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C. MELTING POINTS OF POLYMERS In the following …nguyen.hong.hai.free.fr/EBOOKS/SCIENCE AND...

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Molecular Melting Polymer weight point Refs. Cellulose, see Poly (1,4-P-D-glucose) * Poly(acetaldehyde) - , 2,2,2-trichloro- * Poly(acrylamide) 71.08 - , JV-docosyl- 379.67 68 1906 - , N-dodecyl- 239.40 -8 1906 - , N-hexadecyl- 295.51 45 1906 - , N-isopropyl- * - , W-octadecyl- 323.56 68 1906 - , N-tetradecyl- 267.46 18 1906 Poly(acrylic acid) 72.06 - , allyl ester * -,butyl ester 128.17 47 401 - , sec-butyl ester * -, tert-butyl ester * - , decyl ester 212.33 - , - 1,1-dihydroperfluoro- 554.15 100 1898 - , docosyl ester 380.66 72 1906 - , dodecyl ester 240.39 12 1906 - , hexadecyl ester 296.50 43 1906 - , isobutyl ester * - , isopropyl ester * - , octadecyl ester 324.55 56 1906 - , octyl ester 184.28 - , - , 1,1-dihydroperfluoro- 454.14 35 1898 - , tetradecyl ester 268.44 32 1906 Poly(acrylonitrile) * - , a-ethyl- 81.12 200 436 - , a-isopropyl- 95.14 310 436 - , a-propyl- 95.14 210 436 Poly(2,2 / -adipamidodibenzoic isophthalic anhydride) 514.49 225 1871 Poly(4,4'-adipamidodibenzoic isophthalic anhydride) 514.49 273 1871 Poly(2,2 / -adipamidodibenzoic terephthalic anhydride) 514.49 235 1871 Poly(4,4 / -adipamidodibenzoic terephthalic anhydride) 514.49 285 1871 Poly(adipic anhydride) 128.13 85 1840 98 1841 77 1564 Poly(adipoyl dithionisophthaloyldihydrazide) 336.43 280 1889 Poly(adipoyl ethylenediurea) 256.26 241 402 Poly(adipoyl octamethylenediurea) 340.42 290 402 Poly(adipoyl pentamethylenediurea) 298.34 222 402 Poly((3-alanine), see poly(3-aminopropionic acid) * Poly(allene) * - , tetrafluoro- * Poly(allylbenzene), see Poly(propene), 3-phenyl- * Poly(2-aminoacetic acid), see Poly(glycine) * Poly(m-aminobenzoic acid) 119.12 425 735 Poly(p-aminobenzoic acid) * Poly(3-aminobutyric acid) * Poly(4-aminobutyric acid) * PoIy(10-aminocapric acid) * Poly(6-aminocaproic acid) [caprolactam] * - , D-(-)-3-methyl- * - , 6-methyl- 127.19 185 402 References page VI-159 C. MELTING POINTS OF POLYMERS In the following table of melting points, entries are alphabetical according to the basic structure of the polymer, ignoring substituents. Substituted polymers are listed alphabetically (according to the substituent) under the entry for the unsubstituted polymer. The molecular weight is that of the chemical repeat (the constitutional base unit) in the polymer. Melting points (in 0 C) are taken from the reference cited. Melting points are presented in this table only for those polymers without (as yet) available crystallographic data: an asterisk (*) in the reference column signifies that the relevant melting point data is contained within the "Crystallographic Data" table of Section B. Previous Page
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Page 1: C. MELTING POINTS OF POLYMERS In the following …nguyen.hong.hai.free.fr/EBOOKS/SCIENCE AND ENGINEERING...Molecular Melting Polymer weight point Refs. PoIy(1,4-cyclohexylenedimethylene

Molecular MeltingPolymer weight point Refs.

Cellulose, see Poly (1,4-P-D-glucose) *Poly(acetaldehyde)- , 2,2,2-trichloro- *Poly(acrylamide) 71.08- , JV-docosyl- 379.67 68 1906- , N-dodecyl- 239.40 - 8 1906- , N-hexadecyl- 295.51 45 1906- , N-isopropyl- *- , W-octadecyl- 323.56 68 1906- , N-tetradecyl- 267.46 18 1906Poly(acrylic acid) 72.06- , allyl ester *-,butyl ester 128.17 47 401- , sec-butyl ester *- , tert-butyl ester *- , decyl ester 212.33- , - 1,1-dihydroperfluoro- 554.15 100 1898- , docosyl ester 380.66 72 1906- , dodecyl ester 240.39 12 1906- , hexadecyl ester 296.50 43 1906- , isobutyl ester *- , isopropyl ester *- , octadecyl ester 324.55 56 1906- , octyl ester 184.28- , - , 1,1-dihydroperfluoro- 454.14 35 1898- , tetradecyl ester 268.44 32 1906Poly(acrylonitrile) *- , a-ethyl- 81.12 200 436- , a-isopropyl- 95.14 310 436- , a-propyl- 95.14 210 436Poly(2,2/-adipamidodibenzoic isophthalic anhydride) 514.49 225 1871Poly (4,4'-adipamidodibenzoic isophthalic anhydride) 514.49 273 1871Poly(2,2/-adipamidodibenzoic terephthalic anhydride) 514.49 235 1871Poly(4,4/-adipamidodibenzoic terephthalic anhydride) 514.49 285 1871Poly(adipic anhydride) 128.13 85 1840

98 184177 1564

Poly(adipoyl dithionisophthaloyldihydrazide) 336.43 280 1889Poly(adipoyl ethylenediurea) 256.26 241 402Poly(adipoyl octamethylenediurea) 340.42 290 402Poly(adipoyl pentamethylenediurea) 298.34 222 402Poly((3-alanine), see poly(3-aminopropionic acid) *Poly(allene) *- , tetrafluoro- *Poly(allylbenzene), see Poly(propene), 3-phenyl- *Poly(2-aminoacetic acid), see Poly(glycine) *Poly(m-aminobenzoic acid) 119.12 425 735Poly(p-aminobenzoic acid) *Poly(3-aminobutyric acid) *Poly(4-aminobutyric acid) *PoIy(10-aminocapric acid) *Poly(6-aminocaproic acid) [caprolactam] *- , D-(-)-3-methyl- *- , 6-methyl- 127.19 185 402

References page VI-159

C. MELTING POINTS OF POLYMERS

In the following table of melting points, entries arealphabetical according to the basic structure of the polymer,ignoring substituents. Substituted polymers are listedalphabetically (according to the substituent) under theentry for the unsubstituted polymer. The molecularweight is that of the chemical repeat (the constitutionalbase unit) in the polymer. Melting points (in 0C) are taken

from the reference cited. Melting points are presented inthis table only for those polymers without (as yet) availablecrystallographic data: an asterisk (*) in the referencecolumn signifies that the relevant melting point data iscontained within the "Crystallographic Data" table ofSection B.

Previous Page

Page 2: C. MELTING POINTS OF POLYMERS In the following …nguyen.hong.hai.free.fr/EBOOKS/SCIENCE AND ENGINEERING...Molecular Melting Polymer weight point Refs. PoIy(1,4-cyclohexylenedimethylene

Molecular MeltingPolymer weight point Refs.

Poly(6-aminocaproic acid-a/Ml-aminoundecanoic acid) *Poly(8-aminocaprylic acid) *Poly(3-aminocyclobutylene)-propionic acid) 125.17- , 2,2-dimethyl- 153.22 358 1816Poly(4-aminocyclohexyleneacetic acid) 139.20 400 402Poly(aminodihexamethylene suberamide) 353.55 160 402Poly(aminoditrimethylene oxamide 185.23- , N-methyl 199.25 202 291Poly(22-aminodocosanoic acid) 337.59 145 177Poly(7-aminoenanthic acid) *- , (/0-3-methyl-- , (S)-4-methyl-- , (/?)-5-methyl-- , (/?)-6-methyl-- , Af-methyl- 141.21 65 1828Poly[p-(aminoethylene)-phenyleneacetic acid] 161.20 283 402Poly[/?-(aminoethylene)-phenylenebutyric acid] 189.26 224 402Poly[p-(aminoethylene)-phenylenepropionic acid] 175.23 382 402Poly[p-(aminoethylene)-phenylenevaleric acid] 203.28 275 402Poly(2-aminoethylenesulfonic acid) 107.13 275 1938Poly(17-aminoheptadecanoic acid) 267.46 150 292Poly(aminoformic acid) 43.02- , N- butyl-- , - , 2-methyl- 113.16 220 1909- , N-phenyl- 119.12 275 528Poly(/7-aminohydrocinnamic acid) 147.18 310 402

360 1911PoIy(12-aminolauric acid) *-,TV-methyl- 211.35 52 1929Poly[(3-aminomethylene)-cyclohexyleneacetic acid] 153.22- , 1,3-dimethyl- 181.28 297 1816Poly[/7-(aminomethylene)-phenyleneacetic acid] 147.18 355 402Poly[p-(aminomethylene)-phenylenebutyric acid] 175.23 267 402Poly[p-(aminomethylene)-phenylenepropionic acid] 161.20 300 402Poly[p-(aminomethylene)-phenylenevaleric acid] 189.26 233 402Poly(6-amino-4-oxacaproic acid) 115.13- , 3,5-dimethyl- 143.19 210 1902Poly(5-amino-3-oxavaleric acid) 101.10 148 402Poly(9-aminopelargonic acid) *Poly(3-aminopropionic acid) [p-alanine] *- , 2-butyl-2-methyl- *- , 2,2-dimethyl- , 2,3-dimethyl- 99.13

erythro 405 503threo 355 503

- , 3,3-dimethyl- 99.13 296 503- , 2-ethyl-2-methyl- *- , N-isopropyl- 113.16 130 1869- , Ar-methyl- 85.11 225 1863

202 1869- , 3-methyl-, see Poly(3-aminobutyric acid) *- , 2-methyl-2-propyl- *- , N-phenyl- 147.18 205 1869PoIy(18-aminostearic acid) *Poly(2-aminotetrahydropyran-6-carboxylic acid) *Poly(13-amino-ll-thiatridecanoic acid) 229.38 150 402PoIy(13-amino-12-thiatridecanoic acid) 229.38 150 402Poly(6-aminothiocaproic acid) 129.22 120 402Poly(7-aminothioenanthic acid) 143.25 235 402Poly(a-aminotoluic acid) 133.15 300 444PoIy(13-aminotridecanoic acid) 211.35 183 177Poly(3-aminotrimethylenesulfonic acid) 107.15 260 1932PoIy(11-aminoundecanoic acid) *-,tf-allyl- 223.36 350 402- , /V-ethyl- 212.36 - 3 0 402

Page 3: C. MELTING POINTS OF POLYMERS In the following …nguyen.hong.hai.free.fr/EBOOKS/SCIENCE AND ENGINEERING...Molecular Melting Polymer weight point Refs. PoIy(1,4-cyclohexylenedimethylene

Molecular MeltingPolymer weight point Refs.

