analysis analysis minerals (ash) minerals (ash) PAHs PAHs Using Biochar in Soil Using Biochar in Soil physical & chemical physical & chemical properties properties Standards Standards product identity & product identity & integrity integrity Industry Industry National National International International click to continue
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Page 1: Biochar Characterization Source Material pH Particle Size Density % carbonization Pore size & density Proximate analysis minerals (ash) PAHs Using Biochar.

BiocharBiocharCharacterizationCharacterization

Source MaterialSource MaterialpHpHParticle SizeParticle SizeDensityDensity% carbonization% carbonizationPore size & densityPore size & densityProximate analysisProximate analysisminerals (ash)minerals (ash)PAHsPAHs

Using Biochar in SoilUsing Biochar in Soil

physical & chemical propertiesphysical & chemical properties

StandardsStandardsproduct identity & integrityproduct identity & integrity

IndustryIndustryNationalNational

InternationalInternationalclick tocontinue

Page 2: Biochar Characterization Source Material pH Particle Size Density % carbonization Pore size & density Proximate analysis minerals (ash) PAHs Using Biochar.

Toxicity TestsToxicity Tests

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Earthworm AvoidanceEarthworm AvoidanceMore sensitive and reliableMore sensitive and reliablePrepare soil + biochar blendPrepare soil + biochar blendContainer: half with soilContainer: half with soilhalf soil + biocharhalf soil + biochar10 earthworms introduced10 earthworms introducedAfter 48 hours: count worms in each halfAfter 48 hours: count worms in each halfRigorous test requires replicationsRigorous test requires replications

SeSeed Germinationed GerminationRecommended species:Recommended species:

lettuce, radish, cloverlettuce, radish, cloverTwo (or more) traysTwo (or more) traysPrepare soil + biochar blend(s)Prepare soil + biochar blend(s)One tray: soil onlyOne tray: soil onlyother(s): soil + biochar blend(s)other(s): soil + biochar blend(s)Spread equal number of seeds on all Spread equal number of seeds on all trays; at least 20/traytrays; at least 20/trayGerminate in uniform conditionsGerminate in uniform conditionsCompare germination ratesCompare germination rates

Using Biochar in SoilUsing Biochar in Soil

Page 3: Biochar Characterization Source Material pH Particle Size Density % carbonization Pore size & density Proximate analysis minerals (ash) PAHs Using Biochar.

JOINJOIN IBI Field Trial RegistryIBI Field Trial Registryall data provided will be all data provided will be

open open and accessible to the and accessible to the

publicpublic

4-page 4-page Data FormData Formfor the for the Biochar Trial RegistryBiochar Trial Registry

to record field trial conditions & data to record field trial conditions & data Appendix: IBI Guide to Field TrialsAppendix: IBI Guide to Field Trials

available soon in electronic formavailable soon in electronic form

use IBI Data Form for experimentsuse IBI Data Form for experimentswhether you join Registry or notwhether you join Registry or not

Biochar Trial RegistryBiochar Trial RegistryInternational Biochar Initiative (IBI)International Biochar Initiative (IBI)

contact:contact:Dr. Julie MajorDr. Julie MajorIBI Extension DirectorIBI Extension [email protected]@biochar-international.org

for updates, see IBI website: for updates, see IBI website: www.biochar-international.orgwww.biochar-international.org

Using Biochar in SoilUsing Biochar in Soil

Page 4: Biochar Characterization Source Material pH Particle Size Density % carbonization Pore size & density Proximate analysis minerals (ash) PAHs Using Biochar.

