ANNUAL GROUNDWATER MONITORING REPORT
BROOKS PHARMACY PLAZA (former Buffum's Supermarket) 112 ROCMNGHAM STREET
BELLOWS PALLS, VERMONT SMS site #2001-2855
Phase (check one) Type (Check one)
Prepared for:
0 Corrective Action Feasibility Investigation a Corrective Action Plan Corrective Action Summary Report Operations and Monitoring Report
Connor Contracting Attn: John Connor
110 US RT2 Berlin, Vermont 05602
Work Scope [XI Technical Report
PCF Reimbursement Request General Correspondence
PREPARED BY:
ENVIRONMENTAL COMPLIANCE SERVICES, INC. 30 HARRIS PLACE; BRATTLEBORO, VT 05301
802-257-1195 FAX: 802-257-1603 www.ecsconsult.com
30 H A R R I S PLACE BRATTLEBORO, VT 05301
802-257- 1 1 95 FAX: 802-257- 1 603
WWW.ECSCONSULT.COM
March 2 1,2005 Project: 04-203297.00 File: Annual2004
Mr. Gerold Noyes, Project Manager Sites Management Section VT DEC Waste Management Division 103 South Main Street Waterbury, VT 0567 1-0404
RE: Annual Groundwater Monitoring Report Brooks Pharmacy Plaza (former Buffurn's Supermarket) 1 12 Rockingham Street Bellows Falls, VT SMS site #2001-2855
Dear Mr. Noyes:
This Annual Groundwater Report for the above referenced Site was prepared by Environmental Compliance Sefvices, Inc. (ECS) of Brattleboro, Vermont, on behalf of Conner Contracting, who is working for Brooks Pharmacy. A Site Location Map is provided as Figure 1. Groundwater sampling activities were conducted in accordance with the VTDEC approval of the scope of work presented in a work plan 04-P-0 123V dated December 13,2004, prepared by ECS.
Groundwater samples were collected on February 16, 2005, and submitted to Spectrum Analytical, Inc. of Agawam, Massachusetts. The groundwater sampling log for the February 16, 2005 sampling event and the laboratory analytical data is provided in Attachment I. A summary of relevant site conceptual model information and a discussion of the 2004 groundwater contaminant trends are summarized below.
ACTIVITY SUMMARY FOR MONITORING PERIOD
Monitoring Period: 2004
Dates of Sampling Events and Wells Sampled:
February 16,2005
Groundwater Sampling Method:
Laboratory Analvtical Method:
Data Validation:
HEI- 1 R
Hand-bailing: using disposable PVC bailers.
Volatile Organic Compounds (VOCs) by EPA Method 802 1 8 (VT VOC Scan).
The data collected was determined to be valid based on the evaluation of laboratory Quality Assurance/Quality Control (QAJQC) data and chain of custody conditions.
HADDAM, CT TAMPA. FL AGAWAM. MA AUBURN, MA WAKEFI ELD, BOW, NH MARION, N Y BRATTLEBORO, V T RICHMOND, V T
Mr. Gerold Noyes VT DEC W D SMS March 2005
Groundwater Flow Direction:
Brooks Pharmacy Plaza former Buflum 's Supermarket)
112 Rockingham St., Bellows Falls, VT VT DEC SMS Site # 2001-2855
Groundwater flow was reported to be in an east- southeasterly direction toward the Connecticut River, based on previous investigations by Griffin International.
Light Non-Aqueous Phase Liquid (LNAPL): None observed.
Dissolved VOC Concentrations:
February 16,2005 Vermont Primary Groundwater Quality Standards (PGQS) for ethylbenzene, napthalene, and 1,2,4 and 1,3,5 trimethylbenzenes were exceeded in the sample collected from HEI-1R. A summary of laboratory analytical data from monitoring well HEI-1R is included in Table 1.
The Brooks Pharmacy Plaza is located on Rockingham Street in Bellows Falls, Vermont. The site is abutted immediately to the south by a gasoline station; to the west-southwest by a steep undeveloped/wooded hillside; to the north by Williams Street, across which is another gasoline station; on the east by Rockingham Street, across which are located (north to south)' a restaurant, antique shop, and pub. Behind (east of) the restaurant, antique shop, and pub is a steep grade down to Canal Street, with the Connecticut River beyond. The site is served by municipal water supply and sewer system.