- , 2-methyl- 197.32 130 402- , TV-methyl- 197.32 80 402- , N-phenyl- 259.39 - 3 0 402- , iV-piperazinyl- 267.42 142 402Poly(5-aminovaleric acid) *Poly(L-aspartic acid) 115.09- , oc-isobutyl ester *Poly(azelaic anhydride) 170.21 54 1823Poly(azelaoyl oxalodihydrazide) 270.29 260 402Poly (benzaldehyde-a/f-dimethylketene) 176.22 290 1817-,p-chloro- 210.66 260 1817- , p-methoxy- 206.24 240 1817- , m-nitro- 221.21 240 1817Poly(benzylidenethiodecamethylene sulfide) 294.52 135 1923Poly(benzylidenethiohexamethylene sulfide) 238.42 115 1923-,p-methoxy- 268.44 130 1923Poly(benzylvinyl ether) *Poly(4,4'-biphenyldicarboxaldehyde) 210.23 250 1801Poly(4,4/-biphenylene adipamide) 294.35 400 402Poly(4,4/-biphenylene adipate) 296.32 300 1901Poly(4,4'-biphenylene carbodiimine) 192.22 >300 1907- , 3,3'-dimethoxy- 220.27 190 1907Poly (4,4 '-biphenylene-4",4 "'-dibenzylidenimino adipate) 502.57- , 3",3'"-dimethoxy- 562.62 220 1893Poly(4,4'-biphenylene-4",4'''-dibenzylidenimino sebacate) 558.68- , 3",3'"-dimethoxy 618.73 230 1893Poly[4,4/-(4,4/-biphenylenedioxy)-diphenylene carbonate] 396.40 250 1915Poly(4,4/-biphenylenedioxy 4,4'-diphenylene ketone) *Poly(4,4'-biphenylene disiloxanylenedipropionamide) 370.56- , tetramethyl- (Si) 426.66 300 402Poly [4,4 '-(2,2 '-2,2 /-biphenylenedithiazole)-oxy-/?-phenylene] 486.61 240 1810Poly [4,4 '-(2,2 '-2,2 '-biphenylenedithiazole)-/?-phenylene] 394.51 250 1810Poly(4,4/-biphenylene dithiolisophthalate) 348.44 340 1922Poly(4,4/-biphenylene dithiolterephthalate) 348.44 >460 1922Poly (4,4 '-biphenylenegermylene) 224.79 295 1777Poly(biphenylene 3,3/,4,4/-oxydiphenylenetetracarboximide) *Poly (4,4'-biphenylene pyromellitimide) *Poly(4,4'-biphenylene sebacamide) 350.46 435 402Poly(4,4 '-biphenylene terephthalamide) 314.34 500 402- , 3,3'-dimethyl- 342.40 440 402- , - , AW-diethyl- 398.51 254 1870- , - , JV,AT'-diethyl- 370.45 316 1870Poly(4,4'-biphenylene terephthalate) *- , 2,2'-dipropyl- 400.47 350 1901Poly[4,4'-biphenylene 4",4'"-(thiodiphenylene)-dioxy-3,3 ',4,4'-diphenylenetetracarboximide] 658.68 483 1771PoIy(1,3-butadiene), 1,2- *PoIy(1,3-butadiene), 1,4-- , 2-tert-butyl *- , 2-chloro- [chloroprene] *- , 2,3-dimethyl-- , 1-methoxy- 84.12

trans- 118 1803- , 2-methyl- [isoprene] *- , - , hydrochlorinated *- , 2-methylacetoxy- *- , 2-propyl- *Poly( 1,3-butadiene( 1,4-)-a/Mnethacrylonitrile] 121.18- , 1,1,4,4-tetradeutero- 125.22 75 1825Poly[l,3-butadiene(l,4-)-a/Mnethyl methacrylate] 154.21 56 1849Poly(butadiene oxide) 70.09 74 1809Poly(butenamer) 54.09

I. 210 1864II. 150 1864

PoIy(I-butene)- , 4-cyclohexyl- 138.25 170 282

138 328

References page VI-159

Page 4: C. MELTING POINTS OF POLYMERS In the following …nguyen.hong.hai.free.fr/EBOOKS/SCIENCE AND ENGINEERING...Molecular Melting Polymer weight point Refs. PoIy(1,4-cyclohexylenedimethylene

Molecular MeltingPolymer weight point Refs.

- , 4-n-tt-diisopropylamino- 155.28 315 191- , 3,3-dimethyl- 84.16 260 282- , 3-methyl-- , 3-methyl- (1,3-via hydride shift) *- , 3-phenyl- 132.21 360 90- , 4-phenyl- *- , 4-o-tolyl- 146.23 239 187- , 4-/?-tolyl- 146.23 196 187_, 4,4,4-trifluoro- 110.08 263 1813- , 3-trifluoromethyl- 124.11 300 1813- , 4-trimethylsilyl- *Poly(2-butene-«/r-ethylene) *Poly(2-butene 4-octenediamide) 222.29

trans-, trans- 301 657Poly(2-butene oxide) *-,2-methyl- 86.13 196 1879Poly(2-butene sulfide) 88.17

cis- 156 548trans- 192 548

Poly(2-butenylene hexamethylenediurethane) 256.30cis- 136 402trans- 111 402Poly (4,4'-butylidenediphenylene carbonate) 268.31 170 438Poly[4,4'-(2,2-butylidene)-diphenylene carbonate] 268.31 222 438Poly(butylvinyl ether) *- , 2-methyl-Poly(sec-butylvinyl ether), see Poly(propylvinyl ether), methyl- *Poly(te7t-butylvinyl ether) *Poly(butyraldehyde) *Poly(caprolactam), see Poly(6-aminocaproic acid) *Poly(caprylaldehyde) 128.22 35 329Poly(carbon monoxide-a/f-ethylene) [ketone] *

Poly[m-(carboxyphenoxy)-acetic anhydride] 178.14 134 1565Poly[/7-(carboxyphenoxy)-acetic anhydride] 178.14- , 3-bromo- 257.04 179 1565Poly(chloroprene), see PoIy(1,3-butadiene), chloro- *Poly(chlorotrifluoroethylene-tf/?-ethylene) *Poly (1,3-cyclobutylene) 54.09- , 1-cyano- *Poly( 1,3-cyclobutylene carbonate) 114.10- , 2,2,4,4-tetramethyl-Poly( 1,3-cyclobutyleneoxymethylene oxide) 110.12- , 2,2,4,4-tetramethyl-PoIy (1,2-cycloheptylene-0//-ethylene) *Poly (1,4-poly-1,3-cy clohexadiene) 80.13

trans- 380 221Poly(cyclohexene oxide) 98.14 126 527PoIy(1,3-cyclohexylene adipamide) 224.30

cw- 170 402trans- 300 402

Poly(l,4-cyclohexylene adipamide) 224.30 400 402PoIy(1,4-cyclohexylene adipate) *PoIy(1,3-cyclohexylene azelamide) 266.38

cis- 125 402trans- 300 402

PoIy(1,4-cyclohexylene 3,3/-dibenzamide) 320.39 390 402PoIy(1,3-cyclohexylenedimethylene adipamide) *PoIy(1,4-cyclohexylenedimethylene adipamide) 252.36

cis- 246 385225 1878

trans- 345 385342 1806347 1878

PoIy(1,4-cyclohexylenedimethylene adipate) *

Page 5: C. MELTING POINTS OF POLYMERS In the following …nguyen.hong.hai.free.fr/EBOOKS/SCIENCE AND ENGINEERING...Molecular Melting Polymer weight point Refs. PoIy(1,4-cyclohexylenedimethylene

Molecular MeltingPolymer weight point Refs.

PoIy(1,4-cyclohexylenedimethylene azelamide) 294.44cis- 195 385trans- 275 385

PoIy(1,4-cyclohexylenedimethylene azelate) 296.41cis- 41 547trans- 50 547

Poly( 1,4-cyclohexylenedimethylene1,4-cyclohexylenedicarboxylate) 280.36

cis-, trans- 205 547trans-, trans- 246 547

Poly(1,4-cyclohexylenedimethylene dithiol-1,4-cyclohexylenedicarboxylate) 312.49trans-, trans- 310 1922

PoIy(1,4-cyclohexylenedimethylene dodecanediamide) 336.52cis- 215 385

190 1878trans- 278 385

280 1878PoIy(1,4-cyclohexylenedimethylene dodecanedioate) 338.49

cis- 46 547trans- 85 547

Poly[ 1,4-cyclohexylenedimethylene (ethylenedithio)-diethylenediurethane] 376.53trans- 121 1897

Poly(1,4-cyclohexylenedimethylene glutaramide) 238.33cis- 167 385trans- 290 385

PoIy(1,4-cyclohexylenedimethylene glutarate) 240.30trans- 50 547

Poly[ 1,4-cyclohexylenedimethylene (hexamethylenedithio)-diethylenediurethane] 432.64trans- 124 1897

PoIy(1,4-cyclohexylenedimethylene isophthalamide) 272.35trans- 310 385

Poly(1,4-cyclohexylenedimethylene isophthalate) 274.32trans- 197 547

PoIy(1,4-cyclohexylenedimethylene 2,6-naphthalate) 324.38cw- 287 547trans- 341 547

Poly( 1,4-cyclohexylenedimethylene octamethylenediurethane) 340.46trans- 160 402

160 291PoIy(1,4-cyclohexylenedimethylene oxalate) 198.22

trans- 215 547PoIy(1,4-cyclohexylenedimethylene)-oxymethylene oxide) 156.22

trans- 78 36986 1945

Poly[l,4-cylohexylenedimethylene (pentamethylenedithio)-diethylenediurethane] 418.61trans- 102 1897

PoIy(1,4-cyclohexylenedimethylene /?-phenylenediacetate) 302.37CW- 55 547

Poly(1,4-cyclohexylenedimethylene pimelamide) 266.3 8cis- 191 385trans- 293 385

PoIy(1,4-cyclohexylenedimethylene pimelate) 268.35trans- 42 547

Poly(1,4-cyclohexylenedimethylene sebacamide) 308.47cis- 208 385

200 1878trans- 300 385

296 1878292 1769

Poly(1,4-cyclohexylenedimethylene sebacate) 310.43cis- 50 547trans- 78 547

PoIy(1,4-cyclohexylenedimethylene suberamide) 280.41cis- 215 385trans- 311 385

References page VI-159

Page 6: C. MELTING POINTS OF POLYMERS In the following …nguyen.hong.hai.free.fr/EBOOKS/SCIENCE AND ENGINEERING...Molecular Melting Polymer weight point Refs. PoIy(1,4-cyclohexylenedimethylene

Molecular MeltingPolymer weight point Refs.

Poly(l,4-cyclohexylenedimethylene suberate) 282.38cis- 50 547trans- 96 547

PoIy(1,4-cyclohexylenedimethylene succinate) *PoIy(1,4-cyclohexylenedimethylene terephthalate) *Poly[ 1,4-cyclohexylenedimethylene (tetramethylenedithio)-diethylenediurethane] 404.58

trans- 129 1897Poly[ 1,4-cyclohexylenedimethylene (trimethylenedithio)-diethylenediurethane] 390.56

trans- 105 1897Poly[(l,4-cyclohexylenedioxy)-ditrimethylene adipamide] 340.46 196 402Poly[(l,4-cyclohexylenedioxy)-ditrimethylene 4,4/-(ethylenedioxy)-dibenzamide] 496.60 250 402Poly[(l,4-cyclohexylenedioxy)-ditrimethylene 4,4'-(hexamethylenedioxy)-dibenzamide] 552.71 215 402Poly[(l,4-cyclohexylenedioxy)-ditrimethylene oxamide] 284.36 246 402Poly[(l,4-cyclohexylenedioxy)-ditrimethylene 4,4/-(oxydiethylenedioxy)-dibenzamide] 540.66 125 402Poly[(l,4-cyclohexylenedioxy)-ditrimethylene (/?-phenylenedioxy)-diacetamide] 420.51 160 402Poly[(l,4-cyclohexylenedioxy)-ditrimethylene terephthalamide 360.45 384 402Poly[(l,4-cyclohexylenedioxy)-ditrimethylene 4,4/-(tetramethylenedioxy)-dibenzamide] 524.66 224 402PoIy(1,4-cyclohexylene dithiolsuccinate) 230.35

trans- 302 1922Poly[ 1,4-cyclohexylene (ethylenedithio)-diethylenediurethane] 348.48

trans- 214 1897Poly[ 1,4-cyclohexylene (hexamethylenedithio)-diethylene-diurethane] 404.58

trans- 204 1897PoIy(1,4-cyclohexylene 3,3'-methylenedibenzamide) 334.42 174 402PoIy(1,4-cyclohexylene octamethylenediurethane) 312.41

trans- 255 633255 402221 291

Poly(l,4-cyclohexyleneoxymethylene oxide) 128.17trans- 209 369

Poly[ 1,4-cyclohexylene (pentamethylenedithio)-diethylene-diurethane] 390.56trans- 189 1897