MoistureMoistureInitially, fresh char is hydrophobic = repels waterInitially, fresh char is hydrophobic = repels water

Quench, sprinkle or spray for safety and reduced particle Quench, sprinkle or spray for safety and reduced particle sizesizeSteam – immediately after burn, create live steamSteam – immediately after burn, create live steamFracture (pop open) micropore matrix = activationFracture (pop open) micropore matrix = activationUrineUrine

(poop)(poop)

(pee)(pee)

compost toilet instead of water-borne sewagecompost toilet instead of water-borne sewageclick tocontinue

Preparing BiocharPreparing BiocharUsing Biochar in SoilUsing Biochar in Soil

MineralsMineralsCation & Anion adsorption capacity as delivery mediaCation & Anion adsorption capacity as delivery mediaMineral mix tailored to target soilMineral mix tailored to target soilMajor Minerals: Ca, P – also NMajor Minerals: Ca, P – also Nespecially trace elements as in sea mineralsespecially trace elements as in sea minerals

MicronizedMicronizedMicrobial-scale mixing: more than surface areaMicrobial-scale mixing: more than surface areaMaximum physical intimacyMaximum physical intimacy

MicrobesMicrobesInoculationInoculation: seeding fully functional microbial complexes: seeding fully functional microbial complexescompost, compost tea, BD preps, EM, mycorrhizae, etc.compost, compost tea, BD preps, EM, mycorrhizae, etc.Nitrogen-fixing bacteriaNitrogen-fixing bacteriaNightsoilNightsoil

Page 5: Biochar Characterization Source Material pH Particle Size Density % carbonization Pore size & density Proximate analysis minerals (ash) PAHs Using Biochar.

Applying BiocharApplying BiocharRatesRates9% carbon, 6 feet deep = 10 – 20 tons/acre9% carbon, 6 feet deep = 10 – 20 tons/acrePractical: 1 to 5 tons/acrePractical: 1 to 5 tons/acreGradual, successive, cumulative applicationsGradual, successive, cumulative applicationsStrong response with small initial applicationsStrong response with small initial applicationsInoculated charInoculated char: few hundred lbs/acre – : few hundred lbs/acre – VaTech tomatoes 2009VaTech tomatoes 2009

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Using Biochar in SoilUsing Biochar in Soil

MethodsMethodsbroadcast, band, planting hole, top-dressbroadcast, band, planting hole, top-dressBlended with other moist materials – especially compostBlended with other moist materials – especially compostIntimate contact with seedling rootlets & root zoneIntimate contact with seedling rootlets & root zone

Mixing & TillageMixing & TillageStrive for uniform coverage – esp. with field trialsStrive for uniform coverage – esp. with field trialsKey is root zone; top 6 inches for vegetablesKey is root zone; top 6 inches for vegetablesSimple surface broadcast is effective; biochar migrates downSimple surface broadcast is effective; biochar migrates down

TimingTimingInoculationInoculation: seeding fully functional microbial complexes: seeding fully functional microbial complexesAllow incubation & culturing time: at least two weeksAllow incubation & culturing time: at least two weeksFull ripening & aging may require longer: up to 6 monthsFull ripening & aging may require longer: up to 6 months

Page 6: Biochar Characterization Source Material pH Particle Size Density % carbonization Pore size & density Proximate analysis minerals (ash) PAHs Using Biochar.

Handling & TransportHandling & TransportBiochar is very light, completely dry, low density, brittle Biochar is very light, completely dry, low density, brittle

Even if not fine-grained, usually contains a fine powder fractionEven if not fine-grained, usually contains a fine powder fraction

biochar blowing off biochar blowing off in transport and tillage in transport and tillage

photos courtesy of Blue Leaf, Inc.photos courtesy of Blue Leaf, Inc.St-François-Xavier-de-Brompton, QuébecSt-François-Xavier-de-Brompton, Québec

www.blue-leaf.cawww.blue-leaf.ca

Using Biochar in SoilUsing Biochar in Soil

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Special care required to transport and spread biocharSpecial care required to transport and spread biochar Risk of accidental ignition with some biocharRisk of accidental ignition with some biocharWill blow away while you measure, transport, apply, and incorporateWill blow away while you measure, transport, apply, and incorporateCommercial products moistened before shipping Commercial products moistened before shipping (increases product weight)(increases product weight)

Dust problems controlled by adding water, mix with clay slurry, Dust problems controlled by adding water, mix with clay slurry, pellets, agglomerate, prill with binderpellets, agglomerate, prill with binder

Incorporate into soil to minimize wind erosion and runoff after rainIncorporate into soil to minimize wind erosion and runoff after rainDevelop local systems to produce, store and transport biocharDevelop local systems to produce, store and transport biochar

Page 7: Biochar Characterization Source Material pH Particle Size Density % carbonization Pore size & density Proximate analysis minerals (ash) PAHs Using Biochar.