ECS took over the project from the defunct Griffin Lnternational after approval of the ECS work plan in December 2004. On January 3, 2005, ECS personnel arrived onsite to find that monitoring wells HEI-1, - 3, -4 and -5 had apparently been paved over. ECS personnel returned to the site on January 13, 2005 in order to determine the status of monitoring wells and whether or not repair was possible. The monitoring wells were found to have been filled with grout making simple repair impossible.
ECS gained approval from VT DEC to replace monitoring well HEI-1 only. Replacement of the other three monitoring wells for the purpose of continued monitoring of groundwater flow direction was deemed unnecessary.
Monitoring well HEf-1R was installed by ECS on February 4, 2005 (See the Boring Log in Attachment I11 for well construction detail, soil descriptfons, soil screening results, etc.). Groundwater sampling of HEI-1R occurred approximately 2 weeks later (See Groundwater Sampling Log in Attachement I).
Visual and olfactory evidence of soil and groundwater contamination was observed (during monitoring well replacement) in the split spoon samples collected from 40'-42' and 45'-47' below ground surface depth ranges.
Vermont Primary Groundwater Quality Standards (PGQS) were exceeded in the groundwater sample from monitoring well HEI-1R.
Mr. Gerold Noyes VT DEC WMD SMS March 2005
Brooks Pharmacy Plaza Cfomer Buflum 's Supermarket)
11 2 Rockingham St., Bellows Falls, VT VT DEC SMS Site # 2001-2855
Continued biennial (every 2 years) sampling of HEI-IR, with the next sampling event scheduled for spring of 2007.
If you have any questions or comments regarding this report, please contact the Brattleboro, Vermont office of ECS.
Sincerely, ENVIRONMENTAL COMPLIANCE SERVICES, INC.
Randa 1 K m
Bruce Tease, PhD, LSP, NHPG Branch Manager1 Senior Environmental Scientist
cc: Conner Contracting
FIGURES :
Figure 1 Site Locus Map Figure 2 Site Plan
TABLES:
Table 1 Summary of Groundwater Table Elevation and Laboratory Analysis
ATTACHMENTS:
Attachment I Groundwater Sampling Log and Analytical Laboratory Report Attachment I1 Photographs Attachment 111 Boring log for monitoring well HEI-1R
FIGURES
Environmental Compliance Senrices, Inc.
30 Harrls Place, Brattleboro, VT 05301
Phone (802)-257-1195 Fax (802)-257-1603
1 ~ 0 b Number: 04-203297 1
Brooks Pharmacy (former Buffum's Supermarket)
112 Rockingham Street Bellows Falls (Rockingham), VT
05101 1
1 1 - - - - - 112 0 1 Mile
1 inch = 1500 feet North Contour Interval: 6 Meters
Base Map: U.S. Geological Survey; Quadrangle Location: Bellows Falls, VT
UTM Coordinates: 18 0707487 East / 4778877 Notth
Map Edited: 1985 Map Revised: none Generated By: rek
I
TABLE I
F:\data\projects\04-203001 to 203500\04-203297 Brooks Pharmacy bienial site Bellows Falls\VOC&GWELEVMASTER
former Buffim's Supermarket
112 Rockingham Street
Bellows Falls, VT
Table 1 Summary of Groundwater Elevation Data and
Analytical Results of Groundwater at Monitoring Well HEI-1 R Results reported in micrograms per liter
Bold, highlighted results are reported 2 ~ncentratlons in excess of Vei ldards (PG Shaded results indicate laboratory me1 I detection limits are above Vc Standards (PGQI NA= Information Not Available ND= Not Detected above method detection limit NT = Not Tested (for specific analyte) NS = Not Sampled
ATTACHMENT I =
==01 ME)
Report Date: 01-Mar-05 13:35
SPECTRUM ANALYTICAL, INC. Featuring
HANIBAL TECHNOLOGY
/' Final Report Re-Issued Report Revised Report
Laboratory Report Environmental Compliance Services 30 Harris Place Project: Brooks Pharmacy - Bellows Falls, VT Brattleboro, VT 05301 Project #: 04-203297.00 Attn: Bruce Tease
Laboratory ID Client Sample ID Matrix Date Sampled Date Received SA24450-0 1 HEI- 1 R Ground Water 16-Feb-05 14: 17 17-Feb-05 15:OO SA24450-02 Trip Deionized Water 16-Feb-05 07:07 17-Feb-05 15:OO
I attest that the information contained within the report has been reviewed for accuracy and checked against the quality control requirements for each method. All applicable NELAC requirements have been met. Please note that this report contains 6 pages of analytical data plus Chain of Custody document(s). This report may not be reproduced, except in full, without written approval from Spectrum Analytical, Inc.