Poly(l,3-cyclohexylene sebacamide) 280.41cis- 120 402trans- 290 402

PoIy(1,4-cyclohexylene sebacate) *PoIy(1,4-cyclohexylene suberate) 254.33

trans- 181 1174PoIy(1,2-cyclohexylene sulfide) 114.21 130 1917PoIy(1,3-cyclohexylene sulfide) 114.21 139 1917PoIy(1,2-cyclohexylene sulfone) 146.21 284 1917Poly(l,3-cyclohexylene sulfone) 146.21 309 1917Poly[ 1,4-cyclohexylene (tetramethylenedithio)-diethylene-diurethane] 376.53

trans- 214 1897Poly[ 1,4-cyclohexylene (trimethylenedithio)-diethylene-diurethane] 362.50

trans- 202 1897Poly(l,4-cylclohexylene urethane) 141.17 >355 444Poly(cyclohexylidenedimethylene oxide) 126.20 152 1935- , 3,4-dihydro- 124.18 102 1935- , - , 4-methyl- 138.21 155 1935- , 4-methyl- 140.23 165 1935Poly(4,4/cyclohexylidenediphenylene carbonate) 294.35 260 438- , 2,2'-dimethyl- 322.40 200 1915- , 3,3/,5,5'-tetrachloro- 427.09 270 540Poly(cyclohexylidenethiohexamethylene sulfide) 230.44 75 1923PoIy(1,2-cyclopentylene-a/f-ethylene) *PoIy(1,3-cyclopentylene-tf/Mnethylene) [1,5-hexadiene] *Poly(4,4'-cyclopentylidenediphenylene carbonate) 280.32 250 438Poly(cyclopropylene cyclopropylenedicarboxamide) 166.18 285 1865Poly[cyclopropylene (cyclopropylenedicarboxoyl)-diurethane] 254.20

trans-, trans- 245 1865Poly(cyclopropylenedimethylene cyclopropylenedicarboxamide) 194.23 220 1865Poly(cyclopropylenedimethylene cyclopropylenediurethane) 226.23

cis- 175 1865trans- 210 1865

Page 7: C. MELTING POINTS OF POLYMERS In the following …nguyen.hong.hai.free.fr/EBOOKS/SCIENCE AND ENGINEERING...Molecular Melting Polymer weight point Refs. PoIy(1,4-cyclohexylenedimethylene

Molecular MeltingPolymer weight point Refs.

Poly(cyclopropylenedimethylene hexamethylenediurethane) 270.33cis- 120 1860trans- 165 1860

Poly(cyclopropylenedimethylene isophthalamide) 230.27 220 1865Poly(cyclopropylenedimethylene isophthalate) 232.24 100 1860Poly[cyclopropylenedimethylene 4,4 /-(methylenediphenylene)-diurethane] 352.39

cis- 230 1860trans- 290 1860

Poly(cyclopropylenedimethylene piperazinediurethane) 240.26cis- 70 1860trans- 100 1860

Poly (cyclopropylenedimethylene sebacamide) 266.38 223 1865Poly(cyclopropylenedimethylene terephthalate) 232.24 130 1860Poly(cyclopropylenedimethylene toluylenediurethane) 276.29

cis- 170 1860trans- 200 1860

Poly(cyclopropylene hexamethylenediurea) 240.31 180 1865Poly(cyclopropylene isophthalamide) 202.21 250 1865Poly(cyclopropylene piperazinediurea) 210.24 260 1865Poly(cyclopropylene sebacamide) 238.33 220 1865Poly(cyclopropylidenedimethylene oxide) 84.12 45 1935Poly(decamethylene) 140.27- , 1,2-dichloro- 209.16

trans- 47 1925Poly(decamethylene adipamide) *Poly(decamethylene adipate) *- , 3-methyl-(diacid) 298.42 - 2 1796Poly[decamethylene WV-adipolyldi(6-aminocaproate)] 510.72 137 1792Poly(decamethylene adipoyldiurethane) 370.45 164 402Poly(decamethyleneaminohexamethylene amine) 254.46 102 1829Poly(decamethylene azelamide) *Poly(decamethylene azelate) *Poly(decamethylene 4,4 '-biphenylenediurethane) 410.51- , 3,3'-dimethyl- (diisocyanate) 438.57 219 633Poly (decamethylene carbonate) 200.28 55 1820Poly(decamethylene m-carboxycarbanilate) 319.40 127 1891Poly(decamethylene p-carboxycarbanilate) 319.40 158 1891Poly[decamethylene (decamethylenedisulfonyl)-dicaproamide] 634.98 207 402Poly(decamethylene decamethylenediurethane) 398.59 145 291

142 634Poly (decamethylene 2,2'-dibenzoate) 380.48 - 3 1552Poly(decamethylene 3,3'-dibenzoate) 380.48 90 1552Poly(decamethylene 4,4'-dibenzoate) 380.48 132 1552Poly[(decamethylenedioxy)-dihexamethylene oxide] 356.59 68 542Poly[4,4'"-(4'A//-(decamethylenedioxy)-diphenylenedioxy)-diphenylene terephthalate] 672.78 242 1773Poly[4,4/-(decamethylenedioxy)-diphenyleneoxy-p-xylylene oxide] 460.62 211 1789Poly[3,3/-(decamethylenedioxy)-diphenylene terephthalate] 488.58 108 1773Poly[4,4'-(decamethylenedioxy)-diphenylene terephthalate] 488.58 259 1773- , dichloro-(diol) 557.47 160 1773Poly(4,4/-decamethylenediphenylene carbonate) 352.47 110 1915

150 1174Poly(4,4/-decamethylenedipiperazine sebacamide) *Poly(decamethylene disiloxanylenedipropionamide) 358.63- , tetramethyl- (silicone) 414.74 50 402Poly (decamethylene disulfide) 204.39 45 1868

65 725Poly(decamethylenedithioethylene disulfide) 296.56 80 1837Poly(decamethylenedithiohexamethylene disulfide) 352.67 46 1784Poly(decamethylene dithioladipate) 316.53 75 1922Poly(decamethylene dithiolsebacate) 372.63 103 1922Poly(decamethylene dithiolterephthalate) 336.52 201 1922Poly(decamethylenedithiotetramethylene disulfide) 324.62 56 1837

58 1784Poly(decamethylene docosanediamide) 506.86 169 454Poly (decamethylene dodecamethylenediurea) 424.67 190 634

References page VI-159

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Molecular MeltingPolymer weight point Refs.

Poly(decamethylene phosphinylidenedipropionamide) 330.41- , methyl- (P)Poly(decamethylene phthalamide) 302.42 115 1868Poly(decamethylene pimelate) 298.42 66 764Poly(decamethylene dodecanediamide) 366.59 191 244

192 454Poly[decamethylene ^,A^'-dodecanedioyldiQ^-aminobenzoate)] 606.80 171 1792Poly(decamethylene eicosanediamide) 478.80 171 244Poly[decamethylene 4,4/-(ethylenedioxy)-dibenzoate] 440.54 135 290Poly[decamethylene 4,4/-(ethylenediphenylene)-dioxydiacetamide] 466.62 220 402Poly(decamethylene WV-ethylenediterephthalamate) 494.59 277 781Poly(decamethylene 4,4/-ethylidenedibenzamide) 406.57 150 402Poly(decamethylene fumaramide) 252.36 50 402- , 2,3-dimethyl- (diacid) 280.41

trans- 267 1931- , methyl- (diacid) 266.38 166 1931Poly(decamethylene 2,5-furandicarboxamide) 292.38 130 1905Poly(decamethylene 2,5-furandipropionamide) 348.49 140 402Poly(decamethylene glutaramide) 268.40- , 3-carboxyl- (diacid) 312.41 70 402Poly(decamethylene glutarate) *Poly[decamethylene (hexamethylenedisulfonyl)-dicapromide] 578.87 218 402Poly(decamethylene WV'-hexamethylenediterephthalamate) 550.70 235 781Poly(decamethylene hexamethylenediurea) 340.51 210 402

216 634Poly(decamethylene hexamethylenediurethane) *Poly(decamethylene 3-hexenedioate) *Poly(decamethylene isophthalamide) 302.42 186 1868Poly(decamethylene isophthalate) 304.39 36 1794Poly[decamethylene 4,4/-(isopropylidenediphenylene)-dioxy-diacetamide] 480.65 105 402Poly(decamethylene malonamide) 240.35- , dodecyl-(diacid) 408.67 123 1774Poly(decamethylene malonate) 242.32 34 764Poly(decamethylene 3,3'-methylenedibeiizamide) 392.54 65 402Poly(decamethylene 4,4'-methylenedibenzamide) 392.54 100 402Poly(decamethylene 4,4/-methylenediphenylenediurea) 422.57 246 634Poly(decamethylene 4,4'-methylenediphenylenediurethane) *Poly[decamethylene (methylene-2,5-furan)-dicarboxamide] 306.41 111 402Poly[decamethylene (methylene-2,5-tetrahydrofuran)-dicarboxamide] 310.44 85 402Poly[decamethylene octadecamethylenediurea) 508.84 172 634Poly(decamethylene ocatadecanediamide) 450.75 170 454Poly[decamethylene octadecanedioate) *Poly[decamethylene octamethylenediurea) 368.57 201 634Poly[decamethylene octamethylenediurethane) 370.53 146 402Poly(decamethylene 4-octenediamide) *Poly(decamethylene 4-octenedioate) *Poly(2,5-decamethylene-l,3,4-oxadiazole) 208.30 100 1921Poly(decamethylene oxalate) *Poly(decamethylene oxamide) 226.32 229 291

252 743290 402

Poly(decamethylene oxamide-a/f-decamethylene sebacamide) 564.86 231 1781Poly(decamethylene oxide) *Poly(decamethylene oxydiacetate) 272.34 64 1798Poly(decamethyleneoxymethylene oxide) 186.30 57 695Poly(decamethyleneoxy-/7-phenylene oxide) 248.37 < 100 1868Poly[decamethylene (pentamethylenedisulfonyl)-dicaproamide] 564.84 223 402Poly(decamethylene A^N'-pentamethylenediterephthalamate) 536.67 205 781Poly(decamethylene /?-phenylenediacetamide) 330.47 242 291

265 454Poly[decamethylene (p-phenylenedioxy)-diacetamide] 362.47 188 402Poly(decamethylene /?-phenylenedipropionamide) 358.53 265 402

271 454Poly(decamethylene S^'-phosphinylidenedibenzamide) 426.50- , methyl- (P) 440.52 155 402

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Molecular MeltingPolymer weight point Refs.

