REGIONAL RCVICW OF UNCONTROLLED HAZARDOUS WAST? SITE CONTRACT LABORATORY DATA PACKAGE TOi U.S. Environmental Protection Agency Sample Management Office (SMO) P.O. Box 818 Alexandria, Virginia 22313 The hardcopied (laboratory name) N)lAS <Tc-rp. data package received at R0 9 ian :!. hea been reviewed and the quality aaauranca and performance data summarized. The data reviewed included: Caae No. SMO Sample No. SMO Sample No. SMO Sample No. 5>.;:c-..>v_ •?l» Contract No. requirea that specific analytical work be dona and that aaaociatad reporta be provided by the contractor to the Region*, EMSL-LV, and SMO. The general criteria uaed to determine the performance were baaad on an examination oft a Data conplatanaaa a Duplicate analyaia raaulta e Spectra Hatching quality a Blank analyaia raaulta a Surrogate apika reaulta a DFTPP and Bf8 performance raaulta a Matrix apika reaulta The data review forma for each of the above review itema are contained within the body of thia Commenta: ^«~<rr,*$-X. r>tvd<*lA •jvfu •HS-j^/>. i H -i., -T. / l (T^ '^ 15 SDMS Doc 000209647
Transcript
REGIONAL RCVICW OF UNCONTROLLED HAZARDOUS WAST? SITE CONTRACT LABORATORY DATA PACKAGE
TOi U.S. Environmental Protection Agency Sample Management Office (SMO) P.O. Box 818 Alexandria, Virginia 22313
The hardcopied (laboratory name) N)lAS <Tc-rp. data package received at R09ian :!. hea been reviewed and the quality aaauranca and performance data summarized. The data reviewed included:
Caae No. SMO Sample No. SMO Sample No. SMO Sample No.
5>.;:c-..>v_
•?l»
Contract No. requirea that specific analytical work be dona and that aaaociatad reporta be provided by the contractor to the Region*, EMSL-LV, and SMO. The general criteria uaed to determine the performance were baaad on an examination oft
a Data conplatanaaa a Duplicate analyaia raaulta
e Spectra Hatching quality a Blank analyaia raaulta
a Surrogate apika reaulta a DFTPP and Bf8 performance raaulta
a Matrix apika reaulta
The data review forma for each of the above review itema are contained within the body of thia
Commenta: ^«~<rr,*$-X. r>tvd<*lA
•jvfu •HS-j^/>. i H -i.,
-T. / l
(T^ '^
15
SD
MS
Doc
000209647
i. DATA conrrncss OCCKLIST
t Organic* analyaia data ah**ta
Baaa/nautral - sample chromatogram
Acid - sample chromatogram*
VOA - sample chromatograma
/ Peaticid* - sample chromatograma
S 5a«pla apactra - priority pollutanta and non-priority pollutanta
--'" Library rafaranca apactra
Blank analyaia data
s Duplicate analysis: on* duplicate analyaia of aample .__._____ «aa reported required by contract.
_*/_ Spike data
*s OFTPP critaria forma, spectra and liatinga
~^_ BTB criteria forms, apactra and liatinga
\/ B***/neutral - standard rafaranca apactra and chrosutogram
•/ Acid - standard reference apactra and chroaatograM
/ VOA- standard reference apactra and chroMtogram
_____£ Peaticide - standard chroMatogra*
_____ Baae/neutral aanaitivity teat
Acid s*naitivity t*«t
Tailing factor data
Remark*t
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II. SKCTftA NATCMIIC QUALITY
</ Tha apactra Mara axwinad and found to ba of good Matching quality.
Tha apactra Mara axa*inad and found to ba of poor matching quality dua to:
The reletlve percent difference (RPO) for each parameter group wee evaluated. The duplicate analyaia RPO acceptance criteria ehould bet
MaxiieuB Acceptable Fraction Percent Difference
Volatile 15* Baae/Neutral 50* Acid 40%
The RPOe exceeding the *axi«un acceptable percent difference werei
Concentration
Traction Compound Actual RPO Sample Duplicate
Volatile
Baae/Neutral
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F«ch duplicate analyeia MM examined in reference to coepounde detected in each analyeie. Thoee compounds which were not coieeon to each analyaie for the duplicate eaaple are lieted below:
Traction Seeple No. Conpound Concentration
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<x
r<
V ^
'/
ft
a ; ^
CJ 1
VII. OFT** A» BFB PIH MUSMU VSULTS
The OFTPP performance reeulta were reviewed and found to be within the specified criteria.
The BFB performance reeulte were reviewed and found to be within the specified criteria.
The (DFTPP/BF8) performance reeult(a) wee/were reviewed and the following abundances were found to fall outaide the specified criteria!
Required Actual Compound m/z Abundance Abundance
36.'
The (OFTPP/BFB) performance reaulta which were found to be outaide of the contractually required tuning requirements do not have an adverae technical iepact on the data.
Remarka:
22
VI. BLAMC ANALYSIS RTSULTS
The blank analytic waa raviawad. Tha contaminant a in the blank ara liatad balowi
fraction Compound Concantration
I. tut i-ferlisie.'e. ^hio^ti> 3
-_ ^_ 5"_ S"
Qi -n -Kwi*) jWJU».>fc£» _ fa_ jo
21
vni. cmamToaumr ocas
Typa of Coluani Packad Coluan Fu«ad Silica Capillary Coluan (FSCC)
Packad Co limn Chromatoqr^hy Chack
Tailing Factors
Banzidina
Pantachlorophanol
Acceptanca Window
Laaa than 3
La«a than 5
Actual
FSCC Chroaiatoqraphy Chack
50-ng banzidlna datectabla?
Pantachlorophanol raaponaa factor?
Yaa
Ya«
No
Ma
Remark*:
23
IX. STMCMDS
General ehape of tha- total ion chrmatograaii
BUM/ Acids Neutrals Volatile Pesticide*
Peak Shape
Interference*
Background
Area Response
4-nitropheool
2,4-dinitropnenol
Pentechlorophenol
Benzidina
Hexachlorocyclopent adiana
Nitrobenzene
laopnorona
Dinitrotoluenee
irkai
Reviewer'• Neeiet
FTS Telephone No.s
Coewerciel Telephone No.:
24
X. CALXMATIOH YCTIFICATIW - O P T I O N A L
(lapropar calibration ahould be reported under Oaaaanta Section on the Introduction Paga.)
Calibration verified at laaat once each 8-hour ahifti Yea No