Massachusetts Connecticut # PH-0777 Certification # M-MA 138lM.4 1 1 10
a r i i : +
Florida # E876001E87936 Maine # MA 13 8 c'-
New Hampshire # 253812972 New York # 1 139311 1840 Rhode Island # 98 al . ayeh, Ph.D. USDA # S-5 143 5 Vermont # VT- 1 1393
~residen'tn oratory Director ae Spectrum Analytical, Inc, is a NELAC accredited laboratory organization and meets NELAC testing standards. Use ofthe NELAC logo however does not insure that Spectrum is currently accreditedfor the spec$c method indicated. Please refer to our "Quality" webpage at www.spectrum-analytical.com for a full listing of our current certrfications.
11 Almgren Drive a Agawam, Massachusetts 01001 a Operational Building & Sample Receiving 830 Silver street * Agawam, Massachusetts 01001 *Administrative Offices, Volatile & Air ~ e ~ a r t m e n t s
1-800-789-9115 0 413-789-9018 Fax 413-789-4076 Page 1 of 6
Sample Identification HEI-1R SA24450-0 1
Client Proiect # Matrix Collection DateITime Received 04-203297.00 Ground Water 16-Feb-05 14: 17 17-Feb-05
CAS No. Analvte(s) Result *RDIJUnits Dilution Method Ref: Prepared Analyted Batch Analvst Flag
Volatile Organic Compounds Volatile Organic Cornoounds bv 82608
71-43-2 Benzene BRL 100-41-4 Ethy lbenzene 1,170 ~ d 4 - 0 4 - 4 Methyl tert-butyl ether BRL 91-20-3 Naphthalene 454
108-88-3 Toluene BRL
95-63-6 I ,2,4-Trimethylbenzene 6,420 108-67-8 1,3,5-Trimethylbenzene 2,420
1330-20-7 m,p-Xylene 3,560
95-47-6 o-Xy lene - .- - -- -
475 - -
Surrogate recoveries: 460-00-4 4-Bromoj7uorobenzene 141
2037-26-5 Toluene-dB 103
17060-07-0 1.2-Dichloroethne-d4 109 1868-53-7 Dibromofluorornethane 107
Prepared by method Volatiles R-05
50.0 ug/l 50 SW846 8260B 25-Feb-05 25-Feb-05 50213 15 KL
50.0 ug/l 50 8
50.0 ug/l 50
50.0 ugll 50
50.0 ug/l 50 I I*
50.0 u ~ / I 50 t
50.0 udl 50
100 ug/l 50
50.0 ug/l 50 - -
70-130 % 1 " S-02
70-130 %
70-130 %
70-130 %
--
F This laboratory report is not valid without an authorized signature on the cover page.