Poly(decamethylene 4,4/-phosphinylidenedibenzamide) 426.50- , methyl- (P) 440.52 186 402- , phenyl-(P) 502.59 192 402Poly(decamethylene 2,4-pyridinedicarboxamide) 303.41 190 1905Poly(decamethylene 2,5-pyridinedicarboxamide) 303.41 232 1905Poly(decamethylene 2,6-pyridinedicarboxamide) 303.41 200 1905- , l,4-dihydro-4-0jco- 319.41 137 1905Poly(decamethylene 3,5-pyridinedicarboxamide) 303.41 210 1905Poly(decamethylene pyromelltimide) *- , 3-bromo- (imide) 433.30 291 1267Poly(decamethylene sebacamide) *Poly(decamethylene sebacate) *Poly(decamethylene sebacoyldiurethane) 426.55 153 402Poly(decamethylene suberamide) 310.48 217 244

208 291Poly(decamethylene suberate) *Poly(decamethylene succinamide) *Poly(decamethylene succinate) *- , D-l,2-dihydroxy- (diacid) 288.34 66 609Poly(decamethylene sulfide) 172.33 78 1819

91 181Poly(decamethylene sulfonyldivalerate) 404.56 101 1797Poly(decamethylene terephthalamide) 302.42 276 1868Poly(decamethylene terephthalate) *Poly[decamethylene N,Af'-terephthaloyldi(6-aminocaproate)] 530.71 166 1792Poly(decamethylene tetradecamethylenediurea) 452.73 180 634Poly(decamethylene tetradecanediamide) 394.64 189 2Poly(decamethylene 2,5-tetrahydrofurandipropionamide) 352.52 178 402Poly[decamethylene (tetramethylenedisulfonyl)-dicaproamide] 550.81 236 402Poly(decamethylene AW'-tetramethylenediterephthalamate) 522.64 261 781Poly(decamethylene tetramethylenediurethane) 314.43 171 633Poly(decamethylene thiodivalerate) 372.56 57 767Poly(decamethylenethiohexamethylene sulfide) 288.55 78 1819Poly(decamethylene 2,5-thiophenedicarboxamide) 308.44 250 1905Poly(2,5-decamethylene-l,3,4-triazole) 207.32- , 1-amino- (triazole) 222.34 242 610Poly(decamethylenetridecanediamide) 380.62 175 339Poly(decamethylene AW'-trimethylenediterephthalamate) 508.61 222 781Poly(decamethylene urea) 198.31 200 402

197 634210 291

Poly(decamethylene /7-xylylenediurea) 360.50 260 634Poly(decamethylene /?-xylylenediurethane) 362.47 147 634Poly(decenamer) *PoIy(I-decene)Poly(decylvinyl ether) 184.32 7 1900Poly [2,7-( 1,6-diazanthrylene)-4,4 '-biphenylene] 330.39- , 4,9-diphenyl- 482.58 498 1778Poly [2,8-( 1,9-diazanthrylene)-4,4 '-biphenylene] 330.39- 4,6-diphenyl 482.52 513 1778Poly [2,7-( 1,6-diazanthrylene)-4,4 '-oxydiphenylene] 346.39-,4,9-diphenyl- 498.58 490 1778Poly [2,8-( 1,9-diazanthrylene)-4,4 '-oxydiphenylene] 346.39-,4,6-diphenyl- 498.58 502 1778Poly(dimethyl ketene) *Poly(di-l,4-naphthyleneoxyethylene oxide) 312.37 291 1787Poly(di-l,4-naphthyleneoxyheptamethylene oxide) 382.50 239 1787Poly(di-l,4-naphthyleneoxyhexamethylene oxide) 368.48 280 1787Poly(di-l,4-naphthyleneoxypentamethylene oxide) 354.45 196 1787Poly(di-l,4-naphthyleneoxytetramethylene oxide) 340.42 324 1787Poly(di-l,4-naphthyleneoxytrimethylene oxide) 326.40 278 1787PoIy(1,4-dioxanylene-2,5-dimethylene adipamide) 256.30

trans- 291 1769PoIy(1,4-dioxanylene-2,5-dimethylene sebacamide) 312.41

trans- 262 1769

References page VI-159

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Molecular MeltingPolymer weight point Refs.

PoIy(I, 3-dioxolane), see Poly(ethyleneoxymethylene oxide) *PoIy(1,3-dioxopane), see Poly(methyleneoxytetramethylene oxide) *Poly(dithiodiethylene sebacamide) 318.49 155 402Poly(4,4/-dithiodiphenylene hexamethylenediurea) 416.56 262 402Poly(divinylbenzal) 176.22 100 1830- , 2-methyl- 190.24 95 1830- , 4-methyl- 190.24 115 1830Poly(divinylfurfural) 166.18 145 1830PoIy(I-docosene) *Poly(dodecamethylene) 168.32- , 1,2-dichloro- 237.21

trans- 40 1925- , 1-methyl- 182.35 30 1926Poly(dodecamethylene adipamide) 310.48 210 339

230 544Poly(dodecamethylene adipate) *Poly[dodecamethylene AW-adipoyldi(6-aminocaproate)] 538.77 134 1792Poly(dodecamethylene 4,4'-biphenylenediurethane) 438.57- , 3,3'-dimethyl- (diisocyanate) 466.62 219 402Poly(dodecamethylene decamethylenediurethane) 426.64 133 634Poly[4,4;-(dodecamethylenedioxy)-diphenyleneoxy-/7-xylylene oxide] 488.67 207 1789Poly(dodecamethylene docosanediamide) 534.92 164 454Poly(dodecamethylene A^AT'-dodecamethylenediterephthalamate) *Poly(dodecamethylene dodecamethylenediurethane) 454.70 128 633Poly(dodecamethylene dodecanediamide) 394.64 183 454Poly[dodecamethylene AW'-dodecanedioyldi(p-aminobenzoate)] 634.86 167 1792Poly(dodecamethylene AW-ethylenediterephthalamate) 522.64 264 781Poly(dodecamethylene AW-hexamethylenediterephthalamate) 578.75 231 781Poly(dodecamethylene hexamethylenediurea) 368.57 205 634

238 1892Poly(dodecamethylene hexamethylenediurethane) 370.53 139 634Poly(dodecamethylene 3-hexenedioate) *Poly(dodecamethylene 4,4/-methylenediphenylenediurea) 450.63 240 634Poly(dodecamethylene 4,4'-methylenediphenylenediurethane) 452.59 164 634Poly(dodecamethylene 1,4,5,8-naphthalenetetracarboximide) *Poly(dodecamethylene octadecanediamide) 478.80 167 454Poly(dodecamethylene 4-octenedioate) *Poly(dodecamethylene oxamide) *Poly(dodecamethylene oxamide-a/f-dodecamethylene sebacamide) 620.96 217 1781Poly(dodecamethylene AW-pentamethylenediterephthalamate) 564.72 206 781Poly(dodecamethylene p-phenylenediacetamide) 358.53 256 454Poly(dodecamethylene/?-phenylenedipropionamide) 386.58 263 454Poly(dodecamethylene phosphinylidenedipropionamide) 358.46- , methyl- (P)Poly(dodecamethylene pyromellitimide) *- , 3-bromo-(imide) 461.36 238 1267Poly(dodecamethylene sebacamide) *Poly(dodecamethylene suberate) *Poly(dodecamethylene succinamide) *Poly(dodecamethylene terephthalamide) 330.47 296 454

301 544Poly[dodecamethylene AW'-terephthaloyldi(6-aminocaproate)] 558.76 163 1792Poly(dodecamethylene AW-tetramethylenediterephthalamate) 550.70 258 781Poly(dodecamethylene AW-trimethylenediterephthalamate) 536.67 216 781Poly(dodecamethylene p-xylylenediurea) 388.56 258 634Poly(dodecamethylene p-xylylenediurethane) 390.52 178 634Poly(dodecanedioic anhydride) 212.29 87 1823Poly(dodecenamer) *PoIy(I-dodecene) *Poly(dodecylvinyl ether) 212.38 30 1900Poly(eicosamethylene adipate) 424.67 87 1790- , 3-methyl-(diacid) 438.69 60 1796Poly(eicosamethylene azelate) 466.75 87 1790Poly(eicosamethylene 3,3'-dibenzoate) 520.76 91 1552Poly(eicosamethylene 4,4 '-dibenzoate) 520.76 115 1552

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Molecular MeltingPolymer weight point Refs.

Poly(eicosamethylene glutarate) 410.64 80 1790- , 3-(p-nitrophenyl)- (diacid) 531.74 46 1796Poly(eicosamethylene isophthalate) 444.66 49 1794Poly(eicosamethylene malonate) 382.58 69 1868

69 1790Poly(eicosamethylene oxalate) 368.56 90 1790Poly(eicosamethylene oxydiacetate) 412.61 89 1798Poly(eicosamethylene phthalate) 444.66 52 1794Poly(eicosamethylene pimelate) 438.69 84 1790Poly(eicosamethylene sebacate) 480.78 92 1790Poly(eicosamethylene suberate) 452.72 88 1790Poly(eicosamethylene succinate) 396.61 89 1790Poly(eicosamethylene sulfonyldivalerate) 544.83 117 1797Poly(eicosamethylene terephthalate) 444.66 113 1794Poly(eicosamethylene thiodivalerate) 512.84 79 767Poly(enanthaldehyde, see Poly(heptaldehyde) *Poly(epichlorohydrin), see Poly(ethylene oxide), chloromethyl- *Poly(ethylene)- , chlorotrifluoro- *- , l-butoxy-2-methyl- 114.19

cis- (erythro-di-isotactic) 100 1880trans- (threo-di-isotactic) 100 1880

- , l-tert-butoxy-2-methyl- 114.19cis- (erythro-di-isotactic) >250 1880

- , l-ethoxy-2-methoxy- 102.13trans- 217 141

- , l-ethoxy-2-methyl- 86.13cis- (erythro-di-isotactic) 191 1880trans- (threo-di-isotactic) 207 1880

230 1804243 141

- , isobutoxy-2-methyl- *- , l-isopropoxy-2-methyl- 100.16

cis- (erythro-di-isotactic) 204 1880trans- (threo-di-isotactic) 211 1880

- , l-methoxy-2-methyl- 72.11cis- or trans- (threo-di-isotactic) 230 1880

287 1804210 141

- , l-methyl-2-propoxy- 100.16trans- 168 1804

- , tetrafluoro- *- , trifluoro- *Polyethylene adipamide) 170.21 310 402Polyethylene adipamide-a/f-ethylene oxamide) 284.32 D359 1781Poly(ethylene adipate) *- , methyl-(diol) 186.21 - 2 0 765Polyethylene A^V'-adipoyldi(6-aminocaproate)] 398.50 163 1792Polyethylene adipoyldiurethane) 258.23 210 402Poly(ethylene amine) *- , AT-acetyl- 85.11 200 747- , Af-benzoyl- *- , - , /7-chloro- *- , Af-butyryl- *- , - , 4-(4-methylthiophenyoxy)- *- , N-cyclohexanecarbonyl- 153.22 285 747- , N-dodecanoyl- 225.38 155 747- , Af-heptanoyl- *- , Af-hexanoyl- *- , Af-isobutyryl- *- , Af-isovaleryl- *- , JV-2-naphthoyl- 197.24 258 747- , Af-octadecanoyl- 309.54 145 747- , iV-octanoyl- *- , A -̂perfluorooctanoyl- 439.12 245 747

References page VI-159

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Molecular MeltingPolymer weight point Refs.