Humus into Humic acids (10–15% of original organic carbon)Humus into Humic acids (10–15% of original organic carbon)Super-stable form of carbon: 8 to 10% of soil carbonSuper-stable form of carbon: 8 to 10% of soil carbonIndigestible complex carbon moleculesIndigestible complex carbon moleculesExtremely large carbon molecules: tens to hundreds of carbon atomsExtremely large carbon molecules: tens to hundreds of carbon atomsHeld together by subtle inter-atom electromagnetic forces: Held together by subtle inter-atom electromagnetic forces: hydrogen bonds, vander Walls, hydrophobicityhydrogen bonds, vander Walls, hydrophobicityFulvic (alkali) versus Humic acids (acid)Fulvic (alkali) versus Humic acids (acid)Structural and chemical interactions with charred carbonStructural and chemical interactions with charred carbon

supra-moleculessupra-molecules

GlomalinGlomalin

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mega-structuresmega-structuresIsolated & identified in 1996 by USDA ARS scientist Sara F. WrightIsolated & identified in 1996 by USDA ARS scientist Sara F. WrightGlomalesGlomales species of arbuscular mycorrhizal fungi species of arbuscular mycorrhizal fungi

excretions of hyphal threads, or tubesexcretions of hyphal threads, or tubesGlycoprotein: sugar + amino acid = 30 – 40% carbonGlycoprotein: sugar + amino acid = 30 – 40% carbonGlue “aggregates” soil particles into larger structuresGlue “aggregates” soil particles into larger structuresSuper-stable form of carbon: up to 27% of soil carbonSuper-stable form of carbon: up to 27% of soil carbonWeighs 2 to 24 times more than humic acidsWeighs 2 to 24 times more than humic acids7 to 42 year recalcitrance7 to 42 year recalcitrance

Organic Matter InteractionsOrganic Matter InteractionsHumic AcidsHumic Acids

Using Biochar in SoilUsing Biochar in Soil

Page 8: Biochar Characterization Source Material pH Particle Size Density % carbonization Pore size & density Proximate analysis minerals (ash) PAHs Using Biochar.

““Carbon sequestration in soil has significant potential. Carbon sequestration in soil has significant potential.

““Biochar produced in pyrolysis of residues from crops, Biochar produced in pyrolysis of residues from crops, forestry and animal wastes can restore soil fertility forestry and animal wastes can restore soil fertility while storing carbon for centuries to millennia. while storing carbon for centuries to millennia.

““Biochar helps soil retain nutrients and fertilizers, Biochar helps soil retain nutrients and fertilizers, reducing GHG emissions such as Nreducing GHG emissions such as N22O. O.

““Replacing slash-and-burn agriculture with slash-and-char,Replacing slash-and-burn agriculture with slash-and-char,using farm and forestry wastes for biochar productionusing farm and forestry wastes for biochar production

can provide COcan provide CO22 drawdown drawdown of ~8 ppm or more in half a centuryof ~8 ppm or more in half a century.”.”

Carbon SequestrationCarbon SequestrationCarbon Negative Potential of Biochar

Dr. James HansenDr. James Hansenleading NOAA Climate Scientistleading NOAA Climate Scientistwww.GlobalClimateSolutions.orgwww.GlobalClimateSolutions.org

August 2008August 2008

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Using Biochar in SoilUsing Biochar in Soil

Page 9: Biochar Characterization Source Material pH Particle Size Density % carbonization Pore size & density Proximate analysis minerals (ash) PAHs Using Biochar.

THE END

Anybody want to make Anybody want to make biochar this winter?biochar this winter?

will people buy it?will people buy it?

are you readyare you readyfor the nextfor the next

PARADIGM SHIFT?PARADIGM SHIFT?

Page 10: Biochar Characterization Source Material pH Particle Size Density % carbonization Pore size & density Proximate analysis minerals (ash) PAHs Using Biochar.

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