* Reportable Detection Limit BRL = Below Reporting Limit Page 2 of 6 t 4
Sam~le Identification Trip SA24450-02
Client Proiect # Matrix Collection DatelTime Received 04-203297.00 Deionized Water 16-Feb-05 07:07 17-Feb-05
CAS No. Analyte(s) Result *RDL/Units Dilution Method Ref: Prepared Analyzed Batch Analyst Flag
Volatile Organic Compounds Volatile Organic Comuounds bv 8260B Prepared by method Volatiles
7 1-43-2 Benzene BRL 1.0 ug/l 1 SW846 8260B 25-Feb-05 25-Feb-05 5021315 KL
100-4 1-4 Ethy lbenzene BRL 1.0 ug/l I ,1
1634-04-4 Methyl tea-butyl ether BRL 1 .O ug/l I
91-20-3 Naphthalene BRL 1 .O ug/l 1
108-88-3 Toluene BRL I .O ug/l I !* I9
95-63-6 1,2,4-Trimethy lbenzene BRL 1.0 ug/l I
108-67-8 1,3,5-Trimethylbenzene BRL 1 .O ug/l 1
BRL 2.0 ugll I 1330-20-7 m,p-Xylene
BRL 1.0 ug/l I 95-47-6 o-Xylene
Surrogate recoveries: 100 70-130 % 460-00-4 4-BromoJuorobenzene ,, ,
2037-26-5 Toluene-d8 100 70-130 % ,#
17060-07-0 1,2-Dichloroethane-d4 103 70-130 %
18-58-53-7 Dibromoj2uorornethane 103 70-130 % ! , ,
This laboratory report is not valid without an authorizedsignature on the coverpage.
* Reportable Detection Limit BRL = Below Reporting Limit Page 3 of 6
Volatile Organic Compounds - Quality Control
Spike Source %REC RPD Analyte(s) Result *RDL Units Level Result %REC Limits RPD Limit Flag
Batch 5021315 - Volatiles Blank (50213 15-BLKI)
Benzene Ethylbenzene Methyl tert-butyl ether Naphthalene Toluene
1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene mp-Xy lene o-Xvlene
BRL BRL BRL BRL BRL BRL BRL BRL BRL
Prepared & Analyzed: 25-Feb-05
1.0 ugn 1.0 ug/l 1 .o ug/l 1 .o ug/l 1.0 ug/l 1.0 ug/l 1.0 ug/l 2.0 ug/l 1.0 u d l
Surrogate: 4-Bromofluorobenzene 27.9 ug/l 30.0 93.0 70-130 Surrogate: Toluene-dB 29.3 ug/l 30.0 97.7 70-130 Surrogate: 1,2-Dichloroethane-d4 29.2 ug/l 30.0 97.3 70-130 Surrogate: Dibromojluoromethane 30.7 ug/l 30.0 102 70-130
LCS (5021315-BS~) Prepared & Analyzed: 25-Feb-05
Benzene 21.8 ug/l 20.0 ' 109 70-130 Ethylbenzene 21.5 ug/! 20.0 108 70-130 Methyl tert-butyl ether 19.5 ug/l 20.0 97.5 70-130 Naphthalene 22.2 ug/l 20.0 111 70-130 Toluene 22.3 ug/l 20.0 112 70-130 1,2,4-Trimethy lbenzene 22.3 ug/l 20.0 112 70-130
1.3.5-Trimethy lbenzene 22.0 u d l 20.0 110 70-130
m,p-Xylene 44.4 ug/l 40.0 111 70-130 o-Xylene 21.8 u f l 20.0 109 70-130
Surrogate: 4-Bromofluorobemene 29.1 ug/l 30.0 97.0 70-130 Surrogate: Toluene-dB 30.0 ug/l 30.0 100 70-130 Surrogate: 1,2-Dichloroethane-d4 28.8 ug/l 30.0 96.0 70-130 Surrogate: Dibromojluoromethane 30.5 ug/l 30.0 102 70-130
LCS D u p (5021315-BSD1) Prepared & Analyzed: 25-Feb-05
Benzene 22.3 ug/l 20.0 112 70-130 2.71 30 Ethylbenzene 22.3 ug/l 20.0 112 70-130 3.64 30 Methyl ten-butyl ether 33.7 ugn 20.0 168 70-130 53.1 30 QC-l Naphthalene 22.2 ug/l 20.0 111 70-130 0.00 30 Toluene 23.6 ug/l 20.0 118 70-130 5.22 30 1,2,4-Trimethy lbenzene 24.4 udl 20.0 122 70-130 8.55 30 1.3.5-Trimethylbenzene 23.7 ug/l 20.0 118 70-130 7.02 30 m,p-Xylene 46.5 ug/l 40.0 116 70-130 4.41 30
o-Xylene 23.0 ug/l 20.0 115 70-130 5.36 30
Surrogate: 4-Bromojluorobenzene 30.2 ug/l 30.0 101 70-130 Surrogate: Toluene-d8 31.0 ug/I 30.0 103 70-130 Surrogate: 1,2-Dichloroethane-d4 29.7 ug/l 30.0 99.0 70-130 Surrogate: Dibromofluoromethane 30.7 30.0 102 70-130