- , N-perfluoropropionyl- 189.08 216 747- , JV-pivaloyl- 127.19 320 747- , iV-P-toluoyl- *- , Af-valeryl- *Poly(ethylene azelamide-tf/f-ethylene oxamide) 326.40 343 1781Poly(ethylene azelate) *- , methyl- (diol) 228.29 - 3 8 765Poly(4,4 '-ethylenebiphenylene) 180.25 > 550 1187Polyethylene p-(carboxyphenoxy)-acetate] 222.20 140 290Polyethylene /?-(carboxyphenoxy)-butyrate] 250.25 85 290Polyethylene /?-(carboxyphenoxy)-caproate] 278.30 45 290Polyethylene p-(carboxyphenoxy)-heptanoate] 292.33 55 290Polyethylene p-(carboxyphenoxy)-undecanoate] 348.44 65 290Polyethylene /?-(carboxyphenoxy)-valerate] 264.28 55 290Polyethylene p-(carboxyphenylene)-acetamide] 204.23 221 1904Poly(ethylene 1,4-cyclohexylenedicarboxylate) 198.22

cis- <30 1912trans- 120 1912

Poly(ethylene cyclopropylenedicarboxamide) 154.17trans- 350 1860

Poly(ethylene decamethylenediurethane) *Polyethylene 2,2'-dibenzoate) 268.27 130 1654- , methyl-(diol) 282.30 55 1552Polyethylene 3,3 '-dibenzoate) 268.27 122 1552- , methyl-(diol) 282.30 97 1552Polyethylene 4,4'-dibenzoate) *- , methyl- (diol) 282.30 140 1552Poly(4,4'-ethylenedibenzoic anhydride) 252.27 340 1854Poly(4,4'-ethylenedicyclohexylene dodecanediamide) 418.66 316 1926Poly(4,4/-ethylenedicyclohexylene sebacamide) 390.61 333 1926Poly[3,3 /-(ethylenedioxy)-dibenzoic anhydride] 284.27 237 1854Poly[4,4'-(ethylenedioxy)-dibenzoic anhydride] 284.27 208 1854

215 1565222 1872

- , 3,3/-dimethoxy- 344.32 220 1855Poly[4,4/-(ethylenedioxy)-dibenzoic isophthalic anhydride] 432.38 140 1871Poly[4,4/-(ethylenedioxy)-dibenzoic phthalic anhydride] 432.38 185 1872Poly[4,4'-(ethylenedioxy)-dibenzoic terephthalic anhydride] 432.38 209 1871Poly[(ethylenedioxy)-diethylene adipamide] 258.32 160 291

190 402Poly[(ethylenedioxy)-diethylene adipate] 260.29 - 30 765Poly[(ethylenedioxy)-diethylene azelate] 302.37 - 40 765Poly[(ethylenedioxy)-diethylene 2,2'-dibenzoate] 356.37 41 1552Poly[(ethylenedioxy)-diethylene 3,3'-dibenzoate] 356.37 46 1552Poly[(ethylenedioxy)-diethylene 4,4'-dibenzoate] 356.37 93 1552Poly [4,4'-(ethylenedioxydiethylenedioxy)-diphenylene 3,3',4,4'-(carbonyldiphenylene)tetracarboximide] 616.58 405 1808Poly[3,4 /-(ethylenedioxydiethylenedioxy)-diphenylene 3,3 ',4,4/-(oxydiphenylene)tetracarboximide] *Poly[(ethylenedioxy)-diethylene glutarate] 246.26 - 28 765Poly[(ethylenedioxy)-diethylene isophthalate] 280.28 65 1794Poly[(ethylenedioxy)-diethylene malonate] 218.21 - 2 8 765Poly[(ethylenedioxy)-diethylene oxalate] 204.18 - 1 0 765Poly[(ethylenedioxy)-diethylene pimelate] 274.32 - 37 765Poly[(ethylenedioxy)-diethylene 1,4-piperazinediacetamide] 314.39 115 291Poly[(ethylenedioxy)-diethylene sebacate] 316.39 29 696

35 767Poly[(ethylenedioxy)-diethylene suberate] 288.34 - 36 765Poly[(ethylenedioxy)-diethylene succinate] 232.23 - 1 8 765Poly[(ethylenedioxy)-diethylene sulfonyldivalerate 348.39 27 1797Poly[(ethylenedioxy)-diethylene terephthalate] 280.28 65 1794Poly[(ethylenedioxy)-diethylene thiodivalerate] 348.46 - 37 767Poly[(ethylenedioxy)-diethylene undecanediamide] 328.45- , 6-hydroxy-(diacid) 344.45 156 402Poly[4,4/-(ethylenedioxy)-diphenylene 3,3',4,4'-(carbonyl-diphenylene)-tetracarboximide] 528.48 470 1808Poly[3,4/-(ethylenedioxy)-diphenylene 3,3 /,4,4/-(oxy-diphenylene)-tetracarboximide] *Poly[(ethylenedioxy)-ditrimethylene adipamide] 286.37 180 1791

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Molecular MeltingPolymer weight point Refs.

Poly[(ethylenedioxy)-ditrimethylene azelamide] 328.45 130 1791Poly[(ethylenedioxy)-ditrimethylene sebacamide] 342.48 160 1791Poly[(ethylenedioxy)-ditrimethylene terephthalamide] 306.36 240 1791Poly (4,4'-ethylenediphenylene adipamide) 322.41 400 402Poly(4,4/-ethylenediphenylene carbonate) 240.26 300 438Poly(4,4/-(ethylenediphenylene)-methylene] 194.28 255 1187Poly(4,4/-ethylenediphenylene sebacamide) 378.52 360 402Poly(ethylene disiloxanylenedipropionamide) 246.42- , tetramethyl- (silicone) 302.52 55 402Polyethylene disulfide)Poiy[(ethylenedisulfonyl)-diacetic anhydride] 256.24 185 1856Poly[(ethylenedisulfonyl)-dipropionic anhydride] 284.30 255 1856Poly [4,4 '-(2,2 '-ethylenedithiazole)-/?-phenylene] 270.37 265 1810Poly[(ethylenedithio)-diacetic anhydride] 192.25 83 1565Poly[(ethylenedithio)-dipropionic anhydride] 220.30 75 1565Poly(ethylenedithiohexamethylene disulfide) 240.56 102 1837

107 1784Polyethylene dithioladipate) 204.31 125 1922Polyethylene dithiolisophthalate) 224.30 185 1922Polyethylene dithiol-2,5-pyridinedicarboxylate) 252.29 280 1922Polyethylene dithiolterephthalate) 224.29 340 1922Polyethylene dithionisophthalate) 224.29 80 1889Polyethylene dithiotetramethylene disulfide) 212.40 96 1837

88 1784Polyethylene MA^-dodecamethylenediterephthalamate) *Polyethylene dodecanediamide) 254.37 261 244Polyethylene WV'-dodecanedioyldi(p-aminobenzoate)] 494.59 242 1792Poly[ethylene (ethylenediamino)-dipropionamide] 228.30- , WV'-diisopropyl-, A^V'-dimethyl- 340.51 102 1875Poly(ethylene 4,4/-ethylenedibenzoate) 296.32 212 1566

>320 1654Polyethylene ethylenedioxy)-diacetamide] 202.21 168 1894Polyethylene 3,3 /-(ethylenedioxy)-dibenzoate] 328.32 141 111Poly[ethylene 4,4'-(ethylenedioxy)-dibenzoate] *- , 3,3'-dimethoxy- 388.37 210 1914Polyethylene 4,4/-(ethylenedioxydimethylene)-dibenzoate] 356.38 135 1174Poly[ethylene 4,4/-(ethylenediphenylene)-diurethane] *Poly[ethylene 4,4/-(ethylenedithio)-dibenzoate] 360.44 190 291Polyethylene (ethylenedithio)-diethylenediurethane] 294.38 168 1897Polyethylene fumaramide) 140.14 50 402Polyethylene ghitarate) 158.15- , methyl-(diol) 172.18 - 1 8 765- , 3-(p-nitro)- 279.25 76 1796Polyethylene 2,4-hexadienediamide) 166.18 61 402Poly(ethylene 4,4'-hexamethylenedibenzoate) 352.43 160 1174Poly[ethylene (hexamethylenedithio)-diethylene-diurethane] 350.49 130 1897Poly(ethylene hexamethylenediurea) 228.30 293 1892

240 1768Polyethylene hexamethylenediurethane) *Polyethylene isophthalate) *- , methyl- (diol) 206.20 87 1794Polyethylene WV'-lysyldiurea) 258.28- , methyl ester 272.30 160 1768Polyethylene 4,4'-methylenedibenzoate) 282.30 220 291

>320 1654Poly[ethylene 4,4/-(methylenediphenylene)-diurethane] *Polyethylene 1,5-naphthalate) 242.23 230 291Polyethylene 2,6-naphthalate)Polyethylene 2,7-naphthalate) 242.23 270 1911Poly(ethylene nonamethylenediurethane) *Poly(ethylene oxalate) *Polyethylene oxamide-a/f-ethylene sebacamide) 340.42 323 1781Polyethylene oxamide-aft-ethylene suberamide) 312.37 348 1781Poly(ethylene oxide) *- , 1,1-bischloromethyl- 141.00 180 1816

References page VI-159

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Molecular MeltingPolymer weight point Refs.

- , bromomethyl-[epibromohydrin] 136.98 112 1809- , tert-butyl- *- , chloromethyl- [epichlorohydrin] *- , 1,2-dichloromethyl- 141.00

cis- 235 1779trans- 145 1779

- , fluoromethyl-[epifluorohydrin] 76.07 68 119- , isopropyl- *- , neopentyl- 114.19 82 527- , p-nitrophenol complex *- , resorcinol complex *- , tetrafluoro- 116.02 42 1858-, tetramethyl- 100.16 300 664- , urea complex *Poly(ethylene-p-oxybenzoate) *- , m-chloro- 198.61 285 1174- , o-chloro- 198.61 153 1174- , m-mehthyl- 178.19 292 1174- , 0-methyl- 178.19 157 1174Polyethylene oxydiacetate) 160.13 20 1798- , methyl-(diol) 174.15 21 1798Polyethylene 4,4/-oxydibenzoate) 284.27 152 291

134 1939Poly[ethylene 4,4/-(oxydiethylene)-dioxydibenzoate] 372.37- , 3,3/-dimethoxy- 432.42 118 1914Polyethylene 4,4/-oxydimethylene)-di-2-(l,3-dioxolane)-caprylate] 500.63 19 797Poly(ethyleneoxymethylene oxide) [1,3-dioxolane] *Polyethylene p-oxyphenyleneacetate) 178.19 172 1841Poly(ethyleneoxy-/?-phenylene oxide) 136.15 270 1868Polyethylene 4,4'-(pentamethylenedioxy)-dibenzoate] 370.40 150 1912Polyethylene (pentamethylenedithio)-diethylenediurethane] 336.46 126 1897Polyethylene /?-phenylenediacetate) 220.22 107 325

137 341Polyethylene m-phenylenedisulfonamide) 262.30 182 1384Polyethylene phthalamide) 190.20 250 1833Polyethylene phthalate) 192.17 104 1654- , methyl-(diol) 206.20 50 1794Polyethylene pimelate) *- , methyl- (diol) 200.24 - 3 0 765Polyethylene 1,4-piperazinedicarboxylate) *Polyethylene 1,4-piperazinedipropionamide) 254.33 D231 1875- , A^V'-diisopropyl- 338.50 210 1875Polyethylene 1,4-piperazinedipropionate) 256.30 93 1875Polyethylene sebacamide) 226.32 276 244

254 291280 402

Polyethylene sebacate) *- , methyl (diol) 242.32 - 26 765Polyethylene sebacoyldiurea) 312.37 228 402Polyethylene sebacoyldiurethane) 314.34 198 402Polyethylene suberate) *- , methyl-(diol) 214.26 - 3 4 765Poly(ethylene succinate) *- , methyl- (diol) 158.15 0 765Poly(ethylene sulfide) *- , terf-butyl- *Polyethylene 4,4/-sulfonyldibenzamide) 330.36 380 1835Polyethylene sulfonyldivalerate) 292.35 86 1797- , methyl- (diol) 306.38 68 1797Polyethylene L-tartaramide) 174.16- , di-O-methyl- *Polyethylene terephthalamide) 190.20 455 829- , AW-dimethyl- 218.26 379 829Polyethylene terephthalate)- , chloro- (diacid) 226.62 92 1913

Page 15: C. MELTING POINTS OF POLYMERS In the following …nguyen.hong.hai.free.fr/EBOOKS/SCIENCE AND ENGINEERING...Molecular Melting Polymer weight point Refs. PoIy(1,4-cyclohexylenedimethylene

Molecular MeltingPolymer weight point Refs.