Matr ix S p i k e (5021315-MS1) Source: SA24434-13 Prepared & Analyzed: 25-Feb-05
Benzene 21.7 ug/l 20.0 BRL 108 70-130 Chlorobenzene 22.0 ud l 20.0 BRL 110 70-130
I, 1 -Dichloroethene 20.0 ug/l 20.0 BRL 100 70-130 Toluene 22.2 ug/l 20.0 BRL 1 1 1 70-130
Trichloroethene 20.9 ug/l 20.0 BRL 104 70-130
Surrogate: 4-Bromojluorobenzene 30.2 ug/l 30.0 101 70-130 Surrogate: Toluene-d8 29.6 ug/l 30.0 98.7 70-130 Surrogate: 1.2-Dichloroethane-d4 30.0 ug/l 30.0 100 70-130 Surrogate: Dibromojluoromethane 30 4 udl 30.0 101 70-130
Matr ix S p i k e D u p (5021315-MSDI) Source: SA24434-13 - Prepared & Analyzed: 25-Feb-05
r This laboratory report is no1 valid without an authorized signature on the cover page.
c d * Reportable Detection Limit BRL = Below Reporting Limit Page 4 o f 6
Volatile Organic Compounds - Quality Control
Spike Source %REC RPD Analyte(s) Result *RDL Units Level Result %REC Limits RPD Limit Flag
Batch 5021315 - Volatiles
Matrix Spike Dup (5021315-MSD1) Source: SA24434-13 Prepared & Analyzed: 25-Feb-05
Benzene 21.8 ug/l 20.0 BRL 109 70-130 0.922 30 Chlorobenzene l,l-Dichloroethene Toluene Trichloroethene
Surrogate: 4-Bromofluorobenzene
Surrogate: Toluene-d8
Surrogate: I , 2-Dichloroethane-d4
23.0 udl 20.0 BRL 115 70-130 4.44 30 19.7 441 20.0 BRL 98.5 70-130 1.51 30 22.8 20.0 BRL 114 70-130 2.67 30 21.5 ug/l 20.0 BRL 108 70-130 3.77 30
30.4 ug/l 30.0 101 70-130 30.3 ug/l 30.0 101 70-130
Surrogate: Dibromofluorornethane 26.0 udl 30.0 86.7 70-130
F- This laboratory report is not valid without an authorized signature on the cover page.
,I * Reportable Detection Limit BRL = Below Reporting Limit Page 5 of 6
Notes and Definitions
QC- 1 Analyte out of acceptance range.
R-05 The sample was diluted due to the presence of high levels of non-target analytes resulting in elevated reporting limits
S-02 The surrogate recovery for this sample cannot be accurately quantified due to interference from coeluting organic compounds present in the sample extract.
BRL Below Reporting Limit - Analyte NOT DETECTED at or above the reporting limit
dry Sample results reported on a dry weight basis
NR Not Reported
RPD Relative Percent Difference
A plus sign (+) in the Method Reference column indicates the method is not accredited by NELAC.
Laboratory Control Sample (LCS): A known matrix spiked with compound(s) representative of the target analytes, which is used to document laboratory performance.
Matrix Duplicate: An intra-laboratory split sample which is used to document the precision of a method in a given sample matrix.
Matrix Spike: An aliquot of a sample spiked with a known concentration of target analyte(s). The spiking occurs prior to sample preparation and analysis. A matrix spike is used to document the bias of a method in a given sample matrix.
Method Blank: An analyte-free matrix to which all reagents are added in the same volumes or proportions as used in sample processing. The method blank should be carried through the complete sample preparation and analytical procedure. The method blank is used to document contamination resulting from the analytical process.
Method Detection Limit (MDL): The minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero and is determined from analysis of a sample in a given matrix type containing the analyte.
Reportable Detection Limit (RDL): The lowest concentration that can be reliably achieved within specified limits of precision and accuracy during routine laboratory operating conditions. For many analytes the RDL analyte concentration is selected as the lowest non-zero standard in the calibration curve. While the RDL is approximately 5 to 10 times the MDL, the RDL for each sample takes into account the sample volume/weight, extracttdigestate volume, cleanup procedures and, if applicable, dry weight correction. Sample RDLs are highly matrix-dependent.
Surrogate: An organic compound which is similar to the target analyte(s) in chemical composition and behavior in the analytical process, but which is not normally found in environmental samples. These compounds are spiked into all blanks, standards, and samples prior to analysis. Percent recoveries are calculated for each surrogate.
Validated by: Hanibal C. Tayeh, Ph.D. Nicole Brown
This laboratory report is not valid without an authorized signature on the coverpage.
* Reportable Detection Limit BRL = Below Reporting Limit Page 6 of 6
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Site Name: ~ P U P ~ ~ R C J , [&PAW & % C J ~ C %W.L II'Le%tcl tA$HRIY S f w T
Location: &(rws Cat ( F State: U T
Rush TAT - Date Needed: CHAIN OF CUSTODY RECORD . All TATS subject to laboratory approval. Min. 24-hour notification needed for rushes.
SPEC1 R U M A N A L Y T I C A L INC. Feoturmg
Page 1 of Samples disposed of after 60 days unless HAKIBAL TECHNOLOGY otherwise instructed.
Report To: E c ~ - ~ (LAWCGD~U
Project Mgr.: 'tS , T E A % €
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Invoice To: EC< -&+JAM
1 =Na2S203 2=HC1 3=H2S04 4=HNO3 5=NaOH 6=Ascorbic Acid 7=CH30H 8= NaHS04 9= qbc ( _ i ~ u> 1 o=
DW=Drinking Water GW=Groundwater WW=Wastewater
project NO.: fi'l -( I ?qT. no - " 03
P.O. No.: RQN: Sampler(s): 2 . a ~ ~
Containers:
V1
Analyses:
C d
QA Reporting Notes: (check if needed)
State specific reporting standards Z d > C- >
4 j w 43
O=Oil SW= Surface Water SO=Soil SL=Sludge A=Air X1=T)iHln X2= X3=
G=Grab C=Composite
If applicable, please lisi below.
Provide MCP CAM Report Were all field QC requirements met as per MADEP CAM Section 2.0?
Yes No (Response required for CAMreport)
m Q) .- . d *
Lab Id: Z A ? t % t : 4 t
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Fax results when available to ( )
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ATTACHMENT I1 -
PHOTOS: Brooks Pharmacy Plaza - 112 Rockingham Street, Bellows Falls, VT
PHOTOS: Brooks Pharmacy Plaza - 112 Rockingham Street, Bellows Falls, VT
I PHOTOS: Brooks Pharmacy Plaza - 112 Rockingham Street, Bellows Falls, VT
Work performed: ( Square-cut asphalt in 2 previously identified monitoring well locations (patched asphalt)
Removed asphalt to find wells both wells had been packed with approximately W asphalt and Bentonite or some similar substance to and undetermined depth
[ Broke off approximately 5" of PVC riser and probed with a screwdriver to establish that well was packed with Bentonite to a depth of at least 7" (and presumably completely filled)
I Patched asphalt with concrete mixed with an additive to help concrete set up in cold weather
I PHOTOS: Brooks Pharmacy Plaza - 112 Rockingham Street, Bellows Falls, VT
1 Close-up of monitoring well HEI-4. Grey material is presumed to be Bentonite. r
Y
Rockingham St. (east) to south - 90 degree sweep
Brooks Pharmacy (former Buffum's Supermarket) ECS project #04-203297.00
2/4/05 - Monitoring well replacement -rek
ATTACHMENT 111 -
SOIL BORING and MONITORING WELL
See Site Plan
grey, flne, medium 5 coarse SAND.