- , 2,5-dichloro- 261.06 165 1913- , 2,5-dimethyl- 220.22 180 1913- , methyl- (diacid) 206.20 70 1913- , methyl-(diol) 206.20 111 1794Polyethylene MA^/-terephthaloyldi(6-aminocaproate)] 418.49 204 1792Polyethylene 2,5-tetrahydrofurandipropionamide) 240.30 218 402Polyethylene 4,4/-tetramethylenedibenzoate) 324.38 170 291Poly[ethylene 3,3'-(tetramethylenedioxy)-dibenzoate] 356.37 100 111Polyethylene 4,4/-(tetramethylenedioxy)-dibenzoate] 356.37 252 1841- , 3,3/-dimethoxy- 416.43 117 1914Polyethylene 4,4/-(tetramethylenediphenylene)-diurethane] 354.41 274 414Poly[ethylene (tetramethylenedithio)-diethylene-diurethane] 322.44 126 1897Polyethylene 2,4,8,10-tetraoxa-3,9-spiro(5.5)hendecane-dicaprylate] 470.60 85 797Polyethylene 4,4'-AiOdIbCnZOaIe) 300.33 200 291Polyethylene thiodienanthamide) 314.49 210 402Polyethylene thiodivaleramide) 258.38 220 402Polyethylene thiodivalerate) 260.35 28 1797- , methyl- (diol) 274.38 - 34 767Poly(ethylenethiohexamethylene sulfide) 176.34 86 1819Poly(ethylenethiotetramethylene sulfide) 148.29 89 181Poly(2,5-ethylene-1,3,4-triazole) 95.10- , 1 -amino- (triazole) 110.12 360 610Polyethylene 4,4/-(trimethylenedioxy)-dibenzoate] 342.35 190 1912- , 3,3'-dimethoxy- 403.00 105 1914Polyethylene 4,4/-(trimethylenediphenylene)-diurethane] 340.38 207 414Polyethylene WV'-trimethylenediterephthalamate) 396.40 205 781Polyethylene urea) 86.09 400 402Poly(ethylidene)Poly(4,4/-ethylidenediphenylene carbonate) 240.26 195 438- , phenyl- 316.36 230 438Polyethylidene p-phenylene) 104.15 205 1876Poly(ethylvinyl ether) 72.11 86 114- , 2-chloro- 106.55 150 114- , 2-methoxy- 102.13 73 114- , 2,2,2-trifluoro- 126.08 128 114Poly(formaldehyde), see Poly(oxymethylene) *Poly(2,5-furandipropionic anhydride) 194.19 67 1565Poly(furfural-«/r-dimethylketene) 166.18 180 1817Poly(l,4-P-D-glucose) [cellulose] 162.14- , triacetate *- , tributyrate *- , tricaprate 624.90 88 144- , tricaproate 456.58 94 144- , tricaprylate *- , triheptylate 498.66 88 144- , trilaurate 709.06 91 144- , trimyristate 793.22 106 144- , trinitrate *- , tripalmitate 877.38 105 144- , tripropionate *- , trivalerate 414.50 122 144- , 2.44-nitrate *Poly(glycine) *Poly(glycolic acid), see Poly(2-hydroxyacetic acid) *Poly(glycyl-12-aminododecanoic acid) *Poly(l,3-heptadiene), 1,4-- , 5-methyl- 110.20

trans-isotactic 180 1896

- , 6-methyl- *Poly(heptaldehyde)Poly(heptamethylene) 98.19- , 1,2-dichloro- 167.08

trans- 53 1925Poly(heptamethylene adipamide) *

References page VI-159

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Molecular MeltingPolymer weight point Refs.

Poly(heptamethylene azelamide) *Poly[4,4/-(heptamethylenedioxy)-diphenyleneoxy-/7-xylylene oxide] 418.54 207 1789Poly(heptamethylene disulfide) 162.31 130 1868Poly(heptamethylene AyV'-ethylenediterephthalamate) 452.51 275 781Poly(heptamethylene A^N'-hexamethylenediterephthalamate) 508.61 227 781Poly(heptamethylene hexamethylenediurea) 298.43 243 1892Poly(heptamethylene malonamide) 198.26- , dodecyl-(diacid) 366.59 147 1774Poly[heptamethylene 4,4/-(methylenediphenylene)diurethane] *Poly(heptamethylene 4-octenediamide) 266.38

trans-I. 261 657IL 249 657

Poly(heptamethylene oxamide-«/?-heptamethylene sebacamide) 480.69 248 1781Poly(heptamethylene A^AT'-pentamethylenediterephthalamate) 494.59 199 781Poly(heptamethylene p-phenylenediacetamide) 288.39 234 402Poly(heptamethylene pimelamide) *Poly(heptamethylene sebacamide) *Poly(heptamethylene sebacate) *Poly(heptamethylene suberamide) *Poly(heptamethylene 4,4/-sulfonyldibenzamide) 400.49- , 4,4-dimethyl- 428.55 268 1835Poly(heptamethylene terephthalamide) 260.34 328 1775

330 828341 829

Poly(heptamethylene terephthalate) *Poly(heptamethylene 2,5-tetrahydrofurandipropionamide) 310.44 148 402Poly(heptamethylene AW'-tetramethylenediterephthalamate) 480.56 269 781Poly(2,5-heptamethylene-l,3,4-triazole) 165.24- , 1-amino- 180.26 237 610Poly(heptamethylene MN'-trimethylenediterephthalamate) 466.53 222 781Poly(heptametylene undecanediamide) 310.48 195 2Poly(heptenamer) *PoIy(I -heptene)- , 6,6-dimethyl- 126.24 104 282- , 5-methyl- *Poly[4,4/-heptylidene)-diphenylene carbonate] 310.39 200 438Poly(hexadecamethylene adipate) *Poly(hexadecamethylene decamethylenediurethane) 482.75 128 634Poly(hexadecamethylene hexamethylenediurethane) 426.64 134 634Poly(hexadecamethylene 3-hexenedioate) *Poly(hexadecamethylene 4,4/-(methylenediphenylene)-diurethane] 508.70 152 634Poly(hexadecamethylene 4-octenedioate) *Poly(hexadecamethylene suberate) *Poly(hexadecamethylene/?-xylylenediurethane) 446.63 168 634PoIy(I-hexadecene) *PoIy(1,5-hexadiene), see Poly(cyclopentylene-a/Mnethylene) *PoIy(1,3-hexadiene), 1,4-- , 5-methyl-Poly(2,4-hexadiene), 2,5-- , 2,5-dimethyl-Poly(2,4-hexadienedioic acid), 2,5- 142.11- , diisopropyl ester *Poly(2,4-hexadienoic acid), 2,5- 112.13- , 6-amino- *Poly(2,4-hexadiyne adipate) 220.22 130 1782Poly(2,4-hexadiynediol), 2,5- 110.11- , l,6-bis(/7-methoxyphenylsulfonyl)- *Poly(2,4-hexadiyne hexamethylenediurethane) 278.31 149 1782Poly[2,4-hexadiyne (4,4/-methylenediphenylene)-diurethane] 360.37 150 1782Poly(hexafluoroisobutylene-tf/?-vinylidene fluoride) *Poly(hexamethylene adipamide) *- , 2,5-dihydroxy- (diacid) 258.32 163 402- , WV'-dimethyl- 254.37 75 402- , 3-methyl- (diacid) 240.35 216 291

230 1859

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Molecular MeltingPolymer weight point Refs.

- , 3-methyl-(diamine) 240.35 180 291-,/!-methyl- 240.35 145 291Poly(hexamethylene adipamide-a/f-hexamethylene oxamide) 396.53 268 1781Poly(hexamethylene adipate) *Poly[hexamethylene Af,7V'-adipoyldi(6-aminocaproate)] 454.61 147 1792Poly(hexamethylene adipoyldiurethane) 314.34 206 402Poly(hexamethylene azelamide) *Poly(hexamethylene azelamide-a/f-hexamethylene oxamide) 438.61 254 1781Poly(hexamethylene azelate) 270.37 53 539

55 764Poly(hexamethylene carbonate) 144.17 60 1820Poly(hexamethylene m-carboxycarbanilate) 263.29 96 1891Poly[hexamethylene/?-(carboxyphenoxy)-acetate] 278.30 50 290Poly[hexamethylene /?-(carboxyphenoxy)-caproate] 334.41 60 290Poly[hexamethylene/?-(carboxyphenoxy)-undecanoate] 404.55 72 290Poly[hexamethylene p-(carboxyphenoxy)-valerate] 320.38 60 290Poly[hexamethylene p-(carboxyphenylene)-acetamide] 260.34 227 1904Poly(hexamethylene 1,2-cyclohexylenediacetamide) 280.41 255 402Poly(hexamethylene 1,2-cyclohexylenedicarboxamide) 252.36

trans- 242 402Poly(hexamethylene 1,3-cyclohexylenedicarboxamide) 252.36

trans- 312 402Poly(hexamethylene 1,4-cyclohexylenedicarboxamide) 252.36

trans- 360 402Poly(hexamethylene 1,4-cyclohexylenedicarboxylate) 254.33

trans- 120 1174Poly(hexamethylene cyclopropylenedicarboxamide) 210.28

cis- 180 1860- , - , AUV'-dibutyl 432.45 20 402- , - , JV,iV'-diethyl- 376.34 5 402- , - , WV'-diisopropyl- 404.40 20 402- , - , AW-dimethyl- 348.29 30 402Poly(hexamethylene glutarate) 214.26 34 764Poly [hexamethy lene (hexamethylenedioxy)-dipropionamide] 342.48 105 402Poly[hexamethylene 4,4'-(hexamethylenedisulfonyl)-dibenzoate] 536.66 186 1174Poly[hexamethylene (hexamethylenedisulfonyl)-dicaproamide] 522.76 222 402Poly(hexamethylene Af,Af'-hexamethylenediterephthalamate) *Poly [hexamethy lene (hexamethylenedithio)-diethylene-diurethane] 406.60 106 1897Poly(hexamethylene hexamethylenediurethane) *Poly(hexamethylene 3-hexenedioate) *Poly(hexamethylene isophthalamide) 246.31 220 402

200 828- , 5-terf-butyl- (diacid) 302.42 210 402Poly(hexamethylene isophthalate) 248.28 140 111

80 1794Poly(hexamethylene 4,4/-isopropylidenedibenzamide) 364.49 180 402Poly(hexamethylene 4,4'-ketodibenzamide) 350.42 350 402Poly(hexamethylene ketodipropionamide) 254.33 180 402Poly(hexamethylene N,Ar'-rysyldiurea) 314.38- , methyl ester 328.41 180 1768Poly(hexamethylene malonamide) *- , butyl- (diacid) 240.35 161 1783

160 1774- , decyl- (diacid) 324.51 133 1783

134 1774- , dimethyl-(diacid) 212.19 117 402- , dodecyl- (diacid) 352.56 134 1783

132 1774-, heptadecyl- (diacid) 422.70 166 1774-, heptyl-(diacid) 282.43 135 1774-, hexadecyl-(diacid) 408.67 164 1783

160 1774-, hexyl-(diacid) 268.40 145 1783

144 1774-, nonyl- (diacid) 310.48 137 1774

References page VI-159

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Molecular MeltingPolymer weight point Refs.

- , octadecyl- (diacid) 436.72 167 1783163 1774

- , octyl-(diacid) 296.45 133 1783131 1774

- , pentadecyl- (diacid) 394.64 164 1774- , pentyl- (diacid) 254.37 151 1774- , propyl- (diacid) 226.32 163 1774- , tetradecyl- (diacid) 380.62 152 1783

148 1774- , tridecyl- (diacid) 366.59 133 1774- , undecyl-(diacid) 338.54 133 1774Poly(hexamethylene 3,3 '-methylenedibenzamide) 336.44 113 402Poly(hexamethylene 4,4/-methylenediphenylene) 336.44 132 402Poly[hexamethylene 4,4/-(methylenediphenylene)-dioxy-diacetamide] 396.49 174 402Poly[hexamethylene 4,4/-(methylenediphenylene)-diurea] 366.46 250 402- , 3,3'-dimethyl- 394.52 290 402- , - , AW'-diethyl- 450.63 120 402- , - , WV'-dipropyl- 478.68 90 402Poly[hexamethylene 4,4/-(methylenediphenylene)-diurethane] *Poly[hexamethylene (methylene-2,5-furan)-dicarboxamide] 250.30 115 402Poly[hexamethylene (p-methylenephenoxy)-diacetamide] 304.39 220 402

226 1202Poly[hexamethylene (p-methylenephenylene)-diacetamide] 283.39 204 1202Poly[hexamethylene (methylene-2,5-tetrahydrofuran)-dicarboxamide] 254.33 78 402Poly(hexamethylene naphthalenedicarboxamide) 298.39 200 402Poly(hexamethylene nonamethylenediurea) 326.48 243 1892Poly(hexamethylene octadecamethylenediurea) 452.73 192 634Poly(hexamethylene octadecanediamide) 394.64 192 454- , 9,10-dihydroxy- 426.64 172 402-, AW-dimethyl- 422.70 52 1877Poly(hexamethylene octamethylenedithiourea) 344.58 160 402Poly(hexamethylene octamethylenediurea) 312.46 239 634

253 1892255 402

Poly(hexamethylene octamethylenediurethane) 342.48 153 633Poly(hexamethylene 4-octenediamide) *Poly(hexamethylene 4-octenedioate) *Poly(hexamethylene 5-oxadodecanediamide) 312.45 149 1847Poly(hexamethylene 6-oxaheptadecanediamide) 382.59 160 1847Poly(hexamethylene 5-oxahexadecanediamide) 368.56 159 1847Poly(hexamethylene oxalate) *Poly(hexamethylene oxamide) *- , 3-oxypropyl- 228.29 240 402Poly(hexamethylene oxamide-tf/f-hexamethylene pimelamide) 410.56 259 1781Poly(hexamethylene oxamide-<z/£-hexamethylene sebacamide) 452.64 257 1781Poly(hexamethylene oxamide-a/J-hexamethylene suberamide) 424.58 260 1781Poly(hexamethylene 6-oxapentadecanediamide) 354.53 154 1847Poly(hexamethylene 5-oxasebacamide) 284.40 160 1847Poly(hexamethylene 5-oxatetradecanediamide) 340.51 155 1847Poly(hexamethylene 5-oxaundecanediamide) 298.43 152 1847Poly(hexamethylene oxide) *Poly(hexamethylene oxydiacetamide) 214.26 143 402

172 1894Poly(hexamethylene oxydiacetate) 216.23 51 1798

78 1791Poly(hexamethylene 4,4'-oxydibenzoate) 340.38 74 1939Poly(hexamethylene oxydibutyramide) 270.37 187 1847Poly(hexamethylene oxydicaproamide) 326.48 175 1847Poly(hexamethylene oxydienanthamide) 354.53 170 1847Poly[hexamethylene 4,4/-(oxydimethylene)-di-2-(l,3-dioxolane)-caprylamide] 554.77 145 797Poly(hexamethylene oxydipelarqonamide) 410.64 158 1847Poly[hexamethylene 4,4'-(oxydiphenylene)-dioxydiacetamide] 398.46 220 402Poly(hexamethylene 3,3/,4,4/-oxydiphenylenetetracarboximide) *Poly(hexamethyelene oxydivaleramide) 298.43 180 1847Poly(hexamethyleneoxymethylene oxide) *

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Molecular MeltingPolymer weight point Refs.

Poly(hexamethyleneoxy-/?-phenylene oxide) 192.26 170 1868Poly[hexamethylene (pentamethylenedisulfonyl)-dicaproamide] 508.73 226 402Poly(hexamethylene N,iV'-pentamethylenediterephthalamate) 480.56 238 781Poly[hexamethylene (pentamethylenedithio)-diethylene-diurethane] 392.57 98 1897Poly(hexamethylene pentamethylenediurea) 270.38 251 1892Poly[hexamethylene (p-phenoxy)-diacetamide] 290.36 86 402

180 1202Poly(hexamethylene m-phenylenediacetamide) 274.36 182 402Poly(hexamethylene/7-phenylenediacetamide) 274.36 300 454Poly(hexamethylene 3,3'-/?-phenylenedibutyramide) 330.47 196 1895- , 3,3'-dimethyl- (diacid) 358.52 193 1895Poly[hexamethylene (/?-phenylenedioxy)-diacetamide] 306.36 237 402

239 1202Poly(hexamethylene/?-phenylenedipropionamide) 302.42 290 291

295 402298 1202300 1895

- , 3-methyl- (diacid) 316.44 227 1895Poly(hexamethylene ra-phenylenedisulfonamide) *Poly(hexamethylene m-phenylenediurea) 276.34- , 4-methyl- (diisocyanate) 290.37 235 402Poly(hexamethylene S^'-phosphinylidenedibenzamide) 370.39- , methyl- (P) 384.42 172 402Poly(hexamethylene 4,4/-phosphinylidenedibenzamide) 370.39- , hydroxy- (P) 386.39 245 402-,methyl- (P) 384.42 213 402- , phenyl-(P) 445.48 231 402Poly(hexamethylene phthalamide) 246.31 150 1833Poly(hexamethylene phthalate) 248.28 2 1794Poly(hexamethylene pimelamide) 240.35 228 244

202 339Poly(hexamethylene pimelate) 242.32 50 539

55 764Poly(hexamethylene 1,4-piperazinediacetamide) 282.39 168 291Poly(hexamethylene Af,W-piperazinediterephthalamate) 464.52 255 1174Poly[hexamethylene (l,4-piperazinedithio)-dicarboxylate] 322.44 144 1934Poly(hexamethylene piperazinediurea) 254.33 245 402

265 1838Poly(hexamethylene propylenediurea) 270.33

racemic 230 1768Poly(hexamethylene 4(H)-pyran-2,6-dicarboxamide) 250.30- , 4-oxo- (diacid) 264.28 77 1905Poly(hexamethylene 2,3-pyrazoledicarboxamide) 238.29 140 1905Poly(hexamethylene 2,4-pyrazoledicarboxamide) 238.29 271 1905Poly(hexamethylene 2,3-pyridinedicarboxamide) 247.30 103 1905Poly(hexamethylene 2,4-pyridinedicarboxamide) 247.30 220 1905Poly(hexamethylene 2,5-pyridinedicarboxamide) 247.30 272 1905Poly(hexamethylene 2,6-pyridinedicarboxamide) 247.30 220 1905- , l,4-dihydro-4-oxo- 263.30 178 1905Poly(hexamethylene 3,4-pyridinedicarboxamide) 247.30 101 1905Poly(hexamethylene 3,5-pyridinedicarboxamide) 247.30 257 1905- , 2,6-dimethyl- (diacid) 275.35 140 1905Poly(hexamethylene pyromellitimide) *Poly(hexamethylene 2,5-pyrroledipropionamide) 291.40- , 1-methyl- (diacid) 305.42 180 402Poly(hexamethylene 2,5-pyrrolidinedipropionamide) 295.43- , 1-methyl- (diacid) 309.45 200 402Poly(hexamethylene 5-pyrrolidonylidenedipropionamide) 295.40 250 402Poly(hexamethylene sebacamide) *- , 3-methyl- (diamine) 296.46 153 402Poly(hexamethylene sebacate) *Poly(hexamethylene sebacoyldiurethane) 370.45 158 402Poly(hexamethylene 4,4'-silylenedibenzamide) 352.51- , dimethyl- (Si) 380.56 190 402Poly(hexamethylene suberamide) *

References page VI-159

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Molecular MeltingPolymer weight point Refs.

Poly(hexamethylene suberate) *Poly[hexamethylene A^V'-suberoyldi(/?-aminobenzoate)] 494.59 250 1174Poly(hexamethylene succinamide) *Poly(hexamethylene succinate) 200.23 57 305Poly(hexamethylene sulfide) *Poly(hexamethylene sulfone) *Poly(hexamethylene 4,4'-sulfonyldibenzamide) 386.46 310 1835Poly(hexamethylene 4,4'-sulfonyldibenzoate) 388.44 280 1174Poly[hexamethylene 4,4/-(sulfonyldimethylene)-dibenzoate] 416.49 252 1174Poly(hexamethylene sulfonyldivaleramide) 346.49 215 402Poly(hexamethylene sulfonyldivalerate) 348.46 92 1797Poly(hexamethylenesulfonylpentamethylene sulfone) *Poly(hexamethylenesulfonyltetramethylene sulfone) *Poly (hexamethylene L-tartaramide) 230.26- , di-O-methyl- *Poly(hexamethylene terephthalamide) *- , 2,5-dihydroxy- (diacid) 278.31 334 402- , 2,5-dimethyl- (diacid) 274.36 143 402- , WV'-dimethyl- 274.36 260 829- , methyl- (diacid) 260.34 248 402Poly(hexamethylene terephthalate) *Poly[hexamethylene N,Ar'-terephthaloyldi(6-aminocaproate)] 474.60 177 1792Poly(hexamethylene tetradecamethylenediurea) 396.62 198 634Poly(hexamethylene tetradecanediamide) 338.54 209 2Poly(hexamethylene 2,5-tetrahydrofurandipropionamide) 296.41 182 402Poly[hexamethylene (tetramethylenedioxy)-dipropionamide] 314.43 110 402Poly [hexamethylene (tetramethylenedisulfonyl)-dicaproamide] 494.70 241 402Poly(hexamethylene MN'-tetramethylenediterephthalamate) 466.53 290 781Poly [hexamethylene (tetramethylenedithio)-diethylene-diurethane] 378.55 120 1897Poly(hexamethylene tetramethylenediurea) 256.35 283 1892Poly[hexamethylene 2,4,8,10-tetraoxa-3,9-spiro(5.5)hendecane-dicaprylamide] 524.74 186 797Poly(hexamethylene 4,4/-tetrasiloxanylenedibenzamide) 490.81- , tetramethyl-tetraphenyl- (Si) 847.28 140 402Poly(hexamethylene thiodibutyramide) 286.43 200 291Poly (hexamethylene thiodienanthamide) 370.60 170 402Poly(hexamethylene thiodipropionamide) 258.38 216 1859

219 402Poly(hexamethylene thiodivaleramide) 314.49 180 402

185 1853Poly (hexamethylene thiodivalerate) 316.46 46 767Poly[hexamethylenethio-4,4 /-(methylenediphenylene)-diethylene sulfide] 370.61 88 1819Poly(hexamethylenethiopentamethylene sulfide) 218.42 65 1819Poly(hexamethylene 2,5-thiophenediacetamide) 280.39 230 1905Poly(hexamethylene 2,5-thiophenedicarboxamide) 252.33 315 1905Poly(hexamethylene 2,5-thiophenedipropionamide) 308.44 232 402

210 1905Poly(hexamethylenethiotetramethylene sulfide) 204.39 67 1819

75 181Poly(hexamethylenethioundecamethylene sulfide) 302.59 78 1923Poly(hexamethylene thiourea) 158.26 160 402Poly (2,5-hexamethylene-1,3,4-triazole) 151.21- , 1-amino- (triazole) 166.23 275 610Poly [hexamethylene 4,4/-(trimethylenediphenylene)-dioxy-diacetamide] 424.54 80 402Poly[hexamethylene(trimethylenedisulfonyl)-diimino-dicaproamide] 446.59 185 402Poly(hexamethylene MN'-trimethylenediterephthalamate) 452.51 256 781Poly(hexamethylene trimethylenediurea) 242.32 266 1892Poly (hexamethylene undecanediamide) 296.46- , 6-hydroxy- (diacid) 312.45 165 402Poly(hexamethylene urea) *Poly(hexamethylene 4,4/-vinylenedibenzamide) 348.44- , methyl- (diacid) 362.47 160 402Poly[hexamethylene 4,4'-(p-xylylenedisulfonyl)-dibutyrate] 488.61 196 1174Poly[hexamethylene AW-p-xylylenediterephthalamate) 514.58 285 1174Poly(hexamethylene /7-xylylenediurea) 304.39 306 634Poly(hexamethylene /?-xylylenediurethane) 306.36 209 634

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Molecular MeltingPolymer weight point Refs.

PoIy(1,3,5-hexatriene), 1,6- 80.13 250 1848Poly(hexenamer) 82.15 61 439PoIy(I-hexene) *- , 4,4-dimethyl- 112.22 350 90- , 4-ethyl- 112.22 234 632- , 3-methyl- 98.19 285 441- , 4-methyl- , 5-methyl- *Poly[4,4/-(2,2-hexylidene)-diphenylene carbonate] 296.36 200 438Poly(hydrazo adipamide) 142.16 320 402Poly(hydrazo azelamide) 184.24 237 402Poly(hydrazo docosanediamide) 366.59 210 402Poly(hydrazo dodecanediamide) 226.32 242 402Poly(hydrazo glutaramide) 128.13 140 402Poly(hydrazo pimelamide) 156.18 260 402Poly(hydrazo sebacamide) 198.27 260 402Poly(hydrazo suberamide) 170.21 275 402Poly(hydrazo succinamide) 114.10 360 402Poly(hydrazo thiodivaleramide) 230.33 180 402Poly(2-hydroxyacetic acid) [glycolic acid] *- , diethyl- 114.14 200 1928-,dimethyl- 86.09 190 1174- , isopropyl- 100.12 205 1930Poly(m-hydroxybenzoic acid) 120.11 176 1799Poly(p-hydroxybenzoic acid) *- , 3,5-di-tert-butyl- 232.32 480 1814- , 3-rc-propyl-PoIy(4,4 '-hydroxybibenzoic acid) *Poly(3-hydroxy-3-butenoic acid) *Poly(3-hydroxybutyric acid) *PoIy(I O-hydroxycapric acid)Poly(6-hydroxycaproic acid)Poly[5-hydroxy-2-(l,3-dioxane)-caprylic acid] *Poly(7-hydroxyenanthic acid) 128.17- , 4-methyl- (R + ) 142.20 36 1836Poly[4-hydroxymethylene-2-(l,3-dioxolane)-caprylic acid] *Poly[5-hydroxymethylene-5-methyl-2-(l,3-dioxane)-caprylic acid] 256.34 81 797Poly(5-hydroxy-3-oxavaleric acid) 102.09 89 305Poly[(p-hydroxyphenylene)-acetic acid] 134.13 280 1174Poly[3-(/?-hydroxyphenylene)-propenoic acid] 146.14

trans- 313 1943Poly(2-hydroxypropionic acid) [lactic acid] *Poly(3-hydroxypropionic acid) [propiolactone] *- , 2,2-bischloromethyl- 169.01 302 1174- , 3-chloromethyl- *- , 2,2-dibutyl- 184.28 245 1174- , 3-dichloromethyl- *- , 2,2-diethyl-- , 2,2-dimethyl- [pivalolactone] *- , 3-ethyl- [3-hydroxyvaleric acid]- , - , 1,1-dichloro- 169.01 235 1199- , 2-ethyl-2-methyl-- , 3-isopropyl- *- , 2-methyl-- , 3-methyl-, see Poly(3-hydroxybutyric acid) *- , 2-methyl-2-propyl- *Poly[4-hydroxytetramethylene-2-( 1,3-dioxolane)-caprylic acid] 270.37

cis- 23 797trans- 23 797

Poly(3-hydroxyvaleric acid), see poly(hydroxypropionic acid), 3-ethyl- *Poly(5-hydroxyvaleric acid) 100.12 55 1844

53 305- , 2,3,4-trimethoxy- 190.20 138 305Poly(2-imino-1,3-dithiapentamethylene) 119.20- , A -̂ethyl- 147.25 68 1927

References page VI-159

Page 22: C. MELTING POINTS OF POLYMERS In the following …nguyen.hong.hai.free.fr/EBOOKS/SCIENCE AND ENGINEERING...Molecular Melting Polymer weight point Refs. PoIy(1,4-cyclohexylenedimethylene

Molecular MeltingPolymer weight point Refs.

-,W-methyl- 133.23 89 1927- , N-phenyl- 195.30 128 1927- , -209.32 89 1927Poly(isobutene) *Poly(isobutylene oxide) *Poly(isobutylene sulfide) 88.17 187 548Poly(4,4'-isobutylidenediphenylene carbonate) 268.31 180 438Poly(isobutylvinyl ether) *Poly(isobutyraldehyde) *Poly(isophthalaldehyde) 134.13 80 1801Poly(isophthalic anhydride) 148.12 259 1565Poly[isophthalic 2,2/-(isophthaloyldiamino)-dibenzoic anhydride] 534.48 259 1871Poly[isophthalic (4,4/-isopropylidenediphenylenedioxy)-diacetic anhydride] 474.46 65 1871Poly[isophthalic 4,4;-(methylenedioxy)-dibenzoic anhydride] 418.36- , 3,3'-dimethoxy- 478.41 228 1871Poly[isophthalic (p-phenylenedioxy)-diacetic anhydride] 356.29 297 1871Poly[isophthalic 2,2'-(terephthaloyldiamino)-dibenzoic anhydride] 534.48 291 1871Poly[isophthalic 4,4/-(tetramethylenedioxy)-dibenzoic anhydride] 460.44 100 1871Poly[isophthalic 4,4'-(trimethylenedioxy)-dibenzoic anhydride] 446.41 165 1871- , 3,3'-dimethoxy- 506.46 216 1871Poly[isophthaloyl (m-carboxyphenoxyacetyl)-dihydrazide] 354.32 125 1833Poly[isophthaloyl (m-carboxyphenoxybutyryl)-dihydrazide] 382.38 265 1833Poly[isophthaloyl (m-carboxyphenoxycapryl)-dihydrazide] 410.43 249 1833Poly[isophthaloyl (m-carboxyphenoxypropionyl)-dihydrazide] 368.35 238 1833Poly[2,2 '-(isophthaloyldiamino)-dibenzoic terephthalic anhydride] 534.48 264 1871Poly(isophthaloyl dithionisophthaloyldihydrazide) 356.42 324 1889Poly(isoprene), see PoIy(1,3-butadiene), 2-methyl- *Poly(isopropenylmethyl ketone) *Poly(4,4/-isopropylidenedibenzoic anhydride) 266.30 235 1854

240 1855Polypsopropylidenedimethylene, 4,4/-(methylenediphenylene)-diurethane] 354.41 190 402Poly[isopropylidenedimethylene (1,4-piperazinedithio)-dicarboxylate] 306.40- , 2,5-dimethyl- 334.45 135 1934Poly(4,4/-isopropylidenediphenylene adipate) 338.40- , 3,3',5,5'-tetrachloro-Poly(4,4/-isopropylidenediphenylene carbonate) *- , 3,3;-dichloro- 323.18 210 540

230 736- , 3,3'-diisopropyl- 338.45 110 1915- , 3,3'-dimethyl- 282.34 170 540- , 3,3',5,5'-tetrabromo- 569.87 260 540

267 736- , 3,3',5,5'-ICtTaChIOrO- 392.06 260 540

275 736Poly(4,4'-isopropylidenediphenylene cyclopropylene-dicarboxylate) 322.36

cw- 130 1860trans- 180 1860

- , 1-methyl- (diacid) 336.39trans- 90 1860

- , 3-methyl- (diacid) 336.39trans- 130 1860

Poly[(4,4'-isopropylidenediphenylenedioxy)-diacetic anhydride] 326.35 202 1855Poly[(4,4'-isoproylidenediphenylenedioxy)-diacetic /?-phenylenedioxydiacetic anhydride] 502.52 230 1872Poly[(4,4'-isopropylidenediphenylenedioxy)-diacetic 4-pyridinedicarboxylic anhydride] 475.45 120 1872Poly[(4,4'-isopropylidenediphenylenedioxy)-diacetic terephthalic anhydride] 474.47 270 1871Poly(4,4'-isopropylidenediphenylene dithioladipate) 370.53 198 1922Poly(4,4 '-isopropylidenediphenylene dithiol-1,3-cyclohexylenedicarboxylate) 396.57 220 1922Poly(4,4'-isopropylidenediphenylene dithionisophthalate) 390.52 152 1889Poly(4,4'-isopropylidenediphenylene hexamethylenediurethane) 396.49 130 402Poly(4,4'-isopropylidenediphenylene isophthalamide) 356.42 424 1886Poly(4,4'-isopropylidenediphenylene malonate) 296.32 96 1868Poly(4,4'-isopropylidenediphenylene 4,4'-(methylenediphenylene)-diurethane) 478.55 193 402Poly(4,4'-isopropylidenediphenylene 1,4-piperazinedipropionate) 422.52 145 1875Poly(isopropylidene oxide) *Poly(isopropylidene sulfide) 74.14 125 1882

124 1800

Page 23: C. MELTING POINTS OF POLYMERS In the following …nguyen.hong.hai.free.fr/EBOOKS/SCIENCE AND ENGINEERING...Molecular Melting Polymer weight point Refs. PoIy(1,4-cyclohexylenedimethylene

Molecular MeltingPolymer weight point Refs.

Poly(isopropylvinyl ether) *Poly(ketone), see Poly(carbon monoxide-a/f-ethylene) *Poly(lactic acid), see Poly(2-hydroxypropionic acid) *Poly(Af,Af'-lysyl nonamethylenediurea) 356.47- , methyl ester 370.49 185 1768PoIy(WVMySyI pentamethylenediurea) 300.36- , methyl ester 314.38 175 1768PoIy(WVMySyI propylenediurea) 272.30- , methyl ester 286.33

racemic 175 1768Poly(WV;-lysyl tetramethylenediurea) 286.33- , methyl ester 300.36 185 1768Poly(WV'-lysyl trimethylenediurea) 272.30- , methyl ester 286.33 205 1768Poly(WV'-lysylurea) 172.18- , methyl ester 186.21 175 1768Poly(2-mercaptoacetic acid) 74.10 169 1922- , 2-methyl- 88.13 152 1922Poly(6-mercaptocaproic acid) *- , 4-methyl- 144.24 62 1922Poly(3-mercaptopropionic acid) 88.13 145 1922- , 2-phthalimido- 233.24 260 1922- , 2-(p-toluenesulfonamido)- 257.33 250 1922Poly(methacrylic acid) 86.09- , tert-butyl ester 142.12

isotactic 104 1851syndiotactic 165 1851

- , hexadecyl ester 310.52 22 1900- , methyl ester *- , octadecyl ester *Poly(methacrylonitrile) *Poly(methylene) (see also Poly(ethylene)) 14.03- , diphenyl- 166.22 220 1831- , di-/?-tolyl- 194.28 180 1831Poly(methylene adipamide) *Poly (4,4'-methylenedibenzoic anhydride) 238.24 332 1854Poly[4,4 '-(methylenedioxy)-dibenzoic anhydride] 270.24 220 1854Poly[4,4/-(methylenedioxy)-dibenzoic terephthalic anhydride] 418.36- , 3,3'-dimethoxy- 478.41 267 1871Pory(4,4'-metriylenediphenylene adipamide) 308.38 356 402- , 3,3'-dimethyl- (diamine) 336.44 326 402- , - , WV'-dibutyl- 448.65 57 402- , - , WV'-diethyl- 392.54 79 402- , - , AW-dihexyl- 504.76 45 402- , - , AW'-diisoamyl- 476.70 45 402- , - , WV'-diisopropyl- 420.60 61 402- , WV'-diethyl- 364.49 62 402- , A^V'-dimethyl- 336.44 120 402Poly(4,4/-methylenediphenylene adipate) 310.35 140 1901Poly(4,4/-methylenediphenylene azelamide) 350.46 275 402

268 1443290 1946

- , WV'-diethyl- 406.57 41 402- , WV'-dimethyl- 378.52 58 402Poly(4,4/-methylenediphenylene carbonate) *-,3,3'-dimethyl- 254.29 250 736-,diphenyl- 378.43 230 540- , phenyl- 302.33 215 438Poly[4,4/-(methylenediphenylene)-diethylene sulfide] 254.39 108 1819Poly(4,4'-methylenediphenylene disiloxanylenedipropionamide) 384.58-, tetramethyl- (Si) 440.69 90 402- , - , 3,3'-dimethyl- (diamine) 454.72 265 402Poly[3,3'-(4,4/-methylenediphenylene-A^,A^/-disuccinimidediyl)-imino-4,4/- methylenediphenylene amine] 556.62 295 1876Poly(4,4/-methylenediphenylene dodecanediamide) *Poly(4,4'-methylenediphenylene isophthalamide) 328.37 416 1886

References page VI-159

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